JPH04249848A - Display vacuum tube - Google Patents
Display vacuum tubeInfo
- Publication number
- JPH04249848A JPH04249848A JP41565590A JP41565590A JPH04249848A JP H04249848 A JPH04249848 A JP H04249848A JP 41565590 A JP41565590 A JP 41565590A JP 41565590 A JP41565590 A JP 41565590A JP H04249848 A JPH04249848 A JP H04249848A
- Authority
- JP
- Japan
- Prior art keywords
- film
- phosphor
- metal
- powder
- glass substrate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000843 powder Substances 0.000 claims abstract description 33
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims abstract description 30
- 229910052751 metal Inorganic materials 0.000 claims abstract description 25
- 239000002184 metal Substances 0.000 claims abstract description 25
- 239000011521 glass Substances 0.000 claims abstract description 12
- 239000000758 substrate Substances 0.000 claims abstract description 9
- 238000000034 method Methods 0.000 abstract description 14
- 239000007788 liquid Substances 0.000 abstract description 6
- 238000010894 electron beam technology Methods 0.000 abstract description 4
- 238000009966 trimming Methods 0.000 abstract description 4
- 238000009736 wetting Methods 0.000 abstract description 4
- 238000001035 drying Methods 0.000 abstract description 3
- 238000001704 evaporation Methods 0.000 abstract description 3
- 230000008020 evaporation Effects 0.000 abstract description 3
- 239000006228 supernatant Substances 0.000 abstract description 3
- 238000004519 manufacturing process Methods 0.000 abstract description 2
- 238000001771 vacuum deposition Methods 0.000 abstract description 2
- 238000010030 laminating Methods 0.000 abstract 1
- 239000010408 film Substances 0.000 description 33
- 230000000694 effects Effects 0.000 description 4
- 238000001556 precipitation Methods 0.000 description 4
- 239000010409 thin film Substances 0.000 description 4
- 238000000576 coating method Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 230000035515 penetration Effects 0.000 description 2
- 239000004111 Potassium silicate Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- ITHZDDVSAWDQPZ-UHFFFAOYSA-L barium acetate Chemical compound [Ba+2].CC([O-])=O.CC([O-])=O ITHZDDVSAWDQPZ-UHFFFAOYSA-L 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 238000010304 firing Methods 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 229910052738 indium Inorganic materials 0.000 description 1
- 239000004922 lacquer Substances 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- NNHHDJVEYQHLHG-UHFFFAOYSA-N potassium silicate Chemical compound [K+].[K+].[O-][Si]([O-])=O NNHHDJVEYQHLHG-UHFFFAOYSA-N 0.000 description 1
- 229910052913 potassium silicate Inorganic materials 0.000 description 1
- 235000019353 potassium silicate Nutrition 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- 238000007738 vacuum evaporation Methods 0.000 description 1
- 238000007740 vapor deposition Methods 0.000 description 1
- 238000005019 vapor deposition process Methods 0.000 description 1
Landscapes
- Cathode-Ray Tubes And Fluorescent Screens For Display (AREA)
Abstract
Description
【0001】0001
【産業上の利用分野】本発明は、蛍光面上にメタルバッ
ク膜を有する表示用真空管に関するものである。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a display vacuum tube having a metal back film on a phosphor screen.
【0002】0002
【従来の技術】図2は従来の表示用真空管として用いら
れている例えば光源用表示管の蛍光面の構造を示す要部
断面図である。同図において、1はガラス基体、2は蛍
光体膜、3はフィルミング膜、4はAlメタルバック膜
である。なお、フィルミング膜3は、その上に形成され
るAlメタルバック膜4を一時的にサポートするために
形成するもので、蛍光面焼成後は、消失し、残存しない
ものであり、説明の都合上、図示されている。したがっ
て蛍光面形成後は、蛍光体膜2上にAlメタルバック膜
4が直接的に配置されることになる。2. Description of the Related Art FIG. 2 is a sectional view of a main part showing the structure of a phosphor screen of a display tube for a light source, for example, which is used as a conventional display vacuum tube. In the figure, 1 is a glass substrate, 2 is a phosphor film, 3 is a filming film, and 4 is an Al metal back film. Note that the filming film 3 is formed to temporarily support the Al metal back film 4 formed thereon, and will disappear after the phosphor screen is fired and will not remain for convenience of explanation. Above, illustrated. Therefore, after the phosphor screen is formed, the Al metal back film 4 is placed directly on the phosphor film 2.
【0003】0003
【発明が解決しようとする課題】しかしながら、従来の
光源用表示管において、Alメタルバック膜4は、ガラ
ス基体1上に形成された蛍光体膜2上にフィルミング膜
3を形成し、その上方から真空蒸着法にてAl薄膜を形
成してAlメタルバック膜4としていたので、以下に示
すような問題があった。
(1)Alメタルバック膜4を一様な薄膜状に付着させ
るためにウェッティング工程,フィルミング工程が絶対
的に必要であり、それに用いるフィルミング液を形成す
るラッカー液の濃度管理,塗布工程,乾燥工程,トリミ
ング工程および焼成工程などが必要で多大な工数を要し
ていた。
(2)特にAl薄膜形成工程には、真空蒸着工程が必要
であり、この工程ではガラス管内を真空にしてAl蒸着
を行うという極めてコストの高い工程が必要であり、か
つ蒸発源の温度制御,膜厚のコントロールなどが技術的
に困難な点が多々あった。However, in the conventional light source display tube, the Al metal back film 4 is formed by forming the filming film 3 on the phosphor film 2 formed on the glass substrate 1, and Since the Al metal back film 4 was formed by forming an Al thin film using a vacuum evaporation method, there were the following problems. (1) A wetting process and a filming process are absolutely necessary in order to adhere the Al metal back film 4 in a uniform thin film form, and the concentration control and coating process of the lacquer liquid that forms the filming liquid used therein , a drying process, a trimming process, a firing process, etc., which required a large amount of man-hours. (2) In particular, the Al thin film formation process requires a vacuum evaporation process, which requires an extremely high cost process of vacuuming the inside of the glass tube and performing Al evaporation, and also requires temperature control of the evaporation source. There were many technical difficulties in controlling the film thickness.
【0004】0004
【課題を解決するための手段】このような課題を解決す
るために本発明による表示用真空管は、蛍光体膜上に形
成するメタルバック膜を金属粉体の積層膜で構成するも
のである。[Means for Solving the Problems] In order to solve the above-mentioned problems, in the display vacuum tube according to the present invention, the metal back film formed on the phosphor film is composed of a laminated film of metal powder.
【0005】[0005]
【作用】本発明においては、メタルバック膜を金属粉体
の積層膜により構成することでウェッティング工程,フ
ィルミング工程,トリミング工程,Al蒸着工程が不要
となる。[Function] In the present invention, since the metal back film is composed of a laminated film of metal powder, wetting steps, filming steps, trimming steps, and Al vapor deposition steps are not necessary.
【0006】[0006]
【実施例】以下、図面を用いて本発明の実施例を詳細に
説明する。図1は本発明による表示用真空管として光源
用表示管に適用した一実施例による構成を示す蛍光面の
要部断面図であり、前述の図と同一部分には同一符号を
付してある。同図において、ガラス基体1上には、高速
電子線用蛍光体を沈殿法にて沈殿させ、所定の膜厚の蛍
光体膜2を形成する。乾燥後、この蛍光体膜2上に例え
ばAl微粉末を溶解した沈殿液を注入し、一定時間静置
してその上澄み液を除去した後、乾燥してメタルバック
膜としてのAl粉末層5を形成する。このAl粉末層5
が蛍光体膜2上に付着されて光源用表示管の蛍光面が形
成される。Embodiments Hereinafter, embodiments of the present invention will be explained in detail with reference to the drawings. FIG. 1 is a sectional view of essential parts of a phosphor screen showing a structure according to an embodiment of the present invention applied to a display tube for a light source as a display vacuum tube, and the same parts as those in the previous figures are given the same reference numerals. In the figure, a phosphor for high-speed electron beams is precipitated on a glass substrate 1 by a precipitation method to form a phosphor film 2 having a predetermined thickness. After drying, a precipitate containing, for example, fine Al powder dissolved therein is injected onto the phosphor film 2, left to stand for a certain period of time, the supernatant liquid is removed, and then dried to form an Al powder layer 5 as a metal back film. Form. This Al powder layer 5
is deposited on the phosphor film 2 to form a phosphor screen of a light source display tube.
【0007】このような構成において、蛍光面に図示し
ないカソードからの電子を加速して射突させると、加速
された電子は、Al粉末層5を通過して蛍光体膜2に衝
突し、発光させる。生じた発光は、ガラス基体1を透過
して放射され、また、Al粉末層5に向かった発光は、
Al粉末面で反射され、蛍光体膜2を通してガラス基体
1から放射される。In such a configuration, when accelerated electrons from a cathode (not shown) strike the phosphor screen, the accelerated electrons pass through the Al powder layer 5 and collide with the phosphor film 2, emitting light. let The generated light is transmitted through the glass substrate 1 and emitted, and the light directed toward the Al powder layer 5 is
The light is reflected by the Al powder surface and is emitted from the glass substrate 1 through the phosphor film 2.
【0008】このような構成においては、カソードから
放射された電子を蛍光面へ加速する場合、Al粉末層5
を通過させ、その下部に形成された蛍光体膜2を励起す
る必要があるが、Al粉末層5の膜厚が余り厚すぎると
、電子が透過できず、したがって蛍光体が励起されない
。このAl粉末層5の最大厚みは、トムソン・ウェディ
ングトンの公式から侵入深さXeは、Xe=2.5×1
0−12 ・δ−1・V02(cm)より、計算でき、
例えば金属粉末層がAl粉末,加速電圧が10Kvの場
合、侵入深さXeは0.93μmとなる。これによって
金属粉体は鱗片状でかつ薄膜状の形状が適していること
になる。なお、金属粉体には、種々の形状があるが、例
えば前述した鱗片(フレーク)状の他に球状,偏平状,
棒状,箔状,超微粉末などがあり、これらのうちから適
したものを選んでAl粉末層5を形成することができる
。In such a configuration, when accelerating electrons emitted from the cathode to the phosphor screen, the Al powder layer 5
It is necessary to allow the Al powder layer 5 to pass through and excite the phosphor film 2 formed under it, but if the thickness of the Al powder layer 5 is too thick, electrons cannot pass therethrough and therefore the phosphor is not excited. The maximum thickness of this Al powder layer 5 is the penetration depth Xe from the Thomson-Weddington formula: Xe=2.5×1
It can be calculated from 0-12 ・δ-1・V02 (cm),
For example, when the metal powder layer is Al powder and the accelerating voltage is 10 Kv, the penetration depth Xe is 0.93 μm. This makes it suitable for the metal powder to have a scaly and thin film shape. Note that metal powder has various shapes; for example, in addition to the aforementioned flake shape, there are also spherical, flattened, and
There are rod-shaped, foil-shaped, ultrafine powder, etc., and the Al powder layer 5 can be formed by selecting a suitable one among these.
【0009】次に具体例を用いて説明する。まず、内面
の一部に陽極電極が形成された直径20mm,長さ60
mmの一端封じガラス管内の頭部に高速電子線用蛍光体
を沈殿塗布法にて形成し、膜厚約15μmの蛍光体膜2
を得る。次にこのガラス管内にケイ酸カリウムを含んだ
水溶液2mlを注入し、さらにAl微粉末(鱗状Al粉
末,厚さ0.1μm)と酢酸バリウムとを混合した沈殿
液を注入して約15分間静置する。所定時間経過後、上
澄み液を傾斜法にて除去し、乾燥してAl微粉末による
Al粉末層5を形成する。以上のようにして蛍光体膜2
,Al粉末層5を形成した後は、通常の真空管製造工程
により光源用表示管を形成する。Next, explanation will be given using a specific example. First, a diameter of 20 mm and a length of 60 mm was formed with an anode electrode formed on a part of the inner surface.
A phosphor for high-speed electron beams is formed on the head of a glass tube with one end sealed by a precipitation coating method to form a phosphor film 2 with a thickness of approximately 15 μm.
get. Next, 2 ml of an aqueous solution containing potassium silicate was injected into the glass tube, and then a precipitation solution containing a mixture of Al fine powder (scaly Al powder, thickness 0.1 μm) and barium acetate was injected, and the mixture was allowed to stand for about 15 minutes. place After a predetermined period of time has elapsed, the supernatant liquid is removed by a decanting method and dried to form an Al powder layer 5 made of fine Al powder. As described above, the phosphor film 2
, and after forming the Al powder layer 5, a light source display tube is formed by a normal vacuum tube manufacturing process.
【0010】なお、前述した実施例においては、金属粉
体層の形成にAl粉末を用いたAl粉末層5を形成した
場合について説明したが、本発明は、これに限定される
ものではなく、金属粉体として例えばAu,Ag,In
,Sn,Pdなどのうち少なくとも1種類を用いて形成
しても前述と同様の効果が得られる。また、前述した実
施例においては、このメタルバック膜を光源用表示管の
蛍光面に適用した場合について説明したが、本発明は、
これに限定されるものではなく、電子線の射突により発
光する蛍光面を有する陰極線管,ブラウン管やこれに類
する真空管に適用しても前述と同様の効果が得られる。[0010] In the above-mentioned embodiment, a case was explained in which the Al powder layer 5 was formed using Al powder to form the metal powder layer, but the present invention is not limited to this. Examples of metal powder include Au, Ag, In
, Sn, Pd, etc., the same effect as described above can be obtained. In addition, in the above-mentioned embodiment, the case where this metal back film was applied to the fluorescent screen of a display tube for a light source was explained, but the present invention
The present invention is not limited to this, and the same effects as described above can be obtained even when applied to cathode ray tubes, cathode ray tubes, and similar vacuum tubes that have fluorescent screens that emit light when electron beams strike them.
【0011】[0011]
【発明の効果】以上、説明したように本発明によれば、
蛍光体膜上に形成するメタルバック膜を金属粉体の積層
体で構成したことにより、従来必要であったウェッティ
ング工程,フィルミング工程,トリミング工程,Al蒸
着工程が全て不要となり、大幅な省力化が可能となると
ともにこれらの工程での不良発生を皆無とすることがで
きる。また、極めて簡便な沈殿法にてメタルバック膜が
形成できるので、不良品の発生を著しく減少させること
ができるなどの極めて優れた効果が得られる。[Effects of the Invention] As explained above, according to the present invention,
Since the metal back film formed on the phosphor film is composed of a laminate of metal powder, the conventionally necessary wetting process, filming process, trimming process, and Al vapor deposition process are all unnecessary, resulting in significant labor savings. In addition, it is possible to completely eliminate the occurrence of defects in these steps. Furthermore, since the metal back film can be formed by an extremely simple precipitation method, extremely excellent effects such as the ability to significantly reduce the occurrence of defective products can be obtained.
【図1】本発明による表示用真空管の一実施例による構
成を示す光源用表示管の蛍光面の要部断面図である。FIG. 1 is a sectional view of a main part of a phosphor screen of a display tube for a light source, showing the structure of an embodiment of a display vacuum tube according to the present invention.
【図2】従来の光源用表示管の構成を示す蛍光面の要部
断面図である。FIG. 2 is a sectional view of a main part of a fluorescent screen showing the configuration of a conventional light source display tube.
1 ガラス基体 2 蛍光体膜 5 Al粉末層 1 Glass substrate 2. Phosphor film 5 Al powder layer
Claims (1)
ク膜が順次積層して形成され、前記メタルバック膜は金
属粉体の積層膜で構成することを特徴とした表示用真空
管。1. A display vacuum tube characterized in that a phosphor film and a metal back film are sequentially laminated on a glass substrate, and the metal back film is composed of a laminated film of metal powder.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP41565590A JPH04249848A (en) | 1990-12-28 | 1990-12-28 | Display vacuum tube |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP41565590A JPH04249848A (en) | 1990-12-28 | 1990-12-28 | Display vacuum tube |
Publications (1)
Publication Number | Publication Date |
---|---|
JPH04249848A true JPH04249848A (en) | 1992-09-04 |
Family
ID=18523991
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP41565590A Pending JPH04249848A (en) | 1990-12-28 | 1990-12-28 | Display vacuum tube |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPH04249848A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2011108409A (en) * | 2009-11-13 | 2011-06-02 | Pureron Japan Co Ltd | Field emission lamp |
JP2013536540A (en) * | 2010-06-09 | 2013-09-19 | 海洋王照明科技股▲ふん▼有限公司 | Conductive adhesive mixture, fluorescent screen anode plate and method for producing them |
-
1990
- 1990-12-28 JP JP41565590A patent/JPH04249848A/en active Pending
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2011108409A (en) * | 2009-11-13 | 2011-06-02 | Pureron Japan Co Ltd | Field emission lamp |
JP2013536540A (en) * | 2010-06-09 | 2013-09-19 | 海洋王照明科技股▲ふん▼有限公司 | Conductive adhesive mixture, fluorescent screen anode plate and method for producing them |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP3455380B2 (en) | Field emission device using improved emitter on metal foil and method of making such device | |
JP2006127794A (en) | Image display device | |
JP2918524B2 (en) | Plasma display panel protective layer and method of forming the same | |
JPH04249848A (en) | Display vacuum tube | |
JPS601735B2 (en) | cathode ray tube | |
US2178238A (en) | Electric discharge device | |
JP2793532B2 (en) | Method for manufacturing plasma display panel | |
US20070080637A1 (en) | Image display apparatus and method of manufacturing the image display apparatus | |
US3764367A (en) | Television picture tube having an electron scattering prevention film | |
US3819409A (en) | Method of manufacturing a display screen | |
JP3015093B2 (en) | Plasma display panel and method of manufacturing the same | |
US3526527A (en) | Process of forming a cathodoluminescent screen | |
US2758942A (en) | Cathode-ray tube of the kind comprising a luminescent screen | |
JP3044072B2 (en) | Method for manufacturing plasma display panel | |
US2256341A (en) | Photoelectric device and method of manufacture | |
KR100786858B1 (en) | Flat panel display device having reflective layer and manufacturing method of the reflective layer | |
US2776227A (en) | Method of processing a photosensitive mosaic electrode | |
JPH11167886A (en) | Fluorescent character display device | |
JPH07140906A (en) | Picture display device | |
JPH02270250A (en) | Manufacture of electronic tube | |
JPH02281531A (en) | Diode and its manufacture | |
JPS62229652A (en) | Cold cathode fluorescent lamp | |
JP2000106101A (en) | Field emission display element | |
JPS60160549A (en) | Fluorescent character display tube | |
JPH05182608A (en) | Field emission type electron tube |