JPH0249234B2 - KINZOKUSHOKUEZUKEHOHO - Google Patents
KINZOKUSHOKUEZUKEHOHOInfo
- Publication number
- JPH0249234B2 JPH0249234B2 JP18088081A JP18088081A JPH0249234B2 JP H0249234 B2 JPH0249234 B2 JP H0249234B2 JP 18088081 A JP18088081 A JP 18088081A JP 18088081 A JP18088081 A JP 18088081A JP H0249234 B2 JPH0249234 B2 JP H0249234B2
- Authority
- JP
- Japan
- Prior art keywords
- adhesive
- layer
- deposited layer
- transfer
- aluminum vapor
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000004744 fabric Substances 0.000 claims description 24
- 239000000853 adhesive Substances 0.000 claims description 21
- 230000001070 adhesive effect Effects 0.000 claims description 21
- 229910052782 aluminium Inorganic materials 0.000 claims description 14
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 14
- 239000011888 foil Substances 0.000 claims description 14
- 238000000034 method Methods 0.000 claims description 14
- 239000003086 colorant Substances 0.000 claims description 6
- 238000010030 laminating Methods 0.000 claims description 3
- 238000010422 painting Methods 0.000 claims description 3
- 239000002904 solvent Substances 0.000 claims description 3
- 229910052751 metal Inorganic materials 0.000 claims description 2
- 239000002184 metal Substances 0.000 claims description 2
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 claims 1
- 239000010410 layer Substances 0.000 description 28
- 238000005108 dry cleaning Methods 0.000 description 6
- 229920000728 polyester Polymers 0.000 description 6
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 5
- -1 polypropylene Polymers 0.000 description 5
- 239000004743 Polypropylene Substances 0.000 description 3
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 3
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 3
- 229910052737 gold Inorganic materials 0.000 description 3
- 239000010931 gold Substances 0.000 description 3
- 229920001155 polypropylene Polymers 0.000 description 3
- 229920002635 polyurethane Polymers 0.000 description 3
- 239000004814 polyurethane Substances 0.000 description 3
- 229910052709 silver Inorganic materials 0.000 description 3
- 239000004332 silver Substances 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 239000000020 Nitrocellulose Substances 0.000 description 2
- 239000012790 adhesive layer Substances 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 239000000986 disperse dye Substances 0.000 description 2
- 239000000975 dye Substances 0.000 description 2
- 229920001971 elastomer Polymers 0.000 description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 229920001220 nitrocellulos Polymers 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 2
- VDBJCDWTNCKRTF-UHFFFAOYSA-N 6'-hydroxyspiro[2-benzofuran-3,9'-9ah-xanthene]-1,3'-dione Chemical compound O1C(=O)C2=CC=CC=C2C21C1C=CC(=O)C=C1OC1=CC(O)=CC=C21 VDBJCDWTNCKRTF-UHFFFAOYSA-N 0.000 description 1
- 239000001856 Ethyl cellulose Substances 0.000 description 1
- ZZSNKZQZMQGXPY-UHFFFAOYSA-N Ethyl cellulose Chemical compound CCOCC1OC(OC)C(OCC)C(OCC)C1OC1C(O)C(O)C(OC)C(CO)O1 ZZSNKZQZMQGXPY-UHFFFAOYSA-N 0.000 description 1
- CYTYCFOTNPOANT-UHFFFAOYSA-N Perchloroethylene Chemical group ClC(Cl)=C(Cl)Cl CYTYCFOTNPOANT-UHFFFAOYSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004721 Polyphenylene oxide Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000004840 adhesive resin Substances 0.000 description 1
- 229920006223 adhesive resin Polymers 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 229920001249 ethyl cellulose Polymers 0.000 description 1
- 235000019325 ethyl cellulose Nutrition 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000012948 isocyanate Substances 0.000 description 1
- 150000002513 isocyanates Chemical class 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920001228 polyisocyanate Polymers 0.000 description 1
- 239000005056 polyisocyanate Substances 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- 229950011008 tetrachloroethylene Drugs 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/02—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with cellulose derivatives
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Printing Methods (AREA)
- Decoration By Transfer Pictures (AREA)
- Physical Vapour Deposition (AREA)
Description
【発明の詳細な説明】
本発明は布地等に対して金又は銀色等の金属色
に絵付けする方法に関する。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a method for painting cloth or the like in a metallic color such as gold or silver.
従来、布地等へ金又は銀色の絵柄を施す方法と
して、三種類の方法が知られており、その第一は
金又は銀色の金属粉インキにより基布に直刷りす
る方法である。この方法は、揉みやドライクリー
ニングに弱いという欠点がある。また第二の方法
は支持体上に離型層を介してアルミニウム蒸着層
を設け、その上に熱接着性樹脂層を形成した転写
箔を基布に重ね、熱圧により転写し、支持体を剥
離する方法である。この方法は、熱接着性樹脂を
用いるために、揉みやドライクリーニングに弱い
という欠点がある。第三の方法は、支持体上に離
型層を介してアルミニウム蒸着層を設けて成る転
写箔を、予め接着剤の塗布された基布上に重ねて
転写し、支持体を剥離する方法であり、この方法
は蒸着層の転写された部分が硬くなり、かつドラ
イクリーニングに弱い。 Conventionally, three methods are known for applying gold or silver designs to fabrics, etc., and the first is a method of directly printing onto the base fabric using gold or silver metallic powder ink. This method has the disadvantage that it is susceptible to rubbing and dry cleaning. In the second method, an aluminum vapor-deposited layer is provided on the support via a release layer, a transfer foil with a heat-adhesive resin layer formed thereon is placed on the base fabric, and the transfer is performed using heat and pressure to remove the support. This is a peeling method. This method has the disadvantage that it is susceptible to rubbing and dry cleaning because it uses a thermoadhesive resin. The third method is to transfer a transfer foil comprising an aluminum vapor-deposited layer on a support via a release layer onto a base fabric coated with an adhesive in advance, and then peel off the support. However, in this method, the transferred portion of the vapor deposited layer becomes hard and is susceptible to dry cleaning.
本発明は以上のような事情に鑑みてなされたも
ので、支持フイルムに離型層を介してアルミニウ
ム蒸着層を設けた転写箔の表面に、ドライラミネ
ート機により部分的に接着剤を塗布し、接着剤中
の溶剤を乾燥し、かつ接着剤が十分接着力を有す
る間に基布を重ねて接着し、この後支持フイルム
を剥離して、アルミニウム蒸着層を部分的に転写
することを特徴とする金属色絵付方法であり、転
写箔として、離型層上に、アルミニウム蒸着層と
共に着色剤層を有するものを用いることもでき
る。着色剤層は、普通、離型層と蒸着層の間に設
けられ、転写後にはこの着色剤層を透して、蒸着
層が見えるようになる。 The present invention has been made in view of the above-mentioned circumstances, and involves partially applying an adhesive to the surface of a transfer foil in which an aluminum vapor-deposited layer is provided on a support film via a release layer, using a dry laminating machine. The method is characterized in that the solvent in the adhesive is dried and the base fabrics are layered and adhered while the adhesive has sufficient adhesive strength, and then the supporting film is peeled off to partially transfer the aluminum vapor deposited layer. This is a metal color painting method, and a transfer foil having a coloring agent layer on a release layer together with an aluminum vapor-deposited layer can also be used. A colorant layer is usually provided between the release layer and the vapor deposited layer, and the vapor deposited layer becomes visible through the colorant layer after transfer.
以下、図面を参照して本発明を説明する。図面
は本発明の実施例を示し、第１図は転写箔及び転
写箔上に塗布された接着剤の部分断面図である。 The present invention will be described below with reference to the drawings. The drawings show an embodiment of the invention, and FIG. 1 is a partial cross-sectional view of a transfer foil and an adhesive applied on the transfer foil.
転写箔は支持フイルム１、離型層２、着色層
３、アルミニウム蒸着層４から成り、具体的には
支持フイルム１として延伸又は無延伸のポリプロ
ピレンフイルム、ポリエチレン、ポリエステル等
の合成樹脂フイルムが使用できる。また離型層２
としては、ニトロセルロース、塩化ゴム、アクリ
ル、ポリエステル、ポリエーテル等、もしくはこ
れらにシリコン、ワツクス系樹脂等の離型添加剤
を混合した組成物が使用でき、必要に応じて更に
イソシアネート等を添加できる。 The transfer foil consists of a support film 1, a release layer 2, a colored layer 3, and an aluminum vapor deposited layer 4. Specifically, as the support film 1, stretched or unstretched polypropylene film, polyethylene, polyester, or other synthetic resin film can be used. . Also, release layer 2
As the material, nitrocellulose, chlorinated rubber, acrylic, polyester, polyether, etc., or a composition obtained by mixing these with a mold release additive such as silicone or wax-based resin can be used, and if necessary, isocyanate etc. can be further added. .
着色層３は主成分として着色剤とバインダーと
を含むもので、着色剤としては顔料もしくは分散
染料や油溶性染料等の染料を用いることができ
る。またバインダーとしてはエチルセルロース、
ニトロセルロース、塩化ゴム、アクリル、ポリエ
ステル、ポリウレタン等が使用できる。 The colored layer 3 contains a coloring agent and a binder as main components, and as the coloring agent, a pigment or a dye such as a disperse dye or an oil-soluble dye can be used. In addition, as a binder, ethyl cellulose,
Nitrocellulose, chlorinated rubber, acrylic, polyester, polyurethane, etc. can be used.
アルミニウム蒸着層４は厚みが400〜1000Å程
度で良い。 The aluminum vapor deposited layer 4 may have a thickness of about 400 to 1000 Å.
この転写箔の上に、転写する直前に接着剤５を
塗布する。塗布はドライラミネート機により行な
われ、塗布の後、連続的に接着剤５の溶剤の乾
燥、基布６との重合及び転写が行なわれる。接着
剤５はポリイソシアネートと２個以上の活性水素
原子を持つ化合物との反応によつて接着力を生じ
る二液混合型のポリウレタン接着剤であり、２個
以上の活性水素原子を持つ化合物としてはポリエ
ステル系、アクリル系、エーテル系のものが使用
できる。接着剤５は部分的、即ち、所望の柄状に
塗布するもので、版深100μ前後のグラビアシリ
ンダーにより塗布することが好ましい。 Adhesive 5 is applied onto this transfer foil immediately before transfer. The coating is carried out using a dry laminating machine, and after the coating, the solvent of the adhesive 5 is continuously dried, polymerized with the base fabric 6, and transferred. Adhesive 5 is a two-component polyurethane adhesive that generates adhesive strength through the reaction between polyisocyanate and a compound having two or more active hydrogen atoms, and as a compound having two or more active hydrogen atoms, Polyester-based, acrylic-based, and ether-based materials can be used. The adhesive 5 is applied partially, that is, in a desired pattern shape, and is preferably applied using a gravure cylinder having a plate depth of about 100 μm.
転写箔を基布６に重ね、十分に接着した後、支
持フイルム１を剥離する。基布６としては、天然
繊維、合成繊維あるいはその混紡の織物、編物、
交織品、混撚品もしくは不織布、フロツキー（植
毛布）等が利用できる。第２図は、転写後、支持
フイルム１を剥離した後の基布６を示す。着色層
３及び蒸着層４は、接着層５の塗布した部分だけ
が基布６に転写され、その他の部分は支持フイル
ムに残る。 After the transfer foil is superimposed on the base cloth 6 and sufficiently adhered, the support film 1 is peeled off. The base fabric 6 may be woven or knitted fabrics made of natural fibers, synthetic fibers, or blends thereof.
Mixed woven products, mixed twisted products, non-woven fabrics, flocked fabrics, etc. can be used. FIG. 2 shows the base fabric 6 after the support film 1 has been peeled off after the transfer. Regarding the colored layer 3 and the vapor deposited layer 4, only the portion coated with the adhesive layer 5 is transferred to the base fabric 6, and the other portions remain on the support film.
本発明は以上のような構成であり、接着剤とし
てウタン系接着剤を用いているので、柔軟性があ
り、しかも接着剤が三次元網目構造になるので、
耐洗濯性、耐ドライクリーニング性が優れてい
る。こうして得られた基布は、例えば、和服地、
洋服地、コイノボリの布地、建装材、フスマ地等
に適している。 The present invention has the above-described structure, and since it uses a utane adhesive as the adhesive, it is flexible, and the adhesive has a three-dimensional network structure, so
Excellent washing and dry cleaning resistance. The base fabric obtained in this way is, for example, Japanese kimono fabric,
Suitable for clothing, Koinobori fabric, building materials, fusuma fabric, etc.
実施例 １
延伸ポリプロピレンフイルム（厚さ30μ）に離
型剤としてアクリル系ウレタン樹脂（東洋インキ
(株)製）を２ｇ／m2グラビアコートし、この上に、
C.I.Disperse Yellow−７の分散染料をアクリル
系ウレタン樹脂で練肉して得られたインキを、版
深30μのベタ版でグラビアコートし、さらにこの
上にアルミニウムを500Åの厚さに真空蒸着して
転写箔を得た。Example 1 Acrylic urethane resin (Toyo Ink Co., Ltd.) was added as a release agent to a stretched polypropylene film (thickness 30μ).
Co., Ltd.) was gravure coated at 2g/ m2 , and on top of this,
The ink obtained by kneading CIDisperse Yellow-7 disperse dye with acrylic urethane resin is gravure coated on a solid plate with a plate depth of 30μ, and then aluminum is vacuum-deposited to a thickness of 500Å and transferred. Got the foil.
次にこの転写箔のアルミニウム面に版深100μ
の花柄のグラビア版を用い、ポリエステル系ポリ
ウレタン接着剤（東洋モートン(株)製；BHS
＃6020A.＆．Ｃ）を柄印刷し、これを70℃、30
秒間乾燥させ、ポリエステル100％の布地（ポン
ジイー）に重ね、ニツプロールで加圧した。その
後、１日間常温で放置し、延伸ポリプロピレンフ
イルムを剥離したところ、花柄で金色に輝く風合
良好な金色絵付布が得られた。 Next, apply a plate depth of 100μ to the aluminum surface of this transfer foil.
Using a gravure plate with a floral pattern, polyester-based polyurethane adhesive (manufactured by Toyo Morton Co., Ltd.; BHS
#6020A.&． Print pattern C) and heat it at 70℃ for 30
It was dried for seconds, layered on 100% polyester fabric (Ponzi-E), and pressed with Nitzprol. Thereafter, when the stretched polypropylene film was left at room temperature for one day and peeled off, a gold-painted cloth with a floral pattern and a good texture was obtained.
耐ドライクリーニング性の検査のため、上の布
地をドライクリーニング用のパークロルエチレン
に30分浸漬したが、アルミニウムと布の剥離は起
こらず、良好な密着性を示した。 To test dry cleaning resistance, the upper fabric was immersed in perchlorethylene for dry cleaning for 30 minutes, but no peeling occurred between the aluminum and the fabric, showing good adhesion.
図面は本発明の実施例を示し、第１図は接着剤
を塗布した転写箔の部分断面図、第２図は転写後
の基布の部分断面図である。
１……支持フイルム、２……離型層、３……着
色層、４……アルミニウム蒸着層、５……接着
層、６……基布。
The drawings show an embodiment of the present invention; FIG. 1 is a partial sectional view of a transfer foil coated with an adhesive, and FIG. 2 is a partial sectional view of a base fabric after transfer. DESCRIPTION OF SYMBOLS 1... Support film, 2... Release layer, 3... Colored layer, 4... Aluminum vapor deposited layer, 5... Adhesive layer, 6... Base fabric.
Claims (1)
蒸着層を設けた転写箔の表面に、ドライラミネー
ト機により部分的にウレタン系接着剤を塗布し、
接着剤中の溶剤を乾燥し、かつ接着剤が十分接着
力を有する間に基布を重ねて接着し、この後支持
フイルムを剥離して、アルミニウム蒸着層を部分
的に転写することを特徴とする金属色絵付方法。 ２ 転写箔が、離型層上に、アルミニウム蒸着層
と共に着色剤層を有していることを特徴とする前
記第１項記載の方法。[Claims] 1. A urethane adhesive is partially applied to the surface of a transfer foil in which an aluminum vapor-deposited layer is provided on a support film via a release layer using a dry laminating machine,
The method is characterized in that the solvent in the adhesive is dried and the base fabrics are layered and adhered while the adhesive has sufficient adhesive strength, and then the supporting film is peeled off to partially transfer the aluminum vapor deposited layer. Metal color painting method. 2. The method according to item 1, wherein the transfer foil has a colorant layer on the release layer together with an aluminum vapor deposited layer.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP18088081A JPH0249234B2 (en) | 1981-11-11 | 1981-11-11 | KINZOKUSHOKUEZUKEHOHO |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP18088081A JPH0249234B2 (en) | 1981-11-11 | 1981-11-11 | KINZOKUSHOKUEZUKEHOHO |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5882783A JPS5882783A (en) | 1983-05-18 |
| JPH0249234B2 true JPH0249234B2 (en) | 1990-10-29 |
Family
ID=16090945
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP18088081A Expired - Lifetime JPH0249234B2 (en) | 1981-11-11 | 1981-11-11 | KINZOKUSHOKUEZUKEHOHO |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0249234B2 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH01184883A (en) * | 1988-01-13 | 1989-07-24 | Hitachi Ltd | Resonance tunneling three-pole device |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2501792B2 (en) * | 1986-05-02 | 1996-05-29 | 恵和商工株式会社 | Method for producing thin film coating film having metal vapor deposition layer |
| JP2008181677A (en) * | 2007-01-23 | 2008-08-07 | Fujikura Ltd | Shielded connector |
-
1981
- 1981-11-11 JP JP18088081A patent/JPH0249234B2/en not_active Expired - Lifetime
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH01184883A (en) * | 1988-01-13 | 1989-07-24 | Hitachi Ltd | Resonance tunneling three-pole device |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS5882783A (en) | 1983-05-18 |
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