JP4523313B2 - Hydrogen gas production power generation system and operation method thereof - Google Patents

Description

  In the present invention, after reforming the hydrogen-containing fuel to obtain a reformed gas, unnecessary substances are removed from the reformed gas to purify the hydrogen-rich hydrogen gas, and the hydrogen gas is used as a stationary fuel cell and The present invention relates to a hydrogen gas production power generation system supplied to a fuel cell vehicle and an operation method thereof.

  For example, after reforming a hydrocarbon fuel such as natural gas or a hydrogen-containing fuel containing alcohol such as methanol to obtain a hydrogen-containing gas (reformed gas), the hydrogen-containing gas is purified to obtain a high-purity hydrogen gas. A hydrogen production apparatus is employed to supply fuel cells (power generation units) and the like.

  In hydrogen production equipment, steam fuel reforming of hydrocarbon fuels such as natural gas and city gas produces a hydrogen-containing gas that is a high-concentration hydrogen-rich gas. The high-purity hydrogen is separated from the hydrogen-containing gas via

  As this type of hydrogen production apparatus, for example, a technique disclosed in Patent Document 1 is employed. In this Patent Document 1, as shown in FIG. 5, methanol as a fuel is mixed with water and vaporized by the vaporizer 1, and then introduced into the reformer 2 to be hydrogen, carbon monoxide, carbon dioxide, etc. A reformed gas consisting of In the reformed gas obtained, only hydrogen gas is separated from other gases by the hydrogen separator 3, and this hydrogen gas is stored in the buffer device 6 via the decompressor 4 and the booster 5.

  Hydrogen stored in the buffer device 6 is supplied to the fuel cell 8 as a fuel of a polymer electrolyte fuel cell (PEFC) 8 through a hydrogen supply device 7 such as a pressure reducing valve. The fuel cell 8 is supplied with air in addition to hydrogen as fuel. In addition, an appropriate amount of hydrogen is bypassed from the buffer device 6 to the fuel cell 8 via the line 9, and air is added to the hydrogen to be necessary in the vaporizer 1, the reformer 2, or the hydrogen separator 3. Compensates for heat.

Japanese Patent Laid-Open No. 7-320763 (FIG. 1)

  Recently, a stationary fuel cell is used as a power source for household use, and hydrogen gas obtained by reforming and purifying fuel such as city gas, LPG, kerosene, etc. is supplied to the stationary fuel cell, and the hydrogen gas is supplied to a fuel cell vehicle. A hydrogen gas production power generation system for filling a high-pressure tank has been developed.

  Therefore, when the power generation device of Patent Document 1 is to be employed in the above-described hydrogen gas production power generation system, the hydrogen gas stored in the buffer device 6 is used as the fuel cell 8 that is a stationary fuel cell and the high pressure of the fuel cell vehicle. It is necessary to supply selectively to the tank.

  However, the fuel cell vehicle is provided with a high-pressure tank that is filled with hydrogen gas at a considerably high pressure in order to ensure a desired travel distance. In order to fill the high-pressure tank with the hydrogen gas, a buffer device 6 is provided. The hydrogen gas filled inside must be maintained at a fairly high pressure. On the other hand, the hydrogen gas supplied to the fuel cell 8 is set to a low pressure, and the hydrogen gas stored in the buffer device 6 can be supplied to the fuel cell 8 until the internal pressure reaches substantially zero, for example. it can.

  Therefore, the buffer device 6 must be maintained at a high pressure at all times so that the high-pressure tank of the fuel cell vehicle can be filled with hydrogen gas. When the hydrogen gas is supplied to the fuel cell 8, the hydrogen supply device 7 Therefore, there is a problem that the pressure must be reduced considerably, which is not economical.

  Furthermore, for example, immediately after the reformer 2 is started or when the hydrogen separator 3 is left for a long period of time, the purity of the generated hydrogen gas may be reduced. If this low-purity hydrogen gas is supplied to a high-pressure tank of a fuel cell vehicle, there is a problem that the power generation system of the fuel cell vehicle is hindered.

  The present invention solves this type of problem, and supplies hydrogen gas to a stationary fuel cell and a fuel cell vehicle in a good and efficient manner, and can use the hydrogen gas economically. An object is to provide a production power generation system.

  It is another object of the present invention to provide a method of operating a hydrogen gas production power generation system that can reliably supply high concentration (high purity) hydrogen gas to a fuel cell vehicle with simple control.

The present invention includes a reformer that reforms a hydrogen-containing fuel to obtain a reformed gas, a hydrogen purifier that purifies high-purity hydrogen gas by removing unnecessary substances from the reformed gas, and the hydrogen gas as well as storage, the first hydrogen storage device for supplying the hydrogen gas to the stationary fuel cell, the first hydrogen storage unit the destination of the hydrogen gas hydrogen purity is less than the predetermined value, the hydrogen purity And a control device that controls switching of the supply destination of the hydrogen gas that is equal to or greater than a predetermined value to the second hydrogen storage device.

In addition, a hydrogen concentration detection device that detects the purity of the hydrogen gas purified by the hydrogen purification device is provided, and the control device detects the first hydrogen when the hydrogen purity detected by the hydrogen concentration detection device is less than a predetermined value. While supplying the hydrogen gas only to the storage device, it is preferable to control to supply the hydrogen gas to the second hydrogen storage device when the hydrogen purity is equal to or higher than a predetermined value . Thereby, high purity hydrogen gas can be reliably stored in the second hydrogen storage device.

  Furthermore, the hydrogen concentration detection device preferably estimates the hydrogen concentration based on the operating parameters. The operation parameters include, for example, the time from the start of operation, the temperature in the system, the pressure in the system, or the operation stop time of the hydrogen purifier.

A first flow path that communicates the hydrogen purification apparatus and the first hydrogen storage apparatus; a second flow path that communicates the hydrogen purification apparatus and the second hydrogen storage apparatus; and the first and second flow paths. It is preferable to include a flow path switching device that allows the flow path to communicate and supply hydrogen gas having high hydrogen purity from the second hydrogen storage device to the stationary fuel cell via the first hydrogen storage device.

Furthermore, the present invention includes a reformer for obtaining a reformed gas by reforming a hydrogen containing fuel, and hydrogen purification device for purifying the high purity hydrogen gas to remove unwanted material from the reformed gas, the hydrogen A first hydrogen storage device for storing the gas and supplying the hydrogen gas to a stationary fuel cell; and storing the hydrogen gas at a pressure higher than that of the first hydrogen storage device; A method for operating a hydrogen gas production power generation system including a second hydrogen storage device directly connected to a hydrogen dispenser for supplying gas.

Therefore, first, the purity of the hydrogen gas purified by the hydrogen purifier is detected, and the hydrogen gas is supplied only to the first hydrogen storage device when the detected hydrogen purity is less than a predetermined value . On the other hand, when the detected hydrogen purity is equal to or higher than a predetermined value , hydrogen gas is supplied to the second hydrogen storage device.

In the present invention, a first hydrogen storage device for supplying hydrogen gas to a stationary fuel cell, and a second hydrogen storage device directly connected to a hydrogen dispenser for supplying the hydrogen gas to a fuel cell vehicle, Since it is provided individually, the hydrogen gas stored in the first hydrogen storage device can be supplied to the stationary fuel cell until the internal pressure reaches substantially zero. Therefore, hydrogen gas can be efficiently supplied to the stationary fuel cell, and the hydrogen gas can be used economically.

  Further, in the present invention, it is possible to reliably supply a high concentration of hydrogen gas to the second hydrogen storage device, thereby eliminating the hydrogen supply that would interfere with the power generation system of the fuel cell vehicle, It is economical without discarding hydrogen gas.

  FIG. 1 is a schematic configuration diagram of a domestic hydrogen gas production power generation system 10 for carrying out an operation method according to the first embodiment of the present invention.

  The household hydrogen gas production power generation system 10 supplies hydrogen-containing fuel, for example, hydrocarbon fuel such as methane or propane (hereinafter also referred to as reforming fuel), and hydrogen-rich gas (hereinafter referred to as reforming fuel) by reforming reaction of the reforming fuel. The reformer 16 is also provided.

  A hydrogen purifier 20 having a PSA mechanism or a hydrogen separation membrane is connected downstream of the reformer 16. The PSA mechanism includes a plurality of towers, for example, three towers (not shown) filled with an adsorbent that selectively adsorbs components other than hydrogen under high pressure and desorbs under reduced pressure. By causing each adsorption tower to perform cyclic operation consisting of adsorption, decompression, pressure equalization, desorption, and washing steps, high purity hydrogen is taken out while other components (unnecessary substances) are released as off-gas. This off-gas is effectively used as a heat source for the reformer 16.

  A hydrogen gas path 24 for discharging high-purity hydrogen (hydrogen gas) from each adsorption tower communicates with the hydrogen purifier 20, and a hydrogen concentration detection for detecting the hydrogen concentration of the hydrogen gas is performed in the hydrogen gas path 24. As the device 26, for example, a hydrogen purity meter is provided. The hydrogen gas path 24 is provided with a hydrogen compression device 28 constituting a hydrogen supply device, and a power generation tank (first hydrogen storage device) 32 is connected to the hydrogen compression device 28 via a valve 30a. Filling tanks (second hydrogen storage devices) 34a and 34b are connected via valves 30b and 30c. The valves 30 a to 30 c constitute a flow path switching device 35. Instead of the power generation tank 32, a hydrogen storage alloy may be used.

  The power generation tank 32 is connected to a stationary fuel cell 36 for supplying household power via a hydrogen gas supply path 38. For example, a compressor (or a blower) 40 for supplying air as an oxidant gas is connected to the stationary fuel cell 36. The filling tanks 34a and 34b are connected to a hydrogen dispenser 42 and supply hydrogen gas to a high-pressure tank of a fuel cell vehicle (not shown).

  The home hydrogen gas production power generation system 10 communicates with and controls each auxiliary device, and in the first embodiment, in particular, switches the hydrogen gas supply destination between the power generation tank 32 and the filling tanks 34a and 34b. For example, a control ECU (Electronic Control Unit) 44 is provided as the control device.

  The operation of the household hydrogen gas production power generation system 10 configured as described above will be described below along the flowchart shown in FIG. 2 in relation to the operation method according to the first embodiment.

In the domestic hydrogen gas production power generation system 10, the operation is started via the control ECU 44. For example, reforming fuel such as city gas or propane is sent to the reforming device 16. In the reformer 16, for example, CH ₄ + 2O ₂ → CO ₂ + 2H ₂ O (exothermic reaction) and fuel reforming reaction due to methane, oxygen in the air, and water vapor in the reforming fuel. CH ₄ + 2H ₂ O → CO ₂ + 4H ₂ (endothermic reaction) is simultaneously performed (autothermal method). The reformer 16 may employ steam reforming that supplies heat to CH ₄ + 2H ₂ O → CO ₂ + 4H ₂ (endothermic reaction) that is a fuel reforming reaction.

  As described above, the reformed gas reformed by the reformer 16 is supplied to the hydrogen purifier 20. In the hydrogen purifier 20, components other than hydrogen are adsorbed in each adsorption tower to purify hydrogen gas containing high-concentration hydrogen (hydrogen rich), and this hydrogen gas is supplied to the hydrogen gas path 24.

  A hydrogen concentration detection device 26 is disposed in the hydrogen gas path 24, and the hydrogen purity of the hydrogen gas sent from the hydrogen purification device 20 is detected (step S1 in FIG. 2). If the hydrogen purity detected by the hydrogen concentration detector 26 is less than the predetermined value (YES in step S2), the process proceeds to step S3, the valve 30a is opened, and the power generation tank 32 is filled with the hydrogen gas. .

  On the other hand, if it is determined that the hydrogen purity is equal to or higher than the predetermined value (NO in step S2), the process proceeds to step S4, where the valve 30a is closed, while the valves 30b and 30c are selectively opened, and the filling tank 34a and 34b are selectively filled with hydrogen gas. The supply operation of hydrogen gas to the power generation tank 32 and / or the filling tanks 34a and 34b is continued until the hydrogen production operation is stopped (step S5).

  Next, the hydrogen gas stored in the power generation tank 32 is supplied from the hydrogen gas supply path 38 to the anode electrode (not shown) of the stationary fuel cell 36. On the other hand, the compressor 40 is driven, and air is supplied as an oxidant gas to a cathode side electrode (not shown) of the stationary fuel cell 36. For this reason, the stationary fuel cell 36 generates electric power and generates electric power. This electric power is used as a household power source and also used as a system auxiliary power source including the compressor 40.

  Further, the hydrogen gas stored in the filling tanks 34 a and 34 b is filled into a high-pressure tank of a fuel cell vehicle (not shown) via the hydrogen dispenser 42.

  In the hydrogen purification apparatus 20, off-gas is released from each adsorption tower. This off gas is connected to the combustor 14, and this off gas is effectively used as a heat source for the reformer 16.

  In this case, in the first embodiment, the power generation tank 32 for supplying hydrogen gas to the stationary fuel cell 36 and the filling tanks 34a and 34b for supplying the fuel cell to the fuel cell vehicle are individually provided. Is provided. At that time, the filling tanks 34a and 34b need to be filled with hydrogen gas at a higher pressure than the high-pressure tank of the fuel cell vehicle, and the internal pressure of the filling tanks 34a and 34b needs to be maintained at a considerably high pressure. is there. On the other hand, the power generation tank 32 may be maintained at a pressure required to supply hydrogen gas to the stationary fuel cell 36.

  Accordingly, by providing a power generation tank 32 that is separate from the high-pressure filling tanks 34a and 34b, the hydrogen gas stored in the power generation tank 32 is fixed until the internal pressure of the power generation tank 32 reaches substantially zero. The fuel cell 36 can be supplied. Thereby, the effect that hydrogen gas can be used economically is acquired.

  Furthermore, in the first embodiment, the hydrogen purity of the hydrogen gas sent from the hydrogen purifier 20 is detected via the hydrogen concentration detector 26. Then, based on the detected hydrogen purity, the hydrogen gas is switched and supplied to the power generation tank 32 and the filling tanks 34 a and 34 b under the action of the flow path switching device 35. Here, high purity hydrogen gas is stored in the filling tanks 34 a and 34 b, while low purity hydrogen gas is stored in the power generation tank 32.

  For this reason, the hydrogen gas filled in the fuel cell vehicle is always reliably maintained at a high purity (high concentration), and the low purity hydrogen gas is supplied to the fuel cell vehicle, causing a problem in the power generation system. There is no need to exhaust hydrogen gas at a low concentration, and there is an advantage that it is economical.

  In the domestic hydrogen gas production power generation system 10, hydrogen gas is supplied from the power generation tank 32 to the stationary fuel cell 36 when the system is stationary. When the hydrogen gas in the power generation tank 32 is insufficient during a power failure or the like, the flow path switching device 35 is controlled to supply the hydrogen gas from the filling tank 34a or 34b to the stationary fuel cell 36. The power generation by the stationary fuel cell 36 can be continued.

  FIG. 3 is a schematic configuration diagram of a domestic hydrogen gas production power generation system 60 for carrying out the operation method according to the second embodiment of the present invention. In addition, the same referential mark is attached | subjected to the component same as the household hydrogen gas production power generation system 10 which concerns on 1st Embodiment, and the detailed description is abbreviate | omitted.

  In the second embodiment, as a control device that estimates the hydrogen concentration from the operation parameters and switches the supply destination of the hydrogen gas to the power generation tank 32 and the filling tanks 34a and 34b without using the hydrogen concentration detection device 26. A control ECU 62 is provided. The control ECU 62 has a function as a hydrogen concentration detection device.

  Here, the operation parameter is a parameter related to various operation situations that may affect the concentration of the hydrogen gas to be purified. For example, the time from the start of operation, the temperature in the system, the pressure in the system, or the hydrogen purifier 20 The operation stop time of This is because, for example, when the operation is performed immediately after the system is started or after a long-time operation stop, the purity of the hydrogen gas to be purified is often not stable.

  In the second embodiment configured as described above, an operation parameter related to the handling situation of the domestic hydrogen gas production power generation system 60 is detected via the control ECU 62 (step S11 in FIG. 4). Then, the control ECU 62 determines whether or not the detected operating parameter is outside the setting (step S12). If it is determined that the operating parameter is outside the setting (YES in step S12), the control ECU 62 proceeds to step S13 to generate power. The tank 32 is filled with hydrogen gas. This hydrogen gas is estimated to have a hydrogen concentration below a predetermined value.

  On the other hand, if it is determined that the operation parameter is within the set range (NO in step S12), it is estimated that the purity of the hydrogen gas is equal to or higher than a predetermined value, and the process proceeds to step S14, where hydrogen is charged into the filling tanks 34a and 34b. Filled with gas. As a result, the filling tanks 34a and 34b are reliably filled with high-purity hydrogen gas, and in the second embodiment, the same effects as in the first embodiment can be obtained.

It is a schematic block diagram of the domestic hydrogen gas production power generation system for enforcing the operating method concerning a 1st embodiment of the present invention. It is a flowchart explaining the said driving | running method. It is a schematic block diagram of the household hydrogen gas production power generation system for enforcing the operating method which concerns on the 2nd Embodiment of this invention. It is a flowchart explaining the said driving | running method. It is a schematic explanatory drawing of patent document 1. FIG.

Explanation of symbols

DESCRIPTION OF SYMBOLS 10, 60 ... Domestic hydrogen gas production power generation system 16 ... Reformer 20 ... Hydrogen purification device 24 ... Hydrogen gas path 26 ... Hydrogen concentration detection device 28 ... Hydrogen compression device 30a-30c ... Valve 32 ... Power generation tanks 34a, 34b ... Filling tank 36 ... Stationary fuel cell 40 ... Compressors 44, 62 ... Control ECU

Claims (6)

A reformer for reforming hydrogen-containing fuel to obtain a reformed gas;
A hydrogen purifier for purifying high-purity hydrogen gas by removing unnecessary substances from the reformed gas;
A first hydrogen storage device for storing the hydrogen gas and supplying the hydrogen gas to a stationary fuel cell;
A second hydrogen storage device that stores the hydrogen gas at a pressure higher than that of the first hydrogen storage device and is directly connected to a hydrogen dispenser for supplying the hydrogen gas to a fuel cell vehicle;
The supply destination of the hydrogen gas whose hydrogen purity is less than a predetermined value is switched to the first hydrogen storage device, and the supply destination of the hydrogen gas whose hydrogen purity is a predetermined value or more is switched to the second hydrogen storage device. A control device;
A hydrogen gas production power generation system comprising: The hydrogen gas production power generation system according to claim 1, comprising a hydrogen concentration detection device that detects the purity of the hydrogen gas purified by the hydrogen purification device,
The control device supplies the hydrogen gas only to the first hydrogen storage device when the hydrogen purity detected by the hydrogen concentration detection device is less than a predetermined value , while the hydrogen purity is a predetermined value or more. In this case, the hydrogen gas production power generation system is controlled to supply the hydrogen gas to the second hydrogen storage device.   The hydrogen gas production power generation system according to claim 2, wherein the hydrogen concentration detection device estimates hydrogen purity based on an operation parameter. The hydrogen gas production power generation system according to claim 1 or 2, wherein a first flow path that communicates the hydrogen purification device and the first hydrogen storage device;
A second flow path communicating the hydrogen purification device and the second hydrogen storage device;
Channel switching that makes the first and second channels communicate with each other and enables the hydrogen gas with high hydrogen purity to be supplied from the second hydrogen storage device to the stationary fuel cell through the first hydrogen storage device Equipment,
A hydrogen gas production power generation system comprising: A reformer for reforming the hydrogen-containing fuel to obtain a reformed gas, a hydrogen purifier for purifying high-purity hydrogen gas by removing unnecessary substances from the reformed gas, and storing the hydrogen gas, A first hydrogen storage device for supplying the hydrogen gas to a stationary fuel cell; and storing the hydrogen gas at a pressure higher than that of the first hydrogen storage device and supplying the hydrogen gas to a fuel cell vehicle A method for operating a hydrogen gas production power generation system comprising a second hydrogen storage device directly connected to a hydrogen dispenser,
Detecting the purity of the hydrogen gas purified by the hydrogen purification device;
Supplying the hydrogen gas only to the first hydrogen storage device when the detected hydrogen purity is less than a predetermined value ;
Supplying the hydrogen gas to the second hydrogen storage device when the detected hydrogen purity is a predetermined value or more;
A method for operating a hydrogen gas production power generation system, comprising: In operating method of claim 5 Symbol mounting, at the time of system steady, while supplying the hydrogen gas to the stationary fuel cell from said first hydrogen storage unit,
When the hydrogen gas of the first hydrogen storage device is insufficient, the hydrogen gas is supplied from the second hydrogen storage device to the stationary fuel cell.

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