DE3373902D1 - Azolyl-methyl oxiranes, their preparation and use as medicaments and plant protecting agents - Google Patents

Azolyl-methyl oxiranes, their preparation and use as medicaments and plant protecting agents

Info

Publication number
DE3373902D1
DE3373902D1 DE8383104412T DE3373902T DE3373902D1 DE 3373902 D1 DE3373902 D1 DE 3373902D1 DE 8383104412 T DE8383104412 T DE 8383104412T DE 3373902 T DE3373902 T DE 3373902T DE 3373902 D1 DE3373902 D1 DE 3373902D1
Authority
DE
Germany
Prior art keywords
compound
formula
see diagramm
above meanings
phenyl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
DE8383104412T
Other languages
German (de)
Inventor
Bernd Dr Janssen
Norbert Dr Meyer
Ernst-Heinrich Dr Pommer
Eberhard Dr Ammermann
Friedrich-Wilhelm Dr Kohlmann
Walter Wesenberg
Wolfgang Dr Heberle
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from DE19823218129 external-priority patent/DE3218129A1/en
Priority claimed from DE19823218130 external-priority patent/DE3218130A1/en
Application filed by BASF SE filed Critical BASF SE
Application granted granted Critical
Publication of DE3373902D1 publication Critical patent/DE3373902D1/en
Expired legal-status Critical Current

Links

Classifications

    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/50—1,3-Diazoles; Hydrogenated 1,3-diazoles
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
    • A01N43/647—Triazoles; Hydrogenated triazoles
    • A01N43/653—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/26—Preparation of halogenated hydrocarbons by reactions involving an increase in the number of carbon atoms in the skeleton
    • C07C17/263—Preparation of halogenated hydrocarbons by reactions involving an increase in the number of carbon atoms in the skeleton by condensation reactions
    • C07C17/2635—Preparation of halogenated hydrocarbons by reactions involving an increase in the number of carbon atoms in the skeleton by condensation reactions involving a phosphorus compound, e.g. Wittig synthesis
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D231/00—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings
    • C07D231/02—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
    • C07D231/10—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D231/12—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D233/00—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings
    • C07D233/54—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having two double bonds between ring members or between ring members and non-ring members
    • C07D233/56—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having two double bonds between ring members or between ring members and non-ring members with only hydrogen atoms or radicals containing only hydrogen and carbon atoms, attached to ring carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D249/00—Heterocyclic compounds containing five-membered rings having three nitrogen atoms as the only ring hetero atoms
    • C07D249/02—Heterocyclic compounds containing five-membered rings having three nitrogen atoms as the only ring hetero atoms not condensed with other rings
    • C07D249/08—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
    • C07D303/02—Compounds containing oxirane rings
    • C07D303/08—Compounds containing oxirane rings with hydrocarbon radicals, substituted by halogen atoms, nitro radicals or nitroso radicals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D405/00—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom
    • C07D405/02—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom containing two hetero rings
    • C07D405/06—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom containing two hetero rings linked by a carbon chain containing only aliphatic carbon atoms

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Environmental Sciences (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Zoology (AREA)
  • Pest Control & Pesticides (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Epoxy Compounds (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Cephalosporin Compounds (AREA)
  • Saccharide Compounds (AREA)

Abstract

1. Claims for the Contracting States : BE CH DE FR GB IT LI NL SE An azolylmethyloxirane of the general formula I see diagramm : EP0094564,P22,F4 where A and B are identical or different and, independently of one another, are naphthyl, biphenyl or phenyl, it being possible for the phenyl radical to be substituted by halogen or nitro, or by alkyl, alkoxy or haloalkyl, each of 1 to 4 carbon atoms, or by phenoxy or phenylsulfonyl, and Z is CH or nitrogen, or a physiologically tolerated or plant-tolerated salt thereof. 1. Claims for the Contracting State : AT A process for the preparation of a azolylmethyloxirane of the general formula I see diagramm : EP0094564,P23,F7 where A and B are identical or different, and independently of one another, are naphthyl, biphenyl or phenyl, it being possible for the phenyl radical to be substituted by halogen or nitro, or by alkyl, alkoxy or haloalkyl, each of 1 to 4 carbon atoms, or by phenoxy or phenylsulfonyl, and Z is CH or nitrogen, or a physiologically tolerated salt thereof, wherein (a) a compound of the formula II see diagramm : EP0094564,P24,F1 where A and B have the above meanings and L is a leaving group which can undergo nucleophilic substitution, is reacted with a compound of the formula III see diagramm : EP0094564,P24,F2 where Me is a hydrogen atom or a metal atom, and Z is CH or nitrogen, or (b) a compound of the formula II, where A and B have the above meanings and L is a hydroxyl group, is reacted with a compound of the formula IV see diagramm : EP0094564,P24,F3 where Z has the above meanings and Y is carbon or sulphur, or (c) a compound of the formula V see diagramm : EP0094564,P24,F4 where Z, A and B have the above meanings, is epoxidized, or (d) a compound of the formula VI see diagramm : EP0094564,P24,F5 where Z and A have the above meanings, is reacted with a compound of the general formula VII see diagramm : EP0094564,P24,F6 where B has the above meanings, R**1 and R**2 , which may be identical or different, are each methyl or phenyl, and n is 0 or 1, and, if desired, the compound thus obtained is converted into a salt with a physiologically tolerated acid.
DE8383104412T 1982-05-14 1983-05-05 Azolyl-methyl oxiranes, their preparation and use as medicaments and plant protecting agents Expired DE3373902D1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19823218129 DE3218129A1 (en) 1982-05-14 1982-05-14 Azolylmethyloxiranes, their preparation and use as medicaments
DE19823218130 DE3218130A1 (en) 1982-05-14 1982-05-14 AZOLYL METHYLOXIRANES, METHOD FOR THE PRODUCTION THEREOF AND FUNGICIDES CONTAINING THEM

Publications (1)

Publication Number Publication Date
DE3373902D1 true DE3373902D1 (en) 1987-11-05

Family

ID=25801810

Family Applications (1)

Application Number Title Priority Date Filing Date
DE8383104412T Expired DE3373902D1 (en) 1982-05-14 1983-05-05 Azolyl-methyl oxiranes, their preparation and use as medicaments and plant protecting agents

Country Status (8)

Country Link
EP (1) EP0094564B1 (en)
AT (1) ATE30026T1 (en)
AU (1) AU557154B2 (en)
DE (1) DE3373902D1 (en)
ES (1) ES522378A0 (en)
IL (1) IL68433A (en)
NL (1) NL971020I2 (en)
NZ (1) NZ204222A (en)

Families Citing this family (28)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS57165370A (en) * 1981-03-18 1982-10-12 Ici Ltd Triazole or imidazole compounds, manufacture and fungicidal or plant growth regulant agent
CA1271764A (en) * 1985-03-29 1990-07-17 Stefan Karbach Azolylmethyloxiranes, their preparation and their use as crop protection agents
DE3511411A1 (en) * 1985-03-29 1986-10-02 Basf Ag, 6700 Ludwigshafen USE OF AZOLYLMETHYLOXIRANES TO COMBAT VIRAL DISEASES
DE3601927A1 (en) * 1986-01-23 1987-07-30 Basf Ag ALPHA, BETA-SUBSTITUTED ACROLEINE, METHOD FOR THE PRODUCTION AND USE THEREOF
DE3737888A1 (en) * 1987-11-07 1989-05-18 Basf Ag PROCESS FOR INFLUENCING PLANT GROWTH THROUGH AZOLYL METHYLOXIRANE
DE3803833A1 (en) * 1988-02-09 1989-08-17 Bayer Ag SUBSTITUTED AZOLYL METHYLOXIRANES
DE3805376A1 (en) * 1988-02-20 1989-08-31 Basf Ag NEW AZOLYL METHYLOXIRANES AND FUNGICIDES CONTAINING THEM
DE3805684A1 (en) * 1988-02-24 1989-09-07 Basf Ag AZOLYLMETHYLCYCLOALKYLOXIRANE, THEIR PRODUCTION AND USE AS A PLANT PROTECTION PRODUCT
DE3807951A1 (en) * 1988-03-10 1989-09-21 Basf Ag FUNGICIDAL IMIDAZOLYL METHYLOXIRANE
DE3825586A1 (en) * 1988-07-28 1990-02-01 Basf Ag SUBSTITUTED IMIDAZOLYL METHYLOXIRANES AND SUBSTITUTED IMIDAZOLYL PROPENES, THEIR PRODUCTION AND THEIR FUNGICIDES CONTAINING THEM
DE3825841A1 (en) * 1988-07-29 1990-02-01 Basf Ag 1-HALOGEN-1-AZOLYPROPENE AND METHYLOXIRANE AND FUNGICIDES CONTAINING THEM
IL95493A0 (en) * 1989-09-09 1991-06-30 Basf Ag Azolylmethyloxiranes,their manufacture and their use as fungicides
DE3932387A1 (en) * 1989-09-28 1991-04-11 Basf Ag VINYLAZOLE AND THEIR USE AS A PLANT PROTECTANT
DE3936824A1 (en) * 1989-11-04 1991-05-08 Basf Ag N-OXO-AZOLYL METHYLOXIRANES AND FUNGICIDES AND BIOREGULATORS CONTAINING THEM
DE4117877A1 (en) * 1991-05-31 1992-12-03 Basf Ag METHOD FOR PRODUCING CIS-2- (1H-1,2,4-TRIAZOL-1-YL-METHYL) -2- (HALOGENPHENYL) -3- (HALOGENPHENYL) -OXIRAN
DE4412358A1 (en) * 1994-04-11 1995-10-12 Bayer Ag Cyclopropyl ethyl azoles
DE19520097A1 (en) * 1995-06-01 1996-12-05 Bayer Ag Triazolylmethyl oxiranes
ES2235053T3 (en) * 2001-05-18 2005-07-01 Basf Aktiengesellschaft PROCEDURE FOR OBTAINING TRIAZOLILMETILOXIRANOS.
DE50306914D1 (en) 2002-06-24 2007-05-10 Basf Ag PROCESS FOR THE PREPARATION OF 1,2,4-TRIAZOLYLMETHYL-OXIRANES
UA96450C2 (en) 2006-06-21 2011-11-10 Басф Се Azolylmethyloxiranes, their use for controlling phytopathogenic fungi, a crop protection composition, a method for controlling phytopathogenic fungi and seed
DE502007006380D1 (en) 2006-07-05 2011-03-10 Basf Se AZOLYLMETHYL OXIRANES, THEIR USE IN THE CONTROL OF PLANT PATHOGENIC MUSHROOMS AND THE MEDIUM CONTAINING THEY
US8236788B2 (en) 2006-07-24 2012-08-07 Basf Se Azolylmethyloxiranes, use thereof for controlling plant pathogenic fungi, and agents containing the same
US7910614B2 (en) 2006-07-25 2011-03-22 Basf Se Azolylmethyloxiranes, use thereof for controlling plant pathogenic fungi, and agents containing the same
BRPI0720572A2 (en) * 2006-12-22 2014-02-04 Basf Se COMPOUNDS, USE OF COMPOUNDS, AGENT FOR PROTECTION OF PLANT, SEED, AND PROCESS TO COMBAT PHYTOPATHOGENIC FUNGI
CN101952279A (en) * 2007-12-19 2011-01-19 巴斯夫欧洲公司 Azolylmethyloxiranes, use thereof and agents containing the same
CN102428952B (en) * 2011-11-17 2013-06-26 广东中迅农科股份有限公司 Synergistic germicide composition for controlling wheat take-all
EP2746277A1 (en) 2012-12-19 2014-06-25 Basf Se Fungicidal imidazolyl and triazolyl compounds
CN105123706A (en) * 2015-10-26 2015-12-09 广西南宁益土生物科技有限责任公司 Bactericide with epoxiconazole and cinnamyl aldehyde

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IL60470A0 (en) * 1979-07-04 1980-09-16 Pfizer Imidazole derivatives,their preparation and pharmaceutical compositions containing them
DE3111238A1 (en) * 1981-03-21 1982-10-07 Bayer Ag, 5090 Leverkusen SUBSTITUTED TRIAZOLYL METHYL OXIRANES, METHOD FOR THE PRODUCTION THEREOF AND THEIR USE AS INTERMEDIATE PRODUCTS

Also Published As

Publication number Publication date
EP0094564B1 (en) 1987-09-30
NL971020I2 (en) 1998-04-01
ES8402833A1 (en) 1984-03-01
NL971020I1 (en) 1997-10-01
ATE30026T1 (en) 1987-10-15
NZ204222A (en) 1986-02-21
ES522378A0 (en) 1984-03-01
AU557154B2 (en) 1986-12-11
EP0094564A2 (en) 1983-11-23
IL68433A0 (en) 1983-07-31
EP0094564A3 (en) 1984-06-13
IL68433A (en) 1986-04-29
AU1458883A (en) 1983-11-17

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Legal Events

Date Code Title Description
8364 No opposition during term of opposition
V448 Application of spc

Free format text: PRODUCT NAME: EPOXICONAZOL; REGISTRATION NO/DATE: 04183-00, 19950117

Spc suppl protection certif: 197 75 040

Filing date: 19970721

V457 Spc granted

Free format text: PRODUCT NAME: EPOXICONAZOL; REGISTRATION NO/DATE: 04183-00, 19950117

Spc suppl protection certif: 197 75 040

Filing date: 19970721

V464 Spc expired

Free format text: PRODUCT NAME: EPOXICONAZOL; REGISTRATION NO/DATE: 04183-00, 19950117

Spc suppl protection certif: 197 75 040

Filing date: 19970721