CN1302080C - Water-based termite-proof insect-protected enclosed paint - Google Patents

Water-based termite-proof insect-protected enclosed paint Download PDF

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Publication number
CN1302080C
CN1302080C CNB2004100521325A CN200410052132A CN1302080C CN 1302080 C CN1302080 C CN 1302080C CN B2004100521325 A CNB2004100521325 A CN B2004100521325A CN 200410052132 A CN200410052132 A CN 200410052132A CN 1302080 C CN1302080 C CN 1302080C
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proof
water
insect
mixture
agent
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CNB2004100521325A
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CN1640972A (en
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陈寿生
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Beijing Zhanchen Intelligent Property Management Co ltd
Beijing Zhanchen New Material Co ltd
China Zhanchen New Materials Group Co.,Ltd.
Shanghai Zhanchen Paint Co ltd
Zhuhai Zhanchen New Material Co ltd
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SHENZHEN ZHANCHENDA CHEMICAL INDUSTRY Co Ltd
Shanghai Fuchen Chemical Co Ltd
Beijing Zhanchen Chemical Co Ltd
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  • Paints Or Removers (AREA)
  • Chemical And Physical Treatments For Wood And The Like (AREA)

Abstract

The present invention discloses water-base termite and moth proof sealing paint which is composed of the following components: 80 to 98 wt% of water-base resin with solid content of 25 to 50%, 1 to 15 wt% of antifreezing agents, 0.1 to 0.8 wt% of defoaming agents, 0.1 to 0.8 wt% of substrate wetting agents, 0 to 10% wt% of zinc stearate, 0.5 to 8% wt% of vermin proof agents. The sealing paint of the present invention can be coated on the surfaces of wooden furniture, wood floors, and other wooden articles to form a termite and moth proof thin film, thereby preventing termites and other moths from eating woodenware. The present invention has the advantages of high termite and moth proof efficiency, lasting drug effect, safety, environmental protection, good decorative effect and convenient construction, and can be widely applied to the coating of modern wooden furniture or the decoration of families and office rooms.

Description

Water-based termide-proof and insect-proof seal coat
Technical field
The present invention relates to a kind of water-borne wood coating, relate in particular to a kind of water-based termide-proof and insect-proof seal coat.
Background technology
At present, the termide-proof and insect-proof of timber is handled mainly based on infusion method and squeegee process, being about to timber is immersed in the solution that contains medicine, the solution brushing that maybe will contain medicine is on wood surface, as application number be 88105434.8, name is called the patent application of " long-acting hygiene spraying insecticide and manufacture method thereof ", is exactly with sterilant and the surface that is painted on furniture after membrane-forming agent mixes in this application; Though this spraying agent also can reach the purpose of insect protected, because this spraying agent is directly to impose on furniture surface, its medicine easily runs off, and duration of efficacy is short, and medicine is harmful, can pollute environment; In addition the wood surface brushing behind the drug solution, influenced the lacquer decorations effect of wood surface.Therefore, at present the termide-proof and insect-proof pesticide application technology of timber or plank can not be applicable to the decorations of the application of woodenware such as modern wooden furniture and family, office.
Summary of the invention
The technical problem to be solved in the present invention is to provide a kind of medicine to be difficult for the good water-based termide-proof and insect-proof seal coat of loss, lasting medicine, safety and environmental protection and decorative effect.
The technical scheme that the present invention solves the problems of the technologies described above is, adopt a kind of water-based termide-proof and insect-proof seal coat, the main ingredient of this lacquer and weight proportion thereof are: solids content is 25%~50% water-base resin 80%~98%, frostproofer 1%~15%, defoamer 0.1%~0.8%, ground wetting agent 0.1%~0.8%, insect-proof agent 0.5%~8%;
Wherein, described water-base resin is aqueous polyurethane dispersion or polyacrylate resin emulsion or their mixture; Described defoamer is polysiloxane-polyether copolymer emulsion class, polypropylene glycols, polyoxyethylene glycol-hydrophobic solid-polysiloxane mixture class, mineral oil base class or their mixture; Described ground wetting agent is polysiloxane-polyether copolymer class, pure ethers, dioctyl sulfuration sodium succinate salt or their mixture; Described insect-proof agent is water-soluble pyrethroid insect-proof agent, stuck gram missible oil, 4-phenelyl [3-(4-fluoro-3-phenoxy phenyl) propyl group] dimethylsilane or their mixture; Described frostproofer is propylene glycol or ethylene glycol or their mixture.
In order to increase the grinability of lacquer, this lacquer comprises that also weight ratio is 0~10% Zinic stearas.
Each component and the optimum weight proportioning thereof of this lacquer are: solids content is 32% water-base resin 85%, frostproofer 5%, defoamer 0.35%, ground wetting agent 0.65%, Zinic stearas 5%, insect-proof agent 4%.
Concrete each component that adopts of this lacquer is as follows: described water-base resin adopts aqueous polyurethane dispersion, described frostproofer to adopt ethylene glycol, described defoamer to adopt polyoxyethylene glycol-hydrophobic solid-polysiloxane mixture class, described ground wetting agent to adopt dioctyl sulfuration sodium succinate salt, described insect-proof agent to adopt water-soluble pyrethroid insect-proof agent.
Compare with prior art, with water-based termide-proof and insect-proof seal coat of the present invention is to add filmogen and insect-proof agent in coatings additive(s), can be at wooden furniture, wood product surfaces such as timber floor form the termide-proof and insect-proof film, thereby stop the moth erosion of termite and other moth to woodenware, detect through GB/G18260-2000 " wood preservative is to termite toxic effect test method ", its termide-proof and insect-proof efficient is more than 1 grade, because medicine is difficult for running off by the paint film sealing, thereby to termite, moth has efficiently, persistent prevention and control capability, and can not cause damage to human body, also do not pollute the environment, than safety and environmental protection, and decorative effect is good, easy construction.
Embodiment
The present invention is further illustrated below in conjunction with embodiment.
The main ingredient and the weight proportion thereof of water-based termide-proof and insect-proof seal coat of the present invention are: solids content is 25%~50% water-base resin 80%~98%, frostproofer 1%~15%, defoamer 0.1%~0.8%, ground wetting agent 0.1%~0.8%, insect-proof agent 0.5%~8%.
In order to increase the grinability of lacquer, also can in said components, add 0~10% Zinic stearas.
In above-mentioned each component:
Aqueous polyurethane dispersion or polyacrylate resin emulsion or their mixture that described water-base resin can self-producedly also can adopt sky, Jieyang patina worker company limited or New Orient, Shuande chemical industry company limited to produce.
Described defoamer can adopt polysiloxane-polyether copolymer emulsion class, as the TEG0805 of the high chemical industry of German enlightening company limited production; Polypropylene glycols, the Pluriol P 2000 that produces as German BASF chemical industry company limited; Polyoxyethylene glycol-hydrophobic solid-polysiloxane mixture class is as the BYK024 of German Bi Ke chemistry (Asia-Pacific) private limited partnership production; The mineral oil base class, Foamster309A that produces as river, Shenzhen sea chemical industry company limited etc. or their mixture.
Described ground wetting agent can adopt the polysiloxane-polyether copolymer class, as the TEG0270 of the high chemical industry of German enlightening company limited production; The alcohol ethers, the Emulan HE 50 that produces as German BASF chemical industry company limited; Dioctyl sulfuration sodium succinate salt, Lutensit A-B0 that produces as German BASF chemical industry company limited etc. or their mixture.
Described insect-proof agent can adopt the water-soluble pyrethroid insect-proof agent of Guangdong Province Insects Research Institute development, the stuck gram missible oil that Britain Shell Co. Ltd produces, the white spirit of silicon (that is: 4-phenelyl [3-(4-fluoro-3-phenoxy phenyl) propyl group] dimethylsilane), other insect-proof agent or their mixture that Japan Pyrethrum Co., Ltd produces;
Described frostproofer can adopt Dow Chemical Pacific Ocean company limited or Guangzhou must justify propylene glycol or ethylene glycol or their mixture that trade Co., Ltd produces.
Concrete component and the weight proportion thereof that adopts of seal coat of the present invention can be following prescription:
Prescription one, aqueous polyurethane dispersion (solids content: 32%) be 85%, ethylene glycol is 5%, polyoxyethylene glycol-hydrophobic solid-polysiloxane mixture defoamer BYK024 is 0.35%, dioctyl sulfuration sodium succinate salt ground wetting agent Lutensit A-B0 is 0.65%, Zinic stearas is 5%, water-soluble pyrethroid insect-proof agent is 4%.
Prescription two, aqueous polyurethane dispersion (solids content: 32%) be 89%, ethylene glycol is 4%, polyoxyethylene glycol-hydrophobic solid-polysiloxane mixture defoamer BYK024 is 0.5%, dioctyl sulfuration sodium succinate salt ground wetting agent LutesitA-B0 is 0.5%, Zinic stearas is 3%, water-soluble pyrethroid insect-proof agent is 3%.
Prescription three, aqueous polyurethane dispersion (solids content: 32%) be 82%, ethylene glycol is 7%, polyoxyethylene glycol-hydrophobic solid-polysiloxane mixture defoamer BYK024 is 0.6%, dioctyl sulfuration sodium succinate salt ground wetting agent LutensitA-B0 is 0.4%, Zinic stearas is 5%, water-soluble pyrethroid insect-proof agent is 5%.
Wherein fill a prescription one for optimum formula.
During preparation, after water-base resin and frostproofer, defoamer, ground wetting agent, these coatings additive(s)s of Zinic stearas are fully disperseed, add water-based pyrethroid insect-proof agent and be uniformly dispersed and get final product.During coating decoration, can add an amount of water as the case may be and regulate viscosity, lacquer is applied to wood product surfaces such as furniture, timber floor with the method for brushing or spray again its closed allround is got final product.
Detect with detection method GB/T 18260-2000 " wood preservative is to termite toxic effect test method ", the quality and technical index and the harmful substance contents of water-based termide-proof and insect-proof seal coat of the present invention are as follows:
Sequence number Interventions Requested Assay The method of inspection
1 Appearance of film Surfacing, smooth Range estimation
2 Time of drying (25 ℃) Surface drying 40min GB/T 1728-89 (second method)
Do solid work ≤24h GB/T 1728-89 (first method)
3 Sticking power ≤ 3 grades GB/T 9286-1998
4 Hardness (the pencil method, 72h) HB GB/T 6739-1996 (A method)
5 Pendulum-rocker hardness ≥0.36 GB/T 1730-1993
6 Water tolerance (25 ℃, 24h) Non-foaming, do not come off, wrinkle resistant, allow slightly to turn white, can recover GB/T 1733-93 (first method)
7 Thermotolerance (60 ℃, 2h) No change GB/T 1735-79
8 Volatile organic compounds (VOC) ≤250g/L HBC12-2002
9 Shock-resistance, kgcm ≥45 GB/T 1732-1993
10 Snappiness, mm ≤2 GB/T 1731-1993
After testing, the termide-proof and insect-proof efficient of water-based termide-proof and insect-proof seal coat of the present invention is more than 1 grade.

Claims (4)

1, a kind of water-based termide-proof and insect-proof seal coat, it is characterized in that: the main ingredient of this lacquer and weight proportion thereof are: solids content is 25%~50% water-base resin 80%~98%, frostproofer 1%~15%, defoamer 0.1%~0.8%, ground wetting agent 0.1%~0.8%, insect-proof agent 0.5%~8%;
Described water-base resin is aqueous polyurethane dispersion or polyacrylate resin emulsion or their mixture; Described defoamer is polysiloxane-polyether copolymer emulsion class, polypropylene glycols, polyoxyethylene glycol-hydrophobic solid-polysiloxane mixture class, mineral oil base class or their mixture; Described ground wetting agent is polysiloxane-polyether copolymer class, pure ethers, dioctyl sulfuration sodium succinate salt or their mixture; Described insect-proof agent is water-soluble pyrethroid insect-proof agent, stuck gram missible oil, 4-phenelyl [3-(4-fluoro-3-phenoxy phenyl) propyl group] dimethylsilane or their mixture; Described frostproofer is propylene glycol or ethylene glycol or their mixture.
2, water-based termide-proof and insect-proof seal coat according to claim 1 is characterized in that: this lacquer comprises that also weight ratio is 0~10% Zinic stearas.
3, water-based termide-proof and insect-proof seal coat according to claim 2 is characterized in that: each component and the weight proportion thereof of this lacquer are: solids content is 32% water-base resin 85%, frostproofer 5%, defoamer 0.35%, ground wetting agent 0.65%, Zinic stearas 5%, insect-proof agent 4%.
4, water-based termide-proof and insect-proof seal coat according to claim 3 is characterized in that: described water-base resin adopts aqueous polyurethane dispersion, described frostproofer to adopt ethylene glycol, described defoamer to adopt polyoxyethylene glycol-hydrophobic solid-polysiloxane mixture class, described ground wetting agent to adopt dioctyl sulfuration sodium succinate salt, described insect-proof agent to adopt water-soluble pyrethroid insect-proof agent.
CNB2004100521325A 2004-11-04 2004-11-04 Water-based termite-proof insect-protected enclosed paint Active CN1302080C (en)

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CN1302080C true CN1302080C (en) 2007-02-28

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Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101845266A (en) * 2009-03-24 2010-09-29 陈姣英 Anti-blushing transparent woodwork coating and production process thereof
CN101760105A (en) * 2010-03-24 2010-06-30 龙岩市金雷白蚁防治技术有限公司 Environment-friendly insect-preventing and heat-insulating coating for trees
CN101967756B (en) * 2010-10-15 2012-01-25 江苏宝泽高分子材料股份有限公司 Anti-mosquito water-proof airpermeability wear-resisting resin used for synthesizing leather and preparation method thereof
CN102489443A (en) * 2011-11-22 2012-06-13 南京林业大学 Sealing paint making technology for wood composite door
CN102675936B (en) * 2012-05-23 2014-01-22 王林宝 Colored paint for trees
CN103131270A (en) * 2013-02-19 2013-06-05 刘川 Multifunctional waterproof antiseptic aldehyde-eliminating glue and preparation method
CN104017405B (en) * 2014-06-19 2017-02-08 杨高林 Insect-repelling wood lacquer and preparation method thereof
CN105111861A (en) * 2015-09-11 2015-12-02 中山市和勍涂料科技有限公司 Formula of water-based multifunctional sealing agent
CN105482695A (en) * 2015-12-15 2016-04-13 天津一橙泽恒环保科技发展有限公司 Environment-friendly insect-proof coating
CN107033766A (en) * 2017-06-06 2017-08-11 合肥月煌新型装饰材料有限公司 A kind of furniture coating and preparation method
CN107815234A (en) * 2017-11-21 2018-03-20 广西吉宽太阳能设备有限公司 Termite-proof Furniture panel coating and production method
CN112745757A (en) * 2020-12-29 2021-05-04 东周化学工业(昆山)有限公司 Ultraviolet curing coating and preparation method thereof
CN112724728A (en) * 2020-12-29 2021-04-30 东周化学工业(昆山)有限公司 Termite-resistant water-based paint and preparation method thereof
CN112694802A (en) * 2020-12-29 2021-04-23 东周化学工业(昆山)有限公司 Termite-resistant water-based paint and preparation method thereof

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Publication number Priority date Publication date Assignee Title
CN85107492A (en) * 1985-09-23 1987-04-01 上海华东新型建筑材料厂 Insecticidal coating and manufacture method thereof
CN1039700A (en) * 1988-07-28 1990-02-21 南京军区后勤部军事医学研究所 Long-acting hygiene spraying insecticide and manufacture method thereof
CN1397618A (en) * 2002-07-04 2003-02-19 许凤和 Environment protection type water polyester paint for wood products and its preparing process

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN85107492A (en) * 1985-09-23 1987-04-01 上海华东新型建筑材料厂 Insecticidal coating and manufacture method thereof
CN1039700A (en) * 1988-07-28 1990-02-21 南京军区后勤部军事医学研究所 Long-acting hygiene spraying insecticide and manufacture method thereof
CN1397618A (en) * 2002-07-04 2003-02-19 许凤和 Environment protection type water polyester paint for wood products and its preparing process

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Owner name: ZHANCHEN PAINTS GROUP CO., LTD.

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Patentee after: ZHANCHEN PAINT GROUP Co.,Ltd.

Co-patentee after: Shanghai Vision Chemical Co.,Ltd.

Address before: 518107 Guangming Niu Shan Industrial Zone, Shenzhen, Guangdong, Baoan District

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Address after: 518107, Shenzhen, Guangdong province Baoan District Guangming Street white industrial park on the south side of the sightseeing highway

Co-patentee after: Beijing zhanchen Intelligent Property Management Co.,Ltd.

Patentee after: China Zhanchen New Materials Group Co.,Ltd.

Co-patentee after: SHANGHAI ZHANCHEN PAINT Co.,Ltd.

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Patentee after: China Zhanchen New Materials Group Co.,Ltd.

Co-patentee after: SHANGHAI ZHANCHEN PAINT Co.,Ltd.

Address before: 518107, Shenzhen Baoan District Guangming Street white industrial park on the south side of the sightseeing highway

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