CN109545672A - Wafer bonding method and bonded wafer - Google Patents

Wafer bonding method and bonded wafer Download PDF

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Publication number
CN109545672A
CN109545672A CN201811391856.0A CN201811391856A CN109545672A CN 109545672 A CN109545672 A CN 109545672A CN 201811391856 A CN201811391856 A CN 201811391856A CN 109545672 A CN109545672 A CN 109545672A
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China
Prior art keywords
wafer
dielectric layer
bonding method
central area
bonded
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CN201811391856.0A
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Inventor
闵源
王淞山
许力恒
赵强
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Huaian Imaging Device Manufacturer Corp
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Huaian Imaging Device Manufacturer Corp
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Priority to CN201811391856.0A priority Critical patent/CN109545672A/en
Publication of CN109545672A publication Critical patent/CN109545672A/en
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/04Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
    • H01L21/18Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
    • H01L21/185Joining of semiconductor bodies for junction formation
    • H01L21/187Joining of semiconductor bodies for junction formation by direct bonding
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L27/00Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate
    • H01L27/14Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation
    • H01L27/144Devices controlled by radiation
    • H01L27/146Imager structures
    • H01L27/14601Structural or functional details thereof
    • H01L27/1464Back illuminated imager structures
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L27/00Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate
    • H01L27/14Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation
    • H01L27/144Devices controlled by radiation
    • H01L27/146Imager structures
    • H01L27/14683Processes or apparatus peculiar to the manufacture or treatment of these devices or parts thereof
    • H01L27/14687Wafer level processing

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  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Power Engineering (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Computer Hardware Design (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Electromagnetism (AREA)
  • Manufacturing & Machinery (AREA)
  • Mechanical Treatment Of Semiconductor (AREA)

Abstract

A kind of wafer bonding method and bonded wafer, which comprises the first wafer is provided, semiconductor devices is formed in first wafer, first wafer includes central area and the fringe region around the central area;Dielectric layer is formed on the surface of first wafer;Edge grinding trimming is carried out to first wafer, to remove a part of the dielectric layer on the fringe region surface and first wafer of dielectric layer covering;Second wafer is provided;By first wafer and second wafer bonding, wherein the dielectric layer is towards second wafer.The present invention program can be effectively avoided the problem of the crack that wafer bonding retreads between slope plane and the second wafer is easy to produce cavity and grey side, improve the quality of bonded wafer.

Description

Wafer bonding method and bonded wafer
Technical field
The present invention relates to technical field of manufacturing semiconductors more particularly to a kind of wafer bonding methods and bonded wafer.
Background technique
Imaging sensor is the core component of picture pick-up device, realizes image taking function by converting optical signals into electric signal Energy.By taking cmos image sensor (CMOS Image Sensors, CIS) device as an example, due to its tool There is the advantages of low-power consumption and high s/n ratio, therefore is widely applied in various fields.
By taking back-illuminated type (Back-side Illumination, BSI) CIS as an example, in existing manufacturing process, first in device Logical device, pixel device and metal interconnection structure are formed in part wafer, then by the front for carrying wafer and the device The front bonding of wafer, and then the back of semiconductor substrate carried out thinned, and then CIS is formed at the back side of semiconductor substrate Subsequent technique, such as latticed grid (Grid) is formed at the semiconductor substrate back side of the pixel device, in the grid Between grid in form optical filtering (Filter) matrix etc..
Currently, in the technique that the front that will carry wafer is bonded with the front of the device wafers, in order to reduce wafer The cavity at edge and grey side, it will usually deposit very thick oxidation film, crystal round fringes are then optimized by chemical mechanical grinding Situation, but still there is cavity and grey side, a kind of wafer bonding method is needed, crystal round fringes are optimized.
Summary of the invention
The technical problem to be solved by the present invention is to provide a kind of wafer bonding method and bonded wafers, can be effectively avoided The problem of the crack that wafer bonding retreads between slope plane and the second wafer is easy to produce cavity and grey side, bonded wafer is improved Quality.
In order to solve the above technical problems, the embodiment of the present invention provides a kind of wafer bonding method, comprising: it is brilliant to provide first Justify, semiconductor devices is formed in first wafer, first wafer includes central area and the circular center The fringe region in domain;Dielectric layer is formed on the surface of first wafer;Edge grinding trimming is carried out to first wafer, with Remove a part of the dielectric layer on the fringe region surface and first wafer of dielectric layer covering;There is provided the Two wafers;By first wafer and second wafer bonding, wherein the dielectric layer is towards second wafer.
Optionally, the material of the dielectric layer is selected from silica and silicon nitride.
Optionally, after forming the dielectric layer, the wafer bonding method further include: the dielectric layer is carried out Planarization.
Optionally, the dielectric layer with a thickness of 500nm to 3000nm.
Optionally, edge grinding trimming is carried out to first wafer using milling apparatus;Wherein, the milling apparatus is Cylindric diamond blade.
Optionally, in the fringe region, first wafer includes the first surface around the central area, and Around the second surface of the first surface, wherein the first surface is plane, and the second surface is curved surface.
Optionally, first wafer is device wafers, and second wafer is carrying wafer.
In order to solve the above technical problems, the embodiment of the present invention provides a kind of bonded wafer, comprising: the first wafer, described It is formed with semiconductor devices in one wafer, first wafer includes central area and fringe region, the fringe region A part of first wafer is removed to form groove;Dielectric layer covers the surface of the central area of first wafer, and not Cover the groove;Second wafer, with first wafer bonding, wherein the dielectric layer is towards second wafer.
Optionally, the material of the dielectric layer is selected from silica and silicon nitride.
Optionally, first wafer is device wafers, and second wafer is carrying wafer.
Compared with prior art, the technical solution of the embodiment of the present invention has the advantages that
In embodiments of the present invention, the first wafer is provided, is formed with semiconductor devices in first wafer, described first Wafer includes central area and the fringe region around the central area;Medium is formed on the surface of first wafer Layer;Edge grinding trimming is carried out to first wafer, to remove the dielectric layer and the medium on the fringe region surface A part of first wafer of layer covering;Second wafer is provided;By first wafer and second wafer bonding, In, the dielectric layer is towards second wafer.Using the above scheme, medium is formed on the surface of first wafer by elder generation Then layer carries out edge grinding trimming to first wafer again, Jie on fringe region surface can be removed when grinding trimming Matter layer also just eliminates the slope of dielectric layer edge region, compared with the prior art in first to the first wafer carry out edge grind Mill trimming, re-forms dielectric layer, and then lead to dielectric layer edge region there are slopes, and then retreads slope plane in wafer bonding Crack between the second wafer is easy to produce cavity and grey side, described due to eliminating using the scheme of the embodiment of the present invention The crack to retread between slope plane and the second wafer in wafer bonding can be effectively avoided in the slope of dielectric layer edge region The problem of being easy to produce cavity and grey side, improves the quality of bonded wafer.
Further, after forming the dielectric layer, further includes: the dielectric layer is planarized, compared to In the prior art, the first wafer again planarize dielectric layer after edge grinding trimming, be easy to aggravate dielectric layer Edge region the case where there are slopes, is carrying out edge grinding trimming to the first wafer using the scheme of the embodiment of the present invention The dielectric layer is planarized before, further can effectively avoid retreading slope plane and the second wafer in wafer bonding Between crack the problem of being easy to produce cavity and grey side, to further increase the quality of bonded wafer.
Further, in embodiments of the present invention, first wafer is device wafers, and second wafer is that carrying is brilliant Circle helps to improve device wafers when being bonded device wafers with carrying wafer and carry the bonding quality of wafer, from And improve the device quality of BSI CIS.
Detailed description of the invention
Fig. 1 to Fig. 5 is the corresponding device profile structural schematic diagram of each step in a kind of wafer bonding method in the prior art;
Fig. 6 is a kind of flow chart of wafer bonding method in the embodiment of the present invention;
Fig. 7 to Figure 11 is that the corresponding device profile structure of each step is shown in a kind of wafer bonding method in the embodiment of the present invention It is intended to.
Specific embodiment
In existing BSI CIS technique, the front for needing to carry wafer is bonded with the front of the device wafers, in order to Reduce the cavity and grey side of crystal round fringes, it will usually deposit very thick oxidation film, crystalline substance is then optimized by chemical mechanical grinding The situation of the edge of the circle.However in the prior art, it is easy the presence of cavity and grey side, the device quality of CIS is caused to decline.
Fig. 1 to Fig. 5 is the corresponding device profile structural schematic diagram of each step in a kind of wafer bonding method in the prior art.
Referring to Fig.1, device wafers 100 are provided, could be formed with semiconductor devices in the device wafers 100, described half Conductor device for example may include logical device, pixel device and metal interconnection structure etc..
Wherein, the device wafers 100 may include central area A and fringe region B, the fringe region B circular The central area A.
Referring to Fig. 2, edge grinding trimming is carried out to the device wafers 100, to remove the device of the fringe region B surface A part of part wafer 100.
In specific implementation, by carrying out edge grinding trimming to device wafers 100, not advising for crystal round fringes can be removed Then region prevents edge from problem of Cracking occurs, and reduces the stress of device wafers 100, improves the semiconductor devices of formation Quality.
Referring to Fig. 3, dielectric layer 101 is formed on the surface of the device wafers 100.
Wherein, the dielectric layer 101 is formed in the one side that device wafers 100 are ground after trimming, therefore dielectric layer 101 is in It is step-like.
Referring to Fig. 4, the dielectric layer 101 is planarized.
It in specific implementation, can be using chemically mechanical polishing (Chemical Mechanical Polishing, CMP) Technique planarizes the dielectric layer 101, to improve dielectric layer 101 in the consistency of the surface thickness of device wafers 100.
Referring to Fig. 5, carrying wafer 110 is provided, the device wafers 100 are bonded with the carrying wafer 110, wherein The dielectric layer 101 is towards the carrying wafer 110.
Wherein, the material of the dielectric layer 101 can be silica.
Specifically, the dielectric layer 101 helps to promote to generate silicone hydroxyl key (Si-O-H) in carrying 110 interface of wafer Structure Si-O-Si key is formed between two wafers, and be fixed on one by Si-O-Si key and then in subsequent annealing process It rises.
The present inventor has found after study, in the prior art, first carries out edge grinding to device wafers 100 and repairs It cuts, re-forms dielectric layer 101, be easy to cause dielectric layer 101 in marginal zone during planarizing dielectric layer 101 There is slope (Slope) in domain, such as the part irised out in Fig. 4 and Fig. 5.
Further, after being bonded the device wafers 100 with the carrying wafer 110, slope plane and second It is easy to produce crack (Seam) between wafer, and then is easy to cause cavity and grey side.Wherein, difficult in the region where the cavity To realize bonding, the ash side will lead to the problem of bond strength deficiency.
In embodiments of the present invention, the first wafer is provided, is formed with semiconductor devices in first wafer, described first Wafer includes central area and the fringe region around the central area;Medium is formed on the surface of first wafer Layer;Edge grinding trimming is carried out to first wafer, to remove the dielectric layer and the medium on the fringe region surface A part of first wafer of layer covering;Second wafer is provided;By first wafer and second wafer bonding, In, the dielectric layer is towards second wafer.Using the above scheme, medium is formed on the surface of first wafer by elder generation Then layer carries out edge grinding trimming to first wafer again, Jie on fringe region surface can be removed when grinding trimming Matter layer also just eliminates the slope of dielectric layer edge region, compared with the prior art in first to the first wafer carry out edge grind Mill trimming, re-forms dielectric layer, and then lead to dielectric layer edge region there are slopes, and then retreads slope plane in wafer bonding Crack between the second wafer is easy to produce cavity and grey side, described due to eliminating using the scheme of the embodiment of the present invention The crack to retread between slope plane and the second wafer in wafer bonding can be effectively avoided in the slope of dielectric layer edge region The problem of being easy to produce cavity and grey side, improves the quality of bonded wafer.
It is understandable to enable above-mentioned purpose of the invention, feature and beneficial effect to become apparent, with reference to the accompanying drawing to this The specific embodiment of invention is described in detail.
Referring to Fig. 6, Fig. 6 is a kind of flow chart of wafer bonding method in the embodiment of the present invention.The wafer bonding method May include step S21 to step S25:
Step S21: the first wafer is provided, is formed with semiconductor devices in first wafer, first wafer includes Central area and the fringe region for surrounding the central area;
Step S22: dielectric layer is formed on the surface of first wafer;
Step S23: edge grinding trimming is carried out to first wafer, to remove the medium on the fringe region surface A part of layer and first wafer of dielectric layer covering;
Step S24: the second wafer is provided;
Step S25: by first wafer and second wafer bonding, wherein the dielectric layer is towards described second Wafer.
Above-mentioned each step is illustrated below with reference to Fig. 7 to Figure 11.
Fig. 7 to Figure 11 is that the corresponding device profile structure of each step is shown in a kind of wafer bonding method in the embodiment of the present invention It is intended to.
Referring to Fig. 7, the first wafer 200 is provided, first wafer 200 may include central area A and surround described The fringe region B of central area.
Wherein, it could be formed with semiconductor devices in first wafer 200.
In a kind of specific embodiment of the embodiment of the present invention, first wafer 200 can be device wafers (Device Wafer), the second wafer can be carrying wafer (Carrier Wafer), then the semiconductor devices for example can be with Including logical device, pixel device and metal interconnection structure etc..
The logical device may include the device of the transistors such as gate structure and source and drain doping area.It may be noted that Be, in embodiments of the present invention, for specific logical device composition with no restriction.
The pixel device may include photodiode (Photo Diode, PD) and pixel circuit, wherein described Pixel circuit may include forming selection transistor (Select Transistor), reset transistor (Reset Transistor) and source with the various transistors appropriate such as transistor (Source Follower Transistor) device Part, for example, may include transmission grid (Transfer Gate, TG) and floating diffusion region (Floating Diffusion, FD).It should be pointed out that in embodiments of the present invention, for specific pixel circuit composition with no restriction.
In another specific embodiment of the embodiment of the present invention, first wafer 200 can be logic wafer (Logic Wafer), the second wafer can be pixel wafer (Pixel Wafer), then may include in first wafer 200 Logical device may include pixel device in second wafer.
Referring to Fig. 8, dielectric layer 201 is formed on the surface of first wafer 200.
Wherein, the material of the dielectric layer 201 can be selected from silica and silicon nitride.
Further, the silica for example can be SiO2, the silicon nitride for example can be Si3N4
Preferably, the silica can be prepared using ethyl orthosilicate (TEOS), to improve the dielectric layer 201 Quality and compactness.
Further, the thickness of the dielectric layer 201 can be 500nm to 3000nm.
It should be pointed out that the thickness of the dielectric layer 201 should not be blocked up, otherwise will increase flatening process when It is long;The thickness of the dielectric layer 201 should not be excessively thin, otherwise can reduce bonding effect.
It in embodiments of the present invention, can be flat by the setting dielectric layer 201 with a thickness of 500nm to 3000nm After smooth chemical industry skill, obtain dielectric layer 201 with a thickness of 300nm to 1200nm, to meet bonding demand.
Further, in the fringe region B, first wafer 200 may include around the of the central area A One surface B1, and the second surface B2 around the first surface B1, wherein the first surface B1 is plane, described the Two surface B2 are curved surface.
In embodiments of the present invention, plane is showed by the way that first surface B1 is arranged, and the first wafer 200 is ground The region of trimming includes first surface B1, it can be ensured that it is brilliant to be located at first in the edges of regions trimmed to the first wafer 200 In the plane of circle 200, to improve the bonding effect of the first wafer 200 and the second wafer after subsequent bonding technology.
Referring to Fig. 9, edge grinding trimming is carried out to first wafer 200, to remove Jie of the fringe region B surface The a part for first wafer 200 that matter layer 201 and the dielectric layer 201 cover.
In specific implementation, by carrying out edge grinding trimming to the first wafer 200, not advising for crystal round fringes can be removed Then region prevents edge from problem of Cracking occurs, and reduces the stress of device wafers 200, improves the semiconductor devices of formation Quality.
In embodiments of the present invention, due to being initially formed dielectric layer 201, then edge grinding trimming is carried out to the first wafer 200, A part of dielectric layer 201 can be removed when removing a part at edge of the first wafer 200.
It is possible to further carry out edge grinding trimming to first wafer using milling apparatus;Wherein, the grinding Equipment is cylindric diamond blade.
In specific implementation, the milling apparatus can be cylindric diamond blade.It specifically, can be to the first crystalline substance Circle 200 carries out center rotation, and carries out edge to first wafer 200 using the cylindric diamond blade of rotation and grind Mill trimming, to reduce the thickness of the fringe region B of the first wafer 200.Wherein, described can be one or more.
It should be pointed out that can also be trimmed using other milling apparatus appropriate, it is in embodiments of the present invention, right In milling apparatus specific structure and implementation with no restriction.
Referring to Fig.1 0, after forming the dielectric layer 201, the dielectric layer 201 can also be planarized.
In specific implementation, the dielectric layer 201 can be planarized using CMP process, to improve dielectric layer 201 In the consistency of the surface thickness of the first wafer 200.
In embodiments of the present invention, by being initially formed institute before carrying out edge grinding trimming to first wafer 200 It states dielectric layer 201 and the dielectric layer 201 is planarized, compared in the prior art, edge is carried out to the first wafer Dielectric layer is planarized again after grinding trimming, is easy to aggravate dielectric layer edge region the case where there are slopes, use The scheme of the embodiment of the present invention further can effectively avoid the crack to retread between slope plane and the second wafer in wafer bonding The problem of being easy to produce cavity and grey side, to further increase the quality of bonded wafer.
Referring to Fig.1 1, the second wafer 210 is provided, first wafer 201 is bonded with second wafer 210, wherein The dielectric layer 201 is towards second wafer 210.
In specific implementation, when being bonded to the first wafer 201 with second wafer 210, by the first wafer 201 with the bonding face metallization medium layer 201 of second wafer 210, then by being activated to dielectric layer 201, at interface The structure that place generates silicone hydroxyl key (Si-O-H) forms Si-O-Si between two wafers during subsequent annealed Key, and be fixed together by Si-O-Si key.
In embodiments of the present invention, dielectric layer is formed on the surface of first wafer 200 by elder generation, then again to described First wafer 200 carries out edge grinding trimming, the dielectric layer 201 on fringe region surface can be removed when grinding trimming, also Eliminate the slope of 201 edge region of dielectric layer, compared with the prior art in first to the first wafer carry out edge grinding trimming, Dielectric layer is re-formed, and then leads to dielectric layer edge region there are slope, and then is retreaded slope plane and second in wafer bonding Crack between wafer is easy to produce cavity and grey side, using the scheme of the embodiment of the present invention, due to eliminating the dielectric layer The crack to retread between slope plane and the second wafer 210 in wafer bonding can be effectively avoided in the slope of 201 edge regions The problem of being easy to produce cavity and grey side, improves the quality of bonded wafer.
In embodiments of the present invention, a kind of bonded wafer can also be provided, may include: the first wafer as shown in figure 11 200, semiconductor devices is formed in first wafer 200, first wafer 200 includes central area and marginal zone The a part in domain, the first wafer of the fringe region is removed to form groove;Dielectric layer 201 covers first wafer The surface of 200 central area, and the groove is not covered;Second wafer 210 is bonded with first wafer 201, wherein The dielectric layer 201 is towards second wafer 210.
Further, the material of the dielectric layer 201 can be selected from silica and silicon nitride.
Further, first wafer 200 can be device wafers, and second wafer 210 can be carrying wafer.
The pass above and shown in Fig. 6 to Figure 10 is please referred to about the principle of the bonded wafer, specific implementation and beneficial effect In the associated description of the forming method of bonded wafer, details are not described herein again.
Although present disclosure is as above, present invention is not limited to this.Anyone skilled in the art are not departing from this It in the spirit and scope of invention, can make various changes or modifications, therefore protection scope of the present invention should be with claim institute Subject to the range of restriction.

Claims (10)

1. a kind of wafer bonding method characterized by comprising
First wafer is provided, is formed with semiconductor devices in first wafer, first wafer include central area and Fringe region around the central area;
Dielectric layer is formed on the surface of first wafer;
Edge grinding trimming is carried out to first wafer, to remove the dielectric layer on the fringe region surface, and is given an account of A part of first wafer of matter layer covering;
Second wafer is provided;
By first wafer and second wafer bonding, wherein the dielectric layer is towards second wafer.
2. wafer bonding method according to claim 1, which is characterized in that the material of the dielectric layer be selected from silica with And silicon nitride.
3. wafer bonding method according to claim 1, which is characterized in that after forming the dielectric layer, further includes: The dielectric layer is planarized.
4. wafer bonding method according to claim 1, which is characterized in that the dielectric layer with a thickness of 500nm extremely 3000nm。
5. wafer bonding method according to claim 1, which is characterized in that using milling apparatus to first wafer into The trimming of row edge grinding;
Wherein, the milling apparatus is cylindric diamond blade.
6. wafer bonding method according to claim 1, which is characterized in that in the fringe region, first wafer Including the first surface around the central area, and around the second surface of the first surface, wherein first table Face is plane, and the second surface is curved surface.
7. wafer bonding method according to claim 1, which is characterized in that first wafer is device wafers, described Second wafer is carrying wafer.
8. a kind of bonded wafer characterized by comprising
First wafer is formed with semiconductor devices in first wafer, and first wafer includes central area and edge The a part in region, the first wafer of the fringe region is removed to form groove;
Dielectric layer, covers the surface of the central area of first wafer, and does not cover the groove;
Second wafer, with first wafer bonding, wherein the dielectric layer is towards second wafer.
9. bonded wafer according to claim 8, which is characterized in that the material of the dielectric layer is selected from silica and nitrogen SiClx.
10. bonded wafer according to claim 8, which is characterized in that first wafer be device wafers, described second Wafer is carrying wafer.
CN201811391856.0A 2018-11-21 2018-11-21 Wafer bonding method and bonded wafer Pending CN109545672A (en)

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CN112289694A (en) * 2020-10-30 2021-01-29 长江存储科技有限责任公司 Wafer bonding method
CN114420549A (en) * 2022-03-31 2022-04-29 深圳新声半导体有限公司 Method for bonding silicon dioxide surface and silicon surface at low temperature

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