CN109181531A - A kind of Silicone Rubber Based Coatings and preparation method thereof, application - Google Patents

A kind of Silicone Rubber Based Coatings and preparation method thereof, application Download PDF

Info

Publication number
CN109181531A
CN109181531A CN201811041602.6A CN201811041602A CN109181531A CN 109181531 A CN109181531 A CN 109181531A CN 201811041602 A CN201811041602 A CN 201811041602A CN 109181531 A CN109181531 A CN 109181531A
Authority
CN
China
Prior art keywords
parts
silicone rubber
based coatings
rubber based
weight
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201811041602.6A
Other languages
Chinese (zh)
Inventor
袁野
黄治娟
冉远东
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Chengdu Qing Wei Technology Co Ltd
Original Assignee
Chengdu Qing Wei Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Chengdu Qing Wei Technology Co Ltd filed Critical Chengdu Qing Wei Technology Co Ltd
Priority to CN201811041602.6A priority Critical patent/CN109181531A/en
Publication of CN109181531A publication Critical patent/CN109181531A/en
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D183/00Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
    • C09D183/04Polysiloxanes
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2227Oxides; Hydroxides of metals of aluminium
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2265Oxides; Hydroxides of metals of iron
    • C08K2003/2272Ferric oxide (Fe2O3)
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2265Oxides; Hydroxides of metals of iron
    • C08K2003/2275Ferroso-ferric oxide (Fe3O4)

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Paints Or Removers (AREA)

Abstract

A kind of Silicone Rubber Based Coatings and preparation method thereof, application, are related to paint field.Silicone Rubber Based Coatings include the first major ingredient, the second major ingredient, the first auxiliary material and the second auxiliary material, according to parts by weight, first major ingredient includes: 100 parts and organic solvent 80-120 parts of hydroxyl-terminated injecting two methyl siloxane, first auxiliary material includes: 15-30 parts of reinforced filling, second major ingredient is silane coupling agent 7-14 parts, and the second auxiliary material is organotin catalysts 0.2-1.2 parts.The Silicone Rubber Based Coatings have preferable adhesive force and insulation performance, can restoration switch cabinet insulator.

Description

A kind of Silicone Rubber Based Coatings and preparation method thereof, application
Technical field
The present invention relates to paint fields, and in particular to a kind of Silicone Rubber Based Coatings and preparation method thereof, application.
Background technique
The switchgear of power distribution network is because the reasons such as operation year limit for length, dampness, filth, equipment component insulation performance reduce, out Current situation portion discharge defect, and then lead to dielectric breakdown accident, great influence is caused to the power supply reliability of distribution.Conventional process Method is integral replacing to be carried out to equipment, but since the period is long, investment is big, low efficiency, be unfavorable for the development of daily maintenance work. Preferable repairing effect is not achieved in the reparation of conventional vulcanized silicon rubber.
Summary of the invention
The first object of the present invention is to provide a kind of Silicone Rubber Based Coatings, with preferable adhesive force and insulation performance.
The second object of the present invention is to provide a kind of preparation method of Silicone Rubber Based Coatings, and this method is simple, easy to operate.
The third object of the present invention is to provide the reparation that a kind of Silicone Rubber Based Coatings are applied to switchgear insulator.
The present invention solves its technical problem and adopts the following technical solutions to realize.
The present invention proposes a kind of Silicone Rubber Based Coatings comprising the first major ingredient, the second major ingredient, the first auxiliary material and the second auxiliary material, According to parts by weight, the first major ingredient includes: 100 parts and organic solvent 80-120 parts of hydroxyl-terminated injecting two methyl siloxane, and first is auxiliary Material includes: 15-30 parts of reinforced filling, and the second major ingredient is silane coupling agent 7-14 parts, and the second auxiliary material is organotin catalysts 0.2- 1.2 part.
A kind of preparation method of such as above-mentioned Silicone Rubber Based Coatings, comprising: according to parts by weight, will be uniformly mixed first is main The first auxiliary material, the second major ingredient and the second auxiliary material is sequentially added in material to be uniformly mixed.
The beneficial effect of the embodiment of the present invention is:
The Silicone Rubber Based Coatings each group distribution ratio of the application is suitable, wherein organic solvent is mainly used for terminal hydroxy group poly dimethyl The dissolution of siloxanes, hydroxyl-terminated injecting two methyl siloxane is used as film-forming resin, with excellent dielectric properties.It is urged in organotin In the presence of agent, hydroxyl-terminated injecting two methyl siloxane is crosslinked with the organic functional base in silane coupling agent reacts formationization Learn bonding film forming.Siloxy in silane coupling agent, which is contacted to interfacial migration with the water of insulator surface, occurs hydrolysis life At silanol, and siloxanes is formed in conjunction with insulator ground, to increase film layer in insulator adhesive force.In addition, this implementation The reinforced filling of mode can increase the intensity of film-forming resin.
Specific embodiment
It in order to make the object, technical scheme and advantages of the embodiment of the invention clearer, below will be in the embodiment of the present invention Technical solution be clearly and completely described.The person that is not specified actual conditions in embodiment, according to normal conditions or manufacturer builds The condition of view carries out.Reagents or instruments used without specified manufacturer is the conventional production that can be obtained by commercially available purchase Product.
Below to a kind of Silicone Rubber Based Coatings of the embodiment of the present invention and preparation method thereof, using being specifically described.
Preferable repairing effect is not achieved in the reparation of conventional vulcanized silicon rubber, through hating it has been found that being primarily present coating The problem of aqueous forfeiture, internal field's distortion, insulator surface edge flashing.
Based on this, present embodiment provides a kind of Silicone Rubber Based Coatings comprising the first major ingredient, the second major ingredient, the first auxiliary material With the second auxiliary material, according to parts by weight, the first major ingredient includes: 100 parts of hydroxyl-terminated injecting two methyl siloxane and organic solvent 80- 120 parts, the first auxiliary material includes: 15-30 parts of reinforced filling, and the second major ingredient is silane coupling agent 7-14 parts, and the second auxiliary material is organic 0.2-1.2 parts of tin catalyst.
The Silicone Rubber Based Coatings each group distribution ratio of present embodiment is suitable, wherein organic solvent is mainly used for terminal hydroxy group poly- two The dissolution of methylsiloxane, hydroxyl-terminated injecting two methyl siloxane is used as film-forming resin, with excellent dielectric properties.Organic In the presence of tin catalyst, hydroxyl-terminated injecting two methyl siloxane is crosslinked with the organic functional base in silane coupling agent reacts shape It forms a film at chemical bonding.Water is typically contained on insulator ground, the siloxy in silane coupling agent is to interfacial migration and insulate Sublist face water contact occur hydrolysis generate silanol, silanol polycondensation and form siloxanes in conjunction with insulator ground, thus Film layer is increased in insulator adhesive force.In addition, the reinforced filling of present embodiment can increase the intensity of film-forming resin.
In the present embodiment, catalyst includes dibutyl tin dilaurate.Organic solvent includes but is not limited to white gas. It should be noted that white gas that is to say No. 120 gasoline.
In addition, in the present embodiment, silane coupling agent includes three fourth of 3-aminopropyltriethoxysilane and vinyl Ketoximinosilanes, 3-aminopropyltriethoxysilane that is to say Silane coupling agent KH550.3-aminopropyltriethoxysilane Amino can crosslink and react with hydroxyl-terminated injecting two methyl siloxane, the siloxy of 3-aminopropyltriethoxysilane It is bonded strength can be formed with ground.The vinyl of vinyl tributyl ketoximyl silane can be with hydroxyl-terminated injecting two methyl siloxane React film forming, and it is bonded that the siloxy of vinyl tributyl ketoximyl silane can form strength with ground.
In addition, reinforced filling includes white carbon black and aluminium hydroxide.
White carbon black main component is SiO2, with preferable electrical insulating property and big specific surface area.Due to white carbon black Specific surface area is larger, can be improved the adhesive strength of film layer and substrate in Silicone Rubber Based Coatings.The addition of white carbon black simultaneously can Increase Silicone Rubber Based Coatings electrical insulation capability.
In one embodiment, the first auxiliary material further includes pigments and fillers 3-5 parts of coloring;Colouring pigments and fillers includes iron oxide red and four Any one in Fe 3 O or two kinds.
In one embodiment, hydroxyl-terminated injecting two methyl siloxane is 100 parts, and organic solvent is 85-100 parts, reinforcement Filler is 18-25 parts, 8-12 parts of silane coupling agent, and organotin catalysts are 0.5-1 parts.
Present embodiment also provides a kind of preparation method of Silicone Rubber Based Coatings, comprising: according to parts by weight, will be uniformly mixed The first major ingredient in sequentially add the first auxiliary material, the second major ingredient and the second auxiliary material are uniformly mixed.
Wherein, the first uniformly mixed major ingredient, as hydroxyl-terminated injecting two methyl siloxane are dissolved in organic solvent and obtain Uniformly mixed mixture.The first auxiliary material, which is first added, first to be mixed conducive to hydroxyl-terminated injecting two methyl siloxane with the first auxiliary material It is even, after the second major ingredient silane coupling agent is added, organotin catalysts are added, organotin catalysts can be catalyzed silane coupling agent It crosslinks and reacts with hydroxyl-terminated injecting two methyl siloxane, to being formed uniformly reinforced filling and coloring pigments and fillers in coating In, to improve the adhesive strength of coating.
Present embodiment also provides a kind of application of Silicone Rubber Based Coatings, which is applied to switchgear insulator It repairs, comprising: Silicone Rubber Based Coatings are coated on insulator, then spray the modified powder of PHM in surface, dry solidification is laggard at room temperature Row maintenance.
It should be noted that Silicone Rubber Based Coatings can be coated on by present embodiment by modes such as spraying, brushing or roller coating On insulator.Silane coupling agent crosslinks the film layer for reacting and being formed with hydroxyl-terminated injecting two methyl siloxane and is attached to insulator Surface, the siloxy in silane coupling agent form hydrogen-oxygen with insulator ground and are bonded, and increase film layer and insulator ground Adhesive force, while showing preferable insulation performance.
In addition, the modified powder of PHM has the function of being not easy to form moisture film, generation flashover in insulator surface, water is enabled to Pearl tumbles or explosion, so as to increase present embodiment rubber coating hydrophobic angle.
Feature and performance of the invention are described in further detail with reference to embodiments.
Embodiment 1
The white gas of 120 parts by weight is added in the hydroxyl-terminated injecting two methyl siloxane of 100 parts by weight, is sufficiently mixed stirring Uniformly obtain mixture, sequentially add in the mixture 3 parts by weight of iron oxide red, 8 parts by weight of aluminium hydroxide, 10 parts by weight of white carbon black, 4 parts by weight of vinyl tributyl ketoximyl silane, 5 parts by weight of 3-aminopropyltriethoxysilane and dibutyl tin dilaurate 0.6 parts by weight are uniformly mixed and obtain Silicone Rubber Based Coatings.
On the insulator by the spraying of obtained Silicone Rubber Based Coatings, the modified powder of upper PHM is then sprayed, drying at room temperature solidifies for 24 hours Afterwards, it conserves 7 days and obtains insulating coating.
Embodiment 2
The white gas of 100 parts by weight is added in the hydroxyl-terminated injecting two methyl siloxane of 100 parts by weight, is sufficiently mixed stirring Mixture uniformly is obtained, sequentially adds 4 parts by weight of iron oxide red, 7 parts by weight of aluminium hydroxide, 8 parts by weight of white carbon black, second in the mixture 3 parts by weight of alkenyl tributanoximo silane, 4 parts by weight of 3-aminopropyltriethoxysilane and dibutyl tin dilaurate 0.5 parts by weight are uniformly mixed and obtain Silicone Rubber Based Coatings.
On the insulator by the spraying of obtained Silicone Rubber Based Coatings, the modified powder of upper PHM is then sprayed, drying at room temperature solidifies for 24 hours Afterwards, it conserves 7 days and obtains insulating coating.
Embodiment 3
The white gas of 80 parts by weight is added in the hydroxyl-terminated injecting two methyl siloxane of 100 parts by weight, is sufficiently mixed stirring Mixture uniformly is obtained, sequentially adds 3 parts by weight of ferroso-ferric oxide, 9 parts by weight of aluminium hydroxide, 13 weight of white carbon black in the mixture Measure part, 5 parts by weight of vinyl tributyl ketoximyl silane, 3 parts by weight of 3-aminopropyltriethoxysilane and tin dilaurate two 1 parts by weight of butyl tin are uniformly mixed and obtain Silicone Rubber Based Coatings.
On the insulator by the spraying of obtained Silicone Rubber Based Coatings, the modified powder of upper PHM is then sprayed, drying at room temperature solidifies for 24 hours Afterwards, it conserves 7 days and obtains insulating coating.
Embodiment 4
The white gas of 85 parts by weight is added in the hydroxyl-terminated injecting two methyl siloxane of 100 parts by weight, is sufficiently mixed stirring Mixture uniformly is obtained, sequentially adds 1 parts by weight of iron oxide red, 2.5 parts by weight of ferroso-ferric oxide, 10 weight of aluminium hydroxide in the mixture Measure part, 15 parts by weight of white carbon black, 5 parts by weight of vinyl tributyl ketoximyl silane, 7 parts by weight of 3-aminopropyltriethoxysilane And 0.8 parts by weight of dibutyl tin dilaurate are uniformly mixed and obtain Silicone Rubber Based Coatings.
On the insulator by the spraying of obtained Silicone Rubber Based Coatings, the modified powder of upper PHM is then sprayed, drying at room temperature solidifies for 24 hours Afterwards, it conserves 7 days and obtains insulating coating.
Embodiment 5
The white gas of 90 parts by weight is added in the hydroxyl-terminated injecting two methyl siloxane of 100 parts by weight, is sufficiently mixed stirring Mixture uniformly is obtained, sequentially adds 4.5 parts by weight of iron oxide red, 12 parts by weight of aluminium hydroxide, 16 weight of white carbon black in the mixture Part, two fourth of 8 parts by weight of vinyl tributyl ketoximyl silane, 6 parts by weight of 3-aminopropyltriethoxysilane and tin dilaurate 0.2 parts by weight of base tin are uniformly mixed and obtain Silicone Rubber Based Coatings.
On the insulator by the spraying of obtained Silicone Rubber Based Coatings, the modified powder of upper PHM is then sprayed, drying at room temperature solidifies for 24 hours Afterwards, it conserves 7 days and obtains insulating coating.
Embodiment 6
The white gas of 110 parts by weight is added in the hydroxyl-terminated injecting two methyl siloxane of 100 parts by weight, is sufficiently mixed stirring Uniformly obtain mixture, sequentially add in the mixture 5 parts by weight of iron oxide red, 15 parts by weight of aluminium hydroxide, 15 parts by weight of white carbon black, 6 parts by weight of vinyl tributyl ketoximyl silane, 5 parts by weight of 3-aminopropyltriethoxysilane and dibutyl tin dilaurate 0.2 parts by weight are uniformly mixed and obtain Silicone Rubber Based Coatings.
On the insulator by the spraying of obtained Silicone Rubber Based Coatings, the modified powder of upper PHM is then sprayed, drying at room temperature solidifies for 24 hours Afterwards, it conserves 7 days and obtains insulating coating.
Embodiment 7
The white gas of 105 parts by weight is added in the hydroxyl-terminated injecting two methyl siloxane of 100 parts by weight, is sufficiently mixed stirring Uniformly obtain mixture, sequentially add in the mixture 4 parts by weight of iron oxide red, 10 parts by weight of aluminium hydroxide, 8 parts by weight of white carbon black, 4 parts by weight of vinyl tributyl ketoximyl silane, 6 parts by weight of 3-aminopropyltriethoxysilane and dibutyl tin dilaurate 0.4 parts by weight are uniformly mixed and obtain Silicone Rubber Based Coatings.
On the insulator by the spraying of obtained Silicone Rubber Based Coatings, the modified powder of upper PHM is then sprayed, drying at room temperature solidifies for 24 hours Afterwards, it conserves 7 days and obtains insulating coating.
Embodiment 8
The white gas of 120 parts by weight is added in the hydroxyl-terminated injecting two methyl siloxane of 100 parts by weight, is sufficiently mixed stirring Mixture uniformly is obtained, sequentially adds 3 parts by weight of iron oxide red, 18 parts by weight of aluminium hydroxide, three diacetylmonoxime of vinyl in the mixture 4 parts by weight of base silane, 5 parts by weight of 3-aminopropyltriethoxysilane and the mixing of 0.6 parts by weight of dibutyl tin dilaurate Uniformly obtain Silicone Rubber Based Coatings.
On the insulator by the spraying of obtained Silicone Rubber Based Coatings, the modified powder of upper PHM is then sprayed, drying at room temperature solidifies for 24 hours Afterwards, it conserves 7 days and obtains insulating coating.
Embodiment 9
The white gas of 120 parts by weight is added in the hydroxyl-terminated injecting two methyl siloxane of 100 parts by weight, is sufficiently mixed stirring Mixture uniformly is obtained, sequentially adds 3 parts by weight of iron oxide red, 18 parts by weight of white carbon black, vinyl tributanoximo in the mixture 4 parts by weight of silane, 5 parts by weight of 3-aminopropyltriethoxysilane and the mixing of 0.6 parts by weight of dibutyl tin dilaurate are equal It is even to obtain Silicone Rubber Based Coatings.
On the insulator by the spraying of obtained Silicone Rubber Based Coatings, the modified powder of upper PHM is then sprayed, drying at room temperature solidifies for 24 hours Afterwards, it conserves 7 days and obtains insulating coating.
Test example
(1) test of adhesive force is carried out to the insulating coating of embodiment 1-9, test method is referring to GB/T 1720-1979 (1989) (paint film adhesion measuring method), result is recorded in table 1.
(2) to the insulating coating of embodiment 1-9 carry out surface resistivity, volume resistivity, dielectric constant, dielectric loss because Element and electrical strength are tested, and test method is referring to GB/T1692-2008 (measurement of vulcanized rubber insulation resistivity), knot Fruit is recorded in table 1.
The test result of the insulating coating of 1 embodiment 1-9 of table
Interpretation of result: from the results shown in Table 1, the insulating coating that the Silicone Rubber Based Coatings of embodiment 1-9 eventually form With preferable adhesive force, while also there is preferable insulation performance.
In conclusion Silicone Rubber Based Coatings of the embodiment of the present invention and preparation method thereof, application, pass through spraying, brushing or rolling Silicone Rubber Based Coatings are coated on insulator by the modes such as painting.Silane coupling agent and hydroxyl-terminated injecting two methyl siloxane crosslink instead The film layer that should be formed is attached to insulator surface, and the siloxy in silane coupling agent and insulator ground form hydrogen-oxygen key It closes, increases film layer and insulator substrate adhesion, while showing preferable insulation performance.
Embodiments described above is a part of the embodiment of the present invention, instead of all the embodiments.Reality of the invention The detailed description for applying example is not intended to limit the range of claimed invention, but is merely representative of selected implementation of the invention Example.Based on the embodiments of the present invention, obtained by those of ordinary skill in the art without making creative efforts Every other embodiment, shall fall within the protection scope of the present invention.

Claims (10)

1. a kind of Silicone Rubber Based Coatings, which is characterized in that it includes the first major ingredient, the second major ingredient, the first auxiliary material and the second auxiliary material, is pressed Parts by weight meter, first major ingredient includes: 100 parts and organic solvent 80-120 parts of hydroxyl-terminated injecting two methyl siloxane, described First auxiliary material includes: 15-30 parts of reinforced filling, and second major ingredient is silane coupling agent 7-14 parts, and second auxiliary material is to have 0.2-1.2 parts of machine tin catalyst.
2. Silicone Rubber Based Coatings according to claim 1, which is characterized in that according to parts by weight, the poly- diformazan of terminal hydroxy group Radical siloxane is 100 parts, and the organic solvent is 85-100 parts, and the reinforced filling is 18-25 parts, the silane coupling agent 8- 12 parts, the organotin catalysts are 0.5-1 parts.
3. Silicone Rubber Based Coatings according to claim 1, which is characterized in that the organotin catalysts include tin dilaurate two Butyl tin.
4. Silicone Rubber Based Coatings according to claim 1-3, which is characterized in that according to parts by weight, described first Auxiliary material further includes pigments and fillers 3-5 parts of coloring.
5. Silicone Rubber Based Coatings according to claim 4, which is characterized in that the coloring pigments and fillers include iron oxide red and four oxidations Any one in three-iron or two kinds.
6. Silicone Rubber Based Coatings according to claim 1-3, which is characterized in that the silane coupling agent includes 3- ammonia Base propyl-triethoxysilicane and vinyl tributyl ketoximyl silane.
7. Silicone Rubber Based Coatings according to claim 1-3, which is characterized in that the reinforced filling includes white carbon black And aluminium hydroxide.
8. Silicone Rubber Based Coatings according to claim 1-3, which is characterized in that the organic solvent includes white vapour Oil.
9. a kind of preparation method of such as described in any item Silicone Rubber Based Coatings of claim 1-8 characterized by comprising by weight Number meter is measured, first auxiliary material, second major ingredient and described the are sequentially added in first major ingredient that will be uniformly mixed Two auxiliary materials are uniformly mixed.
10. a kind of reparation for being applied to switchgear insulator such as the described in any item Silicone Rubber Based Coatings of claim 1-8, feature It is, comprising: the Silicone Rubber Based Coatings are coated on the insulator, the modified powder of PHM is then sprayed in surface, dries at room temperature It is conserved after solidification.
CN201811041602.6A 2018-09-06 2018-09-06 A kind of Silicone Rubber Based Coatings and preparation method thereof, application Pending CN109181531A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201811041602.6A CN109181531A (en) 2018-09-06 2018-09-06 A kind of Silicone Rubber Based Coatings and preparation method thereof, application

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201811041602.6A CN109181531A (en) 2018-09-06 2018-09-06 A kind of Silicone Rubber Based Coatings and preparation method thereof, application

Publications (1)

Publication Number Publication Date
CN109181531A true CN109181531A (en) 2019-01-11

Family

ID=64915197

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201811041602.6A Pending CN109181531A (en) 2018-09-06 2018-09-06 A kind of Silicone Rubber Based Coatings and preparation method thereof, application

Country Status (1)

Country Link
CN (1) CN109181531A (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109749623A (en) * 2019-01-11 2019-05-14 广州德海高分子材料科技有限公司 Antirust weathering brushes high molecular material and its preparation method and application
CN114907767A (en) * 2022-04-20 2022-08-16 广东电网有限责任公司 Antibacterial silicone rubber coating and preparation method thereof
CN115011246A (en) * 2022-07-01 2022-09-06 成都拓利科技股份有限公司 High-strength wear-resistant organic silicon protective coating and preparation method thereof
CN115449293A (en) * 2022-10-20 2022-12-09 河南四达检测技术有限公司 Wire insulating paint for coating electrified insulating coating robot

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101942273B (en) * 2010-08-19 2013-03-20 福建瑞森化工有限公司 Anti-explosive splattering paint and preparation method thereof
CN104231919A (en) * 2014-10-15 2014-12-24 大连海事大学 Nanometer reinforced, non-transition-layer, organosilicone and low-surface-energy type antifouling paint and preparation method thereof
CN104673091A (en) * 2015-02-28 2015-06-03 成都拓利化工实业有限公司 RTV anti-pollution flashover coating suitable for automatic dip-coating of insulator and preparation method of RTV anti-pollution flashover coating
CN105086823A (en) * 2015-05-28 2015-11-25 浙江凌志精细化工有限公司 Organosilicone room-temperature-cured anticorrosive coating material
CN106833369A (en) * 2017-01-05 2017-06-13 无锡海特新材料研究院有限公司 A kind of ageing-resistant soil resistance hull coatings material and preparation method thereof

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101942273B (en) * 2010-08-19 2013-03-20 福建瑞森化工有限公司 Anti-explosive splattering paint and preparation method thereof
CN104231919A (en) * 2014-10-15 2014-12-24 大连海事大学 Nanometer reinforced, non-transition-layer, organosilicone and low-surface-energy type antifouling paint and preparation method thereof
CN104673091A (en) * 2015-02-28 2015-06-03 成都拓利化工实业有限公司 RTV anti-pollution flashover coating suitable for automatic dip-coating of insulator and preparation method of RTV anti-pollution flashover coating
CN105086823A (en) * 2015-05-28 2015-11-25 浙江凌志精细化工有限公司 Organosilicone room-temperature-cured anticorrosive coating material
CN106833369A (en) * 2017-01-05 2017-06-13 无锡海特新材料研究院有限公司 A kind of ageing-resistant soil resistance hull coatings material and preparation method thereof

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
黄文润: "《液体硅橡胶》", 30 June 2009, 四川科学技术出版社 *

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109749623A (en) * 2019-01-11 2019-05-14 广州德海高分子材料科技有限公司 Antirust weathering brushes high molecular material and its preparation method and application
CN114907767A (en) * 2022-04-20 2022-08-16 广东电网有限责任公司 Antibacterial silicone rubber coating and preparation method thereof
CN115011246A (en) * 2022-07-01 2022-09-06 成都拓利科技股份有限公司 High-strength wear-resistant organic silicon protective coating and preparation method thereof
CN115449293A (en) * 2022-10-20 2022-12-09 河南四达检测技术有限公司 Wire insulating paint for coating electrified insulating coating robot

Similar Documents

Publication Publication Date Title
CN109181531A (en) A kind of Silicone Rubber Based Coatings and preparation method thereof, application
CN105086823B (en) Room temperature silicone curing and anticorrosive coating
CN106543895B (en) Anti-pollution flashover coating and preparation method thereof
CN102424742B (en) Hot-wet resistant and aging resistant dual-component condensation type room temperature curing silicone rubber
CN103131240B (en) A kind of automatically cleaning antifouling flush paint and preparation method thereof
CN102977700B (en) A kind of comprehensive coating that improves aerial condutor performance
CN106479354B (en) A kind of antifouling anticorrosive nano polysiloxane coating materials of primer-topcoat in one and preparation method thereof
CN103483823B (en) A kind of rubber composition and the technique using its production organic silicon self-adhesive tape
CN103965827A (en) Super-hydrophobic and anti-pollution flashover one-component adhesive, and preparation method and application thereof
CN101575482A (en) Anti-pollution flashover organosilicon coating and preparation method thereof
CN105331199A (en) Visual temperature-measuring and insulating method for power product
CN105754476A (en) Silicon rubber antifouling hydrophobic coating and preparation method thereof
CN109401564B (en) High-weather-resistance hydrophobic self-cleaning metal curtain wall plate and preparation method thereof
CN104297149A (en) Testing method for adhesive force of RTV (Room Temperature Vulcanization) anti-pollution-flashover paint
CN114163884A (en) Waterproof anti-slip coating special for outer wall and preparation method and application thereof
CN107722828A (en) The special antifouling wet coating material of reactor and its manufacture method
CN109536937A (en) Highly corrosion resistant galvanized steel plain sheet and preparation method thereof
CN116574433A (en) Preparation method of silane modified polyether waterproof coating
CN102153754B (en) Silicone resin, latex paint thereof, preparation methods of silicone resin and latex paint thereof and coating
CN110041821A (en) A kind of preparation method coating modified version polyimide wire coating enamel material
CN105038685A (en) Non-tar cable connector polyurethane waterproof sealant and preparation method thereof
CN109161303A (en) A kind of coating material of insulating powder in use
CN108774449A (en) A kind of solvent-free insulated anti-corrosive and waterproof paint and preparation method thereof
CN2399805Y (en) High voltage insulator able to indicate flashover fault
CN109651639B (en) Method for preparing super-hydrophobic surface on surface of silicon rubber

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication

Application publication date: 20190111

RJ01 Rejection of invention patent application after publication