CN109007018A - A kind of antistaling agent and its preparation method and application - Google Patents
A kind of antistaling agent and its preparation method and application Download PDFInfo
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- CN109007018A CN109007018A CN201811057564.3A CN201811057564A CN109007018A CN 109007018 A CN109007018 A CN 109007018A CN 201811057564 A CN201811057564 A CN 201811057564A CN 109007018 A CN109007018 A CN 109007018A
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- antistaling agent
- fresh
- starch
- calcium peroxide
- calper calcium
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- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23B—PRESERVING, e.g. BY CANNING, MEAT, FISH, EGGS, FRUIT, VEGETABLES, EDIBLE SEEDS; CHEMICAL RIPENING OF FRUIT OR VEGETABLES; THE PRESERVED, RIPENED, OR CANNED PRODUCTS
- A23B9/00—Preservation of edible seeds, e.g. cereals
- A23B9/16—Preserving with chemicals
- A23B9/24—Preserving with chemicals in the form of liquids or solids
- A23B9/30—Inorganic compounds
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- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23B—PRESERVING, e.g. BY CANNING, MEAT, FISH, EGGS, FRUIT, VEGETABLES, EDIBLE SEEDS; CHEMICAL RIPENING OF FRUIT OR VEGETABLES; THE PRESERVED, RIPENED, OR CANNED PRODUCTS
- A23B5/00—Preservation of eggs or egg products
- A23B5/08—Preserving with chemicals
- A23B5/12—Preserving with chemicals in the form of liquids or solids
- A23B5/18—Inorganic compounds
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- Engineering & Computer Science (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
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Abstract
The present invention relates to preservation fields, in particular to a kind of antistaling agent and its preparation method and application.A kind of antistaling agent is mainly made of following active principle, percentage, calper calcium peroxide 40%-80%, montmorillonite powder 5%-30%, white carbon black 5%-20%, starch 5%-15%, active carbon 5%-20%.The present invention is to provide a kind of moist antistaling agents of control for having both absorbing carbon dioxide release oxygen, with efficient absorbing carbon dioxide ability, and have type discharge oxygen ability and lasting wettability power, it can make by the reduction of the pack environment oxygen concentration, humidity, carbon dioxide of fresh-keeping object, supremacy clause is provided by the storage life of fresh-keeping object to extend.
Description
Technical field
The present invention relates to preservation fields, in particular to a kind of antistaling agent and its preparation method and application.
Background technique
In vegetable seeds is fresh-keeping and the preservation field of egg, the mode for being all made of refrigeration at present is stored, this technology
It uses till today always, the quality of preserved object is often influenced because of the variation of storage condition during storage, to drop
The quality of low preserved object.And often passes through in the storage art of egg and seed and increase pesticide and addition otherization
Article is learned to reach fresh-keeping effect.Example: " Prochloraz " is placed in rice to prevent rice paddy seed from going mouldy；Egg fresh-keeping passes through " salt
Water ", " limewash " achieve the effect that extend egg storage life to impregnate.
In addition, in vegetable seeds and egg fresh-keeping field, it will usually reduced using dehumidifier by around fresh-keeping object
Air humidity reduce by the water activity of fresh-keeping object, but storage of the seed in collecting season, transportational process and in agency
There is no the dehumidification equipment of profession in depositing, lead to seed moisture absorption moldy metamorphism, influence the germination percentage of seed and egg usually because not
The quality for being effectively protected and reducing egg itself.
In view of the above-mentioned problems, the present invention is specifically proposed.
Summary of the invention
The first object of the present invention is to provide a kind of antistaling agent have efficient absorbing carbon dioxide ability, and have
Standby type discharge oxygen ability and lasting wettability power, can make by the pack environment oxygen concentration of fresh-keeping object, humidity, the drop of carbon dioxide
It is low, supremacy clause is provided by the storage life of fresh-keeping object to extend.
The second object of the present invention is to provide the preparation method of antistaling agent described in one kind, since montmorillonite powder is easy to moisture absorption
Expansion, activated carbon particle size is small, the big mobility and antistaling agent outer bag seal quality for influencing material under Drug packing of packaging dust, this
The preparation method of invention overcomes above-mentioned problem, and preparation process is simple, low in cost, is conducive to industrialized production.
The third object of the present invention provide the antistaling agent vegetable seeds is fresh-keeping and egg it is fresh-keeping in application,
Preservation is not only effectively played, extends fresh keeping time, and increase by the safety of fresh-keeping object.
In order to realize above-mentioned purpose of the invention, the following technical scheme is adopted:
A kind of antistaling agent is mainly made of following active principle, percentage, calper calcium peroxide 40%-80%, is covered
De- mountain flour 5%-30%, white carbon black 5%-20%, starch 5%-15%, active carbon 5%-20%.
The raw material that antistaling agent provided by the invention is related to belong to nontoxic, harmless material, in plant species in the antistaling agent
In fresh-keeping and egg the preservation field of son, completely dispenses with the addition of chemicals and extend that vegetable seeds is fresh-keeping and egg
Fresh keeping time reduces the use of chemicals, increases and protected so can completely be trusted edible and used by fresh-keeping object
The safety of fresh material.
The active carbon being added in the antistaling agent can adsorb the penetrating odor as generated in corn seed " coating ", and inhale
It is attached partly because seed " coating " and generate harmful substance, to reduce injury of the irritant gas in seed to human body.
The antistaling agent is understood in use in constant absorption air and by the moisture of fresh-keeping object itself, to reduce fresh-keeping
Water activity in object and air, the lasting growth for keeping dry environment and preventing bacterium, reaches extension by the guarantor of fresh-keeping object
The matter phase.
According to described in [0005] such as: crop biology key lab of Shandong Agricultural University, Shandong Agricultural University is just to " agricultural university
The corn seed of 108 " brands is made that research, research shows that: with the increase of seed moisture content, carbon dioxide releasing amount is obvious
Increase, shows that the seed respiratory intensity of 18% initial moisture is 615 times of 13% water content seed from experimental data；It is 14% to contain
66 times of water seed；It is 19 times of 15% water content seed；It is 10 times of 16 water content seeds, is 17% water content seed
3 times, which can absorb the moisture generated by the breathing of fresh-keeping object and absorption by fresh-keeping object packet in by the packaging bag of fresh-keeping object
Moisture in pack reaches maintenance by the moisture of fresh-keeping object and reduces by the moisture of fresh-keeping object, to stablize by fresh-keeping object just
Often breathing extended by the shelf-life of fresh-keeping object.
Vegetable seeds is fresh-keeping and egg it is fresh-keeping in because seed and egg have vitality therefore can absorb oxygen release
Carbon dioxide can carry out packaging bag in storage to prick the ventilative processing in hole at present, because having air hole by the packaging bag of fresh-keeping object,
So the moisture and bacterium in air can be entered by air hole by the packaging bag of fresh-keeping object, carried out in by fresh-keeping object numerous
It grows to influence by preservation liquid amount.After the antistaling agent, do not had to carry out ventilative processing by the outer bag of fresh-keeping object, to block
Bacterium and moisture in air enter in packaging bag, and the calper calcium peroxide in antistaling agent has certain biocidal efficacies, can
To kill the bacterium in packaging bag, then the carbon dioxide generated in breathing by fresh-keeping object can be absorbed by antistaling agent discharges oxygen
Gas, white carbon black and active carbon in antistaling agent can absorb the other harmful substances matter generated by fresh-keeping object, to be provided by fresh-keeping object
One clean storage condition and extend by the shelf life of fresh-keeping object.
The present invention is combined by the way that a certain proportion of montmorillonite powder and white carbon black are added in antistaling agent, can be stored a large amount of
Free water is removed and is emptied rapidly the free water by fresh-keeping object in packaging in packaging bag, while can also empty by fresh-keeping object
The free water generated under respiration greatly reduces to make to form circulation in packaging bag by fresh-keeping object packaging bag
Humidity, and there is white carbon black very strong water storage performance to make the inexcessive moisture absorption of the calper calcium peroxide in medicament and put oxygen, thus broken
It is bad to continue the faint performance for putting oxygen.
Vegetable seeds is fresh-keeping and egg it is fresh-keeping in, be 20.9% by oxygen concentration of the fresh-keeping object in storage condition,
And respiration will stronger while generation exhaust gas and consumption self-energy under the higher environment of oxygen concentration by fresh-keeping object
It will increase, just shorten the quality preservation period of seed.Antistaling agent provided by the invention can be absorbed two being put into fresh-keeping object
Carbonoxide and moisture, antistaling agent will do it type discharge oxygen, will not release immediately a large amount of oxygen, pass through the ventilative of antistaling agent outer packing
Processing, will fall below 3%-15% by the bag internal oxygen gas concentration of fresh-keeping object, because the reduction of oxygen concentration is to by fresh-keeping object
Hypopnea reaches extension by the shelf-life of fresh-keeping object, and antistaling agent can in the range of itself puts oxygen amount type discharge oxygen, will not
It allows and anaerobic respiration necrosis is carried out by fresh-keeping object.
To sum up, the present invention is to provide a kind of moist antistaling agent of control for having both absorbing carbon dioxide release oxygen, there is height
The absorbing carbon dioxide ability of effect, and have type discharge oxygen ability and lasting wettability power, it can make by the packaging ring of fresh-keeping object
The reduction of border oxygen concentration, humidity, carbon dioxide provides supremacy clause by the storage life of fresh-keeping object to extend.
Preferably, percentage, calper calcium peroxide 40%-70%, montmorillonite powder 5%-20%, white carbon black 5%-
20%, starch 5%-15%, active carbon 5%-15%.
Preferably, percentage, calper calcium peroxide 40%-55%, montmorillonite powder 5%-15%, white carbon black 5%-
20%, starch 5%-10%, active carbon 8%-15%.
As in various embodiments, calper calcium peroxide can for 40%, 42%, 45%, 48%, 50%, 55%, 58%,
60%, 65%, 68%, 70%, 72%, 75%, 78%, 80% etc., montmorillonite powder can for 5%, 8%, 10%, 12%,
15%, 18%, 20%, 25%, 28%, 30% etc., white carbon black can for 5%, 8%, 10%, 12%, 15%, 18%,
20% etc., starch can be 5%, 7%, 8%, 10%, 12%, 13%, 15% etc., active carbon can for 5%, 8%,
10%, 12%, 15%, 18%, 20% etc..
Further, the starch is at least one of cornstarch, potato starch, tapioca, industrial starch；
Preferably cornstarch and/or potato starch.
Further, the active carbon be wood activated charcoal, active fruit shell carbon, coaly activated carbon, in regenerated carbon at least
It is a kind of；Preferably wood activated charcoal or active fruit shell carbon.
Further, the calper calcium peroxide purity is 50%~70%.Such as in various embodiments, calper calcium peroxide purity
It is 50%, 52%, 55%, 58%, 60%, 65%, 70% etc..
Further, the form of the calper calcium peroxide is powder or particle.
Further, the partial size of the montmorillonite powder is 10-100 mesh, -100 mesh of preferably 80 mesh.Such as in different implementation
In example, the partial size of montmorillonite powder can be 10 mesh, 15 mesh, 18 mesh, 20 mesh, 22 mesh, 25 mesh, 28 mesh, 30 mesh, 35 mesh, 40 mesh, 45
Mesh, 50 mesh, 55 mesh, 60 mesh, 70 mesh, 80 mesh, 85 mesh, 90 mesh, 95 mesh, 100 mesh etc..
The present invention also provides the preparation methods of the antistaling agent, comprising the following steps:
Montmorillonite powder, active carbon, starch and water mixing granulation, obtain hybrid particles；
The hybrid particles be added calper calcium peroxide and white carbon black mixing to get.
The preparation method of antistaling agent provided by the invention is mixed by the way that montmorillonite powder to be first prepared into active carbon and starch
Particle, then mixed with other raw materials, it can solve montmorillonite powder expansion easy to moisture absorption, active carbon carefully packs the big influence medicament of dust very much
Blanking flowability problem is packed, to obtain the good antistaling agent of packaging character.Also, preparation process is simple, low in cost, benefit
In industrialized production.
Further, the moisture content of the hybrid particles is lower than 2%.
Further, the partial size of the hybrid particles is in 0.5-1.0mm.
Antistaling agent provided by the invention is that a kind of particle adds powder agent, and can be put into packaging bag can also be put into box
In obtain finished product for selling or use.
Further, the antistaling agent further includes outer packing.
Further, the outer packing includes satchel or box.
Antistaling agent provided by the invention is that a kind of particle adds powder agent, wherein while moisture absorption, white carbon black can be stored up
A large amount of free water is deposited, volume expansion, hybrid particles generating body can occur for hybrid particles under the synergistic effect with hybrid particles
Wherein calper calcium peroxide can be increased after product expansion can further improve antistaling agent with by the contact area of air in fresh-keeping object packaging bag
Lasting fresh keeping property.
Currently, domestic put oxygen type antistaling agent (domestic antistaling agent spininess at present without what is researched and developed for vegetable seeds, egg
Do not have vital product to food, drug, kind is deoxidizing antistaling agent, alcohol antistaling agent), as vital plant
Species, egg, it is provided by the invention to put oxygen type antistaling agent and be conducive to while having novelty agricultural production and increase egg
Edible safety.
The application that the present invention also provides the antistaling agents in vegetable seeds is fresh-keeping, the antistaling agent are protected in eggs
Application in fresh.
Further, the eggs include egg, duck's egg, goose egg, quail egg.
The control moist antistaling agent prepared by the present invention for having both absorbing carbon dioxide release oxygen puts oxygen ability with lasting,
Oxygen concentration in container can be maintained into 3%-15%, and have quick wettability power, hydroscopicity reaches as high as 50%,
Higher than general hygroscopicity desiccant, (molecular sieve desiccant maximum moisture absorption rate is 19% or so, calcium oxide desiccant maximum moisture absorption rate
It is 32% or so), so that application product is greatly prolonged storage life by the improvement of pack environment.
Compared with prior art, the invention has the benefit that
(1) raw material involved in antistaling agent provided by the invention belong to nontoxic, harmless material, so can by fresh-keeping object
Completely to trust edible and use, the use of chemicals is reduced, is increased by the safety of fresh-keeping object.
(2) antistaling agent provided by the invention has efficient absorbing carbon dioxide ability, and has type discharge oxygen ability
With lasting wettability power, oxygen concentration maintains 3%-15%, can make by pack environment oxygen concentration, humidity, the dioxy of fresh-keeping object
Change the reduction of carbon, supremacy clause is provided by the storage life of fresh-keeping object to extend.
(3) preparation process of the invention is simple, low in cost, is conducive to industrialized production.
(4) present invention is by being first prepared into hybrid particles for montmorillonite powder and active carbon, then mixes with other raw materials, can be with
The expansion easy to moisture absorption of solution montmorillonite powder, active carbon carefully pack the big influence Drug packing blanking flowability problem of dust very much, to obtain
Obtain the good antistaling agent of packaging character.
Specific embodiment
Embodiment of the present invention is described in detail below in conjunction with embodiment, but those skilled in the art will
Understand, the following example is merely to illustrate the present invention, and is not construed as limiting the scope of the invention.It is not specified in embodiment specific
Condition person carries out according to conventional conditions or manufacturer's recommended conditions.Reagents or instruments used without specified manufacturer is
The conventional products that can be obtained by commercially available purchase.
Embodiment 1
The moist antistaling agent of control for having both absorbing carbon dioxide release oxygen, takes each raw material: peroxide by following weight percent
Change calcium 55%, montmorillonite powder 15%, white carbon black 15%, cornstarch 7%, active fruit shell carbon 8%.
Wherein, calper calcium peroxide purity is 50%~70%, and the partial size of montmorillonite powder is 80 mesh.
The preparation method is as follows:
Cornstarch, active fruit shell carbon, montmorillonite powder are put into sugar coating machine and are uniformly mixed by the first step, then will mixing
The water that 3:1 is added in object carries out being thoroughly mixed granulation；
By hybrid particles object, with 150 DEG C of progress, drying to constant weight, and moisture content is lower than 2%, obtains hybrid particles, mixing
The partial size of grain is in 0.5-1.0mm.
Second step, the preparation of antistaling agent finished product:
Calper calcium peroxide and white carbon black are added in hybrid particles, is uniformly mixed, obtains manufactured goods.
By taking 2 grams of net weight of finished product as an example, surveying total amount of carbon dioxide of inhaling is 680ml, and always putting oxygen amount is 340ml, and total moisture absorption is
40%.
Embodiment 2
The moist antistaling agent of control for having both absorbing carbon dioxide release oxygen, takes each raw material: peroxide by following weight percent
Change calcium 47%, montmorillonite powder 15%, white carbon black 20%, cornstarch 10%, active fruit shell carbon 8%.
Wherein, calper calcium peroxide purity is 50%~70%, and the partial size of montmorillonite powder is 100 mesh.
The preparation method is as follows:
Cornstarch, active fruit shell carbon, montmorillonite powder are put into sugar coating machine and are uniformly mixed by the first step, then will mixing
The water that 3:1 is added in object carries out being thoroughly mixed granulation；
By hybrid particles object, with 150 DEG C of progress, drying to constant weight, and moisture content is lower than 2%, obtains hybrid particles, mixing
The partial size of grain is in 0.5-1.0mm.
Second step, the preparation of antistaling agent finished product:
Calper calcium peroxide and white carbon black are added in hybrid particles, is uniformly mixed, obtains manufactured goods.
By taking 2 grams of net weight of finished product as an example, surveying total amount of carbon dioxide of inhaling is 580ml, and always putting oxygen amount is 290ml, and total moisture absorption is
43%.
Embodiment 3
The moist antistaling agent of control for having both absorbing carbon dioxide release oxygen, takes each raw material: peroxide by following weight percent
Change calcium 40%, montmorillonite powder 30%, white carbon black 20%, potato starch 5%, wood activated charcoal 5%.
Wherein, calper calcium peroxide purity is 50%~70%, and the partial size of montmorillonite powder is 80 mesh.
The preparation method is as follows:
Potato starch, wood activated charcoal, montmorillonite powder are put into sugar coating machine and are uniformly mixed, then will mix by the first step
The water for closing addition 2:1 in object carries out being thoroughly mixed granulation；
By hybrid particles object, with 150 DEG C of progress, drying to constant weight, and moisture content is lower than 2%, obtains hybrid particles, mixing
The partial size of grain is in 0.5-1.0mm.
Second step, the preparation of antistaling agent finished product:
Calper calcium peroxide and white carbon black are added in hybrid particles, is uniformly mixed, obtains manufactured goods.
By taking 2 grams of net weight of finished product as an example, surveying total amount of carbon dioxide of inhaling is 550ml, and always putting oxygen amount is 275ml, and total moisture absorption is
50%.
Embodiment 4
The moist antistaling agent of control for having both absorbing carbon dioxide release oxygen, takes each raw material: peroxide by following weight percent
Change calcium 50%, montmorillonite powder 10%, white carbon black 15%, tapioca 10%, wood activated charcoal 15%.
Wherein, calper calcium peroxide purity is 50%~70%, and the partial size of montmorillonite powder is 80 mesh.
The preparation method is as follows:
Tapioca, wood activated charcoal, montmorillonite powder are put into sugar coating machine and are uniformly mixed by the first step, then will mixing
The water that 3:1 is added in object carries out being thoroughly mixed granulation；
By hybrid particles object, with 150 DEG C of progress, drying to constant weight, and moisture content is lower than 2%, obtains hybrid particles, mixing
The partial size of grain is in 0.5-1.0mm.
Second step, the preparation of antistaling agent finished product:
Calper calcium peroxide and white carbon black are added in hybrid particles, is uniformly mixed, obtains manufactured goods.
By taking 2 grams of net weight of finished product as an example, surveying total amount of carbon dioxide of inhaling is 650ml, and always putting oxygen amount is 325ml, and total moisture absorption is
35%.
Embodiment 5
The moist antistaling agent of control for having both absorbing carbon dioxide release oxygen, takes each raw material: peroxide by following weight percent
Change calcium 60%, montmorillonite powder 5%, white carbon black 20%, tapioca 7%, coaly activated carbon 8%.
Wherein, calper calcium peroxide purity is 50%~70%, and the partial size of montmorillonite powder is 80 mesh.
The preparation method is as follows:
Tapioca, coaly activated carbon, montmorillonite powder are put into sugar coating machine and are uniformly mixed by the first step, then will mixing
The water that 3:1 is added in object carries out being thoroughly mixed granulation；
By hybrid particles object, with 150 DEG C of progress, drying to constant weight, and moisture content is lower than 2%, obtains hybrid particles, mixing
The partial size of grain is in 0.5-1.0mm.
Second step, the preparation of antistaling agent finished product:
Calper calcium peroxide and white carbon black are added in hybrid particles, is uniformly mixed, obtains manufactured goods.
By taking 2 grams of net weight of finished product as an example, surveying total amount of carbon dioxide of inhaling is 560ml, and always putting oxygen amount is 280ml, and total moisture absorption is
20%.
Embodiment 6
The moist antistaling agent of control for having both absorbing carbon dioxide release oxygen, takes each raw material: peroxide by following weight percent
Change calcium 40%, montmorillonite powder 20%, white carbon black 10%, cornstarch 15%, regenerated carbon 15%.
Wherein, calper calcium peroxide purity is 50%~70%, and the partial size of montmorillonite powder is 80 mesh.
The preparation method is as follows:
Cornstarch, regenerated carbon, montmorillonite powder are put into sugar coating machine and are uniformly mixed by the first step, then will be in mixture
The water that 3.5:1 is added carries out being thoroughly mixed granulation；
By hybrid particles object, with 150 DEG C of progress, drying to constant weight, and moisture content is lower than 2%, obtains hybrid particles, mixing
The partial size of grain is in 0.5-1.0mm.
Second step, the preparation of antistaling agent finished product:
Calper calcium peroxide and white carbon black are added in hybrid particles, is uniformly mixed, obtains manufactured goods.
By taking 2 grams of net weight of finished product as an example, surveying total amount of carbon dioxide of inhaling is 495ml, and always putting oxygen amount is 247ml, and total moisture absorption is
30%.
Embodiment 7
The moist antistaling agent of control for having both absorbing carbon dioxide release oxygen, takes each raw material: peroxide by following weight percent
Change calcium 70%, montmorillonite powder 5%, white carbon black 5%, potato starch 10%, active fruit shell carbon 10%.
Wherein, calper calcium peroxide purity is 50%~70%, and the partial size of montmorillonite powder is 60 mesh.
The preparation method is as follows:
Potato starch, active fruit shell carbon, montmorillonite powder are put into sugar coating machine and are uniformly mixed, then will mix by the first step
The water for closing addition 2.5:1 in object carries out being thoroughly mixed granulation；
By hybrid particles object, with 150 DEG C of progress, drying to constant weight, and moisture content is lower than 2%, obtains hybrid particles, mixing
The partial size of grain is in 0.5-1.0mm.
Second step, the preparation of antistaling agent finished product:
Calper calcium peroxide and white carbon black are added in hybrid particles, is uniformly mixed, obtains manufactured goods.
By taking 2 grams of net weight of finished product as an example, surveying total amount of carbon dioxide of inhaling is 750ml, and always putting oxygen amount is 375ml, and total moisture absorption is
18%.
Embodiment 8
The moist antistaling agent of control for having both absorbing carbon dioxide release oxygen, takes each raw material: peroxide by following weight percent
Change calcium 70%, montmorillonite powder 5%, white carbon black 5%, industrial starch 5%, active fruit shell carbon 5%.
Wherein, calper calcium peroxide purity is 50%~70%, and the partial size of montmorillonite powder is 10 mesh.
The preparation method is as follows:
Industrial starch, active fruit shell carbon, montmorillonite powder are put into sugar coating machine and are uniformly mixed by the first step, then will mixing
The water that 3:1 is added in object carries out being thoroughly mixed granulation；
By hybrid particles object, with 150 DEG C of progress, drying to constant weight, and moisture content is lower than 2%, obtains hybrid particles, mixing
The partial size of grain is in 0.5-1.0mm.
Second step, the preparation of antistaling agent finished product:
Calper calcium peroxide and white carbon black are added in hybrid particles, is uniformly mixed, obtains manufactured goods.
By taking 2 grams of net weight of finished product as an example, surveying total amount of carbon dioxide of inhaling is 610ml, and always putting oxygen amount is 305ml, and total moisture absorption is
15%.
Comparative example 1
The moist antistaling agent of control for having both absorbing carbon dioxide release oxygen of this comparative example preparation, including it is calper calcium peroxide, white
Carbon black, cornstarch, active fruit shell carbon；
Each raw material: calper calcium peroxide 60%, white carbon black 25%, cornstarch 7%, shell activity is taken by following weight percent
Charcoal 8%.
The preparation method is as follows:
Cornstarch, active fruit shell carbon are put into sugar coating machine and are uniformly mixed, then 3 will be added in mixture by the first step:
1 water carries out being thoroughly mixed granulation, and by hybrid particles object, with 150 DEG C of progress, drying to constant weight, and hybrid particles are made.
Second step, the preparation of antistaling agent finished product: being added calper calcium peroxide, white carbon black in hybrid particles, is uniformly mixed, and obtains
Manufactured goods.
By taking 2 grams of net weight of manufactured goods as an example, surveying total amount of carbon dioxide of inhaling is 456ml, and always putting oxygen amount is 228ml, total moisture absorption
It is 10%.
Comparative example 2
The moist antistaling agent of control for having both absorbing carbon dioxide release oxygen of this comparative example preparation, including it is calper calcium peroxide, white
Carbon black, cornstarch, active fruit shell carbon；
Take each raw material by following weight percent: calper calcium peroxide 47%, white carbon black 35%, cornstarch 10%, shell are living
Property charcoal 8%.
The preparation method is as follows:
Cornstarch, active fruit shell carbon are put into sugar coating machine and are uniformly mixed, then 3 will be added in mixture by the first step:
1 water carries out being thoroughly mixed granulation, and by hybrid particles object, with 150 DEG C of progress, drying to constant weight, and hybrid particles are made.
Second step, the preparation of antistaling agent finished product: being added calper calcium peroxide, white carbon black in hybrid particles, is uniformly mixed, and obtains
Manufactured goods.
By taking 2 grams of net weight of manufactured goods as an example, surveying total amount of carbon dioxide of inhaling is 410ml, and always putting oxygen amount is 205ml, total moisture absorption
It is 12%.
Due to being not put into montmorillonite powder in this comparative example, manufactured goods are expanded during real reaction without substance
And it is loose, cause calper calcium peroxide and tainer air contact area small, leads to antistaling agent absorbing carbon dioxide amount and put oxygen amount not
Sufficiently, oxygen amount is always put to be decreased obviously with wettability power.
Although illustrate and describing the present invention with specific embodiment, it will be appreciated that without departing substantially from of the invention
Many other change and modification can be made in the case where spirit and scope.It is, therefore, intended that in the following claims
Including belonging to all such changes and modifications in the scope of the invention.
Claims (10)
1. a kind of antistaling agent, which is characterized in that be mainly made of following active principle, percentage, calper calcium peroxide
40%-80%, montmorillonite powder 5%-30%, white carbon black 5%-20%, starch 5%-15%, active carbon 5%-20%.
2. antistaling agent according to claim 1, which is characterized in that percentage, calper calcium peroxide 40%-70%,
Montmorillonite powder 5%-20%, white carbon black 5%-20%, starch 5%-15%, active carbon 5%-15%.
3. antistaling agent according to claim 1, which is characterized in that percentage, calper calcium peroxide 40%-55%,
Montmorillonite powder 5%-15%, white carbon black 5%-20%, starch 5%-10%, active carbon 8%-15%.
4. antistaling agent according to claim 1-3, which is characterized in that the starch is cornstarch, potato
At least one of starch, tapioca, industrial starch；Preferably cornstarch and/or potato starch.
5. antistaling agent according to claim 1-3, which is characterized in that the active carbon is wood activated charcoal, fruit
At least one of shell active carbon, coaly activated carbon, regenerated carbon；Preferably wood activated charcoal or active fruit shell carbon.
6. antistaling agent according to claim 1-3, which is characterized in that the calper calcium peroxide purity be 50%~
70%；
Further, the form of the calper calcium peroxide is powder or particle；
Further, the partial size of the montmorillonite powder is 10-100 mesh, -100 mesh of preferably 80 mesh.
7. the preparation method of antistaling agent described in any one of claims 1-6, which comprises the following steps:
Montmorillonite powder, active carbon, starch and water mixing granulation, obtain hybrid particles；
The hybrid particles be added calper calcium peroxide and white carbon black mixing to get.
8. the preparation method of antistaling agent according to claim 7, which is characterized in that the moisture content of the hybrid particles is low
In 2%；
Further, the partial size of the hybrid particles is in 0.5-1.0mm；
Further, the antistaling agent further includes outer packing；
Further, the outer packing includes satchel or box.
9. application of the antistaling agent described in any one of claims 1-6 in vegetable seeds is fresh-keeping.
10. application of the antistaling agent described in any one of claims 1-6 in eggs are fresh-keeping；
Further, the eggs include egg, duck's egg, goose egg, quail egg.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811057564.3A CN109007018A (en) | 2018-09-11 | 2018-09-11 | A kind of antistaling agent and its preparation method and application |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811057564.3A CN109007018A (en) | 2018-09-11 | 2018-09-11 | A kind of antistaling agent and its preparation method and application |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109007018A true CN109007018A (en) | 2018-12-18 |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112568279A (en) * | 2020-12-14 | 2021-03-30 | 寿县向天歌白鹅开发有限公司 | Preservative and preparation method thereof |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20020001548A1 (en) * | 1997-09-26 | 2002-01-03 | Kiyoshi Yoshida | Oxygen generating materials, carbon dioxide absorbing materials, and transport system and transport method of live fishery products |
| US20040087442A1 (en) * | 1992-01-30 | 2004-05-06 | Multisorb Technologies, Inc. | Composition for absorbing oxygen in an oxygen/carbon dioxide environment |
| CN101731322A (en) * | 2008-11-21 | 2010-06-16 | 吴定国 | Fruit and vegetable preservative and use method thereof |
| CN102132722A (en) * | 2010-01-21 | 2011-07-27 | 甘肃省农业科学院农产品贮藏加工研究所 | Fresh-keeping method for storing and transporting vegetables and fruits in airtight environment |
| CN104382185A (en) * | 2014-12-09 | 2015-03-04 | 广东广益科技实业有限公司 | Preparation method of deoxidization preservative agent |
| CN106861379A (en) * | 2017-04-11 | 2017-06-20 | 安徽博硕科技有限公司 | A kind of drier and preparation method thereof |
-
2018
- 2018-09-11 CN CN201811057564.3A patent/CN109007018A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20040087442A1 (en) * | 1992-01-30 | 2004-05-06 | Multisorb Technologies, Inc. | Composition for absorbing oxygen in an oxygen/carbon dioxide environment |
| US20020001548A1 (en) * | 1997-09-26 | 2002-01-03 | Kiyoshi Yoshida | Oxygen generating materials, carbon dioxide absorbing materials, and transport system and transport method of live fishery products |
| CN101731322A (en) * | 2008-11-21 | 2010-06-16 | 吴定国 | Fruit and vegetable preservative and use method thereof |
| CN102132722A (en) * | 2010-01-21 | 2011-07-27 | 甘肃省农业科学院农产品贮藏加工研究所 | Fresh-keeping method for storing and transporting vegetables and fruits in airtight environment |
| CN104382185A (en) * | 2014-12-09 | 2015-03-04 | 广东广益科技实业有限公司 | Preparation method of deoxidization preservative agent |
| CN106861379A (en) * | 2017-04-11 | 2017-06-20 | 安徽博硕科技有限公司 | A kind of drier and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 何国庆等主编: "《食品微生物学》", 30 September 2016, 北京：中国农业大学出版社 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112568279A (en) * | 2020-12-14 | 2021-03-30 | 寿县向天歌白鹅开发有限公司 | Preservative and preparation method thereof |
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