CN106628549B - Multifunctional carbon dioxide absorbs bag and its application - Google Patents
Multifunctional carbon dioxide absorbs bag and its application Download PDFInfo
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- CN106628549B CN106628549B CN201710154863.8A CN201710154863A CN106628549B CN 106628549 B CN106628549 B CN 106628549B CN 201710154863 A CN201710154863 A CN 201710154863A CN 106628549 B CN106628549 B CN 106628549B
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- bag
- carbon
- carbon dioxide
- dioxide
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D81/00—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents
- B65D81/24—Adaptations for preventing deterioration or decay of contents; Applications to the container or packaging material of food preservatives, fungicides, pesticides or animal repellants
- B65D81/26—Adaptations for preventing deterioration or decay of contents; Applications to the container or packaging material of food preservatives, fungicides, pesticides or animal repellants with provision for draining away, or absorbing, or removing by ventilation, fluids, e.g. exuded by contents; Applications of corrosion inhibitors or desiccators
- B65D81/266—Adaptations for preventing deterioration or decay of contents; Applications to the container or packaging material of food preservatives, fungicides, pesticides or animal repellants with provision for draining away, or absorbing, or removing by ventilation, fluids, e.g. exuded by contents; Applications of corrosion inhibitors or desiccators for absorbing gases, e.g. oxygen absorbers or desiccants
- B65D81/268—Adaptations for preventing deterioration or decay of contents; Applications to the container or packaging material of food preservatives, fungicides, pesticides or animal repellants with provision for draining away, or absorbing, or removing by ventilation, fluids, e.g. exuded by contents; Applications of corrosion inhibitors or desiccators for absorbing gases, e.g. oxygen absorbers or desiccants the absorber being enclosed in a small pack, e.g. bag, included in the package
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D85/00—Containers, packaging elements or packages, specially adapted for particular articles or materials
- B65D85/30—Containers, packaging elements or packages, specially adapted for particular articles or materials for articles particularly sensitive to damage by shock or pressure
- B65D85/34—Containers, packaging elements or packages, specially adapted for particular articles or materials for articles particularly sensitive to damage by shock or pressure for fruit, e.g. apples, oranges or tomatoes
- B65D85/345—Containers, packaging elements or packages, specially adapted for particular articles or materials for articles particularly sensitive to damage by shock or pressure for fruit, e.g. apples, oranges or tomatoes having a meshed or apertured closure to allow contents to breathe
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- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Food Science & Technology (AREA)
- Packages (AREA)
- Storage Of Fruits Or Vegetables (AREA)
Abstract
The present invention relates to Multifunctional carbon dioxides to absorb bag, it includes female bag that this Multifunctional carbon dioxide, which absorbs bag, female bag is made of the gas permeable material with micropore, female bag carbon-dioxide absorbent bag placed side by side and moisture absorption jizi for making dumplings bag, carbon-dioxide absorbent is the powdered granule object being made of sodium carbonate and calcium hydroxide, and calcium hydroxide and sodium carbonate are according to molar ratio 1:1 mixing;Hygroscopic agent is housed in moisture absorption jizi for making dumplings bag.Use, which is isolated, in SAP by the present invention with carbon-dioxide absorbent can significantly reduce the absorption efficiency of carbon dioxide, while absorb partial moisture, inhibit the growth of microorganism, be conducive to the extension of agricultural product or fermented food shelf life.
Description
One, technical field:
The present invention relates to the freshness protection packages that use in fresh agricultural product and fermented food packaging, and in particular to be more
Function absorption canisters and its application.
Two, background technology:
Fresh agricultural product can utilize low temperature and controlled atmospheric packing(The gaseous environment of surrounding changes, such as reduces oxygen concentration,
Improve gas concentration lwevel)Carry out fresh-keeping, Shelf-life.Since fresh agricultural product are fresh and alive products, there is normal breathing
The physiological activities such as metabolism, so the oxygen in packaging is gradually consumed by agricultural product, concentration reduces, and carbon dioxide is gradually by agricultural production
Product breathe out, and concentration improves.When especially temperature is high, respiratory intensity significantly increases, and packs interior gas concentration lwevel and often drastically rises
It is high.However, for the sensitive agricultural product in part(Such as banana, mushroom)For, high concentration carbon dioxide easy tos produce physiology wound
The defects of doing harm to, agricultural product made to generate discoloration, quality deterioration.In addition, for the traditional fermented foods such as pickles, due to lactic acid bacteria
Fermentation, produce and the process of circulation in will produce great amount of carbon dioxide, if not in time discharge packaging, can cause to wrap
Internal pressure is filled to increase(Hard packing)Or volume increases(Soft package), its packaging is made to face the risk of rise bag or even broken bag.
Therefore, high concentration carbon dioxide is just particularly important in removal packaging for this agricultural products.
Relative humidity in packaging has very important significance for fresh agricultural products fresh-keeping, and high humility is easy packing
Inside generates condensed water, and appearance is sold in influence, while high humility is also easy to that agricultural product is made to grow putrefactive microorganisms, shortens agricultural product
Shelf life.Therefore the moisture in control packaging, and then control the guarantor that the relative humidity in packaging is beneficial to packaging external appearance
Hold and control the growth and breeding of putrefactive microorganisms.
Three, invention content:
It is an object of the present invention to provide Multifunctional carbon dioxides to absorb bag, and this Multifunctional carbon dioxide absorbs bag and uses
The high concentration carbon dioxide in removal packaging during solving the problems, such as that the sensitive agricultural product in part preserve, of the invention another
Purpose is to provide the application that this Multifunctional carbon dioxide absorbs bag.
The technical solution adopted by the present invention to solve the technical problems is:It includes mother that this Multifunctional carbon dioxide, which absorbs bag,
Bag, female bag is made of the gas permeable material with micropore, female bag carbon-dioxide absorbent bag placed side by side and moisture absorption jizi for making dumplings bag, and two
It is the powdered granule object being made of sodium carbonate and calcium hydroxide to aoxidize absorbent carbon, and calcium hydroxide and sodium carbonate are according to molar ratio 1:
1 mixing;Hygroscopic agent is housed in moisture absorption jizi for making dumplings bag.
Hygroscopic agent is polyacrylate in said program, using Superabsorbent resin(SAP)Polyacrylate is as water suction
Agent absorbs vapor, while also there is the sodium carbonate as carbon-dioxide absorbent very strong water absorbing capacity, the two to make jointly
With, greatly improve the present invention moisture pick-up properties.
Further include alcohol antiseptic in carbon-dioxide absorbent bag in said program, alcohol antiseptic is mixed with absorbent
Together, the stacking thickness of carbon-dioxide absorbent and alcohol antiseptic is no more than 0.5cm in carbon-dioxide absorbent bag.Wine
Smart antiseptic packs after being mixed with carbon-dioxide absorbent, improves the anti-microbial property of the present invention, and due to carbonic acid in the present invention
Sodium and calcium hydroxide are the fine particle of powdery, so alcohol can be evaporated across particulate interspaces, it is anti-to have no effect on it
Bacterium efficiency.
Female bag defends strong or non-woven fabrics by spy and is made in said program.
Above-mentioned Multifunctional carbon dioxide absorbs bag and generates two for the water fruits and vegetables of high concentration carbon dioxide sensitivity, fermentation
The food of carbonoxide it is fresh-keeping.
The food that fermentation generates carbon dioxide in said program is pickles.
Advantageous effect:
1, SAP and carbon-dioxide absorbent are used in mixed way the absorption efficiency that can significantly reduce carbon dioxide by the present invention, therefore
Package construction uses divisional design, i.e., carbon-dioxide absorbent is isolated with SAP, in order to preferably play respective work(
Energy.
2, the present invention is used for the fresh agricultural product sensitive to high concentration carbon dioxide(Such as mushroom)And titanium dioxide can be generated
The fermented food of carbon(Such as Tian jin cabbage pickled in sweet and sour)Packaging reduces gas concentration lwevel in packaging, simultaneously using its carbon dioxide absorption characteristic
Partial moisture is absorbed, inhibits the growth of microorganism, is conducive to the extension of agricultural product or fermented food shelf life.
3, the present invention uses sodium carbonate cooperation calcium hydroxide, can both play the fast advantage of calcium hydroxide absorption rate,
Sodium carbonate can be played again absorbs thorough advantage;Sodium carbonate is the main component of edible soda ash, is put into conduct in vegetable and fruit packaging
Absorbent safety in utilization is good, and during absorbing CO2, sodium carbonate can absorb moisture simultaneously(Vapor), in addition to this, carbon
Sour sodium also has very strong deliquescent effect, that is, is easy to absorb the moisture in air, such double suction adduction is conducive to control packet
Relative humidity in dress.
Four, it illustrates:
Fig. 1 is the structural diagram of the present invention;
Fig. 2 is that 0.0042mol carbon dioxide receives the dioxy of the pouch and liner of agent under the conditions of 10 °C, relative humidity 100%
Change carbon absorption situation map, SC:Sodium carbonate CH:Calcium hydroxide SC/CH:The mixture of sodium carbonate and calcium hydroxide(Molar ratio 1:
1) Pad:It is immersed in the cotton lining pad dried after 40% sodium carbonate liquor of concentration(6 × 6 × 0.3cm).
In figure:1 female bag;2 carbon-dioxide absorbent bags;3 moisture absorption jizi for making dumplings bags.
Five, specific implementation mode:
Following further describes the present invention with reference to the drawings:
As shown in Figure 1, it includes female bag 1 that this Multifunctional carbon dioxide, which absorbs bag, female bag 1 is by the gas permeable material with micropore
It is made, carbon-dioxide absorbent bag 2 and moisture absorption jizi for making dumplings bag 3 placed side by side in female bag 1, carbon-dioxide absorbent is by sodium carbonate
The powdered granule object constituted with calcium hydroxide, calcium hydroxide and sodium carbonate are according to molar ratio 1:1 mixing;Moisture absorption jizi for making dumplings bag 3 is built-in
There is hygroscopic agent.Female bag 1 defends strong or non-woven fabrics by spy and is made, and the size of female bag 1 will match with the amount of absorbent, using saturating
The good spy of gas defends strong or non-woven fabrics as prebagged material, since there are many micropores for the material surface so that gas(Including
Carbon dioxide, oxygen, nitrogen and vapor)It can freely come in and go out.The length of carbon-dioxide absorbent bag 2 is 8.5cm, wide
Degree is 6cm, and moisture absorption jizi for making dumplings bag 3 may be designed in equal in magnitude with carbon-dioxide absorbent bag 2.
Hygroscopic agent is polyacrylate, using Superabsorbent resin(SAP)Polyacrylate absorbs water and steams as water absorbing agent
Gas, while also there is the sodium carbonate as carbon-dioxide absorbent very strong water absorbing capacity, the two collective effect to greatly improve this
The moisture pick-up properties of invention.
Further include alcohol antiseptic in carbon-dioxide absorbent bag 2 in the present invention, alcohol antiseptic is mixed with absorbent
Together, the stacking thickness of carbon-dioxide absorbent and alcohol antiseptic is no more than 0.5cm in carbon-dioxide absorbent bag 2,
In order to avoid influencing absorption and antibacterial effect.Alcohol antiseptic packs after being mixed with carbon-dioxide absorbent, improves the anti-of the present invention
Bacterium performance, and due in the present invention sodium carbonate and calcium hydroxide be the fine particle of powdery, so alcohol can pass through particle
Gap evaporates, and has no effect on its antibacterial efficacy.
Research finds the rate of calcium hydroxide absorbing carbon dioxide quickly, under the conditions of 10 °C, relative humidity 100%, dioxy
Changing concentration of carbon reduces by 40% in 30 minutes, finds carbon dioxide and calcium hydroxide reaction by the reaction equation of the two and is not required to
Water is wanted, on the contrary, water is reaction product.With the progress of reaction process, the concentration of reaction product --- water improves, reaction rate drop
It is low until be zero.Meanwhile research finds that the reaction can not carry through to the end completely(See Fig. 2).There are about 55% carbon dioxide not to have
It is sponged by the calcium hydroxide of equivalent molar number.Thus, it can be concluded that under 100% relative humidities, Strong oxdiative calcium utilizes effect
Rate is not high.Research finds that sodium carbonate being capable of absorbing carbon dioxide, sodium carbonate and carbon dioxide under 100% relative humidities
Reaction almost may proceed to bottom under 100% relative humidities, but reaction rate is so fast not as good as Strong oxdiative calcium(See
Fig. 2).The absorption rate and absorption efficiency of carbon dioxide in order to balance, by calcium hydroxide and sodium carbonate according to 1:1(Molar ratio)It is mixed
It closes and uses, reaction product in the reaction of calcium hydroxide absorbing carbon dioxide --- water can be used as sodium carbonate and carbon dioxide anti-
At once another the reactant needed continues to be utilized, and reacts flat in the reaction to improve calcium hydroxide absorbing carbon dioxide
Weigh coefficient, that is, improves the efficiency of calcium hydroxide absorbing carbon dioxide.
The present invention is suitable for the fruits and vegetables for high concentration carbon dioxide sensitivity, and fermentation generates carbon dioxide
Food such as pickles etc.;The present invention is only used for the occasion of vapor generation, is not suitable for dried foods.
The fresh-keeping verification experimental verification of the present invention:
One, gas concentration changes:
180g mushrooms are packed with punching polyacrylic film bag, the present invention is equally placed in bag as adjunct, it is secret
It is close to carry out fresh-keeping verification experimental verification, 5 days under the conditions of being placed on 10 °C.Carbon dioxide and oxygen concentration situation of change in packaging bag
Figure shows that gas concentration lwevel increase quickly, reaches 15% in 2 days, can be endured considerably beyond mushroom in blank group packaging bag
The upper limit.On the contrary, the gas concentration lwevel rising in processing group packaging bag is slower, can control within 7% substantially.This illustrates this
Invention is selected or the carbon-dioxide absorbent of compounding can actually absorbing carbon dioxide, it is dense effectively to control carbon dioxide in bag
Degree.
Two, moisture changes:
Dehydration situation and carbon-dioxide absorbent, the moisture absorption situation of super water absorbent resin of the mushroom in storage,
It is apparently higher than blank group for the mushroom percentage of water loss of processing group.There is the moisture of 59-71% by titanium dioxide in the moisture that mushroom loses
Absorbent carbon or super water absorbent resin absorb.This explanation remains in the moisture of package interior or is attached to polybag inner surface
Condensed water is less, is conducive to the appearance of polybag and inhibits the growth of microorganism.On the contrary, condensed water is very in blank group polybag
More, many condensed waters drip to mushroom surface again(Make the reduction of its weight-loss ratio to a certain extent)So that its surface is shaded, and is lost
Commodity value.
Three, other quality index change
After being stored 5 days at 10 °C, different disposal group mushroom quality index(Weight-loss ratio, colour brightness, case hardness, smell,
Sense organ acceptance level, total plate count)Comparative situation be shown in Table 1.It can be clearly seen that from table 1, in addition to weight-loss ratio, blank group
Mushroom is below processing group, particularly less than processing group SC and SC/CH in other quality index.The mushroom surface color ratio of blank group
Other groups are deeper darker, and appearance is poor compared with other groups, and there is apparent water logging trace on surface.This illustrates the titanium dioxide made by the present invention
Carbon absorption bag has fairly good fresh-keeping effect for the mushroom of carbon dioxide sensitivity.
Quality index after 1 mushroom of table is stored 5 days at 10 °C compares *
Weight-loss ratio (%) | Colour brightness | Case hardness (N) | Smell | Overall organoleptic's acceptance | Total bacteria count (log CFU/g) | |
SC/SAP | 8.90±0.44c | 48.25±5.02b | 3.99±0.97b | 6.3±2.0c | 6.6±1.9c | 1.59±0.11a |
CH/SAP | 7.02±0.72b | 44.38±5.56ab | 3.77±1.36b | 5.7±1.0bc | 5.7±1.7bc | 2.49±0.01b |
(SC/CH)/SAP | 6.86±0.58b | 46.68±4.51ab | 3.53±1.27ab | 6.3±1.0c | 6.8±1.2c | 2.57±0.06bc |
Pad | 5.59±0.79b | 46.90±4.71ab | 3.41±1.35ab | 4.3±1.7b | 4.6±2.2b | 2.33±0.26b |
Control | 3.00±0.41a | 42.79±4.19a | 2.57±1.05a | 1.7±1.0a | 1.7±1.0a | 2.68±0.07c |
* letter different behind same row numerical value represent significant difference (p<0.05)。
SC/SAP:Additional absorption canisters in packaging(8g sodium carbonate, 10g super water absorbent resins);
CH/SAP:Additional absorption canisters in packaging(10g calcium hydroxides, 18g super water absorbent resins);
(SC/CH)/SAP:Additional absorption canisters in packaging(3.53g sodium carbonate, 2.47g calcium hydroxides and 13g are super
Water-absorbing resins);
Pad:It is immersed in the cotton lining pad dried after a concentration of 40% sodium carbonate liquor(108cm2);
Control:Blank.
Claims (7)
1. a kind of Multifunctional carbon dioxide absorbs bag, it is characterised in that:It includes female bag that this Multifunctional carbon dioxide, which absorbs bag,
(1), female bag(1)It is made of the gas permeable material with micropore, female bag(1)Interior carbon-dioxide absorbent bag placed side by side(2)With
Moisture absorption jizi for making dumplings bag(3), carbon-dioxide absorbent is the powdered granule object being made of sodium carbonate and calcium hydroxide, calcium hydroxide and carbon
Sour sodium is according to molar ratio 1:1 mixing;Hygroscopic agent is housed in moisture absorption jizi for making dumplings bag.
2. Multifunctional carbon dioxide according to claim 1 absorbs bag, it is characterised in that:The hygroscopic agent is polypropylene
Acid esters.
3. Multifunctional carbon dioxide according to claim 2 absorbs bag, it is characterised in that:The carbon-dioxide absorbent
Sub- bag(2)Further include inside alcohol antiseptic, alcohol antiseptic is mixed with absorbent, carbon-dioxide absorbent bag(2)
The stacking thickness of interior carbon-dioxide absorbent and alcohol antiseptic is no more than 0.5cm.
4. Multifunctional carbon dioxide according to claim 3 absorbs bag, it is characterised in that:Female bag(1)It is defended by spy
Strong or non-woven fabrics is made.
5. the Multifunctional carbon dioxide described in a kind of claim 4 absorbs the application of bag, it is characterised in that:Described multi-functional two
Oxidation carbon absorption bag is used for the fresh-keeping of the water fruits and vegetables of high concentration carbon dioxide sensitivity.
6. the Multifunctional carbon dioxide described in a kind of claim 4 absorbs the application of bag, it is characterised in that:Described multi-functional two
Oxidation carbon absorption bag be used for ferment generation carbon dioxide food it is fresh-keeping.
7. Multifunctional carbon dioxide according to claim 6 absorbs the application of bag, it is characterised in that:The fermentation generates
The food of carbon dioxide is pickles.
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CN109927968A (en) * | 2019-03-12 | 2019-06-25 | 福建省亚热带植物研究所 | A kind of packing method of flatulence remover and agricultural product |
CN110124481B (en) * | 2019-05-13 | 2023-10-27 | 江苏欧凯包装科技有限公司 | Active packaging material capable of absorbing oxygen and carbon dioxide simultaneously |
CN110179078B (en) * | 2019-05-17 | 2023-01-03 | 成都新繁食品有限公司 | Method for producing and processing fermentation-free salted packaged fresh capsicum frutescens |
CN113501207A (en) * | 2021-07-20 | 2021-10-15 | 黑龙江八一农垦大学 | Antibacterial water-absorbing liner for keeping fresh of tray-packed cold fresh meat and preparation method thereof |
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CN1212829A (en) * | 1997-09-26 | 1999-04-07 | 三菱瓦斯化学株式会社 | Oxidizing producing agent, carbon dioxide absorbent, transport system for live fish and shellfish and its transport method |
CN101715809A (en) * | 2009-12-14 | 2010-06-02 | 大连市金州区金科科技培训服务中心 | Special preservative for processing peach and preparation method thereof |
CN101731322A (en) * | 2008-11-21 | 2010-06-16 | 吴定国 | Fruit and vegetable preservative and use method thereof |
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CN104093475A (en) * | 2012-01-23 | 2014-10-08 | 赢创工业集团股份有限公司 | Method and absorption medium for absorbing CO2 from a gas mixture |
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JPH06100045A (en) * | 1992-09-08 | 1994-04-12 | Dainippon Printing Co Ltd | Cut vegetable packaging bag |
KR20020019187A (en) * | 2000-09-05 | 2002-03-12 | 최홍식 | Carbon Dioxide Absorber Which Comprises Sodium Carbonate as an Active Ingredient for Controlling Carbon Dioxide Absorption Speed |
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Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
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CN1212829A (en) * | 1997-09-26 | 1999-04-07 | 三菱瓦斯化学株式会社 | Oxidizing producing agent, carbon dioxide absorbent, transport system for live fish and shellfish and its transport method |
CN101731322A (en) * | 2008-11-21 | 2010-06-16 | 吴定国 | Fruit and vegetable preservative and use method thereof |
CN101715809A (en) * | 2009-12-14 | 2010-06-02 | 大连市金州区金科科技培训服务中心 | Special preservative for processing peach and preparation method thereof |
CN102369986A (en) * | 2010-08-26 | 2012-03-14 | 应关雄 | Combined air regulation fresh keeping agent |
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