CN107027811A - A kind of composition pesticide and its medicament-fertilizer mixture containing the composition pesticide - Google Patents
A kind of composition pesticide and its medicament-fertilizer mixture containing the composition pesticide Download PDFInfo
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- CN107027811A CN107027811A CN201610945907.4A CN201610945907A CN107027811A CN 107027811 A CN107027811 A CN 107027811A CN 201610945907 A CN201610945907 A CN 201610945907A CN 107027811 A CN107027811 A CN 107027811A
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N63/00—Biocides, pest repellants or attractants, or plant growth regulators containing microorganisms, viruses, microbial fungi, animals or substances produced by, or obtained from, microorganisms, viruses, microbial fungi or animals, e.g. enzymes or fermentates
- A01N63/30—Microbial fungi; Substances produced thereby or obtained therefrom
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N51/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds having the sequences of atoms O—N—S, X—O—S, N—N—S, O—N—N or O-halogen, regardless of the number of bonds each atom has and with no atom of these sequences forming part of a heterocyclic ring
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05B—PHOSPHATIC FERTILISERS
- C05B7/00—Fertilisers based essentially on alkali or ammonium orthophosphates
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
- C05G3/60—Biocides or preservatives, e.g. disinfectants, pesticides or herbicides; Pest repellants or attractants
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- Life Sciences & Earth Sciences (AREA)
- Pest Control & Pesticides (AREA)
- General Health & Medical Sciences (AREA)
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- Biotechnology (AREA)
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Abstract
The invention belongs to Pesticide formulation technical field, and in particular to be a kind of composition pesticide and its medicament-fertilizer mixture containing the composition pesticide.A kind of composition pesticide, characterized in that, the composition pesticide includes effective constituents A and active ingredient B, effective constituents A is green muscardine fungus, active ingredient B is Diacloden, clothianidin or MTI-446, and described two effective ingredient A and B composition mass ratioes are 1: 50 50: 1.The various pests that the composition pesticide of the present invention and its medicament-fertilizer mixture containing the composition pesticide can be used on the fruit trees such as preventing and treating paddy rice, sugarcane, vegetables, banana.
Description
Technical field
The invention belongs to Pesticide formulation technical field, and in particular to be a kind of composition pesticide and its containing the agriculture
The medicament-fertilizer mixture of drug composition.
Background technology
Medicine fertilizer is to be formulated agricultural chemicals and fertilizer according to a certain percentage to mix, and by certain technology by fertilizer and
Agricultural chemicals is stable at novel ecological compound fertilizer formed by specific compound system, typically with the carrier of fertilizer used as pesticides.For
The sustainable development of Modern Agricultural, medicine fertilizer for the modern agriculture that is supported and drive with powerful technology be it is a kind of newly
Attempt.Medicine fertilizer can make two operating procedures in field unite two into one, and this not only saves labour, and reduces time and energy
The consumption in source.
According to incompletely statistics, by the end of the end of the year in 2012, the fertile compounded product of medicine more than 10 is registered altogether by China.But from 2013
Year so far, is almost registered without the fertile compounded product of new medicine again.
It is to develop pesticide new product at present and prevent and treat resistance disease that the pesticide active ingredient of the different mechanisms of action is carried out into compounding
A kind of effective quick way of insect pest.After different pesticide active ingredients are compounded, three kinds of type of action can be shown：It is added
Effect, synergistic effect and antagonism.Generally, only it can just be learnt after different pesticide active ingredient compoundings by substantial amounts of experiment
Type of action.The Recompounded pesticide of screening tool synergistic effect, can significantly improve prevention effect, reduce Pesticide use amount, reduction
Cost accounting, can also expand preventing and treating spectrum, delay the generation of pest and disease damage resistance, be the important means of current integrated pest prevention and control
One of.
Inventor is tested and field control effectiveness test by a large amount of indoor biometricses, filters out the pesticide synergistic group containing green muscardine fungus
Close, and be applied in pesticide-fertilizer product processing, obtain the medicament-fertilizer mixture containing green muscardine fungus, available for preventing and treating paddy rice, sugarcane, vegetable
Various pests on fruit trees such as dish, banana etc..
The content of the invention
It is an object of the invention to provide a kind of composition pesticide containing green muscardine fungus and its contain the composition pesticide
Medicament-fertilizer mixture, available for the various pests on preventing and treating paddy rice, sugarcane, vegetables, fruit tree etc., and can promote crop to increase.
The present invention realizes that the technical scheme that above-mentioned purpose is used is：
A kind of composition pesticide, it is characterised in that the composition pesticide includes effective constituents A and active ingredient B, effectively
Composition A is green muscardine fungus, and active ingredient B is Diacloden, clothianidin or MTI-446, and described two effective ingredient A and B constitute mass ratio
For 1: 50-50: 1.
A kind of medicament-fertilizer mixture, it is characterised in that it is made up of the component of following weight percentage：Pesticide active ingredient
0.05-50%, macroelement fertilizer 15-50%, trace-element fertilizer 1-15%, auxiliary agent 3-15%, surfactant 3-15%,
Adsorbent 0.5-2%, carrier supplies 100%, and the pesticide active ingredient includes effective constituents A and active ingredient B, active ingredient
A is green muscardine fungus, and active ingredient B is Diacloden, clothianidin or MTI-446, and described two effective ingredient A and B composition mass ratioes are 1:
50-50∶1。
Preferably, the macroelement fertilizer be ammonium sulfate, ammonium chloride, ammonium dihydrogen phosphate, urea, potassium dihydrogen phosphate,
At least one of potassium hydrogen phosphate, potassium chloride, potassium sulfate, potassium nitrate or potassium citrate；The trace-element fertilizer be sodium molybdate,
Ammonium molybdate tetrahydrate, zinc sulfate, manganese sulfate, copper sulphate, ferrous sulfate, boric acid, the Boratex of four water eight, ethylenediamine tetra-acetic acid zinc sodium,
At least one of calcium disodium edathamil, ethylenediamine tetra-acetic acid manganese disodium or cupric ethylene diamine tetraacetate sodium.
Preferably, the auxiliary agent is lauryl sodium sulfate, calcium lignosulfonate, sodium lignin sulfonate or dibutyl naphthalene sulphur
At least one of sour sodium；Described surfactant is AEO, APES or naphthalene sulfonic acids
At least one of salt formaldehyde condensation products；Adsorbent is white carbon.
Preferably, the carrier is at least one of kaolin, diatomite, nacrite or humic acid.
Preferably, the formulation of the insecticide fertilizer containing green muscardine fungus is granule or pulvis.
Preferably, the insecticide fertilizer containing green muscardine fungus is used to prevent and treat the fruit trees such as paddy rice, sugarcane, vegetables, banana
Various pests.
Preferably, the insecticide fertilizer containing green muscardine fungus can be used for preventing and treating banana root-knot nematode.
Compared with prior art, the beneficial effects of the invention are as follows：
1. the composition pesticide and its medicament-fertilizer mixture of the present invention are to utilize effective constituents A and two kinds of activearms of active ingredient B
Part mixture, with obvious synergistic effect, can reduce effective ingredient consumption, the production saved cost accounting, delay pest resistance to insecticide
It is raw.
2. the composition pesticide of the invention and its medicament-fertilizer mixture of the present invention can be used for preventing and treating paddy rice, sugarcane, vegetables, banana
It is especially excellent to banana root-knot nematode prevention effect Deng the various pests of fruit tree, and the invention has promotion to give birth to various crop
Long effect, and the product preparation process of the present invention is simple, condition is easily-controllable, suitable for industrialized production.
Embodiment
In order to make the purpose , technical scheme and advantage of the present invention be clearer, with reference to embodiments, to the present invention
It is further elaborated.
First, indoor joint toxicity measuring test
Green muscardine fungus and the co-toxicity of Diacloden, clothianidin or MTI-446 are tested
1.1 reagent agent
Green muscardine fungus active compound (10,000,000,000 living spores/gram), 95% Diacloden active compound, 95% clothianidin active compound, 95% MTI-446 are former
Medicine；Green muscardine fungus and Diacloden different proportion mixture preparation；Green muscardine fungus and clothianidin different proportion mixture preparation；Green muscardine fungus and furan worm
Amine different proportion mixture preparation.
1.2 selected insect source
Cabbage aphid, sugarcane aphid, brown paddy plant hopper
1.3 single dose assay methods
4 active compounds are all used by a small amount of acetone solution using dip method, then with 0.1% tween water capacity easily dilutable into equal difference
The solution of 5 concentration, is diluted in beaker with standby, and be used as control using clear water.By three generations's cabbage aphid of the same size, sweet
Sugarcane aphid and brown paddy plant hopper adult impregnate 5s in the decoction of leaching worm cage, suck the culture dish that 9cm is placed on after unnecessary decoction
In, fresh cabbage leaves covering is placed with ware.10 are handled per concentration, is repeated 4 times, if blank control.In 27 degree of illumination cultivations
The death rate is checked after keeping 24h in case, it is dead that polypide nonresponder is touched with pulling needle.The death rate is corrected with Abbott for examination,
Further according to log concentration-death rate niqueMin analytic approach, virulence regression equation is obtained and lethal.
The joint toxicity measuring method of 1.4 different ratios
The toxicity test result of foundation single dose, compares green muscardine fungus by active ingredient quality：Clothianidin/MTI-446 is respectively 50:
1、40:1、30:1、20:1、10:1、1:1、1:10、1:20、1:30、1:40、1:50 proportioning carries out mixture.Using above-mentioned 1.3
Method carries out independent measure, calculates LC50, and calculate co-toxicity coefficient (CTC) by the abundant methods of Sun Yun.Co-toxicity coefficient calculation formula is as follows：
In formula：ATI --- mixture surveys toxicity index；
S --- the LC of standard pesticide agent50, unit is milligrams per liter (mg/L)；
The LC of M --- mixture50, unit is milligrams per liter (mg/L).
Mixture theoretical toxicity index is calculated according to following equation
TTI=TIA×PA+TIB×PB……………………………………(2)
In formula：TTI --- mixture theoretical toxicity index；
TIA--- A medicament toxicity index；
PA--- percentage composition of the A medicaments in mixture, unit is percentage (%)；
TIB--- B medicament toxicity index；
PB--- percentage composition of the B medicaments in mixture, unit is percentage (%).
The co-toxicity coefficient of mixture is calculated according to following equation
In formula：CTC --- co-toxicity coefficient；
ATI --- mixture surveys toxicity index；
TTI --- mixture theoretical toxicity index.
The co-toxicity coefficient (CTC) >=120 of built agent shows as synergistic effect；CTC≤80 show as antagonism；80 ＜
CTC ＜ 120 show as summation action.
2 toxicity test results (referring to table 1-2)
The indoor joint toxicity measuring of the green muscardine fungus of table 1 and Diacloden to cabbage aphid
The indoor joint toxicity measuring of the green muscardine fungus of table 2 and clothianidin to cabbage aphid
The indoor joint toxicity measuring of the green muscardine fungus of table 3 and MTI-446 to sugarcane aphid
1 after being compounded between green muscardine fungus it can be seen from table 1-3 and Diacloden, three compositions of clothianidin or MTI-446:
50-50:Its lower co-toxicity coefficient of 1 proportioning is all higher than 120, illustrates that green muscardine fungus is answered with Diacloden, two kinds of compositions of clothianidin or MTI-446
With with obvious synergistic effect.
2nd, insecticide fertilizer prepares embodiment
Embodiment l：0.2% green muscardine fungus clothianidin granular pesticide fertilizer, its formula is as follows：
Its preparation method is：First by green muscardine fungus, clothianidin active compound and auxiliary agent lauryl sodium sulfate and surfactant
AEO is sufficiently mixed the female powder that stirs to obtain, by obtained female powder and ammonium sulfate, potassium dihydrogen phosphate, four water eight
Boratex, ethylenediamine tetra-acetic acid zinc sodium, ammonium molybdate tetrahydrate, white carbon and kaolin carry out granulation in fluidized bed prilling mode and produced
To 0.2% green muscardine fungus clothianidin granular pesticide fertilizer.
Embodiment 2：5.5% green muscardine fungus dinotefuran granules medicine fertilizer, its formula is as follows：
Its preparation method is：First by green muscardine fungus, MTI-446 active compound and auxiliary agent sodium lignin sulfonate and surfactant alkane
Base phenol polyethenoxy ether is sufficiently mixed the female powder that stirs to obtain, by obtained female powder and ammonium dihydrogen phosphate, potassium nitrate, boric acid, second
Ethylenediamine tetraacetic acid (EDTA) manganese disodium, sodium molybdate, calcium disodium edathamil, white carbon and diatomite are carried out in fluidized bed prilling mode
Granulation obtains 5.5% green muscardine fungus dinotefuran granules medicine fertilizer.
Embodiment 3：35% green muscardine fungus clothianidin granular pesticide fertilizer, its formula is as follows：
Its preparation method is：First by green muscardine fungus, clothianidin active compound, auxiliary agent calcium lignosulfonate and face activating agent alkyl phenol
APEO, which is sufficiently mixed, stirs into female powder, by obtained female powder and macroelement fertilizer, trace-element fertilizer, white carbon and
Diatomite is granulated in fluidized bed prilling mode obtains 35% green muscardine fungus clothianidin granular pesticide fertilizer.
Embodiment 4：20% green muscardine fungus clothianidin granular pesticide fertilizer, its formula is as follows：
Its preparation method is：First by green muscardine fungus, clothianidin active compound, auxiliary agent calcium lignosulfonate and face activating agent naphthalene sulfonic acids
Salt formaldehyde condensation products, which are sufficiently mixed, stirs into female powder, by obtained female powder and macroelement fertilizer, trace-element fertilizer, hard charcoal
Black, diatomite is granulated in fluidized bed prilling mode obtains 20% green muscardine fungus clothianidin granular pesticide fertilizer.
Embodiment 5：30% green muscardine fungus MTI-446 powder-type medicine fertilizer, its formula is as follows：
Its preparation method is：First use green muscardine fungus, MTI-446 active compound, auxiliary agent lauryl sodium sulfate and face activating agent alkyl
Phenol polyethenoxy ether is sufficiently mixed the female powder that stirs to obtain, by obtained female powder and macroelement fertilizer, trace-element fertilizer and
Carrier carries out combination drying and crushed to obtain 30% green muscardine fungus MTI-446 powder medicine fertilizer.
Embodiment 6：1% green muscardine fungus clothianidin powder medicine fertilizer, its formula is as follows：
Its preparation method is：First by green muscardine fungus, clothianidin active compound, auxiliary agent sodium butylnaphthalenesulfonate and surfactant alkyl phenol
APEO is sufficiently mixed stirring and obtains female powder, by obtained female powder and macroelement fertilizer, trace-element fertilizer, carrier
Carry out combination drying and crush to obtain 1% green muscardine fungus clothianidin powder medicine fertilizer.
Embodiment 7：10.1% green muscardine fungus MTI-446 powder medicine fertilizer, its formula is as follows：
Its preparation method is：Green muscardine fungus, MTI-446 active compound, auxiliary agent and surfactant are first sufficiently mixed stirring by formula
Female powder is obtained, obtained female powder and macroelement fertilizer, trace-element fertilizer, carrier are carried out combination drying and crushed to produce
To 10.1% green muscardine fungus MTI-446 powder medicine fertilizer.
Embodiment 8：50% green muscardine fungus MTI-446 powder medicine fertilizer, its formula is as follows：
Its preparation method is：By formula first by green muscardine fungus, MTI-446 active compound, auxiliary agent lauryl sodium sulfate and surface-active
Agent AEO is sufficiently mixed stirring and obtains female powder, by obtained female powder and macroelement fertilizer, trace element
Fertilizer, carrier carry out combination drying and crushed to obtain 50% green muscardine fungus MTI-446 powder medicine fertilizer.
3rd, Field information embodiment
Application Example l：
Embodiment 1-3 products obtained therefroms are subjected to cabbage aphid preventing and treating and simulation experiments, following processing is set：
Processing 1：0.2% green muscardine fungus clothianidin granular pesticide fertilizer mu uses 50kg；
Processing 2：The granular pesticide fertilizer mu of 5.5% green muscardine fungus MTI-446 uses 10kg；
Processing 3：35% green muscardine fungus clothianidin granular pesticide fertilizer mu uses 2kg；
Processing 4：5.5% green muscardine fungus MTI-446 (0.5:5) granular pesticide fertilizer mu uses 5kg；
Processing 5：By ammonium dihydrogen phosphate 35%, potassium nitrate 15%, boric acid 5%, ethylenediamine tetra-acetic acid manganese disodium 3%, molybdic acid
The fertilizer mu that sodium 1% and calcium disodium edathamil 5% are constituted uses 12kg；
Processing 6：Blank control.
Above-mentioned processing is prevented and treated in the vegetable field for occurring cabbage aphid, prevention effect such as following table：
According to result of the test, embodiment 1-3 products obtained therefroms are in the prevention effect to cabbage aphid better than prepared by processing 4
Medicament, production-increasing function be far superior to processing 4 and processing 5.
Application Example 2：
Embodiment 4-6 products obtained therefroms are subjected to sugarcane control of aphids and simulation experiments, following processing is set：
Processing 7：20% green muscardine fungus clothianidin granular pesticide fertilizer mu uses 10kg；
Processing 8：30% green muscardine fungus MTI-446 powder medicine fertilizer mu 5kg；
Processing 9：1% green muscardine fungus clothianidin powder medicine fertilizer mu 50kg；
Processing 10：30% green muscardine fungus MTI-446 powder medicine fertilizer (20:10) mu 5kg；
Processing 11：By ammonium dihydrogen phosphate 20%, potassium nitrate 15%, boric acid 0.5%, ethylenediamine tetra-acetic acid manganese disodium, 0.5%
The fertilizer mu that sodium molybdate 0.5%, calcium disodium edathamil 0.5% are constituted uses 20kg；
Processing 12：Blank control.
Above-mentioned handle is subjected to dispenser in the sugarcane field for having sugarcane aphid, prevention effect is as shown in the table：
According to result of the test, embodiment 4-6 products obtained therefroms are made better than processing 10 on the prevention effect to sugarcane aphid
Standby medicament, production-increasing function is far superior to processing 10 and processing 11.
Application Example 3：
Embodiment 7-8 products obtained therefroms are subjected to Brown Planthopper preventing and treating and simulation experiments, following processing is set：
Processing 13：10.1% green muscardine fungus MTI-446 powder medicine fertilizer mu 50kg；
Processing 14：50% green muscardine fungus MTI-446 powder medicine fertilizer mu 50kg；
Processing 15：10.1% green muscardine fungus MTI-446 powder medicine fertilizer (0.1:10) mu 5kg；
Processing 16：By ammonium dihydrogen phosphate 20%, potassium nitrate 15%, boric acid 0.5%, ethylenediamine tetra-acetic acid manganese disodium, 0.5%
The fertilizer mu that sodium molybdate 0.5%, calcium disodium edathamil 0.5% are constituted uses 60kg；
Processing 17：Blank control.
Above-mentioned handle is subjected to dispenser in the rice terrace for having Brown Planthopper, prevention effect is as shown in the table：
According to result of the test, embodiment 7-8 products obtained therefroms are in the prevention effect to Brown Planthopper better than 15 institutes of processing
The medicament of preparation, production-increasing function is far superior to processing 15 and processing 16.
It is foregoing to the present invention specific illustrative embodiment description be in order to illustrate and illustration purpose.These descriptions
It is not wishing to limit the invention to disclosed precise forms, and it will be apparent that according to above-mentioned teaching, can be much changed
And change.The purpose of selecting and describing the exemplary embodiment is that explaining that the certain principles and its reality of the present invention should
With so that those skilled in the art can realize and using the present invention a variety of exemplaries and
A variety of selections and change.The scope of the present invention is intended to be limited by claims and its equivalents.
Claims (6)
1. a kind of composition pesticide, it is characterised in that the composition pesticide includes effective constituents A and active ingredient B, effectively into
It is green muscardine fungus to divide A, and active ingredient B is Diacloden, clothianidin or MTI-446, and described two effective ingredient A and B composition mass ratioes are
1∶50-50∶1。
2. a kind of medicament-fertilizer mixture, it is characterised in that it is made up of the component of following weight percentage：Pesticide active ingredient
0.05-50%, macroelement fertilizer 15-50%, trace-element fertilizer 1-15%, auxiliary agent 3-15%, surfactant 3-15%,
Adsorbent 0.5-2%, carrier supplies 100%, and the pesticide active ingredient includes effective constituents A and active ingredient B, active ingredient
A is green muscardine fungus, and active ingredient B is Diacloden, clothianidin or MTI-446, and described two effective ingredient A and B composition mass ratioes are 1:
50-50∶1。
3. medicament-fertilizer mixture according to claim 2, it is characterised in that the macroelement fertilizer is ammonium sulfate, ammonium chloride, phosphoric acid
At least one of ammonium dihydrogen, urea, potassium dihydrogen phosphate, potassium hydrogen phosphate, potassium chloride, potassium sulfate, potassium nitrate or potassium citrate；Institute
Trace-element fertilizer is stated for sodium molybdate, ammonium molybdate tetrahydrate, zinc sulfate, manganese sulfate, copper sulphate, ferrous sulfate, boric acid, the boron of four water eight
Sour sodium, ethylenediamine tetra-acetic acid zinc sodium, calcium disodium edathamil, ethylenediamine tetra-acetic acid manganese disodium or cupric ethylene diamine tetraacetate sodium
At least one of.
4. medicament-fertilizer mixture according to claim 2, it is characterised in that described auxiliary agent is lauryl sodium sulfate, sulfomethylated lignin
At least one of sour calcium, sodium lignin sulfonate or sodium butylnaphthalenesulfonate；Described surfactant is aliphatic alcohol polyethenoxy
At least one of ether, APES or naphthalenesulfonate formaldehyde condensation compound；The adsorbent is white carbon.
5. medicament-fertilizer mixture according to claim 2, it is characterised in that described carrier be kaolin, diatomite, nacrite or
At least one of humic acid.
6. medicament-fertilizer mixture according to claim 2, it is characterised in that the formulation of described medicament-fertilizer mixture is granule or powder
Agent.
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| CN110934148A (en) * | 2019-11-25 | 2020-03-31 | 华南农业大学 | Compound pesticide of metarhizium anisopliae mutant strain MaUV-1 and thiamethoxam and application thereof |
| CN112425609A (en) * | 2020-12-18 | 2021-03-02 | 重庆谷百奥生物研究院有限公司 | Metarhizium anisopliae preparation for promoting growth of banana plants and preventing and treating banana wilt |
| CN114831123A (en) * | 2022-06-08 | 2022-08-02 | 安徽丰乐农化有限责任公司 | Pesticide fertilizer composition and application thereof |
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Application publication date: 20170811 |