CN106785116B - Lead-acid battery repair active agent without need of supplementing electrolyte and preparation method thereof - Google Patents
Lead-acid battery repair active agent without need of supplementing electrolyte and preparation method thereof Download PDFInfo
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- CN106785116B CN106785116B CN201611205731.5A CN201611205731A CN106785116B CN 106785116 B CN106785116 B CN 106785116B CN 201611205731 A CN201611205731 A CN 201611205731A CN 106785116 B CN106785116 B CN 106785116B
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/42—Methods or arrangements for servicing or maintenance of secondary cells or secondary half-cells
- H01M10/4242—Regeneration of electrolyte or reactants
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/54—Reclaiming serviceable parts of waste accumulators
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/84—Recycling of batteries or fuel cells
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- Manufacturing & Machinery (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Primary Cells (AREA)
- Secondary Cells (AREA)
- Battery Electrode And Active Subsutance (AREA)
Abstract
A lead-acid battery repairing active agent without the need of supplementing electrolyte and a preparation method thereof relate to the technical field of battery repairing, and comprise the following components in parts by weight, namely diammonium hydrogen phosphate, ammonium sulfate, potassium persulfate, sodium pyrophosphate, sodium sulfate, tartaric acid, sodium thiosulfate, zinc sulfate, manganese dioxide, bismuth trioxide, thulium oxide, activated carbon and distilled water. Pouring distilled water into a plastic container, fully mixing diammonium hydrogen phosphate, potassium persulfate, sodium pyrophosphate, ammonium sulfate, sodium sulfate, tartaric acid, sodium thiosulfate and zinc sulfate, pouring into the distilled water in the container, cooling, and adding manganese dioxide, bismuth trioxide, thulium oxide and activated carbon weighed according to parts by weight when the temperature of the solution is restored to 25 ℃. The battery has good performance after being repaired, long service life and high efficiency with good low temperature resistance effect. The battery has good performance after being repaired, does not need to add electrolyte, is convenient to use, has long service life and high efficiency with good low-temperature resistance effect.
Description
The technical field is as follows:
the invention relates to the technical field of battery repair, in particular to a lead-acid battery repair active agent without the need of supplementing electrolyte and a preparation method thereof.
Background art:
in the later charging period of the lead-acid battery, an electrolytic effect can be generated, and the moisture in the electrolyte is partially evaporated. After the battery is charged and discharged for a long time, more water is evaporated, so that the concentration of the electrolyte is increased, and the liquid level is lowered. And the sulfation exists in the long-term use process, so that the sulfuric acid is reduced, distilled water and electrolyte are required to be supplemented, the original height of the liquid surface is recovered, and the normal concentration of the electrolyte is maintained, so that the service life of the lead-acid storage battery is ensured. In the prior art, the performance of a battery is generally recovered by replenishing water and electrolyte, and an active agent is also added in the battery repair, so that the recovery period performance of the battery is ensured.
The invention content is as follows:
the invention aims to provide a lead-acid battery repair active agent which has good performance after battery repair, long service life and good low-temperature resistance effect and does not need to supplement electrolyte, and a preparation method thereof.
The technical problem to be solved by the invention is realized by adopting the following technical scheme.
The lead-acid battery repair active agent without replenishing electrolyte is characterized in that: the water-soluble ammonium hydrogen phosphate fuel comprises, by weight, 10-12 parts of diammonium hydrogen phosphate, 3-5 parts of ammonium sulfate, 6-8 parts of potassium persulfate, 2-4 parts of sodium pyrophosphate, 2-4 parts of sodium sulfate, 2-4 parts of tartaric acid, 4-6 parts of sodium thiosulfate, 0.2-1 part of zinc sulfate, 0.2-0.4 part of manganese dioxide, 0.02-0.08 part of bismuth trioxide, 0.001-0.01 part of thulium oxide, 1-2 parts of activated carbon and 100-200 parts of distilled water in sequence.
Preferably comprises the following components by weight portion, 11 portions of diammonium hydrogen phosphate, 4 portions of ammonium sulfate, 7 portions of potassium persulfate, 3 portions of sodium pyrophosphate, 3 portions of sodium sulfate, 3 portions of tartaric acid, 5 portions of sodium thiosulfate, 0.6 portion of zinc sulfate, 0.3 portion of manganese dioxide, 0.05 portion of bismuth trioxide, 0.006 portion of thulium oxide, 1.5 portions of activated carbon and 150 portions of distilled water.
And 2-4 parts of sodium molybdate.
The preparation method of the lead-acid battery repair active agent without replenishing electrolyte is characterized by comprising the following steps: pouring distilled water heated to 40-50 ℃ into a plastic container, weighing diammonium hydrogen phosphate, ammonium sulfate, potassium persulfate, sodium pyrophosphate, sodium sulfate, tartaric acid, sodium thiosulfate and zinc sulfate according to parts by weight, fully mixing, pouring into the distilled water in the container, stirring while adding, cooling, adding manganese dioxide, bismuth trioxide, thulium oxide and activated carbon weighed according to parts by weight when the temperature of the solution is restored to 25 ℃, and uniformly stirring without stopping.
And a plastic rod or a glass rod is adopted during stirring.
Other impurities are strictly prevented from dropping during the mixing.
The invention is a specially-made battery repairing active agent, which can greatly improve the recovery efficiency of the battery, is more convenient to operate and faster in speed, has better recovered efficiency of the battery, and can reach at least 80% of the efficiency of the original battery.
The invention has the beneficial effects that: the battery has good performance after being repaired, does not need to add electrolyte, is convenient to use, has long service life and high efficiency with good low-temperature resistance effect.
The specific implementation mode is as follows:
in order to make the technical means, the creation characteristics, the achievement purposes and the effects of the invention easy to understand, the invention is further described with the specific embodiments.
Example one
The lead-acid battery repairing active agent without supplementing electrolyte comprises, by weight, 10 parts of diammonium hydrogen phosphate, 3 parts of ammonium sulfate, 2 parts of sodium sulfate, 2 parts of tartaric acid, 2 parts of potassium persulfate, 2 parts of sodium pyrophosphate, 4 parts of sodium thiosulfate, 0.2 part of zinc sulfate, 0.2 part of manganese dioxide, 0.02 part of bismuth trioxide, 0.001 part of thulium oxide, 1 part of activated carbon and 100 parts of distilled water in sequence.
Pouring distilled water heated to 40-50 ℃ into a plastic container, weighing diammonium hydrogen phosphate, ammonium sulfate, potassium persulfate, sodium pyrophosphate, sodium sulfate, tartaric acid, sodium thiosulfate and zinc sulfate according to parts by weight, fully mixing, pouring into the distilled water in the container, stirring while adding, cooling, and adding manganese dioxide, bismuth trioxide, thulium oxide and active carbon weighed according to parts by weight when the temperature of the solution is restored to 25 ℃, and uniformly stirring without stopping.
A plastic rod or a glass rod is adopted during stirring.
Other impurities are strictly prevented from dropping during mixing.
Example two
The lead-acid battery repairing active agent without supplementing electrolyte comprises, by weight, 11 parts of diammonium hydrogen phosphate, 4 parts of ammonium sulfate, 3 parts of sodium sulfate, 3 parts of tartaric acid, 7 parts of potassium persulfate, 3 parts of sodium pyrophosphate, 5 parts of sodium thiosulfate, 0.6 part of zinc sulfate, 0.3 part of manganese dioxide, 0.05 part of bismuth trioxide, 0.006 part of thulium oxide, 1.5 parts of activated carbon and 150 parts of distilled water.
And 2-4 parts of sodium molybdate.
Pouring distilled water heated to 40-50 ℃ into a plastic container, weighing diammonium hydrogen phosphate, ammonium sulfate, potassium persulfate, sodium pyrophosphate, sodium sulfate, tartaric acid, sodium thiosulfate and zinc sulfate according to parts by weight, fully mixing, pouring into the distilled water in the container, stirring while adding, cooling, and adding manganese dioxide, bismuth trioxide, thulium oxide and active carbon weighed according to parts by weight when the temperature of the solution is restored to 25 ℃, and uniformly stirring without stopping.
A plastic rod or a glass rod is adopted during stirring.
Other impurities are strictly prevented from dropping during mixing.
EXAMPLE III
The lead-acid battery repairing active agent without supplementing electrolyte comprises, by weight, 12 parts of diammonium hydrogen phosphate, 5 parts of ammonium sulfate, 4 parts of sodium sulfate, 4 parts of tartaric acid, 8 parts of potassium persulfate, 4 parts of sodium pyrophosphate, 6 parts of sodium thiosulfate, 1 part of zinc sulfate, 0.4 part of manganese dioxide, 0.08 part of bismuth trioxide, 0.01 part of thulium oxide, 2 parts of activated carbon and 200 parts of distilled water in sequence.
Pouring distilled water heated to 40-50 ℃ into a plastic container, weighing diammonium hydrogen phosphate, ammonium sulfate, potassium persulfate, sodium pyrophosphate, sodium sulfate, tartaric acid, sodium thiosulfate and zinc sulfate according to parts by weight, fully mixing, pouring into the distilled water in the container, stirring while adding, cooling, and adding manganese dioxide, bismuth trioxide, thulium oxide and active carbon weighed according to parts by weight when the temperature of the solution is restored to 25 ℃, and uniformly stirring without stopping.
A plastic rod or a glass rod is adopted during stirring.
Other impurities are strictly prevented from dropping during mixing.
The foregoing shows and describes the general principles and broad features of the present invention and advantages thereof. It will be understood by those skilled in the art that the present invention is not limited to the embodiments described above, which are described in the specification and illustrated only to illustrate the principle of the present invention, but that various changes and modifications may be made therein without departing from the spirit and scope of the present invention, which fall within the scope of the invention as claimed. The scope of the invention is defined by the appended claims and equivalents thereof.
Claims (5)
1. The lead-acid battery repair active agent without replenishing electrolyte is characterized in that: comprises the following components in parts by weight: 10-12 parts of diammonium hydrogen phosphate, 3-5 parts of ammonium sulfate, 6-8 parts of potassium persulfate, 2-4 parts of sodium pyrophosphate, 2-4 parts of sodium sulfate, 2-4 parts of tartaric acid, 4-6 parts of sodium thiosulfate, 0.2-1 part of zinc sulfate, 0.2-0.4 part of manganese dioxide, 0.02-0.08 part of bismuth trioxide, 0.001-0.01 part of thulium oxide, 1-2 parts of activated carbon and 100-200 parts of distilled water;
the preparation method of the lead-acid battery repair active agent without supplementing electrolyte comprises the following steps of pouring distilled water heated to 40-50 ℃ into a plastic container, weighing diammonium hydrogen phosphate, ammonium sulfate, potassium persulfate, sodium pyrophosphate, sodium sulfate, tartaric acid, sodium thiosulfate and zinc sulfate according to parts by weight, fully mixing, pouring into the distilled water of the container, stirring while adding, cooling and the like, recovering the temperature of the solution to 25 ℃, adding manganese dioxide, bismuth trioxide, thulium oxide and active carbon according to parts by weight, and uniformly stirring without stopping.
2. The electrolyte-replenishing-free lead-acid battery repair active agent according to claim 1, characterized in that: the ammonium sulfate-containing diammonium hydrogen phosphate-containing fuel comprises, by weight, 11 parts of diammonium hydrogen phosphate, 4 parts of ammonium sulfate, 7 parts of potassium persulfate, 3 parts of sodium pyrophosphate, 3 parts of sodium sulfate, 3 parts of tartaric acid, 5 parts of sodium thiosulfate, 0.6 part of zinc sulfate, 0.3 part of manganese dioxide, 0.05 part of bismuth trioxide, 0.006 part of thulium oxide, 1.5 parts of activated carbon and 150 parts of distilled water.
3. The electrolyte-replenishing-free lead-acid battery repair active agent according to claim 1, characterized in that: and 2-4 parts of sodium molybdate.
4. The electrolyte-replenishing-free lead-acid battery repair active agent according to claim 1, characterized in that: and a plastic rod or a glass rod is adopted during stirring.
5. The electrolyte-replenishing-free lead-acid battery repair active agent according to claim 1, characterized in that: other impurities are strictly prevented from dropping during the mixing.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611205731.5A CN106785116B (en) | 2016-12-23 | 2016-12-23 | Lead-acid battery repair active agent without need of supplementing electrolyte and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611205731.5A CN106785116B (en) | 2016-12-23 | 2016-12-23 | Lead-acid battery repair active agent without need of supplementing electrolyte and preparation method thereof |
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| Publication Number | Publication Date |
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| CN106785116A CN106785116A (en) | 2017-05-31 |
| CN106785116B true CN106785116B (en) | 2020-04-10 |
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Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1492532A (en) * | 2003-09-28 | 2004-04-28 | 李茂慧 | Method for producing storage battery repairing agent |
| CN101022181A (en) * | 2006-02-15 | 2007-08-22 | 王一锋 | Lead-acid battery recovery active agent and lead-acid battery sulfation recovery method |
| CN101478057A (en) * | 2009-01-15 | 2009-07-08 | 公平 | Gel special for gel battery production |
| CN102082305A (en) * | 2010-12-21 | 2011-06-01 | 无锡市霄鹰环境科技有限公司 | Ionic lead-acid cell repair protection solution |
| CN102122730A (en) * | 2011-01-19 | 2011-07-13 | 李海明 | Silicate electrolyte for battery and preparation method thereof |
| CN102618884A (en) * | 2012-03-16 | 2012-08-01 | 北京化工大学 | Lead regeneration method for recovering lead paste from waste lead acid storage battery by wet method |
| WO2014071571A1 (en) * | 2012-11-07 | 2014-05-15 | Empire Technology Development Llc | Liquid-activated hydrogel battery |
-
2016
- 2016-12-23 CN CN201611205731.5A patent/CN106785116B/en active Active
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1492532A (en) * | 2003-09-28 | 2004-04-28 | 李茂慧 | Method for producing storage battery repairing agent |
| CN101022181A (en) * | 2006-02-15 | 2007-08-22 | 王一锋 | Lead-acid battery recovery active agent and lead-acid battery sulfation recovery method |
| CN101478057A (en) * | 2009-01-15 | 2009-07-08 | 公平 | Gel special for gel battery production |
| CN102082305A (en) * | 2010-12-21 | 2011-06-01 | 无锡市霄鹰环境科技有限公司 | Ionic lead-acid cell repair protection solution |
| CN102122730A (en) * | 2011-01-19 | 2011-07-13 | 李海明 | Silicate electrolyte for battery and preparation method thereof |
| CN102618884A (en) * | 2012-03-16 | 2012-08-01 | 北京化工大学 | Lead regeneration method for recovering lead paste from waste lead acid storage battery by wet method |
| WO2014071571A1 (en) * | 2012-11-07 | 2014-05-15 | Empire Technology Development Llc | Liquid-activated hydrogel battery |
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| CN106785116A (en) | 2017-05-31 |
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Effective date of registration: 20200521 Address after: 233799 19th floor, investment building, Chengguan Town, Guzhen County, Bengbu City, Anhui Province Patentee after: Bengbu Zhicong Information Technology Co., Ltd Address before: 230088 Room 1201, Block A, Zhongrui Building, No. 9 Hongfeng Road, Hefei High-tech Zone, Anhui Province Patentee before: Anhui Dart Intellectual Property Service Co.,Ltd. |
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Effective date of registration: 20220622 Address after: Room 205, new energy industry science and technology incubation base, No. 161, Shanshui Road, Zhuliu street, Changle County, Weifang City, Shandong Province, 261000 Patentee after: SHANDONG TENGDAO NEW ENERGY TECHNOLOGY CO.,LTD. Address before: 233799 19th floor, Chengguan town investment building, Guzhen County, Bengbu City, Anhui Province Patentee before: Bengbu Zhicong Information Technology Co.,Ltd. |