CN106785116A - The agent of lead-acid battery repairing activity and its modulator approach of electrolyte need not be supplemented - Google Patents
The agent of lead-acid battery repairing activity and its modulator approach of electrolyte need not be supplemented Download PDFInfo
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- CN106785116A CN106785116A CN201611205731.5A CN201611205731A CN106785116A CN 106785116 A CN106785116 A CN 106785116A CN 201611205731 A CN201611205731 A CN 201611205731A CN 106785116 A CN106785116 A CN 106785116A
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- parts
- lead
- sodium
- distilled water
- acid battery
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/42—Methods or arrangements for servicing or maintenance of secondary cells or secondary half-cells
- H01M10/4242—Regeneration of electrolyte or reactants
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/54—Reclaiming serviceable parts of waste accumulators
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/84—Recycling of batteries or fuel cells
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- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Primary Cells (AREA)
- Secondary Cells (AREA)
- Battery Electrode And Active Subsutance (AREA)
Abstract
The agent of lead-acid battery repairing activity and its modulator approach of electrolyte need not be supplemented, it is related to battery recovery technique field, include following components by weight, successively diammonium hydrogen phosphate, ammonium sulfate, potassium peroxydisulfate, sodium pyrophosphate, sodium sulphate, tartaric acid, sodium thiosulfate, zinc sulfate, manganese dioxide, bismuth oxide, thulium oxide, activated carbon and distilled water.First distilled water is poured into a plastic containers, diammonium hydrogen phosphate, potassium peroxydisulfate, sodium pyrophosphate, ammonium sulfate, sodium sulphate, tartaric acid, sodium thiosulfate and zinc sulfate are sufficiently mixed in distilled water that is rear and pouring into container, the temperature of the solution such as cooling is restored during to 25 DEG C, manganese dioxide, bismuth oxide, thulium oxide and activated carbon that addition is weighed by weight.Performance after battery of the present invention is repaired is good, and long service life, the good efficiency of low temperature resistant effect is high.Performance after battery of the present invention is repaired is good, and easy to use without adding electrolyte, long service life, the good efficiency of low temperature resistant effect is high.
Description
Technical field：
The present invention relates to battery recovery technique field, need not specifically supplement electrolyte the agent of lead-acid battery repairing activity and
Its modulator approach.
Background technology：
Lead-acid battery phase after charging, electrolytic effect can be produced, evaporate the moist part in electrolyte.Battery is through long
After time discharge and recharge use, moisture can evaporate more, raise concentration of electrolyte, and liquid level declines.And in the mistake of long-term use
There is this sulfation in journey, cause sulfuric acid also to tail off, at this moment require supplementation with distilled water and electrolyte, make build-up of fluid original
Highly, electrolyte maintains normal concentration, to ensure lead-acid accumulator service life.In the prior art, during battery is repaired typically all
The performance of the battery for referring to moisturizing and electrolyte to reply, also has and adds activating agent in battery reparation, so that
Battery recovery phase performance is obtained, the species of existing activating agent is relatively simple, and still need benefit while activating agent is added
Electrolyte is filled, use time change is shorter after battery recovery, and resistance to low temperature is poor.
The content of the invention：
The technical problems to be solved by the invention are that the performance provided after a kind of battery reparation is good, and long service life is resistance to
The good lead-acid battery repairing activity agent that need not supplement electrolyte of cryogenic effect and its modulator approach.
The technical problems to be solved by the invention are realized using following technical scheme.
The lead-acid battery repairing activity agent of electrolyte need not be supplemented, it is characterised in that：Include following components by weight, according to
10~12 parts of two ammonium of hypophosphorous acid hydrogen, 3~5 parts of ammonium sulfate, 6~8 parts of potassium peroxydisulfate, 2~4 parts of sodium pyrophosphate, 2~4 parts of sodium sulphate,
2~4 parts of tartaric acid, 4~6 parts of sodium thiosulfate, 0.2~1 part of zinc sulfate, 0.2~0.4 part of manganese dioxide, bismuth oxide
100~200 parts of 0.02~0.08 part, 0.001~0.01 part of thulium oxide, 1~2 part of activated carbon and distilled water.
It is preferred that include following components by weight, 11 parts of diammonium hydrogen phosphate, 4 parts of ammonium sulfate, 7 parts of potassium peroxydisulfate, burnt successively
3 parts of sodium phosphate, 3 parts of sodium sulphate, 3 parts of tartaric acid, 5 parts of sodium thiosulfate, 0.6 part of zinc sulfate, 0.3 part of manganese dioxide, three oxidations
150 parts of two 0.05 part of bismuths, 0.006 part of thulium oxide, 1.5 parts of activated carbon and distilled water.
Also include 2~4 parts of sodium molybdate by weight.
The modulator approach of the lead-acid battery repairing activity agent of electrolyte need not be supplemented, it is characterised in that：Enter according to the following steps
OK, the distilled water that first would be heated to 40~50 DEG C of temperature is poured into a plastic containers, and diammonium hydrogen phosphate, sulphur are weighed by weight
Sour ammonium, potassium peroxydisulfate, sodium pyrophosphate, sodium sulphate, tartaric acid, sodium thiosulfate and zinc sulfate, are sufficiently mixed afterwards and pour into container
Distilled water in, stir while adding, the temperature of solution such as cooling is restored during to 25 DEG C, the titanium dioxide that addition is weighed by weight
Manganese, bismuth oxide, thulium oxide and activated carbon, do not stop to stir.
Sticking plaster or glass bar are used when described stirring.
Forbid to fall into other impurities during described mixing.
The present invention is special battery repairing activity agent, can greatly improve the efficiency of battery recovery, more convenient operation,
Faster, and efficiency after battery recovery is more preferably, can reach the 80% of at least original battery efficiency for speed.
The beneficial effects of the invention are as follows：Performance after battery of the present invention is repaired is good, easy to use without adding electrolyte,
Long service life, the good efficiency of low temperature resistant effect is high.
Specific embodiment：
In order that technological means, creation characteristic, reached purpose and effect that the present invention is realized are easy to understand, tie below
Specific embodiment is closed, the present invention is expanded on further.
Embodiment one
The lead-acid battery repairing activity agent of electrolyte need not be supplemented, by weight including following components, phosphoric acid hydrogen two successively
10 parts of ammonium, 3 parts of ammonium sulfate, 2 parts of sodium sulphate, 2 parts of tartaric acid, potassium peroxydisulfate part, 2 parts of sodium pyrophosphate, 4 parts of sodium thiosulfate, sulphur
0.2 part of sour zinc, 0.2 part of manganese dioxide, 0.02 part of bismuth oxide, 0.001 part of thulium oxide, 1 part of activated carbon and distilled water 100
Part.
The modulator approach of the lead-acid battery repairing activity agent of electrolyte need not be supplemented, is carried out according to the following steps, first will heating
Distilled water to 40~50 DEG C of temperature is poured into a plastic containers, and diammonium hydrogen phosphate, ammonium sulfate, persulfuric acid are weighed by weight
Potassium, sodium pyrophosphate, sodium sulphate, tartaric acid, sodium thiosulfate and zinc sulfate, are sufficiently mixed in distilled water that is rear and pouring into container,
Stir while adding, the temperature of the solution such as cooling is restored during to 25 DEG C, manganese dioxide, three oxidations two that addition is weighed by weight
Bismuth, thulium oxide and activated carbon, do not stop to stir.
Sticking plaster or glass bar are used when stirring.
Forbid to fall into other impurities during mixing.
Embodiment two
The lead-acid battery repairing activity agent of electrolyte need not be supplemented, by weight including following components, phosphoric acid hydrogen two successively
11 parts of ammonium, 4 parts of ammonium sulfate, 3 parts of sodium sulphate, 3 parts of tartaric acid, 7 parts of potassium peroxydisulfate, 3 parts of sodium pyrophosphate, 5 parts of sodium thiosulfate, sulphur
0.6 part of sour zinc, 0.3 part of manganese dioxide, 0.05 part of bismuth oxide, 0.006 part of thulium oxide, 1.5 parts of activated carbon and distilled water 150
Part.
Also include 2~4 parts of sodium molybdate by weight.
The modulator approach of the lead-acid battery repairing activity agent of electrolyte need not be supplemented, is carried out according to the following steps, first will heating
Distilled water to 40~50 DEG C of temperature is poured into a plastic containers, and diammonium hydrogen phosphate, ammonium sulfate, persulfuric acid are weighed by weight
Potassium, sodium pyrophosphate, sodium sulphate, tartaric acid, sodium thiosulfate and zinc sulfate, are sufficiently mixed in distilled water that is rear and pouring into container,
Stir while adding, the temperature of the solution such as cooling is restored during to 25 DEG C, manganese dioxide, three oxidations two that addition is weighed by weight
Bismuth, thulium oxide and activated carbon, do not stop to stir.
Sticking plaster or glass bar are used when stirring.
Forbid to fall into other impurities during mixing.
Embodiment three
The lead-acid battery repairing activity agent of electrolyte need not be supplemented, by weight including following components, phosphoric acid hydrogen two successively
12 parts of ammonium, 5 parts of ammonium sulfate, 4 parts of sodium sulphate, 4 parts of tartaric acid, 8 parts of potassium peroxydisulfate, 4 parts of sodium pyrophosphate, 6 parts of sodium thiosulfate, sulphur
200 parts of 1 part of sour zinc, 0.4 part of manganese dioxide, 0.08 part of bismuth oxide, 0.01 part of thulium oxide, 2 parts of activated carbon and distilled water.
The modulator approach of the lead-acid battery repairing activity agent of electrolyte need not be supplemented, is carried out according to the following steps, first will heating
Distilled water to 40~50 DEG C of temperature is poured into a plastic containers, and diammonium hydrogen phosphate, ammonium sulfate, persulfuric acid are weighed by weight
Potassium, sodium pyrophosphate, sodium sulphate, tartaric acid, sodium thiosulfate and zinc sulfate, are sufficiently mixed in distilled water that is rear and pouring into container,
Stir while adding, the temperature of the solution such as cooling is restored during to 25 DEG C, manganese dioxide, three oxidations two that addition is weighed by weight
Bismuth, thulium oxide and activated carbon, do not stop to stir.
Sticking plaster or glass bar are used when stirring.
Forbid to fall into other impurities during mixing.
General principle of the invention and principal character and advantages of the present invention has been shown and described above.The technology of the industry
Personnel it should be appreciated that the present invention is not limited to the above embodiments, simply explanation described in above-described embodiment and specification this
The principle of invention, without departing from the spirit and scope of the present invention, various changes and modifications of the present invention are possible, these changes
Change and improvement all fall within the protetion scope of the claimed invention.The claimed scope of the invention by appending claims and its
Equivalent thereof.
Claims (6)
1. the lead-acid battery repairing activity agent of electrolyte need not be supplemented, it is characterised in that：Include following components by weight, successively
10~12 parts of diammonium hydrogen phosphate, 3~5 parts of ammonium sulfate, 6~8 parts of potassium peroxydisulfate, 2~4 parts of sodium pyrophosphate, 2~4 parts of sodium sulphate, wine
2~4 parts of stone acid, 4~6 parts of sodium thiosulfate, 0.2~1 part of zinc sulfate, 0.2~0.4 part of manganese dioxide, bismuth oxide 0.02
100~200 parts of~0.08 part, 0.001~0.01 part of thulium oxide, 1~2 part of activated carbon and distilled water.
2. the lead-acid battery repairing activity agent that electrolyte need not be supplemented according to claim 1, it is characterised in that：By weight
Part includes following components, successively 11 parts of diammonium hydrogen phosphate, 4 parts of ammonium sulfate, 7 parts of potassium peroxydisulfate, 3 parts of sodium pyrophosphate, sodium sulphate 3
Part, 3 parts of tartaric acid, 5 parts of sodium thiosulfate, 0.6 part of zinc sulfate, 0.3 part of manganese dioxide, 0.05 part of bismuth oxide, thulium oxide
150 parts of 0.006 part, 1.5 parts of activated carbon and distilled water.
3. the lead-acid battery repairing activity agent that electrolyte need not be supplemented according to claim 1, it is characterised in that：By weight
Part also includes 2~4 parts of sodium molybdate.
4. the modulator approach of the lead-acid battery repairing activity agent that need not supplement electrolyte according to claim 1, its feature
It is：Carry out according to the following steps, the distilled water that first would be heated to 40~50 DEG C of temperature is poured into a plastic containers, by weight
Diammonium hydrogen phosphate, ammonium sulfate, potassium peroxydisulfate, sodium pyrophosphate, sodium sulphate, tartaric acid, sodium thiosulfate and zinc sulfate are weighed, fully
After mixing and pour into the distilled water of container, stir while adding, the temperature of the solution such as cooling is restored during to 25 DEG C, is added by weight
Manganese dioxide, bismuth oxide, thulium oxide and activated carbon that amount part weighs, do not stop to stir.
5. the modulator approach of the lead-acid battery repairing activity agent that need not supplement electrolyte according to claim 4, its feature
It is：Sticking plaster or glass bar are used when described stirring.
6. the modulator approach of the lead-acid battery repairing activity agent that need not supplement electrolyte according to claim 4, its feature
It is：Forbid to fall into other impurities during described mixing.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611205731.5A CN106785116B (en) | 2016-12-23 | 2016-12-23 | Lead-acid battery repair active agent without need of supplementing electrolyte and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611205731.5A CN106785116B (en) | 2016-12-23 | 2016-12-23 | Lead-acid battery repair active agent without need of supplementing electrolyte and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN106785116A true CN106785116A (en) | 2017-05-31 |
| CN106785116B CN106785116B (en) | 2020-04-10 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201611205731.5A Active CN106785116B (en) | 2016-12-23 | 2016-12-23 | Lead-acid battery repair active agent without need of supplementing electrolyte and preparation method thereof |
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Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1492532A (en) * | 2003-09-28 | 2004-04-28 | 李茂慧 | Method for producing storage battery repairing agent |
| CN101022181A (en) * | 2006-02-15 | 2007-08-22 | 王一锋 | Lead-acid battery recovery active agent and lead-acid battery sulfation recovery method |
| CN101478057A (en) * | 2009-01-15 | 2009-07-08 | 公平 | Gel special for gel battery production |
| CN102082305A (en) * | 2010-12-21 | 2011-06-01 | 无锡市霄鹰环境科技有限公司 | Ionic lead-acid cell repair protection solution |
| CN102122730A (en) * | 2011-01-19 | 2011-07-13 | 李海明 | Silicate electrolyte for battery and preparation method thereof |
| CN102618884A (en) * | 2012-03-16 | 2012-08-01 | 北京化工大学 | Lead regeneration method for recovering lead paste from waste lead acid storage battery by wet method |
| WO2014071571A1 (en) * | 2012-11-07 | 2014-05-15 | Empire Technology Development Llc | Liquid-activated hydrogel battery |
-
2016
- 2016-12-23 CN CN201611205731.5A patent/CN106785116B/en active Active
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1492532A (en) * | 2003-09-28 | 2004-04-28 | 李茂慧 | Method for producing storage battery repairing agent |
| CN101022181A (en) * | 2006-02-15 | 2007-08-22 | 王一锋 | Lead-acid battery recovery active agent and lead-acid battery sulfation recovery method |
| CN101478057A (en) * | 2009-01-15 | 2009-07-08 | 公平 | Gel special for gel battery production |
| CN102082305A (en) * | 2010-12-21 | 2011-06-01 | 无锡市霄鹰环境科技有限公司 | Ionic lead-acid cell repair protection solution |
| CN102122730A (en) * | 2011-01-19 | 2011-07-13 | 李海明 | Silicate electrolyte for battery and preparation method thereof |
| CN102618884A (en) * | 2012-03-16 | 2012-08-01 | 北京化工大学 | Lead regeneration method for recovering lead paste from waste lead acid storage battery by wet method |
| WO2014071571A1 (en) * | 2012-11-07 | 2014-05-15 | Empire Technology Development Llc | Liquid-activated hydrogel battery |
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| CN106785116B (en) | 2020-04-10 |
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Effective date of registration: 20200521 Address after: 233799 19th floor, investment building, Chengguan Town, Guzhen County, Bengbu City, Anhui Province Patentee after: Bengbu Zhicong Information Technology Co., Ltd Address before: 230088 Room 1201, Block A, Zhongrui Building, No. 9 Hongfeng Road, Hefei High-tech Zone, Anhui Province Patentee before: Anhui Dart Intellectual Property Service Co.,Ltd. |
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Effective date of registration: 20220622 Address after: Room 205, new energy industry science and technology incubation base, No. 161, Shanshui Road, Zhuliu street, Changle County, Weifang City, Shandong Province, 261000 Patentee after: SHANDONG TENGDAO NEW ENERGY TECHNOLOGY CO.,LTD. Address before: 233799 19th floor, Chengguan town investment building, Guzhen County, Bengbu City, Anhui Province Patentee before: Bengbu Zhicong Information Technology Co.,Ltd. |
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