CN104119738A - Waterborne fluorocarbon coating for corrosion prevention as well as preparation method and application thereof - Google Patents
Waterborne fluorocarbon coating for corrosion prevention as well as preparation method and application thereof Download PDFInfo
- Publication number
- CN104119738A CN104119738A CN201410272338.2A CN201410272338A CN104119738A CN 104119738 A CN104119738 A CN 104119738A CN 201410272338 A CN201410272338 A CN 201410272338A CN 104119738 A CN104119738 A CN 104119738A
- Authority
- CN
- China
- Prior art keywords
- coating
- component
- weight part
- fluorocarbon coating
- anticorrosion
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Paints Or Removers (AREA)
Abstract
The invention discloses a waterborne fluorocarbon coating for corrosion prevention as well as a preparation method and application of the coating. The preparation method comprises the following steps: adding de-ionized water into a container, adding an anti-settling agent, a wetting agent, a dispersant, a defoamer and a pigment in sequence under the low-speed stirring condition, after uniformly stirring, adding glass beads, and grinding at a high speed to obtain color paste; adding waterborne fluorocarbon resin into the container, adding de-ionized water, an assistant and the color paste obtained in the step (1) in sequence under the low-speed stirring condition, dispersing at a high speed, and filtering to obtain a component A of the coating; adding waterborne isocyanate resin into the container, and adding a solvent under the low-speed stirring condition to obtain a component B of the coating. The coating is applied to preparation of steel structure coating products; the obtained coating has good protection functions such as water resistance, chemical resistance, salt mist resistance and weather resistance; steel structure plates are long in service life.
Description
Technical field
The invention belongs to protective system preparing technical field, particularly a kind of anticorrosion use fluorocarbon coating and its preparation method and application.
Background technology
Fluorine carbon paint has excellent weathering resistance, chemical resistance, contamination resistance, is a kind of protection against corrosion finish paint of excellent performance.At present, the high bake type paint taking solvent-borne type PVDF as representative, is applied to various precoating metal building materials; Two component Air drying fluorocarbon coatings taking solvent-borne type FEVE as representative have been applied to large-scale steel structure, external wall.The project of a lot of fluorine carbon applications has still kept certain gloss, color through ten after vicennial test, does not occur serious corrosion condition; Therefore solvent-borne type fluorocarbon coating has started to be particularly widely used in protection against corrosion field in different field.But along with the environmental regulation of international standard and China is increasingly strict to the restriction of VOC (volatile organic compounds) discharge, in the solvent-borne type fluorocarbon coating application that causes a large amount of VOC to volatilize, be subject to certain restrictions.Research and development water-based fluorocarbon antisepsis finishing paint becomes the direction of fluorocarbon coating development.At present obtain promotion and application at external wall taking aqueous fluorine-containing acrylic coating, water-based FEVE fluorocarbon coating, water-based PVDF fluorocarbon coating as the single component thermoplasticity aqueous fluorocarbon coating of representative, but in performance, still had larger gap with solvent-borne type fluorocarbon coating at corrosion-resistant field thermoplasticity aqueous fluorocarbon coating.
Aqueous fluoropolymer has 2 kinds of water-soluble and aqueous dispersion types, wherein water-soluble due to fluoropolymer because of gap between surface tension and water quality interface larger, therefore large according to water-soluble fluorine carbon paint technological development difficulty, product stability is poor.And more ripe as the technological line of developing taking aqueous dispersion type fluorine carbon paint, have not been reported for antisepsis finishing paint.
Water-based fluorocarbon antisepsis finishing paint is divided into again self-emulsifying single-component cross-linking type type and two kinds, two component crosslinking curing types.
Single-component self-emulsifying type, mainly by vinylformic acid branched structure being carried out to the technology of fluorine modification, changes the performance of some weathering resistance deficiency in acrylic ester polymer, and synthetic method is fairly simple, thereby now apply in practice often.But the resin emulsion that this method obtains is because just side chain is fluorine-containing, although in use performance is better than common vinylformic acid, but because self-emulsifying cross-linking density is not high, on antiseptic property, do not reach high acid and alkali-resistance and the salt spray resistance of protective system requirement, on water tolerance and chemical mediator-resitant property, fail to reach especially the requirement of solvent-borne type fluorine carbon finishing paint.
That all adopt about water-based fluorocarbon finish paint at present is single-component thermoplastics type, as patent of invention publication number CN101117483A< aqueous fluorine-carbon paint and preparation method thereof >, CN101397435A< environment friendly water-soluble metal fluorocarbon coatings >, the single-component water-based fluorocarbon coating of CN101717600A< and preparation method thereof >, CN102964927A< high efficient water-proof painting material >, CN103146270A< multifunctional nano colored anti-corrosion coating >, CN101701119A< oil rub resistance self-cleaning aqueous fluorocarbon lacquer > is single-component thermoplastics type fluoro-containing coating, there is no linking agent, coating only depends on the fluoro-resin film forming of emulsification.Or adopt single-component internal emulsification solidifying agent (diacid two hydrazine types) fluorine carbon finishing paint, as patent of invention publication number CN101148553A< waterborne metallic anticorrosion paint and preparation method thereof >.Or the single-component fluorine carbon finishing paint that adopts aqueous silane coupling agent to form, as patent of invention publication number CN103450719A< long-acting aqueous, environmental protective steel construction protection coating >, CN103122186A< rail is anticorrosion with environment-friendly type treatment solution and anticorrosion rail material >, it is coating modified that a CN103788783A< high-performance water-based fluorine carbon paint > etc. all adopts silane coupling agent to carry out, wherein single-component thermoplastics type is larger with the poor distance of cross-linking type on water tolerance and acid-proof alkaline, in single-component, crosslinked emulsification solidifying agent (diacid two hydrazine types) is although fluorine carbon finishing paint and silane coupled formulation fluorine carbon finishing paint have crosslinked, but because cross-linking density is limited, thereby fail to make film self acid-proof alkaline and salt spray resistance to improve a lot.
The present invention is the two curable aqueous fluorine carbon finishing paints of component external crosslinking of normal temperature, mainly formed by hydroxyl water-based fluororesin and water-based isocyanate solidifying agent, owing to adopting external crosslinking type waterborne curing agent to solidify, strengthen the cross-linking density of film, increase film internal cohesive energy, improve the erosion of coating acid and alkali-resistance medium and neutral salt ion, thereby its corrosion resistance nature is better than self-emulsifying aqueous fluorine carbon finishing paint.
Summary of the invention
In order to overcome above-mentioned the deficiencies in the prior art, primary and foremost purpose of the present invention is to provide a kind of two-pack heat curing-type anticorrosion use fluorocarbon coating.
Another object of the present invention is to provide a kind of preparation method of above-mentioned anticorrosion use fluorocarbon coating.
Another object of the present invention is to provide a kind of application of above-mentioned anticorrosion use fluorocarbon coating; Described anticorrosion use fluorocarbon coating can be applicable to prepare application steel construction.
To achieve these goals, the present invention is by the following technical solutions: a kind of preparation method of anticorrosion use fluorocarbon coating, comprises the following steps:
(1) 20.0～30.0 parts by weight of deionized water are placed in to container, under stirring at low speed condition, add successively 0.3～0.5 weight part anti-settling agent, 5～10 weight part wetting dispersing agents and 15～50 weight part pigment, after stirring, add again 100～120 weight part granulated glass spherees, speed lapping, to fineness 30～35 μ m, obtains mill base;
(2) 60～80 weight part water-based fluorocarbon resins are placed in to container, under stirring at low speed condition, add successively after 5～15 parts by weight of deionized water, 0～0.4 weight part flow agent, 0～0.2 weight part defoamer agent and 0～25 weight part step (1) gained mill base, high speed dispersion 15～20 minutes, filter, obtain anticorrosion use fluorocarbon coating A component.
(3) 70～100 weight part water-based isocyanate resins are placed in to container, add successively after 0～30 parts by weight solvent under stirring at low speed condition, low speed disperses 10～15 minutes, filters, and obtains anticorrosion use fluorocarbon coating B component.
The described wetting dispersing agent of step (1) is Byk Chemie GmbH of BYK191(Germany); Described defoamer is 090(Taiwan De Qian Chemical Co., Ltd.); Described anti-settling agent is BP-187 water-based wilkinite (Linan, Zhejiang Ward novel material limited-liability company); Described pigment is carbon black or rutile titanium white.
The rotating speed of the described stirring at low speed of step (1) is 400～500 revs/min; 1000～2000 revs/min of described speed lapping.
The described flow agent of step (2) is Byk Chemie GmbH of BYK381(Germany); Described defoamer is 090(Taiwan De Qian Chemical Co., Ltd.).
The rotating speed of the described stirring at low speed of step (2) is 400～500 revs/min; The rotating speed of described high speed dispersion is 1000～2000 revs/min.
The described solvent of step (3) is N-Methyl pyrrolidone.
The rotating speed of the described stirring at low speed of step (3) is 400～500 revs/min.
The present invention also provides the anticorrosion use fluorocarbon coating of preparing according to aforesaid method.Preferably wherein A component and B component are 5:1 in the present invention.In the time that A component and B component are 5:1, in A component, in contained isocyanic acid root and B component, the ratio of hydroxyl value is 1.2:1.
Above-mentioned anticorrosion use fluorocarbon coating can be applicable to prepare application steel construction.
The preparation method of described application steel construction presses following operation steps:
(1) pre-treatment of steel construction;
(2) through spraying, roller coating on the steel construction of pre-treatment or brush anticorrosion with zinc rich primer;
(3) dry more than 8 hours under the steel construction normal temperature after coating prime lacquer.
(4) spraying, roller coating or brush anticorrosion with cloud iron intermediate coat on dry zinc rich primer
(5) dry more than 8 hours under the steel construction normal temperature after application intermediate coat
(6) water-repellent preservation fluorocarbon coating is pressed to A, B component ratio (W/W=5:1) is prepared, and adds a small amount of deionized water to adjust viscosity (viscosity; 30 – 60 seconds/25 DEG C, are coated with 4# cup), spraying, roller coating or brush anticorrosion use fluorocarbon coating on dry cloud iron intermediate coat.
The described pre-treatment of step (1) is that sandblasting is carried out in the surface of steel construction.
Described application can be applicable to prepare the steel construction of bridge, chemical industry equipment, building or road equipment.
Principle of the present invention is: utilize high fluorine content the water-based FEVE(fluoroolefin-vinyl ether multiple copolymer with certain hydroxyl group) resin dispersion is main film forming matter, taking weather-proof rutile titanium white, the carbon black etc. of height as pigment, modulate A component by various auxiliary agents; Taking water-based isocyanate as B component; When A component and B component are 5:1, in A component, in contained isocyanic acid root and B component, the ratio of hydroxyl value is 1.2:1.NCO group by isocyanic ester reacts with the oh group in A component resin, and micromolecular A component resin is cross-linked into insoluble not molten macromole film; And the high bond energy that relies on F-C key stops the injury of the base material that ultraviolet ray and various hazardous mediums protect film itself and film.
Compared with prior art, the present invention has following beneficial effect: use the anticorrosion use fluorocarbon coating of the present invention as antisepsis finishing paint, performance and oil soluble FEVE fluorocarbon coating are very approaching; Because taking water as main dispersing medium, therefore VOC content is close to zero; There is no fire hazard simultaneously.
Embodiment
Below in conjunction with embodiment, the present invention is described in further detail, but embodiments of the present invention are not limited to this.
Embodiment 1
(1) 20 parts by weight of deionized water are placed in to container, to add successively 75 weight part rutile titanium whites, 0.6 weight part BP-187 water-based wilkinite (Linan, Zhejiang Ward novel material limited-liability company), 5 Byk Chemie GmbH of weight part wetting dispersing agent BYK191(Germany under the rotating speed stirring at low speed condition of 400 revs/min) and 0.2 weight part defoamer 090(Taiwan De Qian Chemical Co., Ltd.), after stirring, add again 120 weight part granulated glass spherees, to fineness 35 μ m, obtain titanium white mill base with the rotating speed speed lappings of 2000 revs/min;
(2) by 70 weight part water-based fluorocarbon resins (Beijing BY-5607 of Bai Yuan Chemical Co., Ltd. fluorine modification hydroxyl dispersion; Admittedly containing 45%, hydroxy radical content 2.7%) be placed in container, under stirring at low speed condition, add successively 9.7 parts by weight of deionized water, 0.2 Byk Chemie GmbH of weight part flow agent BYK381(Germany), 0.1 weight part defoamer 090(Taiwan De Qian Chemical Co., Ltd.) and 20 weight part step (1) gained titanium white mill bases after, high speed dispersion 15～20 minutes, filter, obtain the white aqueous fluorocarbon coating A of anticorrosion use component.
(3) by 90 weight part water-based isocyanate resins (the Shanghai XD803 of Hao Chang Fine Chemical Co., Ltd solidifying agent; NCO content 12.2%, admittedly containing 70%) be placed in container, under stirring at low speed condition, add successively after 10 parts by weight solvent (N-Methyl pyrrolidone), low speed disperses 10～15 minutes, filters, and obtains anticorrosion use fluorocarbon coating B component.
Use white aqueous fluorocarbon coating to the present embodiment gained is anticorrosion, A component and B component are mixed according to weight ratio 5:1, add a small amount of deionized water, adjust viscosity to 30-60(second/25 DEG C, be coated with 4# cup), carry out making sheet according to GB/T1727-1999 " the general preparation method of paint film " dry.Reference standard HG/T 3792-2005 cross-linking type fluorine resin coating (II type) carries out all round properties inspection, and result is as shown in table 1.
The white aqueous fluorocarbon coating check feature test of the anticorrosion use of table 1 embodiment 1 gained
Embodiment 2
(1) 20 parts by weight of deionized water are placed in to container, to add successively 75 weight part rutile titanium whites, 0.6 weight part water-based wilkinite, 5 Byk Chemie GmbH of weight part wetting dispersing agent BYK191(Germany under the rotating speed stirring at low speed condition of 400 revs/min) and 0.2 weight part defoamer 090(Taiwan De Qian Chemical Co., Ltd.), after stirring, add again 120 weight part granulated glass spherees, to fineness 35 μ m, obtain titanium white mill base with the rotating speed speed lappings of 2000 revs/min;
(2) 54.5 parts by weight of deionized water are placed in to container, to add successively 15 Byk Chemie GmbH of weight part wetting dispersing agent BYK191(Germany under the rotating speed stirring at low speed condition of 400 revs/min), 30 weight part carbon blacks, 0.3 weight part BP-187 water-based wilkinite (Linan, Zhejiang Ward novel material limited-liability company) and 0.2 weight part defoamer 090(Taiwan De Qian Chemical Co., Ltd.), after stirring, add again 120 weight part granulated glass spherees, to fineness 35 μ m, obtain black color paste with the rotating speed speed lappings of 2000 revs/min;
(3) by 70 weight part water-based fluorocarbon resins (Beijing BY-5607 of Bai Yuan Chemical Co., Ltd. fluorine modification hydroxyl dispersion; Admittedly containing 45%, hydroxy radical content 2.7%)) be placed in container, under stirring at low speed condition, add successively 9.7 parts by weight of deionized water, 0.2 Byk Chemie GmbH of weight part flow agent BYK381(Germany), 0.1 weight part defoamer 090(Taiwan De Qian Chemical Co., Ltd.), after 18 weight part step (1) gained titanium white mill bases and 2 weight part step (2) gained black color pastes, high speed dispersion 15～20 minutes, filter, obtain anticorrosion by grey aqueous fluorocarbon coating A component.
(3) by 90 weight part water-based isocyanate resins (bodyguard Quanxing, Wuhan water-based isocyanate solidifying agent UC808; NCO content 14%, admittedly containing 80%) be placed in container, under stirring at low speed condition, add successively after 10 parts by weight solvent N-Methyl pyrrolidone, low speed disperses 10～15 minutes, filters, and obtains anticorrosion use fluorocarbon coating B component.
To the anticorrosion grey aqueous fluorocarbon coating of using of the present embodiment gained, A component and B component are mixed according to weight ratio 5:1, add a small amount of deionized water, adjust viscosity to 30-60(second/25 DEG C, be coated with 4# cup), carry out making sheet according to GB/T1727-1999 " the general preparation method of paint film " dry.Reference standard HG/T 3792-2005 cross-linking type fluorine resin coating (II type) carries out all round properties inspection, and result is as shown in table 1.
Table 2 embodiment 2 gained are anticorrosion with the test of grey aqueous fluorocarbon coating check feature
From prior art (as published patent application) known, what all adopt about water-based fluorocarbon finish paint at present is single-component thermoplastics type or adopts single-component internal emulsification solidifying agent (diacid two hydrazine types) fluorine carbon finishing paint.Wherein single-component thermoplastics type is larger with the poor distance of cross-linking type on water tolerance and acid-proof alkaline, crosslinked emulsification solidifying agent (diacid two hydrazine types) in single-component is although that fluorine carbon finishing paint has is crosslinked, but because cross-linking density is limited, thereby fail to make film self acid-proof alkaline and salt spray resistance to improve a lot.This embodiment is different from other publication technology; What adopt is external crosslinking waterborne curing agent, and its cross-linking density is high, and coating internal cohesive energy is larger, can larger raising film self medium-resistance (seeing the following form).
Existing fluorine carbon finishing paint and the embodiment of the present application 2 are relatively
The invention process result, water-based fluorocarbon antisepsis finishing paint film performance is comparatively approaching compared with solvent-borne type fluorine carbon antisepsis finishing paint, has all reached solvent-borne type fluorine carbon antisepsis finishing paint standard especially at water resistance and acid-proof alkaline, salt spray resistance.Can be used for steel structure anti-corrosion by replace solvents type antisepsis finishing paint completely, its maximum is characterised in that; As solvent, reduce organic solvent emission with deionized water, reduce the pollution to environment.
Embodiment 3
Embodiment 2 gained PET films are applied to preparation application PET film with fluorocarbon coating.The preparation method of described application PET film presses following operation steps:
(1) pre-treatment of steel construction; To steel structure surface sandblasting.
(2) through spraying, roller coating on the steel construction of pre-treatment or brush anticorrosion with zinc rich primer;
(3) dry more than 8 hours under the steel construction normal temperature after coating prime lacquer.
(4) spraying, roller coating or brush anticorrosion with cloud iron intermediate coat on dry zinc rich primer
(5) dry more than 8 hours under the steel construction normal temperature after application intermediate coat
(6) A component and B component are mixed according to weight ratio 5:1, add a small amount of deionized water to adjust viscosity to 30-60(second/25 DEG C, be coated with 4# cup), spraying, roller coating or brush anticorrosion use fluorocarbon coating on dry cloud iron intermediate coat.
Above-described embodiment is preferably embodiment of the present invention; but embodiments of the present invention are not restricted to the described embodiments; other any do not deviate from change, the modification done under spirit of the present invention and principle, substitutes, combination, simplify; all should be equivalent substitute mode, within being included in protection scope of the present invention.
Claims (9)
1. a preparation method for anticorrosion use fluorocarbon coating, described water-repellent preservation comprises A component and B component with coating, its preparation method comprises the following steps:
(1) 20.0～30.0 parts by weight of deionized water are placed in to container, under stirring at low speed condition, add successively 0.3～0.5 weight part anti-settling agent, 5～10 weight part wetting dispersing agents and 15～50 weight part pigment, after stirring, add again 100～120 weight part granulated glass spherees, speed lapping, to fineness 30～35 μ m, obtains mill base;
(2) 60～80 weight part water-based fluorocarbon resins are placed in to container, under stirring at low speed condition, add successively after 5～15 parts by weight of deionized water, 0.1～0.6 weight part flow agent, 0.1～0.3 weight part defoamer and 2～25 weight part step (1) gained mill bases, high speed dispersion 15～20 minutes, filter, obtain anticorrosion use fluorocarbon coating A component;
(3) 70～100 weight part water-based isocyanate resins are placed in to container, add successively after 1～30 parts by weight solvent under stirring at low speed condition, low speed disperses 10～15 minutes, filters, and obtains anticorrosion use fluorocarbon coating B component.
2. the preparation method of a kind of anticorrosion use fluorocarbon coating according to claim 1, is characterized in that: the described wetting dispersing agent of step (1) is BYK191; Described defoamer is 090; Described pigment is carbon black or rutile titanium white; Described anti-settling agent is BP-187 water-based wilkinite; The described flow agent of step (2) is BYK381; Described defoamer is 090; The described solvent of step (3) is N-Methyl pyrrolidone.
3. the preparation method of anticorrosion use fluorocarbon coating according to claim 1, is characterized in that: the rotating speed of the described stirring at low speed of step (1) is 400～500 revs/min; 1000～2000 revs/min of described speed lapping; The rotating speed of the described stirring at low speed of step (2) is 400～500 revs/min; 1000～2000 revs/min of the rotating speeds of described high speed dispersion; The rotating speed of the described stirring at low speed of step (3) is 400～500 revs/min.
4. an anticorrosion use fluorocarbon coating of preparing according to claim 1～3 any one method.
5. anticorrosion use fluorocarbon coating according to claim 4, is characterized in that: the weight ratio of A component and B component is 5:1.
6. the anticorrosion use fluorocarbon coating described in claim 4 or 5 is applied to and prepares steel construction.
7. application according to claim 6, is characterized in that: the preparation method of described application steel construction is by following operation steps:
(1) pre-treatment of steel construction;
(2) through spraying, roller coating on the steel construction of pre-treatment or brush anticorrosion with zinc rich primer;
(3) dry more than 8 hours under the steel construction normal temperature after coating prime lacquer;
(4) spraying, roller coating or brush anticorrosion with cloud iron intermediate coat on dry zinc rich primer;
(5) dry more than 8 hours under the steel construction normal temperature after application intermediate coat;
(6) water-repellent preservation fluorocarbon coating is prepared by the part by weight of A and B component 5:1, added a small amount of deionized water to adjust 60 seconds/25 DEG C of viscosity 30 –, spraying, roller coating or brush anticorrosion use fluorocarbon coating on dry cloud iron intermediate coat.
8. application according to claim 7, is characterized in that: the described pre-treatment of step (1) is that sandblasting is carried out in the surface of steel construction.
9. application according to claim 6, is characterized in that: described application steel construction is the steel construction in bridge, chemical industry equipment, building or road equipment.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410272338.2A CN104119738A (en) | 2014-06-19 | 2014-06-19 | Waterborne fluorocarbon coating for corrosion prevention as well as preparation method and application thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410272338.2A CN104119738A (en) | 2014-06-19 | 2014-06-19 | Waterborne fluorocarbon coating for corrosion prevention as well as preparation method and application thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN104119738A true CN104119738A (en) | 2014-10-29 |
Family
ID=51765384
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410272338.2A Pending CN104119738A (en) | 2014-06-19 | 2014-06-19 | Waterborne fluorocarbon coating for corrosion prevention as well as preparation method and application thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104119738A (en) |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109603305A (en) * | 2019-01-10 | 2019-04-12 | 河南德源净化装备有限公司 | A kind of production method of the sintered metal mesh of filtering corrosion resistance |
| CN109762455A (en) * | 2019-02-01 | 2019-05-17 | 赵娜 | Aqueous weather-proof anticorrosive paint of one kind and preparation method thereof |
| CN110003734A (en) * | 2019-03-08 | 2019-07-12 | 嘉宝莉化工集团股份有限公司 | A kind of extra-weather-proof, resistant aqueous double-component fluorine carbon building external paint and preparation method thereof |
| CN110229601A (en) * | 2019-05-30 | 2019-09-13 | 江门市威富科技有限公司 | Fluorocarbon coating and preparation method thereof and coating process |
| CN110423546A (en) * | 2019-02-13 | 2019-11-08 | 青岛润昊氟碳材料有限公司 | A kind of anticorrosion of steel structure aqueous fluorocarbon coating and production and preparation method thereof |
| CN110423545A (en) * | 2019-02-13 | 2019-11-08 | 青岛润昊氟碳材料有限公司 | A kind of aluminum profile anti-corrosion aqueous fluorocarbon coating and production and preparation method thereof |
| CN114292560A (en) * | 2022-01-12 | 2022-04-08 | 上海船舶工艺研究所(中国船舶工业集团公司第十一研究所) | High-durability water-based fluorocarbon paint and preparation method thereof |
| CN116478582A (en) * | 2023-03-30 | 2023-07-25 | 珠海市氟特科技有限公司 | Waterborne thermosetting ether FEVE fluorine coating, preparation method and aluminum metal substrate |
| CN117210080A (en) * | 2023-10-19 | 2023-12-12 | 青岛中氟氟碳材料有限公司 | Preparation method and application of anti-pollution water-based paint for inner wall of high-speed rail |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0173071A2 (en) * | 1984-07-25 | 1986-03-05 | Daikin Kogyo Co., Ltd. | Aqueous coating composition of fluorocarbon resin |
| CN101117483A (en) * | 2007-09-11 | 2008-02-06 | 东莞市英科水墨有限公司 | Aqueous fluorine-carbon paint and method for making same |
| CN101397435A (en) * | 2008-07-10 | 2009-04-01 | 上海三银制漆有限公司 | Environment friendly water-soluble metal fluorocarbon coatings |
| CN101717600A (en) * | 2009-12-23 | 2010-06-02 | 山西北辰涂料有限公司 | Single-component aqueous fluorocarbon paint and preparation method thereof |
| CN103483943A (en) * | 2013-09-30 | 2014-01-01 | 东来涂料技术（上海）有限公司 | Water-based corrosion-resistant decorative fluorocarbon paint and preparation method thereof |
-
2014
- 2014-06-19 CN CN201410272338.2A patent/CN104119738A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0173071A2 (en) * | 1984-07-25 | 1986-03-05 | Daikin Kogyo Co., Ltd. | Aqueous coating composition of fluorocarbon resin |
| CN101117483A (en) * | 2007-09-11 | 2008-02-06 | 东莞市英科水墨有限公司 | Aqueous fluorine-carbon paint and method for making same |
| CN101397435A (en) * | 2008-07-10 | 2009-04-01 | 上海三银制漆有限公司 | Environment friendly water-soluble metal fluorocarbon coatings |
| CN101717600A (en) * | 2009-12-23 | 2010-06-02 | 山西北辰涂料有限公司 | Single-component aqueous fluorocarbon paint and preparation method thereof |
| CN103483943A (en) * | 2013-09-30 | 2014-01-01 | 东来涂料技术（上海）有限公司 | Water-based corrosion-resistant decorative fluorocarbon paint and preparation method thereof |
Cited By (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109603305A (en) * | 2019-01-10 | 2019-04-12 | 河南德源净化装备有限公司 | A kind of production method of the sintered metal mesh of filtering corrosion resistance |
| CN109762455B (en) * | 2019-02-01 | 2021-03-30 | 赵娜 | Water-based weather-resistant anticorrosive paint and preparation method thereof |
| CN109762455A (en) * | 2019-02-01 | 2019-05-17 | 赵娜 | Aqueous weather-proof anticorrosive paint of one kind and preparation method thereof |
| CN110423546B (en) * | 2019-02-13 | 2021-07-02 | 青岛中氟氟碳材料有限公司 | Water-based fluorocarbon coating for corrosion prevention of steel structure and preparation method thereof |
| CN110423546A (en) * | 2019-02-13 | 2019-11-08 | 青岛润昊氟碳材料有限公司 | A kind of anticorrosion of steel structure aqueous fluorocarbon coating and production and preparation method thereof |
| CN110423545A (en) * | 2019-02-13 | 2019-11-08 | 青岛润昊氟碳材料有限公司 | A kind of aluminum profile anti-corrosion aqueous fluorocarbon coating and production and preparation method thereof |
| CN110423545B (en) * | 2019-02-13 | 2021-07-02 | 青岛中氟氟碳材料有限公司 | Water-based fluorocarbon coating for corrosion prevention of aluminum profile and preparation method thereof |
| CN110003734A (en) * | 2019-03-08 | 2019-07-12 | 嘉宝莉化工集团股份有限公司 | A kind of extra-weather-proof, resistant aqueous double-component fluorine carbon building external paint and preparation method thereof |
| CN110229601A (en) * | 2019-05-30 | 2019-09-13 | 江门市威富科技有限公司 | Fluorocarbon coating and preparation method thereof and coating process |
| CN110229601B (en) * | 2019-05-30 | 2021-11-30 | 江门市威富科技有限公司 | Fluorocarbon coating and preparation method and coating method thereof |
| CN114292560A (en) * | 2022-01-12 | 2022-04-08 | 上海船舶工艺研究所(中国船舶工业集团公司第十一研究所) | High-durability water-based fluorocarbon paint and preparation method thereof |
| CN114292560B (en) * | 2022-01-12 | 2024-01-05 | 上海船舶工艺研究所(中国船舶集团有限公司第十一研究所) | High-durability water-based fluorocarbon paint and preparation method thereof |
| CN116478582A (en) * | 2023-03-30 | 2023-07-25 | 珠海市氟特科技有限公司 | Waterborne thermosetting ether FEVE fluorine coating, preparation method and aluminum metal substrate |
| CN116478582B (en) * | 2023-03-30 | 2024-04-09 | 珠海市氟特科技有限公司 | Waterborne thermosetting ether FEVE fluorine coating, preparation method and aluminum metal substrate |
| CN117210080A (en) * | 2023-10-19 | 2023-12-12 | 青岛中氟氟碳材料有限公司 | Preparation method and application of anti-pollution water-based paint for inner wall of high-speed rail |
| CN117210080B (en) * | 2023-10-19 | 2024-03-29 | 青岛中氟氟碳材料有限公司 | Preparation method and application of anti-pollution water-based paint for inner wall of high-speed rail |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104119738A (en) | Waterborne fluorocarbon coating for corrosion prevention as well as preparation method and application thereof | |
| CN108003713B (en) | Water-based marking paint and preparation method and construction method thereof | |
| CN102675998B (en) | Water-based fluorocarbon top coat for wind-powered blades and method for preparing water-based fluorocarbon top coat | |
| CN106479354B (en) | A kind of antifouling anticorrosive nano polysiloxane coating materials of primer-topcoat in one and preparation method thereof | |
| CN103773175B (en) | A kind of environmental friendly, anti-corrosive aqueous priming paint coating and preparation method thereof | |
| CN105086823A (en) | Organosilicone room-temperature-cured anticorrosive coating material | |
| CN103788787A (en) | Single-component water-based natural drying finishing coat for construction crane and preparation method thereof | |
| CN102020904A (en) | Low-temperature quick-drying waterborne metal anti-corrosive coating and preparation method thereof | |
| CN107189638A (en) | Watersoluble plumbago alkene anticorrosive paint | |
| CN102993810A (en) | General water-based quick-drying anti-rust paint and preparation method thereof | |
| CN106366851A (en) | Epoxy ester dip-coating water based paint and preparation method thereof | |
| CN101104764A (en) | Double-anticorrosion paint for steel and preparing method thereof | |
| CN104804633B (en) | A kind of low-temperature quick-drying type acroleic acid polyurethane coating and preparation method thereof | |
| CN109181486B (en) | Low-VOC epoxy primer and preparation method thereof | |
| CN107916024B (en) | Water-based normal-temperature ultrafast-drying workshop precoated primer and preparation method and application thereof | |
| CN103146289A (en) | Powder coating with performances of self-cleaning, heavy corrosion protection and super weather resistance and preparation method and application thereof | |
| CN103666201A (en) | Long-acting acid-base resistant solvent-free anticorrosive paint as well as preparation method and application thereof | |
| CN111019425A (en) | Water-based bi-component epoxy paint and preparation method thereof | |
| CN109401564B (en) | High-weather-resistance hydrophobic self-cleaning metal curtain wall plate and preparation method thereof | |
| CN101463219A (en) | Preparation of fluorine-containing aqueous crackle lacquer and coating method thereof | |
| CN110157333A (en) | A kind of water-based anticorrosive paint and preparation method thereof | |
| CN104017451A (en) | Water-based anticorrosive finish paint for vehicle plate springs and chassis | |
| CN109181473A (en) | A kind of high-performance dual-component aqueous anticorrosive paint and preparation method thereof | |
| CN109535901B (en) | Water impact resistant dark gray conductive primer for electrostatic coating and preparation method thereof | |
| CN113698859A (en) | High-weather-resistance polyurethane anticorrosive paint and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20141029 |