CN103006502B - Hair-dying method, a set of hairdye for the method, and treatment agent for hair - Google Patents
Hair-dying method, a set of hairdye for the method, and treatment agent for hair Download PDFInfo
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- CN103006502B CN103006502B CN201210334862.9A CN201210334862A CN103006502B CN 103006502 B CN103006502 B CN 103006502B CN 201210334862 A CN201210334862 A CN 201210334862A CN 103006502 B CN103006502 B CN 103006502B
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/41—Amines
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/49—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/96—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
- A61K8/97—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution from algae, fungi, lichens or plants; from derivatives thereof
- A61K8/9783—Angiosperms [Magnoliophyta]
- A61K8/9789—Magnoliopsida [dicotyledons]
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/10—Preparations for permanently dyeing the hair
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Abstract
Provided are a hair-dying method, a set of hairdye for the method, and treatment agent for hair. The purpose of the invention aims at providing a hair-dying method capable of maintaining long-time color retention even basic dyestuff is used as basic hairdye. The hair-dying method is characterized by comprising following processes of a first process, a second process, and a third process. In the first process, the basic hairdye containing dye is coated on hair and is laid for a given time. In the second process, the hair coated with the basic hairdye liquid is cleaned. In the third process, after the second process, the hair is coated with catechinic acid aqueous solution and is laid for a given time.
Description
Technical field
The present invention relates to hair colouring methods, for hair dye suit and the hair nursing agent of this hair colouring methods.Specifically, even if relate to, use basic stain etc. as basic stain, also can maintain hair dye suit and the hair nursing agent of high colourability (long-lasting color).
Background technology
In recent years, be widely used the hair dye containing as the p-phenylenediamine (PPD) system of synthetic dyestuffs or the oxidation dye of amino-phenol system.The hue preserving of the hair dye that contains oxidation dye after hair dyeing is excellent, and can show colorful tone.
Yet known oxidation dye can cause dermatosis.In addition be that ecosystem is caused the censure of dysgenic environmental hormone and then is suspected to have carcinogenecity or causes the censure of anaphylaxis etc. in addition.Thus, the hair dye that contains oxidation dye becomes restriction object on Europe and other places.
On the other hand, as the dyestuff composition of hair dye, known have the safety of being noted than the high HC dyestuff of oxidation dye or basic stain etc.All the time, basic stain and HC dyestuff for example as take hair nial polish (hair manicure) that the hue preserving of about 2～3 weeks is object, by 1 week, with several, continue to give the hair dyeing and care plain (color conditioner) of color or nursing agent (colortreatment) use of having hair dyed.For example, in following patent documentation 1, as having the two the whole hair composition of hair dyeing of effect and hair dyeing effect of haircuting concurrently, disclosing, contain the i.e. whole hair composition of hair dyeing of hair dyeing property pigment and at least one alpha-hydroxy acid ester and/or at least one dialkyl carbonate and at least one cross linked polymer of at least one dyestuff of selecting in the group that free HC dyestuff, basic stain, disperse dyes and natural pigment form or pigment.
Prior art document
Patent documentation
Patent documentation 1: TOHKEMY 2005-213212 communique
Summary of the invention
Invent problem to be solved
Basic stain or HC dyestuff be noted compare with oxidation dye safe.Yet, basic stain or HC dyestuff dye on hair on the ground owing to not there is not chemical reaction, so exist the hue preserving (retain a color) after hair dyeing poor, by repeatedly have one's hair wash (shampoo) etc. and the shortcoming of easily fade (colorfailure).Therefore, as mentioned above, thereby as take hair nial polish that the hue preserving of about 2～3 weeks is object or by 1 week with continuing for several times to give hair dyeing and care element or the hair dyeing nursing agent that color maintains color, although also can use in practical the such usage of the permanent hair dye of what is called that the hue preserving of not attempting for example take over 1 month is object.
The object of the invention is to, provide and use the basic stain that contains basic stain or HC dyestuff, can maintain the hair colouring methods of the long hue preserving approaching with permanent hair dye.
For the method for dealing with problems
Hair colouring methods of the present invention is characterised in that, it possesses following operation: the basic dye liquid of basic stain or HC dyestuff etc. is applied on hair and places the first operation of stipulated time; Second operation of rinsing being coated with the hair of basic dye liquid; After the second operation, on hair, be coated with tea catechin aqueous solution and place the 3rd operation of stipulated time.According to such hair colouring methods, even if use basic stain or HC dyestuff etc. as basic stain, also can maintain for a long time hue preserving.Think that effect of the present invention, in repeating the process of many experiments, proves effective with mechanism as described below.For example, in the first operation, by the basic dye liquid that contains basic stain or HC dyestuff is applied on hair, thereby basic stain or HC dyestuff adhere to or are penetrated in hair.And, after rinsing, in the 3rd operation, be coated with tea catechin aqueous solution in the second operation.Thereby think the tea catechin being coated with in the 3rd operation to contact with airborne oxygen and oxidation polymerization occurs to form tunicle, thereby adhere to or the basic stain or the HC dyestuff that are penetrated in hair are dyed more strongly surely.And tea catechin is difficult for being impacted by the color of basic stain or the toning of HC dyestuff.
In addition,, in the 3rd operation, when the hair that is coated with tea catechin aqueous solution is placed to official hour, preferably irradiate far infrared.By irradiating far infrared, thereby hue preserving further improves.Think this chances are for applying while processing, before tea catechin aqueous solution is rinsed out, as the tea catechin of polyphenol, be activated and promote the polyreaction of tea catechin.
In addition, basic dye liquid contains alkaline reducer and pH is 7.5～9 o'clock, and due to hair generation alkali swelling, thereby basic stain or HC dyestuff are easily penetrated in hair, and consequently, hue preserving improves more, is preferred from this starting point.
In addition, hair dye of the present invention suit is the hair dye suit using in order to carry out above-mentioned hair colouring methods, is using for modulating the containing as the basic dye of the basic stain of main constituent and the hair dye suit that forms for the powder combinations that contains tea catechin of brew tea catechin aqueous solution of basic dye liquid.Hair dye suit according to such, can easily carry out above-mentioned hair colouring methods.
Invention effect
According to the present invention, though can provide use basic stain or HC dyestuff as basic stain, also can maintain the hair colouring methods of long-time hue preserving.
The specific embodiment
An embodiment for hair colouring methods of the present invention, is below elaborated.
The hair colouring methods of present embodiment for example possesses following operation: will contain as the basic stain of dyestuff main constituent and the basic dye liquid of the HC dyestuff using is as required applied on hair, place the first operation of stipulated time; Second operation of rinsing being coated with the hair of basic dye liquid; After the second operation, on hair, be coated with tea catechin aqueous solution, place the 3rd operation of stipulated time.
First the first operation is described.
The first operation is to contain as the basic stain of dyestuff main constituent and the basic dye liquid of the HC dyestuff using as required is not omitted the operation of the part of wanting hair dyeing that is applied to hair.
Basic stain is in molecule, have amino or substituted-amino and in aqueous solution, become cationic dyestuff, can be not particularly limited to use all the time as the known dyestuff of basic stain.Basic stain is owing to becoming cation in aqueous solution, thus by the keratic negativity with hair surface partly carry out ionic bonding and on dye.As its object lesson, for example can list Blue 7 (C.i.42595), alkali blue 16(C.I.12210), alkali blue 22(C.I.61512), alkali blue 26 (C.I.44045), alkali blue 99(C.I.56059), alkali blue 117, alkaline purple 1 0(C.I.45170), basic violet 14 (C.I.42515), bismarck brown 16(C.I.12250), bismarck brown 17(C.I.12251), the red 2(C.I.50240 of alkalescence), alkali red 1:1 2(C.I.48070), the red 22(C.I.11055 of alkalescence), alkalescence red 51, the red 76(C.I.12245 of alkalescence), alkali red 1:1 18(C.I.12251:1), Basic Orange 31, Basic Yellow 28 (C.I.48054), basic yellow 57(C.I.12719), basic yellow 87, basic black 2(C.I.11825) etc.They may be used alone, or two or more kinds may be used in combination.
HC dyestuff is knownly to have " HC " as the dyestuff of prefix, owing to being the dyestuff that molecular diameter is less, so the inside that is penetrated into hair by hydrogen bond or intermolecular attraction and on dye, give darker colour developing.As its object lesson, such as listing the red No.1 of HC blue No.2, HC blue No.8, HC orange No.1, HC orange No.2, HC, the red No.3 of HC, the red No.7 of HC, the red No.8 of HC, the red No.10 of HC, the red No.11 of HC, the red No.13 of HC, the yellow No.12 of yellow No.9, the HC of yellow No.7, HC of yellow No.6, HC of yellow No.5, HC of yellow No.2, HC of purple No.2, HC of the red No.16 of HC, HC etc.They may be used alone, or two or more kinds may be used in combination.
The ratio of basic stain and HC dyestuff is not particularly limited, but the ratio of HC dyestuff in the total amount of basic stain and HC dyestuff is preferably 1～30 quality %, more preferably 5～20 quality % left and right.
By hair generation alkali swelling, make basic stain and HC dyestuff easily be penetrated in hair, from this starting point, preferred basic dye liquid has alkalescence, particularly has the alkalescence of pH7.5～9 and then 8～8.5 left and right, in order to be adjusted into such fluidity, basic dye liquid preferably contains alkaline agent.As the object lesson of such alkaline agent, such as listing the alkaline reducers such as acetylcysteine, cysteamine, mercaptoethanol acid, ammonia, various alkanolamine, ammonium salt, organic amine, inorganic base, basic amino acid and their salt etc.In the middle of these, particularly, when the alkaline reducer that uses the alkaline reducer of acetylcysteine, cysteamine, mercaptoethanol acid or acetylcysteine, cysteamine and mercaptoethanol acid are combined, exist dyestuff more easily to enter the tendency of hair.They can distinguish use separately, also two or more can be used in combination.Alkaline reducer preferably contains 0.01～1 quality % in basic dye liquid, further preferably contains 0.1～0.5 quality %.
Basis dye liquid is such as by basic stain, the HC dyestuff using as required, the alkaline agent that uses as required etc., the ratio with regulation coordinates, be mixed into all the time in the liquid mediums such as cream frost base that the medium as hair dye composition uses and be modulated into pasty state or aqueous solution, be applied on hair.In addition, as cream frost base material, such as being not particularly limited to use the white base of cream that emulsifying agents such as the lubricant components such as spermol, stearyl alcohol, octyl dodecanol, oleyl alcohol, isooctadecanol, mineral oil, decyl oleate, the different stearyl ester of myristic acid, isopropyl palmitate, triglyceride (ト リ グ リ セ リ Le) and polyoxyethylene laurel ether, lauric acid sorbitan, CETETH-2, OLETH-10, CETEARETH-20 etc. is suitably coordinated and obtain.
As the concentration of the basic stain containing in basic dye liquid and HC dyestuff, in the total amount of basic stain and HC dyestuff, in paste or aqueous solution, be preferably 0.5～10 quality %, more preferably 1～5 quality %.
The hair that is coated with basic dye liquid is placed official hour.The time of placing is suitably adjusted according to the kind of the hobby of color that hair is given or the dyestuff of use, but from the viewpoint of operation sequence, conventionally preferably places 5～60 minutes, further preferably places 10～30 minutes.In addition,, when placing, preferably to being coated with the hair of basic dye liquid, do not irradiate far infrared with omitting.By hair is irradiated to far infrared, standing time can be shortened.The temperature of the hair surface during as far-infrared radiation, never can damage hair or cause the aspect of excessive burden to set out to human body, is preferably 20～40 ℃, more preferably the temperature of 25～35 ℃ of left and right.
The second operation is to having placed that the hair of the basic dye liquid of being coated with of official hour rinses and the operation that washes away basic dye liquid.
As long as rinse and can wash out the basic dye liquid adhering on hair, its method is not particularly limited, and does not preferably use shampoo, the water of water or tepor to wash out basic dye liquid.After washing out, conventionally towel off dry.
The 3rd operation is on the hair after flushing, to be coated with tea catechin aqueous solution, and places the operation of stipulated time.Tea catechin is difficult for, on being brought impact by the color of basic stain or the toning of HC dyestuff, in addition, being difficult for becoming anaphylactogen.As the object lesson of tea catechin, such as the tea catechin etc. that can list the mixture of any one or they contained in epicatechin, epigallocatechin, epicatechin Gallate catechu ester, epigallocatechin Gallate catechu ester.In addition, tea catechin aqueous solution also can contain other polyphenol.As the object lesson of polyphenol, such as listing flavonoid class (catechin, anthocyanidin, flavone, isoflavone, flavane, flavanone, Lu Ding), phenolic acids (chlorogenic acid, ellagic acid, gallic acid, propyl gallate), lignanoids, curcumin, Coumarins etc.In addition, these compounds, due in the extract being included in a large number from following such natural goods, coordinate so also can be used as extract.They may be used alone, or two or more kinds may be used in combination.In addition, the pigment of Flos Impatientis polyphenol or Folium et Caulis Indigoferae Tinctoriae polyphenol is due to denseer, so there is the tendency that changes the color of mixing colours on bringing impact by the color that basic stain and the toning of HC dyestuff form.
Aqueous solution or aqueous dispersions that tea catechin aqueous solution is modulated into tea catechin are pasty state, then, are applied on hair.As tea catechin aqueous solution, such as the aqueous solution or the dispersion liquid that use the tea powder ends such as green tea powder.Tea catechin is proportional being not particularly limited that contain in paste at aqueous solution or aqueous dispersions, particularly, for example, in tea amount of powder, is preferably 5～20 quality %, more preferably 10～15 quality %.In addition, in tea catechin aqueous solution, in not damaging the scope of effect of the present invention, can coordinate as required the bromic acid of conduct hair dyeing oxidant use etc., while coordinating bromic acid, there is the tendency of the oxidative polymerization that hinders polyphenol, so, as long as no special object, preferably mismatch as far as possible the hair dyeing oxidants such as bromic acid.
By coating tea catechin aqueous solution, and place official hour, thereby the basic stain or the HC dyestuff that adhere to or be penetrated in hair are dyed more strongly surely.The mechanism of its effect is not fully found out, but the most experiments result by inventor can be thought, active much higher phenol is that tea catechin, by airborne oxygen, oxidation polymerization etc. occurs, thereby form to cover, adhere to or be penetrated into basic stain in hair or the tunicle of HC dyestuff, utilize this tunicle, suppress through time fade.Thereby this also can be from particularly increasing this phenomenon and infer such mechanism by irradiate far infrared effect placement.That is, after coating tea catechin aqueous solution, by hair is irradiated to far infrared, thus further suppress through time fade.
Condition as far-infrared radiation, temperature as hair surface, be 20～40 ℃ and then be the temperature of 25～35 ℃ of left and right, irradiate 10～60 minutes and then 15～30 minutes, this is excellent from operating efficiency, can not damage hair or human body is caused to the aspect of excessive burden be also preferred.In addition, after far-infrared radiation, by placing official hour, thereby further suppress to fade.
And, to coating tea catechin aqueous solution and place official hour, preferably irradiate far infrared and the hair placed, implement the hair washing of ending and wash out tea catechin aqueous solution, thereby obtain dyed hair.After washing out, towel off dry and carry out aeration-drying etc.Like this, the hair dyeing that completes hair is processed.
Even if hair colouring methods of the present invention is used the HC dyestuff of basic stain and cooperation as required as basic stain, also can realize for example maintaining of the long hue preserving more than 1 month and then more than 2 months.In addition, due to the HC dyestuff that uses basic stain and coordinate as required as basic stain, so excellent in safety.Therefore, even, also can feel at ease to use while dying poliosis etc. prolonged and repeated.
Embodiment
Below, by embodiment, the present invention is described in more detail.In addition, scope of the present invention is not subject to any restriction of the present embodiment.
(embodiment 1)
Usining in the cream frost base material of spermol as main constituent, the basic stain 50g of the dye mixture 5 quality % that the ratio being mixed with 9:1 is contained to basic stain and HC dyestuff and contain acetylcysteine and the mixture of cysteamine and mercaptoethanol acid is that the alkaline agent 50g of alkaline reducer 1 quality % mixes, modulates basic dye liquid.
Then on the hair bundle being formed by Crinis Carbonisatus that, at one end the gross weight of harness is 10g, be coated with modulated basic dye liquid.In addition, the major part of all Crinis Carbonisatus of formation hair bundle is poliosis.
Then, the hair bundle that is coated with basic dye liquid was placed after 10 minutes, irradiated approximately 15 minutes far infrareies.Now, the temperature of hair bundle is 30 ℃ of left and right.Then, the poliosis of confirming hair bundle do not omit be dyed to dark brown after, water washes out the basic dye liquid adhering on hair bundle.Then, with towel, fully dry moisture.
Then, green tea powder (the お tea カ ラ mono-ト リ mono-ト メ Application ト powder of (strain) ITCB Global system) 25g is dissolved in the water 175g of tepor to brew tea catechin aqueous solution.Then, modulated tea catechin aqueous solution is applied on hair bundle.Then, the hair bundle that is coated with tea catechin aqueous solution was placed after 10 minutes, irradiated approximately 20 minutes far infrareies.Now, the temperature of hair bundle is 30 ℃ of left and right.Then, further naturally place approximately 10 minutes.
Then, hair bundle is had one's hair wash with commercially available shampoo.Then, with towel, fully dry moisture.
In addition, in above-mentioned hair dyeing, by the roughly only length of half hair dyeing of hair bundle, remaining half be hair dyeing not.
Only obtain like this hair bundle that half length is had hair dyed.
Then, to had hair dyed hair bundle, implement 1 hair washing every day, the color of the part that there is no hair dyeing of take is carried out the observation of rheological parameters' change with time to hair dyeing change color partly as benchmark.Consequently, even through 2 months, dark brown dyestuff does not fade yet and remains in the part of hair dyeing, and the part of hair dyeing is residual significantly with the border of the color of the part that does not have to have hair dyed.In addition, when the women commentator of more than 70 year old implement is processed with same processes, the poliosis part of the root growing obviously observing when implementing to process before 2 months with 2 months before the portion boundary of hair dyeing.
(comparative example 1)
Except not being coated with the processing of tea catechin aqueous solution, similarly to Example 1 hair bundle is had hair dyed.That is, similarly to Example 1, on hair bundle, be coated with basic dye liquid, the hair bundle that is coated with basic dye liquid was placed after 10 minutes, irradiate approximately 15 minutes far infrareies.Then, the poliosis of confirming hair bundle do not omit dye dark brown after, water washes out the basic dye liquid adhering on hair bundle, and then, with commercially available shampoo, have one's hair wash.Then, with towel, fully dry moisture.In addition, in above-mentioned hair dyeing, also, by the roughly only length of half hair dyeing of hair bundle, remaining half be hair dyeing not.Only obtain like this hair bundle that half length is had hair dyed.
Then, to had hair dyed hair bundle, implement 1 hair washing every day, the color of the part that there is no hair dyeing of take is carried out the observation of rheological parameters' change with time to hair dyeing change color partly as benchmark.Consequently, during through approximately 3 weeks, the part of hair dyeing is faded, and the part of hair dyeing obviously becomes not distinct with the border of the color of the part that does not have to have hair dyed.
(comparative example 2)
To with the ratio of 1:1, mix with same basic dye liquid and the tea catechin aqueous solution of modulation in embodiment 1.Then, on the hair bundle being formed by Crinis Carbonisatus that at one end gross weight of harness is 10g, be coated with modulated intermixture.In addition, the major part of all Crinis Carbonisatus of formation hair bundle is poliosis.
Then, the hair Shu Ziran that is coated with intermixture was placed after 10 minutes, irradiate approximately 20 minutes far infrareies.Then, further naturally place approximately 10 minutes.Then, by commercially available shampoo hair washing for hair bundle.Then, with towel, fully dry moisture.Only obtain like this hair bundle that half length is had hair dyed.
Then, to had hair dyed hair bundle, implement 1 hair washing every day, the color of the part that there is no hair dyeing of take is that benchmark observes the variation of hair dyeing color partly.Consequently, during through approximately 3 weeks, the part of hair dyeing is faded, and the part of hair dyeing obviously becomes not distinct with the border of the color of the part that does not have to have hair dyed.From this result, even by basic dye liquid and tea catechin aqueous solution coating, also cannot maintain fully hue preserving.
(embodiment 2)
The hair bundle that is coated with tea catechin aqueous solution was placed after 10 minutes, do not irradiated the far infrared of approximately 20 minutes but the hair Shu Ziran that is coated with tea catechin aqueous solution is placed 30 minutes, in addition, similarly to Example 1 hair bundle is had hair dyed.That is, the tea catechin aqueous solution of modulation is similarly to Example 1 applied to hair Shu Shanghou, the hair Shu Ziran that is coated with tea catechin aqueous solution is placed 30 minutes, further naturally place approximately 10 minutes.
Then, by commercially available shampoo hair washing for hair bundle.Then, with towel, fully dry moisture.Except above-mentioned operation, by the hair dyeing of hair bundle, evaluate similarly to Example 1.Consequently, through approximately 2 months time, the part of hair dyeing is faded a little.But the part of hair dyeing is clearly distinguished to a certain extent with the border of the color of the part that does not have to have hair dyed.Its result is compared with the result of embodiment 1, and known by irradiating far infrared, the effect of hue preserving improves.
(comparative example 3)
Replace coating tea catechin aqueous solution, use by Flos Impatientis powder 25g being dissolved into the Flos Impatientis aqueous solution of modulating in water 175g, be coated with the processing of Flos Impatientis aqueous solution, in addition, by the hair dyeing of hair bundle, evaluate similarly to Example 1.Consequently, even through 1 month, the dyestuff of postfermented tea color does not fade yet and remains in the part of hair dyeing, and the part of hair dyeing is obvious with the border of the color of the part that does not have to have hair dyed.
Utilizability in industry
While using hair colouring methods of the present invention to have hair dyed, even if use basic stain or HC dyestuff as basic stain, also can maintain long hue preserving.Therefore the succedaneum that, can be used as the what is called " permanent hair dye " of not take hair dyeing that the hue preserving of short-term is object but can maintain long-term hue preserving is used.
Claims (8)
1. a hair colouring methods, is characterized in that, possesses following operation:
Basic dye liquid is applied on hair and places the first operation of stipulated time;
Second operation of rinsing being coated with the hair of described basic dye liquid;
After described the second operation, on hair, be coated with tea catechin aqueous solution and place the 3rd operation of stipulated time,
Described basic dye liquid contains basic stain as dyestuff main constituent.
2. hair colouring methods according to claim 1, wherein, described basic dye liquid further contains HC dyestuff.
3. hair colouring methods according to claim 1, wherein, described basic dye liquid contains alkaline reducer, and pH is 7.5～9.
4. hair colouring methods according to claim 3, wherein, described alkaline reducer contains at least one selecting in the group that free acetylcysteine, cysteamine and mercaptoethanol acid forms.
5. hair colouring methods according to claim 1, wherein, while placing official hour in described the 3rd operation, irradiates far infrared to described hair.
6. hair colouring methods according to claim 1, wherein, described tea catechin aqueous solution is the aqueous solution at tea powder end.
7. hair colouring methods according to claim 1, wherein, the aqueous solution that described tea catechin aqueous solution is green tea powder.
8. hair colouring methods according to claim 7, wherein, described tea catechin aqueous solution is the aqueous solution of the green tea powder that contains 5～20 quality %.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP209097/2011 | 2011-09-26 | ||
| JP2011209097A JP4993396B1 (en) | 2011-09-26 | 2011-09-26 | Hair dyeing method and hair dye set used for the hair dyeing method |
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| CN103006502A CN103006502A (en) | 2013-04-03 |
| CN103006502B true CN103006502B (en) | 2014-10-08 |
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| CN201210334862.9A Expired - Fee Related CN103006502B (en) | 2011-09-26 | 2012-09-11 | Hair-dying method, a set of hairdye for the method, and treatment agent for hair |
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| JP (1) | JP4993396B1 (en) |
| KR (1) | KR101453159B1 (en) |
| CN (1) | CN103006502B (en) |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| JP5991513B2 (en) * | 2012-04-02 | 2016-09-14 | 株式会社Ｉｃｔｂグローバル | Hair coloring method for gray hair |
| JP5606590B1 (en) * | 2013-05-27 | 2014-10-15 | 株式会社Ｉｃｔｂグローバル | Hair coloring agent and hair dyeing method |
| CN105592839B (en) * | 2014-09-11 | 2017-10-20 | Ictb全球株式会社 | Hair colourant and hair colouring methods |
| CN105534785B (en) * | 2015-12-28 | 2018-11-02 | 肇庆迪彩日化科技有限公司 | A kind of colouring compositions containing natural plant composition |
| JP6856265B2 (en) * | 2018-04-26 | 2021-04-07 | 株式会社Ｒｉｓｉｎｇ Ｄｏｏｒ | Hair dyeing method and hair dyeing set |
| JP7288689B2 (en) * | 2018-10-18 | 2023-06-08 | 株式会社サニープレイス | Hair coloring agent composition |
| JP7065518B2 (en) * | 2019-01-16 | 2022-05-12 | 株式会社サニープレイス | Hair coloring composition |
| JP7004682B2 (en) * | 2019-01-16 | 2022-01-21 | 株式会社サニープレイス | Hair color method |
| JP2022519111A (en) * | 2019-02-01 | 2022-03-18 | エルジー ハウスホールド アンド ヘルスケア リミテッド | Formulation for hair dyeing |
| KR102086071B1 (en) | 2019-02-01 | 2020-03-06 | 주식회사 엘지생활건강 | Hair-dye product |
| KR20230168956A (en) | 2022-06-08 | 2023-12-15 | 주식회사 엘지생활건강 | Composition for hair dye |
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| CN100374101C (en) * | 2002-11-27 | 2008-03-12 | 株式会社资生堂 | Hair dye composition |
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| JPH08291027A (en) * | 1995-04-18 | 1996-11-05 | Kanebo Ltd | Hair cosmetic |
| JP2003089618A (en) * | 2001-09-18 | 2003-03-28 | Lion Corp | Hair cosmetic |
| KR100872898B1 (en) | 2007-04-27 | 2008-12-10 | 김경숙 | Composition for hair color having an extract of green tea |
| JP2010132596A (en) * | 2008-12-04 | 2010-06-17 | M & Smart:Kk | Hair dyeing composition, and method for dyeing hair by using the same |
| JP5548382B2 (en) * | 2009-04-14 | 2014-07-16 | 資生ケミカル株式会社 | Hair dyeing method |
| KR101510486B1 (en) * | 2009-11-30 | 2015-04-10 | (주)아모레퍼시픽 | Hair dye composition comprising catechin |
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| CN100374101C (en) * | 2002-11-27 | 2008-03-12 | 株式会社资生堂 | Hair dye composition |
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| KR20130033291A (en) | 2013-04-03 |
| JP2013067597A (en) | 2013-04-18 |
| KR101453159B1 (en) | 2014-10-27 |
| CN103006502A (en) | 2013-04-03 |
| JP4993396B1 (en) | 2012-08-08 |
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