CN103006502A - Hair-dying method, a set of hairdye for the method, and treatment agent for hair - Google Patents
Hair-dying method, a set of hairdye for the method, and treatment agent for hair Download PDFInfo
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- CN103006502A CN103006502A CN2012103348629A CN201210334862A CN103006502A CN 103006502 A CN103006502 A CN 103006502A CN 2012103348629 A CN2012103348629 A CN 2012103348629A CN 201210334862 A CN201210334862 A CN 201210334862A CN 103006502 A CN103006502 A CN 103006502A
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/41—Amines
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/49—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/96—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
- A61K8/97—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution from algae, fungi, lichens or plants; from derivatives thereof
- A61K8/9783—Angiosperms [Magnoliophyta]
- A61K8/9789—Magnoliopsida [dicotyledons]
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/10—Preparations for permanently dyeing the hair
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Abstract
Provided are a hair-dying method, a set of hairdye for the method, and treatment agent for hair. The purpose of the invention aims at providing a hair-dying method capable of maintaining long-time color retention even basic dyestuff is used as basic hairdye. The hair-dying method is characterized by comprising following processes of a first process, a second process, and a third process. In the first process, the basic hairdye containing dye is coated on hair and is laid for a given time. In the second process, the hair coated with the basic hairdye liquid is cleaned. In the third process, after the second process, the hair is coated with catechinic acid aqueous solution and is laid for a given time.
Description
Technical field
The present invention relates to hair colouring methods, be used for hair dye suit, and the hair nursing agent of this hair colouring methods.Specifically, even relate to hair dye suit, and the hair nursing agent that uses basic stain etc. also can keep high colourability (long-lasting color) as basic stain.
Background technology
In recent years, be widely used the hair dye that contains as the oxidation dye of the p-phenylenediamine (PPD) of synthetic dyestuffs system or amino-phenol system.The hue preserving of hair dye after hair dyeing that contains oxidation dye is excellent, and can show colorful tone.
Yet known oxidation dye can cause dermatosis.In addition, be that ecosystem is caused the censure of dysgenic environmental hormone and then is suspected to have carcinogenecity or causes the censure of anaphylaxis etc. in addition.Thus, the hair dye that contains oxidation dye becomes the restriction object on Europe and other places.
On the other hand, as the dyestuff composition of hair dye, known have pointed out that safety is than the high HC dyestuff of oxidation dye or basic stain etc.All the time, basic stain and HC dyestuff for example as the hue preserving take about 2～3 weeks as the hair nial polish (hair manicure) of purpose, by 1 week with the hair dyeing and care element (color conditioner) or hair dyeing nursing agent (color treatment) use that continue for several times to give color.For example, in the following patent documentation 1, haircut and use compositions as having the two the hair dyeing of effect and hair dyeing effect of haircuting concurrently, disclose and contained the i.e. hair dyeing of hair dyeing property pigment and at least a alpha-hydroxy acid ester and/or at least a dialkyl carbonate and at least a cross linked polymer of at least a dyestuff that is selected from the group that is formed by HC dyestuff, basic stain, disperse dyes and natural pigment or pigment and haircut and use compositions.
The prior art document
Patent documentation
Patent documentation 1: TOHKEMY 2005-213212 communique
Summary of the invention
Invent problem to be solved
Basic stain or HC dyestuff are pointed out to compare with oxidation dye safe.Yet, basic stain or HC dyestuff dye on the hair on the ground owing to chemical reaction not occuring, so exist the hue preserving (retain a color) after the hair dyeing poor, by repeatedly have one's hair wash (shampoo) etc. and the shortcoming of easily fade (color failure).Therefore, as mentioned above, thereby be the hair nial polish of purpose or all with continuing for several times to give hair dyeing and care element or the hair dyeing nursing agent that color is kept color by 1 as the hue preserving take about 2～3 weeks, although also can use in practical, not attempt for example so-called permanent such usage of hair dye take the hue preserving above 1 month as purpose.
The object of the invention is to, provide and use the basic stain that contains basic stain or HC dyestuff, can keep the hair colouring methods of the long hue preserving that approaches with permanent hair dye.
For the method for dealing with problems
Hair colouring methods of the present invention is characterised in that, it possesses following operation: be applied to the basic dye liquid of basic stain or HC dyestuff etc. on the hair and place the first operation of stipulated time; The second operation that the hair that is coated with basic dye liquid is washed; After the second operation at hair coating tea catechin aqueous solution and place the 3rd operation of stipulated time.According to such hair colouring methods, even use basic stain or HC dyestuff etc. as basic stain, also can keep for a long time hue preserving.Think that effect of the present invention in repeating the process of many experiments, proves effective with mechanism as described below.For example, in the first operation, be applied on the hair by the basic dye liquid that will contain basic stain or HC dyestuff, thereby basic stain or HC dyestuff adhere to or are penetrated in the hair.And, after in the second operation, washing, coating tea catechin aqueous solution in the 3rd operation.Thereby think the tea catechin that in the 3rd operation, is coated with to contact with airborne oxygen and oxidation polymerization occurs to form tunicle, thereby adhere to or the basic stain or the HC dyestuff that are penetrated in the hair are dyed more strongly surely.And tea catechin is difficult for being impacted by the color of basic stain or the toning of HC dyestuff.
In addition, in the 3rd operation, when the hair that will be coated with the tea catechin aqueous solution is placed official hour, preferably shine far infrared.By the irradiation far infrared, thereby hue preserving further improves.Think this chances are for applying when processing, before the tea catechin aqueous solution is rinsed out, be activated and promote the polyreaction of tea catechin as the tea catechin of polyphenol.
In addition, basic dye liquid contains alkaline reducer and pH is 7.5～9 o'clock, because hair generation alkali swelling, thereby basic stain or HC dyestuff easily are penetrated in the hair, and consequently, hue preserving improves more, is preferred from this point.
In addition, hair dye of the present invention suit is the hair dye suit that uses in order to carry out above-mentioned hair colouring methods, is to be used for modulating containing as the basic dye of the basic stain of main constituent and being used for the hair dye suit that the powder combinations that contains tea catechin of brew tea catechin aqueous solution forms of basic dye liquid.Hair dye suit according to such can easily carry out above-mentioned hair colouring methods.
The invention effect
According to the present invention, use basic stain or HC dyestuff as basic stain, also can keep the hair colouring methods of long-time hue preserving even can provide.
The specific embodiment
An embodiment for hair colouring methods of the present invention below is elaborated.
The hair colouring methods of present embodiment for example possesses following operation: will contain as the basic stain of dyestuff main constituent and the basic dye liquid of the HC dyestuff that uses as required is applied on the hair, and place the first operation of stipulated time; The second operation that the hair that is coated with basic dye liquid is washed; After the second operation, at hair coating tea catechin aqueous solution, place the 3rd operation of stipulated time.
At first the first operation is described.
The first operation is to contain as the basic stain of dyestuff main constituent and the basic dye liquid of the HC dyestuff that uses as required is not applied to the operation of wanting the part of having hair dyed of hair with omitting.
Basic stain is to have amino or substituted-amino in the molecule and become cationic dyestuff in aqueous solution, can be not particularly limited to use all the time as the known dyestuff of basic stain.Basic stain is owing to becoming cation, so dye on by partly carrying out ionic bonding with the keratic negativity of hair surface in aqueous solution.As its object lesson, for example can list Blue 7 (C.i.42595), alkali blue 16(C.I.12210), alkali blue 22(C.I.61512), alkali blue 26 (C.I.44045), alkali blue 99(C.I.56059), alkali blue 117, alkaline purple 1 0(C.I.45170), basic violet 14 (C.I.42515), bismarck brown 16(C.I.12250), bismarck brown 17(C.I.12251), the red 2(C.I.50240 of alkalescence), alkali red 1:1 2(C.I.48070), the red 22(C.I.11055 of alkalescence), alkalescence red 51, the red 76(C.I.12245 of alkalescence), alkali red 1:1 18(C.I.12251:1), Basic Orange 31, Basic Yellow 28 (C.I.48054), basic yellow 57(C.I.12719), basic yellow 87, basic black 2(C.I.11825) etc.They may be used alone, or two or more kinds may be used in combination.
The HC dyestuff is knownly to have " HC " as the dyestuff of prefix owing to being the less dyestuff of molecular diameter, so the inside that is penetrated into hair by hydrogen bond or intermolecular attraction and on dye, give darker colour developing.As its object lesson, such as listing the red No.1 of HC blue No.2, HC blue No.8, HC orange No.1, HC orange No.2, HC, the red No.3 of HC, the red No.7 of HC, the red No.8 of HC, the red No.10 of HC, the red No.11 of HC, the red No.13 of HC, the yellow No.12 of yellow No.9, the HC of yellow No.7, HC of yellow No.6, HC of yellow No.5, HC of yellow No.2, HC of the red No.16 of HC, HC purple No.2, HC etc.They may be used alone, or two or more kinds may be used in combination.
The ratio of basic stain and HC dyestuff is not particularly limited, but the ratio of the HC dyestuff in the total amount of basic stain and HC dyestuff is preferably 1～30 quality %, more preferably about 5～20 quality %.
Make basic stain and HC dyestuff easily be penetrated in the hair by hair generation alkali swelling, from this point, preferred basic dye liquid has alkalescence, particularly has alkalescence about pH7.5～9 and then 8～8.5, in order to be adjusted into such fluidity, basic dye liquid preferably contains alkaline agent.As the object lesson of such alkaline agent, such as listing the alkaline reducers such as acetylcysteine, cysteamine, mercaptoethanol acid, ammonia, various alkanolamine, ammonium salt, organic amine, inorganic base, basic amino acid and their salt etc.In the middle of these, during the alkaline reducer that particularly combines at the alkaline reducer that uses acetylcysteine, cysteamine, mercaptoethanol acid or with acetylcysteine, cysteamine and mercaptoethanol acid, exist dyestuff more easily to enter the tendency of hair.They can distinguish separately use, also can will be used in combination more than 2 kinds.Alkaline reducer preferably contains 0.01～1 quality % in basic dye liquid, further preferably contain 0.1～0.5 quality %.
Basis dye liquid is such as the ratio cooperations to stipulate such as alkaline agent with basic stain, the HC dyestuff that uses as required, as required use, be mixed into all the time in the liquid mediums such as cream frost base that the medium as the hair dye composition uses and be modulated into pasty state or aqueous solution, be applied on the hair.In addition, as cream frost base material, such as being not particularly limited to use the white base of cream that the lubricant components such as spermol, stearyl alcohol, octyl dodecanol, oleyl alcohol, isooctadecanol, mineral oil, decyl oleate, the different stearyl ester of myristic acid, isopropyl palmitate, triglyceride (ト リ グ リ セ リ Le) and the emulsifying agents such as polyoxyethylene laurel ether, lauric acid sorbitan, CETETH-2, OLETH-10, CETEARETH-20 etc. is suitably cooperated and obtain.
As the concentration of the basic stain that contains in the basic dye liquid and HC dyestuff, in the total amount of basic stain and HC dyestuff, in paste or aqueous solution, be preferably 0.5～10 quality %, more preferably 1～5 quality %.
The hair that is coated with basic dye liquid is placed official hour.The time of placing is suitably adjusted according to the kind of the dyestuff of the hobby of the color that hair is given or use, but from the viewpoint of operation sequence, usually preferred the placement 5～60 minutes, further preferred the placement 10～30 minutes.In addition, when placing, preferably the hair that is coated with basic dye liquid is not shone far infrared with omitting.By to hair irradiation far infrared, standing time can be shortened.The temperature of the hair surface during as far-infrared radiation never can be damaged hair or cause the aspect of excessive burden to set out to human body, is preferably 20～40 ℃, more preferably the temperature about 25～35 ℃.
The second operation is the hair of having placed the basic dye liquid of being coated with of official hour is washed and to wash away the operation of basic dye liquid.
As long as flushing can be washed out the basic dye liquid that adheres on the hair, then its method is not particularly limited, and does not preferably use shampoo, the water of water or tepor to wash out basic dye liquid.After washing out, usually towel off dried.
The 3rd operation is the hair coating tea catechin aqueous solution after flushing, and places the operation of stipulated time.Tea catechin is difficult in addition, being difficult for becoming anaphylactogen to being brought impact by the color of basic stain or the toning of HC dyestuff.As the object lesson of tea catechin, such as tea catechin of the mixture that can list any one or they contained in epicatechin, epigallocatechin, epicatechin Gallate catechu ester, the epigallocatechin Gallate catechu ester etc.In addition, the tea catechin aqueous solution also can contain other polyphenol.As the object lesson of polyphenol, such as listing flavonoid class (catechin, anthocyanidin, flavone, isoflavone, flavane, flavanone, Lu Ding), phenolic acids (chlorogenic acid, ellagic acid, gallic acid, propyl gallate), lignanoids, curcumin, Coumarins etc.In addition, these chemical compounds cooperate so also can be used as extract owing to being included in a large number in the extract from following such natural goods.They may be used alone, or two or more kinds may be used in combination.In addition, the pigment of Flos Impatientis polyphenol or Folium et Caulis Indigoferae Tinctoriae polyphenol brings impact and the tendency of color that change mix colours so exist to the color that forms with basic stain and the toning of HC dyestuff owing to denseer.
Aqueous solution or aqueous dispersions that the tea catechin aqueous solution is modulated into tea catechin are pasty state, then, are applied on the hair.As the tea catechin aqueous solution, such as aqueous solution or the dispersion liquid at the tea powder ends such as use green tea powder.Tea catechin is proportional being not particularly limited that contain in the paste at aqueous solution or aqueous dispersions, particularly, for example is preferably 5～20 quality % in the tea amount of powder, more preferably 10～15 quality %.In addition, in the tea catechin aqueous solution, in the scope of not damaging effect of the present invention, can cooperate as required the bromic acid of conduct hair dyeing oxidant use etc., when cooperating bromic acid, there is the tendency of the oxidative polymerization that hinders polyphenol, so, as long as no special purpose, preferably mismatch as far as possible the hair dyeing oxidants such as bromic acid.
By coating tea catechin aqueous solution, and place official hour, thereby the basic stain or the HC dyestuff that adhere to or be penetrated in the hair are dyed more strongly surely.The mechanism of its effect is not fully found out, but the most experiments result by the inventor can think, active much higher phenol is that tea catechin by airborne oxygen oxidation polymerization etc. occurs, thereby form to cover and to adhere to or be penetrated into basic stain in the hair or the tunicle of HC dyestuff, utilize this tunicle, suppress through the time fade.Thereby this also can infer such mechanism from particularly increasing this phenomenon by irradiation far infrared effect placement.That is, behind the coating tea catechin aqueous solution, by to hair irradiation far infrared, thus further suppress through the time fade.
Condition as far-infrared radiation, temperature as hair surface, be 20～40 ℃ and then be temperature about 25～35 ℃, shone 10～60 minutes and then 15～30 minutes, this is excellent from operating efficiency, can not damage hair or human body is caused the aspect of excessive burden also be preferred.In addition, behind far-infrared radiation, by the placement official hour, thereby further suppress to fade.
And, to coating tea catechin aqueous solution and place official hour, preferably shine far infrared and the hair placed, implement the hair washing of ending and wash out the tea catechin aqueous solution, thereby obtain dyed hair.After washing out, towel off and do and carry out aeration-drying etc.Like this, the hair dyeing of finishing hair is processed.
Even hair colouring methods of the present invention uses the HC dyestuff of basic stain and as required cooperation as basic stain, also can realize for example keeping of the long hue preserving more than 1 month and then more than 2 months.In addition, owing to use basic stain to reach the HC dyestuff that cooperates as required as basic stain, so excellent in safety.Therefore, even, also can feel at ease to use when dying poliosis etc. prolonged and repeated.
Embodiment
Below, the present invention is described in more detail by embodiment.In addition, scope of the present invention is not subjected to any restriction of the present embodiment.
(embodiment 1)
In with the cream frost base material of spermol as main constituent, the ratio with 9:1 of being mixed with is contained basic stain and HC dyestuff dye mixture 5 quality % basic stain 50g and contain acetylcysteine and the mixture of cysteamine and mercaptoethanol acid is that the alkaline agent 50g of alkaline reducer 1 quality % mixes, modulate basic dye liquid.
Then, at one end the gross weight of harness is to be coated with the basic dye liquid of modulating on the hair bundle that is made of Crinis Carbonisatus of 10g.In addition, the major part of all Crinis Carbonisatus of formation hair bundle is poliosis.
Then, the hair bundle that is coated with basic dye liquid placed 10 minutes after, shine approximately 15 minutes far infrareies.At this moment, the temperature of hair bundle is about 30 ℃.Then, the poliosis of confirming the hair bundle be not dyed to with omitting dark brown after, water washes out the basic dye liquid that adheres on the hair bundle.Then, fully dry moisture with towel.
Then, green tea powder (the お tea カ ラ one ト リ one ト メ Application ト powder of (strain) ITCB Global system) 25g is dissolved among the water 175g of tepor brew tea catechin aqueous solution.Then, the tea catechin aqueous solution of modulating is applied on the hair bundle.Then, the hair bundle that is coated with the tea catechin aqueous solution placed 10 minutes after, shine approximately 20 minutes far infrareies.At this moment, the temperature of hair bundle is about 30 ℃.Then, further naturally placed approximately 10 minutes.
Then, the hair bundle is had one's hair wash with commercially available shampoo.Then, fully dry moisture with towel.
In addition, in above-mentioned hair dyeing, with the roughly only length of half hair dyeing of hair bundle, remaining half be hair dyeing not.
Only obtain like this hair bundle that half length is had hair dyed.
Then, to the hair bundle of having hair dyed, implement 1 hair washing every day, take the color of the part that not have hair dyeing as benchmark hair dyeing change color is partly carried out the observation of rheological parameters' change with time.Consequently, even through 2 months, dark brown dyestuff does not remain in the part of hair dyeing with fading yet, and the part of hair dyeing is residual significantly with the border of the color of the part that does not have hair dyeing.In addition, when more than 70 year old women commentator implement is processed with same processes, the poliosis part of the root that grows obviously observing when implementing to process before 2 months with 2 months before the portion boundary of hair dyeing.
(comparative example 1)
Except the processing that is not coated with the tea catechin aqueous solution, similarly to Example 1 the hair bundle is had hair dyed.That is, similarly to Example 1, at the basic dye liquid of hair bundle coating, the hair bundle that is coated with basic dye liquid placed 10 minutes after, shine approximately 15 minutes far infrareies.Then, the poliosis of confirming the hair bundle do not dye with omitting dark brown after, water washes out the basic dye liquid that adheres on the hair bundle, and then, have one's hair wash with commercially available shampoo.Then, fully dry moisture with towel.In addition, in above-mentioned hair dyeing, also with the roughly only length of half hair dyeing of hair bundle, remaining half be hair dyeing not.Only obtain like this hair bundle that half length is had hair dyed.
Then, to the hair bundle of having hair dyed, implement 1 hair washing every day, take the color of the part that not have hair dyeing as benchmark hair dyeing change color is partly carried out the observation of rheological parameters' change with time.Consequently, through about 3 whens week, the part of hair dyeing is faded, and the part of hair dyeing obviously becomes not distinct with the border of the color of the part that not have to have hair dyed.
(comparative example 2)
To mix with the ratio of 1:1 with same basic dye liquid and the tea catechin aqueous solution of modulation among the embodiment 1.Then, at one end the gross weight of harness is to be coated with the intermixture of modulating on the hair bundle that is made of Crinis Carbonisatus of 10g.In addition, the major part of all Crinis Carbonisatus of formation hair bundle is poliosis.
Then, the hair Shu Ziran that is coated with intermixture placed 10 minutes after, shine approximately 20 minutes far infrareies.Then, further naturally placed approximately 10 minutes.Then, the hair bundle is had one's hair wash with commercially available shampoo.Then, fully dry moisture with towel.Only obtain like this hair bundle that half length is had hair dyed.
Then, to the hair bundle of having hair dyed, implement 1 hair washing every day, observe the variation of hair dyeing color partly as benchmark take the color of the part that not have hair dyeing.Consequently, through about 3 whens week, the part of hair dyeing is faded, and the part of hair dyeing obviously becomes not distinct with the border of the color of the part that not have to have hair dyed.By this result as can be known, even with basic dye liquid and tea catechin aqueous solution and coating, also can't keep fully hue preserving.
(embodiment 2)
After the hair bundle that is coated with the tea catechin aqueous solution placed 10 minutes, do not shine approximately 20 minutes far infrared but the hair Shu Ziran that will be coated with the tea catechin aqueous solution placed 30 minutes, in addition, similarly to Example 1 the hair bundle is had hair dyed.That is, the tea catechin aqueous solution of modulating similarly to Example 1 is applied to hair Shu Shanghou, the hair Shu Ziran that is coated with the tea catechin aqueous solution was placed 30 minutes, further naturally placed approximately 10 minutes.
Then, the hair bundle is had one's hair wash with commercially available shampoo.Then, fully dry moisture with towel.Except above-mentioned operation, with the hair dyeing of hair bundle, estimate similarly to Example 1.Consequently, through approximately 2 months the time, the part of hair dyeing is faded a little.But the part of hair dyeing is clearly distinguished to a certain extent with the border of the color of the part that does not have hair dyeing.Its result is compared with the result of embodiment 1, and by the irradiation far infrared, the effect of hue preserving improves as can be known.
(comparative example 3)
Replace coating tea catechin aqueous solution, use by Flos Impatientis powder 25g being dissolved into the Flos Impatientis aqueous solution of modulating among the water 175g, be coated with the processing of Flos Impatientis aqueous solution, in addition, with the hair dyeing of hair bundle, estimate similarly to Example 1.Consequently, even through 1 month, the dyestuff of postfermented tea color does not remain in the part of hair dyeing with fading yet, and the part of hair dyeing is obvious with the border of the color of the part that does not have hair dyeing.
Utilizability on the industry
When using hair colouring methods of the present invention to have hair dyed, even use basic stain or HC dyestuff as basic stain, also can keep long hue preserving.Therefore, can be used as not is that the hair dyeing take the hue preserving of short-term as purpose but the succedaneum that can keep the what is called " permanent hair dye " of long-term hue preserving use.
Claims (12)
1. a hair colouring methods is characterized in that, possesses following operation:
Be applied to basic dye liquid on the hair and place the first operation of stipulated time;
The second operation that the hair that is coated with described basic dye liquid is washed;
After described the second operation at hair coating tea catechin aqueous solution and place the 3rd operation of stipulated time.
2. hair colouring methods according to claim 1, wherein, described basic dye liquid contains basic stain as the dyestuff main constituent.
3. hair colouring methods according to claim 2, wherein, described basic dye liquid further contains the HC dyestuff.
4. hair colouring methods according to claim 1, wherein, described basic dye liquid contains alkaline reducer, and pH is 7.5～9.
5. hair colouring methods according to claim 4, wherein, described alkaline reducer contain be selected from by acetylcysteine, cysteamine, and the group that forms of mercaptoethanol acid at least one.
6. hair colouring methods according to claim 1 wherein, when placing official hour in described the 3rd operation, shines far infrared to described hair.
7. hair colouring methods according to claim 1, wherein, described tea catechin aqueous solution is the aqueous solution at tea powder end.
8. hair colouring methods according to claim 1, wherein, described tea catechin aqueous solution is the aqueous solution of green tea powder.
9. hair colouring methods according to claim 8, wherein, described tea catechin aqueous solution is the aqueous solution that contains the green tea powder of 5～20 quality %.
10. a hair dye suit is characterized in that, it is the hair dye suit for hair colouring methods claimed in claim 1,
It is to be set with as the basic dye of main constituent and for the hair dye that the powder combinations that contains tea catechin of modulating described tea catechin aqueous solution forms for the basic stain that contains of modulating described basic dye liquid.
11. hair dye suit according to claim 10, wherein, described basic dye liquid further contains the HC dyestuff.
12. a hair nursing agent, it comprises green tea powder as main constituent.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP209097/2011 | 2011-09-26 | ||
| JP2011209097A JP4993396B1 (en) | 2011-09-26 | 2011-09-26 | Hair dyeing method and hair dye set used for the hair dyeing method |
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| Publication Number | Publication Date |
|---|---|
| CN103006502A true CN103006502A (en) | 2013-04-03 |
| CN103006502B CN103006502B (en) | 2014-10-08 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201210334862.9A Expired - Fee Related CN103006502B (en) | 2011-09-26 | 2012-09-11 | Hair-dying method, a set of hairdye for the method, and treatment agent for hair |
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| Country | Link |
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| JP (1) | JP4993396B1 (en) |
| KR (1) | KR101453159B1 (en) |
| CN (1) | CN103006502B (en) |
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| CN113438940A (en) * | 2019-02-01 | 2021-09-24 | 株式会社Lg生活健康 | Preparation for hair dyeing |
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| JP7065518B2 (en) * | 2019-01-16 | 2022-05-12 | 株式会社サニープレイス | Hair coloring composition |
| JP7004682B2 (en) * | 2019-01-16 | 2022-01-21 | 株式会社サニープレイス | Hair color method |
| JP2022519111A (en) * | 2019-02-01 | 2022-03-18 | エルジー ハウスホールド アンド ヘルスケア リミテッド | Formulation for hair dyeing |
| KR20230168956A (en) | 2022-06-08 | 2023-12-15 | 주식회사 엘지생활건강 | Composition for hair dye |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN100374101C (en) * | 2002-11-27 | 2008-03-12 | 株式会社资生堂 | Hair dye composition |
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| JPH08291027A (en) * | 1995-04-18 | 1996-11-05 | Kanebo Ltd | Hair cosmetic |
| JP2003089618A (en) * | 2001-09-18 | 2003-03-28 | Lion Corp | Hair cosmetic |
| KR100872898B1 (en) | 2007-04-27 | 2008-12-10 | 김경숙 | Composition for hair color having an extract of green tea |
| JP2010132596A (en) * | 2008-12-04 | 2010-06-17 | M & Smart:Kk | Hair dyeing composition, and method for dyeing hair by using the same |
| JP5548382B2 (en) * | 2009-04-14 | 2014-07-16 | 資生ケミカル株式会社 | Hair dyeing method |
| KR101510486B1 (en) * | 2009-11-30 | 2015-04-10 | (주)아모레퍼시픽 | Hair dye composition comprising catechin |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN100374101C (en) * | 2002-11-27 | 2008-03-12 | 株式会社资生堂 | Hair dye composition |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105592839A (en) * | 2014-09-11 | 2016-05-18 | Ictb全球株式会社 | Hair coloring agent and hair dyeing method |
| CN105592839B (en) * | 2014-09-11 | 2017-10-20 | Ictb全球株式会社 | Hair colourant and hair colouring methods |
| CN105534785A (en) * | 2015-12-28 | 2016-05-04 | 肇庆迪彩日化科技有限公司 | Dyeing composition containing natural plant ingredients |
| TWI825056B (en) * | 2018-10-18 | 2023-12-11 | 日商桑妮布雷斯股份有限公司 | A hair color agent composition |
| CN113438940A (en) * | 2019-02-01 | 2021-09-24 | 株式会社Lg生活健康 | Preparation for hair dyeing |
| CN113438940B (en) * | 2019-02-01 | 2024-03-08 | 株式会社Lg生活健康 | Hair dyeing preparation |
Also Published As
| Publication number | Publication date |
|---|---|
| KR20130033291A (en) | 2013-04-03 |
| JP2013067597A (en) | 2013-04-18 |
| CN103006502B (en) | 2014-10-08 |
| KR101453159B1 (en) | 2014-10-27 |
| JP4993396B1 (en) | 2012-08-08 |
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