CN102415406A - Synergy insecticidal composition containing dinotefuran and pyrethrin pesticide and purpose thereof - Google Patents
Synergy insecticidal composition containing dinotefuran and pyrethrin pesticide and purpose thereof Download PDFInfo
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- CN102415406A CN102415406A CN2010102986074A CN201010298607A CN102415406A CN 102415406 A CN102415406 A CN 102415406A CN 2010102986074 A CN2010102986074 A CN 2010102986074A CN 201010298607 A CN201010298607 A CN 201010298607A CN 102415406 A CN102415406 A CN 102415406A
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Abstract
The invention relates to a synergy insecticidal composition containing dinotefuran and pyrethrin pesticide and purpose thereof. The synergy insecticidal composition contains main effective components of dinotefuran and pyrethrin pesticides. The pyrethrin is one selected from efficient cypermethrin, cyhalothrin, cyhalothrin, bifenthrin, alphacypermethrin, deltamethrin, fenvalerate, cypermethrin, fenpropathrin, silafluofen, efficient cyhalothrin and ethofenprox. The dinotefuran and pyrethrin are in a mass ratio of 0.1-80:0.1-50. The insecticidal composition can generate efficient synergism, overcome and delay resistance of insects and expand control spectrum, and has fast insecticidal speed and reduced drug usage cost. The insecticidal composition of the invention can be used for controlling homoptera insects of aphid and whitefly, etc. and has an effect obvious better than that of a single dose.
Description
Technical field
The invention belongs to pesticide field, be specifically related to a kind of Synergistic insecticidal compositions that contains MTI-446 and pyrethroid insectide and uses thereof.
Background technology
MTI-446 (dinotefuran), chemical name: 1-methyl-2-nitro-3-(tetrahydrochysene-3-furfuryl) guanidine, white crystal, 107.5 ℃ of fusing points, 94.5～101.5 ℃ of industrial goods, vapour pressure＜1.7 * 10
-6Pa (30 ℃), density 1.33 (25 ℃).Solvability is water 40g/L, is insoluble in cyclohexane, solvent wet goods organic solvent.Structural formula is:
MTI-446 is fool proof to mammal, and its acute oral LD50 is male rat 2450mg/kg, female rats 2275mg/kg; Male mice 2840mg/kg, female mice 2000mg/kg.To rat acute through skin LD50＞2000mg/kg (female, hero).No teratogenesis, carcinogenic and mutagenicity.MTI-446 is also fool proof to aquatile.The ichthyotoxin test shows that MTI-446 is to carp nm (48h)＞1000mg/L, to water flea＞1000mg/L; Equally, MTI-446 is also very low to birds toxicity, and through the honeybee test is learnt, MTI-446 is to honeybee safety to quail acute oral LD50＞1000mg/kg., and do not influence honeybee producting honey.This medicament insecticidal spectrum is wide, has remarkable interior suction osmosis, and has promptly shown very high insecticidal activity at very low dosage.This medicament is fool proof to mammal, birds and aquatile, and crop is not had poisoning, can be used for numerous crops such as paddy rice, fruit tree, vegetables.
Pyrethroid insecticides is an insecticide synthetic on the basis of pyrethrum active ingredient chemical constitution research, mainly disturbs neural sodium-ion channel, causes insect death.Comprise decis (decis), cypermethrin (Xing Mianbao), sumicidin (Belmark) etc.This insecticide not only is widely used in the crops deinsectization, but also a large amount of as (kill mosquito with kill insect such as roach bat) hygienic insecticide.Whole world pyrethrin pesticide accounts for 20% in insecticide market at present, and usable floor area accounts for 25% of whole insecticide area, and commercial kind has more than 50.
At present, the resistance of homoptera pest increases gradually, and the agent of agricultural chemicals list descends to the effect of control of insect gradually, does not still have effective preparation for the control of homoptera pest.The inventor finds that after deliberation agriculture chemical compounding can obviously improve drug effect, and can delay the generation of pest resistance.
Summary of the invention
The purpose of this invention is to provide a kind of Synergistic insecticidal compositions that contains MTI-446 and pyrethroid insecticides, this Pesticidal combination production cost is low, have quick-acting and the long-acting pesticidal effect.
The present invention also provides a kind of Synergistic insecticidal compositions that contains MTI-446 and pyrethroid insecticides to prevent and treat the application in the insecticidal materials of resistance homoptera pest in preparation.
For achieving the above object; The present invention is through the network analysis to MTI-446 and pyrethroid insecticides insecticidal properties; Make full use of both mutual supplement with each other's advantages, MTI-446 and pyrethroid insecticides is composite according to certain ratio, obtain Pesticidal combination of the present invention.
The objective of the invention is to realize through following technical scheme:
A kind of Synergistic insecticidal compositions that contains MTI-446 and pyrethroid insecticides; This Synergistic insecticidal compositions is main active ingredient with MTI-446 and pyrethroid insecticides, and pyrethroid insecticides is any one in beta-cypermethrin, cyfloxylate, cyhalothrin, Biphenthrin, alpha-cypermethrin, decis, sumicidin, cypermethrin, fenpropathrin, silafluofene, gamma cyhalothrin, the ether chrysanthemum ester.Wherein, the weight ratio of MTI-446 and pyrethroid insecticides is 0.1～80: 0.1～50.Be preferably 0.5～60: 0.5～40, further be preferably 1～30: 1～30, most preferably be 1～10: 1～10.
In the present composition, the two weight percentage in this Synergistic insecticidal compositions of MTI-446 and pyrethroid insecticides is 1%～85%, and the preferred weight percentage composition is 6%～50%.
This Synergistic insecticidal compositions is any one formulation that allows on main active ingredient (active component) and insecticides adjuvant and the excipients preparation agricultural chemicals with MTI-446 and pyrethroid insecticides, preferred missible oil, aqueous emulsion, microemulsion, suspending agent, wetting powder, water dispersible granules, aqua.Described auxiliary agent can adopt calcium dodecyl benzene sulfonate, APES, polyoxyethylene polyoxy third rare block compound (like farming breast 33
#), NPE etc., excipient can adopt cyclohexanone, vegetable oil, solvent naphtha, water, antifreezing agent (like propane diols), deionized water etc.Above auxiliary agent, excipient can be singly with or and with or also add other auxiliary material.
The above-mentioned Synergistic insecticidal compositions that contains MTI-446 and pyrethroid insecticides is prevented and treated the application in the insecticidal materials of resistance homoptera pest in preparation, and especially effect is remarkable in the insecticidal materials of insects such as preparation control cotten aphid, vegetable aphid and aleyrodid.
Beneficial effect of the present invention:
The present invention provides the Pesticidal combination of a kind of MTI-446 and pyrethroid insecticides; It compared with prior art can produce higher cooperative synergism, overcomes and has delayed pest resistance to insecticide; The expanding prevention spectrum; Desinsection speed is fast, has reduced drug cost, and its effect is used apparently higher than its single agent.
Embodiment
Embodiments of the invention are the methods that adopt indoor bioassay and field trial to combine.Pass through indoor bioassay, the co-toxicity coefficient after clear and definite two kinds of medicaments are composite by a certain percentage earlier; On this basis, carry out field trial again.
Embodiment 1:
Take by weighing MTI-446, beta-cypermethrin, adopting the conventional formulation method to be mixed with MTI-446 and beta-cypermethrin weight percentage by different proportion respectively is 40% MTI-446 r, and specifically ratio is seen table 1,2.
Employing is soaked the leaf dip method and is carried out indoor synergy biologicall test, and selecting the resistance cotten aphid is target pest, and LC is used in every processing repetition 3 times
50Value is pressed the abundant method of Sun Yun and is calculated co-toxicity coefficient:
The Toxicity Determination of table 1 MTI-446 and beta-cypermethrin Synergistic insecticidal compositions and single agent antagonism cotten aphid thereof
Data show in the table, and MTI-446 and the beta-cypermethrin back that is mixed has synergistic effect to cotten aphid, and three listed in table proportioning co-toxicity coefficients are all greater than 120, so MTI-446 and beta-cypermethrin are mixed and have significant synergies.
Employing is soaked the leaf dip method and is carried out indoor synergy biologicall test, and selecting the resistance aleyrodid is target pest, and LC is used in every processing repetition 3 times
50Value is pressed the abundant method of Sun Yun and is calculated co-toxicity coefficient:
The Toxicity Determination of table 2 MTI-446 and beta-cypermethrin Synergistic insecticidal compositions and single agent antagonism aleyrodid thereof
Data show in the table, and MTI-446 and the beta-cypermethrin back that is mixed has synergistic effect to aleyrodid, and three listed in table proportioning co-toxicity coefficients are all greater than 120, so MTI-446 and beta-cypermethrin are mixed and have significant synergies.
Embodiment 2:
Take by weighing 2g MTI-446,8g ether chrysanthemum ester, phenethyl phenol polyethenoxy ether phosphate 3g, farming breast 33
#(alkylaryl polyoxyethylene polyoxypropylene ether) 2g, APES 1g, vegetable oil 13g adds water to 100g.Above raw material is dropped into the mixing kettle high speed by the method for routine preparation aqueous emulsion mix, form main active ingredient weight percentage and be 10% MTI-446 ether chrysanthemum ester aqueous emulsion.
Embodiment 3:
Take by weighing 8g MTI-446,2g ether chrysanthemum ester, sodium lignin sulfonate 8g, lauryl sodium sulfate 2g, ammonium sulfate 5g; Polyvinyl alcohol 5g; Borax 2g; Kaolin 68g, it is 10% MTI-446 ether chrysanthemum ester water dispersion granule that above raw material is processed main active ingredient weight percentage by the method for water dispersion granule.
Adopt embodiment 2 and 3; According to every mu of ground difference medication 10g, 20g, 30g medicament, the contrast medicament is 10% ether chrysanthemum ester WP (wetting powder) 30g/ mu, 10% MTI-446 AS (aqua) 30g/ mu; Every mu of ground water consumption is 30kg; 4 days, 10 days, 15 days, 20 days, 30 days fruits that come to an end after the dispenser, and handle, the result sees table 3:
Table 3: MTI-446 and ether chrysanthemum ester Synergistic insecticidal compositions are to the field test results of cotten aphid
Can know that from last table MTI-446 ether chrysanthemum ester is composite to be better than 10% ether chrysanthemum ester wetting powder, 10% MTI-446 aqua to the cotten aphid drug effect, demonstrates the superiority of prescription.
Adopt the sample of embodiment 2 and 3; According to every mu of ground difference medication 10g, 20g, 30g medicament, the contrast medicament is 10% ether chrysanthemum ester WP (wetting powder) 30g/ mu, 10% MTI-446 AS (aqua) 30g/ mu; Every mu of ground water consumption is 30kg; 4 days, 10 days, 15 days, 20 days, 30 days fruits that come to an end after the dispenser, and handle, the result sees table 4:
Table 4: MTI-446 and ether chrysanthemum ester Synergistic insecticidal compositions are to the field test results of aleyrodid
Can know that from last table MTI-446 ether chrysanthemum ester is composite to be better than 10% ether chrysanthemum ester wetting powder, 10% MTI-446 aqua to the aleyrodid drug effect, demonstrates the superiority of prescription.
Embodiment 4:
Take by weighing 60g MTI-446,5g silafluofene, 1g lauryl sodium sulfate, 0.5g dispersing agent NNO (sodium methylene bis-naphthalene sulfonate), kaolin to 100g; Above raw material is mixed by the method for routine preparation wetting powder, form main active ingredient weight percentage and be 65% MTI-446 silafluofene wetting powder.
Embodiment 5:
Take by weighing 2g MTI-446,1g gamma cyhalothrin, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether phosphate 3g, farming breast 33
#(alkylaryl polyoxyethylene polyoxypropylene ether) 2g, APES 1g, isopropyl alcohol 10g adds water to 100g.Above raw material dropped in the mixing kettle by the method for routine preparation microemulsion mix, form main active ingredient weight percentage and be 3% MTI-446 gamma cyhalothrin microemulsion.
Embodiment 6:
Take by weighing 5g MTI-446,45g cypermethrin, sodium lignin sulfonate 8g, lauryl sodium sulfate 2g, ammonium sulfate 5g; Polyvinyl alcohol 5g; Borax 2g; Kaolin 28g, it is 50% MTI-446 cypermethrin water dispersible granules that above raw material is processed main active ingredient weight percentage by the method for water dispersion granule.
Embodiment 7:
Take by weighing 6g MTI-446,16g sumicidin, sodium lignin sulfonate 2g, polyoxyethylene poly-oxygen propylene aether and sulphate 4g thereof; Xanthans 0.15g; Ethylene glycol 5g, silica ethane 0.10g, aluminium-magnesium silicate 0.5g; Water complements to 100g, and the main active ingredient weight percentage of formation is 22% MTI-446 sumicidin suspending agent under the effect of sand mill.
Embodiment 8:
Take by weighing 60g MTI-446,5g decis, sodium lignin sulfonate 2g, polyoxyethylene poly-oxygen propylene aether and sulphate 4g thereof; Xanthans 0.15g; Ethylene glycol 5g, silica ethane 0.10g, aluminium-magnesium silicate 0.5g; Water complements to 100g, and the main active ingredient weight percentage of formation is 65% MTI-446 decis suspending agent under the effect of sand mill.
Embodiment 9:
Take by weighing 8g MTI-446,60g Biphenthrin, APES 10g, phenethyl phenol polyethenoxy ether 10g, vegetable oil to 100g; Above raw material dropped in the mixing kettle by the method for routine preparation missible oil mix, process main active ingredient weight percentage and be 68% MTI-446 Biphenthrin missible oil.
Embodiment 10:
Take by weighing 0.1g MTI-446,30g cyhalothrin, APES 14g, phenethyl phenol polyethenoxy ether 15g, vegetable oil to 100g; Above raw material dropped in the mixing kettle by the method for routine preparation missible oil mix, process main active ingredient weight percentage and be 30.1% MTI-446 cyhalothrin emulsifiable concentrate.
Embodiment 11:
Take by weighing 70g MTI-446,0.1g cyfloxylate, APES 14g, phenethyl phenol polyethenoxy ether 10g, vegetable oil to 100g; Above raw material dropped in the mixing kettle by the method for routine preparation missible oil mix, process main active ingredient weight percentage and be 70.1% MTI-446 cyfloxylate missible oil.
Embodiment 12:
Take by weighing 5g MTI-446,35g alpha-cypermethrin, sodium lignin sulfonate 8g, lauryl sodium sulfate 2g, ammonium sulfate 5g; Polyvinyl alcohol 5g; Borax 2g; Kaolin 38g, it is 40% MTI-446 alpha-cypermethrin water dispersible granules that above raw material is processed main active ingredient weight percentage by the method for water dispersion granule.
Embodiment 13:
Take by weighing 2g MTI-446,3g fenpropathrin, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether phosphate 3g, agricultural newborn 33# (alkylaryl polyoxyethylene polyoxypropylene ether) 2g, APES 1g, isopropyl alcohol 10g adds water to 100g.Above raw material dropped in the mixing kettle by the method for routine preparation microemulsion mix, form main active ingredient weight percentage and be 5% MTI-446 fenpropathrin microemulsion.
Claims (10)
1. Synergistic insecticidal compositions that contains MTI-446 and pyrethroid insecticides; It is characterized in that this Synergistic insecticidal compositions is main active ingredient with MTI-446 and pyrethroid insectide; Wherein, the weight ratio of MTI-446 and pyrethroid insecticides is 0.1～80: 0.1～50.
2. the Synergistic insecticidal compositions that contains MTI-446 and pyrethroid insectide according to claim 1 is characterized in that the weight ratio of MTI-446 and pyrethroid insectide is 0.5～60: 0.5～40 in the said composition.
3. the Synergistic insecticidal compositions that contains MTI-446 and pyrethroid insectide according to claim 2 is characterized in that the weight ratio of MTI-446 and pyrethroid insectide is 1～30: 1～30 in the said composition.
4. the Synergistic insecticidal compositions that contains MTI-446 and pyrethroid insectide according to claim 1 is characterized in that the two weight percentage in this Synergistic insecticidal compositions of MTI-446 and pyrethroid insectide is 1%～85%.
5. the Synergistic insecticidal compositions that contains MTI-446 and pyrethroid insectide according to claim 4 is characterized in that the two weight percentage in this Synergistic insecticidal compositions of MTI-446 and pyrethroid insectide is 6%～50%.
6. the Synergistic insecticidal compositions that contains MTI-446 and pyrethroid insectide according to claim 1 is characterized in that it is any one formulation that allows on main active ingredient and insecticides adjuvant and the excipients preparation agricultural chemicals with MTI-446 and pyrethroid insectide.
7. the Synergistic insecticidal compositions that contains MTI-446 and pyrethroid insectide according to claim 6 is characterized in that described formulation is missible oil, aqueous emulsion, microemulsion, suspending agent, wetting powder, water dispersible granules or aqua.
8. according to any described Synergistic insecticidal compositions that contains MTI-446 and pyrethroid insectide among the claim 1-7, it is characterized in that pyrethroid insecticides is any one in beta-cypermethrin, cyfloxylate, cyhalothrin, Biphenthrin, alpha-cypermethrin, decis, sumicidin, cypermethrin, fenpropathrin, silafluofene, gamma cyhalothrin, the ether chrysanthemum ester.
9. the described Synergistic insecticidal compositions that contains MTI-446 and pyrethroid insectide of claim 1 is prevented and treated the application in the insecticidal materials of resistance homoptera pest in preparation.
10. application according to claim 9 is characterized in that containing the application of Synergistic insecticidal compositions in the insecticidal materials of preparation control cotten aphid, vegetable aphid and aleyrodid of MTI-446 and pyrethroid insectide.
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Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102239878A (en) * | 2011-07-05 | 2011-11-16 | 江苏丘陵地区镇江农业科学研究所 | Insecticide composite containing dinotefuran, preparation formulations and preparation method thereof |
| CN102246803A (en) * | 2011-08-18 | 2011-11-23 | 南宁市德丰富化工有限责任公司 | Dinotefuran-containing insecticide |
| CN102907454A (en) * | 2011-08-03 | 2013-02-06 | 潘登 | Composite pesticides for controlling rice pests |
| CN103202313A (en) * | 2013-04-28 | 2013-07-17 | 柳州市惠农化工有限公司 | Pesticide composition |
| CN104286017A (en) * | 2014-09-15 | 2015-01-21 | 青岛润鑫伟业科贸有限公司 | Efficient insecticide containing dinotefuran, fenpropathrin, diazinon and spinetoram |
| CN104322541A (en) * | 2014-09-30 | 2015-02-04 | 青岛康和食品有限公司 | Efficient insecticide containing cyhalothrin, dinotefuran and benzoylurea |
| CN110250197A (en) * | 2019-06-25 | 2019-09-20 | 青岛润农化工有限公司 | A kind of Pesticidal combination and its application of dinotefuran and Biphenthrin |
| CN112772671A (en) * | 2019-11-11 | 2021-05-11 | 江苏扬农化工股份有限公司 | Dinotefuran-containing compound insecticidal composition and application thereof |
| WO2021170461A1 (en) * | 2020-02-28 | 2021-09-02 | BASF Agro B.V. | Methods and uses of a mixture comprising alpha-cypermethrin and dinotefuran for combating or controlling mosquitoes |
| WO2021170463A1 (en) * | 2020-02-28 | 2021-09-02 | BASF Agro B.V. | Methods and uses of a mixture comprising alpha-cypermethrin and dinotefuran for controlling invertebrate pests in turf |
| WO2021170462A1 (en) * | 2020-02-28 | 2021-09-02 | BASF Agro B.V. | Methods and uses of a mixture comprising alpha-cypermethrin and dinotefuran for controlling bed bugs |
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Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102239878A (en) * | 2011-07-05 | 2011-11-16 | 江苏丘陵地区镇江农业科学研究所 | Insecticide composite containing dinotefuran, preparation formulations and preparation method thereof |
| CN102907454A (en) * | 2011-08-03 | 2013-02-06 | 潘登 | Composite pesticides for controlling rice pests |
| CN102246803A (en) * | 2011-08-18 | 2011-11-23 | 南宁市德丰富化工有限责任公司 | Dinotefuran-containing insecticide |
| CN103202313A (en) * | 2013-04-28 | 2013-07-17 | 柳州市惠农化工有限公司 | Pesticide composition |
| CN104286017A (en) * | 2014-09-15 | 2015-01-21 | 青岛润鑫伟业科贸有限公司 | Efficient insecticide containing dinotefuran, fenpropathrin, diazinon and spinetoram |
| CN104322541A (en) * | 2014-09-30 | 2015-02-04 | 青岛康和食品有限公司 | Efficient insecticide containing cyhalothrin, dinotefuran and benzoylurea |
| CN110250197A (en) * | 2019-06-25 | 2019-09-20 | 青岛润农化工有限公司 | A kind of Pesticidal combination and its application of dinotefuran and Biphenthrin |
| CN110250197B (en) * | 2019-06-25 | 2021-11-09 | 青岛润农化工有限公司 | Dinotefuran and bifenthrin insecticidal composition and application thereof |
| CN112772671A (en) * | 2019-11-11 | 2021-05-11 | 江苏扬农化工股份有限公司 | Dinotefuran-containing compound insecticidal composition and application thereof |
| WO2021170461A1 (en) * | 2020-02-28 | 2021-09-02 | BASF Agro B.V. | Methods and uses of a mixture comprising alpha-cypermethrin and dinotefuran for combating or controlling mosquitoes |
| WO2021170463A1 (en) * | 2020-02-28 | 2021-09-02 | BASF Agro B.V. | Methods and uses of a mixture comprising alpha-cypermethrin and dinotefuran for controlling invertebrate pests in turf |
| WO2021170462A1 (en) * | 2020-02-28 | 2021-09-02 | BASF Agro B.V. | Methods and uses of a mixture comprising alpha-cypermethrin and dinotefuran for controlling bed bugs |
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Application publication date: 20120418 |