ZA827040B - Triazinyallactams,a process for their preparation,their use as stabilizers for synthetic organic polymers and the polymers stabilized with them - Google Patents

Triazinyallactams,a process for their preparation,their use as stabilizers for synthetic organic polymers and the polymers stabilized with them

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Publication number
ZA827040B
ZA827040B ZA827040A ZA827040A ZA827040B ZA 827040 B ZA827040 B ZA 827040B ZA 827040 A ZA827040 A ZA 827040A ZA 827040 A ZA827040 A ZA 827040A ZA 827040 B ZA827040 B ZA 827040B
Authority
ZA
South Africa
Prior art keywords
group
formula
see diagramm
alkyl
substituted
Prior art date
Application number
ZA827040A
Inventor
Hartmut Wiezer
Gerhard Pfahler
Original Assignee
Hoechst Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hoechst Ag filed Critical Hoechst Ag
Publication of ZA827040B publication Critical patent/ZA827040B/en

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Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D401/00Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
    • C07D401/14Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing three or more hetero rings
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/16Nitrogen-containing compounds
    • C08K5/34Heterocyclic compounds having nitrogen in the ring
    • C08K5/3467Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
    • C08K5/3477Six-membered rings
    • C08K5/3492Triazines
    • C08K5/34926Triazines also containing heterocyclic groups other than triazine groups

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Polyesters Or Polycarbonates (AREA)
  • Polyethers (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

1. Claims for the Contracting States : BE, CH, DE, FR, GB, IT, LI, NL, SE A compound of the formula (I) see diagramm : EP0075849,P13,F1 in which m is 0 or 1, n is also 0 or 1 and A is C4 to C11 alkylene, R**1 , when m is 0, has the meaning of hydrogen, of C1 to C18 alkyl, of C3 to C21 alkoxyalkyl, of C5 to C12 cycloalkyl, which can be substituted by C1 to C4 alkyl, or phenyl or naphthyl, which can be substituted by up to two Cl or C1 to C4 alkyl radicals or by one C1 to C4 alkoxy or C1 to C2 carboalkoxy group, of C7 to C14 phenylalkyl or of a group of the formula (II) see diagramm : EP0075849,P13,F2 wherein R**3 is hydrogen or methyl and R**4 is hydrogen, C1 to C4 alkyl, or is 2,3-epoxypropyl, allyl or benzyl, R**1 and R**2 , when m is 1, are identical or different and represent hydrogen, C1 to C18 alkyl, C5 to C12 cycloalkyl, which can be substituted by up to four C1 to C4 alkyl groups, phenyl, which can be substituted by up to two C1 to C4 alkyl radicals, C7 to C14 phenylalkyl or a group of the formula (II), X1 and X2 , when n is 0, are identical or different and represent halogen, phenyl or a group of the formulae (III), (IV) or (V) see diagramm : EP0075849,P13,F3 see diagramm : EP0075849,P13,F4 -DR**9 (V) but when n is 1, X2 is always a group of the formula see diagramm : EP0075849,P14,F1 with A being C4 to C11 alkylene, wherein, in the formulae (III), (IV) and (V), R**5 and R**6 are identical or different and represent radicals listed for R**2 and R**6 additionally has the meaning of C3 to C21 alkoxyalkyl, or R**5 and R**6 together with the N atom connecting them, also represent a pyrrolidine ring or a piperidine, morpholine or hexamethyleneimine ring which is unsubstituted or substituted by up to four C1 to C4 alkyl groups, r, s and t are identical or different whole numbers from 2 to 6 and v is from 0 to 3, R**7 and R**8 represent identical of different radicals with the meanings indicated for R**2 , T has the meaning of a group of the formula (VI) see diagramm : EP0075849,P14,F2 with X3 and X4 being identical or different radicals of the formulae (III), (IV) or (V), R**9 is one of the radicals mentioned under R**1 , when m is 0, and Y represents C2 to C18 alkylene, C2 to C12 bis(propyloxy)alkylene, monocycloalkylene, dicycloalkylene or tricycloalkylene having 6 to 18 C atoms, which can be substituted by up to four methyl groups and in which up to two C atoms can be replaced by N atoms which can carry propylene groups, or Y represents C6 to C18 arylene, or C7 to C14 aralkylene, or a piperazinylene radical can also take the place of the group see diagramm : EP0075849,P14,F3 or C5 to C6 azamonocycloalkylene or azadicycloalkylene radicals, substituted by up to four methyl groups, can take the place of the group see diagramm : EP0075849,P14,F4 or see diagramm : EP0075849,P14,F5 and in formula (I), at least one group of the formula (II) is present, preferably at least one group of the formula (II) per triazine ring. 1. Claims for the Contracting State : AT A process for the preparation of triazinyllactames of the formula (I) see diagramm : EP0075849,P15,F2 in which m is 0 or 1, n is also 0 or 1 and A is C4 to C11 alkylene, R**1 , when m is 0, has the meaning of hydrogen, of C1 to C18 alkyl, of C3 to C21 alkoxyalkyl, of C5 to C12 cycloalkyl, which can be substituted by C1 to C4 alkyl, or phenyl or naphthyl, which can be substituted by up to two Cl or C1 to C4 alkyl radicals or by one C1 to C4 alkoxy or C1 to C2 carboalkoxy group, of C7 to C14 phenylalkyl or of a group of the formula (II) see diagramm : EP0075849,P16,F1 wherein R**3 is hydrogen or methyl and R**4 is hydrogen, C1 to C4 alkyl, or is 2,3-epoxypropyl, allyl or benzyl, R**1 and R**2 , when m is 1, are identical or different and represent hydrogen, C1 to C18 alkyl, C5 to C12 cycloalkyl, which can be substituted by up to four C1 to C4 alkyl groups phenyl, which can be substituted by up to two C1 to C4 alkyl radicals C7 to C14 phenylalkyl or a group of the formula (II), X1 and X2 , when n is 0, are identical or different and represent halogen, phenyl or a group of the formulae (III), (IV) or (V) see diagramm : EP0075849,P16,F2 see diagramm : EP0075849,P16,F3 -DR**9 (V) but when n is 1, X2 is always a group of the formula see diagramm : EP0075849,P16,F4 with A being C4 to C11 alkylene, wherein, in the formulae (III), (IV) and (V), R**5 and R**6 are identical or different and represent radicals listed for R**2 and R**6 additionally has the meaning of C3 to C21 alkoxyalkyl, or R**5 and R**6 , together with the N atom connecting them, also represent a pyrrolidine ring or a piperidine, morpholine or hexamethyleneimine ring which is unsubstituted or substituted by up to four C1 to C4 alkyl groups, r, s, and t are identical or different whole numbers from 2 to 6 and v is from 0 to 3, R**7 and R**8 represent identical of different radicals with the meanings indicated for R**2 , T has the meaning of a group of the formula (VI) see diagramm : EP0075849,P16,F5 with X3 and X4 being identical or different radicals of the formulae (III), (IV) or (V), R**9 is one of the radicals mentioned under R**1 , when m is 0, and Y represents C2 to C18 alkylene, C2 to C12 bis(propyloxy)alkylene, monocycloalkylene, dicycloalkylene or tricycloalkylene having 6 to 18 C atoms, which can be substituted by up to four methyl groups and in which up to two C atoms can be replaced by N atoms which can carry propylene groups, or Y represents C6 to C18 arylene, or C7 to C14 aralkylene, or a piperazinylene radical can also take the place of the group see diagramm : EP0075849,P17,F1 or C5 to C9 azamonocycloalkylene or azadicycloalkylene radicals, substituted by up to four methyl groups, can take the place of the group see diagramm : EP0075849,P17,F2 or see diagramm : EP0075849,P17,F3 and in formula (I), at least one group of the formula (II) is present, preferably at least one group of the formula (II) per triazine ring, which comprises reacting a compound of the formula (VII) see diagramm : EP0075849,P17,F4 in which R**1 , R**2 , X1 , X2 , Y, m and n have the meanings indicated above and Hal is preferably chlorine, in an inert organic solvent at 100 to 200 degrees C with 1.0 to 1.05 times the equivalent amount, relative to the halogen atoms envisaged for the reaction, of the alkali metal salt of a lactam having 4 to 11 methylene groups.
ZA827040A 1981-09-26 1982-09-24 Triazinyallactams,a process for their preparation,their use as stabilizers for synthetic organic polymers and the polymers stabilized with them ZA827040B (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE19813138343 DE3138343A1 (en) 1981-09-26 1981-09-26 TRIAZINYL LACTAME, METHOD FOR THE PRODUCTION THEREOF, THEIR USE AS STABILIZERS FOR SYNTHETIC ORGANIC POLYMERS AND THE POLYMERS STABILIZED WITH THEM

Publications (1)

Publication Number Publication Date
ZA827040B true ZA827040B (en) 1983-08-31

Family

ID=6142673

Family Applications (1)

Application Number Title Priority Date Filing Date
ZA827040A ZA827040B (en) 1981-09-26 1982-09-24 Triazinyallactams,a process for their preparation,their use as stabilizers for synthetic organic polymers and the polymers stabilized with them

Country Status (4)

Country Link
EP (1) EP0075849B1 (en)
AT (1) ATE28456T1 (en)
DE (2) DE3138343A1 (en)
ZA (1) ZA827040B (en)

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3417079A (en) * 1966-10-19 1968-12-17 Gaf Corp 2-alkylamino-4-halogeno-6-n-lactam-s-triazine derivatives
DE2933078A1 (en) * 1979-08-16 1981-03-26 Hoechst Ag, 65929 Frankfurt NEW TRIAZINE DERIVATIVES, THEIR PRODUCTION AND THEIR USE AS STABILIZERS FOR SYNTHETIC POLYMERS

Also Published As

Publication number Publication date
EP0075849B1 (en) 1987-07-22
ATE28456T1 (en) 1987-08-15
EP0075849A3 (en) 1984-02-22
EP0075849A2 (en) 1983-04-06
DE3138343A1 (en) 1983-04-07
DE3276807D1 (en) 1987-08-27

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