ZA202304573B - A preparation method of fluorite-type high entropy ceramics - Google Patents
A preparation method of fluorite-type high entropy ceramicsInfo
- Publication number
- ZA202304573B ZA202304573B ZA2023/04573A ZA202304573A ZA202304573B ZA 202304573 B ZA202304573 B ZA 202304573B ZA 2023/04573 A ZA2023/04573 A ZA 2023/04573A ZA 202304573 A ZA202304573 A ZA 202304573A ZA 202304573 B ZA202304573 B ZA 202304573B
- Authority
- ZA
- South Africa
- Prior art keywords
- high entropy
- entropy ceramic
- ceramics
- ceramic powder
- fluorite
- Prior art date
Links
- 239000000919 ceramic Substances 0.000 title abstract 11
- 238000002360 preparation method Methods 0.000 title abstract 3
- 239000000843 powder Substances 0.000 abstract 6
- 239000011259 mixed solution Substances 0.000 abstract 2
- 238000005245 sintering Methods 0.000 abstract 2
- -1 transition metal salt Chemical class 0.000 abstract 2
- 238000001354 calcination Methods 0.000 abstract 1
- WUKWITHWXAAZEY-UHFFFAOYSA-L calcium difluoride Chemical group [F-].[F-].[Ca+2] WUKWITHWXAAZEY-UHFFFAOYSA-L 0.000 abstract 1
- 239000012700 ceramic precursor Substances 0.000 abstract 1
- 238000000975 co-precipitation Methods 0.000 abstract 1
- 238000001035 drying Methods 0.000 abstract 1
- 238000000227 grinding Methods 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 239000002244 precipitate Substances 0.000 abstract 1
- 238000001556 precipitation Methods 0.000 abstract 1
- 229910052761 rare earth metal Inorganic materials 0.000 abstract 1
- 239000000126 substance Substances 0.000 abstract 1
- 229910052723 transition metal Inorganic materials 0.000 abstract 1
- 238000005406 washing Methods 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
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- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/50—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on rare-earth compounds
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- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/01—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
- C04B35/48—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on zirconium or hafnium oxides, zirconates, zircon or hafnates
- C04B35/486—Fine ceramics
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- C04B35/4885—Composites with aluminium oxide
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- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/01—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
- C04B35/495—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on vanadium, niobium, tantalum, molybdenum or tungsten oxides or solid solutions thereof with other oxides, e.g. vanadates, niobates, tantalates, molybdates or tungstates
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- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/50—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on rare-earth compounds
- C04B35/505—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on rare-earth compounds based on yttrium oxide
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- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/626—Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B
- C04B35/62605—Treating the starting powders individually or as mixtures
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- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3205—Alkaline earth oxides or oxide forming salts thereof, e.g. beryllium oxide
- C04B2235/3208—Calcium oxide or oxide-forming salts thereof, e.g. lime
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- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
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- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
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- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3231—Refractory metal oxides, their mixed metal oxides, or oxide-forming salts thereof
- C04B2235/3256—Molybdenum oxides, molybdates or oxide forming salts thereof, e.g. cadmium molybdate
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- C04B2235/65—Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes
- C04B2235/656—Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes characterised by specific heating conditions during heat treatment
- C04B2235/6562—Heating rate
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- C04B2235/65—Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes
- C04B2235/656—Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes characterised by specific heating conditions during heat treatment
- C04B2235/6565—Cooling rate
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- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/65—Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes
- C04B2235/656—Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes characterised by specific heating conditions during heat treatment
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- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/70—Aspects relating to sintered or melt-casted ceramic products
- C04B2235/74—Physical characteristics
- C04B2235/76—Crystal structural characteristics, e.g. symmetry
- C04B2235/762—Cubic symmetry, e.g. beta-SiC
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Composite Materials (AREA)
- Inorganic Chemistry (AREA)
- Compositions Of Oxide Ceramics (AREA)
Abstract
The present invention relates to the technical field of high performance ceramics, and in particular to a preparation method for fluorite-type high entropy ceramics. By calcining the high entropy ceramic powder, the fluorite-type high entropy ceramic is obtained. The preparation method of the high entropy ceramic powder includes the following steps: dispersing the transition metal salt with the rare earth metal salt and substance A in water to obtain a mixed solution; adding a precipitant dropwise to the mixed solution until the precipitation is complete, centrifuging after standing, washing and drying the resulting precipitate, grinding, and obtaining the high entropy ceramic powder. The present invention uses co-precipitation method to prepare high entropy ceramic precursor powder (high entropy ceramic powder), which requires simple experimental equipment, easy to operate and convenient for scale production, and at the same time can significantly reduce the sintering temperature of high entropy ceramic powder, and can achieve rapid sintering of ceramics in the temperature range of 1000-1400 degrees Celsius to obtain high entropy ceramics with fluorite structure.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN202310337144.5A CN116375470A (en) | 2023-03-31 | 2023-03-31 | Preparation method of fluorite type high-entropy ceramic |
Publications (1)
Publication Number | Publication Date |
---|---|
ZA202304573B true ZA202304573B (en) | 2023-11-29 |
Family
ID=86960987
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ZA2023/04573A ZA202304573B (en) | 2023-03-31 | 2023-04-20 | A preparation method of fluorite-type high entropy ceramics |
Country Status (2)
Country | Link |
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CN (1) | CN116375470A (en) |
ZA (1) | ZA202304573B (en) |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP7154752B2 (en) * | 2016-12-11 | 2022-10-18 | ゼネラル・エレクトリック・カンパニイ | Thermal barrier coating with low thermal conductivity |
WO2020142125A2 (en) * | 2018-10-09 | 2020-07-09 | Oerlikon Metco (Us) Inc. | High-entropy oxides for thermal barrier coating (tbc) top coats |
EP4263090A1 (en) * | 2020-12-15 | 2023-10-25 | University of Maryland, College Park | Multi-element compound nanoparticles, and systems and methods of making and use thereof |
CN114920559A (en) * | 2022-06-07 | 2022-08-19 | 西北工业大学 | High-entropy oxide powder material for thermal barrier coating and preparation method and application thereof |
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2023
- 2023-03-31 CN CN202310337144.5A patent/CN116375470A/en active Pending
- 2023-04-20 ZA ZA2023/04573A patent/ZA202304573B/en unknown
Also Published As
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CN116375470A (en) | 2023-07-04 |
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