ZA200502918B - Wiping article - Google Patents
Wiping article Download PDFInfo
- Publication number
- ZA200502918B ZA200502918B ZA200502918A ZA200502918A ZA200502918B ZA 200502918 B ZA200502918 B ZA 200502918B ZA 200502918 A ZA200502918 A ZA 200502918A ZA 200502918 A ZA200502918 A ZA 200502918A ZA 200502918 B ZA200502918 B ZA 200502918B
- Authority
- ZA
- South Africa
- Prior art keywords
- wiping article
- article
- surfactant
- wiping
- core layer
- Prior art date
Links
- 239000010410 layer Substances 0.000 claims description 21
- 239000004094 surface-active agent Substances 0.000 claims description 20
- 239000000758 substrate Substances 0.000 claims description 16
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 15
- 238000004140 cleaning Methods 0.000 claims description 11
- 238000010410 dusting Methods 0.000 claims description 11
- 239000012792 core layer Substances 0.000 claims description 10
- 150000001412 amines Chemical class 0.000 claims description 8
- 230000002745 absorbent Effects 0.000 claims description 5
- 239000002250 absorbent Substances 0.000 claims description 5
- 239000011159 matrix material Substances 0.000 claims description 5
- -1 polyethylene Polymers 0.000 description 6
- 239000003599 detergent Substances 0.000 description 5
- 238000000034 method Methods 0.000 description 5
- 239000004743 Polypropylene Substances 0.000 description 4
- 125000000217 alkyl group Chemical group 0.000 description 4
- 229920001155 polypropylene Polymers 0.000 description 4
- 229920001131 Pulp (paper) Polymers 0.000 description 3
- 125000004432 carbon atom Chemical group C* 0.000 description 3
- 238000005238 degreasing Methods 0.000 description 3
- 239000004698 Polyethylene Substances 0.000 description 2
- 239000002280 amphoteric surfactant Substances 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- 229920000098 polyolefin Polymers 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 239000002888 zwitterionic surfactant Substances 0.000 description 2
- 229920000297 Rayon Polymers 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 239000003093 cationic surfactant Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 230000009977 dual effect Effects 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000002657 fibrous material Substances 0.000 description 1
- 238000009408 flooring Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000007970 homogeneous dispersion Substances 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000002648 laminated material Substances 0.000 description 1
- 238000002386 leaching Methods 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000012536 packaging technology Methods 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 239000002964 rayon Substances 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 150000003512 tertiary amines Chemical class 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
- A47L—DOMESTIC WASHING OR CLEANING; SUCTION CLEANERS IN GENERAL
- A47L13/00—Implements for cleaning floors, carpets, furniture, walls, or wall coverings
- A47L13/10—Scrubbing; Scouring; Cleaning; Polishing
- A47L13/16—Cloths; Pads; Sponges
- A47L13/17—Cloths; Pads; Sponges containing cleaning agents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/75—Amino oxides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
- C11D17/049—Cleaning or scouring pads; Wipes
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Cleaning Implements For Floors, Carpets, Furniture, Walls, And The Like (AREA)
- Manufacturing Of Multi-Layer Textile Fabrics (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Description
WIPING ARTICLE
The present invention relates to a wiping article which contains dried surfactant and which can be used when wet or dry for the cleaning or dusting of hard surfaces.
Background to the Invention and Prior Art
Cleaning sheets impregnated with a surfactant component are disclosed, for example, in EP 353 014 which describes a wiping article suitable for use in cleaning soiled surfaces in the presence of water. The article comprises first and second substrate layers (typically water-permeable sheets of fibrous material such as cellulose) with solid surfactant particles sandwiched between the layers. Within the article at the interface between the substrate layers is a discontinuous covering of heat-sealable material such as polyethylene which bonds the layers together. The covering also provides a partial barrier which shields the surfactant particles from water permeating through the substrate layers, and therefore retards dissolution and leaching of the surfactant when the wiping article is brought into contact with water.
The wiping article of EP 353 014 is not suitable for use in the absence of water.
US 6,376,046 describes a detergent-impregnated article comprising a detergent-retaining layer which is formed from bulky hydrophobic material capable of retaining a large quantity of detergent and which is sandwiched between detergent-gradual-releasing layers formed from a fibre aggregate of higher density than the retaining layer. The capillary action of the fibres of the release layers retards detergent release from the retaining layer. The article is designed to be used without water since the impregnated detergent itself contains at least 50% by weight water.
A problem with the wiping article of US 6,376,046 is that the impregnated detergent is already pre-diluted with water to a fixed concentration when it is incorporated into the article. For some tough cleaning applications, it may be desirable to use a higher concentration of detergent.
The present invention provides a wiping article that is equally suitable for use in the presence or absence of water.
The present invention provides a wiping article which is suitable for the cleaning or dusting of hard surfaces, the article comprising a laminated substrate having a core layer sandwiched between dusting layers, the core layer comprising an absorbent fibrous matrix entrapping dried surfactant, and the dusting layers comprising a polymeric fibrous web having a capillary structure which permits uptake of water and release of the surfactant when the article is wetted.
When dry, the wiping article of the invention is especially effective for the entrapment and removal of dust and other particulate soil. When wetted, the wiping article of the invention is especially effective for cleaning and degreasing.
The wiping article of the invention has a number of advantageous properties. In particular, it provides a significant cost benefit to the manufacturer because it does not require expensive packaging technology, unlike conventional "wet wipes", which will dry out and lose functionality unless maintained in airtight sealed conditions.
The wiping article of the invention also provides significant cost benefits to the consumer, because of its dual functionality and the fact that it can be re-used.
Flexibility of usage is also improved since in wet cleaning applications the consumer decides the level of water to be applied to the article. Therefore the concentration of available surfactant which is generated by the wetting process can be tailored according to the degree of soiling and nature of the surface to be treated.
The wiping article of the invention is designed in particular for the cleaning of hard surfaces. By "hard surfaces" is meant those surfaces which are typically found in the household. Examples include furniture surfaces,
kitchen worktops, sinks and appliances, bathroom fixtures and fittings, wall and flooring surfaces.
The wiping article of the invention comprises a laminated substrate having a core layer sandwiched between dusting layers.
The core layer comprises an absorbent fibrous matrix.
Preferably the absorbent fibrous matrix is formed from cellulosic fibres, such as pulp and rayon. Wood pulp fibres are most preferred.
The dusting layers comprise a polymeric fibrous web having a capillary structure which permits uptake of water and release of the surfactant when the article is wetted.
Preferably the polymeric fibrous web is formed from polyolefinic fibres, such as Cz.10 polyolefins or copolymers thereof, especially C;.4 polyolefins such as polyethylene and polypropylene. Polypropylene fibres are most preferred.
Suitable laminated substrates which may be used to form the wiping article of the invention are commercially available and may be formed by many processes such as, for example, meltblowing processes, spunbonding processes, hydroentangling, airlaid and bonded carded web processes.
A commercially available example of a suitable laminated substrate which may be used to form the wiping article of the invention is Akena 4SQ ex Orlandi. This is a laminated material with a layer of wood pulp fibres sandwiched between layers of polypropylene fibres.
In the wiping article according to the invention, the core layer of the laminated substrate entraps dried surfactant.
This may be achieved by a process of impregnating the laminated substrate with a solution of the surfactant in a suitable solvent, followed by heating of the impregnated substrate in order to drive off the solvent and thereby concentrate the surfactant in dried form into the core layer of the laminated substrate.
Suitable surfactants to be used in the wiping article according to the invention include any surfactant known to those skilled in the art like nonionic, anionic, cationic, amphoteric and/or zwitterionic surfactants. Preferred surfactants to be used are the amphoteric and/or zwitterionic surfactants.
Auine oxides are particularly preferred for use in the wiping article of the invention since they are mild, pH neutral and stable to oxidation. They are also especially effective at cleaning and degreasing when the wiping article is wetted, even when they are incorporated into the wiping article at low levels.
Preferably amine oxide is used as the sole surfactant component in the wiping article of the invention.
Suitable amine oxides to be used in the wiping article of the invention may be generally described as those tertiary amine oxides of the formula R3R'NQO, in which each R is a lower alkyl group, for instance an alkyl group having from 1 to 3 carbon atoms, preferably methyl, and R' is a long chain alkyl group, for instance an alkyl group having from 8 to 24 carbon atoms, preferably from 8 to 18 carbon atoms.
In the wiping article of the invention, the total content of dried surfactant (preferably amine oxide) suitably ranges from 0.1 to 5%, preferably from 1 to 4%, more preferably from 1.5 to 3% (by weight based on total weight of the wiping article).
The wiping article of the invention is preferably supplied to the consumer in the form of a pre-cut roll. This is a convenient and cost-effective product format which enables the consumer to tailor the size and thickness of product used more easily than with a conventional "stack" of wipes which have a predetermined size.
The wiping article of the invention can contain other optional ingredients which aid in performance and consumer acceptability.
Examples include: preservatives, perfumes, colours and dyes, hygiene agents, and mixtures thereof.
The invention will now be illustrated by the following non- limiting Example, in which all percentages are by weight based on total weight, unless otherwise indicated.
A wiping article according to the invention is prepared by spraying an aqueous solution of amine oxide onto a dry substrate having a 3-layer structure with two outer layers of polypropylene “sandwiching” an inner core layer of wood pulp (commercially available as Akena 4 SQ, ex Orlandi).
After the substrate has absorbed the aqueous solution of amine oxide homogeneously, it is gently heated between 50 and 90°C in a ventilated oven, to allow a.homogeneous evaporation of the water, and a homogeneous dispersion of the dried amine oxide in the substrate.
After the water has completely evaporated, the wiping article is ready to be used, and contains approximately 50mg of dried amine oxide per 1.8g of dry substrate.
Evaluation of the wiping article showed that it gave excellent dusting performance when dry, as well as cleaning and degreasing performance when wetted with water.
Claims (5)
1. A wiping article which is suitable for the cleaning or dusting of hard surfaces, the article comprising a laminated substrate having a core layer sandwiched between dusting layers, the core layer comprising an absorbent fibrous matrix entrapping dried surfactant, and the dusting layers comprising a polymeric fibrous web having a capillary structure which permits uptake of water and release of the surfactant when the article is wetted.
2. A wiping article according to claim 1, in which the absorbent fibrous matrix of the core layer is formed from cellulosic fibres,
3. A wiping article according to claim 1 or 2, in which the polymeric fibrous web of the dusting layers is formed from polyolefinic fibres.
4. A wiping article according to any of claims 1 to 3, in which the amine oxide is used as the sole surfactant component. og
5. A wiping article according to any of claims 1 to 4, which is in the form of a pre-cut roll. Amended sheet: 4 July 2006
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP02258086 | 2002-11-25 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ZA200502918B true ZA200502918B (en) | 2006-07-26 |
Family
ID=32338170
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ZA200502918A ZA200502918B (en) | 2002-11-25 | 2005-04-11 | Wiping article |
Country Status (8)
| Country | Link |
|---|---|
| EP (1) | EP1565098A1 (en) |
| JP (1) | JP2006507066A (en) |
| AR (1) | AR042114A1 (en) |
| AU (1) | AU2003276208A1 (en) |
| BR (1) | BR0315776A (en) |
| CA (1) | CA2503242A1 (en) |
| WO (1) | WO2004047606A1 (en) |
| ZA (1) | ZA200502918B (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20080082987A (en) * | 2006-01-16 | 2008-09-12 | 긴세이 세이시 가부시키가이샤 | Sheet-like water-disintegratable cleaner |
| US20080166176A1 (en) * | 2007-01-05 | 2008-07-10 | Rees Wayne M | Disposable bleaching cleaning pad |
| EP2197332B1 (en) | 2007-09-03 | 2012-08-15 | SCA Hygiene Products AB | Laminate having improved wiping properties and a method for producing the laminate |
| JP5788503B2 (en) * | 2010-07-02 | 2015-09-30 | ザ プロクター アンド ギャンブルカンパニー | Web material and manufacturing method thereof |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB8322226D0 (en) * | 1983-08-18 | 1983-09-21 | Cosmopolitan Textile Co Ltd | Stitch bonded fabric |
| US4675226A (en) * | 1986-07-07 | 1987-06-23 | Ott Hoye L | Stitchbonded composite wiper |
| US4931201A (en) * | 1988-09-02 | 1990-06-05 | Colgate-Palmolive Company | Wiping cloth for cleaning non-abrasive surfaces |
| FR2680963A1 (en) * | 1991-09-10 | 1993-03-12 | Silver Plastics Gmbh Co Kg | DUST AND WIPING CLOTH, BASED ON POLYOLEFINS. |
| JPH0617361A (en) * | 1992-06-30 | 1994-01-25 | Kao Corp | Bulky sheet |
| JPH1075923A (en) * | 1996-09-02 | 1998-03-24 | M N Eng Kk | Roll sheet for sheet mop |
| US6133166A (en) * | 1997-07-01 | 2000-10-17 | The Procter & Gamble Company | Cleaning articles comprising a cellulosic fibrous structure having discrete basis weight regions treated with a high internal phase inverse emulsion |
| US6432904B1 (en) * | 2001-11-13 | 2002-08-13 | Colgate-Palmolive Company | Cleaning wipe comprising alkanolamide and/or amine oxide |
-
2003
- 2003-10-28 AU AU2003276208A patent/AU2003276208A1/en not_active Abandoned
- 2003-10-28 BR BR0315776-8A patent/BR0315776A/en not_active Application Discontinuation
- 2003-10-28 WO PCT/EP2003/012046 patent/WO2004047606A1/en not_active Application Discontinuation
- 2003-10-28 CA CA002503242A patent/CA2503242A1/en not_active Abandoned
- 2003-10-28 EP EP03811743A patent/EP1565098A1/en not_active Withdrawn
- 2003-10-28 JP JP2004554299A patent/JP2006507066A/en not_active Withdrawn
- 2003-11-21 AR ARP030104307 patent/AR042114A1/en unknown
-
2005
- 2005-04-11 ZA ZA200502918A patent/ZA200502918B/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| AR042114A1 (en) | 2005-06-08 |
| WO2004047606A1 (en) | 2004-06-10 |
| AU2003276208A1 (en) | 2004-06-18 |
| CA2503242A1 (en) | 2004-06-10 |
| BR0315776A (en) | 2005-09-13 |
| EP1565098A1 (en) | 2005-08-24 |
| JP2006507066A (en) | 2006-03-02 |
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