YU179190A - IMPROVED PROCEDURE FOR MAKING 5H-DIBENZ (B-F) AZEPINE - Google Patents
IMPROVED PROCEDURE FOR MAKING 5H-DIBENZ (B-F) AZEPINEInfo
- Publication number
- YU179190A YU179190A YU179190A YU179190A YU179190A YU 179190 A YU179190 A YU 179190A YU 179190 A YU179190 A YU 179190A YU 179190 A YU179190 A YU 179190A YU 179190 A YU179190 A YU 179190A
- Authority
- YU
- Yugoslavia
- Prior art keywords
- dibenz
- azepine
- formula
- making
- improved procedure
- Prior art date
Links
Landscapes
- Other In-Based Heterocyclic Compounds (AREA)
Abstract
POBOLJŠANI POSTUPAK ZA PRAVLJENJE 5H-DIBENZ(B-F)AZEPINA.Pronalazak se odnosi na poboljšan postupak za dobivanje 5H_dibenz (b.f)azepina formule dehidrogenizacijom 10,11-dihidro-5H-dibenz(b,f)azepine formule U prisustvu plemenitog metala kao katalizatora i akceptora vodonika, koji obuhvata izvodjenje reakcije u rastopljenom stanju ili u tečnom stanju u polarnom protičnom rastvaraču visoke tačke ključanja po izboru u smeši sa nepolarnim rastvaračem koji ima višu tačku ključanja od polarnog rastvarača, na temperaturi koja ne prelazi 300 C i korišćenje akceptora vodonika u količini od 0,35 do 2 molarna ekvivalenta, računato na jedinjenje formule II.The invention relates to an improved process for the preparation of 5H-dibenz (bf) azepine of formula by dehydrogenation of 10,11-dihydro-5H-dibenz (b, f) azepine metal of the formula and of a hydrogen acceptor, comprising performing the reaction in the molten or liquid state in a high boiling point polar protic solvent optionally in a mixture with a nonpolar solvent having a higher boiling point than the polar solvent, at a temperature not exceeding 300 C and using a hydrogen acceptor in an amount from 0.35 to 2 molar equivalents, calculated on the compound of formula II.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
YU179190A YU179190A (en) | 1990-09-21 | 1990-09-21 | IMPROVED PROCEDURE FOR MAKING 5H-DIBENZ (B-F) AZEPINE |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
YU179190A YU179190A (en) | 1990-09-21 | 1990-09-21 | IMPROVED PROCEDURE FOR MAKING 5H-DIBENZ (B-F) AZEPINE |
Publications (1)
Publication Number | Publication Date |
---|---|
YU179190A true YU179190A (en) | 1992-12-21 |
Family
ID=47278005
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
YU179190A YU179190A (en) | 1990-09-21 | 1990-09-21 | IMPROVED PROCEDURE FOR MAKING 5H-DIBENZ (B-F) AZEPINE |
Country Status (1)
Country | Link |
---|---|
YU (1) | YU179190A (en) |
-
1990
- 1990-09-21 YU YU179190A patent/YU179190A/en unknown
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