WO2025257439A1 - Micro-alloyed hot rolled strip with improved formability, above 700 mpa - Google Patents
Micro-alloyed hot rolled strip with improved formability, above 700 mpaInfo
- Publication number
- WO2025257439A1 WO2025257439A1 PCT/EP2025/066807 EP2025066807W WO2025257439A1 WO 2025257439 A1 WO2025257439 A1 WO 2025257439A1 EP 2025066807 W EP2025066807 W EP 2025066807W WO 2025257439 A1 WO2025257439 A1 WO 2025257439A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- strip
- hot rolled
- sheet
- rolled steel
- polygonal ferrite
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/04—Ferrous alloys, e.g. steel alloys containing manganese
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
- C21D1/18—Hardening; Quenching with or without subsequent tempering
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
- C21D1/56—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering characterised by the quenching agents
- C21D1/60—Aqueous agents
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D6/00—Heat treatment of ferrous alloys
- C21D6/005—Heat treatment of ferrous alloys containing Mn
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D6/00—Heat treatment of ferrous alloys
- C21D6/02—Hardening by precipitation
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties of ferrous metals or ferrous alloys by deformation combined with, or followed by, heat treatment
- C21D8/02—Modifying the physical properties of ferrous metals or ferrous alloys by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties of ferrous metals or ferrous alloys by deformation combined with, or followed by, heat treatment
- C21D8/02—Modifying the physical properties of ferrous metals or ferrous alloys by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
- C21D8/0221—Modifying the physical properties of ferrous metals or ferrous alloys by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the working steps
- C21D8/0226—Hot rolling
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties of ferrous metals or ferrous alloys by deformation combined with, or followed by, heat treatment
- C21D8/02—Modifying the physical properties of ferrous metals or ferrous alloys by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
- C21D8/0247—Modifying the physical properties of ferrous metals or ferrous alloys by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the heat treatment
- C21D8/0263—Modifying the physical properties of ferrous metals or ferrous alloys by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the heat treatment following hot rolling
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
- C21D9/46—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for sheet metals
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/001—Ferrous alloys, e.g. steel alloys containing N
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/002—Ferrous alloys, e.g. steel alloys containing In, Mg, or other elements not provided for in one single group C22C38/001 - C22C38/60
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/02—Ferrous alloys, e.g. steel alloys containing silicon
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/06—Ferrous alloys, e.g. steel alloys containing aluminium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/12—Ferrous alloys, e.g. steel alloys containing tungsten, tantalum, molybdenum, vanadium, or niobium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/14—Ferrous alloys, e.g. steel alloys containing titanium or zirconium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/42—Ferrous alloys, e.g. steel alloys containing chromium with nickel with copper
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/44—Ferrous alloys, e.g. steel alloys containing chromium with nickel with molybdenum or tungsten
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/46—Ferrous alloys, e.g. steel alloys containing chromium with nickel with vanadium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/48—Ferrous alloys, e.g. steel alloys containing chromium with nickel with niobium or tantalum
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/50—Ferrous alloys, e.g. steel alloys containing chromium with nickel with titanium or zirconium
Definitions
- the invention relates to a hot rolled steel strip or sheet and manufacturing method thereof.
- micro-alloyed hot-rolled strips having S700MC according to EN10149-2 are typically produced on the hot wide strip mill (HWSM) at moderate cooling rates of ⁇ 20-30°C/s, from the hot rolling finish temperature to cooling temperatures of ⁇ 550-600°C.
- the microstructure of such steels typically contains ferrite, coarse cementite and perlite.
- the global ductility is good, e.g. elongation.
- the local ductility is worse, e.g. formability of punched edges: quantifiable by means of Hole Expansion Ratio HER.
- EP3715491 Al disclose a hot rolled sheet and a manufacturing method thereof.
- the tensile strength is 440 MPa or higher.
- the microstructure comprises 30 - 70% of a first ferrite and another structure of at least one among bainite and a second ferrite such that the total sum is 95 % or more.
- the average grain size of the first ferrite is less than 5 pm and the average gran size of the other structure is less than 10 pm.
- the hot rolling finishing temperature is below Ae3.
- EP3516085 B 1 disclose a method of manufacturing a high-strength hot-rolled steel strip.
- the tensile strength is at least 570 MPa, preferably 780 MPa or higher.
- the method includes cooling the hot- rolled steel strip with a primary cooling rate between 50 to 150°C/s to an intermediate temperature between 600 and 720°C and coiling between 580 and 660°C.
- the steel has a substantially single-phase ferritic microstructure.
- EP3926064 Bl disclose a high strength steel product and method of manufacturing the same.
- the steel is among other elements alloyed with Ti and V.
- the yield strength is > 700 MPa and the tensile strength is > 760 MPa.
- the hole expansion ratio is > 50 %.
- the microstructure comprises more >90 % ferrite of which 10 - 50 % is quasi polygonal ferrite and the remainder of the ferrite being polygonal ferrite and/or bainitic ferrite.
- the average grain size of the ferrite is ⁇ 10 pm.
- the most preferred finish rolling temperature is 930 - 970 °C.
- the accelerated cooling is preferably done to 620-660 °C at a rate of 35 - 350 °C/s. Coiling is done at 560 - 670 °C.
- WO2023084926 Al disclose a hot rolled sheet alloyed with Ti and B.
- EP2546377 B 1 disclose a hot rolled sheet and a manufacturing method thereof.
- the tensile strength is above 780 MPa.
- the finish rolling temperature of the inventive examples are from 940 °C or higher and the cooling rate ranges between 26 and 35 °C/s.
- EP2689045 Bl discloses a hot-rolled steel sheet with a yield strength of more than 690 MPa and less than or equal to 840 MPa.
- EP2743264 B 1 disclose hot rolled sheet and a method for producing it. According to the document the following relation is essential, 2.0 ⁇ Mn + 8 x [Ti] + 12 x [Nb] ⁇ 2.6.
- the strip or sheet has a composition consisting of the following alloying elements (in wt. %):
- composition is excluding any coatings applied to the strip or sheet.
- C carbon
- FcsC cementite
- Mn manganese
- the lower limit is set to 1.8, and may be raised tol .85 or 1.9 %.
- the amount of Mn may be > 1.9%.
- the upper limit is set to 2.4, and may be restricted to 2.3, 2.2, 2.1, or 2.0 %. A preferred range is 1.9 - 2.2 %.
- Si silicon is an element having an action of improving the strength of the steel sheet, but also functions as a deoxidizer in the steel melt. Si supresses formation of cementite. However, too high amounts of Si can affect surface quality negatively. Surface defects may affect coatability negatively.
- the upper limit is therefore limited to 0.15.
- the upper limit is 0.15, and may be restricted to 0.14, 0.13, 0.12, 0.11, or 0.10%.
- the lower limit is 0.01 %, and may be raised to 0.02, 0.03, 0.04, or 0.05 %.
- a preferred range is 0.02 - 0. 15.
- Al has an action of deoxidizing molten steel in a refining process of the steel.
- Al further has, similarly to Si, an action of suppressing the precipitation of the iron-based carbides such as cementite and thereby improving the strength and Hole expansion ratio.
- An upper limit of 0. 1 % is set to suppress the generation of a non-metallic inclusion in the steel thereby improving the ductility and the low-temperature toughness.
- the lower limit is set to 0.01 and can be raised to 0.02 %.
- the upper limit can be restricted to 0.08, or 0.06 %.
- a preferred range is 0.02 - 0.08 %.
- Ti can improve the strength of the steel sheet by precipitation strengthening or solidsolution strengthening.
- the addition of Ti can lead to a finer initial structure (the prior austenite grain size).
- a finer prior austenite grain size can increase the elongation at fracture and the Hole expansion ratio.
- too much Ti can cause coarse titanium nitrides, which are bad for the Hole expansion ratio.
- the upper limit of Ti is set to 0.2, and can be restricted to 0.19, 0.18, 0.17, 0.16 or 0.15.
- the lowest amount of Ti is set to 0.02, and can be raised to 0.03, 0.04, 0.05, 0.06, 0.07 or 0.08 %.
- a preferred range is 0.05 - 0.16 %.
- Nb(niobium) improves the strength of the steel sheet by precipitation strengthening or solid-solution strengthening. Furthermore, the addition of Nb can lead to a finer initial structure (the prior austenite grain size). A finer prior austenite grain size can increase the elongation at fracture and the Hole expansion ratio.
- the upper limit is set to 0.08, and can be restricted to 0.07, or 0.06 %.
- the lower limit is set to 0.01 and can be raised to 0.02 %.
- a preferred range is 0.02 - 0.065 %.
- Cr(chromium), Mo (molybdenum) and Ni (nickel) can improve the strength of the steel sheet by solidsolution strengthening or quench-hardening strengthening. Cr, Mo, and Ni affect the Ac3 temperature, and they also promote transformation behaviour. Too much of Cr, Mo, and Ni can affect the Hole expansion ratio and the forming properties negatively. Cr: ⁇ 0.2%
- Cr can assist to retard the austenite to ferrite transformation, to set the desired amount of bainite in the cooling step d).
- the upper limit of Cr is set to 0.2, and can be restricted to 0.15, 0.1, 0.05, 0.01 %.
- the lowest amount of Cr is set to 0.001, and can be raised to 0.005, 0.01, 0.02, 0.03, 0.04 or 0.05 %.
- a deliberate addition of Cr is not necessary according to the present invention.
- the upper limit ofNi is set to 0.25, and can be restricted to 0.2, 0.15, 0.1, 0.05, or 0.01 %.
- the lowest amount ofNi is set to 0.001, and can be raised to 0.005, 0.01, 0.02, 0.03, 0.04 or 0.05 %.
- a deliberate addition ofNi is not necessary according to the present invention.
- the upper limit of Mo is set to 0.2, and can be restricted to 0.15, 0.1, 0.05, 0.01 %.
- the lowest amount of Mo is set to 0.001, and can be raised to 0.005, 0.01, 0.02, 0.03, 0.04 or 0.05 %.
- a deliberate addition of Mo is not necessary according to the present invention.
- Ti + Nb should be at least 0.10 %.
- the combined content of Ti and Nb is preferably restricted to ⁇ 0.2%, more preferably ⁇ 0.15%. Higher amounts of these elements are not necessary to achieve the desired properties of the steel. Ti and Nb are expensive elements and should from this viewpoint be kept as low as possible.
- the combined content of Mn, Si and Cr is preferably restricted to ⁇ 2.3%, preferably ⁇ 2.2%, most preferably ⁇ 2.15%. Higher amounts of these elements are not necessary to achieve the desired properties of the steel.
- V ⁇ 0.02 %
- the steel does not contain deliberately addition of V (vanadium).
- the upper limit is set to 0.02 and can be restricted to 0.01 %.
- S (sulfur) is an element generally contained as an impurity.
- S content is more than 0.010%
- the S content is set to 0.010 or less.
- the upper limit is set to 0.010, and may be restricted to 0.005, 0.003, 0.001, 0.0005 or 0.0001 %
- B is an element that can be added to improve hardenability and strength.
- B can also affect coatability negatively, specifically hot dip galvanising.
- boron may segregate at grain boundaries, especially at higher temperatures such as during welding. Boron should therefore not be deliberately added to the steel of the invention.
- the upper limit is set to 0.0010%, and can further be restricted to 0.0005, or 0.0001 %.
- Ca(calcium) can form inclusions that segregates on the grain boundaries. This can cause surface defects on the steel. Surface defects may affect coatability negatively.
- the upper limit is therefore set to 0.0003 %, and can be further restricted to 0.0002, or 0.0001 %.
- Other impurity elements may be comprised in the steel in normal occurring amounts. However, it is preferred to limit the amounts of As, Zr, Sn, Sb to the following optional maximum contents: As: ⁇ 0.020, or ⁇ 0.015% Zr: ⁇ 0.010, or ⁇ 0.006% Sn: ⁇ 0.050, or ⁇ 0.040% Sb: ⁇ 0.020, or ⁇ 0.010%
- Oxygen and hydrogen can further be limited to
- the steel should fulfil the following conditions:
- TS, YS, TE are examples of properties related global ductility.
- HER is a property related to local ductility.
- the Rm, Rpo 2 values are derived in accordance with the Industrial Standard DIN EN ISO 6892-1:2019, wherein the samples are taken in the longitudinal direction of the strip.
- the Total Elongation is determined according to EN10149-2 2013 (D).
- t ⁇ 3mm Asnmm used, and from t >3mm As (proportional measuring length related to the sample cross-section) is used.
- the Hole expansion ratio (X) is determined by the Hole expansion test according to ISO 16630:2017.
- the lower limit of the Hole expansion ratio ( ) is set to 50, and can be raised to 55, 60, 65, 70, 75 or 80 %.
- the upper limit is set to 200 %, and can be restricted to 150, 120, 100, or 90 %.
- the strip or sheet thickness of the final product is 2.0 - 6.5 mm, preferably 2.5 - 5 mm, more preferably 3 - 4 mm.
- the strip or sheet width may be 500 - 2000 mm, preferably 700 - 1750 mm in non-slit condition.
- the microstructure of the steel contains the main phases ferrite and bainite. High elongation is associated with ferrite, and bainite is associated with good edge stretchability expressed as HER.
- the steel balance strength and formability and is suitable for applications requiring improved edge stretch capability.
- microstructural constituents are in the following expressed in volume % (vol. %).
- the phases a) or b) in the list above may balance the microstructure.
- Bainite represents a carbon-rich second phase of the present steel.
- Bainite can be upper bainite and/or lower bainite and/or granular bainite.
- Quasi polygonal ferrite looks similar to granular bainite (irregular, undulating grain boundaries and a dislocation substructure) and is therefore included in the range.
- Pearlite and/or cementite may be present in lesser amounts.
- the content of pearlite and/or cementite can be 0%. Martensite should preferably not be present but may be present at smaller amount.
- the content may be 0%.
- the upper limit is set to ⁇ 1 %.
- Retained austenite should preferably not be present but may be present at smaller amount.
- the content may be 0%.
- the upper limit is set to ⁇ 1 %.
- the microstructure including the amount of each phase, can be identified in scanning electron microscope (SEM) using 20000 times magnification. Preferably by cutting out a sample from a steel plate and polishing a cross section of a plate parallel to the rolling direction. The microstructure should be taken from ! of the thickness. The surface can be etched to make the phases easier to identify.
- SEM scanning electron microscope
- the amount of retained austenite can e.g. be determined by means of the saturation magnetization method such as described in detail in Proc. Int. Conf, on TRIP -aided high strength ferrous alloys (2002), Ghent, Belgium, p. 61 - 64.
- the coiled strip can be produced by the following steps: a) making steel slabs with the composition defined above.
- the steel slabs may e.g. be produced by converter melting or in an electric steel plant and secondary metallurgy to finalise the composition b) Reheating the slabs to a reheating temperature TRH between 1150 °C and 1300 °C at a heating rate of 0.05 - 10 °C/s.
- a high hot rolling finishing temperature FRT is beneficial for the Hole Expansion Ratio (X).
- An increase in hot rolling finishing temperature FRT leads to more elongated austenite grains which affect the final microstructure positively expressed by an increased Hole Expansion Ratio (X).
- the rolling should be accomplish rolling in the austenite region and the hot rolling finishing temperature FRT is preferably above Ae3 as defined by the formula:
- Ae3 (°C) 919 -266 x [C] + 38 x [Si] - 28 x [Mn] - 27 x [Ni] + 12 x [Mo], The amount of the elements in brackets are in weight %.
- the cooling of the strip is preferably done via water cooling. Cooling from 650 °C to the coiling temperature may be done at any rate, typically at a lower rate, e.g. in the range of 10 - 40 °C/s. Cooling from 650 °C may e.g. be done by water cooling.
- the cooling rate of 40 - 60 °C/s in the temperature range from 850 to 650 °C and the coiling temperature between Bs -150 °C and Bs -50 °C facilitates a ferritic matrix without coarse cementite and without or at most small amounts of pearlite. If the cooling rate is too high and/or the coiling temperature is too low, martensite may form.
- the coiling temperature is between Bs - 125 °C and B s - 75 °C.
- Steel slabs were produced by conventional metallurgy by converter melting and secondary metallurgy.
- compositions of the produced steels 1 - 6 are shown in Table. 1.
- the steels #1 - 6 were reheated to a reheating temperature TRH at a heating rate of about 0.1 °C/s.
- the hot rolling finishing temperatures FRT were between 885 °C (steel #6) and 929 °C (steel #4 and #5).
- the inventive steels had hot rolling finishing temperatures FRT above 920 °C.
- the comparative steels #1 and #2 were cooled at a cooling rate CR of 21 °C/s from 850 to 650 °C, whereas the inventive steels (#3 - 5) were cooled between 50 - 60 °C/s from 850 and 650 °C. By cooling the strip faster in the range 650 to 850 °C, the formation of coarse cementite and perlite can be avoided or be supressed.
- the comparative steel #6 had a lower hot rolling finishing temperature FRT (885 °C) and a lower cooling rate CR (33 °C/s).
- the inventive steels #3 - 5 were all coiled at a coiling temperature within Bs - 150 °C and Bs - 50 °C, whereas the comparative examples #1 and #2, were coiled at temperatures closer to Bs.
- the coiling temperatures CT for the inventive steels were chosen to avoid or supress formation of coarse cementite and perlite and to achieve a high fraction of bainite in the microstructure. After coiling phase transformation is finished for these steels.
- the comparative steel #6 was coiled at Bs - 104 °C.
- the mechanical properties of the produced steel strips #1-6 were determined using the measurement methods defined in the description. Mechanical properties are shown in Table 2. As can be seen, the inventive steels #3 -5 met the mechanical criterions, particular in having a Tensile strength YS in the range of 700 - 850 MPa while having a Hole expansion ratio HER > 50 %, while the comparative examples failed to meet the requirement of the Hole expansion ratio HER. Comparative steel #6 failed to meet the requirement on HER due to the lower hot rolling finishing temperature FRT (885 °C) and the lower cooling rate CR (33 °C/s).
- microstructures of the inventive steel fulfilled in vol. %: polygonal ferrite ⁇ 25 bainite and quasi polygonal ferrite > 75 pearlite ⁇ 1 cementite ⁇ 3
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Heat Treatment Of Sheet Steel (AREA)
Abstract
The invention relates to a hot rolled steel strip or sheet having a composition comprising of: C: 0.045 – 0.09, Mn: 1.8 – 2.4, Al: 0.01 – 0.1, Ti : 0.020 – 0.2, Nb:0.01 – 0.08, Si: 0.01 – 0.15, Cr: 0.01 – 0.2, Ni: 0.01 – 0.25, Mo: 0.01 – 0.2, Cu 0.01 – 0.4, V: 0.01 – 0.02, and balance Fe apart from impurities, and having microstructure comprising (in vol. %): polygonal ferrite (≤ 35), bainite and quasi polygonal ferrite (≥ 65), pearlite (< 3), cementite (< 3), retained austenite (<1), and martensite (<1), and having a Yield strength of 700 – 900 MPa and a Hole expansion ratio (λ) ≥ 50 %, and a thickness of 2.0 – 6.5 mm. The invention also relates to method for producing the strip or sheet.
Description
MICRO-ALLOYED HOT ROLLED STRIP WITH IMPROVED FORMABILITY, ABOVE 700
MPA
TECHNICAL FIELD
The invention relates to a hot rolled steel strip or sheet and manufacturing method thereof.
BACKGROUND ART
Conventional micro-alloyed hot-rolled strips having S700MC according to EN10149-2, are typically produced on the hot wide strip mill (HWSM) at moderate cooling rates of ~20-30°C/s, from the hot rolling finish temperature to cooling temperatures of ~550-600°C.The microstructure of such steels typically contains ferrite, coarse cementite and perlite. The global ductility is good, e.g. elongation. However, the local ductility is worse, e.g. formability of punched edges: quantifiable by means of Hole Expansion Ratio HER.
With conventional micro-alloyed hot-rolled strip, complex forming on stamped edges often cannot be realised. There is a need for a micro-alloyed hot-rolled strips having a minimum yield strength of 700 MPa which have an improvement in the formability of punched edges (HER). It would be desirable if these goals could be met without sacrificing coatability.
EP3715491 Al disclose a hot rolled sheet and a manufacturing method thereof. The tensile strength is 440 MPa or higher. The microstructure comprises 30 - 70% of a first ferrite and another structure of at least one among bainite and a second ferrite such that the total sum is 95 % or more. The average grain size of the first ferrite is less than 5 pm and the average gran size of the other structure is less than 10 pm. The hot rolling finishing temperature is below Ae3.
EP3516085 B 1 disclose a method of manufacturing a high-strength hot-rolled steel strip. The tensile strength is at least 570 MPa, preferably 780 MPa or higher. The method includes cooling the hot- rolled steel strip with a primary cooling rate between 50 to 150°C/s to an intermediate temperature between 600 and 720°C and coiling between 580 and 660°C. The steel has a substantially single-phase ferritic microstructure.
EP3926064 Bl disclose a high strength steel product and method of manufacturing the same. The steel is among other elements alloyed with Ti and V. The yield strength is > 700 MPa and the tensile strength is > 760 MPa. The hole expansion ratio is > 50 %. The microstructure comprises more >90 % ferrite of which 10 - 50 % is quasi polygonal ferrite and the remainder of the ferrite being polygonal ferrite and/or bainitic ferrite. The average grain size of the ferrite is < 10 pm. The most preferred
finish rolling temperature is 930 - 970 °C. The accelerated cooling is preferably done to 620-660 °C at a rate of 35 - 350 °C/s. Coiling is done at 560 - 670 °C.
WO2023084926 Al disclose a hot rolled sheet alloyed with Ti and B.
EP2546377 B 1 disclose a hot rolled sheet and a manufacturing method thereof. The tensile strength is above 780 MPa. The finish rolling temperature of the inventive examples are from 940 °C or higher and the cooling rate ranges between 26 and 35 °C/s.
EP2689045 Bl discloses a hot-rolled steel sheet with a yield strength of more than 690 MPa and less than or equal to 840 MPa.
EP2743264 B 1 disclose hot rolled sheet and a method for producing it. According to the document the following relation is essential, 2.0 < Mn + 8 x [Ti] + 12 x [Nb] < 2.6.
JP2009019265 A disclose a hot rolled sheet and a method for producing it. The steels are processed differently than the steels of the invention. For instance, according to the JP2009019265, the hot rolling finishing temperature should not exceed 900 °C. Moreover, the alloying composition are different.
DISCLOSURE OF THE INVENTION
The invention is described in the claims.
In a preferred embodiment the strip or sheet has a composition consisting of the following alloying elements (in wt. %):
C 0.045 - 0.09
Mn 1.8 - 2.4
Al 0.01 - 0.1
Ti 0.020 - 0.2
Nb 0.01 - 0.08
Nb + Ti 0.1 - 0.2
Si 0.01 - 0.15
Cr 0.001 - 0.2
Ni 0.001 - 0.25
Mo 0.001 - 0.2
Cu 0.001 - 0.4 balance Fe apart from impurities.
The composition is excluding any coatings applied to the strip or sheet.
The steel balance strength and formability and is suitable for applications requiring improved edge stretch capability.
The importance of the separate elements and their interaction with each other as well as the limitations of the chemical ingredients of the claimed alloy are briefly explained in the following. All percentages for the chemical composition of the steel are given in weight % (wt. %) throughout the description.
Upper and lower limits of the individual elements can be freely combined within the limits set out in the claims. The arithmetic precision of the numerical values can be increased by one or two digits for all values given in the present application. Hence, a value of given as e.g., 0.1 % can also be expressed as 0.10 or 0.100 %. The amounts of the microstructural constituents are given in volume % (vol. %).
C: 0.045 - 0.09 %
C (carbon) is an element having an action of improving the strength of the steel sheet. A certain amount is therefore required. Increasing the C content too much can lead to insufficient ductility, and that the strength becomes too high. Furthermore, iron-based carbides such as cementite (FcsC) may form. These can be the starting point of cracking in punching operations and can cause deterioration of the stretch flangeability. A preferred range is 0.05 - 0.085 %.
Mn: 1.8 - 2.4 %
Mn (manganese) improves the strength of the steel sheet through solid-solution strengthening and quench-hardening. Further, increasing Mn can expand the austenite temperature region at the lower temperature side. This improves hardenability and facilitates the formation of a low temperature transformation structure having an excellent burring property. The excellent burring property can be seen by improved Hole Expansion Ratio’s. Mn assists to retard the austenite to ferrite transformation such that the desired amount of bainite in the cooling step d) can be reached. The lower limit is set to 1.8, and may be raised tol .85 or 1.9 %. The amount of Mn may be > 1.9%. The upper limit is set to 2.4, and may be restricted to 2.3, 2.2, 2.1, or 2.0 %. A preferred range is 1.9 - 2.2 %.
Si: 0.01 - 0.15%
Si (silicon) is an element having an action of improving the strength of the steel sheet, but also functions as a deoxidizer in the steel melt. Si supresses formation of cementite. However, too high amounts of Si can affect surface quality negatively. Surface defects may affect coatability negatively.
The upper limit is therefore limited to 0.15. The upper limit is 0.15, and may be restricted to 0.14, 0.13, 0.12, 0.11, or 0.10%. The lower limit is 0.01 %, and may be raised to 0.02, 0.03, 0.04, or 0.05 %. A preferred range is 0.02 - 0. 15.
Al: 0.01 - 0.1 %
Al (aluminium) has an action of deoxidizing molten steel in a refining process of the steel. Al further has, similarly to Si, an action of suppressing the precipitation of the iron-based carbides such as cementite and thereby improving the strength and Hole expansion ratio. An upper limit of 0. 1 % is set to suppress the generation of a non-metallic inclusion in the steel thereby improving the ductility and the low-temperature toughness. The lower limit is set to 0.01 and can be raised to 0.02 %. The upper limit can be restricted to 0.08, or 0.06 %. A preferred range is 0.02 - 0.08 %.
Ti: 0.02- 0.2%
Ti (titanium) can improve the strength of the steel sheet by precipitation strengthening or solidsolution strengthening. The addition of Ti can lead to a finer initial structure (the prior austenite grain size). A finer prior austenite grain size can increase the elongation at fracture and the Hole expansion ratio. However, too much Ti can cause coarse titanium nitrides, which are bad for the Hole expansion ratio. The upper limit of Ti is set to 0.2, and can be restricted to 0.19, 0.18, 0.17, 0.16 or 0.15. The lowest amount of Ti is set to 0.02, and can be raised to 0.03, 0.04, 0.05, 0.06, 0.07 or 0.08 %. A preferred range is 0.05 - 0.16 %.
Nb: 0.01 - 0.08 %
Nb(niobium) improves the strength of the steel sheet by precipitation strengthening or solid-solution strengthening. Furthermore, the addition of Nb can lead to a finer initial structure (the prior austenite grain size). A finer prior austenite grain size can increase the elongation at fracture and the Hole expansion ratio. The upper limit is set to 0.08, and can be restricted to 0.07, or 0.06 %. The lower limit is set to 0.01 and can be raised to 0.02 %. A preferred range is 0.02 - 0.065 %.
Optional elements
Cr, Mo, Ni
Cr(chromium), Mo (molybdenum) and Ni (nickel) can improve the strength of the steel sheet by solidsolution strengthening or quench-hardening strengthening. Cr, Mo, and Ni affect the Ac3 temperature, and they also promote transformation behaviour. Too much of Cr, Mo, and Ni can affect the Hole expansion ratio and the forming properties negatively.
Cr: < 0.2%
Cr can assist to retard the austenite to ferrite transformation, to set the desired amount of bainite in the cooling step d). The upper limit of Cr is set to 0.2, and can be restricted to 0.15, 0.1, 0.05, 0.01 %. The lowest amount of Cr is set to 0.001, and can be raised to 0.005, 0.01, 0.02, 0.03, 0.04 or 0.05 %. A deliberate addition of Cr is not necessary according to the present invention.
Ni: < 0.25%
The upper limit ofNi is set to 0.25, and can be restricted to 0.2, 0.15, 0.1, 0.05, or 0.01 %. The lowest amount ofNi is set to 0.001, and can be raised to 0.005, 0.01, 0.02, 0.03, 0.04 or 0.05 %. A deliberate addition ofNi is not necessary according to the present invention.
Mo: < 0.2%
The upper limit of Mo is set to 0.2, and can be restricted to 0.15, 0.1, 0.05, 0.01 %. The lowest amount of Mo is set to 0.001, and can be raised to 0.005, 0.01, 0.02, 0.03, 0.04 or 0.05 %. A deliberate addition of Mo is not necessary according to the present invention.
Cu: < 0.4%
Cu (copper) improves scale removal and thus has an influence on a better surface quality. If the steel is made from scrap, as is common when using an electric arc furnace, Cu impurities can be up to 0.4 %. The upper limit of Cu is set to 0.4, and can be restricted to 0.3, 0.2, 0.15, 0.1, 0.05, 0.01 %. The lowest amount of Cu is set to 0.001, and can be raised to 0.005, 0.01, 0.02, 0.03, 0.04, 0.05, 0.1, or 0.15 %. A deliberate addition of Cu is not necessary according to the present invention.
Further preferred restrictions
Nb + Ti: 0.10 - 0.2 %
To ensure sufficient strength without affecting surface quality negatively, Ti + Nb should be at least 0.10 %. The combined content of Ti and Nb is preferably restricted to < 0.2%, more preferably < 0.15%. Higher amounts of these elements are not necessary to achieve the desired properties of the steel. Ti and Nb are expensive elements and should from this viewpoint be kept as low as possible.
Mn + Si + Cr < 2.3 %
The combined content of Mn, Si and Cr is preferably restricted to < 2.3%, preferably < 2.2%, most preferably < 2.15%. Higher amounts of these elements are not necessary to achieve the desired properties of the steel.
The following impurities may optionally be limited as disclosed below.
V: < 0.02 %
The steel does not contain deliberately addition of V (vanadium). The upper limit is set to 0.02 and can be restricted to 0.01 %.
N: < 0.015 %
N (nitrogen) is an element generally contained as an impurity. When the N content is too high, N causes cracking in the hot rolling, and deteriorates the aging resistance. Therefore, the N content is set to 0.015 % or less, preferably 0.010 % or less. A nominal amount may be in the range of 0.001 - 0.008 0 //o.
P: < 0.10 %
P (phosphorus) is an element generally contained as an impurity. When the P content is more than 0.10 %, P causes cracking in the hot rolling, and is segregated at a grain boundary to decrease the low- temperature toughness and also decrease the workability and the weldability. Therefore, the P content is set to 0.10 % or less. The upper limit is set to 0.10, and may be restricted to 0.05, 0.04, 0.03 or 0.02 0 //o
S: < 0.010 %
S (sulfur) is an element generally contained as an impurity. When the S content is more than 0.010%,
S causes cracking in the hot rolling, and can generate MnS inclusions in the steel which deteriorates the Hole expansion ratio. Therefore, the S content is set to 0.010 or less. The upper limit is set to 0.010, and may be restricted to 0.005, 0.003, 0.001, 0.0005 or 0.0001 %
B: < 0.0010 %
B (boron) is an element that can be added to improve hardenability and strength. However, B can also affect coatability negatively, specifically hot dip galvanising. Furthermore, boron may segregate at grain boundaries, especially at higher temperatures such as during welding. Boron should therefore not be deliberately added to the steel of the invention. The upper limit is set to 0.0010%, and can further be restricted to 0.0005, or 0.0001 %.
Ca: < 0.0003 %
Ca(calcium) can form inclusions that segregates on the grain boundaries. This can cause surface defects on the steel. Surface defects may affect coatability negatively. The upper limit is therefore set to 0.0003 %, and can be further restricted to 0.0002, or 0.0001 %.
Other impurity elements may be comprised in the steel in normal occurring amounts. However, it is preferred to limit the amounts of As, Zr, Sn, Sb to the following optional maximum contents: As: < 0.020, or < 0.015% Zr: < 0.010, or < 0.006% Sn: < 0.050, or < 0.040% Sb: < 0.020, or < 0.010%
Oxygen and hydrogen can further be limited to
O: < 0.001, or < 0.0003%
H: < 0.0050, or < 0.0020%
Mechanical
The steel should fulfil the following conditions:
YS, Yield strength (Rpo 2) 700 - 900 MPa, preferably 700 - 850 MPa
HER, Hole expansion ratio (X) > 50 %, preferably 60 - 100 %TS, Tensile strength (Rm)
700 - 1000 MPa, preferably 750 - 950 MPa,
TE, Total elongation > 10 %, preferably 13 - 30 %, more preferably 15 - 25%
TS, YS, TE are examples of properties related global ductility. HER is a property related to local ductility.
The Rm, Rpo 2 values are derived in accordance with the Industrial Standard DIN EN ISO 6892-1:2019, wherein the samples are taken in the longitudinal direction of the strip.
The Total Elongation is determined according to EN10149-2 2013 (D). For sheet thickness t <3mm, Asnmm used, and from t >3mm As (proportional measuring length related to the sample cross-section) is used.
The Hole expansion ratio (X) is determined by the Hole expansion test according to ISO 16630:2017.
In this test a conical punch having an apex of 60 ° is forced into a 10 mm diameter punched hole made in a steel sheet having the size of 100 x 100 mm2. The test is stopped as soon as the first crack is determined, and the hole diameter is measured in two directions orthogonal to each other. The arithmetic mean value is used for the calculation.
The Hole expansion ratio (X) in % is calculated as follows:
X = (Dh - Do)/Do x 100 wherein Do is the diameter of the hole at the beginning (10 mm) and Dh is the diameter of the hole after the test.
The lower limit of the Hole expansion ratio ( ) is set to 50, and can be raised to 55, 60, 65, 70, 75 or 80 %. The upper limit is set to 200 %, and can be restricted to 150, 120, 100, or 90 %.
The strip or sheet thickness of the final product is 2.0 - 6.5 mm, preferably 2.5 - 5 mm, more preferably 3 - 4 mm. The strip or sheet width may be 500 - 2000 mm, preferably 700 - 1750 mm in non-slit condition.
Microstructure
The microstructure of the steel contains the main phases ferrite and bainite. High elongation is associated with ferrite, and bainite is associated with good edge stretchability expressed as HER. The steel balance strength and formability and is suitable for applications requiring improved edge stretch capability.
The microstructural constituents are in the following expressed in volume % (vol. %). a) polygonal ferrite < 35, preferably < 30, most preferably < 25 b) bainite and quasi polygonal ferrite > 65, preferably > 70, most preferably > 75 c) pearlite < 3, preferably < 2, most preferably <1 cementite < 3, preferably < 2, most preferably <1 retained austenite < 1 martensite < 1
The phases a) or b) in the list above may balance the microstructure.
Bainite represents a carbon-rich second phase of the present steel. Bainite can be upper bainite and/or lower bainite and/or granular bainite. Quasi polygonal ferrite looks similar to granular bainite (irregular, undulating grain boundaries and a dislocation substructure) and is therefore included in the range.
Pearlite and/or cementite may be present in lesser amounts. The content of pearlite and/or cementite can be 0%.
Martensite should preferably not be present but may be present at smaller amount. The content may be 0%. The upper limit is set to < 1 %.
Retained austenite should preferably not be present but may be present at smaller amount. The content may be 0%. The upper limit is set to < 1 %.
The microstructure, including the amount of each phase, can be identified in scanning electron microscope (SEM) using 20000 times magnification. Preferably by cutting out a sample from a steel plate and polishing a cross section of a plate parallel to the rolling direction. The microstructure should be taken from ! of the thickness. The surface can be etched to make the phases easier to identify.
The amount of retained austenite can e.g. be determined by means of the saturation magnetization method such as described in detail in Proc. Int. Conf, on TRIP -aided high strength ferrous alloys (2002), Ghent, Belgium, p. 61 - 64.
Production of the coiled strip.
The coiled strip can be produced by the following steps: a) making steel slabs with the composition defined above. The steel slabs may e.g. be produced by converter melting or in an electric steel plant and secondary metallurgy to finalise the composition b) Reheating the slabs to a reheating temperature TRH between 1150 °C and 1300 °C at a heating rate of 0.05 - 10 °C/s. c) Hot rolling the slabs in austenitic range including finishing rolling to a final thickness t (2 - 6.5 mm), wherein the hot rolling finishing temperature FRT is within the range of 910 to 940 °C, preferably 920 to 940 °C. A high hot rolling finishing temperature FRT is beneficial for the Hole Expansion Ratio (X). An increase in hot rolling finishing temperature FRT leads to more elongated austenite grains which affect the final microstructure positively expressed by an increased Hole Expansion Ratio (X). The rolling should be accomplish rolling in the austenite region and the hot rolling finishing temperature FRT is preferably above Ae3 as defined by the formula:
Ae3 (°C) = 919 -266 x [C] + 38 x [Si] - 28 x [Mn] - 27 x [Ni] + 12 x [Mo], The amount of the elements in brackets are in weight %. d) Cooling the hot rolled strip wherein the cooling rate (CR) is 40 - 60 °C/s in the temperature range from 850 to 650 °C. The cooling of the strip is preferably done via water cooling. Cooling from 650 °C to the coiling temperature may be done at any rate, typically at a lower rate, e.g. in the range of 10 - 40 °C/s. Cooling from 650 °C may e.g. be done by water cooling.
e) Coiling the cooled strip at a coiling temperature between Bs -150 °C and Bs -50 °C, where Bs (°C) = 637-58 x [C] - 10 x [Mn] - 15 x [Ni] - 34 x [Cr] - 41 x [Mo] + 67 x [V + Nb +Ti] . The amount of the elements in brackets are in weight %. f) optionally batch annealing of the coiled strip at 400 - 600 °C for 1 - 48 h, or sheet annealing at 400 - 650 °C for 1 - 60 minutes, or hot dip galvanising of the strip.
The cooling rate of 40 - 60 °C/s in the temperature range from 850 to 650 °C and the coiling temperature between Bs -150 °C and Bs -50 °C facilitates a ferritic matrix without coarse cementite and without or at most small amounts of pearlite. If the cooling rate is too high and/or the coiling temperature is too low, martensite may form. Preferably the coiling temperature is between Bs - 125 °C and Bs - 75 °C.
EXAMPLE
Steel slabs were produced by conventional metallurgy by converter melting and secondary metallurgy.
The compositions of the produced steels 1 - 6 are shown in Table. 1.
Table 1
Steel strips were produced from the steels. Process values and mechanical parameters are shown in
Table 2.
Table 2
Underlined values are outside the scope of the invention.
The steels #1 - 6 were reheated to a reheating temperature TRH at a heating rate of about 0.1 °C/s.
The reheated samples where thereafter hot rolled in austenitic range to a hot rolled strip. The hot
rolling finishing temperatures FRT were between 885 °C (steel #6) and 929 °C (steel #4 and #5). The inventive steels had hot rolling finishing temperatures FRT above 920 °C.
The comparative steels #1 and #2 were cooled at a cooling rate CR of 21 °C/s from 850 to 650 °C, whereas the inventive steels (#3 - 5) were cooled between 50 - 60 °C/s from 850 and 650 °C. By cooling the strip faster in the range 650 to 850 °C, the formation of coarse cementite and perlite can be avoided or be supressed. The comparative steel #6 had a lower hot rolling finishing temperature FRT (885 °C) and a lower cooling rate CR (33 °C/s).
The inventive steels #3 - 5 were all coiled at a coiling temperature within Bs - 150 °C and Bs - 50 °C, whereas the comparative examples #1 and #2, were coiled at temperatures closer to Bs. The coiling temperatures CT for the inventive steels were chosen to avoid or supress formation of coarse cementite and perlite and to achieve a high fraction of bainite in the microstructure. After coiling phase transformation is finished for these steels. The comparative steel #6 was coiled at Bs - 104 °C.
The mechanical properties of the produced steel strips #1-6 were determined using the measurement methods defined in the description. Mechanical properties are shown in Table 2. As can be seen, the inventive steels #3 -5 met the mechanical criterions, particular in having a Tensile strength YS in the range of 700 - 850 MPa while having a Hole expansion ratio HER > 50 %, while the comparative examples failed to meet the requirement of the Hole expansion ratio HER. Comparative steel #6 failed to meet the requirement on HER due to the lower hot rolling finishing temperature FRT (885 °C) and the lower cooling rate CR (33 °C/s).
The microstructures of the inventive steel fulfilled in vol. %: polygonal ferrite < 25 bainite and quasi polygonal ferrite > 75 pearlite < 1 cementite < 3
Claims
1. A hot rolled steel strip or sheet having a composition consisting of the following alloying elements in weight %:
C 0.045 -0.09
Mn 1.8 -2.4
Al 0.01-0.1
Ti 0.020 - 0.2
Nb 0.01-0.08
Nb + Ti 0.1 -0.2
Si 0.01-0.15
Cr 0.001-0.2
Ni 0.001-0.25
Mo 0.001-0.2
Cu 0.001-0.4 balance Fe apart from impurities, of which the following elements are restricted to in weight %:
B <0.0010
Ca < 0.0003
V < 0.02
N <0.015
P <0.10
S <0.010
As < 0.020
Zr <0.010
Sn < 0.050
Sb < 0.020
O <0.001
H <0.0050 and having microstructure comprising (in vol. %): polygonal ferrite <35 bainite and quasi polygonal ferrite > 65 pearlite < 3 cementite < 3 retained austenite < 1
martensite < 1 the microstructure determined as disclosed under the section Microstructure of the description, and having the following mechanical properties:
YS, Yield strength 700 - 900 MPa
Hole expansion ratio ( ) > 50 % the yield strength, the tensile strength, the hole expansion ratio, and the total elongation are derived as disclosed under the section Mechanical properties of the description, and the strip or sheet having a thickness of 2.0 - 6.5 mm.
2. The hot rolled steel strip or sheet according to claim 1, wherein the following elements are further restricted to in weight %:
C 0.05 - 0.085
Mn 1.8 - 2.2
Al 0.02 - 0.08
Ti 0.02 - 0.16
Nb 0.02 - 0.065
Si < 0.2
Cr < 0.15
Ni < 0.2
Mo < 0.15
Cu < 0.15
V < 0.01
3. The hot rolled steel strip or sheet according to claim 1 or 2, wherein the Hole expansion ratio ( ) is at least 60 %.
4. The hot rolled steel strip or sheet according to any one of claims 1 - 3, following microstructural components are restricted to in volume %: polygonal ferrite < 30 bainite and quasi polygonal ferrite > 70 pearlite < 2
5. The hot rolled steel strip or sheet according to claim 4, wherein the following microstructural components are restricted to in volume %: polygonal ferrite < 25 bainite and quasi
polygonal ferrite > 75 pearlite < 1
6. The hot rolled steel strip or sheet according to any one of claims 1 - 5, wherein the composition fulfils at least one of the following conditions in weight %:
Mn + Si + Cr < 2.3
Nb + Ti: < 0.15
7. A method for producing the hot rolled steel strip or sheet according to any one of claim 1 - 5: the method comprising the steps of: a) making steel slabs according to the composition; b) reheating the slabs to a reheating temperature (TRH) between 1150 °C and 1300 °C at a heating rate of 0.05 - 10 °C/s; c) hot rolling the slabs in austenitic range to a hot rolled strip having a final thickness (t) of 2 - 6.5 mm, wherein the hot rolling finishing temperature (FRT) is within the range of 910 to 940 °C; d) cooling the hot rolled strip wherein the cooling rate (CR) is 40 - 60 °C/s in the temperature range from 850 to 650 °C, e) coiling the cooled strip at a coiling temperature between Bs -150 °C and Bs -50 °C, where Bs = 637-58 x [C] - 10 x [Mn] - 15 x [Ni] - 34 x [Cr] - 41 x [Mo] + 67 x [V + Nb +Ti], and the content of the element is in weight %, f) optionally batch annealing the coiled strip at 400 - 600 °C for 1- 48 h, or sheet annealing at 400 - 650 °C for 1 - 60 minutes, or hot dip galvanising of the strip.
8. The method according to claim 6, wherein the coiling temperature is between Bs - 125 °C and Bs - 75 °C.
9. The method according to claim 6 or 7, wherein the hot rolling finishing temperature (FRT) is within the range of 920 to 940 °C.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP24182344.2A EP4663803A1 (en) | 2024-06-14 | 2024-06-14 | Micro-alloyed hot rolled strip with improved formability, above 700 mpa |
| EP24182344.2 | 2024-06-14 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| WO2025257439A1 true WO2025257439A1 (en) | 2025-12-18 |
Family
ID=91580811
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/EP2025/066807 Pending WO2025257439A1 (en) | 2024-06-14 | 2025-06-16 | Micro-alloyed hot rolled strip with improved formability, above 700 mpa |
Country Status (2)
| Country | Link |
|---|---|
| EP (1) | EP4663803A1 (en) |
| WO (1) | WO2025257439A1 (en) |
Citations (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH08199298A (en) * | 1995-01-20 | 1996-08-06 | Kobe Steel Ltd | High strength hot rolled steel plate excellent in chemical convertibility and its production |
| JP2009019265A (en) | 2007-06-12 | 2009-01-29 | Nippon Steel Corp | High Young's modulus steel plate excellent in hole expansibility and method for producing the same |
| EP2351867A1 (en) * | 2005-03-28 | 2011-08-03 | Kabushiki Kaisha Kobe Seiko Sho (Kobe Steel, Ltd.) | High strength hot rolled steel sheet excellent in bore expanding workability and method for production thereof |
| JP2017025397A (en) * | 2015-07-28 | 2017-02-02 | 新日鐵住金株式会社 | Hot-rolled steel sheet and manufacturing method thereof |
| WO2017050790A1 (en) * | 2015-09-22 | 2017-03-30 | Tata Steel Ijmuiden B.V. | A hot-rolled high-strength roll-formable steel sheet with excellent stretch-flange formability and a method of producing said steel |
| EP2689045B1 (en) | 2011-03-24 | 2017-09-13 | ArcelorMittal | Hot-rolled steel sheet and associated production method |
| EP2546377B1 (en) | 2010-03-10 | 2019-03-06 | Nippon Steel & Sumitomo Metal Corporation | High-strength hot-rolled steel sheet and method of manufacturing the same |
| EP3516085B1 (en) | 2016-09-22 | 2020-07-08 | Tata Steel IJmuiden B.V. | A method of producing a hot-rolled high-strength steel with excellent stretch-flange formability and edge fatigue performance |
| EP3715491A1 (en) | 2017-11-24 | 2020-09-30 | Nippon Steel Corporation | Hot-rolled steel sheet and manufacturing method therefor |
| EP3926064B1 (en) | 2020-06-16 | 2022-08-24 | SSAB Technology AB | High strength strip steel product and method of manufacturing the same |
| WO2023084926A1 (en) | 2021-11-12 | 2023-05-19 | 日本製鉄株式会社 | Hot-rolled steel sheet, hot-dip plated steel sheet, and method for manufacturing hot-rolled steel sheet |
| KR20240011284A (en) * | 2022-07-18 | 2024-01-26 | 주식회사 포스코 | Hot rolled high strength steel sheet having excellent shearing quality and stretch-flangeabilty, and method for the same |
-
2024
- 2024-06-14 EP EP24182344.2A patent/EP4663803A1/en active Pending
-
2025
- 2025-06-16 WO PCT/EP2025/066807 patent/WO2025257439A1/en active Pending
Patent Citations (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH08199298A (en) * | 1995-01-20 | 1996-08-06 | Kobe Steel Ltd | High strength hot rolled steel plate excellent in chemical convertibility and its production |
| EP2351867A1 (en) * | 2005-03-28 | 2011-08-03 | Kabushiki Kaisha Kobe Seiko Sho (Kobe Steel, Ltd.) | High strength hot rolled steel sheet excellent in bore expanding workability and method for production thereof |
| JP2009019265A (en) | 2007-06-12 | 2009-01-29 | Nippon Steel Corp | High Young's modulus steel plate excellent in hole expansibility and method for producing the same |
| EP2546377B1 (en) | 2010-03-10 | 2019-03-06 | Nippon Steel & Sumitomo Metal Corporation | High-strength hot-rolled steel sheet and method of manufacturing the same |
| EP2689045B1 (en) | 2011-03-24 | 2017-09-13 | ArcelorMittal | Hot-rolled steel sheet and associated production method |
| JP2017025397A (en) * | 2015-07-28 | 2017-02-02 | 新日鐵住金株式会社 | Hot-rolled steel sheet and manufacturing method thereof |
| WO2017050790A1 (en) * | 2015-09-22 | 2017-03-30 | Tata Steel Ijmuiden B.V. | A hot-rolled high-strength roll-formable steel sheet with excellent stretch-flange formability and a method of producing said steel |
| EP3516085B1 (en) | 2016-09-22 | 2020-07-08 | Tata Steel IJmuiden B.V. | A method of producing a hot-rolled high-strength steel with excellent stretch-flange formability and edge fatigue performance |
| EP3715491A1 (en) | 2017-11-24 | 2020-09-30 | Nippon Steel Corporation | Hot-rolled steel sheet and manufacturing method therefor |
| EP3926064B1 (en) | 2020-06-16 | 2022-08-24 | SSAB Technology AB | High strength strip steel product and method of manufacturing the same |
| WO2023084926A1 (en) | 2021-11-12 | 2023-05-19 | 日本製鉄株式会社 | Hot-rolled steel sheet, hot-dip plated steel sheet, and method for manufacturing hot-rolled steel sheet |
| KR20240011284A (en) * | 2022-07-18 | 2024-01-26 | 주식회사 포스코 | Hot rolled high strength steel sheet having excellent shearing quality and stretch-flangeabilty, and method for the same |
Non-Patent Citations (1)
| Title |
|---|
| PROC. INT. CONF. ON TRIP-AIDED HIGH STRENGTH FERROUS ALLOYS, 2002, pages 61 - 64 |
Also Published As
| Publication number | Publication date |
|---|---|
| EP4663803A1 (en) | 2025-12-17 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| KR101677396B1 (en) | Ultra high strength steel sheet having excellent formability and expandability, and method for manufacturing the same | |
| CN112752862A (en) | High-strength cold-rolled steel sheet having high hole expansibility, high-strength hot-dip galvanized steel sheet, and methods for producing these | |
| JP7440605B2 (en) | High strength steel plate and its manufacturing method | |
| JP7640703B2 (en) | High-strength steel plate with excellent workability and manufacturing method thereof | |
| CN111094612B (en) | Hot-rolled steel sheet and method for producing same | |
| TWI428454B (en) | Iron-based stainless steel cold-rolled steel sheet with excellent toughness and high corrosion resistance and its manufacturing method | |
| JP7743391B2 (en) | High-strength steel plate and manufacturing method thereof | |
| KR101463526B1 (en) | High-corrosion resistantce hot rolled ferritic stainless steel sheet with excellent toughness | |
| JP2024500851A (en) | Extra-thick steel material with excellent low-temperature impact toughness and its manufacturing method | |
| JP7852934B2 (en) | High-strength steel plate with excellent workability and method for manufacturing the same | |
| JP7006848B1 (en) | Steel sheets, members and their manufacturing methods | |
| JP2023554449A (en) | High-strength steel plate with excellent workability and its manufacturing method | |
| WO2021172298A1 (en) | Steel sheet, member, and methods respectively for producing said steel sheet and said member | |
| CN111133121A (en) | Hot-rolled steel sheet and method for producing same | |
| CA3108674C (en) | Steel for pressure vessel having excellent surface quality and impact toughness, and method for manufacturing same | |
| WO2021172297A1 (en) | Steel sheet, member, and methods respectively for producing said steel sheet and said member | |
| JP7712366B2 (en) | High-strength steel plate with excellent workability and manufacturing method thereof | |
| JP6573459B2 (en) | Ferritic stainless steel plate excellent in hole expansibility and manufacturing method thereof | |
| US20240167137A1 (en) | High strength cold rolled steel sheet for automotive use having excellent global formability and bending property | |
| WO2025257439A1 (en) | Micro-alloyed hot rolled strip with improved formability, above 700 mpa | |
| EP4663804A1 (en) | Micro-alloyed hot rolled strip with improved formability, up to 700 mpa | |
| WO2025204697A1 (en) | Stainless steel sheet and method for manufacturing same | |
| EP4592420A1 (en) | High-strength hot-rolled strip with very good edge formability | |
| WO2024251962A1 (en) | A high strength q&p steel strip or sheet, and a method for producing the same | |
| EP4627131A1 (en) | A cold rolled steel and a production process to it |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 121 | Ep: the epo has been informed by wipo that ep was designated in this application |
Ref document number: 25734614 Country of ref document: EP Kind code of ref document: A1 |