WO2025068356A1 - Use of a sulf-containing polymer for improving sun protection - Google Patents
Use of a sulf-containing polymer for improving sun protection Download PDFInfo
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- WO2025068356A1 WO2025068356A1 PCT/EP2024/077036 EP2024077036W WO2025068356A1 WO 2025068356 A1 WO2025068356 A1 WO 2025068356A1 EP 2024077036 W EP2024077036 W EP 2024077036W WO 2025068356 A1 WO2025068356 A1 WO 2025068356A1
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- A61K8/8158—Homopolymers or copolymers of amides or imides, e.g. (meth) acrylamide; Compositions of derivatives of such polymers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/37—Esters of carboxylic acids
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/49—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
- A61K8/494—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with more than one nitrogen as the only hetero atom
- A61K8/4966—Triazines or their condensed derivatives
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q17/00—Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
- A61Q17/04—Topical preparations for affording protection against sunlight or other radiation; Topical sun tanning preparations
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/02—Preparations for cleaning the hair
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/12—Preparations containing hair conditioners
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/48—Thickener, Thickening system
Definitions
- the present invention relates to the use of a polymer comprising one or more synthetic polymer units comprising repeating units of a structure of Formula (1) for increasing the UV and/or blue light absorption of one or more UV and/or blue light filters.
- the present invention refers to a sunscreen composition comprising such polymer, one or more UV and/or blue light filters and one or more cosmetically acceptable carriers.
- Exposure to sunlight can have desirable effects, such as stimulating the production of vitamin D and tanning the skin.
- the intensity or duration of exposure is too high, the lower wavelength UV-B light below 315 nm can cause erythema, a reddening of the skin, also known as sunburn.
- compositions comprise one or more UV and/or blue light filters such as UV filters.
- UV filters A high number of UV and/or blue light filters in different compositions are known in the art such as, e.g., shown in WO 2010/043588 and WO 2019/096960.
- UV and/or blue light filters can be classified in different ways such as as Bis-Ethylhexyloxyphenol Methoxyphenyl Triazine, oil soluble organic UV absorbers, sparingly soluble organic UV absorbers, inorganic UV absorbers, and water-soluble UV absorbers as shown in WO 2010/043588.
- the sun protection effect of the UV and/or blue light filters known in the art is not entirely satisfying.
- sun protection efficacy e.g., high sun protection factor (SPF)
- SPF sun protection factor
- UV and/or blue light filters that have comparably high efficacy per amount and thus allow using rather low amounts are rather poorly biodegradable.
- good biodegradability is desired, lower efficacy in sun protection must often be accepted or higher amounts of such UV and/or blue light filters required.
- high sun protection efficacy e.g., high sun protection factor (SPF)
- SPF sun protection factor
- particulate UV and/or blue light filters such as some inorganic agents, high amounts of such materials are comparably difficult to spread evenly on the skin and may lead to undesired bright spots on the skin.
- An aspect of the present invention relates to the use of a polymer comprising (or consisting of): (i) one or more synthetic polymer units comprising (or consisting of): (a) repeating units of a structure of Formula (1): wherein R 1 and R 2 are independently selected from H, methyl or ethyl; A is a linear or branched C 1 -C 12 -alkyl group; and Q + is a cosmetically acceptable cation; and (b) optionally one or more crosslinking or branching units; and (c) optionally one or more further repeating units which are different from a repeating unit of structure of Formula (1) and from the crosslinking or branching units crosslinking or branching units; and (ii) one or more water-soluble and/or water-swellable polysaccharide polymer units, for increasing the UV and/or blue light absorption of one or more UV and/or blue light filters.
- R 1 and R 2 are independently selected from H, methyl or ethyl
- A is
- such polymer comprising one or more synthetic polymer units comprising repeating units of a structure of Formula (1) leads to a significant improvement of sun protection effect when added to a composition comprising UV and/or blue light filter.
- the use of the present invention may be increasing the UV and/or blue light absorption of a UV and/or blue light filter in a composition comprising at least one UV and/or blue light filter and optionally one or more further cosmetically acceptable components.
- the polymer as used in the present invention may have a boosting effect on sun protection by increased UV and/or blue light absorption by influencing the spreadability of the sunscreen product on the skin. It will be understood that increased UV and/or blue light absorption typically leads to an increased sun protection factor (SPF) of the composition.
- SPF sun protection factor
- compositions of the present invention can be prepared as having a good biodegradability.
- the present invention relates to a method for sun protection, comprising the steps of: (I) providing a composition of: (a) one or more polymers comprising (or consisting of): (i) one or more synthetic polymer units comprising (or consisting of): (a) repeating units of a structure of Formula (1): wherein R 1 and R 2 are independently selected from H, methyl or ethyl; A is a linear or branched C1-C12-alkyl group; and Q + is a cosmetically acceptable cation; and (b) optionally one or more crosslinking or branching units; and (c) optionally one or more further repeating units which are different from a repeating unit of structure of Formula (1) and from the crosslinking or branching units crosslinking or branching units; and (ii) one or more water-soluble and/or water-swellable polysaccharide polymer units;
- the present invention further relates to a method for increasing the UV and/or blue light absorption of a composition comprising one or more UV and/or blue light filters, comprising the step of admixing one or more polymers to this composition, wherein the one or more polymers comprise (or consist of): (i) one or more synthetic polymer units comprising (or consisting of): (a) repeating units of a structure of Formula (1): wherein R 1 and R 2 are independently selected from H, methyl or ethyl; A is a linear or branched C 1 -C 12 -alkyl group; and Q + is a cosmetically acceptable cation; and (b) optionally one or more crosslinking or branching units; and (c) optionally one or more further repeating units which are different from a repeating unit of structure of Formula (1) and from the crosslinking or branching units crosslink
- Embodiments and aspects described herein may comprise or be combinable with elements, features or components of other embodiments and/or aspects despite not being expressly exemplified in combination, unless an incompatibility is stated.
- the terms “increasing” and “increase” may be understood in the broadest form as any enhancement of the respective value in comparison to a reasonable reference value.
- an increase is an enhancement by at least 1 %, more preferably by at least 5 %, even more preferably by at least 10 %, even more preferably by at least 25 % or even at least 50 % or more than 50 %, related to a reference value.
- the polymer according to Formula (1) may also be considered as a booster of sun protection effect of a UV and/or blue light filter.
- the reference value to which the increase relates to is a comparable composition without the polymer comprising one or more synthetic polymer units comprising repeating units of a structure of Formula (1).
- a “salt” is a cosmetically acceptable salt.
- a salt may be a charged form of a charged functional group such as, e.g., an –SO3- group, an amino group, a carboxylic acid group, etc.
- the counterion may be any counter ion. In at least one embodiment, the counter ion is a cosmetically acceptable counter ion.
- a counter ion is selected from the group consisting of H + , NH4 + , an organic ammonium ion [NHR 5 R 6 R 7 ] + wherein R 5 , R 6 , and R 7 independently of one another is hydrogen, a linear or branched alkyl group having 1 to 22 carbon atoms, a linear or branched, mono- or poly-unsaturated alkenyl group having 2 to 22 carbon atoms, a C6-C22 alkylamidopropyl group, a linear mono-hydroxyalkyl group having 2 to 10 carbon atoms or a linear or branched dihydroxyalkyl group having 3 to 15 carbon atoms, and wherein at least one of the radicals R 5 , R 6 , and R 7 is not hydrogen, or Q + is Li + , Na + , K + , 1 ⁇ 2 Ca ++ , 1 ⁇ 2 Mg ++ , 1 ⁇ 2 Zn ++ , 1/3 Al +++ , or combinations thereof.
- a 1 % gel of the polymer as used herein, in particular wherein the polymer is a hybrid polymer, of the invention in deionized water has a mesh size as described above and a yield point as described above.
- a 1 % gel of the polymer as used herein, in particular wherein the polymer is a hybrid polymer, of the invention in deionized water has a tan delta as described above and a yield point as described above.
- the polymer is a polymer as used herein, in particular wherein the polymer is a hybrid polymer, that is readily biodegradable, which means that the polymer as used herein, in particular wherein the polymer is a hybrid polymer, has a biodegradability of at least 60%, determined according to OECD Method 301 B.
- the polymer as used herein, in particular wherein the polymer is a hybrid polymer, of the invention is inherently biodegradable (OECD 302).
- Example embodiments of polymer as used herein, in particular wherein the polymer is a hybrid polymers, where the polysaccharide polymer unit is glucomannan are given in the following Table 1: Table 1.
- the radical precipitation polymerization is carried out in a polar solvent mixture comprising (or consisting of): I) water and II) a further compound.
- the compound II) is polar and organic.
- the compound II) is selected from polar alcohols and ketones.
- the compound II) is one or more polar alcohols and one or more ketones.
- the initiator is an organic peroxide selected from the group consisting of benzoyl peroxide, tert-butyl hydroperoxide, di-tert-butyl hydroperoxide, triphenylmethyl hydroperoxide, methyl ethyl ketone peroxide, cumene hydroperoxide, dilauroyl peroxide (DLP), and mixtures thereof.
- the polymerization is carried out in the presence of dimethyl 2,2'-azobis(2-methylpropionate), 2,2-azobis(2,4- dimethylvaleronitril) or dilauroyl peroxide (DLP).
- the initiator is an azo initiator selected from the group consisting of azo-bis-isobutyronitrile (AIBN) and azobisamideopropyl hydrochloride (ABAH).
- AIBN azo-bis-isobutyronitrile
- ABAH azobisamideopropyl hydrochloride
- the initiator is a persulfate selected from the group consisting of potassium peroxidisulfate, potassium peroxidisulfate, ammonium peroxidisulfate, potassium peroxi mono sulfat, sodium peroximonosulfate, ammonium peroximonosulfate, and mixtures thereof.
- Organic persulfates are also useful.
- the initiator is selected from the group consisting of inorganic peroxy compounds, such as (NH4)2S2O8, K2S2O8 or H2O2, for example, where appropriate in combination with reducing agents (e.g., sodium hydrogensulfite, ascorbic acid, iron(II) sulfate) or redox systems comprising as reducing component an aliphatic or aromatic sulfonic acid (e.g., benzenesulfonic acid, toluenesulfonic acid, etc.).
- reducing agents e.g., sodium hydrogensulfite, ascorbic acid, iron(II) sulfate
- redox systems comprising as reducing component an aliphatic or aromatic sulfonic acid (e.g., benzenesulfonic acid, toluenesulfonic acid, etc.).
- the structure of the hybrid polymer is such that a polysaccharide polymer unit is a backbone onto which one or more synthetic
- the initiator is a mixture of a redox initiator and an azo initiator. This has the advantage that a redox initiator system generates significant amount of –O* radicals on polysaccharide backbone and azo initiator will deliver enough active synthetic polymer unit chains. The combination of a redox initiator and an azo initiator will increase the amount of grafted synthetic polymer unit chains on polysaccharide backbone.
- the initiator is a mixture of ammonium peroxidisulfate and sodium sulfite, potassium peroxidisulfate and sodium sulfite, ammonium peroxidisulfate and ascorbic acid, sodium peroxidisulfate and ascorbic acid, ammonium peroxidisulfate and N,N,N',N'-tetramethylene diamine, potassium peroxidisulfate and N,N,N',N'-tetramethylene diamine, ammonium peroximonosulfate and N,N,N',N'-tetramethylene diamine, ammonium peroximonosulfate and ascorbic acid, ammonium peroximonosulfate and thiourea, ammonium peroximonosulfate and malonic acid, ammonium peroximonosulfate and glycolic acid, ammoniumperoxi-monosulfate and malic acid, 2-hydroxy-2- sulfonatoacetic
- the polymerization comprises the step of treating the water-soluble and/or water-swellable polysaccharide polymer unit with water prior to polymerization. This water treatment step preferably results in a homogenous distribution of water molecules in the polysaccharide polymer unit.
- the polymerization comprises the step of recovering the polymer, in particular wherein the polymer is a hybrid polymer, after polymerization.
- the compound II) is polar and organic. In at least one embodiment the compound II) is selected from polar alcohols and ketones. In at least one embodiment the compound II) is one or more polar alcohols and one or more ketones.
- the compound II) is selected from the group consisting of methanol, ethanol, 1-propanol, 2-propanol, 2-methyl-2-propanol, 1- butanol, 2-butanol, dimethyl ketone, diethyl ketone, pentan-2-one, butanone, tetrahydropyran, tetrahydrofuran, 2-methyl-tetrahydrofuran, 1,3-dioxane, 1,4- dioxane, preferably 2-propanol, 2-methyl-2-propanol, dimethyl ketone, tetrahydrofuran, 2-methyl-tetrahydrofuran, more preferably 2-methyl-2-propanol and dimethyl ketone.
- the compound II) is 2-methyl-2-propanol.
- the solvent mixture contains from 0.5 to 10 wt.-%, preferably from 1 to 8 wt.-% and more preferably from 2 to 5 wt.-% water.
- the solvent mixture contains from 90 to 99.5 wt.-%, preferably from 92 to 99 wt.-% and more preferably from 95 to 98 wt.-% 2-methyl- 2-propanol.
- the solvent mixture contains water and 2-methyl-2- propanol.
- the solvent mixture contains from 0.5 to 10 wt.-%, preferably from 1 to 8 wt.-% and more preferably from 2 to 5 wt.-% water, and from 90 to 99.5 wt.-%, preferably from 92 to 99 wt.-% and more preferably from 95 to 98 wt.-% 2-methyl-2-propanol.
- the solvent mixture contains from 0.5 to 10 wt.-% water, from 1 to 98.5 wt.-% 2-methyl-2-propanol and from 1 to 98.5 wt.-% dimethyl ketone, preferably from 0.5 to 7.5 wt.-% water, from 5 to 94.5 wt.-% 2-methyl-2- propanol and from 5 to 94.5 wt.-% dimethyl ketone.
- the monomers resulting in units (a) and/or (b) are neutralized with a base prior to the polymerization, and/or the hybrid polymer after polymerization is neutralized with a base.
- the base is selected from bases comprising an ion selected the group consisting of Li + , Na + , K + , Ca ++ , Mg ++ , Zn ++ , Al +++ , and combinations thereof; preferably wherein the base is selected from hydroxides, carbonates and hydrogen carbonates comprising an ion selected the group consisting of Li + , Na + , K + , Ca ++ , Mg ++ , Zn ++ , Al +++ , and combinations thereof.
- the composition comprises from 0.1 to 10 wt.-%, preferably from 0.1 to 2.5 wt.-%, more preferably from 0.1 to 1.0 wt.-%, also more preferably from 0.5 to 2.5 wt.-%, even more preferably from 0.5 to 1.0 wt.-% of the polymer, in particular a hybrid polymer, related to the total weight of the composition.
- the cosmetic composition of the present invention is a skin care composition.
- the cosmetic composition of the present invention is selected from the group consisting of body wash, facial cleanser, cleansing mask, bubble bath, bath oil, cleansing milk, micellar water, make-up remover, cleansing wipes, perfume, soaps, shaving soap, shaving foam, cleansing foam, face mask, intimate wash, micellar water, liquid soap, day cream, anti-aging cream, body milk, body lotion, body mousse, serum (e.g., face serum), eye cream, sunscreen lotion, sunscreen spray, sunscreen gel, sun cream, sun care milk, sun care gel, acne cream, after-shave lotion, pre-shaving cream, depilatory cream, skin-whitening gel, whitening cream, self-tanning cream, anti- acne gel, mascara, foundation, primer, concealer, blush, bronzer, blemish balm (bb) cream, eyeliner, night cream, eye brow gel, highlighter, lip stain, hand sanitizer, nail varnish remover, skin conditioner, split end fluid, deodorant, antiperspirant, baby cream, insect repellent
- the cosmetic composition of the present invention is selected from the group consisting of body wash, facial cleanser, bath oil, cleansing milk, shaving foam, face mask, day cream, anti-aging cream, body milk, body lotion, body mousse, serum (e.g., face serum), eye cream, sunscreen lotion, sun cream, face cream, after-shave lotion, pre-shaving cream, depilatory cream, blemish balm (bb) cream, night cream, highlighter, lip stain, skin conditioner, deodorant, antiperspirant, baby cream, hand cream, sunscreen gel, foot cream, cellulite treatment, nail cuticle cream, lip balm, bath additive, eau de toilette, lubricating gel, moisturizer, cream gel, lip stick, lip gloss, body oil, shower milk, lip crayon, and sunblock.
- serum e.g., face serum
- eye cream sunscreen lotion
- sun cream sun cream
- face cream after-shave lotion
- pre-shaving cream depilatory cream
- blemish balm (bb) cream night cream, highlight
- the cosmetic composition of the present invention is selected from the group consisting of bath oil, cleansing milk, day cream, anti- aging cream, body milk, body lotion, serum (e.g., face serum), eye cream, sunscreen lotion, face cream, pre-shaving cream, night cream, baby cream, hand cream, foot cream, nail cuticle cream, lip balm, moisturizer, lip stick, lip gloss, body oil, and sunblock.
- the cosmetic composition of the present invention is a sunscreen composition.
- the cosmetic composition of the present invention is selected from the group consisting of sunscreen lotion, sunscreen spray, sunscreen gel, sun cream, sun care milk, and sun care gel.
- the cosmetic composition of the present invention is a hair cosmetic composition, such as a hair care composition.
- the cosmetic composition of the present invention is selected from the group consisting of hair styling gel, hair styling cream, hair shine serum, hair colorant, split end fluid, and means for scalp treatment.
- the polymer comprises (or consists of): (i) from 1 wt.-% to 95 wt.-%, preferably from 5 wt.-% to 70 wt.-%, more preferably from 5 wt.-% to 60 wt.-%, even more preferably from 10 wt.-% to 50 wt.-%, even more preferably from 15 wt.-% to 40 wt.-%, even more preferably from 20 wt.-% to 40 wt.-%, in particular from 25 wt.-% to 40 wt.- %, relative to the total mass of the polymer, of a synthetic polymer unit, comprising (or consisting of): (a) from 40 wt.-% to 99.9 wt.-%, preferably from 80 wt.-% to 99.9 wt.-%, in particular from 96
- the polymer comprises (or consists of): (i) from 25 wt.-% to 40 wt.-%, relative to the total mass of the polymer, of a synthetic polymer unit, comprising (or consisting of): (a) from 96 wt.-% to 99.9 wt.-%, relative to the total mass of the synthetic polymer unit, of one or more repeating units of a structure of Formula (1); (b) from 0.01 wt.-% to 3 wt.-%, relative to the total mass of the synthetic polymer unit, of one or more crosslinking or branching units; and (c) from 0 wt.-% to 1 wt.-%, relative to the total mass of the synthetic polymer unit, of one or more repeating neutral structural units; and (ii) from 60 wt.-% to 75 wt.-%, relative to the total mass of the polymer, of a water-soluble and/or water-swellable polysaccharide poly
- the one or more polysaccharide polymer units comprise from 1 wt.-% to 100 wt.-%, preferably from 25 wt.-% to 100 wt.-%, in particular from 50 wt.-% to 100 wt.-% bio-based carbon content, relative to the total mass of carbon in the one or more polysaccharide polymer units, measured according to standard ASTM D6866-12, Method B.
- the repeating units of a structure of Formula (1) comprise from 1 wt.-% to 100 wt.-%, preferably from 25 wt.-% to 100 wt.-%, in particular from 50 wt.-% to 100 wt.-% bio-based carbon content, relative to the total mass of carbon in the repeating units of a structure of Formula (1), measured according to standard ASTM D6866-12, Method B.
- the one or more further repeating units comprise from 1 wt.-% to 100 wt.-%, preferably from 25 wt.-% to 100 wt.-%, in particular from 50 wt.-% to 100 wt.-% bio-based carbon content, relative to the total mass of carbon in the one or more further repeating units, measured according to standard ASTM D6866-12, Method B.
- UV and/or blue light filter A UV and/or blue light filter may be any agent that is suitable for filtering (i.e., absorbing, reflecting and/or scattering, preferably absorbing and optionally also reflecting and/or scattering) UV and/or blue light as generally understood in the art.
- the UV and/or blue light filter is able to absorb and/or reflect and/or scatter, preferably able to absorb, UV light (wavelength range below 400 nm, preferably from 100 to 399 nm) and/or blue light (wavelength range from 400 to 490 nm).
- the UV and/or blue light filter is able to absorb and/or reflect and/or scatter, preferably able to absorb, UV-B (wavelength range from 290 to 319 nm) and/or UV-A (wavelength range from 320 to 399 nm) and optionally also UV-C (wavelength range below 290 nm, preferably from 100 to 289 nm) irradiation.
- the UV and/or blue light filter is able to absorb and/or reflect and/or scatter, preferably able to absorb, blue light irradiation.
- the UV and/or blue light filter is able to absorb and/or reflect and/or scatter, preferably able to absorb, UV-A and reflect blue light (wavelength range from 380 to 450 nm) irradiation and optionally also UV-B and/or UV-C irradiation.
- the UV and/or blue light filter is able to absorb and/or reflect and/or scatter, preferably able to absorb, UV-B and optionally also UV-A and optionally also UV-C irradiation.
- a UV and/or blue light filter is such as described in any of WO 2010/043588 or WO 2019/096960.
- the one or more UV and/or blue light filters are selected from the group consisting of organic UV-screening agents of the oxalanilide type, of the triazine type, of the benzotriazole type, of the vinylamide type, of the cinnamide type, of the type comprising one or more groups which are benzazole and/or benzofuran, benzothiophene, of the indole type, of the aryl vinylene ketone type, of the phenylene bis-benzoxazinone derivative type, of the amide, sulfonamide or acrylonitrile carbamate derivative type, or mixtures thereof.
- At least one of the one or more UV and/or blue light filters is an organic UV and/or blue light filter. In at least one embodiment, at least one of the one or more UV and/or blue light filters is a soluble organic UV and/or blue light filter. In at least one embodiment, at least one of the one or more UV and/or blue light filters is an inorganic UV and/or blue light filter. In at least one embodiment, at least one of the one or more UV and/or blue light filters is an insoluble inorganic UV and/or blue light filter.
- At least one of the one or more UV and/or blue light filters is selected from the group consisting of anthranilates, cinnamic derivatives, dibenzoylmethane derivatives, salicylic derivatives, camphor derivatives, triazine derivatives, benzophenone derivatives, beta,beta’-diphenylacrylate derivatives, benzotriazole derivatives, benzalmalonate derivatives, benzimidazole derivatives, imidazolines, bis-benzazolyl derivatives, p-aminobenzoic acid (PABA) derivatives, benzothiazine derivatives, screening polymers and screening silicones (e.g., Polysilicone 15), alpha-alkylstyrene-based dimers, 4,4-diarylbutadienes, methoxypropylamino cyclohexanylidene ethoxycyanoacetate, methoxypropylamino cyclohexenylidene e
- At least one of the one or more UV and/or blue light filters is selected from the group consisting of anthranilates, cinnamic compounds, dibenzoylmethane compounds, salicylic compounds, camphor compounds, triazine compounds, benzophenone compounds, beta,beta’-diphenylacrylate compounds, benzotriazole compounds, benzalmalonate compounds, benzimidazole compounds, imidazolines, bis-benzazolyl compounds, p- aminobenzoic acid (PABA) compounds, benzothiazine compounds, screening polymers and screening silicones (e.g., Polysilicone 15), alpha-alkylstyrene-based dimers, 4,4-diarylbutadienes, methoxypropylamino cyclohexanylidene ethoxycyanoacetate, methoxypropylamino cyclohexenylidene ethoxyethylcyanoacetate, ethy
- the one or more UV and/or blue light filters are selected from the group consisting of: 4-Aminobenzoic acid (PABA, p-aminobenzoic acid), Polyoxyethylene ethyl-4-aminobenzoate (PEG-25 PABA, Ethoxylated Ethyl-4- Aminobenzoate), 2-Ethylhexyl 4-(dimethylamino)benzoate (Ethylhexyl Dimethyl PABA, Padimate O, 4- dimethyl aminobenzic acid-2-ethylhexylester), Methyl N,N,N-trimethyl-4-[(4,7,7-trimethyl-3-oxobicyclo[2.2.1]hept-2- ylidene)methyl]anilinium Sulphate (Camphor benzalkonium methosulfate, 4-[(2- Oxo-3-bornylidene)methyl]phenyltrimethylammonium methyl sulfate), (1,4-Phen
- the one or more UV and/or blue light filters are selected from the group consisting of butyl methoxydibenzoylmethane, octocrylene, bis-ethylhexyloxyphenol methoxyphenyl triazine, ethylhexyl triazone, ethylhexyl salicylate, diethylamino hydroxybenzoyl hexyl benzoate, ethylhexyl methoxycinnamate, diethylhexyl butamido triazone, dometrizole trisiloxane, phenylbenzimidazole sulfonic acid, methylene bis-benzotriazolyl tetramethylbutylphenol, terephthalydidene dicamphor sulfonic acid, 4- methylbenzylidene camphor, polysilicone-15, isoamyl p-methoxycinnamate, disodium
- UV and/or blue light filters may also be such as disclosed in WO2013017262A1, from page 32, line 11 to the end of page 33 and/or in EP 1084696.
- the UV and/or blue light filter is selected from the group consisting of: (A) an oil soluble organic UV absorber, preferably selected from the group consisting of Bis-Ethylhexyloxyphenol Methoxyphenyl Triazine, Butyl Methoxydibenzoylmethane, Ethylhexyl Methoxycinnamate, Octocrylene, Oxybenzone, Sulisobenzone, Diethylhexyl Butamido Triazone, Drometrizole Trisiloxane, Ethylhexyl Salicylate, Ethylhexyl Triazone, Homosalate, Octisalate, lsoamyl p-Methoxycinnamate, 4-Methylbenzylidene Camphor, Poly
- the one or more UV and/or blue light filters are selected from the group consisting of Bis-Ethylhexyloxyphenol Methoxyphenyl Triazine, Ethylhexyl Methoxycinnamate, Octocrylene, Butyl Methoxydibenzoylmethane, Ethylhexyl Salicylate, Butylmethoxydibenzoylmethane, Phenylbenzimidazolesulfonic Acid, Terephthalylidenedicamphorsulfonic Acid, Benzophenone-3, Benzophenone-4, Benzophenone-5,4- Ethylbenzylidenecamphor, Benzimidazilate, Anisotriazine, Ethylhexyl Triazone, Diethylhexyl Butamidotriazone, Drometrizole Trisiloxane, Methoxypropylamino Cyclohexanylidene Etohycyan
- the sparingly soluble organic UV absorber are micronized.
- the one or more UV and/or blue light filters comprise or consist of a combination of two, three, four or more than four UV and/or blue light filters are used.
- the one or more UV and/or blue light filters comprise or consist of the following UV and/or blue light filters: Butyl Methoxydibenzoylmethane, Bis-Ethylhexyloxyphenol Methoxyphenyl triazine, Ethylhexyl Triazone, Phenylbenzimidazole sulfonic acid, and Diethylamino hydroxybenzoyl hexyl benzoate.
- the one or more UV and/or blue light filters comprise or consist of the following UV and/or blue light filters: Homosalate, Octocrylene, Ethylhexyl salicylate, Butyl Methoxydibenzoylmethane, Ethyl Triazine, Drometrizole Trisiloxane, and Benzyl Salicylate.
- the one or more UV and/or blue light filters comprise or consist of the following UV and/or blue light filters: Ethylhexyl Salicylate, Bis- Ethylhexyloxyphenol Methoxyphenyl triazine, Butyl Methoxydibenzoylmethane, Ethylhexyl Triazone, and Phenylbenzimidazole sulfonic acid.
- the one or more UV and/or blue light filters comprise or consist of the following UV and/or blue light filters: zinc oxide (nano) and titanium oxide (nano).
- the one or more UV and/or blue light filters comprise or consist of the following UV and/or blue light filters: Zinc oxide, Octocrylene, Ethylhexyl Salicylate, Diethylamino Hydroxybenzoyl Hexyl Benzoate, Titanium oxide, Homosalate, Ethylhexyl Triazone Polysilicone-15, and Bis-ethylhexyloxyphenol methoxyphenyl Triazine
- the one or more UV and/or blue light filters comprise or consist of the following UV and/or blue light filters: Homosalate, Butyl Methoxydibenzoylmethane, Ethylhexyl Salicylate, Octocrylene, and Phenylbenzimidazole Sulfonic Acid.
- the one or more UV and/or blue light filters comprise or consist of the following UV and/or blue light filters: Avobenzone, Homosalate, of Octisalate, and Zinc Oxide, preferably comprising or consisting of: 2.3 wt.%, based on the composition as a whole, of Avobenzone, 10.0 wt.%, based on the composition as a whole, of Homosalate, 5.0 wt.%, based on the composition as a whole, of Octisalate, and 5.0 wt.%, based on the composition as a whole, of Zinc Oxide.
- the one or more UV and/or blue light filters comprise or consist of the following UV and/or blue light filters: Butyl Methoxydibenzoylmethane, Titanium oxide, Octocrylene, Ethylhexyl Triazone, Methylene Bis-Benzotriazolyl Tetramethylbutylphenol (nano), Methylene Bis- Benzotriazolyl Tetramethylbutylphenol, Drometrizole trisiloxane, and Terephthalylidene Dicamphor Sulfonic Acid.
- the one or more UV and/or blue light filters comprise or consist of the following UV and/or blue light filters: Ethylhexyl Methoxycinnamate (EHMC), 1 Ethylhexyl Triazone (EHT), and Diethylamino hydroxybenzoyl hexyl benzoate (DHHB), preferably comprising or consisting of: 10 wt.%, based on the composition as a whole, of Ethylhexyl Methoxycinnamate (EHMC), 1 wt.%, based on the composition as a whole, of Ethylhexyl Triazone (EHT), and 8 wt.%, based on the composition as a whole, of Diethylamino hydroxybenzoyl hexyl benzoate (DHHB).
- EHMC Ethylhexyl Methoxycinnamate
- EHT Ethylhexyl Triazone
- DHHB Diethylamin
- the one or more UV and/or blue light filters comprise or consist of the following UV and/or blue light filters: Ethylhexyl Methoxycinnamate (EHMC), 2 Ethylhexyl Triazone (EHT), Diethylamino hydroxybenzoyl hexyl benzoate (DHHB), and Bis-Ethylhexyloxyphenol Methoxyphenyl Triazine (BEMT), preferably comprising or consisting of: 10 wt.%, based on the composition as a whole, of Ethylhexyl Methoxycinnamate (EHMC), 2.5 wt.%, based on the composition as a whole, of Ethylhexyl Triazone (EHT), 10 wt.%, based on the composition as a whole, of Diethylamino hydroxybenzoyl hexyl benzoate (DHHB), and 3 wt.%, based on the composition as DHHB
- the one or more UV and/or blue light filters comprise or consist of the following UV and/or blue light filters: Ethylhexyl Triazone (EHT), Diethylamino hydroxybenzoyl hexyl benzoate (DHHB), and Bis- Ethylhexyloxyphenol Methoxyphenyl Triazine (BEMT), preferably comprising or consisting of: 3 wt.%, based on the composition as a whole, of Ethylhexyl Triazone (EHT), 10 wt.%, based on the composition as a whole, of Diethylamino hydroxybenzoyl hexyl benzoate (DHHB), and 3 wt.%, based on the composition as a whole, of Bis-Ethylhexyloxyphenol Methoxyphenyl Triazine (BEMT).
- EHT Ethylhexyl Triazone
- DHHB Diethylamino hydroxybenzoyl he
- the one or more UV and/or blue light filters comprise or consist of the following UV and/or blue light filters: Ethylhexyl Triazone (EHT), Diethylamino hydroxybenzoyl hexyl benzoate (DHHB), Bis-Ethylhexyloxyphenol Methoxyphenyl Triazine (BEMT), and phenylbenzimidazole sulfonic acid (PBSA), preferably comprising or consisting of: 3 wt.%, based on the composition as a whole, of Ethylhexyl Triazone (EHT), 7 wt.%, based on the composition as a whole, of Diethylamino hydroxybenzoyl hexyl benzoate (DHHB), 4 wt.%, based on the composition as a whole, of Bis-Ethylhexyloxyphenol Methoxyphenyl Triazine (BEMT), and 4 wt.%, based on
- Cosmetic composition The use of the present invention may be carried out in any composition comprising at least one polymer as described herein and at least one UV and/or blue light filter.
- such composition is a cosmetic composition, also designatable as cosmetically acceptable composition.
- such composition further comprises at least one carrier.
- the use is carried out in a cosmetic composition serving for sun protection (also: sunscreen composition).
- the use is carried out in a sunscreen, in particular a sunscreen lotion, sun cream, sunscreen gel, sun spray, or a sunblock.
- Carrier A cosmetic composition may optionally also comprise one or more carriers as component (C).
- a carrier is preferably a cosmetically acceptable carrier.
- a carrier may be useful for providing the compounds used in present invention in liquid form.
- the carrier is a cosmetically acceptable carrier.
- the composition comprises at least 10 wt.-% water. Water is useful for economic reasons but also because it is highly cosmetically acceptable.
- the composition comprises water-miscible or water-soluble solvents such as lower alkyl alcohols.
- the composition comprises C1-C5 alkyl monohydric alcohols, preferably C2-C3 alkyl alcohols.
- the alcohols which may be present are in particular lower monohydric or polyhydric alcohols having 1 to 4 carbon atoms customarily used for cosmetic purposes, such as preferably ethanol and isopropanol.
- the composition comprises a water-soluble polyhydric alcohol.
- the water-soluble polyhydric alcohols are polyhydric alcohols having two or more hydroxyl groups in the molecule.
- the water-soluble polyhydric alcohol is selected from the group consisting of: dihydric alcohols such as ethylene glycol, propylene glycol, trimethylene glycol, 1,2-butylene glycol, 1,3-butylene glycol, 1,4-butylene glycol, tetramethylene glycol, 2,3-butylene glycol, pentamethylene glycol, 2-butene-1,4- diol, hexylene glycol, octylene glycol; trihydric alcohols such as glycerine, trimethylol propane, 1,2,6-hexanetriol and the like; tetrahydric alcohols such as penthaerythritol; pentahydric alcohols such as xylytol, etc.; hexahydric alcohols such as sorbitol, mannitol; polyhydric alcohols such as ethylene glycol
- the composition comprises a cosmetically acceptable carrier selected from the group consisting of water, glycols, ethanol, and combinations thereof.
- the composition comprises an aqueous, alcoholic or aqueous-alcoholic carrier, and wherein the aqueous, alcoholic or aqueous-alcoholic carrier comprises water, ethanol, propanol, isopropanol, 1,2-propylene glycol, 1,3-propylene glycol, isobutanol, butanol, butyl glycol, butyl diglycol, glycerol, or a mixture thereof; preferably wherein the aqueous, alcoholic or aqueous-alcoholic solvent comprises water, ethanol, propanol, isopropanol, 1,2-propylene glycol, 1,3-propylene glycol, glycerol, or mixtures thereof; more preferably wherein the aqueous, alcoholic or aqueous-alcoholic carrier comprises water, isopropanol, 1,2-propylene
- the composition comprises a carrier selected from the group consisting of plant oil, honey, plant- derived sugar compositions, and mixtures thereof.
- the composition may be thickened, i.e., may have viscous flow properties. Viscosity
- the composition has a viscosity of from 0 mPas to 250,000 mPas, or from 1 mPas to 250,000 mPas, or from 50,000 mPas to 200,000 mPas, or from 50,000 mPas to 100,000 mPas.
- the composition has a viscosity of from 0.1 mPas to 50,000 mPas, or from 1 mPas to 20,000 mPas, or from 1 mPas to 10,000 mPas, or from 1 mPas to 5,000 mPas, or from 5 mPas to 3,500 mPas (each referred to at 25°C).
- the composition may have a viscosity of 1 mPas to 5 mPas (e.g., when used as a spray, a mist, or a water thin product), may have a viscosity of 5,000 mPas to 15,000 mPas (e.g., when used as a serum), may have a viscosity of 15,000 mPas to 50,000 mPas (e.g., when used as a lotion), may have a viscosity of 50,000 mPas to 250,000 mPas (e.g., when used as a cream), may have a viscosity of 20,000 mPas to 70,000 mPas (e.g., when used as a gel), may have a viscosity of 7,500 mPas to 20,000 mPas (e.g., when used as a shampoo or a foaming gel), may have a viscosity of 50,000 mP
- the viscosity measurement conditions are defined in the definitions section above. Viscosity may be important for anti-drip reasons. Dripping can be inconvenient for the user. Furthermore, more viscous compositions can be useful for measured dispensing.
- the composition has a viscosity of from 0 mPas to 1,000 mPas, or from 1 mPas to 1,000 mPas. This viscosity range is advantageous when the composition is in the form of a facial cleanser in view of the need for distribution on skin and ability to rinse off.
- the composition further comprises a viscosity- modifying substance.
- the viscosity-modifying substance is preferably a thickening polymer.
- the thickening polymer selected from the group consisting of: copolymers of at least one first monomer type, which is chosen from acrylic acid and methacrylic acid, and at least one second monomer type, which is chosen from esters of acrylic acid and ethoxylated fatty alcohol; crosslinked polyacrylic acid; crosslinked copolymers of at least one first monomer type, which is chosen from acrylic acid and methacrylic acid, and at least one second monomer type, which is chosen from esters of acrylic acid with C 10 - to C 30 -alcohols; copolymers of at least one first monomer type, which is chosen from acrylic acid and methacrylic acid, and at least one second monomer type, which is chosen from esters of itaconic acid and ethoxylated fatty alcohol; copolymers of at least one first monomer type, which is chosen from acrylic acid and methacrylic acid, at least one second monomer type, which is chosen from esters of itaconic acid and ethoxylated fatty alcohol; copo
- the composition may have any pH range.
- the composition has a pH value of from 2.0 to 12.0, preferably from 3.0 to 9.0, more preferably from 4.5 to 8. By varying the pH value, a composition can be made available that is suitable for different applications.
- the composition comprises an alkalizing agent or pH adjusting agent.
- ammonia or caustic soda is suitable, but water-soluble, physiologically tolerable salts of organic and inorganic bases can also be considered.
- the pH adjusting agent is selected from ammonium hydrogen carbonate, ammonia, monoethanolamine, ammonium carbonate.
- the alkalizing agents is selected from the group consisting of 2-amino-2-methyl-1-propanol, 2-amino-2- methyl-1,3-propanediol, 2-amino-2-ethyl-1,3-propanediol, tris(hydroxyl-methyl)- aminomethane, 2-amino-1-butanole, tris-(2-hydroxypropyl)-amine, 2,2-iminobisethanol, lysine, iminourea (guanidine carbonate), tetrahydro-1,4- oxazine, 2-amino-5-guanidin-valeric acid, 2-aminoethansulfonic acid, diethanolamine, triethanolamine, N-methyl ethanolamine, isopropanolamine, diisopropanolamine, triisopropanolamine, glucamine, sodium hydroxide, potassium hydroxide, lithium hydroxide and magnesium oxide, and mixtures thereof.
- the composition comprises an acid selected from the group consisting of hydrochloric acid, phosphoric acid, acetic acid, formic acid, sulfuric acid, hydrochloric acid, citric acid, and mixtures thereof. Citric acid is most preferred in that it has high consumer acceptance.
- the acidic pH is adjusted with a buffer such as a phosphate buffer, a TRIS buffer or a citric buffer. The buffers may be used alone or in combination with an acid.
- the composition is in liquid form, which may also comprise a viscous form.
- the composition is in solid form.
- the composition is in powdered or granulated form.
- a solid form can be achieved by spray drying the composition, the employment of a rotary evaporator, by drying on trays at temperature above the boiling point of the solvent, in vacuum, by drying in the reactor, in vertical or horizontal powder dryers, by atmospheric, pressure or vacuum filtration with subsequent drying of the wet filtrate.
- the composition can be converted into liquid form after it has been shipped e.g. by adding water.
- surfactants A cosmetic composition may optionally also comprise one or more surfactants as component (D). In at least one embodiment, the composition comprises a surfactant or surfactant system.
- the surfactant or surfactant system comprises a surfactant selected from the group consisting of anionic surfactants, cationic surfactants, non-ionic surfactants, zwitterionic surfactants and/or amphoteric surfactants.
- the composition comprises a total amount of surfactant of from 0.01 wt.-% to 70 wt.-%, from 0.1 wt.-% to 40%, from 1 wt.-% to 30%, from 2 wt.-% to 20 wt.-%.
- the composition comprises a non-ionic surfactant. Such non-ionic surfactants may also be used as emulsifiers.
- the non-ionic surfactant has an HLB (Hydrophilic Lipophilic Balance) of greater than 12.
- the non-ionic surfactant is selected from the group consisting of ethoxylated or ethoxylated/propoxylated fatty alcohols with a fatty chain comprising from 12 to 22 carbon atoms, ethoxylated sterols, such as stearyl- or lauryl alcohol (EO-7), PEG-16 soya sterol or PEG-10 soya sterol, polyoxyethylene polyoxypropylene block polymers (poloxamers), and mixtures thereof.
- HLB Hydrophilic Lipophilic Balance
- the non-ionic surfactant is selected from the group consisting of ethoxylated fatty alcohols, fatty acids, fatty acid glycerides or alkylphenols, in particular addition products of from 2 to 30 mol of ethylene oxide and/or 1 to 5 mol of propylene oxide onto C8- to C22-fatty alcohols, onto C12- to C22-fatty acids or onto alkyl phenols having 8 to 15 carbon atoms in the alkyl group, C 12 - to C 22 -fatty acid mono- and diesters of addition products of from 1 to 30 mol of ethylene oxide onto glycerol, addition products of from 5 to 60 mol of ethylene oxide onto castor oil or onto hydrogenated castor oil, fatty acid sugar esters, in particular esters of sucrose and one or two C 8 - to C 22 -fatty acids, INCI: Sucrose Cocoate, Sucrose Dilaurate, Sucrose Distearate, Sucrose Laurate, Sucrose Myr
- the non-ionic surfactant is selected from the group consisting of fatty alcohol ethoxylates (alkylpolyethylene glycols), alkylphenol polyethylene glycols, alkylmercaptan polyethylene glycols, fatty amine ethoxylates (alkylaminopolyethylene glycols), fatty acid ethoxylates (acylpolyethylene glycols), polypropylene glycol ethoxylates (Pluronics â ), fatty acid alkylol amides, (fatty acid amide polyethylene glycols), N-alkyl-, N-alkoxypolyhydroxy-fatty acid amide, sucrose esters, sorbitol esters, polyglycol ethers, and mixtures thereof.
- fatty alcohol ethoxylates alkylpolyethylene glycols
- alkylphenol polyethylene glycols alkylmercaptan polyethylene glycols
- fatty amine ethoxylates alkylaminopol
- the conditioning agent is a silicone (e.g., silicone oil, cationic silicone, silicone gum, high refractive silicone, and silicone resin), an organic conditioning oil (e.g., hydrocarbon oils, polyolefins, and fatty esters), or combinations thereof.
- the conditioning agent is a silicone, and wherein the composition comprises from 0.01 wt.-% to 10 wt.-%, or from 0.1 wt.-% to 5 wt.-% silicone conditioning agent, by total weight of the composition. Suitable silicone conditioning agents, and optional suspending agents for the silicone, are described in US 5,104,646.
- the composition comprises a silicone gum selected from the group consisting of polydimethylsiloxane, (polydimethylsiloxane) (methylvinylsiloxane) copolymer, poly(dimethylsiloxane) (diphenylsiloxane) (methylvinylsiloxane) copolymer, and mixtures thereof.
- the composition comprises a terminal aminosilicone.
- Terminal aminosilicone as defined herein means silicone comprising one or more amino groups at one or both ends of the silicone backbone.
- the composition is substantially free of any silicone compound comprising pendant amino groups.
- the composition is substantially free of any silicone compound other than terminal aminosilicones.
- the amino group at least one terminus of the silicone backbone of the terminal aminosilicone is selected from the group consisting of primary amines, secondary amines and tertiary amines.
- the composition comprises a terminal aminosilicone conforming to Formula (S): (R F )aG3-a-Si-(-OSiG2)n-O-SiG3-a(R F ) a (S) wherein G is hydrogen, phenyl, hydroxy, or C1-C8 alkyl, preferably methyl; a is an integer having a value from 1 to 3, preferably 1; b is 0, 1 or 2, preferably 1; n is a number from 0 to 1,999; R F is a monovalent radical conforming to the general formula CqH2qL, wherein q is an integer having a value from 2 to 8 and L is selected from the following groups: -N(R T )CH 2 -CH 2 -N(R T ) 2 ; -N(R T ) 2 ; -N(R T )3A-; -N(R T )CH2-CH2-NR T H2A-; wherein R T is hydrogen, phenyl, hydroxy
- the terminal aminosilicone is selected from the group consisting of bis-aminomethyl dimethicone, bisaminoethyl dimethicone, bis-aminopropyl dimethicone, bis-aminobutyl dimethicone, and mixtures thereof.
- the viscosity of the terminal aminosilicone is from 1,000 to 30,000 mPas, or from 5,000 to 20,000 mPas measured at 25 °C.
- the composition comprises from 0.1 wt.-% to 20 wt.-%, or from 0.5 wt.-% to 10 wt.-%, or from 1 wt.-% to 6 wt.-% terminal aminosilicone, by total weight of the composition.
- the composition comprises a high melting point fatty compound.
- the high melting point fatty compound has a melting point of 25 °C or higher.
- the high melting point fatty compound is selected from the group consisting of a fatty alcohol, fatty acid, fatty alcohol derivative, fatty acid derivative, and mixtures thereof.
- the composition may comprise from 0.1 wt.-% to 40 wt.-%, or from 1 wt.-% to 30 wt.-%, or from 1.5 wt.-% to 16 wt.-%, or from 1.5 wt.-% to 8 wt.-% of a high melting point fatty compound, by total weight of the composition. This is advantageous in view of providing improved conditioning benefits such as slippery feel during the application to wet hair, softness and moisturized feel on dry hair.
- the fatty alcohol is selected from the group consisting of: cetyl alcohol, stearyl alcohol, behenyl alcohol, and mixtures thereof.
- the composition comprises a linear fatty alcohol, wherein the linear fatty alcohol is also comprised in a lamellar gel matrix.
- the lamellar gel matrix is suitable for providing various conditioning benefits such as slippery feel during the application to wet hair and softness and moisturized feel on dry hair.
- the linear fatty alcohol may comprise from 8 to 24 carbon atoms.
- the linear fatty alcohol is selected from the group consisting of: cetyl alcohol, stearyl alcohol, and mixtures thereof.
- the weight ratio of total linear fatty alcohol to terminal aminosilicone is from 0.5:1 to 10:1, or from 1:1 to 5:1, or from 2.4:1 to 2.7:1.
- the lamellar gel matrix comprises a cationic surfactant and a high melting point fatty compound.
- the cationic surfactant and the high melting point fatty compound are contained at a level such that the weight ratio of the cationic surfactant to the high melting point fatty compound is in the range of from 1: 1 to 1: 10, or from 1: 1 to 1:6.
- Hairstyling polymers A cosmetic composition may optionally also comprise one or more hair styling polymers as component (D).
- the composition further comprises a hairstyling polymer.
- the hairstyling polymer is selected from the group consisting of: amphoteric hairstyling polymers, zwitterionic hairstyling polymers, anionic hairstyling polymers, non-ionic hairstyling polymers, cationic hairstyling polymers, and mixtures thereof.
- the composition comprises from 0.01 wt.-% to 20 wt.-%, or from 0.01 wt.-% to 16 wt.-%, or from 0.01 wt.-% to 10 wt.-%, or from 1 wt.-% to 8 wt.-%, or from 2 wt.-% to 6 wt.-% of hairstyling polymer.
- the hairstyling polymer is a water-compatible hairstyling polymer, alternatively a water-soluble hairstyling polymer.
- the composition is substantially free of a water-incompatible hairstyling polymer.
- An example of a water-incompatible hairstyling polymer includes an Acrylates/t-Butylacrylamide Copolymer which is a copolymer of tert-butyl acrylamide and one or more monomers of acrylic acid, methacrylic acid, or one of their simple esters (e.g. Ultrahold ® 8 from BASF).
- Balance ® CR from Akzo Nobel, which is an acrylates copolymer of two or more monomers of (meth)acrylic acid or one of their simple esters, is water-compatible.
- the octylacrylamide/acrylate/butylaminoethyl methacrylate copolymer Amphomer ® is also water-compatible.
- the hairstyling polymer is a latex hairstyling polymer.
- the composition may comprise a cationic hairstyling polymer.
- the cationic hairstyling polymers is selected from from group consisting of those with primary, secondary, tertiary or quaternary amino groups.
- the cationic hairstyling polymer has a cationic charge density, and wherein the cationic charge density is from 1 to 7 meq/g.
- the cationic hairstyling polymer comprises quaternary amino groups.
- the cationic hairstyling polymer is a homo- or copolymer where the quaternary nitrogen groups are contained either in the polymer chain or as substituents on one or more of the monomers.
- the ammonium group-containing monomers can be copolymerized with non-cationic monomers.
- the cationic hairstyling polymer comprises cationic monomers where the cationic monomers are unsaturated compounds that can undergo radical polymerization, and which bear at least one cationic group.
- the cationic monomers are selected from the group consisting of: ammonium-substituted vinyl monomers such as, for example, trialkylmethacryloxyalkylammonium, trialkylacryloxyalkylammonium, dialkyldiallylammonium and quaternary vinylammonium monomers with cyclic, cationic nitrogen-containing groups such as pyridinium, imidazolium or quaternary pyrrolidones, e.g. alkylvinylimidazolium, alkylvinylpyridinium, or alkylvinylpyrrolidone salts.
- ammonium-substituted vinyl monomers such as, for example, trialkylmethacryloxyalkylammonium, trialkylacryloxyalkylammonium, dialkyldiallylammonium and quaternary vinylammonium monomers with cyclic, cationic nitrogen-containing groups such as pyridinium, imidazolium or qua
- alkyl groups of these monomers may be lower alkyl groups such, as for example, C1- to C7-alkyl groups, and may also be C1- to C3- alkyl groups.
- cationic hairstyling polymer comprises ammonium group-containing monomers being copolymerized with non-cationic monomers.
- the non-cationic monomers may be selected from the group consisting of: acrylamide, methacrylamide, alkyl- and dialkylacrylamide, alkyl- and dialkylmethacrylamide, alkyl acrylate, alkyl methacrylate, vinylcaprolactone, vinylcaprolactam, vinylpyrrolidone, vinyl esters, for example vinyl acetate, vinyl alcohol, propylene glycol or ethylene glycol, and mixture thereof.
- the alkyl groups of these monomers may be C1- to C7-alkyl groups and may be C1- to C3-alkyl groups.
- cationic hairstyling polymer comprises at least one quaternary amino group.
- Suitable polymers with at least one quaternary amino group include, for example, those described in the CTFA Cosmetic Ingredient Dictionary under the designations ‘polyquaternium’ such as methylvinylimidazolium chloride/vinylpyrrolidone copolymer (polyquaternium-16) or quaternized vinylpyrrolidone/dimethylaminoethyl methacrylate copolymer (polyquaternium-11; Gafquat ® 755N-PW from ISP) as well as quaternary silicone polymers or silicone oligomers such as, for example, silicone polymers with quaternary end groups (quatemium-80).
- polyquaternium such as methylvinylimidazolium chloride/vinylpyrrolidone copolymer (polyquaternium-16) or quaternized vinylpyrrolidone/dimethylaminoethyl methacrylate copolymer (polyquaternium-11; Gafquat ® 755
- the hairstyling polymer is a cationic hairstyling polymer being of synthetic origin.
- the cationic hairstyling polymers of synthetic origin are selected from the group consisting of: poly(dimethyldiallylammonium chloride); copolymers from acrylamide and dimethyldiallylammonium chloride; quaternary ammonium polymers, formed by the reaction of diethyl sulfate with a copolymer from vinylpyrrolidone and dimethylaminoethyl methacrylate, especially vinylpyrrolidone/dimethylaminoethyl methacrylate methosulfate copolymer (e.g.
- Gafquat ® HS 100 copolymers from vinylpyrrolidone and dimethylaminoethyl methacrylate; copolymers from vinylpyrrolidone, vinylcaprolactam, and dimethylaminopropylacrylamide; poly- or oligoesters formed from at least one first type of monomer that is selected from hydroxyacids substituted with at least one quaternary ammonium group; dimethylpolysiloxane substituted with quaternary ammonium groups in the terminal positions; and mixtures thereof.
- the hairstyling polymer is a cationic hairstyling polymer being of natural origin.
- the cationic hairstyling polymers being of natural origin are selected from the group consisting of: cationic derivatives of polysaccharides, for example, cationic cellulose derivatives, starch, guar, and mixtures thereof.
- Cationic derivatives of polysaccharides may be represented by the general formula (D): G–O–B–N + –R a –R b –R c X- (D) wherein G is an anhydroglucose residue, for example, starch or cellulose anhydroglucoses; B is a divalent bonding group, for example, alkylene, oxyalkylene, polyoxyalkylene or hydroxyalkylene; R a , R b and R c are independently from one another, alkyl, aryl, alkylaryl, arylalkyl, alkoxyalkyl or alkoxyaryl, any of which can have up to 22 carbon atoms, wherein the total number of carbon atoms in R a , R b and R c may be a maximum of 20.
- the composition comprises a non-ionic hairstyling polymer, wherein are non-ionic hairstyling polymer is a homo- or copolymer that is formed from at least one of the following monomers: vinylpyrrolidone, vinylcaprolactam, vinyl esters such as, for example, vinyl acetate, vinyl alcohol, acrylamide, methacrylamide, alkyl- and dialkylacrylamide, alkyl- and dialkylmethacrylamide, alkyl acrylate, alkyl methacrylate, propylene glycol or ethylene glycol, where the alkyl groups in these monomers may be C 1 - to C 7 -alkyl groups or C 1 - to C 3 -alkyl groups.
- vinylpyrrolidone vinylcaprolactam
- vinyl esters such as, for example, vinyl acetate, vinyl alcohol, acrylamide, methacrylamide, alkyl- and dialkylacrylamide, alkyl- and dialkylmethacrylamide, alkyl acrylate
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Abstract
The present invention relates to the use of a polymer comprising one or more synthetic polymer units comprising repeating units of a structure of Formula (1) for increasing the UV and/or blue light absorption of one or more UV and/or blue light filters. Furthermore, the present invention refers to a sunscreen composition comprising such polymer, one or more UV and/or blue light filters and one or more cosmetically acceptable carriers.
Description
USE OF A POLMER FOR IMPROVING SUN PROTECTION The present invention relates to the use of a polymer comprising one or more synthetic polymer units comprising repeating units of a structure of Formula (1)
for increasing the UV and/or blue light absorption of one or more UV and/or blue light filters. Furthermore, the present invention refers to a sunscreen composition comprising such polymer, one or more UV and/or blue light filters and one or more cosmetically acceptable carriers. Exposure to sunlight can have desirable effects, such as stimulating the production of vitamin D and tanning the skin. However, if the intensity or duration of exposure is too high, the lower wavelength UV-B light below 315 nm can cause erythema, a reddening of the skin, also known as sunburn. Severe tissue damage can occur, including actinic keratosis and skin cancer. Further, the skin can premature early. Thus, protection from sunlight is often desired, especially on skin areas not covered by UV protective cloths. A number of sunscreen formulations have been known for decades. Typically, such compositions comprise one or more UV and/or blue light filters such as UV filters. A high number of UV and/or blue light filters in different compositions are known in the art such as, e.g., shown in WO 2010/043588 and WO 2019/096960. Such more UV and/or blue light filters can be classified in different ways such as as Bis-Ethylhexyloxyphenol Methoxyphenyl Triazine, oil soluble organic UV absorbers, sparingly soluble organic UV absorbers, inorganic UV absorbers, and water-soluble UV absorbers as shown in WO 2010/043588.
The sun protection effect of the UV and/or blue light filters known in the art is not entirely satisfying. When using moderate contents, sun protection efficacy (e.g., high sun protection factor (SPF)) is limited. Thus, to achieve a desired SPF which is often in the range of >30, very high amounts of UV and/or blue light filters are required. Often, UV and/or blue light filters that have comparably high efficacy per amount and thus allow using rather low amounts are rather poorly biodegradable. When, on the other hand, good biodegradability is desired, lower efficacy in sun protection must often be accepted or higher amounts of such UV and/or blue light filters required. In other words, it is a challenge to provide compositions that are readily biodegradable and still bear high sun protection efficacy (e.g., high sun protection factor (SPF)). In addition, in the case of particulate UV and/or blue light filters such as some inorganic agents, high amounts of such materials are comparably difficult to spread evenly on the skin and may lead to undesired bright spots on the skin. Thus, it is still an unmet need to improve efficacy of UV and/or blue light filters. It is a particular desire to provide sun protection compositions that have a higher biodegradability and still bear a good or even bear an increased sun protection efficacy in comparison to compositions that bear the UV and/or blue light filters without a boostering component. Surprisingly, it has been found that polymers comprising one or more synthetic polymer units comprising repeating units of a structure of Formula (1) lead to a significant improvement of sun protection by increasing the UV and/or blue light absorption of one or more UV and/or blue light filters. It has been further surprisingly found that compositions having comparably high biodegradability having such good sun protection can be provided.
An aspect of the present invention relates to the use of a polymer comprising (or consisting of): (i) one or more synthetic polymer units comprising (or consisting of): (a) repeating units of a structure of Formula (1):
wherein R1 and R2 are independently selected from H, methyl or ethyl; A is a linear or branched C1-C12-alkyl group; and Q+ is a cosmetically acceptable cation; and (b) optionally one or more crosslinking or branching units; and (c) optionally one or more further repeating units which are different from a repeating unit of structure of Formula (1) and from the crosslinking or branching units crosslinking or branching units; and (ii) one or more water-soluble and/or water-swellable polysaccharide polymer units, for increasing the UV and/or blue light absorption of one or more UV and/or blue light filters. It has been shown that such polymer comprising one or more synthetic polymer units comprising repeating units of a structure of Formula (1) leads to a significant improvement of sun protection effect when added to a composition comprising UV and/or blue light filter. The use of the present invention may be increasing the UV and/or blue light absorption of a UV and/or blue light filter in a composition comprising at least one UV and/or blue light filter and optionally one or more further cosmetically acceptable components. The polymer as used in the present invention may have a boosting effect on sun protection by increased UV and/or blue light absorption by influencing the spreadability of the sunscreen product on the skin. It will be understood that increased UV and/or blue light absorption
typically leads to an increased sun protection factor (SPF) of the composition. Surprisingly, it has been further found that the compositions of the present invention can be prepared as having a good biodegradability. The present invention relates to a method for sun protection, comprising the steps of: (I) providing a composition of: (a) one or more polymers comprising (or consisting of): (i) one or more synthetic polymer units comprising (or consisting of): (a) repeating units of a structure of Formula (1):
wherein R1 and R2 are independently selected from H, methyl or ethyl; A is a linear or branched C1-C12-alkyl group; and Q+ is a cosmetically acceptable cation; and (b) optionally one or more crosslinking or branching units; and (c) optionally one or more further repeating units which are different from a repeating unit of structure of Formula (1) and from the crosslinking or branching units crosslinking or branching units; and (ii) one or more water-soluble and/or water-swellable polysaccharide polymer units; and (b) one or more UV and/or blue light filters; and (II) applying the composition of step (I) to a surface, preferably a skin surface, of interest which is exposed to sun light,
wherein UV and/or blue light absorption of the composition of step (I) is higher than UV and/or blue light absorption of a comparable composition without the one or more polymers. It will be understood that the method of the definitions and preferred embodiments of the use of the present invention mutatis mutandis apply to the methods of the present invention. The present invention further relates to a method for increasing the UV and/or blue light absorption of a composition comprising one or more UV and/or blue light filters, comprising the step of admixing one or more polymers to this composition, wherein the one or more polymers comprise (or consist of): (i) one or more synthetic polymer units comprising (or consisting of): (a) repeating units of a structure of Formula (1):
wherein R1 and R2 are independently selected from H, methyl or ethyl; A is a linear or branched C1-C12-alkyl group; and Q+ is a cosmetically acceptable cation; and (b) optionally one or more crosslinking or branching units; and (c) optionally one or more further repeating units which are different from a repeating unit of structure of Formula (1) and from the crosslinking or branching units crosslinking or branching units; and (ii) one or more water-soluble and/or water-swellable polysaccharide polymer units, preferably wherein UV and/or blue light absorption of the composition comprising the one or more polymers is higher than UV and/or blue light absorption of a comparable composition without the one or more polymers.
General Definitions As used herein, including in all embodiments of all aspects of the present invention, the following definitions apply unless specifically stated otherwise. All percentages, as far as not defined otherwise, may be understood as percent by weight (w/w) of the respective composition/composition they refer to. The term “wt.-%” means percentage by weight. All ratios, as far as not defined otherwise, are weight ratios. All ranges are inclusive and combinable. The number of significant digits conveys neither a limitation on the indicated amounts nor on the accuracy of the measurements. All measurements, as far as not otherwise stated, are understood to be made at (approximately) 23°C and at ambient conditions, where “ambient conditions” means at (approximately) 1 atmosphere (atm) of pressure and at (approximately) 50 % relative humidity. “Relative humidity” refers to the ratio (stated as a percent) of the moisture content of air compared to the saturated moisture level at the same temperature and pressure. Relative humidity may be measured with a hygrometer, in particular with a probe hygrometer from VWR® International. Embodiments and aspects described herein may comprise or be combinable with elements, features or components of other embodiments and/or aspects despite not being expressly exemplified in combination, unless an incompatibility is stated. As used herein, the terms “increasing” and “increase” may be understood in the broadest form as any enhancement of the respective value in comparison to a reasonable reference value. Preferably, an increase is an enhancement by at least 1 %, more preferably by at least 5 %, even more preferably by at least 10 %, even more preferably by at least 25 % or even at least 50 % or more than 50 %, related to a reference value. As used herein, the terms “increasing, “enhancing”, “boostering”, etc. may be understood interchangeably. The polymer according to
Formula (1) may also be considered as a booster of sun protection effect of a UV and/or blue light filter. In the context increasing the UV and/or blue light absorption of a UV and/or blue light filter in the context of the present invention, it will be understood that the reference value to which the increase relates to is a comparable composition without the polymer comprising one or more synthetic polymer units comprising repeating units of a structure of Formula (1). Thus, in the context increasing the UV and/or blue light absorption of a UV and/or blue light filter in the context of the present invention, an increase preferably is an enhancement by at least 1 %, more preferably by at least 5 %, even more preferably by at least 10 %, even more preferably by at least 25 % or even at least 50 % or more than 50 %, related to a comparable composition without the polymer comprising one or more synthetic polymer units comprising repeating units of a structure of Formula (1). It will be understood that all components mentioned herein also embrace salts thereof. As used herein, a “salt” of a polymer or any unit thereof, a monomer, an UV and/or blue light filter, or any other component may be any salt. In at least one embodiment, a “salt” is a cosmetically acceptable salt. For example, a salt may be a charged form of a charged functional group such as, e.g., an –SO3- group, an amino group, a carboxylic acid group, etc. The counterion may be any counter ion. In at least one embodiment, the counter ion is a cosmetically acceptable counter ion. In at least one embodiment, a counter ion is selected from the group consisting of H+, NH4+, an organic ammonium ion [NHR5R6R7]+ wherein R5, R6, and R7 independently of one another is hydrogen, a linear or branched alkyl group having 1 to 22 carbon atoms, a linear or branched, mono- or poly-unsaturated alkenyl group having 2 to 22 carbon atoms, a C6-C22 alkylamidopropyl group, a linear mono-hydroxyalkyl group having 2 to 10 carbon atoms or a linear or branched dihydroxyalkyl group having 3 to 15 carbon atoms, and wherein at least one of the radicals R5, R6, and R7 is not hydrogen, or Q+ is Li+, Na+, K+, ½ Ca++, ½ Mg++, ½ Zn++, 1/3 Al+++, or combinations thereof.
As used herein, the term “alkyl” may be understood in the broadest sense. When it is a bivalent residue, such as, e.g., in the definition of residue A in Formula (1), it may also be designated as “alkylene”. This does not mean that it contains double bonds. It is preferably saturated. In a preferred embodiment, an alkylene is a bivalent residue having a sum formula --[CnH2n]-, wherein n is an integer of at least 1, more preferably of 1 to 30, even more preferably of 1 to 12, in particular 1 to 4, as far as not otherwise specified. “Molecular weight” or “M.Wt.” or “MW” and grammatical equivalents mean the weight average molecular weight unless otherwise specifically specified. Number average molecular weight: Mn The number average molecular weight is the statistical average molecular weight of all the polymer chains in the sample, and is defined by:
where Mi is the molecular weight of a chain and Ni is the number of chains of that molecular weight. Mn can be predicted by polymerization mechanisms and is measured by methods that determine the number of molecules in a sample of a given weight; for example, colligative methods such as end-group assay. If Mn is quoted for a molecular weight distribution, there are equal numbers of molecules on either side of Mn in the distribution. Weight average molecular weight: Mw The weight average molecular weight is defined by:
Compared to Mn, Mw takes into account the molecular weight of a chain in determining contributions to the molecular weight average. The more massive the chain, the more the chain contributes to Mw. The polydispersity index PDI is used as a measure of the broadness of a molecular weight distribution of a polymer, and is defined by:
The larger the PDI, the broader the molecular weight distribution. A monodisperse polymer where all the chain lengths are equal has an Mw/Mn=1. “Viscosity” is measured at 25 °C in centipoise (cP) (= millipascal seconds (mPas)) using an RV Brookfield viscometer with 10 - 90 % torque at 20 RPM, unless otherwise stated. “Water-soluble” refers to any material that is sufficiently soluble in water to form a clear solution to the naked eye at a concentration of 0.1 % by weight of the material in water at 25 °C. The term “water-insoluble” refers to any material that is not “water-soluble”. “Substantially free from” or “substantially free of” means less than 1 %, or less than 0.8 %, or less than 0.5 %, or less than 0.3 %, or about 0 %, by total weight of the composition or formulation. “Cosmetically acceptable” means that the compositions, formulations or components described are suitable for use in contact with human keratinous tissue without undue toxicity, incompatibility, instability, allergic response, and the like. All compositions and formulations described herein which have the purpose of being directly applied to keratinous tissue are limited to those being cosmetically acceptable.
The term “derivative” may include but is not limited to amide, ether, ester, amino, carboxyl, acetyl, acid, salt and/or alcohol derivatives of a given compound. In at least one embodiment, “derivatives thereof” means the amide, ether, ester, amino, carboxyl, acetyl, acid, salt and/or alcohol derivatives thereof. The term “monomer” means a discrete, non-polymerized chemical moiety capable of undergoing polymerization in the presence of an initiator or any suitable reaction that creates a macromolecule, e.g. such as radical polymerization, polycondensation, polyaddition, anionic or cationic polymerization, ring opening polymerization or coordination insertion polymerization. “Unit” means a monomer that has already been polymerized, i.e. is part of a polymer. As used herein, the term "polymer" may be understood in the broadest sense as a chemical formed from polymerization of two or more monomers. The term "polymer" shall include all materials made by the polymerization of monomers synthetically as well as natural polymers. Polymers made from only one type of monomer are called homopolymers. Herein, a polymer comprises at least two monomers. Polymers made from two or more different types of monomers are called copolymers. The distribution of the different monomers can be random, alternating or block-wise (i.e. block copolymer). It will be understood that a copolymerized part of a polymer may also be combined with one or more blocks of polymer units. The term “polymer” used herein may include any type of polymer including homopolymers, copolymers, and bockpolymers. As used herein, a UV and/or blue light filter may be understood as any substance that is exclusively or mainly intended to protect the skin against UV and/or blue light radiation by absorbing, reflecting and/or scattering UV and/or blue light. Preferably, a UV and/or blue light filter may be understood as any substance that is exclusively or mainly intended to protect the skin against UV and/or blue light radiation by absorbing UV and/or blue light and optionally also reflecting and/or scattering UV and/or blue light. As used herein, a “UV light filter” (also: “UV filter” or “UV-filter”) may be understood
as any substance that is exclusively or mainly intended to protect the skin against UV radiation by absorbing, reflecting and/or scattering UV light. Preferably, a UV light filter may be understood as any substance that is exclusively or mainly intended to protect the skin against UV radiation by absorbing UV light and optionally also reflecting and/or scattering UV light. A UV light filter may be such in the sense of the EU Cosmetics Regulation No.1223/ 2009. In a preferred embodiment, as used herein, a UV light filter may be understood as any substance that absorbs (and optionally reflects and/or scatters) light in the UV range, in other words adsorbs UV light. As used herein, UV light has a wavelength range below 400 nm, preferably from 100 to 399 nm. UV light may be UV-A light (wavelength range from 320 to 399 nm), UV-B light (wavelength range from 290 to 319 nm), and/or UV-C light (wavelength range below 290 nm, preferably 100 to 289 nm). In a preferred embodiment, UV light is UV-A and/or UV-B light. As used herein, a blue light filter may be understood as any substance that is exclusively or mainly intended to protect the skin against blue light radiation by absorbing, reflecting and/or scattering blue light. Preferably, a blue light filter may be understood as any substance that is exclusively or mainly intended to protect the skin against blue light radiation by absorbing blue light and optionally also reflecting and/or scattering blue light. In a preferred embodiment, as used herein, a blue light filter may be understood as any substance that absorbs (and optionally reflects and/or scatters) light in the blue range, in other words adsorbs blue light. As used herein, blue light is light of a wavelength range from 400 to 490 nm. The “biobased content” as used herein is reported in ASTM D6866-12, Method B (see section 3.3.9 of ASTM D6866-12). “Biobased carbon content”, “biobased content”, “biogenic carbon content”, “bio-based content”, “biomass-derived carbon” herein refer to the same thing and are all measured in wt.-%. Herein, the term ‘bio- based carbon content’ is used. ASTM D6866-12, Method B lab results report the percentage of bio-based carbon content relative to total carbon, and not to total mass of the sample or molecular weight. A comment on bio-based carbon content calculation: Presently ASTM D6866-12, Method B (see section 9 of ASTM D6866- 12) requires the percent modern carbon value (pMC) reported to be multiplied by a
correction factor of 0.95 to account for excess carbon-14 in the atmosphere due to nuclear weapons testing. However, a revision is pending for ASTM D6866-12, Method B to update the correction factor to 0.98 due to ongoing decrease in excess atmospheric 14CO2. For the purposes of accuracy, the new correction factor of 0.98 is often reported in the field e.g. by suppliers. Generally, results below ~20 % bio-based carbon will not be affected. However, results close to 100% will be ~2-3 % bio-based carbon higher using the 0.98 factor vs 0.95. Results between ~20-90 % will increase by 0-3 %. Hence the term “bio-based carbon content” as used herein is defined by the equation: Bio-based carbon content = pMC * 0.95 (%) A review on measurement methods of bio-based carbon content for biomass- based chemicals and plastics is given by Massao Kunioka in Radioisotopes, 62, 901-925 (2013). Explanation of benefits provided by the invention As noted above, it has been found a polymer as defined herein leads to a significant improvement of sun protection effect when added to a composition comprising UV and/or blue light filter. The use of the present invention may be increasing the UV and/or blue light absorption of a UV and/or blue light filter in a composition comprising at least one UV and/or blue light filter and optionally one or more further cosmetically acceptable components. This allows either achieving a higher UV and/or blue light absorption without increasing the content of the one or more UV and/or blue light filters in a composition and/or reduction of the content of the UV and/or blue light filters while at least maintain the SFP of the composition. As the polymer as defined herein may be synthesised in a one-step process, rather than a process requiring multiple synthesis and/or purification steps such as by radical precipitation polymerization in a polar solvent. It may be provided in a highly concentrated for, in pellets and even powder form. This allows highly
concentrated and/or well storable and shippable mixtures with one or more UV and/or blue light filters. Polymer Synthetic polymer units The hybrid polymer comprises synthetic polymer units. “Synthetic polymer units” herein means any polymer units that are not a naturally-occurring polymer units nor derivatives of naturally-occurring polymer units. In at least one embodiment, the synthetic polymer unit comprises from 90 mol-% to 99.9 mol-% repeating units of a structure of Formula (1) (units (a)) and from 0.01 mol-% to 10 mol-% crosslinking or branching units (units (b)). Preferably, the synthetic polymer unit comprises from 95 mol-% to 99.9 mol-% units (a). Preferably, the synthetic polymer unit comprises from 0.01 mol-% to 5 mol-% units (b), more preferably from 0.01 mol-% to 3 mol-% units (b). In at least one embodiment, the synthetic polymer unit comprises units (a) and units (b) such that the sum thereof is at least 99 mol-%. In at least one embodiment, the synthetic polymer unit consists of units (a) and units (b). Repeating units of a structure of Formula (1) (Units (a)) In at least one embodiment, the synthetic polymer unit comprises at least one repeating unit according to Formula (1). In at least one embodiment, the synthetic polymer unit comprises two or more different repeating units according to Formula (1), such as repeating units according to Formula (1) having different Q+ counterions. The cation Q+ may be any a cosmetically acceptable cation. In at least one embodiment, Q+ is H+, NH4 +, an organic ammonium ion [NHR5R6R7]+ wherein R5, R6, and R7 independently of one another is hydrogen, a linear or branched alkyl group having 1 to 22 carbon atoms, a linear or branched, mono- or poly-
unsaturated alkenyl group having 2 to 22 carbon atoms, a C6-C22 alkylamidopropyl group, a linear mono-hydroxyalkyl group having 2 to 10 carbon atoms or a linear or branched dihydroxyalkyl group having 3 to 15 carbon atoms, and wherein at least one of the radicals R5, R6, and R7 is not hydrogen, or Q+ is Li+, Na+, K+, ½ Ca++, ½ Mg++, ½ Zn++, 1/3 Al+++, or combinations thereof. In at least one embodiment, the synthetic polymer unit comprises repeating units according to Formula (1)
wherein R1 and R2 are independently selected from H, methyl or ethyl; A is a linear or branched C1-C12-alkyl group; and Q+ is H+, NH4+, an organic ammonium ion conforming to [NHR5R6R7]+ wherein R5, R6, and R7 independently of one another is hydrogen, a linear or branched alkyl group having 1 to 22 carbon atoms, a linear or branched, mono- or poly-unsaturated alkenyl group having 2 to 22 carbon atoms, a C6-C22 alkylamidopropyl group, a linear mono- hydroxyalkyl group having 2 to 10 carbon atoms or a linear or branched dihydroxyalkyl group having 3 to 15 carbon atoms, and wherein at least one of the radicals R5, R6, and R7 is not hydrogen, or Q+ is Li+, Na+, K+, ½ Ca++, ½ Mg++, ½ Zn++, 1/3 Al+++, or combinations thereof. Preferably, Q+ is H+, NH4 +, Na+, or K+. More preferably, Q+ is H+, NH4 +, Na+. Particularly preferably, Q+ is NH4 + or Na+. In at least one embodiment, the synthetic polymer unit comprises at least one repeating unit (a) according to Formula (1) wherein R1 and R2 are independently
selected from H, methyl or ethyl; A is a linear or branched C1-C12-alkyl group; and Q+ is H+, Li+, Na+, K+, ½ Ca++, ½ Mg++, ½ Zn++, 1/3 Al+++, or combinations thereof, preferably wherein Q+ is Na+. In at least one embodiment, Q+ is NH4 +. In at least one embodiment, Q+ is selected from the group monoalkylammonium, dialkylammonium, trialkylammonium and/or tetraalkylammonium salts, in which the alkyl substituents of the amines may independently of one another be (C1 to C22)-alkyl radicals or (C2 to C10)- hydroxyalkyl radicals. NH4 + is preferred because it is more soluble in the favored solvent used in the polymer synthesis. Na+ is preferred because of reduced likelihood of undesired gases being produced during synthesis and also due to economic advantages. In at least one embodiment, the repeating units according to Formula (1) is defined in that residue R1 is H, methyl or ethyl, preferably H or methyl, in particular H. In at least one embodiment, the repeating units according to Formula (1) is defined in that residue R2 is methyl or ethyl, preferably H or methyl, in particular H. In at least one embodiment, the repeating units according to Formula (1) is defined in that residue A is defined as being a bivalent residue having a sum formula --[CnH2n]-, wherein n is 1, 2, 3, 4, 5, 6, 7, 8, 9, 10, 11, or 12. In at least one embodiment, the repeating units according to Formula (1) is defined in that residue A is -C(CH3)2-, - CH(CH3)-, -CH2-, -CH2-C(CH3)2-, -CH2-CH(CH3)-, or -CH2-CH2-, in particular is - C(CH3)2-. In at least one embodiment, the repeating units according to Formula (1) is defined in that residues R1 and R2 are both each selected from H, methyl and ethyl, preferably are both each selected from H or methyl, in particular are both each H. In at least one embodiment, the repeating units according to Formula (1) is defined in that residue R1 is H and residue A is -C(CH3)2-. In at least one embodiment, the repeating units according to Formula (1) is defined in that residue R2 is H and residue A is -C(CH3) 2-. In at least one embodiment, the repeating units according to Formula (1) is defined in that residues R1 and R2 are both each H and residue A is -C(CH3) 2-.
In at least one embodiment, the repeating units according to Formula (1) result from the incorporation of a monomer selected from the group consisting of acryloyldimethyltaurates, acryloyl-1,1-dimethyl-2-methyltaurates, acryloyltaurates, acryloyl-N-methyltaurates, and salts and combinations thereof. In at least one embodiment, the repeating units according to Formula (1) result from the incorporation of a monomer selected from the group consisting of acryloyldimethyltaurates, acryloyl-1,1-dimethyl-2-methyltaurates, acryloyltaurates, acryloyl-N-methyltaurates, and combinations thereof and salts thereof with one or more counterions Q+ as defined herein, in particular wherein Q+ is H+, NH4+, Na+, K+, or a combination of two or more thereof. Preferably, the repeating units according to Formula (1) result from the incorporation of acryloyldimethyltaurate or a salt thereof. Preferably, the repeating units according to Formula (1) result from the incorporation of acryloyldimethyltaurate or one or more salts thereof with one or more counterions Q+ as defined herein, in particular wherein Q+ is H+, NH4+, Na+, K+, or a combination of two or more thereof. In at least one embodiment, the repeating units according to Formula (1) have a degree of neutralization of between 0 mol-% and 100 mol-%. In at least one embodiment, the repeating units according to Formula (1) have a degree of neutralization of from 50.0 to 100 mol-%, preferably from 80 mol-% to 100 mol-%, more preferably from 90.0 to 100 mol-%, even more preferably from 95.0 to 100 mol-%. Particular preference is given to a degree of neutralization of more than 80 mol-%, more preferably more than 90 mol-%, even more preferably more than 95 mol-%. In at least one embodiment, the monomers resulting in units in the synthetic polymer unit are neutralized with a base prior to the polymerization, and/or the hybrid polymer after polymerization is neutralized with a base. In at least one embodiment, the monomers resulting in units (a) and/or (b) are neutralized with a base prior to the polymerization, and/or the hybrid polymer after polymerization is neutralized with a base.
In at least one embodiment, the base is selected from bases comprising a cation selected from the group consisting of NH4+, Li+, Na+, K+, Ca++, Mg++, Zn++, Al+++, Zr++++ and mixtures thereof. In at least one embodiment, monomers resulting in the one or more synthetic polymer units are neutralized with a base prior to polymerization, and/or the polymer is neutralized with a base after polymerization, preferably wherein the base is selected from bases comprising an ion selected from the group consisting of Li+, Na+, K+, Ca++, Mg++, Zn++, Al+++, and combinations thereof, in particular wherein the base is selected from hydroxides, carbonates and hydrogen carbonates comprising an ion selected from the group consisting of Li+, Na+, K+, Ca++, Mg++, Zn++, Al+++, and combinations thereof. In at least one embodiment, the base is selected from hydroxides, carbonates and hydrogen carbonates comprising a cation selected from the group consisting of NH4 +, Li+, Na+, K+, Ca++, Mg++, Zn++, Al+++ and mixtures thereof. In at least one embodiment, the base is selected from the group consisting of gaseous ammonia, ammonium hydrogen carbonate, ammonium carbonate, ammonium hydroxide, sodium hydrogen carbonate, sodium carbonate, sodium hydroxide, potassium hydrogen carbonate, potassium carbonate, potassium hydroxide, lithium hydrogen carbonate, lithium carbonate, lithium hydroxide, calcium hydrogen carbonate, calcium carbonate, calcium hydroxide, preferably sodium hydrogen carbonate, sodium carbonate, sodium hydroxide, potassium hydrogen carbonate, potassium carbonate, potassium hydroxide, even more preferably sodium hydrogen carbonate, sodium carbonate, sodium hydroxide, most preferably sodium hydrogen carbonate and sodium carbonate. In at least one embodiment, the synthetic polymer unit comprises from 95 mol-% to 99.9 mol-%, or at least 95.5 mol-%, or at least 96 mol-%, or at least 96.5 mol-%, or at least 97 mol-%, or at least 97.5 mol-%, or at least 98 mol-%, or at least 98.5 mol-%, or at least 99 mol-%, or at least 99.5 mol-% of repeating units according to Formula (1). Crosslinking or branching units (Units (b))
In at least one embodiment, the polymer comprises one or more crosslinking or branching units. Such crosslinking or branching units may be any units that enable crosslinking or branching polymeric units. Preferably, the crosslinking or branching units result from the incorporation of a monomer comprising at least two olefinically unsaturated double bonds. The synthetic polymer unit may comprise crosslinking or branching units, wherein the crosslinking or branching units result from the incorporation of a monomer comprising at least two olefinically unsaturated double bonds. The one or more synthetic polymer units may comprise from 0.01 mol-% to 10 mol-%, preferably from 0.01 mol-% to 5 mol-%, more preferably from 0.01 mol- % to 3 mol-% of crosslinking or branching units. In at least one embodiment, the crosslinking or branching units comprise at least one oxygen, nitrogen, sulfur or phosphorus atom. In at least one embodiment, the crosslinking or branching units result from monomers having a molecular weight of less than 500 g/mol. In at least one embodiment, the units (b) are bifunctional or trifunctional crosslinking agents. In at least one embodiment, the synthetic polymer unit comprises at least one crosslinking or branching unit. In at least one embodiment, the synthetic polymer unit comprises two or more different crosslinking or branching units. In at least one embodiment, the crosslinking or branching units result from the incorporation of a monomer according to Formula (2):
wherein
R1 is independently selected from H, methyl or ethyl; and R2 is a linear or branched alkylene group having 1 to 6 carbon atoms, or is a linear or branched, mono- or polyunsaturated alkenylene group having 2 to 6 carbon atoms. In at least one embodiment, the crosslinking or branching units result from the incorporation of a monomer according to Formula (3)
wherein R1 is independently selected from H, methyl or ethyl; and R2 is H, or is a linear or branched alkyl group having 1 to 6 carbon atoms, or is a linear or branched, mono- or polyunsaturated alkylene group having 2 to 6 carbon atoms; D, E, and F are independently methyleneoxy (-CH2O-), ethyleneoxy (-CH2-CH2-O- ), propyleneoxy (-CH(CH3)-CH2-O-), a linear or branched alkylene group having 1 to 6 carbon atoms, a linear or branched, singularly or multiply unsaturated alkenylene group having 2 to 6 carbon atoms, a linear mono-hydroxyalkylene group having 2 to 6 carbon atoms or a linear or branched dihydroxyalkylene group having 3 to 6 carbon atoms; and o, p, and q each independently are an integer from 1 to 50. It will be understood that also more than one crosslinking or branching units may be combined with each other, in other words, may be incorporate into the polymer.
Thus, also one or crosslinking or branching units of Formula (2) may be combined with also one or crosslinking or branching units of Formula (3). In at least one embodiment, the crosslinking or branching units result from the incorporation of a crosslinker selected from the group consisting of methylenebisacrylamide; methylenebismethacrylamide; esters of unsaturated monocarboxylic and polycarboxylic acids with polyols, preferably di-acrylates and tri-acrylates and -methacrylates (e.g. glycerol propoxylate triacrylate [GPTA]), more preferably butanediol and ethylene glycol diacrylate and -methacrylate, trimethylolpropane triacrylate (TMPTA) and trimethylolpropane trimethacrylate (TMPTMA); allyl compounds, preferably allyl (meth)acrylate, triallyl cyanurate, diallyl maleate, polyallyl esters, tetraallyloxyethane, triallylamine, tetraallylethylenediamine; allyl esters of phosphoric acid, vinylphosphonic acid derivatives, and salts and combinations thereof. In at least one embodiment, the crosslinking or branching units result from the incorporation of trimethylolpropane triacrylate (TMPTA). In at least one embodiment, the crosslinking or branching units result from the incorporation of a crosslinker selected from the group consisting of methylenebisacrylamide; methylenebismethacrylamide; esters of unsaturated monocarboxylic and polycarboxylic acids with polyols, preferably di-acrylates and tri-acrylates and -methacrylates (e.g. glycerol propoxylate triacrylate [GPTA]), more preferably butanediol and ethylene glycol diacrylate and -methacrylate, trimethylolpropane triacrylate (TMPTA) and trimethylolpropane trimethacrylate (TMPTMA); allyl compounds, preferably allyl (meth)acrylate, triallyl cyanurate, diallyl maleate, polyallyl esters, tetraallyloxyethane, triallylamine, tetraallylethylenediamine; allyl esters of phosphoric acid, and salts and combinations thereof. In at least one embodiment, the crosslinking or branching units result from the incorporation of trimethylolpropane triacrylate (TMPTA). Particularly preferred as crosslinkers for the synthetic polymer units of the invention are glycerol propoxylate triacrylate (GPTA), trimethylolpropane triacrylate (TMPTA), pentaerythritol diacrylate mono stearate (PEAS), hexanediol diacrylate
(HDDA), hexanediol dimethacrylate (HDDMA), PEG-Dimethacrylate (e.g., average Mn 550), and Glyceryl Propoxy Triacrylate, and a combination of two or more thereof. Especially preferred is glycerol propoxylate triacrylate (GPTA). In one embodiment, the polymer contains 0.1 to 20 wt.-%, or 0.2 to 10 wt.-%, or 0.3 to 9 wt.-%, or 0.4 to 8 wt.-%, or 0.5 to 7 wt.-%, or 0.6 to 5 wt.-%, or 0.6 to 1.0 wt.-%, of one or more crosslinkers. In one embodiment, the polymer as used in the context of the present invention contains 2-acrylamido-2-methylpropane sulfonic acid. In one embodiment, the polymer as used in the context of the present invention contains 20 to 100 wt.-%, or 230 to 99 wt.-%, or 40 to 98 wt.-%, or 45 to 97 wt.-%, or 50 to 96 wt.-%, or 60 to 90 wt.-%, or 75 to 85 wt.-%, of 2-acrylamido-2-methylpropane sulfonic acid. In one embodiment, the polymer as used in the context of the present invention contains one or more (poly)saccharides as one or more further monomers. In one embodiment, the polymer as used in the context of the present invention contains one or more Tara gum repeating units as one or more further monomers. The polymer may be prepared by any means. In one embodiment, the polymer is prepared by using one or more peroxides. In one embodiment, the polymer is prepared by using one or more peroxides selected from the group consisting of dilauroylperoxide, and tert.- butylhydroperoxide. In one embodiment, the polymer is prepared by using 2- methylpropionate. In one embodiment, the polymer contains or consists of Caesalpinia Spinosa Gum/Ammonium AMPS Crosspolymer (Aristoflex Eco T). In a preferred embodiment of the present invention, the polymer is Aristoflex Eco T, which may comprise AMPS, tara gum, and a crosslinker. It is polymerized by radical polymerization.
Further repeating units (Units (c)) Optionally, further repeating units, which are different from a repeating unit of structure of Formula (1) and from the crosslinking or branching units crosslinking or branching units, may also be present in the polymer. In at least one embodiment, the one or more synthetic polymer units comprise a unit (c) from 1.0 mol-% to 9.99 mol-%, preferably from 2.0 mol-% to 9.99 mol-% of neutral repeating structural units. In at least one embodiment, the one or more synthetic polymer units comprise at least one neutral repeating structural unit as unit (c). In at least one embodiment, the synthetic polymer unit comprises at least one neutral repeating structural unit selected from the group consisting of N-vinylformamide, N-vinylacetamide, N-methyl-N-vinylformamide, N-methyl-N- vinylacetamide, N-vinyl-2-pyrrolidone, N-vinylcaprolactam, vinylacetate, N,N-dimethylacrylamide, N-isopropylacrylamide, acrylamide, methylacrylate, behenylpolyethoxy-(25)-methacrylate, laurylpoly-ethoxy-(7)-methacrylate, cetylpolyethoxy-(10)-methacrylate, stearylpoly-ethoxy-(8)-methacrylate, methoxypoly-ethoxy-(12)-methacrylate, and combinations thereof. Optionally, the synthetic polymer unit may comprise at least one anionic repeating structural unit which are different from the repeating units of a structure of Formula (1) of unit (a) as unit (c). In at least one embodiment, the synthetic polymer unit comprises from 1.0 mol-% to 9.99 mol-%, preferably from 2.0 mol-% to 9.99 mol-% of anionic repeating structural units, wherein the anionic repeating structural units result from the incorporation of a monomer comprising at least one carboxylate anion, and wherein the anionic repeating structural units are different from units (a). In at least one embodiment, the anionic repeating structural unit results from the incorporation of monomers according to formula (A):
wherein R1 and R3 are H, methyl or ethyl, or C(O)O-Z+; X, Y are selected from a covalent bond, O, CH 3 2, C(O)O, OC(O), C(O)NR or NR3C(O); M are selected from a covalent bond, -[C(O)O-CH2-CH2]n-, a linear or branched alkylene group with 1 to 6 carbon atoms, a linear or branched, mono- or polyunsaturated alkenylene group with 2 to 6 carbon atoms, a linear mono-hydroxyalkylene group with 2 to 6 carbon atoms or a linear or branched di-hydroxyalkylene group with 3 to 6 carbon atoms; n is an integer from 1 - 5 and Z+ is H+, NH4+, an organic ammonium ion [HNR5R6R7]+ wherein R5, R6 and R7 are independently hydrogen, a linear or branched alkyl group with 1 to 22 carbon atoms, a linear or branched, mono- or polyunsaturated alkenyl group with 2 to 22 carbon atoms, a C6 to C22 alkylamidopropyl group, a linear mono-hydroxyalkyl group with 2 to 10 carbon atoms or a linear or branched di-hydroxyalkyl group with 3 to 10 carbon atoms, and wherein at least one of R5, R6 and R7 is not hydrogen, or Z+ is Li+, Na+, K+, ½ Ca++, ½ Mg++, ½ Zn++, 1/3 Al+++, or combinations thereof. In at least one embodiment, Z+ is H+, NH4 +, Li+, Na+, K+, ½ Ca++, ½ Mg++, ½ Zn++, or 1/3 Al+++, preferably H+, NH4+, Li+, Na+ or K+. In at least one embodiment, the anionic repeating structural unit results from the incorporation of monomers according to formula (A) wherein X is a covalent bond or is CH2. In at least one embodiment, the anionic repeating structural unit results
from the incorporation of monomers according to formula (A) wherein Y is a covalent bond, CH2, C(O)O, or C(O)NR3. In at least one embodiment, the anionic repeating structural unit results from the incorporation of monomers according to formula (A) wherein M is a covalent bond, -[C(O)O-CH2-CH2]n-, a linear or branched alkylene group with 1 to 6 carbon atoms. In at least one embodiment, the anionic repeating structural unit results from the incorporation of monomers according to formula (A) wherein R1 is H, methyl or ethyl; X is a covalent bond or is CH2; Y is a covalent bond, CH2, C(O)O, or C(O)NR3; R3 is H, methyl or ethyl; M is a covalent bond, -[C(O)O-CH2-CH2]n-, a linear or branched alkylene group with 1 to 6 carbon atoms; Z+ is H+, NH4 +, Li+, Na+, K+, ½ Ca++, ½ Mg++, ½ Zn++, or 1/3 Al+++, or combinations thereof. In at least one embodiment, the synthetic polymer unit comprises at least one anionic repeating structural unit selected from the group consisting of acrylic acid, methacrylic acid, itaconic acid, carboxyethylacrylate, carboxyethylacrylate oligomers, 2-propylacrylic acid 2-ethylacrylic acid, and their respective alkali or alkaline earth metal salts. Optionally, the synthetic polymer unit may comprise at least one further optional unit which is different from the above units as unit (c). In at least one embodiment, the synthetic polymer unit comprises at least one of such further optional unit. In at least one embodiment, the optional unit results from the incorporation of a monomer selected from the group consisting of unsaturated carboxylic acids and their anhydrides and salts, and also their esters with aliphatic, olefinic, cycloaliphatic, arylaliphatic or aromatic alcohols having a carbon number of from 1 to 22. In at least one embodiment, the optional unit results from the incorporation of at least one monomer selected from the group consisting of functionalized (meth)acrylic acid esters, acrylic or methacrylic acid amides, polyglycol acrylic or methacrylic acid esters, polyglycol acrylic or methacrylic acid amides, dipropyleneglycolacrylic or methacrylic acid esters, dipropylenglycolacrylic or methacrylic acid amides, ethoxylated fatty alcohol acrylates or -methacrylates,
propoxylated fatty alcohol acrylates or linear or cyclic N-vinylamides or N-methylvinyl amides. In at least one embodiment, the optional unit results from the incorporation of a monomer selected from the group consisting of N-vinylformamide, N-vinylacetamide, N methyl-N-vinylformamide, N-methyl-N-vinylacetamide, N-vinyl-2-pyrrolidone (NVP), N vinylcaprolactam, vinylacetate, methylvinylether, ethylvinylether, methylallylether, ethylmethallylether, styrol, acetoxystyrol, methylmethallylether, ethylallylether, tert-butylacrylamide, N,N-diethylacrylamide, N,N-dimethylacrylamide, N,N-dimethylmethacrylamide, N,N-dipropylacrylamide, N-isopropylacrylamide, N-propylacrylamide, acrylamide, methacrylamide, methylacrylate, methymethylacrylate, tert-butylacrylate, tert-butylmethacrylate, n-butylacrylate, n-butylmethacrylate, laurylacrylate, laurylmethacrylate, behenylacrylate, behenylmethacrylate, cetylacrylate, cetylmethacrylate, stearylacrylate, stearylmethacrylate, tridecylacrylate, tridecylmethacrylate, polyethoxy-(5)-methacrylate, polyethoxy-(5)-acrylate, polyethoxy-(10)- methacrylate, polyethoxy-(10)-acrylate, behenylpolyethoxy-(7)-methacrylate, behenylpolyethoxy-(7)-acrylate, behenylpolyethoxy-(8)-methacrylate, behenylpoly- ethoxy-(8)-acrylate, behenylpolyethoxy-(12)-methacrylate, behenylpoly-ethoxy- (12)-acrylate, behenylpolyethoxy-(16)-methacrylate, behenylpolyethoxy-(16)- acrylate, behenylpolyethoxy-(25)-methacrylate, behenylpolyethoxy-(25)-acrylate, laurylpoly-ethoxy-(7)-methacrylate, laurylpolyethoxy-(7)-acrylate, laurylpolyethoxy- (8)-methacrylate, laurylpolyethoxy-(8)-acrylate, laurylpolyethoxy-(12)-methacrylate, laurylpolyethoxy-(12)-acrylate, laurylpolyethoxy-(16)-methacrylate, laurylpolyethoxy-(16)-acrylate, laurylpolyethoxy-(22)-methacrylate, laurylpolyethoxy-(22)-acrylate, laurylpolyethoxy-(23)-methacrylate, laurylpolyethoxy-(23)-acrylate, cetylpolyethoxy-(2)-methacrylate, cetylpolyethoxy- (2)-acrylate, cetylpolyethoxy-(7)-methacrylate, cetylpolyethoxy-(7)-acrylate, cetylpolyethoxy-(10)-methacrylate, cetylpolyethoxy-(10)-acrylate, cetylpolyethoxy- (12)-methacrylate, cetylpolyethoxy-(12)-acrylate cetylpoly-ethoxy-(16)- methacrylate, cetylpolyethoxy-(16)-acrylate cetylpolyethoxy-(20)-methacrylate, cetylpolyethoxy-(20)-acrylate, cetylpolyethoxy-(25)-methacrylate, cetylpolyethoxy- (25)-acrylate, cetylpolyethoxy-(25)-methacrylate, cetylpolyethoxy-(25)-acrylate,
stearylpolyethoxy-(7)-methacrylate, stearylpolyethoxy-(7)-acrylate, stearylpoly- ethoxy-(8)-methacrylate, stearylpolyethoxy-(8)-acrylate, stearylpolyethoxy-(12)- methacrylate, stearylpolyethoxy-(12)-acrylate, stearylpolyethoxy-(16)- methacrylate, stearylpolyethoxy-(16)-acrylate, stearylpolyethoxy-(22)- methacrylate, stearylpoly-ethoxy-(22)-acrylate, stearylpolyethoxy-(23)- methacrylate, stearylpolyethoxy-(23)-acrylate, stearylpolyethoxy-(25)- methacrylate, stearylpolyethoxy-(25)-acrylate, tridecylpolyethoxy-(7)-methacrylate, tridecylpolyethoxy-(7)-acrylate, tridecylpolythoxy-(10)-methacrylate, tridecylpolyethoxy-(10)-acrylate, tridecylpolyethoxy-(12)-methacrylate, tridecylpolyethoxy-(12)-acrylate, tridecylpolyethoxy-(16)-methacrylate, tridecylpolyethoxy-(16)-acrylate, tridecylpolyethoxy-(22)-methacrylate, tridecylpoly- ethoxy-(22)-acrylate, tridecylpolyethoxy-(23)-methacrylate, tridecylpolyethoxy-(23)- acrylate, tridecylpoly-ethoxy-(25)-methacrylate, tridecylpolyethoxy-(25)-acrylate, methoxypolyethoxy-(7)-methacrylate, methoxy-polyethoxy-(7)-acrylate, methoxypoly-ethoxy-(12)-methacrylate, methoxypolyethoxy-(12)-acrylate, methoxypolyethoxy-(16)-methacrylate, methoxypolyethoxy-(16)-acrylate, methoxypolyethoxy-(25)-methacrylate, methoxy-polyethoxy-(25)-acrylate, acrylic acid, ammonium acrylate, sodium acrylate, potassium acrylate, lithium acrylate, zinc acrylate, calcium acrylate, magnesium acrylate, zirconium acrylate, methacrylic acid, ammonium methacrylate, sodium methacrylate, potassium methacrylate, lithium methacrylate, calcium methacrylate, magnesium methacrylatee, zirconium methacrylate, zinc methacrylate, 2-carboxyethylacrylate, ammonium 2-carboxyethylacrylate, sodium 2-carboxyethylacrylate, potassium 2-carboxyethylacrylate, lithium 2 carboxyethylacrylate, zinc 2-carboxyethylacrylate, calcium 2-carboxyethylacrylate, magnesium 2-carboxyethylacrylate, zirconium 2-carboxyethylacrylate, 2-carboxyethylacrylate-oligomere, ammonium 2-carboxyethylacrylate-oligomers, sodium 2-carboxyethylacrylate-oligomers, potassium 2-carboxyethylacrylate-oligomers, lithium 2 carboxyethylacrylate- oligomers, zinc 2-carboxyethylacrylate-oligomers, calcium 2-carboxyethylacrylate- oligomers, magnesium 2-carboxyethylacrylate-oligomers, zirconium 2-carboxyethylacrylate-oligomers, itaconic acid, sodium itaconate, potassium itaconate, lithium itaconate, calcium itaconate, magnesium itaconate, zirconium itaconate, zinc itaconate,2-ethylacryl acid, ammonium 2-ethylacrylate, sodium
2-ethylacrylate, potassium 2-ethylacrylate, lithium 2-ethylacrylate, calcium 2-ethylacrylate, magnesium 2-ethylacrylate, zirconium 2-ethylacrylate, zinc 2-ethylacrylate, 2-propylacryl acid, ammonium 2-propylacrylate, sodium 2-propylacrylate, potassium 2-propylacrylate, lithium 2-propylacrylate, calcium 2-propylacrylate, magnesium 2-propylacrylate, magnesium 2-propylacrylate, zirconium 2-propylacrylate, zinc 2-propylacrylate, and combinations thereof. In at least one embodiment, the optional unit results from the incorporation of a monomer selected from the group consisting of N-vinylformamide, N- vinylacetamide, N-methyl-N-vinylacetamide, N-vinyl-2-pyrrolidone (NVP), N,N- diethylacrylamide, acrylamide, methacrylamide, methylacrylate, methylmethylacrylate, tert-butylacrylate, acrylic acid, methacrylic acid, 2- carboxyethylacrylate, 2-carboxyethylacrylate oligomers, itaconic acid, and combinations thereof. In at least one embodiment, the optional unit results from the incorporation of a monomer selected from the group consisting of acrylic acid, methacrylic acid, styrenesulfonic acid, maleic acid, fumaric acid, crotonic acid, itaconic acid, and senecic acid. In at least one embodiment, the optional unit results from monomers selected from the group consisting of open-chain N-vinyl amides, preferably N-vinylformamide (VIFA), N-vinylmethylformamide, N-vinylmethylacetamide (VIMA) and N-vinylacetamides; cyclic N-vinyl amides (N-vinyl lactams) with a ring size of 3 to 9, preferably N-vinylpyrrolidones (NVP) and N-vinylcaprolactam; amides of acrylic and methacrylic acid, preferably acrylamide, methacrylamide, N,N-dimethylacrylamide, N,N-diethylacrylamide, and N,N-diisopropylacrylamide; alkoxylated acrylamides and methacrylamides, preferably hydroxyethyl methacrylate, hydroxymethylmethacrylamide; hydroxyethylmethacryl amide, hydroxypropylmethacrylamide, and mono[2-(methacryloyloxy)ethyl]succinate; N,N-dimethylaminomethacryIate; diethylaminomethylmethacryIate; acrylamideo- and methacrylamideoglycolic acid; 2- and 4-vinylpyridine; vinyl acetate; glycidyl methacrylate; styrene; acrylonitrile; vinyl chloride; stearyl acrylate; lauryl methacrylate; vinylidene chloride; tetrafluoroethylene; and combinations thereof.
Hybrid polymer The polysaccharide polymer unit may be uncharged or charged (i.e., a salt). In at least one preferred embodiment, the polysaccharide polymer unit is uncharged. Preferably, such polymer unit is a water-soluble and/or water-swellable polymer unit. Polysaccharide polymer unit. In at least one embodiment, the polymer is a hybrid polymer comprising polysaccharide polymer unit. In at least one embodiment, the polymer is a water- soluble and/or water-swellable hybrid polymer comprising at least one water- soluble and/or water-swellable polysaccharide polymer unit. In at least one embodiment, the water-soluble and/or water-swellable polysaccharide polymer unit is an uncharged polysaccharide polymer unit. In at least one particularly preferred embodiment, the polymer is a water-soluble and/or water-swellable uncharged polysaccharide polymer unit. In at least one embodiment, the polysaccharide polymer unit absorbs water and/or forms a gel or gum when immersed in water. In at least one embodiment, the polysaccharide polymer unit is a natural gum or mucilage. Natural gums are useful because they are generally soluble in water due to the presence of an excessive number of -OH moieties which form hydrogen bonds with water molecules. In at least one embodiment, the polysaccharide polymer unit is a natural gum derived from a plant. In at least one embodiment, the polysaccharide polymer is selected from the group consisting of wherein the water-soluble and/or water-swellable polysaccharide polymer unit is selected from the group consisting of chitosan, xanthan gum, fenugreek gum, tara gum, locust bean gum, carrageenan, guar gum, alginate, agar, gum tragacanth, tamarind kernel gum, gum arabica, cherry gum, gum karaya, okra gum, cassia gum, chicle gum, konjac gum glucomannan, gum ghatti,
pectin, sclerotium gum, gellan gum, Tamarindus indica seed gum, sclerotium gum, dextran, dextrin, starch, derivatives thereof, and combinations thereof. In at least one embodiment, the polysaccharide polymer is selected from the group consisting of wherein the water-soluble and/or water-swellable polysaccharide polymer unit is selected from the group consisting of chitosan, xanthan gum, fenugreek gum, tara gum, locust bean gum, carrageenan, guar gum, alginate, agar, gum tragacanth, tamarind kernel gum, gum arabica, cherry gum, gum karaya, okra gum, cassia gum, chicle gum, konjac gum glucomannan, gum ghatti, pectin, sclerotium gum, gellan gum, Tamarindus indica seed gum, sclerotium gum, dextran, dextrin, starch, and combinations thereof. Chemically modified versions of such polymers may also be used. “Modified polysaccharides” means that the polysaccharide polymer treated by one or more suitable physical, enzymatic or chemical process into another modified form of the polysaccharide polymer. A modified form of the polysaccharide polymer treat by a suitable physical, enzymatic or chemical process mean e.g.: - Acidic treatment of polysaccharide polymer by the reaction with Acids (e.g. hydrochloric acid, phosphoric acid, or sulphuric acid) - Alkaline treatment of polysaccharide polymer by the reaction with bases (e.g. Sodium hydroxide or potassium hydroxide) - bleached polysaccharide polymer by the reaction with peracetic acid, hydrogene peroxide, sodium hypochlorite, sulfur dioxide, sulphites, potassium permanganate or ammonium persulfate. - Enzymatic modified form of the polysaccharide polymer by the treatment with encymes. - oxidised polysaccharide polymer by oxidation (e.g. with Sodium hypochlorite) - acetylated polysaccharide polymer by esterification with e.g. anhydrides - hydroxypropyl Polysaccharide by reaction with propylene oxide
- hydroxyethyl Polysaccharide by reaction with ethylene oxide Chitosan is a linear polysaccharide composed of randomly distributed β-linked D glucosamine and N-acetyl-D-glucosamine monomers. Xanthan gum is composed of pentasaccharide repeat units, comprising glucose, mannose, and glucuronic acid in the molar ratio of about 2.0:2.0:1.0. Fenugreek gum is, as its name suggests, derived from fenugreek and is a galactomannan where the ratio of mannose:galactose is approximately 1:1. Tara gum is a galactomannan and comes from the small tree or thorny shrub having the latin name Caesalpinia spinosa. The ratio of mannose:galactose in tara gum is approximately 3:1. Locust bean gum is a galactomannan vegetable gum extracted from the seeds of the carob tree. Locust bean gum consists mainly of high-molecular-weight hydrocolloidal polysaccharides composed of galactose and mannose units combined through glycosidic linkages. Carrageenan is a linear sulfated polysaccharide that are extracted from red edible seaweeds. There are three main varieties of carrageenan, which differ in their degree of sulfation: kappa- carrageenan has one sulfate group per disaccharide; iota-carrageenan has two sulfates per disaccharide; lambda carrageenan has three sulfates per disaccharide. All carrageenans are high-molecular weight polysaccharides made up of repeating galactose units and 3,6-anhydrogalactose, both sulfated and non sulfated. The units are joined by alternating α-1,3 and β-1,4 glycosidic linkages. Guar gum is a polysaccharide composed of the sugars galactose and mannose: the backbone is a linear chain of β 1,4-linked mannose residues to which galactose residues are 1,6-linked at every second mannose, forming short side- branches. Guar gum is primarily the groand endosperm of guar beans. Alginate may also be referred to in the literature as algin or alginic acid. Alginate is an anionic polysaccharide derived from brown algae and is a linear copolymer with homopolymeric blocks of (1-4)-linked β-D-mannuronate residues and α L guluronate residues. Agar is derived from the polysaccharide agarose, which forms the supporting structure in the cell walls of certain species of algae. Agar is actually the resulting mixture of two components: the linear polysaccharide agarose, and a heterogeneous mixture of smaller molecules called agaropectin. Agarose is a linear polymer made up of the repeating unit of agarobiose, which is
a disaccharide made up of D-galactose and 3,6-anhydro-L-galactopyranose. Gum tragacanth is a natural gum obtained from the dried sap of several species of Middle Eastern legumes of the genus Astragalus. Gum tragacanth is made up of two types of polysaccharide fractions: tragacanthin and bassorin. Tragacanthin is water-soluble and bassorin is water-swellable. The polysaccharide fractions of gum tragacanth comprise D galacturonic acid, D-galactose, L-fructose, D-xylose and L-arabinose. Tamarind kernel gum is a polysaccharide of glucose, galactose and xylose in a molar ratio of about 3:2:1. The backbone of the tamarind seed gum polysaccharide is based on a glucose units that are substituted with galactose and xylose. Gum Arabica comes from the Acacia tree. Both gum Arabica and gum ghatti comprise arabinogalactan polysaccharide, which consists of arabinose and galactose monosaccharides. Konjac glucomannan is a non-ionic polysaccharide foand in the tubers of Amorphophallus konjac and consists of (1,4)-linked β D mannose and β –D-glucose in a molar ratio of about 1.6:1. Preferably, the polysaccharide polymer unit is an uncharged polysaccharide polymer unit. The term “uncharged polysaccharide polymer unit” is well known to a person skilled in the art. In at least one embodiment, the polysaccharide polymer unit is selected from the group consisting of tara gum, guar gum, locust bean gum, cassia gum (e.g., cassia tora gum), fenugreek gum, cellulose, starch, glucomannan, Tamarindus Indica Seed Gum, sclerotium gum, dextran, dextrin, xanthan gum, and combinations thereof, preferably from the group consisting of tara gum, guar gum, glucomannan, and combinations thereof. In at least one embodiment, the polysaccharide polymer comprises glucose and/or galactose units. In at least one embodiment, the polysaccharide polymer is a galactomannan. Galactomannans are polysaccharides consisting of a mannose backbone with galactose side groups (more specifically, a (1-4)-linked beta-D- mannopyranose backbone with branchpoints from their 6-positions linked to alpha- D-galactose, i.e.1-6-linked alpha-D-galactopyranose). In at least one embodiment, the polysaccharide polymer is a guar gum or a guar gum derivative. In at least one embodiment, the guar gum derivative is selected from the group consisting of
hydroxypropyl guar gum, carboxymethyl guar gum, carboxymethyl hydroxypropyl guar gum, and quaternary ammonium guar gum. In at least one embodiment, the polysaccharide polymer is an arabinogalactan. In at least one embodiment, the polysaccharide polymer is selected from the group consisting of chitosan, xanthan gum, locust bean gum, carrageenan, guar gum, alginate, agar, fenugreek gum, konjac gum, derivatives thereof, and combinations thereof. In at least one embodiment, the polysaccharide polymer is selected from the group consisting of xanthan gum, carrageenan, guar gum, chitosan and alginate. In a preferred embodiment, the polysaccharide polymer is selected from the group consisting of xanthan gum, carrageenan, guar gum, and combinations thereof. In a preferred embodiment, the polysaccharide polymer is xanthan gum. In at least one embodiment, the polysaccharide polymer unit is selected from the group consisting of tara gum, guar gum, locust bean gum, cassia gum (e.g., cassia tora gum), fenugreek gum, cellulose, starch, glucomannan, and combinations thereof, preferably from the group consisting of tara gum, guar gum, glucomannan, and combinations thereof. In at least one embodiment, the polysaccharide polymer unit is selected from the group consisting of tara gum, guar gum, locust bean gum, cassia gum ((e.g., cassia tora gum), fenugreek gum, cellulose, starch, xanthan gum, and combinations thereof, preferably from the group consisting of tara gum, guar gum, and combinations thereof. In at least one embodiment, the polysaccharide polymer unit comprises mannose and/or galactose units, preferably the polysaccharide polymer unit is a galactomannan. Galactomannans are polysaccharides consisting of a mannose backbone with galactose side groups (more specifically, a (1-4)-linked beta-D- mannopyranose backbone with branching points from their 6-positions linked to alpha-D-galactose, i.e.1-6-linked alpha-D-galactopyranose).
In at least one embodiment, the polysaccharide polymer unit is selected from the group consisting of tara gum, guar gum, locust bean gum, cassia gum (e.g., cassia tora gum), fenugreek gum, glucomannan, Tamarindus Indica Seed Gum, sclerotium gum, dextran, dextrin, xanthan gum, starch, and combinations thereof, preferably from the group consisting of tara gum, guar gum, glucomannan, and combinations thereof. In at least one embodiment, the polysaccharide polymer unit is selected from the group consisting of tara gum, guar gum, xanthan gum, locust bean gum, cassia gum (e.g., cassia tora gum), fenugreek gum, glucomannan, and combinations thereof, preferably from the group consisting of tara gum, guar gum, glucomannan, and combinations thereof. In at least one embodiment, the polysaccharide polymer unit is selected from the group consisting of tara gum, guar gum, locust bean gum, cassia gum (e.g., cassia tora gum), fenugreek gum, and combinations thereof, preferably from the group consisting of tara gum, guar gum, and combinations thereof. In at least one embodiment, the polysaccharide polymer unit is selected from the group consisting of tara gum, guar gum, and combinations thereof. In a particularly preferred embodiment, the polysaccharide polymer unit comprises tara gum, preferably is tara gum. In a particularly preferred embodiment, the polysaccharide polymer unit comprises guar gum, preferably is guar gum. In a particularly preferred embodiment, the polysaccharide polymer unit comprises glucomannan, preferably is glucomannan. Purified versions of the above polysaccharides may also be used. Chemically modified versions of the above polysaccharides may also be used. “Modified polysaccharide” means that the polysaccharide polymer unit was subjected to one or more suitable physical, enzymatic or chemical process(es) to
be converted into a modified form of the polysaccharide polymer unit. Examples of such processes include: - acidic treatment of polysaccharide polymer unit by the reaction with acids (e.g. hydrochloric acid, phosphoric acid, or sulphuric acid) - alkaline treatment of polysaccharide polymer unit by the reaction with bases (e.g. sodium hydroxide or potassium hydroxide) - bleached polysaccharide polymer unit by the reaction with peracetic acid, hydrogen peroxide, sodium hypochlorite, sulfur dioxide, sulphites, potassium permanganate or ammonium persulfate - enzymatic modified form of the polysaccharide polymer unit by the treatment with enzymes - oxidized polysaccharide polymer unit by oxidation (e.g. with sodium hypochlorite) - acetylated polysaccharide polymer unit by esterification with e.g. anhydrides - hydroxypropyl polysaccharide by reaction with propylene oxide - hydroxyethyl polysaccharide by reaction with ethylene oxide In at least one embodiment, the polysaccharide polymer unit is a guar gum or a guar gum derivative. In at least one embodiment, the guar gum derivative is selected from the group consisting of hydroxypropyl guar gum, carboxymethyl guar gum, carboxymethyl hydroxypropyl guar gum, and quaternary ammonium guar gum. Fenugreek gum is, as its name suggests, derived from fenugreek and is a galactomannan where the ratio of mannose:galactose is approximately 1:1. Tara gum is a galactomannan and comes from the small tree or thorny shrub having the latin name Caesalpinia spinosa. The ratio of mannose:galactose in tara gum is approximately 3:1. Locust bean gum is a galactomannan vegetable gum extracted from the seeds of the carob tree. Locust bean gum consists mainly of high- molecular-weight hydrocolloidal polysaccharides composed of galactose and mannose units combined through glycosidic linkages. Guar gum is a polysaccharide composed of the sugars galactose and mannose: the backbone is a linear chain of β 1,4-linked mannose residues to which galactose residues are
1,6-linked at every second mannose, forming short side-branches. Guar gum is primarily the ground endosperm of guar beans. Glucomannan is a polysaccharide composed of the sugars glucose and mannose. In at least one embodiment, the polysaccharide polymer unit is substantially free of starch, amylose, amylopectin, glycogen, cellulose, and derivatives thereof. Cellulose derivatives include for example cellulose ethers, carboxymethylcellulose, and hydroxyethylcellulose. In another embodiment, the polysaccharide polymer unit comprises at least one of starch, amylose, amylopectin, glycogen, cellulose, and derivatives thereof. Cellulose derivatives include for example cellulose ethers, carboxymethylcellulose, or hydroxyethylcellulose. In at least one embodiment, the polymer is a water-soluble and/or water-swellable hybrid polymer comprising (i) from 1 wt.-% to 70 wt.-% synthetic polymer unit comprising (a) from 90 mol-% to 99.9 mol-%, preferably 95 mol-% to 99.5 mol-% of repeating units according to Formula (1)
wherein R1 and R2 are independently selected from H, methyl or ethyl; A is a linear or branched C1-C12-alkyl group; and Q+ is H+, NH4+, an organic ammonium ion [NHR5R6R7]+ wherein R5, R6, and R7 independently of one another is hydrogen, a linear or branched alkyl group having 1 to 22 carbon atoms, a linear or branched, mono- or poly-unsaturated alkenyl group having 2 to 22 carbon atoms, a C6-C22 alkylamidopropyl group, a linear mono- hydroxyalkyl group having 2 to 10 carbon atoms or a linear or branched dihydroxyalkyl group having 3 to 15 carbon atoms, and
wherein at least one of the radicals R5, R6, and R7 is not hydrogen, or Q+ is Li+, Na+, K+, ½ Ca++, ½ Mg++, ½ Zn++, 1/3 Al+++, or combinations thereof; (b) from 0.01 mol-% to 10 mol-%, preferably to 5 mol-%, more preferably to 3 mol-% of crosslinking or branching units, wherein the crosslinking or branching units result from the incorporation of a monomer comprising at least two olefinically unsaturated double bonds; (ii) from 30 wt.-% to 99 wt.-% water-soluble and/or water-swellable polysaccharide polymer unit, wherein the polysaccharide polymer unit is an uncharged polysaccharide polymer unit; wherein the components (i) and (ii) are polymerized by radical precipitation polymerization in a polar solvent. In at least one embodiment, the polymer is a water-soluble and/or water-swellable hybrid polymer may herein simply be referred to as ‘hybrid polymer’, for brevity. The hybrid polymer comprises (ii) from 30 wt.-% to 99 wt.-% polysaccharide polymer unit and (i) from 1 wt.-% to 70 wt.-% synthetic polymer unit. Preferably, the hybrid polymer comprises (ii) from 30 wt.-% to 95 wt.-% polysaccharide polymer unit and (i) from 5 wt.-% to 70 wt.-% synthetic polymer unit. In at least one embodiment, the hybrid polymer comprises or consists of: (i) from 10 wt.-% to 70 wt.-%, or from 15 wt.-% to 70 wt.-%, or from 20 wt.-% to 70 wt.-%, or from 25 wt.-% to 70 wt.-%, or from 30 wt.-% to 70 wt.-%, or from 35 wt.-% to 65 wt.-%, or from 40 wt.-% to 60 wt.-%, or from 45 wt.-% to 55 wt.-% synthetic polymer unit, by total weight of the hybrid polymer; and (ii) from 30 wt.-% to 90 wt.-%, or from 30 wt.-% to 85 wt.-%, or from 30 wt.-% to 80 wt.-%, or from 30 wt.-% to 75 wt.-%, or from 30 wt.-% to 70 wt.-%, or from 35 wt.-% to 65 wt.-%, or from 40 wt.-% to 60 wt.-%, or from 45 wt.-% to 55 wt.-% polysaccharide polymer unit, by total weight of the hybrid polymer. In at least one embodiment, the hybrid polymer comprises at least 40 wt.-%, preferably at least 50 wt.-%, more preferably at least 60 wt.-%, even more
preferably at least 65 wt.-%, or at least 70 wt.-% polysaccharide polymer unit, by total weight of the hybrid polymer. In at least one embodiment, the hybrid polymer comprises at most 60 wt.-%, preferably at most 50 wt.-%, more preferably at most 40 wt.-%, more preferably at most 30 wt.-%, more preferably at most 25 wt.-%, even more preferably at most 20 wt.-%, even more preferably at most 15 wt.-%, particularly preferably at most 10 wt.-% synthetic polymer unit, by total weight of the hybrid polymer. In at least one embodiment, the hybrid polymer comprises (i) from 5 wt.-% to 60 wt.-%, preferably from 10 wt.-% to 50 wt.-%, more preferably from 15 wt.-% to 40 wt.-%, more preferably from 20 wt.-% to 40 wt.-%, even more preferably from 25 wt.-% to 40 wt.-%, particularly preferably from 30 wt.-% to 40 wt.-%, or from 25 wt.-% to 35 wt.-% synthetic polymer unit, by total weight of the hybrid polymer; and (ii) from 40 wt.-% to 95 wt.-%, preferably from 50 wt.-% to 90 wt.-%, more preferably from 60 wt.-% to 85 wt.-%, more preferably from 60 wt.-% to 80 wt.-%, even more preferably from 60 wt.-% to 75 wt.-%, particularly preferably from 60 wt.-% to 70 wt.-%, or from 65 wt.-% to 75 wt.-% polysaccharide polymer unit, by total weight of the hybrid polymer. In another preferred embodiment, the hybrid polymer comprises (ii) from 5 wt.-% to 50 wt.-%, preferably from 5 wt.-% to 40 wt.-%, more preferably from 5 wt.-% to 30 wt.-%, even more preferably from 5 wt.-% to 20 wt.-% synthetic polymer unit, by total weight of the hybrid polymer; and (i) from 50 wt.-% to 95 wt.-%, preferably from 60 wt.-% to 95 wt.-%, more preferably from 70 wt.-% to 95 wt.-%, even more preferably from 80 wt.-% to 95 wt.-% polysaccharide polymer unit, by total weight of the hybrid polymer. For example, the hybrid polymer has a weight ratio of polysaccharide polymer unit to synthetic polymer unit of 30:70; or 40:60; or 50:50; or 60:40; or 70:30; or 80:20; or 90:10; or 95:5; or 99:1; or any other ratio between 30:70 and 99:1.
In at least one embodiment, the hybrid polymer is substantially free of species that release ammonia when the hybrid polymer is used, e.g. employed in alkaline cosmetic compositions. In at least one embodiment, the structure of the hybrid polymer is such that a polysaccharide polymer unit is a backbone onto which one or more synthetic polymer units are grafted. In at least one embodiment, a 1 wt.-% gel of the polymer in deionized water has: a mesh size of from 10 nm to 80 nm, preferably from 10 nm to 50 nm, more preferably from 15 nm to 50 nm, even more preferably from 20 nm to 50 nm, particularly preferably from 30 nm to 40 nm; a tan delta of from 0.2 to 0.9, preferably from 0.3 to 0.7, particularly preferably from 0.3 to 0.6; and/or a yield point of from 1 Pa to 15 Pa, preferably from 2 Pa to 12 Pa, more preferably from 2 Pa to 9 Pa, even more preferably from 2 Pa to 8 Pa, particularly preferably from 3 Pa to 7 Pa. In at least one embodiment, a 1% gel of the polymer as used herein, in particular wherein the polymer is a hybrid polymer, of the invention in deionized water has a mesh size of from 10 nm to 40 nm, preferably from 15 nm to 40 nm. The % as used in this context refers to wt.-%. A mesh size within these ranges is advantageous because it forms a stable polymer gel. The mesh size as used herein is calculated as follows: mesh size [nm] = ^ ^^^⁄ ^′^^^^^^^ wherein: G’initial is the network stability G’initial; k is the Boltzmann constant; and
T is the measurement temperature: k Boltzmann constant 1.380649E-23 J/K T Measurement temperature 293.15 K G’initial Network stability G’initial Pa The network stability G’initial as used herein is determined using a hybrid rheometer. More specifically, a DHR-3 of TA Instruments is used. DHR refers to Discovery Hybrid Rheometer. In at least one embodiment, a 1 % gel of the polymer as used herein, in particular wherein the polymer is a hybrid polymer, of the invention in deionized water has a tan delta (elasticity loss factor) of from 0.2 to 0.9, preferably from 0.3 to 0.7, more preferably from 0.3 to 0.6, particularly preferably from 0.4 to 0.6. The % as used in this context refers to wt.-%. A tan delta within these ranges is advantageous because it shows a viscoelastic behavior. The tan delta as used herein is determined using a hybrid rheometer. More specifically, a DHR-3 of TA Instruments is used. DHR refers to Discovery Hybrid Rheometer. In at least one embodiment, a 1 % gel of the polymer as used herein, in particular wherein the polymer is a hybrid polymer, of the invention in deionized water has a yield point of from 1 Pa to 15 Pa, preferably from 2 Pa to 12 Pa, more preferably from 2 Pa to 9 Pa, even more preferably from 2 Pa to 8 Pa, even more preferably from 3 Pa to 7 Pa, particularly preferably from 3 Pa to 6 Pa. The % as used in this context refers to wt.-%. A yield point within these ranges is advantageous because it fits to the desired rheology-modifying properties. The yield point as used herein is determined using a hybrid rheometer. More
specifically, a DHR-3 of TA Instruments is used. DHR refers to Discovery Hybrid Rheometer. In at least one embodiment, a 1 % gel of the polymer as used herein, in particular wherein the polymer is a hybrid polymer, of the invention in deionized water has a mesh size as described above or a tan delta as described above or a yield point as described above. In at least one embodiment, a 1 % gel of the polymer as used herein, in particular wherein the polymer is a hybrid polymer, of the invention in deionized water has a mesh size as described above or a tan delta as described above. In at least one embodiment, a 1 % gel of the polymer as used herein, in particular wherein the polymer is a hybrid polymer, of the invention in deionized water has a mesh size as described above or a yield point as described above. In at least one embodiment, a 1 % gel of the polymer as used herein, in particular wherein the polymer is a hybrid polymer, of the invention in deionized water has a tan delta as described above or a yield point as described above. In at least one embodiment, a 1 % gel of the polymer as used herein, in particular wherein the polymer is a hybrid polymer, of the invention in deionized water has a mesh size as described above and a tan delta as described above. In at least one embodiment, a 1 % gel of the polymer as used herein, in particular wherein the polymer is a hybrid polymer, of the invention in deionized water has a mesh size as described above and a yield point as described above. In at least one embodiment, a 1 % gel of the polymer as used herein, in particular wherein the polymer is a hybrid polymer, of the invention in deionized water has a tan delta as described above and a yield point as described above.
In a particularly preferred embodiment, a 1 % gel of the polymer as used herein, in particular wherein the polymer is a hybrid polymer, of the invention in deionized water has a mesh size as described above and a tan delta as described above and a yield point as described above. In at least one embodiment, the polymer has a biodegradability of at least 30%, preferably at least 60%, more preferably at least 70%, particularly preferably at least 80%, determined according to OECD Method 301 B. In at least one embodiment, the polymer is a polymer as used herein, in particular wherein the polymer is a hybrid polymer, that is readily biodegradable, which means that the polymer as used herein, in particular wherein the polymer is a hybrid polymer, has a biodegradability of at least 60%, determined according to OECD Method 301 B. In another embodiment, the polymer as used herein, in particular wherein the polymer is a hybrid polymer, of the invention is inherently biodegradable (OECD 302). Example embodiments of polymer as used herein, in particular wherein the polymer is a hybrid polymers, where the polysaccharide polymer unit is glucomannan are given in the following Table 1: Table 1. Exemplified polymers Synthetic Crosslinker Example Glucomannan Polymer Monomer [Name / mol- embodiment [wt.-%] [ATBS / [wt.-%] %] mol-%] E1 69.5 30.5 98.7 TMPTA 1.3 E2 69.5 30.5 99.1 GPTA 0.9 E3 80 20 98.1 TMPTA 1.9
E4 80 20 98.7 GPTA 1.3 E5 90 10 96.1 TMPTA 3.9 Such polymer as used herein, in particular wherein the polymer is a hybrid polymers can, for example, be prepared according to the methods described in the Examples section. Polymerization The polymer as used herein may be obtained by any means. The polymer as used herein, in particular when it is a hybrid polymer comprising one or more synthetic polymer units (component (i)) and one or more polysaccharide polymer units (component (ii)) is preferably polymerized by radical precipitation polymerization in a solvent. In at least one embodiment, the polymer is obtained by radical precipitation polymerization, preferably in a polar solvent, in particular wherein the radical precipitation polymerization is carried out in a polar solvent mixture comprising water and a further compound. Radical precipitation polymerization may have the advantage over other synthesis methods in that it results in a more useful level of polymer branching. In at least one embodiment, the polymerization is grafting radical precipitation polymerization. In at least one embodiment, the solvent is an organic or inorganic solvent having a highly inert behaviour in free-radical polymerization reactions and which advantageously allows the formation of medium or high molecular weights, or mixtures of such solvents. The choice of chemistry and level of solvent is important in view of ensuring the dispersion and dissolving of the units making up the polymer, in particular when it is a hybrid polymer, in the reaction mixture. Furthermore, the polymer, in particular when it is a hybrid polymer, as it is synthesised should not result in the build-up of clumps and/or adhesions in the reaction mixture or on the equipment. It is advantageous that no significant agglomerates and adhesions build up within the stirring equipment because of the risk of damage and extension cleaning requirements. In at least one embodiment,
the solvent has a boiling point of from 20 °C to 110 °C, or from 40 °C to 95 °C, or from 50 °C to 90 °C. In at least one embodiment, the solvent is a polar solvent. In at least one embodiment, the solvent is selected from the group consisting of water, lower alcohols, and mixtures of water and lower alcohols. In at least one embodiment, the solvent is selected from the group consisting of methanol, ethanol, propanol, acetone, iso-, sec- and t-butanol, hydrocarbons having 1 to 30 carbon atoms, and mixtures and emulsions thereof. In at least one embodiment, the solvent is a mixture of water and a solvent selected from the group consisting of methanol, ethanol, propanol, acetone, iso-, sec- and t-butanol, hydrocarbons having 1 to 30 carbon atoms. In at least one embodiment, the solvent is selected from the group consisting of methanol, ethanol, 1-propanol, 2-propanol, 2-methyl-2-propanol, 1-butanol, 2-butanol, dimethyl ketone, diethyl ketone, tetrahydropyran, tetrahydrofuran, 2-methyltetrahydrofuran, 1,3-dioxane, 1,4-dioxane, preferably ethanol, 1-propanol, 2-propanol, 2-methylpropan-2-ol, 1-butanol, 2-butanol, dimethyl ketone, tetrahydrofuran, 2-methyltetrahydrofuran, 1,3-dioxane, even more preferably 2-propanol, 2-methylpropan-2-ol, dimethyl ketone, tetrahydrofuran, 2-methyltetrahydrofuran, 1,3-dioxane, most preferably 2-methylpropan-2-ol and dimethyl ketone. In at least one embodiment, the solvent is a mixture of water and a solvent is selected from the group consisting of methanol, ethanol, 1-propanol, 2-propanol, 2-methyl-2-propanol, 1-butanol, 2-butanol, dimethylketone, diethylketone, tetrahydropyran, tetrahydrofuran, 2-methyltetrahydrofuran, 1,3-dioxane, 1,4-dioxane, preferably ethanol, 1-propanol, 2-propanol, 2-methylpropan-2-ol, 1-butanol, 2-butanol, dimethylketone, tetrahydrofuran, 2-methyltetrahydrofuran, 1,3-dioxane, even more preferably 2-propanol, 2-methylpropan-2-ol, dimethylketone, tetrahydrofuran, 2-methyltetrahydrofuran, 1,3-dioxane, most preferably 2-methylpropan-2-ol and dimethyl ketone. In at least one embodiment, the solvent mixture comprises from 0.1 wt.-% to 30 wt.-% water, or from 0.5 wt.-% to 25 wt.-% water, or from 1 wt.-% to 20 wt.-% water, preferably from 0,5 wt.-% to 15 wt.-% water. It is advantageous to ensure that the level of water in the solvent is 30 wt.-% or below in view of reduced likelihood of clumping during the polymerization process. Such build-up of clumps can put the stirring mechanism under undesirable strain. In at least one embodiment, the solvent mixture comprises from 1 wt.-% to 99.5 wt.-% preferably
from 5 wt.-% to 95 wt.-%, more preferably from 10 wt.-% to 90 wt.-% 2-methylpropan-2-ol. In at least one embodiment, the solvent mixture is 2-methylpropan-2-ol and dimethyl ketone. In at least one embodiment, the solvent mixture comprises from 0.5 to 10 wt.-% water, from 1 wt.-% to 98.5 wt.-% 2 methylpropan-2-ol and from 1 wt.-% to 98.5 wt.-% dimethyl ketone, preferably from 0.5 wt.-% to 7.5 wt.-% water, from 5 wt.-% to 94.5 wt.-% 2-methylpropan-2-ol and from 5 wt.-% to 94.5 wt.-% dimethyl ketone, most preferably from 1 wt.-% to 5 wt.-% water, from 7.5 wt.-% to 91.5 wt.-% 2-methylpropan-2-ol and from 7.5 wt.-% to 91.5 wt.-% dimethyl ketone. In at least one embodiment, the radical precipitation polymerization is carried out in a polar solvent mixture comprising (or consisting of): I) water and II) a further compound. In at least one embodiment the compound II) is polar and organic. In at least one embodiment the compound II) is selected from polar alcohols and ketones. In at least one embodiment the compound II) is one or more polar alcohols and one or more ketones. In at least one embodiment, the compound II) is selected from the group consisting of methanol, ethanol, 1-propanol, 2-propanol, 2-methyl-2-propanol, 1- butanol, 2-butanol, dimethyl ketone, diethyl ketone, pentan-2-one, butanone, tetrahydropyran, tetrahydrofuran, 2-methyl-tetrahydrofuran, 1,3-dioxane, 1,4- dioxane, preferably 2-propanol, 2-methyl-2-propanol, dimethyl ketone, tetrahydrofuran, 2-methyl-tetrahydrofuran, more preferably 2-methyl-2-propanol and dimethyl ketone. In a particularly preferred embodiment, the compound II) is 2-methyl-2-propanol. In at least one embodiment, the solvent mixture contains from 0.5 to 10 wt.-%, preferably from 1 to 8 wt.-% and more preferably from 2 to 5 wt.-% water.
In at least one embodiment, the solvent mixture contains from 90 to 99.5 wt.-%, preferably from 92 to 99 wt.-% and more preferably from 95 to 98 wt.-% 2-methyl- 2-propanol. In at least one embodiment, the solvent mixture contains from 0.5 to 10 wt.-% water, from 1 to 98.5 wt.-% 2-methyl-2-propanol and from 1 to 98.5 wt.-% dimethyl ketone, preferably from 0.5 to 7.5 wt.-% water, from 5 to 94.5 wt.-% 2-methyl-2- propanol and from 5 to 94.5 wt.-% dimethyl ketone. In at least one embodiment, the polymerization takes place at a temperature of from 0 °C to 150 °C, or from 10 °C to 100 °C, or from 20 °C to 90 °C, or from 30 °C to 80 °C, or from 30 °C to 70 °C, or from 40 °C to 60 °C, or from 50 °C to 70 °C. In at least one embodiment, the polymerization takes place at either atmospheric pressure or under elevated or reduced pressure. In at least one embodiment, the polymerization may also be performed under an inert gas atmosphere, preferably under nitrogen gas. In at least one embodiment, the polymerization is carried out in the presence of an initiator. The initiator is used for initiating the polymerization. In at least one embodiment, the initiator is selected from high-energy electromagnetic rays, mechanical energy, a chemical initiator, or combinations thereof. In at least one embodiment, the initiator is a radical-producing initiator. In at least one embodiment, the initiator is selected from the group consisting of organic peroxides, persulfates, azo initiators, and mixtures thereof. In at least one embodiment, the initiator is an organic peroxide selected from the group consisting of benzoyl peroxide, tert-butyl hydroperoxide, di-tert-butyl hydroperoxide, triphenylmethyl hydroperoxide, methyl ethyl ketone peroxide, cumene hydroperoxide, dilauroyl peroxide (DLP), and mixtures thereof. In a particularly preferred embodiment, the polymerization is carried out in the presence of dimethyl 2,2'-azobis(2-methylpropionate), 2,2-azobis(2,4- dimethylvaleronitril) or dilauroyl peroxide (DLP). In a particularly preferred
embodiment, the polymerization is carried out in the presence of dimethyl 2,2'- azobis(2-methylpropionate) or 2,2-azobis(2,4-dimethylvaleronitril). In a particularly preferred embodiment, the polymerization is carried out in the presence of dilauroyl peroxide (DLP). In at least one embodiment, the initiator is an azo initiator selected from the group consisting of azo-bis-isobutyronitrile (AIBN), 2,2'-azobis(4-methoxy-2.4-dimethyl valeronitrile), 2,2'-azobis(2,4-dimethyl valeronitrile), dimethyl 2,2'-azobis(2- methylpropionate), 2,2'-azobis(2-methylbutyronitrile), 1,1'-azobis(cyclohexane-1- carbonitrile), 2,2'-azobis[n-(2-propenyl)-2-methyl-propionamide], azobisamideopropyl hydrochloride (ABAH), and mixtures thereof. In at least one embodiment, the initiator is an azo initiator selected from the group consisting of azo-bis-isobutyronitrile (AIBN) and azobisamideopropyl hydrochloride (ABAH). In at least one embodiment, the initiator is a persulfate selected from the group consisting of potassium peroxidisulfate, potassium peroxidisulfate, ammonium peroxidisulfate, potassium peroxi mono sulfat, sodium peroximonosulfate, ammonium peroximonosulfate, and mixtures thereof. Organic persulfates are also useful. In at least one embodiment, the initiator is selected from the group consisting of inorganic peroxy compounds, such as (NH4)2S2O8, K2S2O8 or H2O2, for example, where appropriate in combination with reducing agents (e.g., sodium hydrogensulfite, ascorbic acid, iron(II) sulfate) or redox systems comprising as reducing component an aliphatic or aromatic sulfonic acid (e.g., benzenesulfonic acid, toluenesulfonic acid, etc.). As noted above, in at least one embodiment, the structure of the hybrid polymer is such that a polysaccharide polymer unit is a backbone onto which one or more synthetic polymer units are grafted. In at least one embodiment, the initiator is a mixture of a redox initiator and an azo initiator. This has the advantage that a redox initiator system generates significant amount of –O* radicals on polysaccharide backbone and azo initiator will deliver enough active synthetic
polymer unit chains. The combination of a redox initiator and an azo initiator will increase the amount of grafted synthetic polymer unit chains on polysaccharide backbone. In at least one embodiment, the initiator is a mixture of ammonium peroxidisulfate and sodium sulfite, potassium peroxidisulfate and sodium sulfite, ammonium peroxidisulfate and ascorbic acid, sodium peroxidisulfate and ascorbic acid, ammonium peroxidisulfate and N,N,N',N'-tetramethylene diamine, potassium peroxidisulfate and N,N,N',N'-tetramethylene diamine, ammonium peroximonosulfate and N,N,N',N'-tetramethylene diamine, ammonium peroximonosulfate and ascorbic acid, ammonium peroximonosulfate and thiourea, ammonium peroximonosulfate and malonic acid, ammonium peroximonosulfate and glycolic acid, ammoniumperoxi-monosulfate and malic acid, 2-hydroxy-2- sulfonatoacetic acid and sodium sulfite, 2-hydroxy-2- sulfonatoacetic acid and ammonium peroximonosulfat, 2-hydroxy-2- sulfonatoacetic acid and N,N,N',N'-tetramethylendiamin, tert.-butylhydroperoxide and N,N,N',N'-tetramethylendiamin, 2-hydroxy-2-sulfonatoacetic acid and tert.-butylhydroperoxide, blends of sodium sulfite, 2-hydroxy-2-sulfonatoacetic acid disodium salt, 2-hydroxy-2-sulfinatoacetic acid disodium salt with tert.- butylhydroperoxide, Bruggolite® E28, TP 1651, NHS, FF6 M or FF7 with organic peroxides, for example tert.-butylhydroxy peroxide or lauroylperoxide. In at least one embodiment, the polymerization comprises the step of treating the water-soluble and/or water-swellable polysaccharide polymer unit with water prior to polymerization. This water treatment step preferably results in a homogenous distribution of water molecules in the polysaccharide polymer unit. In at least one embodiment, the polymerization comprises the step of recovering the polymer, in particular wherein the polymer is a hybrid polymer, after polymerization. In at least one embodiment the compound II) is polar and organic.
In at least one embodiment the compound II) is selected from polar alcohols and ketones. In at least one embodiment the compound II) is one or more polar alcohols and one or more ketones. In at least one embodiment, the compound II) is selected from the group consisting of methanol, ethanol, 1-propanol, 2-propanol, 2-methyl-2-propanol, 1- butanol, 2-butanol, dimethyl ketone, diethyl ketone, pentan-2-one, butanone, tetrahydropyran, tetrahydrofuran, 2-methyl-tetrahydrofuran, 1,3-dioxane, 1,4- dioxane, preferably 2-propanol, 2-methyl-2-propanol, dimethyl ketone, tetrahydrofuran, 2-methyl-tetrahydrofuran, more preferably 2-methyl-2-propanol and dimethyl ketone. In a particularly preferred embodiment, the compound II) is 2-methyl-2-propanol. In at least one embodiment, the solvent mixture contains from 0.5 to 10 wt.-%, preferably from 1 to 8 wt.-% and more preferably from 2 to 5 wt.-% water. In at least one embodiment, the solvent mixture contains from 90 to 99.5 wt.-%, preferably from 92 to 99 wt.-% and more preferably from 95 to 98 wt.-% 2-methyl- 2-propanol. In at least one embodiment, the solvent mixture contains water and 2-methyl-2- propanol. In at least one embodiment, the solvent mixture contains from 0.5 to 10 wt.-%, preferably from 1 to 8 wt.-% and more preferably from 2 to 5 wt.-% water, and from 90 to 99.5 wt.-%, preferably from 92 to 99 wt.-% and more preferably from 95 to 98 wt.-% 2-methyl-2-propanol. In at least one embodiment, the solvent mixture contains from 0.5 to 10 wt.-% water, from 1 to 98.5 wt.-% 2-methyl-2-propanol and from 1 to 98.5 wt.-% dimethyl ketone, preferably from 0.5 to 7.5 wt.-% water, from 5 to 94.5 wt.-% 2-methyl-2- propanol and from 5 to 94.5 wt.-% dimethyl ketone. In at least one embodiment, the monomers resulting in units (a) and/or (b) are neutralized with a base prior to the polymerization, and/or the hybrid polymer after
polymerization is neutralized with a base. In at least one embodiment, the base is selected from bases comprising an ion selected the group consisting of Li+, Na+, K+, Ca++, Mg++, Zn++, Al+++, and combinations thereof; preferably wherein the base is selected from hydroxides, carbonates and hydrogen carbonates comprising an ion selected the group consisting of Li+, Na+, K+, Ca++, Mg++, Zn++, Al+++, and combinations thereof. In at least one embodiment, the composition comprises from 0.1 to 10 wt.-%, preferably from 0.1 to 2.5 wt.-%, more preferably from 0.1 to 1.0 wt.-%, also more preferably from 0.5 to 2.5 wt.-%, even more preferably from 0.5 to 1.0 wt.-% of the polymer, in particular a hybrid polymer, related to the total weight of the composition. Particularly preferably, the cosmetic composition of the present invention is a skin care composition. In at least one embodiment, the cosmetic composition of the present invention is selected from the group consisting of body wash, facial cleanser, cleansing mask, bubble bath, bath oil, cleansing milk, micellar water, make-up remover, cleansing wipes, perfume, soaps, shaving soap, shaving foam, cleansing foam, face mask, intimate wash, micellar water, liquid soap, day cream, anti-aging cream, body milk, body lotion, body mousse, serum (e.g., face serum), eye cream, sunscreen lotion, sunscreen spray, sunscreen gel, sun cream, sun care milk, sun care gel, acne cream, after-shave lotion, pre-shaving cream, depilatory cream, skin-whitening gel, whitening cream, self-tanning cream, anti- acne gel, mascara, foundation, primer, concealer, blush, bronzer, blemish balm (bb) cream, eyeliner, night cream, eye brow gel, highlighter, lip stain, hand sanitizer, nail varnish remover, skin conditioner, split end fluid, deodorant, antiperspirant, baby cream, insect repellent, hand cream, foot cream, exfoliator, scrub (e.g., body scrub), cellulite treatment, bar soap, nail cuticle cream, lip balm, eye shadow, bath additive, body mist, eau de toilette, lubricating gel, moisturizer, toner, aqua sorbet, cream gel, lip stick, lip gloss, hydro-alcoholic gel, body oil, shower milk, illuminator, lip crayon, and sunblock. In at least one embodiment, the cosmetic composition of the present invention is
selected from the group consisting of body wash, facial cleanser, bath oil, cleansing milk, shaving foam, face mask, day cream, anti-aging cream, body milk, body lotion, body mousse, serum (e.g., face serum), eye cream, sunscreen lotion, sun cream, face cream, after-shave lotion, pre-shaving cream, depilatory cream, blemish balm (bb) cream, night cream, highlighter, lip stain, skin conditioner, deodorant, antiperspirant, baby cream, hand cream, sunscreen gel, foot cream, cellulite treatment, nail cuticle cream, lip balm, bath additive, eau de toilette, lubricating gel, moisturizer, cream gel, lip stick, lip gloss, body oil, shower milk, lip crayon, and sunblock. In at least one embodiment, the cosmetic composition of the present invention is selected from the group consisting of bath oil, cleansing milk, day cream, anti- aging cream, body milk, body lotion, serum (e.g., face serum), eye cream, sunscreen lotion, face cream, pre-shaving cream, night cream, baby cream, hand cream, foot cream, nail cuticle cream, lip balm, moisturizer, lip stick, lip gloss, body oil, and sunblock. In a preferred embodiment, the cosmetic composition of the present invention is a sunscreen composition. In at least one embodiment, the cosmetic composition of the present invention is selected from the group consisting of sunscreen lotion, sunscreen spray, sunscreen gel, sun cream, sun care milk, and sun care gel. Particularly preferably, the cosmetic composition of the present invention is a hair cosmetic composition, such as a hair care composition. In at least one embodiment, the cosmetic composition of the present invention is selected from the group consisting of hair styling gel, hair styling cream, hair shine serum, hair colorant, split end fluid, and means for scalp treatment. Content ranges of units in the polymer The polymer components may be used in different content ranges In at least one embodiment, the polymer comprises (or consists of):
(i) from 1 wt.-% to 95 wt.-%, preferably from 5 wt.-% to 70 wt.-%, more preferably from 5 wt.-% to 60 wt.-%, even more preferably from 10 wt.-% to 50 wt.-%, even more preferably from 15 wt.-% to 40 wt.-%, even more preferably from 20 wt.-% to 40 wt.-%, in particular from 25 wt.-% to 40 wt.- %, relative to the total mass of the polymer, of a synthetic polymer unit, comprising (or consisting of): (a) from 40 wt.-% to 99.9 wt.-%, preferably from 80 wt.-% to 99.9 wt.-%, in particular from 96 wt.-% to 99.9 wt.-%, relative to the total mass of the synthetic polymer unit, of one or more repeating units of a structure of Formula (1); (b) from 0.01 wt.-% to 10 wt.-%, preferably from 0.01 wt.-% to 5 wt.-%, in particular from 0.01 wt.-% to 3 wt.-%, relative to the total mass of the synthetic polymer unit, of one or more crosslinking or branching units; and (c) from 0 wt.-% to 60 wt.-%, preferably from 0 wt.-% to 20 wt.-%, in particular from 0 wt.-% to 1 wt.-%, relative to the total mass of the synthetic polymer unit, of one or more repeating neutral structural units; and (ii) from 5 wt.-% to 99 wt.-%, preferably from 30 wt.-% to 95 wt.-%, more preferably from 40 wt.-% to 95 wt.-%, even more preferably from 50 wt.-% to 90 wt.-%, even more preferably from 60 wt.-% to 85 wt.-%, even more preferably from 60 wt.-% to 80 wt.-%, in particular from 60 wt.-% to 75 wt.- %, relative to the total mass of the polymer, of a water-soluble and/or water- swellable polysaccharide polymer unit. In at least one embodiment, the polymer comprises (or consists of): (i) from 25 wt.-% to 40 wt.-%, relative to the total mass of the polymer, of a synthetic polymer unit, comprising (or consisting of): (a) from 96 wt.-% to 99.9 wt.-%, relative to the total mass of the synthetic polymer unit, of one or more repeating units of a structure of Formula (1); (b) from 0.01 wt.-% to 3 wt.-%, relative to the total mass of the synthetic polymer unit, of one or more crosslinking or branching units; and
(c) from 0 wt.-% to 1 wt.-%, relative to the total mass of the synthetic polymer unit, of one or more repeating neutral structural units; and (ii) from 60 wt.-% to 75 wt.-%, relative to the total mass of the polymer, of a water-soluble and/or water-swellable polysaccharide polymer unit. Bio-based carbon content Each of the components of the polymer may optionally be bio-based. In at least one embodiment, the one or more polysaccharide polymer units comprise from 1 wt.-% to 100 wt.-%, preferably from 25 wt.-% to 100 wt.-%, in particular from 50 wt.-% to 100 wt.-% bio-based carbon content, relative to the total mass of carbon in the one or more polysaccharide polymer units, measured according to standard ASTM D6866-12, Method B. In at least one embodiment, the repeating units of a structure of Formula (1) comprise from 1 wt.-% to 100 wt.-%, preferably from 25 wt.-% to 100 wt.-%, in particular from 50 wt.-% to 100 wt.-% bio-based carbon content, relative to the total mass of carbon in the repeating units of a structure of Formula (1), measured according to standard ASTM D6866-12, Method B. In at least one embodiment, the one or more further repeating units comprise from 1 wt.-% to 100 wt.-%, preferably from 25 wt.-% to 100 wt.-%, in particular from 50 wt.-% to 100 wt.-% bio-based carbon content, relative to the total mass of carbon in the one or more further repeating units, measured according to standard ASTM D6866-12, Method B. UV and/or blue light filter A UV and/or blue light filter may be any agent that is suitable for filtering (i.e., absorbing, reflecting and/or scattering, preferably absorbing and optionally also reflecting and/or scattering) UV and/or blue light as generally understood in the art. The person skilled in the art is well aware of a large number of UV and/or blue light
filters, including a variety of commercially available UV and/or blue light filters. Preferably, the UV and/or blue light filter is able to absorb and/or reflect and/or scatter, preferably able to absorb, UV light (wavelength range below 400 nm, preferably from 100 to 399 nm) and/or blue light (wavelength range from 400 to 490 nm). In one embodiment, the UV and/or blue light filter is able to absorb and/or reflect and/or scatter, preferably able to absorb, UV-B (wavelength range from 290 to 319 nm) and/or UV-A (wavelength range from 320 to 399 nm) and optionally also UV-C (wavelength range below 290 nm, preferably from 100 to 289 nm) irradiation. In one embodiment, the UV and/or blue light filter is able to absorb and/or reflect and/or scatter, preferably able to absorb, blue light irradiation. In one embodiment, the UV and/or blue light filter is able to absorb and/or reflect and/or scatter, preferably able to absorb, UV-A and reflect blue light (wavelength range from 380 to 450 nm) irradiation and optionally also UV-B and/or UV-C irradiation. In one embodiment, the UV and/or blue light filter is able to absorb and/or reflect and/or scatter, preferably able to absorb, UV-B and optionally also UV-A and optionally also UV-C irradiation. In at least one embodiment, a UV and/or blue light filter is such as described in any of WO 2010/043588 or WO 2019/096960. In at least one embodiment, the one or more UV and/or blue light filters are selected from the group consisting of organic UV-screening agents of the oxalanilide type, of the triazine type, of the benzotriazole type, of the vinylamide type, of the cinnamide type, of the type comprising one or more groups which are benzazole and/or benzofuran, benzothiophene, of the indole type, of the aryl
vinylene ketone type, of the phenylene bis-benzoxazinone derivative type, of the amide, sulfonamide or acrylonitrile carbamate derivative type, or mixtures thereof. In at least one embodiment, at least one of the one or more UV and/or blue light filters is an organic UV and/or blue light filter. In at least one embodiment, at least one of the one or more UV and/or blue light filters is a soluble organic UV and/or blue light filter. In at least one embodiment, at least one of the one or more UV and/or blue light filters is an inorganic UV and/or blue light filter. In at least one embodiment, at least one of the one or more UV and/or blue light filters is an insoluble inorganic UV and/or blue light filter. In at least one embodiment, at least one of the one or more UV and/or blue light filters is selected from the group consisting of anthranilates, cinnamic derivatives, dibenzoylmethane derivatives, salicylic derivatives, camphor derivatives, triazine derivatives, benzophenone derivatives, beta,beta’-diphenylacrylate derivatives, benzotriazole derivatives, benzalmalonate derivatives, benzimidazole derivatives, imidazolines, bis-benzazolyl derivatives, p-aminobenzoic acid (PABA) derivatives, benzothiazine derivatives, screening polymers and screening silicones (e.g., Polysilicone 15), alpha-alkylstyrene-based dimers, 4,4-diarylbutadienes, methoxypropylamino cyclohexanylidene ethoxycyanoacetate, methoxypropylamino cyclohexenylidene ethoxyethylcyanoacetate, ethyl 9-oxo-9H- thioxanthene-2-carboxylate, sun protecting peptides (e.g., Sr-hydrozoan polypeptide-1, nicotinoyl octapeptide-9), titanium oxide (also: titanium dioxide), zinc oxide, iron oxide, and mixtures thereof. In at least one embodiment, at least one of the one or more UV and/or blue light filters is selected from the group consisting of anthranilates, cinnamic compounds, dibenzoylmethane compounds, salicylic compounds, camphor compounds, triazine compounds, benzophenone compounds, beta,beta’-diphenylacrylate compounds, benzotriazole compounds, benzalmalonate compounds, benzimidazole compounds, imidazolines, bis-benzazolyl compounds, p- aminobenzoic acid (PABA) compounds, benzothiazine compounds, screening polymers and screening silicones (e.g., Polysilicone 15), alpha-alkylstyrene-based
dimers, 4,4-diarylbutadienes, methoxypropylamino cyclohexanylidene ethoxycyanoacetate, methoxypropylamino cyclohexenylidene ethoxyethylcyanoacetate, ethyl 9-oxo-9H-thioxanthene-2-carboxylate, sun protecting peptides (e.g., Sr-hydrozoan polypeptide-1, nicotinoyl octapeptide-9), titanium oxide (also: titanium dioxide), zinc oxide, iron oxide, and mixtures thereof. In at least one embodiment, the one or more UV and/or blue light filters are selected from the group consisting of: 4-Aminobenzoic acid (PABA, p-aminobenzoic acid), Polyoxyethylene ethyl-4-aminobenzoate (PEG-25 PABA, Ethoxylated Ethyl-4- Aminobenzoate), 2-Ethylhexyl 4-(dimethylamino)benzoate (Ethylhexyl Dimethyl PABA, Padimate O, 4- dimethyl aminobenzic acid-2-ethylhexylester), Methyl N,N,N-trimethyl-4-[(4,7,7-trimethyl-3-oxobicyclo[2.2.1]hept-2- ylidene)methyl]anilinium Sulphate (Camphor benzalkonium methosulfate, 4-[(2- Oxo-3-bornylidene)methyl]phenyltrimethylammonium methyl sulfate), (1,4-Phenylenebis{(E)methylylidene[(3E)-7,7-dimethyl-2-oxobicyclo[2.2.1]hept-1- yl-3-ylidene]})dimethanesulfonic acid and its salts (Terephthalylidene Dicamphor Sulfonic Acid, Ecamsule, 3,3'-(1,4-phenylenedimethylene)bis[7,7-dimethyl-2-oxo- bicyclo[2.2.1]heptane-1-methanesulfonic Acid] ), 1,7,7-trimethyl-3-(phenylmethylene)bicyclo[2.2.1]heptan-2-one and its salts (3- benzylidene Camphor sulfonic acid), polymer of N-{(2 and 4)-[(2-Oxoborn-3-ylidine)methyl]benzyl}acrylamide (Polyacrylamidomethyl Benzylidene Camphor), 3-Benzylidene-1,7,7-trimethylbicyclo[2.2.1]heptan-2-one (3-benzylidene camphor, 1,7,7-trimethyl-3-(phenylmethylene)bicyclo[2.2.1]heptan-2-one 3(4'- methylbenzyliden)-D,L-camphor), (3E)-1,7,7-Trimethyl-3-(4-methylbenzylidene)bicyclo[2.2.1]heptan-2-one (4- Methylbenzylidene Camphor, Enzacamene), 3,3,5-Trimethylcyclohexyl salicylate (Homosalate), 3-Octanyl salicylate (Ethylhexyl Salicylate, Octisalate), 2-ethylhexyl 4-methoxycinnamate (Ethylhexyl methoxycinnamate, Octinoxate),
3-Methylbutyl (2E)-3-(4-methoxyphenyl)acrylate (Isoamyl 4-methoxycinnamate, Amiloxate, 4-methoxy-cinnamic acid-isoamylester), 4-(1,1,1,3,5,5,5-Heptamethyl-3-trisiloxanyl)-3-methylbutyl (2E)-3-(3,4,5- trimethoxyphenyl)acrylate (Isopentyl trimethoxycinnamate trisiloxane) 2-Ethoxyethyl (2E)-3-(4-methoxyphenyl)acrylate (Cinoxate, 2-Ethoxyethyl-p- methoxycinnamate), Mixture: Isopropyl p-methoxycinnamate + Ethyl diisopropylcinnamate + Methyl-2,4-diisopropylcinnamate 1-(4-Methoxyphenyl)-3-[4-(2-methyl-2-propanyl)phenyl]-1,3-propanedione (Butyl Methoxydibenzoylmethane, Avobenzone, 1-(4-tert-Butylphenyl)-3-(4- methoxyphenyl)propane-1,3-dione), Bis(2,4-dihydroxyphenyl)methanone (Benzophenone-2, 2,2',4,4'- tetrahydroxybenzophenone), (2-Hydroxy-4-methoxyphenyl)(phenyl)methanone (Benzophenone-3, Oxybenzone), 5-Benzoyl-4-hydroxy-2-methoxybenzenesulfonic acid (Benzophenone-4, Sulisobenzone), Benzenesulfonic Acid, 5-benzoyl-4-hydroxy-2-methoxy-, Monosodium Salt (Benzophenone-5, Sulisobenzone Sodium, hydroxy-4-methoxy-benzophenone-5 sulfonic acid and the sodium salt thereof), Bis(2-hydroxy-4-methoxyphenyl)methanone (Benzophenone-6, 2,2'-dihydroxy- 4,4'-dimethoxybenzophenone), (2-Hydroxy-4-methoxyphenyl)(2-hydroxyphenyl)methanone (Benzophenone-8, Dioxybenzone, 2,2'-dihydroxy-4-methoxybenzophenone), Disodium 3,3'-carbonylbis(4-hydroxy-6-methoxybenzenesulfonate) (Benzophenone-9, Disodium 3,3'-carbonylbis[4-hydroxy-6- methoxybenzenesulphonate]), 4-(2-Beta-Glucopyranosiloxy)propoxy-2-/hydroxybenzophenone, Hexyl 2-[4-(diethylamino)-2-hydroxybenzoyl]benzoate ( Diethylamino hydroxybenzoyl hexyl benzoate (DHHB), Benzoic Acid, 2-[4-(diethylamino)-2- hydroxybenzoyl]-, Hexyl Ester), 2-Phenyl-1H-benzimidazole-5-sulfonic acid and potassium-, sodium- and triethanolamine salts there of ( Phenylbenzimidazole sulphonic acid, Ensulizole),
Disodium 2,2'-(1,4-phenylene)bis(6-sulfo-1H-benzimidazole-4-sulfonate) (Disodium Phenyl Dibenzimidazole Tetrasulfonate, Bisdisulizole Disodium, 1h- benzimidazole-4,6-disulfonic Acid, 2,2'-(1,4-phenylene)bis-, Disodium Salt), 2-Ethylhexyl 2-cyano-3,3-diphenylacrylate (Octocrylene, 2-Cyano-3,3- diphenylacrylic acid 2-ethylhexyl ester), 4,4'-[(6-[4-((1,1-dimethylethyl)-amino-carbonyl)phenylamino]-1,3,5-triazin-2,4- yl)diimino]bis-(benzoic acid-2-ethylhexylester) – (Diethylhexyl butamido triazone, Iscotrizinol), 2,2'-[6-(4-Methoxyphenyl)-1,3,5-triazine-2,4-diyl]bis{5-[(2-ethylhexyl)oxy]phenol} (Bis-ethylhexyloxyphenol Methoxyphenyl Triazine, Bemotrizinol), 2,4,6-Tri(4-biphenylyl)-1,3,5-triazine (Tris-biphenyl triazine (nano)), 3,3′-(1,4-phenylene)bis(5,6-diphenyl-1,2,4-triazine) (Phenylene Bis- diphenyltriazine), Tris(2-ethylhexyl) 4,4',4''-(1,3,5-triazine-2,4,6-triyltriimino)tribenzoate ( Ethylhexyl Triazone, 2-(2H-benzotriazole-2-yl)-4-methyl-6-(2-methyl-3-(1,3,3,3- tetramethyl-1-(trimethylsilyloxy)-disiloxanyl)-propyl)phenol 2,4,6-tris-[p-(2- ethylhexyloxycarbonyl)anilino]-1,3,5-triazine), 2-(2H-Benzotriazol-2-yl)-6-[3-(1,1,1,3,5,5,5-heptamethyl-3-trisiloxanyl)-2- methylpropyl]-4-methylphenol (Drometrizole Trisiloxane, Silatrizole, Phenol,2-(2h- benzotriazol-2-yl)-4-methyl-6-(2-methyl-3-(1,3,3,3-tetramethyl-1- (trimethylsilyl)oxy)-disiloxanyl)propyl), 2,2'-methylene-bis-(6-(2h-benzotriazol-2-yl)-4-(1,1,3,3-tetramethylbutyl)phenol) (Methylene Bis-benzotriazolyl Tetramethylbutylphenol, Bisoctrizole, MBBT), Siloxanes and silicones, dimethyl, 3-(4-(2,2- di(ethoxycarbonyl)ethenyl)phenoxy)propen-2-yl methyl, 3-(4-(2,2- di(ethoxycarbonyl)ethenyl)phenoxy)propen-1-yl methyl, trimethylsilyl terminated (Polysilicone-15, Dimethicodiethylbenzalmalonate), Menthyl Anthranilate, Meradimate Methoxypropylamino Cyclohexenylidene Ethoxyethylcyanoacetate, titanium oxide (also: Titanium dioxide and Titanium dioxide TiO2 (nano)), zinc oxide (also: Zinc Oxide and Zinc oxide ZnO (nano)), Iron Oxide, and combinations of two or more thereof.
In at least one embodiment, the one or more UV and/or blue light filters are selected from the group consisting of butyl methoxydibenzoylmethane, octocrylene, bis-ethylhexyloxyphenol methoxyphenyl triazine, ethylhexyl triazone, ethylhexyl salicylate, diethylamino hydroxybenzoyl hexyl benzoate, ethylhexyl methoxycinnamate, diethylhexyl butamido triazone, dometrizole trisiloxane, phenylbenzimidazole sulfonic acid, methylene bis-benzotriazolyl tetramethylbutylphenol, terephthalydidene dicamphor sulfonic acid, 4- methylbenzylidene camphor, polysilicone-15, isoamyl p-methoxycinnamate, disodium phenyl dibenzimidazole tetrasulfonate, tris-biphenyl triazine, phenylene bis-diphenyltriazine, homosalate, and combinations of two or more thereof. UV and/or blue light filters may also be such as disclosed in WO2013017262A1, from page 32, line 11 to the end of page 33 and/or in EP 1084696. In at least one embodiment, the UV and/or blue light filter is selected from the group consisting of: (A) an oil soluble organic UV absorber, preferably selected from the group consisting of Bis-Ethylhexyloxyphenol Methoxyphenyl Triazine, Butyl Methoxydibenzoylmethane, Ethylhexyl Methoxycinnamate, Octocrylene, Oxybenzone, Sulisobenzone, Diethylhexyl Butamido Triazone, Drometrizole Trisiloxane, Ethylhexyl Salicylate, Ethylhexyl Triazone, Homosalate, Octisalate, lsoamyl p-Methoxycinnamate, 4-Methylbenzylidene Camphor, Polysilicone-15, Diethylamino Hydroxy Benzoyl Hexyl Benzoate, Methoxypropylamino Cyclohexenylidene Ethoxyethylcyanoacetate, ethyl 9- oxo-9H-thioxanthene-2-carboxylate, Diethylamino Hydroxybenzoyl Hexyl Benzoate, Ethyl Triazine, Benzyl Salicylate, Avobenzone, and mixtures thereof; (B) a sparingly soluble organic UV absorber, preferably selected from the group consisting of Methylene Bis-Benzotriazolyl Tetramethylbutylphenol, Tris- Biphenyl Triazine, Methanone, 1,1'-(1,4-piperazinediyl)bis[1-[2-[4- (diethylamino)-2-hydroxybenzoyl]phenyl]-methanone, and mixtures thereof;
(C) an inorganic UV absorber, preferably selected from the group consisting of titanium oxide (also: titanium dioxide), zinc oxide, iron oxide, and mixtures thereof; (D) a water soluble UV absorber, preferably selected from the group consisting of Phenylbenzimidazole Sulfonic Acid, Sulisobenzone sodium salt, Benzylidene Camphor Sulfonic Acid, Camphor Benzalkonium Methosulfate, Cinoxate, Disodium Phenyl Dibenzylmidazole Tetrasulfonate, Terephthalylidene Dicamphor Sulfonic Acid, PABA, PEG-25 PABA and mixtures thereof; and salts and mixtures thereof. In at least one embodiment, the one or more UV and/or blue light filters are selected from the group consisting of Bis-Ethylhexyloxyphenol Methoxyphenyl Triazine, Ethylhexyl Methoxycinnamate, Octocrylene, Butyl Methoxydibenzoylmethane, Ethylhexyl Salicylate, Butylmethoxydibenzoylmethane, Phenylbenzimidazolesulfonic Acid, Terephthalylidenedicamphorsulfonic Acid, Benzophenone-3, Benzophenone-4, Benzophenone-5,4- Ethylbenzylidenecamphor, Benzimidazilate, Anisotriazine, Ethylhexyl Triazone, Diethylhexyl Butamidotriazone, Drometrizole Trisiloxane, Methoxypropylamino Cyclohexanylidene Etohycyanoacetate, ethyl 9-oxo-9H-thioxanthene-2- carboxylate, and salts and mixtures thereof. In at least one embodiment, the sparingly soluble organic UV absorber are micronized. In at least one embodiment, the one or more UV and/or blue light filters comprise or consist of a combination of two, three, four or more than four UV and/or blue light filters are used. In at least one embodiment, the one or more UV and/or blue light filters comprise or consist of the following UV and/or blue light filters: Butyl Methoxydibenzoylmethane, Bis-Ethylhexyloxyphenol Methoxyphenyl triazine, Ethylhexyl Triazone, Phenylbenzimidazole sulfonic acid, and Diethylamino
hydroxybenzoyl hexyl benzoate. In at least one embodiment, the one or more UV and/or blue light filters comprise or consist of the following UV and/or blue light filters: Homosalate, Octocrylene, Ethylhexyl salicylate, Butyl Methoxydibenzoylmethane, Ethyl Triazine, Drometrizole Trisiloxane, and Benzyl Salicylate. In at least one embodiment, the one or more UV and/or blue light filters comprise or consist of the following UV and/or blue light filters: Ethylhexyl Salicylate, Bis- Ethylhexyloxyphenol Methoxyphenyl triazine, Butyl Methoxydibenzoylmethane, Ethylhexyl Triazone, and Phenylbenzimidazole sulfonic acid. In at least one embodiment, the one or more UV and/or blue light filters comprise or consist of the following UV and/or blue light filters: zinc oxide (nano) and titanium oxide (nano). In at least one embodiment, the one or more UV and/or blue light filters comprise or consist of the following UV and/or blue light filters: Zinc oxide, Octocrylene, Ethylhexyl Salicylate, Diethylamino Hydroxybenzoyl Hexyl Benzoate, Titanium oxide, Homosalate, Ethylhexyl Triazone Polysilicone-15, and Bis-ethylhexyloxyphenol methoxyphenyl Triazine In at least one embodiment, the one or more UV and/or blue light filters comprise or consist of the following UV and/or blue light filters: Homosalate, Butyl Methoxydibenzoylmethane, Ethylhexyl Salicylate, Octocrylene, and Phenylbenzimidazole Sulfonic Acid. In at least one embodiment, the one or more UV and/or blue light filters comprise or consist of the following UV and/or blue light filters: Avobenzone, Homosalate, of Octisalate, and Zinc Oxide, preferably comprising or consisting of: 2.3 wt.%, based on the composition as a whole, of Avobenzone, 10.0 wt.%, based on the composition as a whole, of Homosalate, 5.0 wt.%, based on the composition as a whole, of Octisalate, and
5.0 wt.%, based on the composition as a whole, of Zinc Oxide. In at least one embodiment, the one or more UV and/or blue light filters comprise or consist of the following UV and/or blue light filters: Butyl Methoxydibenzoylmethane, Titanium oxide, Octocrylene, Ethylhexyl Triazone, Methylene Bis-Benzotriazolyl Tetramethylbutylphenol (nano), Methylene Bis- Benzotriazolyl Tetramethylbutylphenol, Drometrizole trisiloxane, and Terephthalylidene Dicamphor Sulfonic Acid. In at least one embodiment, the one or more UV and/or blue light filters comprise or consist of the following UV and/or blue light filters: Ethylhexyl Methoxycinnamate (EHMC), 1 Ethylhexyl Triazone (EHT), and Diethylamino hydroxybenzoyl hexyl benzoate (DHHB), preferably comprising or consisting of: 10 wt.%, based on the composition as a whole, of Ethylhexyl Methoxycinnamate (EHMC), 1 wt.%, based on the composition as a whole, of Ethylhexyl Triazone (EHT), and 8 wt.%, based on the composition as a whole, of Diethylamino hydroxybenzoyl hexyl benzoate (DHHB). In at least one embodiment, the one or more UV and/or blue light filters comprise or consist of the following UV and/or blue light filters: Ethylhexyl Methoxycinnamate (EHMC), 2 Ethylhexyl Triazone (EHT), Diethylamino hydroxybenzoyl hexyl benzoate (DHHB), and Bis-Ethylhexyloxyphenol Methoxyphenyl Triazine (BEMT), preferably comprising or consisting of: 10 wt.%, based on the composition as a whole, of Ethylhexyl Methoxycinnamate (EHMC), 2.5 wt.%, based on the composition as a whole, of Ethylhexyl Triazone (EHT), 10 wt.%, based on the composition as a whole, of Diethylamino hydroxybenzoyl hexyl benzoate (DHHB), and 3 wt.%, based on the composition as a whole, of Bis-Ethylhexyloxyphenol Methoxyphenyl Triazine (BEMT). In at least one embodiment, the one or more UV and/or blue light filters comprise or consist of the following UV and/or blue light filters: Ethylhexyl Triazone (EHT), Diethylamino hydroxybenzoyl hexyl benzoate (DHHB), and Bis-
Ethylhexyloxyphenol Methoxyphenyl Triazine (BEMT), preferably comprising or consisting of: 3 wt.%, based on the composition as a whole, of Ethylhexyl Triazone (EHT), 10 wt.%, based on the composition as a whole, of Diethylamino hydroxybenzoyl hexyl benzoate (DHHB), and 3 wt.%, based on the composition as a whole, of Bis-Ethylhexyloxyphenol Methoxyphenyl Triazine (BEMT). In at least one embodiment, the one or more UV and/or blue light filters comprise or consist of the following UV and/or blue light filters: Ethylhexyl Triazone (EHT), Diethylamino hydroxybenzoyl hexyl benzoate (DHHB), Bis-Ethylhexyloxyphenol Methoxyphenyl Triazine (BEMT), and phenylbenzimidazole sulfonic acid (PBSA), preferably comprising or consisting of: 3 wt.%, based on the composition as a whole, of Ethylhexyl Triazone (EHT), 7 wt.%, based on the composition as a whole, of Diethylamino hydroxybenzoyl hexyl benzoate (DHHB), 4 wt.%, based on the composition as a whole, of Bis-Ethylhexyloxyphenol Methoxyphenyl Triazine (BEMT), and 4 wt.%, based on the composition as a whole, of phenylbenzimidazole sulfonic acid (PBSA). Cosmetic composition The use of the present invention may be carried out in any composition comprising at least one polymer as described herein and at least one UV and/or blue light filter. In at least one embodiment, such composition is a cosmetic composition, also designatable as cosmetically acceptable composition. In at least one embodiment, such composition further comprises at least one carrier. In at least one embodiment, the use is carried out in a cosmetic composition serving for sun protection (also: sunscreen composition). In at least one embodiment, the use is carried out in a sunscreen, in particular a sunscreen lotion, sun cream, sunscreen gel, sun spray, or a sunblock. Carrier
A cosmetic composition may optionally also comprise one or more carriers as component (C). Thus, a carrier is preferably a cosmetically acceptable carrier. A carrier may be useful for providing the compounds used in present invention in liquid form. In at least one embodiment, the carrier is a cosmetically acceptable carrier. In at least one embodiment, the composition comprises at least 10 wt.-% water. Water is useful for economic reasons but also because it is highly cosmetically acceptable. Optionally the composition comprises water-miscible or water-soluble solvents such as lower alkyl alcohols. In at least one embodiment, the composition comprises C1-C5 alkyl monohydric alcohols, preferably C2-C3 alkyl alcohols. The alcohols which may be present are in particular lower monohydric or polyhydric alcohols having 1 to 4 carbon atoms customarily used for cosmetic purposes, such as preferably ethanol and isopropanol. In at least one embodiment, the composition comprises a water-soluble polyhydric alcohol. In at least one embodiment, the water-soluble polyhydric alcohols are polyhydric alcohols having two or more hydroxyl groups in the molecule. In at least one embodiment, the water-soluble polyhydric alcohol is selected from the group consisting of: dihydric alcohols such as ethylene glycol, propylene glycol, trimethylene glycol, 1,2-butylene glycol, 1,3-butylene glycol, 1,4-butylene glycol, tetramethylene glycol, 2,3-butylene glycol, pentamethylene glycol, 2-butene-1,4- diol, hexylene glycol, octylene glycol; trihydric alcohols such as glycerine, trimethylol propane, 1,2,6-hexanetriol and the like; tetrahydric alcohols such as penthaerythritol; pentahydric alcohols such as xylytol, etc.; hexahydric alcohols such as sorbitol, mannitol; polyhydric alcohol polymers such as diethylene glycol, dipropylene glycol, polyethylene glycol, polypropylene glycol, tetraethylene glycol, diglycerine, polyethylene glycol, triglycerine, tetraglycerine, polyglycerine; dihydric alcohol alkyl ethers such as ethylene glycol monomethyl ether, ethylene glycol monoethyl ether, ethylene glycol monobutyl ether, ethylene glycol monophenyl ether, ethylene glycol monohexyl ether, ethylene glycol mono-2-methylhexyl ether, ethylene glycol isoamyl ether, ethylene glycol benzyl ether, ethylene glycol isopropyl ether, ethylene glycol dimethyl ether, ethylene glycol diethyl ether, ethylene glycol dibutyl ether; dihydric alcohol alkyl ethers such as diethylene glycol monomethyl ether, diethylene glycol monoethyl ether, diethylene glycol monobutyl
ether, diethylene glycol dimethyl ether, diethylene glycol diethyl ether, diethylene glycol butyl ether, diethylene glycol methyl ethyl ether, triethylene glycol monomethyl ether, triethylene glycol monoethyl ether, propylene glycol monomethyl ether, propylene glycol monoethyl ether, propylene glycol monobutyl ether, propylene glycol isopropyl ether, dipropylene glycol methyl ether, dipropylene glycol ethyl ether, dipropylene glycol butyl ether; dihydric alcohol ether esters such as ethylene glycol monomethyl ether acetate, ethylene glycol monoethyl ether acetate, ethylene glycol monobutyl ether acetate, ethylene glycol monophenyl ether acetate, ethylene glycol diadipate, ethylene glycol disuccinate, diethylene glycol monoethyl ether acetate, diethylene glycol monobutyl ether acetate, propylene glycol monomethyl ether acetate, propylene glycol monoethyl ether acetate, propylene glycol monopropyl ether acetate, propylene glycol monophenyl ether acetate; glycerine monoalkyl ethers such as xyl alcohol, selachyl alcohol, batyl alcohol; sugar alcohols such as sorbitol, maltitol, maltotriose, mannitol, sucrose, erythritol, glucose, fructose, starch sugar, maltose, xylytose, starch sugar reduced alcohol, glysolid, tetrahydrofurfuryl alcohol, POE tetrahydrofurfuryl alcohol, POP butyl ether, POP POE butyl ether, tripolyoxypropylene glycerine ether, POP glycerine ether, POP glycerine ether phosphoric acid, POP POE pentanerythritol ether, and mixtures thereof. In at least one embodiment, the composition comprises a cosmetically acceptable carrier selected from the group consisting of water, glycols, ethanol, and combinations thereof. In at least one embodiment, the composition comprises an aqueous, alcoholic or aqueous-alcoholic carrier, and wherein the aqueous, alcoholic or aqueous- alcoholic carrier comprises water, ethanol, propanol, isopropanol, 1,2-propylene glycol, 1,3-propylene glycol, isobutanol, butanol, butyl glycol, butyl diglycol, glycerol, or a mixture thereof; preferably wherein the aqueous, alcoholic or aqueous-alcoholic solvent comprises water, ethanol, propanol, isopropanol, 1,2-propylene glycol, 1,3-propylene glycol, glycerol, or mixtures thereof; more preferably wherein the aqueous, alcoholic or aqueous-alcoholic carrier comprises water, isopropanol, 1,2-propylene glycol, 1,3-propylene glycol, or mixtures thereof;
even more preferably wherein the aqueous, alcoholic or aqueous-alcoholic carrier consists of water or consists of a mixture of water and an alcohol wherein the alcohol is selected from the group consisting of isopropanol, 1,2-propylene glycol and 1,3-propylene glycol. Natural carriers can also be used. In at least one embodiment, the composition comprises a carrier selected from the group consisting of plant oil, honey, plant- derived sugar compositions, and mixtures thereof. Depending on the content of the polymer, the composition may be thickened, i.e., may have viscous flow properties. Viscosity In at least one embodiment, the composition has a viscosity of from 0 mPas to 250,000 mPas, or from 1 mPas to 250,000 mPas, or from 50,000 mPas to 200,000 mPas, or from 50,000 mPas to 100,000 mPas. In at least one embodiment, the composition has a viscosity of from 0.1 mPas to 50,000 mPas, or from 1 mPas to 20,000 mPas, or from 1 mPas to 10,000 mPas, or from 1 mPas to 5,000 mPas, or from 5 mPas to 3,500 mPas (each referred to at 25°C). For instance, the composition may have a viscosity of 1 mPas to 5 mPas (e.g., when used as a spray, a mist, or a water thin product), may have a viscosity of 5,000 mPas to 15,000 mPas (e.g., when used as a serum), may have a viscosity of 15,000 mPas to 50,000 mPas (e.g., when used as a lotion), may have a viscosity of 50,000 mPas to 250,000 mPas (e.g., when used as a cream), may have a viscosity of 20,000 mPas to 70,000 mPas (e.g., when used as a gel), may have a viscosity of 7,500 mPas to 20,000 mPas (e.g., when used as a shampoo or a foaming gel), may have a viscosity of 50,000 mPas to 250,000 mPas (e.g., when used as a conditioner), or may have a viscosity of 120,000 mPas to 170,000 mPas (e.g., when used as a mascara).
The viscosity measurement conditions are defined in the definitions section above. Viscosity may be important for anti-drip reasons. Dripping can be inconvenient for the user. Furthermore, more viscous compositions can be useful for measured dispensing. In at least one embodiment, the composition has a viscosity of from 0 mPas to 1,000 mPas, or from 1 mPas to 1,000 mPas. This viscosity range is advantageous when the composition is in the form of a facial cleanser in view of the need for distribution on skin and ability to rinse off. In at least one embodiment, the composition further comprises a viscosity- modifying substance. The viscosity-modifying substance is preferably a thickening polymer. In at least one embodiment, the thickening polymer selected from the group consisting of: copolymers of at least one first monomer type, which is chosen from acrylic acid and methacrylic acid, and at least one second monomer type, which is chosen from esters of acrylic acid and ethoxylated fatty alcohol; crosslinked polyacrylic acid; crosslinked copolymers of at least one first monomer type, which is chosen from acrylic acid and methacrylic acid, and at least one second monomer type, which is chosen from esters of acrylic acid with C10- to C30-alcohols; copolymers of at least one first monomer type, which is chosen from acrylic acid and methacrylic acid, and at least one second monomer type, which is chosen from esters of itaconic acid and ethoxylated fatty alcohol; copolymers of at least one first monomer type, which is chosen from acrylic acid and methacrylic acid, at least one second monomer type, which is chosen from esters of itaconic acid and ethoxylated C10- to C30-alcohol and a third monomer type, chosen from C1-to C4-aminoalkyl acrylates; copolymers of two or more monomers chosen from acrylic acid, methacrylic acid, acrylic esters and methacrylic esters; homopolymers of acryloyldimethyltaurate; crosslinked homopolymers of acryloyldimethyltaurate; copolymers of vinylpyrrolidone and salts of acryloyldimethyltaurate; copolymers of salts of acryloyldimethyltaurate and monomers chosen from esters of methacrylic acid and ethoxylated fatty alcohols; copolymers of salts of acryloyldimethyltaurate, methacrylic acid and monomers chosen from and alkylated acrylamid; salts of acryloyldimethyltaurate and N-vinylpyrrolidone; salts of acryloyldimethyltaurate, methacrylic acid and monomers chosen from esters of methacrylic acid; hydroxyethylcellulose; hydroxypropylcellulose; hydroxypropylguar; glyceryl
polyacrylate; glyceryl polymethacrylate; copolymers of at least one C2-, C3- or C4-alkylene and styrene; polyurethanes; hydroxypropyl starch phosphate; polyacrylamide; copolymer of maleic anhydride and methyl vinyl ether crosslinked with decadiene; carob seed flour; guar gum; xanthan; dehydroxanthan; carrageenan; karaya gum; hydrolyzed corn starch; copolymers of polyethylene oxide, fatty alcohols and saturated methylenediphenyl diisocyanate (e.g. PEG-150/stearyl alcohol/SMDI copolymer); and mixtures thereof. pH The composition may have any pH range. In at least one embodiment, the composition has a pH value of from 2.0 to 12.0, preferably from 3.0 to 9.0, more preferably from 4.5 to 8. By varying the pH value, a composition can be made available that is suitable for different applications. In at least one embodiment, the composition comprises an alkalizing agent or pH adjusting agent. In at least one embodiment, ammonia or caustic soda is suitable, but water-soluble, physiologically tolerable salts of organic and inorganic bases can also be considered. In at least one embodiment, the pH adjusting agent is selected from ammonium hydrogen carbonate, ammonia, monoethanolamine, ammonium carbonate. In at least one embodiment, the alkalizing agents is selected from the group consisting of 2-amino-2-methyl-1-propanol, 2-amino-2- methyl-1,3-propanediol, 2-amino-2-ethyl-1,3-propanediol, tris(hydroxyl-methyl)- aminomethane, 2-amino-1-butanole, tris-(2-hydroxypropyl)-amine, 2,2-iminobisethanol, lysine, iminourea (guanidine carbonate), tetrahydro-1,4- oxazine, 2-amino-5-guanidin-valeric acid, 2-aminoethansulfonic acid, diethanolamine, triethanolamine, N-methyl ethanolamine, isopropanolamine, diisopropanolamine, triisopropanolamine, glucamine, sodium hydroxide, potassium hydroxide, lithium hydroxide and magnesium oxide, and mixtures thereof. To establish an acidic pH value, and acid can be included. In at least one embodiment, the composition comprises an acid selected from the group consisting of hydrochloric acid, phosphoric acid, acetic acid, formic acid, sulfuric
acid, hydrochloric acid, citric acid, and mixtures thereof. Citric acid is most preferred in that it has high consumer acceptance. In at least one embodiment, the acidic pH is adjusted with a buffer such as a phosphate buffer, a TRIS buffer or a citric buffer. The buffers may be used alone or in combination with an acid. Form In at least one embodiment, the composition is in liquid form, which may also comprise a viscous form. In an alternative embodiment, the composition is in solid form. Optionally, the composition is in powdered or granulated form. This is advantageous in that it is not needed to ship liquid, which is typically heavy over long distances, and thus has economic and environmental benefits. A solid form can be achieved by spray drying the composition, the employment of a rotary evaporator, by drying on trays at temperature above the boiling point of the solvent, in vacuum, by drying in the reactor, in vertical or horizontal powder dryers, by atmospheric, pressure or vacuum filtration with subsequent drying of the wet filtrate. The composition can be converted into liquid form after it has been shipped e.g. by adding water. Surfactants A cosmetic composition may optionally also comprise one or more surfactants as component (D). In at least one embodiment, the composition comprises a surfactant or surfactant system. In at least one embodiment, the surfactant or surfactant system comprises a surfactant selected from the group consisting of anionic surfactants, cationic surfactants, non-ionic surfactants, zwitterionic surfactants and/or amphoteric surfactants. In at least one embodiment, the composition comprises a total amount of surfactant of from 0.01 wt.-% to 70 wt.-%, from 0.1 wt.-% to 40%, from 1 wt.-% to 30%, from 2 wt.-% to 20 wt.-%.
In at least one embodiment, the composition comprises a non-ionic surfactant. Such non-ionic surfactants may also be used as emulsifiers. In at least one embodiment, the non-ionic surfactant has an HLB (Hydrophilic Lipophilic Balance) of greater than 12. Optionally, the non-ionic surfactant is selected from the group consisting of ethoxylated or ethoxylated/propoxylated fatty alcohols with a fatty chain comprising from 12 to 22 carbon atoms, ethoxylated sterols, such as stearyl- or lauryl alcohol (EO-7), PEG-16 soya sterol or PEG-10 soya sterol, polyoxyethylene polyoxypropylene block polymers (poloxamers), and mixtures thereof. In at least one embodiment, the non-ionic surfactant is selected from the group consisting of ethoxylated fatty alcohols, fatty acids, fatty acid glycerides or alkylphenols, in particular addition products of from 2 to 30 mol of ethylene oxide and/or 1 to 5 mol of propylene oxide onto C8- to C22-fatty alcohols, onto C12- to C22-fatty acids or onto alkyl phenols having 8 to 15 carbon atoms in the alkyl group, C12- to C22-fatty acid mono- and diesters of addition products of from 1 to 30 mol of ethylene oxide onto glycerol, addition products of from 5 to 60 mol of ethylene oxide onto castor oil or onto hydrogenated castor oil, fatty acid sugar esters, in particular esters of sucrose and one or two C8- to C22-fatty acids, INCI: Sucrose Cocoate, Sucrose Dilaurate, Sucrose Distearate, Sucrose Laurate, Sucrose Myristate, Sucrose Oleate, Sucrose Palmitate, Sucrose Ricinoleate, Sucrose Stearate, esters of sorbitan and one, two or three C8- to C22-fatty acids and a degree of ethoxylation of from 4 to 20, polyglyceryl fatty acid esters, in particular of one, two or more C8- to C22-fatty acids and polyglycerol having preferably 2 to 20 glyceryl units, alkyl glucosides, alkyl oligoglucosides and alkyl polyglucosides having C8 to C22-alkyl groups, e.g. decylglucoside or laurylglucoside, and mixtures thereof. In at least one embodiment, the non-ionic surfactant is selected from the group consisting of fatty alcohol ethoxylates (alkylpolyethylene glycols), alkylphenol polyethylene glycols, alkylmercaptan polyethylene glycols, fatty amine ethoxylates (alkylaminopolyethylene glycols), fatty acid ethoxylates (acylpolyethylene glycols),
polypropylene glycol ethoxylates (Pluronicsâ), fatty acid alkylol amides, (fatty acid amide polyethylene glycols), N-alkyl-, N-alkoxypolyhydroxy-fatty acid amide, sucrose esters, sorbitol esters, polyglycol ethers, and mixtures thereof. In at least one embodiment, the composition comprises from 1 wt.-% to 20 wt.-%, more preferably from 2 wt.-% to 10 wt.-%, even more preferably from 3 wt.-% to 7 wt.-% non-ionic surfactant. Conditioning agent A cosmetic composition may optionally also comprise one or more conditioning agents as component (D). In at least one embodiment, the composition comprises a conditioning agent. In at least one embodiment, the composition comprises a conditioning agent. In at least one embodiment, the conditioning agent is a water insoluble, water dispersible, non-volatile, liquid that forms emulsified, liquid particles. In at least one embodiment, the conditioning agent is a silicone (e.g., silicone oil, cationic silicone, silicone gum, high refractive silicone, and silicone resin), an organic conditioning oil (e.g., hydrocarbon oils, polyolefins, and fatty esters), or combinations thereof. In at least one embodiment, the conditioning agent is a silicone, and wherein the composition comprises from 0.01 wt.-% to 10 wt.-%, or from 0.1 wt.-% to 5 wt.-% silicone conditioning agent, by total weight of the composition. Suitable silicone conditioning agents, and optional suspending agents for the silicone, are described in US 5,104,646. In at least one embodiment, the composition comprises a silicone gum selected from the group consisting of polydimethylsiloxane, (polydimethylsiloxane) (methylvinylsiloxane) copolymer, poly(dimethylsiloxane) (diphenylsiloxane) (methylvinylsiloxane) copolymer, and mixtures thereof. In at least one embodiment, the composition comprises a terminal aminosilicone. "Terminal aminosilicone" as defined herein means silicone comprising one or more amino groups at one or both ends of the silicone backbone. In at least one
embodiment, the composition is substantially free of any silicone compound comprising pendant amino groups. In an embodiment, the composition is substantially free of any silicone compound other than terminal aminosilicones. In at least one embodiment, the amino group at least one terminus of the silicone backbone of the terminal aminosilicone is selected from the group consisting of primary amines, secondary amines and tertiary amines. In at least one embodiment, the composition comprises a terminal aminosilicone conforming to Formula (S): (RF)aG3-a-Si-(-OSiG2)n-O-SiG3-a(RF)a (S) wherein G is hydrogen, phenyl, hydroxy, or C1-C8 alkyl, preferably methyl; a is an integer having a value from 1 to 3, preferably 1; b is 0, 1 or 2, preferably 1; n is a number from 0 to 1,999; RF is a monovalent radical conforming to the general formula CqH2qL, wherein q is an integer having a value from 2 to 8 and L is selected from the following groups: -N(RT)CH2-CH2-N(RT)2; -N(RT)2; -N(RT)3A-; -N(RT)CH2-CH2-NRTH2A-; wherein RT is hydrogen, phenyl, benzyl, or a saturated hydrocarbon radical, preferably an alkyl radical from having from 1 to 20 carbon atoms; A- is a halide ion. In at least one embodiment, the terminal aminosilicone corresponding to Formula (S) has a=1, q=3, G=methyl, n is from 1000 to 2500, alternatively from 1500 to 1700; and L is -N(CH3)2. A suitable terminal aminosilicone corresponding to Formula (S) has a=O, G=methyl, n is from 100 to 1500, or from 200 to 800, and L is selected from the following groups: -N(RT)CH2-CH2-N(RT)2; -N(RT)2; -N(RT)3A-; -N(RT)CH2-CH2-NRTH2A-; wherein RT is selected from hydrogen, phenyl, benzyl, or a saturated hydrocarbon radical, preferably an alkyl radical from having from 1 to 20 carbon atoms; A- is a halide ion, alternatively L is -NH2. In at least one embodiment, the terminal aminosilicone is selected from the group consisting of bis-aminomethyl dimethicone, bisaminoethyl dimethicone, bis-aminopropyl dimethicone, bis-aminobutyl dimethicone, and mixtures thereof. In at least one
embodiment, the viscosity of the terminal aminosilicone is from 1,000 to 30,000 mPas, or from 5,000 to 20,000 mPas measured at 25 °C. In at least one embodiment, the composition comprises from 0.1 wt.-% to 20 wt.-%, or from 0.5 wt.-% to 10 wt.-%, or from 1 wt.-% to 6 wt.-% terminal aminosilicone, by total weight of the composition. In at least one embodiment, the composition comprises a high melting point fatty compound. The high melting point fatty compound has a melting point of 25 °C or higher. In at least one embodiment, the high melting point fatty compound is selected from the group consisting of a fatty alcohol, fatty acid, fatty alcohol derivative, fatty acid derivative, and mixtures thereof. Non-limiting examples of the high melting point compounds are found in International Cosmetic Ingredient Dictionary, Fifth Edition, 1993, and CTFA Cosmetic Ingredient Handbook, Second Edition, 1992. The composition may comprise from 0.1 wt.-% to 40 wt.-%, or from 1 wt.-% to 30 wt.-%, or from 1.5 wt.-% to 16 wt.-%, or from 1.5 wt.-% to 8 wt.-% of a high melting point fatty compound, by total weight of the composition. This is advantageous in view of providing improved conditioning benefits such as slippery feel during the application to wet hair, softness and moisturized feel on dry hair. In at least one embodiment, the fatty alcohol is selected from the group consisting of: cetyl alcohol, stearyl alcohol, behenyl alcohol, and mixtures thereof. In at least one embodiment, the composition comprises a linear fatty alcohol, wherein the linear fatty alcohol is also comprised in a lamellar gel matrix. The lamellar gel matrix is suitable for providing various conditioning benefits such as slippery feel during the application to wet hair and softness and moisturized feel on dry hair. The linear fatty alcohol may comprise from 8 to 24 carbon atoms. In at least one embodiment, the linear fatty alcohol is selected from the group consisting of: cetyl alcohol, stearyl alcohol, and mixtures thereof. In an embodiment, the weight ratio of total linear fatty alcohol to terminal aminosilicone is from 0.5:1 to 10:1, or from 1:1 to 5:1, or from 2.4:1 to 2.7:1. In at least one embodiment, the lamellar gel matrix comprises a cationic surfactant and a high melting point fatty compound. In view of providing the lamellar gel matrix, the cationic surfactant and the high melting point fatty compound are contained at a level such that the weight ratio of
the cationic surfactant to the high melting point fatty compound is in the range of from 1: 1 to 1: 10, or from 1: 1 to 1:6. Hairstyling polymers A cosmetic composition may optionally also comprise one or more hair styling polymers as component (D). In at least one embodiment, the composition further comprises a hairstyling polymer. In at least one embodiment, the hairstyling polymer is selected from the group consisting of: amphoteric hairstyling polymers, zwitterionic hairstyling polymers, anionic hairstyling polymers, non-ionic hairstyling polymers, cationic hairstyling polymers, and mixtures thereof. In at least one embodiment, the composition comprises from 0.01 wt.-% to 20 wt.-%, or from 0.01 wt.-% to 16 wt.-%, or from 0.01 wt.-% to 10 wt.-%, or from 1 wt.-% to 8 wt.-%, or from 2 wt.-% to 6 wt.-% of hairstyling polymer. In at least one embodiment, the hairstyling polymer is a water-compatible hairstyling polymer, alternatively a water-soluble hairstyling polymer. In at least one embodiment, the composition is substantially free of a water-incompatible hairstyling polymer. An example of a water-incompatible hairstyling polymer includes an Acrylates/t-Butylacrylamide Copolymer which is a copolymer of tert-butyl acrylamide and one or more monomers of acrylic acid, methacrylic acid, or one of their simple esters (e.g. Ultrahold® 8 from BASF). Balance® CR from Akzo Nobel, which is an acrylates copolymer of two or more monomers of (meth)acrylic acid or one of their simple esters, is water-compatible. The octylacrylamide/acrylate/butylaminoethyl methacrylate copolymer Amphomer® is also water-compatible. In at least one embodiment, the hairstyling polymer is a latex hairstyling polymer. The composition may comprise a cationic hairstyling polymer. In at least one embodiment, the cationic hairstyling polymers is selected from from group consisting of those with primary, secondary, tertiary or quaternary amino groups. In at least one embodiment, the cationic hairstyling polymer has a cationic charge density, and wherein the cationic charge density is from 1 to 7 meq/g. In at least
one embodiment, the cationic hairstyling polymer comprises quaternary amino groups. In at least one embodiment, the cationic hairstyling polymer is a homo- or copolymer where the quaternary nitrogen groups are contained either in the polymer chain or as substituents on one or more of the monomers. The ammonium group-containing monomers can be copolymerized with non-cationic monomers. In at least one embodiment, the cationic hairstyling polymer comprises cationic monomers where the cationic monomers are unsaturated compounds that can undergo radical polymerization, and which bear at least one cationic group. In at least one embodiment, the cationic monomers are selected from the group consisting of: ammonium-substituted vinyl monomers such as, for example, trialkylmethacryloxyalkylammonium, trialkylacryloxyalkylammonium, dialkyldiallylammonium and quaternary vinylammonium monomers with cyclic, cationic nitrogen-containing groups such as pyridinium, imidazolium or quaternary pyrrolidones, e.g. alkylvinylimidazolium, alkylvinylpyridinium, or alkylvinylpyrrolidone salts. The alkyl groups of these monomers may be lower alkyl groups such, as for example, C1- to C7-alkyl groups, and may also be C1- to C3- alkyl groups. In at least one embodiment, cationic hairstyling polymer comprises ammonium group-containing monomers being copolymerized with non-cationic monomers. The non-cationic monomers may be selected from the group consisting of: acrylamide, methacrylamide, alkyl- and dialkylacrylamide, alkyl- and dialkylmethacrylamide, alkyl acrylate, alkyl methacrylate, vinylcaprolactone, vinylcaprolactam, vinylpyrrolidone, vinyl esters, for example vinyl acetate, vinyl alcohol, propylene glycol or ethylene glycol, and mixture thereof. The alkyl groups of these monomers may be C1- to C7-alkyl groups and may be C1- to C3-alkyl groups. In at least one embodiment, cationic hairstyling polymer comprises at least one quaternary amino group. Suitable polymers with at least one quaternary amino group include, for example, those described in the CTFA Cosmetic Ingredient Dictionary under the designations ‘polyquaternium’ such as methylvinylimidazolium chloride/vinylpyrrolidone copolymer (polyquaternium-16) or quaternized vinylpyrrolidone/dimethylaminoethyl methacrylate copolymer (polyquaternium-11; Gafquat® 755N-PW from ISP) as well as quaternary silicone
polymers or silicone oligomers such as, for example, silicone polymers with quaternary end groups (quatemium-80). In at least one embodiment, the hairstyling polymer is a cationic hairstyling polymer being of synthetic origin. In at least one embodiment, the cationic hairstyling polymers of synthetic origin are selected from the group consisting of: poly(dimethyldiallylammonium chloride); copolymers from acrylamide and dimethyldiallylammonium chloride; quaternary ammonium polymers, formed by the reaction of diethyl sulfate with a copolymer from vinylpyrrolidone and dimethylaminoethyl methacrylate, especially vinylpyrrolidone/dimethylaminoethyl methacrylate methosulfate copolymer (e.g. Gafquat® 755 N; Gafquat® 734); quaternary ammonium polymers from methylvinylimidazolium chloride and vinylpyrrolidone (e.g. Luviquat® HM 550 from BASF; Luviquat® Hold from BASF; polyquaternium-46 [vinylcaprolactam {VCap}, vinylpyrrolidone {VP} and quaternized vinylimidazole {QVI}] from BASF; Luviquat® FC 905 from BASF [polyquaternium-16]); Luviquat Supreme® from BASF (polyquaternium-68, quaternised copolymer of vinyl pyrrolidone, methacrylamides, vinyl imidazole and quaternized vinyl imidazole); polyquaternium-35; polyquaternium-57; polymers from trimethylammonium ethyl methacrylate chloride; terpolymers from dimethyldiallylammonium chloride, sodium acrylate and acrylamide (e.g. Merquat® Plus 3300); copolymers from vinylpyrrolidone, dimethylaminopropyl methacrylamide, and methacryloylaminopropyllauryldimethylammonium chloride; terpolymers from vinylpyrrolidone, dimethylaminoethyl methacrylate, and vinylcaprolactam (e.g. Gaffix® VC 713); vinylpyrrolidone/methacrylamidopropyltrimethylammonium chloride copolymers (e.g. Gafquat® HS 100); copolymers from vinylpyrrolidone and dimethylaminoethyl methacrylate; copolymers from vinylpyrrolidone, vinylcaprolactam, and dimethylaminopropylacrylamide; poly- or oligoesters formed from at least one first type of monomer that is selected from hydroxyacids substituted with at least one quaternary ammonium group; dimethylpolysiloxane substituted with quaternary ammonium groups in the terminal positions; and mixtures thereof.
In at least one embodiment, the hairstyling polymer is a cationic hairstyling polymer being of natural origin. In at least one embodiment, the cationic hairstyling polymers being of natural origin are selected from the group consisting of: cationic derivatives of polysaccharides, for example, cationic cellulose derivatives, starch, guar, and mixtures thereof. Cationic derivatives of polysaccharides may be represented by the general formula (D): G–O–B–N+–Ra–Rb–Rc X- (D) wherein G is an anhydroglucose residue, for example, starch or cellulose anhydroglucoses; B is a divalent bonding group, for example, alkylene, oxyalkylene, polyoxyalkylene or hydroxyalkylene; Ra, Rb and Rc are independently from one another, alkyl, aryl, alkylaryl, arylalkyl, alkoxyalkyl or alkoxyaryl, any of which can have up to 22 carbon atoms, wherein the total number of carbon atoms in Ra, Rb and Rc may be a maximum of 20. In at least one embodiment, the hairstyling polymer is a cationic cellulose derivative being selected from the group consisting of: those that have at least one quaternary ammonium group, e.g. a copolymer made of hydroxyethyl cellulose and diallyldimethyl ammonium chloride (polyquaternium-4), or the reaction product made of hydroxyethyl cellulose and an epoxide substituted with a trialkyl ammonium group (polyquaternium-10), wherein the alkyl groups can have 1 to 20 carbon atoms, or wherein the alkyl group is methyl. In at least one embodiment, the hairstyling polymer is a cationic cellulose derivative having a molecular weight of from 100,000 Da to 600,000 Da, or from 200,000 Da to 400,000 Da. In at least one embodiment, the cationic cellulose derivative has a nitrogen content, wherein the nitrogen content is from 0.5 wt.-% to 4 wt.-%, or from about 1.5 wt.-% to 3 wt.-%. In at least one embodiment, the hairstyling polymer is a cationic cellulose derivative being polyquaternium-4. Polyquaternium-4 is sold under the trade names Celquat® HlOO and Celquat® L200, of which Celquat® L200 is especially preferred.
In at least one embodiment, the hairstyling polymer is a cationic latex hairstyling polymer. In at least one embodiment, the cationic hairstyling polymer is selected from the group consisting of: polyquaternium-4, polyquaternium-11, polyquaternium-16, polyquaternium-68, mixtures thereof, and mixtures of polyquaternium-68 with a non-ionic hairstyling polymer. In at least one embodiment, the hairstyling polymer is selected from the group consisting of: polyquaternium-4, polyquaternium-11, polyquaternium-68, and mixtures thereof. In at least one embodiment, the composition comprises a chitosan, a chitosan salt or a chitosan derivative. In at least one embodiment, the composition comprises less than 0.1 wt.-% by weight chitosan, chitosan salts and chitosan derivatives. In another embodiment, the composition is substantially free from chitosan, chitosan salts and chitosan derivatives. In at least one embodiment, the composition comprises a hairstyling polymer selected from the group consisting of: polyquaternium-4, polyquaternium-11, polyquaternium-16, polyquaternium-68, mixtures thereof; or from the group consisting of: polyquaternium-4, polyquaternium-68, and mixtures thereof. In at least one embodiment, the composition comprises a hairstyling polymer selected from the group consisting of: polyquaternium-4, polyquaternium-11, polyquaternium-68, mixtures thereof; or from the group consisting of: polyquaternium-4, polyquaternium-68, and mixtures thereof. In at least one embodiment, the composition comprises less than 0.5 wt.-% of a cationic hairstyling polymer by total weight of the composition. In at least one embodiment, the composition comprises an amphoteric or zwitterionic hairstyling polymer. In at least one embodiment, the amphoteric or zwitterionic hairstyling polymer is selected from the group consisting of: copolymers formed from alkylacrylamide, alkylaminoalkyl methacrylate, and two or more monomers from acrylic acid and methacrylic acid as well as, if necessary, their esters, especially copolymers from octylacrylamide, acrylic acid, butylaminoethyl methacrylate, methyl methacrylate and hydroxypropyl methacrylate (octylacrylamide/acrylate/butylaminoethyl methacrylate copolymer,
for example Amphomer® from Akzo Nobel); copolymers, that are formed from at least one of a first type of monomer that possesses quaternary amino groups and at least one of a second type of monomer that possesses acid groups; copolymers from fatty alcohol acrylates, alkylamine oxide methacrylate and at least one monomer selected from acrylic acid and methacrylic acid as well as, if necessary, acrylic acid esters and methacrylic acid esters, especially copolymers from lauryl acrylate, stearyl acrylate, ethylamine oxide methacrylate and at least one monomer selected from acrylic acid and methacrylic acid as well as, if necessary, their esters; copolymers from methacryloyl ethyl betaine and at least one monomer selected from methacrylic acid and methacrylic acid esters; copolymers from acrylic acid, methyl acrylate and methacrylamidopropyltrimethylammonium chloride (polyquaternium-47); copolymers from acrylamidopropyltrimethylammonium chloride and acrylates or copolymers from acrylamide, acrylamidopropyltrimethylammonium chloride, 2-amidopropylacrylamide sulfonate and dimethylaminopropylamine (polyquaternium-43); oligomers or polymers, producible from quaternary crotonoylbetaines or quaternary crotonoylbetaine esters. In at least one embodiment, the composition comprises an amphoteric or zwitterionic latex hairstyling polymer. In at least one embodiment, the hairstyling polymer is selected from the group consisting of: polyquaternium-47, octylacrylamide/acrylate/butylaminoethyl methacrylate copolymers, and mixtures thereof. The hairstyling composition may comprise an anionic hairstyling polymer. In at least one embodiment, the anionic hairstyling polymer is selected from the group consisting of: acrylates copolymers of two or more monomers of (meth)acrylic acid or one of their simple esters (e.g. Balance® CR from Akzo Nobel); acrylates/hydroxyesters acrylates copolymers including those being copolymers of butyl acrylate, methyl methacrylate, methacrylic acid, ethyl acrylate and hydroxyethyl methacrylate (e.g. Acudyne™ 1000 from Dow Personal Care); terpolymers of acrylic acid, ethyl acrylate, and N-tert-butylacrylamide; crosslinked or uncrosslinked vinyl acetate/crotonic acid copolymers; terpolymers of tert-butylacrylate, ethyl acrylate and methacrylic acid; sodium
polystyrenesulfonate; copolymers of vinyl acetate, crotonic acid and vinyl propionate; copolymers of vinyl acetate, crotonic acid and vinyl neodecanoate; aminomethylpropanol/acrylate copolymers; copolymers of vinylpyrrolidone and at least one further monomer selected from among acrylic acid, methacrylic acid, acrylic acid esters and methacrylic acid esters; copolymers of methyl vinyl ether and maleic acid monoalkyl esters; aminomethylpropanol salts of copolymers of allyl methacrylate and at least one further monomer selected from among acrylic acid, methacrylic acid, acrylic acid esters and methacrylic acid esters; crosslinked copolymers of ethyl acrylate and methacrylic acid; copolymers of vinyl acetate, mono-n-butyl maleate and isobornyl acrylate; copolymers of two or more monomers selected from among acrylic acid, methacrylic acid, acrylic acid esters and methacrylic acid esters, copolymers of octylacrylamide and at least one monomer selected from among acrylic acid, methacrylic acid, acrylic acid esters and methacrylic acid esters; polyesters of diglycol, cyclohexanedimethanol, isophthalic acid and sulfoisophthalic acid; polyurethanes; and copolymers of polyurethane and acrylates. e.g. polyurethane-14/AMP-acrylates polymer blend (e.g. DynamX® from Akzo Nobel). Suitable polyester polymers include polyester-5 polymers, for example AQ® 48 Ultra Polymer, (diglycol/CHDM/isophthalates/SIP copolymer [a copolymer of diethylene glycol, 1,4-cyclohexanedimethanol and the simple esters of isophthalic acid and sulfoisophthalic acid]), AQ® 55 S, and AQ® 38 S, all from Eastman Chemical Company. Also suitable is a polyvinylmethacrylic acid/maleic acid copolymer (Omnirez® 2000 from ISP). Anionic latex hairstyling polymers are also suitable. In at least one embodiment, the anionic hairstyling polymer is selected from the group consisting of: polyurethane-1 (e.g. Luviset® P.U.R. from BASF), polyurethane-14/AMP-acrylates copolymer blend (e.g. DynamX® from Akzo Nobel), acrylates copolymers of two or more monomers of (meth)acrylic acid or one of their simple esters (e.g. Balance® CR from Akzo Nobel), and mixtures thereof. In at least one embodiment, the anionic hairstyling polymer is polyurethane-1. The composition may comprise a non-ionic hairstyling polymer. In at least one embodiment, the composition comprises a non-ionic hairstyling polymer, wherein are non-ionic hairstyling polymer is a homo- or copolymer that is formed from at
least one of the following monomers: vinylpyrrolidone, vinylcaprolactam, vinyl esters such as, for example, vinyl acetate, vinyl alcohol, acrylamide, methacrylamide, alkyl- and dialkylacrylamide, alkyl- and dialkylmethacrylamide, alkyl acrylate, alkyl methacrylate, propylene glycol or ethylene glycol, where the alkyl groups in these monomers may be C1- to C7-alkyl groups or C1- to C3-alkyl groups. In at least one embodiment, the composition comprises a homopolymer selected from the group consisting of: vinylcaprolactam, vinylpyrrolidone, N-vinylformamide and mixtures thereof. In at least one embodiment, the non-ionic hairstyling polymer is selected from the group consisting of: copolymers of vinylpyrrolidone and vinyl acetate, terpolymers of vinylpyrrolidone, vinyl acetate and vinyl propionate, polyacrylamides; polyvinyl alcohols as well as polyethylene glycol/polypropylene glycol copolymers; and mixtures thereof. In at least one embodiment, the non-ionic hairstyling polymer is selected from the group consisting of: polyvinylpyrrolidone/dimethylaminopropylaminoacrylates copolymer (Aquaflex® SF 40 from ISP); isobutylene ethylmaleinimide/hydroxy ethylmaleinimide copolymer (Aquaflex® FX 64 from ISP); vinylcaprolactam/polyvinylpyrrolidone/dimethylaminoethyl methacrylate copolymer (Advantage® from ISP); and mixtures thereof. Non-ionic latex hairstyling polymers are also suitable. In at least one embodiment, the non-ionic hairstyling polymer is selected from the group consisting of: polyvinylpyrrolidone (K90, 85, 80, 60, 30), polyvinylpyrrolidone/vinyl acetate copolymers (PVP/VA 64), terpolymers of vinylpyrrolidone, methacrylamide and vinylimidazole (e.g. Luviset® Clear from BASF), and mixtures thereof. In at least one embodiment, the non-ionic hairstyling polymer is selected from the group consisting of: PVP K 60, 30, and PVP/VA 37/64. In at least one embodiment, the non-ionic hairstyling polymer is selected from the group consisting of: PVP K60 and PVP/VA 37/64. In at least one embodiment, the composition comprises an anionic latex hairstyling polymer. In at least one embodiment, the anionic latex hairstyling polymer is a urethane-based polymer, for example polyurethane-34 (Baycusan® from Bayer). Polyurethane-34 is described in EP2105127A1. In at least one embodiment, the hairstyling polymer is the latex hairstyling polymer polyurethane-34.
In at least one embodiment, the anionic hairstyling polymer and/or cationic hairstyling polymer is present in neutralized or partially neutralized form. In at least one embodiment, the composition comprises a neutralizing agent, and wherein the neutralizing agent is selected from the group consisting of: potassium hydroxide, sodium hydroxide, triisopropanolamine (TIPA), 2-aminobutanol, 2-aminomethyl propanol (AMP), aminoethylpropandiol, dimethyl stearamine (Armeen 18 D), sodium silicate, tetrahydroxypropyl ethylenediamine (Neutrol® TE), ammonia (NH3), triethanolamine, trimethylamine (Tris Amino Ultra), aminomethylpropandiol (AMPD) and mixtures thereof. In at least one embodiment, the neutralizing agent is 2-aminomethyl propanol. Auxiliaries A cosmetic composition may optionally also comprise one or more auxiliaries as component (D). In at least one embodiment, the composition comprises additives common in cosmetology, pharmacy, and dermatology, which are hereinafter called auxiliaries. In at least one embodiment, the auxiliary is selected from the group consisting of oily substances, emulsifiers, coemulsifiers, cationic polymers, film formers, superfatting agents, stabilizers, active biogenic substances, dispersing agent, wetting agent, film former, emulsion stabilizer, binding agent, or antifoaming agent, glycerol, preservatives, pearlizing agents, dyes and fragrances, solvents, opacifiers, functional acids, and also protein derivatives such as gelatin, collagen hydrolysates, natural or synthetic-based polypeptides, egg yolk, lecithin, lanolin and lanolin derivatives, fatty alcohols, silicones, deodorants, substances with a keratolytic and keratoplastic action, enzymes, and/or carriers/solvents. In at least one embodiment, the composition comprises water soluble vitamins and their derivatives, water soluble amino acids and their salts and/or derivatives, viscosity modifiers, dyes, nonvolatile solvents or diluents (water soluble and insoluble), pearlescent aids, thickeners, foam boosters, additional surfactants or nonionic co-surfactants, pediculocides, pH adjusting agents, perfumes, preservatives, chelants, proteins, skin active agents, sunscreens, UV absorbers, vitamins, niacinamide, caffeine, minoxidil, and combinations thereof. In at least
one embodiment, the composition comprises from 0 wt.-% to 5 wt.-% vitamins and amino acids, by total weight of the composition. The composition may also comprise pigment materials such as inorganic, nitroso, monoazo, disazo, carotenoid, triphenyl methane, triaryl methane, xanthene, quinoline, oxazine, azine, anthraquinone, indigoid, thionindigoid, quinacridone, phthalocianine, botanical, natural colors, including: water soluble components such as those having C.I. Names. The composition may comprise from 0 wt.-% to 5 wt.-% pigment materials. The composition may comprise from 0 wt.-% to 5 wt.-% antimicrobial agents. In at least one embodiment, the composition comprises an oily substance, which is any fatty substance which is liquid at room temperature (25 °C). In at least one embodiment, the composition comprises oily substance selected from the group consisting of silicone oils, volatile or nonvolatile, linear, branched or cyclic, optionally with organic modification; phenylsilicones; silicone resins and silicone gums; mineral oils such as paraffin oil or vaseline oil; oils of animal origin such as perhydrosqualene, lanolin; oils of plant origin such as liquid triglycerides, e.g., sunflower oil, corn oil, soybean oil, rice oil, jojoba oil, babusscu oil, pumpkin oil, grapeseed oil, sesame oil, walnut oil, apricot oil, macadamia oil, avocado oil, sweet almond oil, lady’s-smock oil, castor oil, triglycerides of caprylic/capric acids, olive oil, peanut oil, rapeseed oil, argan oil, abyssinian oil, and coconut oil; synthetic oils such as purcellin oil, isoparaffins, linear and/or branched fatty alcohols and fatty acid esters, preferably guerbet alcohols having 6 to 18, preferably 8 to 10, carbon atoms; esters of linear (C6-C13) fatty acids with linear (C6-C20) fatty alcohols; esters of branched (C6-C13) carboxylic acids with linear (C6-C20) fatty alcohols, esters of linear (C6-C18) fatty acids with branched alcohols, especially 2-ethylhexanol; esters of linear and/or branched fatty acids with polyhydric alcohols (such as dimerdiol or trimerdiol, for example) and/or guerbet alcohols; triglycerides based on (C6-C10) fatty acids; esters such as dioctyl adipate, diisopropyl dimer dilinoleate; propylene glycols/dicaprylate or waxes such as beeswax, paraffin wax or microwaxes, alone or in combination with hydrophilic waxes, such as cetylstearyl alcohol, for example; fluorinated and perfluorinated oils; fluorinated silicone oils; mixtures of the aforementioned compounds.
In at least one embodiment, the composition comprises a non-ionic coemulsifier. In at least one embodiment, the non-ionic coemulsifier is selected from adducts of from 0 to 30 mol of ethylene oxide and/or from 0 to 5 mol of propylene oxide with linear fatty alcohols having 8 to 22 carbon atoms, with fatty acids having 12 to 22 carbon atoms, with alkylphenols having 8 to 15 carbon atoms in the alkyl group, and with sorbitan or sorbitol esters; (C12-C18) fatty acid monoesters and diesters of adducts of from 0 to 30 mol of ethylene oxide with glycerol; glycerol monoesters and diesters and sorbitan monoesters and diesters of saturated and unsaturated fatty acids having 6 to 22 carbon atoms and, where appropriate, their ethylene oxide adducts; adducts of from 15 to 60 mol of ethylene oxide with castor oil and/or hydrogenated castor oil; polyol esters and especially polyglycerol esters, such as polyglyceryl polyricinoleate and polyglyceryl poly-12-hydroxystearate, for example. Likewise suitable are mixtures of compounds from one or more of these classes of substance. Examples of suitable ionogenic coemulsifiers include anionic emulsifiers, such as mono -, di- or tri-phosphoric esters, but also cationic emulsifiers such as mono-, di-, and tri-alkyl quats and their polymeric derivatives. In at least one embodiment, the composition comprises a cationic polymer. Suitable cationic polymers include those known under the INCI designation “Polyquaternium“, especially Polyquaternium-31, Polyquaternium-16, Polyquaternium-24, Polyquaternium-7, Polyquaternium-22, Polyquaternium-39, Polyquaternium-28, Polyquaternium-2, Polyquaternium-10, Polyquaternium-11, and also Polyquaternium 37 & mineral oil & PPG trideceth (Salcare SC95), PVP-dimethylaminoethyl methacrylate copolymer, guar-hydroxypropyltriammonium chlorides, and also calcium alginate and ammonium alginate. It is additionally possible to employ cationic cellulose derivatives; cationic starch; copolymers of diallylammonium salts and acrylamides; quaternized vinylpyrrolidone/vinylimidazole polymers; condensation products of polyglycols and amines; quaternized collagen polypeptides; quaternized wheat polypeptides; polyethyleneimines; cationic silicone polymers, such as amidomethicones, for example; copolymers of adipic acid and
dimethylaminohydroxypropyldiethylenetriamine; polyaminopolyamide and cationic chitin derivatives, such as chitosan, for example. In at least one embodiment, the composition comprises a superfatting agent. As superfatting agents it is possible to use substances such as, for example, polyethoxylated lanolin derivatives, lecithin derivatives, polyol fatty acid esters, monoglycerides, and fatty acid alkanol amides, the latter serving simultaneously as foam stabilizers. Moisturizers available include for example isopropyl palmitate, glycerol and/or sorbitol. In at least one embodiment, the composition comprises a stabiliser. As stabiliser it is possible to use metal salts of fatty acids, such as magnesium, aluminum and/or zinc stearate, for example. In at least one embodiment, the composition comprises a care additive. The compositions can be blended with conventional ceramides, pseudoceramides, fatty acid N-alkylpolyhydroxyalkyl amides, cholesterol, cholesterol fatty acid esters, fatty acids, triglycerides, cerebrosides, phospholipids, panthenol and similar substances as a care additive. In at least one embodiment, the composition comprises a preservative or preservative system. Examples of suitable preservatives include benzyl alcohol, piroctone olamine, phenoxyethanol, parabens, pentanediol, benzoic acid/sodium benzoate, sorbic acid/potassium sorbate, and other organic acids used to provide antimicrobial protection. Preservation boosting ingredients include anisic acid, lactic acid, sorbitan caprylate, ethylhexylglycerin, caprylyl glycol, octanediol, and similar substances. In at least one embodiment, the composition comprises 0.01 to 5 wt.-%, particularly preferably from 0.05 wt.-% to 1 wt.-% of at least one preservative. Suitable preservatives are the substances listed in the International Cosmetic Ingredient Dictionary and Handbook, 9th Edition with the function "preservatives". In at least one embodiment, the preservative is selected from the group consisting of phenoxyethanol, benzyl paraben, butyl paraben, ethyl paraben, isobutyl paraben, isopropyl paraben, methyl paraben, propyl paraben,
iodopropynyl butylcarbamate, methyldibromoglutaronitrile, DMDM hydantoin and combinations thereof. In at least one embodiment, the composition comprises a preservative selected from the group consisting of cetyltrimethyl ammoniumchloride, cetylpyridinium chloride, benzethonium chloride, diisobutylethoxyethyldimethyl benzylammoniumchloride, sodium N-lauryl sarcosinate, sodium-N-palmethylsarcosinate, Lauroylsarcosine, N-myristoylglycine, potassium-N-laurylsarcosine, trimethylammoniumchloride, sodium aluminium chlorohydroxylactate, triethylcitrate, tricetylmethylammoniumchloride, 2,4,4'-trichloro-2'-hydroxydiphenylether (Triclosan), phenoxyethanol, 1,5-pentandiol, 1,6-hexandiol, 3,4,4'-trichlorocarbanilide (Triclocarban), diaminoalkylamide, L-lysine hexadecylamide, heavy metal citrate salts, salicylate, piroctose, zinc salts, pyrithione and its heavy metal salts, zinc pyrithione, zinc phenol sulfate, farnesol, ketoconazol, oxiconazol, bifonazole, butoconazole, cloconazole, clotrimazole, econazole, enilconazole, fenticonazole, isoconazole, miconazole, sulconazole, tioconazole, fluconazole, itraconazole, terconazole, naftifine, terbinafine, selenium disulfide, Octopirox®, methylchloroisothiazolinone, methylisothiazolinone, methyldibromo glutaronitrile, AgCl, chloroxylenol, sodium salts of diethylhexylsulfosuccinate, sodiumbenzoate, phenoxyethanol, benzylalkohol, phenoxyisopropanol, paraben, such as butyl-, ethyl-, methyl- und propylparaben, and their salts, pentandiol, 1,2-octanediol, ethylhexylglycerin, benzylalcohol, sorbic acid, benzoic acid, lactic acid, imidazolidinyl urea, diazolidinyl urea, dimethylol dimethyl hydantoin (DMDMH), sodium salts of hydroxymethyl glycinate, hydroxyethylglycine of sorbic acid and combinations thereof. In at least one embodiment, the preservative is selected from the group consisting of phenoxyethanol, benzyl paraben, butyl paraben, ethyl paraben, isobutyl paraben, isopropyl paraben, methyl paraben, propyl paraben, iodopropynyl butylcarbamate, methyldibromoglutaronitrile, DMDM hydantoin and combinations thereof. In at least one embodiment, the composition is substantially free of parabens. In at least one embodiment, the composition comprises an anti-fungal substance. In at least one embodiment, the anti-fungal substance is selected from the group consisting of ketoconazole, oxiconazole, bifonazole, butoconazole, cloconazole,
clotrimazole, econazole, enilconazole, fenticonazole, isoconazole, miconazole, sulconazole, tioconazole, fluconazole, itraconazole, terconazole, naftifine and terbinafine, zinc pyrithione, octopirox, and combinations thereof. In at least one embodiment, the composition comprises a total amount of anti-fungal substance in the composition of from 0.1 wt.-% to 1 wt.-%. In at least one embodiment, the composition comprises a pyridinethione anti-dandruff particulates, for example 1-hydroxy-2-pyridinethione salts, are highly preferred particulate anti-dandruff agents. The concentration of pyridinethione antidandruff particulate may ranges from 0.1 % to 4 %, by weight of the composition, preferably from 0.1 % to 3 %, more preferably from 0.3 % to 2 %. Preferred pyridinethione salts include those formed from heavy metals such as zinc, tin, cadmium, magnesium, aluminum and zirconium, preferably zinc, more preferably the zinc salt of 1-hydroxy-2- pyridinethione (known as "zinc pyridinethione" or "ZPT"), more preferably 1-hydroxy-2-pyridinethione salts in platelet particle form. Salts formed from other cations, such as sodium, may also be suitable. Pyridinethione anti-dandruff agents are described, for example, in US2809971; US3236733; US3753196; US3761418; US4345080; US4323683; US4379753; and US4470982. It is contemplated that when ZPT is used as the anti-dandruff particulate in the compositions herein, that the growth or regrowth of hair may be stimulated or regulated, or both, or that hair loss may be reduced or inhibited, or that hair may appear thicker or fuller. Functional acids are acidic substances used to impart a clinical functionality to the skin or hair upon application. Suitable functional acids include alpha hydroxy acids, beta-hydroxy acids, lactic acid, retinoic acid, and similar substances. In at least one embodiment, the composition comprises an astringent. In at least one embodiment, the astringent is selected from the group consisting of magnesium oxide, aluminum oxide, titanium oxide (which can also be used as UV and/or blue light filter, also: titanium dioxide), zirconium dioxide, zinc oxide, oxide hydrates, aluminium oxide hydrate (boehmite) and hydroxide, chlorohydrates of calcium, magnesium, aluminium, titanium, zirconium or zinc. In at least one embodiment, the composition comprises from 0.001 wt.-% to 10 wt.-%, or from
0.01 wt.-% to 9 wt.-%, or from 0.05 wt.-% to 8 wt.-%, or from 0.1 wt.-% to 5 wt.-% astringent. In at least one embodiment, the composition comprises an anti-oxidant. In at least one embodiment, the anti-oxidant is selected from the group consisting of amino acids, peptides, sugars, imidazoles, carotinoids, carotenes, chlorogenic acid, lipoic acid, thiols, thiol glycosyl esters, thiol N-acetyl esters, thiol methyl esters, thiol ethyl esters, thiol propyl esters, thiol amyl esters, thiol butyl esters, thiol lauryl esters, thiol palmitoyl esters, thiol oleyl esters, thiol linoleyl esters, thiol cholesteryl esters, thiol glyceryl esters, dilaurylthiodipropionate, distearylthiodipropionate, thiodipropionic acid, metal chelators, hydroxy acids, fatty acids, folic acids, vitamin C, tocopherol, vitamin A, stilbenes, derivatives and combinations thereof. In at least one embodiment, the anti-oxidant is selected from the group consisting of glycine, histidine, tyrosine, tryptophan, urocaninic acid, D,L-carnosine, D-carnosine, L-carnosine, beta-carotene, alpha-carotene, lycopene, dihydrolipoic acid, aurothioglucose, propylthiouracil, thioredoxine, glutathione, cysteine, cystine, cystamine, buthioninsulfoximine, homocysteinsulfoximine, buthioninsulfone, penta-, hexa-, heptathioninsulfoximine, hydroxyfatty acids, palmitic acid, phytinic acid, lactoferrin, citric acid, lactic acid, malic acid, humic acid, bile acid, bilirubin, biliverdin, EDTA, EGTA, linoleic acid, linolenic acid, oleic acid, butylhydroxyanisol, trihydroxybutyrophenone, ubichinon, ubichinol, ascorbylpalmitate, Mg-ascorbylphosphate, ascorbylacetate, vitamin E acetate, vitamin A palmitate, carnosine, mannose, ZnO, ZnSO4, selenium methionine, stilbenes, superoxide dismutase, and combinations thereof. In at least one embodiment, the antioxidant is selected from the group consisting of vitamin A, vitamin A derivatives, vitamin E, vitamin E derivatives, and combinations thereof. In at least one embodiment, the composition comprises from 0.001 wt.-% to 10 wt.-%, preferably from 0.05 wt.-% to 5 wt.-%, even more preferably from 0.1 wt.-% to 3 wt.-%, most preferably from 0.05 wt.-% to 1 wt.-% antioxidant. In at least one embodiment, the composition comprises a dye or pigment. In at least one embodiment, the composition comprises at least one pigment. Suitable dyes and pigments are disclosed in WO2013017262A1 in the table spanning
pages 36 to 43. These may be colored pigments which impart color effects to the product mass or to hair, or they may be luster effect pigments which impart luster effects to the product mass or to the hair. The color or luster effects on the hair are preferably temporary, i.e. they last until the next hair wash and can be removed again by washing the hair with customary shampoos. In at least one embodiment, the composition comprises a total amount of from 0.01 wt.-% to 25 wt.-%, preferably from 5 wt.-% to 15 wt.-% pigment. In at least one embodiment, the particle size of the pigment is from 1 micron to 200 micron, preferably from 3 micron to 150 micron, more preferably 10 micron to 100 micron. The pigments are colorants which are virtually insoluble in the application medium, and may be inorganic or organic. Inorganic-organic mixed pigments are also possible. Preference is given to inorganic pigments. The advantage of inorganic pigments is their excellent resistance to light, weather and temperature. The inorganic pigments may be of natural origin. In at least one embodiment, the inorganic pigment is selected from the group consisting of chalk, ochre, umber, green earth, burnt sienna, graphite, and combinations thereof. The pigments may be white pigments, such as, for example, titanium oxide (which can also be used as UV and/or blue light filter, also: titanium dioxide) or zinc oxide (which can also be used as UV and/or blue light filter), black pigments, such as, for example, iron oxide black, colored pigments, such as, for example, ultramarine or iron oxide red, luster pigments, metal effect pigments, pearlescent pigments, and fluorescent or phosphorescent pigments, where preferably at least one pigment is a colored, nonwhite pigment. In at least one embodiment, the pigment is selected from the group consisting of metal oxides, hydroxides and oxide hydrates, mixed phase pigments, sulfur-containing silicates, metal sulfides, complex metal cyanides, metal sulfates, chromates and molybdates, and the metals themselves (bronze pigments), and combinations thereof. In at least one embodiment, the pigment is selected from the group consisting of titanium dioxide (CI 77891), black iron oxide (CI 77499), yellow iron oxide (CI 77492), red and brown iron oxide (CI 77491), manganese violet (CI 77742), ultramarine (sodium aluminum sulfosilicates, CI 77007, Pigment Blue 29), chromium oxide hydrate (CI 77289), Prussian blue (ferric ferrocyanide, CI 77510), carmine (cochineal), and combinations thereof. In at least one embodiment, the pigment is selected from the group consisting of
pearlescent and colored pigments based on mica which are coated with a metal oxide or a metal oxychloride, such as titanium dioxide or bismuth oxychloride, and optionally further color-imparting substances, such as iron oxides, Prussian blue, ultramarine, carmine etc. and where the color can be determined by varying the layer thickness. Such pigments are sold, for example, under the trade names Rona®, Colorona®, Dichrona® and Timiron® by Merck, Germany. In at least one embodiment, the pigment is selected from the group consisting of organic pigments such as sepia, gamboge, bone charcoal, Cassel brown, indigo, chlorophyll and other plant pigments. In at least one embodiment, the pigment is selected from the group consisting of synthetic organic pigments such as azo pigments, anthraquinoids, indigoids, dioxazine, quinacridone, phthalocyanine, isoindolinone, perylene and perinone, metal complex, alkali blue and diketopyrrolopyrrole pigments. In at least one embodiment, the composition comprises from 0.01 wt.-% to 10 wt.-%, preferably from 0.05 wt.-% to 5 wt.-%, of at least one particulate substance. Suitable substances are, for example, substances which are solid at room temperature (25 °C) and are in the form of particles. In at least one embodiment, the particulate substance is selected from the group consisting of silica, silicates, aluminates, clay earths, mica, insoluble salts, in particular insoluble inorganic metal salts, metal oxides, e.g. titanium dioxide, minerals and insoluble polymer particles are suitable. The particles are present in the composition in undissolved, preferably stably dispersed form, and, following application to the keratin substrate and evaporation of the solvent, can deposit on the substrate in solid form. A stable dispersion can be achieved by providing the composition with a yield point which is large enough to prevent the solid particles from sinking. An adequate yield point can be established using suitable gel formers in a suitable amount. In at least one embodiment, the particulate substance is selected from the group consisting of silica (silica gel, silicon dioxide) and metal salts, in particular inorganic metal salts, where silica is particularly preferred. Metal salts are, for example, alkali metal or alkaline earth metal halides, such as sodium chloride or potassium chloride; alkali metal or alkaline earth metal sulfates, such as sodium sulfate or magnesium sulfate.
In at least one embodiment, the composition comprises a direct dye. Preferred among the direct dyes are the following compounds, alone or in combination with one another: Hydroxyethyl-2-nitro-p-toluidine, 2-hydroxyethylpicramic acid, 4-nitrophenylaminourea, tri(4-amino-3-methylphenyl)carbenium chloride (Basic Violet 2), 1,4-di-amino-9,10-anthracenedione (Disperse Violet 1), 1-(2-hydroxy- ethyl)amino-2-nitro-4-[di(2-hydroxyethyl)amino]benzene (HC Blue No.2), 4-[ethyl- (2-hydroxyethyl)amino]-1-[(2-hydroxyethyl)amino]-2-nitrobenzene hydrochloride (HC Blue No.12), 1-amino-4-[di(2-hydroxyethyl)amino]-2-nitrobenzene hydrochloride (HC Red No.13), 4-amino-1-[(2-hydroxyethyl)amino]-2-nitrobenzene (HC Red No.3), 4-amino-3-nitrophenol, 4-[(2-hydroxyethyl)amino]-3-nitrophenol, 1-amino-5-chloro-4-[(2,3-dihydroxypropyl)amino]-2-nitrobenzene (HC Red No.10), 5-chloro-1,4-[di(2,3-dihydroxypropyl)amino]-2-nitrobenzene (HC Red No.11), 2-chloro-6-ethylamino-4-nitrophenol, 2-amino-6-chloro-4-nitrophenol, 4-[(2-hydroxyethyl)amino]-3-nitro-1-trifluoromethylbenzene (HC Yellow No.13), 8-amino-2-bromo-5-hydroxy-4-imino-6-{[3-(trimethylammonio)-phenyl]amino}- 1(4H)-naphthalenone chloride (C.I.56059; Basic Blue No.99), 1-[(4-aminophenyl)azo]-7-(trimethylammonio)-2-naphthol chloride (C.I.12250; Basic Brown No.16), 1-[(4-amino-2-nitrophenyl)azo]-7-(trimethylammonio)-2- naphthol chloride (Basic Brown No.17), 2-hydroxy-1-[(2-methoxyphenyl)azo]-7- (trimethylammonio)naphthalene chloride (C.I.12245; Basic Red No.76), 3-methyl- 1-phenyl-4-{[3-(trimethylammonio)phenyl]azo}pyrazol-5-one chloride (C.I.12719; Basic Yellow No.57) and 2,6-diamino-3-[(pyridin-3-yl)azo]pyridine as well as the salts thereof. Particularly preferred among the aforesaid direct dyes are the following compounds, alone or in combination with one another: hydroxyethyl-2- nitro-p-toluidine, 2-hydroxyethylpicramic acid, 4-nitrophenylaminourea, tri(4-amino- 3-methylphenyl)carbenium chloride (Basic Violet 2), 1,4-di-amino-9,10- anthracenedione (Disperse Violet 1), 1-(2-hydroxy-ethyl)amino-2-nitro-4-[di(2- hydro-xyethyl)amino]benzene (HC Blue No.2), 4-[ethyl-(2-hydroxyethyl)amino]-1- [(2-hydroxyethyl)amino]-2-nitrobenzene hydrochloride (HC Blue No.12), 1-amino- 4-[di(2-hydroxyethyl)amino]-2-nitrobenzene hydrochloride (HC Red No.13), 4-amino-1-[(2-hydroxyethyl)amino]-2-nitrobenzene (HC Red No.3), 4-amino-3- nitrophenol, 4-[(2-hydroxyethyl)amino]-3-nitrophenol, 1-amino-5-chloro-4-[(2,3-
dihydroxypropyl)amino]-2-nitrobenzene (HC Red No.10), 5-chloro-1,4-[di(2,3- dihydroxypropyl)- amino]-2-nitrobenzene (HC Red No.11), 2-chloro-6-ethylamino- 4-nitrophenol, 2-amino-6-chloro-4-nitrophenol, 4-[(2-hydroxyethyl)amino]-3-nitro-1- trifluoromethylbenzene (HC Yellow No.13), 8-amino-2-bromo-5-hydroxy-4-imino- 6-{[3-(trimethylammonio)-phenyl]amino}-1(4H)-naphthalenone chloride (C.I.56059; Basic Blue No.99), 1-[(4-aminophenyl)azo]-7-(trimethylammonio)-2- naphthol chloride (C.I.12250; Basic Brown No.16), 1-[(4-amino-2- nitrophenyl)azo]-7-(trimethylammonio)-2-naphthol chloride (Basic Brown No.17), 2-hydroxy-1-[(2-methoxyphenyl)azo]-7-(trimethylammonio)naphthalene chloride (C.I.12245; Basic Red No.76), 3-methyl-1-phenyl-4-{[3- (trimethylammonio)phenyl]azo}pyrazol-5-one chloride (C.I.12719; Basic Yellow No.57) and 2,6-diamino-3-[(pyridin-3-yl)azo]pyridine as well as the salts thereof. In at least one embodiment, the total quantity of direct dyes in the composition amounts to 0.01 to 15 wt.-%, preferably 0.1 to 10 wt.-%, most preferred 0.5 to 8 wt.-%. In one embodiment of the present invention, the use is carried out in a cosmetic composition comprising (or consisting of): (A) one or more polymers according to Formula (1) as defined herein; (B) one or more of the UV and/or blue light filters as defined herein; and (C) one or more cosmetically acceptable carriers as defined herein; and (D) optionally one or more further cosmetically acceptable components different from (A) to (C). In one embodiment of the present invention, the use is carried out in a cosmetic composition comprising (or consisting of): (A) 0.1 to 20 wt.-%, preferably 0.15 to 10 wt.-% or 0.2 to 5 wt.-%, in particular 0.5 to 2.5 wt.-%, related to the total mass of the cosmetic composition, of one or more polymers according to Formula (1) as defined herein; (B) 0.1 to 50 wt.-%, preferably 1 to 40 wt.-%, in particular 5 to 20 wt.-% or 15 to 40 wt.-%, related to the total mass of the cosmetic composition, of one or more UV and/or blue light filters;
(C) 10 to 80 wt.-%, preferably 20 to 70 wt.-%, in particular 30 to 60 wt.-%, related to the total mass of the cosmetic composition, of one or more cosmetically acceptable carriers; and (D) 5 to 60 wt.-%, preferably 7.5 to 40 wt.-%, in particular 10 to 30 wt.-%, related to the total mass of the cosmetic composition, of one or more further cosmetically acceptable components different from (A) to (C). In one embodiment of the present invention, the use is carried out in a cosmetic composition comprising (or consisting of): (A) 0.2 to 5 wt.-%, related to the total mass of the cosmetic composition, of one or more polymers according to Formula (1) as defined herein; (B) 1 to 40 wt.-%, related to the total mass of the cosmetic composition, of one or more UV and/or blue light filters; (C) 20 to 70 wt.-%, related to the total mass of the cosmetic composition, of one or more cosmetically acceptable carriers; and (D) 7.5 to 40 wt.-%, related to the total mass of the cosmetic composition, of one or more further cosmetically acceptable components different from (A) to (C). In one embodiment of the present invention, the use is carried out in a cosmetic composition comprising (or consisting of): (A) 0.5 to 2.5 wt.-%, related to the total mass of the cosmetic composition, of one or more polymers according to Formula (1) as defined herein; (B) 5 to 20 wt.-% or 15 to 40 wt.-%, related to the total mass of the cosmetic composition, of one or more UV and/or blue light filters; (C) 30 to 60 wt.-%, related to the total mass of the cosmetic composition, of one or more cosmetically acceptable carriers; and (D) 10 to 30 wt.-%, related to the total mass of the cosmetic composition, of one or more further cosmetically acceptable components different from (A) to (C). The one or more further cosmetically acceptable components different from (A) to (C) may be any known in the art as described above. In one embodiment, one or
more further cosmetically acceptable components are selected from the group consisting of one or more emollients (e.g., fatty acid ester (e.g., ethylhexyl olivate (e.g., as hydrogenated ethylhexyl olivate and/or hydrogenated olive oil unsaponifiables), ethylhexyl stearate, decyl oleate, lauryl/myristyl polyricinoleate (e.g., usable as lauryl/myristyl polyricinoleate (and) glycerin), octyldodecanol, dimethicone, C12-15 alkyl benzoate, cetereth-2, or a combination of two or more thereof), one or more emulsifiers (e.g., trilaureth-4 phosphate, potassium cetyl phosphate), one or more humectants (e.g., glycerol (also: glycerin), one or more rheology modifiers (e.g., xanthan gum, carbomer, Caesalpinia spinosa gum, hydroxymethyl cellulose, or combination of two or more thereof), one or more pH adjusters (e.g., sodium hydroxide), One or more stabilizers (e.g, cetearyl alcohol), One or more preservatives (e.g., piroctone olamine, phenoxyethanol, parabene derivative (e.g., methylparaben, ethylparaben, propylparaben, isobutylparaben), one or more antioxidants (e.g., ascorbinic acid, tocopherol derivative (also: vitamin E (and derivatives thereof such as, e.g, tocopheryl acetate) or a combination thereof), one or more fragrances, one or more colorants, one or more structure formers (e.g, polyglyceryl-2 sesquiisostearate, hydrogenated vegetable oil, microcrystalline wax, stearic acid, myristic acid, glyceryl stearate (and) cetearyl alcohol (and) sodium stearoyl lactylate, tapioca starch, or a combination of two or more thereof), one or more surfactants (e.g., as defined above), one or more auxiliaries (e.g., as defined above), one or more hairstyling polymers (e.g., as defined above), one or more conditioning agents (e.g., as defined above), and a combination of two or more thereof. Cosmetic composition The present invention further refers to a cosmetic composition comprising (or consisting of): (A) one or more polymers comprising (or consisting of): (i) one or more synthetic polymer units comprising (or consisting of): (a) repeating units of a structure of Formula (1):
wherein R1 and R2 are independently selected from H, methyl or ethyl; A is a linear or branched C1-C12-alkyl group; and Q+ is a cosmetically acceptable cation; and (b) optionally one or more crosslinking or branching units; and (c) optionally one or more further repeating units which are different from a repeating unit of structure of Formula (1) and from the crosslinking or branching units crosslinking or branching units; and (ii) one or more water-soluble and/or water-swellable polysaccharide polymer units; (B) one or more UV and/or blue light filters; and (C) one or more cosmetically acceptable carriers. In a preferred embodiment, the cosmetic composition of the present invention is a sunscreen composition. The present invention further refers to a cosmetic composition comprising (or consisting of): (A) 0.1 to 20 wt.-%, preferably 0.2 to 5 wt.-%, in particular 0.5 to 2.5 wt.-%, related to the total mass of the cosmetic composition, of one or more polymers comprising (or consisting of): (i) one or more synthetic polymer units comprising (or consisting of): (a) repeating units of a structure of Formula (1):
wherein R1 and R2 are independently selected from H, methyl or ethyl; A is a linear or branched C1-C12-alkyl group; and Q+ is a cosmetically acceptable cation; and (b) optionally one or more crosslinking or branching units; and (c) optionally one or more further repeating units which are different from a repeating unit of structure of Formula (1) and from the crosslinking or branching units crosslinking or branching units; and (ii) one or more water-soluble and/or water-swellable polysaccharide polymer units; (B) 0.1 to 50 wt.-%, preferably 1 to 40 wt.-%, in particular 5 to 20 wt.-% or 15 to 40 wt.-%, related to the total mass of the cosmetic composition, of one or more UV and/or blue light filters; (C) 10 to 80 wt.-%, preferably 20 to 70 wt.-%, in particular 30 to 60 wt.-%, related to the total mass of the cosmetic composition, of one or more cosmetically acceptable carriers; and (D) 5 to 60 wt.-%, preferably 7.5 to 40 wt.-%, in particular 10 to 30 wt.-%, related to the total mass of the cosmetic composition, of one or more further cosmetically acceptable components different from (A) to (C). It will be understood that the definitions and embodiments as defined in the context of the use above mutatis mutandis apply to the sunscreen composition of the present invention. The cosmetic composition may be any cosmetic composition. Preferably, the cosmetic composition is a cosmetic composition that is used on skin and/or hair.
Preferably, the cosmetic composition is a cosmetic composition that is used on skin and/or hair exposed to sun light. In a preferred composition, the cosmetic composition is a sunscreen composition. The invention is further exemplified by the Examples, which are intended to illustrate the invention, but not limiting its scope. Examples Example 1 Impact of Polymers on UV and/or Blue Light Absorption; Determination of Sun Protection Factor (SPF) Preparation of the tested mixtures Different test mixtures (“SPF 30 Base Formulae”) each containing 1.0 wt.-% of polymer were prepared as depicted in Table 2 below. Table 2. Tested mixtures (“SPF 30 Base Formulae”) Phase Ingredient INCI % Bis-Ethylhexyloxyphenol Methoxyphenyl A Eclipsogen Sorb S Triazine 2.0 Eclipsogen AVB Butyl Methoxydibenzoyl-methane 4.0 Eclipsogen EHMC Ethylhexyl Methoxycinnamate 10.0 Neo Heliopan 303 Octocrylene 3.0 Hostaphat KW 340 D Triceteareth-4 Phosphate 3.0 Cithrol GMS Glyceryl Stearate 2.0 Crodamol AB C12-C15 Alkyl Benzoate 10.0 B Water Aqua 59.0 Genapol G 260 Glycereth-26 5.0 C Polymer - 1.0 Nipaguard SCP Sorbitan Caprylate (and) Phenoxyethanol 1.0 Total 100.0
Phase A was combined at 80 °C while stirring. Phase B was mixed well and heated at 80 °C. Subsequently, phase B was added into phase A and the mixture was stirred thoroughly for 5 min at 400 rpm. Phase C was added to the mixture of phases A and B and the obtained mixture was homogenized for 2 min at 140000 rpm. The obtained “SPF 30 Base Formula” was cooled to room temperature. Different polymers were used in the test mixtures (“SPF 30 Base Formulae”). These are specified in the context of the results in Table 3 below. In vitro testing (SPF measurement) Materials and methods: A Labsphere® UV-2000 S Transmittance analyzer was used in the determination of the diffuse transmission spectrum of UV radiation through the substrate before and after application of the sunscreen. A poly(methyl methacrylate) (PMMA) plate was used to obtain the blank transmittance spectrum from 290 to 400 nm. A tested mixture (“SPF 30 Base Formula”) as described above was used as sunscreen product. It was spread over the whole surface by means of light strokes with a fingertip. The sample was allowed to settle for 15 min in the dark at room temperature to ensure a leveling of the formula. A total of 9 UV transmission spectra (from 290 to 400 nm, 1-nm increment steps) were recorded on each plate at different locations. Results: The results obtained for the tested mixtures (“SPF 30 Base Formulae”) as laid out before depending on various polymers are given in the table below. Table 3. Results of in vitro testing (SPF measurement) No. Polymer INCI SPF value C1 No Polymer - 15.64
C2 Carbopol 980 Carbomer 23.79 Plantasens C3 Caesalpinia Spinosa Gum 23.84 Biogum Tara C4 Xanthan gum Xanthan gum 24.81 Caesalpinia Spinosa Gum/Ammonium Exp.1 Aristoflex Eco T 42.72 AMPS Crosspolymer C1-C4 are comparative experiments, Exp.1 is according to the present invention. It was surprisingly found that polymers according to the present invention show particularly high increase of UV and/or blue light absorption when combined with UV and/or blue light filters. Application Examples Potential compositions that may be used as sun protection compositions are exemplified in the following tables. Application Example 1 – Sun cream Phase Ingredient INCI Function Wt.-% A Water Aqua Diluent ad 100 Glycerin Glycerin Humectant 3.00 Eclipsogen® Phenylbenzimidazole PBSA Sulfonic Acid) UV filter 2.00 Sodium Sodium Hydroxide pH A q.s. to Hydroxide djuster pH 7 Host ® B aphat KL 340 D Trilaureth-4 Phosphate Emulsifier 0.75 Lanette O Cetearyl Alcohol Stabilizer 2.25 Plantasens® Squalane Squalane Emollient 4.00 Plantasens® Pro Lauryl/ Myristyl LM Polyricinoleate (and) Emollient 2.00 Glycerin Eclipsogen® Bis-Ethylhexyloxyphenol Sorb S Methoxyphenyl Triazine UV filter 8.00 Eclipsogen® OC Octocrylene UV filter 9.00
Eclipsogen® EHT Ethylhexyl Triazone UV filter 7.00 Caesalpinia Spinosa C Aristoflex® Eco T Gum/Ammonium AMPS Polymer 1.50 Crosspolymer D Nipaguard® PO5 Phenoxyethanol (and) Piroctone Olamine Preservative 1.00 Fragrance Fragrance Fragrance 0.30 Application Example 2 – Light Sunscreen Cream Phase Ingredient INCI Function Wt.-% A Water Aqua Diluent ad 100 Eclipsogen PBSA Phenylbenzimidazole Sulfonic Acid UV filter 2.50 Sodium Hydroxide Sodium Hydroxide pH Adjuster 3.20 B Glycerin (85%) Glycerin Humectant 3.00 Caesalpinia Spinosa C Aristoflex® Eco T Gum/Ammonium AMPS Polymer 0.70 Crosspolymer D Hostaphat KW 340 D Triceteareth-4 Phosphate Emulsifier 1.20 Lanette O Cetearyl Alcohol Stabilizer 1.80 Hydrogenated Ethylhexyl Plantasens Olive Olivate (and) LD Hydrogenated Emollient 2.00 Olive Oil Unsaponifiables Cetiol 88 Ethylhexyl Stearate Emollient 7.00 Cetiol V Decyl Oleate Emollient 5.00 Eclipsogen® OC Octocrylene UV filter 4.50 Eclipsogen® AVB Butyl Methoxydibenzoylmethane UV filter 4.00 Neo Heliopan OS Ethylhexyl Salicylate UV filter 4.50 Neo Heliopan HMS Homosalate UV filter 5.00 E Nipaguard PO5 Phenoxyethanol (and) Piroctone Olamine Preservative 1.00 Fragrance Fragrance Fragrance 0.30 Application Example 3 – Sunscreen Phase Ingredient INCI Function Wt.-% A Eutanol G Octyldodecanol Emollient 8.00
Eclipsogen® EHMC Ethylhexyl UV filter Methoxycinnamate 6.00 Eclipsogen ® OC Octocrylene UV filter 5.00 Eclipsogen® AVB Butyl UV filter Methoxydibenzoylmethane 2.00 Lanette® O Cetearyl Alcohol Emulsifier 1.50 Phenoxyethanol, Methylparaben, Phenonip® Ethylparaben, Preservative 1.20 Propylparaben, Isobutylparaben Caesalpinia Spinosa B Aristoflex® Eco T Gum/Ammonium AMPS Polymer 0.40 Crosspolymer C Water Water Diluent ad 100 Glycerin Glycerin Humectant 5.00 D Tocopheryl Acetate Tocopheryl Acetate Antioxidant 4.50 Application Example 4 – Sunscreen Lotion with TiO2 Phase Ingredient INCI Function Wt.-% Hostap ® A hat KL 340 D Trilaureth-4 Phosphate Emulsifier 1.50 Octyldodecanol Octyldodecanol Emollient 9.00 Neo Heliopan OS Ethylhexyl Salicylate UV filter 4.50 Eclipsogen® AVB Butyl UV filter Methoxydibenzoylmethane 4.50 Neo Heliopan UV fi HMS Homosalate lter 9.00 Lanette O Cetearyl Alcohol Stabilizer 0.40 Dimethicone, 50 cS Dimethicone Emollient 4.00 Titanium Dioxide Titanium Dioxide UV filter 1.00 Crodamol AB C12-15 Alkyl Benzoate Emollient 3.00 Cetereth-2 Cetereth-2 Emollient 0.80 Phenoxyethanol, Methylparaben, Phenonip® Ethylparaben, Preservative 0.60 Propylparaben, Isobutylparaben B Water Water Solvent 30.00
Amphisol K Potassium Cetyl Phosphate Emulsifier 1.50 Caesalpinia Spinosa C Aristoflex® Eco T Gum/Ammonium AMPS Polymer 0.30 Crosspolymer D Water Water Diluent ad 100 Glycerin (85%) Glycerin Humectant 4.00
Claims
Claims 1. Use of a polymer comprising: (i) one or more synthetic polymer units comprising: (a) repeating units of a structure of Formula (1):
wherein R1 and R2 are independently selected from H, methyl or ethyl; A is a linear or branched C1-C12-alkyl group; and Q+ is a cosmetically acceptable cation; and (b) optionally one or more crosslinking or branching units; and (c) optionally one or more further repeating units which are different from a repeating unit of structure of Formula (1) and from the crosslinking or branching units crosslinking or branching units; and (ii) one or more water-soluble and/or water-swellable polysaccharide polymer units, for increasing the UV and/or blue light absorption of one or more UV and/or blue light filters. 2. The use according to claim 1, wherein Q+ is H+, NH4 +, an organic ammonium ion [NHR5R6R7]+ wherein R5, R6, and R7 independently of one another is hydrogen, a linear or branched alkyl group having 1 to 22 carbon atoms, a linear or branched, mono- or poly-unsaturated alkenyl group having 2 to 22 carbon atoms, a C6-C22 alkylamidopropyl group, a linear mono-hydroxyalkyl group having 2 to 10 carbon atoms or a linear or branched dihydroxyalkyl group having 3 to 15 carbon atoms, and wherein at
least one of the radicals R5, R6, and R7 is not hydrogen, or Q+ is Li+, Na+, K+, ½ Ca++, ½ Mg++, ½ Zn++, 1/3 Al+++, or combinations thereof. 3. The use according to claim 1 or 2, wherein the repeating units according to Formula (1) result from the incorporation of a monomer selected from the group consisting of acryloyldimethyltaurates, acryloyl-1,1-dimethyl-2- methyltaurates, acryloyltaurates, acryloyl-N-methyltaurates, and salts and combinations thereof, in particular wherein the repeating units according to Formula (1) result from the incorporation of acryloyldimethyltaurate or a salt thereof. 4. The use according to any of claims 1 to 3, wherein the water-soluble and/or water-swellable polysaccharide polymer unit is selected from the group consisting of chitosan, xanthan gum, fenugreek gum, tara gum, locust bean gum, carrageenan, guar gum, alginate, agar, gum tragacanth, tamarind kernel gum, gum arabica, cherry gum, gum karaya, okra gum, cassia gum, chicle gum, konjac gum glucomannan, gum ghatti, pectin, sclerotium gum, gellan gum, Tamarindus indica seed gum, sclerotium gum, dextran, dextrin, starch, derivatives thereof, and combinations thereof, preferably wherein the water-soluble and/or water-swellable polysaccharide polymer unit is an uncharged polysaccharide polymer unit, preferably wherein the polysaccharide polymer unit is selected from the group consisting of tara gum, guar gum, locust bean gum, cassia gum, fenugreek gum, glucomannan, Tamarindus indica seed gum, sclerotium gum, dextran, dextrin, xanthan gum, starch, and combinations thereof, preferably from the group consisting of tara gum, guar gum, glucomannan, and combinations thereof, in particular is selected from the group consisting of tara gum, guar gum, and combinations thereof. 5. The use according to any of claims 1 to 4, wherein the structure of the hybrid polymer is such that a polysaccharide polymer unit is a backbone onto which one or more synthetic polymer units are grafted.
6. The use according to any of claims 1 to 5, wherein the polymer comprises crosslinking or branching units resulting from the incorporation of a monomer according to any of the following structures or a salt or combination thereof: (I) Formula (2):
wherein R1 is independently selected from H, methyl or ethyl; and R2 is a linear or branched alkylene group having 1 to 6 carbon atoms, or is a linear or branched, mono- or polyunsaturated alkenylene group having 2 to 6 carbon atoms; or (II) Formula (3):
wherein R1 is independently selected from H, methyl or ethyl; and R2 is H, or is a linear or branched alkyl group having 1 to 6 carbon atoms, or is a linear or branched, mono- or polyunsaturated alkylene group having 2 to 6 carbon atoms; D, E, and F are independently methyleneoxy (-CH2O-), ethyleneoxy (-CH2- CH2-O-), propyleneoxy (-CH(CH3)-CH2-O-), a linear or branched alkylene
group having 1 to 6 carbon atoms, a linear or branched, singularly or multiply unsaturated alkenylene group having 2 to 6 carbon atoms, a linear mono- hydroxyalkylene group having 2 to 6 carbon atoms or a linear or branched dihydroxyalkylene group having 3 to 6 carbon atoms; and o, p and q each independently are an integer from 1 to 50, preferably wherein the crosslinking or branching units result from the incorporation of a crosslinker selected from the group consisting of methylenebisacrylamide; methylenebismethacrylamide; esters of unsaturated monocarboxylic and polycarboxylic acids with polyols, preferably di-acrylates and tri-acrylates and -methacrylates (e.g. glycerol propoxylate triacrylate [GPTA]), more preferably butanediol and ethylene glycol diacrylate and -methacrylate, trimethylolpropane triacrylate (TMPTA) and trimethylolpropane trimethacrylate (TMPTMA); allyl compounds, preferably allyl (meth)acrylate, triallyl cyanurate, diallyl maleate, polyallyl esters, tetraallyloxyethane, triallylamine, tetraallylethylenediamine; allyl esters of phosphoric acid, vinylphosphonic acid derivatives, and salts and combinations thereof. 7. The use according to any of claims 1 to 6, wherein the polymer has a biodegradability of at least 30%, preferably at least 60%, more preferably at least 70%, particularly preferably at least 80%, determined according to OECD Method 301 B. 8. The use according to any of claims 1 to 7, wherein the polymer comprises: (i) from 1 wt.-% to 95 wt.-%, preferably from 5 wt.-% to 70 wt.-%, more preferably from 5 wt.-% to 60 wt.-%, even more preferably from 10 wt.-% to 50 wt.-%, even more preferably from 15 wt.-% to 40 wt.-%, even more preferably from 20 wt.-% to 40 wt.-%, in particular from 25 wt.-% to 40 wt.-%, relative to the total mass of the polymer, of a synthetic polymer unit, comprising: (a) from 40 wt.-% to 99.9 wt.-%, preferably from 80 wt.-% to 99.9 wt.-%, in particular from 96 wt.-% to 99.9 wt.-%, relative to the
total mass of the synthetic polymer unit, of one or more repeating units of a structure of Formula (1); (b) from 0.01 wt.-% to 10 wt.-%, preferably from 0.01 wt.-% to 5 wt.-%, in particular from 0.01 wt.-% to 3 wt.-%, relative to the total mass of the synthetic polymer unit, of one or more crosslinking or branching units; and (c) from 0 wt.-% to 60 wt.-%, preferably from 0 wt.-% to 20 wt.-%, in particular from 0 wt.-% to 1 wt.-%, relative to the total mass of the synthetic polymer unit, of one or more repeating neutral structural units; and (ii) from 5 wt.-% to 99 wt.-%, preferably from 30 wt.-% to 95 wt.-%, more preferably from 40 wt.-% to 95 wt.-%, even more preferably from 50 wt.-% to 90 wt.-%, even more preferably from 60 wt.-% to 85 wt.-%, even more preferably from 60 wt.-% to 80 wt.-%, in particular from 60 wt.-% to 75 wt.-%, relative to the total mass of the polymer, of a water-soluble and/or water-swellable polysaccharide polymer unit. 9. The use according to any of claims 1 to 8, wherein the crosslinking or branching units result from the incorporation of a monomer comprising at least two olefinically unsaturated double bonds. 10. The use according to any of claims 1 to 9, wherein the polymer is obtained by radical precipitation polymerization, preferably in a polar solvent, in particular wherein the radical precipitation polymerization is carried out in a polar solvent mixture comprising water and a further compound. 11. The use according to any of claims 1 to 10, wherein at least one of the one or more UV and/or blue light filters is selected from the group consisting of anthranilates, cinnamic derivatives, dibenzoylmethane derivatives, salicylic derivatives, camphor derivatives, triazine derivatives, benzophenone derivatives, beta,beta’-diphenylacrylate derivatives, benzotriazole derivatives, benzalmalonate derivatives, benzimidazole derivatives, imidazolines, bis-benzazolyl derivatives, p-aminobenzoic acid (PABA)
derivatives, benzothiazine derivatives, screening polymers and screening silicones, alpha-alkylstyrene-based dimers, 4,4-diarylbutadienes, methoxypropylamino cyclohexanylidene ethoxycyanoacetate, methoxypropylamino cyclohexenylidene ethoxyethylcyanoacetate, ethyl 9- oxo-9H-thioxanthene-2-carboxylate, sun protecting peptides, titanium dioxide, zinc oxide, iron oxide, and mixtures thereof. 12. The use according to any of claims 1 to 11, wherein the one or more UV and/or blue light filters are selected from the group consisting of: 4-Aminobenzoic acid (PABA, p-aminobenzoic acid), Polyoxyethylene ethyl-4-aminobenzoate (PEG-25 PABA, Ethoxylated Ethyl- 4-Aminobenzoate), 2-Ethylhexyl 4-(dimethylamino)benzoate (Ethylhexyl Dimethyl PABA, Padimate O, 4- dimethyl aminobenzic acid-2-ethylhexylester), Methyl N,N,N-trimethyl-4-[(4,7,7-trimethyl-3-oxobicyclo[2.2.1]hept-2- ylidene)methyl]anilinium Sulphate (Camphor benzalkonium methosulfate, 4- [(2-Oxo-3-bornylidene)methyl]phenyltrimethylammonium methyl sulfate), (1,4-Phenylenebis{(E)methylylidene[(3E)-7,7-dimethyl-2- oxobicyclo[2.2.1]hept-1-yl-3-ylidene]})dimethanesulfonic acid and its salts (Terephthalylidene Dicamphor Sulfonic Acid, Ecamsule, 3,3'-(1,4- phenylenedimethylene)bis[7,7-dimethyl-2-oxo-bicyclo[2.2.1]heptane-1- methanesulfonic Acid] ), 1,7,7-trimethyl-3-(phenylmethylene)bicyclo[2.2.1]heptan-2-one and its salts (3-benzylidene Camphor sulfonic acid), polymer of N-{(2 and 4)-[(2-Oxoborn-3-ylidine)methyl]benzyl}acrylamide (Polyacrylamidomethyl Benzylidene Camphor), 3-Benzylidene-1,7,7-trimethylbicyclo[2.2.1]heptan-2-one (3-benzylidene camphor, 1,7,7-trimethyl-3-(phenylmethylene)bicyclo[2.2.1]heptan-2-one 3(4'-methylbenzyliden)-D,L-camphor), (3E)-1,7,7-Trimethyl-3-(4-methylbenzylidene)bicyclo[2.2.1]heptan-2-one (4- Methylbenzylidene Camphor, Enzacamene), 3,3,5-Trimethylcyclohexyl salicylate (Homosalate), 3-Octanyl salicylate (Ethylhexyl Salicylate, Octisalate),
2-ethylhexyl 4-methoxycinnamate (Ethylhexyl methoxycinnamate, Octinoxate), 3-Methylbutyl (2E)-3-(4-methoxyphenyl)acrylate (Isoamyl 4- methoxycinnamate, Amiloxate, 4-methoxy-cinnamic acid-isoamylester), 4-(1,1,1,3,5,5,5-Heptamethyl-3-trisiloxanyl)-3-methylbutyl (2E)-3-(3,4,5- trimethoxyphenyl)acrylate (Isopentyl trimethoxycinnamate trisiloxane) 2-Ethoxyethyl (2E)-3-(4-methoxyphenyl)acrylate (Cinoxate, 2-Ethoxyethyl-p- methoxycinnamate), Mixture: Isopropyl p-methoxycinnamate + Ethyl diisopropylcinnamate + Methyl-2,4-diisopropylcinnamate 1-(4-Methoxyphenyl)-3-[4-(2-methyl-2-propanyl)phenyl]-1,3-propanedione (Butyl Methoxydibenzoylmethane, Avobenzone, 1-(4-tert-Butylphenyl)-3-(4- methoxyphenyl)propane-1,3-dione), Bis(2,4-dihydroxyphenyl)methanone (Benzophenone-2, 2,2',4,4'- tetrahydroxybenzophenone), (2-Hydroxy-4-methoxyphenyl)(phenyl)methanone (Benzophenone-3, Oxybenzone), 5-Benzoyl-4-hydroxy-2-methoxybenzenesulfonic acid (Benzophenone-4, Sulisobenzone), Benzenesulfonic Acid, 5-benzoyl-4-hydroxy-2-methoxy-, Monosodium Salt (Benzophenone-5, Sulisobenzone Sodium, hydroxy-4-methoxy- benzophenone-5 sulfonic acid and the sodium salt thereof), Bis(2-hydroxy-4-methoxyphenyl)methanone (Benzophenone-6, 2,2'- dihydroxy-4,4'-dimethoxybenzophenone), (2-Hydroxy-4-methoxyphenyl)(2-hydroxyphenyl)methanone (Benzophenone-8, Dioxybenzone, 2,2'-dihydroxy-4- methoxybenzophenone), Disodium 3,3'-carbonylbis(4-hydroxy-6-methoxybenzenesulfonate) (Benzophenone-9, Disodium 3,3'-carbonylbis[4-hydroxy-6- methoxybenzenesulphonate]), 4-(2-Beta-Glucopyranosiloxy)propoxy-2-/hydroxybenzophenone,
Hexyl 2-[4-(diethylamino)-2-hydroxybenzoyl]benzoate ( Diethylamino hydroxybenzoyl hexyl benzoate (DHHB), Benzoic Acid, 2-[4-(diethylamino)- 2-hydroxybenzoyl]-, Hexyl Ester), 2-Phenyl-1H-benzimidazole-5-sulfonic acid and potassium-, sodium- and triethanolamine salts there of (Phenylbenzimidazole sulphonic acid, Ensulizole), Disodium 2,2'-(1,4-phenylene)bis(6-sulfo-1H-benzimidazole-4-sulfonate) (Disodium Phenyl Dibenzimidazole Tetrasulfonate, Bisdisulizole Disodium, 1h-benzimidazole-4,6-disulfonic Acid, 2,2'-(1,4-phenylene)bis-, Disodium Salt), 2-Ethylhexyl 2-cyano-3,3-diphenylacrylate (Octocrylene, 2-Cyano-3,3- diphenylacrylic acid 2-ethylhexyl ester), 4,4'-[(6-[4-((1,1-dimethylethyl)-amino-carbonyl)phenylamino]-1,3,5-triazin- 2,4-yl)diimino]bis-(benzoic acid-2-ethylhexylester) – (Diethylhexyl butamido triazone, Iscotrizinol), 2,2'-[6-(4-Methoxyphenyl)-1,3,5-triazine-2,4-diyl]bis{5-[(2- ethylhexyl)oxy]phenol} (Bis-ethylhexyloxyphenol Methoxyphenyl Triazine, Bemotrizinol), 2,4,6-Tri(4-biphenylyl)-1,3,5-triazine (Tris-biphenyl triazine (nano)), 3,3′-(1,4-phenylene)bis(5,6-diphenyl-1,2,4-triazine) (Phenylene Bis- diphenyltriazine), Tris(2-ethylhexyl) 4,4',4''-(1,3,5-triazine-2,4,6-triyltriimino)tribenzoate ( Ethylhexyl Triazone, 2-(2H-benzotriazole-2-yl)-4-methyl-6-(2-methyl-3- (1,3,3,3-tetramethyl-1-(trimethylsilyloxy)-disiloxanyl)-propyl)phenol 2,4,6-tris- [p-(2-ethylhexyloxycarbonyl)anilino]-1,3,5-triazine), 2-(2H-Benzotriazol-2-yl)-6-[3-(1,1,1,3,5,5,5-heptamethyl-3-trisiloxanyl)-2- methylpropyl]-4-methylphenol (Drometrizole Trisiloxane, Silatrizole, Phenol,2-(2h-benzotriazol-2-yl)-4-methyl-6-(2-methyl-3-(1,3,3,3- tetramethyl-1-(trimethylsilyl)oxy)-disiloxanyl)propyl), 2,2'-methylene-bis-(6-(2h-benzotriazol-2-yl)-4-(1,1,3,3- tetramethylbutyl)phenol) (Methylene Bis-benzotriazolyl Tetramethylbutylphenol, Bisoctrizole, MBBT),
Siloxanes and silicones, dimethyl, 3-(4-(2,2- di(ethoxycarbonyl)ethenyl)phenoxy)propen-2-yl methyl, 3-(4-(2,2- di(ethoxycarbonyl)ethenyl)phenoxy)propen-1-yl methyl, trimethylsilyl terminated (Polysilicone-15, Dimethicodiethylbenzalmalonate), Menthyl Anthranilate, Meradimate Methoxypropylamino Cyclohexenylidene Ethoxyethylcyanoacetate, Titanium dioxide and Titanium dioxide TiO2 (nano), Zinc Oxide and Zinc oxide ZnO (nano), Iron Oxide, and combinations of two or more thereof, preferably wherein the one or more UV and/or blue light filters are selected from the group consisting of butyl methoxydibenzoylmethane, octocrylene, bis-ethylhexyloxyphenol methoxyphenyl triazine, ethylhexyl triazone, ethylhexyl salicylate, diethylamino hydroxybenzoyl hexyl benzoate, ethylhexyl methoxycinnamate, diethylhexyl butamido triazone, dometrizole trisiloxane, phenylbenzimidazole sulfonic acid, methylene bis-benzotriazolyl tetramethylbutylphenol, terephthalydidene dicamphor sulfonic acid, 4- methylbenzylidene camphor, polysilicone-15, isoamyl p-methoxycinnamate, disodium phenyl dibenzimidazole tetrasulfonate, tris-biphenyl triazine, phenylene bis-diphenyltriazine, homosalate, and combinations of two or more thereof. 13. The use according to any of claims 1 to 12, wherein the one or more UV and/or blue light filters are selected from the group consisting of: (A) an oil soluble organic UV absorber, preferably selected from the group consisting of Bis-Ethylhexyloxyphenol Methoxyphenyl Triazine Butyl, Methoxydibenzoylmethane, Ethylhexyl Methoxycinnamate, Octocrylene, Oxybenzone, Sulisobenzone, Diethylhexyl Butamido Triazone, Drometrizole Trisiloxane, Ethylhexyl Salicylate, Ethylhexyl Triazone, Homosalate, Octisalate, lsoamyl p-Methoxycinnamate, 4- Methylbenzylidene Camphor, Polysilicone-15, Diethylamino Hydroxy Benzoyl Hexyl Benzoate, Methoxypropylamino Cyclohexanylidene Ethoxyethylcyanoacetate, ethyl 9-oxo-9H-thioxanthene-2-carboxylate,
Diethylamino Hydroxybenzoyl Hexyl Benzoate, Ethyl Triazine, Benzyl Salicylate, Avobenzone, and mixtures thereof; (B) a sparingly soluble organic UV absorber, preferably selected from the group consisting of Methylene Bis-Benzotriazolyl Tetramethylbutylphenol, Tris-Biphenyl Triazine, Methanone, 1,1'-(1,4- piperazinediyl)bis[1-[2-[4-(diethylamino)-2-hydroxybenzoyl]phenyl]- methanone, and mixtures thereof; (C) an inorganic UV absorber, preferably selected from the group consisting of titanium oxide, zinc oxide, iron oxide, and mixtures thereof; (D) a water soluble UV absorber, preferably selected from the group consisting of Phenylbenzimidazole Sulfonic Acid, Sulisobenzone- sodium salt, Benzylidene Camphor Sulfonic Acid, Camphor Benzalkonium Methosulfate, Cinoxate, Disodium Phenyl Dibenzylmidazole Tetrasulfonate, Terephthalylidene Dicamphor Sulfonic Acid, PABA, PEG-25 PABA and mixtures thereof; and salts and mixtures thereof, in particular the one or more UV and/or blue light filters are selected from the group consisting of Bis-Ethylhexyloxyphenol Methoxyphenyl Triazine, Ethylhexyl Methoxycinnamate, Octocrylene, Butyl Methoxydibenzoylmethane, Ethylhexyl Salicylate, Butylmethoxydibenzoylmethane, Phenylbenzimidazolesulfonic Acid, Terephthalylidenedicamphorsulfonic Acid, Benzophenone-3, Benzophenone-4, Benzophenone-5,4-ethylbenzylidenecamphor, Benzimidazilate, Anisotriazine, Ethylhexyl Triazone, Diethylhexyl Butamidotriazone, Drometrizole Trisiloxane, and salts and mixtures thereof. 14. The use according to any of claims 1 to 13, wherein the use is carried out in a cosmetic composition serving for sun protection, preferably a sunscreen, in particular a sunscreen lotion, sun cream, sunscreen gel, sun spray, or a sunblock. 15. A cosmetic composition comprising:
(A) 0.1 to 20 wt.-%, preferably 0.2 to 5 wt.-%, in particular 0.5 to 2.5 wt.-%, related to the total mass of the cosmetic composition, of one or more polymers comprising (or consisting of): (i) one or more synthetic polymer units comprising (or consisting of): (a) repeating units of a structure of Formula (1):
wherein R1 and R2 are independently selected from H, methyl or ethyl; A is a linear or branched C1-C12-alkyl group; and Q+ is a cosmetically acceptable cation; and (b) optionally one or more crosslinking or branching units; and (c) optionally one or more further repeating units which are different from a repeating unit of structure of Formula (1) and from the crosslinking or branching units crosslinking or branching units; and (ii) one or more water-soluble and/or water-swellable polysaccharide polymer units; (B) 0.1 to 50 wt.-%, preferably 1 to 40 wt.-%, in particular 5 to 20 wt.-% or 15 to 40 wt.-%, related to the total mass of the cosmetic composition, of one or more UV and/or blue light filters; (C) 10 to 80 wt.-%, preferably 20 to 70 wt.-%, in particular 30 to 60 wt.-%, related to the total mass of the cosmetic composition, of one or more cosmetically acceptable carriers; and
(D) 5 to 60 wt.-%, preferably 7.5 to 40 wt.-%, in particular 10 to 30 wt.-%, related to the total mass of the cosmetic composition, of one or more further cosmetically acceptable components different from (A) to (C).
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Citations (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2809971A (en) | 1955-11-22 | 1957-10-15 | Olin Mathieson | Heavy-metal derivatives of 1-hydroxy-2-pyridinethiones and method of preparing same |
| US3236733A (en) | 1963-09-05 | 1966-02-22 | Vanderbilt Co R T | Method of combatting dandruff with pyridinethiones metal salts detergent compositions |
| US3753196A (en) | 1971-10-05 | 1973-08-14 | Kulite Semiconductor Products | Transducers employing integral protective coatings and supports |
| US3761418A (en) | 1967-09-27 | 1973-09-25 | Procter & Gamble | Detergent compositions containing particle deposition enhancing agents |
| US4323683A (en) | 1980-02-07 | 1982-04-06 | The Procter & Gamble Company | Process for making pyridinethione salts |
| US4345080A (en) | 1980-02-07 | 1982-08-17 | The Procter & Gamble Company | Pyridinethione salts and hair care compositions |
| US4379753A (en) | 1980-02-07 | 1983-04-12 | The Procter & Gamble Company | Hair care compositions |
| US4470982A (en) | 1980-12-22 | 1984-09-11 | The Procter & Gamble Company | Shampoo compositions |
| US5104646A (en) | 1989-08-07 | 1992-04-14 | The Procter & Gamble Company | Vehicle systems for use in cosmetic compositions |
| EP1084696A1 (en) | 1999-09-16 | 2001-03-21 | L'oreal | Cosmetic composition containing at least a silicone/acrylate copolymer and at least a photoprotectant |
| US20040005279A1 (en) * | 2002-01-24 | 2004-01-08 | L'oreal | Composition containing a semi-crystalline polymer and methods of use |
| FR2885797B1 (en) * | 2005-05-17 | 2007-07-27 | Oreal | GELIFIED OIL PARTICLES COMPRISING AT LEAST ONE HYDROPHOBIC SOLAR FILTER |
| EP2105127A1 (en) | 2008-03-26 | 2009-09-30 | Bayer MaterialScience AG | Hair fixing composition |
| WO2010043588A1 (en) | 2008-10-17 | 2010-04-22 | Basf Se | Sunscreen and personal care compositions comprising a random terpolymer |
| US20100278763A1 (en) * | 2007-12-21 | 2010-11-04 | Clariant Finance (Bvi) Limited | Water-Soluble Or Water-Swellable Polymers On The Basis Of Salts Of Acryloyldimethyltaurine Acid Or The Derivatives Thereof, The Production Thereof And The Use Thereof As Thickener, Stabilizer And Consistency Agents |
| WO2013017262A1 (en) | 2011-08-04 | 2013-02-07 | Clariant International Ltd | Compositions comprising isosorbide monoesters and halogenated antimicrobial active substances |
| WO2019096961A1 (en) * | 2017-11-15 | 2019-05-23 | L'oreal | Composition comprising a uv-screening agent, an acrylic copolymer and an acrylamidomethylpropanesulfonic acid copolymer |
| WO2019096960A1 (en) | 2017-11-15 | 2019-05-23 | L'oreal | Compositions comprising at least one acrylic polymer and at least one insoluble organic screening agent |
| WO2023099681A1 (en) * | 2021-12-05 | 2023-06-08 | Clariant International Ltd | Water-soluble and/or water-swellable hybrid polymer |
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2024
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Patent Citations (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2809971A (en) | 1955-11-22 | 1957-10-15 | Olin Mathieson | Heavy-metal derivatives of 1-hydroxy-2-pyridinethiones and method of preparing same |
| US3236733A (en) | 1963-09-05 | 1966-02-22 | Vanderbilt Co R T | Method of combatting dandruff with pyridinethiones metal salts detergent compositions |
| US3761418A (en) | 1967-09-27 | 1973-09-25 | Procter & Gamble | Detergent compositions containing particle deposition enhancing agents |
| US3753196A (en) | 1971-10-05 | 1973-08-14 | Kulite Semiconductor Products | Transducers employing integral protective coatings and supports |
| US4323683A (en) | 1980-02-07 | 1982-04-06 | The Procter & Gamble Company | Process for making pyridinethione salts |
| US4345080A (en) | 1980-02-07 | 1982-08-17 | The Procter & Gamble Company | Pyridinethione salts and hair care compositions |
| US4379753A (en) | 1980-02-07 | 1983-04-12 | The Procter & Gamble Company | Hair care compositions |
| US4470982A (en) | 1980-12-22 | 1984-09-11 | The Procter & Gamble Company | Shampoo compositions |
| US5104646A (en) | 1989-08-07 | 1992-04-14 | The Procter & Gamble Company | Vehicle systems for use in cosmetic compositions |
| EP1084696A1 (en) | 1999-09-16 | 2001-03-21 | L'oreal | Cosmetic composition containing at least a silicone/acrylate copolymer and at least a photoprotectant |
| US20040005279A1 (en) * | 2002-01-24 | 2004-01-08 | L'oreal | Composition containing a semi-crystalline polymer and methods of use |
| FR2885797B1 (en) * | 2005-05-17 | 2007-07-27 | Oreal | GELIFIED OIL PARTICLES COMPRISING AT LEAST ONE HYDROPHOBIC SOLAR FILTER |
| US20100278763A1 (en) * | 2007-12-21 | 2010-11-04 | Clariant Finance (Bvi) Limited | Water-Soluble Or Water-Swellable Polymers On The Basis Of Salts Of Acryloyldimethyltaurine Acid Or The Derivatives Thereof, The Production Thereof And The Use Thereof As Thickener, Stabilizer And Consistency Agents |
| EP2105127A1 (en) | 2008-03-26 | 2009-09-30 | Bayer MaterialScience AG | Hair fixing composition |
| WO2010043588A1 (en) | 2008-10-17 | 2010-04-22 | Basf Se | Sunscreen and personal care compositions comprising a random terpolymer |
| WO2013017262A1 (en) | 2011-08-04 | 2013-02-07 | Clariant International Ltd | Compositions comprising isosorbide monoesters and halogenated antimicrobial active substances |
| WO2019096961A1 (en) * | 2017-11-15 | 2019-05-23 | L'oreal | Composition comprising a uv-screening agent, an acrylic copolymer and an acrylamidomethylpropanesulfonic acid copolymer |
| WO2019096960A1 (en) | 2017-11-15 | 2019-05-23 | L'oreal | Compositions comprising at least one acrylic polymer and at least one insoluble organic screening agent |
| WO2023099681A1 (en) * | 2021-12-05 | 2023-06-08 | Clariant International Ltd | Water-soluble and/or water-swellable hybrid polymer |
Non-Patent Citations (4)
| Title |
|---|
| "CTFA Cosmetic Ingredient Handbook", 1992 |
| "International Cosmetic Ingredient Dictionary and Handbook" |
| "International Cosmetic Ingredient Dictionary", 1993 |
| MASSAO KUNIOKA, RADIOISOTOPES, vol. 62, 2013, pages 901 - 925 |
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