WO2024117138A1 - Production method for airbag having enhanced internal-pressure retaining performance - Google Patents

Production method for airbag having enhanced internal-pressure retaining performance Download PDF

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Publication number
WO2024117138A1
WO2024117138A1 PCT/JP2023/042592 JP2023042592W WO2024117138A1 WO 2024117138 A1 WO2024117138 A1 WO 2024117138A1 JP 2023042592 W JP2023042592 W JP 2023042592W WO 2024117138 A1 WO2024117138 A1 WO 2024117138A1
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Prior art keywords
base fabric
film
airbag
protective material
fabric panels
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PCT/JP2023/042592
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French (fr)
Japanese (ja)
Inventor
拓海 壁谷
達夫 田中
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旭化成株式会社
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Publication of WO2024117138A1 publication Critical patent/WO2024117138A1/en

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B60VEHICLES IN GENERAL
    • B60RVEHICLES, VEHICLE FITTINGS, OR VEHICLE PARTS, NOT OTHERWISE PROVIDED FOR
    • B60R21/00Arrangements or fittings on vehicles for protecting or preventing injuries to occupants or pedestrians in case of accidents or other traffic risks
    • B60R21/02Occupant safety arrangements or fittings, e.g. crash pads
    • B60R21/16Inflatable occupant restraints or confinements designed to inflate upon impact or impending impact, e.g. air bags
    • B60R21/23Inflatable members
    • B60R21/231Inflatable members characterised by their shape, construction or spatial configuration

Definitions

  • the present invention relates to a method for manufacturing an airbag used in an airbag device mounted on a vehicle. More specifically, the present invention relates to a method for manufacturing an airbag in which the outer edges of a pair of base fabric panels are sewn together, and which has improved internal pressure retention performance.
  • airbags used in airbag devices mounted on vehicles are made by sewing (stitching) the outer edges of a pair of base fabric panels together to form a bag-like shape, into which gas is instantly injected to inflate and deploy.
  • sewing is usually done using sewing thread, gas leakage between the pair of base fabric panels and through the holes in the sewing needle is unavoidable.
  • Airbags absorb impacts on the human body by retaining injected gas.
  • DABs meet performance requirements if they can handle instantaneous impacts (first impacts).
  • CABs must maintain the inflated state of the airbag even during the rotation (rollover) of the vehicle after the first impact, and are required to maintain a constant pressure (e.g., 30 kPa) or higher (i.e., internal pressure maintenance) within the airbag for a long period of time (e.g., six seconds).
  • a constant pressure e.g. 30 kPa
  • internal pressure maintenance i.e., internal pressure maintenance
  • pedestrian airbags require internal pressure maintenance for a longer period of time than DABs, because the timing at which a pedestrian lands on the bonnet and hits the vehicle body (e.g., the pillar section) varies.
  • One method is to bond the outer edges of a pair of base fabric panels with only an adhesive instead of sewing. Although this method can prevent gas leakage, there is a risk that the adhesive will not be able to withstand the strength required for the airbag to deploy because there is no sewing.
  • Another method is to manufacture a pair of base fabric panels using the One Piece Woven method and then coat the outside of the base fabric.
  • This method there are no stitching and the coating means there is no problem with airtightness, and there are no problems with strength either, but it is difficult to create complex shapes, the coating needs to be applied relatively thickly, and this tends to increase the weight of the airbag, and it is also expensive.
  • Another method is to bond the outer edges of a pair of base fabric panels with a silicone adhesive and then sew the bonded portion.
  • This method can ensure strength while suppressing gas leakage, but it has problems such as low productivity, thick bonded portions, and poor folding and storage properties of the airbag.
  • the weight of the silicone adhesive increases the weight of the airbag. As illustrated in FIG. 2, in this method, the silicone adhesive stretches during airbag deployment, preventing gas from accessing the stitching.
  • silicone adhesives are suitable for such applications because of their high adhesive strength with base fabric panels, but the adhesive takes half a day to about a day to harden, resulting in low productivity, and for example, the folded thickness of a pair of base fabric panels is 2.2 mm at the location where there is no adhesive (location where internal pressure does not need to be maintained), whereas the folded thickness at the location where there is adhesive and stitching is 5.2 mm, resulting in a lack of compactness (foldability, storability). Furthermore, silicone adhesives must be separated from the airbag fabric when recycled, and they emit a relatively large amount of GHG (Green House Gas) during production, so they are not environmentally friendly in the manufacture and disposal of airbags.
  • GHG Green House Gas
  • Patent Document 1 describes an airbag device having a protective cloth sewn along a seam where a pair of opposing portions of a base fabric are sewn together, at a position away from the seam so as to cover the seam from the inside where gas from the inflator is introduced (see Figures 2 and 7 of the same document).
  • Patent Document 1 discloses a protective material for the seam, but this protective material is fixed to the base fabric by sewing, not by adhesion. The purpose of this protective material is to prevent the seam from being directly exposed to the high-pressure gas from the inflator and being destroyed, and to distribute tension in the protective material's seam to prevent damage to the seam of the pair of base fabrics, but is not intended to maintain internal pressure without damaging the seam.
  • Patent Document 2 discloses an airbag having walls including a laminate material, the laminate material including a backing layer having a breathable sheet-like structure made of a woven or knitted fabric, at least two layers of coextruded polymer film, a first polymer layer having a predetermined glass transition temperature on the backing layer side, and a second polymer layer having a predetermined storage modulus on the opposite side to the backing layer, the airbag having walls bonded together such that the second polymer layer is bonded at the edge of the airbag, and a manufacturing method for bonding the first polymer layer and the second polymer layer by applying different thermal energies to them.
  • 5,399,633 is to provide an airbag which can be produced at low cost and which is easy and reliable to seal (see Figs. 1-3 of the same document).
  • Patent Document 2 does not disclose any protective material for the seams of the airbag, and the manufacturing method therefor is primarily intended to increase productivity, not to maintain internal pressure.
  • Patent Document 3 describes an airbag in which panels are joined together at joints, the panels having a woven fabric and a synthetic resin film bonded to the woven fabric via an adhesive, the panels are joined together by pressurizing and heating with a hot melt adhesive sheet interposed between the panels, and the synthetic resin film is disposed on the outside of the airbag.
  • the object of the invention described in Patent Document 3 is to provide an airbag in which the strength of the seams between the panels is high, the durability is excellent, gas leakage is prevented, and handling is easy (see Figures 3 and 4).
  • Patent Document 3 does not describe a method for preventing gas leakage from stitching holes due to stress being applied to the joints between the panels when the adhesive surface around the outer periphery of the airbag is stressed during deployment, which may cause the adhesive to break.Furthermore, there is no mention of the technical idea of adhering a protective material for the stitching to the base fabric at a location separate from the stitching, and maintaining the adhesion between the protective material and the base fabric to maintain the internal pressure.
  • the problem that the present invention aims to solve is to provide a highly productive method for manufacturing an airbag in which a pair of base fabric panels are sewn together at their outer periphery to form a bag body, in which an airtight structure is formed by bonding both outer surfaces of a half-folded, strip-shaped, non-breathable protective material to the inner surface of each of the pair of base fabric panels in a bonding region of a predetermined width along the stitching from near the stitching toward the inside of the bag body, the bonding region having a proximal end and a distal end, and which maintains this structure even when the airbag is deployed, thereby improving the internal pressure retention performance, and providing a low-cost, highly productive, and highly compact airbag manufacturing method.
  • the present invention is as follows.
  • a method for manufacturing an airbag having at least one pair of base fabric panels sewn together at their outer periphery comprising the steps of: a welding step of continuously sandwiching a semi-folded, band-shaped non-breathable film-like protective material, which is made of a monolayer resin film having a predetermined width with a release paper sandwiched therebetween or a laminated resin film having two or more layers including a first surface layer and a second surface layer, between the inner surfaces of the pair of base fabric panels while applying tension to the material along the linear or curved outer periphery of the pair of base fabric panels, and applying heat or ultrasonic waves from the outside of the pair of base fabric panels to weld a surface of the monolayer resin film or the first surface layer to the inner surface of the base fabric panel in an adhesive region of a predetermined width, wherein although the surfaces of the monolayer resin film on the release paper side are not welded to each other due to the presence of the release paper, or the second surface layers of the laminated resin film are not welded
  • [3] A step of heating a part or the whole of the half-folded, band-shaped, non-breathable film-like protective material before a welding step of welding the half-folded, band-shaped, non-breathable film-like protective material;
  • the method according to any one of the above [1] to [3], [5] In the welding process of welding the half-folded band-shaped non-breathable film-like protective material, a process of heating and/or cooling a part or the whole of the half-folded band-shaped non-breathable film-like protective material while intermittently applying/releasing the pressure of a hot plate and/or a cold plate;
  • the method for manufacturing an airbag according to the present invention comprises bonding the outer surfaces of both ends of a folded, strip-shaped, non-breathable protective material to the inner surface of each of at least a pair of base fabric panels in bonding areas of a predetermined width along the seams, having proximal and distal ends from near the seams toward the inside of the bag, and when a tensile force is applied to the pair of base fabric panels when the airbag is deployed, substantially no tensile force is applied to the bonding areas, thereby maintaining an airtight structure.
  • this method for manufacturing an airbag has high internal pressure retention performance, is low cost, has high productivity, and is also highly compact. Therefore, the airbag and the manufacturing method thereof according to the present invention can be suitably used for automobile airbags, in particular for CABs and pedestrian airbags which require high internal pressure retention performance.
  • FIG. 1 is a plan view of an airbag in which a pair of base fabric panels are sewn together at their outer periphery to form a bag body, which can be manufactured by the manufacturing method of this embodiment.
  • 2 is an explanatory diagram of a state of an airbag when deployed, in a location corresponding to the cross section AA in FIG. 1, in which a portion bonded with a silicone adhesive is sewn.
  • FIG. FIG. 2 is an explanatory diagram of the state of a non-breathable protective material in an airbag that can be manufactured by the manufacturing method of this embodiment when the airbag is deployed.
  • 1 is an explanatory diagram showing the relationship between the resin constituting the first surface layer and the resin constituting the second surface layer of a laminated resin film which is a non-breathable film-like protective material folded in half.
  • FIG. 2 is an explanatory diagram of an example of a method for producing a half-folded non-breathable film-like protective material (winding up a half-folded film).
  • FIG. 13 is an explanatory diagram of a state in which a wound, half-folded non-breathable film-like protective material is supplied to a heat welding location.
  • FIG. 1 is a diagram explaining the supply state of a half-folded, strip-shaped, non-breathable film-like protective material, which is made of a single-layer resin film with a release paper of a predetermined width sandwiched between the inner surfaces of a pair of base fabric panels, or a laminated resin film of two or more layers including a first surface layer and a second surface layer, is continuously sandwiched along the straight or curved outer peripheral edge of the pair of base fabric panels while applying tension to the material, and then heat or ultrasound is applied from the outside of the pair of base fabric panels to weld the surface of the single-layer resin film or the first surface layer to the inner surface of the base fabric panels.
  • FIG. 1 is a diagram explaining the supply state of a half-folded, strip-shaped, non-breathable film-like protective material, which is made of a single-layer resin film with a release paper of a predetermined width sandwiched between the inner surfaces of a pair of base fabric panels, or a laminated resin film of two or more layers
  • FIG. 1 is an explanatory diagram of a method for winding a multi-layer film in a two-ply state around a 3-inch paper tube by an inflation method using a multi-layer circular die.
  • FIG. 2 is a schematic diagram of a jig (half-folding former) used to fold a film in half.
  • 1 is an explanatory diagram of an example of an airbag (cushion) including an isolated sewn portion (in the center) of a closed space.
  • 10 is an explanatory diagram of one method of adhering a folded film to an isolated sewn portion of a closed space.
  • FIG. FIG. 15 is an explanatory diagram of the sealing state according to the method 1 shown in FIG. 14 .
  • FIG. 13A and 13B are explanatory diagrams of another method for adhering a folded film to an isolated sewn portion of a closed space and a sealed state.
  • FIG. 2 is an explanatory diagram of the layer structure of a folded film in terms of the melting point difference (left side) and the interlayer SP value difference (right side).
  • An embodiment of the present invention is a method for manufacturing an airbag having at least one pair of fabric panels sewn together at a periphery thereof, the method comprising the steps of: a welding step of continuously sandwiching a semi-folded, band-shaped non-breathable film-like protective material, which is made of a monolayer resin film having a predetermined width with a release paper sandwiched therebetween or a laminated resin film having two or more layers including a first surface layer and a second surface layer, between the inner surfaces of the pair of base fabric panels while applying tension to the material along the linear or curved outer periphery of the pair of base fabric panels, and applying heat or ultrasonic waves from the outside of the pair of base fabric panels to weld a surface of the monolayer resin film or the first surface layer to the inner surface of the base fabric panel in an adhesive region of a predetermined width, wherein although the surfaces of the monolayer resin film on the release paper side are not
  • the pair of base fabric panels is not particularly limited and may be a plain weave fabric of polyamide or polyester that is normally used as a base fabric for airbags.
  • the fineness of the fibers constituting the base fabric used in this embodiment is preferably 150 to 900 dtex.
  • a fineness of 150 dtex or more can provide the strength required for an airbag, and a fineness of 900 dtex or less can provide a soft base fabric for an airbag.
  • the fiber When the fiber is in this range, it is flexible when used as a base fabric for an airbag and has a high deployment speed.
  • the weaving density of the base fabric used in this embodiment is preferably 30 to 90 threads/inch for both warp and weft, and the cover factor is preferably 1500 to 2500.
  • the base fabric panel may be coated with resin on one or both sides or laminated with a single or multi-layer film to reduce breathability.
  • the resin used for the resin coating may be a silicone or polyurethane coating, or a method of thermal lamination using a flame-retardant thermoplastic resin film, etc. may be used.
  • the coating amount is preferably 5 to 50 g/m 2.
  • the thickness of the film is preferably 0.001 mm or more and 0.5 mm or less. Within this range, a base fabric that is flexible and has excellent airtightness when used as a base fabric for an airbag can be obtained.
  • the airbag according to this embodiment can be one in which a pair of base fabric panels are sewn together at their outer periphery to form a bag, as shown in FIG. 1.
  • reference numeral 2 indicates the sewn (stitched) portion of the main panel
  • reference numeral 4' indicates the position of the inner edge (top of the loop) of a semi-folded non-breathable protective material, which is on the back side of the front base fabric panel and which will be described below.
  • an inner tube reference numeral 23
  • the stitching is not particularly limited as long as it is not broken when the airbag is inflated and deployed, but it is preferably machine-sewn with sewing thread made of multifilament fiber of the same material as the base fabric panel. As described above, in order to maintain the internal pressure, it is required that the stitching does not break when the airbag is deployed and that there is substantially no gas leakage.
  • the sewing thread may be a single twisted fiber or a multiple twisted fiber having two or more single twisted fibers twisted together, and the total fineness of the twisted fibers is preferably 700 to 2000 dtex.
  • the sewing method may be a lock stitch, a chain stitch, etc.
  • the number of stitches (stitch pitch) is preferably 30 to 60 stitches/10 cm.
  • Fig. 2 is an enlarged view of the area corresponding to the A-A cross section in Fig. 1 to prevent gas leakage at the seams, and explains the state of an airbag when it is deployed if it is sewn to the area bonded with silicone adhesive in the conventional technology.
  • silicone adhesive When silicone adhesive is used, the silicone adhesive deforms and stretches during deployment to seal in the gas, improving the internal pressure retention, but the thickness of the silicone adhesive after curing increases the thickness of the airbag after folding (when stored), making it difficult to store, and it takes a long time, from half a day to about a day, to cure, reducing the productivity of the airbag.
  • an airbag can be manufactured with high productivity in which both end outer surfaces of a folded, band-like, non-breathable film-like protective material are bonded to the inner surface of each of a pair of base fabric panels in an adhesive region of a predetermined width along the seam from the vicinity of the seam toward the inside of the bag body, the outer surfaces being bonded in a straight or curved line, the non-breathable film-like protective material being a laminated resin film of two or more layers including a first surface layer and a second surface layer, the first surface layer being welded to the base fabric panel, and the second surface layers being not bonded to each other, or being bonded to each other but causing the second surface layer to peel off when a tensile force is applied to the pair of base fabric panels when the airbag is deployed.
  • the length between the distal ends along the folded non-breathable film-like protective material is greater than or equal to the length between the distal ends along the pair of base fabric panels.
  • the manufacturing method of this embodiment can be used for the entire outer periphery of the airbag, or for a portion of the airbag.
  • a portion means, for example, 50% or more.
  • a manufacturing method using, for example, silicone adhesive for the stitching that may cause other gas leaks in the airbag can be selected in order to ensure airtightness for the entire airbag.
  • this characteristic structure can be applied to the vicinity of the stitching of any two (a pair) of base fabric panels of an airbag composed of at least two or more base fabric panels.
  • the pair of base fabric panels do not necessarily need to have the same shape, and as long as the airtightness of the adhesive area is not compromised, the pair of base fabric panels may be three-dimensionally sewn with different shapes of stitching lines.
  • an airbag formed by sewing at least one pair of fabric panels together at their outer periphery refers to an airbag in which the fabric panels are sewn together to form an inflation chamber for the airbag, and in which two or more fabric panels are sewn together at the outer periphery of the chamber. Therefore, the airbag is not limited to an airbag composed of only two fabric panels, which are made by overlapping two fabric panels of the same shape, as shown in Figures 1 and 13, and there is no limit to the number of fabric panels that make up the airbag or the overall structure of the airbag, as long as there is a portion where two or more fabric panels are joined together at the outer periphery of the chamber.
  • this broadly includes a single, line-symmetrical base fabric panel that is folded along the line of symmetry and the overlapping portions sewn together, a single, strip-shaped base fabric panel that is rolled into a tube and the overlapping portions sewn together, and three or more base fabric panels that are sewn together, that is, as long as the partial structure has a non-breathable protective material covering the sewn portions of the base fabric panels.
  • non-breathable refers to the surface property of a protective material that suppresses ventilation to a degree that does not significantly impair the airtightness of the airbag.
  • the amount of gas passing through the surface is preferably 0.5 L/ dm2 /min or less, more preferably 0.1 L/ dm2 /min or less, and even more preferably 0.05 L/ dm2 /min or less.
  • Fig. 3 illustrates the state of the semi-folded non-breathable protective material when the airbag is deployed.
  • the semi-folded non-breathable protective material presents a loop shape toward the inside of the airbag and forms an airtight structure in the bonded area with the base fabric panel, thereby exhibiting internal pressure retention.
  • the length between the distal ends along the folded non-breathable protective material is preferably greater than or equal to the length between the distal ends along a pair of base fabric panels when the airbag is deployed, thereby maintaining an airtight structure in the adhesive region.
  • the non-breathable film-like protective material has high extensibility, even if the length of the loop of the protective material before the airbag is deployed (when the airbag is housed) is approximately the same as or shorter than the adhesive distance along the base fabric panels, the non-breathable protective material is stretched by the tensile force applied when the airbag is deployed, and if the seam is destroyed first, substantially no force is applied to the adhesive region, resulting in the same result.
  • the state of the airbag when it is deployed can be simulated by, for example, using the following method. First, the stored airbag is taken out, a part of the protective material and the base fabric panel are cut, and the pair of base fabric panels are spread 180° as shown in the deployed state in Figures 4(a) and (b).
  • Figure 4(a) is the first pattern
  • Figure 4(b) is the second pattern (loop outside, film folded back and stored).
  • the length between the distal ends along the half-folded non-breathable protective material is greater than or equal to the length between the distal ends along the pair of base fabric panels, thereby maintaining an airtight structure in the adhesive region.
  • half-folded non-breathable film-like protective material includes not only a material that is half-folded when housed in an airbag, as shown in the upper part of Figures 4(a) and (b), i.e., a material made by folding a strip-shaped single-layer or multi-layer resin film or laminate base fabric in half, but also a material that is folded multiple times, such as into an accordion-like shape, or a material made by overlapping two strip-shaped (including curved) single-layer or multi-layer resin film or laminate base fabric and bonding one end with an adhesive or welding (i.e., a material made by laminating two sheets).
  • it is preferable to manufacture protective materials by continuously supplying half-folded strip-shaped films, etc., and heat welding them, as shown in Figures 8 to 10 and 12, rather than by laminating two sheets.
  • Such a band-shaped, semi-folded, non-breathable film-like protective material is adhered to the base fabric in a straight or curved manner along the seams.
  • two sheets of a band-shaped non-breathable film-like protective material are used, which are obtained by cutting a resin film into a desired shape, and the outer layers of one end (inner edge side) of the multilayer film are welded together (for example, in the case of a PE (second surface layer)-PA6/12 (first surface layer) multilayer film, a part of the second surface layer is peeled off and the first surface layers are welded together) along the inner edge so that the length from the outer edge is a predetermined length, for example, a width of 5 mm, or the sheets are bonded together with, for example, a cyanoacrylate-based instant adhesive (manufactured by Konishi Co., Ltd.) and thoroughly dried (that is, a method of bonding two protective materials cut into a base fabric panel shape (hors
  • the protective material by continuously supplying a band-shaped sheet of resin film folded in half and heat welding it while applying tension, as shown in FIGS. 8 to 10, rather than by manufacturing the protective material by a two-sheet bonding method.
  • the two-sheet lamination method requires cutting out the resin film along the sewing shape of the airbag, the use of a half-folded belt-shaped resin film can maximize the efficiency of film utilization, and can increase productivity because there is no need to bond the films together.
  • the non-breathable film-like protective material there are no particular limitations on the non-breathable film-like protective material, so long as it is not destroyed when the airbag is inflated and deployed, and single-layer or multi-layer resin films can be used. From the viewpoint of reducing the weight and compactness (ease of folding and storage) of the airbag, it is preferable to use single-layer or multi-layer resin films as the non-breathable protective material.
  • the adhesive strength can be increased by bonding the same type of single-layer or multi-layer resin film to a laminated base fabric panel, thereby improving the internal pressure retention of the airbag.
  • the same type of single-layer or multi-layer resin film (and substrate) used in the non-breathable protective material and the base fabric panel recyclability can be improved.
  • the term “bonding” includes bonding with an adhesive and welding with ultrasonic waves or heat.
  • the base fabric panel and the protective material can be bonded together by welding using heat or ultrasonic waves to form a bonded area that will not peel off even when the airbag is deployed and can maintain airtightness. Welding without using adhesives is preferable from the standpoint of thickness after folding, productivity, recycling, etc.
  • the term "bonded area (5, 5')" has a proximal end (6, 6') and a distal end (7, 7') with respect to the seam (2), respectively.
  • the proximal end (6, 6') may be located on the inside of the airbag from the seam (2) or on the outside of the airbag. In the latter case, the bonded area will extend to the seam allowance.
  • the loop structure of the non-breathable protective material folded in half in the adhesive region may be arranged so as to face the outer edge of the airbag (outside of the airbag).
  • the half-folded non-breathable protective material has a loop shape toward the inside of the airbag, and the length between the distal ends along the half-folded non-breathable protective material is greater than the length between the distal ends along a pair of base fabric panels, so that an airtight structure can be formed in the adhesive region with the base fabric panels as in the case of Fig. 4(a).
  • the loop structure of the non-breathable protective material in order to prevent the part that contributes to maintaining the internal pressure of the protective material from being damaged by sewing, it is preferable to arrange the loop structure of the non-breathable protective material so as to face the inside of the airbag.
  • the "bonded region" need only be bonded in such a way that it will not be destroyed or peeled off when the airbag inflates and deploys, and that it maintains airtightness and internal pressure retention.
  • the thickness of the non-breathable film-like protective material is preferably 0.001 mm or more and 0.5 mm or less, and more preferably 0.001 mm or more and 0.1 mm or less, from the viewpoint of the folded thickness.
  • the adhesive strength (peel strength) in the adhesive region between the base fabric panel and the non-breathable film-like protective material is preferably 1 N/cm or more, and more preferably 3 N/cm or more, from the viewpoint of airtightness. If the adhesive strength is 3 N/cm or more, the occurrence of leaks caused by the film peeling off from the panel base fabric due to the wind pressure of the gas when the airbag is deployed is significantly reduced.
  • the tensile modulus of the semi-folded band-shaped non-breathable protective material is preferably 100 to 800 MPa in both MD (machine direction) and TD (transverse direction), more preferably 150 to 600 MPa, and even more preferably 200 to 500 MPa.
  • the tensile modulus of the film referred to here is the measurement result when the band-shaped non-breathable film-like protective material is opened from the half-folded state and pulled.
  • the above tensile modulus (flexibility) makes it easy to form a curved structure to follow the curved parts (including R parts and reverse R parts) that are usually used in the main fabric of an airbag.
  • the film has good handleability (balance between ease of deformation at curved parts and handling of the film) due to moderate flexibility.
  • the tensile breaking strength of the film is preferably 10 to 100 MPa in both MD and TD from the viewpoint of durability, more preferably 15 to 80 MPa, and even more preferably 20 to 60 MPa.
  • the airbag of this embodiment may have, in the adhesive region, an R portion with a curvature radius of 300 mm or less and/or an inverse R portion with a curvature radius of 300 mm or less, as shown in FIG. 1 and FIG.
  • the R portion is a portion of the seam line along the outer periphery of the base fabric panel that is curved convexly toward the side other than the inflatable portion (chamber) of the airbag.
  • the X portion in FIG. 1 corresponds to this.
  • the reverse R portion is a portion of the seam line along the outer periphery of the base fabric panel that is curved convexly toward the inflatable portion (chamber) of the airbag.
  • the degree of wrinkles when the non-breathable protective material is adhered can be confirmed by measuring the step (peak-valley difference) between the wrinkled portion and the normal portion.
  • the step (peak-valley difference) between the wrinkled portion and the normal portion of such R portion is preferably 400 ⁇ m or less, more preferably 300 ⁇ m or less, even more preferably 200 ⁇ m or less, and even more preferably 100 ⁇ m or less.
  • the step between the wrinkled portion and the normal portion can be made small, thereby preventing stress concentration, suppressing gas leakage from the adhesive portion, and resulting in an airbag with excellent storage properties.
  • the ratio (R portion/straight portion) of the step (peak-valley difference) between the wrinkled portion and the normal portion of the R portion to the step (peak-valley difference) between the wrinkled portion and the normal portion of the approximately straight portion excluding the R portion is preferably 0.6 to 2.0, and more preferably 0.8 to 1.5.
  • the wrinkle step measurement was performed using a surface roughness measuring instrument (SURFTEST EXTREME SV-3000CNC) manufactured by Mitutoyo Corporation, and the wrinkled area and the surrounding normal area were measured in three-dimensional mode under the following measurement conditions.
  • An arbitrary cross-section extraction function was used in the obtained three-dimensional image to extract a cross-section that included the largest step area, and a baseline was drawn on the extracted cross-section (two-dimensional) connecting the start point and end point of the wrinkled area (step), and the maximum height from the baseline was determined.
  • a multilayer resin film is used as the half-folded belt-shaped protective material, and a release paper is not used, and the second surface layers on the inside of the loop are not bonded to each other or are welded by heat welding or ultrasonic welding, but when a tensile force is applied to the pair of base fabric panels when the airbag is deployed, the second surface layers are peeled off, which improves the productivity of the airbag in that the process of inserting and/or removing the release paper is not required, the consideration of the material and physical properties of the release paper and its handling are not required, and the tension can be easily adjusted.
  • Such a configuration can be achieved, for example, by setting the melting point of the resin constituting the first surface layer of the laminated resin film, which is a non-breathable film-like protective material folded in half, to be 50°C to 160°C, and preferably 60°C to 160°C, lower than the melting point of the resin constituting the second surface layer, so that the second surface layers on the inside of the loop are not welded to each other, or by setting the difference in SP value of the resin constituting the first surface layer, the resin constituting the second surface layer, and the resin constituting the other layer of the laminated resin film, which is a non-breathable film-like protective material folded in half, to be 2.0 [cal/ cm3 ) 1/2 ] or more between adjacent layers, so that delamination occurs between any of the layers, or the second surface layer delaminates from an adjacent layer.
  • the difference in SP value between any adjacent layers is preferably 2.0 [cal/ cm3 ) 1/2 ] or more, more preferably 2.5 [cal/ cm3 ) 1/2 ] or more, even more preferably 3.0 [cal/ cm3 ) 1/2 ] or more, and even more preferably 4.0 [cal/ cm3 ) 1/2 ] or more.
  • the melting point of PA6/12 is 128°C
  • that of TPEE is 216°C
  • that of PA6/66 is 194°C
  • that of PA12 elastomer is 176°C
  • that of PO acid-modified polyethylene
  • that of PE LDPE
  • the difference in melting point between the resin constituting the first surface layer and the resin constituting the second surface layer can be made 50°C or more.
  • the preferred range of the melting point difference is 50°C to 160°C, more preferably 60°C to 160°C, and even more preferably 80°C to 160°C.
  • the adhesive strength with the base fabric panel can be increased and the range of adhesion temperatures at which fusion between the second surfaces can be made difficult to occur can be widened, improving production stability.
  • the melting point difference 160°C or less for example, when producing a film by inflation molding, flow unevenness and melt tension are appropriately maintained, improving film formation stability.
  • the melting point of the resin constituting the protective material is preferably 90° C. or higher, more preferably 100° C. or higher, and even more preferably 110° C. or higher. By making the melting point 90° C. or higher, sufficient adhesive strength can be maintained even when the temperature inside the vehicle becomes high.
  • the SP value of PE is 8.1 [cal/cm 3 ) 1/2
  • the SP value of PA6/66 is 13.6 [cal/cm 3 ) 1/2
  • the SP value of PA6/12 is 13.6 [cal/cm 3 ) 1/2
  • the SP value of PET is 10.7 [cal/cm 3 ) 1/2 ]
  • PE (second surface layer)-PA6/66 release layer side of the first surface layer, which is a multilayer film)
  • PE (second surface layer, release layer)-PET (first surface layer) is used as the protective material
  • the difference in SP value with the PA base fabric or PET base fabric, respectively can be made 2.0 [cal/cm 3 ) 1/2 ] or more.
  • the first surface layer (fabric panel side) can be considered to be composed of an adhesive layer (PA6/12), while the second surface layer (inside the loop) can be considered to be composed of four layers including a release layer (PE), an intermediate layer (acid-modified PE), and a high melting point layer (PA6/66).
  • PA6/12 adhesive layer
  • PA6/12 adhesive layer
  • PA6/66 high melting point layer
  • the release effect can be achieved not only when the SP value difference between the high melting point layer (PA6/66) and the release layer (PE) is greater than or equal to 2.0 [cal/cm3)1/2], but also when the SP value difference between any of the adjacent layers constituting the first surface layer, the adhesive layer (PA6/12), the X layer (e.g., the intermediate layer (acid-modified PE)), and the high melting point layer (PA6/66), is greater than or equal to 2.0 [cal/ cm3 ) 1/2 .
  • the above-mentioned configuration based on the SP value difference is preferable to the above-mentioned configuration based on the melting point difference.
  • the reason for this is that the fusion (processing) temperature can be raised above the melting point of the film, making it possible to strengthen the adhesion between the base fabric panel and the film, and by increasing the processing speed, productivity can be improved.
  • the SP value (Hildebrand solubility parameter) is a physical property defined as the square root of the cohesive energy density, and indicates the solubility behavior of a solvent. Therefore, the inventors of this application used combinations with large differences in SP value as indicators for selecting the release layer.
  • the SP values of various resins are listed, for example, in "Guide to Various Standards and Usage: Plastic Material Test Methods, Comparisons, Evaluations, and Results” p. 32 (2nd edition, May 10, 2011) by Sangyo Gijutsu Center Co., Ltd., and a reference for calculating the SP value is "Practical Polymers for Engineers" by Kodansha, August 1, 1989.
  • HSP Hansen solubility parameter
  • the HSP value is also shown in the examples, but the peeling effect can be achieved by making the HSP value difference 1.0 (cal/ cm3 ) 1/2 or more.
  • HSP is a predicted value by Winmostar (V9.3.0) manufactured by CrossAbility Co., Ltd., and is calculated by the dispersion term ( ⁇ D), polarization term ( ⁇ P), and hydrogen bond term ( ⁇ H) between certain substances.
  • the HSP calculation for the copolymer composition is a value obtained by calculating the HSP of each homopolymer and multiplying it by the composition ratio (volume ratio) to obtain a total value.
  • the glass transition temperature (Tg) of the second surface layer (inside of the loop) is preferably 0°C or higher, more preferably 20°C or higher, and even more preferably 30°C or higher.
  • the upper limit of the glass transition temperature is 80°C or lower, more preferably 70°C or lower, and even more preferably 60°C or lower.
  • An airbag in which a pair of base fabric panels are sewn together at their outer periphery to form a bag body, An airbag can be provided with high productivity in which both end outer surfaces of a folded, band-like, non-breathable film-like protective material are bonded to the inner surface of each of the pair of base fabric panels in an adhesive region of a predetermined width along the seam from near the seam toward the inside of the bag body, the outer surfaces being bonded in a straight or curved line, the folded, non-breathable film-like protective material being a laminated resin film of two or more layers including a first surface layer and a second surface layer, the first surface layer being welded to the base fabric panel, and the second surface layers being not bonded to each other, or being bonded to each other but causing the second surface layer to peel off when a tensile force is applied to the pair of base fabric panels when the airbag is deployed.
  • the tensile modulus of the film is preferably 100 to 800 MPa in both MD (machine direction) and TD (transverse direction), more preferably 150 to 600 MPa, and even more preferably 200 to 500 MPa.
  • the tensile modulus of the film referred to here is the measurement result when the band-shaped non-air-permeable and breathable film-like protective material is opened from a half-folded state and pulled.
  • the above tensile modulus (flexibility) makes it easy to form a curved structure that fits the curved part that is usually used in the main fabric of an airbag.
  • the tensile modulus By setting the tensile modulus to 100 to 800 MPa, the film has a moderate flexibility and good handleability (balance between ease of deformation at curved parts and handling of the film).
  • the tensile breaking strength of the film is preferably 10 to 100 MPa in both MD and TD from the viewpoint of durability, more preferably 15 to 80 MPa, and even more preferably 20 to 60 MPa.
  • the tensile breaking strength is 100 MPa or less, the rigidity is suppressed and the film has good handling properties. Furthermore, when the band-shaped non-permeable and breathable film-like protective material is deformed to follow the curved outer peripheral edge by applying tension, it is preferable to use a thermoplastic resin film, since the film can be easily stretched by applying heat.
  • methods for sandwiching a strip-shaped non-breathable film-like protective material along the straight or curved outer peripheral edges of a pair of base fabric panels include a method of preparing a roll of half-folded film in advance and feeding the strip-shaped non-breathable film-like protective material from the wound roll to the welding point by heat welding or ultrasonic welding, as exemplified in Figures 8 to 10, a method of preparing a roll of the half-folded strip-shaped non-breathable film-like protective material in an unfolded state and feeding the strip-shaped non-breathable film-like protective material from the wound roll to the welding point by heat welding or ultrasonic welding, folding it in half during the process of feeding it to the welding point by heat welding or ultrasonic welding, and then feeding it to the welding point, and a method of folding in half a strip-shaped non-breathable film-like protective material that has been cut in advance to the length of the straight or curved outer peripheral edges of a pair of base fabric panels, and feeding it to the welding point
  • the pleats in the folded portion can be firmly fixed, and by continuously feeding the film from the wound roll, the folded portion of the film is less likely to shift, and warping (curling) of the folded film is suppressed (as the film structure is symmetrical between the top and bottom), which is expected to have the further effect of suppressing the occurrence of wrinkles (improving quality).
  • the method of applying tension to the half-folded film is not particularly limited, but for example, as shown in Figure 17, a method can be used in which the tape is held down with one hand and the base fabric with the other while the tape is pulled while adjusting the tension applied to it so that it conforms to the shape of the outer periphery of the airbag.
  • a roll of half-folded film may be prepared in advance, and a tension control mechanism may be provided during the process of sending the band-shaped non-breathable film-like protective material from the roll to the welding location by heat welding or ultrasonic welding.
  • the base fabric is sandwiched between upper and lower conveyor belts at the welding location, and while the base fabric is transported by the conveyor belt, it is sandwiched between upper and lower hot plates and heat is applied, so that continuous welding can be performed.
  • the tape (sandwiched between the base fabrics) is in a heated state, and the tape is stretched to fit the shape of the outer periphery of the airbag by applying tension, so that the non-air-permeable and breathable film-like protective material can be bonded without wrinkles even in curved parts including R parts and reverse R parts.
  • a part or the whole of the non-air-permeable and breathable film-like protective material can be preheated by a method such as a hot plate or hot air, so that the tape can be easily stretched to fit the shape of the outer periphery of the airbag.
  • a cooling section using a cooling plate may be provided immediately after welding.
  • the adhesiveness of the non-permeable, breathable film-like protective material is improved.
  • the welding workability of the curved section can be improved.
  • the method of continuously sandwiching the half-folded film (tape) along the straight or curved outer periphery of the pair of base fabric panels while applying tension to the film and applying heat or ultrasonic waves from the outside of the pair of base fabric panels to bond the panels together may lead to misalignment of the base fabrics, as the upper and lower base fabrics are bonded together continuously and simultaneously. Also, in the final stages of bonding or depending on the sewing shape of the airbag, there may be a small space, which may make it difficult to insert the tape under the upper base fabric.
  • the following two-step method may be used, in which, rather than clamping the tape between a pair of base fabric panels, one side of the tape is adhered to the first piece of base fabric (1st step), and then a second piece of base fabric is placed on top of the tape and compressed (2nd step).
  • the tape is fed onto one base fabric panel while applying tension, and then the tape is welded onto the first base fabric by heating from below, fixing the tape onto the one base fabric panel without wrinkles (1st step).
  • a second base fabric is then placed on top of the tape, and pressure is applied by heating using thermal welding or ultrasonic welding (2nd step). This eliminates the need to simultaneously operate the upper and lower base fabrics as described above, and only one base fabric is operated, and because the tape is not sandwiched between the base fabrics, there is no problem with the space becoming narrow at the final stage of bonding, etc.
  • the method of applying tension to the tape is not particularly limited, and a method of pulling the tape while adjusting the tension applied to it so that it conforms to the shape of the outer periphery of the airbag can be used, similar to the above-mentioned tension application and clamping method, while holding the tape with one hand and the base fabric with the other hand.
  • a roll of half-folded film may be prepared in advance, and a tension control mechanism may be provided in the process of sending the band-shaped non-breathable film-like protective material from the roll to the welding point by thermal welding or ultrasonic welding.
  • the tape can be welded onto the first base fabric by a hot plate from below the belt heat pressing machine, while the tape is heated by the upper hot plate to assist in stretching the tape in the R and reverse R sections.
  • the method for placing a second base fabric on the tape and heating it by thermal welding or ultrasonic welding is not particularly limited, and it may be continuously welded using a belt heat pressing machine as in the first step, or it may be welded all at once using a heat press machine that can heat the welded parts simultaneously, but from the viewpoint of productivity, it is preferable to use a heat press machine that can heat the welded parts simultaneously.
  • the first step is expected to have the secondary effect of improving the processing speed by temporarily fixing the parts.
  • the airbag is sealed by the adhesive area in both A-A'section and C-C'section.
  • the half-folded band-shaped non-breathable protective material is adhered to the inner surface of each of the pair of base fabric panels in an overlapping manner, and the end of the non-breathable protective material may be sealed.
  • the non-breathable protective material is "adhered to the overlapping manner" means that a plurality of the non-breathable protective materials are arranged in an overlapping manner, the non-breathable protective materials are adhered to each other, and the non-breathable protective material closest to the base fabric panel is adhered to the inner surface of each of the pair of base fabric panels.
  • the non-breathable protective materials may be overlapped at the same sewing portion and adhered to each other, or in a sewing shape having a branch point, a half-folded band-shaped non-breathable protective material arranged near one sewing line and a half-folded band-shaped non-breathable protective material arranged near the other sewing line may be partially overlapped and adhered near the sewing branch point.
  • the multiple non-breathable protective materials are united to form a loop-shaped structure bonded to the inner surface of each of the base fabric panels, and when a tensile force is applied between the pair of base fabric panels, a state can be formed in which the length between the distal ends along the folded non-breathable protective materials is greater than or equal to the length between the distal ends along the pair of base fabric panels.
  • the term "sealed end portions" of the non-breathable protective material refers to a state in which the end portions of the plurality of non-breathable protective materials are not open to the inflatable portion (chamber) of the airbag.
  • the method for sealing the end portions of the non-breathable protective materials is not particularly limited, and may be adhesion with an adhesive, heat welding, ultrasonic welding, or folding the non-breathable protective material. Also, as shown in FIG. 16, a structure in which the end portions are exposed to the outside of the inflatable portion (chamber) may be used.
  • This manufacturing method can be used as a method for intentionally providing a joint portion of a band-shaped non-breathable protective material folded in half when welding a band-shaped non-breathable protective material folded in half near a sewing shape having a branch point or a bent sewing shape, when the airbag size is large and the process is divided from the viewpoint of workability, etc.
  • the tension application or clamping method it can be widely applied to the 2-step method, the two-sheet bonding method, etc.
  • Si-coated fabric used as the base fabric panel and/or protective material was a plain weave fabric woven using nylon 66 multifilament fibers as the warp and weft, with one side coated with silicone resin.
  • the total fineness of the weaving yarn constituting the base fabric was 470 dtex, the number of filaments was 136, the weaving density of the coated fabric was 49/inch (2.54 cm), and the amount of silicone resin coated was 25 g/ m2 .
  • a film to be used as a protective material was prepared as follows. As shown in Fig. 11, a multilayer circular die was used to wind a desired multilayer film in a two-ply state around a 3-inch paper tube by the inflation method. At this time, the film was formed so that the inner surface side 3b of the tubular film was the adhesive layer and the outer surface side 3a was the outer layer.
  • the tensile elongation at break of the film is the measurement result when a band-shaped non-permeable and breathable film-like protective material is opened from a half-folded state and pulled. If the length of the measurement sample is short and the chuck distance cannot be satisfied, the chuck distance may be narrowed. In this case, a tensile speed at which the strain rate is 100%/min is selected.
  • the obtained film was cut along the MD direction to make a strip film 40 mm wide, and wound into a roll.
  • the upper heater temperature of the belt thermocompression machine was set to 100°C
  • the lower heater temperature was 230°C
  • the feed speed was set to 1.0 m/min
  • the entire film was heated to 100°C on one main panel using a Ryobi hot air gun (HAG-1551), and the tape was fed out while applying tension, and the tape was welded onto the first base fabric by heating from below (step 1).
  • a second base fabric was placed on top of the tape, and the tape was pressed for 3 seconds at a pressure temperature of 190°C using a hot plate jig having a shape that matches the bonded portion in step 1 (step 2).
  • Comparative Example 1 Preparation of a belt-shaped folded film (room temperature fixing method)
  • the coated fabric or laminate base fabric previously folded in half was wound into a roll, and a length equal to the sewing length of the outer edge of the airbag was cut and used.
  • the internal pressure of the airbag 6 seconds after the solenoid valve was opened was divided by the maximum internal pressure of the airbag after the solenoid valve was opened, and the value was recorded.
  • the test was performed once for each of the three airbags, and the average of the three measurements was calculated as the internal pressure retention rate after 6 seconds, expressed as a percentage.
  • the tensile modulus of the film referred to here was the measurement result when a strip-shaped non-permeable and breathable film-like protective material was opened from a half-folded state and pulled.
  • the chuck distance may be narrowed. In this case, a tensile speed at which the strain rate is 5%/min is selected.
  • Manufacturing time per bag The time required from the process of cutting sample pieces from the sample fabric to the production of three bags sewn according to each specification described below was divided by 3 to obtain the manufacturing time per bag, which was expressed as an index with Example 1 set as the standard of 100. However, the process of producing the protective material was carried out and prepared in advance.
  • the protective material used had a layer structure of "adhesive layer/intermediate layer/resin layer 1/resin layer 2", and was a multilayer film made of PA6/12 for the adhesive layer, POm-PE for the intermediate layer, PA6/66 polymer for resin layer 1, and PE (LDPE) for resin layer 2, which were extruded from a multilayer circular die and made into a 30 ⁇ m-thick four-type four-layer film by the inflation method.
  • LDPE PE
  • the layer structure of the protective material used was a multilayer film consisting of "adhesive layer/resin layer 1/intermediate layer/resin layer 1/resin layer 2/resin layer 3", in which PA6/12 was used for the adhesive layer, PO for resin layer 1, PO elastomer for the intermediate layer, PA6/66 polymer for resin layer 2, and PE (LDPE) for resin layer 3, and the film was extruded from a multilayer circular die and made into a 5-type 6-layer film with a thickness of 30 ⁇ m by the inflation method.
  • the layer structure of the protective material used was a multilayer film consisting of "adhesive layer/intermediate layer/resin layer 1", with PA6/66 polymer used for the adhesive layer, POm-PE for the intermediate layer, and PA6/66 polymer used for the resin layer 1, which were extruded from a multilayer circular die and made into a 30 ⁇ m thick two-kind three-layer film by the inflation method.
  • the physical properties of the multilayer films obtained and the evaluation results of airbag test pieces using these films as protective materials are shown in Table 1 below.
  • Example 1 a four-type, four-layer multilayer resin film was used as the non-breathable film-like protective material.
  • the elastic modulus of this film in the MD direction was 245 MPa
  • the elastic modulus in the TD direction was 250 MPa.
  • the method of sandwiching the band-shaped non-breathable film-like protective material along the straight or curved outer periphery of a pair of base fabric panels was to prepare a roll of half-folded film in advance, and send the band-shaped non-breathable film-like protective material from the roll to the welding point by heat welding. This method allowed for good handling during processing of the R section, and the obtained airbag had a high internal pressure retention rate and good compactness.
  • Example 2 was the same as Example 1, except that the elastic modulus of the film in the MD direction was 200 MPa and the elastic modulus in the TD direction was 200 MPa. This method provided excellent handling during processing of the R section, and the airbag obtained had a high internal pressure retention rate and good compactness.
  • Example 3 was the same as Example 1, except that the elastic modulus of the film in the MD direction was 300 MPa and the elastic modulus in the TD direction was 290 MPa. With this method, the film was somewhat hard and difficult to deform, which slightly worsened the handling properties during processing of the R section, but the airbag obtained had a high internal pressure retention rate and good compactness.
  • Example 4 was the same as Example 1, except that the elastic modulus of the film in the MD direction was 150 MPa and the elastic modulus in the TD direction was 125 MPa. With this method, the film was soft and sometimes difficult to handle, and the handling properties during processing of the R section were slightly worse, but the airbag obtained had a high internal pressure retention rate and good compactness.
  • Example 5 a two-type, three-layer multilayer resin film was used as the non-breathable film-like protective material.
  • a roll of half-folded film was prepared in advance to sandwich the band-shaped non-breathable film-like protective material along the straight or curved outer periphery of a pair of base fabric panels, and a 20 mm wide PE film (thickness 50 ⁇ m) was sandwiched inside the fold of the half-folded film as a release paper.
  • the band-shaped non-breathable film-like protective material was sent from the roll to the welding point by heat welding. With this method, the release paper may be misaligned, making it difficult to handle, and the handling during processing of the R section was slightly deteriorated, but the obtained airbag had a high internal pressure retention rate and good compactness.
  • Example 6 the same film as in Example 5 was used, but a roll of strip-shaped film was prepared in advance without being folded in half, and a strip-shaped non-breathable film-like protective material was folded in half using a half-folding former in the process of sending it from the roll to the welding point by heat welding, and then a 20 mm wide PE film (thickness 50 ⁇ m) was sandwiched as release paper inside the fold of the half-folded film and sent to the welding point.
  • the release paper and film were prone to shifting, making them difficult to handle, and handling during processing of the R section was impaired, but the resulting airbag had a high internal airbag pressure retention rate and good compactness.
  • Example 7 the same film as in Example 1 was used, but a roll of strip-shaped film was prepared in advance without being folded in half, and in the process of sending the strip-shaped non-breathable film-like protective material from the roll to the welding location by heat welding, the material was folded in half using a half-folding former, and then sent to the welding location.
  • the film was prone to shifting and curling, making it difficult to handle, and the handling properties during processing of the R section were somewhat worse, but the resulting airbag had a high internal airbag pressure retention rate and good compactness.
  • Example 8 the same film as in Example 1 was used, but when making the airbag, instead of sandwiching a strip-shaped non-air-permeable, breathable film-like protective material along the straight or curved outer periphery of a pair of base fabric panels, a tape was fed onto one main panel while applying tension, and the tape was welded onto the first base fabric by heating from below (step 1). After that, a second base fabric was placed on top of the tape and pressed onto it (step 2). This method allowed for good handling during processing of the R-section, the manufacturing time per bag was short, and the resulting airbag had a high airbag internal pressure retention rate and good compactness.
  • Comparative Example 1 the same film as in Example 1 was used, but when the airbag was made, the film-like protective material was sandwiched between two panels of cloth so as to form a loop on the inside of the airbag, and the panels of cloth were sewn together, and then the protective material and the laminated surface of the panel cloth were heat-sealed inside the stitching. Because the protective material was fixed by sewing when bonding, it was bonded without applying tension to the protective material. With this method, the film was prone to shifting and wrinkling, which could make it difficult to handle, and the handling during processing of the R section was poor. In addition, the manufacturing time per bag was long, and the resulting airbag had a low internal pressure retention rate and was not very compact.
  • the method for manufacturing an airbag according to the present invention comprises bonding the outer surfaces of both ends of a folded, strip-shaped, non-breathable protective material to the inner surface of each of at least a pair of base fabric panels in bonding regions of a predetermined width along the seams from near the seams toward the inside of the bag, the bonding regions having proximal and distal ends.
  • This method is highly productive for producing an airbag which has high internal pressure retention performance, is low cost, has high productivity, and is also highly compact. Therefore, the airbag manufacturing method according to the present invention can be suitably used for automobile airbags, CABs and pedestrian airbags which particularly require high internal pressure retention performance.
  • Base fabric panel (panel fabric, main panel) 1' Base fabric panel (panel fabric, main panel) Reference Signs List 2: Sewn (stitched) portion 2': Isolated sewn (stitched) portion 3: Silicone adhesive 4: Non-breathable (film-like) protective material 4': Inner edge of non-breathable (film-like) protective material 4": Half-folded strip-shaped non-breathable (film-like) protective material 5: Adhesive area 5': Adhesive area 6: Proximal end of adhesive area 6': Proximal end of adhesive area 7: Distal end of adhesive area 7': Distal end of adhesive area 8: End (sealed) portion of non-breathable (film-like) protective material 8': End (sealed) portion of non-breathable (film-like) protective material 10: Bag-shaped airbag with outer edge sewn A-A: Cross section 11: Multilayer film 11a: Multilayer film (outer layer) 11b Multilayer film (adhesive layer) 12 Multi-layer

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Abstract

Provided is a production method for an airbag that has high internal-pressure retaining performance, is low-cost, is highly producible, and is excellent in compactness. The production method according to the present invention is a manufacturing method for an airbag formed by stitching at least one pair of base fabric panels at the peripheral edges thereof. The production method includes: a fusion-bonding step for fusion-bonding the first surface layer to the inner surfaces of the base fabric panels by applying heat or ultrasonic waves from the outside of the pair of base fabric panels while applying a tensile force to a strip-shaped impermeable film type protection material that has been center-folded, comprises a laminated resin film including a first surface layer and a second surface layer, and is located between the inner surfaces of the respective base fabric panels, and while the strip-shaped impermeable film-type protection material is continuously inserted along the linear or curved peripheral edges of the pair of base fabric panels, and in this step, the second surface layer peels when the second surface layer is not fusion-bonded to itself by thermal fusion-bonding or ultrasonic fusion-bonding, or when a strong tensile force is applied to the pair of base fabric panels; and a stitching step for stitching the pair of base fabric panels in the vicinity of a bonding region before, after, or simultaneously with bonding. Said production method also executes, in two stages, the bonding of one of the base fabric panels, the protection material, and the other of the base fabric panels.

Description

内圧保持性能を高めたエアバッグの製法Airbag manufacturing method with improved internal pressure retention
 本発明は、車両に搭載されるエアバッグ装置に使用されるエアバッグの製法に関する。より詳しくは、1対の基布パネル同士の外縁部が縫合されたエアバッグにおいて、内圧保持性能を高めたエアバッグの製法に関する。 The present invention relates to a method for manufacturing an airbag used in an airbag device mounted on a vehicle. More specifically, the present invention relates to a method for manufacturing an airbag in which the outer edges of a pair of base fabric panels are sewn together, and which has improved internal pressure retention performance.
 従来、車両に搭載されるエアバッグ装置のエアバッグとして、1対の基布パネルの外縁部を縫合(縫製)して袋状にしたものにガスを瞬間的に注入し、膨張させて展開するエアバッグが使用されてきた。しかしながら、縫合(縫製)は、通常、ミシン糸を用いて行われるため、1対の基布パネルの間や、ミシン針の孔からのガスの漏れは避けられない。 Conventionally, airbags used in airbag devices mounted on vehicles are made by sewing (stitching) the outer edges of a pair of base fabric panels together to form a bag-like shape, into which gas is instantly injected to inflate and deploy. However, because the sewing (stitching) is usually done using sewing thread, gas leakage between the pair of base fabric panels and through the holes in the sewing needle is unavoidable.
 今日、車両への装着場所に応じてPAB(Passenger Airbag)、DAB(Driver Airbag)、SAB(Side Airbag)、KAB(Knee Airbag)、CAB(Curtain Airbag)、歩行者エアバッグ等の各種エアバッグが使用されている。エアバッグは注入したガスを保持することで人体への衝撃を吸収するものであるが、特に、DABでは、瞬間的な衝撃(ファーストインパクト)に対応できれば性能要求を一応満たすものの、例えば、CABでは、ファーストインパクト後の車両の回転(ロールオーバー)中にもエアバッグの膨張状態を維持する必要があり、長時間(例えば、6秒間)エアバッグ内の圧力を一定(例えば、30kPa)以上に維持することが(すなわち、内圧保持)が要求されている。また、歩行者エアバッグでは、歩行者がボンネットに乗り上げ、車体(例えばピラー部)に衝突するタイミングがまちまちであるため、DAB等と比較して長時間の内圧保持が必要とされる。 Today, various types of airbags are used depending on where they are installed in a vehicle, including PAB (Passenger Airbag), DAB (Driver Airbag), SAB (Side Airbag), KAB (Knee Airbag), CAB (Curtain Airbag), and pedestrian airbags. Airbags absorb impacts on the human body by retaining injected gas. In particular, DABs meet performance requirements if they can handle instantaneous impacts (first impacts). However, for example, CABs must maintain the inflated state of the airbag even during the rotation (rollover) of the vehicle after the first impact, and are required to maintain a constant pressure (e.g., 30 kPa) or higher (i.e., internal pressure maintenance) within the airbag for a long period of time (e.g., six seconds). In addition, pedestrian airbags require internal pressure maintenance for a longer period of time than DABs, because the timing at which a pedestrian lands on the bonnet and hits the vehicle body (e.g., the pillar section) varies.
 かかる内圧保持の要求を満たすべく、以下の方法が考えられてきた。
 1つの方法は、1対の基布パネルの外縁部を、縫製に代えて接着剤のみで接着する方法である。かかる方法では、ガス漏れは抑制できるものの、縫製がないため、接着がエアバッグ展開時の強度に耐えられない虞がある。
In order to meet the requirement of maintaining the internal pressure, the following methods have been considered.
One method is to bond the outer edges of a pair of base fabric panels with only an adhesive instead of sewing. Although this method can prevent gas leakage, there is a risk that the adhesive will not be able to withstand the strength required for the airbag to deploy because there is no sewing.
 他の方法は、1対の基布パネルを袋織OPW(One Piece Woven)で製造し、基布の外側からコーティングする方法である。かかる方法は、縫製が存在せずコーティングがあるため気密性に問題はなく、また、強度にも問題はないものの、複雑な形状が作り難く、コーティングを比較的厚く塗工する必要がありエアバッグの重量が大きくなりやすく、また、高コストとなるという問題がある。 Another method is to manufacture a pair of base fabric panels using the One Piece Woven method and then coat the outside of the base fabric. With this method, there are no stitching and the coating means there is no problem with airtightness, and there are no problems with strength either, but it is difficult to create complex shapes, the coating needs to be applied relatively thickly, and this tends to increase the weight of the airbag, and it is also expensive.
 さらに、他の方法は、1対の基布パネルの外縁部を、シリコーン接着剤で接着した後、接着部を縫製する方法である。この方法は、ガス漏れを抑制しつつ強度も確保できるが、生産性が低く、また、接着部が分厚くなり、エアバッグの折り畳み性や収容性が悪化するという問題がある。また、シリコーン接着剤の重量の分、エアバッグの重量が大きくなる。
 図2に例示するように、この方法では、エアバッグ展開時にシリコーン接着剤が伸びて縫製部へのガスのアクセスが回避される。
 一般に、シリコーン接着剤は、基布パネルとの接着強度が高いため、かかる用途に適したものであるが、接着剤の硬化に半日~約1日かかり、生産性が低く、また、例えば、接着剤がない箇所(内圧保持を必要としない箇所)での1対の基布パネルの折り畳み厚みが2.2mmであるのに対し、接着剤と縫製がある箇所での折り畳み厚みは5.2mmとなり、コンパクト性(折り畳み性、収納性)に欠けるものとなる。さらに、シリコーン接着剤は、リサイクルの際にエアバッグ織物と分離する必要があり、生産時のGHG(Green House Gas)排出量も比較的多くなるため、エアバッグの製造・廃棄において環境に優しいとは言えない。
Another method is to bond the outer edges of a pair of base fabric panels with a silicone adhesive and then sew the bonded portion. This method can ensure strength while suppressing gas leakage, but it has problems such as low productivity, thick bonded portions, and poor folding and storage properties of the airbag. In addition, the weight of the silicone adhesive increases the weight of the airbag.
As illustrated in FIG. 2, in this method, the silicone adhesive stretches during airbag deployment, preventing gas from accessing the stitching.
Generally, silicone adhesives are suitable for such applications because of their high adhesive strength with base fabric panels, but the adhesive takes half a day to about a day to harden, resulting in low productivity, and for example, the folded thickness of a pair of base fabric panels is 2.2 mm at the location where there is no adhesive (location where internal pressure does not need to be maintained), whereas the folded thickness at the location where there is adhesive and stitching is 5.2 mm, resulting in a lack of compactness (foldability, storability). Furthermore, silicone adhesives must be separated from the airbag fabric when recycled, and they emit a relatively large amount of GHG (Green House Gas) during production, so they are not environmentally friendly in the manufacture and disposal of airbags.
 以下の特許文献1には、基布の対向部分を一対縫合した縫合部から離れた位置で、インフレータからのガスが導入される内側からの該縫合部を覆うように、該縫合部に沿って縫着され保護布を有するエアバッグ装置が記載されている(同書、図2、図7参照)。特許文献1には、縫合部に対する保護材が開示されているが、かかる保護材は、基布に接着ではなく、縫着により固定されている。かかる保護材の目的は、縫合部がインフレータからの高圧ガスに直接晒され、破壊されることを回避すること、また、保護材の縫合部に張力を分散させて、一対の基布の縫合部の破損を防止することであり、縫合部が破損しない状態での内圧保持を目的とするものではない。 The following Patent Document 1 describes an airbag device having a protective cloth sewn along a seam where a pair of opposing portions of a base fabric are sewn together, at a position away from the seam so as to cover the seam from the inside where gas from the inflator is introduced (see Figures 2 and 7 of the same document). Patent Document 1 discloses a protective material for the seam, but this protective material is fixed to the base fabric by sewing, not by adhesion. The purpose of this protective material is to prevent the seam from being directly exposed to the high-pressure gas from the inflator and being destroyed, and to distribute tension in the protective material's seam to prevent damage to the seam of the pair of base fabrics, but is not intended to maintain internal pressure without damaging the seam.
 以下の特許文献2には、ラミネート材を含む壁部を持つエアバッグであって、該ラミネート材は、織編物からなる通気性シート状構造の裏打ち層、少なくとも2層の共押し出しポリマーフィルム、該裏打ち層側の所定のガラス転移温度を有する第1ポリマー層、該裏打ち層とは反対側の所定の貯蔵モジュラスを有する第2ポリマー層を含み、エアバッグの縁部で第2ポリマー層が結合するように、壁部を結合したエアバッグ、及び第1ポリマー層と第2ポリマー層に異なる熱エネルギーを与えることで結合させる製法が開示されている。
 特許文献2に記載された発明の目的は、低コストで生産でき、かつ、シールが容易かつ信頼性の高いエアバッグを提供することである(同書、Fig. 1-3参照)。
 特許文献2には、エアバッグ縫合部に対する保護材は開示されておらず、また、その製法は、主に生産性を高めることを目的としており、内圧保持を目的としていない。
Patent Document 2 listed below discloses an airbag having walls including a laminate material, the laminate material including a backing layer having a breathable sheet-like structure made of a woven or knitted fabric, at least two layers of coextruded polymer film, a first polymer layer having a predetermined glass transition temperature on the backing layer side, and a second polymer layer having a predetermined storage modulus on the opposite side to the backing layer, the airbag having walls bonded together such that the second polymer layer is bonded at the edge of the airbag, and a manufacturing method for bonding the first polymer layer and the second polymer layer by applying different thermal energies to them.
The object of the invention described in US Pat. No. 5,399,633 is to provide an airbag which can be produced at low cost and which is easy and reliable to seal (see Figs. 1-3 of the same document).
Patent Document 2 does not disclose any protective material for the seams of the airbag, and the manufacturing method therefor is primarily intended to increase productivity, not to maintain internal pressure.
 以下の特許文献3には、パネル同士を接合部で接合したエアバッグであって、パネルは、織布と、該織布に接着剤を介して接着された合成樹脂フィルムとを有し、パネル同士の間にホットメルト接着剤シートを介在させて加圧加熱しパネル同士を接合し、合成樹脂フィルムをエアバッグの外側に配置したエアバッグが記載される。特許文献3に記載の発明の目的は、パネル同士の縫合部の強度が高く、また耐久性に優れ、ガスリークが防止され、かつ取り扱い性も良好なエアバッグを提供することである(図3、4参照)。
 特許文献3に記載の発明では、ホットメルト接着剤よりなる接合層でパネル同士を接着することでパネル同士の接合部の強度を高めて、織布の糸密度を小さくし、かつ、合成樹脂フィルムをパネルの外側に配置して織布の車体内面への直な接触を回避し、耐久性を高め、また、ホットメルト接着剤を織布の縫合部に含浸させて、針孔からのガスリークや縫合の糸抜けを防止している。
 特許文献3には、エアバッグ展開時にエアバッグの外周接着面に応力がかかったとき、パネル同士の接合部に応力がかかり、接着が破壊され、縫製穴からのガスリークが発生することを防ぐ手法については記載されていない。ましてや、縫合に対する保護材を、縫合とは別の場所で基布に接着させ、該保護材と基布との間の接着を維持して内圧保持を図るという技術思想は見られない。
The following Patent Document 3 describes an airbag in which panels are joined together at joints, the panels having a woven fabric and a synthetic resin film bonded to the woven fabric via an adhesive, the panels are joined together by pressurizing and heating with a hot melt adhesive sheet interposed between the panels, and the synthetic resin film is disposed on the outside of the airbag. The object of the invention described in Patent Document 3 is to provide an airbag in which the strength of the seams between the panels is high, the durability is excellent, gas leakage is prevented, and handling is easy (see Figures 3 and 4).
In the invention described in Patent Document 3, panels are bonded together with a bonding layer made of hot melt adhesive, thereby increasing the strength of the joints between the panels, reducing the thread density of the woven fabric, and a synthetic resin film is placed on the outside of the panel to prevent the woven fabric from coming into direct contact with the inside of the vehicle body, thereby increasing durability. In addition, the stitching of the woven fabric is impregnated with hot melt adhesive to prevent gas leaks from pinholes and stitching threads from coming loose.
Patent Document 3 does not describe a method for preventing gas leakage from stitching holes due to stress being applied to the joints between the panels when the adhesive surface around the outer periphery of the airbag is stressed during deployment, which may cause the adhesive to break.Furthermore, there is no mention of the technical idea of adhering a protective material for the stitching to the base fabric at a location separate from the stitching, and maintaining the adhesion between the protective material and the base fabric to maintain the internal pressure.
 このように、従来技術の水準に鑑み、膨張展開時の、内圧保持性能に優れ、低コストで、生産性が高く、かつ、コンパクト性に優れたエアバッグ、及びその製法は、未だ提供されていない。 In light of the state of the art, an airbag that has excellent internal pressure retention when inflated and deployed, is low cost, highly productive, and has excellent compactness, and a manufacturing method thereof, has not yet been provided.
国際公開第2010/122852号International Publication No. 2010/122852 米国特許出願公開第2010/0320736号明細書US Patent Application Publication No. 2010/0320736 特開2018-177122号公報JP 2018-177122 A
 かかる従来技術の水準の下、本発明が解決しようとする課題は、1対の基布パネルが外周縁で縫合され袋体を形成するエアバッグにおいて、該1対の基布パネルの各々の内面に、該縫合近傍から袋体内部に向かって近位端と遠位端を有する所定幅の該縫合に沿う接着領域で、半折された帯状の非通気性保護材の両端外面を、それぞれ、接着せしめた気密を構造形成し、これを展開時にも維持することにより内圧保持性能を高めつつ、低コストで、生産性が高く、かつ、コンパクト性にも優れるエアバッグの、生産性の高い製法を提供することである。 Under the level of the conventional technology, the problem that the present invention aims to solve is to provide a highly productive method for manufacturing an airbag in which a pair of base fabric panels are sewn together at their outer periphery to form a bag body, in which an airtight structure is formed by bonding both outer surfaces of a half-folded, strip-shaped, non-breathable protective material to the inner surface of each of the pair of base fabric panels in a bonding region of a predetermined width along the stitching from near the stitching toward the inside of the bag body, the bonding region having a proximal end and a distal end, and which maintains this structure even when the airbag is deployed, thereby improving the internal pressure retention performance, and providing a low-cost, highly productive, and highly compact airbag manufacturing method.
 本願発明者らは、前記課題を解決すべく、鋭意検討し実験を重ねた結果、以下に規定する構造を有する非通気性保護材を用いることにより、前記課題を解決できることを予想外に見出し、本発明を完成するに至ったものである。
 すなわち、本発明は以下のとおりのものである。
The inventors of the present application conducted intensive research and repeated experiments in order to solve the above-mentioned problems, and unexpectedly discovered that the above-mentioned problems could be solved by using a non-breathable protective material having the structure defined below, which led to the completion of the present invention.
That is, the present invention is as follows.
 [1]少なくとも1対の基布パネルが外周縁で縫合されてなるエアバッグの製造方法であって、以下の工程:
 該1対の基布パネルの各々の内面の間に、所定幅の、剥離紙を挟んだ単層樹脂フィルムからなる又は第1表面層と第2表面層を含む2層以上の積層樹脂フィルムからなる半折された帯状の非通気性フィルム状保護材に、張力を付与しながら、これを、該1対の基布パネルの直線又は曲線状の外周縁に沿って、連続的に、挟み込みつつ、該1対の基布パネルの外側から、熱又は超音波を適用して、該単層樹脂フィルムの表面を又は該第1表面層を、該基布パネルの内面に、所定幅の接着領域において、溶着する溶着工程、ここで、該単層樹脂フィルムの剥離紙側の表面同士は剥離紙の存在により溶着されていないか、あるいは該積層樹脂フィルムの第2表面層同士は、熱溶着又は超音波溶着により溶着されていないか、又は、熱溶着又は超音波溶着により溶着されているものの、該エアバッグの展開に際し、該1対の基布パネル同士に引張強力がかかる時、該第2表面層が剥離する;
 前記接着の前、接着の後、又は同時に、該接着領域の近傍で、該1対の基布パネルを縫合する縫合工程;
を含む、前記製造方法。
 [2]前記半折された帯状の非通気性フィルム状保護材を、半折された状態で巻き取られたロールから送り出し、1対の基布パネルに挟み込む、前記[1]に記載の方法。
 [3]前記半折された帯状の非通気性フィルム状保護材を、溶着する溶着工程の前に、該前記半折された帯状の非通気性フィルム状保護材の一部又は全体を加熱する工程;
を含む、前記[1]又は[2]に記載の方法。
 [4]前記半折された帯状の非通気性フィルム状保護材を、溶着する溶着工程の後に、該前記半折された帯状の非通気性フィルム状保護材の一部又は全体を冷却する工程;
を含む、前記[1]~[3]のいずれかに記載の方法。
 [5]前記半折された帯状の非通気性フィルム状保護材を、溶着する溶着工程において、熱板及び/又は冷却板の押し圧を間歇的に印加/解除しながら、該前記半折された帯状の非通気性フィルム状保護材の一部又は全体を加熱及び/又は冷却する工程;
を含む、前記[1]~[4]のいずれかに記載の方法。
 [6]前記半折された非通気性フィルム状保護材である積層樹脂フィルムの第1表面層を構成する樹脂の融点が、第2表面層を構成する樹脂の融点よりも、50℃~160℃低い、前記[1]~[5]のいずれかに記載の方法。
 [7]前記半折された非通気性フィルム状保護材である、単層又は積層樹脂フィルムの第1表面層と第2表面層を含む多層フィルムにおいて、いずれかの隣接する層間のSP値の差が、2.0[cal/cm)1/2]以上である、前記[1]~[6]のいずれかに記載の方法。
 [8]前記半折された非通気性フィルム状保護材である、単層又は積層樹脂フィルムの第1表面層と第2表面層を含む多層フィルムにおいて、いずれかの隣接する層間のHSP値の差が、1.0[cal/cm)1/2]以上である、前記[1]~[7]のいずれかに記載の方法。
 [9]エアバッグの展開に際し、前記1対の基布パネル同士に引張強力がかかる時、該1対の基布パネルに沿った遠位端間の長さよりも、該半折された非通気性フィルム状保護材に沿った遠位端間の長さが、大きいか又はこれに等しい、前記[1]~[8]のいずれかに記載の方法。
 [10]前記接着の後に、該接着領域の近傍で、該1対の基布パネルを縫合する縫合工程;
を含む、前記[1]~[9]のいずれかに記載の方法。
 [11]1の基布パネルの上に、所定幅の、第1表面層と第2表面層を含む2層以上の積層樹脂フィルムからなる半折された帯状の非通気性フィルム状保護材に、張力を付与しながら、これを、該1の基布パネルの直線又は曲線状の外周縁に沿って、連続的に、該1の基布パネルの下側から、熱又は超音波を適用して、該第1表面層を、該基布パネルの上面に溶着する溶着工程;
 該溶着されたフィルム状保護材の上に他の基布パネルを重ね、該重ねた基布パネルの上側から、熱又は超音波を適用して、該第1表面層を、該重ねた基布パネルの下面に溶着する溶着工程、ここで、該積層樹脂フィルムの第2表面層同士は、熱溶着又は超音波溶着により溶着されていないか、又は、熱溶着又は超音波溶着により溶着されているものの、該エアバッグの展開に際し、該基布パネル同士に引張強力がかかる時、該第2表面層が剥離する;
 前記接着の後、得られる溶着の領域の近傍で、該基布パネルを縫合する縫合工程;
を含む、前記製造方法。
[1] A method for manufacturing an airbag having at least one pair of base fabric panels sewn together at their outer periphery, comprising the steps of:
a welding step of continuously sandwiching a semi-folded, band-shaped non-breathable film-like protective material, which is made of a monolayer resin film having a predetermined width with a release paper sandwiched therebetween or a laminated resin film having two or more layers including a first surface layer and a second surface layer, between the inner surfaces of the pair of base fabric panels while applying tension to the material along the linear or curved outer periphery of the pair of base fabric panels, and applying heat or ultrasonic waves from the outside of the pair of base fabric panels to weld a surface of the monolayer resin film or the first surface layer to the inner surface of the base fabric panel in an adhesive region of a predetermined width, wherein although the surfaces of the monolayer resin film on the release paper side are not welded to each other due to the presence of the release paper, or the second surface layers of the laminated resin film are not welded to each other by heat welding or ultrasonic welding, or are welded to each other by heat welding or ultrasonic welding, the second surface layer peels off when a tensile force is applied to the pair of base fabric panels when the airbag is deployed;
a sewing step of sewing the pair of fabric panels together adjacent the bonded areas before, after, or simultaneously with the bonding;
The manufacturing method comprising the steps of:
[2] The method according to [1], wherein the half-folded band-shaped non-breathable film-like protective material is fed from a roll in which it is wound in a half-folded state, and sandwiched between a pair of base fabric panels.
[3] A step of heating a part or the whole of the half-folded, band-shaped, non-breathable film-like protective material before a welding step of welding the half-folded, band-shaped, non-breathable film-like protective material;
The method according to any one of claims 1 to 2, further comprising:
[4] A step of cooling a part or the whole of the half-folded, band-shaped, non-breathable film-like protective material after a welding step of welding the half-folded, band-shaped, non-breathable film-like protective material;
The method according to any one of the above [1] to [3],
[5] In the welding process of welding the half-folded band-shaped non-breathable film-like protective material, a process of heating and/or cooling a part or the whole of the half-folded band-shaped non-breathable film-like protective material while intermittently applying/releasing the pressure of a hot plate and/or a cold plate;
The method according to any one of the above [1] to [4],
[6] The method according to any one of [1] to [5], wherein the melting point of the resin constituting the first surface layer of the laminated resin film which is the half-folded non-breathable film-like protective material is 50°C to 160°C lower than the melting point of the resin constituting the second surface layer.
[7] The method according to any one of [1] to [6] above, wherein the half-folded non-breathable film-like protective material is a single-layer or multilayer film including a first surface layer and a second surface layer of a laminated resin film, and the difference in SP value between any adjacent layers is 2.0 [cal/ cm3 ) 1/2 ] or more.
[8] The method according to any one of [1] to [7] above, wherein the half-folded non-breathable film-like protective material is a single-layer or multilayer film including a first surface layer and a second surface layer of a laminated resin film, and the difference in HSP value between any adjacent layers is 1.0 [cal/ cm3 ) 1/2 ] or more.
[9] The method according to any one of [1] to [8], wherein when a tensile force is applied between the pair of base fabric panels during deployment of the airbag, the length between the distal ends along the folded non-breathable film-like protective material is greater than or equal to the length between the distal ends along the pair of base fabric panels.
[10] a sewing step of sewing the pair of base fabric panels together adjacent to the bonded areas after the bonding;
The method according to any one of the above [1] to [9],
[11] a welding step of applying tension to a semi-folded band-shaped non-breathable film-like protective material having a predetermined width and made of a laminated resin film of two or more layers including a first surface layer and a second surface layer, from below the first fabric panel, continuously along a straight or curved outer periphery of the first fabric panel, thereby welding the first surface layer to an upper surface of the first fabric panel;
a welding step of overlapping another base fabric panel on the welded film-like protective material and applying heat or ultrasonic waves from the upper side of the overlapped base fabric panel to weld the first surface layer to the lower surface of the overlapped base fabric panel, wherein the second surface layers of the laminated resin film are not welded to each other by thermal welding or ultrasonic welding, or are welded to each other by thermal welding or ultrasonic welding, but the second surface layer peels off when a tensile force is applied to the base fabric panels when the airbag is deployed;
a sewing step of sewing the fabric panels together adjacent the areas of the resulting welds after said bonding;
The manufacturing method comprising the steps of:
 本発明に係るエアバッグの製法は、少なくとも1対の基布パネルの各々の内面に、縫合近傍から袋体内部に向かって近位端と遠位端を有する所定幅の該縫合に沿う接着領域で、半折された帯状の非通気性保護材の両端外面が、それぞれ、接着されており、該エアバッグの展開に際し、該1対の基布パネル同士に引張強力がかかる時、かかる接着領域には引張強力が実質的にかからないために気密構造が維持される結果、内圧保持性能が高く、低コストで、生産性が高く、かつ、コンパクト性にも優れるエアバッグの生産性の高い製法である。
 したがって、発明に係るエアバッグ、及びその製法は、自動車用エアバッグ、とりわけ内圧保持性能が特に要求されるCABや歩行者エアバッグに好適に利用可能である。
The method for manufacturing an airbag according to the present invention comprises bonding the outer surfaces of both ends of a folded, strip-shaped, non-breathable protective material to the inner surface of each of at least a pair of base fabric panels in bonding areas of a predetermined width along the seams, having proximal and distal ends from near the seams toward the inside of the bag, and when a tensile force is applied to the pair of base fabric panels when the airbag is deployed, substantially no tensile force is applied to the bonding areas, thereby maintaining an airtight structure.As a result, this method for manufacturing an airbag has high internal pressure retention performance, is low cost, has high productivity, and is also highly compact.
Therefore, the airbag and the manufacturing method thereof according to the present invention can be suitably used for automobile airbags, in particular for CABs and pedestrian airbags which require high internal pressure retention performance.
本実施形態の製法で製造しうる1対の基布パネルが外周縁で縫合され袋体を形成するエアバッグの平面図である。1 is a plan view of an airbag in which a pair of base fabric panels are sewn together at their outer periphery to form a bag body, which can be manufactured by the manufacturing method of this embodiment. 図1のA-A断面に相当する箇所において、シリコーン接着剤での接着部に縫合する場合のエアバッグ展開時の状態の説明図である。2 is an explanatory diagram of a state of an airbag when deployed, in a location corresponding to the cross section AA in FIG. 1, in which a portion bonded with a silicone adhesive is sewn. FIG. 本実施形態の製法で製造しうるエアバッグにおける非通気性保護材のエアバッグ展開時の状態の説明図である。FIG. 2 is an explanatory diagram of the state of a non-breathable protective material in an airbag that can be manufactured by the manufacturing method of this embodiment when the airbag is deployed. 本実施形態の製法で製造しうるエアバッグにおける、該エアバッグの展開に際し、該1対の基布パネル同士に引張強力がかかる時、該1対の基布パネルに沿った遠位端間の長さよりも、該半折された非通気性保護材に沿った遠位端間の長さが、大きいか又はこれに等しく、それにより該接着領域における気密構造が維持される状態の説明図である。This is an explanatory diagram of a state in which, in an airbag that can be manufactured by the manufacturing method of this embodiment, when a tensile force is applied between the pair of base fabric panels during deployment of the airbag, the length between the distal ends along the half-folded non-breathable protective material is greater than or equal to the length between the distal ends along the pair of base fabric panels, thereby maintaining an airtight structure in the adhesive region. 半折された非通気性フィルム状保護材は、第1表面層と第2表面層を含む2層以上の積層樹脂フィルムであり、かつ、該第1表面層は該基布パネルに溶着されているが、該第2表面層同士が、接着されていないことにより該接着領域における気密構造が維持される状態の説明図である。This is an explanatory diagram of a state in which a non-breathable film-like protective material that is folded in half is a laminated resin film of two or more layers including a first surface layer and a second surface layer, and the first surface layer is welded to the base fabric panel, but the second surface layers are not bonded to each other, thereby maintaining an airtight structure in the adhesive area. 半折された非通気性フィルム状保護材は、第1表面層と第2表面層を含む2層以上の積層樹脂フィルムであり、かつ、該第1表面層は該基布パネルに溶着されているが、該第2表面層同士は、接着されているものの、該エアバッグの展開に際し、該1対の基布パネル同士に引張強力がかかる時、該第2表面層が剥離し、それにより該接着領域における気密構造が維持される状態の説明図である。This is an explanatory diagram of a state in which the half-folded non-breathable film-like protective material is a laminated resin film of two or more layers including a first surface layer and a second surface layer, and the first surface layer is welded to the base fabric panel, while the second surface layers are bonded together.However, when a tensile force is applied to the pair of base fabric panels when the airbag is deployed, the second surface layer peels off, thereby maintaining an airtight structure in the adhesive area. 半折された非通気性フィルム状保護材である積層樹脂フィルムの第1表面層を構成する樹脂と、第2表面層を構成する樹脂との関係の説明図である。1 is an explanatory diagram showing the relationship between the resin constituting the first surface layer and the resin constituting the second surface layer of a laminated resin film which is a non-breathable film-like protective material folded in half. FIG. 半折された非通気性フィルム状保護材の製造方法の一例(半折フィルムの巻取り)の説明図である。FIG. 2 is an explanatory diagram of an example of a method for producing a half-folded non-breathable film-like protective material (winding up a half-folded film). 巻き取った半折された非通気性フィルム状保護材を熱溶着箇所に供給する状態の説明図である。FIG. 13 is an explanatory diagram of a state in which a wound, half-folded non-breathable film-like protective material is supplied to a heat welding location. 1対の基布パネルの各々の内面の間に、所定幅の、剥離紙を挟んだ単層樹脂フィルムからなる又は第1表面層と第2表面層を含む2層以上の積層樹脂フィルムからなる半折された帯状の非通気性フィルム状保護材に、張力を付与しながら、これを、該1対の基布パネルの直線又は曲線状の外周縁に沿って、連続的に、挟み込みつつ、該1対の基布パネルの外側から、熱又は超音波を適用して、該単層樹脂フィルムの表面を又は該第1表面層を、該基布パネルの内面に溶着する溶着工程における、半折フィルムの供給状態を説明する図面である。This is a diagram explaining the supply state of a half-folded, strip-shaped, non-breathable film-like protective material, which is made of a single-layer resin film with a release paper of a predetermined width sandwiched between the inner surfaces of a pair of base fabric panels, or a laminated resin film of two or more layers including a first surface layer and a second surface layer, is continuously sandwiched along the straight or curved outer peripheral edge of the pair of base fabric panels while applying tension to the material, and then heat or ultrasound is applied from the outside of the pair of base fabric panels to weld the surface of the single-layer resin film or the first surface layer to the inner surface of the base fabric panels. 多層サーキュラーダイを用いた、インフレーション法による多層フィルムを二枚重ね状態で3インチ紙管に巻き取る方法の説明図である。FIG. 1 is an explanatory diagram of a method for winding a multi-layer film in a two-ply state around a 3-inch paper tube by an inflation method using a multi-layer circular die. フィルムの半折化に用いる治具(半折フォーマー)の概略図である。FIG. 2 is a schematic diagram of a jig (half-folding former) used to fold a film in half. 閉空間の(中央に)孤立縫製部を含むエアバッグ(クッション)の一例の説明図である。1 is an explanatory diagram of an example of an airbag (cushion) including an isolated sewn portion (in the center) of a closed space. 閉空間の孤立縫製部への半折フィルムの接着の1の方法の説明図である。10 is an explanatory diagram of one method of adhering a folded film to an isolated sewn portion of a closed space. FIG. 図14に示す1の方法による封止状態の説明図である。FIG. 15 is an explanatory diagram of the sealing state according to the method 1 shown in FIG. 14 . 閉空間の孤立縫製部への半折フィルムの接着の他の方法と、封止状態の説明図である。13A and 13B are explanatory diagrams of another method for adhering a folded film to an isolated sewn portion of a closed space and a sealed state. 融点差(左側)と層間SP値差(右側)における半折フィルムの層構成係の説明図である。FIG. 2 is an explanatory diagram of the layer structure of a folded film in terms of the melting point difference (left side) and the interlayer SP value difference (right side).
 以下、図面を参照しながら、本発明の実施形態を詳細に説明する。
 本発明の実施形態は、少なくとも1対の基布パネルが外周縁で縫合されてなるエアバッグの製造方法であって、以下の工程:
 該1対の基布パネルの各々の内面の間に、所定幅の、剥離紙を挟んだ単層樹脂フィルムからなる又は第1表面層と第2表面層を含む2層以上の積層樹脂フィルムからなる半折された帯状の非通気性フィルム状保護材に、張力を付与しながら、これを、該1対の基布パネルの直線又は曲線状の外周縁に沿って、連続的に、挟み込みつつ、該1対の基布パネルの外側から、熱又は超音波を適用して、該単層樹脂フィルムの表面を又は該第1表面層を、該基布パネルの内面に、所定幅の接着領域において、溶着する溶着工程、ここで、該単層樹脂フィルムの剥離紙側の表面同士は剥離紙の存在により溶着されていないか、あるいは該積層樹脂フィルムの第2表面層同士は、熱溶着又は超音波溶着により溶着されていないか、又は、熱溶着又は超音波溶着により溶着されているものの、該エアバッグの展開に際し、該1対の基布パネル同士に引張強力がかかる時、該第2表面層が剥離する;
 前記接着の前、接着の後、又は同時に、該接着領域の近傍で、該1対の基布パネルを縫合する縫合工程;
を含む、前記製造方法である。
Hereinafter, embodiments of the present invention will be described in detail with reference to the drawings.
An embodiment of the present invention is a method for manufacturing an airbag having at least one pair of fabric panels sewn together at a periphery thereof, the method comprising the steps of:
a welding step of continuously sandwiching a semi-folded, band-shaped non-breathable film-like protective material, which is made of a monolayer resin film having a predetermined width with a release paper sandwiched therebetween or a laminated resin film having two or more layers including a first surface layer and a second surface layer, between the inner surfaces of the pair of base fabric panels while applying tension to the material along the linear or curved outer periphery of the pair of base fabric panels, and applying heat or ultrasonic waves from the outside of the pair of base fabric panels to weld a surface of the monolayer resin film or the first surface layer to the inner surface of the base fabric panel in an adhesive region of a predetermined width, wherein although the surfaces of the monolayer resin film on the release paper side are not welded to each other due to the presence of the release paper, or the second surface layers of the laminated resin film are not welded to each other by heat welding or ultrasonic welding, or are welded to each other by heat welding or ultrasonic welding, the second surface layer peels off when a tensile force is applied to the pair of base fabric panels when the airbag is deployed;
a sewing step of sewing the pair of fabric panels together adjacent the bonded areas before, after, or simultaneously with the bonding;
The manufacturing method includes the steps of:
[基布パネル(パネル布、メインパネル)]
 1対の基布パネルに、特に制限はなく、エアバッグの基布として通常使用されるポリアミドやポリエステルの平織の布であることができる。本実施形態に使用する基布を構成する繊維の繊度は150~900dtexが好ましい。繊度が150dtex以上であることでエアバッグとしての強度を得ることができ、900dtex以下であることでエアバッグ用基布とした時に柔軟なものが得られる。
 本実施形態に使用する基布を構成する繊維にはマルチフィラメントを用いることが好ましく、繊維の単糸繊度は0.1~10dtexであることが好ましい。この範囲であると、エアバッグ用基布とした時に柔軟であり、かつ、展開速度が大きいものが得られる。
 また、本実施形態に使用する基布の織密度は経緯共、30~90本/inchが好ましく、カバーファクターは1500~2500が好ましい。この範囲であると、エアバッグ用基布とした時に柔軟であり、かつ、展開に耐える強力を得ることができる。ただし、カバーファクターは次式により計算される値である。
   CF=(2.54cmあたりの経糸本数)×√(経糸総繊度(dtex))+(2.54cmあたりの緯糸本数)×√(緯糸総繊度(dtex))
[Base fabric panel (panel fabric, main panel)]
The pair of base fabric panels is not particularly limited and may be a plain weave fabric of polyamide or polyester that is normally used as a base fabric for airbags. The fineness of the fibers constituting the base fabric used in this embodiment is preferably 150 to 900 dtex. A fineness of 150 dtex or more can provide the strength required for an airbag, and a fineness of 900 dtex or less can provide a soft base fabric for an airbag.
It is preferable to use a multifilament as the fiber constituting the base fabric used in this embodiment, and the single yarn fineness of the fiber is preferably 0.1 to 10 dtex. When the fiber is in this range, it is flexible when used as a base fabric for an airbag and has a high deployment speed.
In addition, the weaving density of the base fabric used in this embodiment is preferably 30 to 90 threads/inch for both warp and weft, and the cover factor is preferably 1500 to 2500. Within this range, when used as a base fabric for an airbag, it is flexible and can obtain strength sufficient to withstand deployment. However, the cover factor is a value calculated by the following formula.
CF = (number of warp threads per 2.54 cm) × √ (total warp thread size (dtex)) + (number of weft threads per 2.54 cm) × √ (total weft thread size (dtex))
 基布パネルは、通気性を低下させるために、両面又は片面に樹脂を塗工したものや単層又は多層フィルムをラミネートしたものでも構わない。この時、樹脂コーティングに用いる樹脂としては、シリコーン系やポリウレタン系のコーティング、難燃性の熱可塑性樹脂フィルム等を用いた熱ラミネーションという方法を採用することができる。
 樹脂をコーティングする場合、コート量は5~50g/mが好ましい。基布にフィルムをラミネートする場合、フィルムの厚みは0.001mm以上0.5mm以下であることが好ましい。この範囲であれば、エアバッグ用基布とした時に柔軟であり、かつ、気密性に優れた基布が得られる。
The base fabric panel may be coated with resin on one or both sides or laminated with a single or multi-layer film to reduce breathability. In this case, the resin used for the resin coating may be a silicone or polyurethane coating, or a method of thermal lamination using a flame-retardant thermoplastic resin film, etc. may be used.
When coating with a resin, the coating amount is preferably 5 to 50 g/m 2. When laminating a film on a base fabric, the thickness of the film is preferably 0.001 mm or more and 0.5 mm or less. Within this range, a base fabric that is flexible and has excellent airtightness when used as a base fabric for an airbag can be obtained.
 本実施形態に係るエアバッグは、図1に例示するように、1対の基布パネルが外周縁で縫合され袋体を形成するものであることができる。図1中、符号2はメインパネルの縫合(縫製)部を示し、符号4’は、表の基布パネルの裏側にある以下に説明する半折りされた非通気性保護材の内縁部(ループの頂上)の位置を示す。図1に示すように、開口部には、通常、同材質の基パネルにより筒状に作製されたインナーチューブ(符号23)を挿入することができ、エアバッグ膨張・展開時には、インナーチューブの内部からエアバッグ内に瞬間的にガスが注入される。 The airbag according to this embodiment can be one in which a pair of base fabric panels are sewn together at their outer periphery to form a bag, as shown in FIG. 1. In FIG. 1, reference numeral 2 indicates the sewn (stitched) portion of the main panel, and reference numeral 4' indicates the position of the inner edge (top of the loop) of a semi-folded non-breathable protective material, which is on the back side of the front base fabric panel and which will be described below. As shown in FIG. 1, an inner tube (reference numeral 23), which is usually made into a cylindrical shape from base panels of the same material, can be inserted into the opening, and when the airbag inflates and deploys, gas is instantly injected into the airbag from inside the inner tube.
[縫合]
 縫合は、エアバッグの膨張・展開時に破壊されない限り特に制限はないが、好ましくは、基布パネルと同じ素材のマルチフィラメント繊維の縫合糸によるミシン縫製である。前記したように、内圧保持のためには、エアバッグ展開時に縫合部での破壊が生じず、かつ、ガス漏れが実質的にないことが要求される。
 縫製糸は1本の片撚りでも、片撚りした繊維を2本以上撚り合わせた諸撚りであってもよく、構成する撚り後の繊維の総繊度は700~2000dtexが好ましい。
 また、縫合方法には本縫いや環縫い等を用いることができる。運針数(縫いピッチ)は30~60針/10cmが好ましい。
[suture]
The stitching is not particularly limited as long as it is not broken when the airbag is inflated and deployed, but it is preferably machine-sewn with sewing thread made of multifilament fiber of the same material as the base fabric panel. As described above, in order to maintain the internal pressure, it is required that the stitching does not break when the airbag is deployed and that there is substantially no gas leakage.
The sewing thread may be a single twisted fiber or a multiple twisted fiber having two or more single twisted fibers twisted together, and the total fineness of the twisted fibers is preferably 700 to 2000 dtex.
The sewing method may be a lock stitch, a chain stitch, etc. The number of stitches (stitch pitch) is preferably 30 to 60 stitches/10 cm.
[半折りされたフィルム状非通気性保護材]
 図2は、縫合部でのガス漏れを防止するために、図1のA-A断面に相当する箇所を拡大し、従来技術においてシリコーン接着剤での接着部に縫合した場合のエアバッグ展開時の状態を説明する。シリコーン接着剤を用いる場合、展開時にシリコーン接着剤が変形し伸びてガスを封止することができ、内圧保持性は向上するものの、硬化後のシリコーン接着剤の厚みにより、エアバッグ折り畳み後(収容時)の厚みが大きくなるため収納性が悪化したり、その硬化に半日~約1日と長時間を要するため、エアバッグの生産性も低下する。
[Semi-folded non-breathable film-like protective material]
Fig. 2 is an enlarged view of the area corresponding to the A-A cross section in Fig. 1 to prevent gas leakage at the seams, and explains the state of an airbag when it is deployed if it is sewn to the area bonded with silicone adhesive in the conventional technology. When silicone adhesive is used, the silicone adhesive deforms and stretches during deployment to seal in the gas, improving the internal pressure retention, but the thickness of the silicone adhesive after curing increases the thickness of the airbag after folding (when stored), making it difficult to store, and it takes a long time, from half a day to about a day, to cure, reducing the productivity of the airbag.
 本実施形態の製法により、かかるシリコーン接着剤に代えて、1対の基布パネルの各々の内面に、該縫合近傍から袋体内部に向かって近位端と遠位端を有する所定幅の該縫合に沿う接着領域で、半折された帯状のフィルム状非通気性保護材の両端外面が、それぞれ、直線又は曲線を描き接着されており、該半折された非通気性フィルム状保護材は、第1表面層と第2表面層を含む2層以上の積層樹脂フィルムであり、かつ、該第1表面層は該基布パネルに溶着されているが、該第2表面層同士は、接着されていないか、あるいは、接着されているものの、該エアバッグの展開に際し、該1対の基布パネル同士に引張強力がかかる時、該第2表面層が剥離する、エアバッグを、高い生産性をもって製造することができる。
 エアバッグの展開に際しては、1対の基布パネル同士に引張強力がかかる時、該1対の基布パネルに沿った遠位端間の長さよりも、該半折された非通気性フィルム状保護材に沿った遠位端間の長さが、大きいか又はこれに等しいことが好ましい。
According to the manufacturing method of this embodiment, instead of using such a silicone adhesive, an airbag can be manufactured with high productivity in which both end outer surfaces of a folded, band-like, non-breathable film-like protective material are bonded to the inner surface of each of a pair of base fabric panels in an adhesive region of a predetermined width along the seam from the vicinity of the seam toward the inside of the bag body, the outer surfaces being bonded in a straight or curved line, the non-breathable film-like protective material being a laminated resin film of two or more layers including a first surface layer and a second surface layer, the first surface layer being welded to the base fabric panel, and the second surface layers being not bonded to each other, or being bonded to each other but causing the second surface layer to peel off when a tensile force is applied to the pair of base fabric panels when the airbag is deployed.
When the airbag is deployed, when a tensile force is applied between a pair of base fabric panels, it is preferable that the length between the distal ends along the folded non-breathable film-like protective material is greater than or equal to the length between the distal ends along the pair of base fabric panels.
 本実施形態の製法は、該エアバッグの外周全ての領域に用いることも、該エアバッグの一部に用いることもできる。ここで、一部とは、例えば、50%以上である。該エアバッグの一部にかかる製法を用いる場合、エアバッグ全体の気密性を得るために、例えば該エアバッグの他のガスリークを生じうる縫製部にシリコーン接着剤を用いる製法を選択することができる。また、かかる特徴の構造は、少なくとも2枚以上の基布パネルで構成されるエアバッグのうちの任意の2枚(1対)の基布パネルの縫合近傍において適用可能である。1対の基布パネルは必ずしも同一形状である必要はなく、接着領域の気密性が損なわれない範囲であれば、該1対の基布パネル同士の縫製ラインの形状が異なる立体縫製であってもよい。 The manufacturing method of this embodiment can be used for the entire outer periphery of the airbag, or for a portion of the airbag. Here, a portion means, for example, 50% or more. When using this manufacturing method for a portion of the airbag, a manufacturing method using, for example, silicone adhesive for the stitching that may cause other gas leaks in the airbag can be selected in order to ensure airtightness for the entire airbag. Furthermore, this characteristic structure can be applied to the vicinity of the stitching of any two (a pair) of base fabric panels of an airbag composed of at least two or more base fabric panels. The pair of base fabric panels do not necessarily need to have the same shape, and as long as the airtightness of the adhesive area is not compromised, the pair of base fabric panels may be three-dimensionally sewn with different shapes of stitching lines.
 本明細書中、用語「少なくとも1対の基布パネルが外周縁で縫合されてなるエアバッグ」とは、エアバッグの膨張気室(チャンバー)を形成すべく基布パネルを縫合したもので、気室の外周縁で2枚以上の基布パネルが縫合したエアバッグである。したがって、図1、図13に示すような、同一形状の基布パネルを2枚重ね合わせてできた、2枚の基布パネルのみで構成されるエアバッグに限定されず、気室の外周縁で2枚以上の基布パネルが繋ぎ合わせられている部分を有してさえいれば、エアバッグを構成する基布パネルの枚数や、エアバッグ全体の構造には限定されない。ここで、縫合される基布パネルは、少なくとも1対、つまり、少なくとも2枚であり、これらの縫合基布パネルは同布であっても異布であってもよい。例えば、1枚の線対称形の基布パネルを対称線で折り畳み、重ねた部分を縫合したものや、1枚の帯状の基布パネルを筒状に巻いて重なる部分を縫合したものや、3枚以上の基布パネルを縫合したものも、すなわち、基布パネルの縫合部を非通気性保護材で覆う部分構造を有する限り、広く包含する。 In this specification, the term "an airbag formed by sewing at least one pair of fabric panels together at their outer periphery" refers to an airbag in which the fabric panels are sewn together to form an inflation chamber for the airbag, and in which two or more fabric panels are sewn together at the outer periphery of the chamber. Therefore, the airbag is not limited to an airbag composed of only two fabric panels, which are made by overlapping two fabric panels of the same shape, as shown in Figures 1 and 13, and there is no limit to the number of fabric panels that make up the airbag or the overall structure of the airbag, as long as there is a portion where two or more fabric panels are joined together at the outer periphery of the chamber. Here, there is at least one pair of fabric panels to be sewn together, that is, at least two, and these sewn fabric panels may be made of the same fabric or different fabrics. For example, this broadly includes a single, line-symmetrical base fabric panel that is folded along the line of symmetry and the overlapping portions sewn together, a single, strip-shaped base fabric panel that is rolled into a tube and the overlapping portions sewn together, and three or more base fabric panels that are sewn together, that is, as long as the partial structure has a non-breathable protective material covering the sewn portions of the base fabric panels.
 本明細書中、用語「非通気性」とは、エアバッグの気密性を著しく損なわない程度に通気を抑制する保護材の表面特性を指す。保護材の表裏に500Paの差圧を与えたとき、表面を通過するガス量が0.5L/dm/min以下であることが好ましく、0.1L/dm/min以下がより好ましく、0.05L/dm/min以下がさらに好ましい。 In this specification, the term "non-breathable" refers to the surface property of a protective material that suppresses ventilation to a degree that does not significantly impair the airtightness of the airbag. When a differential pressure of 500 Pa is applied between the front and back of the protective material, the amount of gas passing through the surface is preferably 0.5 L/ dm2 /min or less, more preferably 0.1 L/ dm2 /min or less, and even more preferably 0.05 L/ dm2 /min or less.
 図3は、半折りされた非通気性保護材のエアバッグ展開時の状態を説明する。図3から分かるように、半折りされた非通気性保護材が、エアバッグの内側に向かってループ状形状を呈し、基布パネルとの接着領域で気密構造を形成するため、内圧保持性が発揮される。
 本実施形態の製法で製造しうるエアバッグでは、好ましくは、エアバッグ展開時の状態において、1対の基布パネルに沿った遠位端間の長さよりも、該半折された非通気性保護材に沿った遠位端間の長さが、大きいか又はこれに等しく、それにより該接着領域における気密構造が維持される。すなわち、図4(a)、(b)に示すように、ループ状の保護材が十分な長さを有するため、エアバッグ展開時に縫合部を起点として水平に引っ張られた時、保護材と基布パネルとの間の接着領域に、実質的に力がかからず、接着領域における剥離や破壊がないため、気密性が保持される。尚、非通気性フィルム状保護材の伸張性が高い場合には、エアバッグ展開前(エアバッグ収容時)の保護材のループの長さが、基布パネルに沿った接着間距離とほぼ同じまたは接着間距離よりも短い場合であっても、エアバッグ展開時にかかる引張力により非通気性保護材が伸長され、先に縫合部が破壊する場合には、接着領域に実質的に力がかからないため、同様の結果となる。
 エアバッグ展開時の状態は、例えば、以下の方法を用いることで模擬的に確認することが可能である。まず、収容されたエアバッグを取り出し、保護材と基布パネルの一部をカットし、図4(a)、(b)の展開時の状態に示すように1対の基布パネルを180°広げ、それぞれの基布パネルを把持して基布パネルに平行な方向に引っ張った時、保護材より先に縫合部が破壊されるかどうかを確認する。この時、引張方向に対して縫合部が略垂直になるように配置することに注意する。尚、前記したように、図4(a)は、第一のパターン、そして図4(b)は、第二のパターン(ループ外側、フィルム折り返し収納)であり、いずれのパターンであっても、エアバッグ展開時の状態において、1対の基布パネルに沿った遠位端間の長さよりも、該半折された非通気性保護材に沿った遠位端間の長さが、大きいか又はこれに等しく、それにより該接着領域における気密構造が維持される。
Fig. 3 illustrates the state of the semi-folded non-breathable protective material when the airbag is deployed. As can be seen from Fig. 3, the semi-folded non-breathable protective material presents a loop shape toward the inside of the airbag and forms an airtight structure in the bonded area with the base fabric panel, thereby exhibiting internal pressure retention.
In the airbag that can be manufactured by the manufacturing method of this embodiment, the length between the distal ends along the folded non-breathable protective material is preferably greater than or equal to the length between the distal ends along a pair of base fabric panels when the airbag is deployed, thereby maintaining an airtight structure in the adhesive region. That is, as shown in Figures 4(a) and 4(b), since the loop-shaped protective material has a sufficient length, when the airbag is deployed and pulled horizontally from the seam, substantially no force is applied to the adhesive region between the protective material and the base fabric panel, and there is no peeling or destruction in the adhesive region, so that airtightness is maintained. Note that, when the non-breathable film-like protective material has high extensibility, even if the length of the loop of the protective material before the airbag is deployed (when the airbag is housed) is approximately the same as or shorter than the adhesive distance along the base fabric panels, the non-breathable protective material is stretched by the tensile force applied when the airbag is deployed, and if the seam is destroyed first, substantially no force is applied to the adhesive region, resulting in the same result.
The state of the airbag when it is deployed can be simulated by, for example, using the following method. First, the stored airbag is taken out, a part of the protective material and the base fabric panel are cut, and the pair of base fabric panels are spread 180° as shown in the deployed state in Figures 4(a) and (b). When each base fabric panel is grasped and pulled in a direction parallel to the base fabric panel, it is confirmed whether the seam is broken before the protective material. At this time, attention is paid to arranging the seam so that it is approximately perpendicular to the pulling direction. As described above, Figure 4(a) is the first pattern, and Figure 4(b) is the second pattern (loop outside, film folded back and stored). In either pattern, in the state when the airbag is deployed, the length between the distal ends along the half-folded non-breathable protective material is greater than or equal to the length between the distal ends along the pair of base fabric panels, thereby maintaining an airtight structure in the adhesive region.
 本明細書中、用語「半折りされた非通気性フィルム状保護材」とは、図4(a)、(b)の上段に示すような、エアバッグ収容時には、半折りされた状態となるもの、すなわち、1枚の帯状の単層又は多層樹脂フィルムやラミネート基布を半折りしたものだけでなく、蛇腹状などの複数回折り畳まれたものや、2枚の帯状(曲線状も含む)の単層又は多層樹脂フィルムやラミネート基布を重ねて、1端を接着剤で接着したり、溶着させたもの(すなわち、2枚貼り合わせ方法で作製したもの)をも包含する。ただし、保護材は、2枚貼り合わせ方法で製造するよりも、図8~10、12に示すように、半折りした帯状のフィルム等を、連続的に供給して熱溶着して製造する方が、生産性向上の観点から好ましい。 In this specification, the term "half-folded non-breathable film-like protective material" includes not only a material that is half-folded when housed in an airbag, as shown in the upper part of Figures 4(a) and (b), i.e., a material made by folding a strip-shaped single-layer or multi-layer resin film or laminate base fabric in half, but also a material that is folded multiple times, such as into an accordion-like shape, or a material made by overlapping two strip-shaped (including curved) single-layer or multi-layer resin film or laminate base fabric and bonding one end with an adhesive or welding (i.e., a material made by laminating two sheets). However, from the viewpoint of improving productivity, it is preferable to manufacture protective materials by continuously supplying half-folded strip-shaped films, etc., and heat welding them, as shown in Figures 8 to 10 and 12, rather than by laminating two sheets.
 かかる帯状の半折りされた非通気性フィルム状保護材は、縫合部に沿って、直線又は曲線状に基布に接着されるものである。本実施形態の製法においては、帯状の半折りされた非通気性フィルム状保護材を、所望の形状に樹脂フィルムを裁断したものを2枚用いて、多層フィルムの1端(内縁側)の外層同士(例えば、PE(第2表面層)-PA6/12(第1表面層)多層フィルムの場合、第2表面層の一部を剥いで、第1表面層同士)外縁からの長さが所定の長さになるように内縁に沿って、例えば、幅5mmで、溶着させるか、又は、例えば、シアノアクリレート系瞬間接着剤(コニシ(株)製)で貼り合わせ、十分に乾燥させて、(すなわち、帯状ではなく、例えば、図1に示す基布パネル形状(馬蹄形)に切り取った保護材の2枚貼り合わせ方法で)作製して接着しても構わないが、保護材は、2枚貼り合わせ方法で製造するよりも、図8~10に示すように、一枚ものの樹脂フィルムを半折りした帯状のものを、連続的に供給して張力を加えながら熱溶着して製造する方が、好ましい。なぜならば、2枚貼り合わせ方法では樹脂フィルムをエアバッグの縫製形状に沿って切り出す必要があるが、半折りした帯状の樹脂フィルムを用いることで、フィルムの利用効率を最大限高めることができることに加え、フィルム同士を接着させる工程がないため、生産性を高めることができるからである。また、実際のエアバッグは折り畳まれた状態から瞬時に展開するため、展開初期等にはエアバッグの一部分が非常に速いインフレータガス流速に曝される場合があるが、1枚ものの樹脂フィルムを用いることで、樹脂フィルム同士の接着代が不要になることにより、接着代部分がガス流速に曝されて破壊されるのを防ぐことができる。さらには、樹脂フィルム同士を貼り合わせる必要がないため、半折りした帯状の樹脂フィルムに沿った遠位端間でのループ状の樹脂フィルムの厚みや硬さの変化が少なく、エアバッグ展開時に早いガス流速に曝されても、樹脂フィルム同士の接着界面等での厚みや硬さの変化箇所に応力集中が生じループ状構造が破壊されるのを防ぐことができる。加えて、1枚ものの樹脂フィルムを用いることで、2枚貼り合わせ方法と比較して、フィルム同士の接着によってフィルムが硬くなることを防ぐことができ、またフィルム同士の接着代が不要になることで、エアバッグを軽量化し、エアバッグの収納性を改善させることができる。 Such a band-shaped, semi-folded, non-breathable film-like protective material is adhered to the base fabric in a straight or curved manner along the seams. In the manufacturing method of the present embodiment, two sheets of a band-shaped non-breathable film-like protective material are used, which are obtained by cutting a resin film into a desired shape, and the outer layers of one end (inner edge side) of the multilayer film are welded together (for example, in the case of a PE (second surface layer)-PA6/12 (first surface layer) multilayer film, a part of the second surface layer is peeled off and the first surface layers are welded together) along the inner edge so that the length from the outer edge is a predetermined length, for example, a width of 5 mm, or the sheets are bonded together with, for example, a cyanoacrylate-based instant adhesive (manufactured by Konishi Co., Ltd.) and thoroughly dried (that is, a method of bonding two protective materials cut into a base fabric panel shape (horseshoe shape) as shown in FIG. 1, rather than a band-shaped protective material), but it is preferable to manufacture the protective material by continuously supplying a band-shaped sheet of resin film folded in half and heat welding it while applying tension, as shown in FIGS. 8 to 10, rather than by manufacturing the protective material by a two-sheet bonding method. This is because, while the two-sheet lamination method requires cutting out the resin film along the sewing shape of the airbag, the use of a half-folded belt-shaped resin film can maximize the efficiency of film utilization, and can increase productivity because there is no need to bond the films together. In addition, since an actual airbag is deployed instantly from a folded state, a part of the airbag may be exposed to a very fast inflator gas flow rate at the initial stage of deployment, etc., but by using a single resin film, the adhesive margin between the resin films is not required, and it is possible to prevent the adhesive margin from being exposed to the gas flow rate and being destroyed. Furthermore, since it is not necessary to bond the resin films together, there is little change in thickness and hardness of the loop-shaped resin film between the distal ends along the half-folded belt-shaped resin film, and even if the airbag is exposed to a fast gas flow rate when it is deployed, stress concentration occurs at the part where the thickness and hardness change at the adhesive interface between the resin films, etc., and the loop-shaped structure is prevented from being destroyed. In addition, by using a single resin film, compared to the two-film lamination method, it is possible to prevent the film from becoming hard due to adhesion between the films, and by eliminating the need for adhesion between the films, it is possible to reduce the weight of the airbag and improve the storability of the airbag.
 半折りされた非通気性保護材として樹脂フィルムを用いることにより、後述する連続的に供給して張力を加えながら熱溶着して製造する方法を用いることで、1枚ものの非通気性保護材であったとしても、曲線部(R部、逆R部を含む)も皺なく溶着することができ、優れた気密性を有するエアバッグとすることができる。 By using a resin film as the half-folded non-breathable protective material and using the manufacturing method described below of continuously supplying and heat welding while applying tension, even curved sections (including R sections and reverse R sections) can be welded without wrinkles, even if it is a single sheet of non-breathable protective material, making it possible to produce an airbag with excellent airtightness.
 非通気性フィルム状保護材としては、エアバッグの膨張・展開時に破壊されない限り特に制限はなく、単層又は多層樹脂フィルムを用いることができる。エアバッグの軽量化及びコンパクト性(折り畳み性、収納性)の観点から、非通気性保護材として単層又は多層樹脂フィルムを用いることが好ましい。非通気性フィルム状保護材として単層又は多層樹脂フィルムを用いる際、それらと同種の単層又は多層樹脂フィルムをラミネートした基布パネルと接着させることで、接着力を高めエアバッグの内圧保持性を高めることができる。さらには、非通気性保護材に用いる単層又は多層樹脂フィルム(及び基材)と基布パネルを同種とすることで、リサイクル性を高めることができる。 There are no particular limitations on the non-breathable film-like protective material, so long as it is not destroyed when the airbag is inflated and deployed, and single-layer or multi-layer resin films can be used. From the viewpoint of reducing the weight and compactness (ease of folding and storage) of the airbag, it is preferable to use single-layer or multi-layer resin films as the non-breathable protective material. When using single-layer or multi-layer resin films as the non-breathable film-like protective material, the adhesive strength can be increased by bonding the same type of single-layer or multi-layer resin film to a laminated base fabric panel, thereby improving the internal pressure retention of the airbag. Furthermore, by using the same type of single-layer or multi-layer resin film (and substrate) used in the non-breathable protective material and the base fabric panel, recyclability can be improved.
 本明細書中、用語「接着」とは、接着剤による接着や、超音波又は熱による溶着を包含する。以下のエアバッグの製造方法の欄で説明するように、基布パネルの材質と半折りされた非通気性保護材の外側層の材質が同種であれば、加熱や超音波の適用による溶着により、基布パネルと保護材とを接着して、エアバッグ展開時であっても剥離せず、気密性を保持することができる接着領域を形成することができる。接着剤を使用しない溶着は、折り畳み後の厚みや生産性、リサイクル等の観点から、好ましい。 In this specification, the term "bonding" includes bonding with an adhesive and welding with ultrasonic waves or heat. As explained in the section on the manufacturing method of the airbag below, if the material of the base fabric panel and the material of the outer layer of the semi-folded non-breathable protective material are the same, the base fabric panel and the protective material can be bonded together by welding using heat or ultrasonic waves to form a bonded area that will not peel off even when the airbag is deployed and can maintain airtightness. Welding without using adhesives is preferable from the standpoint of thickness after folding, productivity, recycling, etc.
 図4(a)、(b)に示すように、用語「接着領域(5、5’)」は、縫合部(2)に対して、それぞれ、近位端(6、6’)と遠位端(7、7’)を有する。図4(a)に示すように、近位端(6、6’)は、縫合部(2)からエアバッグの内側に位置しても、あるいはエアバッグの外側に位置しても構わない。後者の場合、接着領域は縫代まで延びることになる。
 さらには、図4(b)に示すように、接着領域において半折りされた非通気性保護材のループ構造がエアバッグ外縁部(エアバッグの外側)を向くように配置しても構わない。エアバッグ展開時の状態において、半折りされた非通気性保護材が、エアバッグの内側に向かってループ状形状を呈し、1対の基布パネルに沿った遠位端間の長さよりも、該半折された非通気性保護材に沿った遠位端間の長さが大きくなり、基布パネルとの接着領域で気密構造を、図4(a)の場合と同様に形成できるためである。但し、保護材を接着後、エアバッグ外縁部を縫製する場合、保護材の内圧保持に寄与する部分を縫製により傷つけないようにするためには、非通気性保護材のループ構造がエアバッグの内側を向くように配置するのが好ましい。
 「接着領域」は、エアバッグ膨張・展開時に破壊・剥離されず、気密性・内圧保持性を保持するように接着されていればよい。
As shown in Figures 4(a) and (b), the term "bonded area (5, 5')" has a proximal end (6, 6') and a distal end (7, 7') with respect to the seam (2), respectively. As shown in Figure 4(a), the proximal end (6, 6') may be located on the inside of the airbag from the seam (2) or on the outside of the airbag. In the latter case, the bonded area will extend to the seam allowance.
Furthermore, as shown in Fig. 4(b), the loop structure of the non-breathable protective material folded in half in the adhesive region may be arranged so as to face the outer edge of the airbag (outside of the airbag). In the state when the airbag is deployed, the half-folded non-breathable protective material has a loop shape toward the inside of the airbag, and the length between the distal ends along the half-folded non-breathable protective material is greater than the length between the distal ends along a pair of base fabric panels, so that an airtight structure can be formed in the adhesive region with the base fabric panels as in the case of Fig. 4(a). However, when sewing the outer edge of the airbag after adhering the protective material, in order to prevent the part that contributes to maintaining the internal pressure of the protective material from being damaged by sewing, it is preferable to arrange the loop structure of the non-breathable protective material so as to face the inside of the airbag.
The "bonded region" need only be bonded in such a way that it will not be destroyed or peeled off when the airbag inflates and deploys, and that it maintains airtightness and internal pressure retention.
 本実施形態の製法で製造しうるエアバッグでは、非通気性フィルム状保護材の厚みは、折り畳み厚みの観点から、0.001mm以上0.5mm以下であることが好ましく、より好ましくは0.001mm以上0.1mm以下である。 In the airbag that can be manufactured by the manufacturing method of this embodiment, the thickness of the non-breathable film-like protective material is preferably 0.001 mm or more and 0.5 mm or less, and more preferably 0.001 mm or more and 0.1 mm or less, from the viewpoint of the folded thickness.
 本実施形態の製法で製造しうるエアバッグでは、基布パネルと非通気性フィルム状保護材との間の接着領域における接着強度(剥離強度)は、気密性の観点から、1N/cm以上が好ましく、より好ましくは3N/cm以上である。接着強度が3N/cm以上であれば、エアバッグ展開時にガスの風圧でフィルムがパネル基布から剥離することに因るリークの発生が大幅に低下する。 In the airbag that can be manufactured by the manufacturing method of this embodiment, the adhesive strength (peel strength) in the adhesive region between the base fabric panel and the non-breathable film-like protective material is preferably 1 N/cm or more, and more preferably 3 N/cm or more, from the viewpoint of airtightness. If the adhesive strength is 3 N/cm or more, the occurrence of leaks caused by the film peeling off from the panel base fabric due to the wind pressure of the gas when the airbag is deployed is significantly reduced.
 前記半折された帯状の非通気性保護材の引張弾性率は、MD(機械方向)、TD(横方向)共に100~800MPaであることが好ましく、150~600MPaであることがさらに好ましく、200~500MPaであることが一層好ましい。ただし、ここで言うフィルムの引張弾性率は帯状の非通気性フィルム状保護材を半折された状態から開いて引っ張った際の測定結果である。帯状の非通気性フィルム状保護材を、張力を付与することで、曲線状の外周縁に沿うように変形させる際、上記の引張弾性率(柔軟性)を有することで、エアバッグのメイン布において通常用いられる曲線部(R部、逆R部を含む)に沿うよう曲線構造を形成させやすい。引張弾性率を100~800MPaとすることで、適度な柔軟性により、ハンドリング性(曲線部での変形のさせやすさとフィルムの取り回しのバランス)のよいフィルムとなる。また、フィルムに必要な耐久性として、フィルムの引張破断強度は、耐久性の観点から、MD、TD共に10~100MPaであることが好ましく、より好ましくは15~80MPaであり、更に好ましくは20~60MPaである。引張破断強度を100MPa以下とすることで、剛性をおさえ、ハンドリング性のよいフィルムとなる。さらに、帯状の非透気通気性フィルム状保護材を、張力を付与することで、曲線状の外周縁に沿うように変形させる際、熱を与えることでフィルムを伸長させやすくすることができる点で、熱可塑性樹脂フィルムを用いることが好ましい。 The tensile modulus of the semi-folded band-shaped non-breathable protective material is preferably 100 to 800 MPa in both MD (machine direction) and TD (transverse direction), more preferably 150 to 600 MPa, and even more preferably 200 to 500 MPa. However, the tensile modulus of the film referred to here is the measurement result when the band-shaped non-breathable film-like protective material is opened from the half-folded state and pulled. When the band-shaped non-breathable film-like protective material is deformed to follow the curved outer edge by applying tension, the above tensile modulus (flexibility) makes it easy to form a curved structure to follow the curved parts (including R parts and reverse R parts) that are usually used in the main fabric of an airbag. By setting the tensile modulus to 100 to 800 MPa, the film has good handleability (balance between ease of deformation at curved parts and handling of the film) due to moderate flexibility. In addition, in terms of the durability required for the film, the tensile breaking strength of the film is preferably 10 to 100 MPa in both MD and TD from the viewpoint of durability, more preferably 15 to 80 MPa, and even more preferably 20 to 60 MPa. By setting the tensile breaking strength to 100 MPa or less, the rigidity is suppressed and the film has good handling properties. Furthermore, when the band-shaped non-permeable and breathable film-like protective material is deformed to follow the curved outer peripheral edge by applying tension, it is preferable to use a thermoplastic resin film, since the film can be easily stretched by applying heat.
 本実施形態のエアバッグは、前記接着領域において、図1、図13、に示すように、接着領域において、曲率半径300mm以下のR部、及び/又は曲率半径300mm以下の逆R部を有することができる。
 ここで、R部とは、基布パネルの外周縁に沿った縫合線のうちエアバッグの膨張部(チャンバー)側ではない方に凸の曲線形状となる部分である。例えば、図1のX部位が該当する。一方、逆R部とは、基布パネルの外周縁に沿った縫合線のうちエアバッグの膨張部(チャンバー)側に凸の曲線形状となる部分である。例えば、図1のY部位が該当する。 かかるR部、逆R部を含む曲線縫合部では、直線縫合部と比較して非通気性保護材を縫合線に沿うように接着させる際に皺が発生しやすく、またエアバッグの展開時には縫製部への張力がかかりやすい。非通気性保護材の接着時の皺の発生の程度は、皺部と正常部の段差(山谷差)を測定することで確認できる。かかるR部の皺部と正常部の段差(山谷差)は、400μm以下であることが好ましく、300μm以下であることがより好ましく、200μm以下であることがさらに好ましく、100μm以下であることが一層好ましい。R部の表面段差(山谷差)が400μm以下であることで、皺部と正常部の段差を小さくして応力集中を防ぐことができ、接着部からのガスリークを抑制し、収納性に優れたエアバッグとすることができる。
 また、前記R部の皺部と正常部の段差(山谷差)と、該R部を除く略直線部の皺部と正常部の段差(山谷差)の比(R部/直線部)が、0.6~2.0であることが好ましく、0.8~1.5であることがさらに好ましい。
The airbag of this embodiment may have, in the adhesive region, an R portion with a curvature radius of 300 mm or less and/or an inverse R portion with a curvature radius of 300 mm or less, as shown in FIG. 1 and FIG.
Here, the R portion is a portion of the seam line along the outer periphery of the base fabric panel that is curved convexly toward the side other than the inflatable portion (chamber) of the airbag. For example, the X portion in FIG. 1 corresponds to this. On the other hand, the reverse R portion is a portion of the seam line along the outer periphery of the base fabric panel that is curved convexly toward the inflatable portion (chamber) of the airbag. For example, the Y portion in FIG. 1 corresponds to this. In curved seams including such R portions and reverse R portions, wrinkles are more likely to occur when the non-breathable protective material is adhered along the seam line than in straight seams, and tension is more likely to be applied to the sewn portion when the airbag is deployed. The degree of wrinkles when the non-breathable protective material is adhered can be confirmed by measuring the step (peak-valley difference) between the wrinkled portion and the normal portion. The step (peak-valley difference) between the wrinkled portion and the normal portion of such R portion is preferably 400 μm or less, more preferably 300 μm or less, even more preferably 200 μm or less, and even more preferably 100 μm or less. By making the surface step (peak-to-valley difference) of the R portion 400 μm or less, the step between the wrinkled portion and the normal portion can be made small, thereby preventing stress concentration, suppressing gas leakage from the adhesive portion, and resulting in an airbag with excellent storage properties.
In addition, the ratio (R portion/straight portion) of the step (peak-valley difference) between the wrinkled portion and the normal portion of the R portion to the step (peak-valley difference) between the wrinkled portion and the normal portion of the approximately straight portion excluding the R portion is preferably 0.6 to 2.0, and more preferably 0.8 to 1.5.
 尚、皺の段差測定は(株)ミツトヨ製の表面粗さ測定機(SURFTEST EXTREME SV-3000CNC)を用い、皺発生部位とその周辺の正常部を三次元モードで下記の測定条件に従い測定した。得られた三次元画像において任意断面抽出機能を使用し、最も大きい段差部位が含まれるように断面を抽出し、該抽出断面(2次元)において皺部(段差)の始点と終点を繋ぐベースラインを引き、該ベースラインからの最大高さを求めた。
(表面粗さ測定条件)
・測定長さ:10mm
・測定幅:5mm
・測定速度:5mm/sec
・サンプリングピッチ:1μm
・サンプリング間隔:50μm
・スタイラス:半径=10μm(コードNo.12AAB415)
(画像処理)
・トレンド補正「平面」のみ実施
The wrinkle step measurement was performed using a surface roughness measuring instrument (SURFTEST EXTREME SV-3000CNC) manufactured by Mitutoyo Corporation, and the wrinkled area and the surrounding normal area were measured in three-dimensional mode under the following measurement conditions. An arbitrary cross-section extraction function was used in the obtained three-dimensional image to extract a cross-section that included the largest step area, and a baseline was drawn on the extracted cross-section (two-dimensional) connecting the start point and end point of the wrinkled area (step), and the maximum height from the baseline was determined.
(Surface roughness measurement conditions)
Measurement length: 10 mm
Measurement width: 5 mm
Measurement speed: 5 mm/sec
Sampling pitch: 1 μm
Sampling interval: 50 μm
Stylus: radius = 10 μm (Code No. 12AAB415)
(Image processing)
-Trend correction is only performed on the "plane"
 図5~7に示すように、基布パネルと保護材との加熱による熱溶着に際し、保護材として単層の樹脂フィルムを用いる場合、ループの内側に剥離紙を挿入すれば、接着領域の気密性を保持できる十分なループ長の保護材を接着することが可能となる。剥離紙の素材に特に限定はなく、単層の樹脂フィルム同士の接着を防ぐことができるものであれば、紙、布、フィルムなどが使用できる。
 上記構成と比較して、半折りの帯状の保護材として多層樹脂フィルムを用い、剥離紙を用いずに、ループ内側の第2表面層同士が、接着されていないか、あるいは、熱溶着又は超音波溶着により溶着されているものの、該エアバッグの展開に際し、該1対の基布パネル同士に引張強力がかかる時、該第2表面層が剥離するように構成した方が、剥離紙の挿入及び/又は除去の工程が不要になる点、剥離紙の素材や物性の検討及びその取り扱いが不要となる点、また、張力の調整が容易になる点で、エアバッグの生産性が向上する。また、かかる構成とすることで、エアバッグの縫製形状によって、曲線や円形の形状の縫製の剥離紙を取り出すことが困難な場合であっても、剥離紙がエアバッグ中に残らないため、エアバッグの重量増加や収納性の悪化を招くことがなく、また剥離紙がエアバッグの展開速度や展開挙動に影響を及ぼすことを避けることができる。
As shown in Figures 5 to 7, when a single-layer resin film is used as the protective material during thermal welding by heating the base fabric panel and the protective material, if a release paper is inserted inside the loop, it becomes possible to bond the protective material with a loop length sufficient to maintain airtightness in the bonding area. There are no particular limitations on the material of the release paper, and paper, cloth, film, etc. can be used as long as it can prevent the bonding of the single-layer resin film to each other.
In comparison with the above configuration, a multilayer resin film is used as the half-folded belt-shaped protective material, and a release paper is not used, and the second surface layers on the inside of the loop are not bonded to each other or are welded by heat welding or ultrasonic welding, but when a tensile force is applied to the pair of base fabric panels when the airbag is deployed, the second surface layers are peeled off, which improves the productivity of the airbag in that the process of inserting and/or removing the release paper is not required, the consideration of the material and physical properties of the release paper and its handling are not required, and the tension can be easily adjusted. Furthermore, with this configuration, even if it is difficult to remove the release paper from the sewn airbag in a curved or circular shape due to the sewing shape of the airbag, the release paper does not remain in the airbag, so that the weight of the airbag does not increase and the storability does not deteriorate, and the release paper can be prevented from affecting the deployment speed and deployment behavior of the airbag.
 かかる構成は、例えば、半折された非通気性フィルム状保護材である積層樹脂フィルムの第1表面層を構成する樹脂の融点が、第2表面層を構成する樹脂の融点よりも、50℃~160℃、好ましくは60℃から160℃低いものとして、ループ内側の第2表面層同士が溶着されないようにするか、あるいは、半折された非通気性フィルム状保護材である積層樹脂フィルムの第1表面層を構成する樹脂、第2表面層を構成する樹脂、及びそのほかの層を構成する樹脂の各SP値の差を、隣接する層間において、2.0[cal/cm)1/2]以上の差として、いずれかの層間で層間剥離を生じさせるか、又は隣接する層から第2表面層が剥離するようにすることで、達成することができる。 Such a configuration can be achieved, for example, by setting the melting point of the resin constituting the first surface layer of the laminated resin film, which is a non-breathable film-like protective material folded in half, to be 50°C to 160°C, and preferably 60°C to 160°C, lower than the melting point of the resin constituting the second surface layer, so that the second surface layers on the inside of the loop are not welded to each other, or by setting the difference in SP value of the resin constituting the first surface layer, the resin constituting the second surface layer, and the resin constituting the other layer of the laminated resin film, which is a non-breathable film-like protective material folded in half, to be 2.0 [cal/ cm3 ) 1/2 ] or more between adjacent layers, so that delamination occurs between any of the layers, or the second surface layer delaminates from an adjacent layer.
 すなわち、前記半折された非通気性フィルム状保護材である積層樹脂フィルムの第1表面層と第2表面層を含む多層フィルムにおいて、いずれかの隣接する層間のSP値の差が、2.0[cal/cm)1/2]以上であることが好ましく、より好ましくは2.5[cal/cm)1/2]以上であり、さらに好ましくは3.0[cal/cm)1/2]以上であり、一層好ましくは4.0[cal/cm)1/2]以上である。 That is, in a multilayer film including a first surface layer and a second surface layer of the laminated resin film which is the half-folded non-breathable film-like protective material, the difference in SP value between any adjacent layers is preferably 2.0 [cal/ cm3 ) 1/2 ] or more, more preferably 2.5 [cal/ cm3 ) 1/2 ] or more, even more preferably 3.0 [cal/ cm3 ) 1/2 ] or more, and even more preferably 4.0 [cal/ cm3 ) 1/2 ] or more.
 以下、図17を参照しながら、かかる構成を説明する。
 例えば、PA6/12の融点は128℃、TPEEの融点は216℃、PA6/66の融点は194℃、PA12エラストマーの融点は176℃、PO(酸変性ポリエチレン)の融点は120℃、PE(LDPE)の融点は110℃なので、TPEE(第2表面層)-PA6/12(第1表面層)多層フィルム、TPEE-PO-PA6/12多層フィルム、PA6/66-PO-PA6/12多層フィルムを保護材として用いれば、第1表面層を構成する樹脂の融点と、第2表面層を構成する樹脂の融点との差を、50℃以上にすることができる。
 ここで融点差の好ましい範囲としては、50℃~160℃であり、より好ましくは60℃~160℃、更に好ましくは80℃~160℃である。融点差を50℃以上にすることにより、基布パネルとの接着強度を高めると共に第2表面同士の融着が起こり難くすることができる接着温度の範囲を広くとることができ、生産安定性が向上する。また、融点差を160℃以下にすることにより、例えば、インフレーション成形によりフィルムを作製する際、流れ斑と溶融張力が適正に維持されるため製膜の安定性が向上する。
 また、保護材を構成する樹脂の融点は90℃以上であることが好ましく、より好ましくは100℃以上、更に好ましくは110℃以上である。融点を90℃以上にすることで、車内温度が高温状態になっても十分な接着強度を維持することができる。
Hereinafter, such a configuration will be described with reference to FIG.
For example, the melting point of PA6/12 is 128°C, that of TPEE is 216°C, that of PA6/66 is 194°C, that of PA12 elastomer is 176°C, that of PO (acid-modified polyethylene) is 120°C, and that of PE (LDPE) is 110°C. Therefore, by using a TPEE (second surface layer)-PA6/12 (first surface layer) multilayer film, a TPEE-PO-PA6/12 multilayer film, or a PA6/66-PO-PA6/12 multilayer film as the protective material, the difference in melting point between the resin constituting the first surface layer and the resin constituting the second surface layer can be made 50°C or more.
Here, the preferred range of the melting point difference is 50°C to 160°C, more preferably 60°C to 160°C, and even more preferably 80°C to 160°C. By making the melting point difference 50°C or more, the adhesive strength with the base fabric panel can be increased and the range of adhesion temperatures at which fusion between the second surfaces can be made difficult to occur can be widened, improving production stability. In addition, by making the melting point difference 160°C or less, for example, when producing a film by inflation molding, flow unevenness and melt tension are appropriately maintained, improving film formation stability.
The melting point of the resin constituting the protective material is preferably 90° C. or higher, more preferably 100° C. or higher, and even more preferably 110° C. or higher. By making the melting point 90° C. or higher, sufficient adhesive strength can be maintained even when the temperature inside the vehicle becomes high.
 また、例えば、PEのSP値は8.1[cal/cm)1/2]、PA6/66のSP値は13.6[cal/cm)1/2]、PA6/12のSP値は13.6[cal/cm)1/2]、PETのSP値は10.7[cal/cm)1/2]なので、PE(第2表面層)-PA6/66(多層フィルムである第1表面層の剥離層側)又はPE(第2表面層、剥離層)-PET(第1表面層)を保護材として用いれば、それぞれ、PA基布又はPET基布のSP値との差を、2.0[cal/cm)1/2]以上にすることができる。 For example, the SP value of PE is 8.1 [cal/cm 3 ) 1/2 ], the SP value of PA6/66 is 13.6 [cal/cm 3 ) 1/2 ], the SP value of PA6/12 is 13.6 [cal/cm 3 ) 1/2 ] and the SP value of PET is 10.7 [cal/cm 3 ) 1/2 ], so if PE (second surface layer)-PA6/66 (release layer side of the first surface layer, which is a multilayer film) or PE (second surface layer, release layer)-PET (first surface layer) is used as the protective material, the difference in SP value with the PA base fabric or PET base fabric, respectively, can be made 2.0 [cal/cm 3 ) 1/2 ] or more.
 例えば、図17の右側の図(SP値差)の場合、第1表面層(基布パネル側)は、接着層(PA6/12)で構成され、他方、第2表面層(ループ内側)は、剥離層(PE)で構成され、他に中間層(酸変性PE)と高融点層(PA6/66)を含む4層で構成されていると考えることができる。ここで、高融点層(PA6/66)と剥離層(PE)の間のSP値の差だけでなく、第1表面層を構成する接着層(PA6/12)、X層(例えば、中間層(酸変性PE))、及び高融点層(PA6/66)のいずれかの隣接する層間のSP値の差が2.0[cal/cm)1/2]以上であっても、前記剥離効果が奏されることに留意すべきである。 For example, in the case of the diagram on the right side of Fig. 17 (SP value difference), the first surface layer (fabric panel side) can be considered to be composed of an adhesive layer (PA6/12), while the second surface layer (inside the loop) can be considered to be composed of four layers including a release layer (PE), an intermediate layer (acid-modified PE), and a high melting point layer (PA6/66). It should be noted that the release effect can be achieved not only when the SP value difference between the high melting point layer (PA6/66) and the release layer (PE) is greater than or equal to 2.0 [cal/cm3)1/2], but also when the SP value difference between any of the adjacent layers constituting the first surface layer, the adhesive layer (PA6/12), the X layer (e.g., the intermediate layer (acid-modified PE)), and the high melting point layer (PA6/66), is greater than or equal to 2.0 [cal/ cm3 ) 1/2 .
 上記SP値差による構成は、上記融点差による構成よりも好ましい。その理由は、融着(加工)温度をフィルムの融点以上に上げられるため、基布パネルとフィルムとの間の接着性をより強くすることができたり、加工速度を上げることで生産性を向上させることができるからである。 The above-mentioned configuration based on the SP value difference is preferable to the above-mentioned configuration based on the melting point difference. The reason for this is that the fusion (processing) temperature can be raised above the melting point of the film, making it possible to strengthen the adhesion between the base fabric panel and the film, and by increasing the processing speed, productivity can be improved.
 尚、SP値(Hildebrand溶解度パラメータ)とは、凝集エネルギー密度の平方根で定義される物性値であり、溶媒の溶解挙動を示すため、本願発明者らは、SP値の差が大きい組み合わせを、剥離層選定の指標として用いた。また、各種樹脂のSP値は、例えば、産業技術センター社 「各種規格と使い方のみちしるべ プラスチック材料試験方法・比較・評価・結果 P.32(2011年5月10日 第2版)に記載されており、また、SP値の計算方法の参考文献として「技術者のための実学高分子」講談社 89.8.1が挙げられる。 The SP value (Hildebrand solubility parameter) is a physical property defined as the square root of the cohesive energy density, and indicates the solubility behavior of a solvent. Therefore, the inventors of this application used combinations with large differences in SP value as indicators for selecting the release layer. The SP values of various resins are listed, for example, in "Guide to Various Standards and Usage: Plastic Material Test Methods, Comparisons, Evaluations, and Results" p. 32 (2nd edition, May 10, 2011) by Sangyo Gijutsu Center Co., Ltd., and a reference for calculating the SP value is "Practical Polymers for Engineers" by Kodansha, August 1, 1989.
 SP値には、前記SP値以外にハンセンの溶解度パラメータ(HSP)も一般的に用いられるパラメータである。実施例にはHSP値も併記したが、HSP値差においても1.0(cal/cm)1/2)以上にすることで前記剥離効果が奏される。
 ここで、HSPは(株)クロスアビリティ製のWinmostar(V9.3.0)による予測値であり、ある物質間において分散項(δD)、分極項(δP)、水素結合項(δH)により算出される。また、共重合組成物の場合のHSP算出は、各ホモポリマーのHSPを算出し、組成比(体積比率)を掛け合わせた時の値を合計した値である。
In addition to the SP value, the Hansen solubility parameter (HSP) is also a commonly used parameter. The HSP value is also shown in the examples, but the peeling effect can be achieved by making the HSP value difference 1.0 (cal/ cm3 ) 1/2 or more.
Here, HSP is a predicted value by Winmostar (V9.3.0) manufactured by CrossAbility Co., Ltd., and is calculated by the dispersion term (δD), polarization term (δP), and hydrogen bond term (δH) between certain substances. In addition, the HSP calculation for the copolymer composition is a value obtained by calculating the HSP of each homopolymer and multiplying it by the composition ratio (volume ratio) to obtain a total value.
 尚、上記融点差による構成は、高温環境下でのタッキングを回避し、エージング後の内圧保持性を保証する観点から、第2表面層(ループ内側)のガラス転移温度(Tg)は、好ましくは0℃以上であり、より好ましくは20℃以上、更に好ましくは30℃以上である。一方、柔軟性の観点からガラス転移温度の上限は80℃以下、より好ましくは70℃以下、更に好ましくは60℃以下である。 In addition, in order to avoid tacking in a high-temperature environment and ensure internal pressure retention after aging, the glass transition temperature (Tg) of the second surface layer (inside of the loop) is preferably 0°C or higher, more preferably 20°C or higher, and even more preferably 30°C or higher. On the other hand, in terms of flexibility, the upper limit of the glass transition temperature is 80°C or lower, more preferably 70°C or lower, and even more preferably 60°C or lower.
 以上のような製造方法を用いれば、1対の基布パネルが外周縁で縫合され袋体を形成するエアバッグにおいて、
 該1対の基布パネルの各々の内面に、該縫合近傍から袋体内部に向かって近位端と遠位端を有する所定幅の該縫合に沿う接着領域で、半折された帯状の非通気性フィルム状保護材の両端外面が、それぞれ、直線又は曲線を描き接着されており、該半折された非通気性フィルム状保護材は、第1表面層と第2表面層を含む2層以上の積層樹脂フィルムであり、かつ、該第1表面層は該基布パネルに溶着されているが、該第2表面層同士は、接着されていないか、あるいは、接着されているものの、該エアバッグの展開に際し、該1対の基布パネル同士に引張強力がかかる時、該第2表面層が剥離する、エアバッグを、高い生産性をもって提供することができる。
By using the above-described manufacturing method, in an airbag in which a pair of base fabric panels are sewn together at their outer periphery to form a bag body,
An airbag can be provided with high productivity in which both end outer surfaces of a folded, band-like, non-breathable film-like protective material are bonded to the inner surface of each of the pair of base fabric panels in an adhesive region of a predetermined width along the seam from near the seam toward the inside of the bag body, the outer surfaces being bonded in a straight or curved line, the folded, non-breathable film-like protective material being a laminated resin film of two or more layers including a first surface layer and a second surface layer, the first surface layer being welded to the base fabric panel, and the second surface layers being not bonded to each other, or being bonded to each other but causing the second surface layer to peel off when a tensile force is applied to the pair of base fabric panels when the airbag is deployed.
 本実施形態の製法において、フィルムを曲線状に溶着させる作業性(R加工性)のためには、フィルムの引張弾性率は、MD(機械方向)、TD(横方向)共に100~800MPaであることが好ましく、150~600MPaであることがさらに好ましく、200~500MPaであることが一層好ましい。ただし、ここで言うフィルムの引張弾性率は帯状の非透気通気性フィルム状保護材を半折された状態から開いて引っ張った際の測定結果である。帯状の非透気通気性フィルム状保護材を、張力を付与することで、曲線状の外周縁に沿うように変形させる際、上記の引張弾性率(柔軟性)を有することで、エアバッグのメイン布において通常用いられる曲線部に沿うよう曲線構造を形成させやすい。引張弾性率を100~800MPaとすることで、適度な柔軟性により、ハンドリング性(曲線部での変形のさせやすさとフィルムの取り回しのバランス)のよいフィルムとなる。また、フィルムに必要な耐久性として、フィルムの引張破断強度は、耐久性の観点から、MD、TD共に10~100MPaであることが好ましく、より好ましくは15~80MPaであり、更に好ましくは20~60MPaである。引張破断強度を100MPa以下とすることで、剛性をおさえ、ハンドリング性のよいフィルムとなる。さらに、帯状の非透気通気性フィルム状保護材を、張力を付与することで、曲線状の外周縁に沿うように変形させる際、熱を与えることでフィルムを伸長させやすくすることができる点で、熱可塑性樹脂フィルムを用いることが好ましい。 In the manufacturing method of this embodiment, for the ease of welding the film into a curved shape (R processability), the tensile modulus of the film is preferably 100 to 800 MPa in both MD (machine direction) and TD (transverse direction), more preferably 150 to 600 MPa, and even more preferably 200 to 500 MPa. However, the tensile modulus of the film referred to here is the measurement result when the band-shaped non-air-permeable and breathable film-like protective material is opened from a half-folded state and pulled. When the band-shaped non-air-permeable and breathable film-like protective material is deformed to fit the curved outer edge by applying tension, the above tensile modulus (flexibility) makes it easy to form a curved structure that fits the curved part that is usually used in the main fabric of an airbag. By setting the tensile modulus to 100 to 800 MPa, the film has a moderate flexibility and good handleability (balance between ease of deformation at curved parts and handling of the film). In addition, in terms of the durability required for the film, the tensile breaking strength of the film is preferably 10 to 100 MPa in both MD and TD from the viewpoint of durability, more preferably 15 to 80 MPa, and even more preferably 20 to 60 MPa. By setting the tensile breaking strength to 100 MPa or less, the rigidity is suppressed and the film has good handling properties. Furthermore, when the band-shaped non-permeable and breathable film-like protective material is deformed to follow the curved outer peripheral edge by applying tension, it is preferable to use a thermoplastic resin film, since the film can be easily stretched by applying heat.
 本実施形態の製造方法において、1対の基布パネルの直線又は曲線状の外周縁に沿って、帯状の非通気性フィルム状保護材を挟み込む方法としては、図8~10に例示するように、半折りフィルムを巻き取ったロールを予め用意し、かかる巻き取ったロールから、帯状の非通気性フィルム状保護材を熱溶着又は超音波溶着による溶着箇所に送り出す方法の他、前記半折された帯状の非通気性フィルム状保護材を半折りされていない状態で巻き取ったロールを予め用意し、かかる巻き取ったロールから、帯状の非通気性フィルム状保護材を熱溶着又は超音波溶着による溶着箇所に送り出す過程で半折させた後、かかる溶着箇所に送り出す方法、1対の基布パネルの直線又は曲線状の外周縁の長さに予めカットしておいた帯状の非通気性フィルム状保護材を半折りし、熱溶着又は超音波溶着による溶着箇所に送り出す方法などがあるが、1つ目の方法が好ましい。予め半折させたフィルムをロールに巻き取ることで、半折部のプリーツを強く固定することができ、且つ巻き取ったロールから連続的に送り出すことで、フィルムの半折部がずれにくくなったり、半折りフィルムの反り(カール)が抑制(上下でフィルム構成が対称となるため)されたりすることで、しわの発生が抑制される(品質向上)という更なる効果が期待できるためである。 In the manufacturing method of this embodiment, methods for sandwiching a strip-shaped non-breathable film-like protective material along the straight or curved outer peripheral edges of a pair of base fabric panels include a method of preparing a roll of half-folded film in advance and feeding the strip-shaped non-breathable film-like protective material from the wound roll to the welding point by heat welding or ultrasonic welding, as exemplified in Figures 8 to 10, a method of preparing a roll of the half-folded strip-shaped non-breathable film-like protective material in an unfolded state and feeding the strip-shaped non-breathable film-like protective material from the wound roll to the welding point by heat welding or ultrasonic welding, folding it in half during the process of feeding it to the welding point by heat welding or ultrasonic welding, and then feeding it to the welding point, and a method of folding in half a strip-shaped non-breathable film-like protective material that has been cut in advance to the length of the straight or curved outer peripheral edges of a pair of base fabric panels, and feeding it to the welding point by heat welding or ultrasonic welding, with the first method being preferred. By winding the film that has already been folded in half onto a roll, the pleats in the folded portion can be firmly fixed, and by continuously feeding the film from the wound roll, the folded portion of the film is less likely to shift, and warping (curling) of the folded film is suppressed (as the film structure is symmetrical between the top and bottom), which is expected to have the further effect of suppressing the occurrence of wrinkles (improving quality).
 かかる製造方法において、前記した半折フィルム(テープ)に張力をかける方法は特に限定されないが、例えば図17に示すように、一方の手でテープ、他方の手で基布を押さえながら、エアバッグの外周縁の形状に沿うようにテープにかかる張力を加減しながら引っ張る方法を用いることができる。あるいは、半折りフィルムを巻き取ったロールを予め用意し、かかる巻き取ったロールから、帯状の非通気性フィルム状保護材を熱溶着又は超音波溶着による溶着箇所に送り出す過程で張力制御機構を設けてもよい。 In this manufacturing method, the method of applying tension to the half-folded film (tape) is not particularly limited, but for example, as shown in Figure 17, a method can be used in which the tape is held down with one hand and the base fabric with the other while the tape is pulled while adjusting the tension applied to it so that it conforms to the shape of the outer periphery of the airbag. Alternatively, a roll of half-folded film may be prepared in advance, and a tension control mechanism may be provided during the process of sending the band-shaped non-breathable film-like protective material from the roll to the welding location by heat welding or ultrasonic welding.
 また、例えば、図10に示すように溶着箇所で基布を上下のコンベア式ベルトで挟み込み、コンベア式ベルトによって基布を搬送しながら、上下の熱板で挟み込みつつ熱を与えることで、連続的に溶着することができる。溶着箇所の近傍では、(基布に挟まれた)テープが加熱された状態となっており、張力がかかることでエアバッグの外周縁の形状に沿うようにテープが伸長し、R部、逆R部を含む曲線部であっても皺なく非透気通気性フィルム状保護材を接着させることができる。さらに、熱溶着又は超音波溶着による溶着の前に、熱板や熱風等の方法で非透気通気性フィルム状保護材の一部または全体を予熱することで、エアバッグの外周縁の形状に沿うようにテープを伸長させやすくすることができる。
 図10に示すように、溶着直後に冷却板による冷却部を設けてもよい。冷却部を設けることにより、非透気通気性フィルム状保護材の接着性が向上する。また、熱板及び冷却板の押し圧を間歇的に印加/解除することで、曲線部の溶着作業性を向上させることができる。
Also, for example, as shown in Fig. 10, the base fabric is sandwiched between upper and lower conveyor belts at the welding location, and while the base fabric is transported by the conveyor belt, it is sandwiched between upper and lower hot plates and heat is applied, so that continuous welding can be performed. In the vicinity of the welding location, the tape (sandwiched between the base fabrics) is in a heated state, and the tape is stretched to fit the shape of the outer periphery of the airbag by applying tension, so that the non-air-permeable and breathable film-like protective material can be bonded without wrinkles even in curved parts including R parts and reverse R parts. Furthermore, before welding by heat welding or ultrasonic welding, a part or the whole of the non-air-permeable and breathable film-like protective material can be preheated by a method such as a hot plate or hot air, so that the tape can be easily stretched to fit the shape of the outer periphery of the airbag.
As shown in Fig. 10, a cooling section using a cooling plate may be provided immediately after welding. By providing a cooling section, the adhesiveness of the non-permeable, breathable film-like protective material is improved. In addition, by intermittently applying and releasing the pressure of the hot plate and the cooling plate, the welding workability of the curved section can be improved.
 しかしながら、前記した半折フィルム(テープ)に、張力を付与しながら、これを、該1対の基布パネルの直線又は曲線状の外周縁に沿って、連続的に、挟み込みつつ、該1対の基布パネルの外側から、熱又は超音波を適用して接着する方法は、上下の基布を連続的に同時に接着するため、基布の位置ズレ等が発生しやすくなる場合がある。また、接着の最終盤や、エアバッグの縫製形状によってはスペースが狭く、上側基布の下に潜らせてテープを挿入する操作の作業性が悪化する場合がある。 However, the method of continuously sandwiching the half-folded film (tape) along the straight or curved outer periphery of the pair of base fabric panels while applying tension to the film and applying heat or ultrasonic waves from the outside of the pair of base fabric panels to bond the panels together may lead to misalignment of the base fabrics, as the upper and lower base fabrics are bonded together continuously and simultaneously. Also, in the final stages of bonding or depending on the sewing shape of the airbag, there may be a small space, which may make it difficult to insert the tape under the upper base fabric.
 そこで、前記した張力付加、挟み込み方法に代えて、1対の基布パネルの間にテープを挟み込むのではなく、基布1枚目の上にテープを片面接着(1Step)した後に、該テープの上に2枚目の基布を重ねて圧着する(2Step)という、以下の2Step方法を採用してもよい。 Instead of the tensioning and clamping method described above, the following two-step method may be used, in which, rather than clamping the tape between a pair of base fabric panels, one side of the tape is adhered to the first piece of base fabric (1st step), and then a second piece of base fabric is placed on top of the tape and compressed (2nd step).
[2Step方法]
 1の基布パネルの上に、所定幅の、第1表面層と第2表面層を含む2層以上の積層樹脂フィルムからなる半折された帯状の非通気性フィルム状保護材に、張力を付与しながら、これを、該1の基布パネルの直線又は曲線状の外周縁に沿って、連続的に、該1の基布パネルの下側から、熱又は超音波を適用して、該第1表面層を、該基布パネルの上面に溶着する溶着工程;
 該溶着されたフィルム状保護材の上に他の基布パネルを重ね、該重ねた基布パネルの上側から、熱又は超音波を適用して、該第1表面層を、該重ねた基布パネルの下面に溶着する溶着工程、ここで、該積層樹脂フィルムの第2表面層同士は、熱溶着又は超音波溶着により溶着されていないか、又は、熱溶着又は超音波溶着により溶着されているものの、該エアバッグの展開に際し、該基布パネル同士に引張強力がかかる時、該第2表面層が剥離する;
 前記接着の後、得られる溶着の領域の近傍で、該基布パネルを縫合する縫合工程;
を含む、前記製造方法。
[2-Step Method]
a welding step of applying heat or ultrasonic waves to a semi-folded band-shaped non-breathable film-like protective material of a predetermined width, which is made of a laminated resin film of two or more layers including a first surface layer and a second surface layer, on one of the base fabric panels, continuously along a straight or curved outer periphery of the one of the base fabric panels from below the one of the base fabric panels while applying tension to the material, thereby welding the first surface layer to an upper surface of the one of the base fabric panels;
a welding step of overlapping another base fabric panel on the welded film-like protective material and applying heat or ultrasonic waves from the upper side of the overlapped base fabric panel to weld the first surface layer to the lower surface of the overlapped base fabric panel, wherein the second surface layers of the laminated resin film are not welded to each other by thermal welding or ultrasonic welding, or are welded to each other by thermal welding or ultrasonic welding, but the second surface layer peels off when a tensile force is applied to the base fabric panels when the airbag is deployed;
a sewing step of sewing the fabric panels together adjacent the areas of the resulting welds after said bonding;
The manufacturing method comprising the steps of:
 2Step方法では、1対の基布パネルの間にテープを挟み込むのではなく、まず、1枚の基布パネルの上に張力付加をしながらテープを送り出し、下側からの加熱により1枚目基布の上にテープを溶着することで、1枚の基布パネルの上にテープを皺なく固定する(1step)。その後、該テープの上に2枚目の基布を重ねて、熱溶着又は超音波溶着による加熱により、圧着する(2step)。これにより、前記した上下の基布の同時操作が不要となるため1枚の基布のみの操作となり、また、テープを基布の間に挟み込まないため、接着の最終盤等でスペースが狭くなるという状態は発生しない。 In the 2-step method, instead of sandwiching the tape between a pair of base fabric panels, first the tape is fed onto one base fabric panel while applying tension, and then the tape is welded onto the first base fabric by heating from below, fixing the tape onto the one base fabric panel without wrinkles (1st step). A second base fabric is then placed on top of the tape, and pressure is applied by heating using thermal welding or ultrasonic welding (2nd step). This eliminates the need to simultaneously operate the upper and lower base fabrics as described above, and only one base fabric is operated, and because the tape is not sandwiched between the base fabrics, there is no problem with the space becoming narrow at the final stage of bonding, etc.
 かかる製造方法において、前記したテープに張力をかける方法は特に限定されず、前記した張力付加、挟み込み方法と同様に、一方の手でテープ、他方の手で基布を押さえながら、エアバッグの外周縁の形状に沿うようにテープにかかる張力を加減しながら引っ張る方法を用いることができる。あるいは、半折りフィルムを巻き取ったロールを予め用意し、かかる巻き取ったロールから、帯状の非通気性フィルム状保護材を熱溶着又は超音波溶着による溶着箇所に送り出す過程で張力制御機構を設けてもよい。かかる製造方法では、テープを基布の間に挟み込まないため、溶着機(ベルト熱圧着機)の熱板部に自動的にテープを挿入しながら連続的に溶着させる操作を行いやすいという利点がある。加熱部にテープを自動的に挿入することにより、手作業によるテープの位置ズレに因る加工不良の問題の発生が低減される。また、ベルト熱圧着機にテープを自動挿入する場合、基布側を送り込む際の方向転換によって、間接的にテープに張力を与え、エアバッグの外周縁の形状に沿うように溶着箇所の近傍でテープを伸長させることもできる。かかる製造方法においては、前記した張力付加、挟み込み方法と同様に、テープの一部または全体を予熱することや、冷却部を設けること、熱板及び冷却板の押し圧を間歇的に印加/解除することができる。テープの予熱においては、例えばベルト熱圧着機の下側からの熱板により1枚目基布の上にテープを溶着しながら、上側熱板による加熱によりR部、逆R部におけるテープの延伸補助を行うことができる。 In this manufacturing method, the method of applying tension to the tape is not particularly limited, and a method of pulling the tape while adjusting the tension applied to it so that it conforms to the shape of the outer periphery of the airbag can be used, similar to the above-mentioned tension application and clamping method, while holding the tape with one hand and the base fabric with the other hand. Alternatively, a roll of half-folded film may be prepared in advance, and a tension control mechanism may be provided in the process of sending the band-shaped non-breathable film-like protective material from the roll to the welding point by thermal welding or ultrasonic welding. In this manufacturing method, since the tape is not sandwiched between the base fabrics, there is an advantage that the operation of continuously welding the tape while automatically inserting it into the hot plate part of the welding machine (belt heat pressing machine) is easy to perform. By automatically inserting the tape into the heating part, the occurrence of processing defects due to the positional deviation of the tape caused by manual work is reduced. In addition, when the tape is automatically inserted into the belt heat pressing machine, tension can be indirectly applied to the tape by changing the direction when feeding the base fabric side, and the tape can be stretched near the welding point so as to conform to the shape of the outer periphery of the airbag. In this manufacturing method, like the tension application and clamping methods described above, it is possible to preheat part or all of the tape, provide a cooling section, and apply/release the pressure of the hot plate and cooling plate intermittently. When preheating the tape, for example, the tape can be welded onto the first base fabric by a hot plate from below the belt heat pressing machine, while the tape is heated by the upper hot plate to assist in stretching the tape in the R and reverse R sections.
 かかる製造方法において、前記した該テープの上に2枚目の基布を重ねて、熱溶着又は超音波溶着による加熱を行うための方法は特に限定されず、1Step目と同様にベルト熱圧着機を用いて連続的に溶着させてもよいし、溶着部を同時に加熱できる熱プレス機で一度に溶着させてもよいが、生産性の観点からは溶着部を同時に加熱できる熱プレス機を用いることが好ましい。かかる製造方法では、溶着部への加熱を2度行うため、1Step目は、仮止めとすることにより加工速度を向上させることができるという副次的効果が期待できる。 In this manufacturing method, the method for placing a second base fabric on the tape and heating it by thermal welding or ultrasonic welding is not particularly limited, and it may be continuously welded using a belt heat pressing machine as in the first step, or it may be welded all at once using a heat press machine that can heat the welded parts simultaneously, but from the viewpoint of productivity, it is preferable to use a heat press machine that can heat the welded parts simultaneously. In this manufacturing method, since the welded parts are heated twice, the first step is expected to have the secondary effect of improving the processing speed by temporarily fixing the parts.
[閉空間の孤立縫製部を含むエアバッグの製造方法]
 図13に示すような、閉空間の孤立縫製部において、張力付加、挟み込み方法を用いてエアバッグの内圧保持性を確保するためには、半折された帯状のフィルムの末端部(始点・終点のいずれも)が開放状態とならないよう作製する必要がある。そのため、以下の2つの方法を採用することができる。
 1つの方法は、図14に示すように、半折された帯状のフィルムを、余裕をもった所定長にカットし、両末端部を予め封止する(a)(例えば、内層のLDPEフィルムを剥いでから十分に時間をかけて熱圧着する)。その後、1の末端部を残して基布へ挟み込んで接着(熱溶着)を開始し(b)、最後に他の末端部を重ねて両末端同士を接着し(c)、その後に縫製する(d)方法である。縫製後の封止状態を図14に示す。
 2つ目の方法は、図15に示すように、半折された帯状のフィルムの両末端部を予め封止せずに、1の末端部を、縫製部となるべき点線を右側に跨いで(図15左端図参照)、基布へ挟み込んで接着(熱溶着)を開始し、最後に他の末端部を、同じく、縫製部となるべき点線を右側に跨いで重ねて、両末端同士を接着し、その後に縫製する方法である。図15右側端図に示すように、A-A’sectionとC-C’sectionのいずれにおいても、接着領域のにより、エアバッグが封止されていることが分かる。
 図15、16に例示するように、前記1対の基布パネルの各々の内面に、前記半折された帯状の非通気性保護材が重複して接着されており、かつ、該非通気性保護材の末端部が封止されている箇所が存在することができる。ここで、該非通気性保護材が「重複して接着されて」いるとは、複数の該非通気性保護材が重なって配置され、該非通気性保護材同士が接着されており、かつ、該1対の基布パネルの各々の内面に、基布パネルに最も近い該非通気性保護材が、それぞれ、接着されている状態をいう。例えば、図15、16に示すように、同一縫製部に対して該非通気性保護材をオーバーラップさせ、該非通気性保護材同士が接着させることや、分岐点を有する縫製形状において、一方の縫製線近傍に配置した半折された帯状の非通気性保護材と、他方の縫製線近傍に配置した半折された帯状の非通気性保護材を縫製分岐点近傍で部分的に重ね合わせて接着させることもできる。いずれの場合においても、該複数の非通気性保護材は一体となって該基布パネルの各々の内面に接着されたループ状構造を形成し、該1対の基布パネル同士に引張強力がかかる時、該1対の基布パネルに沿った遠位端間の長さよりも、該半折された非通気性保護材に沿った遠位端間の長さが、大きいか又はこれに等しい状態を形成することができる。
該非通気性保護材の「末端部が封止されている」とは、該複数の非通気性保護材の末端部が該エアバッグの膨張部(チャンバー)に対して開放されていない状態をいう。ここで、該非通気性保護材の末端部を封止する方法は特に限定されず、接着剤による接着、熱溶着、超音波溶着の他、該非通気性保護材を折り畳む等してもよい。また、図16に示すように末端部を膨張部(チャンバー)の外側に逃がす構造をとることもできる。
 かかる製造方法は、分岐点を有する縫製形状や、屈曲した縫製形状の近傍に半折された帯状の非通気性保護材を溶着させる場合や、エアバッグサイズが大きく、作業性等の観点で工程を分割する場合等に、意図的に半折された帯状の非通気性保護材のジョイント部を設ける方法として用いることができる。また、張力付加、挟み込み方法によらず、2Step方法や2枚貼り合わせ方法等に広く適用できる。
[Method of manufacturing an airbag including an isolated sewn portion in a closed space]
In order to ensure the internal pressure of the airbag by applying tension and sandwiching in an isolated sewn area in a closed space as shown in Fig. 13, it is necessary to fabricate the film so that the ends (both the start and end) of the folded strip of film are not open. For this purpose, the following two methods can be adopted.
One method is to cut a strip of film folded in half to a certain length with a margin, and seal both ends in advance (a) (for example, after peeling off the LDPE film of the inner layer, heat-pressure bonding is performed for a sufficient time). Then, one end is left and sandwiched between the base fabric to start adhesion (thermal welding) (b), and finally the other end is overlapped and both ends are adhered to each other (c), and then sewn (d). The sealed state after sewing is shown in Fig. 14.
In the second method, as shown in Fig. 15, instead of sealing both ends of the folded strip film in advance, one end is sandwiched between the base fabric and straddles the dotted line to the right of the sewn part (see the leftmost drawing in Fig. 15), and adhesion (thermal welding) is started, and finally the other end is overlapped, also straddles the dotted line to the right of the sewn part, and both ends are adhered to each other, and then sewn. As shown in the rightmost drawing in Fig. 15, it can be seen that the airbag is sealed by the adhesive area in both A-A'section and C-C'section.
As shown in Fig. 15 and Fig. 16, the half-folded band-shaped non-breathable protective material is adhered to the inner surface of each of the pair of base fabric panels in an overlapping manner, and the end of the non-breathable protective material may be sealed. Here, the non-breathable protective material is "adhered to the overlapping manner" means that a plurality of the non-breathable protective materials are arranged in an overlapping manner, the non-breathable protective materials are adhered to each other, and the non-breathable protective material closest to the base fabric panel is adhered to the inner surface of each of the pair of base fabric panels. For example, as shown in Fig. 15 and Fig. 16, the non-breathable protective materials may be overlapped at the same sewing portion and adhered to each other, or in a sewing shape having a branch point, a half-folded band-shaped non-breathable protective material arranged near one sewing line and a half-folded band-shaped non-breathable protective material arranged near the other sewing line may be partially overlapped and adhered near the sewing branch point. In either case, the multiple non-breathable protective materials are united to form a loop-shaped structure bonded to the inner surface of each of the base fabric panels, and when a tensile force is applied between the pair of base fabric panels, a state can be formed in which the length between the distal ends along the folded non-breathable protective materials is greater than or equal to the length between the distal ends along the pair of base fabric panels.
The term "sealed end portions" of the non-breathable protective material refers to a state in which the end portions of the plurality of non-breathable protective materials are not open to the inflatable portion (chamber) of the airbag. The method for sealing the end portions of the non-breathable protective materials is not particularly limited, and may be adhesion with an adhesive, heat welding, ultrasonic welding, or folding the non-breathable protective material. Also, as shown in FIG. 16, a structure in which the end portions are exposed to the outside of the inflatable portion (chamber) may be used.
This manufacturing method can be used as a method for intentionally providing a joint portion of a band-shaped non-breathable protective material folded in half when welding a band-shaped non-breathable protective material folded in half near a sewing shape having a branch point or a bent sewing shape, when the airbag size is large and the process is divided from the viewpoint of workability, etc. Moreover, regardless of the tension application or clamping method, it can be widely applied to the 2-step method, the two-sheet bonding method, etc.
 以下、実施例、比較例により本発明を具体的に説明する。
 まず、実施例、比較例に用いた材料、物性の測定方法等について説明する。
The present invention will be specifically described below with reference to examples and comparative examples.
First, the materials used in the examples and comparative examples, and the methods for measuring the physical properties will be described.
[(Si)コート(基)布]
 基布パネル及び/又は保護材として用いるSiコート布として、ナイロン66マルチフィラメント繊維を経糸と緯糸に用いて製織した平織物の片面にシリコーン樹脂を塗工したものを用いた。基布を構成する織糸の総繊度は470dtex、フィラメント数は136本であり、該コート布の織密度は49本/inch(2.54cm)で、シリコーン樹脂塗工量は25g/mであった。
[(Si) coated (base) fabric]
The Si-coated fabric used as the base fabric panel and/or protective material was a plain weave fabric woven using nylon 66 multifilament fibers as the warp and weft, with one side coated with silicone resin. The total fineness of the weaving yarn constituting the base fabric was 470 dtex, the number of filaments was 136, the weaving density of the coated fabric was 49/inch (2.54 cm), and the amount of silicone resin coated was 25 g/ m2 .
(フィルムの作製方法)
 保護材として用いるフィルムを以下のようにして作製した。
 図11に例示するように、多層サーキュラーダイを用い、インフレーション法により所望の多層フィルムを二枚重ね状態で3インチ紙管に巻き取った。この時、チューブ状フィルムの内面側3bが接着層、外面側3aが外層となるように製膜を行った。製膜条件は以下の通りであった。
  ダイ温度設定:210℃
  サーキュラーダイ:リップ外形=95mm、リップクリアランス=3mm
  ブローアップ比:1.1倍
  エアリング温度:22℃
  ピンチロール直前のフィルム表面温度:32℃
  サーキュラーダイ~ピンチロール間距離:2.4m
  引取速度:12m/分
(Film Preparation Method)
A film to be used as a protective material was prepared as follows.
As shown in Fig. 11, a multilayer circular die was used to wind a desired multilayer film in a two-ply state around a 3-inch paper tube by the inflation method. At this time, the film was formed so that the inner surface side 3b of the tubular film was the adhesive layer and the outer surface side 3a was the outer layer. The film formation conditions were as follows.
Die temperature setting: 210°C
Circular die: Lip outer diameter = 95 mm, lip clearance = 3 mm
Blow-up ratio: 1.1 times Air ring temperature: 22℃
Film surface temperature just before pinch rolling: 32°C
Distance between circular die and pinch roll: 2.4 m
Take-off speed: 12 m/min
(フィルムの原料)
(樹脂A)
PE:LDPE(旭化成製):商品名「サンテックLD F1920」(MFR=2.0、Tm=110℃、SP値=8.1(cal/cm)1/2、HSP値=18.0(cal/cm)1/2
(樹脂B)
PA6/12:商品名「Ube Nylon 7128B」(宇部興産製)ミド6/12共重合体(Tg=47℃、Tm=128℃、SP値=13.6(cal/cm)1/2、HSP値=20.7(cal/cm)1/2
(樹脂C)
PA6/66:商品名「Ube Nylon NAV503X10」(宇部興産社製) ポリアミド6/66共重合体(Tg=43℃、Tm=194℃、SP値=13.6(cal/cm)1/2、HSP値=22.8(cal/cm)1/2
(樹脂D)
m-PE:商品名「Admer NF528」(三井化学製)酸変性ポリエチレン(Tm=120℃)
(樹脂E)
POエラストマー:商品名「エンゲージ EG8100」(ダウケミカル日本製)(Tm=60℃、メルトインデックス=1.0g/10分(190℃/2.16kg)
(Film raw material)
(Resin A)
PE: LDPE (manufactured by Asahi Kasei): Trade name "Suntech LD F1920" (MFR = 2.0, Tm = 110°C, SP value = 8.1 (cal/ cm3 ) 1/2 , HSP value = 18.0 (cal/ cm3 ) 1/2 )
(Resin B)
PA6/12: Product name "Ube Nylon 7128B" (manufactured by Ube Industries) mid 6/12 copolymer (Tg = 47°C, Tm = 128°C, SP value = 13.6 (cal/ cm3 ) 1/2 , HSP value = 20.7 (cal/ cm3 ) 1/2 )
(Resin C)
PA6/66: Product name "Ube Nylon NAV503X10" (manufactured by Ube Industries, Ltd.) Polyamide 6/66 copolymer (Tg = 43°C, Tm = 194°C, SP value = 13.6 (cal/ cm3 ) 1/2 , HSP value = 22.8 (cal/ cm3 ) 1/2 )
(Resin D)
m-PE: Product name "Admer NF528" (manufactured by Mitsui Chemicals) acid-modified polyethylene (Tm = 120°C)
(Resin E)
PO elastomer: Product name "Engage EG8100" (Dow Chemical, Japan) (Tm = 60°C, melt index = 1.0g/10min (190°C/2.16kg)
 実施例1~8で用いたフィルム構成を以下の表1に示す。 The film configurations used in Examples 1 to 8 are shown in Table 1 below.
(フィルムの引張破断伸度)
 フィルムの引張破断伸度の測定は、ASTM D-882に準拠して測定した。測定は23℃、50%RHの雰囲気中で行った。オートグラフAG-IS(島津製作所製)を用いて、MD方向とTD方向の引張破断伸度を測定した。試料フィルムの幅は10mm、チャック間距離は50mm、引張速度は50mm/min(歪み速度=100%/min)である。フィルムをMD又はTD方向に長さ150mm、幅10mmに切ったサンプルの引張破断伸度を測定した。但し、フィルムの引張破断伸度は帯状の非透気通気性フィルム状保護材を半折された状態から開いて引っ張った際の測定結果であり、測定サンプルの長さが短く、前記チャック間距離を満たせない場合、チャック間距離を狭めてもよい。この場合、歪み速度が100%/minになる引張速度を選択する。
(Film Tensile Elongation at Break)
The tensile elongation at break of the film was measured in accordance with ASTM D-882. The measurement was performed in an atmosphere of 23°C and 50% RH. The tensile elongation at break in the MD and TD directions was measured using an autograph AG-IS (manufactured by Shimadzu Corporation). The width of the sample film was 10 mm, the chuck distance was 50 mm, and the tensile speed was 50 mm/min (strain rate = 100%/min). The tensile elongation at break of a sample cut into a length of 150 mm and a width of 10 mm in the MD or TD direction was measured. However, the tensile elongation at break of the film is the measurement result when a band-shaped non-permeable and breathable film-like protective material is opened from a half-folded state and pulled. If the length of the measurement sample is short and the chuck distance cannot be satisfied, the chuck distance may be narrowed. In this case, a tensile speed at which the strain rate is 100%/min is selected.
(フィルムの融点(Tm))
 前述の「フィルム作製方法」に従い、インフレーション法で作製したフィルムを、JIS K 7121に準拠し測定した。
(Film Melting Point (Tm))
A film prepared by the inflation method according to the above-mentioned "Film Preparation Method" was measured in accordance with JIS K 7121.
(フィルムの第2表面層のガラス転移温度(Tg))
 前述の「フィルム作製方法」に従い、インフレーション法で作製したフィルムを、JIS K 7244-2に準拠し、測定した。
・ノーマルフォース:-0.3N
・振り角:0.1%
・周波数:1Hz
・昇温速度:1.5℃/min
(Glass Transition Temperature (Tg) of Second Surface Layer of Film)
A film prepared by the inflation method according to the above-mentioned "Film Preparation Method" was measured in accordance with JIS K 7244-2.
・Normal force: -0.3N
Swing angle: 0.1%
Frequency: 1Hz
Heating rate: 1.5°C/min
 得られたフィルムはMD方向に沿って裁断し、幅40mmの帯状フィルムとし、ロール状に巻き取った。 The obtained film was cut along the MD direction to make a strip film 40 mm wide, and wound into a roll.
[ミシン糸]
 グンゼ(株)製エアバッグ用ミシン糸(総繊度1880dtex、ナイロン66マルチフィラメント繊維940dtex2本撚り)を上糸と下糸に用いた。
[Sewing thread]
Airbag sewing thread manufactured by Gunze Ltd. (total fineness 1880 dtex, nylon 66 multifilament fiber 940 dtex two-ply twist) was used for the upper and lower threads.
[ミシン]
 エアバッグの各パーツの縫製には、JUKI(株)製LU-2210W-7を用いた。
[sewing machine]
Each part of the airbag was sewn using LU-2210W-7 manufactured by JUKI Corporation.
[熱溶着]
 保護材とメインパネルとの溶着には、クインライト電子精工(株)製の連続送り式小型熱板装置LHP-PP1(溶着機(ベルト熱圧着機))を用いた。上部ヒーター温度は230℃、下部ヒーター温度は190℃、送り速度は0.3m/minとし、メインパネルを上下から挟むように適用した。図10に示すように、かかる装置を用いることで、上下の(加)熱板、冷却板による効率的な熱伝導が可能であり、温度制御により、パネル基布の溶融ダメージを回避しながら、接着部に熱をかけながら十分な強度の接着部を形成することができる。
[Heat welding]
The protective material and the main panel were welded using a continuous feed type small hot plate device LHP-PP1 (welding machine (belt heat pressing machine)) manufactured by Quinlite Electronics Co., Ltd. The upper heater temperature was 230°C, the lower heater temperature was 190°C, and the feed speed was 0.3 m/min, and the main panel was sandwiched from above and below. As shown in FIG. 10, by using such a device, efficient heat conduction is possible through the upper and lower (heating) plates and cooling plates, and by temperature control, it is possible to form a bonded part of sufficient strength while applying heat to the bonded part while avoiding melting damage to the panel base fabric.
[熱溶着(2step)]
 まず、前記ベルト熱圧着機の上部ヒーター温度を100℃、下部ヒーター温度は230℃、送り速度は1.0m/minとし、1枚のメインパネルの上に、リョービ製ホットエアガン(HAG-1551)を用いてフィルム全体を100℃に加熱して張力付加をしながらテープを送り出し、下側からの加熱により1枚目基布の上にテープを溶着した(1step)。その後、該テープの上に2枚目の基布を重ねて、1stepによる接着部分に一致する形状の熱板治具を用いて、圧着温度190℃で3秒間圧着した(2step)。
[Heat welding (2 steps)]
First, the upper heater temperature of the belt thermocompression machine was set to 100°C, the lower heater temperature to 230°C, and the feed speed was set to 1.0 m/min, and the entire film was heated to 100°C on one main panel using a Ryobi hot air gun (HAG-1551), and the tape was fed out while applying tension, and the tape was welded onto the first base fabric by heating from below (step 1). After that, a second base fabric was placed on top of the tape, and the tape was pressed for 3 seconds at a pressure temperature of 190°C using a hot plate jig having a shape that matches the bonded portion in step 1 (step 2).
[半折フォーマー(テープ曲げ治具)]
 図12に記載のテープ曲げ治具を使用して、溶着の直前で半折加工をする実施した。半折フォーマーを通して半折化させたフィルムは、端がずれることがあるので、半折フォーマーから出た後に手で、ずれた両端を合わせる作業が生じた。
[Half-fold former (tape bending jig)]
The tape was folded in half immediately before welding using the tape bending jig shown in Fig. 12. The ends of the film folded in half through the half-folding former may shift, so the shifted ends had to be aligned by hand after the film left the half-folding former.
[帯状の半折りフィルムの作製(加熱引張り法)]
 実施例1~8においては、前記、幅40mmの帯状フィルムを、図8に示す半折加工装置を用いて、幅20mmの半折りフィルムに加工し、ロールに巻き取った。
[Preparation of a belt-shaped folded film (heat tension method)]
In Examples 1 to 8, the above-mentioned strip-shaped film having a width of 40 mm was folded into a film having a width of 20 mm using the folding device shown in FIG. 8, and then wound into a roll.
[帯状の半折りフィルムの作製(常温固定法)]
 比較例1においては、前記予め半折させたコート布又はラミネート基布をロールに巻き取ったものから、エアバッグ外縁縫製長と同じ長さの分だけをカットして用いた。
[Preparation of a belt-shaped folded film (room temperature fixing method)]
In Comparative Example 1, the coated fabric or laminate base fabric previously folded in half was wound into a roll, and a length equal to the sewing length of the outer edge of the airbag was cut and used.
[メイン(基布)パネルの作製]
 エアバッグの袋状膨張部(メインパネル)として、図1に示す形状に基布を裁断したものをコートしていない面が内側同士となるように2枚重ね合わせた。後述する保護材の挿入、溶着を行った後、前記ミシン糸で前記ミシンを用いて50針/10cmの運針数で、縫い代が10mmとなるように外周部を縫製した。尚、縫い始めと縫い終わりには3針の返し縫いを行った。
[Making the main (base fabric) panel]
Two pieces of base fabric cut into the shape shown in Fig. 1 were stacked together to form the bag-shaped inflatable portion (main panel) of the airbag, with the uncoated surfaces facing each other. After inserting and welding the protective material described below, the outer periphery was sewn with the sewing machine using the sewing thread described above at a stitch count of 50 stitches/10 cm with a seam allowance of 10 mm. Three backstitches were used at the beginning and end of the stitching.
[インナーチューブの作製]
 エアバッグのエアー入口の内側に挿入するためのインナーチューブとして、前記Siコート布を図1に示す形状に裁断したものを2枚用いて、コート面が内側同士になるように重ね合わせ、前記ミシン糸で前記ミシンを用いて50針/10cmの運針数で、縫い代が10mmとなるように両端部を縫製した。尚、縫い始めと縫い終わりには3針の返し縫いを行った。
[Preparation of inner tube]
To form an inner tube to be inserted inside the air inlet of an airbag, two pieces of the Si-coated fabric cut into the shape shown in Fig. 1 were used, overlapped with the coated surfaces facing each other, and both ends were sewn together with the sewing machine using the sewing thread at a stitch count of 50 stitches/10 cm with a seam allowance of 10 mm. Note that three backstitches were used at the beginning and end of the stitching.
(1)6秒後の内圧保持率(%)
 後述の各仕様で縫製したメインパネルの取り付け口からインナーチューブを入れ、メインパネルとインナーチューブの位置関係を調整し、評価用エアバッグとした。該エアバッグを、内圧8800kPaとなるように、容量0.22リットルのタンクに常温のヘリウムを充填し、該タンク先端に金属製のパイプ(内径21.3mm)を介して接続し、該タンクの先端付近に取り付けた電磁弁を瞬時に開閉し、その後、該パイプとエアバッグの接続部付近に取り付けてある圧力センサー(共和電業(社)製PGMC-A-1MPa)にてエアバッグの内圧の経時変化を調べた。
 電磁弁開放後6秒後のエアバッグの内圧を、電磁弁開放後のエアバッグの最大内圧で除した値を記録した。3個のエアバッグで1回ずつ試験を実施し、計3回の測定結果の平均値を6秒後の内圧保持率として百分率で算出した。
(1) Internal pressure retention rate after 6 seconds (%)
An inner tube was inserted through the mounting opening of the main panel sewn to each of the specifications described below, and the relative positions of the main panel and the inner tube were adjusted to prepare an airbag for evaluation. The airbag was filled with room temperature helium in a 0.22 liter tank so that the internal pressure was 8800 kPa, and the tank was connected to the tip of the tank via a metal pipe (inner diameter 21.3 mm). An electromagnetic valve attached near the tip of the tank was instantly opened and closed, and then the change in the internal pressure of the airbag over time was examined using a pressure sensor (PGMC-A-1 MPa, manufactured by Kyowa Electric Industry Co., Ltd.) attached near the connection between the pipe and the airbag.
The internal pressure of the airbag 6 seconds after the solenoid valve was opened was divided by the maximum internal pressure of the airbag after the solenoid valve was opened, and the value was recorded. The test was performed once for each of the three airbags, and the average of the three measurements was calculated as the internal pressure retention rate after 6 seconds, expressed as a percentage.
(2)折り畳み後の厚み(mm)
 後述の各仕様で縫製したメインパネルの直線縫製部(図1のB部)をカットし、60mm×30mmの厚み評価用サンプル片とした。カットしたサンプル片を直線縫製に対して垂直に二つ折りすることで30mm×30mmの折り畳みサンプルを作製した。折り畳み部の縫製部の上から、ミツトヨ(社)製デジタルノギス(ABSデジマチックキャリパCD-20APX)を用いて、ノギスの測定部で折り目から縫製部10mmを挟みこみ、300gfの強さで押し込んだときの値を記録した。3個のエアバッグで1回ずつ試験を実施し、計3回の測定結果の平均値を折り畳み後の厚みとした。
(2) Thickness after folding (mm)
The straight stitched portion (part B in FIG. 1) of the main panel sewn according to each specification described below was cut to obtain a 60 mm x 30 mm sample piece for thickness evaluation. The cut sample piece was folded in half perpendicular to the straight stitching to produce a folded sample of 30 mm x 30 mm. Using a digital caliper (ABS Digimatic Caliper CD-20APX) manufactured by Mitutoyo Corporation, the measurement part of the caliper was used to pinch the stitched portion 10 mm from the fold and press it with a force of 300 gf, and the value was recorded. The test was performed once for each of the three airbags, and the average value of the three measurements was taken as the thickness after folding.
(3)MD及びTD方向のフィルム弾性率(MPa)
 フィルムの引張弾性率の測定には、オートグラフAG-IS(島津製作所製)を使用し、23℃、50%RHの雰囲気中にした。ASTM-D-882に記載の方法に準拠し、5mm/minの引張速度(歪み速度=5%/min)、チャック間距離100mmの条件で、フィルムをMD又はTD方向に切ったサンプルを0.05%から0.25%まで変位した時の応力から引張弾性率を求めた。ただし、ここで言うフィルムの引張弾性率は帯状の非透気通気性フィルム状保護材を半折された状態から開いて引っ張った際の測定結果とした。また、測定サンプルの長さが短く、前記チャック間距離を満たせない場合、チャック間距離を狭めてもよい。この場合、歪み速度が5%/minになる引張速度を選択する。
(3) Elastic modulus of film in MD and TD directions (MPa)
The tensile modulus of the film was measured using an autograph AG-IS (manufactured by Shimadzu Corporation) in an atmosphere of 23°C and 50% RH. In accordance with the method described in ASTM-D-882, a sample cut from the film in the MD or TD direction was displaced from 0.05% to 0.25% under the conditions of a tensile speed of 5 mm/min (strain speed = 5%/min) and a chuck distance of 100 mm, and the tensile modulus was calculated from the stress when the sample was displaced from 0.05% to 0.25%. However, the tensile modulus of the film referred to here was the measurement result when a strip-shaped non-permeable and breathable film-like protective material was opened from a half-folded state and pulled. In addition, if the length of the measurement sample is short and the chuck distance cannot be satisfied, the chuck distance may be narrowed. In this case, a tensile speed at which the strain rate is 5%/min is selected.
(4)R部加工時のハンドリングの評価
 後述の各仕様でエアバッグを作製する際、フィルムの溶着工程において、曲線部での変形のさせやすさとフィルムの取り回し(フィルムのズレやカールの有無、フィルムが柔らかく持ちにくくないか)に関して、接着作業を行う作業者に対し、各仕様での作業性を4段階(A:非常に作業しやすい、B:作業しやすい、C:やや作業しにくい、D:作業しにくい、E:作業できない)で評価してもらった。計5名の作業者に評価してもらい、最も多い回答をR部加工時のハンドリングの評価結果とした。
(4) Evaluation of handling during R section processing When manufacturing airbags with each of the specifications described below, in the film welding process, workers performing the bonding work were asked to evaluate the ease of deformation at curved sections and handling of the film (whether the film shifts or curls, and whether the film is soft and difficult to hold) on a four-point scale (A: very easy to work with, B: easy to work with, C: somewhat difficult to work with, D: difficult to work with, E: not possible to work with). A total of five workers were asked to evaluate, and the most common answer was taken as the evaluation result for handling during R section processing.
(5)バッグ1個あたりの製造時間
 試料布から試料片を裁断する工程から、後述の各仕様で縫製したバッグを3個作製するまでに要した時間を3で除し、バッグ1個あたりの製造時間とし、実施例1を基準の100とした指数で示した。但し、保護材の作製の工程は予め実施し準備した。
(5) Manufacturing time per bag The time required from the process of cutting sample pieces from the sample fabric to the production of three bags sewn according to each specification described below was divided by 3 to obtain the manufacturing time per bag, which was expressed as an index with Example 1 set as the standard of 100. However, the process of producing the protective material was carried out and prepared in advance.
[実施例1~8、比較例1]
 実施例1、2、4、7、8、比較例1では、使用する保護材の層構成が、「接着層/中間/樹脂層1/樹脂層2」よりなる多層フィルムであり、接着層にはPA6/12、中間層にはPОm-PE、樹脂層1にはPA6/66重合体、樹脂層2にはPE(LDPE)を用いて多層サーキュラーダイより押し出し、インフレーション法により、厚さ30μmの4種4層フィルムとした。各樹脂層の層比率を変更することで、MD方向とTD方向のフィルム弾性率が異なるフィルムを得た。
 実施例3では、使用する保護材の層構成が、「接着層/樹脂層1/中間層/樹脂層1/樹脂層2/樹脂層3」よりなる多層フィルムであり、接着層にはPA6/12、樹脂層1にはPО、中間層にはPOエラストマー、樹脂層2にはPA6/66重合体、樹脂層3にはPE(LDPE)を用いて多層サーキュラーダイより押し出し、インフレーション法により、厚さ30μmの5種6層フィルムとした。
 実施例5、6では、使用する保護材の層構成が、「接着層/中間/樹脂層1」よりなる多層フィルムであり、接着層にはPA6/66重合体、中間層にはPОm-PE、樹脂層1にはPA6/66重合体、を用いて多層サーキュラーダイより押し出し、インフレーション法により、厚さ30μmの2種3層フィルムとした。
 以下の表1に得られた多層フィルムの物性及び、それらを保護材として用いたエアバッグ試験片の評価結果を記載する。
[Examples 1 to 8, Comparative Example 1]
In Examples 1, 2, 4, 7, and 8 and Comparative Example 1, the protective material used had a layer structure of "adhesive layer/intermediate layer/resin layer 1/resin layer 2", and was a multilayer film made of PA6/12 for the adhesive layer, POm-PE for the intermediate layer, PA6/66 polymer for resin layer 1, and PE (LDPE) for resin layer 2, which were extruded from a multilayer circular die and made into a 30 μm-thick four-type four-layer film by the inflation method. By changing the layer ratio of each resin layer, films with different film elastic moduli in the MD and TD directions were obtained.
In Example 3, the layer structure of the protective material used was a multilayer film consisting of "adhesive layer/resin layer 1/intermediate layer/resin layer 1/resin layer 2/resin layer 3", in which PA6/12 was used for the adhesive layer, PO for resin layer 1, PO elastomer for the intermediate layer, PA6/66 polymer for resin layer 2, and PE (LDPE) for resin layer 3, and the film was extruded from a multilayer circular die and made into a 5-type 6-layer film with a thickness of 30 μm by the inflation method.
In Examples 5 and 6, the layer structure of the protective material used was a multilayer film consisting of "adhesive layer/intermediate layer/resin layer 1", with PA6/66 polymer used for the adhesive layer, POm-PE for the intermediate layer, and PA6/66 polymer used for the resin layer 1, which were extruded from a multilayer circular die and made into a 30 μm thick two-kind three-layer film by the inflation method.
The physical properties of the multilayer films obtained and the evaluation results of airbag test pieces using these films as protective materials are shown in Table 1 below.
 実施例1では、非通気性フィルム状保護材として4種4層の多層樹脂フィルムを用いた。このフィルムのMD方向の弾性率は245MPa、TD方向の弾性率は250MPaであった。エアバッグの作製に際し、1対の基布パネルの直線又は曲線状の外周縁に沿って、帯状の非透気通気性フィルム状保護材を挟み込む方法としては、半折りフィルムを巻き取ったロールを予め用意し、かかる巻き取ったロールから、帯状の非通気性フィルム状保護材を熱溶着による溶着箇所に送り出す方法とした。この方法では、R部加工時のハンドリングが良好であり、得られたエアバッグは、エアバッグ内圧保持率が高く、コンパクト性も良好であった。 In Example 1, a four-type, four-layer multilayer resin film was used as the non-breathable film-like protective material. The elastic modulus of this film in the MD direction was 245 MPa, and the elastic modulus in the TD direction was 250 MPa. When making the airbag, the method of sandwiching the band-shaped non-breathable film-like protective material along the straight or curved outer periphery of a pair of base fabric panels was to prepare a roll of half-folded film in advance, and send the band-shaped non-breathable film-like protective material from the roll to the welding point by heat welding. This method allowed for good handling during processing of the R section, and the obtained airbag had a high internal pressure retention rate and good compactness.
 実施例2では、フィルムのMD方向の弾性率が200MPa、TD方向の弾性率が200MPaとした以外は、実施例1と同様とした。この方法では、R部加工時のハンドリングが非常に良好であり、得られたエアバッグは、エアバッグ内圧保持率が高く、コンパクト性も良好であった。 Example 2 was the same as Example 1, except that the elastic modulus of the film in the MD direction was 200 MPa and the elastic modulus in the TD direction was 200 MPa. This method provided excellent handling during processing of the R section, and the airbag obtained had a high internal pressure retention rate and good compactness.
 実施例3では、フィルムのMD方向の弾性率が300MPa、TD方向の弾性率が290MPaとした以外は、実施例1と同様とした。この方法では、フィルムがやや硬く変形させにくかったことからR部加工時のハンドリング性がやや悪化したが、得られたエアバッグは、エアバッグ内圧保持率が高く、コンパクト性も良好であった。 Example 3 was the same as Example 1, except that the elastic modulus of the film in the MD direction was 300 MPa and the elastic modulus in the TD direction was 290 MPa. With this method, the film was somewhat hard and difficult to deform, which slightly worsened the handling properties during processing of the R section, but the airbag obtained had a high internal pressure retention rate and good compactness.
 実施例4では、フィルムのMD方向の弾性率が150MPa、TD方向の弾性率が125MPaとした以外は、実施例1と同様とした。この方法では、フィルムが柔らかく取り回ししにくい場合があり、R部加工時のハンドリング性がやや悪化したが、得られたエアバッグは、エアバッグ内圧保持率が高く、コンパクト性も良好であった。 Example 4 was the same as Example 1, except that the elastic modulus of the film in the MD direction was 150 MPa and the elastic modulus in the TD direction was 125 MPa. With this method, the film was soft and sometimes difficult to handle, and the handling properties during processing of the R section were slightly worse, but the airbag obtained had a high internal pressure retention rate and good compactness.
 実施例5では、非通気性フィルム状保護材として2種3層の多層樹脂フィルムを用いた。エアバッグの作製に際し、1対の基布パネルの直線又は曲線状の外周縁に沿って、帯状の非透気通気性フィルム状保護材を挟み込む方法としては、半折りフィルムを巻き取ったロールを予め用意し、半折りフィルムの折り目の内側には、予め剥離紙として幅20mmのPE製のフィルム(厚み50μm)を挟み込んだ。かかる巻き取ったロールから、帯状の非通気性フィルム状保護材を熱溶着による溶着箇所に送り出す方法とした。この方法では、剥離紙のズレにより、取り回ししにくい場合があり、R部加工時のハンドリング性がやや悪化したが、得られたエアバッグは、エアバッグ内圧保持率が高く、コンパクト性も良好であった。 In Example 5, a two-type, three-layer multilayer resin film was used as the non-breathable film-like protective material. In producing the airbag, a roll of half-folded film was prepared in advance to sandwich the band-shaped non-breathable film-like protective material along the straight or curved outer periphery of a pair of base fabric panels, and a 20 mm wide PE film (thickness 50 μm) was sandwiched inside the fold of the half-folded film as a release paper. The band-shaped non-breathable film-like protective material was sent from the roll to the welding point by heat welding. With this method, the release paper may be misaligned, making it difficult to handle, and the handling during processing of the R section was slightly deteriorated, but the obtained airbag had a high internal pressure retention rate and good compactness.
 実施例6では、実施例5と同様のフィルムを用いたが、帯状のフィルムを半折りされていない状態で巻き取ったロールを予め用意し、かかる巻き取ったロールから、帯状の非通気性フィルム状保護材を熱溶着による溶着箇所に送り出す過程で半折フォーマーを用いて半折させた後、半折りフィルムの折り目の内側に、剥離紙として幅20mmのPE製のフィルム(厚み50μm)を挟み込み、かかる溶着箇所に送り出す方法とした。この方法では、剥離紙やフィルムのズレが発生しやすく、取り回ししにくい場合があり、R部加工時のハンドリング性が悪化したが、得られたエアバッグは、エアバッグ内圧保持率が高く、コンパクト性も良好であった。 In Example 6, the same film as in Example 5 was used, but a roll of strip-shaped film was prepared in advance without being folded in half, and a strip-shaped non-breathable film-like protective material was folded in half using a half-folding former in the process of sending it from the roll to the welding point by heat welding, and then a 20 mm wide PE film (thickness 50 μm) was sandwiched as release paper inside the fold of the half-folded film and sent to the welding point. With this method, the release paper and film were prone to shifting, making them difficult to handle, and handling during processing of the R section was impaired, but the resulting airbag had a high internal airbag pressure retention rate and good compactness.
 実施例7では、実施例1と同様のフィルムを用いたが、帯状のフィルムを半折りされていない状態で巻き取ったロールを予め用意し、かかる巻き取ったロールから、帯状の非通気性フィルム状保護材を熱溶着による溶着箇所に送り出す過程で半折フォーマーを用いて半折させた後、かかる溶着箇所に送り出す方法とした。この方法では、フィルムのズレやカールが発生しやすく、取り回ししにくい場合があり、R部加工時のハンドリング性がやや悪化したが、得られたエアバッグは、エアバッグ内圧保持率が高く、コンパクト性も良好であった。 In Example 7, the same film as in Example 1 was used, but a roll of strip-shaped film was prepared in advance without being folded in half, and in the process of sending the strip-shaped non-breathable film-like protective material from the roll to the welding location by heat welding, the material was folded in half using a half-folding former, and then sent to the welding location. With this method, the film was prone to shifting and curling, making it difficult to handle, and the handling properties during processing of the R section were somewhat worse, but the resulting airbag had a high internal airbag pressure retention rate and good compactness.
 実施例8では、実施例1と同様のフィルムを用いたが、エアバッグの作製に際し、1対の基布パネルの直線又は曲線状の外周縁に沿って、帯状の非透気通気性フィルム状保護材を挟み込むのではなく、1枚のメインパネルの上に、張力付加をしながらテープを送り出し、下側からの加熱により1枚目基布の上にテープを溶着した(1step)。その後、該テープの上に2枚目の基布を重ねて圧着した(2step)。この方法では、R部加工時のハンドリングが良好であり、バッグ1個あたりの製造時間も短く、得られたエアバッグは、エアバッグ内圧保持率が高く、コンパクト性も良好であった。 In Example 8, the same film as in Example 1 was used, but when making the airbag, instead of sandwiching a strip-shaped non-air-permeable, breathable film-like protective material along the straight or curved outer periphery of a pair of base fabric panels, a tape was fed onto one main panel while applying tension, and the tape was welded onto the first base fabric by heating from below (step 1). After that, a second base fabric was placed on top of the tape and pressed onto it (step 2). This method allowed for good handling during processing of the R-section, the manufacturing time per bag was short, and the resulting airbag had a high airbag internal pressure retention rate and good compactness.
 比較例1では、実施例1と同様のフィルムを用いたが、エアバッグの作製に際し、フィルム状保護材がエアバッグの内側にループを形成するように、2枚のパネル布で挟み込み、パネル布同士を縫製した後、縫製の内側で保護材とパネル布のラミネート面との間を熱溶着した。接着時には、縫製により保護材が固定されているため、保護材に張力をかけずに接着した。この方法では、フィルムのズレや皺が発生しやすく、取り回ししにくい場合があり、R部加工時のハンドリング性が悪化した上、バッグ1個あたりの製造時間も長く、得られたエアバッグは、エアバッグ内圧保持率が低く、コンパクト性も良好ではなかった。 In Comparative Example 1, the same film as in Example 1 was used, but when the airbag was made, the film-like protective material was sandwiched between two panels of cloth so as to form a loop on the inside of the airbag, and the panels of cloth were sewn together, and then the protective material and the laminated surface of the panel cloth were heat-sealed inside the stitching. Because the protective material was fixed by sewing when bonding, it was bonded without applying tension to the protective material. With this method, the film was prone to shifting and wrinkling, which could make it difficult to handle, and the handling during processing of the R section was poor. In addition, the manufacturing time per bag was long, and the resulting airbag had a low internal pressure retention rate and was not very compact.
 本発明に係るエアバッグの製法は、少なくとも1対の基布パネルの各々の内面に、縫合近傍から袋体内部に向かって近位端と遠位端を有する所定幅の該縫合に沿う接着領域で、半折された帯状の非通気性保護材の両端外面が、それぞれ、接着されており、内圧保持性能が高く、低コストで、生産性が高く、かつ、コンパクト性にも優れるエアバッグの生産性の高い製法である。
 したがって、発明に係るエアバッグの製法は、自動車用エアバッグ、内圧保持性能が特に要求されるCABや歩行者エアバッグに好適に利用可能である。
The method for manufacturing an airbag according to the present invention comprises bonding the outer surfaces of both ends of a folded, strip-shaped, non-breathable protective material to the inner surface of each of at least a pair of base fabric panels in bonding regions of a predetermined width along the seams from near the seams toward the inside of the bag, the bonding regions having proximal and distal ends. This method is highly productive for producing an airbag which has high internal pressure retention performance, is low cost, has high productivity, and is also highly compact.
Therefore, the airbag manufacturing method according to the present invention can be suitably used for automobile airbags, CABs and pedestrian airbags which particularly require high internal pressure retention performance.
 1   基布パネル(パネル布、メインパネル)
 1’  基布パネル(パネル布、メインパネル)
 2   縫合(縫製)部
 2’  孤立縫合(縫製)部
 3   シリコーン接着剤
 4   非通気性(フィルム状)保護材
 4’  非通気性(フィルム状)保護材の内縁部
 4”  半折りされた帯状の非通気性(フィルム状)保護材
 5   接着領域
 5’  接着領域
 6   接着領域の近位端
 6’  接着領域の近位端
 7   接着領域の遠位端
 7’  接着領域の遠位端
 8   非通気性(フィルム状)保護材の末端(封止)部
 8’  非通気性(フィルム状)保護材の末端(封止)部
 10  外縁部が縫合された袋状エアバッグ
 A-A 断面
 11  多層フィルム
 11a 多層フィルム(外層)
 11b 多層フィルム(接着層)
 12  多層ダイ
 13  エアリング
 14  デフレータ(フリーロール)
 15  第一ピンチ駆動ロール
 16  ガイドロール(フリーロール)
 17  第二ピンチ駆動ロール
 18  タッチロール(フリーロール)
 19  巻取駆動ロール
 20  ナイロン66製基布
 21  加圧ロール(シリコンゴムライニング)
 22  加熱ロール(クロムメッキ加工)
 23  インナーチューブ
 24  インナーチューブの縫製部
1. Base fabric panel (panel fabric, main panel)
1' Base fabric panel (panel fabric, main panel)
Reference Signs List 2: Sewn (stitched) portion 2': Isolated sewn (stitched) portion 3: Silicone adhesive 4: Non-breathable (film-like) protective material 4': Inner edge of non-breathable (film-like) protective material 4": Half-folded strip-shaped non-breathable (film-like) protective material 5: Adhesive area 5': Adhesive area 6: Proximal end of adhesive area 6': Proximal end of adhesive area 7: Distal end of adhesive area 7': Distal end of adhesive area 8: End (sealed) portion of non-breathable (film-like) protective material 8': End (sealed) portion of non-breathable (film-like) protective material 10: Bag-shaped airbag with outer edge sewn A-A: Cross section 11: Multilayer film 11a: Multilayer film (outer layer)
11b Multilayer film (adhesive layer)
12 Multi-layer die 13 Air ring 14 Deflator (free roll)
15 First pinch drive roll 16 Guide roll (free roll)
17 Second pinch drive roll 18 Touch roll (free roll)
19 Winding drive roll 20 Nylon 66 base fabric 21 Pressure roll (silicon rubber lining)
22 Heating roll (chrome plated)
23 Inner tube 24 Sewing part of inner tube

Claims (11)

  1.  少なくとも1対の基布パネルが外周縁で縫合されてなるエアバッグの製造方法であって、以下の工程:
     該1対の基布パネルの各々の内面の間に、所定幅の、剥離紙を挟んだ単層樹脂フィルムからなる又は第1表面層と第2表面層を含む2層以上の積層樹脂フィルムからなる半折された帯状の非通気性フィルム状保護材に、張力を付与しながら、これを、該1対の基布パネルの直線又は曲線状の外周縁に沿って、連続的に、挟み込みつつ、該1対の基布パネルの外側から、熱又は超音波を適用して、該単層樹脂フィルムの表面を又は該第1表面層を、該基布パネルの内面に、所定幅の接着領域において、溶着する溶着工程、ここで、該単層樹脂フィルムの剥離紙側の表面同士は剥離紙の存在により溶着されていないか、あるいは該積層樹脂フィルムの第2表面層同士は、熱溶着又は超音波溶着により溶着されていないか、又は、熱溶着又は超音波溶着により溶着されているものの、該エアバッグの展開に際し、該1対の基布パネル同士に引張強力がかかる時、該第2表面層が剥離する;
     前記接着の前、接着の後、又は同時に、該接着領域の近傍で、該1対の基布パネルを縫合する縫合工程;
    を含む、前記製造方法。
    A method for manufacturing an airbag having at least one pair of fabric panels sewn together at a peripheral edge, the method comprising the steps of:
    a welding step of continuously sandwiching a semi-folded, band-shaped non-breathable film-like protective material, which is made of a monolayer resin film having a predetermined width with a release paper sandwiched therebetween or a laminated resin film having two or more layers including a first surface layer and a second surface layer, between the inner surfaces of the pair of base fabric panels while applying tension to the material along the linear or curved outer periphery of the pair of base fabric panels, and applying heat or ultrasonic waves from the outside of the pair of base fabric panels to weld a surface of the monolayer resin film or the first surface layer to the inner surface of the base fabric panel in an adhesive region of a predetermined width, wherein although the surfaces of the monolayer resin film on the release paper side are not welded to each other due to the presence of the release paper, or the second surface layers of the laminated resin film are not welded to each other by heat welding or ultrasonic welding, or are welded to each other by heat welding or ultrasonic welding, the second surface layer peels off when a tensile force is applied to the pair of base fabric panels when the airbag is deployed;
    a sewing step of sewing the pair of fabric panels together adjacent the bonded areas before, after, or simultaneously with the bonding;
    The manufacturing method comprising the steps of:
  2.  前記半折された帯状の非通気性フィルム状保護材を、半折された状態で巻き取られたロールから送り出し、1対の基布パネルに挟み込む、請求項1に記載の方法。 The method according to claim 1, wherein the semi-folded band-shaped non-breathable film-like protective material is fed from a roll wound in a semi-folded state and sandwiched between a pair of base fabric panels.
  3.  前記半折された帯状の非通気性フィルム状保護材を、溶着する溶着工程の前に、該前記半折された帯状の非通気性フィルム状保護材の一部又は全体を加熱する工程;
    を含む、請求項1又は2に記載の方法。
    a step of heating a part or the whole of the half-folded band-shaped non-breathable film-like protective material before a welding step of welding the half-folded band-shaped non-breathable film-like protective material;
    The method of claim 1 or 2, comprising:
  4.  前記半折された帯状の非通気性フィルム状保護材を、溶着する溶着工程の後に、該前記半折された帯状の非通気性フィルム状保護材の一部又は全体を冷却する工程;
    を含む、請求項1又は2に記載の方法。
    a step of cooling a part or the whole of the semi-folded, band-shaped, non-breathable film-like protective material after a welding step of welding the semi-folded, band-shaped, non-breathable film-like protective material;
    The method of claim 1 or 2, comprising:
  5.  前記半折された帯状の非通気性フィルム状保護材を、溶着する溶着工程において、熱板及び/又は冷却板の押し圧を間歇的に印加/解除しながら、該前記半折された帯状の非通気性フィルム状保護材の一部又は全体を加熱及び/又は冷却する工程;
    を含む、請求項1又は2に記載の方法。
    a step of heating and/or cooling a part or the whole of the half-folded band-shaped non-breathable film-like protective material while intermittently applying/releasing the pressure of a hot plate and/or a cold plate in a welding step of welding the half-folded band-shaped non-breathable film-like protective material;
    The method of claim 1 or 2, comprising:
  6.  前記半折された非通気性フィルム状保護材である積層樹脂フィルムの第1表面層を構成する樹脂の融点が、第2表面層を構成する樹脂の融点よりも、50℃~160℃低い、請求項1又は2に記載の方法。 The method according to claim 1 or 2, wherein the melting point of the resin constituting the first surface layer of the laminated resin film, which is the half-folded non-breathable film-like protective material, is 50°C to 160°C lower than the melting point of the resin constituting the second surface layer.
  7.  前記半折された非通気性フィルム状保護材である、単層又は積層樹脂フィルムの第1表面層と第2表面層を含む多層フィルムにおいて、いずれかの隣接する層間のSP値の差が、2.0[cal/cm)1/2]以上である、請求項1又は2に記載の方法。 The method according to claim 1 or 2, wherein the half-folded non-breathable film-like protective material is a single-layer or multilayer film including a first surface layer and a second surface layer of a laminated resin film, and the difference in SP value between any adjacent layers is 2.0 [cal/ cm3 ) 1/2 ] or more.
  8.  前記半折された非通気性フィルム状保護材である、単層又は積層樹脂フィルムの第1表面層と第2表面層を含む多層フィルムにおいて、いずれかの隣接する層間のHSP値の差が、1.0[cal/cm)1/2]以上である、請求項1又は2に記載の方法。 The method according to claim 1 or 2, wherein the half-folded non-breathable film-like protective material is a single-layer or multilayer film including a first surface layer and a second surface layer of a laminated resin film, and the difference in HSP value between any adjacent layers is 1.0 [cal/ cm3 ) 1/2 ] or more.
  9.  エアバッグの展開に際し、前記1対の基布パネル同士に引張強力がかかる時、該1対の基布パネルに沿った遠位端間の長さよりも、該半折された非通気性フィルム状保護材に沿った遠位端間の長さが、大きいか又はこれに等しい、請求項1又は2に記載の方法。 The method according to claim 1 or 2, wherein when a tensile force is applied between the pair of base fabric panels during deployment of the airbag, the length between the distal ends along the folded non-breathable film-like protective material is greater than or equal to the length between the distal ends along the pair of base fabric panels.
  10.  前記接着の後に、該接着領域の近傍で、該1対の基布パネルを縫合する縫合工程;
    を含む、請求項1又は2に記載の方法。
    a sewing step of sewing the pair of base fabric panels together adjacent the bonded areas after the bonding;
    The method of claim 1 or 2, comprising:
  11.  1の基布パネルの上に、所定幅の、第1表面層と第2表面層を含む2層以上の積層樹脂フィルムからなる半折された帯状の非通気性フィルム状保護材に、張力を付与しながら、これを、該1の基布パネルの直線又は曲線状の外周縁に沿って、連続的に、該1の基布パネルの下側から、熱又は超音波を適用して、該第1表面層を、該基布パネルの上面に溶着する溶着工程;
     該溶着されたフィルム状保護材の上に他の基布パネルを重ね、該重ねた基布パネルの上側から、熱又は超音波を適用して、該第1表面層を、該重ねた基布パネルの下面に溶着する溶着工程、ここで、該積層樹脂フィルムの第2表面層同士は、熱溶着又は超音波溶着により溶着されていないか、又は、熱溶着又は超音波溶着により溶着されているものの、該エアバッグの展開に際し、該基布パネル同士に引張強力がかかる時、該第2表面層が剥離する;
     前記接着の後、得られる溶着の領域の近傍で、該基布パネルを縫合する縫合工程;
    を含む、前記製造方法。
    a welding step of applying heat or ultrasonic waves to a semi-folded band-shaped non-breathable film-like protective material of a predetermined width, which is made of a laminated resin film of two or more layers including a first surface layer and a second surface layer, on one of the base fabric panels, continuously along a straight or curved outer periphery of the one of the base fabric panels from below the one of the base fabric panels while applying tension to the material, thereby welding the first surface layer to an upper surface of the one of the base fabric panels;
    a welding step of overlapping another base fabric panel on the welded film-like protective material and applying heat or ultrasonic waves from the upper side of the overlapped base fabric panel to weld the first surface layer to the lower surface of the overlapped base fabric panel, wherein the second surface layers of the laminated resin film are not welded to each other by thermal welding or ultrasonic welding, or are welded to each other by thermal welding or ultrasonic welding, but the second surface layer peels off when a tensile force is applied to the base fabric panels when the airbag is deployed;
    a sewing step of sewing the fabric panels together adjacent the areas of the resulting welds after said bonding;
    The manufacturing method comprising the steps of:
PCT/JP2023/042592 2022-11-29 2023-11-28 Production method for airbag having enhanced internal-pressure retaining performance WO2024117138A1 (en)

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Publication number Priority date Publication date Assignee Title
US6435553B1 (en) * 2000-03-20 2002-08-20 Breed Automotive Technology, Inc. Air bag and method of seam assembly for minimizing gas leakage
JP2003514144A (en) * 1999-11-17 2003-04-15 ミリケン・アンド・カンパニー Inflatable fabric with peel seams
JP2007223373A (en) * 2006-02-21 2007-09-06 Nippon Plast Co Ltd Air bag and manufacturing method of air bag
WO2010122852A1 (en) * 2009-04-23 2010-10-28 芦森工業株式会社 Airbag device
JP2015515942A (en) * 2012-05-03 2015-06-04 ティーケー ホールディングス インク.Tk Holdings Inc. Airbag module with lightweight airbag cushion

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2003514144A (en) * 1999-11-17 2003-04-15 ミリケン・アンド・カンパニー Inflatable fabric with peel seams
US6435553B1 (en) * 2000-03-20 2002-08-20 Breed Automotive Technology, Inc. Air bag and method of seam assembly for minimizing gas leakage
JP2007223373A (en) * 2006-02-21 2007-09-06 Nippon Plast Co Ltd Air bag and manufacturing method of air bag
WO2010122852A1 (en) * 2009-04-23 2010-10-28 芦森工業株式会社 Airbag device
JP2015515942A (en) * 2012-05-03 2015-06-04 ティーケー ホールディングス インク.Tk Holdings Inc. Airbag module with lightweight airbag cushion

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