WO2024110643A1 - Procédés, systèmes et équipement de traitement pour la commande optimisée de processus d'hydrolyse thermique - Google Patents

Procédés, systèmes et équipement de traitement pour la commande optimisée de processus d'hydrolyse thermique Download PDF

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WO2024110643A1
WO2024110643A1 PCT/EP2023/083025 EP2023083025W WO2024110643A1 WO 2024110643 A1 WO2024110643 A1 WO 2024110643A1 EP 2023083025 W EP2023083025 W EP 2023083025W WO 2024110643 A1 WO2024110643 A1 WO 2024110643A1
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biomass material
yield stress
pulper
thermal hydrolysis
thp
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Hans Rasmus Holte
Andreas Helland LILLEBØ
Alexandru BOTAN
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Cambi Technology As
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    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12M—APPARATUS FOR ENZYMOLOGY OR MICROBIOLOGY; APPARATUS FOR CULTURING MICROORGANISMS FOR PRODUCING BIOMASS, FOR GROWING CELLS OR FOR OBTAINING FERMENTATION OR METABOLIC PRODUCTS, i.e. BIOREACTORS OR FERMENTERS
    • C12M21/00—Bioreactors or fermenters specially adapted for specific uses
    • C12M21/04—Bioreactors or fermenters specially adapted for specific uses for producing gas, e.g. biogas
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F11/00—Treatment of sludge; Devices therefor
    • C02F11/006—Electrochemical treatment, e.g. electro-oxidation or electro-osmosis
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F11/00—Treatment of sludge; Devices therefor
    • C02F11/06—Treatment of sludge; Devices therefor by oxidation
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F11/00—Treatment of sludge; Devices therefor
    • C02F11/06—Treatment of sludge; Devices therefor by oxidation
    • C02F11/08—Wet air oxidation
    • C02F11/086—Wet air oxidation in the supercritical state
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F11/00—Treatment of sludge; Devices therefor
    • C02F11/10—Treatment of sludge; Devices therefor by pyrolysis
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F9/00—Multistage treatment of water, waste water or sewage
    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12M—APPARATUS FOR ENZYMOLOGY OR MICROBIOLOGY; APPARATUS FOR CULTURING MICROORGANISMS FOR PRODUCING BIOMASS, FOR GROWING CELLS OR FOR OBTAINING FERMENTATION OR METABOLIC PRODUCTS, i.e. BIOREACTORS OR FERMENTERS
    • C12M41/00—Means for regulation, monitoring, measurement or control, e.g. flow regulation
    • C12M41/44—Means for regulation, monitoring, measurement or control, e.g. flow regulation of volume or liquid level
    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12M—APPARATUS FOR ENZYMOLOGY OR MICROBIOLOGY; APPARATUS FOR CULTURING MICROORGANISMS FOR PRODUCING BIOMASS, FOR GROWING CELLS OR FOR OBTAINING FERMENTATION OR METABOLIC PRODUCTS, i.e. BIOREACTORS OR FERMENTERS
    • C12M45/00—Means for pre-treatment of biological substances
    • C12M45/06—Means for pre-treatment of biological substances by chemical means or hydrolysis
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F11/00—Treatment of sludge; Devices therefor
    • C02F11/02—Biological treatment
    • C02F11/04—Anaerobic treatment; Production of methane by such processes
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F11/00—Treatment of sludge; Devices therefor
    • C02F11/18—Treatment of sludge; Devices therefor by thermal conditioning
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00—Controlling or monitoring parameters in water treatment
    • C02F2209/02—Temperature
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00—Controlling or monitoring parameters in water treatment
    • C02F2209/03—Pressure
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00—Controlling or monitoring parameters in water treatment
    • C02F2209/05—Conductivity or salinity
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00—Controlling or monitoring parameters in water treatment
    • C02F2209/06—Controlling or monitoring parameters in water treatment pH
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00—Controlling or monitoring parameters in water treatment
    • C02F2209/09—Viscosity
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00—Controlling or monitoring parameters in water treatment
    • C02F2209/10—Solids, e.g. total solids [TS], total suspended solids [TSS] or volatile solids [VS]
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00—Controlling or monitoring parameters in water treatment
    • C02F2209/10—Solids, e.g. total solids [TS], total suspended solids [TSS] or volatile solids [VS]
    • C02F2209/105—Particle number, particle size or particle characterisation
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00—Controlling or monitoring parameters in water treatment
    • C02F2209/21—Dissolved organic carbon [DOC]
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00—Controlling or monitoring parameters in water treatment
    • C02F2209/22—O2
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00—Controlling or monitoring parameters in water treatment
    • C02F2209/24—CO2
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00—Controlling or monitoring parameters in water treatment
    • C02F2209/28—CH4
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00—Controlling or monitoring parameters in water treatment
    • C02F2209/40—Liquid flow rate

Definitions

  • the present invention relates to methods, systems, process equipment and plants useful in the context of subjecting biomass material, having a dry-matter content (DS%) of at least 8%, preferably at least 12%, to thermal hydrolysis processes (THP) and subsequent processing in the form of e.g. anaerobic fermentation, thermal reduction, biological, chemical or electrochemical processing or the like.
  • THP thermal hydrolysis processes
  • the present invention also relates to methods for retrofitting existing plants employing Thermal Hydrolysis Processes (THP).
  • Thermal hydrolysis is a process, which involves treating a wet or moist material, e.g. a biomass material, at elevated temperature followed by rapid decompression. In waste treatment industry such a combination of process steps is often referred to as a thermal hydrolysis process (THP).
  • THP thermal hydrolysis process
  • the application of THP is not limited to pretreatment of organic materials prior to biological downstream treatment, e.g.
  • anaerobic digestion or fermentation for production of biogas or bio-ethanol can be also used in connection with non-biological downstream processing, for instance, for the production of fuel-pellets from lignocellulosic material or for the further extraction and production of added value compounds, such as amino acids, peptides proteins, short chain fatty acids, enzymes, pesticides, bio-plastics, bio-flocculants and bio-surfactants.
  • added value compounds such as amino acids, peptides proteins, short chain fatty acids, enzymes, pesticides, bio-plastics, bio-flocculants and bio-surfactants.
  • THP Thermal Hydrolysis Processes
  • the methods, systems, process equipment and plants of the present invention are relevant for both THP designed for batch and THP designed for continuous mode. Furthermore, the methods of the present invention can both be integrated in new plants and implemented into existing plants by retrofitting, involving installing relevant additional equipment and making relevant modifications.
  • the material is treated with a desired partial pressure of steam.
  • retention time the time the material is kept at the desired conditions.
  • the overall average retention time is a value, which can be calculated from the overall through-put of the overall process.
  • the material will experience a rapid pressure reduction and undergo steam-explosion as it is discharged from the THP system, e.g. through a nozzle, to a flashtank.
  • This opens cell walls, disintegrates organic materials, reduces particle sizes and apparent viscosity, e.g. the static yield stress, T 0 , and/or the dynamic yield stress, T y , of the material.
  • the flash-steam resulting from the steam-explosion can be used to pre-heat material in a pressure vessel that can be referred to as a pulper.
  • the use of flashsteam to pre-heat material prior to reactor treatment is important for achieving the highest possible energy efficiency and the lowest possible steam consumption.
  • THP The general technology behind THP is described in great details in e.g.
  • WO/1996/009882 and WO/2008/026932 material is first pre-heated from ambient temperature with flash steam resulting from at least one subsequent pressure reduction step. Pre-heated material is then transferred to a (thermal hydrolysis) reactor where pressure increases up to 2.7-26 bar, e.g. by means of live steam injection as described in WO/1996/009882. In certain situations, this will correspond to temperatures up to 226°C. In most cases, however, the temperature will be within a certain somewhat lower range as overheating may lead to undesirable changes in chemical composition of the material.
  • a (thermal hydrolysis) reactor where pressure increases up to 2.7-26 bar, e.g. by means of live steam injection as described in WO/1996/009882. In certain situations, this will correspond to temperatures up to 226°C. In most cases, however, the temperature will be within a certain somewhat lower range as overheating may lead to undesirable changes in chemical composition of the material.
  • the preferred temperature for a THP process/System is typically in the range of 130-200°C for materials like municipal and industrial sludge qualities. However, more elevated temperatures may be beneficial for several other materials or to achieve certain benefits.
  • the material is rapidly discharged from the (thermal hydrolysis) reactor, e.g. through one or more blowdown conduits, to a pressure relief vessel, which is also sometimes referred to as flash tank.
  • WO/2011/006854 describes yet another batch process for THP, which, via the use of a nozzle by which the sludge can be transferred to a first pressure relief tank, i.e. flash tank, mitigates the need for a pressure relief of the thermal hydrolysis reactor as such.
  • WO/2014/123426 describes a method and equipment for carrying out THP in which vacuum is provided in the hydrolysis reactor by supplying cold water to the hydrolysis reactor and opening a supply valve between the preheating tank and the reactor, whereby heated organic material can be transferred from the preheating tank to the reactor with the help of a vacuum and gravity up to a predetermined level.
  • WO2015/097254 describes methods for the continuous thermal hydrolysis of a biomass material having a high dry matter content, in which the apparent viscosity of the material is reduced upstream the thermal hydrolysis by subjecting it to a) a highspeed gradient (i.e. high shear strain) in a so-called dynamic mixer, which mechanically de- structures, i.e. breaks down, the material, and b) heating it by passing it through a heat exchanger in which heat is recovered directly from the hydrolysed sludge (i.e. without using any intermediate heat-carrying fluid).
  • a highspeed gradient i.e. high shear strain
  • WO/2017/066752 describes THP methods in which the hydrolysed material is mixed with part of the content of a downstream digestion tank, via the use of a recirculation loop, before this mixture enters the digestion tank.
  • WO/2020/126397 describes THP methods involving flashing below ambient pressure and using the resulting flash steam for direct steam injection to pre-heat incoming feed in a pre-heating vessel maintained below ambient pressure to facilitate the flash steam transfer.
  • the methods rely on maintaining parts of the system below ambient pressure by removing non-condensable gases by using a vacuum system and a minimum of two pulpers and one flashtank upstream of the thermal hydrolysis reactor.
  • THP methods for both batch and continuous mode, have been developed in the prior art, which are each aimed at 1) making THP processes more versatile, e.g. as regards materials having a high dry solid content, 2) reducing the overall energy consumption of THP processes and/or 3) improving, the quality and/or nature of the resulting hydrolysed material thereby enabling a simplification of downstream processing and ultimately the use of standard equipment for both the THP as such and downstream processing units.
  • the prior art does not, in contrast to the present invention, describe pulpers particularly suited for homogenizing and pre-heating non-Newtonian biomass material having a dry-matter content (DS%) above 8%, preferably at least 12%, and producing a material having a temperature within certain predetermined limits for subsequent thermal hydrolysis in a downstream thermal hydrolysis reactor, which are characterized in that both the total volume of the pulper and the specific placement of the outlet nozzle of the pulper, i.e. for discharging the pre-heated material from the pulper, are based on the average filling volume of the downstream thermal hydrolysis reactor of the THP system.
  • DS% dry-matter content
  • the methods, systems, process equipment and plants according to the present invention meets an increasing need for optimization of energy consumption of both the THP process as such and any subsequent processing systems, particularly in case of non-Newtonian biomass material having a dry-matter content (DS%) above 8%, preferably at least 12%.
  • DS% dry-matter content
  • the methods, systems, process equipment and plants according to the present invention allows for an optimization of also any subsequent (i.e. downstream of the THP) processing steps, again particularly in case of non-Newtonian biomass material having a dry-matter content (DS%) above 8%, preferably at least 12%, preferably at least 16%, more preferably at least 18%.
  • DS% dry-matter content
  • DS% dry-matter content
  • a preferred embodiment of a pulper according to the present invention is characterized in that:
  • the total volume of this pulper is based on the average filling volume of the downstream thermal hydrolysis reactor of the relevant THP system
  • the pulper comprises an outlet nozzle, for discharging the pre-heated material from the pulper, which is placed in such a way that:
  • the part of the total volume of the pulper, which is below the outlet nozzle is a certain number of times the average filling volume of the downstream thermal hydrolysis reactor of the relevant THP system
  • the part of the total volume of the pulper, which is not below the outlet nozzle is a certain other factor times the average filling volume of the thermal hydrolysis reactor of the relevant THP system.
  • this preferred embodiment of a pulper according to the present invention provides the possibility to effectively control and stably maintain relevant characteristics, including not least the temperature, of preheated biomass material discharged from the pulper through the nozzle.
  • this preferred embodiment of a pulper according to the present invention thereby provides the possibility of ensuring that preheated biomass material subsequently fed to any downstream thermal hydrolysis reactor of a TH P system, and/or subsequently from the THP system to any subsequent processing steps, is of a uniform character in accordance with any predetermined desirable characteristics, e.g. a certain predetermined temperature.
  • the features of the present invention ensures that pre-heated biomass material produced in a pulper from a non-Newtonian biomass material and to be subsequently fed to any downstream thermal hydrolysis reactor of a THP system, and/or subsequently from the THP system to any subsequent processing steps, is of a uniform temperature, i.e. such that the average standard variation in temperature is ⁇ 12°C or more preferably ⁇ 6°C, and even more preferably ⁇ 2°C, when this standard variation in temperature is calculated based on a temperature measurement resolution of ⁇ 5 seconds, and used to calculate an overall average for each individual reactor filling.
  • - of hydrolyzed biomass material displaying a certain apparent viscosity, e.g. static yield stress, T 0 , and/or dynamic yield stress, T y , pr. unit of time through feed lines for subsequent processing systems, is, in relation to a given system for subsequent processing of THP treated material, characteristic of one or more parameters of the relevant subsequent processing steps.
  • a certain apparent viscosity e.g. static yield stress, T 0
  • dynamic yield stress, T y , pr. unit of time is, in relation to a given system for subsequent processing of THP treated material, characteristic of one or more parameters of the relevant subsequent processing steps.
  • the methods, systems, process equipment and plants according to the present invention thereby, particularly in case of non-Newtonian biomass material having a dry-matter content (DS%) above 8%, preferably at least 12%, preferably at least 16%, more preferably at least 18%, provides the possibility of controlling relevant parameters of both the THP system and subsequent processing steps, by controlling the feed of raw biomass, pre-heated biomass and/or hydrolysed biomass material displaying a certain apparent viscosity, e.g. static yield stress, T 0 , and/or dynamic yield stress, T y , pr. unit of time through the THP system.
  • DS% dry-matter content
  • non-Newtonian biomass material having a dry-matter content (DS%) above 8% allows for the optimization of any subsequent processing steps, in terms of controlling the apparent viscosity, e.g static yield stress, To, and/or dynamic yield stress, T y , to be displayed by a given hydrolyzed biomass material produced in a THP per unit of time, in order to optimize e.g. the yield or overall energy consumption of any subsequent processing steps in which this hydrolyzed biomass material is to be further processed.
  • DS% dry-matter content
  • the methods, systems, process equipment and plants according to the present invention meets both an increasing need for optimization of energy consumption by achieving a lower overall energy consumption of both the THP process as such and any subsequent processing systems compared to the processes of the prior art, particularly in case of non-Newtonian biomass material having a drymatter content (DS%) above 8%, preferably at least 12%, preferably at least 16%, more preferably at least 18%.
  • DS% drymatter content
  • the methods, systems, process equipment and plants according to the present invention allows for an optimization of also other parameters, e.g. yield, of any subsequent (i.e. downstream of the THP) processing steps, again particularly in case of non-Newtonian biomass material having a dry-matter content (DS%) above 8%, preferably at least 12%, preferably at least 16%, more preferably at least 18%.
  • DS% dry-matter content
  • pre-heated biomass material produced in a pulper from a non-Newtonian biomass material and to be subsequently fed to any downstream thermal hydrolysis reactor of a THP system, and/or subsequently from the THP system to any subsequent processing steps, is of a uniform temperature, i.e. such that the average standard variation in temperature is ⁇ 12°C or more preferably ⁇ 6°C, and even more preferably ⁇ 2°C, when this standard variation in temperature is calculated based on a temperature measurement resolution of ⁇ 5 seconds, and used to calculate an overall average for each individual reactor filling.
  • the total volume of said pulper is > 2.6 times and ⁇ 20 times, preferably 2.6 to 6 times, the average filling volume of said thermal hydrolysis reactor,
  • said pulper comprises an outlet nozzle, for discharging said pre-heated material from said pulper, which is placed in such a way that:
  • said system is further characterized in that:
  • said system is further characterized in that: - the total volume of said pulper is > 3.2 times the average filling volume of said thermal hydrolysis reactor,
  • said system is further characterized in that:
  • said system is further characterized in that said pre-heating in said pulper is at least partly achieved by injection of flash steam from a thermal hydrolysis system.
  • said system is further characterized in that:
  • said system is further characterized in that said outlet nozzle is in the form of an overflow edge, knife or similar outlet fitted on the first of said at least two separate interconnected chambers or tanks, which ensures that a volume corresponding to > 1.6 the average filling volume of said thermal hydrolysis reactor is continuously present below said edge, knife or similar outlet in said first of said at least two separate interconnected chambers or tanks.
  • said system is further characterized in that said pulper includes a biomass material distributer, preferably designed as an extruder, acting to split incoming cold biomass material into smaller segments before the biomass material enters the pulper.
  • a biomass material distributer preferably designed as an extruder, acting to split incoming cold biomass material into smaller segments before the biomass material enters the pulper.
  • said system is further characterized in that said pulper includes a recirculation loop for recycling preheated biomass material from said pulper and mixing said preheated biomass material with cold biomass material prior to its entry into or inside said biomass material distributer.
  • said system is further characterized in that the recirculation loop is capable of recycling an amount of preheated biomass material from the pulper equivalent to at least 0.5 times the amount of cold biomass material feed, preferrable more than 1 times the cold biomass material feed, and even more preferably more than 2 times the cold biomass material feed.
  • said system is further characterized in that said biomass material distributer is located in the head space of the pulper above liquid level, the upper (half) section of the total volume or the bottom section of the total volume of the pulper.
  • a method for treating a non-Newtonian biomass material having:
  • DS% dry-matter content
  • COD/VS-ratio a ratio between the chemical oxygen demand (COD) and volatile solids content (VS), COD/VS-ratio, of less than 2.0, preferably less than 1.8, and even more preferably less than 1.6, and
  • T 0 a static yield stress
  • T y a dynamic yield stress
  • said method comprising the steps of: a) feeding said non-Newtonian biomass material to one or more pulpers by one or more pulper feed lines at a controlled DS% and/or COD loading rate, b) homogenizing and pre-heating said non-Newtonian biomass material in said one or more pulpers resulting in a pre-heated biomass material, c) discharging said pre-heated biomass material from said one or more pulpers, d) feeding said pre-heated biomass material to a thermal hydrolysis system, operated at a higher temperature than the temperature of said pre-heated biomass material, by one or more feed lines at a controlled DS% and/or COD loading rate, e) thermally hydrolyzing said pre-heated biomass material in said thermal hydrolysis system resulting in a hydrolyzed biomass material, and subsequently processing parts of, or all of, said hydrolyzed biomass material
  • step f said controlled DS% and/or COD loading rate of said hydrolysed biomass material through said one or more feed lines of step f), is controlled based on:
  • step d) and e) one or more thermal hydrolysis discharge or recirculation lines of said thermal hydrolysis system of step d) and e), and/or
  • step f - continuously or semi-continuously measuring one or more parameters of said one or more subsequent processing systems of step f) thereby establishing, which controlled DS% and/or COD loading rate;
  • said method may be further characterized in that said subsequent processing at least part of said hydrolysed biomass material in one or more subsequent processing systems by transferring said hydrolysed biomass material to said one or more subsequent processing systems, by one or more feed lines at a controlled DS% and/or COD loading rate in accordance with step f) comprises: f1) transferring said hydrolyzed biomass material, by one or more feed lines, to a separation step to produce at least two fractions, of which one is rich in liquid compared to said hydrolyzed biomass material and one is rich in solids compared to said hydrolyzed biomass material, and/or, f2) transferring, by one or more feed lines, said hydrolyzed biomass material, parts of, or all of, one or all of said at least two fractions produced in said separation step of step f1) to one or more processing units for anaerobic fermentation, and/or, f3) transferring, by one or more feed lines, said hydrolyzed biomass material, parts of, or all of,
  • thermal processing for reduction of nutrient concentration e.g. steam stripper
  • chemical or thermal reaction or extraction of inorganic or organic chemical compounds in the hydrolyzed biomass material such as magnesium-ammonium-phosphate, lignocellulosic compounds, feed additives, medical additives, cosmetic additives, etc.
  • said controlled DS% and/or COD loading rate of said hydrolyzed biomass material pr. unit of time through said one or more feed lines of steps f1)-f4) is controlled based on:
  • step d) and e) one or more thermal hydrolysis discharge or recirculation lines of said thermal hydrolysis system of step d) and e), and/or
  • said method is further characterized in that said non-Newtonian biomass material displays an apparent viscosity at different shear rates characteristic of a static yield stress, T 0 , of between 150 and 2500 Pa, such as above 200, such as above 250 Pa, such as above 300 Pa, such as above 350 Pa, such as above 400 Pa, such as above 450 Pa, such as above 500 Pa, such as below 2400 Pa, such as below 2300 Pa, such as below 2200 Pa, such as below 2100 Pa, such as below 2000 Pa, such as below 1900 Pa, such as below 1800 Pa, such as below 1700 Pa, such as below 1600 Pa, such as between 300 and 1700 Pa, such as between 400 and 1700 Pa, such as between 500 and 1700 Pa, such as between 600 and 1700 Pa, such as between 700 and 1700 Pa, such as between 800 and 1700 Pa, such as between 900 and 1700 Pa, such as between 1000 and 1700 Pa and/or displays a static yield stress, T 0 , of between 150 and 2500 Pa, such as above 200, such as above 250
  • said method is further characterized in that said non-Newtonian biomass material displays an apparent viscosity at different shear rates characteristic of a static yield stress, T 0 , of at least 500 Pa, such as at least 600 Pa, such as at least 700 Pa, such as at least 800 Pa, such as at least 900 Pa, such as at least 1000 Pa, such as at least 1100 Pa, such as at least 1200 Pa, such as at least 1300 Pa, such as at least 1400 Pa, such as at least 1500 Pa and/or displays a static yield stress, T 0 , which is at least 500 Pa, such as at least 600 Pa, such as at least 700 Pa, such as at least 800 Pa, such as at least 900 Pa, such as at least 1000 Pa, such as at least 1100 Pa, such as at least 1200 Pa, such as at least 1300 Pa, such as at least 1400 Pa, such as at least 1500 Pa.
  • T 0 which is at least 500 Pa, such as at least 600 Pa, such as at least 700 Pa, such as at least 800 Pa, such as at
  • said method is further characterized in that said non-Newtonian biomass material displays an apparent viscosity at different shear rates characteristic of a dynamic yield stress, T y , of between 50 and 500 Pa, such as above 60 Pa, such as above 70 Pa, such as above 80 Pa, such as above 90 Pa, such as above 100, such as above 150 Pa, such as above 200 Pa, such as as below 450 Pa, such as below 400 Pa, such as below 350 Pa, such as below 300 Pa, such as below 250 Pa, such as between 60 and 400 Pa, such as between 70 and 300 Pa, such as between 80 and 250 Pa and/or displays a dynamic yield stress, T y , of between 50 and 500 Pa, such as above 60 Pa, such as above 70 Pa, such as above 80 Pa, such as above 90 Pa, such as above 100, such as above 150 Pa, such as above 200 Pa, such as as below 450 Pa, such as below 400 Pa, such as below 350 Pa, such as below 300 Pa, such as below 250 Pa, such as between 60 and
  • said method is further characterized in that said non-Newtonian biomass material displays an apparent viscosity at different shear rates characteristic of a dynamic yield stress, T y , which is at least 50 Pa, such as at least 60 Pa, such as at least 70 Pa, such as at least 80 Pa, such as at least 90 Pa, such as at least 100 Pa, such as at least 110 Pa, such as at least 120 Pa, such as at least 130 Pa, such as at least 140 Pa, such as at least 150 Pa, and/or displays a dynamic yield stress, T y , of at least 50 Pa, such as at least 60 Pa, such as at least 70 Pa, such as at least 80 Pa, such as at least 90 Pa, such as at least 100 Pa, such as at least 110 Pa, such as at least 120 Pa, such as at least 130 Pa, such as at least 140 Pa, such as at least 150 Pa.
  • T y which is at least 50 Pa, such as at least 60 Pa, such as at least 70 Pa, such as at least 80 Pa, such as at least 90 Pa, such as at least 100
  • said method is further characterized in that said thermal hydrolysis system of steps d) and e) includes:
  • said method is further characterized in that said non-Newtonian biomass material has a dry-matter content (DS%) above 20% and:
  • the biomass material is pre-heated in said pulpers of steps a) to c) and thermally hydrolysed in said thermal hydrolysis system of steps d) and e) by subjecting said biomass material to multiple steps involving stepwise heating and cooling.
  • said method is further characterized in that said non-Newtonian biomass material has a dry-matter content (DS%) above 20% and wherein said one or more subsequent processing systems of step f) includes: f 1 ) a separation step to produce at least two fractions, of which one is rich in liquid compared to said hydrolysed biomass material and one is rich in solids compared to said hydrolysed biomass material, and, f2) transferring, by one or more feed lines, said hydrolysed biomass material, parts of, or all of, one or all of said at least two fractions produced in said separation step of step f 1 ) to one or more processing units for anaerobic fermentation, and, f3) transferring, by one or more feed lines, said hydrolysed biomass material, parts of, or all of, one or all of said at least two fractions produced in said separation step of step f1) to one or more processing units for thermal reduction of organic compounds, and wherein:
  • step f2 at least part of a material resulting from said anaerobic fermentation of step f2) is at least partly dewatered and the resulting dewatered material is transferred by one or more feed lines, to said one or more processing units for thermal reduction of organic compounds of step f3).
  • this stepwise heating and cooling will preferably take place in one or more pulpers for heating, one or more reactors for treatment at a pre-selected temperature of above 150°C, more preferably above 160°C, or even more preferably above 180°C, and one or more flashtanks for pressure reduction and/or cooling.
  • the individual vessels employed in this stepwise heating and cooling may be connected in parallel or in series.
  • any of the above embodiments in which the biomass material is pre-heated in said pulpers of steps a) to c) and thermally hydrolysed in said thermal hydrolysis system of steps d) and e) by subjecting said biomass material to multiple steps involving stepwise heating and cooling, could be performed either as a continuous or a discontinuous process with tubular or tank vessels.
  • the total volume of each preheating pulper is typically equal to or greater than the corresponding average reactor filling volume. More preferably the total volume of each preheating pulper is typically equal to or greater than 2 times the corresponding average reactor filling volume.
  • the preheating pulper used is a pulper in accordance with the first aspect of the present invention.
  • said method is further characterized in that said resulting hydrolyzed biomass material of step e) is recirculated by transport from i) downstream said hydrolysis system of steps d) and e), to ii) upstream one or more of said pulpers of steps a) - c) and mixed with said nonNewtonian biomass material thereby acting to reduce the apparent viscosity, e.g. static yield stress, T 0 , and/or dynamic yield stress, T y , of the material fed to said pulpers.
  • said apparent viscosity e.g. static yield stress, T 0 , and/or dynamic yield stress, T y
  • said method is further characterized in that preheated biomass material from one or more pulpers of steps a) - c) is recirculated by transport to upstream said one or more pulpers of steps a) - c) and mixed with said non-Newtonian biomass material thereby acting to reduce the apparent viscosity, e.g. static yield stress, T 0 , and/or dynamic yield stress, T y , of the material fed to said pulpers.
  • preheated biomass material from one or more pulpers of steps a) - c) is recirculated by transport to upstream said one or more pulpers of steps a) - c) and mixed with said non-Newtonian biomass material thereby acting to reduce the apparent viscosity, e.g. static yield stress, T 0 , and/or dynamic yield stress, T y , of the material fed to said pulpers.
  • said method is further characterized in that recirculating said resulting hydrolyzed biomass of step e) or preheated biomass material of step b) is achieved by use of one or more mixing augers and pumps, preferably progressive cavity pumps, and preferably one or more augers with a conveying capacity of at least 1.5 times that of the pumps.
  • said method is further characterized in that recirculating said resulting hydrolyzed biomass or preheated biomass material is achieved by use of one or more mixing augers and pumps, preferably a progressive cavity pumps, and preferably one or more augers with a conveying capacity of at least 1.5 times that of the pumps.
  • said method further comprises the steps of:
  • dilution liquid e.g. water
  • T y the apparent viscosity, e.g. the static yield stress, To, and/or dynamic yield stress, T y , of said non-Newtonian biomass material, said preheated biomass material, said hydrolyzed biomass material and/or
  • non-Newtonian biomass material acting to directly or indirectly influence other properties of the biomass material, e.g. chemical or biochemical composition, microbial composition or content, cellular structure, particle size distribution or particle shape distribution, known to directly or indirectly influence the apparent viscosity, e.g. static yield stress and/or dynamic yield stress, of said nonNewtonian biomass material.
  • properties of the biomass material e.g. chemical or biochemical composition, microbial composition or content, cellular structure, particle size distribution or particle shape distribution, known to directly or indirectly influence the apparent viscosity, e.g. static yield stress and/or dynamic yield stress, of said nonNewtonian biomass material.
  • said method is further characterized in that heat-exchangers are employed to recover heat from the cooling of said hydrolyzed biomass material of step e) prior to said hydrolyzed biomass material being subjected to said subsequent processing in said one or more processing units of steps f1) f4), preferably by cooling said hydrolyzed biomass of step e) by subjecting said hydrolyzed biomass material to heat-exchange with water in a heat-exchanger, and subsequently injecting said water into said non Newtonian biomass material of step a) or pre-heated biomass material of step b).
  • said method is further characterized in that said recovered heat is used to either:
  • said method is further characterized in that the apparent viscosity of said non-Newtonian biomass material of step a) is indicative of, and/or said static yield stress, T 0 , of said nonNewtonian biomass material of step a) is, above 2000 Pa, such as above 2200 Pa, such as above 2300 Pa, and the apparent viscosity of the material fed to said pulpers is reduced to a value indicative of a static yield stress, T 0 , below 1700 Pa, such as below 1500 Pa, and/or the static yield stress, T 0 , of the material fed to said pulpers is reduced to, below 1700 Pa, such as below 1500 Pa, and
  • said method is further characterized in that the apparent viscosity of said non-Newtonian biomass material of step a) is indicative of, and/or said dynamic yield stress, T y , of said nonNewtonian biomass material of step a) is, above 300 Pa, such as above 350 Pa, such as above 400 Pa, and the apparent viscosity of the material fed to said pulpers is reduced to a value indicative of a dynamic yield stress, T y , below 300 Pa, such as below 250 Pa, and/or the dynamic yield stress, T y , of the material fed to said pulpers is reduced to, below 300 Pa, such as below 250 Pa, and
  • steps f1) - f4) optionally inorganic particles and/or undissolved material is continuously separated from said hydrolyzed biomass material of step by degritting e) prior to said subsequent processing of steps f1) - f4).
  • said method is further characterized in that at least part of the at least one fraction of step f1) rich in liquid compared to said hydrolyzed biomass material is recirculated by transport to
  • the homogenization and pre-heating of said non-Newtonian biomass material in said one or more pulper(s) in steps a) - c), and the thermal hydrolysis of steps d) - e) is performed in a system in accordance with the first aspect of the present invention.
  • step f said controlled DS% and/or COD loading rate of said hydrolysed biomass material through said one or more feed lines of step f), is controlled based on:
  • step d) and e) one or more thermal hydrolysis discharge or recirculation lines of said thermal hydrolysis system of step d) and e), and/or
  • step f - continuously or semi-continuously measuring one or more parameters of said one or more subsequent processing systems of step f) thereby establishing, which controlled DS% and/or COD loading rate;
  • said means may be further characterized in that said subsequent processing at least part of said hydrolysed biomass material in one or more subsequent processing systems by transferring said hydrolysed biomass material to said one or more subsequent processing systems, by one or more feed lines at a controlled DS% and/or COD loading rate in accordance with step f) comprises: f1) means for transferring said hydrolyzed biomass material, by one or more feed lines, to a separation step to produce at least two fractions, of which one is rich in liquid compared to said hydrolyzed biomass material and one is rich in solids compared to said hydrolyzed biomass material, and/or, f2) means for transferring, by one or more feed lines, said hydrolyzed biomass material, parts of, or all of, one or all of said at least two fractions produced in said separation step of step f1) to one or more processing units for anaerobic fermentation, and/or, f3) means for transferring, by one or more feed lines, said hydrolyzed biomass material, parts
  • said controlled DS% and/or COD loading rate of said hydrolyzed biomass material pr. unit of time through said one or more feed lines of steps f1)-f4) can be controlled based on: - continuously or semi-continuously determining the apparent viscosity, e.g. the static yield stress, T 0 , and/or dynamic yield stress, T y , of said non-Newtonian biomass material, said pre-heated biomass material and/or said hydrolyzed biomass material, by continuously or semi- continuously measuring pressure drop, temperature and flowrate in:
  • step d) and e) one or more thermal hydrolysis discharge or recirculation lines of said thermal hydrolysis system of step d) and e), and/or
  • said method is further characterized in that said non-Newtonian biomass material displays an apparent viscosity at different shear rates characteristic of a static yield stress, T 0 , of at least 500 Pa, such as at least 1000 Pa, such as at least 1500 Pa, and/or displays a static yield stress, To, of at least 500 Pa, such as at least 1000 Pa, such as at least 1500 Pa.
  • said method is further characterized in that said non-Newtonian biomass material displays an apparent viscosity at different shear rates characteristic of a dynamic yield stress, T y , of at least 50 Pa, such as at least 60 Pa, such as at least 70 Pa, such as at least 80 Pa, such as at least 90 Pa, such as at least 100 Pa and/or displays a dynamic yield stress, T y , of at least 50 Pa, such as at least 60 Pa, such as at least 70 Pa, such as at least 80 Pa, such as at least 90 Pa, such as at least 100 Pa.
  • a method for retrofitting an existing system comprising a pulper for homogenizing and pre-heating a biomass material having a dry-matter content (DS%) above 8%, preferably at least 12%, such as above 14%, such as above 16%, preferably above 18%, and a thermal hydrolysis reactor for subsequent thermal hydrolysis of said biomass material, whereby said retrofitting ensures that said pulper is characterized in that:
  • the total volume of said pulper is > 2.6 times and ⁇ 20 times, preferably 2.6 to 6 times, the average filling volume of said thermal hydrolysis reactor
  • said pulper comprises an outlet nozzle, for discharging said pre-heated material from said pulper, which is placed in such a way that:
  • a varying pressure drop in the pulper feed line resulting from varying dry solids concentration in the pulper feed system (and the therefrom resulting variations in apparent viscosity), and the consequential difficulty in establishing a stable dilution rate to control apparent viscosity, may be mitigated by intensifying the mixing in pulper.
  • This intensified mixing may be obtained by recycling, pre-heated and/or hydrolysed material and mixing it into the pulper feed system to homogenize the characteristics of the material ultimately fed to the pulper.
  • pre-heated biomass material produced in a pulper from a non-Newtonian biomass material and to be subsequently fed to any downstream thermal hydrolysis reactor of a TH P system, and/or subsequently from the THP system to any subsequent processing steps is of a uniform temperature, i.e. such that the average standard variation in temperature is ⁇ 12°C or more preferably ⁇ 6°C, and even more preferably ⁇ 2°C, when this standard variation in temperature is calculated based on a temperature measurement resolution of ⁇ 5 seconds, and used to calculate an overall average for each individual reactor filling.
  • the optimal temperature and pressures in the individual vessels in a method, system or plant according to the present invention will depend on the temperature in the feed to the THP.
  • the temperature in the feed to a THP is approximately 15 C, and the normal range is from 10 to 30 C, such as 15-25 C.
  • Flashsteam is preferably injected below liquid level in the pulpers. This ensures that steam condenses in the liquid while other non-condensable gases travel through the liquid and enters the headspace. Temperature and pressure transmitters are used to calculate the partial pressure of steam and other non-condensable gases in the headspace of the pulper vessels. Input from these instruments are used to control a valve that releases gases out from the vessels. This ensures that steam carried with the process gas may be is used for heating in other parts of the process.
  • the temperature of the liquid material fed to the pulper or pulpers in a method, system or plant according to the present invention will be in the range from 10 to 30 C, such as 15-25 C, e.g. 20-25 C, and the hydrolysis temperature applied in the one or more reactors working in parallel or series downstream of the pulper(s) will be in the range between 120 to 220 C, such as 140 to 180 C, such as 155-165 C, e.g. app 160 C depending on ambient temperature and feedstock.
  • the apparent viscosity of most liquid materials, and the static yield stress, T 0 , and/or dynamic yield stress, T y decreases with increasing temperature and increases with increasing dry solids content.
  • the apparent viscosity, and the static yield stress, T 0 , and/or dynamic yield stress, T y is normally greatly reduced by heating the material from ambient temperatures to approximately at least 50 C, such as app. At least 60 C, such as app. At least 70 C.
  • Apparent viscosity, and the static yield stress, T 0 , and/or dynamic yield stress, T y continues to decrease by heating to higher temperatures, but to a somewhat smaller extent.
  • the working pressure of the pulper(s) will typically be more than 1 barA.
  • this would be a process, in which the liquid material is pre-heated to a temperature of 40 C, with small amounts of noncondensable gases, and where the hydrolysis is performed at a temperature of 220 C (and 23.2 barA).
  • the pulper(s) will typically be run at 115 C and about 1.8 barA.
  • Another example of such a method and/or plant would be a method/plant relying on feed having a temperature of about 65-70 C and a reactor pressure about 7 barA.
  • the biomass material temperature and the hydrolysis temperature will be lower than 60 C and 200 C, respectively, such as lower than 40 C and 180 C, respectively.
  • An important aspect of the present invention is to recover heat. It is crucial that all steam brought back to the pre-heating vessels condenses into the material that is to be pre-heated. This becomes extra challenging in pulper(s) that operate(s) at low temperatures because apparent viscosity, and static yield stress, T 0 , and/or dynamic yield stress, T y , increases with decreasing temperatures.
  • so-called steam 33escribe33g which is characterized by steam traveling from the injection point through the liquid surface, can be avoided by ensuring efficient mixing of the material in the pre-heating vessel. The density of steam decreases with decreasing pressure. As a result, the volume of steam transferred to a pre-heating vessel will in most scenarios be large.
  • This effect can be exploited and used to mix the material in the pre-heating vessel by injecting steam at carefully designed injection points. This makes it possible to treat highly viscous materials with high dry solids content, such as above 8%, preferably at least 12%, even at low temperatures. Efficient mixing is not only important for ensuring condensation of all steam returned to the pre-heating vessel(s), but also for homogenizing the material prior to further processing. Thus, homogenizing the material prior to treatment in any downstream reactor(s) also ensures a more complete hydrolysis.
  • apparent viscosity, and static yield stress, T 0 , and/or dynamic yield stress, T y increases with dry solid concentration, whereas apparent viscosity decreases with increasing temperatures.
  • the apparent viscosity, and static yield stress, T 0 , and/or dynamic yield stress, T y of raw materials such as sludge is typically greatly reduced upon heating from ambient temperatures to about 50 C, such as about 50 C to 70 C, such as 60 to 65 C. Heating to even higher temperatures will lead to a further reduction in apparent viscosity, and static yield stress, T 0 , and/or dynamic yield stress, T y .
  • the present invention enables operation at high dry solids concentration. As would be known by the skilled person, high dry solids concentrations will in itself contribute to reduced steam consumption in the magnitude of app. 10%- 30% depending on material characteristics.
  • a further preferred embodiment of the present invention is for any pulper(s) to include a steam introduction system that enables high intensity mixing by using voluminous vapors, whereby the need for mechanical mixing as such would be reduced.
  • Whichever means of mixing are used in a certain embodiment, enhanced mixing can be achieved through an optimized orientation of the lances and through additional pumping.
  • the present invention thus, provides a method for continuous or batch hydrolysis of material by using pre-heating and cooling by using injection of flash steam and facilitating steam flashing, respectively.
  • the preheating pulper feed is either introduced into the bottom of the preheating pulper, or above liquid level of the preheating pulper in combination with a material size reduction and distribution system that increases specific surface area of the cold material, or below liquid level of the preheating pulper in combination with a material size reduction and distribution system that increases specific surface area of the cold material.
  • reactors of a method or plant according to the present invention can be in series or in parallel.
  • Figure 1(A) shows a rotational rheometer for measuring the static and dynamic yield stress of a biomass material.
  • the rotational rheometer includes a vane that can be immersed in a cup comprising the biomass material.
  • Figure 1(B) shows the viscosity characteristics, including the relation between shear rate and shear stress, of different kinds of non-Newtonian liquids/biomass materials.
  • Figure 1(C) shows typical shear stress-shear rate curves obtained for 2 different samples of municipal sewage sludge obtained by use of a rotational rheometer as the one shown in figure 1 (A).
  • Figure 1(D) shows typical shear stress-shear rate curve obtained for 2 hydrolysed municipal sewage sludge obtained by use of a rotational rheometer as the one shown in figure 1 (A).
  • Figure 2 shows the viscosity characteristics of different kinds of sludge as regards the relation between shear rate and shear stress.
  • Figure 3 illustrates the calculated pressure drop (head loss) in a pulper feed line as a function of the flow rate for a certain type of waste activated sludge as a function of flowrate at high temperature (low pressure drop) and at low temperature (high pressure drop), respectively.
  • Figure 4 shows the calculated head loss (bar) as a function of pipe diameter (mm) for a sludge transfer line for two different sludge qualities and pipe configurations at approx. 20-25°C.
  • Figure 5 illustrates the average temperature of a sludge mixture as a function of return flow temperature.
  • Figure 6 illustrates the average temperature of a sludge mixture as function of return flow ratio at a return flow temperature of 90°C and a feed flow temperature of 20°C.
  • FIG. 7 shows a possible design of a particular beneficial pulper design of the methods, systems, process equipment and plants employing Thermal Hydrolysis Processes (THP) of the present invention.
  • THP Thermal Hydrolysis Processes
  • Figure 8 shows embodiments of the present invention including a particular beneficial pulper design according to the present invention.
  • Figure 9 shows a preferred sludge extruder in a particular beneficial pulper design according to the present invention.
  • Figure 10A shows data from a case study in relation to performance data of a pulper modification upgrade, involving the upgrade from a prior art design (8 hour trends) to a particular beneficial pulper design according to the present invention (16 hour trends).
  • Figure 10B shows the standard deviation of reactor feed temperature for individual reactor fillings in a method according to the present invention, employing a pulper according to the present invention based on temperature measurements every 5 seconds.
  • Figure 11 shows data from a case study in relation to performance data of a pulper modification upgrade as regards reactor flow, involving the upgrade from a prior art design (without new invention) to a particular beneficial pulper design according to the present invention (with new invention).
  • Figures 12, 13A and 13B show the relationship between fo and WAS% when operating at selected dry solids content from 16% to 18%DS, during development and testing of the particularly beneficial pulper design according to the present invention described in example 4.
  • Figure 14 shows the relationship between specific energy content, measured as COD/VS and rheology, measured as T 0 when making use of a particularly beneficial pulper design according to the present invention described in example 4.
  • Figure 15 shows the relationship between T 0 and WAS/Primary sludge ratio when making use of a particularly beneficial pulper design according to the present invention described in example 4.
  • Figure 16 shows the relationship between T 0 and organic Nitrogen content of VS when making use of a particularly beneficial pulper design according to the present invention described in example 4.
  • the present invention relates to methods, systems, process equipment and plants employing Thermal Hydrolysis Processes (THP), which make use of pulpers for preheating.
  • the present invention also relates to methods for retrofitting existing plants employing Thermal Hydrolysis Processes (THP).
  • the present invention relates to methods, systems, process equipment and plants employing Thermal Hydrolysis Processes (THP), which are useful for the processing of “biomass material”, having a dry-matter content (DS%) of at least 8%, preferably at least 12%, such as at least 14%, such as at least 16%, such as at least 18%, such as at least 20%.
  • DS% dry-matter content
  • biomass material which may be processed in the methods, systems, process equipment and plants of the present invention stems from so-called primary wastewater treatment, involving gravity sedimentation of screened, degritted wastewater to remove settleable solids. In many scenarios, this will amount to slightly more than one-half of the suspended solids ordinarily present in wastewater.
  • the residue from primary treatment is a concentrated suspension of particles in water called, also often referred to as “primary sludge” or “primary biosolid”.
  • secondary municipal wastewater treatment e.g.
  • microorganisms in suspension are used to remove biodegradable organic material from the wastewater.
  • Part of the organic material is oxidized by the microorganisms to produce carbon dioxide and other end products, and the remainder provides the energy and materials needed to support microorganism growth.
  • the microorganisms thereby formed settle as particles, and, following biological treatment, this excess biomass is separated in sedimentation tanks as a concentrated suspension called “secondary sludge”/ “secondary biosolid” or “waste activated sludge”/”WAS”.
  • WAS waste activated sludge
  • Return Activated Sludge This part, i.e. the retuned part, is sometimes referred to as “Return Activated Sludge “RAS”.
  • “primary sludge”/”primary biolsoid”, “secondary sludge”/”secondary biosolid”/”waste activated sludge”/”WAS” and “Return Activated Sludge “RAS” are all solid, semisolid, or slurry residual materials, which are produced as a by-product of wastewater treatment processes.
  • biomass material is to be construed as referring to any material comprising organic material, i.e. material based on living organisms, such as microorganisms, plants and animals, which may be used as a “substrate” in methods, systems, process equipment and plants employing Thermal Hydrolysis Processes (THP) according to the present invention.
  • THP Thermal Hydrolysis Processes
  • biomass materials are energy crops, agricultural crop residues, forestry residues, algae, wood processing residues, municipal waste, and wet waste, such as crop wastes, forest residues, purpose-grown grasses, woody energy crops, algae, industrial wastes, sorted municipal solid waste [MSW], urban wood waste, and food waste and waste from industry, farms and households, such as “wastewater” (see above), “biological sludge”, “sludge” or the like.
  • the “biomass material”, i.e. “substrate”, which is processed, comprises one specific “biomass material” or a specific mixture of several specific “biomass materials”, e.g “wastewater”, “primary sludge”/”primary biosolid”, “secondary sludge”/”secondary biosolid”/”waste activated sludge”/”WAS” and/or “Return Activated Sludge “RAS”.
  • this possible further specification of the “biomass material” is intended to provide specific examples of how a skilled person may arrive at a “biomass material” characterised by e.g.
  • a “biomass material”, i.e. “substrate”, displaying similar specific characteristics could equally well be obtained from another “biomass material”, or another mixture of “biomass materials”, than the one(s) specifically identified in the relevant aspect and/or embodiment.
  • Non-newtonian biomass material is to be construed as referring to a biomass material (see above), which does not follow Newton’s law of viscosity.
  • the viscosity of a “non-Newtonian biomass material” can change when under force to being either more liquid or more solid, and the relation between the shear stress and the shear rate, is either not linear and/or does not pass through the origin, as for Newtonian fluids, c.f. Figure 1 (B).
  • the relation between the shear stress and the shear rate is different and a constant coefficient of viscosity cannot be defined.
  • static yield point In the context of the present invention the term “static yield point”, and the term “T 0 ”, is to be construed as the amount of shear stress at which an otherwise solid material begins to flow, sometimes referred to as the “static yield stress”. Hence, in the context of the present invention “static yield point”/” static yield stress”/”T 0 ” is to be construed as a measure of the resistance of a given “biomass material” to flow, or in other words, it is to be construed as the shear stress required to start movement of a given “biomass material” in the form of a flow.
  • “static yield point”/“T o 7”static yield stress” is a property, which can be associated with a “biomass material” according to the present invention, whereby the “biomass material” does not flow unless the applied shear stress exceeds the “static yield point”/“T o 7”static yield stress”.
  • the SI unit for “static yield point”/”static yield stress”/”T 0 ” is Pascal (Pa) or Nm 2 .
  • the term “dynamic yield point”, and the term “T y ” is to be construed as the amount of shear stress to maintain flow of a material, sometimes referred to as the “dynamic yield stress”.
  • dynamic yield point”/”dynamic yield stress”/”“T y ” is to be construed as the shear stress required to maintain movement of a given “biomass material” in the form of a flow.
  • “dynamic yield point”/“T y ”dynamic yield stress” is a property, which can be associated with a “biomass material” according to the present invention, whereby the “biomass material” does not keep flowing unless the applied shear stress exceeds the “dynamic yield point”/“T y ’’/’’dynamic yield stress”.
  • the SI unit for “dynamic yield point”/”dynamic yield stress”/‘T y ” is Pascal (Pa) or Nm 2 .
  • the static, T 0 , and dynamic, T y , yield stress of a “biomass material” may be determined using a rotational rheometer.
  • the working principle is as follow. A vane is immersed in a cup comprising the “biomass material” as shown in Figure 1(A). The shaft’s angular velocity is then gradually increased, while the applied torque is measured. This, when combined with a proper calibration, yields a shear stress-shear rate curve, e.g. as the one shown in Figure 1 (C).
  • the “biomass material” labelled “1” originates from a Bio-P process and has a dry solids content of 18.2%.
  • the “biomass material” labelled “2” has been pretreated at approx. 80°C and has a dry solid concentration of 17.5%.
  • the measurements for both samples were made at 21°C. From a shear rate of app. 6 s-1 both materials show a Bingham plastic fluid behaviour, and the plastic viscosity (slope of the curve) is close to 0.
  • the dashed line corresponds to a dynamic yield stress of 130 Pa.
  • the key difference between the two materials is the amplitude of the static yield stress: 1200 Pa vs 400 Pa.
  • Apparent viscosity is the shear stress applied to a fluid divided by the shear rate.
  • the “apparent viscosity” is constant, and equals the Newtonian viscosity of the fluid.
  • the “apparent viscosity” depends on the shear rate as illustrated in figure 1 (C).
  • the apparent viscosity characteristics of the non-Newtonian biomass material which is preferably to be treated in the methods, systems, process equipment and plants employing Thermal Hydrolysis Processes (THP) of the present invention, is to be characterized by being indicative of a static yield stress, T 0 , of between 150 and 2500 Pa, such as at least 1000 Pa, such as at least 1100 Pa, such as at least 1200 Pa, such as at least 1300 Pa and such as at least 1400 Pa.
  • the nonNewtonian biomass material which is preferably to be treated in the methods, systems, process equipment and plants employing Thermal Hydrolysis Processes (THP) of the present invention, is to display a static yield stress, T 0 , of at least 1000 Pa, such as at least 1100 Pa, such as at least 1200 Pa, such as at least 1300 Pa and such as at least 1400 Pa.
  • T 0 a static yield stress
  • the apparent viscosity characteristics of the non-Newtonian biomass material which is preferably to be treated in the methods, systems, process equipment and plants employing Thermal Hydrolysis Processes (THP) of the present invention, is to be characterized by being indicative of a and/or dynamic yield stress, T y , of between 50 and 500 Pa, such at least 60 Pa, such as at least 70 Pa, such as at least 80 Pa, such as at least 90 Pa, such as at least 100 Pa, such as at least 110 Pa, such as at least 120 Pa, such as at least 130 Pa and such as at least 140 Pa.
  • T y Thermal Hydrolysis Processes
  • the nonNewtonian biomass material which is preferably to be treated in the methods, systems, process equipment and plants employing Thermal Hydrolysis Processes (THP) of the present invention, is to display a dynamic yield stress, T y , of at least 150 Pa, such as at least 160 Pa, such as at least 170 Pa, such as at least 180 Pa and such as at least 190 Pa.
  • T y a dynamic yield stress
  • the apparent viscosity of the a nonNewtonian biomass material, which is to be treated in the methods, systems, process equipment and plants employing Thermal Hydrolysis Processes (THP) of the present invention is adjusted to be indicative of a static yield stress, T 0 , below 1700 Pa such as below 1500 Pa, by reducing the apparent viscosity of a biomass material, which would otherwise be indicative of a static yield stress, T 0 , of above 2000 Pa, such as above 2200 Pa, such as above 2500 Pa, before this is feed to the pulpers of the methods, systems, process equipment and plants employing Thermal Hydrolysis Processes (THP) of the present invention.
  • the static yield stress, T 0 of a non-Newtonian biomass material, which is to be treated in the methods, systems, process equipment and plants employing Thermal Hydrolysis Processes (THP) of the present invention, which displays a static yield stress, T 0 , of above 2000 Pa, such as above 2200 Pa, such as above 2500 Pa, may be reduced to a static yield stress, T 0 , below 1700 Pa such as below 1500 Pa.
  • THP Thermal Hydrolysis Processes
  • the apparent viscosity of the a nonNewtonian biomass material, which is to be treated in the methods, systems, process equipment and plants employing Thermal Hydrolysis Processes (THP) of the present invention is adjusted to be indicative of a dynamic yield stress, T y , below 300 Pa such as below 250 Pa, by reducing the apparent viscosity of a biomass material, which would otherwise be indicative of a dynamic yield stress, T y , of above 300 Pa, such as above 350 Pa, such as above 400 Pa, before this is feed to the pulpers of the methods, systems, process equipment and plants employing Thermal Hydrolysis Processes (THP) of the present invention.
  • the dynamic yield stress, T y of a non-Newtonian biomass material, which is to be treated in the methods, systems, process equipment and plants employing Thermal Hydrolysis Processes (THP) of the present invention, which displays and/or dynamic yield stress, T y , of above 250 Pa, such as above 300 Pa, such as above 350 Pa, may be reduced to a dynamic yield stress, T y , below 250 Pa such as below 200 Pa.
  • THP Thermal Hydrolysis Processes
  • This may be done by adding dilution liquid, e.g. water, or adding additives to said nonNewtonian biomass material acting to reduce the apparent viscosity, e.g. the static yield stress, T 0 , and/or dynamic yield stress, T y , of the material fed to said pulpers, and/or by adding additives to said non-Newtonian biomass material acting to start an exotherm reaction that increases the temperature of said non-Newtonian biomass material, and/or adding additives to said non-Newtonian biomass material acting to directly or indirectly influence other properties of the biomass material, e.g. chemical or biochemical composition, microbial composition or content, cellular structure, particle size distribution or particle shape distribution, known to directly or indirectly influence the apparent viscosity, e.g.
  • COD chemical oxygen demand
  • volatile solids content VS
  • VS content % by weight
  • the term “ratio between the chemical oxygen demand (COD) and volatile solids content (VS), CO D/VS- ratio”, also sometimes referred to as the “specific energy content”, is to be construed as referring to the COD expressed in milligrams per litre (mg/L) divided by the VS expressed in % by weight.
  • the COD/VS-ratio of the non-Newtonian biomass material, which is to be treated in the methods, systems, process equipment and plants employing Thermal Hydrolysis Processes (THP) of the present invention is less than 2.0, such as less than 1.9, such as less than 1.8, such as less than 1.7 and such as less than 1.6.
  • the relationship between specific energy content, measured as COD/VS, and apparent viscosity, e.g. static yield stress, measured as T 0 , and/or dynamic yield stress, measured as T y , of the non-Newtonian biomass material, which is to be treated in the methods, systems, process equipment and plants employing Thermal Hydrolysis Processes (THP) of the present invention is as depicted in Figure 14, which is based on an average energy content in Primary sludge of 1 ,7 and an average energy content in in Waste Activated sludge of 1 ,45. This relationship has in the context of the present invention been found to be useful to determine the energy content, i.e.
  • COD/VS in sludge on basis of its apparent viscosity, e.g. static yield stress and/or dynamic yield stress. I.e. for static yield stress, To, for To >500 -1000 Pa and COD/VS >1 ,52 depending on type of substrate. Based on this relationship, the COD/VS-ratio of the non-Newtonian biomass material, which is to be treated in the methods, systems, process equipment and plants employing Thermal Hydrolysis Processes (THP) of the present invention, is preferably more than 1.5. Variations in energy content will, however, depend on sludge origin, sludge age, etc, and a calibration is recommended for each sludge mix.
  • THP Thermal Hydrolysis Processes
  • the term “degritting” is to be construed as referring to any process resulting in the removal of fine solid particles (grit) from a liquid carrier, e.g. by gravity separation (settling) or centrifugation.
  • separation is to be construed as referring to any process resulting in the separation of a starting mixture (e.g. a hydrolysed biomass material) into different portions and/or fractions thereof through differences in physical and/or chemical properties.
  • a starting mixture e.g. a hydrolysed biomass material
  • anaerobic fermentation is to be construed as referring to any process that results in the conversion of a hydrolysed biomass material to a desirable end product (e.g. organic acids, gases or alcohols), under anaerobic conditions.
  • a desirable end product e.g. organic acids, gases or alcohols
  • Incineration is to be construed as referring to full combustion of a given material, e.g. a hydrolysed biomass material, with excess of air.
  • Incineration may prevent spreading of deceases and environmentally hazardous substances including micro plastics.
  • Incineration is a method that eliminates the concerns of recycling biosolids to agricultural land and other land applications.
  • Incineration may also be used to eliminate the need for recovery and reuse of a range of micro and macro nutrients.
  • Incineration is a common technology to eliminate toxic substances. According to the European Waste Incineration Directive, incineration plants must be designed to ensure that the flue gases reach a temperature of at least 850 °C for 2 seconds in order to ensure proper breakdown of toxic organic substances.
  • the term “Gasification” is to be construed as referring to a process that converts biomass- or fossil fuel-based carbonaceous materials into gases, including as the largest fractions: nitrogen (N2), carbon monoxide (CO), hydrogen (H2), and carbon dioxide (CO2). This may be achieved by reacting the material, e.g. a hydrolysed biomass material, at high temperatures (typically >700 °C), without combustion/incineration, via controlling the amount of oxygen and/or steam present in the reaction. The resulting gas mixture is called syngas and may itself be used as a fuel due to the flammability of the H2 and CO of which the gas is largely composed.
  • Power can be derived from the subsequent combustion of the resultant gas, and is considered to be a source of renewable energy if the gasified compounds were obtained from a biomass material, e.g. a hydrolysed biomass material.
  • Gasification to syngas can be more efficient than direct incineration of the biomass material, e.g. a hydrolysed biomass material, because the syngas can be combusted at higher temperatures so that the thermodynamic upper limit to the efficiency defined by Carnot’s rule is higher.
  • Syngas may also be used as the hydrogen source in fuel cells, however the syngas produced by most gasification systems requires additional processing and reforming to remove contaminants and other gases such as CO and CO2 to be suitable for low-temperature fuel cell use, but high-temperature solid oxide fuel cells are capable of directly accepting mixtures of steam, and methane.
  • Syngas is most commonly burned directly in gas engines, used to produce methanol and hydrogen, or converted into synthetic fuel.
  • gasification can be an alternative to landfilling and incineration, resulting in lowered emissions of atmospheric pollutants such as methane and particulates.
  • Some gasification processes aim at refining out corrosive ash elements such as chloride and potassium, allowing clean gas production from otherwise problematic feedstock material.
  • Gasification of fossil fuels is currently widely used on industrial scales to generate electricity. Gasification can generate lower amounts of some pollutants as SO X and NOxthan incineration.
  • Pyrolysis is to be construed as referring to a process by which a solid (or a liquid) material, e.g. a hydrolysed biomass material, undergoes thermal degradation into smaller volatile molecules, without interacting with oxygen or any other oxidants.
  • Pyrolysis which is also the first step in gasification and incineration, occurs in the absence or near absence of oxygen, and it is thus distinct from incineration (burning), which can take place only if sufficient oxygen is present.
  • the rate of pyrolysis increases with temperature. In industrial applications the temperatures used are often 430 °C or higher, whereas in smaller- scale operations the temperature may be much lower.
  • Two well-known products created by pyrolysis are a form of charcoal called biochar, created by heating wood, and coke (which is used as an industrial fuel and a heat shield), created by heating coal. Pyrolysis also produces condensable liquids (or tar) and non-condensable gases. If the purpose is to maximize the yield of liquid products resulting from biomass pyrolysis, a low temperature, high heating rate, short gas residence time process would be required. For a high char production, a low temperature, low heating rate process would be chosen. If the purpose was to maximize the yield of fuel gas resulting from pyrolysis, a high temperature, low heating rate, long gas residence time process would be preferred.
  • reaction is to be construed as a mild form of pyrolysis at temperatures typically between 200 and 320°C.
  • Supercritical water oxidation is to be construed as referring to the process of oxidation occurring in supercritical water when an oxidant is added.
  • a supercritical fluid is any substance at a temperature and pressure above its critical point, where distinct liquid and gas phases do not exist, but below the pressure required to compress it into a solid. Water becomes supercritical at a temperature above app. 373°C and a pressure above app 220 bar.
  • Supercritical water liquification is to be construed as referring to the process of co-liquifying a given material with water at conditions where water is a supercritical state.
  • Supercritical water liquefaction can be utilized for effective treatment of biomass in terms of material recovery.
  • Cellulose one of the main components of biomass, is completely dissolved in supercritical water. Once dissolved, reaction of cellulose can take place swiftly by either hydrolysis and/or pyrolysis/torrefaction.
  • the hydrolysis reaction otherwise slower than pyrolysis/torrefaction due to the mass transfer limitation, is faster than decomposition in supercritical water, and efficient glucose recovery from cellulose has been shown to be possible.
  • Lignin can be also converted into specialty chemicals by using supercritical cresol/water mixture as a solvent.
  • Hydrothermal carbonization is to be construed as referring to a thermochemical treatment process where biomass is treated under hot compressed water to produce hydrochar.
  • HTC hydrothermal carbonization
  • HTC hydrothermal carbonization
  • Hydrothermal oxidation is to be construed as referring to a process involving treatment at temperatures and pressures below and above the critical point for water, i.e. app. 373°C and app 220bar, respectively.
  • Subcritical water oxidation achieves incomplete sludge oxidation ( ⁇ 95% COD removal) and produces high-strength liquors containing significant quantities of volatile fatty acids (VFAs).
  • SubCWO also achieves efficient destruction of the organic component of sludge solids, resulting in significant mass and volume reductions.
  • Supercritical wateroxidation (SCWO) on the other hand can completely oxidize the organic component of sludge (>99.9% COD reduction), produce high quality effluents and disposable ashes and air emissions.
  • electrochemical processing is to be construed as referring to processes involving the setting up of an electric field between anodes and cathodes to degrade and convert compounds.
  • Bioelectrochemcial processing are electrochemical processes where biological activity on the electrodes assists or drives the degradation. Biocatalysts may also be used to accelerate a more efficient degradation. Such methods are also called Microbial electrosynthesis.
  • Electrochemical processing designed for the waste water industry have been developed. These methods and the technology are still in the development phase, however, and more research and development is expected in the years to come.
  • biological processing for reduction of organic compounds is to be construed as referring to biological processing, which utilizes the biological growth of microorganisms to digest and bind compounds in e.g. waste water by controlling the processing conditions.
  • Important factors are temperature, pH, dissolved oxygen, nutrient concentration and the content of toxic materials.
  • These processes can be either aerobic or anaerobic, or can include arranging both aerobic and anaerobic processes in series.
  • a range of biological processing methods are established to achieve a reduction in organic compounds as well as nutrient reduction. This includes but is not limited to activated sludge treatment systems, Bio-P treatment systems, MBR (Membrane Bio Reactors), MMBR (Moving Bed Biofilm processes).
  • anaerobic ammonium oxidation (anammox) process is one such process, which has been widely acknowledged as an environmentally friendly and time-saving technique capable of achieving efficient nitrogen removal.
  • biological processing for reduction of nutrients concentration is to be construed as referring to e.g. annamox processes.
  • the term “chemical processing for reduction of nutrients concentration” is to be construed as referring to processing, which in different ways binds nutrients present in a material, e.g. a biomass material, chemically in order to remove (i.e. “strip”) the nutrients and other compounds from the material.
  • Typical chemical wastewater treatment processes are; chemical precipitation, ion exchange, neutralization, adsorption and disinfection processes.
  • Evaporation technologies can also be applied to bind nutrients chemically. The water is evaporated and recovered as a condensate which is low on nutrients. The condensation heat is recovered internally in evaporators to reduce overall energy consumption. Different evaporation principles are available.
  • Air strippers is another technology that can be applied to remove nutrients. The removal efficiency of nitrogen removal can be improved by increasing pH. Increased pH can be achieved by adding chemicals. Nitrogen removed by stripping can be recovered with chemicals to produce ammonia salts or by distillation as ammonia water.
  • thermal processing for reduction of nutrient concentration is to be construed as referring to processing, which at elevated temperature enhances the removal of nutrients present in a material, e.g. a biomass material being treated by chemical processing (see above).
  • a material e.g. a biomass material being treated by chemical processing (see above).
  • the efficiency of Air strippers can be improved by increased temperature which can be achieved by adding heat in various ways, indirectly through heat exchangers or directly by steam (e.g. in the form of a so-called steam stripper).
  • heat-exchangers is to be construed as referring to any means, which may be used for transferring heat energy present in one material to another material, e.g. by the cooling of a material, e.g. a hydrolysed biomass material, by subjecting it to heat-exchange with water, which is then heated.
  • the terms “retention time” and “average overall retention time” are to be construed as referring to Hydraulic Retention Time (HRT), defined as the ratio between the average reactor filling volume and the feed flow rate. In other words it represents the average amount of time that any sub-part of the biomass material stay in a reactor or tank. It is calculated by dividing the average filing volume of a reactor (e.g. m3) by the influent flow rate (e.g. m3/day).
  • HRT Hydraulic Retention Time
  • SRT solids retention time
  • the term “DS%” is to be construed as referring to the total dry solids content of a given material, including both the suspended solids and the dissolved materials, e.g. salts.
  • the term “(DS%)”, also called “dry-matter content” is to be construed as referring to the percentage of solids in a mixture, e.g. a “biomass material”. The higher this proportion, the drier the mixture.
  • One unit of DS content is % by weight. Expressed as a ratio of weights obtained before and after a drying process, in which a sample of the material is placed in an oven at a temperature of 105 °C until a steady mass is obtained. Drying at 175-185°C and comparing the result obtained by drying at 105°C enables the evaluation of the content of crystallisation water of certain salts, e.g. hydroxides, which might be part of the sample.
  • VS volatile solids
  • VS% is to be construed as referring to the % of the total dry solids content (DS%), which is volatile at a temperature of 550°C.
  • SS suspended solids
  • TSS Total Suspended Solids
  • SS and TSS can be reported as mg/L, ppm or %.
  • the amount of suspended solids (SS) or total suspended solids (TSS) may be measured by the use of e.g acoustic or ultrasonic type instrument, or gamma type instrument, or by measuring the turbidity of the sample in question.
  • particle size distribution is to be construed as referring to the particle-size distribution of particles dispersed in a sample, in the form of a list of values or a mathematical function that defines the relative amount, typically by mass, of particles present according to their size.
  • particle shape distribution is to be construed as referring to the particle-shpae distribution of particles dispersed in a sample, in the form of a list of values or a mathematical function that defines the relative amount, typically by mass, of particles present according to their shape.
  • the particle size distribution and/or the particle shape distribution of a sample may be determined by a number of different techniques, such as Sieve analysis, Air elutriation analysis, Photoanalysis, Optical granulometry, Optical counting methods, Electroresistance counting methods, Sedimentation techniques, Laser diffraction methods, Laser Obscuration Time” (LOT) or “Time Of Transition” (TOT) and/or Acoustic spectroscopy or ultrasound attenuation spectroscopy.
  • Sieve analysis Air elutriation analysis
  • Photoanalysis Optical granulometry
  • Optical counting methods Electroresistance counting methods
  • Sedimentation techniques Sedimentation techniques
  • Laser diffraction methods Laser Obscuration Time” (LOT) or “Time Of Transition” (TOT)
  • Acoustic spectroscopy or ultrasound attenuation spectroscopy such as Sieve analysis, Air elutriation analysis, Photoanalysis, Optical granulometry, Optical counting methods, Electrores
  • the term “FOS/TAC ratio by the Nordmann method” is to be construed as referring to measurements of volatile organic acids (FOS) and total inorganic carbon (TAG) (i.e. carbon buffer capacity) by what is normally referred to as the Nordmann method.
  • the FOS/TAC ratio is a commonly applied measurement for observing stability and indicating if corrective action must be taken in an anaerobic digestion process of e.g. a biogas plant.
  • FOS/TAC a representative sample of the relevant biomass material is used. All particulate matter must be removed by filtration or centrifugation, and all sample preparation must be performed in the same manner. Typical sample volume of the substrate is 20 mL but may be diluted with deionized water if there is an insufficient amount. Note that the TAC equation must be altered to account for the dilution.
  • TAC in mg CaCO 3 /L is measured by titrating the sample to pH 5.0 with 0.1 N sulphuric acid and can be calculated by using the following equation:
  • TAC (EP1 x Concentration of titrant x 50045) I (Volume of sample) where EP1 is the volume of the titrant at pH 5.0 in mL. If Ctitrant is 0.1 N and Volume of sample is 20 mL, the equation can be simplified to:
  • TAC EP1 x 250 [mg/L CaCO 3 ]
  • the Nordmann method is used to determine the FOS (in mg/L Hac) content by titrating a 20 mL sample from pH 5.0 to pH 4.4 using 0.1 N sulphuric acid. Using the following equation where B is the acid consumed in mL (i.e. volume of titrant at pH 5.0 - volume of titrant at pH 4.4).
  • FOS/TAC value 0.3-0.4 is considered optimal.
  • every digester has a unique optimal ratio. Above 0.4, there is normally excessive biomass input and below 0.3, there is normally too little biomass input.
  • the term “amount of dissolved organic carbon”, also sometimes called DOC, is to be construed as referring to the fraction of organic carbon in a given biomass material, which can pass through a filter with a given pore size, typically between 0.22 and 0.7 micrometers. The fraction remaining on the relevant filter is then called particulate organic carbon (POC).
  • the term “amount of dissolved organic nitrogen”, also sometimes referred to as (DON) is to be construed as referring to that subset of the dissolved organic carbon (DOC) pool that also contains N.
  • DIN Dissolved inorganic nitrogen
  • DIN Dissolved inorganic nitrogen
  • dissolved organic matter refers to the total mass of the dissolved organic matter. That is, DOM also includes the mass of other elements present in the organic material, such as nitrogen, oxygen and hydrogen.
  • DOC is a component of DOM and there is typically about twice as much DOM as DOC.
  • the methods, systems, process equipment and plants employing Thermal Hydrolysis Processes (THP) of the present invention includes several improvements compared with prior art thermal hydrolysis processes.
  • the methods, systems, process equipment and plants employing Thermal Hydrolysis Processes (THP) of the present invention enable stable operation of thermal hydrolysis systems at high apparent viscosity and variable high dry solids content.
  • Thermal hydrolysis operated at high dry solids concentration is important in order to minimize specific energy consumption (e.g. measured as kg steam/tonne dry solids).
  • THP Thermal Hydrolysis Processes
  • substrates or substrate mixtures now-a-days treated by thermal hydrolysis could be of significant different apparent viscosity, e.g. static yield stress and/or dynamic yield stress.
  • apparent viscosity e.g. static yield stress and/or dynamic yield stress
  • the methods, systems, process equipment and plants employing Thermal Hydrolysis Processes (THP) of the present invention enables continuous monitoring of the apparent viscosity, e.g. static yield stress and/or dynamic yield stress, of the mixture inside the thermal hydrolysis process, and makes it possible to optimize both mixture rate, preheating as well as dilution rate in order to minimize specific heat consumption during the thermal hydrolysis process.
  • the methods, systems, process equipment and plants employing Thermal Hydrolysis Processes (THP) of the present invention includes a design of a pre-conditioning system, that increases the feed temperature and enable operation at high apparent viscosity, e.g static yield stress and/or dynamic yield stress, and thus facilitate for high dry solids thermal hydrolysis.
  • the system also includes a monitoring system to ensure compliant processing conditions.
  • the methods, systems, process equipment and plants employing Thermal Hydrolysis Processes (THP) of the present invention optionally includes a pre-conditioning device to further reduce apparent viscosity, e.g. static yield stress and/or dynamic yield stress, (due to both increased temperature and applied shear forces) enabling operation at higher dry solids content.
  • a pre-conditioning device to further reduce apparent viscosity, e.g. static yield stress and/or dynamic yield stress, (due to both increased temperature and applied shear forces) enabling operation at higher dry solids content.
  • apparent viscosity e.g. static yield stress and/or dynamic yield stress
  • This addresses challenges in both the THP feed system due to the high apparent viscosity, e.g. static yield stress and/or dynamic yield stress, as well as reducing the specific heat consumption in the thermal hydrolysis process.
  • the reason for reduced heat consumption in the thermal hydrolysis process is both the higher dry solids concentration, as well as the elevated feed temperature.
  • the pre-conditioning device will be perfectly matched with the cooling demand usually required for hydrolysed sludge and thus enable a more cost efficient heat recovery that directly influences the specific steam consumption required in thermal hydrolysis processes.
  • the pre-conditioning device may also receive preheated dilution water from other sources depending on what is most cost efficient.
  • the methods, systems, process equipment and plants employing Thermal Hydrolysis Processes (THP) of the present invention enables these to be self-optimizing through controlling the pre-heating and dilution rate depending on measured apparent viscosity, e.g. static yield stress and/or dynamic yield stress, through an advanced monitoring system.
  • measured apparent viscosity e.g. static yield stress and/or dynamic yield stress
  • the measured apparent viscosity can be used to optimize the ratio of different substrates throughout the process cycle.
  • THP Thermal Hydrolysis Processes
  • THP Thermal Hydrolysis Processes
  • THP Thermal Hydrolysis Processes
  • THP Thermal Hydrolysis Processes
  • THP Thermal Hydrolysis Processes
  • the methods, systems, process equipment and plants employing Thermal Hydrolysis Processes (THP) of the present invention allow for operation of THP systems at highest possible dry solids content, while at the same time reducing the specific energy demand. This builds on the finding that apparent viscosity, e.g. static yield stress and/or dynamic yield stress, is a limiting factor for operating THP plants at high dry solids.
  • the invention uses the continuously monitored rheology data and thermal hydrolysis performance data as information to learn the thermal hydrolysis systems to self-adjust the dry solids content at highest possible dry solids level.
  • the methods, systems, process equipment and plants employing Thermal Hydrolysis Processes (THP) of the present invention allow for the prediction of dry solid content (DS%) and Volatile Solids Content (VS%) based on rheology data measured for a given biomass material throughout the process. It does this by establishing a series of soft sensors throughout the thermal hydrolysis process as the rheology changes throughout the process and the continuous measurement of rheology characteristics allows to the use of these rheology data to predict DS% and VS%, specific energy content (COD/VS) and/or nitrogen content of the biomass material, e.g. sludge, being processed. This again allows for the optimization of apparent viscosity, e.g.
  • THP Thermal Hydrolysis Processes
  • the methods, systems, process equipment and plants employing Thermal Hydrolysis Processes (THP) of the present invention allow for the inclusion of a self-correcting system into the THP process to avoid operational disturbances in case of varying apparent viscosity, e.g. static yield stress and/or dynamic yield stress, in the substrate or mixture of substrates being treated.
  • apparent viscosity e.g. static yield stress and/or dynamic yield stress
  • the system will automatically adjust the apparent viscosity, e.g. static yield stress and/or dynamic yield stress, through a stepwise dilution with preheated water in a pulper feed system and in the pulper circulation/reactor feed system.
  • Preheating is preferably achieved by cooling of hydrolysed sludge at the back end of the process.
  • the over-all steam consumption in the thermal hydrolysis system may typically decrease in the range of 3-15% as a result of such preheating.
  • THP Thermal Hydrolysis Processes
  • the methods, systems, process equipment and plants employing Thermal Hydrolysis Processes (THP) of the present invention includes a novel design of a preheating vessel (pulper) particularly suited to enable operation at elevated apparent viscosity, e.g. static yield stress and/or dynamic yield stress.
  • Pulper (s) Some of the key elements of the design of this preferred pre-heating vessel (pulper (s)) is to utilize the discovery that in a thermal hydrolysis pulper, fitted for recovery of downstream flash steam, the upper section of the vessel is warmer and more homogeneous than the bottom section of the vessel, coupled with the fact that operation becomes increasingly difficult if the temperature of the material in the pulper discharge line is not kept relatively constant. Steam or recovered flash steam is injected into the lower part of the vessel and thus heat the substrate as the steam/flash steam raises to the upper section of the vessel. This leads both to warming up cold sludge and to transferring warm sludge towards the upper part of the vessel, while a larger proportion of the cold sludge is found in the lower part of the vessel.
  • the injection of steam in the lower part of the vessel causes a mixing effect as it travels through the liquid and condenses in contact with colder liquid.
  • this injection of steam is done by steam lances.
  • substrate may (or may not) be circulated on the vessel by pumping substrate from an elevated warmer part of the vessel and reintroduced into the colder bottom section and/or into the top section together with cold substrate, preferably through an extruder or a similar distribution system.
  • any extruder may optionally be located outside the pre-heating vessel, and my optionally be replaced with a recycle flow back to a pre-conditioner.
  • the methods, systems, process equipment and plants employing Thermal Hydrolysis Processes (THP) of the present invention in the above-mentioned preferred aspect includes a specifically designed Pre-conditioning device upstream the pulper (in connection with the pulper feed system) to enable efficient dilution, pre-heating mixing and recovery of heat from downstream hydrolysed sludge.
  • This Preconditioning device applied at the front end of a thermal hydrolysis system, thereby becomes an integrated part of the THP “train” and may serve as a buffer between any upstream pre-dewatering system or substrate processing or substrate reception system and the actual thermal hydrolysis system.
  • the pre-conditioning system links with the back end of the thermal hydrolysis system by capturing surplus heat that is available in warm hydrolysed sludge and recovers this heat to increase the feed temperature of cold substrate entering the thermal hydrolysis system.
  • the methods, systems, process equipment and plants employing Thermal Hydrolysis Processes (THP) of the present invention use rheology data from hydrolysed sludge measured on e.g. a digester feed line and/or pre-cooler and convert this into expected DS%, VS%, COD/VS and/or N-content and thereby enables the calculation of and the control of the digester loading rate based on rheology data of the biomass material at different stages before and during the THP process.
  • THP Thermal Hydrolysis Processes
  • the methods, systems, process equipment and plants employing Thermal Hydrolysis Processes (THP) of the present invention include an extensive digester monitoring program, which directly reduce digester feed and thus THP feed in order to avoid overload.
  • THP Thermal Hydrolysis Processes
  • the methods, systems, process equipment and plants employing Thermal Hydrolysis Processes (THP) of the present invention will adjust DS% in THP based on apparent viscosity, e.g. static yield stress and/or dynamic yield stress, a constant volumetric feed flow for the digester will not provide a constant VS loading of the digester.
  • the system needs to self-adjust in case of any indication of digester overloading.
  • the energy feed rate for the digester can be controlled by monitoring rheology.
  • THP Thermal Hydrolysis Processes
  • the methods, systems, process equipment and plants employing Thermal Hydrolysis Processes (THP) of the present invention solves the problem that feeding digesters based only on a measure of dry solids or volatile solids, fails to take into account that different substrates have different specific energy content pr unit of dry solids and pr unit of volatile solids.
  • the methods, systems, process equipment and plants employing Thermal Hydrolysis Processes (THP) of the present invention make use of a biomass materials rheological behaviour to predict its specific energy content.
  • THP Thermal Hydrolysis Processes
  • the discovery of this relationship inter alia paves the way for the optional addition of chemical agents into the biomass material in the pre-conditioner in order to a) reduce apparent viscosity, e.g. static yield stress and/or dynamic yield stress, and/or b) start an exotherm reaction that increases feed temperature and thus reduces apparent viscosity, e.g. static yield stress and/or dynamic yield stress, and decrease specific heat consumption in the thermal hydrolysis step.
  • the discovery of this relationship paves the way for the optional addition of chemical agents known to directly or indirectly influencing other properties of the biomass material, e.g. chemical or biochemical composition, microbial composition or content, cellular structure, particle size distribution or particle shape distribution, known to directly or indirectly influence the apparent viscosity, e.g. static yield stress and/or dynamic yield stress, of the biomass material .
  • THP Thermal Hydrolysis Processes
  • Digester loading is normally controlled by sampling of DS% and VS% and controlling the feed flow to the digester manually.
  • the methods, systems, process equipment and plants employing Thermal Hydrolysis Processes (THP) of the present invention rather use apparent viscosity, e.g. static yield stress and/or dynamic yield stress, measured continuously at several points throughout the process, which are subsequently converted into calculated digester loading rates and introduce both a self-improving cross-calibration system to reduce error margin and a self-controlling system to avoid overloading of the digester and optimize the AD process.
  • THP Thermal Hydrolysis Processes
  • the methods, systems, process equipment and plants employing Thermal Hydrolysis Processes (THP) of the present invention enable control of the COD/VS loading rate (rather than simply the DS% and/or VS% loading rate) due to the relationship that has been determined between apparent viscosity, e.g. static yield stress and/or dynamic yield stress, and energy content measured as COD/VS.
  • the integrated self-controlling system includes monitoring of parameters such as pH, Gas production, methane content and/or the FOS/TAC ratio of the digester. When reaching certain levels and/or rates in the raisin of pH, FOS/TAC and or CH4 concentration the thermal hydrolysis loading rate would then automatically adjust the loading rate down to an acceptable level.
  • the automatic self-controlling systems of the methods, systems, process equipment and plants employing Thermal Hydrolysis Processes (THP) of the present invention facilitates demand-based digester operation through maximizing biogas production during periods with high value of the biogas, e.g. demonstrated by waste water utilities in the UK to capitalize on fluctuating electricity prices in UK.
  • the methods, systems, process equipment and plants employing Thermal Hydrolysis Processes (THP) of the present invention enables maximized and controlled loading of both the thermal hydrolysis step and a downstream digestion process through monitoring the limiting factor for the thermal hydrolysis step, which is apparent viscosity, e.g. static yield stress and or dynamic yield stress, in the THP.
  • the apparent viscosity, e.g. static yield stress and/or dynamic yield stress, levels monitored may be converted into values for the DS and VS loading rate of the digester.
  • the rheology measurement may be used to activate dilution prior to the pre-cooler in order to optimize heat transfer and thus total max capacity of the pre-cooler.
  • a proportion of the digested and dewatered cake may be recycled back to pulper feed.
  • Digested cake can be of high apparent viscosity, e.g. static yield stress and/or dynamic yield stress, similar to waste activated sludge.
  • Digested cake also behaves as a nonNewtonian fluid. Due to the thermal hydrolysis process, the cake is well dewatered and the apparent viscosity, e.g.
  • THP Thermal Hydrolysis Processes
  • this particular embodiment of the invention would increase biogas production in the magnitude of 20% and reduced cake production in the magnitude of 15%.
  • the overall THP system would however consume more heat due to the return flow of digested cake.
  • the net energy surplus could, however, be approximately 8%.
  • this particular embodiment of the invention would increase biogas production in the magnitude of 10-15% and reduced cake production in the magnitude of 10%. In case biogas is consumed to produce the increased heat consumption, the net biogas surplus could in some cases be approximately 5-6%.
  • compressed process gases may be used to 1) reduce pressure drop in the pulper feed line and/or 2) improve digester performance, e.g. if the compressed process gasses are deaerated in the pulper, and injected into the digester using a compressor.
  • the process gases will be odorous and contain harmful substances that can be toxic even in small concentrations. It is thus important to handle the process gases with care in a closed system. The processes gases should not in any case be emitted directly.
  • the methods, systems, process equipment and plants employing Thermal Hydrolysis Processes (THP) of the present invention include a closed system that inject the process gases into the digester for 1) adsorption into the liquid face and 2) biological treatment. Some of the organic compounds precent in the process gases as well as oxygen possibly released through deaeration will further enhance the digester performance. The addition of oxygen into the pulper or pulper feed line enable optimization of the digestion process.
  • the volume below the outlet nozzle for the pump(s) should be >1.6 average reactor fill volume.
  • the volume above the nozzle should preferably be >1 average reactor filling volume plus some safety margin above the nozzle but may be larger, such as 1.2, 1.4, 1.6 or 1.8 average reactor filling volume.
  • Pre-heating of substrate prior to thermal hydrolysis processes is beneficial in order to reduce the specific energy consumption.
  • Thermally hydrolysed sludge will leave the hydrolysis process at a high temperature unless it is diluted with cold water.
  • Preheating of the biomass provides an opportunity for cost efficient recovery of surplus heat available in the hydrolysed sludge that will otherwise be left unused at high cost.
  • the methods, systems, process equipment and plants employing Thermal Hydrolysis Processes (THP) of the present invention can use incoming cold substrate as a source of cooling of already hydrolysed substrate and at the same time recover more heat, and reduce specific heat consumption in the thermal hydrolysis process.
  • THP Thermal Hydrolysis Processes
  • static yield stress and/or dynamic yield stress measuring instruments, which are prone to give rise to difficulties when applied to inhomogeneous substrates with high content of fibers, sand, grit, hair, twigs, etc.
  • apparent viscosity e.g. static yield stress and/or dynamic yield stress
  • THP Thermal Hydrolysis Processes
  • a continuous monitoring of the digester performance enables full control over the dry solid loading throughout the process and enables safe operation of both the THP and any downstream anaerobic digestion process without unnecessary safety margins.
  • the present invention describes a novel design to enable continuous monitoring of apparent viscosity, e.g. static yield stress and/or dynamic yield stress, in a thermal hydrolysis process and the use of the data obtained to continuously optimize the operation.
  • THP Thermal Hydrolysis Processes
  • the pre-heating will, in methods, systems, process equipment and plants employing Thermal Hydrolysis Processes (THP) of the present invention, take place in an upstream pre-conditioning device. Sludge and similar substrates that have a typical non-Newtonian behaviour, will reduce its apparent viscosity, e.g. static yield stress and/or dynamic yield stress, when exposed to shear forces.
  • a specific feature of the design of the methods, systems, process equipment and plants employing Thermal Hydrolysis Processes (THP) of the present invention is that the pre-conditioning device introduces shear forces to the substrates and through that reduces the apparent viscosity, e.g. static yield stress and/or dynamic yield stress. As a result of the reduced apparent viscosity, e.g.
  • the pumping to the next processing step in the thermal hydrolysis system can be done at a lower resistance in the pipeline.
  • the reduced apparent viscosity e.g. static yield stress and/or dynamic yield stress
  • the specific pressure drop will decrease and thus the power consumption required for pumping decrease accordingly.
  • the reduced apparent viscosity, e.g. static yield stress and/or dynamic yield stress due to the shear forces applied to the substrate, in methods, systems, process equipment and plants employing Thermal Hydrolysis Processes (THP) of the present invention, will decrease over time and the apparent viscosity, e.g. static yield stress and/or dynamic yield stress, of the biomass material will revert back to the same apparent viscosity, e.g.
  • the retention time in the transfer pipe should, in methods, systems, process equipment and plants employing Thermal Hydrolysis Processes (THP) of the present invention, be kept as low as possible by minimizing the length of the transfer Pipe.
  • THP Thermal Hydrolysis Processes
  • THP Thermal Hydrolysis Processes
  • Pre-cooling can, in methods, systems, process equipment and plants employing Thermal Hydrolysis Processes (THP) of the present invention, be done in several ways.
  • the most common way of pre-cooling is to use tube-in-tube heat exchangers.
  • Another and more advanced way of pre-cooling would be to apply a flash-cooler using vacuum to reach preferred temperature.
  • An advantage with flash coolers is that they eliminate the challenges with heat transfer coefficient dependency on apparent viscosity, e.g. static yield stress and/or dynamic yield stress. For substrates showing high apparent viscosity, e.g. static yield stress and/or dynamic yield stress, heat transfer is low. When operating at the maximum apparent viscosity, e.g.
  • coolers so that the required heat surface area is not dependent on sludge apparent viscosity, e.g. static yield stress and/or dynamic yield stress.
  • sludge apparent viscosity e.g. static yield stress and/or dynamic yield stress.
  • the heat transfer will take place by condensation of steam on heat surfaces rather than by sludge being in contact with heat surfaces, which is the case in standard heat exchanges used in the industry such as e.g. tube in tube or spiral type heat exchangers.
  • excess heat can be used for preheating dilution water for the pre-conditioner.
  • a low level e.g. 40 or 50°C
  • high temperature excess heat will not be available unless lifting the heat assisted by other technologies. However, this low temperature excess heat may still be utilized for preheating.
  • Recovered heat using any cooler design can be recovered upstream the thermal hydrolysis system either by adding hot water in the pulper, or upstream the pulper by mixing it with a substrate at high dry solids above 8% DS, preferably at least 12% DS, preferably above 18% DS or even more preferably above 20% DS.
  • Recovered heat may also be used for preheating polymer/water in upstream pre-dewatering or thickening processes and, thus, both assist in improving dewatering properties that can be achieved at elevated temperature and assist in improving the overall heat balance across the thermal hydrolysis process due to increased feed temperature to the thermal hydrolysis system.
  • THP Thermal Hydrolysis Processes
  • An important task for the pre-conditioning device, of the methods, systems, process equipment and plants employing Thermal Hydrolysis Processes (THP) of the present invention is to produce a well-mixed and homogenous substrate for A) pumping to downstream THP at lowest possible pressure drop (and energy consumption) and B) reduce the apparent viscosity, e.g. static yield stress and/or dynamic yield stress, in sludge prior to entering the THP pulper, thereby reducing the need for mixing in the pulper and enabling operation at higher dry solids by the use of minimum possible power consumption.
  • THP Thermal Hydrolysis Processes
  • pre-heated water will be added to the preconditioner device with the objective of producing a well mixed substrate.
  • the preconditioner device, of the methods, systems, process equipment and plants employing Thermal Hydrolysis Processes (THP) of the present invention could either be an integrated part of the THP feed pump or an upstream mixer.
  • the mixing is done in a screw conveyer having a larger, preferably at least 1.5 times larger, conveying capacity than the subsequent THP feed pump. The substrate will thus be leaking back in a loop, whereby the substrate will be mixed.
  • the pump capacity should be in the range of 50-90% of the conveyer capacity in order to provide a sufficiently high relation between the conveyer capacity and the pump capacity.
  • the average hydraulic retention time in the mixer should be at least in the range of 1-15 minutes to secure a well-mixed substrate. The correct/sufficient hydraulic retention time in the mixer will depend on the apparent viscosity, e.g. static yield stress and/or dynamic yield stress, of the substrate, the temperature, and the dilution rate of the mixer.
  • the retention time in the mixer should typically be 1-15 minutes.
  • THP Thermal Hydrolysis Processes
  • THP Thermal Hydrolysis Processes
  • THP Thermal Hydrolysis Processes
  • the addition of chemicals could be beneficial for pre-conditioning in relation to any downstream anaerobic digestion (as well as other fermentation processes).
  • the pre-conditioning device needs to be designed to tolerate the chemicals used for preconditioning as well as the temperatures it may be exposed to.
  • chemicals that reduce apparent viscosity e.g. static yield stress and/or dynamic yield stress, and chemicals that increase temperature may be added.
  • Such chemicals could also be beneficial for any downstream anaerobic digestion process.
  • An example is the addition of an alkali to achieve a thermal alkaline hydrolysis.
  • the exotherm reaction resulting from the addition of lime or caustic (or any other chemical causing and exotherm reaction) would be followed by a temperature increase.
  • a temperature increase would benefit the downstream thermal hydrolysis with regards to lowering the steam consumption.
  • the increased temperature would reduce the apparent viscosity, e.g. static yield stress and/or dynamic yield stress, of the substrate.
  • Any chemical causing an exotherm reaction needs to be followed and monitored thoroughly in order to avoid undesired events such as overheating as well as direct exposure of chemicals on the elastomers used in the stator.
  • temperature and apparent viscosity e.g. static yield stress and/or dynamic yield stress, should be monitored.
  • enzymes reducing apparent viscosity may be added in order to further enlarge the operational window for thermal hydrolysis on a specific substrate.
  • the relevant type of enzymes will depend on the specific substrate, and the pre-heating and pre-conditioning device should be designed to ensure sufficient mixing of the added enzymes into the substrate.
  • lubrication would be located directly downstream the pump located downstream dewatering.
  • lubrication would be located at a distance of up 2-10 meters downstream the pump located downstream dewatering, and this distance would be used to measure the apparent viscosity, e.g.
  • THP Thermal Hydrolysis Processes
  • the pulper circulation is circulated via the pre-conditioner to increase the temperature in the mix that is returned to the pulper.
  • THP Thermal Hydrolysis Processes
  • Figure 3 illustrates the calculated pressure drop (head loss) in a pulper feed line as a function of the flow rate.
  • the calculation is based on sludge rheology data measured in the pulper feed line at two different plants.
  • the two different plants produce a sludge quality with similar rheology behaviour provided that the sludge is at the same temperature.
  • the measured head loss in one plant becomes much lower than what is the case at the other plant.
  • Data acquired from these two plants are basis for the calculation of head loss for a specific pipe geometry and dimension.
  • the calculation is made for a pulper feed pipe length of 45 meter and diameter DN250mm.
  • the pressure drop may in some cases be almost independent of the flowrate, for this type of sludge with a nonNewtonian behaviour, within the flow range of 0-18m 3 /h.
  • the main parameters for influencing pressure drop for a certain sludge quality is pipe diameter and rheology characteristics. Additionally, rheology characteristics is again significantly influenced by temperature.
  • the sludge with the lowest calculated head loss in figure 3 has been preheated to 80°C, while the sludge with the highest calculated head loss is cold sludge at 20°C.
  • Figure 4 is based on data for two different sludge qualities and pipe configurations at approx. 20-25°C. Both data sets are re-calculated for the same pipe configuration for a Herschel-Bulkley, a Bingham Plastic, a Bingham pseudoplastic or a Ostwald-de Waele non-Newtonian fluid and also confirms the importance of pipe size in order to achieve an acceptable head loss.
  • the pulper feed pump can be e.g. a 2 stage pump rather than a much more expensive 4 stage pump.
  • specially designed stators with mechanical anchoring should be used because of the elevated temperature and the presence of elevated levels of organic acids and other components that may harm the stator.
  • the mixing of hot substrate returned from the pulper is done in the mixing zone of the preconditioner. In case the recycled flow of hot substrate from the pulper is larger than the cold sludge feed flow, e.g.
  • the average temperature will be sufficiently high to allow for the extruder to be be removed.
  • This embodiment of the invention is particularly suitable for inhomogeneous substrates with fibers etc that may block extruders.
  • the recycled flow has a temperature of 90°C and this is mixed with cold substrate at 15°C in a proportion of 1:3, the average temperature of the mixture will be 71 ,2°C.
  • Figure 5 illustrates the average temperature of the mixture as a function of return flow temperature.
  • Figure 6 illustrates the average temperature of the mixture as function of return flow ratio.
  • Return flow ratio is the ratio between the return flow at high temperature (90 C) and the feed flow at low temperature (20 C).
  • THP plants The ability to operate THP plants at high dry solid concentration is essential in order to hydrolyse high viscous substrates at a minimum of heat consumption.
  • the higher energy cost are, the more important it is to be able to operate at high dry solids concentration.
  • THP Thermal Hydrolysis Processes
  • a solution aimed enable high dry solids operation of thermal hydrolysis processes known from the prior art is a dynamic mixer.
  • this solution only partly solves the problem and does not address the problems associated with heat recovery and operation of high viscous substrates at low temperature.
  • a dynamic mixer requires increased power consumption, which is not beneficial for the overall energy consumption and operational costs. It also introduces an additional and unnecessary piece of rotating equipment that requires maintenance and represents an additional source of failures and mal-function followed by down-time of a THP plant.
  • the methods, systems, process equipment and plants employing Thermal Hydrolysis Processes (THP) of the present invention in one embodiment describes such a solution in the form of a pre-heating tank (pulper) that utilizes the heat distribution throughout the pulper in such a way that fully preheated substrate is always pumped into the downstream THP reactors.
  • the methods, systems, process equipment and plants employing Thermal Hydrolysis Processes (THP) of the present invention also ensure a well-mixed tank (pulper), which avoids that lumps of substrate or collection of incompletely heated substrate is conveyed further into the THP train, i.e. the reactor(s) for thermal hydrolysis. This is absolutely essential for efficient operation, since such an incompletely mixed and pre-conditioned substrate would, in case of high apparent viscosity, not be fully heated and hydrolysed in the downstream reactors.
  • THP Thermal Hydrolysis Processes
  • control points to verify a well functioning process are e.g.
  • THP Thermal Hydrolysis Processes
  • the apparent viscosity e.g. static yield stress and/or dynamic yield stress
  • measured and the data from the control points may also be utilized to control the operation of upstream dewatering process.
  • the apparent viscosity, e.g. static yield stress and/or dynamic yield stress, of the hydrolysed sludge may also be measured, and this may be used to control dilution of the digester feed based on the apparent viscosity, e.g. static yield stress and/or dynamic yield stress, of the hydrolysed biomass material and the process may be verified through digester monitoring.
  • apparent viscosity e.g. static yield stress and/or dynamic yield stress
  • THP Thermal Hydrolysis Processes
  • static yield stress and/or dynamic yield stress rather than dry solids concentration, it is important to realize that different substrates may have very differing viscosities.
  • the difference in apparent viscosity, e.g. static yield stress and/or dynamic yield stress, of two substrates at the same dry solids content (DS%) and temperature could be as much as 1 :500 and in some cases even more.
  • THP Thermal Hydrolysis Processes
  • the methods, systems, process equipment and plants employing Thermal Hydrolysis Processes (THP) of the present invention can through reduced energy consumption improve the carbon footprint during operation.
  • the prior art processes have for almost all substrates, as a precaution, and in order to always be 100% certain that the thermal hydrolysis process will work well with full heat recovery rate, been run at dry solids content of average 16,5% and maximum 18,0% by default.
  • the methods, systems, process equipment and plants employing Thermal Hydrolysis Processes (THP) of the present invention enables a differentiation of dry solids content based on the discovery that the actual limiting factor for a THP process, apparent viscosity, e.g. static yield stress and/or dynamic yield stress, is continuously monitored and optimized through:
  • THP Thermal Hydrolysis Processes
  • the total pulper volume vs the average reactor filling volume is in the range of 2.1 and 3.0.
  • the pulper outlet nozzle connected to the reactor feed pump is at an elevated level in order to ensure that preheated substrate will be extracted from the pulper and avoid that insufficient heated sludge and cold sludge is extracted from the bottom of the vessel.
  • the volume below the outlet nozzle for the pump(s) is >1.6 times the average reactor filling volume.
  • the volume above the nozzle is >1 times the average reactor filling volume.
  • the head space volume at maximum fill rate should be at least 10%, preferably >20% of the total volume or more favourable 20-30% of total volume. This will allow for splashing and foaming incidents without causing operational problems.
  • the plant may operate typically at 70-80% fill rate as a target, while the actual volume will vary depending on the average reactor feed rate.
  • the dimension of the pulper outlet nozzle in the particular beneficial pulper design of the present invention, is preferably be > DN200 to handle high viscous substrates, and the length of the suction pipe between the nozzle and the pump does preferably not exceed 4m.
  • the length of the pipe should be reduced to ensure low pressure loss through the pipe.
  • the sludge entering a pulper vessel is colder than the sludge inside the pulper.
  • the cold feed sludge has a higher apparent viscosity, e.g. static yield stress and/or dynamic yield stress, than the warmer sludge inside the pulper.
  • the cold feed sludge is added into the hot sludge via a sludge distributer in the upper part of the pulper in order to distribute the cold sludge entering the vessel into the pre-heated sludge.
  • the distribution device should be located in the headspace preferably above liquid level.
  • the sludge distributer will be in the form of an extruder consisting of a pipe with many holes where the sludge is distributed and sliced into smaller parts and thus create a larger surface area.
  • the total area of the holes in the extruder should be >2,5 times the cross section of the feed pipe(s) to the extruder to avoid undesirable pressure loss across the extruder.
  • the dimension of the holes in the extruder should be between 10mm and 50mm, preferably between 18 and 35mm, most preferably 20-30mm. The smaller the holes, the better distribution, however, substrate includes fiber, textiles, plastic, hair and other particles that tend to block an extruder with too small holes. For most substrates an extruder with 25mm holes will suffice.
  • the extruder may also have oval holes, slits or any other shapes that ensures an efficient distribution of substrate in the top section of the pulper.
  • Other distribution systems may also be used, such as screw, spreader stoker, dices or any other system that distribute the incoming sludge into smaller particles that provides an extended heat surface to transfer heat from the preheated sludge inside the pulper.
  • Sludge entry into the tank should not be located straight above the outlet nozzle. Short horizontal distance between inlet nozzle and outlet nozzle will cause short-circuiting.
  • the inlet of sludge, preferably through and extruder, should be located at the opposite side of the pulper.
  • the inlet extruder should be located horizontally and diagonally 90° away from the outlet nozzle, and not closer to the outlet nozzle than diagonally in centre of the vessel, preferably off set center away from the outlet nozzle.
  • the particular beneficial pulper design according to the present invention may also be horizontal, and in also in such cases, the extruder should be located in a far distance away from the outlet nozzle. This can be achieved by different orientations and location of the extruder.
  • parts of the extruder is blocked in order to 1) increase distance to the outlet nozzle of the pulper, and 2) avoid splashing into other nozzles located in the headspace of the pulper.
  • This recirculation may also include a partial or full flow back to the pre-conditioner in order to improve premixing as well as reduce pressure drop in pulper feedline.
  • this recirculation loop is capable of recycling an amount of preheated biomass material from the pulper equivalent to at least 0.5 times the amount of cold biomass material feed, preferrable more than 1 times the cold biomass material feed, and even more preferably more than 2 times the cold biomass material feed.
  • the apparent viscosity is measured in the reactor feed line.
  • the reactor feed line includes a pump function capable of producing a controlled flowrate, a pipe section with a known geometry restricting the flow.
  • the apparent viscosity e.g. static yield stress and/or dynamic yield stress, is then measured in terms of pressure drop at a known flowrate through the known pipe geometry.
  • Pump function in a particular beneficial pulper design according to the present invention can be fulfilled in several different ways, e.g. progressive cavity pump, centrifugal pump, piston pump, barometric egg, or any other way of controlling the flowrate.
  • a flowmeter can be used to verify flowrate, or control flow through the system.
  • a pressure sensor can be used to measure pressure drop.
  • Another embodiment of the invention would be to establish an overflow vessel, or compartment of a vessel that is essentially always filled.
  • heated sludge would flow to the next vessel or compartment that is used as a chamber for pumping the material into the downstream reactors.
  • This embodiment of the invention would in the same way as the previously described embodiment of the invention utilize the temperature stratification that takes place in the pulper, and always skim off the warmest sludge.
  • the pumping of heated substrate from the pulper to the reactor vessels may take place by conventional pumps e.g. progressive cavity pumps, centrifugal pumps or any other pump type.
  • the pumping could also take place by pressurizing the pulper vessel compartments in order to push the substrate to downstream reactors.
  • a particular preferred embodiment of a particular beneficial pulper design includes an alternative design of the extruder, in which the extruder is located outside the pulper vessel.
  • the extruder can thus be isolated and cleaned on regular basis without interfering with the pre-heating vessel (pulper) itself.
  • the extruder may be by-passed, or the system is equipped with duty standby extruders to ensure that one extruder will always be in operation.
  • the extruder design may also include a self-cleaning function.
  • the methods, systems, process equipment and plants employing Thermal Hydrolysis Processes (THP) of the present invention are able to utilize any type of extruder or filter that cuts the cold substrate into smaller pieces, where the smaller pieces with a larger specific surface area is blended into the warmer substrate.
  • the extruder or filter applied should provide preferably >10x larger specific surface area of the cold substrate by distributing the supplied cold substrate into smaller parts.
  • the extruded or filtered substrate with a larger specific surface area is mixed into a larger amount of preheated substrate that is circulated from the preheating tank (pulper).
  • the amount of circulated pre-heated substrate should be at least >3x the amount of cold substrate feed to the system.
  • the extruder may also be implemented in form of a screw press to enable continuous removal of grit, fiber, plastic, textiles etc.
  • the extruder could also be prepared for injection and more efficient mixing of chemicals as the sludge, once preheated, has a significant lower apparent viscosity than when not preheated.
  • THP Thermal Hydrolysis Processes
  • Apparent viscosity e.g. static yield stress and/or dynamic yield stress
  • measurement in the pulper feed line can be achieved by installing Pressure transmitters right after the pulper feed pump and after some meters of pipe, preferably prior to the pulper inlet. Pressure drop is measured on the pipe section and dilution and preheating is based on the measured pressure drop.
  • Apparent viscosity, e.g. static yield stress and/or dynamic yield stress, measurement in the pulper feed line can also be achieved by installing temperature transmitter on the pulper feed line to have a reference for determining the apparent viscosity, e.g. static yield stress and/or dynamic yield stress. Flowmeters are more difficult and inaccurate due to the low flowrate and the fact that small cross sections in flow transmitters is not preferred as it will cause additional pressure drop.
  • Apparent viscosity e.g. static yield stress and/or dynamic yield stress
  • measurement in the Pulper circulation line can be achieved by:
  • Apparent viscosity e.g. static yield stress and/or dynamic yield stress
  • measurement in the Reactor feed line can be achieved by:
  • Apparent viscosity e.g. static yield stress and/or dynamic yield stress
  • measurement in the Reactor feed line can be achieved by using the torque or power consumption available on the pump frequency converter.
  • Apparent viscosity e.g. static yield stress and/or dynamic yield stress
  • measurement in the Digester feed line can be achieved by:
  • Figure 8 shows embodiments of the present invention including a particular beneficial pulper design according to the present invention.
  • Figure 9 shows a preferred sludge extruder in a particular beneficial pulper design according to the present invention.
  • FIG 10A shows data from a case study in relation to performance data of a pulper modification upgrade, involving the upgrade from a prior art design to a particular beneficial pulper design according to the present invention.
  • the ability of the pulper according to the present invention to keep the temperature of the material discharged from the pulper within certain limits is dramatically improved compared to that of the prior art.
  • a pulper according to the present invention (16 hour trends) makes it possible to keep the temperature of the material discharged from the pulper within a temperature span of app. 20 C (i.e. varying from app. 65 C to app. 85 C), whereas the temperature span enabled by the pulper of the prior art (8 hour trends) is almost twice as large, i.e. 40 C (vis. From app. 45 C to app. 85 C).
  • Figure 10B shows the standard deviation of reactor feed temperature for individual reactor fillings in a method according to the present invention, employing a pulper according to the present invention calculated based on temperature measurement every 5 seconds.
  • pre-heated biomass material produced in a pulper from a non-Newtonian biomass material and to be subsequently fed to any downstream thermal hydrolysis reactor of a THP system, and/or subsequently from the THP system to any subsequent processing steps is of a uniform temperature, i.e. such that the average standard variation in temperature is ⁇ 12°C, when this standard variation in temperature is calculated based on a temperature measurement resolution of ⁇ 5 seconds, and used to calculate an overall average for each individual reactor filling.
  • Figure 11 shows data from a case study in relation to performance data of a pulper modification upgrade, involving the upgrade from a prior art design to a particular beneficial pulper design according to the present invention (i.e. with and without upgrade kit).
  • the ability of the pulper according to the present invention to provide reactor feed flows of above 30 m 3 /h at even very high dry matter content is dramatically improved compared to that of the prior art.
  • a pulper according to the present invention makes it possible to work reactor feed flows of above 30 m 3 /h when working with material having a DS well-above 14%, which is not possible with a pulper of the prior art.
  • Figure 12 is based on data from operation at selected dry solids content from 16% to 18%DS, during development and testing of the particularly beneficial pulper design according to the present invention described in example 4, and shows the relationship between fo and WAS%. As can be seen it was shown that WAS% up to 100% can been achieved at dry solids content up to 18%.
  • the dry solids content can be increased from 16-18%DS and up to 20-22%DS, and in some cases further increased up to 25%DS or more for some substrates or mixes of substrates. Such an increase would cause a reduced specific steam consumption of 20% and 38% respectively.
  • An additional benefit is that the hydraulic capacity can be maintained at high dry solids operation. As a consequence, the dry solids capacity can also be increased with 20% and 38% respectively.
  • THP Thermal Hydrolysis Processes
  • the calculated function of T 0 as f(COD/VS), which is visualised in Figure 14, is based on energy content in Primary sludge of 1,7 and in Waste Activated sludge of 1,45. Variations in energy content can be expected depending on sludge origin, sludge age, etc, and a calibration is recommended for each sludge mix.
  • the validity of the identified relationship that can be used to determine energy content in sludge and thus be used to control energy feed rate to digesters is predominantly for T 0 >500 - 1000 Pa and COD/VS >1 ,52 depending on type of substrate.
  • One way of controlling the validity of a calibrated system and to determine the need for closer monitoring and possible recalibration is, in addition to regular sampling for analysis of COD/VS, to also analyse for organic Nitrogen content.
  • Different sludge and substrates have different organic nitrogen content.
  • primary sludge has an organic nitrogen content of around 2,5% of the VS content
  • Waste activated sludge typically has an organic nitrogen content of around 6,0%.
  • An indirect way of controlling the energy content is thus to analyse for the organic nitrogen content of the sludge.
  • the relationship between T 0 and organic nitrogen content in sludge can be calculated as shown in Figure 16. Also this relationship will vary, depending on the waste water treatment process, waste water quality, how the process is operated, sludge age, etc.
  • THP Thermal Hydrolysis Processes
  • THP Thermal Hydrolysis Processes
  • the methods, systems, process equipment and plants employing Thermal Hydrolysis Processes (THP) of the present invention enable an automatic increase in DS% through a reduced dilution rate or an increased DS% from pre-dewatering.
  • a way to further improve digester loading rate is by predicting both DS%, VS% and COD/VS (energy density) as well as organic Nitrogen content based on measurements of the rheological behaviour of the biomass material throughout the THP process.
  • digester control can be further improved by monitoring key performance indicators in the anaerobic digestion process.
  • KPI Key Performance Indicators
  • DS% and VS% should be sampled and analysed continuously in order to calibrate the relation between apparent viscosity, e.g. static yield stress and/or dynamic yield stress, and DS% and between apparent viscosity, e.g. static yield stress and/or dynamic yield stress, and VS%. This should be done both in the digester feed line and in the pulper circulation/reactor feed line.

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  • Biochemistry (AREA)
  • General Engineering & Computer Science (AREA)
  • General Health & Medical Sciences (AREA)
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Abstract

Procédés, systèmes, équipements de traitement et installations utiles pour soumettre la matière de biomasse à des procédés d'hydrolyse thermique (THP) et à un traitement ultérieur sous la forme, par exemple, d'une fermentation anaérobie, d'une réduction thermique, d'un traitement biologique, chimique ou électrochimique, ou similaire. La présente invention concerne également des procédés de modernisation de plantes existantes utilisant des procédés d'hydrolyse thermique (THP).
PCT/EP2023/083025 2022-11-24 2023-11-24 Procédés, systèmes et équipement de traitement pour la commande optimisée de processus d'hydrolyse thermique WO2024110643A1 (fr)

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