WO2024079263A1 - Stratégie de chauffage interne pour empêcher des ponts de glace pour une soufflante de recirculation de h2 dans un système de pile à combustible - Google Patents

Stratégie de chauffage interne pour empêcher des ponts de glace pour une soufflante de recirculation de h2 dans un système de pile à combustible Download PDF

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Publication number
WO2024079263A1
WO2024079263A1 PCT/EP2023/078343 EP2023078343W WO2024079263A1 WO 2024079263 A1 WO2024079263 A1 WO 2024079263A1 EP 2023078343 W EP2023078343 W EP 2023078343W WO 2024079263 A1 WO2024079263 A1 WO 2024079263A1
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WO
WIPO (PCT)
Prior art keywords
water
fuel cell
recirculation fan
heat
heating device
Prior art date
Application number
PCT/EP2023/078343
Other languages
German (de)
English (en)
Inventor
Matthias Deinert
Original Assignee
Robert Bosch Gmbh
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Robert Bosch Gmbh filed Critical Robert Bosch Gmbh
Publication of WO2024079263A1 publication Critical patent/WO2024079263A1/fr

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Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/04Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04082Arrangements for control of reactant parameters, e.g. pressure or concentration
    • H01M8/04089Arrangements for control of reactant parameters, e.g. pressure or concentration of gaseous reactants
    • H01M8/04097Arrangements for control of reactant parameters, e.g. pressure or concentration of gaseous reactants with recycling of the reactants
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/04Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04223Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids during start-up or shut-down; Depolarisation or activation, e.g. purging; Means for short-circuiting defective fuel cells
    • H01M8/04228Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids during start-up or shut-down; Depolarisation or activation, e.g. purging; Means for short-circuiting defective fuel cells during shut-down
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/04Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04223Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids during start-up or shut-down; Depolarisation or activation, e.g. purging; Means for short-circuiting defective fuel cells
    • H01M8/04253Means for solving freezing problems
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/04Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04291Arrangements for managing water in solid electrolyte fuel cell systems
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/04Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04298Processes for controlling fuel cells or fuel cell systems
    • H01M8/043Processes for controlling fuel cells or fuel cell systems applied during specific periods
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/04Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04298Processes for controlling fuel cells or fuel cell systems
    • H01M8/04313Processes for controlling fuel cells or fuel cell systems characterised by the detection or assessment of variables; characterised by the detection or assessment of failure or abnormal function
    • H01M8/0432Temperature; Ambient temperature
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/04Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04298Processes for controlling fuel cells or fuel cell systems
    • H01M8/04313Processes for controlling fuel cells or fuel cell systems characterised by the detection or assessment of variables; characterised by the detection or assessment of failure or abnormal function
    • H01M8/04492Humidity; Ambient humidity; Water content
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2250/00Fuel cells for particular applications; Specific features of fuel cell system
    • H01M2250/20Fuel cells in motive systems, e.g. vehicle, ship, plane

Definitions

  • Recirculation blowers are also referred to as anode recirculation blowers or ARB for short.
  • Recirculation fans are components of an anode subsystem of the fuel cell, which usually has a water separator upstream of the recirculation fan to separate the process water of the fuel cell.
  • recirculation blowers can also have an integrated water separator.
  • the combination of two water separators is intended to further increase the proportion of separated process water in order to pump as little water as possible to the fuel inlet through the recirculation blower.
  • process water Even if a large proportion of the process water can be separated in this way, a small amount of process water can still remain within the anode subsystem, for example in pipes or within the recirculation fan.
  • the remaining process water can freeze when the vehicle is parked and temperatures are below 0 °C and may block moving components or small channels in the fuel cell. Especially with the recirculation fan there is a risk that the remaining process water will form ice bridges.
  • Ice bridges are ice connections between two components caused by icing. Ice bridges are particularly problematic in components that have to move relative to each other during operation. Ice bridges can therefore mean that the recirculation fan cannot be controlled or rotated when starting.
  • a common and well-known position where ice bridges often form is a gap between a magnet pot of the recirculation fan and a gap pot of the recirculation fan. The formation of ice bridges at this point prevents a recirculation fan impeller from turning loose. If the torque of the recirculation fan is not sufficient to break the ice bridges, the recirculation fan cannot operate in this state.
  • the heat can be provided, for example, by additional heating cartridges, which can be installed in an impeller housing of the recirculation fan.
  • the heat can be provided by deliberately generating eddy current losses in the recirculation fan. It is also known to control the recirculation fan in a targeted manner to break off the ice bridges, for example by oscillating. All such devices and methods aim to remove the ice that is already present as part of a start-up process for the fuel cell.
  • a method for operating a fuel cell with a recirculation fan comprises:
  • the method is carried out before an ambient temperature of the motor vehicle reaches or falls below freezing point.
  • the heating device provides heat for evaporating the water.
  • providing heat to the recirculation fan can include, for example, providing heat to an outside of the recirculation fan and/or inside the recirculation fan.
  • the heat is preferably provided in such a way that the heat is supplied to process water collection points where process water collects in order to evaporate this process water in a targeted manner.
  • the heat is preferably provided in such a way that the recirculation fan or at least parts of the recirculation fan, in particular which are in contact with process water, are heated to a temperature of at least 100 °C.
  • the water is evaporated at the recirculation fan.
  • the water is therefore supplied with heat in such a way that it evaporates.
  • the predefined evaporation criterion is met, the heat supply for evaporating the water is stopped.
  • the evaporation criterion determines when the heat supply should stop.
  • the evaporation criterion can, for example, specify which amount of water should be safely evaporated or how high the proportion of evaporated water should be in relation to the total remaining amount of water before evaporation.
  • the evaporation criterion can, for example, specify that at least 95% of the remaining water must have evaporated.
  • Compliance with the evaporation criterion can be checked, for example, using characteristic maps, empirical values or the like. After the heat supply has ceased, there is only so much water left in or on the recirculation fan that there is no longer a risk of channels or rotating parts on the recirculation fan becoming blocked by frozen water, or the risk is only such that any ice that has formed can be easily removed by operating the recirculation fan and without any delay in the operation of the recirculation fan.
  • a method according to the invention for operating a fuel cell with a recirculation fan has the advantage over conventional methods that the extent of icing on the recirculation fan can be significantly reduced using simple means and in a cost-effective manner. If the method according to the invention is carried out accordingly, the formation of ice in the area of the recirculation fan can be completely prevented. This means that the fuel cell can be put back into operation without delay when the motor vehicle is started. Complex de-icing processes are no longer necessary.
  • the evaporation of the water has the further advantage that the fuel gas, such as hydrogen, conveyed to the fuel inlet via the recirculation fan contains no or only a very small amount of water.
  • a method can be provided for the heat to be provided while the fuel cell is inactive.
  • the method is preferably carried out immediately after the fuel cell is switched off.
  • switching off the fuel cell means putting the fuel cell into an inactive state.
  • no hydrogen is supplied to the fuel cell for combustion, so that no electrical current is generated and no process water is produced.
  • no oxygen is supplied to the fuel cell in the inactive state.
  • an electric motor of the recirculation fan is operated as a heating device for providing the heat for evaporating the water by specifically controlling the electric motor.
  • the electric motor is preferably controlled in such a way that the iron losses are particularly high. This can be done, for example, via voltage vectors of equal magnitude with a phase shift of 180°, with the voltages being provided at a predetermined frequency, so that a constant change in the flow direction of the magnetic field of the electric motor is thereby caused.
  • the control is preferably carried out in such a way that no rotating field is generated for rotating the rotor.
  • the targeted control of the electric motor causes the stator and/or the rotor of the electric motor to heat up, preferably to a temperature of over 100°C, so that the remaining process water is thereby evaporated.
  • This has the advantage that the heat for evaporating the water is provided using simple means and in a cost-effective manner. Additional heating devices are not required, so that the costs and weight of the fuel cell can be reduced.
  • the heating device is preferably arranged directly on the recirculation fan in order to heat the recirculation fan in a targeted manner.
  • the heating device can have, for example, a heat exchanger and/or a resistance heating element and/or a burner device or the like.
  • the heating device is preferably designed in such a way that the heating device can be controlled independently of the control of the recirculation fan. This means that the rotor of the recirculation fan can continue to operate when the heating device is activated, for example.
  • the heating device that can be controlled separately from the recirculation fan and the recirculation fan are preferably used as the heating device to provide the heat for evaporating the water, so that the dimensioning of the separately controllable heating device can be particularly cost-effective, space-saving and lightweight to provide the required heating energy.
  • This has the advantage that it can be achieved with simple means and in a A particularly efficient evaporation of water is achieved in a cost-effective manner.
  • a method can be provided in which the recirculation fan is operated in fan mode to remove the evaporated water. As the water evaporates, at least part of the evaporated water is removed from the fuel cell. In order to prevent the water from condensing again on the recirculation fan after the heat supply has ended, from depositing on the recirculation fan and from forming ice bridges in the event of frost, the recirculation fan is operated to transport the water out of the recirculation fan. This has the advantage that a particularly large proportion of the water can be removed from the fuel cell using simple means and in a cost-effective manner, thus significantly reducing the risk of ice bridges forming.
  • a specific time period for providing the heat to evaporate the water is used as the evaporation criterion. If the heating output of the heating device is known, it is easy to determine from experience, simulations, algorithms, characteristic maps or the like which amount of water has evaporated after a defined period of time with a defined heating output. By estimating the amount of water present before the heat is provided to evaporate the water, the time period after which the amount of water has evaporated can be determined. A safety factor can be used here so that a higher amount of water is assumed when determining the time period, for example. This ensures that the recirculation fan is also dry after the heat has been provided for the defined period of time.
  • an outside temperature and/or a temperature of the recirculation fan is taken into account here.
  • excessive heat provision can be avoided, so that the process can be carried out in a particularly energy-efficient manner.
  • the specific time period is determined as a function of a determined amount of water on the recirculation fan and/or an evaporation capacity of the heating device.
  • the amount of water can be determined, for example, by sensors, empirical values, operating data of the fuel cell, simulations, algorithms, characteristic maps or the like.
  • the evaporation capacity of the heating device can be determined, for example, via empirical values, simulations, algorithms, characteristic maps or the like.
  • the specific time period is preferably determined by determining the amount of water and the evaporation capacity.
  • the heating device is particularly preferably controlled by a fan control device of the recirculation fan and/or a central control device of the fuel cell to provide the heat for evaporating the water.
  • a heating device designed to be separately controllable from the recirculation fan is controlled by the fan control device or the central control device.
  • the recirculation fan can also be controlled as a heating device by the fan control device or the central control device.
  • Parallel controls of the recirculation fan and/or the separately designed heating device by the fan control device and the central control device can also be provided within the scope of the method. This has the advantage that reliable control of the heating device to provide the heat is ensured using simple means and in a cost-effective manner.
  • an outside temperature is determined in the area of the fuel cell, whereby the provision of heat for Evaporation of the water occurs specifically when the outside temperature falls below a temperature threshold.
  • the temperature threshold can be between 3 °C and 5 °C, for example. If the outside temperature is higher than the temperature threshold, no heat is provided to evaporate the water.
  • a current outside temperature and/or a forecast outside temperature i.e. an outside temperature expected in the future, can be used.
  • the value of the outside temperature can be determined, for example, using a temperature sensor in the vehicle. This has the advantage that a temperature to which the fuel cell is actually exposed is determined in this way.
  • the value of the outside temperature can be obtained from a server and based, for example, on weather data from a weather station.
  • the outside temperature can also be determined from a temperature forecast based on weather data or empirical values.
  • a current outside temperature can, for example, be greater than 5 °C, while an outside temperature of below 0 °C is forecast for a few hours later.
  • the temperature forecast can, for example, also be made taking empirical values into account. If the temperature in winter is around 6 °C at 4:00 p.m., it can be assumed that the outside temperature can fall below 0 °C by midnight.
  • the heat is preferably provided at a time when the recirculation fan is expected to have a maximum temperature, so that the amount of heat to be provided to evaporate the water is at a minimum, since the residual heat of the recirculation fan can be used in this case.
  • a fuel cell for directly generating electrical energy from hydrogen.
  • the fuel cell comprises an anode, a cathode, an electrolyte membrane arranged between the anode and the cathode, an electrolyte, a Fuel inlet, an oxygen inlet, an exhaust outlet, a recirculation fan for returning unused fuel from the exhaust outlet, a water outlet for discharging water from the fuel cell and a central control device for controlling the fuel cell.
  • the fuel cell is designed to carry out a method according to the invention.
  • the recirculation fan of the fuel cell is preferably designed as a heating device for providing the heat for evaporating the water at the recirculation fan.
  • the fuel cell can have an additional heating device for providing the heat for evaporating the water.
  • the central control device is designed to control the fuel cell.
  • the central control device is preferably designed to control the recirculation fan.
  • the fuel cell can have an additional fan control device for controlling the recirculation fan.
  • the fuel cell preferably has one or more water separators for separating the process water during operation of the fuel cell. Outlets of the water separators are preferably coupled to the water outlet in a fluid-communicating manner. Water, such as process water, can be discharged from the fuel cell via the water outlet.
  • the fuel cell is designed to evaporate remaining water during an inactive state of the fuel cell by providing heat from the heating device, or at least to evaporate a predominant part of it, and to lead the water vapor thus generated, or at least a predominant part of the water vapor, out of the fuel cell.
  • the fuel cell according to the invention provides all the advantages that have already been described for a method for operating a fuel cell with a recirculation fan according to the first aspect of the invention. Accordingly, the fuel cell according to the invention has the advantage over conventional fuel cells that the extent of icing on the recirculation fan can be significantly reduced using simple means and in a cost-effective manner. With appropriate operation of the The fuel cell according to the invention can completely prevent the formation of ice in the area of the recirculation fan. This means that the fuel cell can be put back into operation without delay when the motor vehicle is started. Complex de-icing processes are no longer necessary.
  • the evaporation of the water has the further advantage that the fuel gas, such as hydrogen, conveyed to the fuel inlet via the recirculation fan contains no or only a very small amount of water.
  • Figure 1 shows a perspective view of an anode subsystem of a fuel cell for carrying out the method according to the invention
  • Figure 2 shows a sectional view of a recirculation fan of the anode subsystem from Figure 1,
  • Figure 3 shows a sectional view of a fuel cell according to a preferred embodiment of the invention.
  • Figure 4 shows a flow chart of a preferred embodiment of a method according to the invention.
  • an anode subsystem 14 of a fuel cell 1 (cf. Fig. 3) for carrying out the method according to the invention is shown schematically in a perspective view.
  • the anode subsystem 14 has a main water separator 15 and a recirculation fan 2 arranged thereon with an integrated secondary water separator 16.
  • Fig. 2 shows the recirculation fan 2 of the anode subsystem 14 from Fig. 1 schematically in a sectional view.
  • the recirculation fan 2 has an electric motor 4, which is designed as a heating device 3 for providing heat for evaporating water on or in the recirculation fan 2.
  • the electric motor 4 has a stator 17, which is arranged in a containment shell 18 of the electric motor 4.
  • the stator 17 and the containment shell 18 are together surrounded by a stator housing 19 of the electric motor 4, wherein the stator housing 19 is open on one end face of the containment shell 18.
  • An impeller 20 of the electric motor 4 is arranged on a hub 21 of the electric motor 4.
  • a magnet pot 22 of the electric motor 4 is arranged on the hub 21.
  • the magnet pot 22 has a plurality of permanent magnets, which are not shown in this figure.
  • the impeller 20, the hub 21 and the magnet pot 22 are arranged in an impeller housing 23 of the electric motor 4 that is open towards the stator 17.
  • the hub 21 is rotatably mounted on the impeller housing 23.
  • the magnet pot 22 is arranged adjacent to the containment pot 18 and faces directly towards it, so that a gap is formed between the magnet pot 22 and the containment pot 18, in which gap water W is arranged.
  • the water W can be evaporated, so that no ice bridges can form between the magnet pot 22 and the containment pot 18.
  • a fuel cell 1 according to a preferred embodiment of the invention is shown schematically in a sectional view.
  • the fuel cell 1 has an anode 7 and a cathode 8, which are arranged in an electrolyte E.
  • An electrolyte membrane 9 is arranged between the anode 7 and the cathode 8.
  • the fuel cell 1 has a fuel inlet 10 on the anode side for supplying hydrogen.
  • the fuel cell 1 has an exhaust gas outlet 12 on the anode side for removing anode gas.
  • the fuel cell 1 has an oxygen inlet 11 on the cathode side for supplying oxygen.
  • the fuel cell 1 has a water outlet 13 on the cathode side for removing water W.
  • the fuel cell 1 has a central control device 6 for controlling the fuel cell 1.
  • the fuel cell has an anode subsystem 14 with a recirculation fan 2 that can be operated as a heating device 3, an additional, optional heating device 3 and a fan control device 5 for controlling the recirculation fan 2.
  • the anode subsystem 14 is coupled in a fluid-communicating manner to the water outlet 13 for the removal of separated water W.
  • the anode subsystem 14 is coupled in a fluid-communicating manner to the fuel inlet 10 via a return line 24 for the return of unused hydrogen.
  • Fig. 4 shows the preferred embodiment of a method according to the invention schematically in a flow chart.
  • a first method step 100 an operating state of the fuel cell 1 is monitored, for example by the central control device 6 of the fuel cell 1. If the central control device 6 determines that the fuel cell 1 is inactive, for example in a parked motor vehicle, the outside temperature in the area of the fuel cell 1 is monitored in a second method step 200. In this case, for example, a current outside temperature or a predicted outside temperature can be monitored. The outside temperature can also be monitored while the fuel cell 1 is still active.
  • a heating device 3 of the fuel cell 1 is controlled by means of the fan control device 5 and/or the central control device 6 in such a way that heat is provided for evaporating water W at the recirculation fan 2. This can be done, for example, by specifically controlling the recirculation fan 2 to generate high iron losses and thus waste heat and/or controlling the optional additional heating device 3.
  • the provision of heat is terminated when the predefined evaporation criterion, such as a predetermined period of time, a predefined amount of heat or the like, is met.
  • the evaporation criterion is determined in such a way that after the execution of the Process no water W remains in the recirculation blower 2 or only so little water W remains in the recirculation blower 2 that the formation of ice bridges between moving parts of the recirculation blower 2 or the blockage of lines of the recirculation blower 2 by ice is avoided even when the recirculation blower 2 cools below 0 °C. In this way, rapid starting of the fuel cell 1 is ensured without the need for melting processes.

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  • Life Sciences & Earth Sciences (AREA)
  • Sustainable Development (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Sustainable Energy (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Fuel Cell (AREA)

Abstract

L'invention concerne un procédé de fonctionnement d'une pile à combustible (1) comprenant une soufflante de recirculation (2). En fonction d'un critère d'évaporation, un dispositif de chauffage (3) fournit de la chaleur de manière ciblée pour évaporer l'eau (W) sur la soufflante de recirculation (2). L'invention concerne en outre une pile à combustible (1) pour la production directe d'énergie électrique à partir d'hydrogène, qui est conçue pour mettre en œuvre un procédé selon l'invention.
PCT/EP2023/078343 2022-10-13 2023-10-12 Stratégie de chauffage interne pour empêcher des ponts de glace pour une soufflante de recirculation de h2 dans un système de pile à combustible WO2024079263A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102022210789.6A DE102022210789A1 (de) 2022-10-13 2022-10-13 Interne Heizstrategie zur Vermeidung von Eisbrücken für ein H2-Rezirkulationsgebläse in einem Brennstoffzellensystem
DE102022210789.6 2022-10-13

Publications (1)

Publication Number Publication Date
WO2024079263A1 true WO2024079263A1 (fr) 2024-04-18

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PCT/EP2023/078343 WO2024079263A1 (fr) 2022-10-13 2023-10-12 Stratégie de chauffage interne pour empêcher des ponts de glace pour une soufflante de recirculation de h2 dans un système de pile à combustible

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DE (1) DE102022210789A1 (fr)
WO (1) WO2024079263A1 (fr)

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2008041433A (ja) * 2006-08-07 2008-02-21 Toyota Motor Corp 燃料電池システムおよびこの制御方法
DE102008058959A1 (de) * 2008-11-25 2010-05-27 Daimler Ag Verfahren zum Betreiben eines Brennstoffzellensystems
DE102010035039A1 (de) * 2010-08-20 2012-02-23 Pierburg Gmbh Pumpe mit einem Elektromotor sowie Verfahren zum Einschalten einer derartigen Pumpe
CN111156181A (zh) * 2020-01-21 2020-05-15 中山大洋电机股份有限公司 一种氢气循环泵组件及其应用的燃料电池

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2008041433A (ja) * 2006-08-07 2008-02-21 Toyota Motor Corp 燃料電池システムおよびこの制御方法
DE102008058959A1 (de) * 2008-11-25 2010-05-27 Daimler Ag Verfahren zum Betreiben eines Brennstoffzellensystems
DE102010035039A1 (de) * 2010-08-20 2012-02-23 Pierburg Gmbh Pumpe mit einem Elektromotor sowie Verfahren zum Einschalten einer derartigen Pumpe
CN111156181A (zh) * 2020-01-21 2020-05-15 中山大洋电机股份有限公司 一种氢气循环泵组件及其应用的燃料电池

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