WO2024068158A1 - Dispositif de stockage d'énergie électrique pour un dispositif de stimulation médicale implantable - Google Patents
Dispositif de stockage d'énergie électrique pour un dispositif de stimulation médicale implantable Download PDFInfo
- Publication number
- WO2024068158A1 WO2024068158A1 PCT/EP2023/073565 EP2023073565W WO2024068158A1 WO 2024068158 A1 WO2024068158 A1 WO 2024068158A1 EP 2023073565 W EP2023073565 W EP 2023073565W WO 2024068158 A1 WO2024068158 A1 WO 2024068158A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- energy storage
- electrical energy
- electrical
- current collector
- electrode
- Prior art date
Links
- 238000004146 energy storage Methods 0.000 title claims abstract description 158
- 230000000638 stimulation Effects 0.000 title claims abstract description 33
- 239000000463 material Substances 0.000 claims description 11
- 239000004020 conductor Substances 0.000 claims description 6
- 239000007772 electrode material Substances 0.000 description 19
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 18
- -1 Ag2O2 Inorganic materials 0.000 description 11
- 229910052782 aluminium Inorganic materials 0.000 description 10
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 10
- 239000003792 electrolyte Substances 0.000 description 9
- 239000003990 capacitor Substances 0.000 description 8
- 238000005245 sintering Methods 0.000 description 8
- 229910052799 carbon Inorganic materials 0.000 description 7
- 239000002245 particle Substances 0.000 description 7
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 6
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 6
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 6
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 6
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 6
- 229910052783 alkali metal Inorganic materials 0.000 description 6
- 229910002804 graphite Inorganic materials 0.000 description 6
- 239000010439 graphite Substances 0.000 description 6
- 229910052744 lithium Inorganic materials 0.000 description 6
- NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Chemical compound O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 description 6
- 229910052708 sodium Inorganic materials 0.000 description 6
- 239000011734 sodium Substances 0.000 description 6
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 5
- 239000011888 foil Substances 0.000 description 5
- 238000000034 method Methods 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- 229910052700 potassium Inorganic materials 0.000 description 5
- 239000011591 potassium Substances 0.000 description 5
- 239000000843 powder Substances 0.000 description 5
- 229910052715 tantalum Inorganic materials 0.000 description 5
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 description 5
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- 150000001340 alkali metals Chemical class 0.000 description 4
- 230000000747 cardiac effect Effects 0.000 description 4
- 239000011248 coating agent Substances 0.000 description 4
- 238000000576 coating method Methods 0.000 description 4
- 238000003306 harvesting Methods 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 229910052758 niobium Inorganic materials 0.000 description 4
- 239000010955 niobium Substances 0.000 description 4
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 description 4
- FJKROLUGYXJWQN-UHFFFAOYSA-N 4-hydroxybenzoic acid Chemical compound OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 description 3
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 3
- 229920000106 Liquid crystal polymer Polymers 0.000 description 3
- 239000004977 Liquid-crystal polymers (LCPs) Substances 0.000 description 3
- SBZXBUIDTXKZTM-UHFFFAOYSA-N diglyme Chemical compound COCCOCCOC SBZXBUIDTXKZTM-UHFFFAOYSA-N 0.000 description 3
- 238000010292 electrical insulation Methods 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 210000005241 right ventricle Anatomy 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 230000035939 shock Effects 0.000 description 3
- 238000005476 soldering Methods 0.000 description 3
- XTHFKEDIFFGKHM-UHFFFAOYSA-N Dimethoxyethane Chemical compound COCCOC XTHFKEDIFFGKHM-UHFFFAOYSA-N 0.000 description 2
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 2
- FXHOOIRPVKKKFG-UHFFFAOYSA-N N,N-Dimethylacetamide Chemical compound CN(C)C(C)=O FXHOOIRPVKKKFG-UHFFFAOYSA-N 0.000 description 2
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 2
- 239000002033 PVDF binder Substances 0.000 description 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
- 229910001069 Ti alloy Inorganic materials 0.000 description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
- 239000004760 aramid Substances 0.000 description 2
- 229920003235 aromatic polyamide Polymers 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 2
- 239000000919 ceramic Substances 0.000 description 2
- 230000008878 coupling Effects 0.000 description 2
- 238000010168 coupling process Methods 0.000 description 2
- 238000005859 coupling reaction Methods 0.000 description 2
- 229940113088 dimethylacetamide Drugs 0.000 description 2
- 229920001971 elastomer Polymers 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 229910021389 graphene Inorganic materials 0.000 description 2
- IIPYXGDZVMZOAP-UHFFFAOYSA-N lithium nitrate Chemical compound [Li+].[O-][N+]([O-])=O IIPYXGDZVMZOAP-UHFFFAOYSA-N 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 2
- 239000004810 polytetrafluoroethylene Substances 0.000 description 2
- 229920002981 polyvinylidene fluoride Polymers 0.000 description 2
- 210000005245 right atrium Anatomy 0.000 description 2
- 239000005060 rubber Substances 0.000 description 2
- RAVDHKVWJUPFPT-UHFFFAOYSA-N silver;oxido(dioxo)vanadium Chemical compound [Ag+].[O-][V](=O)=O RAVDHKVWJUPFPT-UHFFFAOYSA-N 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000010935 stainless steel Substances 0.000 description 2
- 229910001220 stainless steel Inorganic materials 0.000 description 2
- 239000010936 titanium Substances 0.000 description 2
- 229910052719 titanium Inorganic materials 0.000 description 2
- ZZXUZKXVROWEIF-UHFFFAOYSA-N 1,2-butylene carbonate Chemical compound CCC1COC(=O)O1 ZZXUZKXVROWEIF-UHFFFAOYSA-N 0.000 description 1
- LZDKZFUFMNSQCJ-UHFFFAOYSA-N 1,2-diethoxyethane Chemical compound CCOCCOCC LZDKZFUFMNSQCJ-UHFFFAOYSA-N 0.000 description 1
- CAQYAZNFWDDMIT-UHFFFAOYSA-N 1-ethoxy-2-methoxyethane Chemical compound CCOCCOC CAQYAZNFWDDMIT-UHFFFAOYSA-N 0.000 description 1
- 229940090248 4-hydroxybenzoic acid Drugs 0.000 description 1
- KAUQJMHLAFIZDU-UHFFFAOYSA-N 6-Hydroxy-2-naphthoic acid Chemical compound C1=C(O)C=CC2=CC(C(=O)O)=CC=C21 KAUQJMHLAFIZDU-UHFFFAOYSA-N 0.000 description 1
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 1
- USFZMSVCRYTOJT-UHFFFAOYSA-N Ammonium acetate Chemical compound N.CC(O)=O USFZMSVCRYTOJT-UHFFFAOYSA-N 0.000 description 1
- 239000005695 Ammonium acetate Substances 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- OIFBSDVPJOWBCH-UHFFFAOYSA-N Diethyl carbonate Chemical compound CCOC(=O)OCC OIFBSDVPJOWBCH-UHFFFAOYSA-N 0.000 description 1
- YTPLMLYBLZKORZ-UHFFFAOYSA-N Divinylene sulfide Natural products C=1C=CSC=1 YTPLMLYBLZKORZ-UHFFFAOYSA-N 0.000 description 1
- KMTRUDSVKNLOMY-UHFFFAOYSA-N Ethylene carbonate Chemical compound O=C1OCCO1 KMTRUDSVKNLOMY-UHFFFAOYSA-N 0.000 description 1
- 229920000271 Kevlar® Polymers 0.000 description 1
- 229910015040 LiAsFe Inorganic materials 0.000 description 1
- 229910013188 LiBOB Inorganic materials 0.000 description 1
- 229910010941 LiFSI Inorganic materials 0.000 description 1
- 229910012223 LiPFe Inorganic materials 0.000 description 1
- 229910014332 N(SO2CF3)2 Inorganic materials 0.000 description 1
- 229920000459 Nitrile rubber Polymers 0.000 description 1
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 description 1
- 229910003092 TiS2 Inorganic materials 0.000 description 1
- 239000007983 Tris buffer Substances 0.000 description 1
- 239000004979 Vectran Substances 0.000 description 1
- 229920000508 Vectran Polymers 0.000 description 1
- YALCWJZSJOMTCG-UHFFFAOYSA-N [O--].[O--].[O--].[O--].[V+5].[Cu++].[Ag+] Chemical compound [O--].[O--].[O--].[O--].[V+5].[Cu++].[Ag+] YALCWJZSJOMTCG-UHFFFAOYSA-N 0.000 description 1
- JKLVRIRNLLAISP-UHFFFAOYSA-N [O-2].[V+5].[Cu+2] Chemical compound [O-2].[V+5].[Cu+2] JKLVRIRNLLAISP-UHFFFAOYSA-N 0.000 description 1
- 239000002250 absorbent Substances 0.000 description 1
- 230000002745 absorbent Effects 0.000 description 1
- KXKVLQRXCPHEJC-UHFFFAOYSA-N acetic acid trimethyl ester Natural products COC(C)=O KXKVLQRXCPHEJC-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- NDPGDHBNXZOBJS-UHFFFAOYSA-N aluminum lithium cobalt(2+) nickel(2+) oxygen(2-) Chemical compound [Li+].[O--].[O--].[O--].[O--].[Al+3].[Co++].[Ni++] NDPGDHBNXZOBJS-UHFFFAOYSA-N 0.000 description 1
- 229940043376 ammonium acetate Drugs 0.000 description 1
- 235000019257 ammonium acetate Nutrition 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 239000010405 anode material Substances 0.000 description 1
- 239000003125 aqueous solvent Substances 0.000 description 1
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 1
- 239000004327 boric acid Substances 0.000 description 1
- 229920005549 butyl rubber Polymers 0.000 description 1
- 239000002041 carbon nanotube Substances 0.000 description 1
- 229910021393 carbon nanotube Inorganic materials 0.000 description 1
- 229910010293 ceramic material Inorganic materials 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- 239000002482 conductive additive Substances 0.000 description 1
- 229920001940 conductive polymer Polymers 0.000 description 1
- 150000003950 cyclic amides Chemical class 0.000 description 1
- 150000005676 cyclic carbonates Chemical class 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- IEJIGPNLZYLLBP-UHFFFAOYSA-N dimethyl carbonate Chemical compound COC(=O)OC IEJIGPNLZYLLBP-UHFFFAOYSA-N 0.000 description 1
- VUPKGFBOKBGHFZ-UHFFFAOYSA-N dipropyl carbonate Chemical compound CCCOC(=O)OCCC VUPKGFBOKBGHFZ-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- JBTWLSYIZRCDFO-UHFFFAOYSA-N ethyl methyl carbonate Chemical compound CCOC(=O)OC JBTWLSYIZRCDFO-UHFFFAOYSA-N 0.000 description 1
- CYEDOLFRAIXARV-UHFFFAOYSA-N ethyl propyl carbonate Chemical compound CCCOC(=O)OCC CYEDOLFRAIXARV-UHFFFAOYSA-N 0.000 description 1
- 229910021385 hard carbon Inorganic materials 0.000 description 1
- 230000003116 impacting effect Effects 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 229910052740 iodine Inorganic materials 0.000 description 1
- 239000011630 iodine Substances 0.000 description 1
- 239000004761 kevlar Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229910003473 lithium bis(trifluoromethanesulfonyl)imide Inorganic materials 0.000 description 1
- 229910000625 lithium cobalt oxide Inorganic materials 0.000 description 1
- GELKBWJHTRAYNV-UHFFFAOYSA-K lithium iron phosphate Chemical compound [Li+].[Fe+2].[O-]P([O-])([O-])=O GELKBWJHTRAYNV-UHFFFAOYSA-K 0.000 description 1
- 229910002102 lithium manganese oxide Inorganic materials 0.000 description 1
- VDVLPSWVDYJFRW-UHFFFAOYSA-N lithium;bis(fluorosulfonyl)azanide Chemical compound [Li+].FS(=O)(=O)[N-]S(F)(=O)=O VDVLPSWVDYJFRW-UHFFFAOYSA-N 0.000 description 1
- QSZMZKBZAYQGRS-UHFFFAOYSA-N lithium;bis(trifluoromethylsulfonyl)azanide Chemical compound [Li+].FC(F)(F)S(=O)(=O)[N-]S(=O)(=O)C(F)(F)F QSZMZKBZAYQGRS-UHFFFAOYSA-N 0.000 description 1
- VGYDTVNNDKLMHX-UHFFFAOYSA-N lithium;manganese;nickel;oxocobalt Chemical compound [Li].[Mn].[Ni].[Co]=O VGYDTVNNDKLMHX-UHFFFAOYSA-N 0.000 description 1
- BFZPBUKRYWOWDV-UHFFFAOYSA-N lithium;oxido(oxo)cobalt Chemical compound [Li+].[O-][Co]=O BFZPBUKRYWOWDV-UHFFFAOYSA-N 0.000 description 1
- VLXXBCXTUVRROQ-UHFFFAOYSA-N lithium;oxido-oxo-(oxomanganiooxy)manganese Chemical compound [Li+].[O-][Mn](=O)O[Mn]=O VLXXBCXTUVRROQ-UHFFFAOYSA-N 0.000 description 1
- 229910052960 marcasite Inorganic materials 0.000 description 1
- KKQAVHGECIBFRQ-UHFFFAOYSA-N methyl propyl carbonate Chemical compound CCCOC(=O)OC KKQAVHGECIBFRQ-UHFFFAOYSA-N 0.000 description 1
- 229910003455 mixed metal oxide Inorganic materials 0.000 description 1
- 210000004165 myocardium Anatomy 0.000 description 1
- 229910021396 non-graphitizing carbon Inorganic materials 0.000 description 1
- 239000011255 nonaqueous electrolyte Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- 229920000128 polypyrrole Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- RUOJZAUFBMNUDX-UHFFFAOYSA-N propylene carbonate Chemical compound CC1COC(=O)O1 RUOJZAUFBMNUDX-UHFFFAOYSA-N 0.000 description 1
- NIFIFKQPDTWWGU-UHFFFAOYSA-N pyrite Chemical compound [Fe+2].[S-][S-] NIFIFKQPDTWWGU-UHFFFAOYSA-N 0.000 description 1
- 229910052683 pyrite Inorganic materials 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 229910000108 silver(I,III) oxide Inorganic materials 0.000 description 1
- 229910000679 solder Inorganic materials 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 229920003048 styrene butadiene rubber Polymers 0.000 description 1
- PCCVSPMFGIFTHU-UHFFFAOYSA-N tetracyanoquinodimethane Chemical compound N#CC(C#N)=C1C=CC(=C(C#N)C#N)C=C1 PCCVSPMFGIFTHU-UHFFFAOYSA-N 0.000 description 1
- ZUHZGEOKBKGPSW-UHFFFAOYSA-N tetraglyme Chemical compound COCCOCCOCCOCCOC ZUHZGEOKBKGPSW-UHFFFAOYSA-N 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- 229940015849 thiophene Drugs 0.000 description 1
- 229930192474 thiophene Natural products 0.000 description 1
- YFNKIDBQEZZDLK-UHFFFAOYSA-N triglyme Chemical compound COCCOCCOCCOC YFNKIDBQEZZDLK-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61N—ELECTROTHERAPY; MAGNETOTHERAPY; RADIATION THERAPY; ULTRASOUND THERAPY
- A61N1/00—Electrotherapy; Circuits therefor
- A61N1/18—Applying electric currents by contact electrodes
- A61N1/32—Applying electric currents by contact electrodes alternating or intermittent currents
- A61N1/36—Applying electric currents by contact electrodes alternating or intermittent currents for stimulation
- A61N1/372—Arrangements in connection with the implantation of stimulators
- A61N1/378—Electrical supply
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G9/00—Electrolytic capacitors, rectifiers, detectors, switching devices, light-sensitive or temperature-sensitive devices; Processes of their manufacture
- H01G9/004—Details
- H01G9/008—Terminals
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/64—Carriers or collectors
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/50—Current conducting connections for cells or batteries
- H01M50/531—Electrode connections inside a battery casing
Definitions
- the instant invention concerns an electrical energy storage device for an implantable medical stimulation device according to the preamble of claim 1.
- An electrical energy storage device of this kind may for example be formed by an electrochemical battery or an electric capacitor, in particular an electrolytic capacitor.
- An electrical energy storage device of the type concerned herein generally comprises a housing, a first electrical electrode and a second electrical electrode having different electrical polarities, one of the first electrical electrode and the second electrical electrode being formed by an electrode element having an electrically conductive electrode body arranged in the housing.
- a current collector arrangement is electrically connected to the electrode element for collecting and/or conducting electrical charges , e.g. electrons, at the electrode element in order to provide electrical energy from the electrical energy storage device.
- An electrode body of an electrode element as concerned herein may formed as a massive or solid body forming a block-like element, which serves as an electrode active material during operation of the electrical energy storage device.
- the electrode element may for example be formed by employing a sintering technique, in the course of which particles are compressed and partially melted in order to increase the density of the material and to form bridges between particles. By sintering, a compact metal part is formed from an originally porous powder material.
- Such sintered electrode bodies are particularly used when tantalum or niobium are used as electrode active materials.
- the electrode body may be designed in form of a foil or a sheet made from a suitable electrode active material, e.g. a metal such as an alkaline metal (lithium, sodium) or aluminum.
- the electrode body may be formed from an electrode active material being in a powder or granular form, wherein the electrode active material is pressed into the desired form, however, without being sintered afterwards.
- electrode active material comprising carbon (graphite, carbon monofluoride or the like), manganese dioxide or other mixed metal oxides as electrode active material.
- an electrode element is used to collect electrical charges , e.g. electrons, at the electrode element, the electrode element having the shape of a wire or a mesh for example embedded within the material of the electrode element or arranged on or at the electrode element.
- electrical charges e.g. electrons
- this may cause collection of electrical charges in particular in the vicinity of the current collector element and may have the effect that efficiency of electrical charge collection is not optimal, such that the stored energy of the electrical energy storage device may not be optimally exploited, for example when using the electrical energy storage device for a high-current discharge to generate a stimulation shock in an implantable medical stimulation device, such as an implantable defibrillator device.
- US 2018/0159113 Al describes an electrical energy storage device having the shape of a battery comprising an electrode assembly housed inside a casing.
- an electrical energy storage device comprising the features of claim 1.
- the current collector arrangement comprises a first current collector element forming a first current collection section having a first free end and a second current collector element forming a second current collection section having a second free end.
- the first current collection section and the second current collection section each extend in the electrode body or along a surface of the electrode body such that the first free end of the first collector element and the second free end of the second connector element are arranged at a distance with respect to one another in or on the electrode body.
- the electrical energy storage device comprises a first electrode and a second electrode having different polarities, one of which is formed by an electrode element having an electrode body, in particular a massive or solid electrode body, for example formed by a sintering technique.
- the electrode body as a whole, is electrically conductive such that, by means of the electrode body, electrical charges, e.g. electrons may be collected and/or conducted in order to harvest energy from the electrical energy storage device.
- a current collector arrangement which comprises (at least) a first current collector element forming a first current collection section and a second current collector element forming a second current collection section.
- at least two current collector elements are used on the (single) electrode element, the current collection sections being arranged in the electrode body or on a surface of the electrode body such that the current collection sections effectively are coupled to the electrode body.
- the electrode element As (at least) two current collector elements are used on the electrode element for collecting or conducting electrical charges during operation of the electrical energy storage device, efficiency of collecting and/or conducting electrical charges and hence the efficiency of harvesting and exploiting stored energy from the electrical energy storage device may be improved.
- the effective area for collecting electrical charges may be increased by increasing the number of current collector elements.
- the current collector arrangement may comprise two or more current collector elements.
- more than two current collector elements for example three, four or five current collector elements for establishing a connection to the (single or individual) electrode element.
- the electrical energy storage device in particular may be used in an implantable medical stimulation device, for example an implantable medical stimulation device providing for a cardiac stimulation function, such as an implantable defibrillator or the like.
- the first current collector element and the second collector element, with their current collection sections, are arranged in or on the electrode body of the electrode element, such that their free ends are spatially separate from one another.
- the current collection sections of the current collector elements hence, except for the connection provided by the electrode body, are structurally separate from one another such that the first free end of the first current collection section of the first current collector element and the second free end of the second current collection section of the second current collector element are not structurally connected, by a structure of the current collector arrangement itself, within the electrode body, except by the electrode body.
- the current collector elements hence form separate current collection sections extending in and across different regions of the electrode body, such that electrical charges may be effectively collected and/or conducted at the electrode body in a wide area across the electrode body.
- the first current collection section and the second current collection section are not structurally connected to each other within the volume of the electrode body, except by the electrode body. Other than via the electrode body, hence, there is no structural connection in between the first current collection section and the second current collection section within the volume of the electrode body.
- the current collector elements, with the free ends of the current collection sections, hence, are free from one another.
- the electrode body comprises a first (effective) electrical conductivity
- the first current collector element and the second current collector element each comprise a second (effective) electrical conductivity, wherein the first (effective) electrical conductivity is smaller than the second (effective) electrical conductivity.
- the current collector elements in comparison to the electrode body, thus provide for a reduced electrical resistance and hence allow for an electrical charge or current conduction in the electrode body and away from the electrode body with a reduced electrical resistance as compared to a conduction in the material of the electrode body.
- the current collector elements hence are operative to collect and/or conduct electrical charges within the electrode body, such that energy may efficiently be harvested by providing an electrical current from the energy storage device.
- multiple current collector elements having multiple current collection sections extending in or on the electrode body are provided, multiple current paths formed by the current collector elements are provided within or on the electrode body for collecting and/or conducting electrical charges.
- the electrode body may for example be formed by employing a sintering technique, in which particles, for example a particle powder, is compressed and heated such that particles are partially melted and bonded to each other, and a dense, compact body is formed.
- a sintering technique in which particles, for example a particle powder, is compressed and heated such that particles are partially melted and bonded to each other, and a dense, compact body is formed.
- the particle powder essentially consists of or comprises tantalum or niobium.
- the electrode body may be formed by pressing a composition comprising an electrode active particle powder and optionally a binder and/or conductive additive, e.g. made from carbon (e.g. graphite, graphene or hardened carbon) into a desired form, particularly in case of the electrode active material essentially consists of or comprises graphite, carbon monofluoride or manganese dioxide.
- the electrode body may be formed by a foil or sheet of electrode active material, wherein the electrode active material may comprise aluminum, or an alkaline metal, particularly lithium, sodium, or potassium.
- the first current collection section of the first current collector element and the second current collection section of the second current collector element are each embedded within the material of the electrode body.
- the current collection sections of the current collector elements are placed within the material of the electrode body, such that the current collection sections are integrally embedded within the electrode body, for example when sintering the electrode body.
- the first current collection section and the second current collection section extend along different directions in or on the electrode body.
- the current collector elements may reach into the electrode body along opposite directions, such that the first current collector element is arranged at a first face of the electrode body and the second current collector element is arranged at a second, opposite face of the electrode body.
- the current collector elements may be arranged to extend along different directions arranged at an angle with respect to one another in or on the electrode body.
- the electrical energy storage device comprises a first electrical electrode and a second electrical electrode which are at different polarities (+ vs. -).
- One of the electrical electrodes forms a cathode, whereas the other electrical electrode forms an anode.
- the electrode element may function as anode within the electrical energy storage device, such that the other electrode element serves as cathode.
- the housing is made from an electrically conductive material, wherein the other of the first electrical electrode and the second electrical electrode is formed by the housing or is electrically connected to the housing.
- the housing encloses the electrode element, but is electrically separate from the electrode element, the housing for example forming or being connected to the cathode of the electrical energy storage device.
- suitable electrically conductive materials include titanium, a titanium alloy, aluminum, or stainless steel.
- an electrical connection is established between the housing and an associated electrical electrode inside the housing, such that via the housing the electrical electrode associated with the housing may be electrically contacted.
- the current collector arrangement comprises at least one output section.
- the housing comprises at least one feedthrough for guiding the at least one output section through the housing, the at least one feedthrough providing for an electrical insulation of the at least one output section with respect to the housing such that an effective electrical coupling to the electrode element received within the housing may be established using the at least one output section.
- connection lines such as connective bands, wires or strips, in particular flexible strips, or printed circuit boards, or insulated conductors.
- Connection lines may for example be connected to the housing for establishing an electrical connection to the electrical electrode associated with the housing, and to one or multiple output sections of the collector elements associated with the electrode element received within the housing for establishing an electrical connection to the electrode element within the housing.
- the housing is hermetically tight, i.e. fluid tight.
- the at least one feedthrough is hermetically tight such that the output section is guided through the housing via the feedthrough while not impacting the hermetic tightness of the housing.
- the feedthrough is for example made from or comprises a ceramic, a glass or glass solder, or a polymer, particularly an epoxy resin, silicone, or a liquid crystal polymer.
- a liquid crystal polymer is used in the meaning known to and commonly used by a person skilled in the art.
- a “liquid crystal polymer” refers in particular to an aromatic polymer, which has highly ordered or crystalline regions in the molten state or in solution.
- Non-limiting examples include aromatic polyamides such as aramid (Kevlar) and aromatic polyesters of hydroxybenzoic acid, such as a polycondensate of 4-hydroxybenzoic acid and 6-hydroxynaphthalene-2-carboxylic acid (Vectran).
- the feedthrough is inserted into an opening formed in the housing such that, beneficially, the feedthrough provides for an electrical insulation of the output section with respect to the housing and at the same time tightly closes the opening in the housing.
- the current collector arrangement may employ, in one embodiment, a single output section, which within the housing is electrically coupled to both current collector elements. In this embodiment, a single feedthrough for guiding one output section through the housing is sufficient.
- the current collector arrangement may employ multiple output sections, for example one output section associated with each current collector element.
- no electrical coupling in between the current collector elements within the housing is required, but rather output sections are separately coupled each to an associated current collector element and are separately guided, by using a feedthrough for each, through the housing.
- the electrical energy storage device is designed as an electrochemical cell, particularly as a battery. In another embodiment, the electrical energy storage device is designed as a capacitor, particularly as an electrolytic capacitor.
- one of the electrical electrodes comprises an alkali metal, particularly selected from lithium, sodium or potassium.
- the battery may be a primary battery or a secondary battery.
- the electrical energy storage device is designed as primary battery, wherein one of the electrical electrodes comprises for example an alkali metal as an electrode active material, particularly selected from lithium, sodium or potassium, and the other of the electrical electrodes comprises as an electrode active material carbon monofluoride (CFx), manganese dioxide (MnCh), graphite, iodine (I2), silver vanadium oxide (SVO), copper silver vanadium oxide (CSVO), V2O2, TiS2, CuCh, 12S, FeS, FeS2, Ag2O, Ag2O2, CuF, Ag2CrO4, CuO, CU2P2O7, CU4P2O9, CU5P2O10, Ag2Cu2?2O8, Ag2CusP2O9, copper vanadium oxide or a mixture thereof.
- CFx carbon monofluoride
- MnCh manganes
- the electrical energy storage device is designed as a secondary battery, wherein one of the electrical electrodes for example comprises an alkali metal as an electrode active material, particularly selected from lithium, sodium, potassium or carbon, particularly graphite, hard carbon or non-graphitizing carbon, and the other of the electrical electrodes comprises as an electrode active material particularly lithium cobalt oxide (LiCoCh), lithium nickel manganese cobalt oxide (mixed oxides of LiCoCh, LiNiCh and LiMnCh), lithium nickel cobalt aluminum oxide (NCA), lithium manganese oxide (LiM Ch), or lithium iron phosphate (LiFePCh).
- LiCoCh lithium cobalt oxide
- LiCoCh lithium nickel manganese cobalt oxide
- NCA lithium nickel cobalt aluminum oxide
- LiM Ch lithium manganese oxide
- LiFePCh lithium iron phosphate
- the electrical energy storage device is designed as a battery (primary battery or secondary battery) and further comprises an electrolyte, preferably a non-aqueous electrolyte, wherein particularly one of the electrical electrodes comprises as an electrode active material an alkali metal, particularly selected from lithium, sodium or potassium.
- Suitable electrolytes include, without being restricted to, non-aqueous, preferable aprotic, solvents, such as an ester, an ether and a dialkyl carbonate, particularly tetrahydrofuran, methyl acetate, diglyme (bi s(2-m ethoxy ethyl)ether), triglyme (tris(2-methoxyethyl)ether), tetraglyme (tetra(2-methoxyethyl)ether), 1,2-dimethoxy ethane, 1,2-di ethoxy ethane, 1- ethoxy-2-methoxyethane, dimethyl carbonate, diethyl carbonate, dipropyl carbonate, ethyl methyl carbonate, methyl propyl carbonate, ethyl propyl carbonate or a mixture thereof, or a cyclic carbonate, a cyclic ester, a cyclic amide, particularly propylene carbonate, ethylene carbonate
- Suitable electrolytes also comprise polar non-aqueous solvents such as acetonitrile, dimethyl sulfoxide, dimethyl formamide, dimethyl acetamide or a mixture thereof.
- the electrolyte comprises at least one conductive salt.
- the conductive salt is preferably an inorganic alkali metal salt, whereby the alkali metal cation is the same as the active anode material.
- Suitable anions are PFe , BF4 , AsFe", SbFe", CIO4 , O2 , AICI4 , GaCh", SCN", SO3(C 6 F 5 )-, C(SO 2 CF 3 ) 3 , N(SO 2 CF 3 ) 2 and SO 3 CF 3 among others.
- the concentration of the conductive salt is , LiPFe, LiCICh, LiFSI, LiTFSI, LiAsFe, LiBOB, LiODFB, or LiNO 3 .
- the electrical energy storage device is designed as an electrolytic capacitor, wherein one of the electrical electrodes comprises as an electrode active material for example tantalum or niobium, and the other of the electrical electrodes comprise as an electrode active material for example activated carbon, graphite, graphene, a carbon nanotube, and a conductive polymer.
- one of the electrical electrodes comprises as an electrode active material for example tantalum or niobium
- the other of the electrical electrodes comprise as an electrode active material for example activated carbon, graphite, graphene, a carbon nanotube, and a conductive polymer.
- the housing is electrically conductive and e.g. is made from aluminum, titanium, a titanium alloy, or stainless steel, wherein one of the electrical electrodes of the electrical energy storage device is formed by a layer or coating applied on an inner surface of the conductive housing, the layer or coating being in electrically conductive communication with the conductive housing.
- the layer of coating may be attached to the inner surface of the conductive housing by means of an adhesion layer.
- the layer or coating may further comprise a binder such as polyvinylidene fluoride (PVDF) polytetrafluoroethylene (PTFE), carboxymethyl cellulose (CMC) or a rubber, particularly acryl rubber, nitrile butadiene rubber, styrene butadiene rubber (SBR) or butyl rubber.
- PVDF polyvinylidene fluoride
- CMC carboxymethyl cellulose
- SBR styrene butadiene rubber
- one of the electrical electrodes comprises, as an electrode active material, aluminum, preferably an aluminum foil
- the other of the electrical electrodes comprises, as an electrode material, aluminum, preferably an aluminum foil, wherein particularly a separator is arranged between the electrical electrodes.
- the separator may e.g. be made from an absorbent paper.
- the electrical energy storage device comprises an aqueous electrolyte.
- the electrolyte comprises ethylene glycol and optionally an acid, particularly boric acid or acetic acid.
- One of the electrical electrodes for example the electrode element received in the housing, may e.g.
- the electrolyte comprises aluminium or tantalum as electrode active material.
- the electrolyte comprises ethylene glycol, acetic acid and ammonium acetate.
- the electrolyte comprises dimethylformamide, dimethylacetamide and/or y -butyrolactone.
- the electrolyte comprises tetracyanoquinodimethane, polypyrrole, or poly(3,4- ethy 1 enedi oxy thi ophene) .
- the housing comprises at least one rounded edge.
- the housing may comprise a rounded face.
- the housing comprises a planar face at one side and the rounded face at an opposite side.
- the rounded face may in particular be adapted such that it conforms with the shape of a generator device housing of an implantable medical stimulation device, such that the energy storage device may be tightly fitted in a cavity of the generator device housing.
- the rounded edge of the housing may in particular comprise a radius of curvature of at least 0.5 mm, preferably larger than 1 mm, even more preferably larger than 2.5 mm.
- the housing, the electrode element and the current collector arrangement comprising the first current collector element and the second current collector element are arranged symmetrically with respect to a plane of symmetry, the first current collector element being arranged at a first side of the plane of symmetry and the second current collector element being arranged at a second side of the plane of symmetry.
- the entire electrical energy storage device may exhibit a symmetry with respect to the plane of symmetry, wherein the symmetry is such that the collector elements are arranged symmetrically, with respect to the plane of symmetry, on the electrode body of the electrode element and, beneficially, output sections are symmetrically guided through the housing of the electrical energy storage device by means of corresponding feedthroughs at symmetrical locations at a first side of the plane of symmetry and at a second side of the plane of symmetry.
- the electrical energy storage device By forming the electrical energy storage device symmetrically with respect to a central plane of symmetry, it in particular may be facilitated to combine multiple energy storage devices to form an assembly of energy storage devices to increase the overall energy storage capacity. Due to the symmetric structure of the energy storage devices, output sections for establishing an electrical connection in between the different energy storage devices are symmetrically placed on the housing of the energy storage devices, such that an electrical connection in between the electrical energy storage devices may easily and space-efficiently be established.
- the electrical energy storage device comprises a connection line which electrically connects the first current collector element and the second current collector element.
- the connection line is arranged outside of the electrode body and hence is separate from the electrode body.
- the connection line may be for example received within the housing and hence may run inside the housing.
- the connection line may extend outside of the housing and may provide for an electrical connection in between the collector elements outside of the housing.
- connection line is placed on a carrier element attached to the housing, for example outside of the housing.
- the carrier element may for example be formed by a printed circuit board (PCB), wherein by means of the connection line an electrical connection in between the different collector elements, for example between output sections associated with the different collector elements, is established.
- PCB printed circuit board
- an assembly of at least two electrical energy storage devices is used to provide for an increased energy storage capacity.
- the electrical energy storage devices may for example be electrically connected by a connection arrangement, which employs a multiplicity of connection lines which establish a functional, electrical connection in between the energy storage devices.
- the at least two electrical energy storage devices may electrically be connected in series, such that the output voltages of the electrical energy storage devices add to one another.
- the at least two electrical energy storage devices may electrically be connected in parallel.
- the housings of a first of the at least two electrical energy storage devices and a second of the at least two electrical energy storage devices each comprise a rounded face and a planar face.
- the first and the second of the at least two energy storage devices are arranged with respect to one another such that the housings of the first and the second of the at least two energy storage devices face towards each other with the planar faces and face away from one another with the rounded faces.
- the outer shape of the assembly may be such that it conforms to the shape of a generator device housing and hence may be efficiently received in the generator device housing, hence optimally using a space available within the generator device housing.
- an implantable medical stimulation device comprises an electrical energy storage device according to the type described above or an assembly of at least two electrical energy storage devices according to the type described above.
- Fig. 1 shows a schematic view of an implantable medical stimulation device having a generator device
- Fig. 2 shows a schematic drawing of an electrical energy storage device for use in an implantable medical stimulation device
- Fig. 3 shows a schematic view of another embodiment of an electrical energy storage device
- Fig. 4 shows an embodiment of an assembly of electrical energy storage devices
- Fig. 5 shows the assembly of Fig. 4, in an electrically connected state
- Fig. 6 shows another example of an assembly of electrical energy storage devices
- Fig. 7 shows yet another example of an assembly of electrical energy storage devices
- Fig. 8 shows yet another example of an assembly of electrical energy storage devices
- Fig. 9 shows another embodiment of an electrical energy storage device
- Fig. 10 shows yet another embodiment of an electrical energy storage device
- Fig. 11 shows yet another embodiment of an electrical energy storage device
- Fig. 12 shows a schematic drawing of an electrode element with a collector element arranged thereon
- Fig. 13 A shows an embodiment of an electrode element with a collector element arranged thereon
- Fig. 13B shows another embodiment of a collector element arranged on an electrode element
- Fig. 13C shows yet another embodiment of a collector element arranged on an electrode element. Subsequently, embodiments of the invention shall be described in detail with reference to the drawings. In the drawings, like reference numerals designate like structural elements.
- Fig. 1 shows, in a schematic drawing, an embodiment of an implantable medical stimulation device 1 implanted in a patient, the implantable medical stimulation device 1 comprising a generator 12 connected to leads 10, 11 extending from the generator 12 through the superior vena V into the patient's heart H.
- the leads 10, 11 electrical pulses for providing a pacing action and/or defibrillation in the heart H may be delivered to intra-cardiac tissue potentially at different locations within the heart, and sense signals may be received.
- an electrode lead 10 is implanted into the heart H such that it extends into the right ventricle RV of the heart H and is arranged on intra-cardiac tissue M in the right ventricle RV of the heart H.
- An electrode lead 11 in turn is implanted such that it reaches into the right atrium RA.
- An implantable medical stimulation device 1 as concerned herein may generally be a cardiac stimulation device, such as a cardiac pacemaker or defibrillator device, e.g. a one-chamber or two-chamber implantable pulse generator (IPG), or a one-chamber or two-chamber implantable cardioverter defibrillator (ICD).
- a stimulation device 1 of this kind may comprise a generator 12, as shown in Fig. 1, which may be subcutaneously implanted in a patient at a location remote from the heart H, and one or multiple leads 10, 11 extending from the generator 12 into the heart H for emitting stimulation pulses in the heart H or for obtaining sense signals at one or multiple locations from the heart H.
- the leads 10, 11 each form a generally longitudinal, tubular body, which reaches into the heart H and is anchored at a location of interest within the heart H.
- the generator device 12 comprises processing circuitry 120 which is configured to control operation of the implantable medical stimulation device 1, in particular for processing sensed signals and for generating stimulation signals for performing a stimulation action on the patient’ s heart H.
- the generator device 12 comprises an electrical energy storage device 2 or an assembly 3 of electrical energy storage devices 2 which serve to supply electrical energy for enabling operation of the implantable medical stimulation device 1.
- the energy storage device 2 or the assembly 3 of energy storage devices 2 is configured to generate one or multiple shock pulses in order to output defibrillation shocks.
- an electrical energy storage device 2 comprises a housing 20 which receives an electrode element 21 therein.
- the housing 20 may serve or may be electrically connected to a first electrical electrode, the electrode element 21 serving as another, second electrical electrode having a different polarity in comparison to the electrical electrode formed by or connected to the housing 20.
- the electrode element 21 comprises an electrode body 210 which may be formed, as schematically indicated in Fig. 12, by a massive block element which for example is formed by a sintering technique from an electrically conductive material, such as an niobium or tantalum material.
- the electrode body 120 may be designed in form of a foil or sheet made from, e.g. aluminum. In order to collect electrical charges , e.g.
- a current collector arrangement 22 comprises current collector elements 220, 221 which are arranged on the electrode body 210 of the electrode element 21, such that electrical charges may be received at the current collector elements 220, 221 and a current may be output by the electrical energy storage device 2 via the collector elements 220, 221.
- the current collector elements 220, 221 each comprise a current collection section 222, 223 which reaches into the electrode body 210 of the electrode element 21, the current collection sections 222, 223 in each case forming a free end 227, 228 which is placed within the electrode body 210 or on a surface of the electrode body 210.
- the current collection sections 222, 223 may be embedded within the material of the electrode body 210, as this is schematically illustrated in Fig. 12.
- the current collection sections 222, 223 may be integrally received and embedded within the electrode body 210 in that the current collection sections 222, 223 of the current collector elements 220, 221 are placed within the material of the electrode body 210 during manufacturing of the electrode body 210 and are integrally connected to the electrode body 210 for example when sintering the electrode body 210.
- the current collector elements 220, 221 typically electrical charges are collected in a spatial region Al, A2 in the vicinity of the current collection sections 222, 223.
- the effective region increases from which electrical charges may be collected on the electrode body 210 of the electrode element 21, such that the energy exploitation of the electrical energy storage device 2 may be increased in that stored energy may be efficiently harvested from the electrical energy storage device 2, for example for use in an implantable medical stimulation device 1 such as an implantable defibrillator.
- two current collector elements 220, 221 are used on a (single, individual) electrode element 21.
- more than two collector elements 220, 221 may be employed, for example three or more current collector elements.
- the housing 20 is made from an electrically conductive material and forms or is connected to an electrical electrode serving as a counter electrode to the electrical electrode formed by the electrode element 21.
- Output sections 224, 225 of the collector elements 220, 221 are guided through the housing 20 at feedthroughs 200, 201, the feedthroughs 200, 201 providing for an electrical insulation of the output sections 224, 225 with respect to the housing 20.
- the feedthroughs 200, 201 may for example be made from a glass or ceramic material, or a polymer material.
- the housing 20 is hermetically tight, in particular fluid tight, such that liquid and gas may not enter into our exit from the housing 20.
- the tight sealing of the housing 20 herein is not impacted by the feedthroughs 200, 201, which provide for a fluid- tight guidance of the output sections 224, 225 through the housing 20.
- the current collector elements 220, 221 of the current collector arrangement 22 are arranged such that they are aligned with their current collection sections 222, 223, the free ends 227, 228 being arranged at a distance within the electrode body 210 of the electrode element 21.
- the current collection sections 222, 223 herein extend along opposite directions into the electrode body 210.
- the current collector elements 220, 221, at their current collection sections 222, 223 within the electrode body 210, are structurally not connected to each other, except by the electrode body 210.
- the free ends 227, 228 hence are structurally separate from one another in that no structure of the current collector arrangement 22 provides for an interconnection in between the collection sections 222, 223 within the electrode body 210.
- the housing 20 and the electrode element 21 may differ from a rectangular (cubic) shape. Rather, the housing 20 and the electrode element 21 in a top view may have a polygonal shape, hence allowing to adapt the shape of the electrical energy storage device 2 to the shape of a cavity within a generator device housing of a generator device 12, such that the electrical energy storage device 2 may be space-efficiently received within the generator device housing.
- current collection sections 222, 223 of the current collector elements 220, 221 are arranged at an angle with respect to one another, wherein like in the embodiment of Fig. 2 the current collection section 222, 223 are structurally separate from one another except for the connection provided by the embedding within the material of the electrode body 210.
- output sections 224, 225 are guided through the housing 20 at feedthroughs 200, 201 at a common face of the housing 20, such that the output sections 224, 225 in parallel extend from the housing 20 and are accessible at the common face.
- the electrical energy storage device 2 is formed symmetrically with respect to a plane of symmetry P.
- the plane of symmetry P is oriented perpendicularly in between the current collector elements 220, 221, such that the current collector elements 220, 221 are arranged at opposite sides with respect to the plane of symmetry P.
- the output sections 224, 225 on the feedthroughs 200, 201 are arranged at either side of the plane of symmetry P and are equidistantly placed with respect to the plane of symmetry P.
- the housing 20 and the electrode element 21 are symmetrical with respect to the plane of symmetry P.
- a symmetry of the electrical energy storage device 2 allows to form an assembly 3 of multiple electrical energy storage devices 2A, 2B, which may be received in a space-efficient manner in a generator device housing of a generator device 12 of an implantable medical stimulation device 1.
- the housings 20 of the electrical energy storage devices 2A, 2B may each comprise a planar face 207.
- the planar faces 207 of the housings 20 may be abutted on one another for forming the assembly 3, such that the electrical energy storage devices 2 A, 2B may be arranged on one another in a space-efficient manner.
- each housing 20 comprises, facing away from the planar face 207, a rounded face 206 which faces outwards.
- An outer envelope of the assembly 3 herein is formed by the rounded faces 206 of the housings 20 of the individual electrical energy storage devices 2A, 2B, the shaping of the rounded faces 206 allowing for adapting the assembly 3 to the shape of a cavity within a generator device housing to space-efficiently receive the assembly 3 within the generator device housing.
- the feedthroughs 200, 201 and the output sections 224, 225 on the housings 20 of the electrical energy storage devices 2A, 2B are aligned with one another and are arranged proximally with respect to one another when forming the assembly 3. This allows to establish an electrical connection in between the electrical energy storage devices 2A, 2B by employing short electrical connection lines, thus using minimum space for establishing an electrical connection.
- connection arrangement 23 is formed by a set of connection lines 230-233 such that output voltages of the electrical energy storage devices 2A, 2B add up according to the series connection.
- connection terminals 202, 203 are formed on each housing 20 of the electrical energy storage devices 2A, 2B, the terminals 202, 203 of the housing 20 of the electrical energy storage devices 2A being connected to output sections 224, 225 at the feedthroughs 200, 201 of the housing of the electrical energy storage device 2B.
- Output terminals of the assembly 3 are provided by connection lines 230, 233, the connection line 230 being connected to the output section 224 at the feedthrough 200 of the electrical energy storage device 2 A and the connection line 233 being connected to the connection terminal 203 on the housing 20 of the electrical energy storage device 2B.
- the connection lines 230, 233 hence provide for output terminals at opposite polarities at which the combined output voltage of both electrical energy storage devices 2A, 2B is output.
- connection lines 230-233 may for example be formed by connective bands or strips, such as flexible strips, or by printed circuit boards.
- electrically insulated lines for example guided in a plastic or ceramic insulation, may be used.
- an additional, third electrical energy storage device 2C is added to the assembly of Fig. 5, in that the electrical energy storage device 2C by connection lines 233, 234 is connected to the electrical energy storage device 2B, namely by connecting the housing 20 of the electrical energy storage device 2B to the output sections 224, 225 at the feedthroughs 200, 201 of the electrical energy storage device 2C.
- connection line 235 connected to the connection terminal 203 on the housing 20 of the electrical energy storage device 2C an output terminal for the assembly 3 is formed on the electrical energy storage device 2C, such that in between the output terminals formed by the connection lines 230, 235 the combined output voltage of the three electrical energy storage devices 2 A, 2B, 2C is output.
- connection line 236 is connected to the output section 225 at the feedthrough 201 of the electrical energy storage device 2A, whereas connection line 237 is connected to a connection terminal 202 on the housing 20 of the electrical energy storage device 2C.
- connection line 237 is connected to a connection terminal 202 on the housing 20 of the electrical energy storage device 2C.
- two first output terminals corresponding to the polarity of the output sections 224, 225 on the feedthroughs 200, 201 of the electrical energy storage device 2A are provided in parallel.
- two second output terminals corresponding to the polarity of the housing 20 of the electrical energy storage device 2C are provided in parallel.
- the embodiment of Fig. 8 differs from the embodiment of Fig. 6 in that an additional connection line 236 is provided which connects the output section 225 at the feedthrough 201 to the output section 224 at the feedthrough 200 on the electrical energy storage device 2 A, such that the electrode elements 220, 221 associated with the output sections 224, 225 are electrically connected to one another outside of the electrical energy storage device 2A.
- the different collector elements 220, 221 of an electrical energy storage device 2 may be electrically connected to one another within the housing 20 of the electrical energy storage device 2 or outside of the housing 20.
- connection terminals 202, 203 on the housing 20 of a particular electrical energy storage device 2A, 2B, 2C may be configured to establish for example a soldering connection to the associated connection lines 230-237.
- plug-in connections may be established by using suitable electrical connectors.
- soldering connections or plug-in connections may be established in between the associated connection lines 230-237 and the output sections 224, 225 at the feedthroughs 200, 201.
- connection of current collector elements 220, 221 may for example be established outside of the housing 20 by using a connection line 240 running in between the feedthroughs 200, 201 and the corresponding output sections 224, 225 of the current collector elements 220, 221 arranged thereon.
- the connection line 240 is arranged on a carrier element 24, for example a printed circuit board, which is placed on and connected to the housing 20.
- connection terminals 202, 203 for establishing an electrical connection to the housing 20 may be provided on the carrier element 24, the connection terminals 202, 203 being electrically connected to the housing 20 for example by electrical interconnections, for example soldering connections.
- connection terminals 202, 203 are arranged in the vicinity to the feedthrough 200, 201, such that two electrical interconnections to the housing 20 in the vicinity of the feedthroughs 200, 201 may be established.
- connection terminal 202 is provided on the carrier element 24 for establishing an electrical connection to the housing 20, the connection terminal 202 being connected to the housing 20 by an electrical interconnection 204.
- a central connection terminal 241 centrally on the connection line 240 is provided to establish an electrical interconnection to the connection line 240 and, in this way, to the output sections 224, 225 of the collector elements 220, 221 associated with the feedthroughs 200, 201.
- an electrical connection between the collector elements 220, 221 may be established by a connection line 226 received within the housing 20 of the electrical energy storage device 2.
- the current collector elements 220, 221 hence are electrically connected within the housing 20, but externally of the electrode element 21.
- a single feedthrough 200 for guiding a single output section 224 through the housing 20 suffices.
- each current collector element 220, 221 may for example be formed by a wire or another, more complex conductive structure, for example a mesh, as described below.
- the current collection section 222, 223 of each current collector element 220, 221 in particular may extend straight within the electrode body 210 of the electrode element 21, as it is shown in Fig. 13 A, or may follow a meandering path, as it is shown in Fig. 13B.
- the current collection section 222, 223 may have a web or mesh shape, as shown in Fig. 13C.
- free ends 227, 228 of the current collection sections 222, 223 of the current collector elements 220, 221 are not structurally interconnected with one another within the electrode body 210 of the electrode element 21, except by the electrode body 210.
- the idea of the invention is not limited to the embodiments described above, but may be implemented in an entirely different fashion.
- An electrical energy storage device or an assembly of multiple electrical energy storage devices as described herein may be used in an implantable medical stimulation device, such as an implantable cardiac stimulation device, for example a stimulation device having a defibrillation function.
- An electrical energy storage device or an assembly of multiple electrical energy storage devices of the type concerned herein may also be used in other electrical or electronic devices, in particular also outside of the medical field.
Landscapes
- Engineering & Computer Science (AREA)
- Power Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Electrochemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Chemical & Material Sciences (AREA)
- Radiology & Medical Imaging (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- General Health & Medical Sciences (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Animal Behavior & Ethology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Nuclear Medicine, Radiotherapy & Molecular Imaging (AREA)
- Biomedical Technology (AREA)
- Electrotherapy Devices (AREA)
Abstract
Un dispositif de stockage d'énergie électrique (2, 2A-2C) pour un dispositif de stimulation médicale implantable (1) comprend un boîtier (20), une première électrode électrique et une seconde électrode électrique ayant des polarités électriques différentes, l'une de la première électrode électrique et de la seconde électrode électrique étant formée par un élément d'électrode (21) ayant un corps d'électrode électroconducteur (210) disposé dans le boîtier (20), et un agencement de collecteur de courant (22) connecté électriquement à l'élément d'électrode (20). L'agencement de collecteur de courant (22) comprend un premier élément collecteur de courant (220) formant une première section de collecte de courant (222) ayant une première extrémité libre (227) et un second élément collecteur de courant (221) formant une seconde section de collecte de courant (223) ayant une seconde extrémité libre (228), la première section de collecte de courant (222) et la seconde section de collecte de courant (223) s'étendant chacune dans le corps d'électrode (210) ou le long d'une surface du corps d'électrode (210) de telle sorte que la première extrémité libre (227) du premier élément collecteur de courant (220) et la seconde extrémité libre (228) du second élément collecteur de courant (221) sont disposées à une certaine distance l'une de l'autre dans ou sur le corps d'électrode (210).
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP22198947 | 2022-09-30 | ||
EP22198947.8 | 2022-09-30 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2024068158A1 true WO2024068158A1 (fr) | 2024-04-04 |
Family
ID=83508946
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/EP2023/073565 WO2024068158A1 (fr) | 2022-09-30 | 2023-08-28 | Dispositif de stockage d'énergie électrique pour un dispositif de stimulation médicale implantable |
Country Status (1)
Country | Link |
---|---|
WO (1) | WO2024068158A1 (fr) |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP2363867A1 (fr) * | 2000-11-03 | 2011-09-07 | Cardiac Pacemakers, Inc. | Condensateur avec portions de bordure décalées |
US20130209847A1 (en) * | 2012-02-15 | 2013-08-15 | GM Global Technology Operations LLC | Battery design |
US20160020035A1 (en) * | 2014-07-18 | 2016-01-21 | Semiconductor Energy Laboratory Co., Ltd. | Electrode, power storage device, electronic device, and vehicle |
US20180159113A1 (en) | 2016-12-07 | 2018-06-07 | Greatbatch Ltd. | Closure system for the electrolyte fill port of an electrochemical cell |
US20210346705A1 (en) * | 2020-05-08 | 2021-11-11 | Pacesetter, Inc. | Hermetic feedthrough assembly and associated methods |
-
2023
- 2023-08-28 WO PCT/EP2023/073565 patent/WO2024068158A1/fr unknown
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP2363867A1 (fr) * | 2000-11-03 | 2011-09-07 | Cardiac Pacemakers, Inc. | Condensateur avec portions de bordure décalées |
US20130209847A1 (en) * | 2012-02-15 | 2013-08-15 | GM Global Technology Operations LLC | Battery design |
US20160020035A1 (en) * | 2014-07-18 | 2016-01-21 | Semiconductor Energy Laboratory Co., Ltd. | Electrode, power storage device, electronic device, and vehicle |
US20180159113A1 (en) | 2016-12-07 | 2018-06-07 | Greatbatch Ltd. | Closure system for the electrolyte fill port of an electrochemical cell |
US20210346705A1 (en) * | 2020-05-08 | 2021-11-11 | Pacesetter, Inc. | Hermetic feedthrough assembly and associated methods |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US6040082A (en) | Volumetrically efficient battery for implantable medical devices | |
US5154989A (en) | Energy storage device | |
US20060166088A1 (en) | Electrode connector tabs | |
JP3326671B2 (ja) | 再平衡リチウム/酸化バナジウム銀電池を用いた心臓の細動除去器 | |
US7018743B2 (en) | Dual chemistry electrode design | |
US6627337B2 (en) | Conversion of low rate energy into high rate energy by parallel discharging | |
WO2006050393A2 (fr) | Ensembles d'electrodes sous forme de plaques pliees pour cathodes de batteries | |
US7927738B2 (en) | Battery having improved headspace insulator | |
EP0237146A1 (fr) | Pile de métal alkalin non-aqueuse | |
US20070254212A1 (en) | Battery assembly for use in implantable medical device | |
US20130131745A1 (en) | Electrochemical cell with adjacent cathodes | |
US20090246617A1 (en) | Vanadium connector in an electrochemical cell for an implantable medical device | |
US6383680B1 (en) | Wound cell stack design for enhanced battery performance | |
KR20010032592A (ko) | 복합 배터리 및 그 제조 방법 | |
WO2004075332A1 (fr) | Electrolyte liquide pour pile electrochimique, pile electrochimique et dispositif medical implantable | |
JP4447217B2 (ja) | 二次電気化学電池 | |
JP2004039614A (ja) | 同一ケース内におけるSVO/CFx並列電池デザイン | |
US20090208816A1 (en) | Properly positioning stacked plate electrode for high volume assembly | |
US20110151310A1 (en) | High energy density battery for use in implantable medical devices and methods of manufacture | |
US10686228B2 (en) | Pouch battery for use in implantable electronic devices | |
WO2024068158A1 (fr) | Dispositif de stockage d'énergie électrique pour un dispositif de stimulation médicale implantable | |
US7482093B1 (en) | Insulator design to prevent lithium cluster bridging | |
US20140212736A1 (en) | Cathode composition for primary battery | |
US11362316B2 (en) | Battery having hybrid cathode configuration | |
US5587258A (en) | Galvanic cell having improved cathode |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
121 | Ep: the epo has been informed by wipo that ep was designated in this application |
Ref document number: 23761930 Country of ref document: EP Kind code of ref document: A1 |