WO2024068116A1 - Method for storing a concentrated frozen confection premix - Google Patents
Method for storing a concentrated frozen confection premix Download PDFInfo
- Publication number
- WO2024068116A1 WO2024068116A1 PCT/EP2023/072059 EP2023072059W WO2024068116A1 WO 2024068116 A1 WO2024068116 A1 WO 2024068116A1 EP 2023072059 W EP2023072059 W EP 2023072059W WO 2024068116 A1 WO2024068116 A1 WO 2024068116A1
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- WO
- WIPO (PCT)
- Prior art keywords
- premix
- concentrated
- concentrated premix
- storage period
- amount
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims abstract description 31
- 235000009508 confectionery Nutrition 0.000 title claims abstract description 24
- 238000003860 storage Methods 0.000 claims abstract description 66
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 19
- 239000007788 liquid Substances 0.000 claims abstract description 18
- 235000000346 sugar Nutrition 0.000 claims abstract description 12
- 150000008163 sugars Chemical class 0.000 claims abstract description 12
- 239000007764 o/w emulsion Substances 0.000 claims abstract description 8
- 108090000623 proteins and genes Proteins 0.000 claims abstract description 7
- 102000004169 proteins and genes Human genes 0.000 claims abstract description 7
- 239000003755 preservative agent Substances 0.000 claims description 12
- 230000002335 preservative effect Effects 0.000 claims description 12
- 230000000694 effects Effects 0.000 claims description 7
- 239000003995 emulsifying agent Substances 0.000 claims description 7
- 239000003085 diluting agent Substances 0.000 claims description 5
- 239000003381 stabilizer Substances 0.000 claims description 5
- 239000004302 potassium sorbate Substances 0.000 claims description 3
- 235000010241 potassium sorbate Nutrition 0.000 claims description 3
- 235000010199 sorbic acid Nutrition 0.000 claims description 3
- 239000004334 sorbic acid Substances 0.000 claims description 3
- CHHHXKFHOYLYRE-UHFFFAOYSA-M 2,4-Hexadienoic acid, potassium salt (1:1), (2E,4E)- Chemical compound [K+].CC=CC=CC([O-])=O CHHHXKFHOYLYRE-UHFFFAOYSA-M 0.000 claims description 2
- BEFDCLMNVWHSGT-UHFFFAOYSA-N ethenylcyclopentane Chemical compound C=CC1CCCC1 BEFDCLMNVWHSGT-UHFFFAOYSA-N 0.000 claims description 2
- 229940069338 potassium sorbate Drugs 0.000 claims description 2
- 229940075582 sorbic acid Drugs 0.000 claims description 2
- 239000003921 oil Substances 0.000 description 21
- 235000019198 oils Nutrition 0.000 description 21
- 239000000203 mixture Substances 0.000 description 13
- 238000006243 chemical reaction Methods 0.000 description 11
- 235000019197 fats Nutrition 0.000 description 10
- 239000007787 solid Substances 0.000 description 9
- 239000000839 emulsion Substances 0.000 description 8
- 239000004615 ingredient Substances 0.000 description 7
- 238000004519 manufacturing process Methods 0.000 description 7
- 239000000047 product Substances 0.000 description 6
- 108010005094 Advanced Glycation End Products Proteins 0.000 description 5
- 238000004581 coalescence Methods 0.000 description 5
- 150000002772 monosaccharides Chemical class 0.000 description 5
- 235000018102 proteins Nutrition 0.000 description 5
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 4
- 238000010790 dilution Methods 0.000 description 4
- 239000012895 dilution Substances 0.000 description 4
- 238000000265 homogenisation Methods 0.000 description 4
- 235000015243 ice cream Nutrition 0.000 description 4
- 244000005700 microbiome Species 0.000 description 4
- 239000008346 aqueous phase Substances 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 239000003240 coconut oil Substances 0.000 description 3
- 235000019864 coconut oil Nutrition 0.000 description 3
- 235000008504 concentrate Nutrition 0.000 description 3
- 239000012141 concentrate Substances 0.000 description 3
- 150000002016 disaccharides Chemical class 0.000 description 3
- 239000000796 flavoring agent Substances 0.000 description 3
- 235000013305 food Nutrition 0.000 description 3
- 239000008187 granular material Substances 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 229920001542 oligosaccharide Polymers 0.000 description 3
- 150000002482 oligosaccharides Chemical class 0.000 description 3
- 230000001953 sensory effect Effects 0.000 description 3
- 235000020357 syrup Nutrition 0.000 description 3
- 239000006188 syrup Substances 0.000 description 3
- 229930091371 Fructose Natural products 0.000 description 2
- 239000005715 Fructose Substances 0.000 description 2
- RFSUNEUAIZKAJO-ARQDHWQXSA-N Fructose Chemical compound OC[C@H]1O[C@](O)(CO)[C@@H](O)[C@@H]1O RFSUNEUAIZKAJO-ARQDHWQXSA-N 0.000 description 2
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 2
- 229920000161 Locust bean gum Polymers 0.000 description 2
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 2
- 239000004283 Sodium sorbate Substances 0.000 description 2
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 2
- 229930006000 Sucrose Natural products 0.000 description 2
- 240000008042 Zea mays Species 0.000 description 2
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 2
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- 238000013459 approach Methods 0.000 description 2
- 235000010244 calcium sorbate Nutrition 0.000 description 2
- 239000004303 calcium sorbate Substances 0.000 description 2
- 239000004202 carbamide Substances 0.000 description 2
- 239000001768 carboxy methyl cellulose Substances 0.000 description 2
- 235000010418 carrageenan Nutrition 0.000 description 2
- 239000000679 carrageenan Substances 0.000 description 2
- 229920001525 carrageenan Polymers 0.000 description 2
- 238000004040 coloring Methods 0.000 description 2
- 235000005822 corn Nutrition 0.000 description 2
- 235000013365 dairy product Nutrition 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 238000004945 emulsification Methods 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 238000007710 freezing Methods 0.000 description 2
- 230000008014 freezing Effects 0.000 description 2
- 229960001031 glucose Drugs 0.000 description 2
- 239000008103 glucose Substances 0.000 description 2
- 235000010417 guar gum Nutrition 0.000 description 2
- 239000000665 guar gum Substances 0.000 description 2
- 235000010420 locust bean gum Nutrition 0.000 description 2
- 239000000711 locust bean gum Substances 0.000 description 2
- 230000002906 microbiologic effect Effects 0.000 description 2
- 238000009928 pasteurization Methods 0.000 description 2
- 239000001814 pectin Substances 0.000 description 2
- 235000010987 pectin Nutrition 0.000 description 2
- 229920001277 pectin Polymers 0.000 description 2
- 239000012071 phase Substances 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 235000019250 sodium sorbate Nutrition 0.000 description 2
- 239000005720 sucrose Substances 0.000 description 2
- 235000010491 tara gum Nutrition 0.000 description 2
- 239000000213 tara gum Substances 0.000 description 2
- 235000019871 vegetable fat Nutrition 0.000 description 2
- 235000010493 xanthan gum Nutrition 0.000 description 2
- 239000000230 xanthan gum Substances 0.000 description 2
- 229920001285 xanthan gum Polymers 0.000 description 2
- HDTRYLNUVZCQOY-UHFFFAOYSA-N α-D-glucopyranosyl-α-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OC1C(O)C(O)C(O)C(CO)O1 HDTRYLNUVZCQOY-UHFFFAOYSA-N 0.000 description 1
- SPFMQWBKVUQXJV-BTVCFUMJSA-N (2r,3s,4r,5r)-2,3,4,5,6-pentahydroxyhexanal;hydrate Chemical compound O.OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C=O SPFMQWBKVUQXJV-BTVCFUMJSA-N 0.000 description 1
- GUBGYTABKSRVRQ-XLOQQCSPSA-N Alpha-Lactose Chemical compound O[C@@H]1[C@@H](O)[C@@H](O)[C@@H](CO)O[C@H]1O[C@@H]1[C@@H](CO)O[C@H](O)[C@H](O)[C@H]1O GUBGYTABKSRVRQ-XLOQQCSPSA-N 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- WQZGKKKJIJFFOK-QTVWNMPRSA-N D-mannopyranose Chemical compound OC[C@H]1OC(O)[C@@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-QTVWNMPRSA-N 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 229920002907 Guar gum Polymers 0.000 description 1
- GUBGYTABKSRVRQ-QKKXKWKRSA-N Lactose Natural products OC[C@H]1O[C@@H](O[C@H]2[C@H](O)[C@@H](O)C(O)O[C@@H]2CO)[C@H](O)[C@@H](O)[C@H]1O GUBGYTABKSRVRQ-QKKXKWKRSA-N 0.000 description 1
- 102000014171 Milk Proteins Human genes 0.000 description 1
- 108010011756 Milk Proteins Proteins 0.000 description 1
- 235000019482 Palm oil Nutrition 0.000 description 1
- 108010064851 Plant Proteins Proteins 0.000 description 1
- MUPFEKGTMRGPLJ-RMMQSMQOSA-N Raffinose Natural products O(C[C@H]1[C@@H](O)[C@H](O)[C@@H](O)[C@@H](O[C@@]2(CO)[C@H](O)[C@@H](O)[C@@H](CO)O2)O1)[C@@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 MUPFEKGTMRGPLJ-RMMQSMQOSA-N 0.000 description 1
- 240000004808 Saccharomyces cerevisiae Species 0.000 description 1
- HDTRYLNUVZCQOY-WSWWMNSNSA-N Trehalose Natural products O[C@@H]1[C@@H](O)[C@@H](O)[C@@H](CO)O[C@@H]1O[C@@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 HDTRYLNUVZCQOY-WSWWMNSNSA-N 0.000 description 1
- MUPFEKGTMRGPLJ-UHFFFAOYSA-N UNPD196149 Natural products OC1C(O)C(CO)OC1(CO)OC1C(O)C(O)C(O)C(COC2C(C(O)C(O)C(CO)O2)O)O1 MUPFEKGTMRGPLJ-UHFFFAOYSA-N 0.000 description 1
- 108010046377 Whey Proteins Proteins 0.000 description 1
- 102000007544 Whey Proteins Human genes 0.000 description 1
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 235000010443 alginic acid Nutrition 0.000 description 1
- 229920000615 alginic acid Polymers 0.000 description 1
- HDTRYLNUVZCQOY-LIZSDCNHSA-N alpha,alpha-trehalose Chemical compound O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@@H]1O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 HDTRYLNUVZCQOY-LIZSDCNHSA-N 0.000 description 1
- WQZGKKKJIJFFOK-PHYPRBDBSA-N alpha-D-galactose Chemical compound OC[C@H]1O[C@H](O)[C@H](O)[C@@H](O)[C@H]1O WQZGKKKJIJFFOK-PHYPRBDBSA-N 0.000 description 1
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 235000014121 butter Nutrition 0.000 description 1
- MCFVRESNTICQSJ-RJNTXXOISA-L calcium sorbate Chemical compound [Ca+2].C\C=C\C=C\C([O-])=O.C\C=C\C=C\C([O-])=O MCFVRESNTICQSJ-RJNTXXOISA-L 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 229940113118 carrageenan Drugs 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 230000000368 destabilizing effect Effects 0.000 description 1
- 229960000673 dextrose monohydrate Drugs 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 229930182830 galactose Natural products 0.000 description 1
- 150000004676 glycans Chemical class 0.000 description 1
- 229960002154 guar gum Drugs 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000003384 imaging method Methods 0.000 description 1
- 230000002452 interceptive effect Effects 0.000 description 1
- 239000008101 lactose Substances 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000011169 microbiological contamination Methods 0.000 description 1
- 235000021239 milk protein Nutrition 0.000 description 1
- 239000001788 mono and diglycerides of fatty acids Substances 0.000 description 1
- 239000003346 palm kernel oil Substances 0.000 description 1
- 235000019865 palm kernel oil Nutrition 0.000 description 1
- 239000002540 palm oil Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 235000021118 plant-derived protein Nutrition 0.000 description 1
- 229920001282 polysaccharide Polymers 0.000 description 1
- 239000005017 polysaccharide Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000000770 propane-1,2-diol alginate Substances 0.000 description 1
- 238000005086 pumping Methods 0.000 description 1
- MUPFEKGTMRGPLJ-ZQSKZDJDSA-N raffinose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO[C@@H]2[C@@H]([C@@H](O)[C@@H](O)[C@@H](CO)O2)O)O1 MUPFEKGTMRGPLJ-ZQSKZDJDSA-N 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 238000010008 shearing Methods 0.000 description 1
- 235000020183 skimmed milk Nutrition 0.000 description 1
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 description 1
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 description 1
- 235000019333 sodium laurylsulphate Nutrition 0.000 description 1
- LROWVYNUWKVTCU-STWYSWDKSA-M sodium sorbate Chemical compound [Na+].C\C=C\C=C\C([O-])=O LROWVYNUWKVTCU-STWYSWDKSA-M 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000000527 sonication Methods 0.000 description 1
- 238000011064 split stream procedure Methods 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 239000003981 vehicle Substances 0.000 description 1
- 238000010947 wet-dispersion method Methods 0.000 description 1
- 235000021119 whey protein Nutrition 0.000 description 1
- 229940082509 xanthan gum Drugs 0.000 description 1
- UHVMMEOXYDMDKI-JKYCWFKZSA-L zinc;1-(5-cyanopyridin-2-yl)-3-[(1s,2s)-2-(6-fluoro-2-hydroxy-3-propanoylphenyl)cyclopropyl]urea;diacetate Chemical compound [Zn+2].CC([O-])=O.CC([O-])=O.CCC(=O)C1=CC=C(F)C([C@H]2[C@H](C2)NC(=O)NC=2N=CC(=CC=2)C#N)=C1O UHVMMEOXYDMDKI-JKYCWFKZSA-L 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23G—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
- A23G9/00—Frozen sweets, e.g. ice confectionery, ice-cream; Mixtures therefor
- A23G9/04—Production of frozen sweets, e.g. ice-cream
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23G—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
- A23G9/00—Frozen sweets, e.g. ice confectionery, ice-cream; Mixtures therefor
- A23G9/32—Frozen sweets, e.g. ice confectionery, ice-cream; Mixtures therefor characterised by the composition containing organic or inorganic compounds
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23G—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
- A23G9/00—Frozen sweets, e.g. ice confectionery, ice-cream; Mixtures therefor
- A23G9/52—Liquid products; Solid products in the form of powders, flakes or granules for making liquid products ; Finished or semi-finished solid products, frozen granules
Definitions
- the invention relates to concentrated premixes for the manufacture of frozen confections; in particular, to a method for storing such concentrated premixes.
- the concentrated premixes are oil-in water emulsions having a high total solids content.
- the manufacture of frozen confections is an energy intensive process typically involving several stages, namely: mix preparation (which consists of dosing and mixing of the ingredients); pasteurization and homogenization; ageing; freezing and hardening. Each of these stages requires energy.
- the production of frozen confections with sought-after organoleptic properties involves emulsifying the fat in the premix so that it is present in the form of very small droplets. This is typically achieved using homogenization equipment, most commonly a valve-type homogenizer in which the mix is forced through a small valve under high pressure. The usage efficiency of the homogenization equipment is thus a significant contributing factor to the overall energy consumption of the manufacturing process.
- the process described in WO 2016/116336 aims to improve the usage efficiency of homogenization equipment. This is achieved by a split stream process in which an emulsion with a high fat content is prepared, and then subsequently diluted with an adjunct composition and aqueous liquid to form the premix.
- the adjunct composition is granulated with the concentrated emulsion as the binder.
- the granules are said to be much more stable than a liquid emulsion.
- the drying step can introduce unwanted off-flavours.
- the later stages of Maillard reactions include the formation of advanced glycation end products (AGEs) and melanoidins, which cause colour changes, influence sensory properties, and in some cases compromise shelf life.
- AGEs advanced glycation end products
- melanoidins which cause colour changes, influence sensory properties, and in some cases compromise shelf life.
- Formation of AGEs and melanoidins can be significantly enhanced by elevated temperatures (such as those used during sterilization or UHT processing), and they are known to accumulate during long-term storage or during transportation.
- elevated temperatures such as those used during sterilization or UHT processing
- the rate of Maillard reactions may be influenced by several factors including, but not limited to, type of reactants, temperature/time combinations, water activity, and pH.
- the present invention relates to a method for storing a concentrated frozen confection premix, wherein the method comprises storing the concentrated premix in a closed container for a storage period of up to 84 days, wherein the concentrated premix is an oil-in-water emulsion in liquid form, the oil-in-water emulsion comprising: fat in an amount of 8 wt% to 20 wt%; sugars in an amount of 40 wt% to 64 wt%; protein in an amount of 1 .5 wt% to 14 wt%; and water in an amount of 16 wt% to 36 wt%; and wherein the concentrated premix is not subjected to a temperature:
- the present invention relates to a method for storing a concentrated frozen confection premix.
- the concentrated frozen confection premix (which, for the sake of brevity, is referred to herein as “concentrated premix”) is an oil-in-water emulsion in liquid form having a high total solids content.
- the concentrated premix can simply be diluted with an aqueous liquid to produce a premix which contains all the ingredients in the appropriate proportions.
- the premix can be tailored in the dilution step, for example by adding a small quantity of flavouring and/or colouring.
- the concentrated premix is an oil-in-water emulsion comprising fat in an amount of 8 wt% to 20 wt%, sugars in an amount of 40 wt% to 64 wt%, protein in an amount of 1 .5 wt% to 14 wt%; and water in an amount of 16 wt% to 36 wt%.
- the method comprises storing the concentrated premix in a closed container for a storage period of up to 84 days.
- the closed container helps prevent microbiological contamination of the concentrated premix during the storage period.
- the concentrated premix remains stable for the storage period if the temperature is controlled according to the limits of the present invention.
- the storage period is up to 70 days, up to 56 days, up to 42 days, up to 35 days, up to 28 days, or even up to 21 days.
- the storage period is preferably at least 1 day, at least 5 days, at least 7 days, at least 10 days, or even at least 14 days.
- the concentrated premix may be held in one location during the storage period, or it may be transported between locations (e.g. from production factory to finishing factory) for at least part of the storage period.
- the concentrated premix is not subjected to a temperature exceeding 37°C for more than 3 days during the storage period.
- the concentrated premix is not subjected to a temperature exceeding 37°C for more than 2 days during the storage period, more preferably the concentrated premix is not subjected to a temperature exceeding 37°C for more than 1 day during the storage period.
- the concentrated premix is not subjected to a temperature exceeding 35°C for more than 12 days during the storage period. More preferably, the concentrated premix is not subjected to a temperature exceeding 35°C for more than 6 days during the storage period, and most preferably the concentrated premix is not subjected to a temperature exceeding 35°C for more than 3 days during the storage period.
- the concentrated premix is not subjected to a temperature exceeding 30°C for more than 21 days during the storage period. More preferably, the concentrated premix is not subjected to a temperature exceeding 30°C for more than 14 days during the storage period, and most preferably the concentrated premix is not subjected to a temperature exceeding 30°C for more than 7 days during the storage period.
- the concentrated premix is not subjected to a temperature below 6°C for more than 6 days during the storage period.
- the concentrated premix is not subjected to a temperature below 6°C for more than 4 days during the storage period, more preferably the concentrated premix is not subjected to a temperature below 6°C for more than 2 days during the storage period.
- the concentrated premix is not subjected to a temperature below 10°C for more than 28 days during the storage period. More preferably, the concentrated premix is not subjected to a temperature below 10°C for more than 21 days during the storage period, and most preferably the concentrated premix is not subjected to a temperature below 10°C for more than 14 days during the storage period.
- the mean temperature of the concentrated premix averaged over the storage period is from 6°C to 37°C, more preferably from 8°C to 35°C, from 10°C to 30°C, or even from 12°C to 27°C.
- the concentrated premix preferably has a water activity of no more than 0.84, for example from 0.70 to 0.84. Additionally or alternatively, it is preferred that the pH of the concentrated premix is from 5 to 8.
- the concentrated premix only needs to be diluted with an aqueous liquid (such as water) to produce a premix for a frozen confection.
- the concentrated premix comprises fat in amount of 8 wt% to 20 wt%, and preferably comprises fat in an amount of 9 wt% to 19 wt%, 10 wt% to 18 wt%, or even 11 wt% to 17 wt%.
- the fat is preferably dairy fat (such as butter fat) or vegetable fat (such as coconut oil, palm oil, palm kernel oil, or a mixture thereof). It is preferred that the fat is vegetable fat, and particularly preferred that the fat is coconut oil.
- the concentrated premix comprises sugars in an amount of 40 wt% to 64 wt%, and preferably comprises sugars in an amount of 42 wt% to 62 wt%, 44 wt% to 60 wt%, or even 46 wt% to 58 wt%.
- sucrose includes monosaccharides, disaccharides and oligosaccharides (which are formed from 3 to 10 monosaccharide units).
- Monosaccharides include glucose, fructose, galactose and mannose.
- Disaccharides include sucrose, lactose and trehalose.
- Oligosaccharides include raffinose.
- the term “sugars” does not include polysaccharides, which comprise >10 monosaccharides. Some ingredients commonly included in frozen confections may contribute to the amount of sugars.
- corn syrup sometimes called glucose syrup
- oligosaccharides is a mixture of monosaccharides, disaccharides and oligosaccharides.
- the concentrated premix comprises protein in an amount of 1.5 wt% to 14 wt%, and preferably comprises protein in an amount of 1.6 wt% to 12 wt%, 1.7 wt% to 10 wt%, 1.8 wt% to 8 wt%, or even 1.9 wt% to 6 wt%.
- the protein is milk protein or plant protein, or a mixture thereof. If the emulsion becomes too concentrated it may become difficult to handle in subsequent processing, in particular it may become difficult to pump. On the other hand, a low water activity can mean that the concentrated premix has a longer shelf-life.
- the concentrated premix comprises water in an amount of 16 wt% to 36 wt%.
- the concentrated premix comprises water in an amount of at least 17 wt%, at least 18 wt%, or at least 19 wt%.
- the concentrated premix comprises water in an amount of no more than 32 wt%, no more than 29 wt%, no more than 28 wt%, no more than 27 wt%, or even no more than 26 wt%.
- the concentrate premix of the present invention has a high total solids content. The total solids content is the sum of all the ingredients other than water. Since the concentrated premix comprises water in an amount of 16 wt% to 36 wt%, the total solids content of the concentrated premix is 64 wt% to 84 wt%.
- the total solids content of the concentrated premix affects the viscosity, with higher total solids leading to higher viscosity. This can be advantageous, since higher viscosities are associated with better oil droplet breakup.
- the power input required to achieve emulsification of the oil also increases with viscosity, and at very high viscosities there is a risk of the emulsification equipment being overloaded. Therefore, there is a need to balance these competing technical considerations.
- the total solids content of the concentrated premix is at least 68 wt%, at least 71 wt%, at least 72 wt%, at least 73 wt% or at least 74 wt%.
- the total solids content of the premix is no more than 83 wt%, no more than 82 wt%, or no more than 81 wt%.
- the concentrated premix preferably comprises stabilizer in an amount of 0.3 wt% to 3 wt% and/or emulsifier in an amount of 0.1 wt% to 2 wt%.
- the concentrated premix comprises stabilizer in an amount of 0.2 wt% to 2 wt%, 0.4 wt% to 1.5 wt%, or even 0.6 wt% to 1.0 wt%.
- the stabilizer is preferably selected from the group consisting of alginates (E400-E405), carrageenan (E407), locust bean gum (E410), guar gum (E412), xanthan gum (E415), tara gum (E417), pectin (E440), sodium carboxymethyl cellulose (E466), and mixtures thereof.
- the concentrated premix comprises emulsifier in an amount of 0.2 wt% to 1.5 wt%, 0.3 wt% to 1.2 wt%, or even 0.4 wt% to 1.0 wt%. A single emulsifier or a mixture of emulsifiers may be used.
- the concentrated premix of the present invention may be susceptible to microbiological spoilage.
- a common approach to limiting such spoilage is refrigerated storage.
- this is not appropriate for the concentrated premix of the present invention, as it has unexpectedly been found to promote coalescence of oil droplets. Therefore, it may be appropriate to utilise a different approach to inhibit spoilage microorganisms.
- the concentrated premix is preferably subjected to a sanitisation step (such as pasteurisation) prior to storage.
- the method may comprise aseptically dosing the concentrated premix into the container prior to closing the container and storing the concentrated premix for the storage period.
- This step is most likely to be appropriate where a long shelf life is required (i.e. several weeks). However, in practice this step is not usually required. Indeed, it is preferred that, following the sanitisation step, the concentrated premix is dosed into the container before being cooled (typically referred to as “hot filling”).
- the concentrated premix may optionally comprise a preservative. Addition of a preservative may be appropriate if a long shelf life of several weeks is required, and may provide a cheaper and/or more convenient alternative to aeseptic dosing of the concentrated premix.
- the concentrated premix preferably comprises 0.02 wt% to 0.5 wt% preservative, and the preservative is preferably sorbic acid (E200) or a salt thereof. Suitable salts include sodium sorbate (E201), potassium sorbate (E202), and calcium sorbate (E203).
- a successful preservative inhibits spoilage microorganisms without interfering with the sensorial properties of the final frozen confection product.
- the level of preservative in the concentrated premix will not be the level of preservative in the final frozen confection product, since the concentrate premix will be diluted prior to being used to prepare a frozen confection. This means that a relatively high level of preservative can be added to the concentrated premix without compromising the sensorial properties of the final frozen confection. However, it is preferred to keep the level of preservative as low as possible, whilst still including a sufficient amount to inhibit spoilage microorganisms.
- the concentrated premix preferably comprises the preservative in an amount of 0.02 wt% to 0.5 wt%, 0.06 wt% to 0.4 wt%, 0.1 wt% to 0.3 wt%, or even 0.12 wt% to 0.2 wt%.
- the method comprises storing the concentrated premix in a closed container.
- the concentrated premix can be stored in any suitable container.
- Non-limiting examples of potential containers include pouches, tanks, bottles, kegs, barrels, drums, jerry cans, and intermediate bulk containers (IBCs).
- the volume of the container is preferably at least 500 ml, and more preferably 1 L to 2000 L.
- the container is preferably a rigid or flexible intermediate bulk container having a volume of up to 2000 L, preferably from 250 L to 2000 L.
- An advantage of the concentrated premix is that it can be shipped to a remote location during the storage period and then simply diluted with an aqueous liquid (preferably water) at the remote location before being frozen in a conventional manner to produce a high quality frozen confection in a finishing factory.
- an aqueous liquid preferably water
- the container is preferably an intermediate bulk container (preferably having a volume of 250 L to 2000 L) or a tanker truck (preferably having a volume of 10,000 L to 44,000 L).
- Tanker trucks usually comprise a cylindrical tank lying upon the body of the truck in an essentially horizontal manner. The tank will typically comprise multiple compartments and/or baffles to prevent load movement destabilizing the vehicle during transit.
- the tanker truck should be suitable for transporting food-grade material, and will typically be equipped with a pumping system to allow for loading and unloading of the liquid load.
- the concentrated premix may be transported to a retail outlet rather than a factory.
- this scenario may occur where the concentrated premix is for a soft-serve ice cream product.
- Such products are made in a small ice cream freezer, for example in an ice cream van or a cafe, and eaten immediately.
- the container is likely to be smaller, and is preferably a bottle or a pouch with a volume of 500 ml to 50 L, more preferably 500 ml to 10 L, or even 500 ml to 2 L.
- a diluent liquid is added to the concentrated premix at the end of the storage period.
- the diluent liquid is an aqueous liquid, preferably water.
- the ratio of concentrated premix to diluent liquid is preferably 1 :1 to 1:3.
- the dilution step provides a premix which can be frozen to produce a frozen confection.
- the premix can be tailored in the dilution step by adding a small quantity of flavouring and/or colouring.
- Figure 1 is a plot of oil droplet size data from Example 1;
- Figures 2a and 2b are plots of colour change data from Example 1.
- a concentrated premix having the formulation shown in Table 1 was prepared. Briefly, the aqueous phase was prepared by adding hot water (at 80°C) to a mixing vessel, followed by sucrose, stabilizer, corn syrups, fructose, dextrose monohydrate, skimmed milk powder, and whey protein concentrate. The mixer was set at 3000 rpm during aqueous phase ingredient addition, with heating at 60°C to 75°C to ensure complete dissolution/dispersion of the ingredients.
- the oil phase was prepared by melting the coconut oil and combining it with the emulsifier.
- a concentrated oil-in-water emulsion was prepared by adding the oil phase to the aqueous phase and passing the mixture through a rotor-stator mixer set at 4200 rpm. The rotor-stator mixer had a rotor diameter of 0.145 m and a shearing clearance of 0.5 mm. The concentrated premix was pasteurized.
- the concentrated premix was separated into containers, and the containers were sealed. Containers were stored at a constant temperature of 5°C, 20°C, 25°C, 30°C, 35°C, or 40°C, and the trials were run for up to 84 days. Oil droplet coalescence was investigated at 5°C or 20°C over a storage period of up to 28 days. Colour changes were investigated at various storage temperatures (20°C, 30°C, 35°C, 40°C) over a storage period of up to 21 days, with samples being analysed periodically from 3 days storage onwards. In addition, microbiological growth was investigated at 25°C (chosen as being the most favourable temperature for yeast and mould growth); the concentrated premix showed no spoilage due to growth of mould for storage periods up to and including 84 days. Oil droplet size
- Oil droplet size was measured using a Malvern Mastersizer 3000 equipped with a wet dispersion unit to determine surface weighted mean droplet size (Da,2).
- the premix samples were diluted 10-fold in a solution of sodium dodecyl sulphate (SDS) and urea (6.6 M urea, 0.1% SDS, pH 7), and subjected to 1 minute of full power sonication within the dispersion unit prior to the start of particle size measurement.
- SDS sodium dodecyl sulphate
- urea 6.6 M urea, 0.1% SDS, pH 7
- the later stages of Maillard reactions include the formation of advanced glycation end products (AGEs) and melanoidins, which cause colour changes, influence sensory properties, and in some cases compromise shelf life.
- AGEs advanced glycation end products
- melanoidins which cause colour changes, influence sensory properties, and in some cases compromise shelf life.
- LAB colour analysis was used to identify any colour changes which occurred during the storage trials.
- a digital colour imaging system (Digieye, VeriVede) was used to measure colour and appearance of samples. Samples were photographed using a Nikon AF-S Nikor in a VeriVede cabinet under standardised D65 light without UV, with lighting set to diffuse and no internal mirrors. Camera settings were as follows:
- Focus Auto Focus
- Measurement mode Diffuse Mode, d90 diffused
- CIE76 colour values were generated from representative regions of photographs of the samples. Change between CIE76 colour values for sample and reference are reported independently, and used to calculate AE colour change values, which can range from 0 to 100. AE values greater than 1 indicate a perceivable difference in colour between samples.
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Abstract
The invention relates to a method for storing a concentrated frozen confection premix, wherein the concentrated premix is an oil-in-water emulsion in liquid form comprising: fat in an amount of 8 wt% to 20 wt%; sugars in an amount of 40 wt% to 64 wt%; protein in an amount of 1.5 wt% to 14 wt%; and water in an amount of 16 wt% to 36 wt%. The method comprises storing the concentrated premix in a closed container for a storage period of up to 84 days, wherein the concentrated premix is not subjected to a temperature: exceeding 37°C for more than 3 days during the storage period; and below 6°C for more than 6 days during the storage period.
Description
METHOD FOR STORING A CONCENRTATED FROZEN CONFECTION PREMIX
Field of the invention
The invention relates to concentrated premixes for the manufacture of frozen confections; in particular, to a method for storing such concentrated premixes. The concentrated premixes are oil-in water emulsions having a high total solids content.
Background of the invention
The manufacture of frozen confections (such as ice cream) is an energy intensive process typically involving several stages, namely: mix preparation (which consists of dosing and mixing of the ingredients); pasteurization and homogenization; ageing; freezing and hardening. Each of these stages requires energy.
The production of frozen confections with sought-after organoleptic properties involves emulsifying the fat in the premix so that it is present in the form of very small droplets. This is typically achieved using homogenization equipment, most commonly a valve-type homogenizer in which the mix is forced through a small valve under high pressure. The usage efficiency of the homogenization equipment is thus a significant contributing factor to the overall energy consumption of the manufacturing process.
The process described in WO 2016/116336 aims to improve the usage efficiency of homogenization equipment. This is achieved by a split stream process in which an emulsion with a high fat content is prepared, and then subsequently diluted with an adjunct composition and aqueous liquid to form the premix. In order to enable storage for longer periods and/or transport over longer distances, the adjunct composition is granulated with the concentrated emulsion as the binder. The granules are said to be much more stable than a liquid emulsion. However, aside from the energy input required to dry the granules to an appropriate moisture level, the drying step can introduce unwanted off-flavours.
Therefore, it would be desirable to provide a concentrated premix in liquid form - as this would avoid both the energy input associated with producing/drying the granules, and the concomitant production of off-flavours.
Storage of concentrated oil-in water emulsions in liquid form is not straightforward. Firstly, oil droplet coalescence must be controlled, as small oil droplets are necessary to produce the desired organoleptic properties in the final frozen confection. In addition, there is a need to control Maillard reactions. Maillard reactions are known to affect food quality parameters, including organoleptic properties. For certain food products (such as dairy products) the changes ascribed to Maillard reactions are often undesirable - for example, the products of Maillard reactions may be perceived as off-flavours. The later stages of Maillard reactions include the formation of advanced glycation end products (AGEs) and melanoidins, which cause colour changes, influence sensory properties, and in some cases compromise shelf life. Formation of AGEs and melanoidins can be significantly enhanced by elevated temperatures (such as those used during sterilization or UHT processing), and they are known to accumulate during long-term storage or during transportation. Thus, being able to control Maillard reactions during food production and storage is important. The rate of Maillard reactions may be influenced by several factors including, but not limited to, type of reactants, temperature/time combinations, water activity, and pH.
We have found that carefully controlled storage conditions are required to prevent concentrated emulsions becoming unstable. In particular, it is important to control storage temperature over time.
Summary of the invention
The present invention relates to a method for storing a concentrated frozen confection premix, wherein the method comprises storing the concentrated premix in a closed container for a storage period of up to 84 days, wherein the concentrated premix is an oil-in-water emulsion in liquid form, the oil-in-water emulsion comprising: fat in an amount of 8 wt% to 20 wt%; sugars in an amount of 40 wt% to 64 wt%; protein in an amount of 1 .5 wt% to 14 wt%; and water in an amount of 16 wt% to 36 wt%; and wherein the concentrated premix is not subjected to a temperature:
• exceeding 37°C for more than 3 days during the storage period; and
• below 6°C for more than 6 days during the storage period.
Detailed description
The present invention relates to a method for storing a concentrated frozen confection premix. The concentrated frozen confection premix (which, for the sake of brevity, is referred to herein as “concentrated premix”) is an oil-in-water emulsion in liquid form having a high total solids content. The concentrated premix can simply be diluted with an aqueous liquid to produce a premix which contains all the ingredients in the appropriate proportions. Furthermore, the premix can be tailored in the dilution step, for example by adding a small quantity of flavouring and/or colouring.
The concentrated premix is an oil-in-water emulsion comprising fat in an amount of 8 wt% to 20 wt%, sugars in an amount of 40 wt% to 64 wt%, protein in an amount of 1 .5 wt% to 14 wt%; and water in an amount of 16 wt% to 36 wt%.
The method comprises storing the concentrated premix in a closed container for a storage period of up to 84 days. The closed container helps prevent microbiological contamination of the concentrated premix during the storage period. The concentrated premix remains stable for the storage period if the temperature is controlled according to the limits of the present invention. Preferably the storage period is up to 70 days, up to 56 days, up to 42 days, up to 35 days, up to 28 days, or even up to 21 days. The storage period is preferably at least 1 day, at least 5 days, at least 7 days, at least 10 days, or even at least 14 days.
The concentrated premix may be held in one location during the storage period, or it may be transported between locations (e.g. from production factory to finishing factory) for at least part of the storage period.
To prevent Maillard reactions, which can cause unwanted colour changes, and compromise sensory properties, the concentrated premix is not subjected to a temperature exceeding 37°C for more than 3 days during the storage period. Preferably the concentrated premix is not subjected to a temperature exceeding 37°C for more than 2 days during the storage period, more preferably the concentrated premix is not subjected to a temperature exceeding 37°C for more than 1 day during the storage period.
It is preferred that the concentrated premix is not subjected to a temperature exceeding 35°C for more than 12 days during the storage period. More preferably, the concentrated premix is not subjected to a temperature exceeding 35°C for more than 6 days during the storage period, and most preferably the concentrated premix is not subjected to a temperature exceeding 35°C for more than 3 days during the storage period.
It is preferred that the concentrated premix is not subjected to a temperature exceeding 30°C for more than 21 days during the storage period. More preferably, the concentrated premix is not subjected to a temperature exceeding 30°C for more than 14 days during the storage period, and most preferably the concentrated premix is not subjected to a temperature exceeding 30°C for more than 7 days during the storage period.
We have surprisingly found that storage of the concentrated premix at low temperatures promotes oil droplet coalescence, which in turn impacts the organoleptic properties of the final frozen confection. In order to limit oil droplet coalescence, the concentrated premix is not subjected to a temperature below 6°C for more than 6 days during the storage period. Preferably the concentrated premix is not subjected to a temperature below 6°C for more than 4 days during the storage period, more preferably the concentrated premix is not subjected to a temperature below 6°C for more than 2 days during the storage period.
It is preferred that the concentrated premix is not subjected to a temperature below 10°C for more than 28 days during the storage period. More preferably, the concentrated premix is not subjected to a temperature below 10°C for more than 21 days during the storage period, and most preferably the concentrated premix is not subjected to a temperature below 10°C for more than 14 days during the storage period.
Preferably the mean temperature of the concentrated premix averaged over the storage period is from 6°C to 37°C, more preferably from 8°C to 35°C, from 10°C to 30°C, or even from 12°C to 27°C.
In order to further control the extent of Maillard reactions and/or inhibit growth of microorganisms, the concentrated premix preferably has a water activity of no more than
0.84, for example from 0.70 to 0.84. Additionally or alternatively, it is preferred that the pH of the concentrated premix is from 5 to 8.
The concentrated premix only needs to be diluted with an aqueous liquid (such as water) to produce a premix for a frozen confection. As such, the concentrated premix comprises fat in amount of 8 wt% to 20 wt%, and preferably comprises fat in an amount of 9 wt% to 19 wt%, 10 wt% to 18 wt%, or even 11 wt% to 17 wt%. The fat is preferably dairy fat (such as butter fat) or vegetable fat (such as coconut oil, palm oil, palm kernel oil, or a mixture thereof). It is preferred that the fat is vegetable fat, and particularly preferred that the fat is coconut oil.
High concentrations of sugars may contribute unwanted sweetness and/or calories to the frozen confection that is ultimately prepared from the concentrated premix (following dilution and freezing). Conversely, low concentrations of sugars may be inappropriate if the frozen confection that is ultimately prepared from the concentrated premix is a scoopable product, since low concentrations of sugars tend to result in a frozen confection with a high ice content. Therefore, the concentrated premix comprises sugars in an amount of 40 wt% to 64 wt%, and preferably comprises sugars in an amount of 42 wt% to 62 wt%, 44 wt% to 60 wt%, or even 46 wt% to 58 wt%. As used herein the term “sugars” includes monosaccharides, disaccharides and oligosaccharides (which are formed from 3 to 10 monosaccharide units). Monosaccharides include glucose, fructose, galactose and mannose. Disaccharides include sucrose, lactose and trehalose. Oligosaccharides include raffinose. The term “sugars” does not include polysaccharides, which comprise >10 monosaccharides. Some ingredients commonly included in frozen confections may contribute to the amount of sugars. An example is corn syrup (sometimes called glucose syrup) - which is a mixture of monosaccharides, disaccharides and oligosaccharides.
The concentrated premix comprises protein in an amount of 1.5 wt% to 14 wt%, and preferably comprises protein in an amount of 1.6 wt% to 12 wt%, 1.7 wt% to 10 wt%, 1.8 wt% to 8 wt%, or even 1.9 wt% to 6 wt%. Preferably the protein is milk protein or plant protein, or a mixture thereof.
If the emulsion becomes too concentrated it may become difficult to handle in subsequent processing, in particular it may become difficult to pump. On the other hand, a low water activity can mean that the concentrated premix has a longer shelf-life. The concentrated premix comprises water in an amount of 16 wt% to 36 wt%. Preferably the concentrated premix comprises water in an amount of at least 17 wt%, at least 18 wt%, or at least 19 wt%. Preferably the concentrated premix comprises water in an amount of no more than 32 wt%, no more than 29 wt%, no more than 28 wt%, no more than 27 wt%, or even no more than 26 wt%. The concentrate premix of the present invention has a high total solids content. The total solids content is the sum of all the ingredients other than water. Since the concentrated premix comprises water in an amount of 16 wt% to 36 wt%, the total solids content of the concentrated premix is 64 wt% to 84 wt%. The total solids content of the concentrated premix affects the viscosity, with higher total solids leading to higher viscosity. This can be advantageous, since higher viscosities are associated with better oil droplet breakup. However, the power input required to achieve emulsification of the oil also increases with viscosity, and at very high viscosities there is a risk of the emulsification equipment being overloaded. Therefore, there is a need to balance these competing technical considerations. Preferably the total solids content of the concentrated premix is at least 68 wt%, at least 71 wt%, at least 72 wt%, at least 73 wt% or at least 74 wt%. Preferably the total solids content of the premix is no more than 83 wt%, no more than 82 wt%, or no more than 81 wt%.
The concentrated premix preferably comprises stabilizer in an amount of 0.3 wt% to 3 wt% and/or emulsifier in an amount of 0.1 wt% to 2 wt%. Preferably the concentrated premix comprises stabilizer in an amount of 0.2 wt% to 2 wt%, 0.4 wt% to 1.5 wt%, or even 0.6 wt% to 1.0 wt%. The stabilizer is preferably selected from the group consisting of alginates (E400-E405), carrageenan (E407), locust bean gum (E410), guar gum (E412), xanthan gum (E415), tara gum (E417), pectin (E440), sodium carboxymethyl cellulose (E466), and mixtures thereof. Preferably the concentrated premix comprises emulsifier in an amount of 0.2 wt% to 1.5 wt%, 0.3 wt% to 1.2 wt%, or even 0.4 wt% to 1.0 wt%. A single emulsifier or a mixture of emulsifiers may be used. For example, mono-/diglycerides (E471), which are commonly used as emulsifiers in frozen confections.
The concentrated premix of the present invention may be susceptible to microbiological spoilage. A common approach to limiting such spoilage is refrigerated storage. However, this is not appropriate for the concentrated premix of the present invention, as it has unexpectedly been found to promote coalescence of oil droplets. Therefore, it may be appropriate to utilise a different approach to inhibit spoilage microorganisms. As such, the concentrated premix is preferably subjected to a sanitisation step (such as pasteurisation) prior to storage. Following such a sanitisation step, the method may comprise aseptically dosing the concentrated premix into the container prior to closing the container and storing the concentrated premix for the storage period. This step is most likely to be appropriate where a long shelf life is required (i.e. several weeks). However, in practice this step is not usually required. Indeed, it is preferred that, following the sanitisation step, the concentrated premix is dosed into the container before being cooled (typically referred to as “hot filling”).
The concentrated premix may optionally comprise a preservative. Addition of a preservative may be appropriate if a long shelf life of several weeks is required, and may provide a cheaper and/or more convenient alternative to aeseptic dosing of the concentrated premix. The concentrated premix preferably comprises 0.02 wt% to 0.5 wt% preservative, and the preservative is preferably sorbic acid (E200) or a salt thereof. Suitable salts include sodium sorbate (E201), potassium sorbate (E202), and calcium sorbate (E203). A successful preservative inhibits spoilage microorganisms without interfering with the sensorial properties of the final frozen confection product. It should be noted that the level of preservative in the concentrated premix will not be the level of preservative in the final frozen confection product, since the concentrate premix will be diluted prior to being used to prepare a frozen confection. This means that a relatively high level of preservative can be added to the concentrated premix without compromising the sensorial properties of the final frozen confection. However, it is preferred to keep the level of preservative as low as possible, whilst still including a sufficient amount to inhibit spoilage microorganisms. Thus, the concentrated premix preferably comprises the preservative in an amount of 0.02 wt% to 0.5 wt%, 0.06 wt% to 0.4 wt%, 0.1 wt% to 0.3 wt%, or even 0.12 wt% to 0.2 wt%.
The method comprises storing the concentrated premix in a closed container. The concentrated premix can be stored in any suitable container. Non-limiting examples of potential containers include pouches, tanks, bottles, kegs, barrels, drums, jerry cans, and intermediate bulk containers (IBCs). The volume of the container is preferably at least 500 ml, and more preferably 1 L to 2000 L. In particular, the container is preferably a rigid or flexible intermediate bulk container having a volume of up to 2000 L, preferably from 250 L to 2000 L.
An advantage of the concentrated premix is that it can be shipped to a remote location during the storage period and then simply diluted with an aqueous liquid (preferably water) at the remote location before being frozen in a conventional manner to produce a high quality frozen confection in a finishing factory. This means that the finishing factory does not need to be equipped with a mix plant capable of handling and blending multiple ingredients.
In circumstances where the concentrated premix will be transported between locations (e.g. from a hub factory to a finishing factory), the container is preferably an intermediate bulk container (preferably having a volume of 250 L to 2000 L) or a tanker truck (preferably having a volume of 10,000 L to 44,000 L). Tanker trucks usually comprise a cylindrical tank lying upon the body of the truck in an essentially horizontal manner. The tank will typically comprise multiple compartments and/or baffles to prevent load movement destabilizing the vehicle during transit. The tanker truck should be suitable for transporting food-grade material, and will typically be equipped with a pumping system to allow for loading and unloading of the liquid load.
It is also envisaged that the concentrated premix may be transported to a retail outlet rather than a factory. For example, this scenario may occur where the concentrated premix is for a soft-serve ice cream product. Such products are made in a small ice cream freezer, for example in an ice cream van or a cafe, and eaten immediately. As such, the container is likely to be smaller, and is preferably a bottle or a pouch with a volume of 500 ml to 50 L, more preferably 500 ml to 10 L, or even 500 ml to 2 L.
It is preferred that a diluent liquid is added to the concentrated premix at the end of the storage period. The diluent liquid is an aqueous liquid, preferably water. The ratio of concentrated premix to diluent liquid is preferably 1 :1 to 1:3.
The dilution step provides a premix which can be frozen to produce a frozen confection. The premix can be tailored in the dilution step by adding a small quantity of flavouring and/or colouring.
Unless otherwise specified, numerical ranges expressed in the format "from x to y" are understood to include x and y, and in specifying any range of values or amounts, any particular upper value or amount can be associated with any particular lower value or amount.
Except in the examples and comparative experiments, or where otherwise explicitly indicated, all numbers are to be understood as modified by the word “about”. As used herein, the indefinite article “a” or “an” and its corresponding definite article “the” means at least one, or one or more, unless specified otherwise.
Figures
By way of example, the present invention is illustrated with reference to the following figures, in which:
Figure 1 is a plot of oil droplet size data from Example 1;
Figures 2a and 2b are plots of colour change data from Example 1.
Examples
The examples are intended to illustrate the invention and are not intended to limit the invention to those examples perse.
Example 1
Preparation of a concentrated premix
A concentrated premix having the formulation shown in Table 1 was prepared. Briefly, the aqueous phase was prepared by adding hot water (at 80°C) to a mixing vessel, followed by sucrose, stabilizer, corn syrups, fructose, dextrose monohydrate, skimmed
milk powder, and whey protein concentrate. The mixer was set at 3000 rpm during aqueous phase ingredient addition, with heating at 60°C to 75°C to ensure complete dissolution/dispersion of the ingredients. The oil phase was prepared by melting the coconut oil and combining it with the emulsifier. A concentrated oil-in-water emulsion was prepared by adding the oil phase to the aqueous phase and passing the mixture through a rotor-stator mixer set at 4200 rpm. The rotor-stator mixer had a rotor diameter of 0.145 m and a shearing clearance of 0.5 mm. The concentrated premix was pasteurized.
Storage trials
The concentrated premix was separated into containers, and the containers were sealed. Containers were stored at a constant temperature of 5°C, 20°C, 25°C, 30°C, 35°C, or 40°C, and the trials were run for up to 84 days. Oil droplet coalescence was investigated at 5°C or 20°C over a storage period of up to 28 days. Colour changes were investigated at various storage temperatures (20°C, 30°C, 35°C, 40°C) over a storage period of up to 21 days, with samples being analysed periodically from 3 days storage onwards. In addition, microbiological growth was investigated at 25°C (chosen as being the most favourable temperature for yeast and mould growth); the concentrated premix showed no spoilage due to growth of mould for storage periods up to and including 84 days.
Oil droplet size
The effect of the storage trials on oil droplet size was determined. Oil droplet size was measured using a Malvern Mastersizer 3000 equipped with a wet dispersion unit to determine surface weighted mean droplet size (Da,2). The premix samples were diluted 10-fold in a solution of sodium dodecyl sulphate (SDS) and urea (6.6 M urea, 0.1% SDS, pH 7), and subjected to 1 minute of full power sonication within the dispersion unit prior to the start of particle size measurement. This treatment ensures that any weakly bound or flocculated oil droplets are separated into individual oil droplets to give a more accurate representation of the oil droplet size (such treatment cannot break up fully coalesced or aggregated oil droplets).
The effect of storage temperature over time on oil droplet size is shown by the data in Figure 1 , with the dashed line representing storage at 20°C and the solid line representing storage at 5°C. The results show that oil droplet size remains constant (at less than 1 pm) when the concentrated premix is stored at 20°C. In contrast, storage at 5°C leads to a marked increase in droplet size over time, indicating coarsening of the emulsion. Although not included in Figure 1 , the oil droplet size remains constant for significantly longer than 15 days when the concentrated premix is stored at 20°C (i.e. for a storage period of at least 28 days).
Colour analysis
The later stages of Maillard reactions include the formation of advanced glycation end products (AGEs) and melanoidins, which cause colour changes, influence sensory properties, and in some cases compromise shelf life. In order to assess the effect of Maillard reactions on the concentrated premix, LAB colour analysis was used to identify any colour changes which occurred during the storage trials.
A digital colour imaging system (Digieye, VeriVede) was used to measure colour and appearance of samples. Samples were photographed using a Nikon AF-S Nikor in a VeriVede cabinet under standardised D65 light without UV, with lighting set to diffuse and no internal mirrors. Camera settings were as follows:
Camera zoom: 35 mm,
Focus: Auto Focus,
Measurement mode: Diffuse Mode, d90 diffused,
Chart type: Digitizer Chart V3.94,
Aperture: 8,
Shutter: 1/6.
Calibration Wizard was run before measurements were taken to ensure consistent calibration (maximum <10, median <1 , RGB values = 210 ± 10). CIE76 colour values were generated from representative regions of photographs of the samples. Change between CIE76 colour values for sample and reference are reported independently, and used to calculate AE colour change values, which can range from 0 to 100. AE values greater than 1 indicate a perceivable difference in colour between samples.
The data in Figures 2a and 2b show the colour changes that occurred over time at storage temperatures of 20°C, 30°C, 35°C, and 40°C for two different storage trials. In both cases, samples stored at a temperature of 20°C show almost no change in colour over time. In contrast, samples stored at a temperature of 40°C show significant colour change - even after very short periods of time.
Claims
1 . A method for storing a concentrated frozen confection premix, wherein the method comprises storing the concentrated premix in a closed container for a storage period of up to 84 days, wherein the concentrated premix is an oil-in-water emulsion in liquid form, the oil- in-water emulsion comprising: fat in an amount of 8 wt% to 20 wt%; sugars in an amount of 40 wt% to 64 wt%; protein in an amount of 1.5 wt% to 14 wt%; and water in an amount of 16 wt% to 36 wt%; and wherein the concentrated premix is not subjected to a temperature:
• exceeding 37°C for more than 3 days during the storage period; and
• below 6°C for more than 6 days during the storage period.
2. The method as claimed in claim 1 wherein the concentrated premix is not subjected to a temperature exceeding 35°C for more than 12 days during the storage period.
3. The method as claimed in claim 1 or claim 2 wherein concentrated premix is not subjected to a temperature exceeding 30°C for more than 21 days during the storage period.
4. The method as claimed in any one of the claims 1 to 3 wherein the concentrated premix is not subjected to a temperature below 10°C for more than 28 days during the storage period.
5. The method as claimed in any one of claims 1 to 4 wherein the mean temperature of the concentrated premix averaged over the storage period is from 6°C to 37°C.
6. The method as claimed in any one of claims 1 to 5 wherein the concentrated premix has a water activity of no more than 0.84, preferably from 0.70 to 0.84.
7. The method as claimed in any one of claims 1 to 6 wherein the pH of the concentrated premix is from 5 to 8.
The method as claimed in any one of claims 1 to 7 wherein the concentrated premix comprises stabilizer in an amount of 0.3 wt% to 3 wt% and/or emulsifier in an amount of 0.1 wt% to 2 wt%. The method as claimed in any one of claims 1 to 8 wherein the concentrated premix comprises 0.02 wt% to 0.5 wt% preservative, and the preservative is preferably sorbic acid or potassium sorbate. The method as claimed in any one of claims 1 to 9 wherein the concentrated premix is subjected to a sanitisation step prior to storage. The method as claimed in claim 10 wherein the method comprises aseptically dosing the concentrated premix into the container prior to closing the container and storing the concentrated premix for the storage period. The method as claimed in any one of claims 1 to 11 wherein the volume of the container is at least 500 ml, and preferably 1 L to 2000 L. The method as claimed in any one of claims 1 to 12 wherein the container is a rigid or flexible intermediate bulk container having a volume of up to 2000 L, and preferably from 250 L to 2000 L. The method as claimed in any one of claims 1 to 13 wherein a diluent liquid is added to the concentrated premix at the end of the storage period. The method as claimed in claim 14 wherein the ratio of concentrated premix to diluent liquid is 1 :1 to 1 :3.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
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EP22198204.4 | 2022-09-27 | ||
EP22198204 | 2022-09-27 |
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WO2024068116A1 true WO2024068116A1 (en) | 2024-04-04 |
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Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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PCT/EP2023/072059 WO2024068116A1 (en) | 2022-09-27 | 2023-08-09 | Method for storing a concentrated frozen confection premix |
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Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
ZA9810254B (en) * | 1998-11-10 | 1999-08-25 | Moshe Trop | Ice cream mix and method of manufacture |
EP1415542A1 (en) * | 2002-11-04 | 2004-05-06 | Campina B.V. | Ice-cream dessert material and method for the preparation thereof |
WO2016116336A1 (en) | 2015-01-20 | 2016-07-28 | Unilever Plc | Frozen confection manufacture |
WO2017125213A1 (en) * | 2016-01-18 | 2017-07-27 | Unilever N.V. | Aqueous composition in liquid form for quiescent freezing |
EP3727011A1 (en) * | 2017-12-22 | 2020-10-28 | Unilever PLC | Aerated frozen confection |
-
2023
- 2023-08-09 WO PCT/EP2023/072059 patent/WO2024068116A1/en unknown
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
ZA9810254B (en) * | 1998-11-10 | 1999-08-25 | Moshe Trop | Ice cream mix and method of manufacture |
EP1415542A1 (en) * | 2002-11-04 | 2004-05-06 | Campina B.V. | Ice-cream dessert material and method for the preparation thereof |
WO2016116336A1 (en) | 2015-01-20 | 2016-07-28 | Unilever Plc | Frozen confection manufacture |
WO2017125213A1 (en) * | 2016-01-18 | 2017-07-27 | Unilever N.V. | Aqueous composition in liquid form for quiescent freezing |
EP3727011A1 (en) * | 2017-12-22 | 2020-10-28 | Unilever PLC | Aerated frozen confection |
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