WO2024040762A1 - Production method for high-nickel medium-thick steel plate for low-temperature service - Google Patents
Production method for high-nickel medium-thick steel plate for low-temperature service Download PDFInfo
- Publication number
- WO2024040762A1 WO2024040762A1 PCT/CN2022/132527 CN2022132527W WO2024040762A1 WO 2024040762 A1 WO2024040762 A1 WO 2024040762A1 CN 2022132527 W CN2022132527 W CN 2022132527W WO 2024040762 A1 WO2024040762 A1 WO 2024040762A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- temperature
- rolling
- controlled
- steel plate
- steel
- Prior art date
Links
- 229910000831 Steel Inorganic materials 0.000 title claims abstract description 63
- 239000010959 steel Substances 0.000 title claims abstract description 63
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 title claims abstract description 30
- 229910052759 nickel Inorganic materials 0.000 title claims abstract description 22
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 14
- 238000005096 rolling process Methods 0.000 claims abstract description 51
- 238000010438 heat treatment Methods 0.000 claims abstract description 49
- 238000001816 cooling Methods 0.000 claims abstract description 26
- 238000000034 method Methods 0.000 claims abstract description 20
- 238000009749 continuous casting Methods 0.000 claims abstract description 13
- 238000003723 Smelting Methods 0.000 claims abstract description 10
- 239000012535 impurity Substances 0.000 claims abstract description 6
- 238000004381 surface treatment Methods 0.000 claims abstract description 6
- 230000000171 quenching effect Effects 0.000 claims description 21
- 238000010791 quenching Methods 0.000 claims description 20
- 229910052698 phosphorus Inorganic materials 0.000 claims description 17
- 239000011248 coating agent Substances 0.000 claims description 16
- 238000000576 coating method Methods 0.000 claims description 16
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 13
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 12
- 239000011574 phosphorus Substances 0.000 claims description 12
- 229910052760 oxygen Inorganic materials 0.000 claims description 10
- 238000005496 tempering Methods 0.000 claims description 8
- 229910052717 sulfur Inorganic materials 0.000 claims description 6
- 230000009466 transformation Effects 0.000 claims description 6
- 229910000859 α-Fe Inorganic materials 0.000 claims description 6
- 229910052787 antimony Inorganic materials 0.000 claims description 5
- 239000007864 aqueous solution Substances 0.000 claims description 5
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 5
- 229910001566 austenite Inorganic materials 0.000 claims description 5
- 238000005422 blasting Methods 0.000 claims description 5
- 229910052796 boron Inorganic materials 0.000 claims description 5
- 229910052739 hydrogen Inorganic materials 0.000 claims description 5
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims description 5
- 229910052757 nitrogen Inorganic materials 0.000 claims description 5
- 230000003647 oxidation Effects 0.000 claims description 5
- 238000007254 oxidation reaction Methods 0.000 claims description 5
- 239000001301 oxygen Substances 0.000 claims description 5
- 238000005266 casting Methods 0.000 claims description 4
- 229910052748 manganese Inorganic materials 0.000 claims description 4
- 230000001681 protective effect Effects 0.000 claims description 4
- 238000009489 vacuum treatment Methods 0.000 claims description 4
- 229910052799 carbon Inorganic materials 0.000 claims description 3
- 229910001563 bainite Inorganic materials 0.000 claims description 2
- 238000005520 cutting process Methods 0.000 claims description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 abstract description 38
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 abstract description 6
- 238000005516 engineering process Methods 0.000 abstract description 5
- 230000008569 process Effects 0.000 description 8
- 150000002500 ions Chemical class 0.000 description 7
- 238000000227 grinding Methods 0.000 description 6
- 230000009286 beneficial effect Effects 0.000 description 5
- 238000004088 simulation Methods 0.000 description 4
- 230000007547 defect Effects 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- 238000005275 alloying Methods 0.000 description 2
- 238000005265 energy consumption Methods 0.000 description 2
- 238000009863 impact test Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- JZQOJFLIJNRDHK-CMDGGOBGSA-N alpha-irone Chemical compound CC1CC=C(C)C(\C=C\C(C)=O)C1(C)C JZQOJFLIJNRDHK-CMDGGOBGSA-N 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000000498 cooling water Substances 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 238000002309 gasification Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 229910001562 pearlite Inorganic materials 0.000 description 1
- 239000010970 precious metal Substances 0.000 description 1
- 231100000241 scar Toxicity 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 238000010583 slow cooling Methods 0.000 description 1
- 239000006104 solid solution Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 238000010301 surface-oxidation reaction Methods 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 238000003466 welding Methods 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/02—Ferrous alloys, e.g. steel alloys containing silicon
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
- C21D8/0205—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips of ferrous alloys
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
- C21D8/0221—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the working steps
- C21D8/0226—Hot rolling
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
- C21D8/0247—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the heat treatment
- C21D8/0263—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the heat treatment following hot rolling
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C33/00—Making ferrous alloys
- C22C33/04—Making ferrous alloys by melting
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/04—Ferrous alloys, e.g. steel alloys containing manganese
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/06—Ferrous alloys, e.g. steel alloys containing aluminium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/08—Ferrous alloys, e.g. steel alloys containing nickel
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/60—Ferrous alloys, e.g. steel alloys containing lead, selenium, tellurium, or antimony, or more than 0.04% by weight of sulfur
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Definitions
- the invention belongs to the field of metallurgical technology and relates to a production method of high-nickel and low-temperature steel medium-thick plates.
- Nickel is an important alloying element in steel materials. It can form infinite solid solution with austenite in steel and is an austenite-forming element. It can reduce the critical cooling rate of supercooled austenite and improve the hardenability of steel.
- the maximum solubility of nickel in ⁇ -iron is about 10%. It is one of the few alloying elements that can toughen ⁇ -Fe and is particularly effective in improving the low-temperature toughness of the steel matrix. Therefore, nickel is often added to low-temperature steel to reduce its ductile-brittle transition temperature. However, nickel is a precious metal, and if the content is too high, it will increase the stickiness of the iron oxide scale on the surface of the steel plate, making it difficult to remove the scale. It can easily cause the iron oxide scale to press in and affect the surface quality of the steel plate.
- the object of the present invention is to provide a method for producing high-nickel low-temperature steel medium-thick plates, which adopts hot-feeding and hot-charging technology and controls the oxide scale on the surface of the slab and steel plate, so that the surface quality of the obtained high-nickel low-temperature steel plate is good, and at the same time, the steel plate It has excellent low-temperature toughness, -100°C Charpy impact absorbed energy ⁇ 60J.
- the surface temperature of the cast slab is controlled to be between 900 and 1000°C and the heating time is ⁇ 30 min; at the same time, the total heating time is controlled to be no less than ( TF -1000-20 ⁇ O R )min but no higher than ( T F -850-20 ⁇ O R )min, where T F is the maximum furnace temperature, controlled at 1250 ⁇ 1300°C, O R is the residual oxygen in the furnace, controlled at 2.5% ⁇ 5.0%;
- Cooling After rolling, use water cooling to accelerate cooling to above A r3 , and then cool to room temperature at a cooling rate not exceeding air cooling; where A r3 is the starting temperature of the transformation of supercooled austenite to ferrite;
- Heat treatment quenching + tempering heat treatment is adopted.
- the quenching temperature is 840 ⁇ 870°C, and the furnace time is not less than 2 times the plate thickness mm ⁇ min/mm; the tempering temperature is 650 ⁇ 670°C, and the furnace time is not less than 2 times. At 2.5 times plate thickness mm ⁇ min/mm.
- the production method of the present invention is set based on:
- the invention controls the key process parameters of smelting, continuous casting, heating, rolling, cooling, surface treatment and heat treatment. On the one hand, it ensures the quality of molten steel and cast slabs and the performance of steel plates. On the other hand, it focuses on controlling the surface oxidation of cast slabs and steel plates. Iron condition.
- the present invention uses low superheat and controls the drawing speed to reduce the thickness of the iron oxide scale on the surface of the cast slab. If the pulling speed is too low, the thickness of the iron oxide scale will be larger; but if the pulling speed is too high, it will easily cause surface defects in the high-nickel steel cast slab.
- the present invention performs surface quenching on the cast slab to form a large temperature difference between the surface and the core, causing greater stress on the surface of the cast slab, and uses small water pressure to allow the surface quenching process to be exposed to surface tensile stress for a longer period of time.
- the aqueous solution of Cl and S ions makes the initial iron oxide scale on the surface of the cast slab more likely to break and reduces its adhesion; then the surface temperature of the cast slab after quenching is controlled below B s to allow the surface to recover during the air cooling process after quenching.
- the diffusion of Ni element from ⁇ -Fe to the internal unphased ⁇ -Fe can occur, so that the outer layer of iron oxide scale formed on the surface of the cast slab after heating has a lower Ni content, which is more loose and easy to remove.
- the heating process of the present invention mainly considers that when the heating temperature is high, the adhesion of the iron oxide scale is enhanced, so a certain heating time and the amount of residual oxygen in the furnace must be guaranteed to increase the amount of iron oxide scale generated, which increases the volume change on the surface.
- the greater stress produced makes the iron oxide scale easy to peel, which is beneficial to its removal; at the same time, controlling the temperature range of 900 to 1000°C, where the surface iron oxide scale is easy to peel, and heating for a long time is also beneficial to the initial growth of the slab before heating.
- Iron oxide scale and the heating process remove the iron oxide scale once.
- the rolling time and rolling temperature are controlled to control the secondary iron oxide scale, and then the quenching effect of cooling water is used and the iron oxide scale is carried out in the pro-eutectoid transformation and eutectoid transformation temperature ranges. Slow cooling improves the peelability of surface oxide scale.
- the invention performs shot blasting and coating treatment on the surface of the steel plate before heat treatment, which can hinder the generation of iron oxide scale during the heat treatment process and finally obtain a finished steel plate with excellent surface quality.
- the steel plate can be used to prevent rust liquid from dripping and painting when it is exposed. It is beneficial to improve the coating life.
- the heat treatment process of the present invention enables the steel plate to obtain fine ferrite and pearlite structures, so that the steel plate has good low-temperature toughness at -100°C.
- the beneficial effects of the present invention (1) The method of the present invention significantly improves the intrusion of iron oxide scale on the surface of high-nickel steel, greatly reducing the steel plate grinding rate. At the same time, the steel plate surface is not easily rusted, which is beneficial to the storage and transportation of the steel plate; ( 2)
- the high-nickel low-temperature steel of the present invention is designed with low carbon and high nickel components, has a low welding cold crack sensitivity index, and contains few impurity elements such as P, S, Sb, B, O, N, and H in the steel, and the steel quality Clean, and delivered in a normalized + tempered state.
- the steel plate has a uniform structure and low internal stress, so that the steel plate has excellent low-temperature toughness, -100°C Charpy impact absorption energy ⁇ 60J, and has good weldability and Formability can be used in the manufacture of low-temperature pressure vessels such as low-temperature washing towers, ammonia synthesis towers, and gasification furnaces; (3)
- the present invention adopts a hot charging and hot-transfer process to ensure the surface quality of the steel plate while reducing energy consumption and improving efficiency. Productivity.
- the key processes and process parameters adopted in the present invention are operable in industrial mass production.
- Figure 1 shows the surface micromorphology of the steel plate in Example 1.
- a production method of high-nickel low-temperature steel medium-thick plate the steel plate thickness is 25mm.
- Heating During the heating process, the heating time when the surface temperature of the slab is between 900 and 1000°C is 40 minutes; the total heating time is 240 minutes, the maximum furnace temperature is 1260°C, and the residual oxygen in the furnace is 2.9% to 3.6%;
- Cooling After rolling, use water cooling to accelerate cooling to 700°C, which is higher than A r3 (A r3 measured in the thermal simulation test is 680°C), and then air cool to room temperature;
- Heat treatment quenching + tempering heat treatment is adopted, the quenching temperature is 860°C, the furnace time is 55min, the tempering temperature is 660°C, and the furnace time is 70min.
- the microscopic morphology of the surface of the steel plate was observed using a scanning electron microscope. As shown in Figure 1, it can be seen that the iron oxide scale on the surface of the steel plate is dense and uniform, and there is no intrusion defect of the iron oxide scale. The surface quality of the steel plate is good.
- Example 1 A standard Charpy V-type impact specimen was taken for an impact test at a temperature of -100°C. The result was 280/243/286J. It can be seen that the steel plate of Example 1 has excellent low temperature toughness.
- Heating During the heating process, the heating time when the surface temperature of the slab is between 900 and 1000°C is 45 minutes; the total heating time is 300 minutes, the maximum furnace temperature is 1280°C, and the residual oxygen in the furnace is 3.0% to 4.0%;
- Cooling After rolling, use water cooling to accelerate cooling to 690°C, which is higher than A r3 (thermal simulation test measured A r3 to be 680°C), and then air-cool for a period of time and then stack the steel plates to cool to room temperature;
- Heat treatment quenching + tempering heat treatment is adopted.
- the quenching temperature is 850°C and the furnace time is 150min.
- the tempering temperature is 660°C and the furnace time is 180min.
- Example 2 A standard Charpy V-type impact specimen was taken for an impact test at a temperature of -100°C. The result was 217/205/211J. It can be seen that the steel plate of Example 2 has excellent low temperature toughness.
Abstract
A production method for a high-nickel medium-thick steel plate for low-temperature service. The steel comprises the following components in percentage by weight: C: 0.05-0.08%; Si≤0.30%; Mn: 0.50-0.80%; P≤0.008%; S≤0.005%; Al: 0.02-0.05%; Ni: 3.0-4.0%; Sb≤0.003%; B≤0.0005%; O≤0.0015%; N≤0.0050%; H≤0.0002%; Cu+Cr+Mo≤0.08%; and Ti+Nb+V≤0.01%, with the balance being Fe and inevitable impurity elements. The key process steps comprise smelting, continuous casting, heating, rolling, cooling, surface treatment and heat treatment. According to the present invention, hot delivery and hot charging technology is used, and by controlling iron oxide scale on the surfaces of a plate blank and a steel plate, the surface quality of the obtained high-nickel steel plate for low-temperature service is good; moreover, the steel plate has excellent low-temperature toughness, and the Charpy impact absorbed energy at -100°C is greater than or equal to 60 J.
Description
本发明属于冶金技术领域，涉及一种高镍低温钢中厚板的生产方法。The invention belongs to the field of metallurgical technology and relates to a production method of high-nickel and low-temperature steel medium-thick plates.
镍是钢铁材料中的重要合金元素，在钢中可以与奥氏体无限固溶，是奥氏体形成元素，能够降低过冷奥氏体的临界冷却速度，提高钢的淬透性。镍在α铁中的最大溶解度约10％，是少数能韧化α-Fe的合金元素，对改善钢基体的低温韧性特别有效。因此，低温钢中常添加镍元素来降低其韧脆转变温度。但镍是贵重金属，且含量过高会增加钢板表面氧化铁皮的粘性，使除鳞去除困难，易造成氧化铁皮压入而影响钢板的表面质量。Nickel is an important alloying element in steel materials. It can form infinite solid solution with austenite in steel and is an austenite-forming element. It can reduce the critical cooling rate of supercooled austenite and improve the hardenability of steel. The maximum solubility of nickel in α-iron is about 10%. It is one of the few alloying elements that can toughen α-Fe and is particularly effective in improving the low-temperature toughness of the steel matrix. Therefore, nickel is often added to low-temperature steel to reduce its ductile-brittle transition temperature. However, nickel is a precious metal, and if the content is too high, it will increase the stickiness of the iron oxide scale on the surface of the steel plate, making it difficult to remove the scale. It can easily cause the iron oxide scale to press in and affect the surface quality of the steel plate.
为改善这一问题，诸多技术提出在加热轧制前对铸坯进行表面修磨和抗高温氧化涂层处理。如中国专利CN114438393A、CN114367537A、CN114525389A等都涉及这些技术的改进问题。但铸坯修磨和涂层多在室温由人工操作，不仅增加人力成本、恶化劳动条件，而且降低生产效率、增加能耗、降低成材率。也有采用机械修磨和自动化喷涂的技术，但不仅需要增设相应设备，使之难以实现，尤其需要带温操作时，而且对有些铸坯，因平直度问题，机械修磨可能会造成条状坑疤类缺陷。为避免这一问题，中国专利CN111571385A采用铸坯预轧处理后再进行机械修磨，然后才进行成品轧制。新问题是，二火成材不仅增加了生产成本，而且延长了生产周期。In order to improve this problem, many technologies propose surface grinding and high-temperature oxidation-resistant coating treatment on the cast slab before heating and rolling. For example, Chinese patents CN114438393A, CN114367537A, CN114525389A, etc. all involve the improvement of these technologies. However, slab grinding and coating are mostly performed manually at room temperature, which not only increases labor costs and worsens working conditions, but also reduces production efficiency, increases energy consumption, and reduces the yield rate. There are also techniques for mechanical grinding and automatic spraying, but not only does it require the addition of corresponding equipment, making it difficult to implement, especially when it requires warm operation, but also for some billets, mechanical grinding may cause strips due to flatness issues. Pit scar type defects. In order to avoid this problem, Chinese patent CN111571385A adopts pre-rolling treatment of the billet and then mechanical grinding before rolling the finished product. The new problem is that the secondary fire not only increases the production cost, but also prolongs the production cycle.
发明内容Contents of the invention
本发明的目的在于提供一种高镍低温钢中厚板的生产方法，采用热送热装技术，通过板坯和钢板表面氧化铁皮的控制，使获得的高镍低温钢板表面质量好，同时钢板具有优异的低温韧性，-100℃夏比冲击吸收功≥60J。The object of the present invention is to provide a method for producing high-nickel low-temperature steel medium-thick plates, which adopts hot-feeding and hot-charging technology and controls the oxide scale on the surface of the slab and steel plate, so that the surface quality of the obtained high-nickel low-temperature steel plate is good, and at the same time, the steel plate It has excellent low-temperature toughness, -100℃ Charpy impact absorbed energy ≥60J.
本发明的技术方案是：The technical solution of the present invention is:
一种高镍低温钢中厚板的生产方法，钢的重量百分组成为C＝0.05％～0.08％、Si≤0.30％、Mn＝0.50％～0.80％、P≤0.008％、S≤0.005％、Al＝0.02％～0.05％、Ni＝3.0％～4.0％、Sb≤0.003％、B≤0.0005％、O≤0.0015％、N≤0.0050％、H≤0.0002％、且Cu+Cr+Mo≤0.08％、Ti+Nb+V≤0.01％，余量为Fe和不可避免的杂质元素；关键工艺步骤包括：A method for producing medium-thick plates of high-nickel and low-temperature steel. The weight percentage of the steel is C=0.05%~0.08%, Si≤0.30%, Mn=0.50%~0.80%, P≤0.008%, S≤0.005%, Al＝0.02%～0.05%, Ni＝3.0%～4.0%, Sb≤0.003%, B≤0.0005%, O≤0.0015%, N≤0.0050%, H≤0.0002%, and Cu+Cr+Mo≤0.08% , Ti+Nb+V≤0.01%, the balance is Fe and inevitable impurity elements; key process steps include:
(1)冶炼：按上述钢的重量百分组成冶炼钢水并真空处理；(1) Smelting: smelting molten steel according to the weight percentage of the above steel and vacuum treatment;
(2)连铸：采用全程保护浇注，控制过热度为10～20℃、拉速为0.8～1.0m/min；连铸坯经切割后置于水冷装置中摆动进行表面淬火，控制水压为1～4kg/cm
2，水溶液中Cl离子含量不低于0.1mol/L、S离子含量不低于0.01mol/L；控制铸坯表面淬火后表面温度低于B
s且与中心的温度差在150℃以上，然后空冷使该温度差缩小至50℃以内再将连铸坯热送热装至步进梁式加热炉中加热；其中B
s为贝氏体转变开始温度；
(2) Continuous casting: Adopt full-process protective casting, control the superheat to 10-20°C, and the pulling speed to 0.8-1.0m/min; after cutting, the continuous casting billet is placed in a water-cooling device to swing for surface quenching, and the water pressure is controlled to 1~4kg/cm 2 , the Cl ion content in the aqueous solution is not less than 0.1mol/L, and the S ion content is not less than 0.01mol/L; control the surface temperature of the slab after quenching to be lower than B s and the temperature difference with the center is within 150℃ or above, and then air cooling to reduce the temperature difference to within 50℃, and then the continuous casting billet is heated in a walking beam heating furnace; where B s is the bainite transformation starting temperature;
(3)加热：加热过程中控制铸坯表面温度介于900～1000℃的加热时间≥30min；同时控制总加热时间不低于(T
F－1000－20×O
R)min但不高于(T
F-850－20×O
R)min，其中T
F为最高炉膛温度，控制为1250～1300℃，O
R为炉内残氧量，控制为2.5％～5.0％；
(3) Heating: During the heating process, the surface temperature of the cast slab is controlled to be between 900 and 1000°C and the heating time is ≥ 30 min; at the same time, the total heating time is controlled to be no less than ( TF -1000-20×O R )min but no higher than ( T F -850-20×O R )min, where T F is the maximum furnace temperature, controlled at 1250~1300℃, O R is the residual oxygen in the furnace, controlled at 2.5%~5.0%;
(4)轧制：铸坯出加热炉后进行初除磷，除磷高压水压力不小于22MPa、除磷速度不高于1.0m/s；然后进行粗轧和精轧的两阶段控制轧制，粗轧和精轧的轧制时间均不大于180s，同时两个轧制阶段间隔时间不大于60s，并控制粗轧结束道次板坯表面温度为950～980℃、精轧结束道次板坯表面温度为750～800℃；(4) Rolling: After the slab comes out of the heating furnace, initial phosphorus removal is carried out. The high-pressure water pressure for phosphorus removal is not less than 22MPa and the phosphorus removal speed is not higher than 1.0m/s; then two-stage controlled rolling of rough rolling and finishing rolling is carried out. , the rolling time of rough rolling and finish rolling is not more than 180s, and the interval between the two rolling stages is not more than 60s, and the surface temperature of the slab at the end of rough rolling is controlled to be 950~980°C, and the surface temperature of the plate at the end of finish rolling is controlled The surface temperature of the billet is 750~800℃;
(5)冷却：轧制后采用水冷加速冷却至A
r3以上，然后以不超过空冷的冷速冷却至室温；其中A
r3为过冷奥氏体向铁素体转变的开始温度；
(5) Cooling: After rolling, use water cooling to accelerate cooling to above A r3 , and then cool to room temperature at a cooling rate not exceeding air cooling; where A r3 is the starting temperature of the transformation of supercooled austenite to ferrite;
(6)表面处理：涂层前对钢板表面进行抛丸处理，抛丸除锈等级不低于Sa2.5；然后喷涂抗高温氧化涂料，涂层厚度为40～100um；(6) Surface treatment: Before coating, the surface of the steel plate is shot blasted, and the shot blasting rust removal grade is not lower than Sa2.5; then the high temperature oxidation resistant coating is sprayed with a coating thickness of 40 to 100um;
(7)热处理：采用淬火+回火热处理，淬火温度为840～870℃，在炉时间不低于2倍板厚mm×min/mm；回火温度为650～670℃，在炉时间不低于2.5倍板厚mm×min/mm。(7) Heat treatment: quenching + tempering heat treatment is adopted. The quenching temperature is 840~870℃, and the furnace time is not less than 2 times the plate thickness mm×min/mm; the tempering temperature is 650~670℃, and the furnace time is not less than 2 times. At 2.5 times plate thickness mm×min/mm.
本发明所述生产方法的设定依据在于：The production method of the present invention is set based on:
本发明控制冶炼、连铸、加热、轧制、冷却、表面处理和热处理的关键工艺参数，一方面确保钢水和铸坯的质量以及钢板的性能，另一方面着重控制铸坯和钢板的表面氧化铁皮状况。本发明采用低过热度并控制拉速以减小铸坯表面氧化铁皮厚度，拉速太低，氧化铁皮厚度较大；但拉速太高又容易使高镍钢铸坯产生表面缺陷。本发明对铸坯进行表面淬火形成表面与心部的大温度差使铸坯表面产生较大应力，并使用小水压，使表面淬火过程有更长时间置于表面拉应力状态下，同时使用含Cl和S离子的水溶液，从而使铸坯表面初始氧化铁皮更容易发生破碎，降低其附着力；然后将铸坯淬火后的表面温度控制在B
s以下，使表面在淬火后的空冷回温过程能发生Ni元素从α-Fe中向内部未相变的γ-Fe中扩散，从而使铸坯加热后表面形成的氧化铁皮外层中Ni含量较低，其更疏松和易被去除。 本发明的加热工艺主要考虑当加热温度较高时，氧化铁皮粘附性增强，所以必须保证一定的加热时间和炉内残氧量，使生成的氧化铁皮增加，这样增大了表面的体积变化而产生较大的应力，又使氧化铁皮容易起皮，有利于去除；同时控制在表面氧化铁皮容易起皮的温度区间900～1000℃有较长时间的加热，也有利于铸坯加热前初生氧化铁皮和加热过程一次氧化铁皮的去除。本发明通过高压力和低速度除鳞干净后，控制轧制时间和轧制温度以控制二次氧化铁皮，然后使用冷却水的急冷作用以及在氧化铁皮先共析转变和共析转变温度区间进行缓冷，使表面氧化铁皮的剥离性得以改善。本发明在钢板热处理前对钢板表面进行抛丸和涂层处理，可以阻碍热处理过程氧化铁皮的生成，最终获得表面质量非常出色的成品钢板，同时对钢板裸露使用时防止锈液流挂和涂漆使用时提高涂层寿命等有利。本发明的热处理工艺使钢板获得细小的铁素体和珠光体组织，从而使钢板在-100℃时具有良好的低温韧性。
The invention controls the key process parameters of smelting, continuous casting, heating, rolling, cooling, surface treatment and heat treatment. On the one hand, it ensures the quality of molten steel and cast slabs and the performance of steel plates. On the other hand, it focuses on controlling the surface oxidation of cast slabs and steel plates. Iron condition. The present invention uses low superheat and controls the drawing speed to reduce the thickness of the iron oxide scale on the surface of the cast slab. If the pulling speed is too low, the thickness of the iron oxide scale will be larger; but if the pulling speed is too high, it will easily cause surface defects in the high-nickel steel cast slab. The present invention performs surface quenching on the cast slab to form a large temperature difference between the surface and the core, causing greater stress on the surface of the cast slab, and uses small water pressure to allow the surface quenching process to be exposed to surface tensile stress for a longer period of time. The aqueous solution of Cl and S ions makes the initial iron oxide scale on the surface of the cast slab more likely to break and reduces its adhesion; then the surface temperature of the cast slab after quenching is controlled below B s to allow the surface to recover during the air cooling process after quenching. The diffusion of Ni element from α-Fe to the internal unphased γ-Fe can occur, so that the outer layer of iron oxide scale formed on the surface of the cast slab after heating has a lower Ni content, which is more loose and easy to remove. The heating process of the present invention mainly considers that when the heating temperature is high, the adhesion of the iron oxide scale is enhanced, so a certain heating time and the amount of residual oxygen in the furnace must be guaranteed to increase the amount of iron oxide scale generated, which increases the volume change on the surface. The greater stress produced makes the iron oxide scale easy to peel, which is beneficial to its removal; at the same time, controlling the temperature range of 900 to 1000°C, where the surface iron oxide scale is easy to peel, and heating for a long time is also beneficial to the initial growth of the slab before heating. Iron oxide scale and the heating process remove the iron oxide scale once. In the present invention, after descaling at high pressure and low speed, the rolling time and rolling temperature are controlled to control the secondary iron oxide scale, and then the quenching effect of cooling water is used and the iron oxide scale is carried out in the pro-eutectoid transformation and eutectoid transformation temperature ranges. Slow cooling improves the peelability of surface oxide scale. The invention performs shot blasting and coating treatment on the surface of the steel plate before heat treatment, which can hinder the generation of iron oxide scale during the heat treatment process and finally obtain a finished steel plate with excellent surface quality. At the same time, the steel plate can be used to prevent rust liquid from dripping and painting when it is exposed. It is beneficial to improve the coating life. The heat treatment process of the present invention enables the steel plate to obtain fine ferrite and pearlite structures, so that the steel plate has good low-temperature toughness at -100°C.
本发明的有益效果：(1)本发明方法对高镍钢表面氧化铁皮压入的改善明显，使钢板修磨率大幅降低，同时钢板表面不容易被锈蚀，有利于钢板的存储和运输；(2)本发明的高镍低温钢采用低碳高镍的成分设计，焊接冷裂纹敏感性指数低，且钢中的P、S、Sb、B、O、N、H等杂质元素少，钢质洁净，同时采用正火+回火的状态交货，钢板组织均匀、内应力低，从而使钢板具有优异的低温韧性，-100℃夏比冲击吸收功≥60J，同时具有良好的可焊性和成型性，可用于低温洗涤塔、氨合成塔、气化炉等低温压力容器的制造；(3)本发明采用热装热送工艺，在保证钢板表面质量的同时，降低了能耗、提高了生产效率。(4)本发明采用的关键工序及工艺参数在工业化大生产中具有可操作性。The beneficial effects of the present invention: (1) The method of the present invention significantly improves the intrusion of iron oxide scale on the surface of high-nickel steel, greatly reducing the steel plate grinding rate. At the same time, the steel plate surface is not easily rusted, which is beneficial to the storage and transportation of the steel plate; ( 2) The high-nickel low-temperature steel of the present invention is designed with low carbon and high nickel components, has a low welding cold crack sensitivity index, and contains few impurity elements such as P, S, Sb, B, O, N, and H in the steel, and the steel quality Clean, and delivered in a normalized + tempered state. The steel plate has a uniform structure and low internal stress, so that the steel plate has excellent low-temperature toughness, -100℃ Charpy impact absorption energy ≥ 60J, and has good weldability and Formability can be used in the manufacture of low-temperature pressure vessels such as low-temperature washing towers, ammonia synthesis towers, and gasification furnaces; (3) The present invention adopts a hot charging and hot-transfer process to ensure the surface quality of the steel plate while reducing energy consumption and improving efficiency. Productivity. (4) The key processes and process parameters adopted in the present invention are operable in industrial mass production.
图1为实施例1钢板的表面微观形貌。Figure 1 shows the surface micromorphology of the steel plate in Example 1.
下面结合实施例及附图进一步说明本发明的内容。The content of the present invention will be further described below in conjunction with the embodiments and drawings.
实施例1：Example 1:
一种高镍低温钢中厚板的生产方法，钢板厚度25mm。钢的重量百分组成为C＝0.07％、Si＝0.20％、Mn＝0.72％、P＝0.006％、S＝0.003％、Al＝0.025％、Ni＝3.55％、Sb＝0.002％、B＝0.0003％、O＝0.0012％、N＝0.0041％、H＝0.00015％、且Cu+Cr+Mo＝0.05％、Ti+Nb+V＝0.006％，余量为Fe和不可避免的杂质元素；关键工艺步骤包括：A production method of high-nickel low-temperature steel medium-thick plate, the steel plate thickness is 25mm. The weight percentage of steel is C=0.07%, Si=0.20%, Mn=0.72%, P=0.006%, S=0.003%, Al=0.025%, Ni=3.55%, Sb=0.002%, B=0.0003% , O=0.0012%, N=0.0041%, H=0.00015%, and Cu+Cr+Mo=0.05%, Ti+Nb+V=0.006%, the balance is Fe and inevitable impurity elements; key process steps include :
(1)冶炼：按上述成分冶炼钢水并真空处理；(1) Smelting: smelting molten steel according to the above composition and vacuum treatment;
(2)连铸：采用全程保护浇注，过热度控制为15℃、拉速为0.95m/min；连铸坯经切割后置于水冷装置中摆动进行表面淬火，控制水压为2kg/cm
2，水溶液中Cl离子含量为0.12mol/L、S离子含量为0.015mol/L；铸坯表面淬火后表面温度为550℃，其低于B
s(其中热模拟试验测得B
s为600℃)并与中心的温度差在150℃以上，然后空冷使铸坯表面回温至750℃，其与中心的温度差缩小至50℃以内，此时再将连铸坯热送热装至步进梁式加热炉中加热；
(2) Continuous casting: full-process protective casting is adopted, the superheat is controlled to 15°C, and the pulling speed is 0.95m/min; after the continuous casting billet is cut, it is placed in a water-cooling device to swing for surface quenching, and the water pressure is controlled to 2kg/cm 2 , the Cl ion content in the aqueous solution is 0.12mol/L, and the S ion content is 0.015mol/L; the surface temperature of the cast slab after quenching is 550°C, which is lower than B s (the thermal simulation test measured B s as 600°C) And the temperature difference with the center is above 150℃, and then the surface of the slab is air-cooled to return to 750℃, and the temperature difference with the center is reduced to within 50℃. At this time, the continuous casting slab is hot-loaded to the walking beam. Heating in type heating furnace;
(3)加热：加热过程中铸坯表面温度介于900～1000℃区间的加热时间为40min；总加热时间为240min，最高炉膛温度为1260℃，炉内残氧量为2.9％～3.6％；(3) Heating: During the heating process, the heating time when the surface temperature of the slab is between 900 and 1000°C is 40 minutes; the total heating time is 240 minutes, the maximum furnace temperature is 1260°C, and the residual oxygen in the furnace is 2.9% to 3.6%;
(4)轧制：铸坯出加热炉后进行初除磷，除磷高压水压力为22MPa、除磷速度为1.0m/s；然后进行粗轧和精轧的两阶段控制轧制，粗轧轧制时间为155s，精轧轧制时间为160s，两个轧制阶段间隔时间为50s，粗轧结束道次板坯表面温度为960℃、精轧结束道次板坯表面温度为780℃；(4) Rolling: After the cast slab comes out of the heating furnace, initial phosphorus removal is carried out. The high-pressure water pressure for phosphorus removal is 22MPa and the phosphorus removal speed is 1.0m/s; then two-stage controlled rolling of rough rolling and finish rolling is carried out. Rough rolling The rolling time is 155s, the finishing rolling time is 160s, the interval between the two rolling stages is 50s, the surface temperature of the slab at the end of rough rolling is 960°C, and the surface temperature of the slab at the end of finish rolling is 780°C;
(5)冷却：轧制后采用水冷加速冷却至700℃，其高于A
r3(热模拟试验测得A
r3为680℃)，然后空冷至室温；
(5) Cooling: After rolling, use water cooling to accelerate cooling to 700°C, which is higher than A r3 (A r3 measured in the thermal simulation test is 680°C), and then air cool to room temperature;
(6)表面处理：涂层前对钢板表面进行抛丸处理，抛丸除锈等级不低于Sa2.5；然后喷涂抗高温氧化涂料，涂层厚度为50um；(6) Surface treatment: Before coating, the surface of the steel plate is shot blasted, and the shot blasting rust removal grade is not lower than Sa2.5; then the anti-high temperature oxidation coating is sprayed, and the coating thickness is 50um;
(7)热处理：采用淬火+回火热处理，淬火温度为860℃，在炉时间为55min，回火温度为660℃，在炉时间为70min。(7) Heat treatment: quenching + tempering heat treatment is adopted, the quenching temperature is 860°C, the furnace time is 55min, the tempering temperature is 660°C, and the furnace time is 70min.
采用扫描电镜观察钢板表面微观形貌，如图1所示，可见钢板表面氧化铁皮致密均匀，未见氧化铁皮压入缺陷，钢板表面质量好。The microscopic morphology of the surface of the steel plate was observed using a scanning electron microscope. As shown in Figure 1, it can be seen that the iron oxide scale on the surface of the steel plate is dense and uniform, and there is no intrusion defect of the iron oxide scale. The surface quality of the steel plate is good.
取标准夏比V型冲击试样进行-100℃温度下的冲击试验，结果为280/243/286J。可见实施例1钢板具有优异的低温韧性。A standard Charpy V-type impact specimen was taken for an impact test at a temperature of -100°C. The result was 280/243/286J. It can be seen that the steel plate of Example 1 has excellent low temperature toughness.
实施例2：Example 2:
一种高镍低温钢中厚板的生产方法，钢板厚度60mm。钢的重量百分组成为C＝0.06％、Si＝0.22％、Mn＝0.75％、P＝0.005％、S＝0.002％、Al＝0.030％、Ni＝3.60％、Sb＝0.0015％、B＝0.0004％、O＝0.0011％、N＝0.0038％、H＝0.00012％、且Cu+Cr+Mo＝0.06％、Ti+Nb+V＝0.005％，余量为Fe和不可避免的杂质元素；关键工艺步骤包括：A method for producing medium-thick plates of high-nickel and low-temperature steel, with a thickness of 60 mm. The weight percentage of steel is C=0.06%, Si=0.22%, Mn=0.75%, P=0.005%, S=0.002%, Al=0.030%, Ni=3.60%, Sb=0.0015%, B=0.0004% , O=0.0011%, N=0.0038%, H=0.00012%, and Cu+Cr+Mo=0.06%, Ti+Nb+V=0.005%, the balance is Fe and inevitable impurity elements; key process steps include :
(1)冶炼：按上述成分冶炼钢水并真空处理；(1) Smelting: smelting molten steel according to the above composition and vacuum treatment;
(2)连铸：采用全程保护浇注，过热度控制为15～18℃、拉速为0.85m/min；连铸坯 经切割后置于水冷装置中摆动进行表面淬火，控制水压为2.5kg/cm
2，水溶液中Cl离子含量为0.15mol/L、S离子含量为0.01mol/L；铸坯表面淬火后表面温度为580℃，其低于B
s(其中热模拟试验测得B
s为600℃)并与中心的温度差在150℃以上，然后空冷使铸坯表面回温至780℃，其与中心的温度差缩小至50℃以内，此时再将连铸坯热送热装至步进梁式加热炉中加热；
(2) Continuous casting: full-process protective casting is adopted, the superheat is controlled to 15~18°C, and the pulling speed is 0.85m/min; after the continuous casting billet is cut, it is placed in a water-cooling device to swing for surface quenching, and the water pressure is controlled to 2.5kg /cm 2 , the Cl ion content in the aqueous solution is 0.15mol/L, and the S ion content is 0.01mol/L; the surface temperature of the cast slab after quenching is 580°C, which is lower than B s (where B s measured in the thermal simulation test is 600℃) and the temperature difference with the center is above 150℃, and then the surface of the slab is air-cooled to return to 780℃, and the temperature difference with the center is reduced to within 50℃. At this time, the slab is hot-loaded to Heating in walking beam heating furnace;
(3)加热：加热过程中铸坯表面温度介于900～1000℃区间的加热时间为45min；总加热时间为300min，最高炉膛温度为1280℃，炉内残氧量为3.0％～4.0％；(3) Heating: During the heating process, the heating time when the surface temperature of the slab is between 900 and 1000°C is 45 minutes; the total heating time is 300 minutes, the maximum furnace temperature is 1280°C, and the residual oxygen in the furnace is 3.0% to 4.0%;
(4)轧制：铸坯出加热炉后进行初除磷，除磷高压水压力为22MPa、除磷速度为0.8m/s；然后进行粗轧和精轧的两阶段控制轧制，粗轧轧制时间为150s，精轧轧制时间为120s，两个轧制阶段间隔时间为45s，粗轧结束道次板坯表面温度为970℃、精轧结束道次板坯表面温度为770℃；(4) Rolling: After the cast slab comes out of the heating furnace, initial phosphorus removal is carried out. The high-pressure water pressure for phosphorus removal is 22MPa and the phosphorus removal speed is 0.8m/s; then two-stage controlled rolling of rough rolling and finish rolling is carried out. Rough rolling The rolling time is 150s, the finishing rolling time is 120s, the interval between the two rolling stages is 45s, the surface temperature of the slab at the end of rough rolling is 970°C, and the surface temperature of the slab at the end of finish rolling is 770°C;
(5)冷却：轧制后采用水冷加速冷却至690℃，其高于A
r3(热模拟试验测得A
r3为680℃)，然后空冷一段时间后将钢板堆冷至室温；
(5) Cooling: After rolling, use water cooling to accelerate cooling to 690°C, which is higher than A r3 (thermal simulation test measured A r3 to be 680°C), and then air-cool for a period of time and then stack the steel plates to cool to room temperature;
(6)表面处理：涂层前对钢板表面进行抛丸处理，抛丸除锈等级不低于Sa2.5；然后喷涂抗高温氧化涂料，涂层厚度为80um；(6) Surface treatment: Before coating, the surface of the steel plate is shot blasted, and the shot blasting rust removal grade is not lower than Sa2.5; then the anti-high temperature oxidation coating is sprayed, and the coating thickness is 80um;
(7)热处理：采用淬火+回火热处理，淬火温度为850℃，在炉时间为150min，回火温度为660℃，在炉时间为180min。(7) Heat treatment: quenching + tempering heat treatment is adopted. The quenching temperature is 850°C and the furnace time is 150min. The tempering temperature is 660°C and the furnace time is 180min.
取标准夏比V型冲击试样进行-100℃温度下的冲击试验，结果为217/205/211J。可见实施例2钢板具有优异的低温韧性。A standard Charpy V-type impact specimen was taken for an impact test at a temperature of -100°C. The result was 217/205/211J. It can be seen that the steel plate of Example 2 has excellent low temperature toughness.
Claims (1)
- 一种高镍低温钢中厚板的生产方法，其特征在于：钢的重量百分组成为C＝0.05％～0.08％、Si≤0.30％、Mn＝0.50％～0.80％、P≤0.008％、S≤0.005％、Al＝0.02％～0.05％、Ni＝3.0％～4.0％、Sb≤0.003％、B≤0.0005％、O≤0.0015％、N≤0.0050％、H≤0.0002％、且Cu+Cr+Mo≤0.08％、Ti+Nb+V≤0.01％，余量为Fe和不可避免的杂质元素；关键工艺步骤包括：A method for producing medium-thick plates of high-nickel low-temperature steel, characterized in that: the weight percentage of the steel is C=0.05%~0.08%, Si≤0.30%, Mn=0.50%~0.80%, P≤0.008%, S ≤0.005%, Al=0.02%～0.05%, Ni=3.0%～4.0%, Sb≤0.003%, B≤0.0005%, O≤0.0015%, N≤0.0050%, H≤0.0002%, and Cu+Cr+ Mo≤0.08%, Ti+Nb+V≤0.01%, the balance is Fe and inevitable impurity elements; key process steps include:(1)冶炼：按上述钢的重量百分组成冶炼钢水并真空处理；(1) Smelting: Smelting molten steel according to the weight percentage of the above steel and vacuum treatment;(2)连铸：采用全程保护浇注，控制过热度为10～20℃、拉速为0.8～1.0m/min；连铸坯经切割后置于水冷装置中摆动进行表面淬火，控制水压为1～4kg/cm 2，水溶液中Cl离子含量不低于0.1mol/L、S离子含量不低于0.01mol/L；控制铸坯表面淬火后表面温度低于B s且与中心的温度差在150℃以上，然后空冷使该温度差缩小至50℃以内再将连铸坯热送热装至步进梁式加热炉中加热；其中B s为贝氏体转变开始温度； (2) Continuous casting: Adopt full-process protective casting, control the superheat to 10-20°C, and the pulling speed to 0.8-1.0m/min; after cutting, the continuous casting billet is placed in a water-cooling device to swing for surface quenching, and the water pressure is controlled to 1~4kg/cm 2 , the Cl ion content in the aqueous solution is not less than 0.1mol/L, and the S ion content is not less than 0.01mol/L; control the surface temperature of the slab after quenching to be lower than B s and the temperature difference with the center is within 150℃ or above, and then air cooling to reduce the temperature difference to within 50℃, and then the continuous casting billet is heated in a walking beam heating furnace; where B s is the bainite transformation starting temperature;(3)加热：加热过程中控制铸坯表面温度介于900～1000℃的加热时间≥30min；同时控制总加热时间不低于(T F－1000－20×O R)min但不高于(T F-850－20×O R)min，其中T F为最高炉膛温度，控制为1250～1300℃，O R为炉内残氧量，控制为2.5％～5.0％； (3) Heating: During the heating process, the surface temperature of the cast slab is controlled to be between 900 and 1000°C and the heating time is ≥ 30 min; at the same time, the total heating time is controlled to be no less than ( TF -1000-20×O R )min but no higher than ( T F -850-20×O R )min, where T F is the maximum furnace temperature, controlled at 1250~1300℃, O R is the residual oxygen in the furnace, controlled at 2.5%~5.0%;(4)轧制：铸坯出加热炉后进行初除磷，除磷高压水压力不小于22MPa、除磷速度不高于1.0m/s；然后进行粗轧和精轧的两阶段控制轧制，粗轧和精轧的轧制时间均不大于180s，同时两个轧制阶段间隔时间不大于60s，并控制粗轧结束道次板坯表面温度为950～980℃、精轧结束道次板坯表面温度为750～800℃；(4) Rolling: After the slab comes out of the heating furnace, initial phosphorus removal is carried out. The high-pressure water pressure for phosphorus removal is not less than 22MPa and the phosphorus removal speed is not higher than 1.0m/s; then two-stage controlled rolling of rough rolling and finishing rolling is carried out. , the rolling time of rough rolling and finish rolling is not more than 180s, and the interval between the two rolling stages is not more than 60s, and the surface temperature of the slab at the end of rough rolling is controlled to be 950~980°C, and the surface temperature of the plate at the end of finish rolling is controlled The surface temperature of the billet is 750~800℃;(5)冷却：轧制后采用水冷加速冷却至A r3以上，然后以不超过空冷的冷速冷却至室温；其中A r3为过冷奥氏体向铁素体转变的开始温度； (5) Cooling: After rolling, use water cooling to accelerate cooling to above A r3 , and then cool to room temperature at a cooling rate not exceeding air cooling; where A r3 is the starting temperature of the transformation of supercooled austenite to ferrite;(6)表面处理：涂层前对钢板表面进行抛丸处理，抛丸除锈等级不低于Sa2.5；然后喷涂抗高温氧化涂料，涂层厚度为40～100um；(6) Surface treatment: Before coating, the surface of the steel plate is shot blasted, and the shot blasting rust removal grade is not lower than Sa2.5; then the high temperature oxidation resistant coating is sprayed with a coating thickness of 40 to 100um;(7)热处理：采用淬火+回火热处理，淬火温度为840～870℃，在炉时间不低于2倍板厚mm×min/mm；回火温度为650～670℃，在炉时间不低于2.5倍板厚mm×min/mm。(7) Heat treatment: quenching + tempering heat treatment is adopted. The quenching temperature is 840~870℃, and the furnace time is not less than 2 times the plate thickness mm×min/mm; the tempering temperature is 650~670℃, and the furnace time is not less than 2 times. At 2.5 times plate thickness mm×min/mm.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202211027800.3 | 2022-08-25 | ||
| CN202211027800.3A CN115418565B (en) | 2022-08-25 | 2022-08-25 | Production method of high-nickel low-temperature steel medium plate |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| WO2024040762A1 true WO2024040762A1 (en) | 2024-02-29 |
Family
ID=84199541
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/CN2022/132527 WO2024040762A1 (en) | 2022-08-25 | 2022-11-17 | Production method for high-nickel medium-thick steel plate for low-temperature service |
Country Status (2)
| Country | Link |
|---|---|
| CN (1) | CN115418565B (en) |
| WO (1) | WO2024040762A1 (en) |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2945164A1 (en) * | 1979-11-08 | 1981-05-14 | Vladimir Vasil'evič Leningrad Šitkov | Weldable martensitic stainless steel - contains niobium and/or zirconium plus yttrium, cerium and/or lanthanum to improve weldability and corrosion resistance |
| JPS59232225A (en) * | 1983-06-13 | 1984-12-27 | Nippon Kokan Kk <Nkk> | Manufacture of bent pipe with high tension and toughness |
| CN103320707A (en) * | 2013-06-20 | 2013-09-25 | 宝山钢铁股份有限公司 | High-strength stainless steel tube with excellent toughness and manufacturing method thereof |
| CN105441798A (en) * | 2015-11-18 | 2016-03-30 | 南京钢铁股份有限公司 | Method for manufacturing Ni steel moderately-thick plate for low-temperature container |
| CN106676402A (en) * | 2015-11-06 | 2017-05-17 | 攀钢集团攀枝花钢铁研究院有限公司 | Chromium-titanium-containing atmosphere corrosion-resistant section molten steel and atmosphere corrosion-resistant section steel as well as production method thereof |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103305758B (en) * | 2013-06-21 | 2015-12-09 | 舞阳钢铁有限责任公司 | A kind of steel plate for low temperature pressure container and production method thereof |
| CN103882312B (en) * | 2014-03-04 | 2016-04-27 | 南京钢铁股份有限公司 | The manufacture method of low-cost high-toughness-140 DEG C of Steel Plates For Low Temperature Service |
| CN109694987B (en) * | 2017-10-20 | 2021-02-23 | 鞍钢股份有限公司 | High-nickel steel for ultralow-temperature pressure vessel and manufacturing method thereof |
| CN111304426B (en) * | 2020-03-31 | 2021-09-03 | 湖南华菱湘潭钢铁有限公司 | Production method of high-strength steel sheet |
-
2022
- 2022-08-25 CN CN202211027800.3A patent/CN115418565B/en active Active
- 2022-11-17 WO PCT/CN2022/132527 patent/WO2024040762A1/en unknown
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2945164A1 (en) * | 1979-11-08 | 1981-05-14 | Vladimir Vasil'evič Leningrad Šitkov | Weldable martensitic stainless steel - contains niobium and/or zirconium plus yttrium, cerium and/or lanthanum to improve weldability and corrosion resistance |
| JPS59232225A (en) * | 1983-06-13 | 1984-12-27 | Nippon Kokan Kk <Nkk> | Manufacture of bent pipe with high tension and toughness |
| CN103320707A (en) * | 2013-06-20 | 2013-09-25 | 宝山钢铁股份有限公司 | High-strength stainless steel tube with excellent toughness and manufacturing method thereof |
| CN106676402A (en) * | 2015-11-06 | 2017-05-17 | 攀钢集团攀枝花钢铁研究院有限公司 | Chromium-titanium-containing atmosphere corrosion-resistant section molten steel and atmosphere corrosion-resistant section steel as well as production method thereof |
| CN105441798A (en) * | 2015-11-18 | 2016-03-30 | 南京钢铁股份有限公司 | Method for manufacturing Ni steel moderately-thick plate for low-temperature container |
Also Published As
| Publication number | Publication date |
|---|---|
| CN115418565A (en) | 2022-12-02 |
| CN115418565B (en) | 2023-09-05 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106544597B (en) | Ultra-thin ultra-wide steel for nuclear power pressure equipment plate and its manufacture method | |
| CN107779577B (en) | A kind of garden tool set steel that processing performance is excellent and its production method | |
| CN112981235B (en) | Hardened and tempered steel plate with yield strength of 420MPa grade for building structure and production method thereof | |
| CN101368251B (en) | Steel plate for large-thickness hydrogen-contacting equipment and its production technology | |
| CN100467652C (en) | Easy-weld hardening high-strength steel plate and production method thereof | |
| CN104328356A (en) | Manufacturing method of thin-specification high-strength-structure steel plate with steckel mill | |
| CN105039866A (en) | 1400 MPa super-high strength alloy steel and manufacturing method thereof | |
| CN109504897A (en) | A kind of big thickness water power steel of 80kg grades of low-carbon-equivalent low-crackle sensitive and its manufacturing method | |
| CN102876997B (en) | Easy-welding tempering high-strength steel plate for ocean platform and production method thereof | |
| CN102230057A (en) | Method for producing steel plate of petroleum storage tank by using direct quenching process | |
| CN104762559A (en) | Method for producing steel plate for hydrogen-contacting equipment | |
| CN107794451A (en) | A kind of plastic die steel 718 and its production technology | |
| CN109266964A (en) | A kind of steel forgings production and processing technology | |
| CN105624554B (en) | A kind of effective steel plate of 70 grades of SA671 electro-fusion weldings and manufacturing method with good hic resistance characteristic | |
| CN112981232A (en) | 12Cr2Mo1VR steel plate with low compression ratio and high flaw detection quality requirement for continuous casting billet finished product and production process thereof | |
| CN103361552A (en) | V-N microalloying 460MPa-level thick plate and manufacturing method thereof | |
| CN102191430A (en) | Easy welding steel plate with yield strength of 550MPa and high toughness and manufacturing method thereof | |
| CN103834873A (en) | Low-alloy high-strength steel plate for big-thickness boiler drum and manufacturing method of low-alloy high-strength steel plate | |
| CN107119238B (en) | The 690MPa grades wide thin steel for engineering machinery plate of yield strength and its production method | |
| WO2024040762A1 (en) | Production method for high-nickel medium-thick steel plate for low-temperature service | |
| CN111500918A (en) | Production method of wear-resistant steel plate | |
| CN110273106A (en) | A kind of 260MPa grades of cold-rolling continuous annealing glassed steel and its production method | |
| CN110512151A (en) | A kind of rare earth NM450 Wide and Heavy Plates and its production method | |
| CN103045958A (en) | High-strength steel plate used at low temperature of subzero 50 DEG C and preparation method thereof | |
| CN116121644A (en) | High-toughness mine disc saw blade steel plate and manufacturing method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 121 | Ep: the epo has been informed by wipo that ep was designated in this application |
Ref document number: 22956297 Country of ref document: EP Kind code of ref document: A1 |