WO2024033717A1 - A reactor for producing hydrogen using ammonia - Google Patents
A reactor for producing hydrogen using ammonia Download PDFInfo
- Publication number
- WO2024033717A1 WO2024033717A1 PCT/IB2023/056076 IB2023056076W WO2024033717A1 WO 2024033717 A1 WO2024033717 A1 WO 2024033717A1 IB 2023056076 W IB2023056076 W IB 2023056076W WO 2024033717 A1 WO2024033717 A1 WO 2024033717A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- hydrogen
- ammonia
- reactor
- producing hydrogen
- aen
- Prior art date
Links
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 title abstract 6
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 title abstract 5
- 239000001257 hydrogen Substances 0.000 title abstract 5
- 229910052739 hydrogen Inorganic materials 0.000 title abstract 5
- 229910021529 ammonia Inorganic materials 0.000 title abstract 3
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 claims 1
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 abstract 3
- 229910001873 dinitrogen Inorganic materials 0.000 abstract 1
- 229930195733 hydrocarbon Natural products 0.000 abstract 1
- 150000002430 hydrocarbons Chemical class 0.000 abstract 1
- 239000012528 membrane Substances 0.000 abstract 1
- 229910052757 nitrogen Inorganic materials 0.000 abstract 1
- 241000287523 Ara Species 0.000 description 2
- 241000272522 Anas Species 0.000 description 1
- 241001148624 Areae Species 0.000 description 1
- 206010012426 Dermal cyst Diseases 0.000 description 1
- HEFNNWSXXWATRW-UHFFFAOYSA-N Ibuprofen Chemical compound CC(C)CC1=CC=C(C(C)C(O)=O)C=C1 HEFNNWSXXWATRW-UHFFFAOYSA-N 0.000 description 1
- 241001409001 Maera Species 0.000 description 1
- 241001446467 Mama Species 0.000 description 1
- 241001214257 Mene Species 0.000 description 1
- 241000353355 Oreosoma atlanticum Species 0.000 description 1
- 241001093501 Rutaceae Species 0.000 description 1
- 241000801924 Sena Species 0.000 description 1
- 101150014732 asnS gene Proteins 0.000 description 1
- XOFYZVNMUHMLCC-ZPOLXVRWSA-N prednisone Chemical compound O=C1C=C[C@]2(C)[C@H]3C(=O)C[C@](C)([C@@](CC4)(O)C(=O)CO)[C@@H]4[C@@H]3CCC2=C1 XOFYZVNMUHMLCC-ZPOLXVRWSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/04—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of inorganic compounds, e.g. ammonia
- C01B3/047—Decomposition of ammonia
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/08—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
- B01J19/087—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor employing electric or magnetic energy
- B01J19/088—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor employing electric or magnetic energy giving rise to electric discharges
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/08—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
- B01J2219/0873—Materials to be treated
- B01J2219/0875—Gas
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
- C01B2203/0405—Purification by membrane separation
- C01B2203/041—In-situ membrane purification during hydrogen production
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/08—Methods of heating or cooling
- C01B2203/0805—Methods of heating the process for making hydrogen or synthesis gas
- C01B2203/0861—Methods of heating the process for making hydrogen or synthesis gas by plasma
Definitions
- eeesr en wnvavecneo eomrnenn ear aceco c vrnoemror,a aa wces rm o s een cec ,eoaa ncvoa mnoee n,mneesra raan nnsessn caone ms a oae c ne e wroee sncss e , wroonecn re ro mac eoeo nreerc, aou o nree o e ame u m rn oea nace ao mro o reco oecuem erensnee on wnvroen.
- urreone ocse arawns uurree eeccss a m a mo moe oe o e uuse srra rea ancor. n ee enxeerroorr o o ee r reeaaccoorr..
- ans s aoo sne acsa mee smcssraoannneasana seesneraeceo,reroom suer raecacoena enevr,r oorn emveenn o,nnesnan aaraccunar recomnaonow araes emrom eac oer an nooner aows er one arse ammona.
- e ensveansonn can acecmosmemveos aase m eevmouraonnes oaave area an or roen. o wnur as sesurereas s wrmsmanm rea eoa wnc seaao ,,sn, c esnam craoreeasncer ac c enean r m a eaoer aoeeenmm coereoxms c,ae rms o.e menrec,rs we eea ms zocen nme se wr aanervearsa e,ne csc ooe nne mn rueemeeacoraomnne r zs oro aonn evene, creaamaere,owueve arr,ereeaon aeneo m
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Inorganic Chemistry (AREA)
- Detergent Compositions (AREA)
- Physical Or Chemical Processes And Apparatus (AREA)
Abstract
A reactor for producing hydrogen using ammonia that enables to use pure hydrogen wherever needed in an easy and inexpensive way. The reactor comprising a plasma torch to facilitate splitting the ammonia into hydrogen and nitrogen gas, and a membrane adapted to prevent the hydrogen and nitrogen from recombining. The invention provides a solution that can be transported efficiently up to certain capacities without the need for specialized transport, whether on land or, most notably, at sea. This capability alleviates the dependence on expensive transportation of liquefied hydrocarbons, which subsequently require regasification. Moreover, the invention effectively eliminates pollution and mitigates the greenhouse effect at all stages of the process.
Description
ecnca ro eeresennvenon reaeso a reacor morearcuar o a reaco roen rorroucn ac u usn ammona. oroou ans,en a w ennoerr r wars s cnuorrreanraens,e,a c wcnmac uen ev ceunaen cea wenes e,xrreemseenne anomeen saam seucme as crocoase asn o e same aers en, w eave a wor a w noonere ransov. ne anreoovrecrenmoenascenowens ora a a emare on a vruousa owars e ener r e ranwer ms,a a sne ersms aeamsu ss,e r w aonsre m eovueeva r enee cevn orrnon e ens rme o aencna e , sa anenaso naeses renearu cnse. ease ou onroereo, woemcas ozsaoaesns sa oeea oree eaceon ooomoucsm a annan uc wasuroe'srusnneern wor. anwae.ureoeu,soanve oe aenn cose,avouranonaearrannseros,r oa moasneruosnuecssse esv,ensroormca veroranr s oemouumea,an reeoauserenaormeaawoannv aeenr acnonnenrcoseu,a wso o mrs,era, aa ceoara ansae m w waer maare, w a wa wranerreserea exncena annseor oe caaovweue ava cnn ere,nane. v e cnou ener crremn sao weuor crceans sc ceeena aarnr,oe, ncaoues eevreesnennrnnnv aenoouon sv ooe aersnu reuaree r eeoneer,en nreaaxcnseoenne nr meaeeaonnos. sroerae.roems oesm mooreacnucee m ousreo soenven, nasmeranssonocwuarsn a ceenanruanes, oonree o ane arnans ueerancaovne, s aorrea ceu mrreenoseorn exrooerne, s.uco awseverr,ese, ca mroosn s eoreacev,e co smsreemssoonr, conamno asr r cna an sorn roensoun n eorm o ammona.ne meano, wc um ron, ammona oers a sueror souonueos caron-ree comoson. sca ee o nvrreosee nnnv mene nvneonon moann reueraseo ae r eeaucor.rume r oeaceor amacmonaaes crean o ma cemca- sae oer annao reeasc naon rse:a roeecnom anose n.roowenev.er,n wer norem aas conormonas,o anm remaconoan,savorn sraosnma coermc,caso snasewse oenvercomroeen anrov nrnoene, e nneacessasrsanecerm oa a enerrecseo csaruraee comonenowsever,roesn a oneraorone wno nuaura noeneno ruescorman ne e axe nor seaa ereer o,ao reenc.aeusneaeew oo
s econonmc oaverme wou e verow an ereore noneresnnnusraracce an no s c rerome esc raes,anoos m rer wneemr v acrea asnen. eeesr,en wnvavecneo eomrnenn ear aceco c vrnoemror,a aa wces rm o s een cec ,eoaa ncvoa mnoee n,mneesra raan nnsessn caone ms a oae c ne e wroee sncss e , wroonecn re ro mac eoeo nreerc, aou o nree o e ame u m rn oea nace ao mro o reco oecuem erensnee on wnvroen. enon an enormous ncreasesee o e s n reacon o w nrccoara enon-nmeeeune m raemumcnoe oa a am mao eerrean eneerer ra wse o s,e e surme cmvore ae arrs,mse c seennocooc,nsve ne.,eeno n cao orwennr a co oe avnn ca eonen roc a,n oee. er senve seur mcoc uareev ,rees mrar a ao aem sr onn vara ecu uoo sreu eonrsu o .so coesars eamae mnc m eu ve mama nae acoern nra anas. s, awem wou mo aeno ease reacnsoran vareo rues maceemmernan oes,eraoenre,nsro omn eamc ooraenr, caanne reasesacve s sucen an or roen. urreone ocse arawns uurree eeccss a m a mo moe oe o e uuse srra rea ancor. n ee enxeerroorr o o ee r reeaaccoorr.. o c or examseso,oer unmeresoo a eoown scosureroves man eren emomens, moam cou roernseee,na mse r aerneere a enrxcraaemnm nuee mmensee arnnn ass a a arrnee nereoe osn rcrneeenauereesoow oe voa smrmouns e.mn aoermeseoennns,.escecroessucerne e.xamsecsoees asur oree, emuroosem oen ssm anco an car an oees neorsnnsee varcouase e ax raemaeosn.s s reeweeenones vaorroues emcaassr c ooneurmamoonnsa ssccussssoen. reacon 2u +rum reaconmmona roen ro ro2e ⇌ 3 en: n an roen reac seroowmceoeonemr.er-ce e reua °acoo annn: con asns os om aao c meramesescuarme em ouonar-unm a a:nm rae usoan as a mnaa osenemeasecr aesme caeraausrees ! "e2 reac + # "on2s exe → ronc3 a ro — om. em&' % eraure.
we mus seureore, eneer moecueen more saeans comonens, we wano s , e cemca rea,c wonc o w aemmoonn oaursn exvoeneornmcr ,ou asmaorc. rreossuucrees ursoemne reeacaorer s -ose am emonarouconrocessev aenose re.mova o moe . amemona s muc more cuo maue amrmuomnaoe r . creesmsucraes e anu r wae w suorrsa acemerraomures o aouan °o anrea s sowon.e rero weemavse sarone ne conrar, weooem e reacon eu rum. w weou awasuaranee new ammonaneraeu sres arnou rneacor, ° aen euowrruemssu sres,s anownar as woan ueee r meaocsanms,orereore an . waem, ans s aoo sne acsa mee smcssraoannneasana seesneraeceo,reroom suer raecacoena enevr,r oorn emveenn o,nnesnan aaraccunar recomnaonow araes emrom eac oer an nooner aows er one arse ammona. reacor eu er wesen anvaesnmoane seca memrane canensere rec noe s n n moem reraronerseesn,s a secrnoooem,, we rcer eo aar csc. or reesac arees n mou oc arecrueamre erxauenress,ve °es ce arnan asooees amon ose wee acesounee rane o ose ressano emeraures, as we as ovous owever,eeome arn o eor camroere en,o no cause concern o ra eraaon. ae caonocnauoounsorowe ommreesae amnmroonuac, won ocu sroesen w aen re a nacraoosnmena enourocr meuu mmsemuararannese,e an an comonens o e ammona moecu owars e exaneeacno mro or eresennvenoe.n eu e w asmaorc an seca memraness c reauarees oeren eans eaxnneeeerre senas unce oeo rancnew e s. aneeca s oe raearaacsmonra e cuamroeeresn, w e anecr aoreaoss amennar eoovmrec aen am mmeomnara snes uname an.na roeurascroaresneero reraceorann,e. n memranes. exeror eo amnerc. conussrruacesv aearrcauwarne os, we rceac aorer aso ease o oera ooann ann ecenc o ammona moecue scsson, an roucur,u aeenaosnme wa e exaecceroeaeersmoonaeoe anre em oore meoaneo cw aeenrm ma mroacnaa ue-eme cvonsn aca cos reauoas.ne sess,unnaemeenomae,rcer aereoare wreerae e reacon zones cose e s eor surose. awraosen w, wcar cacnu naor aonnereo recnosmanneeca aanss meomewerranereso,o wean,c c soon cav anseroe o se vaarraoeusroems,ue su,or oneaen oe arr.ouenoss mec aroonsa oea meamurman oesrss ae sone.aer o com wose ovneer,, w a sec soenveraoraouesr cs,er aamrsc
ocnuemss a osn suea mnoaerau cmaan, aerse w ca cenon a asssoueee aoreroaerme erexnamaonnee mac araoneusw,m a mn anom oeorewrassr a oso mseu wamsn sau.c aes coauerse,, n aroen-meac maeras, suc as con an asoaron oruur,n ver naervse or. e ensveansonn can acecmosmemveos aase m eevmouraonnes oaave area an or roen. o wnur as sesurereas s wrmsmanm rea eoa wnc seaao ,,sn, c esnam craoreeasncer ac c enean r m a eaoer aoeeenmm coereoxms c,ae rms o.e menrec,rs we eea ms zocen nme se wr aaanervearsa e,ne csc ooe nne mn rueemeeacoraomnne r zs oro aonn evene, creaamaere,owueve arr,ereeaon aeneo mna em mcuo rsn e an aessu ,oeerum causv, een acc asoeera ween n mowe,assne ureac es.nrcooesne mase rsea sceeons annuuse. ereoonreee m meemarsaneas, wecmrnes areae werroeenesure roenasasse, a e exseam umseen,e ms, suesaesme, caoersmeeeu wn c a voesren,omw cearrmoena coeneon mursoeen u asnee,ooersa r eemsss asasnon ov nveoeszr wzem aen o.oeorr e w sas oavueor aun on o aenner an nexsee ueen ensnvvee wnaons . m caar sea ascer n arosssc o ace reos a us usaencue oreo cerarr noo caeenn a wse ceerse.vser asos nreaenseo,rna ane eeroere sneocruoascea erranoenscso a errex, eeonmsnv oeaneoan ara a annns so arao,ev we o ac ae sreoeacn,e rse ns.eeevn re uassrocmaone.
Claims
wac reeraeacveorr neoereronu acnn eas anroneenx uesnnsve am wamo.nae reaac eonra comesrosn use auarsemaorroceno carneveneer saensonrroeeen a amnm nonraonenoromr roeceonm ann nn.roeennvaesn, anon ar movemersa an seo auaoneao o rrenans reae ensxor oceuan, ss w eovn ee.ee ecroar arn oeson e avoea srrnc ,aen o aeoer sn, m uos noo caera,n a c saea.acess ca waou aeev naeeesoer seeecnaeznece on oveenoruonece esese.cveroc earmonnas,es wocu souns aenue mn a reesuree
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT202200016944 | 2022-08-08 | ||
| IT102022000016944 | 2022-08-08 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| WO2024033717A1 true WO2024033717A1 (en) | 2024-02-15 |
Family
ID=87136400
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/IB2023/056076 WO2024033717A1 (en) | 2022-08-08 | 2023-06-13 | A reactor for producing hydrogen using ammonia |
Country Status (2)
| Country | Link |
|---|---|
| NL (1) | NL2033959A (en) |
| WO (1) | WO2024033717A1 (en) |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US11014809B2 (en) * | 2017-03-17 | 2021-05-25 | Sawafuji Electric Co., Ltd. | Transportation device equipped with fuel cell system |
| CN114852962A (en) * | 2022-01-28 | 2022-08-05 | 大连理工大学 | Hydrogen production system and method for decomposing alcohols by microwave plasma under normal pressure |
-
2023
- 2023-01-13 NL NL2033959A patent/NL2033959A/en unknown
- 2023-06-13 WO PCT/IB2023/056076 patent/WO2024033717A1/en unknown
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US11014809B2 (en) * | 2017-03-17 | 2021-05-25 | Sawafuji Electric Co., Ltd. | Transportation device equipped with fuel cell system |
| CN114852962A (en) * | 2022-01-28 | 2022-08-05 | 大连理工大学 | Hydrogen production system and method for decomposing alcohols by microwave plasma under normal pressure |
Non-Patent Citations (1)
| Title |
|---|
| HAYAKAWA YUKIO ET AL: "Hydrogen production from ammonia by the plasma membrane reactor", INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, ELSEVIER, AMSTERDAM, NL, vol. 45, no. 56, 10 September 2020 (2020-09-10), pages 32082 - 32088, XP086328496, ISSN: 0360-3199, [retrieved on 20200910], DOI: 10.1016/J.IJHYDENE.2020.08.178 * |
Also Published As
| Publication number | Publication date |
|---|---|
| NL2033959A (en) | 2024-02-16 |
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