WO2024027730A1 - Micromachined ultrasonic transducer structure having having dual pmuts provided at same side as substrate, and manufacturing method therefor - Google Patents
Micromachined ultrasonic transducer structure having having dual pmuts provided at same side as substrate, and manufacturing method therefor Download PDFInfo
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- WO2024027730A1 WO2024027730A1 PCT/CN2023/110644 CN2023110644W WO2024027730A1 WO 2024027730 A1 WO2024027730 A1 WO 2024027730A1 CN 2023110644 W CN2023110644 W CN 2023110644W WO 2024027730 A1 WO2024027730 A1 WO 2024027730A1
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- PIGFYZPCRLYGLF-UHFFFAOYSA-N Aluminum nitride Chemical compound [Al]#N PIGFYZPCRLYGLF-UHFFFAOYSA-N 0.000 description 2
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- UKDIAJWKFXFVFG-UHFFFAOYSA-N potassium;oxido(dioxo)niobium Chemical compound [K+].[O-][Nb](=O)=O UKDIAJWKFXFVFG-UHFFFAOYSA-N 0.000 description 2
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- JNQQEOHHHGGZCY-UHFFFAOYSA-N lithium;oxygen(2-);tantalum(5+) Chemical compound [Li+].[O-2].[O-2].[O-2].[Ta+5] JNQQEOHHHGGZCY-UHFFFAOYSA-N 0.000 description 1
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B06—GENERATING OR TRANSMITTING MECHANICAL VIBRATIONS IN GENERAL
- B06B—METHODS OR APPARATUS FOR GENERATING OR TRANSMITTING MECHANICAL VIBRATIONS OF INFRASONIC, SONIC, OR ULTRASONIC FREQUENCY, e.g. FOR PERFORMING MECHANICAL WORK IN GENERAL
- B06B1/00—Methods or apparatus for generating mechanical vibrations of infrasonic, sonic, or ultrasonic frequency
- B06B1/02—Methods or apparatus for generating mechanical vibrations of infrasonic, sonic, or ultrasonic frequency making use of electrical energy
- B06B1/06—Methods or apparatus for generating mechanical vibrations of infrasonic, sonic, or ultrasonic frequency making use of electrical energy operating with piezoelectric effect or with electrostriction
- B06B1/0607—Methods or apparatus for generating mechanical vibrations of infrasonic, sonic, or ultrasonic frequency making use of electrical energy operating with piezoelectric effect or with electrostriction using multiple elements
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B06—GENERATING OR TRANSMITTING MECHANICAL VIBRATIONS IN GENERAL
- B06B—METHODS OR APPARATUS FOR GENERATING OR TRANSMITTING MECHANICAL VIBRATIONS OF INFRASONIC, SONIC, OR ULTRASONIC FREQUENCY, e.g. FOR PERFORMING MECHANICAL WORK IN GENERAL
- B06B1/00—Methods or apparatus for generating mechanical vibrations of infrasonic, sonic, or ultrasonic frequency
- B06B1/02—Methods or apparatus for generating mechanical vibrations of infrasonic, sonic, or ultrasonic frequency making use of electrical energy
- B06B1/06—Methods or apparatus for generating mechanical vibrations of infrasonic, sonic, or ultrasonic frequency making use of electrical energy operating with piezoelectric effect or with electrostriction
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B06—GENERATING OR TRANSMITTING MECHANICAL VIBRATIONS IN GENERAL
- B06B—METHODS OR APPARATUS FOR GENERATING OR TRANSMITTING MECHANICAL VIBRATIONS OF INFRASONIC, SONIC, OR ULTRASONIC FREQUENCY, e.g. FOR PERFORMING MECHANICAL WORK IN GENERAL
- B06B3/00—Methods or apparatus specially adapted for transmitting mechanical vibrations of infrasonic, sonic, or ultrasonic frequency
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B81—MICROSTRUCTURAL TECHNOLOGY
- B81B—MICROSTRUCTURAL DEVICES OR SYSTEMS, e.g. MICROMECHANICAL DEVICES
- B81B7/00—Microstructural systems; Auxiliary parts of microstructural devices or systems
- B81B7/02—Microstructural systems; Auxiliary parts of microstructural devices or systems containing distinct electrical or optical devices of particular relevance for their function, e.g. microelectro-mechanical systems [MEMS]
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B81—MICROSTRUCTURAL TECHNOLOGY
- B81C—PROCESSES OR APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OR TREATMENT OF MICROSTRUCTURAL DEVICES OR SYSTEMS
- B81C3/00—Assembling of devices or systems from individually processed components
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B06—GENERATING OR TRANSMITTING MECHANICAL VIBRATIONS IN GENERAL
- B06B—METHODS OR APPARATUS FOR GENERATING OR TRANSMITTING MECHANICAL VIBRATIONS OF INFRASONIC, SONIC, OR ULTRASONIC FREQUENCY, e.g. FOR PERFORMING MECHANICAL WORK IN GENERAL
- B06B2201/00—Indexing scheme associated with B06B1/0207 for details covered by B06B1/0207 but not provided for in any of its subgroups
- B06B2201/50—Application to a particular transducer type
- B06B2201/55—Piezoelectric transducer
Definitions
- Embodiments of the present invention relate to the field of semiconductors, and in particular to a micromachined ultrasonic transducer structure with dual PMUTs (Piezoelectric Micromachined Ultrasonic Transducer, PMUT) disposed on the same side of the base and a manufacturing method thereof, and a micromachined ultrasonic transducer having the same electronic equipment.
- PMUT Pielectric Micromachined Ultrasonic Transducer
- ultrasonic transducer As an electroacoustic component, ultrasonic transducer is widely used in production and life.
- the ultrasonic transducer emits ultrasonic waves to the external environment, and receives the reflected ultrasonic waves through the ultrasonic transducer and converts them into electrical signals for sensing, imaging, and acting on the external environment.
- Typical applications of ultrasonic transducers include fingerprint recognition, ultrasonic imaging, ultrasonic radar and ranging, non-destructive testing, flow measurement, force feedback, etc., in human body imaging, car reversing radar, underwater sonar detection, sweeping robots, ultrasonic smoke It will be used in scenes such as alarms.
- the above applications all involve the transmission of ultrasonic signals and the reception of ultrasonic signal echoes by the ultrasonic transducer. Therefore, the transmitting sensitivity and receiving sensitivity of the ultrasonic transducer determine the quality of the ultrasonic transducer to a large extent.
- Ultrasonic transducers developed using MEMS technology are mainly based on two principles: capacitive and piezoelectric, corresponding to capacitive micromachined ultrasonic transducer (CMUT) and piezoelectric micromachined ultrasonic transducer (PMUT) respectively. ), they can be integrated with complementary metal oxide semiconductor (Complementary Metal Oxide Semiconductor, CMOS) circuits to achieve low-cost, consistent and large-scale manufacturing of micro-ultrasound transducers with high integration and strong computing capabilities.
- CMUT capacitive micromachined ultrasonic transducer
- PMUT piezoelectric micromachined ultrasonic transducer
- the CMUT needs to apply a large bias voltage when working, resulting in high power consumption and certain limitations in application.
- PMUT is a promising solution.
- the effective integration of PMUT and CMOS is a crucial factor in realizing the above-mentioned ultrasonic transducer.
- the transmitting sensitivity and receiving sensitivity of the piezoelectric micromachined ultrasonic transducer PMUT play a vital role in the application of PMUT in the above-mentioned scenarios. If the transmitting sensitivity and receiving sensitivity are too low, the signal signal-to-noise ratio will be affected. Eventually the system becomes inoperable or performs poorly.
- the PMUT usually exhibits bending vibration mode.
- an alternating electric field is applied to the electrodes on both sides of the piezoelectric film. Due to the inverse piezoelectric effect, transverse stress is generated in the piezoelectric layer, which in turn generates a bending moment, forcing the film to deviate from the plane and emit into the surrounding medium. Sound pressure wave.
- the ultrasonic emission sensitivity S T of the flexural vibration PMUT is proportional to the piezoelectric coefficient réelle 31f of the piezoelectric film: S T ⁇ e 31f (1)
- the receiving sensitivity S R is proportional to the ratio of the piezoelectric coefficient réelle 31f and the dielectric constant ⁇ 33 ; S R ⁇ e 31f / ⁇ 33 (2)
- the ultrasonic transducer probe In ultrasonic imaging, the ultrasonic transducer probe not only serves as a transmitter to emit ultrasonic waves, but also as a receiver to receive ultrasonic waves reflected back from the object to be imaged.
- the working mode is usually pulse-echo mode, as shown in formula (3). shows that the PMUT pulse-echo sensitivity S T ⁇ S R is proportional to the ratio of the square of the piezoelectric coefficient réelle 31 to the dielectric constant ⁇ 33 .
- Piezoelectric coefficient and dielectric constant are the basic properties of piezoelectric materials. Table 1 lists the piezoelectric coefficient and dielectric constant properties of PZT and AlN among common piezoelectric materials.
- the dielectric constant of PZT is about 110 times that of AlN. times, so the receiving sensitivity of PZT-based PMUT will be about one-twelfth that of AlN-based PMUT.
- the sensitivity of the pulse-echo (transmit-receive) signal of the PMUT developed is equivalent.
- the PMUT manufacturing process includes the deposition of various films (such as piezoelectric films, electrode films, etc.) at different temperatures and the etching of corresponding films in different atmospheres and liquid environments. These processing processes may cause damage to CMOS circuits.
- the thinning and patterning processes of different piezoelectric materials and the electrode materials deposited on both sides of the film are also very different. Therefore, there is a process incompatibility problem when processing PMUTs of two materials on the same substrate. This leads to great risks and difficulties in fabricating PMUTs based on different piezoelectric films layer by layer on the same wafer. It is necessary to develop a PMUT-on-CMOS integration with strong process compatibility and convenience that contains different types of piezoelectric materials. plan.
- Embodiments of the present invention relate to a micromechanical ultrasonic transducer structure, including:
- the PMUT unit includes a PMUT substrate, a first PMUT and a second PMUT.
- Each PMUT includes a first electrode layer, a second electrode layer and a piezoelectric layer,
- the first PMUT and the second PMUT are laterally spaced apart from each other and arranged on one side of the PMUT substrate;
- the piezoelectric coefficient of the piezoelectric layer of the first PMUT is higher than the piezoelectric coefficient of the piezoelectric layer of the second PMUT, and the dielectric constant of the piezoelectric layer of the first PMUT is lower than the dielectric constant of the piezoelectric layer of the second PMUT.
- Embodiments of the present invention also relate to a method for manufacturing a micromechanical ultrasonic transducer structure, which includes the steps:
- a transistor unit including a transistor substrate and first and second transistors arranged spaced apart in a lateral direction;
- a PMUT unit bonded to a surface of one side of the transistor unit includes a PMUT substrate, a first PMUT and a second PMUT.
- the PMUT base is bonded to the surface of one side of the transistor unit in a surface bonding manner.
- Each PMUT includes a third PMUT. an electrode layer, a second electrode layer and a piezoelectric layer,
- the first PMUT and the second PMUT are laterally spaced apart from each other and arranged on one side of the PMUT substrate, and respectively correspond to the first transistor and the second transistor in the thickness direction of the micromachined ultrasound transducer structure;
- the piezoelectric coefficient of the piezoelectric layer of the first PMUT is higher than the piezoelectric coefficient of the piezoelectric layer of the second PMUT, and the dielectric constant of the piezoelectric layer of the first PMUT is lower than the dielectric constant of the piezoelectric layer of the second PMUT.
- Embodiments of the present invention also relate to an electronic device, including the above-mentioned micro-machined ultrasonic transducer structure, or the micro-machined ultrasonic transducer structure manufactured by the above-mentioned manufacturing method.
- 1-4 are schematic structural diagrams of micromachined ultrasound transducer structures according to different exemplary embodiments of the present invention.
- 5-13 are schematic cross-sectional views illustrating a manufacturing method of the micromachined ultrasonic transducer structure shown in FIG. 2 according to an exemplary embodiment of the present invention
- Figure 14 is a schematic diagram of a PMUT structure array according to an exemplary embodiment of the present invention.
- a piezoelectric material-based PMUT with a high voltage coefficient is used as an ultrasonic transmitter and a piezoelectric material-based PMUT with a low dielectric constant is used as an ultrasonic receiver, for example, they can be integrated on a set of ultrasonic transducers as shown in the table below.
- the PZT-based PMUT and AlN-based PMUT shown in 1 where the PZT-based PMUT is used as the ultrasonic transmitter and the AlN-based PMUT is used as the ultrasonic receiver, its pulse-echo sensitivity will be 100 times higher than that of a single material-based PMUT.
- CMOS wafer As the substrate, perform various thin film deposition and etching processes on it, and then The PMUT manufacturing process includes the deposition of various films (such as piezoelectric films, electrode films, etc.) at different temperatures and the etching of corresponding films in different atmospheres and liquid environments. This requires that the processing process does not cause damage to the CMOS circuit.
- films such as piezoelectric films, electrode films, etc.
- piezoelectric materials only a few piezoelectric films such as AlN-based piezoelectric materials have MEMS manufacturing processes that are compatible with CMOS. Therefore, this solution is mainly used for the development of integrated ultrasonic transducers based on corresponding piezoelectric materials. .
- the piezoelectric properties of the piezoelectric film are a crucial determinant of PMUT performance.
- piezoelectric materials with very excellent piezoelectric properties such as PZT and LiNbO 3 have more demanding processing techniques than AlN and poor compatibility with CMOS. Therefore, the development of CMOS integrated PMUT based on the above process flow is very limited and difficult to achieve.
- the cavity size is the core factor that determines the PMUT ultrasonic frequency, and changes in the cavity size will lead to changes in the PMUT ultrasonic frequency.
- alignment deviations inevitably occur, resulting in random deviations between the vibration unit area and its own design, resulting in frequency fluctuations of the developed CMOS integrated PMUT.
- the diameter of PMUT transducers used in the field of ultrasound imaging is very small, usually tens of microns or even smaller. Even an alignment deviation of 1 micron will cause great adverse effects.
- the present invention proposes to separately integrate piezoelectric material-based PMUTs with high voltage electrical coefficients (for example, the absolute value is higher than 1C/m 2 , and further higher than 5C/m 2 ) and low voltage electrical coefficients on the same CMOS wafer.
- Two types of ultrasonic transducers are piezoelectric material-based PMUTs with a dielectric constant (for example, lower than 1200 and further lower than 100).
- piezoelectric material-based PMUTs with high dielectric coefficient are dedicated to emitting ultrasonic waves, while those with low dielectric coefficients are
- the constant piezoelectric material-based PMUT is used to receive the reflected ultrasonic waves.
- the above-mentioned PMUT and CMOS integration solution is the key to developing MEMS ultrasound transducers with excellent performance and low cost.
- the present invention also proposes a solution to simultaneously integrate the above two types of piezoelectric material-based PMUTs on the same CMOS wafer.
- CMOS unit or transistor unit 1000: CMOS unit or transistor unit.
- CMOS substrate or transistor substrate optional materials are single crystal silicon, gallium nitride, gallium arsenide, sapphire, quartz, silicon carbide, diamond, etc.
- Circuit protection layer which is an insulating material layer, which can be silicon dioxide, silicon nitride, etc.
- the electrical connection layer within the transistor unit layer, corresponding to the first electrical connection layer, the material can be molybdenum, ruthenium, gold, aluminum, magnesium, tungsten, copper, titanium, iridium, osmium, chromium or a composite of the above metals or their alloys etc., the above materials are also suitable for other electrical connection layers.
- PMUT preliminary substrate optional materials are single crystal silicon, gallium nitride, gallium arsenide, sapphire, quartz, silicon carbide, diamond, etc.
- the material of the support layer may be the same as or different from the material of the electrode layer.
- the support layer can be provided at the lower part of the PMUT as shown in Figure 6, that is, between the PMUT and the PMUT substrate.
- the support layer is an insulating layer, and its material can be non-conductive materials such as silicon, silicon dioxide, and silicon nitride.
- the support layer can also be provided on the upper part of the PMUT. It should be pointed out that the support layer does not need to be provided.
- Electrode layer the material can be molybdenum, ruthenium, gold, aluminum, magnesium, tungsten, copper, titanium, iridium, osmium, chromium or composites of the above metals or their alloys, etc.
- the materials of the two electrode layers can be the same or different.
- Piezoelectric layer Materials available include polycrystalline aluminum nitride (AlN), polycrystalline zinc oxide, polycrystalline lead zirconate titanate (PZT), polycrystalline lithium niobate (LiNbO 3 ), polycrystalline lithium tantalate (LiTaO 3 ), polycrystalline niobium Materials such as potassium nitrate (KNbO 3 ), or single crystal aluminum nitride, single crystal gallium nitride, single crystal lithium niobate, single crystal lead zirconate titanate, single crystal potassium niobate, single crystal quartz film, or single crystal tantalum Lithium oxide and other materials, the above-mentioned single crystal or polycrystalline materials can also include rare earth element doped materials with a certain atomic ratio, all of which belong to the piezoelectric layer that can be used in the present invention, such as scandium Doped aluminum nitride (AlScN).
- AlScN scandium Doped aluminum nitride
- Structural protective layer usually dielectric material, such as silicon dioxide, aluminum nitride, silicon nitride, etc.
- Conductive layer or electrical connection layer the material of which can be selected from the materials used to form the electrode layer.
- Conductive layer or electrical connection layer the material of which can be selected from the materials used to form the electrode layer.
- Device protective layer usually dielectric material, such as silicon dioxide, aluminum nitride, silicon nitride, etc.
- Auxiliary substrate, optional materials are single crystal silicon, gallium nitride, gallium arsenide, sapphire, quartz, silicon carbide, diamond, etc.
- Temporary adhesive layer which can be made of any material that can temporarily join the PMUT unit and the auxiliary substrate 300, such as photoresist.
- Bonding material layer see Figure 4, which can be a metal bonding layer, such as gold-gold bonding, aluminum-germanium bonding, etc., or other material layers that bond two layers together.
- Micromachined ultrasound transducer structure or PMUT structure see Figure 1 and Figure 14).
- 1-4 are schematic structural diagrams of a micromachined ultrasound transducer structure 3000 according to different exemplary embodiments of the present invention.
- a single PMUT generally includes a support layer 210, a piezoelectric layer 230, and a top electrode layer 240 and a bottom electrode layer 220 on both sides of the piezoelectric layer 230 (see, for example, Figures 6 to 9).
- the PMUT vibrates Cavities 201 and 202 are provided on the side of the unit facing the CMOS, so that the PMUT vibration unit can generate effective bending vibration to generate ultrasonic waves.
- two types of ultrasonic transducers a piezoelectric material-based PMUT with a high voltage coefficient and a piezoelectric material-based PMUT with a low dielectric constant, are simultaneously integrated on a CMOS wafer or the transistor unit 1000 as shown in the figure.
- 230 and 270 respectively represent the high-voltage coefficient-based piezoelectric film and the low-dielectric constant-based piezoelectric film.
- 201 and 202 are respectively the cavity areas where the PMUT composed of two types of piezoelectric films undergoes effective bending vibration.
- 200 is a substrate for building a PMUT or a PMUT base
- 100 is a substrate for building a CMOS circuit or a transistor base
- 110 is a circuit protection layer.
- the absolute value of the piezoelectric coefficient of the piezoelectric layer 230 is greater than 1 C/m 2 , and/or the dielectric constant of the piezoelectric layer 270 is less than 1200. Further, the absolute value of the piezoelectric coefficient of the piezoelectric layer 230 is greater than 5C/m 2 , and/or the dielectric constant of the piezoelectric layer 270 is less than 100.
- piezoelectric layer 230 is PZT or doped PZT
- piezoelectric layer 270 is ALN or AlScN.
- the present invention produces CMOS wafers and PMUT wafers respectively, in which two types of piezoelectric film-based PMUTs are produced on the PMUT wafer, and then the substrate side of the PMUT wafer is thinned and combined with the CMOS The front side of the wafer is bonded, and finally the PMUT wafer electrodes are interconnected with the corresponding electrodes on the CMOS wafer to achieve electrical connection. If necessary, the surface of the device is protected (for details, please refer to the examples in Figures 5 to 13). gender description). In this integrated solution, when processing different types of piezoelectric film-based PMUTs, even if there are relatively harsh processing conditions, the CMOS wafer will not be damaged, and the process compatibility is good.
- the cavities can be formed by presetting the cavities, filling them with sacrificial layer materials, and releasing them in the final stage.
- Figure 2 shows the cavity formed by back-engraving.
- Figure 3 shows a piezoelectric film-based PMUT that uses a back-engraving method, and another piezoelectric film-based PMUT that uses a sacrificial layer to form a cavity.
- the PMUT wafer substrate layer can be directly bonded to the circuit protection layer of the CMOS wafer (for example, see Figure 1- Figure 3), or through an intermediate bonding layer material (such as Metal bonding, etc., corresponding to the bonding material layer 500) realizes the integration of the PMUT unit and the CMOS unit (see, for example, Figure 4).
- the PMUT unit includes two PMUTs spaced apart in the lateral direction, namely a first PMUT and a second PMUT.
- the piezoelectric coefficient of the piezoelectric layer 230 of the first PMUT is high.
- the piezoelectric coefficient of the piezoelectric layer 270 of the second PMUT, and the dielectric constant of the piezoelectric layer 230 of the first PMUT is lower than the dielectric constant of the piezoelectric layer 270 of the second PMUT.
- the piezoelectric layer 230 of the first PMUT is PZT and the piezoelectric layer 270 of the second PMUT is AlN.
- the PMUT substrate can be a substrate such as single crystal silicon, gallium nitride, gallium arsenide, sapphire, quartz, silicon carbide, diamond, etc., as shown in Figures 1 to 4,
- Other support structures for generating PMUT may also be used, which are all within the protection scope of the present invention.
- a PMUT-on-CMOS structure is adopted, but the present invention is not limited thereto.
- the above-mentioned PMUT unit can also be arranged on other structures, and PMUT-on-CMOS is an advantageous embodiment of the present invention.
- the first PMUT of the PMUT unit is used to transmit ultrasonic waves
- the second PMUT is used to receive ultrasonic waves.
- FIG. 5-13 are exemplary illustrations of the microcomputer shown in FIG. 2 according to an exemplary embodiment of the present invention.
- the piezoelectric layer 230 is made of PZT, and the low dielectric constant material 270 or the piezoelectric layer 270 of the second PMUT is made of AlN to construct a PMUT-on-CMOS ultrasonic transducer with ultra-high pulse-echo sensitivity.
- Transistor unit 1000 is provided first.
- Figure 5 is a schematic diagram of the CMOS structure, in which 100 is the CMOS substrate, that is, the transistor substrate (which can be silicon, etc.), and 110 is the circuit protection layer (which can be silicon oxide, silicon nitride, etc.).
- 101 is the source and drain of the transistor
- 111 is the gate of the transistor
- 113A, 113B, 113 and 115 are the electrical connection layers within the CMOS layer
- 112 and 114 are the electrical connection layers between the CMOS layers.
- the transistor unit includes a transistor substrate 100 and first and second transistors spaced apart in the lateral direction. It should be noted that the structure shown in Figure 2 is exemplary.
- the CMOS unit 1000 may include a CMOS transistor and a circuit protection layer 110, and may optionally include a first electrical connection layer 113A, a second electrical connection layer 113A, and a second electrical connection layer 113A. Connection layer 113B.
- the PMUT preliminary unit 2000' includes a PMUT preliminary base 200', a first PMUT and a second PMUT. Each PMUT includes a bottom electrode layer 220, a top electrode layer 240, and a piezoelectric layer 230. The following describes how to provide the PMUT preliminary unit 2000' with specific reference to Figures 6-9.
- a PZT-based PMUT is first formed on the support layer 210, where 200' is the PMUT substrate, that is, the PMUT initial substrate (which can be silicon), 210 is the support layer (can be silicon oxide, etc.), and 230 is PZT Piezoelectric film layer or piezoelectric layer, 220 and 240 are the bottom and top electrode layers on both sides of the piezoelectric film layer. MEMS technology can be used to form PZT-based PMUT.
- the initial substrate 200' here is relative to the substrate 200 in Figure 11. The initial substrate 200' becomes the substrate 200 after being thinned.
- a structural protective layer 250 is deposited on the surface of the PZT-based PMUT to protect the PZT-based PMUT during the subsequent processing of the AlN-based PMUT.
- an AlN-based PMUT is constructed on a wafer or initial substrate 200' provided with a PZT-based PMUT.
- the AlN-based PMUT includes a piezoelectric film layer or an ALN piezoelectric layer 270 and top and bottom electrode layers 280 and 260.
- the structural protection layer 250 of the PZT-based PMUT is removed to obtain the PMUT unit 2000 .
- the PMUT preliminary unit 2000' does not include an electrical connection structure that connects the PMUT electrodes and the CMOS electrodes together.
- the thickness of the PMUT preliminary substrate 200' in Figure 9 is too large and needs to be thinned in subsequent steps based on the subsequent thinning process to make the electrical connection part between the PMUT and CMOS as short as possible and requires bonding
- the thickness of the PMUT substrate on the CMOS wafer should be as thin as possible, preferably below 10 microns, or even below 5 microns.
- the subsequent substrate thinning step may not be performed, or if the length of the electrical connection part between the PMUT and CMOS can be tolerated, the subsequent substrate thinning step may not be performed. Thinning steps, these are all within the protection scope of the present invention.
- the following exemplifies how to bond the PMUT unit 2000 to the transistor unit 1000 with reference to FIGS. 10 and 11 .
- the PZT-based PMUT and the AlN-based PMUT are covered with a temporary adhesive layer 310 and an auxiliary substrate 300 is provided.
- the auxiliary substrate 300 is bonded to the temporary adhesive layer 310 .
- the auxiliary substrate 300 is provided for subsequent PMUT initial substrate thinning.
- a thinning process is performed on the other side of the initial substrate 200' to form the PMUT substrate 200.
- the auxiliary substrate 200' in Figure 10 can be thinned to a required size, for example, less than 10 ⁇ m, or even less than 5 ⁇ m, and can be surface polished if required by the bonding process. Then the cavities 201 and 202 required for PMUT vibration are etched through a back etching process, as shown in Figure 11.
- the PMUT substrate 200 is bonded to the surface of the transistor unit or the CMOS circuit protection layer 110, and the temporary adhesive layer 310 and the auxiliary substrate 300 are removed, as shown in FIG. 11 .
- Various bonding solutions can be selected, including silicon-silicon bonding, silicon-silicon oxide bonding, and metal bonding.
- the PMUT substrate 200 and the CMOS circuit protection layer 110 are etched through an etching process to form conductive holes, exposing the electrical connection terminals or the electrical connection layer of the CMOS.
- a first conductive hole 400A and a second conductive hole 400B are etched to expose the intra-transistor unit layer electrical connection layer 113A and the transistor unit layer intra-electrical connection layer 113B respectively.
- the first electrical connection layer 113A is electrically connected to one of the electrodes of the CMOS transistor (for example, the source), and the second electrical connection layer 113B is electrically connected to another one of the electrodes of the CMOS transistor (for example, the gate). .
- the first electrical connection layer 113A and/or the second electrical connection layer 113B can also be electrically connected thereto, which is also within the scope of the present invention. within the range.
- the electrical connection layers 235 and 275 of PMUT and CMOS are provided, Realize the electrical connection between PMUT and CMOS.
- a protective layer or device protection layer 290 is deposited over the entire device surface.
- 235 and 275 are electrical connection layers.
- Various conductive materials can be used, such as materials to form electrode layers.
- the conductive channel or electrical connection layer 235 used to connect the PZT-based PMUT and the CMOS circuit is similar to the material used to realize AlN.
- the conductive channel or electrical connection layer 275 that electrically connects the base PMUT to the CMOS may be of the same type of material or may be of different types of conductive materials.
- the electrical connection layers 235 and 275 are electrically insulated from each other, and both the electrical connection layers 235 and 275 are electrically connected to the transistor unit intra-layer electrical connection layer 113A and the intra-layer electrical connection layer 113B respectively through conductive holes. .
- the bonding between the PMUT unit and the transistor unit is achieved by providing the bonding material layer 500, then the PMUT unit, the transistor unit and the bonding material layer jointly define a cavity, and the bonding material layer 500 The thickness defines the height of the cavity.
- the PMUT substrate 200 is bonded to the circuit protection layer 110, as shown in Figure 1, that is, the base side (or back side) of the PMUT unit 2000 is bonded to the wafer side (or front side) of the CMOS unit 1000. , thus: (1) When PMUT needs to be prepared on the PMUT substrate 200 in subsequent steps, the PMUT substrate 200 can protect the CMOS unit 1000, or (2) the PMUT unit 2000 can be directly connected to the CMOS unit 1000 without considering the preparation of PMUT. impact on the CMOS unit 1000.
- micromechanical ultrasonic transducer structure highly adaptable to piezoelectric materials, which can be aluminum nitride (AlN), lead zirconate titanate (PZT), or lithium niobate (LiNbO 3 ) , lithium tantalate (LiTaO 3 ), potassium niobate (KNbO 3 ) and other materials.
- AlN aluminum nitride
- PZT lead zirconate titanate
- LiNbO 3 lithium niobate
- LiTaO 3 lithium tantalate
- KNbO 3 potassium niobate
- the "bonding of the PMUT substrate and the circuit protection layer" in the present invention not only includes the direct bonding of the two as shown in Figure 1, but also includes other bonding layers or film layers provided between the two.
- a bonding material layer 500 which may be a metal bonding layer, is provided between the PMUT substrate and the circuit protection layer.
- connection between the PMUT substrate and the circuit protection layer is taken as an example for illustration.
- connection between the PMUT substrate and the CMOS unit 1000 may be to define the surface of the CMOS unit.
- the circuit protection layer which may also be other layers defining the surface of the CMOS unit, is within the scope of the present invention.
- the CMOS unit 1000 further includes a CMOS substrate 100 , one side of the circuit protection layer 110 is bonded to the PMUT substrate 200 , and the other side of the circuit protection layer 110 is bonded to the CMOS substrate 100 .
- the PMUT unit can also be bonded to the CMOS substrate 100, which is also within the protection scope of the present invention.
- CMOS is used as an example of a transistor, and thus a CMOS unit is used as an example of a transistor unit.
- the transistor can also be a BiMOS unit or BCD, etc., so that a transistor
- the unit can also be a BiMOS unit or a BCD unit, etc.
- the "surface bonding of the PMUT unit and the transistor unit” in the present invention may be the case where the PMUT unit is directly bonded to the surface of the transistor unit, and may also include The situation where other bonding layers or film layers are provided between the surface of the unit and the transistor unit are within the scope of protection of the present invention.
- the PMUT substrate 200 is provided with a cavity 201 for the PMUT. That is, in the case where the PMUT unit 2000 is used to bond with the CMOS unit 1000, the cavity 201 has been set in the PMUT unit 2000. In other words, in wafer-level manufacturing, the cavity structure required for PMUT vibration is set on the side of the PMUT wafer, and there is no need to form a cavity on the CMOS wafer. Therefore, there is no alignment problem during the integration process between the CMOS wafer and the PMUT wafer.
- cavity 201 may extend through PMUT substrate 200 .
- the PMUT substrate 200 is provided with a cavity 201 for the PMUT.
- the cavity 201 may not be provided in the PMUT substrate 200.
- a bonding material layer 500 is provided between the PMUT unit 2000 and the transistor unit.
- the PMUT unit 2000, the transistor unit 1000 and the bonding material layer 500 jointly define the cavity 201.
- the thickness of the bonding material layer 500 defines the height of the cavity 201 . In this way, in wafer-level manufacturing, the cavity 201 required for PMUT vibration does not need to be formed on the CMOS wafer, and the bonding material layer 500 based on, for example, a metal bonding layer can define the sides of the cavity 201 in the lateral direction.
- the area of the cavity 201 is larger, which can reduce the changes in the vibration area caused by the alignment deviation during the integration process of the CMOS wafer and the PMUT wafer, and the resulting changes in the frequency of the ultrasonic transducer, overcoming or reducing
- the integration process of CMOS and PMUT adversely affects the cavity size.
- the cavity 201 is located on the side of the joint surface where the PMUT unit is installed. The formation of the cavity 201 will not cause additional changes to the structure of the transistor unit. There is no need to set a cavity in the transistor unit before integrating the two. , reducing or avoiding the technical problem in the prior art that the integration process of the CMOS unit and the PMUT unit has an adverse impact on the cavity size.
- the micromachined ultrasonic transducer structure is provided with a first conductive hole 400A and a second conductive hole 400B.
- the first conductive hole 400A through The second conductive hole 400B penetrates the PMUT substrate 200 and/or the support layer 210 and reaches the first electrical connection layer 113A in the circuit protection layer 110.
- Two electrical connection layers 113B wherein: the first conductive layer 235 is electrically connected to the first electrical connection layer 113A through the first conductive hole 400A, and the second conductive layer 275 is electrically connected to the second electrical connection layer 113B through the second conductive hole 400B. connect.
- the PMUT unit 2000 includes a support layer 210, and the support layer 210 is used to realize the bending vibration of the PMUT.
- the support layer 210 is provided between the PMUT (including the electrode layers 220, 240 and the piezoelectric layer 230) and the PMUT substrate 200.
- the first conductive hole 400A and the second conductive hole 400B Through the support layer 210.
- the support layer 210 may not be provided, or the support layer 210 may be provided above the top electrode or the first electrode layer 240. In this case, the first conductive hole 400A and the second conductive hole 400B do not use or have no through support. layer situation.
- the first conductive holes 400A and the second conductive holes 400B need to penetrate the PMUT unit to reach the underlying electrical connection layer.
- first conductive layer 235 and the second conductive layer 275 may be electrically connected to the first electrical connection layer 113A and the second electrical connection layer 113B exposed on the side of the micromachined ultrasonic transducer structure, respectively. It is also within the protection scope of the present invention.
- the cavity plays a protective role in isolating the PMUT (especially the piezoelectric layer) from the external environment, which can improve the reliability and long-term stability of the PMUT, and then be used in the above-mentioned PMUT structure.
- the reliability and long-term stability of the final imaging system can be improved.
- FIG 14 is a schematic diagram of a PMUT structure array according to an exemplary embodiment of the present invention.
- the above-mentioned PMUT structure 3000 may be only one array element in the array 4000.
- the hollow circle represents the PMUT vibration area of the PMUT structure 3000. In addition to the circle, it can be any desired shape such as an ellipse, a polygon, and a combination thereof.
- the solid black circle represents the electrical connection between the PMUT unit and the CMOS unit, as shown in Figure 5 at the first electrical connection layer 113A and the second electrical connection layer 113B, which can also be in any desired shape.
- the PMUT structures 3000 are combined to form a PMUT structure array 4000.
- Each PMUT unit can be individually controlled through a matching CMOS circuit to form a two-dimensional PMUT structure array 4000.
- Multiple PMUT structures 3000 can also be connected together.
- the electrodes of the PMUT structures 3000 on the same column are interconnected to form a one-dimensional line array.
- the circuit of the CMOS unit and the electrical connection point of the PMUT unit Reduce, the electrical connection points of a pair of CMOS units and PMUT units control multiple PMUT units simultaneously.
- An ultrasonic transducer can be formed based on a PMUT structure or a PMUT structure array.
- the ultrasonic transducer can be used in an ultrasonic imager.
- the PMUT structure or PMUT structure array can also be used in other electronic devices, such as ultrasonic rangefinders, Ultrasonic fingerprint sensors, non-destructive flaw detectors used in industrial fields, etc.
- a micromechanical ultrasonic transducer structure including:
- the PMUT unit includes a PMUT substrate, a first PMUT and a second PMUT.
- Each PMUT includes a first electrode layer, a second electrode layer and a piezoelectric layer,
- the first PMUT and the second PMUT are laterally spaced apart from each other and arranged on one side of the PMUT substrate;
- the piezoelectric coefficient of the piezoelectric layer of the first PMUT is higher than the piezoelectric coefficient of the piezoelectric layer of the second PMUT, and the dielectric constant of the piezoelectric layer of the first PMUT is lower than the dielectric constant of the piezoelectric layer of the second PMUT.
- the piezoelectric layer of the first PMUT is PZT or doped PZT, and the piezoelectric layer of the second PMUT is ALN or AlScN.
- the first PMUT is used to transmit ultrasonic waves
- the second PMUT is used to receive ultrasonic waves.
- micromechanical ultrasonic transducer structure according to any one of 1-3, also includes:
- a transistor unit including a transistor substrate and a first transistor and a second transistor arranged spaced apart in a lateral direction, the first PMUT and the second PMUT being respectively aligned with the first transistor and the second transistor in the thickness direction of the micromachined ultrasonic transducer structure corresponding;
- the PMUT unit is bonded to a surface on one side of the transistor unit, and the surface on one side of the transistor unit is the bonding surface of the transistor unit.
- micromechanical ultrasonic transducer structure according to 4, wherein:
- the cavities for the first PMUT and the second PMUT are on the side of the joint surface on which the PMUT units are disposed.
- micromechanical ultrasonic transducer structure according to 5, wherein:
- the PMUT substrate is bonded to the surface of one side of the transistor cell, the PMUT substrate being provided with the cavity.
- the PMUT unit also includes a support layer for supporting the PMUT, and the support layer is disposed between the two PMUTs and the PMUT substrate.
- the cavity penetrates the PMUT substrate
- a bonding material layer is provided between the PMUT unit and the transistor unit.
- the PMUT unit, the transistor unit and the bonding material layer jointly define the cavity.
- the thickness of the bonding material layer defines the cavity. high.
- micromechanical ultrasonic transducer structure according to 4, wherein:
- Each transistor unit includes the transistor, a first electrical connection layer and a second electrical connection layer electrically insulated from each other;
- the micromachined ultrasonic transducer structure further includes a first conductive layer and a second conductive layer that are electrically insulated from each other, and the first electrode layer is electrically connected to the first electrical connection layer through the first conductive layer. connection, the second electrode layer is electrically connected to the second electrical connection layer via the second conductive layer.
- each PMUT and corresponding transistor it also includes:
- a first conductive hole and a second conductive hole The first conductive hole penetrates the PMUT unit and reaches the first electrical connection layer in the transistor unit.
- the first conductive layer is electrically connected to the first electrical connection layer through the first conductive hole
- the second conductive layer is electrically connected to the second electrical connection layer through the second conductive hole.
- micromechanical ultrasonic transducer structure according to 4, wherein:
- the transistor unit includes a circuit protection layer covering the transistor
- the surface on one side of the circuit protection layer is the joint surface.
- micromechanical ultrasonic transducer structure according to 4, wherein:
- the transistor unit includes one of a CMOS unit, a BiMOS unit, and a BCD unit.
- the absolute value of the piezoelectric coefficient of the piezoelectric layer of the first PMUT is greater than 1C/m 2 ;
- the dielectric constant of the piezoelectric layer of the second PMUT is less than 1200.
- micromechanical ultrasonic transducer structure according to 13, wherein:
- the absolute value of the piezoelectric coefficient of the piezoelectric layer of the first PMUT is greater than 5C/m 2 ;
- the dielectric constant of the piezoelectric layer of the second PMUT is less than 100.
- a method for manufacturing a micromechanical ultrasonic transducer structure including the steps:
- a transistor unit including a transistor substrate and first and second transistors arranged spaced apart in a lateral direction;
- a PMUT unit bonded to a surface of one side of the transistor unit includes a PMUT substrate, a first PMUT and a second PMUT.
- the PMUT base is bonded to the surface of one side of the transistor unit in a surface bonding manner.
- Each PMUT includes a third PMUT. an electrode layer, a second electrode layer and a piezoelectric layer,
- the first PMUT and the second PMUT are laterally spaced apart from each other and arranged on one side of the PMUT substrate, and respectively correspond to the first transistor and the second transistor in the thickness direction of the micromachined ultrasound transducer structure;
- the piezoelectric coefficient of the piezoelectric layer of the first PMUT is higher than the piezoelectric coefficient of the piezoelectric layer of the second PMUT, and the dielectric constant of the piezoelectric layer of the first PMUT is lower than the dielectric constant of the piezoelectric layer of the second PMUT.
- step of providing the PMUT unit includes:
- step of providing the PMUT unit includes:
- the method further includes the step of removing the temporary adhesive layer and the auxiliary substrate.
- the PMUT substrate is bonded to the surface of one side of the transistor unit using a bonding material layer.
- the PMUT unit, the transistor unit and the bonding material layer jointly define the cavity.
- the thickness of the bonding material layer defines the cavity. cavity height.
- the transistor unit For each transistor, the transistor unit includes a first electrical connection layer and a second electrical connection layer that are electrically insulated from each other;
- the method further includes the steps of: for each PMUT and the corresponding transistor, providing a first conductive layer and a second conductive layer that are electrically insulated from each other, the first electrode layer is electrically connected to the first electrical connection layer via the first conductive layer, and The two electrode layers are electrically connected to the second electrical connection layer through the second conductive layer.
- the method further includes the step of forming a first conductive hole and a second conductive hole, and the first conductive hole penetrates the PMUT unit and reaches to expose the inside of the transistor unit.
- the first electrical connection layer, the second conductive hole penetrates the PMUT unit and reaches to expose the second electrical connection layer in the transistor unit;
- the first conductive layer is electrically connected to the first electrical connection layer through the first conductive hole
- the second conductive layer is electrically connected to the first conductive layer through the second conductive hole.
- the two electrical connection layers are electrically connected.
- Providing a transistor unit includes providing a transistor wafer based on a MEMS process, the transistor wafer being formed with a plurality of transistor units, each transistor unit including a first transistor and a second transistor arranged spaced apart in a lateral direction;
- Providing a PMUT unit bonded to the surface of one side of the transistor unit includes: providing a PMUT wafer based on the MEMS process, the PMUT wafer is formed with a plurality of PMUT units respectively corresponding to the plurality of transistor units, each PMUT unit including a first PMUT and a second PMUT arranged laterally spaced apart from each other, the first PMUT and the second PMUT respectively corresponding to the first transistor and the second transistor in the thickness direction of the micromechanical ultrasonic transducer structure;
- the method also includes the step of performing cutting to form a micromachined ultrasound transducer structure including a single PMUT unit and a single transistor unit.
- the piezoelectric layer of the first PMUT is PZT or doped PZT, and the piezoelectric layer of the second PMUT is AlN or AlScN.
- the first PMUT is used to transmit ultrasonic waves
- the second PMUT is used to receive ultrasonic waves.
- the transistor unit includes one of a CMOS unit, a BiMOS unit, and a BCD unit.
- the absolute value of the piezoelectric coefficient of the piezoelectric layer of the first PMUT is greater than 1C/m 2 ;
- the dielectric constant of the piezoelectric layer of the second PMUT is less than 1200.
- the absolute value of the piezoelectric coefficient of the piezoelectric layer of the first PMUT is greater than 5C/m 2 ;
- the dielectric constant of the piezoelectric layer of the second PMUT is less than 100.
- An electronic device including the micromachined ultrasonic transducer structure according to any one of 1-14, or the micromachined ultrasonic transducer structure manufactured according to the manufacturing method according to any one of 15-26 .
- the electronic device includes at least one of the following: an ultrasonic imager, an ultrasonic range finder, an ultrasonic fingerprint sensor, a non-destructive flaw detector, a flow meter, a force feedback device, and a smoke alarm.
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Abstract
The present invention relates to a micromachined ultrasonic transducer structure and a manufacturing method therefor. The micromachined ultrasonic transducer structure comprises a PMUT unit; the PMUT unit comprises a PMUT substrate, a first PMUT, and a second PMUT; each PMUT comprises a first electrode layer, a second electrode layer, and a piezoelectric layer, wherein the first PMUT and the second PMUT are arranged as laterally spaced apart at one side of the PMUT substrate; the piezoelectric coefficient of the piezoelectric layer of the first PMUT is higher than the piezoelectric coefficient of the piezoelectric layer of the second PMUT; and the permittivity of the piezoelectric layer of the first PMUT is lower than the permittivity of the piezoelectric layer of the second PMUT. The present invention further relates to an electronic device comprising the present micromachined ultrasonic transducer structure.
Description
本发明的实施例涉及半导体领域,尤其涉及一种基底同侧设置有双PMUT(Piezoelectric Micromachined Ultrasonic Transducer,PMUT)的微机械超声换能器结构及其制造方法、一种具有该微机械超声换能器结构的电子设备。Embodiments of the present invention relate to the field of semiconductors, and in particular to a micromachined ultrasonic transducer structure with dual PMUTs (Piezoelectric Micromachined Ultrasonic Transducer, PMUT) disposed on the same side of the base and a manufacturing method thereof, and a micromachined ultrasonic transducer having the same electronic equipment.
超声换能器作为一种电声元件广泛应用于生产生活中。超声换能器通过发射超声波至外界环境,并通过超声换能器接收反射回来的超声波转换为电信号进行传感、成像以及对外界环境的作用。超声换能器的典型应用包括指纹识别、超声成像、超声雷达和测距、无损检测、流量测量、力觉反馈等,在人体成像、汽车倒车雷达、水下声纳探测、扫地机器人、超声烟雾报警器等场景都会用到。上述应用中,均涉及超声换能器的超声信号发射及超声信号回波的接收,因此超声换能器的发射灵敏度以及接收灵敏度在很大程度上决定了超声换能器的优劣,是上述应用场景下的关键指标。As an electroacoustic component, ultrasonic transducer is widely used in production and life. The ultrasonic transducer emits ultrasonic waves to the external environment, and receives the reflected ultrasonic waves through the ultrasonic transducer and converts them into electrical signals for sensing, imaging, and acting on the external environment. Typical applications of ultrasonic transducers include fingerprint recognition, ultrasonic imaging, ultrasonic radar and ranging, non-destructive testing, flow measurement, force feedback, etc., in human body imaging, car reversing radar, underwater sonar detection, sweeping robots, ultrasonic smoke It will be used in scenes such as alarms. The above applications all involve the transmission of ultrasonic signals and the reception of ultrasonic signal echoes by the ultrasonic transducer. Therefore, the transmitting sensitivity and receiving sensitivity of the ultrasonic transducer determine the quality of the ultrasonic transducer to a large extent. The above-mentioned Key indicators in application scenarios.
利用传统机械切割方案制造超声换能器,在振动单元的尺寸微型化方面,以及生产成本、效率及产品一致性和良率等方面受限,不能满足超声成像仪进一步发展,特别是在低成本、便携化、高分辨率等方面的需求。The use of traditional mechanical cutting solutions to manufacture ultrasonic transducers is limited in terms of miniaturization of the size of the vibration unit, production cost, efficiency, product consistency and yield, etc., and cannot satisfy the further development of ultrasonic imagers, especially in low-cost, Portability, high resolution, etc.
基于半导体工业的MEMS制造技术是高效、低成本、批量化生产小尺寸器件的非常有效的方式。利用MEMS技术开发的超声换能器主要基于电容式和压电式两种原理,分别对应于电容式微机械超声换能器(Capacitive Micromachined Ultrasonic Transducer,CMUT)和压电式微机械超声换能器(PMUT),他们能够与互补金属氧化物半导体(Complementary Metal Oxide Semiconductor,CMOS)电路集成,实现具有高集成度、强运算能力的微型超声换能器的低成本、一致性和规模化制造。在这两种换能器中,CMUT工作时需要施加较大偏置电压,致使功耗较高,应用受到一定限制。相比而言,PMUT是一种很有前途的方案。其中PMUT与CMOS的有效集成是实现上述超声换能器的至关重要的因素。
MEMS manufacturing technology based on the semiconductor industry is a very effective way to produce small-size devices with high efficiency, low cost, and mass production. Ultrasonic transducers developed using MEMS technology are mainly based on two principles: capacitive and piezoelectric, corresponding to capacitive micromachined ultrasonic transducer (CMUT) and piezoelectric micromachined ultrasonic transducer (PMUT) respectively. ), they can be integrated with complementary metal oxide semiconductor (Complementary Metal Oxide Semiconductor, CMOS) circuits to achieve low-cost, consistent and large-scale manufacturing of micro-ultrasound transducers with high integration and strong computing capabilities. Among these two transducers, the CMUT needs to apply a large bias voltage when working, resulting in high power consumption and certain limitations in application. In comparison, PMUT is a promising solution. The effective integration of PMUT and CMOS is a crucial factor in realizing the above-mentioned ultrasonic transducer.
压电式微机械超声换能器PMUT的发射灵敏度和接收灵敏度作为关键性能指标,对PMUT应用于上述多种场景起到至关重要的作用,发射灵敏度和接收灵敏度过低将影响信号信噪比,最终导致系统无法工作或性能低下。As key performance indicators, the transmitting sensitivity and receiving sensitivity of the piezoelectric micromachined ultrasonic transducer PMUT play a vital role in the application of PMUT in the above-mentioned scenarios. If the transmitting sensitivity and receiving sensitivity are too low, the signal signal-to-noise ratio will be affected. Eventually the system becomes inoperable or performs poorly.
PMUT通常呈弯曲振动模式。作为超声发射器时,在压电薄膜两侧的电极上施加交变电场,由于逆压电效应导致压电层中产生横向应力,进而产生一个弯曲力矩,迫使薄膜偏离平面,向周围介质中发射声压波。如公式(1)所示,弯曲振动的PMUT的超声发射灵敏度ST正比于压电薄膜的压电系数е31f:
ST∝e31f (1)PMUT usually exhibits bending vibration mode. When used as an ultrasonic transmitter, an alternating electric field is applied to the electrodes on both sides of the piezoelectric film. Due to the inverse piezoelectric effect, transverse stress is generated in the piezoelectric layer, which in turn generates a bending moment, forcing the film to deviate from the plane and emit into the surrounding medium. Sound pressure wave. As shown in formula (1), the ultrasonic emission sensitivity S T of the flexural vibration PMUT is proportional to the piezoelectric coefficient е 31f of the piezoelectric film:
S T ∝e 31f (1)
ST∝e31f (1)PMUT usually exhibits bending vibration mode. When used as an ultrasonic transmitter, an alternating electric field is applied to the electrodes on both sides of the piezoelectric film. Due to the inverse piezoelectric effect, transverse stress is generated in the piezoelectric layer, which in turn generates a bending moment, forcing the film to deviate from the plane and emit into the surrounding medium. Sound pressure wave. As shown in formula (1), the ultrasonic emission sensitivity S T of the flexural vibration PMUT is proportional to the piezoelectric coefficient е 31f of the piezoelectric film:
S T ∝e 31f (1)
当PMUT作为超声接收器时,入射超声波使压电薄膜偏转产生横向应力,由于正压电效应,在压电薄膜两侧的电极上集聚电荷,形成电压信号,如公式(2)所示,其接收灵敏度SR正比于压电系数е31f与介电常数ε33的比值;
SR∝e31f/ε33 (2)When the PMUT is used as an ultrasonic receiver, the incident ultrasonic wave deflects the piezoelectric film to generate lateral stress. Due to the positive piezoelectric effect, charges are accumulated on the electrodes on both sides of the piezoelectric film to form a voltage signal, as shown in formula (2). The receiving sensitivity S R is proportional to the ratio of the piezoelectric coefficient е 31f and the dielectric constant ε 33 ;
S R ∝e 31f /ε 33 (2)
SR∝e31f/ε33 (2)When the PMUT is used as an ultrasonic receiver, the incident ultrasonic wave deflects the piezoelectric film to generate lateral stress. Due to the positive piezoelectric effect, charges are accumulated on the electrodes on both sides of the piezoelectric film to form a voltage signal, as shown in formula (2). The receiving sensitivity S R is proportional to the ratio of the piezoelectric coefficient е 31f and the dielectric constant ε 33 ;
S R ∝e 31f /ε 33 (2)
超声成像中,超声换能器探头既做发射器向外发射超声波,又作为接受器,接受从待成像对象处反射回来的超声波,工作模式通常是脉冲-回波模式,如公式(3)所示,PMUT脉冲-回波灵敏度ST·SR正比于压电系数е31的平方与介电常数ε33的比值。
In ultrasonic imaging, the ultrasonic transducer probe not only serves as a transmitter to emit ultrasonic waves, but also as a receiver to receive ultrasonic waves reflected back from the object to be imaged. The working mode is usually pulse-echo mode, as shown in formula (3). shows that the PMUT pulse-echo sensitivity S T · S R is proportional to the ratio of the square of the piezoelectric coefficient е 31 to the dielectric constant ε 33 .
In ultrasonic imaging, the ultrasonic transducer probe not only serves as a transmitter to emit ultrasonic waves, but also as a receiver to receive ultrasonic waves reflected back from the object to be imaged. The working mode is usually pulse-echo mode, as shown in formula (3). shows that the PMUT pulse-echo sensitivity S T · S R is proportional to the ratio of the square of the piezoelectric coefficient е 31 to the dielectric constant ε 33 .
压电系数和介电常数是压电材料的基本特性,表1列举了常见压电材料中PZT和AlN的压电系数和介电常数特性。Piezoelectric coefficient and dielectric constant are the basic properties of piezoelectric materials. Table 1 lists the piezoelectric coefficient and dielectric constant properties of PZT and AlN among common piezoelectric materials.
表1.常见压电材料中PZT和AlN的性质
Table 1. Properties of PZT and AlN in common piezoelectric materials
Table 1. Properties of PZT and AlN in common piezoelectric materials
比较PZT和AlN两种压电材料可知,当仅作为发射超声波探头使用时,PZT的压电常数比AlN的高10倍,基于公式(1),PZT基PMUT的发射灵敏度将是AlN基PMUT的10倍。Comparing the two piezoelectric materials PZT and AlN, it can be seen that when used only as a transmitting ultrasonic probe, the piezoelectric constant of PZT is 10 times higher than that of AlN. Based on formula (1), the emission sensitivity of PZT-based PMUT will be that of AlN-based PMUT. 10 times.
然而,仅仅作为接收超声波的探头使用时,PZT的介电常数是AlN的约110
倍,因此PZT基PMUT的接收灵敏度将是AlN基PMUT的约十二分之一。在同时做发射和接收模式的超声探头时,利用PZT或者AlN单一压电材料时,如表1所示,其所开发的PMUT的脉冲-回波(发射-接收)信号的灵敏度相当。However, when used only as a probe for receiving ultrasonic waves, the dielectric constant of PZT is about 110 times that of AlN. times, so the receiving sensitivity of PZT-based PMUT will be about one-twelfth that of AlN-based PMUT. When using an ultrasonic probe in both transmitting and receiving modes, using PZT or AlN as a single piezoelectric material, as shown in Table 1, the sensitivity of the pulse-echo (transmit-receive) signal of the PMUT developed is equivalent.
因此,单一压电材料难以满足同时具有高压电系数和低介电常数的特性,基于单一压电材料的例如PMUT-on-CMOS器件不能实现同时具有超高超声波发射强度和超高超声接收灵敏度的应用需求。Therefore, it is difficult for a single piezoelectric material to meet the characteristics of both high voltage coefficient and low dielectric constant. Devices such as PMUT-on-CMOS based on a single piezoelectric material cannot achieve ultra-high ultrasonic emission intensity and ultra-high ultrasonic receiving sensitivity at the same time. application requirements.
此外,PMUT制造流程包含多种薄膜(比如压电薄膜、电极薄膜等)在不同温度下的沉积以及相应薄膜在不同气氛、液体环境的刻蚀,这些加工流程可能对CMOS电路造成破坏。另外不同压电材料的薄膜化、图案化工艺及在薄膜两侧沉积的电极材料也存在极大不同,因此在同一衬底上加工两种材质的PMUT存在工艺不兼容问题。这导致在同一片晶圆上依次逐层制作不同压电薄膜基PMUT存在很大的风险和难度,需要开发一种工艺兼容性强、便捷的含有不同类型压电材料的PMUT-on-CMOS集成方案。In addition, the PMUT manufacturing process includes the deposition of various films (such as piezoelectric films, electrode films, etc.) at different temperatures and the etching of corresponding films in different atmospheres and liquid environments. These processing processes may cause damage to CMOS circuits. In addition, the thinning and patterning processes of different piezoelectric materials and the electrode materials deposited on both sides of the film are also very different. Therefore, there is a process incompatibility problem when processing PMUTs of two materials on the same substrate. This leads to great risks and difficulties in fabricating PMUTs based on different piezoelectric films layer by layer on the same wafer. It is necessary to develop a PMUT-on-CMOS integration with strong process compatibility and convenience that contains different types of piezoelectric materials. plan.
发明内容Contents of the invention
为缓解或解决现有技术中的上述问题的至少一个方面,提出本发明。In order to alleviate or solve at least one aspect of the above-mentioned problems in the prior art, the present invention is proposed.
本发明的实施例涉及一种微机械超声换能器结构,包括:Embodiments of the present invention relate to a micromechanical ultrasonic transducer structure, including:
PMUT单元,包括PMUT基底、第一PMUT和第二PMUT,每个PMUT包括第一电极层、第二电极层与压电层,The PMUT unit includes a PMUT substrate, a first PMUT and a second PMUT. Each PMUT includes a first electrode layer, a second electrode layer and a piezoelectric layer,
其中:in:
第一PMUT和第二PMUT在横向上彼此间隔开设置在PMUT基底的一侧;The first PMUT and the second PMUT are laterally spaced apart from each other and arranged on one side of the PMUT substrate;
第一PMUT的压电层的压电系数高于第二PMUT的压电层的压电系数,且第一PMUT的压电层的介电常数低于第二PMUT的压电层的介电常数。The piezoelectric coefficient of the piezoelectric layer of the first PMUT is higher than the piezoelectric coefficient of the piezoelectric layer of the second PMUT, and the dielectric constant of the piezoelectric layer of the first PMUT is lower than the dielectric constant of the piezoelectric layer of the second PMUT. .
本发明的实施例还涉及一种微机械超声换能器结构的制造方法,包括步骤:Embodiments of the present invention also relate to a method for manufacturing a micromechanical ultrasonic transducer structure, which includes the steps:
提供晶体管单元,晶体管单元包括晶体管基底以及在横向方向上间隔开布置的第一晶体管和第二晶体管;以及A transistor unit is provided, the transistor unit including a transistor substrate and first and second transistors arranged spaced apart in a lateral direction; and
提供与晶体管单元的一侧的表面接合的PMUT单元,PMUT单元包括PMUT基底、第一PMUT和第二PMUT,PMUT基底与晶体管单元的一侧的表面以面接合的方式接合,每个PMUT包括第一电极层、第二电极层与压电层,A PMUT unit bonded to a surface of one side of the transistor unit is provided. The PMUT unit includes a PMUT substrate, a first PMUT and a second PMUT. The PMUT base is bonded to the surface of one side of the transistor unit in a surface bonding manner. Each PMUT includes a third PMUT. an electrode layer, a second electrode layer and a piezoelectric layer,
其中:
in:
第一PMUT和第二PMUT在横向上彼此间隔开设置在PMUT基底的一侧,且分别与第一晶体管和第二晶体管在微机械超声换能器结构的厚度方向上对应;且The first PMUT and the second PMUT are laterally spaced apart from each other and arranged on one side of the PMUT substrate, and respectively correspond to the first transistor and the second transistor in the thickness direction of the micromachined ultrasound transducer structure; and
第一PMUT的压电层的压电系数高于第二PMUT的压电层的压电系数,第一PMUT的压电层的介电常数低于第二PMUT的压电层的介电常数。The piezoelectric coefficient of the piezoelectric layer of the first PMUT is higher than the piezoelectric coefficient of the piezoelectric layer of the second PMUT, and the dielectric constant of the piezoelectric layer of the first PMUT is lower than the dielectric constant of the piezoelectric layer of the second PMUT.
本发明的实施例还涉及一种电子设备,包括上述的微机械超声换能器结构,或者上述制造方法制造的微机械超声换能器结构。Embodiments of the present invention also relate to an electronic device, including the above-mentioned micro-machined ultrasonic transducer structure, or the micro-machined ultrasonic transducer structure manufactured by the above-mentioned manufacturing method.
以下描述与附图可以更好地帮助理解本发明所公布的各种实施例中的这些和其他特点、优点,图中相同的附图标记始终表示相同的部件,其中:These and other features and advantages of various disclosed embodiments of the present invention may be better aided in understanding by the following description and accompanying drawings, in which like reference numerals refer to like parts throughout, wherein:
图1-图4为根据本发明的不同示例性实施例的微机械超声换能器结构的结构示意图;1-4 are schematic structural diagrams of micromachined ultrasound transducer structures according to different exemplary embodiments of the present invention;
图5-13为根据本发明的一个示例性实施例的示例性示出图2所示的微机械超声换能器结构的制造方法的截面示意图;5-13 are schematic cross-sectional views illustrating a manufacturing method of the micromachined ultrasonic transducer structure shown in FIG. 2 according to an exemplary embodiment of the present invention;
图14为根据本发明的一个示例性实施例的PMUT结构阵列的示意图。Figure 14 is a schematic diagram of a PMUT structure array according to an exemplary embodiment of the present invention.
下面通过实施例,并结合附图,对本发明的技术方案作进一步具体的说明。在说明书中,相同或相似的附图标号指示相同或相似的部件。下述参照附图对本发明实施方式的说明旨在对本发明的总体发明构思进行解释,而不应当理解为对本发明的一种限制。发明的一部分实施例,而并不是全部的实施例。基于本发明中的实施例,本领域普通技术人员所获得的所有其他实施例,都属于本发明保护的范围。The technical solution of the present invention will be further described in detail below through examples and in conjunction with the accompanying drawings. In the specification, the same or similar reference numbers indicate the same or similar components. The following description of the embodiments of the present invention with reference to the accompanying drawings is intended to explain the general inventive concept of the present invention and should not be understood as a limitation of the present invention. Some, but not all, embodiments of the invention. Based on the embodiments of the present invention, all other embodiments obtained by those of ordinary skill in the art fall within the scope of protection of the present invention.
发明人发现,如果用具有高压电系数的压电材料基PMUT作为超声发射器,低介电常数的压电材料基PMUT作为超声接收器,比如在一套超声换能器上共同集成如表1所示的PZT基PMUT和AlN基PMUT,其中PZT基PMUT作为超声发射器,AlN基PMUT作为超声接收器,则其脉冲-回波灵敏度将较单一材料基PMUT高100倍。The inventor found that if a piezoelectric material-based PMUT with a high voltage coefficient is used as an ultrasonic transmitter and a piezoelectric material-based PMUT with a low dielectric constant is used as an ultrasonic receiver, for example, they can be integrated on a set of ultrasonic transducers as shown in the table below. For the PZT-based PMUT and AlN-based PMUT shown in 1, where the PZT-based PMUT is used as the ultrasonic transmitter and the AlN-based PMUT is used as the ultrasonic receiver, its pulse-echo sensitivity will be 100 times higher than that of a single material-based PMUT.
此外,现有PMUT与CMOS的集成主要是通过如下两种方案实现的:In addition, the existing integration of PMUT and CMOS is mainly achieved through the following two solutions:
方案1.以CMOS晶圆为基片,对其进行各种薄膜沉积和刻蚀流程加工,然
而PMUT制造流程包含多种薄膜(比如压电薄膜、电极薄膜等)在不同温度下的沉积以及相应薄膜在不同气氛、液体环境的刻蚀,这就需要该加工工艺流程不对CMOS电路造成破坏。目前已知压电材料中,仅有AlN基压电材料等少数几种压电薄膜的MEMS制造流程与CMOS兼容,故而这种方案主要用于相应压电材料基集成化超声换能器的开发。然而压电薄膜的压电特性是PMUT性能的至关重要的决定部分,比如PZT、LiNbO3等具有非常优异压电特性的压电材料,其加工工艺较AlN苛刻,与CMOS兼容性较差,故而基于上述工艺流程的CMOS集成化PMUT的开发受限较多,很难实现。Plan 1. Use the CMOS wafer as the substrate, perform various thin film deposition and etching processes on it, and then The PMUT manufacturing process includes the deposition of various films (such as piezoelectric films, electrode films, etc.) at different temperatures and the etching of corresponding films in different atmospheres and liquid environments. This requires that the processing process does not cause damage to the CMOS circuit. Among known piezoelectric materials, only a few piezoelectric films such as AlN-based piezoelectric materials have MEMS manufacturing processes that are compatible with CMOS. Therefore, this solution is mainly used for the development of integrated ultrasonic transducers based on corresponding piezoelectric materials. . However, the piezoelectric properties of the piezoelectric film are a crucial determinant of PMUT performance. For example, piezoelectric materials with very excellent piezoelectric properties such as PZT and LiNbO 3 have more demanding processing techniques than AlN and poor compatibility with CMOS. Therefore, the development of CMOS integrated PMUT based on the above process flow is very limited and difficult to achieve.
方案2.分别加工PMUT晶圆和CMOS晶圆,设定PMUT晶圆的设置压电薄膜的一侧以及CMOS晶圆的设置晶体管的一侧为相应晶圆的正面,将PMUT晶圆的正面和CMOS正面键合,构建CMOS集成化PMUT。与上述方案1相比,该方案对压电材料的局限性较小,然而,PMUT机械振动单元的有效振动是高效地发射和接受超声波的关键,这需要振动单元下方含有空腔结构,提供空间供振动单元有效振动,这需要CMOS上含有相应空腔。然而空腔尺寸是决定PMUT超声频率的核心要素,空腔尺寸的变化将导致PMUT超声频率的变化。在PMUT和CMOS两片晶圆键合时,不可避免的存在对准偏差,导致振动单元区域与本身设计之间存在随机偏差,造成所开发的CMOS集成化PMUT的频率波动。值得指出的是,应用于超声成像领域的PMUT振元的直径都非常小,通常在几十微米甚至更小,即使1微米的对准偏差也将造成很大的不利影响。Option 2. Process PMUT wafers and CMOS wafers separately, set the side of the PMUT wafer with the piezoelectric film and the side of the CMOS wafer with the transistor as the front side of the corresponding wafer, connect the front side of the PMUT wafer and CMOS front-side bonding to build a CMOS integrated PMUT. Compared with the above scheme 1, this scheme has fewer limitations on piezoelectric materials. However, the effective vibration of the PMUT mechanical vibration unit is the key to efficiently transmitting and receiving ultrasonic waves, which requires a cavity structure below the vibration unit to provide space For the vibration unit to vibrate effectively, this requires a corresponding cavity on the CMOS. However, the cavity size is the core factor that determines the PMUT ultrasonic frequency, and changes in the cavity size will lead to changes in the PMUT ultrasonic frequency. When two wafers of PMUT and CMOS are bonded, alignment deviations inevitably occur, resulting in random deviations between the vibration unit area and its own design, resulting in frequency fluctuations of the developed CMOS integrated PMUT. It is worth pointing out that the diameter of PMUT transducers used in the field of ultrasound imaging is very small, usually tens of microns or even smaller. Even an alignment deviation of 1 micron will cause great adverse effects.
因此,现有技术中还存在开发出如下的CMOS与PMUT集成方案的需求:对压电材料本身普适性强,和/或CMOS单元与PMUT单元的集成过程不对空腔尺寸产生影响。Therefore, there is still a need in the existing technology to develop a CMOS and PMUT integration solution that is highly adaptable to the piezoelectric material itself, and/or the integration process of the CMOS unit and the PMUT unit does not affect the cavity size.
基于上述,本发明提出在同一CMOS晶圆上,分别集成具有高压电系数(例如,绝对值高于1C/m2,进一步的高于5C/m2)的压电材料基PMUT和具有低介电常数(例如,低于1200,进一步低于100)的压电材料基PMUT两类超声换能器,其中具有高压电系数的压电材料基PMUT专用于发射超声波,而具有低介电常数的压电材料基PMUT用于接收反射回来的超声波。上述PMUT与CMOS集成方案是开发拥有优异性能、低廉成本的MEMS超声换能器的关键。Based on the above, the present invention proposes to separately integrate piezoelectric material-based PMUTs with high voltage electrical coefficients (for example, the absolute value is higher than 1C/m 2 , and further higher than 5C/m 2 ) and low voltage electrical coefficients on the same CMOS wafer. Two types of ultrasonic transducers are piezoelectric material-based PMUTs with a dielectric constant (for example, lower than 1200 and further lower than 100). Among them, piezoelectric material-based PMUTs with high dielectric coefficient are dedicated to emitting ultrasonic waves, while those with low dielectric coefficients are The constant piezoelectric material-based PMUT is used to receive the reflected ultrasonic waves. The above-mentioned PMUT and CMOS integration solution is the key to developing MEMS ultrasound transducers with excellent performance and low cost.
本发明还提出了一种同时将上述两种类型压电材料基PMUT集成在同一CMOS晶圆上的方案。
The present invention also proposes a solution to simultaneously integrate the above two types of piezoelectric material-based PMUTs on the same CMOS wafer.
首先,本发明的附图中的附图标记说明如下:First, the reference numbers in the drawings of the present invention are explained as follows:
1000:CMOS单元或晶体管单元。1000: CMOS unit or transistor unit.
100:CMOS基底或晶体管基底,可选材料为单晶硅、氮化镓、砷化镓、蓝宝石、石英、碳化硅、金刚石等。100: CMOS substrate or transistor substrate, optional materials are single crystal silicon, gallium nitride, gallium arsenide, sapphire, quartz, silicon carbide, diamond, etc.
101:晶体管的源极和漏极。101: Source and drain of the transistor.
110:电路保护层,其为绝缘材料层,可以是二氧化硅、氮化硅等。110: Circuit protection layer, which is an insulating material layer, which can be silicon dioxide, silicon nitride, etc.
111:晶体管的栅极。111: Gate of transistor.
113A:晶体管单元层内电连接层,对应于第一电连接层,材料可选钼、钌、金、铝、镁、钨、铜,钛、铱、锇、铬或以上金属的复合或其合金等,上述材料也适用于其他电连接层。113A: The electrical connection layer within the transistor unit layer, corresponding to the first electrical connection layer, the material can be molybdenum, ruthenium, gold, aluminum, magnesium, tungsten, copper, titanium, iridium, osmium, chromium or a composite of the above metals or their alloys etc., the above materials are also suitable for other electrical connection layers.
113B:晶体管单元层内电连接层,对应于第二电连接层。113B: Electrical connection layer within the transistor unit layer, corresponding to the second electrical connection layer.
113、115:其他晶体管单元层内电连接层。113, 115: Electrical connection layers within other transistor unit layers.
112和114:晶体管单元层间电连接层。112 and 114: electrical connection layers between transistor unit layers.
2000’:PMUT初步单元,例如参见图9。2000’: PMUT preliminary unit, see Figure 9 for example.
2000:PMUT单元,参见图11。2000: PMUT unit, see Figure 11.
200’:PMUT初步基底,可选材料为单晶硅、氮化镓、砷化镓、蓝宝石、石英、碳化硅、金刚石等。200’: PMUT preliminary substrate, optional materials are single crystal silicon, gallium nitride, gallium arsenide, sapphire, quartz, silicon carbide, diamond, etc.
200:PMUT基底,材料与PMUT初步基底一致。200: PMUT substrate, the material is consistent with the PMUT preliminary substrate.
201和202:用于PMUT的空腔。201 and 202: Cavities for PMUT.
210:支撑层,其材料可以与电极层的材料相同,或者不同。支撑层可以如图6所示设置在PMUT的下部,即设置在PMUT与PMUT基底之间,此时支撑层为绝缘层,其材料可以为硅、二氧化硅、氮化硅等不导电材料。支撑层也可以设置在PMUT的上部。需要指出的是,也可以不设置支撑层。210: The material of the support layer may be the same as or different from the material of the electrode layer. The support layer can be provided at the lower part of the PMUT as shown in Figure 6, that is, between the PMUT and the PMUT substrate. In this case, the support layer is an insulating layer, and its material can be non-conductive materials such as silicon, silicon dioxide, and silicon nitride. The support layer can also be provided on the upper part of the PMUT. It should be pointed out that the support layer does not need to be provided.
220、240:电极层,材料可选钼、钌、金、铝、镁、钨、铜,钛、铱、锇、铬或以上金属的复合或其合金等。两个电极层的材料可以相同也可以不同。220, 240: Electrode layer, the material can be molybdenum, ruthenium, gold, aluminum, magnesium, tungsten, copper, titanium, iridium, osmium, chromium or composites of the above metals or their alloys, etc. The materials of the two electrode layers can be the same or different.
230、270:压电层。材料可选多晶氮化铝(AlN)、多晶氧化锌、多晶锆钛酸铅(PZT)、多晶铌酸锂(LiNbO3)、多晶钽酸锂(LiTaO3)、多晶铌酸钾(KNbO3)等材料,或者单晶氮化铝、单晶氮化镓、单晶铌酸锂、单晶锆钛酸铅、单晶铌酸钾、单晶石英薄膜、或者单晶钽酸锂等材料,上述的单晶或多晶材料还可以包括一定原子比的稀土元素掺杂材料,均属于本发明可以使用的压电层,如钪
掺杂氮化铝(AlScN)。230, 270: Piezoelectric layer. Materials available include polycrystalline aluminum nitride (AlN), polycrystalline zinc oxide, polycrystalline lead zirconate titanate (PZT), polycrystalline lithium niobate (LiNbO 3 ), polycrystalline lithium tantalate (LiTaO 3 ), polycrystalline niobium Materials such as potassium nitrate (KNbO 3 ), or single crystal aluminum nitride, single crystal gallium nitride, single crystal lithium niobate, single crystal lead zirconate titanate, single crystal potassium niobate, single crystal quartz film, or single crystal tantalum Lithium oxide and other materials, the above-mentioned single crystal or polycrystalline materials can also include rare earth element doped materials with a certain atomic ratio, all of which belong to the piezoelectric layer that can be used in the present invention, such as scandium Doped aluminum nitride (AlScN).
250:结构保护层,一般为介质材料,如二氧化硅、氮化铝、氮化硅等。250: Structural protective layer, usually dielectric material, such as silicon dioxide, aluminum nitride, silicon nitride, etc.
235:导电层或电连接层,其材料可以选自用于形成电极层的材料。235: Conductive layer or electrical connection layer, the material of which can be selected from the materials used to form the electrode layer.
275:导电层或电连接层,其材料可以选自用于形成电极层的材料。275: Conductive layer or electrical connection layer, the material of which can be selected from the materials used to form the electrode layer.
290:器件保护层,一般为介质材料,如二氧化硅、氮化铝、氮化硅等。290: Device protective layer, usually dielectric material, such as silicon dioxide, aluminum nitride, silicon nitride, etc.
300:辅助基底,可选材料为单晶硅、氮化镓、砷化镓、蓝宝石、石英、碳化硅、金刚石等。300: Auxiliary substrate, optional materials are single crystal silicon, gallium nitride, gallium arsenide, sapphire, quartz, silicon carbide, diamond, etc.
310:临时粘合层,可以是由任何能够将PMUT单元和辅助基底300临时接合的材料,例如可以为光刻胶。310: Temporary adhesive layer, which can be made of any material that can temporarily join the PMUT unit and the auxiliary substrate 300, such as photoresist.
400A:第一导电用孔。400A: First conductive hole.
400B:第二导电用孔。400B: Second conductive hole.
500:接合材料层,参见图4,其可以是金属键合层,例如金-金键合、铝-锗键合等,也可以是其它将两层接合在一起的材料层。500: Bonding material layer, see Figure 4, which can be a metal bonding layer, such as gold-gold bonding, aluminum-germanium bonding, etc., or other material layers that bond two layers together.
3000:微机械超声换能器结构或PMUT结构(参见图1和图14)。3000: Micromachined ultrasound transducer structure or PMUT structure (see Figure 1 and Figure 14).
4000:PMUT结构阵列(参见图14)。4000: PMUT structure array (see Figure 14).
图1-图4为根据本发明的不同示例性实施例的微机械超声换能器结构3000的结构示意图。1-4 are schematic structural diagrams of a micromachined ultrasound transducer structure 3000 according to different exemplary embodiments of the present invention.
在图示的实施例中,单个PMUT通常包括支撑层210,压电层230以及压电层230两侧的顶电极层240、底电极层220(例如参见图6-图9),在PMUT振动单元面向CMOS的一侧设置空腔201和202,使PMUT振动单元能够产生有效的弯曲振动产生超声波。本发明中,CMOS晶圆或者如图所示的晶体管单元1000上同时集成具有高压电系数的压电材料基PMUT和具有低介电常数的压电材料基PMUT两类超声换能器。In the illustrated embodiment, a single PMUT generally includes a support layer 210, a piezoelectric layer 230, and a top electrode layer 240 and a bottom electrode layer 220 on both sides of the piezoelectric layer 230 (see, for example, Figures 6 to 9). When the PMUT vibrates Cavities 201 and 202 are provided on the side of the unit facing the CMOS, so that the PMUT vibration unit can generate effective bending vibration to generate ultrasonic waves. In the present invention, two types of ultrasonic transducers, a piezoelectric material-based PMUT with a high voltage coefficient and a piezoelectric material-based PMUT with a low dielectric constant, are simultaneously integrated on a CMOS wafer or the transistor unit 1000 as shown in the figure.
如图1所示,230和270分别代表高压电系数基压电薄膜和低介电常数基压电薄膜。201和202分别是两种类型压电薄膜所构成PMUT进行有效弯曲振动的空腔区域。200是构建PMUT的衬底或者PMUT基底,100是构建CMOS电路的衬底或者晶体管基底,110是电路保护层。As shown in Figure 1, 230 and 270 respectively represent the high-voltage coefficient-based piezoelectric film and the low-dielectric constant-based piezoelectric film. 201 and 202 are respectively the cavity areas where the PMUT composed of two types of piezoelectric films undergoes effective bending vibration. 200 is a substrate for building a PMUT or a PMUT base, 100 is a substrate for building a CMOS circuit or a transistor base, and 110 is a circuit protection layer.
如前所述的,在更具体的实施例中,压电层230的压电系数绝对值大于1C/m2,和/或压电层270的介电常数小于1200。进一步的,压电层230的压电系数绝对值大于5C/m2,和/或压电层270的介电常数小于100。
As mentioned before, in more specific embodiments, the absolute value of the piezoelectric coefficient of the piezoelectric layer 230 is greater than 1 C/m 2 , and/or the dielectric constant of the piezoelectric layer 270 is less than 1200. Further, the absolute value of the piezoelectric coefficient of the piezoelectric layer 230 is greater than 5C/m 2 , and/or the dielectric constant of the piezoelectric layer 270 is less than 100.
在更具体的实施例中,压电层230为PZT或掺杂PZT,压电层270为ALN或AlScN。在PMUT-on-CMOS集成方面,本发明分别制作CMOS晶圆和PMUT晶圆,其中在PMUT晶圆上制作两种类型压电薄膜基PMUT,之后将PMUT晶圆衬底侧减薄并与CMOS晶圆正面进行键合,最后将PMUT晶圆电极与CMOS晶圆上相应电极互连实现电学连接,如有需要并对器件进行表面保护(可以具体的参见后续参照附图5-图13的示例性说明)。该集成方案中,不同类型压电薄膜基PMUT加工中,即使存在比较苛刻的加工条件,也不会对CMOS晶圆产生破坏,工艺兼容性好。In a more specific embodiment, piezoelectric layer 230 is PZT or doped PZT, and piezoelectric layer 270 is ALN or AlScN. In terms of PMUT-on-CMOS integration, the present invention produces CMOS wafers and PMUT wafers respectively, in which two types of piezoelectric film-based PMUTs are produced on the PMUT wafer, and then the substrate side of the PMUT wafer is thinned and combined with the CMOS The front side of the wafer is bonded, and finally the PMUT wafer electrodes are interconnected with the corresponding electrodes on the CMOS wafer to achieve electrical connection. If necessary, the surface of the device is protected (for details, please refer to the examples in Figures 5 to 13). gender description). In this integrated solution, when processing different types of piezoelectric film-based PMUTs, even if there are relatively harsh processing conditions, the CMOS wafer will not be damaged, and the process compatibility is good.
在PMUT振动所需空腔201和202的形成方式上,如图1所示,其可以通过预置空腔,填充牺牲层材料,在最后阶段释放的方式形成空腔。图2是通过背刻方式形成空腔。图3是一种压电薄膜基PMUT是通过背刻方式,另一种压电薄膜基PMUT是通过牺牲层方式形成空腔。In terms of the formation method of the cavities 201 and 202 required for PMUT vibration, as shown in Figure 1, the cavities can be formed by presetting the cavities, filling them with sacrificial layer materials, and releasing them in the final stage. Figure 2 shows the cavity formed by back-engraving. Figure 3 shows a piezoelectric film-based PMUT that uses a back-engraving method, and another piezoelectric film-based PMUT that uses a sacrificial layer to form a cavity.
在PMUT晶圆与CMOS晶圆的键合中,PMUT晶圆衬底层可与CMOS晶圆的电路保护层直接键合(例如参见图1-图3),也可通过中间键合层材料(比如金属键合等,对应于接合材料层500)实现PMUT单元与CMOS单元的集成(例如参见图4)。In the bonding of PMUT wafers and CMOS wafers, the PMUT wafer substrate layer can be directly bonded to the circuit protection layer of the CMOS wafer (for example, see Figure 1-Figure 3), or through an intermediate bonding layer material (such as Metal bonding, etc., corresponding to the bonding material layer 500) realizes the integration of the PMUT unit and the CMOS unit (see, for example, Figure 4).
在图1-图4所示的实施例中,PMUT单元包括了两个在横向方向上间隔开的PMUT,即第一PMUT和第二PMUT,第一PMUT的压电层230的压电系数高于第二PMUT的压电层270的压电系数,且第一PMUT的压电层230的介电常数低于第二PMUT的压电层270的介电常数。在进一步的实施例中,第一PMUT的压电层230为PZT,第二PMUT的压电层270为AlN。In the embodiment shown in FIGS. 1 to 4 , the PMUT unit includes two PMUTs spaced apart in the lateral direction, namely a first PMUT and a second PMUT. The piezoelectric coefficient of the piezoelectric layer 230 of the first PMUT is high. The piezoelectric coefficient of the piezoelectric layer 270 of the second PMUT, and the dielectric constant of the piezoelectric layer 230 of the first PMUT is lower than the dielectric constant of the piezoelectric layer 270 of the second PMUT. In a further embodiment, the piezoelectric layer 230 of the first PMUT is PZT and the piezoelectric layer 270 of the second PMUT is AlN.
在本发明中,对于独立权利要求而言,PMUT基底可以是如图1-图4所示的为单晶硅、氮化镓、砷化镓、蓝宝石、石英、碳化硅、金刚石等的基底,也可以是其他的用于生成PMUT的其他支撑结构,均在本发明的保护范围之内。In the present invention, for the independent claims, the PMUT substrate can be a substrate such as single crystal silicon, gallium nitride, gallium arsenide, sapphire, quartz, silicon carbide, diamond, etc., as shown in Figures 1 to 4, Other support structures for generating PMUT may also be used, which are all within the protection scope of the present invention.
在图1-图4所示的实施例中,采用了PMUT-on-CMOS的结构,但是本发明不限于此。上述的PMUT单元也可以设置在其他的结构上,PMUT-on-CMOS是本发明的一个有利的实施例。In the embodiments shown in FIGS. 1 to 4 , a PMUT-on-CMOS structure is adopted, but the present invention is not limited thereto. The above-mentioned PMUT unit can also be arranged on other structures, and PMUT-on-CMOS is an advantageous embodiment of the present invention.
在图1-图4所示的实施例中,PMUT单元的第一PMUT用于发射超声波,第二PMUT用于接收超声波。In the embodiment shown in FIGS. 1 to 4 , the first PMUT of the PMUT unit is used to transmit ultrasonic waves, and the second PMUT is used to receive ultrasonic waves.
图5-图13为根据本发明的一个示例性实施例的示例性示出图2所示的微机
械超声换能器结构的制造方法的截面示意图。更具体的,图5-图13是以背刻形式形成PMUT振动所需空腔,以PMUT基底200与CMOS电路保护层110直接键合为例,其中高压电系数材料230或第一PMUT的压电层230选用PZT,低介电常数材料270或第二PMUT的压电层270选用AlN,构建具有超高脉冲-回波灵敏度的PMUT-on-CMOS超声换能器。5-13 are exemplary illustrations of the microcomputer shown in FIG. 2 according to an exemplary embodiment of the present invention. Schematic cross-sectional view of the manufacturing method of the mechanical ultrasonic transducer structure. More specifically, Figures 5 to 13 illustrate the formation of the cavity required for PMUT vibration in the form of back-engraving, taking the direct bonding of the PMUT substrate 200 and the CMOS circuit protection layer 110 as an example, in which the high-voltage electrical coefficient material 230 or the first PMUT The piezoelectric layer 230 is made of PZT, and the low dielectric constant material 270 or the piezoelectric layer 270 of the second PMUT is made of AlN to construct a PMUT-on-CMOS ultrasonic transducer with ultra-high pulse-echo sensitivity.
先提供晶体管单元1000。图5是CMOS结构示意图,其中100为CMOS的衬底,即晶体管基底(可以是硅等),110为电路保护层(可以是氧化硅、氮化硅等)。101为晶体管的源极和漏级,111为晶体管的栅极,113A、113B、113和115是CMOS层内电连接层,112和114是CMOS层间电连接层。如图5所示,晶体管单元包括晶体管基底100以及在横向方向上间隔开布置的第一晶体管和第二晶体管。需要指出的是,图2所示结构为示例性的,对于本发明而言,CMOS单元1000可以包括CMOS晶体管和电路保护层110,还可以可选的包括第一电连接层113A、第二电连接层113B。Transistor unit 1000 is provided first. Figure 5 is a schematic diagram of the CMOS structure, in which 100 is the CMOS substrate, that is, the transistor substrate (which can be silicon, etc.), and 110 is the circuit protection layer (which can be silicon oxide, silicon nitride, etc.). 101 is the source and drain of the transistor, 111 is the gate of the transistor, 113A, 113B, 113 and 115 are the electrical connection layers within the CMOS layer, and 112 and 114 are the electrical connection layers between the CMOS layers. As shown in FIG. 5 , the transistor unit includes a transistor substrate 100 and first and second transistors spaced apart in the lateral direction. It should be noted that the structure shown in Figure 2 is exemplary. For the present invention, the CMOS unit 1000 may include a CMOS transistor and a circuit protection layer 110, and may optionally include a first electrical connection layer 113A, a second electrical connection layer 113A, and a second electrical connection layer 113A. Connection layer 113B.
接着,提供PMUT初步单元2000’,参见图9。PMUT初步单元2000’包括PMUT初步基底200’、第一PMUT和第二PMUT。每个PMUT包括底电极层220、顶电极层240与压电层230。下面具体参照图6-图9说明如何提供PMUT初步单元2000’。Next, a PMUT preliminary unit 2000' is provided, see Figure 9. The PMUT preliminary unit 2000' includes a PMUT preliminary base 200', a first PMUT and a second PMUT. Each PMUT includes a bottom electrode layer 220, a top electrode layer 240, and a piezoelectric layer 230. The following describes how to provide the PMUT preliminary unit 2000' with specific reference to Figures 6-9.
图6中,先在支撑层210上形成PZT基PMUT,其中,200’为PMUT的衬底,即PMUT初始基底(可以是硅),210为支撑层(可以是氧化硅等),230为PZT压电薄膜层或压电层,220和240为压电薄膜层两侧的底、顶电极层。可以采用MEMS工艺,形成PZT基PMUT。这里的初始基底200’是相对于图11中的基底200而言的,初始基底200’减薄后成为基底200。In Figure 6, a PZT-based PMUT is first formed on the support layer 210, where 200' is the PMUT substrate, that is, the PMUT initial substrate (which can be silicon), 210 is the support layer (can be silicon oxide, etc.), and 230 is PZT Piezoelectric film layer or piezoelectric layer, 220 and 240 are the bottom and top electrode layers on both sides of the piezoelectric film layer. MEMS technology can be used to form PZT-based PMUT. The initial substrate 200' here is relative to the substrate 200 in Figure 11. The initial substrate 200' becomes the substrate 200 after being thinned.
如图7所示,PZT基PMUT的压电层230以及顶、底电极结构图案化之后,在PZT基PMUT表面沉积结构保护层250,用于后续AlN基PMUT加工过程中对PZT基PMUT的保护。As shown in Figure 7, after the piezoelectric layer 230 and the top and bottom electrode structures of the PZT-based PMUT are patterned, a structural protective layer 250 is deposited on the surface of the PZT-based PMUT to protect the PZT-based PMUT during the subsequent processing of the AlN-based PMUT. .
如图8所示,在设置有PZT基PMUT的晶圆或初始基底200’上,构建的AlN基PMUT,AlN基PMUT包含压电薄膜层或ALN压电层270以及顶、底电极层280和260。As shown in Figure 8, on a wafer or initial substrate 200' provided with a PZT-based PMUT, an AlN-based PMUT is constructed. The AlN-based PMUT includes a piezoelectric film layer or an ALN piezoelectric layer 270 and top and bottom electrode layers 280 and 260.
如图9所示,待PZT基PMUT和AlN基PMUT在晶圆或初始基底200’上形成之后,去除PZT基PMUT的结构保护层250,以得到PMUT单元2000。如图9所
示,其包括了PZT基PMUT和AlN基PMUT两个PMUT。As shown in FIG. 9 , after the PZT-based PMUT and the AlN-based PMUT are formed on the wafer or initial substrate 200 ′, the structural protection layer 250 of the PZT-based PMUT is removed to obtain the PMUT unit 2000 . As shown in Figure 9 It includes two PMUTs, PZT-based PMUT and AlN-based PMUT.
如图9所示,PMUT初步单元2000’中,并不包括将PMUT电极与CMOS电极连接在一起的电连接结构。在图9中,如图9中的PMUT初步基底200’的厚度过大,需要基于后续的减薄工艺在后续步骤中减薄,以使PMUT和CMOS之间电连接部分尽量短,需要键合到CMOS晶圆上的PMUT基底的厚度尽量薄,最好在10微米以下,甚至是5微米以下。不过,在PMUT基底的厚度已经满足要求的情况下,也可以不执行后续的基底减薄步骤,或者在能够忍受PMUT和CMOS之间电连接部分的长度的情况下,也可以不执行后续的基底减薄步骤,这些都在本发明的保护范围之内。As shown in Figure 9, the PMUT preliminary unit 2000' does not include an electrical connection structure that connects the PMUT electrodes and the CMOS electrodes together. In Figure 9, the thickness of the PMUT preliminary substrate 200' in Figure 9 is too large and needs to be thinned in subsequent steps based on the subsequent thinning process to make the electrical connection part between the PMUT and CMOS as short as possible and requires bonding The thickness of the PMUT substrate on the CMOS wafer should be as thin as possible, preferably below 10 microns, or even below 5 microns. However, if the thickness of the PMUT substrate already meets the requirements, the subsequent substrate thinning step may not be performed, or if the length of the electrical connection part between the PMUT and CMOS can be tolerated, the subsequent substrate thinning step may not be performed. Thinning steps, these are all within the protection scope of the present invention.
下面参照图10-图11示例性说明如何将PMUT单元2000接合到晶体管单元1000上。The following exemplifies how to bond the PMUT unit 2000 to the transistor unit 1000 with reference to FIGS. 10 and 11 .
如图10所示,以临时粘合层310覆盖PZT基PMUT和AlN基PMUT以及设置辅助基底300,所述辅助基底300与所述临时粘合层310接合。在晶圆级制作中,设置辅助基底300是为了后续PMUT初始基底减薄。As shown in FIG. 10 , the PZT-based PMUT and the AlN-based PMUT are covered with a temporary adhesive layer 310 and an auxiliary substrate 300 is provided. The auxiliary substrate 300 is bonded to the temporary adhesive layer 310 . In wafer-level fabrication, the auxiliary substrate 300 is provided for subsequent PMUT initial substrate thinning.
如图11所示,在初始基底200’的另一侧执行减薄工艺以形成PMUT基底200。可以将图10中辅助基底200’减薄至所需尺寸,例如小于10μm,甚至是小于5μm,如果键合流程需要,可以对其进行表面抛光化。然后通过背刻工艺刻蚀出PMUT振动所需空腔201和202,如图11所示。As shown in FIG. 11, a thinning process is performed on the other side of the initial substrate 200' to form the PMUT substrate 200. The auxiliary substrate 200' in Figure 10 can be thinned to a required size, for example, less than 10 μm, or even less than 5 μm, and can be surface polished if required by the bonding process. Then the cavities 201 and 202 required for PMUT vibration are etched through a back etching process, as shown in Figure 11.
然后,将PMUT基底200与晶体管单元的表面或者CMOS电路保护层110接合,以及移除临时粘合层310和辅助基底300,最终如图11所示。接合方案可选择硅-硅键合,硅-氧化硅键合、金属键合等各种方案。Then, the PMUT substrate 200 is bonded to the surface of the transistor unit or the CMOS circuit protection layer 110, and the temporary adhesive layer 310 and the auxiliary substrate 300 are removed, as shown in FIG. 11 . Various bonding solutions can be selected, including silicon-silicon bonding, silicon-silicon oxide bonding, and metal bonding.
如图12所示,通过刻蚀工艺将PMUT基底200和CMOS电路保护层110刻蚀以形成导电用孔,露出CMOS的电连接端或电连接层。如图12所示,对于每一个PMUT,刻蚀出第一导电用孔400A和第二导电用孔400B,以分别露出晶体管单元层内电连接层113A和晶体管单元层内电连接层113B。可选的,第一电连接层113A与CMOS晶体管的电极中的一个(例如源极)电连接,第二电连接层113B与CMOS晶体管的电极中的另外的一个电极(例如栅极)电连接。不过,在CMOS单元中存在其他的电连接结构的情况下,基于需要和要求,第一电连接层113A和/或第二电连接层113B也可以与之电连接,这也在本发明的保护范围之内。As shown in FIG. 12 , the PMUT substrate 200 and the CMOS circuit protection layer 110 are etched through an etching process to form conductive holes, exposing the electrical connection terminals or the electrical connection layer of the CMOS. As shown in FIG. 12 , for each PMUT, a first conductive hole 400A and a second conductive hole 400B are etched to expose the intra-transistor unit layer electrical connection layer 113A and the transistor unit layer intra-electrical connection layer 113B respectively. Optionally, the first electrical connection layer 113A is electrically connected to one of the electrodes of the CMOS transistor (for example, the source), and the second electrical connection layer 113B is electrically connected to another one of the electrodes of the CMOS transistor (for example, the gate). . However, when there are other electrical connection structures in the CMOS unit, based on needs and requirements, the first electrical connection layer 113A and/or the second electrical connection layer 113B can also be electrically connected thereto, which is also within the scope of the present invention. within the range.
如图13所示,例如以沉积工艺,设置PMUT和CMOS的电连接层235和275,
实现PMUT和CMOS的电连接。最后,如果需要,在整个器件表面沉积保护层或器件保护层290。其中235和275为电连接层,可以选用各种各样的导电材料,例如是形成电极层的材料,另外连接PZT基PMUT与CMOS电路的导电通道或电连接层235所采用的材料与实现AlN基PMUT与CMOS电连接的导电通道或电连接层275可以是同种材料,也可以是不同种导电材料。如能理解的,明显的,电连接层235和275彼此电绝缘,电连接层235和275均是经由导电用孔分别与晶体管单元层内电连接层113A和层内电连接层113B形成电连接。As shown in Figure 13, for example, using a deposition process, the electrical connection layers 235 and 275 of PMUT and CMOS are provided, Realize the electrical connection between PMUT and CMOS. Finally, if desired, a protective layer or device protection layer 290 is deposited over the entire device surface. Among them, 235 and 275 are electrical connection layers. Various conductive materials can be used, such as materials to form electrode layers. In addition, the conductive channel or electrical connection layer 235 used to connect the PZT-based PMUT and the CMOS circuit is similar to the material used to realize AlN. The conductive channel or electrical connection layer 275 that electrically connects the base PMUT to the CMOS may be of the same type of material or may be of different types of conductive materials. As can be understood, it is obvious that the electrical connection layers 235 and 275 are electrically insulated from each other, and both the electrical connection layers 235 and 275 are electrically connected to the transistor unit intra-layer electrical connection layer 113A and the intra-layer electrical connection layer 113B respectively through conductive holes. .
如能够理解的,在上述的方法中,如果通过设置接合材料层500实现PMUT单元与晶体管单元之间的接合,则PMUT单元、晶体管单元以及所述接合材料层共同限定空腔,接合材料层500的厚度限定所述空腔的高度。As can be understood, in the above method, if the bonding between the PMUT unit and the transistor unit is achieved by providing the bonding material layer 500, then the PMUT unit, the transistor unit and the bonding material layer jointly define a cavity, and the bonding material layer 500 The thickness defines the height of the cavity.
此外,在上述的技术方案中,PMUT基底200与电路保护层110接合,如图1所示,即PMUT单元2000的基底侧(或反面)与CMOS单元1000的晶圆侧(或正面)相接合,从而:(1)在后续的步骤中需要在PMUT基底200上制备PMUT时,PMUT基底200可以保护CMOS单元1000,或者(2)可以直接以PMUT单元2000与CMOS单元1000接合,不用考虑制备PMUT时对CMOS单元1000的影响。这可以使得上述的微机械超声换能器结构对于压电材料的普适性强,既可以为氮化铝(AlN),也可以为锆钛酸铅(PZT)、铌酸锂(LiNbO3)、钽酸锂(LiTaO3)、铌酸钾(KNbO3)等材料。In addition, in the above technical solution, the PMUT substrate 200 is bonded to the circuit protection layer 110, as shown in Figure 1, that is, the base side (or back side) of the PMUT unit 2000 is bonded to the wafer side (or front side) of the CMOS unit 1000. , thus: (1) When PMUT needs to be prepared on the PMUT substrate 200 in subsequent steps, the PMUT substrate 200 can protect the CMOS unit 1000, or (2) the PMUT unit 2000 can be directly connected to the CMOS unit 1000 without considering the preparation of PMUT. impact on the CMOS unit 1000. This can make the above-mentioned micromechanical ultrasonic transducer structure highly adaptable to piezoelectric materials, which can be aluminum nitride (AlN), lead zirconate titanate (PZT), or lithium niobate (LiNbO 3 ) , lithium tantalate (LiTaO 3 ), potassium niobate (KNbO 3 ) and other materials.
需要指出的是,本发明中的“PMUT基底与电路保护层接合”不仅包括如图1所示的两者直接接合的情况,还可以包括在两者之间设置有其他接合用层或膜层的情况,例如在图4中,PMUT基底与电路保护层之间设置有可以是金属键合层的接合材料层500。It should be pointed out that the "bonding of the PMUT substrate and the circuit protection layer" in the present invention not only includes the direct bonding of the two as shown in Figure 1, but also includes other bonding layers or film layers provided between the two. For example, in Figure 4, a bonding material layer 500, which may be a metal bonding layer, is provided between the PMUT substrate and the circuit protection layer.
需要专门指出的是,在本发明的具体的实施例中,以PMUT基底与电路保护层接合为例作了示例性说明,但是,PMUT基底与CMOS单元1000的接合可以是限定CMOS单元的表面的电路保护层,也可以是限定CMOS单元的表面的其他层,均在本发明的保护范围之内。It should be noted that in the specific embodiment of the present invention, the connection between the PMUT substrate and the circuit protection layer is taken as an example for illustration. However, the connection between the PMUT substrate and the CMOS unit 1000 may be to define the surface of the CMOS unit. The circuit protection layer, which may also be other layers defining the surface of the CMOS unit, is within the scope of the present invention.
如图1-图4所示的实施例中,CMOS单元1000还包括CMOS基底100,电路保护层110的一侧与PMUT基底200接合,电路保护层110的另一侧与CMOS基底100接合。可选的,在有些情况下,PMUT单元也可以与CMOS基底100接合,这也在本发明的保护范围之内。
In the embodiment shown in FIGS. 1 to 4 , the CMOS unit 1000 further includes a CMOS substrate 100 , one side of the circuit protection layer 110 is bonded to the PMUT substrate 200 , and the other side of the circuit protection layer 110 is bonded to the CMOS substrate 100 . Optionally, in some cases, the PMUT unit can also be bonded to the CMOS substrate 100, which is also within the protection scope of the present invention.
还需要专门指出的是,在本发明中,以CMOS作为晶体管的一个示例,从而以CMOS单元作为晶体管单元的一个示例,但是本发明不限于此,晶体管还可以是BiMOS单元或BCD等,从而晶体管单元还可以是BiMOS单元或BCD单元等。It should also be specifically pointed out that in the present invention, CMOS is used as an example of a transistor, and thus a CMOS unit is used as an example of a transistor unit. However, the invention is not limited thereto. The transistor can also be a BiMOS unit or BCD, etc., so that a transistor The unit can also be a BiMOS unit or a BCD unit, etc.
类似于对“PMUT基底与电路保护层接合”的解释和说明,本发明中的“PMUT单元与晶体管单元的表面接合”可以是PMUT单元与晶体管单元的表面直接接合的情况,还可以包括在PMUT单元与晶体管单元的表面之间设置有其他接合用层或膜层的情况,均在本发明的保护范围之内。Similar to the explanation and description of "the PMUT substrate is bonded to the circuit protective layer", the "surface bonding of the PMUT unit and the transistor unit" in the present invention may be the case where the PMUT unit is directly bonded to the surface of the transistor unit, and may also include The situation where other bonding layers or film layers are provided between the surface of the unit and the transistor unit are within the scope of protection of the present invention.
如图1-图4所示,PMUT基底200设置有用于PMUT的空腔201。即在采用PMUT单元2000与CMOS单元1000接合的情况下,空腔201已经设置在PMUT单元2000中。换言之,在晶圆级制造中,PMUT振动所需的空腔结构设置在PMUT晶圆侧,不需要在CMOS晶圆上形成空腔,从而CMOS晶圆与PMUT晶圆集成过程不存在因对准偏差引起的振动区域的变化,以及由此引起的超声换能器频率的变化,克服了现有技术中CMOS与PMUT的集成过程对空腔尺寸产生不利影响这样的技术问题。虽然没有示出,在可选的实施例中,空腔201可以贯穿PMUT基底200。As shown in Figures 1-4, the PMUT substrate 200 is provided with a cavity 201 for the PMUT. That is, in the case where the PMUT unit 2000 is used to bond with the CMOS unit 1000, the cavity 201 has been set in the PMUT unit 2000. In other words, in wafer-level manufacturing, the cavity structure required for PMUT vibration is set on the side of the PMUT wafer, and there is no need to form a cavity on the CMOS wafer. Therefore, there is no alignment problem during the integration process between the CMOS wafer and the PMUT wafer. The change in the vibration area caused by the deviation, and the resulting change in the frequency of the ultrasonic transducer, overcome the technical problem in the existing technology that the integration process of CMOS and PMUT has a negative impact on the cavity size. Although not shown, in alternative embodiments, cavity 201 may extend through PMUT substrate 200 .
在上述图1-图4所示的结构中,PMUT基底200设置有用于PMUT的空腔201。但是,本发明不限于此。空腔201也可以不设置在PMUT基底200中,更具体的,PMUT单元2000与晶体管单元之间设置有接合材料层500,PMUT单元2000、晶体管单元1000以及接合材料层500共同限定空腔201,接合材料层500的厚度限定空腔201的高度。如此,晶圆级制造中,PMUT振动所需的空腔201也不需要在CMOS晶圆上形成,而且基于例如金属键合层的接合材料层500可以限定空腔201在横向方向上的侧面从而空腔201的区域较大,从而可以减小CMOS晶圆与PMUT晶圆集成过程因对准偏差引起的振动区域的变化,以及由此引起的超声换能器频率的变化,克服了或减少了现有技术中CMOS与PMUT的集成过程对空腔尺寸产生不利影响这样的技术问题。上述方案中,空腔201处于所述接合面的设置了PMUT单元的一侧,形成空腔201不会对晶体管单元的结构发生额外的改变,不必在两者集成之前在晶体管单元中设置空腔,减少或者避免了现有技术中CMOS单元与PMUT单元的集成过程对空腔尺寸产生不利影响的技术问题。In the structure shown in FIGS. 1-4 above, the PMUT substrate 200 is provided with a cavity 201 for the PMUT. However, the present invention is not limited to this. The cavity 201 may not be provided in the PMUT substrate 200. More specifically, a bonding material layer 500 is provided between the PMUT unit 2000 and the transistor unit. The PMUT unit 2000, the transistor unit 1000 and the bonding material layer 500 jointly define the cavity 201. The thickness of the bonding material layer 500 defines the height of the cavity 201 . In this way, in wafer-level manufacturing, the cavity 201 required for PMUT vibration does not need to be formed on the CMOS wafer, and the bonding material layer 500 based on, for example, a metal bonding layer can define the sides of the cavity 201 in the lateral direction. The area of the cavity 201 is larger, which can reduce the changes in the vibration area caused by the alignment deviation during the integration process of the CMOS wafer and the PMUT wafer, and the resulting changes in the frequency of the ultrasonic transducer, overcoming or reducing In the prior art, there is a technical problem that the integration process of CMOS and PMUT adversely affects the cavity size. In the above solution, the cavity 201 is located on the side of the joint surface where the PMUT unit is installed. The formation of the cavity 201 will not cause additional changes to the structure of the transistor unit. There is no need to set a cavity in the transistor unit before integrating the two. , reducing or avoiding the technical problem in the prior art that the integration process of the CMOS unit and the PMUT unit has an adverse impact on the cavity size.
如图1-图4所示,在可选的实施例中,对于每一个PMUT,微机械超声换能器结构设置有第一导电用孔400A和第二导电孔400B,第一导电用孔400A贯
穿PMUT基底200和/或支撑层210以及抵达电路保护层110内的第一电连接层113A,第二导电用孔400B贯穿PMUT基底200和/或支撑层210以及抵达电路保护层110内的第二电连接层113B,其中:第一导电层235经由第一导电用孔400A与第一电连接层113A电连接,第二导电层275经由第二导电用孔400B与第二电连接层113B电连接。As shown in Figures 1-4, in an optional embodiment, for each PMUT, the micromachined ultrasonic transducer structure is provided with a first conductive hole 400A and a second conductive hole 400B. The first conductive hole 400A through The second conductive hole 400B penetrates the PMUT substrate 200 and/or the support layer 210 and reaches the first electrical connection layer 113A in the circuit protection layer 110. Two electrical connection layers 113B, wherein: the first conductive layer 235 is electrically connected to the first electrical connection layer 113A through the first conductive hole 400A, and the second conductive layer 275 is electrically connected to the second electrical connection layer 113B through the second conductive hole 400B. connect.
如图1-图4所示,在可选的实施例中,PMUT单元2000包括支撑层210,支撑层210用于实现PMUT的弯曲振动。如图1-图4所示,支撑层210设置在PMUT(包括电极层220、240和压电层230)与PMUT基底200之间,此时,第一导电用孔400A和第二导电孔400B贯穿支撑层210。如能够理解的,也可以不设置支撑层210,或者支撑层210设置在顶电极或者第一电极层240的上方,此时第一导电用孔400A和第二导电孔400B不用或不存在贯穿支撑层的情况。这些方案都在本发明的保护范围之内。As shown in Figures 1-4, in an optional embodiment, the PMUT unit 2000 includes a support layer 210, and the support layer 210 is used to realize the bending vibration of the PMUT. As shown in Figures 1 to 4, the support layer 210 is provided between the PMUT (including the electrode layers 220, 240 and the piezoelectric layer 230) and the PMUT substrate 200. At this time, the first conductive hole 400A and the second conductive hole 400B Through the support layer 210. As can be understood, the support layer 210 may not be provided, or the support layer 210 may be provided above the top electrode or the first electrode layer 240. In this case, the first conductive hole 400A and the second conductive hole 400B do not use or have no through support. layer situation. These solutions are all within the protection scope of the present invention.
但是,不论是否设置支撑层210和/或PMUT基底200,第一导电用孔400A和第二导电孔400B均需要贯穿PMUT单元以抵达下方的电连接层。However, regardless of whether the support layer 210 and/or the PMUT substrate 200 is provided, the first conductive holes 400A and the second conductive holes 400B need to penetrate the PMUT unit to reach the underlying electrical connection layer.
虽然没有示出,第一导电层235和第二导电层275可以在微机械超声换能器结构的侧面分别与在侧面露出的第一电连接层113A和第二电连接层113B电连接,这也在本发明的保护范围之内。Although not shown, the first conductive layer 235 and the second conductive layer 275 may be electrically connected to the first electrical connection layer 113A and the second electrical connection layer 113B exposed on the side of the micromachined ultrasonic transducer structure, respectively. It is also within the protection scope of the present invention.
另外,当PMUT设置在空腔内时,空腔对PMUT(尤其是压电层)起到与外界环境隔离的保护作用,能够提高PMUT的可靠性和长期稳定性,进而在上述的PMUT结构用在例如成像仪中时,可以提高最终成像系统的可靠性和长期稳定性。In addition, when the PMUT is placed in the cavity, the cavity plays a protective role in isolating the PMUT (especially the piezoelectric layer) from the external environment, which can improve the reliability and long-term stability of the PMUT, and then be used in the above-mentioned PMUT structure. When used, for example, in an imager, the reliability and long-term stability of the final imaging system can be improved.
图14为根据本发明的一个示例性实施例的PMUT结构阵列的示意图。如图14所示,上述的PMUT结构3000可以仅仅是阵列4000中的一个阵元。图14中,空心圆代表PMUT结构3000的PMUT振动区域,除了圆形之外,其可以是椭圆、多边形及其组合等任意需要的形状。黑实心圆代表PMUT单元与CMOS单元实现电连接,如图5所示的第一电连接层113A和第二电连接层113B处,其也可以是任意需要的形状。PMUT结构3000组合构成PMUT结构阵列4000。Figure 14 is a schematic diagram of a PMUT structure array according to an exemplary embodiment of the present invention. As shown in Figure 14, the above-mentioned PMUT structure 3000 may be only one array element in the array 4000. In Figure 14, the hollow circle represents the PMUT vibration area of the PMUT structure 3000. In addition to the circle, it can be any desired shape such as an ellipse, a polygon, and a combination thereof. The solid black circle represents the electrical connection between the PMUT unit and the CMOS unit, as shown in Figure 5 at the first electrical connection layer 113A and the second electrical connection layer 113B, which can also be in any desired shape. The PMUT structures 3000 are combined to form a PMUT structure array 4000.
每个PMUT单元可以通过与之匹配的CMOS电路单独控制,形成二维PMUT结构阵列4000。Each PMUT unit can be individually controlled through a matching CMOS circuit to form a two-dimensional PMUT structure array 4000.
也可以将多个PMUT结构3000连接在一起,比如同一列上的PMUT结构3000的电极互联,形成一维线阵列,此时CMOS单元的电路与PMUT单元的电连接点
减少,一对CMOS单元与PMUT单元的电连接点对多个PMUT单元同时控制。Multiple PMUT structures 3000 can also be connected together. For example, the electrodes of the PMUT structures 3000 on the same column are interconnected to form a one-dimensional line array. At this time, the circuit of the CMOS unit and the electrical connection point of the PMUT unit Reduce, the electrical connection points of a pair of CMOS units and PMUT units control multiple PMUT units simultaneously.
可以基于PMUT结构或者PMUT结构阵列,形成超声换能器,该超声换能器可以用在超声成像仪上,PMUT结构或者PMUT结构阵列也可以用在其他的电子设备上,例如超声测距仪、超声指纹传感器、用于工业领域的无损探伤仪等。An ultrasonic transducer can be formed based on a PMUT structure or a PMUT structure array. The ultrasonic transducer can be used in an ultrasonic imager. The PMUT structure or PMUT structure array can also be used in other electronic devices, such as ultrasonic rangefinders, Ultrasonic fingerprint sensors, non-destructive flaw detectors used in industrial fields, etc.
基于以上,本发明提出了如下技术方案:Based on the above, the present invention proposes the following technical solutions:
1、一种微机械超声换能器结构,包括:1. A micromechanical ultrasonic transducer structure, including:
PMUT单元,包括PMUT基底、第一PMUT和第二PMUT,每个PMUT包括第一电极层、第二电极层与压电层,The PMUT unit includes a PMUT substrate, a first PMUT and a second PMUT. Each PMUT includes a first electrode layer, a second electrode layer and a piezoelectric layer,
其中:in:
第一PMUT和第二PMUT在横向上彼此间隔开设置在PMUT基底的一侧;The first PMUT and the second PMUT are laterally spaced apart from each other and arranged on one side of the PMUT substrate;
第一PMUT的压电层的压电系数高于第二PMUT的压电层的压电系数,且第一PMUT的压电层的介电常数低于第二PMUT的压电层的介电常数。The piezoelectric coefficient of the piezoelectric layer of the first PMUT is higher than the piezoelectric coefficient of the piezoelectric layer of the second PMUT, and the dielectric constant of the piezoelectric layer of the first PMUT is lower than the dielectric constant of the piezoelectric layer of the second PMUT. .
2、根据1所述的微机械超声换能器结构,其中:2. The micromechanical ultrasonic transducer structure according to 1, wherein:
第一PMUT的压电层为PZT或掺杂PZT,第二PMUT的压电层为ALN或AlScN。The piezoelectric layer of the first PMUT is PZT or doped PZT, and the piezoelectric layer of the second PMUT is ALN or AlScN.
3、根据1所述的微机械超声换能器结构,其中:3. The micromechanical ultrasonic transducer structure according to 1, wherein:
第一PMUT用于发射超声波,第二PMUT用于接收超声波。The first PMUT is used to transmit ultrasonic waves, and the second PMUT is used to receive ultrasonic waves.
4、根据1-3中任一项所述的微机械超声换能器结构,还包括:4. The micromechanical ultrasonic transducer structure according to any one of 1-3, also includes:
晶体管单元,包括晶体管基底以及在横向方向上间隔开布置的第一晶体管和第二晶体管,第一PMUT和第二PMUT分别与第一晶体管和第二晶体管在微机械超声换能器结构的厚度方向上对应;A transistor unit, including a transistor substrate and a first transistor and a second transistor arranged spaced apart in a lateral direction, the first PMUT and the second PMUT being respectively aligned with the first transistor and the second transistor in the thickness direction of the micromachined ultrasonic transducer structure corresponding;
PMUT单元与晶体管单元的一侧的表面接合,晶体管单元的一侧的表面为晶体管单元的接合面。The PMUT unit is bonded to a surface on one side of the transistor unit, and the surface on one side of the transistor unit is the bonding surface of the transistor unit.
5、根据4所述的微机械超声换能器结构,其中:5. The micromechanical ultrasonic transducer structure according to 4, wherein:
用于第一PMUT和第二PMUT的空腔处于所述接合面的设置了PMUT单元的一侧。The cavities for the first PMUT and the second PMUT are on the side of the joint surface on which the PMUT units are disposed.
6、根据5所述的微机械超声换能器结构,其中:6. The micromechanical ultrasonic transducer structure according to 5, wherein:
PMUT基底与晶体管单元的一侧的表面接合,PMUT基底设置有所述空腔。The PMUT substrate is bonded to the surface of one side of the transistor cell, the PMUT substrate being provided with the cavity.
7、根据6所述的微机械超声换能器结构,其中:7. The micromechanical ultrasonic transducer structure according to 6, wherein:
PMUT单元还包括用于支撑PMUT的支撑层,支撑层设置在两个PMUT与PMUT基底之间。
The PMUT unit also includes a support layer for supporting the PMUT, and the support layer is disposed between the two PMUTs and the PMUT substrate.
8、根据6所述的微机械超声换能器结构,其中:8. The micromechanical ultrasonic transducer structure according to 6, wherein:
所述空腔贯穿PMUT基底;或者The cavity penetrates the PMUT substrate; or
所述PMUT单元与晶体管单元之间设置有接合材料层,所述PMUT单元、所述晶体管单元以及所述接合材料层共同限定所述空腔,所述接合材料层的厚度限定所述空腔的高度。A bonding material layer is provided between the PMUT unit and the transistor unit. The PMUT unit, the transistor unit and the bonding material layer jointly define the cavity. The thickness of the bonding material layer defines the cavity. high.
9、根据4所述的微机械超声换能器结构,其中:9. The micromechanical ultrasonic transducer structure according to 4, wherein:
每个晶体管单元包括所述晶体管、彼此电绝缘的第一电连接层和第二电连接层;且Each transistor unit includes the transistor, a first electrical connection layer and a second electrical connection layer electrically insulated from each other; and
对于每一个PMUT和对应的晶体管:所述微机械超声换能器结构还包括彼此电绝缘的第一导电层与第二导电层,第一电极层经由第一导电层与第一电连接层电连接,第二电极层经由第二导电层与第二电连接层电连接。For each PMUT and corresponding transistor: the micromachined ultrasonic transducer structure further includes a first conductive layer and a second conductive layer that are electrically insulated from each other, and the first electrode layer is electrically connected to the first electrical connection layer through the first conductive layer. connection, the second electrode layer is electrically connected to the second electrical connection layer via the second conductive layer.
10、根据9所述的微机械超声换能器结构,对于每一个PMUT和对应的晶体管,还包括:10. According to the micromachined ultrasonic transducer structure described in 9, for each PMUT and corresponding transistor, it also includes:
第一导电用孔和第二导电孔,第一导电用孔贯穿PMUT单元以及抵达晶体管单元内的第一电连接层,第二导电用孔贯穿PMUT单元以及抵达晶体管单元内的第二电连接层,A first conductive hole and a second conductive hole. The first conductive hole penetrates the PMUT unit and reaches the first electrical connection layer in the transistor unit. The second conductive hole penetrates the PMUT unit and reaches the second electrical connection layer in the transistor unit. ,
其中:in:
第一导电层经由第一导电用孔与第一电连接层电连接,第二导电层经由第二导电用孔与第二电连接层电连接。The first conductive layer is electrically connected to the first electrical connection layer through the first conductive hole, and the second conductive layer is electrically connected to the second electrical connection layer through the second conductive hole.
11、根据4所述的微机械超声换能器结构,其中:11. The micromechanical ultrasonic transducer structure according to 4, wherein:
所述晶体管单元包括电路保护层,所述电路保护层覆盖所述晶体管;且The transistor unit includes a circuit protection layer covering the transistor; and
所述电路保护层的一侧的表面为所述接合面。The surface on one side of the circuit protection layer is the joint surface.
12、根据4所述的微机械超声换能器结构,其中:12. The micromechanical ultrasonic transducer structure according to 4, wherein:
所述晶体管单元包括CMOS单元、BiMOS单元、BCD单元中的一种。The transistor unit includes one of a CMOS unit, a BiMOS unit, and a BCD unit.
13、根据1所述的微机械超声换能器结构,其中:13. The micromechanical ultrasonic transducer structure according to 1, wherein:
第一PMUT的压电层的压电系数绝对值大于1C/m2;和/或The absolute value of the piezoelectric coefficient of the piezoelectric layer of the first PMUT is greater than 1C/m 2 ; and/or
第二PMUT的压电层的介电常数小于1200。The dielectric constant of the piezoelectric layer of the second PMUT is less than 1200.
14、根据13所述的微机械超声换能器结构,其中:14. The micromechanical ultrasonic transducer structure according to 13, wherein:
第一PMUT的压电层的压电系数绝对值大于5C/m2;和/或The absolute value of the piezoelectric coefficient of the piezoelectric layer of the first PMUT is greater than 5C/m 2 ; and/or
第二PMUT的压电层的介电常数小于100。
The dielectric constant of the piezoelectric layer of the second PMUT is less than 100.
15、一种微机械超声换能器结构的制造方法,包括步骤:15. A method for manufacturing a micromechanical ultrasonic transducer structure, including the steps:
提供晶体管单元,晶体管单元包括晶体管基底以及在横向方向上间隔开布置的第一晶体管和第二晶体管;以及A transistor unit is provided, the transistor unit including a transistor substrate and first and second transistors arranged spaced apart in a lateral direction; and
提供与晶体管单元的一侧的表面接合的PMUT单元,PMUT单元包括PMUT基底、第一PMUT和第二PMUT,PMUT基底与晶体管单元的一侧的表面以面接合的方式接合,每个PMUT包括第一电极层、第二电极层与压电层,A PMUT unit bonded to a surface of one side of the transistor unit is provided. The PMUT unit includes a PMUT substrate, a first PMUT and a second PMUT. The PMUT base is bonded to the surface of one side of the transistor unit in a surface bonding manner. Each PMUT includes a third PMUT. an electrode layer, a second electrode layer and a piezoelectric layer,
其中:in:
第一PMUT和第二PMUT在横向上彼此间隔开设置在PMUT基底的一侧,且分别与第一晶体管和第二晶体管在微机械超声换能器结构的厚度方向上对应;且The first PMUT and the second PMUT are laterally spaced apart from each other and arranged on one side of the PMUT substrate, and respectively correspond to the first transistor and the second transistor in the thickness direction of the micromachined ultrasound transducer structure; and
第一PMUT的压电层的压电系数高于第二PMUT的压电层的压电系数,第一PMUT的压电层的介电常数低于第二PMUT的压电层的介电常数。The piezoelectric coefficient of the piezoelectric layer of the first PMUT is higher than the piezoelectric coefficient of the piezoelectric layer of the second PMUT, and the dielectric constant of the piezoelectric layer of the first PMUT is lower than the dielectric constant of the piezoelectric layer of the second PMUT.
16、根据15所述的方法,其中,提供PMUT单元的步骤包括:16. The method according to 15, wherein the step of providing the PMUT unit includes:
在形成一个PMUT后设置覆盖其的保护层;After forming a PMUT, set a protective layer covering it;
与所述一个PMUT在横向上间隔开的设置另一个PMUT;disposing another PMUT laterally spaced apart from the one PMUT;
移除所述保护层。Remove the protective layer.
17、根据15或16所述的方法,其中,提供PMUT单元的步骤包括:17. The method according to 15 or 16, wherein the step of providing the PMUT unit includes:
提供PMUT初始基底以及设置在初始基底的一侧上的在横向方向上间隔开的第一PMUT和第二PMUT;providing a PMUT initial base and laterally spaced first and second PMUTs disposed on one side of the initial base;
以临时粘合层覆盖第一PMUT和第二PMUT以及设置辅助基底,所述辅助基底与所述临时粘合层接合;covering the first PMUT and the second PMUT with a temporary adhesive layer and providing an auxiliary substrate, the auxiliary substrate being bonded to the temporary adhesive layer;
在初始基底的另一侧执行减薄工艺以形成所述PMUT基底,且Perform a thinning process on the other side of the initial substrate to form the PMUT substrate, and
在将PMUT基底与晶体管单元的表面接合的步骤之后,所述方法还包括步骤:移除临时粘合层和辅助基底。After the step of bonding the PMUT substrate to the surface of the transistor unit, the method further includes the step of removing the temporary adhesive layer and the auxiliary substrate.
18、根据15所述的方法,其中:18. The method according to 15, wherein:
利用接合材料层将PMUT基底与晶体管单元的一侧的表面接合,所述PMUT单元、所述晶体管单元以及所述接合材料层共同限定所述空腔,所述接合材料层的厚度限定所述空腔的高度。The PMUT substrate is bonded to the surface of one side of the transistor unit using a bonding material layer. The PMUT unit, the transistor unit and the bonding material layer jointly define the cavity. The thickness of the bonding material layer defines the cavity. cavity height.
19、根据15所述的方法,其中:19. The method according to 15, wherein:
对于每个晶体管,所述晶体管单元包括彼此电绝缘的第一电连接层和第二电连接层;
For each transistor, the transistor unit includes a first electrical connection layer and a second electrical connection layer that are electrically insulated from each other;
所述方法还包括步骤:对于每一个PMUT和对应的晶体管,提供彼此电绝缘的第一导电层与第二导电层,第一电极层经由第一导电层与第一电连接层电连接,第二电极层经由第二导电层与第二电连接层电连接。The method further includes the steps of: for each PMUT and the corresponding transistor, providing a first conductive layer and a second conductive layer that are electrically insulated from each other, the first electrode layer is electrically connected to the first electrical connection layer via the first conductive layer, and The two electrode layers are electrically connected to the second electrical connection layer through the second conductive layer.
20、根据19所述的方法,对于每一个PMUT和对应的晶体管,其中:20. According to the method described in 19, for each PMUT and corresponding transistor, where:
在提供彼此电绝缘的第一导电层与第二导电层的步骤之前,还包括步骤:形成第一导电用孔和第二导电孔,第一导电用孔贯穿PMUT单元以及抵达从而露出晶体管单元内的第一电连接层,第二导电用孔贯穿PMUT单元以及抵达从而露出晶体管单元内的第二电连接层;Before the step of providing the first conductive layer and the second conductive layer that are electrically insulated from each other, the method further includes the step of forming a first conductive hole and a second conductive hole, and the first conductive hole penetrates the PMUT unit and reaches to expose the inside of the transistor unit. The first electrical connection layer, the second conductive hole penetrates the PMUT unit and reaches to expose the second electrical connection layer in the transistor unit;
在提供彼此电绝缘的第一导电层与第二导电层的步骤中,第一导电层经由第一导电用孔与第一电连接层电连接,第二导电层经由第二导电用孔与第二电连接层电连接。In the step of providing the first conductive layer and the second conductive layer that are electrically insulated from each other, the first conductive layer is electrically connected to the first electrical connection layer through the first conductive hole, and the second conductive layer is electrically connected to the first conductive layer through the second conductive hole. The two electrical connection layers are electrically connected.
21、根据15-20中任一项所述的方法,其中:21. The method according to any one of 15-20, wherein:
提供晶体管单元包括提供晶体管晶圆,基于MEMS工艺,所述晶体管晶圆形成有多个晶体管单元,每个晶体管单元包括在横向方向上间隔开布置的第一晶体管和第二晶体管;Providing a transistor unit includes providing a transistor wafer based on a MEMS process, the transistor wafer being formed with a plurality of transistor units, each transistor unit including a first transistor and a second transistor arranged spaced apart in a lateral direction;
提供与晶体管单元的一侧的表面接合的PMUT单元包括:提供PMUT晶圆,基于MEMS工艺,所述PMUT晶圆形成有与所述多个晶体管单元分别对应的多个PMUT单元,每个PMUT单元包括在横向上彼此间隔开设置的第一PMUT和第二PMUT,第一PMUT和第二PMUT分别与第一晶体管和第二晶体管在微机械超声换能器结构的厚度方向上对应;Providing a PMUT unit bonded to the surface of one side of the transistor unit includes: providing a PMUT wafer based on the MEMS process, the PMUT wafer is formed with a plurality of PMUT units respectively corresponding to the plurality of transistor units, each PMUT unit including a first PMUT and a second PMUT arranged laterally spaced apart from each other, the first PMUT and the second PMUT respectively corresponding to the first transistor and the second transistor in the thickness direction of the micromechanical ultrasonic transducer structure;
所述方法还包括步骤:执行切割以形成包括单个PMUT单元与单个晶体管单元的微机械超声换能器结构。The method also includes the step of performing cutting to form a micromachined ultrasound transducer structure including a single PMUT unit and a single transistor unit.
22、根据15-21中任一项所述的方法,其中:22. The method according to any one of 15-21, wherein:
第一PMUT的压电层为PZT或掺杂PZT,第二PMUT的压电层为AlN或AlScN。The piezoelectric layer of the first PMUT is PZT or doped PZT, and the piezoelectric layer of the second PMUT is AlN or AlScN.
23、根据15-22中任一项所述的方法,其中:23. The method according to any one of 15-22, wherein:
第一PMUT用于发射超声波,第二PMUT用于接收超声波。The first PMUT is used to transmit ultrasonic waves, and the second PMUT is used to receive ultrasonic waves.
24、根据15-23中任一项所述的方法,其中:24. The method according to any one of 15-23, wherein:
所述晶体管单元包括CMOS单元、BiMOS单元、BCD单元中的一种。The transistor unit includes one of a CMOS unit, a BiMOS unit, and a BCD unit.
25、根据15所述的方法,其中:25. The method according to 15, wherein:
第一PMUT的压电层的压电系数绝对值大于1C/m2;和/或
The absolute value of the piezoelectric coefficient of the piezoelectric layer of the first PMUT is greater than 1C/m 2 ; and/or
第二PMUT的压电层的介电常数小于1200。The dielectric constant of the piezoelectric layer of the second PMUT is less than 1200.
26、根据25所述的方法,其中:26. The method according to 25, wherein:
第一PMUT的压电层的压电系数绝对值大于5C/m2;和/或The absolute value of the piezoelectric coefficient of the piezoelectric layer of the first PMUT is greater than 5C/m 2 ; and/or
第二PMUT的压电层的介电常数小于100。The dielectric constant of the piezoelectric layer of the second PMUT is less than 100.
27、一种电子设备,包括根据1-14中任一项所述的微机械超声换能器结构,或者根据15-26中任一项所述的制造方法制造的微机械超声换能器结构。27. An electronic device, including the micromachined ultrasonic transducer structure according to any one of 1-14, or the micromachined ultrasonic transducer structure manufactured according to the manufacturing method according to any one of 15-26 .
28、根据27所述的电子设备,其中:28. The electronic device according to 27, wherein:
所述电子设备包括如下中的至少一种:超声成像仪、超声测距仪、超声指纹传感器、无损探伤仪、流量计、力觉反馈设备、烟雾报警器。The electronic device includes at least one of the following: an ultrasonic imager, an ultrasonic range finder, an ultrasonic fingerprint sensor, a non-destructive flaw detector, a flow meter, a force feedback device, and a smoke alarm.
尽管已经示出和描述了本发明的实施例,对于本领域的普通技术人员而言,可以理解在不脱离本发明的原理和精神的情况下可以对这些实施例进行变化,本发明的范围由所附权利要求及其等同物限定。
Although embodiments of the invention have been shown and described, it will be understood by those of ordinary skill in the art that changes may be made in these embodiments without departing from the principles and spirit of the invention. The scope of the invention is determined by are defined in the appended claims and their equivalents.
Claims (28)
- 一种微机械超声换能器结构,包括:A micromachined ultrasonic transducer structure, including:PMUT单元,包括PMUT基底、第一PMUT和第二PMUT,每个PMUT包括第一电极层、第二电极层与压电层,The PMUT unit includes a PMUT substrate, a first PMUT and a second PMUT. Each PMUT includes a first electrode layer, a second electrode layer and a piezoelectric layer,其中:in:第一PMUT和第二PMUT在横向上彼此间隔开设置在PMUT基底的一侧;The first PMUT and the second PMUT are laterally spaced apart from each other and arranged on one side of the PMUT substrate;第一PMUT的压电层的压电系数高于第二PMUT的压电层的压电系数,且第一PMUT的压电层的介电常数低于第二PMUT的压电层的介电常数。The piezoelectric coefficient of the piezoelectric layer of the first PMUT is higher than the piezoelectric coefficient of the piezoelectric layer of the second PMUT, and the dielectric constant of the piezoelectric layer of the first PMUT is lower than the dielectric constant of the piezoelectric layer of the second PMUT. .
- 根据权利要求1所述的微机械超声换能器结构,其中:The micromachined ultrasonic transducer structure according to claim 1, wherein:第一PMUT的压电层为PZT或掺杂PZT,第二PMUT的压电层为ALN或AlScN。The piezoelectric layer of the first PMUT is PZT or doped PZT, and the piezoelectric layer of the second PMUT is ALN or AlScN.
- 根据权利要求1所述的微机械超声换能器结构,其中:The micromachined ultrasonic transducer structure according to claim 1, wherein:第一PMUT用于发射超声波,第二PMUT用于接收超声波。The first PMUT is used to transmit ultrasonic waves, and the second PMUT is used to receive ultrasonic waves.
- 根据权利要求1-3中任一项所述的微机械超声换能器结构,还包括:The micromechanical ultrasonic transducer structure according to any one of claims 1-3, further comprising:晶体管单元,包括晶体管基底以及在横向方向上间隔开布置的第一晶体管和第二晶体管,第一PMUT和第二PMUT分别与第一晶体管和第二晶体管在微机械超声换能器结构的厚度方向上对应;A transistor unit, including a transistor substrate and a first transistor and a second transistor arranged spaced apart in a lateral direction, the first PMUT and the second PMUT being respectively aligned with the first transistor and the second transistor in the thickness direction of the micromachined ultrasonic transducer structure corresponding;PMUT单元与晶体管单元的一侧的表面接合,晶体管单元的一侧的表面为晶体管单元的接合面。The PMUT unit is bonded to a surface on one side of the transistor unit, and the surface on one side of the transistor unit is the bonding surface of the transistor unit.
- 根据权利要求4所述的微机械超声换能器结构,其中:The micromachined ultrasound transducer structure according to claim 4, wherein:用于第一PMUT和第二PMUT的空腔处于所述接合面的设置了PMUT单元的一侧。The cavities for the first PMUT and the second PMUT are on the side of the joint surface on which the PMUT units are disposed.
- 根据权利要求5所述的微机械超声换能器结构,其中:The micromachined ultrasonic transducer structure according to claim 5, wherein:PMUT基底与晶体管单元的一侧的表面接合,PMUT基底设置有所述空腔。The PMUT substrate is bonded to the surface of one side of the transistor cell, the PMUT substrate being provided with the cavity.
- 根据权利要求6所述的微机械超声换能器结构,其中:The micromachined ultrasound transducer structure according to claim 6, wherein:PMUT单元还包括用于支撑PMUT的支撑层,支撑层设置在两个PMUT 与PMUT基底之间。The PMUT unit also includes a support layer for supporting the PMUT. The support layer is provided on the two PMUTs. and PMUT substrate.
- 根据权利要求6所述的微机械超声换能器结构,其中:The micromachined ultrasound transducer structure according to claim 6, wherein:所述空腔贯穿PMUT基底;或者The cavity penetrates the PMUT substrate; or所述PMUT单元与晶体管单元之间设置有接合材料层,所述PMUT单元、所述晶体管单元以及所述接合材料层共同限定所述空腔,所述接合材料层的厚度限定所述空腔的高度。A bonding material layer is provided between the PMUT unit and the transistor unit. The PMUT unit, the transistor unit and the bonding material layer jointly define the cavity. The thickness of the bonding material layer defines the cavity. high.
- 根据权利要求4所述的微机械超声换能器结构,其中:The micromachined ultrasound transducer structure according to claim 4, wherein:每个晶体管单元包括所述晶体管、彼此电绝缘的第一电连接层和第二电连接层;且Each transistor unit includes the transistor, a first electrical connection layer and a second electrical connection layer electrically insulated from each other; and对于每一个PMUT和对应的晶体管:所述微机械超声换能器结构还包括彼此电绝缘的第一导电层与第二导电层,第一电极层经由第一导电层与第一电连接层电连接,第二电极层经由第二导电层与第二电连接层电连接。For each PMUT and corresponding transistor: the micromachined ultrasonic transducer structure further includes a first conductive layer and a second conductive layer that are electrically insulated from each other, and the first electrode layer is electrically connected to the first electrical connection layer through the first conductive layer. connection, the second electrode layer is electrically connected to the second electrical connection layer via the second conductive layer.
- 根据权利要求9所述的微机械超声换能器结构,对于每一个PMUT和对应的晶体管,还包括:The micromachined ultrasonic transducer structure according to claim 9, for each PMUT and corresponding transistor, further comprising:第一导电用孔和第二导电孔,第一导电用孔贯穿PMUT单元以及抵达晶体管单元内的第一电连接层,第二导电用孔贯穿PMUT单元以及抵达晶体管单元内的第二电连接层,A first conductive hole and a second conductive hole. The first conductive hole penetrates the PMUT unit and reaches the first electrical connection layer in the transistor unit. The second conductive hole penetrates the PMUT unit and reaches the second electrical connection layer in the transistor unit. ,其中:in:第一导电层经由第一导电用孔与第一电连接层电连接,第二导电层经由第二导电用孔与第二电连接层电连接。The first conductive layer is electrically connected to the first electrical connection layer through the first conductive hole, and the second conductive layer is electrically connected to the second electrical connection layer through the second conductive hole.
- 根据权利要求4所述的微机械超声换能器结构,其中:The micromachined ultrasound transducer structure according to claim 4, wherein:所述晶体管单元包括电路保护层,所述电路保护层覆盖所述晶体管;且The transistor unit includes a circuit protection layer covering the transistor; and所述电路保护层的一侧的表面为所述接合面。The surface on one side of the circuit protection layer is the joint surface.
- 根据权利要求4所述的微机械超声换能器结构,其中:The micromachined ultrasound transducer structure according to claim 4, wherein:所述晶体管单元包括CMOS单元、BiMOS单元、BCD单元中的一种。The transistor unit includes one of a CMOS unit, a BiMOS unit, and a BCD unit.
- 根据权利要求1所述的微机械超声换能器结构,其中:The micromachined ultrasonic transducer structure according to claim 1, wherein:第一PMUT的压电层的压电系数绝对值大于1C/m2;和/或The absolute value of the piezoelectric coefficient of the piezoelectric layer of the first PMUT is greater than 1C/m 2 ; and/or第二PMUT的压电层的介电常数小于1200。The dielectric constant of the piezoelectric layer of the second PMUT is less than 1200.
- 根据权利要求13所述的微机械超声换能器结构,其中: The micromachined ultrasound transducer structure according to claim 13, wherein:第一PMUT的压电层的压电系数绝对值大于5C/m2;和/或The absolute value of the piezoelectric coefficient of the piezoelectric layer of the first PMUT is greater than 5C/m 2 ; and/or第二PMUT的压电层的介电常数小于100。The dielectric constant of the piezoelectric layer of the second PMUT is less than 100.
- 一种微机械超声换能器结构的制造方法,包括步骤:A method for manufacturing a micromechanical ultrasonic transducer structure, including the steps:提供晶体管单元,晶体管单元包括晶体管基底以及在横向方向上间隔开布置的第一晶体管和第二晶体管;以及A transistor unit is provided, the transistor unit including a transistor substrate and first and second transistors arranged spaced apart in a lateral direction; and提供与晶体管单元的一侧的表面接合的PMUT单元,PMUT单元包括PMUT基底、第一PMUT和第二PMUT,PMUT基底与晶体管单元的一侧的表面以面接合的方式接合,每个PMUT包括第一电极层、第二电极层与压电层,A PMUT unit bonded to a surface of one side of the transistor unit is provided. The PMUT unit includes a PMUT substrate, a first PMUT and a second PMUT. The PMUT base is bonded to the surface of one side of the transistor unit in a surface bonding manner. Each PMUT includes a third PMUT. an electrode layer, a second electrode layer and a piezoelectric layer,其中:in:第一PMUT和第二PMUT在横向上彼此间隔开设置在PMUT基底的一侧,且分别与第一晶体管和第二晶体管在微机械超声换能器结构的厚度方向上对应;且The first PMUT and the second PMUT are laterally spaced apart from each other and arranged on one side of the PMUT substrate, and respectively correspond to the first transistor and the second transistor in the thickness direction of the micromachined ultrasound transducer structure; and第一PMUT的压电层的压电系数高于第二PMUT的压电层的压电系数,第一PMUT的压电层的介电常数低于第二PMUT的压电层的介电常数。The piezoelectric coefficient of the piezoelectric layer of the first PMUT is higher than the piezoelectric coefficient of the piezoelectric layer of the second PMUT, and the dielectric constant of the piezoelectric layer of the first PMUT is lower than the dielectric constant of the piezoelectric layer of the second PMUT.
- 根据权利要求15所述的方法,其中,提供PMUT单元的步骤包括:The method of claim 15, wherein the step of providing a PMUT unit includes:在形成一个PMUT后设置覆盖其的保护层;After forming a PMUT, set a protective layer covering it;与所述一个PMUT在横向上间隔开的设置另一个PMUT;disposing another PMUT laterally spaced apart from the one PMUT;移除所述保护层。Remove the protective layer.
- 根据权利要求15或16所述的方法,其中,提供PMUT单元的步骤包括:The method according to claim 15 or 16, wherein the step of providing a PMUT unit includes:提供PMUT初始基底以及设置在初始基底的一侧上的在横向方向上间隔开的第一PMUT和第二PMUT;providing a PMUT initial base and laterally spaced first and second PMUTs disposed on one side of the initial base;以临时粘合层覆盖第一PMUT和第二PMUT以及设置辅助基底,所述辅助基底与所述临时粘合层接合;covering the first PMUT and the second PMUT with a temporary adhesive layer and providing an auxiliary substrate, the auxiliary substrate being bonded to the temporary adhesive layer;在初始基底的另一侧执行减薄工艺以形成所述PMUT基底,且Perform a thinning process on the other side of the initial substrate to form the PMUT substrate, and在将PMUT基底与晶体管单元的表面接合的步骤之后,所述方法还包括步骤:移除临时粘合层和辅助基底。After the step of bonding the PMUT substrate to the surface of the transistor unit, the method further includes the step of removing the temporary adhesive layer and the auxiliary substrate.
- 根据权利要求15所述的方法,其中:The method of claim 15, wherein:利用接合材料层将PMUT基底与晶体管单元的一侧的表面接合,所述 PMUT单元、所述晶体管单元以及所述接合材料层共同限定所述空腔,所述接合材料层的厚度限定所述空腔的高度。The PMUT substrate is bonded to the surface of one side of the transistor unit using a layer of bonding material, the The PMUT unit, the transistor unit and the bonding material layer together define the cavity, and the thickness of the bonding material layer defines the height of the cavity.
- 根据权利要求15所述的方法,其中:The method of claim 15, wherein:对于每个晶体管,所述晶体管单元包括彼此电绝缘的第一电连接层和第二电连接层;For each transistor, the transistor unit includes a first electrical connection layer and a second electrical connection layer that are electrically insulated from each other;所述方法还包括步骤:对于每一个PMUT和对应的晶体管,提供彼此电绝缘的第一导电层与第二导电层,第一电极层经由第一导电层与第一电连接层电连接,第二电极层经由第二导电层与第二电连接层电连接。The method further includes the steps of: for each PMUT and the corresponding transistor, providing a first conductive layer and a second conductive layer that are electrically insulated from each other, the first electrode layer is electrically connected to the first electrical connection layer via the first conductive layer, and The two electrode layers are electrically connected to the second electrical connection layer through the second conductive layer.
- 根据权利要求19所述的方法,对于每一个PMUT和对应的晶体管,其中:The method of claim 19, for each PMUT and corresponding transistor, wherein:在提供彼此电绝缘的第一导电层与第二导电层的步骤之前,还包括步骤:形成第一导电用孔和第二导电孔,第一导电用孔贯穿PMUT单元以及抵达从而露出晶体管单元内的第一电连接层,第二导电用孔贯穿PMUT单元以及抵达从而露出晶体管单元内的第二电连接层;Before the step of providing the first conductive layer and the second conductive layer that are electrically insulated from each other, the method further includes the step of forming a first conductive hole and a second conductive hole, and the first conductive hole penetrates the PMUT unit and reaches to expose the inside of the transistor unit. The first electrical connection layer, the second conductive hole penetrates the PMUT unit and reaches to expose the second electrical connection layer in the transistor unit;在提供彼此电绝缘的第一导电层与第二导电层的步骤中,第一导电层经由第一导电用孔与第一电连接层电连接,第二导电层经由第二导电用孔与第二电连接层电连接。In the step of providing the first conductive layer and the second conductive layer that are electrically insulated from each other, the first conductive layer is electrically connected to the first electrical connection layer through the first conductive hole, and the second conductive layer is electrically connected to the first conductive layer through the second conductive hole. The two electrical connection layers are electrically connected.
- 根据权利要求15-20中任一项所述的方法,其中:The method according to any one of claims 15-20, wherein:提供晶体管单元包括提供晶体管晶圆,基于MEMS工艺,所述晶体管晶圆形成有多个晶体管单元,每个晶体管单元包括在横向方向上间隔开布置的第一晶体管和第二晶体管;Providing a transistor unit includes providing a transistor wafer based on a MEMS process, the transistor wafer being formed with a plurality of transistor units, each transistor unit including a first transistor and a second transistor arranged spaced apart in a lateral direction;提供与晶体管单元的一侧的表面接合的PMUT单元包括:提供PMUT晶圆,基于MEMS工艺,所述PMUT晶圆形成有与所述多个晶体管单元分别对应的多个PMUT单元,每个PMUT单元包括在横向上彼此间隔开设置的第一PMUT和第二PMUT,第一PMUT和第二PMUT分别与第一晶体管和第二晶体管在微机械超声换能器结构的厚度方向上对应;Providing a PMUT unit bonded to the surface of one side of the transistor unit includes: providing a PMUT wafer based on the MEMS process, the PMUT wafer is formed with a plurality of PMUT units respectively corresponding to the plurality of transistor units, each PMUT unit including a first PMUT and a second PMUT arranged laterally spaced apart from each other, the first PMUT and the second PMUT respectively corresponding to the first transistor and the second transistor in the thickness direction of the micromechanical ultrasonic transducer structure;所述方法还包括步骤:执行切割以形成包括单个PMUT单元与单个晶体管单元的微机械超声换能器结构。The method also includes the step of performing cutting to form a micromachined ultrasound transducer structure including a single PMUT unit and a single transistor unit.
- 根据权利要求15-21中任一项所述的方法,其中:The method according to any one of claims 15-21, wherein:第一PMUT的压电层为PZT或掺杂PZT,第二PMUT的压电层为AlN或 AlScN。The piezoelectric layer of the first PMUT is PZT or doped PZT, and the piezoelectric layer of the second PMUT is AlN or AlScN.
- 根据权利要求15-22中任一项所述的方法,其中:The method according to any one of claims 15-22, wherein:第一PMUT用于发射超声波,第二PMUT用于接收超声波。The first PMUT is used to transmit ultrasonic waves, and the second PMUT is used to receive ultrasonic waves.
- 根据权利要求15-23中任一项所述的方法,其中:The method according to any one of claims 15-23, wherein:所述晶体管单元包括CMOS单元、BiMOS单元、BCD单元中的一种。The transistor unit includes one of a CMOS unit, a BiMOS unit, and a BCD unit.
- 根据权利要求15所述的方法,其中:The method of claim 15, wherein:第一PMUT的压电层的压电系数绝对值大于1C/m2;和/或The absolute value of the piezoelectric coefficient of the piezoelectric layer of the first PMUT is greater than 1C/m 2 ; and/or第二PMUT的压电层的介电常数小于1200。The dielectric constant of the piezoelectric layer of the second PMUT is less than 1200.
- 根据权利要求25所述的方法,其中:The method of claim 25, wherein:第一PMUT的压电层的压电系数绝对值大于5C/m2;和/或The absolute value of the piezoelectric coefficient of the piezoelectric layer of the first PMUT is greater than 5C/m 2 ; and/or第二PMUT的压电层的介电常数小于100。The dielectric constant of the piezoelectric layer of the second PMUT is less than 100.
- 一种电子设备,包括根据权利要求1-14中任一项所述的微机械超声换能器结构,或者根据权利要求15-26中任一项所述的制造方法制造的微机械超声换能器结构。An electronic device, comprising a micromachined ultrasonic transducer structure according to any one of claims 1-14, or a micromachined ultrasonic transducer manufactured according to the manufacturing method according to any one of claims 15-26 device structure.
- 根据权利要求27所述的电子设备,其中:The electronic device of claim 27, wherein:所述电子设备包括如下中的至少一种:超声成像仪、超声测距仪、超声指纹传感器、无损探伤仪、流量计、力觉反馈设备、烟雾报警器。 The electronic device includes at least one of the following: an ultrasonic imager, an ultrasonic range finder, an ultrasonic fingerprint sensor, a non-destructive flaw detector, a flow meter, a force feedback device, and a smoke alarm.
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US20170194934A1 (en) * | 2014-05-09 | 2017-07-06 | Chirp Microsystems, Inc. | Micromachined ultrasound transducer using multiple piezoelectric materials |
CN110575946A (en) * | 2019-09-26 | 2019-12-17 | 索夫纳特私人有限公司 | Piezoelectric micro-mechanical ultrasonic transducer |
CN111182429A (en) * | 2020-01-03 | 2020-05-19 | 武汉大学 | High fill rate MEMS transducer |
TW202139493A (en) * | 2020-04-06 | 2021-10-16 | 日商住友化學股份有限公司 | Piezoelectric stack up, method of producing piezoelectric stack up, and piezoelectric device |
CN114682472A (en) * | 2022-03-25 | 2022-07-01 | 深圳市汇顶科技股份有限公司 | Ultrasonic transducer and method of manufacturing the same |
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US20170194934A1 (en) * | 2014-05-09 | 2017-07-06 | Chirp Microsystems, Inc. | Micromachined ultrasound transducer using multiple piezoelectric materials |
CN110575946A (en) * | 2019-09-26 | 2019-12-17 | 索夫纳特私人有限公司 | Piezoelectric micro-mechanical ultrasonic transducer |
CN111182429A (en) * | 2020-01-03 | 2020-05-19 | 武汉大学 | High fill rate MEMS transducer |
TW202139493A (en) * | 2020-04-06 | 2021-10-16 | 日商住友化學股份有限公司 | Piezoelectric stack up, method of producing piezoelectric stack up, and piezoelectric device |
CN114682472A (en) * | 2022-03-25 | 2022-07-01 | 深圳市汇顶科技股份有限公司 | Ultrasonic transducer and method of manufacturing the same |
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