WO2024021084A1 - Plate preparation method, plate preparation device, plate, electrode assembly, battery cell, battery and electric device - Google Patents

Plate preparation method, plate preparation device, plate, electrode assembly, battery cell, battery and electric device Download PDF

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Publication number
WO2024021084A1
WO2024021084A1 PCT/CN2022/109153 CN2022109153W WO2024021084A1 WO 2024021084 A1 WO2024021084 A1 WO 2024021084A1 CN 2022109153 W CN2022109153 W CN 2022109153W WO 2024021084 A1 WO2024021084 A1 WO 2024021084A1
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WO
WIPO (PCT)
Prior art keywords
active material
mold
pole piece
base material
cover
Prior art date
Application number
PCT/CN2022/109153
Other languages
French (fr)
Chinese (zh)
Inventor
黄彩虾
陈伟
葛少兵
佘扬帆
梁静冰
唐鸣浩
Original Assignee
宁德时代新能源科技股份有限公司
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Application filed by 宁德时代新能源科技股份有限公司 filed Critical 宁德时代新能源科技股份有限公司
Priority to PCT/CN2022/109153 priority Critical patent/WO2024021084A1/en
Publication of WO2024021084A1 publication Critical patent/WO2024021084A1/en

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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/05Accumulators with non-aqueous electrolyte
    • H01M10/052Li-accumulators
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/13Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/139Processes of manufacture
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

Definitions

  • the present application relates to the field of battery technology, specifically, to a pole piece preparation method, pole piece preparation device, pole piece, electrode assembly, battery cell, battery and electrical device.
  • Electric vehicles have become an important part of the sustainable development of the automobile industry due to their advantages in energy conservation and environmental protection.
  • battery technology is an important factor related to their development.
  • This application provides a pole piece preparation method, pole piece preparation device, pole piece, electrode assembly, battery cell, battery and electrical device.
  • the pole piece preparation method can effectively simplify the pole piece production process, improve battery production efficiency, and at the same time , this pole piece preparation method facilitates and effectively improves the energy density of the battery.
  • this application provides a pole piece preparation method, which includes: adding active material and base material into the mold cavity of the mold; covering the active material and base material with a cover; The cover and/or the mold apply force, and the active material and the base material are co-extruded through the cover and the mold, so that the active material and the base material are composited to form a pole piece.
  • the pole piece formed by extrusion compounding can effectively improve the compaction and density of the active material on the base material, and can effectively improve its energy density
  • the compaction of the pole piece Adjustable, pole pieces with different compaction densities can be obtained by designing molds with different cavity volumes or by controlling different feeding amounts; on the other hand, the method of forming pole pieces through die extrusion and compounding facilitates an increase in the thickness of the active material layer. , thus enabling the preparation of pole pieces with higher thickness requirements to meet the preparation requirements for thick pole pieces, and increasing the thickness of the pole pieces can effectively increase the active material capacity, thereby effectively increasing its energy density.
  • the cavity of the mold plays a role in limiting and shaping the active material.
  • pole pieces of the target shape and size can be directly prepared.
  • the technical solution of this application can effectively simplify the processes such as coating, substrate rewinding and unwinding, pole piece cutting, etc., and reduce the transfer time between each process, reduce the working hours of coating, drying and other processes, thereby effectively improving Pole piece production efficiency.
  • the method further includes: drying the pole piece located in the mold cavity; and taking out the dried pole piece from the mold.
  • the pole pieces formed by extrusion and compounding are directly dried in the mold cavity, and then the dried pole pieces are separated from the mold cavity.
  • it can effectively avoid the problem caused by directly demolding the extruded pole pieces.
  • Problems such as pole piece deformation and active material displacement can effectively ensure the structural stability of the pole piece and the production yield of the pole piece.
  • the pole piece compounding and pole piece drying are integrated into the same work station. This further reduces the transportation and transfer time in pole piece production, further improving the pole piece production efficiency.
  • drying the pole piece located in the mold cavity includes: increasing the temperature of the mold and/or the cover to dry the pole piece .
  • the pole pieces are dried by increasing the temperature of the mold and/or the cover.
  • the extruded pole pieces are located between the mold and the cover, and the temperature of the mold and/or the cover is directly increased to dry the pole pieces.
  • Heating the pole pieces can effectively reduce the heating distance of the pole pieces, improve the uniformity of heating of the pole pieces, and thereby improve the drying efficiency of the pole pieces; on the other hand, the mold and cover play a role in the heating and drying process of the pole pieces.
  • the positioning and shaping effect can effectively reduce the risk of warping and deformation of the pole pieces during the heating process, thereby effectively ensuring the drying quality of the pole pieces; furthermore, compared with traditional pole piece drying through ovens, ovens and other equipment,
  • the method of heating the pole pieces by raising the temperature of the mold and/or cover can provide the pole pieces with a small heating range but more accurate heat source, which is not only conducive to improving the heating and drying efficiency of the pole pieces, but also effectively reduces the drying time. Dry heat energy demand, saving the investment cost of drying equipment, is conducive to significantly reducing the production cost of pole pieces, and has high economic benefits.
  • the mold is a metal piece
  • raising the temperature of the mold and/or the cover includes: energizing the mold to increase the temperature of the mold.
  • the temperature of the mold can be increased by energizing the metal mold.
  • the mold heats up quickly and has a strong temperature rise balance, which is conducive to further improving the pole piece drying efficiency and pole piece drying quality, and is conducive to further reducing the pole piece drying efficiency.
  • adding the active material and the base material into the mold cavity of the mold includes sequentially adding the active material and the base material into the mold cavity; and covering the cover in the mold cavity.
  • Placing the active material and the base material includes: covering the base material with the covering member.
  • the active material and the base material are added sequentially into the mold cavity, the base material is covered on the active material, and then the cover is covered on the base material, and the cover and the mold jointly extrude the active material and the base material to form The active material is extruded and compounded on the side of the base material away from the cover to form a single-sided coated pole piece.
  • adding the active material and the base material into the mold cavity of the mold includes: sequentially adding a first layer of the active material, the base material and a second layer into the mold cavity.
  • the active material; covering the covering member on the active material and the base material includes: covering the covering member on the second layer of the active material.
  • the first layer of active material, the base material and the second layer of active material are sequentially added into the mold cavity.
  • the base material is located between the two layers of active material, and then the cover is covered on the second layer of active material.
  • the component and the die co-extrude two layers of active materials and the base material, so that the two layers of active materials are extruded and compounded on both sides of the base material to form a double-sided coated pole piece.
  • the mold includes a body and a protruding portion, the body has the mold cavity, the protruding portion protrudes from the bottom wall of the mold cavity, and the bottom wall is connected to the mold cavity.
  • the openings of the mold cavity are opposite to each other; and sequentially adding the first layer of the active material, the base material and the second layer of the active material into the mold cavity includes: sequentially adding the first layer into the mold cavity.
  • the active material and the base material covering the cover on the base material; applying force to the cover and/or the mold, and extruding the first through the cover and the mold together.
  • the mold includes a protruding portion provided on the bottom wall of the mold cavity.
  • the protruding portion can form a container for accommodating the electrolyte on the active material. cavity to promote the storage and infiltration of electrolyte inside the pole piece, improve the problem of large ionic resistance of the pole piece, and increase the battery cycle life;
  • the protruding part can penetrate the base material, This is to ensure that the protrusions can form accommodation cavities for the active materials on both sides of the base material.
  • the base material and the second layer of active material When adding the first layer of active material, the base material and the second layer of active material into the mold cavity in sequence, first add the first layer of active material and the base material into the mold cavity in sequence. Because there are protrusions in the mold cavity, The base material will resist the end of the protrusion without force, which will affect the addition of the second layer of active material into the mold cavity. At this time, the cover is covered on the base material, and the base material and the first layer of active material are extruded together through the cover and the mold, so that the base material penetrates the protruding portion and moves closer to the first layer of active material. The second layer of active material makes room for filling.
  • the cover is again covered on the second layer of active material and extruded together with the mold, so that the first layer of active material, the base material and the second layer of active material are compositely formed into one body.
  • the protruding portion forms accommodating cavities in both the first layer of active material and the second layer of active material.
  • the application provides a pole piece preparation device, including: a mold, the mold is provided with a mold cavity, the mold cavity is used to accommodate active materials and base materials; a cover, the cover is configured The purpose is to at least partially extend into the mold cavity through the opening of the mold cavity, so as to co-extrude the active material and the base material with the mold, so that the active material and the base material are composited to form a pole piece.
  • the pole piece preparation device of the technical solution of the present application includes a mold and a cover.
  • the mold is provided with a mold cavity for accommodating active materials and base materials. When used, the active materials and base materials are added to the mold cavity, and the cover is covered on the mold. On the active material or substrate in the cavity, force is applied to the mold and/or cover so that at least part of the cover extends into the mold cavity, and the cover and the mold jointly squeeze the active material and substrate, so that the active material and The base materials are combined to form pole pieces.
  • the structure in which the mold and the cover are co-extruded can effectively improve the compaction and density of the active material on the substrate, and can effectively increase the energy density of the pole piece.
  • the structure in which the mold and the cover are co-extruded It is convenient to thicken the thickness of the active material layer, so that pole pieces with higher thickness requirements can be stably prepared to meet the preparation needs of thick pole pieces, and it is also convenient to effectively increase the active material capacity by increasing the thickness of the pole piece, thereby effectively increasing its energy density. . Furthermore, by controlling the shape and size of the mold cavity, pole pieces of the target shape and size can be directly prepared, which is beneficial to improving the production efficiency of the pole pieces.
  • the mold includes a body and a protruding portion, the body has the mold cavity, the protruding portion protrudes from the bottom wall of the mold cavity, and the bottom wall is connected to the mold cavity.
  • the openings of the mold cavity are opposite to each other, and the protruding portion is used to form a receiving cavity for accommodating electrolyte on the active material.
  • the mold includes a protrusion arranged on the bottom wall of the mold cavity.
  • the protrusion can be used during the compaction process of the active material.
  • a certain space is reserved on the active material, which forms a holding cavity for accommodating the electrolyte. The thicker the electrode piece, the longer the diffusion path of liquid phase ions, and the greater the diffusion resistance of the electrolyte, which will affect the battery. of magnification.
  • a receiving cavity for accommodating electrolyte is provided in the active material layer of the pole piece by physically forming holes, which can increase the thickness and compactness of the active material layer of the pole piece and at the same time promote the electrolyte in the pole piece.
  • the storage and infiltration inside the chip improves the problem of large ionic resistance of the electrode piece and effectively increases the cycle life of the battery, which is beneficial to effectively ensure the charge and discharge rate of the battery while ensuring the energy density of the battery.
  • a plurality of spaced-apart protrusions are provided in the mold cavity to form a plurality of spaced-apart accommodation cavities for accommodating electrolyte on the pole piece, thereby further improving the storage and storage of electrolyte on the pole piece. infiltration amount, and effectively improve the uniformity of electrolyte distribution and penetration.
  • the cover is provided with an escape hole for the protruding portion to pass through.
  • the cover is provided with an escape hole for the protruding portion to pass through.
  • the arrangement of the escape hole can provide more extension space for the protruding portion, thereby ensuring the depth of the accommodation cavity along the thickness direction of the pole piece. , effectively increasing the volume of the accommodation cavity, and enabling the protruding portion to penetrate the pole piece along the thickness direction of the pole piece.
  • active materials can be provided on both sides of the thickness direction of the base material, and the protruding portion Penetrating the pole piece along the thickness direction of the pole piece is conducive to forming accommodation cavities for the active materials on both sides of the base material; on the other hand, the setting of the avoidance hole can effectively avoid positional interference between the cover and the protruding portion, which affects the mold and The problem of the extrusion strength of the cover piece can effectively ensure the compactness of the extrusion molding of the pole piece, and ensure the structural stability of the pole piece while ensuring the energy density of the pole piece.
  • the pole piece preparation device further includes: a drying mechanism for drying the pole piece.
  • the pole piece preparation device is provided with a drying mechanism to dry the extruded pole pieces.
  • the drying mechanism includes a power supply mechanism
  • the mold is a metal piece
  • the power supply mechanism is used to energize the mold to heat the mold to dry the pole piece
  • the cover is a metal piece, and the power supply mechanism is used to energize the cover to raise the temperature of the cover to dry the pole piece.
  • a power supply mechanism is provided to energize the metal mold and/or the metal cover. After the mold and/or the cover are energized, the temperature rises to directly heat the pole piece located between the mold and the cover. drying.
  • a power supply mechanism is used to supply power to the mold and/or cover.
  • the mold and/or cover heats up quickly and with a strong balance of temperature rise, which is conducive to further improving the pole piece drying efficiency and pole piece drying quality, and is conducive to further reducing the pole piece drying efficiency. Production cost; at the same time, the pole pieces are heated and dried between the mold and the cover.
  • the mold and the cover play a role in clamping and positioning the pole pieces, effectively reducing the risk of pole piece drying deformation, thereby ensuring the pole piece drying quality.
  • the pole piece preparation device further includes: a pressurizing mechanism connected to the cover, and the pressurizing mechanism is used to apply pressure to the cover so that the cover and The die co-extrudes the active material and substrate in the die cavity.
  • a pressurizing mechanism is provided to apply pressure to the cover, so that the cover and the mold can jointly squeeze the active material and the base material in the mold cavity, so that the active material and the base material can be compositely formed into pole pieces.
  • the present application provides a pole piece, including: a base material; a first active material layer disposed on one side of the base material in the thickness direction, and the first active material layer includes a layer facing away from the base material.
  • the first surface wherein, the first surface is provided with a first accommodation cavity for accommodating electrolyte.
  • the pole piece includes a base material and a first active material layer.
  • the first active material layer is provided with a first accommodation cavity, and the first accommodation cavity is used to accommodate electrolyte.
  • the thicker the pole piece the longer the diffusion path of liquid ions and the greater the diffusion resistance of the electrolyte.
  • the design of the first accommodation cavity can increase the active material of the pole piece. While improving the layer thickness and pressure tightness, it promotes the storage and infiltration of electrolyte inside the pole piece, improves the problem of large ion resistance of the pole piece, and effectively increases the cycle life of the battery.
  • the setting of the first accommodation cavity can assist the electrolyte to penetrate into the interior of the first active material layer, effectively increasing the penetration thickness of the electrolyte, thereby ensuring the full utilization of the pole pieces and reducing insufficient reaction due to thick pole pieces. Therefore, the pole piece of the technical solution of the present application can effectively ensure the battery performance while effectively ensuring the energy density of the battery.
  • the pole piece further includes: a second active material layer disposed on the other side in the thickness direction of the base material, and the second active material layer includes a third active material layer facing away from the base material. Two surfaces, the second surface is provided with a second accommodation cavity for accommodating electrolyte.
  • the pole piece includes a base material and a first active material layer and a second active material layer coated on both sides in the thickness direction of the base material, which effectively increases the active material passenger capacity of the pole piece, thereby increasing the energy density;
  • first Both the active material layer and the second active material layer are provided with accommodating cavities, which is conducive to further improving the storage capacity and infiltration efficiency of the electrolyte, and effectively improves the uniformity of the distribution and penetration of the electrolyte on the pole piece, ensuring double-sided coated poles. full utilization of the film.
  • the base material is provided with a through hole, and the first accommodation cavity and the second accommodation cavity are connected to each other through the through hole.
  • the first accommodation cavity and the second accommodation cavity are connected through the through hole on the base material, which can effectively improve the circulation of the electrolyte and further improve the infiltration efficiency of the electrolyte.
  • the thickness of the second active material layer is H1, satisfying H1 ⁇ 1500 ⁇ m, preferably, 70 ⁇ m ⁇ H1 ⁇ 1500 ⁇ m.
  • the thickness of the active material layer of the pole piece provided with the accommodation cavity of the present application can reach 70 ⁇ m to 1500 ⁇ m, which can effectively increase the thickness of the pole piece and simultaneously Ensure the reaction adequacy and rate capability of the pole piece, thereby effectively ensuring the energy density and charge and discharge rate of the battery using the pole piece.
  • the thickness of the first active material layer is H2, satisfying H2 ⁇ 1500 ⁇ m, preferably, 70 ⁇ m ⁇ H2 ⁇ 1500 ⁇ m.
  • both the first active material layer and the second active material layer are provided with accommodation cavities.
  • the thickness of the first active material layer can reach 70 ⁇ m to 1500 ⁇ m, which can effectively increase the thickness of the pole piece while ensuring the reaction of the pole piece. Adequacy and rate capability further ensure the energy density of the battery using the pole piece while ensuring its performance.
  • the first active material layer is provided with a mounting hole penetrating the first active material layer along a first direction, the first direction intersects with the plane of the base material, and the pole
  • the sheet also includes: an electric energy extraction part, which is inserted through the mounting hole. One end of the electric energy extraction part is welded to the base material, and the other end extends out of the outline of the pole piece.
  • the electric energy extraction part of the pole piece is extracted along the first direction that intersects with the surface of the base material.
  • the base material and active material it is more convenient for the base material and active material to be placed in the mold Extrusion molding effectively reduces the risk of bending, deformation or even breakage of the electrical energy extraction part during the extrusion molding of the pole piece.
  • the present application also provides an electrode assembly, including a positive electrode piece, a negative electrode piece and a separation film.
  • the positive electrode piece, the negative electrode piece and the separation film are stacked to form the electrode assembly, so The isolation film is disposed between the positive electrode piece and the negative electrode piece; wherein at least one of the positive electrode piece and the negative electrode piece is the electrode piece described in any one of the above.
  • the electrode assembly proposed in the fourth aspect of this application is also beneficial to ensuring the energy density of the battery while ensuring the performance of the battery.
  • the present application also provides a battery cell, including a case and the electrode assembly described in the above solution, and the electrode assembly is accommodated in the case.
  • the present application also provides a battery, including a box and the battery cell described in the above solution, and the battery cell is accommodated in the box.
  • the present application also provides an electrical device, including the battery cell described in the above solution, where the battery cell is used to provide electric energy.
  • Figure 1 is a schematic diagram of the overall flow of the pole piece preparation method provided by some embodiments of the present application.
  • Figure 2 is a schematic diagram of the state in which the cover and the mold co-extrude the active material and the base material provided by some embodiments of the present application;
  • Figure 3 is a schematic sub-flow diagram of the pole piece preparation method provided by some embodiments of the present application.
  • Figure 4 is a schematic diagram of the state in which the protrusion penetrates the base material provided in some embodiments of the present application;
  • Figure 5 is a schematic diagram of the state in which the cover and the mold co-extrude the first layer of active material, the base material and the second layer of active material provided by some embodiments of the present application;
  • Figure 6 is a schematic structural diagram of a pole piece preparation device provided by some embodiments of the present application.
  • Figure 7 is a schematic structural diagram of a pole piece preparation device provided by some embodiments of the present application.
  • Figure 8 is a schematic structural diagram of an electrical device provided by some embodiments of the present application.
  • Figure 9 is an exploded view of a battery provided by some embodiments of the present application.
  • Figure 10 is an exploded view of a battery cell provided by some embodiments of the present application.
  • Figure 11 is an exploded view of a battery cell provided by some embodiments of the present application.
  • Figure 12 is an isometric view of a pole piece provided by some embodiments of the present application.
  • Figure 13 is an isometric view of a pole piece provided by some embodiments of the present application.
  • Figure 14 is a side cross-sectional view of a pole piece provided by some embodiments of the present application.
  • Figure 15 is an isometric view of a pole piece provided by some embodiments of the present application.
  • Marking description 1000-vehicle; 100-battery; 10-battery cell; 1-casing; 11-case; 12-cover; 2-electrode assembly; 21-pole piece; 21a-positive electrode piece; 21b-negative electrode Pole piece; 211-substrate; 2111-through hole; 2112-pole tab area; 212-first active material layer; 2121-first surface; 2122-first accommodation cavity; 2123-mounting hole; 213-second Active material layer; 2131-second surface; 2132-second accommodation cavity; 214-electric energy extraction part; 214a-positive electrode electric energy extraction part; 214b-negative electrode electric energy extraction part; 22-isolation film; 20-box; 201- The first part; 202-the second part; 200-controller; 300-motor; 2000-pole piece preparation device; 2100-mold; 2110-body; 2120-mold cavity; 2130-protrusion; 2140-avoidance groove; 2200 - cover; 2210-avoidance hole; 2220-extension;
  • an embodiment means that a particular feature, structure or characteristic described in connection with the embodiment can be included in at least one embodiment of the present application.
  • the appearances of this phrase in various places in the specification are not necessarily all referring to the same embodiment, nor are separate or alternative embodiments mutually exclusive of other embodiments. Those skilled in the art understand, both explicitly and implicitly, that the embodiments described herein may be combined with other embodiments.
  • the term “plurality” refers to two or more (including two).
  • the battery mentioned in the embodiments of this application refers to a single physical module including one or more battery cells to provide higher voltage and capacity.
  • the battery mentioned in this application may include a battery module or a battery pack.
  • multiple battery cells can be connected in series, parallel or mixed connection to directly form a battery.
  • Mixed connection means that multiple battery cells are connected in series and in parallel.
  • Multiple battery cells can also be connected in series, parallel or mixed to form a battery cell group, and then multiple battery cell groups can be connected in series, parallel or mixed to form a battery.
  • the battery may include a case for enclosing one or more battery cells.
  • the box can prevent liquid or other foreign matter from affecting the charging or discharging of the battery cells.
  • the battery cells may include lithium ion secondary batteries, lithium ion primary batteries, lithium-sulfur batteries, sodium lithium ion batteries, sodium ion batteries or magnesium ion batteries, etc., which are not limited in the embodiments of this application.
  • the battery cell may be in the shape of a flat body, a cylinder, a cuboid, or other shapes, and the embodiments of the present application are not limited to this.
  • the battery cell includes an electrode assembly and an electrolyte.
  • the electrode assembly consists of a positive electrode plate, a negative electrode plate and a separator. Battery cells mainly rely on the movement of metal ions between the positive and negative electrodes to work.
  • the positive electrode sheet includes a positive electrode current collector (the current collector is the base material described below) and a positive electrode active material layer.
  • the positive electrode active material layer is coated on the surface of the positive electrode current collector.
  • the positive electrode current collector that is not coated with the positive electrode active material layer can be convex.
  • the cathode current collector coated with the cathode active material layer serves as the cathode tab.
  • the material of the positive electrode current collector can be aluminum, and the positive electrode active material can be lithium cobalt oxide, lithium iron phosphate, ternary lithium or lithium manganate, etc.
  • the negative electrode sheet includes a negative electrode current collector and a negative electrode active material layer.
  • the negative electrode active material layer is coated on the surface of the negative electrode current collector.
  • the negative electrode current collector that is not coated with the negative electrode active material layer can protrude from the negative electrode that is coated with the negative electrode active material layer.
  • the current collector serves as the negative electrode tab.
  • the material of the negative electrode current collector can be copper, and the negative electrode active material can be carbon or silicon.
  • the number of positive electrode tabs can be multiple and stacked together, and the number of negative electrode tabs can be multiple and stacked together.
  • the material of the isolation film can be PP (polypropylene, polypropylene) or PE (polyethylene, polyethylene), etc.
  • the electrode assembly may have a rolled structure or a laminated structure, and the embodiments of the present application are not limited thereto.
  • pole pieces adopts a wet coating process, which mainly involves making binders, active substances, conductive agents and other materials into a slurry, and then wet-coating the slurry on the surface of the current collector, and then the current collector enters a high-temperature oven. Evaporate the solvent to dryness to obtain the required pole piece.
  • the method mainly includes: adding active materials and base materials into the mold cavity of the mold; The active material and the base material are covered with a piece; force is applied to the covering piece and/or the mold, and the active material and the base material are co-extruded through the covering piece and the mold, so that the active material and the base material are compounded to form a pole piece.
  • the pole pieces formed by extrusion compounding can effectively improve the compaction and density of the active material on the substrate, and can effectively increase its energy density.
  • the compaction of the pole pieces can be adjusted by designing different molds. Molds with cavity volumes or by controlling different feeding amounts can obtain pole pieces with different compaction densities; on the other hand, extrusion molding can effectively increase the compaction of the pole pieces, which can effectively reduce the risk of pole piece cracking, thus making it easier to increase
  • the thickness of the active material layer can be used to prepare pole pieces with higher thickness requirements to meet the preparation requirements of thick pole pieces. By increasing the thickness of the pole pieces, the active material passenger capacity can be effectively increased, thereby effectively increasing its energy density.
  • the cavity of the mold plays a role in limiting and shaping the active material.
  • pole pieces of the target shape and size can be directly prepared.
  • the technical solution of this application can effectively simplify the processes such as coating, substrate rewinding and unwinding, pole piece cutting, etc., and reduce the transfer time between each process, reduce the coating and drying hours, thereby effectively improving the pole piece production efficiency.
  • the batteries disclosed in the embodiments of this application can be used in, but are not limited to, electrical equipment such as vehicles, ships, or aircrafts, and the batteries disclosed in this application can be used to form the power supply system of the electrical equipment.
  • Battery cells suitable for the pole pieces prepared by the pole piece preparation method of the present application may include lithium ion secondary batteries, lithium ion primary batteries, lithium sulfur batteries, sodium lithium ion batteries, sodium ion batteries or magnesium ion batteries, etc., the application implements This example is not limiting.
  • the pole piece preparation device in this application can, but is not limited to, prepare pole pieces suitable for batteries such as lithium ion secondary batteries, lithium ion primary batteries, lithium sulfur batteries, sodium lithium ion batteries, sodium ion batteries or magnesium ion batteries.
  • batteries such as lithium ion secondary batteries, lithium ion primary batteries, lithium sulfur batteries, sodium lithium ion batteries, sodium ion batteries or magnesium ion batteries.
  • This application implements This example is not limiting.
  • Figure 1 is a schematic diagram of the overall flow of the pole piece preparation method provided by some embodiments of the present application.
  • Figure 2 is a schematic diagram of the active material and base material co-extruded between the cover and the die provided by some embodiments of the present application. Status diagram.
  • Some embodiments of the present application provide a pole piece preparation method, including:
  • the active material 3000 can be added to the mold cavity 2120 first, and then the base material 211 can be covered on the active material 3000.
  • the base material 211 can be added to the mold cavity 2120 first, and then the base material 211 can be covered with the active material 3000.
  • the substrate 211 can even be placed between two layers of active material 3000 .
  • the active material 3000 can be a dry powder mixture containing electrode active materials, conductive agents, binders and other materials, or it can be a slurry with a high solid content, or a group-shaped active material with certain viscosity and plasticity. wait.
  • the base material 211 can be a positive electrode base material or a negative electrode base material.
  • the active material 3000 can be a positive electrode active material or a negative electrode active material.
  • the shape of the base material 211 can be adapted to the shape and size of the mold cavity 2120.
  • the peripheral dimension of the base material 211 may also be smaller than the inner peripheral dimension of the mold cavity 2120 (that is, there is a gap between the outer periphery of the base material 211 and the inner peripheral surface of the mold cavity 2120).
  • S2 Cover the covering member 2200 on the active material 3000 or the base material 211.
  • the cover 2200 can cover the active material 3000 or the base material 211.
  • the cover 2200 covers the active material 3000, and
  • the cover 2200 covers the base material 211.
  • the active material 3000 and the base material 211 are sequentially added into the mold cavity 2120 , and the cover 2200 covers the base material 211 .
  • S3 Apply force to the cover 2200 and/or the mold 2100, and jointly extrude the active material 3000 and the base material 211 through the cover 2200 and the mold 2100, so that the active material 3000 and the base material 211 are composited to form the pole piece 21.
  • the active material 3000 is extruded and compounded with the base material 211, and the extruded active material 3000 forms the active material layer of the pole piece 21; force can only be applied to the cover 2200 (the mold 2100 remains stationary), or You can only apply force to the mold 2100 (the cover 2200 remains stationary after covering the active material 3000 or the base material 211), or you can apply force to the mold 2100 and the cover 2200 at the same time, so that the mold 2100 and the cover 2200 move toward each other. Pressing, for example, the mold 2100 remains stationary, applying force to the cover 2200.
  • force can be applied to the cover 2200 and/or the mold 2100 manually, or force can be applied to the cover 2200 and/or the mold 2100 through driving components such as a hydraulic system, a pneumatic system, and a servo cylinder.
  • driving components such as a hydraulic system, a pneumatic system, and a servo cylinder.
  • the embodiment of the present application does not apply force to the cover 2200 and/or the mold 2100. It is uniquely qualified.
  • the active material 3000 and the base material 211 are added to the mold cavity 2120 of the mold 2100, and then the cover 2200 and the mold 2100 are matched to jointly extrude the active material 3000 and the base material 211, so that The active material 3000 and the base material 211 are directly compounded to form the pole piece 21.
  • the pole piece 21 formed by extrusion compounding can effectively improve the compaction and density of the active material 3000 on the base material 211, and can effectively increase its energy. Density, and the compaction of the pole piece 21 is adjustable.
  • the pole pieces 21 with different compaction densities can be obtained by designing molds 2100 with different mold cavity 2120 volumes or by controlling different feeding amounts; on the other hand, extrusion through the mold 2100
  • the method of compositely forming the pole piece 21 facilitates an increase in the thickness of the active material layer, thereby enabling the preparation of a pole piece 21 with a higher thickness requirement to meet the preparation requirements for a thick pole piece 21, and making it easy to effectively increase the activity by increasing the thickness of the pole piece 21 material passenger capacity, thereby effectively increasing its energy density.
  • the pole piece 21 of the target shape and size can be directly prepared.
  • the technical solution of the present application can effectively improve the production efficiency of the pole piece 21.
  • the method further includes: drying the pole piece 21 located in the mold cavity 2120; and taking out the dried pole piece 21 from the mold 2100.
  • the mold 2100 carrying the pole pieces 21 can be sent into a drying equipment such as an oven or oven, so that the pole pieces 21 can be dried.
  • Special drying equipment can also be set up, so that the drying equipment is close to the mold 2100 or extends into the mold cavity 2120 to bake the pole pieces 21 in the mold cavity 2120, and so on.
  • the mold 2100 carrying the pole piece 21 can be sent into the oven.
  • the mold 2100 enters the oven through the inlet of the oven on the conveyor line, and is discharged through the outlet of the oven, so that the mold 2100
  • the pole piece 21 is dried during the process of passing through the oven.
  • the pole piece 21 in the fixture can be taken out manually or with production equipment. Similarly, there are many ways to take out the pole piece 21. You can use a vacuum nozzle to suck the pole piece 21 out of the mold cavity 2120, or you can invert the jig to discharge the pole piece 21.
  • the pole piece 21 extruded and compounded in the mold cavity 2120 is directly dried, and then the dried pole piece 21 is separated from the mold cavity 2120.
  • it can effectively avoid the damage caused by directly demolding the extruded pole piece 21.
  • Problems such as the deformation of the pole piece 21 and the displacement of the active material 3000 can effectively ensure the structural stability of the pole piece 21 and the preparation yield of the pole piece 21; on the other hand, the composite of the pole piece 21 and the drying of the pole piece 21 are integrated It is carried out at the same work station, thereby further reducing the transportation and transfer time in the production of the pole piece 21, and further improving the production efficiency of the pole piece 21.
  • drying the pole piece 21 located in the mold cavity 2120 includes: increasing the temperature of the mold 2100 and/or the cover 2200 to dry the pole piece 21 .
  • the temperature of the mold 2100 or the cover 2200 can be increased individually, or the temperatures of the mold 2100 and the cover 2200 can be increased simultaneously.
  • the temperature of the mold 2100 or the cover 2200 on the side close to the active material 3000 can be increased. That is, if the active material 3000 is located between the mold 2100 and the substrate 211, the temperature of the mold 2100 can be increased to affect the active material 3000. For heating, if the active material 3000 is located between the substrate 211 and the cover 2200, the temperature of the cover 2200 can be increased to heat the active material 3000.
  • the wall of the mold 2100 and the cover 2200 can be a hollow structure containing a heating medium. By raising the temperature of the heating medium, the mold 2100 and the cover 2200 can be raised. Part 2200 temperature.
  • the pole piece 21 is dried by increasing the temperature of the mold 2100 and/or the cover 2200.
  • the extruded pole piece 21 is located between the mold 2100 and the cover 2200, directly raising the temperature of the mold 2100 and/or the cover 2200.
  • Heating the pole piece 21 at a temperature can effectively reduce the heating distance of the pole piece 21 and improve the heating uniformity of the pole piece 21, thereby improving the drying efficiency of the pole piece 21; on the other hand, the mold 2100 and the cover 2200 are in the pole piece 21 During the heating and drying process, the pole piece 21 plays a positioning and shaping role, which can effectively reduce the risk of warping and deformation of the pole piece 21 during the heating process, thereby effectively ensuring the drying quality of the pole piece 21; furthermore, compared with the traditional The method of drying the pole piece 21 through ovens, ovens and other equipment, and the method of heating the pole piece 21 by raising the temperature of the mold 2100 and/or the cover 2200 can provide the pole piece 21 with a small heating range but more precise heating.
  • the heat source is not only conducive to improving the heating and drying efficiency of the pole piece 21, but also can effectively reduce the drying heat energy demand, save the investment cost of drying equipment, and is conducive to significantly reducing the production cost of the pole piece 21, and has high economic benefits.
  • the mold 2100 is a metal piece
  • increasing the temperature of the mold 2100 and/or the cover 2200 includes: energizing the mold 2100 to increase the temperature of the mold 2100 .
  • the mold 2100 is a metal conductor, and the mold 2100 generates electric heat (when electric current passes through the conductor, the conductor will generate heat, and this heat generated by the electric current is called electric heat) to heat and dry the pole piece 21 in the mold cavity 2120. .
  • the inner wall of the mold cavity 2120 can be provided with an insulating layer with good thermal conductivity, which can effectively prevent the impact of electricity on the mold 2100 on the active material 3000 and the base material 211.
  • the cover 2200 can also be a metal conductor. By energizing the cover 2200 to increase the temperature of the cover 2200, the pole piece 21 is heated through the cover 2200.
  • At least the surface of the cover 2200 that is in contact with the mold 2100 and the pole piece 21 can be provided with an insulating layer with good thermal conductivity, which can effectively prevent the mold 2100 from being energized and affecting the active material 3000 and the base material 211 .
  • the temperature of the mold 2100 can be increased.
  • the temperature rise speed is fast and the temperature rise balance is strong, which is conducive to further improving the drying efficiency and drying quality of the pole piece 21, and is conducive to further reducing the temperature of the pole piece 21. Cost of production.
  • adding the active material 3000 and the base material 211 into the mold cavity 2120 of the mold 2100 including sequentially adding the active material 3000 and the base material 211 into the mold cavity 2120; covering the Covering the active material 3000 and the base material 211 with the member 2200 includes: covering the covering member 2200 on the base material 211 .
  • the pole piece 21 when preparing the pole piece 21, first lay a layer of active material 3000 in the mold cavity 2120, then cover the base material 211 on the active material 3000 in the mold cavity 2120, and then cover the base material 211 with the covering member 2200. The side facing away from the active material 3000 in the thickness direction.
  • the active material 3000 and the base material 211 are sequentially added into the mold cavity 2120.
  • the base material 211 is covered on the active material 3000, and then the cover 2200 is covered on the base material 211.
  • the cover 2200 and the mold 2100 jointly extrusion the active material 3000. and the base material 211, so that the active material 3000 is extruded and compounded on the side of the base material 211 away from the cover 2200 to form a single-sided coated pole piece 21.
  • Figure 3 is a schematic sub-flow diagram of a pole piece preparation method provided by some embodiments of the present application
  • Figure 4 is a protrusion penetrating base provided by some embodiments of the present application
  • Figure 5 is a schematic diagram of the state of the cover and the die co-extruded by some embodiments of the present application to extrudate the first layer of active material, the base material and the second layer of active material.
  • Adding the active material 3000 and the base material 211 to the mold cavity 2120 of the mold 2100 includes: sequentially adding the first layer of active material 3100, the base material 211 and the second layer of active material 3200 into the mold cavity 2120; covering the cover 2200 On the active material 3000 and the base material 211, the method includes: covering the second layer of active material 3200 with the cover 2200.
  • the first layer of active material 3100, the base material 211 and the second layer of active material 3200 are sequentially added into the mold cavity 2120.
  • the base material 211 is located between the two layers of active material 3000, and then the cover 2200 is covered on the second layer of active material 3200.
  • the cover 2200 and the mold 2100 co-extrude the two layers of active material 3000 and the base material 211, so that the two layers of active material 3000 are extruded and compounded on both sides of the base material 211 to form a double-sided coated pole piece 21.
  • the mold 2100 includes a body 2110 and a protruding portion 2130.
  • the body 2110 has a mold cavity 2120.
  • the protruding portion 2130 protrudes from the bottom wall of the mold cavity 2120.
  • the bottom wall is connected to the mold cavity 2120.
  • the openings of the cavity 2120 are opposite; the first layer of active material 3100, the base material 211 and the second layer of active material 3200 are sequentially added into the mold cavity 2120, including:
  • the protruding part 2130 may be a cylindrical structure, a vertebral structure, or other conventional or special-shaped three-dimensional structure.
  • One protruding part 2130 may be provided, or multiple protruding parts 2130 may be provided.
  • a plurality of protruding parts 2130 are provided, and the plurality of protruding parts 2130 are distributed at scattered points on the bottom wall of the mold cavity 2120.
  • the distances between the plurality of protruding parts 2130 may be equal. Of course, the distances between the plurality of protruding parts 2130 may also be unequal.
  • the height of the protruding portion 2130 protruding from the bottom wall can be less than the depth of the mold cavity 2120 (the distance between the bottom wall and the opening), or can be equal to the depth of the mold cavity 2120 (that is, the distance between the end surface of the protruding portion 2130 and the distance between the mold cavity 2120 The opening surface is flush).
  • the height of the protruding portion 2130 protruding from the bottom wall can also be greater than the depth of the mold cavity 2120 (that is, the end surface of the protruding portion 2130 protrudes from the opening surface of the mold cavity 2120).
  • the end surface of the protruding portion 2130 is flush with the opening surface of the mold cavity 2120 .
  • cover 2200 can be provided with an escape hole 2210 to avoid the protruding portion 2130 to prevent the protruding portion 2130 from interfering with the extrusion of the mold 2100 and the cover 2200.
  • the protruding portion 2130 is provided in the mold cavity 2120, after the base material 211 is added to the mold cavity 2120, the end of the protruding portion 2130 presses against the base material 211, and the cover 2200 covers the base material 211 and moves toward the base material 211.
  • the cover 2200 and/or the mold 2100 exert force to cause the protruding portion 2130 to exert force on the base material 211 and penetrate the base material 211 .
  • the protruding portion 2130 penetrating the base material 211 enters the filling space of the second layer of active material 3200 .
  • the mold 2100 can be exerted to make the protruding portion 2130 directly exert force on the base material 211, or the cover 2200 can be exerted to make the protruding portion 2130 exert a reverse force on the base material 211.
  • it can also be Force is applied to both the mold 2100 and the base material 211, so that the protruding portion 2130 applies an acting force and a reverse force to the base material 211 at the same time.
  • the second layer of active material 3200 is added into the mold cavity 2120.
  • the mold includes a protrusion 2130 disposed on the bottom wall of the mold cavity 2120.
  • the protrusion 2130 can be formed on the active material 3000 to accommodate the electrolyte.
  • accommodating cavity to promote the storage and infiltration of electrolyte inside the pole piece 21, improve the problem of large ionic resistance of the pole piece 21, and increase the 100 cycle life of the battery; when the pole piece 21 is a double-sided coated pole piece 21,
  • the protruding portion 2130 can penetrate the base material 211 to ensure that the protruding portion 2130 can form accommodating cavities on the active materials 3000 on both sides of the base material 211 .
  • the base material 211 and the second layer of active material 3200 are sequentially added to the mold cavity 2120, first the first layer of active material 3100 and the base material 211 are sequentially added to the mold cavity 2120, through the cover 2200
  • the base material 211 and the first layer of active material 3100 are extruded together with the mold 2100, so that the base material 211 penetrates the protruding portion 2130 and moves closer to the first layer of active material 3100, freeing up space for the second layer of active material 3200 to be filled. space.
  • the cover 2200 is again covered on the second layer of active material 3200 and extruded together with the mold 2100, so that the first layer of active material 3100, the base material 211 and the second layer
  • the active material 3200 is compositely molded into one body.
  • the protruding portion 2130 forms accommodating cavities in both the first layer of active material 3100 and the second layer of active material 3200 .
  • Figure 6 is a schematic structural diagram of a pole piece preparation device provided by some embodiments of the present application.
  • the present application provides a pole piece preparation device 2000.
  • the pole piece preparation device 2000 includes: a mold 2100 and a cover 2200.
  • the mold 2100 is provided with a mold cavity 2120, which is used to accommodate the active material 3000 and the base material 211.
  • the cover 2200 is configured to at least partially extend into the mold cavity 2120 through the opening of the mold cavity 2120, so as to co-extrude the active material 3000 and the base material 211 with the mold 2100, so that the active material 3000 and the base material 211 are composited to form the pole piece 21.
  • the mold cavity 2120 of the mold 2100 (a mold and tool used for molding articles) is used to accommodate the active material 3000 and the base material 211, so as to have a limiting and boundary limiting effect on the active material 3000 and the base material 211.
  • the cross-sectional shape of the mold cavity 2120 can correspond to the shape of the pole piece 21.
  • the cross-sectional shape of the mold cavity 2120 can be circular to extrudate the circular pole piece 21.
  • the cross-sectional shape of the mold cavity 2120 can be It is rectangular, and the rectangular pole piece 21 is extruded.
  • the cross-sectional shape of the mold cavity 2120 can also be other conventional shapes to prepare pole pieces 21 of different shapes.
  • the overall shape of the mold 2100 may or may not correspond to the shape of the mold cavity 2120 .
  • At least the part of the cover 2200 that extends into the mold cavity 2120 can match the mold cavity 2120, or the outer circumferential size of the cover 2200 is slightly smaller than the opening size of the mold cavity 2120.
  • the cross section of the mold cavity 2120 is rectangular, and the cover 2200 has a rectangular cross-section.
  • the cross-section of 2200 is also rectangular, and the cover 2200 is adapted to the mold cavity 2120.
  • the cover 2200 may be a plate-like structure or a block-like structure.
  • FIG. 7 is a schematic structural diagram of a pole piece preparation device provided in some embodiments of the present application.
  • An extension 2220 may be provided on one edge of the cover 2200 , and an extension 2220 may be provided on the side wall of the mold 2100 .
  • the edge on one side of the base material 211 can be provided with a blank area that can extend out of the mold cavity 2120. This blank area can eventually become the tab of the pole piece 21.
  • the base material 211 When the base material 211 is placed into the mold cavity 2120, it can be The blank area is inserted into the escape groove 2140. After the mold 2100 and the cover 2200 are pressed toward each other, the blank area extending from the edge of the base material 211 is clamped between the extension part 2220 and the bottom wall of the escape groove 2140, so as to Effectively avoid folding and wrinkles in the blank area.
  • the pole piece 21 preparation device includes a mold 2100 and a cover 2200.
  • the mold 2100 is provided with a mold cavity 2120 for accommodating the active material 3000 and the base material 211.
  • the active material 3000 and the base material 211 are added to the mold cavity 2120, and the The cover 2200 covers the active material 3000 or the substrate 211 in the mold cavity 2120, and exerts force on the mold 2100 and/or the cover 2200, so that at least part of the cover 2200 extends into the mold cavity 2120, and the cover 2200 and the mold 2100 co-extrudes the active material 3000 and the base material 211, so that the active material 3000 and the base material 211 are composited to form the pole piece 21.
  • the co-extruded structure of the mold 2100 and the cover 2200 can effectively improve the compaction and density of the active material 3000 on the base material 211, and can effectively increase the energy density of the pole piece 21.
  • the mold 2100 and the cover The co-extruded structure of the parts 2200 is convenient for thickening the thickness of the active material layer, so that the pole piece 21 with a higher thickness requirement can be stably prepared to meet the preparation requirements of the thick pole piece 21, and it is easy to effectively increase the activity by increasing the thickness of the pole piece 21 material passenger capacity, thereby effectively increasing its energy density.
  • the pole piece 21 of the target shape and size can be directly prepared, which is beneficial to improving the production efficiency of the pole piece 21.
  • the mold 2100 includes a body 2110 and a protruding portion 2130.
  • the body 2110 has a mold cavity 2120.
  • the protruding portion 2130 protrudes from the bottom wall of the mold cavity 2120.
  • the wall is opposite to the opening of the mold cavity 2120, and the protruding portion 2130 is used to form a receiving cavity on the active material 3000 to accommodate the electrolyte.
  • the protruding portion 2130 can be a cylindrical structure, a vertebral structure, or other conventional or special-shaped three-dimensional structures.
  • One or more protruding portions 2130 can be provided. Examples
  • multiple protrusions 2130 are provided, and the plurality of protrusions 2130 are spacedly distributed on the bottom wall of the mold cavity 2120. The distance between the plurality of protrusions 2130 may be equal or unequal.
  • the height of the protruding portion 2130 protruding from the bottom wall may be less than, greater than, or equal to the depth of the mold cavity 2120 (the distance between the bottom wall and the opening).
  • the end surface of the protruding portion 2130 and the opening surface of the mold cavity 2120 Flush.
  • the mold 2100 includes a protruding portion 2130 disposed on the bottom wall of the mold cavity 2120.
  • the protruding portion 2130 can move the active material
  • a certain space is reserved on the active material 3000. This space forms a receiving cavity for accommodating the electrolyte.
  • a receiving cavity for containing the electrolyte can be provided, which can increase the thickness and compactness of the active material layer 3000 of the pole piece 21 and at the same time promote the electrolyte.
  • the storage and infiltration inside the pole piece 21 improves the problem of large ionic resistance of the pole piece 21 and effectively increases the cycle life of the battery 100, thereby ensuring the energy density of the battery 100 while effectively ensuring the charge and discharge rate of the battery 100.
  • multiple protrusions 2130 are provided, and the plurality of protrusions 2130 are spaced apart.
  • the plurality of protrusions 2130 can be distributed on the bottom wall of the mold cavity 2120 in a scattered point manner, and the distance between the plurality of protrusions 2130 can be equal or unequal. For example, The distances between the plurality of protrusions 2130 are equal.
  • a plurality of spaced-apart protrusions 2130 are provided in the mold cavity 2120 to form a plurality of spaced-apart accommodation cavities for accommodating electrolyte on the pole piece 21 , thereby further improving the storage of electrolyte on the pole piece 21 , infiltration amount, and effectively improve the uniformity of electrolyte distribution and penetration.
  • the cover 2200 is provided with an escape hole 2210 for the protrusion 2130 to pass through.
  • the cover 2200 can be provided with multiple escape holes 2210 , and the multiple escape holes 2210 are connected to the multiple protrusions 2130 one by one. correspond.
  • the cover 2200 is provided with an escape hole 2210 for the protruding portion 2130 to pass through.
  • the arrangement of the escape hole 2210 can provide more extension space for the protruding portion 2130, thereby ensuring that the accommodation cavity is arranged along the thickness direction of the pole piece 21. depth, effectively increasing the volume of the accommodation cavity, and enabling the protruding portion 2130 to penetrate the pole piece 21 along the thickness direction of the pole piece 21.
  • active elements can be provided on both sides of the substrate 211 in the thickness direction.
  • the protruding portion 2130 penetrates the pole piece 21 along the thickness direction of the pole piece 21, which is beneficial to forming accommodation cavities for the active material 3000 on both sides of the base material 211; on the other hand, the setting of the avoidance hole 2210 can effectively avoid covering
  • the problem of positional interference between the member 2200 and the protruding portion 2130 affects the extrusion strength of the mold 2100 and the covering member 2200, thereby effectively ensuring the compactness of the extrusion molding of the pole piece 21, and ensuring the energy density of the pole piece 21 while ensuring the pole piece 21. Structural stability of sheet 21.
  • the pole piece preparation device 2000 also includes a drying mechanism, which is used to dry the pole piece 21 .
  • the drying mechanism can use drying equipment used in industrial production (such as ovens, ovens, etc.), and can take out the extruded pole piece 21 from the mold 2100 Then it is sent to the drying equipment, or the mold 2100 carrying the pole piece 21 can be directly sent to the drying equipment, so that the pole piece 21 is dried.
  • drying equipment used in industrial production such as ovens, ovens, etc.
  • the pole piece preparation device is provided with a drying mechanism to dry and shape the extruded pole piece 21 .
  • the drying mechanism includes a power supply mechanism.
  • the mold 2100 is a metal part.
  • the power supply mechanism is used to energize the mold 2100 to heat the mold 2100 to dry the pole piece 21; and/or the cover 2200 is metal.
  • the power supply mechanism is used to energize the cover 2200 to heat the cover 2200 to dry the pole piece 21 .
  • the power supply mechanism generally refers to a mechanism that can energize the mold 2100 and/or the cover 2200. It can use a conventional mains power supply structure or a conventional battery power supply structure, as long as it can energize the metal to make it heat.
  • the power supply mechanism can energize the mold 2100 to generate electric heat (when current passes through a conductor, the conductor will generate heat, and this heat generated by the current is called electric heat) to heat and dry the pole piece 21 in the mold cavity 2120.
  • the power supply mechanism can also energize the cover 2200 alone, or energize the mold 2100 and the cover 2200 at the same time to heat and dry the pole piece 21 in the mold cavity 2120.
  • the inner wall of the mold cavity 2120 can be provided with an insulating layer with good thermal conductivity, which can effectively prevent the impact of electricity on the mold 2100 on the active material 3000 and the base material 211.
  • the cover 2200 when the cover 2200 is powered on, at least the surface of the cover 2200 that is in contact with the mold 2100 and the pole piece 21 can also be provided with an insulating layer with good thermal conductivity to effectively prevent the impact of the cover 2200 on the active material 3000 and the base material 211 .
  • a power supply mechanism is used to supply power to the mold 2100 and/or the cover 2200.
  • the mold 2100 and/or the cover 2200 generate electric heat, which has a fast heating speed and strong temperature rise balance, which is conducive to further improving the drying efficiency of the pole piece 21 and the drying efficiency of the pole piece 21. dry quality, and is conducive to further reducing the production cost of the pole piece 21; at the same time, the pole piece 21 is heated and dried between the mold 2100 and the cover 2200, and the mold 2100 and the cover 2200 play a clamping and positioning role for the pole piece 21, effectively The risk of drying deformation of the pole piece 21 is reduced, thereby ensuring the drying quality of the pole piece 21.
  • the pole piece preparation device 2000 further includes a pressurizing mechanism connected to the cover 2200.
  • the pressurizing mechanism is used to apply pressure to the cover 2200 so that the cover 2200 and the mold 2100 are co-extruded.
  • the active material 3000 and the substrate 211 in the mold cavity 2120 are pressed.
  • the pressurizing mechanism refers to a structure that can provide pressure drive for the cover 2200.
  • the pressurizing mechanism can be a hydraulic press, and the hydraulic press drives the cover 2200 to move.
  • the pressurizing mechanism can also be a pressure providing mechanism such as a pneumatic press or a servo electric cylinder.
  • the position of the mold 2100 is fixed, and the cover 2200 is installed at the output end of the pressurizing mechanism.
  • the pressurizing mechanism can drive the cover 2200 to move toward the mold 2100, so that the cover 2200 and the mold 2100 jointly squeeze the material in the mold cavity 2120.
  • the base material 211 and the active material 3000, and the pressing mechanism can also drive the cover 2200 to move away from the mold 2100, so that the cover 2200 is separated from the mold 2100.
  • a pressurizing mechanism is provided to apply pressure to the cover 2200, so that the cover 2200 and the mold 2100 can jointly squeeze the active material 3000 and the base material 211 in the mold cavity 2120, so that the active material 3000 and the base material 211 can be compositely formed into the pole piece 21 .
  • the electrical device can be, but is not limited to, a mobile phone, a tablet, a laptop, an electric toy, an electric tool, a battery car, an electric vehicle, a ship, a spacecraft, etc.
  • electric toys can include fixed or mobile electric toys, such as game consoles, electric car toys, electric ship toys, electric airplane toys, etc.
  • spacecraft can include airplanes, rockets, space shuttles, spaceships, etc.
  • the battery described in the embodiments of the present application is not limited to the above-described electrical devices, but can also be applied to all electrical devices using batteries. However, for the sake of simplicity of description, the following embodiment uses an example of an embodiment of the present application.
  • An electrical device is a vehicle as an example for illustration.
  • FIG. 8 is a schematic structural diagram of a vehicle 1000 provided by some embodiments of the present application.
  • the vehicle 1000 may be a fuel vehicle, a gas vehicle or a new energy vehicle, and the new energy vehicle may be a pure electric vehicle, a hybrid vehicle or an extended-range vehicle, etc.
  • the battery 100 is disposed inside the vehicle 1000 , and the battery 100 may be disposed at the bottom, head, or tail of the vehicle 1000 .
  • the battery 100 may be used to power the vehicle 1000 , for example, the battery 100 may serve as an operating power source for the vehicle 1000 .
  • the vehicle 1000 may also include a controller 200 and a motor 300 .
  • the controller 200 is used to control the battery 100 to provide power to the motor 300 , for example, for starting, navigating and driving the vehicle 1000 .
  • the battery 100 can not only be used as an operating power source for the vehicle 1000 , but also can be used as a driving power source for the vehicle 1000 , replacing or partially replacing fuel or natural gas to provide driving power for the vehicle 1000 .
  • the battery 100 may include a box 20 and a battery cell 10 , and the battery cell 10 is accommodated in the box 20 .
  • the box 20 is used to provide an accommodation space for the battery cells 10 , and the box 20 can adopt a variety of structures.
  • the box 20 may include a first part 201 and a second part 202 , the first part 201 and the second part 202 cover each other, and the first part 201 and the second part 202 jointly define a space for accommodating the battery cell 10 of accommodation space.
  • the second part 202 may be a hollow structure with one end open, and the first part 201 may be a plate-like structure.
  • the first part 201 covers the open side of the second part 202 so that the first part 201 and the second part 202 jointly define a receiving space.
  • the first part 201 and the second part 202 may also be hollow structures with one side open, and the open side of the first part 201 is covered with the open side of the second part 202.
  • the box 20 formed by the first part 201 and the second part 202 can be in various shapes, such as rectangular parallelepiped, cube, etc.
  • the battery 100 there may be a plurality of battery cells 10 , and the plurality of battery cells 10 may be connected in series, in parallel, or in mixed connection.
  • Mixed connection means that the plurality of battery cells 10 are connected in series and in parallel.
  • Multiple battery cells 10 can be directly connected in series or in parallel or mixed together.
  • FIG. 10 is an exploded view of a battery cell 10 provided in some embodiments of the present application.
  • the battery cell 10 provided in some embodiments of the present application may include a casing 1, an electrode assembly 2 and an electrolyte.
  • the casing 1 is made of Parts used to accommodate the electrode assembly 2, electrolyte and other components.
  • the housing 1 can be in various shapes, such as rectangular parallelepiped.
  • FIG. 11 is an exploded view of the battery cell 10 provided in some embodiments of the present application.
  • the casing 1 is in the form of a cylinder.
  • the shape of the shell is not limited to the above-mentioned rectangular parallelepiped and cylinder, and can also be other shapes.
  • the housing 1 may include a housing 11 and a cover 12.
  • the cover 12 covers the opening of the housing 11.
  • the cover 12 and the housing 11 jointly define a sealed space for accommodating the electrode assembly 2, electrolyte and other components.
  • the electrode assembly 2 is a component in the battery cell 10 where electrochemical reactions occur.
  • the electrode assembly 2 may include a positive electrode piece 21a, a negative electrode piece 21b, and a separation film 22.
  • the electrode assembly 2 may be a rolled structure formed by winding the positive electrode piece 21a, the isolation film 22 and the negative electrode piece 21b, or may be a laminate structure.
  • the electrode assembly 2 is a laminate structure.
  • FIG 12 is an isometric view of a pole piece provided by some embodiments of the present application.
  • Some embodiments of the present application also provide a pole piece 21.
  • the pole piece 21 includes a base material 211 and a first active material layer 212.
  • the first active material layer 212 is disposed on one side of the base material 211 in the thickness direction.
  • the active material layer 212 includes a first surface 2121 facing away from the substrate 211; wherein the first surface 2121 is provided with a first accommodation cavity 2122 for accommodating electrolyte.
  • the pole piece 21 can be made by using the aforementioned pole piece preparation method and pole piece preparation device.
  • the base material 211 can be a positive electrode base material or a negative electrode base material.
  • the first active material layer 212 can be extruded and compounded by the active material 3000. formed on the base material 211.
  • the first active material layer 212 can also be compounded with the base material 211 by spraying, rolling, or other methods.
  • the first surface 2121 faces away from the base material 211 , and the first accommodation cavity 2122 may penetrate the first active material layer 212 along the thickness direction of the pole piece 21 , or may not penetrate the first active material layer 212 .
  • One first accommodating cavity 2122 may be provided, or multiple first accommodating cavities 2122 may be provided at intervals. For example, a plurality of first accommodating cavities 2122 may be provided at intervals.
  • the first receiving cavity 2122 can be directly formed through the protruding portion 2130 in the mold 2100 when the pole piece 21 is extruded. That is, the mold 2100 includes a body 2110 and a protruding portion 2130. The body 2110 has a mold cavity 2120 and a protruding portion 2130. Protruding from the bottom wall of the mold cavity 2120 , the mold 2100 and the cover 2200 jointly squeeze the active material 3000 and the base material 211 , and the protruding portion 2130 forms a first accommodation cavity 2122 on the active material 3000 .
  • the first accommodating cavity 2122 can also be processed on the finished pole piece 21 .
  • a blank area that can protrude out of the mold cavity 2120 may be provided on the edge of one side of the base material 211 , and this blank area eventually becomes the tab area 2112 of the pole piece 21 .
  • the pole piece 21 includes a base material 211 and a first active material layer 212.
  • the first active material layer 212 is provided with a first accommodation cavity 2122, and the first accommodation cavity 2122 is used to accommodate electrolyte.
  • the design of the first accommodation cavity 2122 can increase the electrode size.
  • the thickness and tightness of the active material layer 3000 of the sheet 21 simultaneously promotes the storage and infiltration of the electrolyte inside the pole piece 21, improves the problem of large ionic impedance of the pole piece 21, and effectively increases the cycle life of the battery 100.
  • the setting of the first accommodation cavity 2122 can assist the electrolyte to penetrate into the interior of the first active material layer 212, effectively increasing the penetration thickness of the electrolyte, thereby ensuring the full utilization of the pole piece 21 and reducing the risk of the thick pole piece 21. There is a risk of insufficient reaction. Therefore, the pole piece 21 of the technical solution of the present application can effectively ensure the energy density of the battery 100 and the performance of the battery 100 at the same time.
  • Figure 13 is an isometric view of a pole piece provided in some further embodiments of the present application
  • Figure 14 is a side view of a pole piece provided in some further embodiments of the present application. View section view.
  • the pole piece 21 also includes a second active material layer 213.
  • the second active material layer 213 is disposed on the other side in the thickness direction of the base material 211.
  • the second active material layer 213 includes a second surface 2131 facing away from the base material 211.
  • the surface 2131 is provided with a second containing cavity 2132 for containing electrolyte.
  • the second active material layer 213 and the first active material layer 212 are made of the same material.
  • the second active material layer 213 can be formed by extrusion compounding of the active material 3000 on the base material 211 .
  • the second active material layer 213 can also be compounded with the base material 211 by spraying, rolling, or other methods.
  • the second surface 2131 faces away from the base material 211 , and the second accommodation cavity 2132 may penetrate the second active material layer 213 along the thickness direction of the pole piece 21 , or may not penetrate the second active material layer 213 .
  • One second accommodating cavity 2132 may be provided, or multiple second accommodating cavities 2132 may be provided at intervals. For example, a plurality of second accommodating cavities 2132 may be provided at intervals.
  • the second accommodating cavity 2132 can be directly formed through the protruding portion 2130 in the mold 2100 when the pole piece 21 is extruded.
  • the second accommodating cavity 2132 can also be formed on the finished pole piece 21 Processed.
  • the pole piece 21 includes a base material 211 and a first active material layer 212 and a second active material layer 213 coated on both sides of the thickness direction of the base material 211, which effectively increases the active material capacity of the pole piece 21, thereby increasing the energy density; Both the first active material layer 212 and the second active material layer 213 are provided with accommodating cavities, which is conducive to further improving the storage capacity and infiltration efficiency of the electrolyte, and effectively improves the uniformity of the distribution and penetration of the electrolyte on the pole piece 21 to ensure both sides. Full utilization of the surface-coated pole piece 21.
  • the base material 211 is provided with a through hole 2111 , and the first accommodating cavity 2122 and the second accommodating cavity 2132 are connected to each other through the through hole 2111 .
  • the through hole 2111 can be directly formed by penetrating the base material 211 through the protruding portion 2130 in the mold 2100 when the pole piece 21 is extruded.
  • the base material 211 can be provided with through holes 2111 in advance before the pole piece 21 is formed, and the through holes 2111 can allow the protruding portion 2130 to pass through.
  • the number of through holes 2111 may correspond to the first accommodating cavity 2122 and the second accommodating cavity 2132.
  • the first accommodating cavity 2122 and the second accommodating cavity 2132 are connected through the through hole 2111 on the base material 211, which can effectively improve the circulation of the electrolyte in the pole piece 21, increase the infiltration path of the electrolyte, and further improve the efficiency of the electrolyte. Wetting efficiency and penetration adequacy.
  • the thickness of the second active material layer 213 is H1, satisfying H1 ⁇ 1500 ⁇ m, preferably, 70 ⁇ m ⁇ H1 ⁇ 1500 ⁇ m.
  • the thickness H1 of the second active material layer 213 can be any value greater than 0 and less than or equal to 1500 ⁇ m.
  • H1 can be 10 ⁇ m, 50 ⁇ m, 100 ⁇ m, 300 ⁇ m, 1000 ⁇ m, 1500 ⁇ m, etc.
  • H1 can be any value greater than or equal to 70 ⁇ m and less than or equal to 1500 ⁇ m.
  • H1 can be 70 ⁇ m, 80 ⁇ m, 200 ⁇ m, 1200 ⁇ m, etc.
  • H1 is 1500 ⁇ m.
  • the thickness of the pole piece 21 is too large, problems such as low reaction adequacy and poor rate capability may occur.
  • the thickness of the active material layer of the pole piece 21 provided with the accommodation cavity of the present application can reach 70 ⁇ m to 1500 ⁇ m, which effectively increases the thickness of the pole piece 21.
  • the reaction adequacy and rate capability of the pole piece 21 can be ensured, thereby effectively ensuring the energy density and charge and discharge rate of the battery using the pole piece 21.
  • the thickness of the first active material layer 212 is H2, satisfying H2 ⁇ 1500 ⁇ m, preferably, 70 ⁇ m ⁇ H2 ⁇ 1500 ⁇ m.
  • the thickness H2 of the first active material layer 212 can be any value greater than 0 and less than or equal to 1500 ⁇ m.
  • H2 can be 70 ⁇ m, 80 ⁇ m, 200 ⁇ m, 1200 ⁇ m, etc.
  • H2 can be any value greater than or equal to 70 ⁇ m and less than or equal to 1500 ⁇ m.
  • H2 can be 70 ⁇ m, 80 ⁇ m, 200 ⁇ m, 1200 ⁇ m, etc.
  • H2 is 1500 ⁇ m.
  • H1 and H2 may be the same or different.
  • H1 and H2 are the same.
  • Both the first active material layer 212 and the second active material layer 213 are provided with accommodating cavities for accommodating the electrolyte.
  • the thickness of the first active material layer 212 can reach 70 ⁇ m to 1500 ⁇ m, which can effectively increase the thickness of the pole piece 21 while ensuring the electrolyte.
  • the reaction adequacy and rate capability of the pole piece 21 further ensure the energy density of the battery using the pole piece 21 while ensuring its performance.
  • FIG. 15 is an isometric view of a pole piece provided in some further embodiments of the present application.
  • the first active material layer 212 is provided with a first active material layer penetrating through the first active material layer 212 along the first direction X.
  • the first direction 211 welding the other end extends out of the outline of pole piece 21.
  • the electric energy extraction part plays an overcurrent role and is used to extract the electric energy from the pole piece 21 .
  • the electric energy extraction part 214 can serve as the pole tab of the pole piece 21 .
  • the intersection of the first direction X and the plane of the base material 211 means that the angle between the first direction X and the plane of the base material 211 is not zero.
  • the first direction The plane where the base material 211 is located, for example, the first direction X is perpendicular to the plane where the base material 211 is located.
  • one end of the electric energy extraction part 214 extending out of the outline of the pole piece 21 can be connected to the electrode terminal provided on the casing 1 of the battery cell 10 through an adapter or other current-carrying component. (It is used to draw the electric energy in the battery cell 10 out of the battery cell 10 ).
  • one end of the electric energy extraction part 214 extending out of the outline of the pole piece 21 can also directly extend out of the casing 1 of the battery cell 10 .
  • the electric energy extraction part 214 can be welded on the base material 211 in advance, and then the active material and the base material 211 with the electric energy extraction part 214 are added to the mold cavity 2120, and the pole piece 21 is extruded through the cover 2200 and the mold 2100.
  • the mounting hole 2123 can be processed in the first active material layer 212, and then the electric energy extraction part 214 can be welded to the base material 211.
  • the pole piece 21 is provided with an electric energy extraction part 214, and the electric energy extraction part 214 is along the first direction that intersects with the surface of the base material 211.
  • X extraction makes it easier for the base material 211 and the active material to be extruded in the mold 2100, effectively reducing the risk of the electrical energy extraction part 214 being bent, deformed or even broken during the extrusion molding of the pole piece 21.
  • This application also provides an electrode assembly 2, including a positive electrode piece 21a, a negative electrode piece 21b and an isolation film 22.
  • the positive electrode piece 21a, the negative electrode piece 21b and the isolation film 22 are stacked to form the electrode assembly 2 , the isolation film 22 is disposed between the positive electrode piece 21a and the negative electrode piece 21b; wherein at least one of the positive electrode piece 21a and the negative electrode piece 21b is the pole piece 21 described in any one of the above.
  • both the positive electrode piece 21a and the negative electrode piece 21b can be the pole piece 21 described in the above solution, or only one of them can be the pole piece 21 described in the above solution.
  • both the positive electrode piece 21a and the negative electrode piece 21b are the electrode pieces 21 described in the above solution.
  • the positive electrode piece 21a can include a positive electric energy extraction part 214a
  • the negative electrode piece 21b can include a negative electrode electric energy extraction part 214b.
  • the positive electrode electric energy extraction part 214a and the negative electrode electric energy extraction part 214b can be distributed between the positive electrode piece 21a and the negative electrode piece 21b. Both sides of the stacking direction.
  • the electrode assembly 2 is beneficial to ensure the energy density of the battery 100 while ensuring the performance of the battery 100 .
  • This application also provides a battery cell 10, which includes a case 11 and the electrode assembly 2 described in the above solution.
  • the electrode assembly 2 is accommodated in the case 11.
  • the housing 1 can be a housing of any structure mentioned above, and the housing 1 can include one aforementioned electrode assembly 2 or multiple aforementioned electrode assemblies 2.
  • the housing 1 houses multiple electrode assemblies 2
  • multiple electrode assemblies 2 may be stacked along the stacking direction of the pole pieces 21 , or may be arranged in a direction perpendicular to the stacking direction of the pole pieces 21 , which is not uniquely limited in this embodiment.
  • the housing 1 has a cylindrical structure, and the pole pieces 21 are also circular structures.
  • the housing 1 includes an electrode assembly 2, and the stacking direction of the pole pieces 21 of the electrode assembly 2 is along the direction of the housing 11. Axial extension.
  • the positive electrode piece 21a and the negative electrode piece 21b of the electrode assembly 2 each include a base material 211, a first active material layer 212 and a second active material layer 213.
  • the first active material layer 212 is provided with a plurality of first accommodation cavities 2122.
  • the second active material layer 213 is provided with a plurality of second accommodating cavities 2132.
  • the base material 211 is provided with a plurality of through holes 2111.
  • the first accommodating cavities 2122 are connected to the second accommodating cavities 2132 through the through holes 2111 in a one-to-one correspondence.
  • the first active material layer 212 of the positive electrode piece 21a and the negative electrode piece 21b is distributed on both sides of the stacking direction of the electrode piece 21.
  • the positive electrode piece 21a includes a positive electric energy extraction part 214a. One end of the positive electric energy extraction part 214a is connected to the positive electrode piece 21a.
  • the base material 211 is welded, and the other end extends out of the first active material layer 212 of the positive electrode piece 21a along the axial direction of the housing 11.
  • the negative electrode piece 21b includes a negative electrode electric energy extraction part 214b. One end of the negative electrode electric energy extraction part 214b is connected to the negative electrode.
  • the base material 211 of the piece 21b is welded, and the other end extends out of the first active material layer 212 of the negative electrode piece 21b along the axial direction of the housing 11.
  • Some embodiments of the present application provide a battery 100, including a box 20 and the battery cell 10 described in the above solution, and the battery cell 10 is accommodated in the box 20.
  • Some embodiments of the present application provide an electrical device, including the battery cell 10 described in the above solution.
  • the battery cell 10 is used to provide electrical energy.
  • the electrical device can be any of the aforementioned electrical devices.
  • the pole piece preparation device 2000 includes: a mold 2100, a cover 2200, a power supply mechanism and a pressurizing mechanism.
  • the mold 2100 includes a body 2110 and a The body 2110 has a plurality of protrusions 2130.
  • the body 2110 has a mold cavity 2120.
  • the plurality of protrusions 2130 protrude from the bottom wall of the mold cavity 2120 and are spaced apart from each other.
  • the bottom wall is opposite to the opening of the mold cavity 2120.
  • the mold cavity 2120 is used to accommodate The active material 3000 and the substrate 211 are placed.
  • the cover 2200 is provided with an escape hole 2210 for the protruding portion 2130 to pass through.
  • the output end of the pressurizing mechanism is connected to the cover 2200.
  • the pressurizing mechanism is used to apply pressure to the cover 2200 so that the cover 2200 passes through the mold cavity 2120.
  • the opening at least partially extends into the mold cavity 2120, and the active material 3000 and the base material 211 are extruded together with the mold 2100, so that the active material 3000 and the base material 211 are combined to form the pole piece 21, and the plurality of protrusions 2130 are used to form the pole piece 21
  • a plurality of accommodation chambers for accommodating electrolyte are formed on the active material 3000.
  • the mold 2100 is a metal piece, and the power supply mechanism is used to energize the mold 2100 to heat the mold 2100 to dry the pole piece 21 .
  • the pole piece 21 includes a base material 211, a first active material layer 212, a second active material layer 213 and an electric energy extraction part 214.
  • An active material layer 212 is provided on one side of the substrate 211 in the thickness direction, and a second active material layer 213 is provided on the other side of the substrate 211 in the thickness direction.
  • the first active material layer 212 includes a first layer facing away from the substrate 211 .
  • the second active material layer 213 includes a second surface 2131 facing away from the substrate 211, wherein the first surface 2121 is provided with a first accommodation cavity 2122 for accommodating the electrolyte, and the second surface 2131 is provided with a first accommodation cavity 2122 for accommodating the electrolyte.
  • the base material 211 is provided with a through hole 2111, and the first accommodating cavity 2122 and the second accommodating cavity 2132 are connected to each other through the through hole 2111.
  • the first active material layer 212 is provided with a mounting hole 2123 that penetrates the first active material layer 212 along the first direction X.
  • the first direction One end of the portion 214 is welded to the base material 211, and the other end extends out of the outline of the pole piece 21.

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Abstract

Provided in the present application are a plate preparation method, a plate preparation device, a plate, an electrode assembly, a battery cell, a battery and an electric device. The plate preparation method comprises: adding an active material and a base material into a mold cavity of a mold; covering the active material and the base material with a coverage member; and applying force to the coverage member and/or the mold, and using the coverage member and the mold to jointly extrude the active material and the base material, so as to compound the active material and the base material to form a plate. By means of the plate preparation method in the technical solution of the present application, energy density of the battery can be effectively increased. In addition, working procedures such as plate coating, base material winding and unwinding, and plate cutting are effectively simplified, and working hours of all the working procedures are shortened, thereby effectively increasing the production efficiency of the plate and then effectively increasing the production efficiency of the battery.

Description

极片制备方法、极片制备装置、极片、电极组件、电池单体、电池及用电装置Pole piece preparation method, pole piece preparation device, pole piece, electrode assembly, battery cell, battery and electrical device 技术领域Technical field
本申请涉及电池技术领域,具体而言,涉及一种极片制备方法、极片制备装置、极片、电极组件、电池单体、电池及用电装置。The present application relates to the field of battery technology, specifically, to a pole piece preparation method, pole piece preparation device, pole piece, electrode assembly, battery cell, battery and electrical device.
背景技术Background technique
节能减排是汽车产业可持续发展的关键,电动车辆由于其节能环保的优势成为汽车产业可持续发展的重要组成部分。对于电动车辆而言,电池技术又是关乎其发展的一项重要因素。Energy conservation and emission reduction are the key to the sustainable development of the automobile industry. Electric vehicles have become an important part of the sustainable development of the automobile industry due to their advantages in energy conservation and environmental protection. For electric vehicles, battery technology is an important factor related to their development.
在电池生产中,如何在提高电池的能量密度的同时提高电池生产效率,是一个亟需解决的问题。In battery production, how to improve battery production efficiency while increasing battery energy density is an urgent problem that needs to be solved.
发明内容Contents of the invention
本申请提供一种极片制备方法、极片制备装置、极片、电极组件、电池单体、电池及用电装置,该极片制备方法能够有效简化极片生产工序、提高电池生产效率,同时,该极片制备方法便于有效提高电池的能量密度。This application provides a pole piece preparation method, pole piece preparation device, pole piece, electrode assembly, battery cell, battery and electrical device. The pole piece preparation method can effectively simplify the pole piece production process, improve battery production efficiency, and at the same time , this pole piece preparation method facilitates and effectively improves the energy density of the battery.
第一方面,本申请提供了一种极片制备方法,包括:将活性物料和基材加入到模具的模腔中;将覆盖件覆盖在所述活性物料和所述基材上;向所述覆盖件和/或所述模具施力,通过所述覆盖件和所述模具共同挤压所述活性物料和基材,以使所述活性物料与所述基材复合形成极片。In a first aspect, this application provides a pole piece preparation method, which includes: adding active material and base material into the mold cavity of the mold; covering the active material and base material with a cover; The cover and/or the mold apply force, and the active material and the base material are co-extruded through the cover and the mold, so that the active material and the base material are composited to form a pole piece.
本申请技术方案的极片制备方法中,通过挤压复合形成的极片可有效提高活性物料在基材上的压实性和致密性,能够有效提高其能量密度,且极片的压密性可调,可以通过设计不同模腔容积的模具或者通过控制不同的加料量得到不同压实密度的极片;另一方面,通过模具挤压复合形成极片的方法便于实现活性物料层厚度的增加,从而能够制备出厚度需求较高的极片,以满足厚极片制备需求,且增加极片的厚度可有效提高活性物质客容量,从而有效提高其能量密度。再者,模具的模腔对活性物料起到限位整形作用,通过控制模具模腔的形状、尺寸,即可直接制备得到目标形状和尺寸的极片,相较于传统的湿法涂布式极片制备工艺,本申请技术方案可有效简化涂布、基材收放卷、极片裁切等工序,且减少各工序间转运时间,减少涂布、烘干等工序的工时,从而有效提高极片生产效率。In the pole piece preparation method of the technical solution of the present application, the pole piece formed by extrusion compounding can effectively improve the compaction and density of the active material on the base material, and can effectively improve its energy density, and the compaction of the pole piece Adjustable, pole pieces with different compaction densities can be obtained by designing molds with different cavity volumes or by controlling different feeding amounts; on the other hand, the method of forming pole pieces through die extrusion and compounding facilitates an increase in the thickness of the active material layer. , thus enabling the preparation of pole pieces with higher thickness requirements to meet the preparation requirements for thick pole pieces, and increasing the thickness of the pole pieces can effectively increase the active material capacity, thereby effectively increasing its energy density. Furthermore, the cavity of the mold plays a role in limiting and shaping the active material. By controlling the shape and size of the mold cavity, pole pieces of the target shape and size can be directly prepared. Compared with the traditional wet coating method, pole piece preparation process, the technical solution of this application can effectively simplify the processes such as coating, substrate rewinding and unwinding, pole piece cutting, etc., and reduce the transfer time between each process, reduce the working hours of coating, drying and other processes, thereby effectively improving Pole piece production efficiency.
根据本申请的一些实施例,还包括:对位于所述模腔内的所述极片进行干燥;将干燥后的所述极片从所述模具中取出。According to some embodiments of the present application, the method further includes: drying the pole piece located in the mold cavity; and taking out the dried pole piece from the mold.
上述技术方案中,对模腔中挤压复合成型的极片直接进行干燥,再将干燥后的极片脱离模腔,一方面,可有效避免直接将挤压成型的极片脱模而造成的极片变形、活性物料移位等问题,从而有效保证极片的结构稳定性,且有效保证极片的制备良率;另一方面,将极片复合和极片干燥整合于同一工位进行,从而进一步减少极片生产中的输送、转运时间,使得极片生产效率得到进一步提高。In the above technical solution, the pole pieces formed by extrusion and compounding are directly dried in the mold cavity, and then the dried pole pieces are separated from the mold cavity. On the one hand, it can effectively avoid the problem caused by directly demolding the extruded pole pieces. Problems such as pole piece deformation and active material displacement can effectively ensure the structural stability of the pole piece and the production yield of the pole piece. On the other hand, the pole piece compounding and pole piece drying are integrated into the same work station. This further reduces the transportation and transfer time in pole piece production, further improving the pole piece production efficiency.
根据本申请的一些实施例,所述对位于所述模腔内的所述极片进行干燥,包括:提高所述模具和/或所述覆盖件的温度,以对所述极片进行烘干。According to some embodiments of the present application, drying the pole piece located in the mold cavity includes: increasing the temperature of the mold and/or the cover to dry the pole piece .
上述技术方案中,通过提高模具和/或覆盖件的温度对极片进行烘干,一方面,挤压成型的极片位于模具和覆盖件之间,直接提高模具和/或覆盖件的温度对极片进行加热,可有效减小极片受热距离,提高极片受热均匀性,从而提高极片烘干效率;另一方面,模具和覆盖件在极片受热 烘干过程中对极片起到定位整形作用,可有效降低极片受热过程中发生翘曲、变形的风险,从而有效保证极片的烘干质量;再者,相较于传统的通过烤炉、烤箱等设备进行极片烘干的方式,通过模具和/或覆盖件升温而加热极片的方式可为极片提供供热范围小但供热更精准的热源,不仅有利于提高极片受热烘干效率,且可有效降低烘干热能需求、节省烘干设备投入成本,有利于大幅度降低极片生产成本,具有较高的经济效益。In the above technical solution, the pole pieces are dried by increasing the temperature of the mold and/or the cover. On the one hand, the extruded pole pieces are located between the mold and the cover, and the temperature of the mold and/or the cover is directly increased to dry the pole pieces. Heating the pole pieces can effectively reduce the heating distance of the pole pieces, improve the uniformity of heating of the pole pieces, and thereby improve the drying efficiency of the pole pieces; on the other hand, the mold and cover play a role in the heating and drying process of the pole pieces. The positioning and shaping effect can effectively reduce the risk of warping and deformation of the pole pieces during the heating process, thereby effectively ensuring the drying quality of the pole pieces; furthermore, compared with traditional pole piece drying through ovens, ovens and other equipment, The method of heating the pole pieces by raising the temperature of the mold and/or cover can provide the pole pieces with a small heating range but more accurate heat source, which is not only conducive to improving the heating and drying efficiency of the pole pieces, but also effectively reduces the drying time. Dry heat energy demand, saving the investment cost of drying equipment, is conducive to significantly reducing the production cost of pole pieces, and has high economic benefits.
根据本申请的一些实施例,所述模具为金属件,所述提高所述模具和/或所述覆盖件的温度,包括:对所述模具通电,以提高所述模具的温度。According to some embodiments of the present application, the mold is a metal piece, and raising the temperature of the mold and/or the cover includes: energizing the mold to increase the temperature of the mold.
上述技术方案中,对金属材质的模具通电即可提高模具的温度,模具升温速度快且升温均衡性强,有利于进一步提高极片烘干效率和极片烘干质量,且有利于进一步降低极片生产成本。In the above technical solution, the temperature of the mold can be increased by energizing the metal mold. The mold heats up quickly and has a strong temperature rise balance, which is conducive to further improving the pole piece drying efficiency and pole piece drying quality, and is conducive to further reducing the pole piece drying efficiency. Film production costs.
根据本申请的一些实施例,所述将活性物料和基材加入到模具的模腔中,包括向所述模腔内依次加入所述活性物料和所述基材;所述将覆盖件覆盖在所述活性物料和所述基材上包括:将所述覆盖件覆盖在所述基材上。According to some embodiments of the present application, adding the active material and the base material into the mold cavity of the mold includes sequentially adding the active material and the base material into the mold cavity; and covering the cover in the mold cavity. Placing the active material and the base material includes: covering the base material with the covering member.
上述技术方案中,向模腔内依次加入活性物料和基材,基材覆盖在活性物料上,然后将覆盖件再覆盖在基材上,覆盖件和模具共同挤压活性物料和基材,以使活性物料挤压复合在基材的背离覆盖件的一侧而形成单面涂覆式极片。In the above technical solution, the active material and the base material are added sequentially into the mold cavity, the base material is covered on the active material, and then the cover is covered on the base material, and the cover and the mold jointly extrude the active material and the base material to form The active material is extruded and compounded on the side of the base material away from the cover to form a single-sided coated pole piece.
根据本申请的一些实施例,所述将活性物料和基材加入到模具的模腔中,包括:向所述模腔内依次加入第一层所述活性物料、所述基材和第二层所述活性物料;所述将覆盖件覆盖在所述活性物料和所述基材上,包括:将所述覆盖件覆盖在第二层所述活性物料上。According to some embodiments of the present application, adding the active material and the base material into the mold cavity of the mold includes: sequentially adding a first layer of the active material, the base material and a second layer into the mold cavity. The active material; covering the covering member on the active material and the base material includes: covering the covering member on the second layer of the active material.
上述技术方案中,向模腔内依次加入第一层活性物料、基材和第二层活性物料,基材位于两层活性物料之间,然后将覆盖件覆盖在第二层活性物料上,覆盖件和模具共同挤压两层活性物料和基材,以使两层活性物料分别挤压复合在基材的两侧而形成双面涂覆式极片。In the above technical solution, the first layer of active material, the base material and the second layer of active material are sequentially added into the mold cavity. The base material is located between the two layers of active material, and then the cover is covered on the second layer of active material. The component and the die co-extrude two layers of active materials and the base material, so that the two layers of active materials are extruded and compounded on both sides of the base material to form a double-sided coated pole piece.
根据本申请的一些实施例,所述模具包括本体和凸出部,所述本体具有所述模腔,所述凸出部凸出于所述模腔的底壁,所述底壁与所述模腔的开口相对;所述向所述模腔内依次加入第一层所述活性物料、所述基材和第二层所述活性物料,包括:向所述模腔内依次加入第一层所述活性物料和所述基材;将所述覆盖件覆盖在所述基材上;向所述覆盖件和/或所述模具施力,通过所述覆盖件和所述模具共同挤压第一层所述活性物料和基材,以使所述凸出部贯穿所述基材;向所述模腔内加入第二层所述活性物料。According to some embodiments of the present application, the mold includes a body and a protruding portion, the body has the mold cavity, the protruding portion protrudes from the bottom wall of the mold cavity, and the bottom wall is connected to the mold cavity. The openings of the mold cavity are opposite to each other; and sequentially adding the first layer of the active material, the base material and the second layer of the active material into the mold cavity includes: sequentially adding the first layer into the mold cavity. The active material and the base material; covering the cover on the base material; applying force to the cover and/or the mold, and extruding the first through the cover and the mold together. One layer of the active material and the base material, so that the protrusion penetrates the base material; add a second layer of the active material into the mold cavity.
上述技术方案中,模具包括设置在模腔底壁的凸出部,通过覆盖件和模具共同挤压活性物料和基材时,凸出部可以在活性物料上形成用于容纳电解液的容置腔,以促进电解液在极片内部的存储和浸润,改善极片离子阻抗大的问题,增加电池循环寿命;当极片为双面涂覆式极片时,凸出部可以贯穿基材,以确保凸出部能够在基材的两侧的活性物料上均形成容置腔。In the above technical solution, the mold includes a protruding portion provided on the bottom wall of the mold cavity. When the active material and the base material are co-extruded through the cover and the mold, the protruding portion can form a container for accommodating the electrolyte on the active material. cavity to promote the storage and infiltration of electrolyte inside the pole piece, improve the problem of large ionic resistance of the pole piece, and increase the battery cycle life; when the pole piece is a double-sided coated pole piece, the protruding part can penetrate the base material, This is to ensure that the protrusions can form accommodation cavities for the active materials on both sides of the base material.
在向模腔内依次加入第一层活性物料、基材和第二层活性物料时,先向模腔内依次加入第一层活性物料和基材,因为模腔内设置有凸出部,所以基材在不受力情况下会抵在凸出部的端部,影响第二层活性物料加入模腔。而此时将覆盖件覆盖在基材上,先通过覆盖件和模具共同挤压基材和第一层活性物料,从而使得基材穿设于凸出部并向第一层活性物料靠拢,为第二层活性物料腾出填入空间。将第二层活性物料加入模具后,再次将覆盖件覆盖在第二层活性物料上并与模具共同挤压,以使第一层活性物料、基材和第二层活性物料复合成型为一体,同时,凸出部在第一层活性物料内和第二层活性物料内均形成容置腔。When adding the first layer of active material, the base material and the second layer of active material into the mold cavity in sequence, first add the first layer of active material and the base material into the mold cavity in sequence. Because there are protrusions in the mold cavity, The base material will resist the end of the protrusion without force, which will affect the addition of the second layer of active material into the mold cavity. At this time, the cover is covered on the base material, and the base material and the first layer of active material are extruded together through the cover and the mold, so that the base material penetrates the protruding portion and moves closer to the first layer of active material. The second layer of active material makes room for filling. After the second layer of active material is added to the mold, the cover is again covered on the second layer of active material and extruded together with the mold, so that the first layer of active material, the base material and the second layer of active material are compositely formed into one body. At the same time, the protruding portion forms accommodating cavities in both the first layer of active material and the second layer of active material.
第二方面,本申请提供了一种极片制备装置,包括:模具,所述模具设有模腔,所述模腔用于容置活性物料和基材;覆盖件,所述覆盖件被配置为经所述模腔的开口至少部分伸入所述模腔,以与所述模具共同挤压所述活性物料和基材,使所述活性物料与所述基材复合形成极片。In a second aspect, the application provides a pole piece preparation device, including: a mold, the mold is provided with a mold cavity, the mold cavity is used to accommodate active materials and base materials; a cover, the cover is configured The purpose is to at least partially extend into the mold cavity through the opening of the mold cavity, so as to co-extrude the active material and the base material with the mold, so that the active material and the base material are composited to form a pole piece.
本申请技术方案的极片制备装置包括模具和覆盖件,模具设有用于容置活性物料和基材的模腔,使用时,将活性物料和基材加入模腔,并将覆盖件覆盖在模腔内的活性物料或基材上,向模具和/或覆盖件施力,以使覆盖件的至少部分伸入模腔,覆盖件和模具共同挤压活性物料和基材,以使活性物料和基材复合形成极片。一方面,模具和覆盖件共同挤压的结构可有效提高活性物料在基材上的压实性和致密性,能够有效提高极片能量密度,另一方面,模具和覆盖件共同挤压的结构便于增厚活性物料层厚度,从而能够稳定制备出厚度需求较高的极片,以满足厚极片制备需求,且便于通过增加极片的厚度有效提高活性物质客容量,从而有效提高其能量密度。再者,通过控制模 具模腔的形状、尺寸,即可直接制备得到目标形状和尺寸的极片,有利于提高极片生产效率。The pole piece preparation device of the technical solution of the present application includes a mold and a cover. The mold is provided with a mold cavity for accommodating active materials and base materials. When used, the active materials and base materials are added to the mold cavity, and the cover is covered on the mold. On the active material or substrate in the cavity, force is applied to the mold and/or cover so that at least part of the cover extends into the mold cavity, and the cover and the mold jointly squeeze the active material and substrate, so that the active material and The base materials are combined to form pole pieces. On the one hand, the structure in which the mold and the cover are co-extruded can effectively improve the compaction and density of the active material on the substrate, and can effectively increase the energy density of the pole piece. On the other hand, the structure in which the mold and the cover are co-extruded It is convenient to thicken the thickness of the active material layer, so that pole pieces with higher thickness requirements can be stably prepared to meet the preparation needs of thick pole pieces, and it is also convenient to effectively increase the active material capacity by increasing the thickness of the pole piece, thereby effectively increasing its energy density. . Furthermore, by controlling the shape and size of the mold cavity, pole pieces of the target shape and size can be directly prepared, which is beneficial to improving the production efficiency of the pole pieces.
根据本申请的一些实施例,所述模具包括本体和凸出部,所述本体具有所述模腔,所述凸出部凸出于所述模腔的底壁,所述底壁与所述模腔的开口相对,所述凸出部用于在所述活性物料上形成容纳电解液的容置腔。According to some embodiments of the present application, the mold includes a body and a protruding portion, the body has the mold cavity, the protruding portion protrudes from the bottom wall of the mold cavity, and the bottom wall is connected to the mold cavity. The openings of the mold cavity are opposite to each other, and the protruding portion is used to form a receiving cavity for accommodating electrolyte on the active material.
上述技术方案中,模具包括设置在模腔底壁上的凸出部,通过模具和覆盖件共同挤压活性物料和基材以复合形成极片时,凸出部能够在活性物料被压实过程中在活性物料上预留出一定空间,该空间形成用于容纳电解液的容置腔,极片厚度越厚,液相离子的扩散路径越长,电解液的扩散阻抗越大,会影响电池的倍率性。而本申请通过物理成孔的方式在极片的活性物料层设置用于容纳电解液的容置腔,可在增大极片的活性物料层厚度和压密性的同时,促进电解液在极片内部的存储和浸润,改善极片离子阻抗大的问题,有效增加电池的循环寿命,从而有利于在保证电池能量密度的同时有效保证电池的充放电倍率。In the above technical solution, the mold includes a protrusion arranged on the bottom wall of the mold cavity. When the active material and the base material are extruded together by the mold and the cover to compositely form the pole piece, the protrusion can be used during the compaction process of the active material. A certain space is reserved on the active material, which forms a holding cavity for accommodating the electrolyte. The thicker the electrode piece, the longer the diffusion path of liquid phase ions, and the greater the diffusion resistance of the electrolyte, which will affect the battery. of magnification. In this application, a receiving cavity for accommodating electrolyte is provided in the active material layer of the pole piece by physically forming holes, which can increase the thickness and compactness of the active material layer of the pole piece and at the same time promote the electrolyte in the pole piece. The storage and infiltration inside the chip improves the problem of large ionic resistance of the electrode piece and effectively increases the cycle life of the battery, which is beneficial to effectively ensure the charge and discharge rate of the battery while ensuring the energy density of the battery.
根据本申请的一些实施例,所述凸出部设有多个,多个所述凸出部间隔设置。According to some embodiments of the present application, there are multiple protrusions, and the plurality of protrusions are spaced apart.
上述技术方案中,模腔内设置多个间隔分布的凸出部,以便于在极片上形成多个间隔分布的用于容纳电解液的容置腔,从而进一步提高电解液在极片上的存储、浸润量,且有效提高电解液分布、渗透的均匀性。In the above technical solution, a plurality of spaced-apart protrusions are provided in the mold cavity to form a plurality of spaced-apart accommodation cavities for accommodating electrolyte on the pole piece, thereby further improving the storage and storage of electrolyte on the pole piece. infiltration amount, and effectively improve the uniformity of electrolyte distribution and penetration.
根据本申请的一些实施例,所述覆盖件设有供所述凸出部穿过的避让孔。According to some embodiments of the present application, the cover is provided with an escape hole for the protruding portion to pass through.
上述技术方案中,覆盖件设有供凸出部穿过的避让孔,一方面,避让孔的设置可为凸出部提供更多延伸空间,从而保证容置腔沿极片的厚度方向的深度,有效增大容置腔的容积,并且,能够使得凸出部沿极片的厚度方向贯穿极片,在一些实施例中,基材的厚度方向的两侧可均设置活性物料,凸出部沿极片的厚度方向贯穿极片有利于在基材两侧的活性物料上均形成容置腔;另一方面,避让孔的设置可有效避免覆盖件与凸出部发生位置干涉而影响模具和覆盖件的挤压强度的问题,从而有效保证极片的挤压成型的致密性,在保证极片能量密度的同时保证极片的结构稳定性。In the above technical solution, the cover is provided with an escape hole for the protruding portion to pass through. On the one hand, the arrangement of the escape hole can provide more extension space for the protruding portion, thereby ensuring the depth of the accommodation cavity along the thickness direction of the pole piece. , effectively increasing the volume of the accommodation cavity, and enabling the protruding portion to penetrate the pole piece along the thickness direction of the pole piece. In some embodiments, active materials can be provided on both sides of the thickness direction of the base material, and the protruding portion Penetrating the pole piece along the thickness direction of the pole piece is conducive to forming accommodation cavities for the active materials on both sides of the base material; on the other hand, the setting of the avoidance hole can effectively avoid positional interference between the cover and the protruding portion, which affects the mold and The problem of the extrusion strength of the cover piece can effectively ensure the compactness of the extrusion molding of the pole piece, and ensure the structural stability of the pole piece while ensuring the energy density of the pole piece.
根据本申请的一些实施例,所述极片制备装置还包括:烘干机构,用于对所述极片进行烘干。According to some embodiments of the present application, the pole piece preparation device further includes: a drying mechanism for drying the pole piece.
上述技术方案中,极片制备装置设置烘干机构,以对挤压成型的极片进行烘干。In the above technical solution, the pole piece preparation device is provided with a drying mechanism to dry the extruded pole pieces.
根据本申请的一些实施例,所述烘干机构包括供电机构,所述模具为金属件,所述供电机构用于向所述模具通电,使所述模具升温以烘干所述极片;和/或,所述覆盖件为金属件,所述供电机构用于向所述覆盖件通电,使所述覆盖件升温以烘干所述极片。According to some embodiments of the present application, the drying mechanism includes a power supply mechanism, the mold is a metal piece, and the power supply mechanism is used to energize the mold to heat the mold to dry the pole piece; and /Or, the cover is a metal piece, and the power supply mechanism is used to energize the cover to raise the temperature of the cover to dry the pole piece.
上述技术方案中,设置供电机构对金属材质的模具和/或金属材质的覆盖件通电,模具和/或覆盖件通电后温度升高,以对位于模具和覆盖件之间的极片直接进行加热烘干。采用供电机构向模具和/或覆盖件供电,模具和/或覆盖件升温速度快且升温均衡性强,有利于进一步提高极片烘干效率和极片烘干质量,且有利于进一步降低极片生产成本;同时,极片在模具和覆盖件之间受热烘干,模具和覆盖件对极片起到夹持定位作用,有效降低极片烘干变形的风险,从而保证极片烘干质量。In the above technical solution, a power supply mechanism is provided to energize the metal mold and/or the metal cover. After the mold and/or the cover are energized, the temperature rises to directly heat the pole piece located between the mold and the cover. drying. A power supply mechanism is used to supply power to the mold and/or cover. The mold and/or cover heats up quickly and with a strong balance of temperature rise, which is conducive to further improving the pole piece drying efficiency and pole piece drying quality, and is conducive to further reducing the pole piece drying efficiency. Production cost; at the same time, the pole pieces are heated and dried between the mold and the cover. The mold and the cover play a role in clamping and positioning the pole pieces, effectively reducing the risk of pole piece drying deformation, thereby ensuring the pole piece drying quality.
根据本申请的一些实施例,所述极片制备装置还包括:加压机构,连接于所述覆盖件,所述加压机构用于向所述覆盖件施加压力,以使所述覆盖件和所述模具共同挤压所述模腔内的所述活性物料和基材。According to some embodiments of the present application, the pole piece preparation device further includes: a pressurizing mechanism connected to the cover, and the pressurizing mechanism is used to apply pressure to the cover so that the cover and The die co-extrudes the active material and substrate in the die cavity.
上述技术方案中,设置加压机构向覆盖件施加压力,使得覆盖件能够和模具共同挤压模腔内的活性物料和基材,以便于活性物料和基材复合成型为极片。In the above technical solution, a pressurizing mechanism is provided to apply pressure to the cover, so that the cover and the mold can jointly squeeze the active material and the base material in the mold cavity, so that the active material and the base material can be compositely formed into pole pieces.
第三方面,本申请提供了一种极片,包括:基材;第一活性物料层,设置于所述基材的厚度方向的一侧,所述第一活性物料层包括背离所述基材的第一表面;其中,所述第一表面设有用于容纳电解液的第一容置腔。In a third aspect, the present application provides a pole piece, including: a base material; a first active material layer disposed on one side of the base material in the thickness direction, and the first active material layer includes a layer facing away from the base material. The first surface; wherein, the first surface is provided with a first accommodation cavity for accommodating electrolyte.
上述技术方案中,极片包括基材和第一活性物料层,第一活性物料层设置有第一容置腔,第一容置腔用于容纳电解液。极片厚度越厚,液相离子的扩散路径越长,电解液的扩散阻抗越大,将该极片应用至电池单体后,第一容置腔的设计可在增大极片的活性物料层厚度和压密性的同时,促进电解液在极片内部的存储和浸润,改善极片离子阻抗大的问题,有效增加电池的循环寿命。同时,第一容置腔的设置可协助电解液向第一活性物料层的内部渗透,有效提高电解液渗透厚度,从而保证极片的充分利用性,降低因极片厚度较厚而反应不充分的风险,因此,本申请技术方案的极 片可在有效保证电池能量密度的同时有效保证电池的使用性能。In the above technical solution, the pole piece includes a base material and a first active material layer. The first active material layer is provided with a first accommodation cavity, and the first accommodation cavity is used to accommodate electrolyte. The thicker the pole piece, the longer the diffusion path of liquid ions and the greater the diffusion resistance of the electrolyte. After applying the pole piece to the battery cell, the design of the first accommodation cavity can increase the active material of the pole piece. While improving the layer thickness and pressure tightness, it promotes the storage and infiltration of electrolyte inside the pole piece, improves the problem of large ion resistance of the pole piece, and effectively increases the cycle life of the battery. At the same time, the setting of the first accommodation cavity can assist the electrolyte to penetrate into the interior of the first active material layer, effectively increasing the penetration thickness of the electrolyte, thereby ensuring the full utilization of the pole pieces and reducing insufficient reaction due to thick pole pieces. Therefore, the pole piece of the technical solution of the present application can effectively ensure the battery performance while effectively ensuring the energy density of the battery.
根据本申请的一些实施例,所述极片还包括:第二活性物料层,设置于所述基材的厚度方向的另一侧,所述第二活性物料层包括背离所述基材的第二表面,所述第二表面设有用于容纳电解液的第二容置腔。According to some embodiments of the present application, the pole piece further includes: a second active material layer disposed on the other side in the thickness direction of the base material, and the second active material layer includes a third active material layer facing away from the base material. Two surfaces, the second surface is provided with a second accommodation cavity for accommodating electrolyte.
上述技术方案中,极片包括基材和涂覆在基材厚度方向两侧的第一活性物料层和第二活性物料层,有效提高极片的活性物质客容量,从而提高能量密度;第一活性物料层和第二活性物料层均设置容置腔,有利于进一步提高电解液的存储量和浸润效率,且有效提高电解液在极片上分布、渗透的均匀性,保证双面涂覆式极片的充分利用性。In the above technical solution, the pole piece includes a base material and a first active material layer and a second active material layer coated on both sides in the thickness direction of the base material, which effectively increases the active material passenger capacity of the pole piece, thereby increasing the energy density; first Both the active material layer and the second active material layer are provided with accommodating cavities, which is conducive to further improving the storage capacity and infiltration efficiency of the electrolyte, and effectively improves the uniformity of the distribution and penetration of the electrolyte on the pole piece, ensuring double-sided coated poles. full utilization of the film.
根据本申请的一些实施例,所述基材设有通孔,所述第一容置腔和所述第二容置腔通过所述通孔相互连通。According to some embodiments of the present application, the base material is provided with a through hole, and the first accommodation cavity and the second accommodation cavity are connected to each other through the through hole.
上述技术方案中,第一容置腔和第二容置腔通过基材上的通孔连通,可有效提高电解液的流通性,进一步提高电解液的浸润效率。In the above technical solution, the first accommodation cavity and the second accommodation cavity are connected through the through hole on the base material, which can effectively improve the circulation of the electrolyte and further improve the infiltration efficiency of the electrolyte.
根据本申请的一些实施例,所述第二活性物料层的厚度为H1,满足H1≤1500μm,优选地,70μm≤H1≤1500μm。According to some embodiments of the present application, the thickness of the second active material layer is H1, satisfying H1≤1500 μm, preferably, 70 μm≤H1≤1500 μm.
极片厚度过大易存在反应充分性低、倍率性差的问题,而本申请的设置有容置腔的极片的活性物料层的厚度可以达到70μm至1500μm,在有效增加极片厚度的同时能够保证极片的反应充分性、倍率性,从而有效保证应用该极片的电池的能量密度和充放电倍率。Excessive thickness of the pole piece may lead to problems of low reaction adequacy and poor rate capability. However, the thickness of the active material layer of the pole piece provided with the accommodation cavity of the present application can reach 70 μm to 1500 μm, which can effectively increase the thickness of the pole piece and simultaneously Ensure the reaction adequacy and rate capability of the pole piece, thereby effectively ensuring the energy density and charge and discharge rate of the battery using the pole piece.
根据本申请的一些实施例,所述第一活性物料层的厚度为H2,满足H2≤1500μm,优选地,70μm≤H2≤1500μm。According to some embodiments of the present application, the thickness of the first active material layer is H2, satisfying H2≤1500 μm, preferably, 70 μm≤H2≤1500 μm.
上述技术方案中,第一活性物料层和第二活性物料层均设置有容置腔,第一活性物料层的厚度可以达到70μm至1500μm,在有效增加极片厚度的同时能够保证极片的反应充分性、倍率性,进一步在保证应用该极片的电池的能量密度的同时保证其使用性能。In the above technical solution, both the first active material layer and the second active material layer are provided with accommodation cavities. The thickness of the first active material layer can reach 70 μm to 1500 μm, which can effectively increase the thickness of the pole piece while ensuring the reaction of the pole piece. Adequacy and rate capability further ensure the energy density of the battery using the pole piece while ensuring its performance.
根据本申请的一些实施例,所述第一活性物料层设有沿第一方向贯穿所述第一活性物料层的安装孔,所述第一方向与所述基材所在平面相交,所述极片还包括:电能引出部,穿设于所述安装孔,所述电能引出部的一端与所述基材焊接,另一端伸出所述极片的轮廓。According to some embodiments of the present application, the first active material layer is provided with a mounting hole penetrating the first active material layer along a first direction, the first direction intersects with the plane of the base material, and the pole The sheet also includes: an electric energy extraction part, which is inserted through the mounting hole. One end of the electric energy extraction part is welded to the base material, and the other end extends out of the outline of the pole piece.
上述技术方案中,极片的电能引出部沿与基材所在表面相交的第一方向引出,相较于电能引出部从基材的侧边引出的结构,更方便基材和活性物料在模具内挤压成型,有效降低电能引出部在极片挤压成型中发生弯折、变形甚至断裂的风险。In the above technical solution, the electric energy extraction part of the pole piece is extracted along the first direction that intersects with the surface of the base material. Compared with the structure in which the electric energy extraction part is extracted from the side of the base material, it is more convenient for the base material and active material to be placed in the mold Extrusion molding effectively reduces the risk of bending, deformation or even breakage of the electrical energy extraction part during the extrusion molding of the pole piece.
第四方面,本申请还提供了一种电极组件,包括正极极片、负极极片和隔离膜,所述正极极片、所述负极极片和所述隔离膜层叠形成所述电极组件,所述隔离膜设置于所述正极极片和所述负极极片之间;其中,所述正极极片和所述负极极片中的至少一者为上述任一项所述的极片。In a fourth aspect, the present application also provides an electrode assembly, including a positive electrode piece, a negative electrode piece and a separation film. The positive electrode piece, the negative electrode piece and the separation film are stacked to form the electrode assembly, so The isolation film is disposed between the positive electrode piece and the negative electrode piece; wherein at least one of the positive electrode piece and the negative electrode piece is the electrode piece described in any one of the above.
由于本申请第三方面提出的极片的特性,本申请第四方面提出的电极组件也有利于保证电池的能量密度的同时保证电池的使用性能。Due to the characteristics of the pole piece proposed in the third aspect of this application, the electrode assembly proposed in the fourth aspect of this application is also beneficial to ensuring the energy density of the battery while ensuring the performance of the battery.
第五方面,本申请还提供了一种电池单体,包括壳体和上述方案所述的电极组件,所述电极组件容置于所述壳体内。In a fifth aspect, the present application also provides a battery cell, including a case and the electrode assembly described in the above solution, and the electrode assembly is accommodated in the case.
第六方面,本申请还提供了一种电池,包括箱体和上述方案所述的电池单体,所述电池单体容置于所述箱体内。In a sixth aspect, the present application also provides a battery, including a box and the battery cell described in the above solution, and the battery cell is accommodated in the box.
第七方面,本申请还提供了一种用电装置,包括上述方案所述的电池单体,所述电池单体用于提供电能。In a seventh aspect, the present application also provides an electrical device, including the battery cell described in the above solution, where the battery cell is used to provide electric energy.
附图说明Description of drawings
为了更清楚地说明本申请实施例的技术方案,下面将对实施例中所需要使用的附图作简单地介绍,应当理解,以下附图仅示出了本申请的某些实施例,因此不应被看作是对范围的限定,对于本领域普通技术人员来讲,在不付出创造性劳动的前提下,还可以根据这些附图获得其他相关的附图。In order to more clearly illustrate the technical solutions of the embodiments of the present application, the drawings required to be used in the embodiments will be briefly introduced below. It should be understood that the following drawings only show some embodiments of the present application and therefore do not It should be regarded as a limitation of the scope. For those of ordinary skill in the art, other relevant drawings can be obtained based on these drawings without exerting creative efforts.
图1为本申请一些实施例提供的极片制备方法的总流程示意图;Figure 1 is a schematic diagram of the overall flow of the pole piece preparation method provided by some embodiments of the present application;
图2为本申请一些实施例提供的覆盖件与模具共同挤压活性物料和基材的状态示意图;Figure 2 is a schematic diagram of the state in which the cover and the mold co-extrude the active material and the base material provided by some embodiments of the present application;
图3为本申请一些实施例提供的极片制备方法的子流程示意图;Figure 3 is a schematic sub-flow diagram of the pole piece preparation method provided by some embodiments of the present application;
图4为本申请一些实施例提供的凸出部贯穿基材的状态示意图;Figure 4 is a schematic diagram of the state in which the protrusion penetrates the base material provided in some embodiments of the present application;
图5为本申请一些实施例提供的覆盖件与模具共同挤压第一层活性物料、基材和第二层活性物料的状态示意图;Figure 5 is a schematic diagram of the state in which the cover and the mold co-extrude the first layer of active material, the base material and the second layer of active material provided by some embodiments of the present application;
图6为本申请一些实施例提供的极片制备装置的结构示意图;Figure 6 is a schematic structural diagram of a pole piece preparation device provided by some embodiments of the present application;
图7为本申请又一些实施例提供的极片制备装置的结构示意图;Figure 7 is a schematic structural diagram of a pole piece preparation device provided by some embodiments of the present application;
图8为本申请一些实施例提供的用电装置的结构示意图;Figure 8 is a schematic structural diagram of an electrical device provided by some embodiments of the present application;
图9为本申请一些实施例提供的电池的爆炸图;Figure 9 is an exploded view of a battery provided by some embodiments of the present application;
图10为本申请一些实施例提供的电池单体的爆炸图;Figure 10 is an exploded view of a battery cell provided by some embodiments of the present application;
图11为本申请又一些实施例提供的电池单体的爆炸图;Figure 11 is an exploded view of a battery cell provided by some embodiments of the present application;
图12为本申请一些实施例提供的极片的轴测图;Figure 12 is an isometric view of a pole piece provided by some embodiments of the present application;
图13为本申请又一些实施例提供的极片的轴测图;Figure 13 is an isometric view of a pole piece provided by some embodiments of the present application;
图14为本申请又一些实施例提供的极片的侧视剖面图;Figure 14 is a side cross-sectional view of a pole piece provided by some embodiments of the present application;
图15为本申请再一些实施例提供的极片的轴测图。Figure 15 is an isometric view of a pole piece provided by some embodiments of the present application.
在附图中,附图并未按照实际的比例绘制。In the drawings, the drawings are not drawn to actual scale.
标记说明:1000-车辆;100-电池;10-电池单体;1-外壳;11-壳体;12-盖体;2-电极组件;21-极片;21a-正极极片;21b-负极极片;211-基材;2111-通孔;2112-极耳区;212-第一活性物料层;2121-第一表面;2122-第一容置腔;2123-安装孔;213-第二活性物料层;2131-第二表面;2132-第二容置腔;214-电能引出部;214a-正极电能引出部;214b-负极电能引出部;22-隔离膜;20-箱体;201-第一部分;202-第二部分;200-控制器;300-马达;2000-极片制备装置;2100-模具;2110-本体;2120-模腔;2130-凸出部;2140-避让槽;2200-覆盖件;2210-避让孔;2220-延伸部;3000-活性物料;3100-第一层活性物料;3200-第二层活性物料;X-第一方向。Marking description: 1000-vehicle; 100-battery; 10-battery cell; 1-casing; 11-case; 12-cover; 2-electrode assembly; 21-pole piece; 21a-positive electrode piece; 21b-negative electrode Pole piece; 211-substrate; 2111-through hole; 2112-pole tab area; 212-first active material layer; 2121-first surface; 2122-first accommodation cavity; 2123-mounting hole; 213-second Active material layer; 2131-second surface; 2132-second accommodation cavity; 214-electric energy extraction part; 214a-positive electrode electric energy extraction part; 214b-negative electrode electric energy extraction part; 22-isolation film; 20-box; 201- The first part; 202-the second part; 200-controller; 300-motor; 2000-pole piece preparation device; 2100-mold; 2110-body; 2120-mold cavity; 2130-protrusion; 2140-avoidance groove; 2200 - cover; 2210-avoidance hole; 2220-extension; 3000-active material; 3100-first layer of active material; 3200-second layer of active material; X-first direction.
具体实施方式Detailed ways
为使本申请实施例的目的、技术方案和优点更加清楚,下面将结合本申请实施例中的附图,对本申请实施例中的技术方案进行清楚、完整地描述,显然,所描述的实施例是本申请一部分实施例,而不是全部的实施例。通常在此处附图中描述和示出的本申请实施例的组件可以以各种不同的配置来布置和设计。In order to make the purpose, technical solutions and advantages of the embodiments of the present application clearer, the technical solutions in the embodiments of the present application will be clearly and completely described below in conjunction with the drawings in the embodiments of the present application. Obviously, the described embodiments These are part of the embodiments of this application, but not all of them. The components of the embodiments of the present application generally described and illustrated in the figures herein may be arranged and designed in a variety of different configurations.
因此,以下对在附图中提供的本申请的实施例的详细描述并非旨在限制要求保护的本申请的范围,而是仅仅表示本申请的选定实施例。基于本申请中的实施例,本领域普通技术人员在没有作出创造性劳动前提下所获得的所有其他实施例,都属于本申请保护的范围。Accordingly, the following detailed description of the embodiments of the application provided in the appended drawings is not intended to limit the scope of the claimed application, but rather to represent selected embodiments of the application. Based on the embodiments in this application, all other embodiments obtained by those of ordinary skill in the art without creative efforts fall within the scope of protection of this application.
下面将结合附图对本申请技术方案的实施例进行详细的描述。以下实施例仅用于更加清楚地说明本申请的技术方案,因此只作为示例,而不能以此来限制本申请的保护范围。The embodiments of the technical solution of the present application will be described in detail below with reference to the accompanying drawings. The following examples are only used to illustrate the technical solution of the present application more clearly, and are therefore only used as examples and cannot be used to limit the protection scope of the present application.
除非另有定义,本文所使用的所有的技术和科学术语与属于本申请的技术领域的技术人员通常理解的含义相同;本文中所使用的术语只是为了描述具体的实施例的目的,不是旨在于限制本申请;本申请的说明书和权利要求书及上述附图说明中的术语“包括”和“具有”以及它们的任何变形,意图在于覆盖不排他的包含。Unless otherwise defined, all technical and scientific terms used herein have the same meanings as commonly understood by those skilled in the technical field belonging to this application; the terms used herein are for the purpose of describing specific embodiments only and are not intended to be used in Limitation of this application; the terms "including" and "having" and any variations thereof in the description and claims of this application and the above description of the drawings are intended to cover non-exclusive inclusion.
在本申请实施例的描述中,技术术语“第一”“第二”等仅用于区别不同对象,而不能理解为指示或暗示相对重要性或者隐含指明所指示的技术特征的数量、特定顺序或主次关系。在本申请实施例的描述中,“多个”的含义是两个以上,除非另有明确具体的限定。In the description of the embodiments of this application, the technical terms "first", "second", etc. are only used to distinguish different objects, and cannot be understood as indicating or implying the relative importance or implicitly indicating the quantity or specificity of the indicated technical features. Sequence or priority relationship. In the description of the embodiments of this application, "plurality" means two or more, unless otherwise explicitly and specifically limited.
在本文中提及“实施例”意味着,结合实施例描述的特定特征、结构或特性可以包含在本申请的至少一个实施例中。在说明书中的各个位置出现该短语并不一定均是指相同的实施例,也不是与其它实施例互斥的独立的或备选的实施例。本领域技术人员显式地和隐式地理解的是,本文所 描述的实施例可以与其它实施例相结合。Reference herein to "an embodiment" means that a particular feature, structure or characteristic described in connection with the embodiment can be included in at least one embodiment of the present application. The appearances of this phrase in various places in the specification are not necessarily all referring to the same embodiment, nor are separate or alternative embodiments mutually exclusive of other embodiments. Those skilled in the art understand, both explicitly and implicitly, that the embodiments described herein may be combined with other embodiments.
在本申请实施例的描述中,术语“多个”指的是两个以上(包括两个)。In the description of the embodiments of this application, the term "plurality" refers to two or more (including two).
在本申请实施例的描述中,技术术语“中心”“纵向”“横向”“长度”“宽度”“厚度”“上”“下”“前”“后”“左”“右”“竖直”“水平”“顶”“底”“内”“外”“顺时针”“逆时针”“轴向”“径向”“周向”等指示的方位或位置关系为基于附图所示的方位或位置关系,仅是为了便于描述本申请实施例和简化描述,而不是指示或暗示所指的装置或元件必须具有特定的方位、以特定的方位构造和操作,因此不能理解为对本申请实施例的限制。In the description of the embodiments of this application, the technical terms "center", "longitudinal", "transverse", "length", "width", "thickness", "upper", "lower", "front", "back", "left", "right" and "vertical" The orientation or positional relationships indicated by "horizontal", "top", "bottom", "inner", "outer", "clockwise", "counterclockwise", "axial", "radial", "circumferential", etc. are based on those shown in the accompanying drawings. The orientation or positional relationship is only for the convenience of describing the embodiments of the present application and simplifying the description. It does not indicate or imply that the device or element referred to must have a specific orientation, be constructed and operated in a specific orientation, and therefore cannot be understood as a limitation on the implementation of the present application. Example limitations.
在本申请实施例的描述中,除非另有明确的规定和限定,技术术语“设置”“安装”“相连”“连接”“固定”等术语应做广义理解,例如,可以是固定连接,也可以是可拆卸连接,或成一体;可以是机械连接,也可以是电连接、信号连接;可以是直接相连,也可以通过中间媒介间接相连,可以是两个元件内部的连通或两个元件的相互作用关系。对于本领域的普通技术人员而言,可以根据具体情况理解上述术语在本申请实施例中的具体含义。In the description of the embodiments of the present application, unless otherwise explicitly stated and limited, technical terms such as "setting", "installation", "connecting", "connecting" and "fixing" should be understood in a broad sense. For example, it can be a fixed connection, or a fixed connection. It can be a detachable connection or integrated; it can be a mechanical connection, an electrical connection, or a signal connection; it can be a direct connection or an indirect connection through an intermediate medium; it can be an internal connection between two elements or an internal connection between two elements. interactive relationship. For those of ordinary skill in the art, the specific meanings of the above terms in the embodiments of this application can be understood according to specific circumstances.
在本申请的实施例中,相同的附图标记表示相同的部件,并且为了简洁,在不同实施例中,省略对相同部件的详细说明。应理解,附图示出的本申请实施例中的各种部件的厚度、长宽等尺寸,以及集成装置的整体厚度、长宽等尺寸仅为示例性说明,而不应对本申请构成任何限定。In the embodiments of the present application, the same reference numerals represent the same components, and for the sake of simplicity, detailed descriptions of the same components in different embodiments are omitted. It should be understood that the thickness, length, width and other dimensions of various components in the embodiments of the present application shown in the drawings, as well as the overall thickness, length and width of the integrated device, are only illustrative illustrations and should not constitute any limitation to the present application. .
本申请的实施例所提到的电池是指包括一个或多个电池单体以提供更高的电压和容量的单一的物理模块。例如,本申请中所提到的电池可以包括电池模块或电池包等。其中,多个电池单体之间可以串联、并联或者混联直接组成电池,混联指的是,多个电池单体中既有串联又有并联。多个电池单体也可以先串联、并联或者混联组成电池单体组,多个电池单体组再串联、并联或者混联组成电池。电池可以包括用于封装一个或多个电池单体的箱体。箱体可以避免液体或其他异物影响电池单体的充电或放电。The battery mentioned in the embodiments of this application refers to a single physical module including one or more battery cells to provide higher voltage and capacity. For example, the battery mentioned in this application may include a battery module or a battery pack. Among them, multiple battery cells can be connected in series, parallel or mixed connection to directly form a battery. Mixed connection means that multiple battery cells are connected in series and in parallel. Multiple battery cells can also be connected in series, parallel or mixed to form a battery cell group, and then multiple battery cell groups can be connected in series, parallel or mixed to form a battery. The battery may include a case for enclosing one or more battery cells. The box can prevent liquid or other foreign matter from affecting the charging or discharging of the battery cells.
本申请中,电池单体可以包括锂离子二次电池、锂离子一次电池、锂硫电池、钠锂离子电池、钠离子电池或镁离子电池等,本申请实施例对此并不限定。电池单体可呈扁平体、圆柱体、长方体或其它形状等,本申请实施例对此也不限定。In this application, the battery cells may include lithium ion secondary batteries, lithium ion primary batteries, lithium-sulfur batteries, sodium lithium ion batteries, sodium ion batteries or magnesium ion batteries, etc., which are not limited in the embodiments of this application. The battery cell may be in the shape of a flat body, a cylinder, a cuboid, or other shapes, and the embodiments of the present application are not limited to this.
电池单体包括电极组件和电解液,电极组件由正极极片、负极极片和隔离膜组成。电池单体主要依靠金属离子在正极极片和负极极片之间移动来工作。正极极片包括正极集流体(集流体即为下述的基材)和正极活性物料层,正极活性物料层涂覆于正极集流体的表面,未涂敷正极活性物料层的正极集流体可以凸出于已涂覆正极活性物料层的正极集流体而作为正极极耳。以锂离子电池为例,正极集流体的材料可以为铝,正极活性物质可以为钴酸锂、磷酸铁锂、三元锂或锰酸锂等。负极极片包括负极集流体和负极活性物料层,负极活性物料层涂覆于负极集流体的表面,未涂敷负极活性物料层的负极集流体可以凸出于已涂覆负极活性物料层的负极集流体而作为负极极耳。负极集流体的材料可以为铜,负极活性物质可以为碳或硅等。为了保证通过大电流而不发生熔断,正极极耳的数量可以为多个且层叠在一起,负极极耳的数量为多个且层叠在一起。隔离膜的材质可以为PP(polypropylene,聚丙烯)或PE(polyethylene,聚乙烯)等。此外,电极组件可以是卷绕式结构,也可以是叠片式结构,本申请实施例并不限于此。The battery cell includes an electrode assembly and an electrolyte. The electrode assembly consists of a positive electrode plate, a negative electrode plate and a separator. Battery cells mainly rely on the movement of metal ions between the positive and negative electrodes to work. The positive electrode sheet includes a positive electrode current collector (the current collector is the base material described below) and a positive electrode active material layer. The positive electrode active material layer is coated on the surface of the positive electrode current collector. The positive electrode current collector that is not coated with the positive electrode active material layer can be convex. The cathode current collector coated with the cathode active material layer serves as the cathode tab. Taking lithium-ion batteries as an example, the material of the positive electrode current collector can be aluminum, and the positive electrode active material can be lithium cobalt oxide, lithium iron phosphate, ternary lithium or lithium manganate, etc. The negative electrode sheet includes a negative electrode current collector and a negative electrode active material layer. The negative electrode active material layer is coated on the surface of the negative electrode current collector. The negative electrode current collector that is not coated with the negative electrode active material layer can protrude from the negative electrode that is coated with the negative electrode active material layer. The current collector serves as the negative electrode tab. The material of the negative electrode current collector can be copper, and the negative electrode active material can be carbon or silicon. In order to ensure that large currents can pass through without melting, the number of positive electrode tabs can be multiple and stacked together, and the number of negative electrode tabs can be multiple and stacked together. The material of the isolation film can be PP (polypropylene, polypropylene) or PE (polyethylene, polyethylene), etc. In addition, the electrode assembly may have a rolled structure or a laminated structure, and the embodiments of the present application are not limited thereto.
电池生产技术的发展要从多方面进步,比如能量密度、生产效率等等。The development of battery production technology requires progress in many aspects, such as energy density, production efficiency, etc.
传统的极片制备采用湿法涂布工艺,主要是将粘结剂、活性物质、导电剂等材料制成浆料,再将浆料湿法涂覆于集流体表面,集流体再进高温烘箱将溶剂蒸干得到所需要的极片。The traditional preparation of pole pieces adopts a wet coating process, which mainly involves making binders, active substances, conductive agents and other materials into a slurry, and then wet-coating the slurry on the surface of the current collector, and then the current collector enters a high-temperature oven. Evaporate the solvent to dryness to obtain the required pole piece.
发明人发现,采用湿法涂布的工艺制备极片存在较多缺点,主要有:(1)浆料压实密度低,导致低能量密度、高电阻和低循环寿命;(2)极片容易出现开裂等问题,无法满足活性物料层较厚的极片的制备需求,无法有效提升电池的能量密度;(3)极片制备工序繁琐,工艺周期长,不利于提高极片生产效率。The inventor found that there are many shortcomings in using the wet coating process to prepare pole pieces, mainly including: (1) The compaction density of the slurry is low, resulting in low energy density, high resistance and low cycle life; (2) The pole pieces are easy to Problems such as cracking occur, which makes it impossible to meet the preparation needs of pole pieces with thick active material layers, and cannot effectively improve the energy density of the battery; (3) the pole piece preparation process is cumbersome and the process cycle is long, which is not conducive to improving the production efficiency of the pole pieces.
基于以上原因,为了提高能量密度和生产效率,本申请发明人经过深入研究,提供了一种极片制备方法,该方法主要包括:将活性物料和基材加入到模具的模腔中;将覆盖件覆盖在活性物料和基材上;向覆盖件和/或模具施力,通过覆盖件和模具共同挤压活性物料和基材,以使活性物料与基材复合形成极片。Based on the above reasons, in order to improve energy density and production efficiency, the inventor of the present application has conducted in-depth research and provided a pole piece preparation method. The method mainly includes: adding active materials and base materials into the mold cavity of the mold; The active material and the base material are covered with a piece; force is applied to the covering piece and/or the mold, and the active material and the base material are co-extruded through the covering piece and the mold, so that the active material and the base material are compounded to form a pole piece.
一方面,通过挤压复合形成的极片可有效提高活性物料在基材上的压实性和致密性,能够有效提高其能量密度,且极片的压密性可调,可以通过设计不同模腔容积的模具或者通过控制不同 的加料量得到不同压实密度的极片;另一方面,通过挤压成型的方式有效增加极片的压实性,可有效降低极片开裂风险,从而便于增加活性物料层厚度,制备出厚度需求较高的极片,以满足厚极片制备需求,且通过增加极片的厚度可有效提高活性物质客容量,从而有效提高其能量密度。再者,模具的模腔对活性物料起到限位整形作用,通过控制模具模腔的形状、尺寸,即可直接制备得到目标形状和尺寸的极片,相较于传统的湿法涂布式极片制备工艺,本申请技术方案可有效简化涂布、基材收放卷、极片裁切等工序,且减少各工序间转运时间,减少涂布、烘干工时,从而有效提高极片生产效率。On the one hand, the pole pieces formed by extrusion compounding can effectively improve the compaction and density of the active material on the substrate, and can effectively increase its energy density. Moreover, the compaction of the pole pieces can be adjusted by designing different molds. Molds with cavity volumes or by controlling different feeding amounts can obtain pole pieces with different compaction densities; on the other hand, extrusion molding can effectively increase the compaction of the pole pieces, which can effectively reduce the risk of pole piece cracking, thus making it easier to increase The thickness of the active material layer can be used to prepare pole pieces with higher thickness requirements to meet the preparation requirements of thick pole pieces. By increasing the thickness of the pole pieces, the active material passenger capacity can be effectively increased, thereby effectively increasing its energy density. Furthermore, the cavity of the mold plays a role in limiting and shaping the active material. By controlling the shape and size of the mold cavity, pole pieces of the target shape and size can be directly prepared. Compared with the traditional wet coating method, Pole piece preparation process, the technical solution of this application can effectively simplify the processes such as coating, substrate rewinding and unwinding, pole piece cutting, etc., and reduce the transfer time between each process, reduce the coating and drying hours, thereby effectively improving the pole piece production efficiency.
本申请实施例公开的电池可以但不限用于车辆、船舶或飞行器等用电设备中,可以使用本申请公开的电池组成该用电设备的电源系统。The batteries disclosed in the embodiments of this application can be used in, but are not limited to, electrical equipment such as vehicles, ships, or aircrafts, and the batteries disclosed in this application can be used to form the power supply system of the electrical equipment.
采用本申请极片制备方法制备的极片适用的电池单体可以包括锂离子二次电池、锂离子一次电池、锂硫电池、钠锂离子电池、钠离子电池或镁离子电池等,本申请实施例对此并不限定。Battery cells suitable for the pole pieces prepared by the pole piece preparation method of the present application may include lithium ion secondary batteries, lithium ion primary batteries, lithium sulfur batteries, sodium lithium ion batteries, sodium ion batteries or magnesium ion batteries, etc., the application implements This example is not limiting.
本申请中极片制备装置可以但不限于制备适用于锂离子二次电池、锂离子一次电池、锂硫电池、钠锂离子电池、钠离子电池或镁离子电池等电池的极片,本申请实施例对此并不限定。The pole piece preparation device in this application can, but is not limited to, prepare pole pieces suitable for batteries such as lithium ion secondary batteries, lithium ion primary batteries, lithium sulfur batteries, sodium lithium ion batteries, sodium ion batteries or magnesium ion batteries. This application implements This example is not limiting.
请参照图1和图2,图1为本申请一些实施例提供的极片制备方法的总流程示意图,图2为本申请一些实施例提供的覆盖件与模具共同挤压活性物料和基材的状态示意图。本申请一些实施例提供了一种极片制备方法,包括:Please refer to Figures 1 and 2. Figure 1 is a schematic diagram of the overall flow of the pole piece preparation method provided by some embodiments of the present application. Figure 2 is a schematic diagram of the active material and base material co-extruded between the cover and the die provided by some embodiments of the present application. Status diagram. Some embodiments of the present application provide a pole piece preparation method, including:
S1:将活性物料3000和基材211加入到模具2100的模腔2120中。S1: Add the active material 3000 and the base material 211 into the mold cavity 2120 of the mold 2100.
具体而言,可以先向模腔2120加入活性物料3000,再将基材211覆盖在活性物料3000上,或者,先向模腔2120内加入基材211,再将基材211盖在活性物料3000上,甚至,可以将基材211放置在两层活性物料3000之间。Specifically, the active material 3000 can be added to the mold cavity 2120 first, and then the base material 211 can be covered on the active material 3000. Alternatively, the base material 211 can be added to the mold cavity 2120 first, and then the base material 211 can be covered with the active material 3000. On the other hand, the substrate 211 can even be placed between two layers of active material 3000 .
其中,活性物料3000可以是包含电极活性材料、导电剂、粘结剂等材料的干粉混合料,也可以是固含量较高的浆料,或者是具有一定黏性和可塑性的团状的活性物料等。Among them, the active material 3000 can be a dry powder mixture containing electrode active materials, conductive agents, binders and other materials, or it can be a slurry with a high solid content, or a group-shaped active material with certain viscosity and plasticity. wait.
可以理解的是,基材211可以是正极基材也可以是负极基材,同样的,与基材211的极性相同,活性物料3000可以是正极活性物料或负极活性物料。It can be understood that the base material 211 can be a positive electrode base material or a negative electrode base material. Similarly, with the same polarity as the base material 211, the active material 3000 can be a positive electrode active material or a negative electrode active material.
基材211的形状可以和模腔2120的形状、大小适配。基材211的外围尺寸也可以小于模腔2120的内周尺寸(即基材211的外周与模腔2120的内周面之间存在间隙)。The shape of the base material 211 can be adapted to the shape and size of the mold cavity 2120. The peripheral dimension of the base material 211 may also be smaller than the inner peripheral dimension of the mold cavity 2120 (that is, there is a gap between the outer periphery of the base material 211 and the inner peripheral surface of the mold cavity 2120).
S2:将覆盖件2200覆盖在活性物料3000或基材211上。S2: Cover the covering member 2200 on the active material 3000 or the base material 211.
具体而言,覆盖件2200可以覆盖在活性物料3000上也可以覆盖在基材211上,向模腔2120内顺序加入基材211和活性物料3000时,覆盖件2200覆盖在活性物料3000上,而向模腔2120内顺序加入活性物料3000和基材211时,覆盖件2200覆盖在基材211上。Specifically, the cover 2200 can cover the active material 3000 or the base material 211. When the base material 211 and the active material 3000 are sequentially added to the mold cavity 2120, the cover 2200 covers the active material 3000, and When the active material 3000 and the base material 211 are sequentially added into the mold cavity 2120, the cover 2200 covers the base material 211.
示例性的,如图2所示,向模腔2120内顺序加入活性物料3000和基材211,覆盖件2200覆盖在基材211上。For example, as shown in FIG. 2 , the active material 3000 and the base material 211 are sequentially added into the mold cavity 2120 , and the cover 2200 covers the base material 211 .
S3:向覆盖件2200和/或模具2100施力,通过覆盖件2200和模具2100共同挤压活性物料3000和基材211,以使活性物料3000与基材211复合形成极片21。S3: Apply force to the cover 2200 and/or the mold 2100, and jointly extrude the active material 3000 and the base material 211 through the cover 2200 and the mold 2100, so that the active material 3000 and the base material 211 are composited to form the pole piece 21.
具体而言,活性物料3000受挤压后与基材211复合,挤压后的活性物料3000形成极片21的活性物料层;可以只向覆盖件2200施力(模具2100保持静止状态),也可以只向模具2100施力(覆盖件2200覆盖在活性物料3000或基材211上后保持静止状态),还可以同时向模具2100和覆盖件2200施力,使得模具2100和覆盖件2200相向移动挤压,示例性的,模具2100保持静止,向覆盖件2200施力。Specifically, the active material 3000 is extruded and compounded with the base material 211, and the extruded active material 3000 forms the active material layer of the pole piece 21; force can only be applied to the cover 2200 (the mold 2100 remains stationary), or You can only apply force to the mold 2100 (the cover 2200 remains stationary after covering the active material 3000 or the base material 211), or you can apply force to the mold 2100 and the cover 2200 at the same time, so that the mold 2100 and the cover 2200 move toward each other. Pressing, for example, the mold 2100 remains stationary, applying force to the cover 2200.
其中,可通过手动方式向覆盖件2200和/或模具2100施力,也可通过液压系统、气压系统、伺服电缸等驱动件向覆盖件2200和/或模具2100施力,本申请实施例不对其做唯一性限定。Among them, force can be applied to the cover 2200 and/or the mold 2100 manually, or force can be applied to the cover 2200 and/or the mold 2100 through driving components such as a hydraulic system, a pneumatic system, and a servo cylinder. The embodiment of the present application does not apply force to the cover 2200 and/or the mold 2100. It is uniquely qualified.
本申请技术方案的极片21制备方法中,将活性物料3000和基材211加入模具2100的模腔2120,然后覆盖件2200和模具2100相配合,共同挤压活性物料3000和基材211,使得活性物料3000和基材211直接复合形成极片21,一方面,通过挤压复合形成的极片21可有效提高活性物料3000在基材211上的压实性和致密性,能够有效提高其能量密度,且极片21的压密性可调,可以通过设计不同模腔2120容积的模具2100或者通过控制不同的加料量得到不同压实密度的 极片21;另一方面,通过模具2100挤压复合形成极片21的方法便于实现活性物料层厚度的增加,从而能够制备出厚度需求较高的极片21,以满足厚极片21制备需求,且便于通过增加极片21的厚度有效提高活性物质客容量,从而有效提高其能量密度。再者,通过控制模具2100模腔2120的形状、尺寸,即可直接制备得到目标形状和尺寸的极片21,相较于传统的湿法涂布式极片制备工艺,本申请技术方案可有效简化涂布、基材211收放卷、极片21裁切等工序,且减少各工序间转运时间,从而有效提高极片21生产效率。In the preparation method of the pole piece 21 of the technical solution of the present application, the active material 3000 and the base material 211 are added to the mold cavity 2120 of the mold 2100, and then the cover 2200 and the mold 2100 are matched to jointly extrude the active material 3000 and the base material 211, so that The active material 3000 and the base material 211 are directly compounded to form the pole piece 21. On the one hand, the pole piece 21 formed by extrusion compounding can effectively improve the compaction and density of the active material 3000 on the base material 211, and can effectively increase its energy. Density, and the compaction of the pole piece 21 is adjustable. The pole pieces 21 with different compaction densities can be obtained by designing molds 2100 with different mold cavity 2120 volumes or by controlling different feeding amounts; on the other hand, extrusion through the mold 2100 The method of compositely forming the pole piece 21 facilitates an increase in the thickness of the active material layer, thereby enabling the preparation of a pole piece 21 with a higher thickness requirement to meet the preparation requirements for a thick pole piece 21, and making it easy to effectively increase the activity by increasing the thickness of the pole piece 21 material passenger capacity, thereby effectively increasing its energy density. Furthermore, by controlling the shape and size of the cavity 2120 of the mold 2100, the pole piece 21 of the target shape and size can be directly prepared. Compared with the traditional wet coating pole piece preparation process, the technical solution of the present application can effectively The processes such as coating, substrate 211 rewinding and unwinding, and pole piece 21 cutting are simplified, and the transfer time between each process is reduced, thereby effectively improving the production efficiency of the pole piece 21.
根据本申请的一些实施例,还包括:对位于模腔2120内的极片21进行干燥;将干燥后的极片21从模具2100中取出。According to some embodiments of the present application, the method further includes: drying the pole piece 21 located in the mold cavity 2120; and taking out the dried pole piece 21 from the mold 2100.
对位于模腔2120内的极片21进行干燥有多种实施形式,比如,可以将承载有极片21的模具2100送入烤炉、烤箱等烘干设备,使得极片21进行烘干。也可以设置专用的烘干设备,使得烘干设备靠近模具2100或伸入模腔2120对模腔2120内的极片21进行烘烤等等。There are many implementation forms for drying the pole pieces 21 located in the mold cavity 2120. For example, the mold 2100 carrying the pole pieces 21 can be sent into a drying equipment such as an oven or oven, so that the pole pieces 21 can be dried. Special drying equipment can also be set up, so that the drying equipment is close to the mold 2100 or extends into the mold cavity 2120 to bake the pole pieces 21 in the mold cavity 2120, and so on.
示例性的,可将承载有极片21的模具2100送入烤炉,模具2100在输送线上经烤炉的进料口进入烤炉,并经烤炉的出料口排出,使得模具2100内的极片21在过烤炉的过程中烘干。For example, the mold 2100 carrying the pole piece 21 can be sent into the oven. The mold 2100 enters the oven through the inlet of the oven on the conveyor line, and is discharged through the outlet of the oven, so that the mold 2100 The pole piece 21 is dried during the process of passing through the oven.
极片21干燥后,通过人工或生产设备将治具内的极片21取出即可。同样的,取出极片21的实施形式有多种,可以借助真空吸嘴将极片21从模腔2120内吸出,也可以倒置治具使极片21落料排出等。After the pole piece 21 is dried, the pole piece 21 in the fixture can be taken out manually or with production equipment. Similarly, there are many ways to take out the pole piece 21. You can use a vacuum nozzle to suck the pole piece 21 out of the mold cavity 2120, or you can invert the jig to discharge the pole piece 21.
对模腔2120中挤压复合成型的极片21直接进行干燥,再将干燥后的极片21脱离模腔2120,一方面,可有效避免直接将挤压成型的极片21脱模而造成的极片21变形、活性物料3000移位等问题,从而有效保证极片21的结构稳定性,且有效保证极片21的制备良率;另一方面,将极片21复合和极片21干燥整合于同一工位进行,从而进一步减少极片21生产中的输送、转运时间,使得极片21生产效率得到进一步提高。The pole piece 21 extruded and compounded in the mold cavity 2120 is directly dried, and then the dried pole piece 21 is separated from the mold cavity 2120. On the one hand, it can effectively avoid the damage caused by directly demolding the extruded pole piece 21. Problems such as the deformation of the pole piece 21 and the displacement of the active material 3000 can effectively ensure the structural stability of the pole piece 21 and the preparation yield of the pole piece 21; on the other hand, the composite of the pole piece 21 and the drying of the pole piece 21 are integrated It is carried out at the same work station, thereby further reducing the transportation and transfer time in the production of the pole piece 21, and further improving the production efficiency of the pole piece 21.
根据本申请的一些实施例,对位于模腔2120内的极片21进行干燥,包括:提高模具2100和/或覆盖件2200的温度,以对极片21进行烘干。According to some embodiments of the present application, drying the pole piece 21 located in the mold cavity 2120 includes: increasing the temperature of the mold 2100 and/or the cover 2200 to dry the pole piece 21 .
具体而言,可以单独提高模具2100的温度或覆盖件2200的温度,也可以同时提高模具2100和覆盖件2200的温度。Specifically, the temperature of the mold 2100 or the cover 2200 can be increased individually, or the temperatures of the mold 2100 and the cover 2200 can be increased simultaneously.
示例性的,可提高靠近活性物料3000一侧的模具2100或覆盖件2200的温度,也就是说,如果活性物料3000位于模具2100和基材211之间,可以提高模具2100的温度对活性物料3000加热,如果活性物料3000位于基材211和覆盖件2200之间,可以提高覆盖件2200的温度以对活性物料3000加热。For example, the temperature of the mold 2100 or the cover 2200 on the side close to the active material 3000 can be increased. That is, if the active material 3000 is located between the mold 2100 and the substrate 211, the temperature of the mold 2100 can be increased to affect the active material 3000. For heating, if the active material 3000 is located between the substrate 211 and the cover 2200, the temperature of the cover 2200 can be increased to heat the active material 3000.
提高模具2100和覆盖件2200的温度的实施形式有多种,比如,模具2100的壁部和覆盖件2200可以为容置有加热介质的空心结构,对加热介质升温,即可提高模具2100和覆盖件2200的温度。There are many ways to increase the temperature of the mold 2100 and the cover 2200. For example, the wall of the mold 2100 and the cover 2200 can be a hollow structure containing a heating medium. By raising the temperature of the heating medium, the mold 2100 and the cover 2200 can be raised. Part 2200 temperature.
通过提高模具2100和/或覆盖件2200的温度对极片21进行烘干,一方面,挤压成型的极片21位于模具2100和覆盖件2200之间,直接提高模具2100和/或覆盖件2200的温度对极片21进行加热,可有效减小极片21受热距离,提高极片21受热均匀性,从而提高极片21烘干效率;另一方面,模具2100和覆盖件2200在极片21受热烘干过程中对极片21起到定位整形作用,可有效降低极片21受热过程中发生翘曲、变形的风险,从而有效保证极片21的烘干质量;再者,相较于传统的通过烤炉、烤箱等设备进行极片21烘干的方式,通过模具2100和/或覆盖件2200升温而加热极片21的方式可为极片21提供供热范围小但供热更精准的热源,不仅有利于提高极片21受热烘干效率,且可有效降低烘干热能需求、节省烘干设备投入成本,有利于大幅度降低极片21生产成本,具有较高的经济效益。The pole piece 21 is dried by increasing the temperature of the mold 2100 and/or the cover 2200. On the one hand, the extruded pole piece 21 is located between the mold 2100 and the cover 2200, directly raising the temperature of the mold 2100 and/or the cover 2200. Heating the pole piece 21 at a temperature can effectively reduce the heating distance of the pole piece 21 and improve the heating uniformity of the pole piece 21, thereby improving the drying efficiency of the pole piece 21; on the other hand, the mold 2100 and the cover 2200 are in the pole piece 21 During the heating and drying process, the pole piece 21 plays a positioning and shaping role, which can effectively reduce the risk of warping and deformation of the pole piece 21 during the heating process, thereby effectively ensuring the drying quality of the pole piece 21; furthermore, compared with the traditional The method of drying the pole piece 21 through ovens, ovens and other equipment, and the method of heating the pole piece 21 by raising the temperature of the mold 2100 and/or the cover 2200 can provide the pole piece 21 with a small heating range but more precise heating. The heat source is not only conducive to improving the heating and drying efficiency of the pole piece 21, but also can effectively reduce the drying heat energy demand, save the investment cost of drying equipment, and is conducive to significantly reducing the production cost of the pole piece 21, and has high economic benefits.
根据本申请的一些实施例,模具2100为金属件,提高模具2100和/或覆盖件2200的温度,包括:对模具2100通电,以提高模具2100的温度。According to some embodiments of the present application, the mold 2100 is a metal piece, and increasing the temperature of the mold 2100 and/or the cover 2200 includes: energizing the mold 2100 to increase the temperature of the mold 2100 .
具体而言,模具2100为金属导体,模具2100产生电热(电流通过导体时,导体会发热,这种由电流产生的热,叫做电热),以对模腔2120内的极片21进行加热烘干。Specifically, the mold 2100 is a metal conductor, and the mold 2100 generates electric heat (when electric current passes through the conductor, the conductor will generate heat, and this heat generated by the electric current is called electric heat) to heat and dry the pole piece 21 in the mold cavity 2120. .
可以理解的是,模腔2120的内壁可以设置导热性能好的绝缘层,可有效防止模具2100通电对活性物料3000和基材211造成影响。It can be understood that the inner wall of the mold cavity 2120 can be provided with an insulating layer with good thermal conductivity, which can effectively prevent the impact of electricity on the mold 2100 on the active material 3000 and the base material 211.
在其他一些实施例中,覆盖件2200也可以为金属导体,通过对覆盖件2200通电以提 高覆盖件2200的温度,通过覆盖件2200对极片21进行加热。In some other embodiments, the cover 2200 can also be a metal conductor. By energizing the cover 2200 to increase the temperature of the cover 2200, the pole piece 21 is heated through the cover 2200.
可以理解的是,覆盖件2200的至少与模具2100和极片21接触的表面可以设置导热性能好的绝缘层,可有效防止模具2100通电对活性物料3000和基材211造成影响。It can be understood that at least the surface of the cover 2200 that is in contact with the mold 2100 and the pole piece 21 can be provided with an insulating layer with good thermal conductivity, which can effectively prevent the mold 2100 from being energized and affecting the active material 3000 and the base material 211 .
对金属材质的模具2100通电即可提高模具2100的温度,升温速度快且升温均衡性强,有利于进一步提高极片21烘干效率和极片21烘干质量,且有利于进一步降低极片21生产成本。By energizing the metal mold 2100, the temperature of the mold 2100 can be increased. The temperature rise speed is fast and the temperature rise balance is strong, which is conducive to further improving the drying efficiency and drying quality of the pole piece 21, and is conducive to further reducing the temperature of the pole piece 21. Cost of production.
根据本申请的一些实施例,请再次参照图2,将活性物料3000和基材211加入到模具2100的模腔2120中,包括向模腔2120内依次加入活性物料3000和基材211;将覆盖件2200覆盖在活性物料3000和基材211上包括:将覆盖件2200覆盖在基材211上。According to some embodiments of the present application, please refer to Figure 2 again, adding the active material 3000 and the base material 211 into the mold cavity 2120 of the mold 2100, including sequentially adding the active material 3000 and the base material 211 into the mold cavity 2120; covering the Covering the active material 3000 and the base material 211 with the member 2200 includes: covering the covering member 2200 on the base material 211 .
具体而言,制备极片21时,先向模腔2120内铺设一层活性物料3000,再将基材211覆盖在模腔2120内的活性物料3000上,然后将覆盖件2200覆盖在基材211厚度方向的背离活性物料3000的一侧。Specifically, when preparing the pole piece 21, first lay a layer of active material 3000 in the mold cavity 2120, then cover the base material 211 on the active material 3000 in the mold cavity 2120, and then cover the base material 211 with the covering member 2200. The side facing away from the active material 3000 in the thickness direction.
向模腔2120内依次加入活性物料3000和基材211,基材211覆盖在活性物料3000上,然后将覆盖件2200再覆盖在基材211上,覆盖件2200和模具2100共同挤压活性物料3000和基材211,以使活性物料3000挤压复合在基材211的背离覆盖件2200的一侧而形成单面涂覆式极片21。The active material 3000 and the base material 211 are sequentially added into the mold cavity 2120. The base material 211 is covered on the active material 3000, and then the cover 2200 is covered on the base material 211. The cover 2200 and the mold 2100 jointly extrusion the active material 3000. and the base material 211, so that the active material 3000 is extruded and compounded on the side of the base material 211 away from the cover 2200 to form a single-sided coated pole piece 21.
根据本申请的一些实施例,请参照图3至图5,图3为本申请一些实施例提供的极片制备方法的子流程示意图;图4为本申请一些实施例提供的凸出部贯穿基材的状态示意图;图5为本申请一些实施例提供的覆盖件与模具共同挤压第一层活性物料、基材和第二层活性物料的状态示意图。将活性物料3000和基材211加入到模具2100的模腔2120中,包括:向模腔2120内依次加入第一层活性物料3100、基材211和第二层活性物料3200;将覆盖件2200覆盖在活性物料3000和基材211上,包括:将覆盖件2200覆盖在第二层活性物料3200上。According to some embodiments of the present application, please refer to Figures 3 to 5. Figure 3 is a schematic sub-flow diagram of a pole piece preparation method provided by some embodiments of the present application; Figure 4 is a protrusion penetrating base provided by some embodiments of the present application. Figure 5 is a schematic diagram of the state of the cover and the die co-extruded by some embodiments of the present application to extrudate the first layer of active material, the base material and the second layer of active material. Adding the active material 3000 and the base material 211 to the mold cavity 2120 of the mold 2100 includes: sequentially adding the first layer of active material 3100, the base material 211 and the second layer of active material 3200 into the mold cavity 2120; covering the cover 2200 On the active material 3000 and the base material 211, the method includes: covering the second layer of active material 3200 with the cover 2200.
具体而言,制备极片21时,先向模腔2120内铺设第一层活性物料3100,再将基材211覆盖在模腔2120内的第一层活性物料3100上,然后向模腔2120内加入第二层活性物料3200,并将覆盖件2200覆盖在第二层活性物料3200上,以与模具2100共同挤压第一层活性物料3100、基材211和第二层活性物料3200。Specifically, when preparing the pole piece 21, first lay the first layer of active material 3100 into the mold cavity 2120, then cover the base material 211 on the first layer of active material 3100 in the mold cavity 2120, and then lay the first layer of active material 3100 into the mold cavity 2120. Add the second layer of active material 3200, and cover the second layer of active material 3200 with the cover 2200 to co-extrude the first layer of active material 3100, the base material 211 and the second layer of active material 3200 with the mold 2100.
向模腔2120内依次加入第一层活性物料3100、基材211和第二层活性物料3200,基材211位于两层活性物料3000之间,然后将覆盖件2200覆盖在第二层活性物料3200上,覆盖件2200和模具2100共同挤压两层活性物料3000和基材211,以使两层活性物料3000分别挤压复合在基材211的两侧而形成双面涂覆式极片21。The first layer of active material 3100, the base material 211 and the second layer of active material 3200 are sequentially added into the mold cavity 2120. The base material 211 is located between the two layers of active material 3000, and then the cover 2200 is covered on the second layer of active material 3200. On the top, the cover 2200 and the mold 2100 co-extrude the two layers of active material 3000 and the base material 211, so that the two layers of active material 3000 are extruded and compounded on both sides of the base material 211 to form a double-sided coated pole piece 21.
根据本申请的一些实施例,如图5所示,模具2100包括本体2110和凸出部2130,本体2110具有模腔2120,凸出部2130凸出于模腔2120的底壁,底壁与模腔2120的开口相对;向模腔2120内依次加入第一层活性物料3100、基材211和第二层活性物料3200,包括:According to some embodiments of the present application, as shown in Figure 5, the mold 2100 includes a body 2110 and a protruding portion 2130. The body 2110 has a mold cavity 2120. The protruding portion 2130 protrudes from the bottom wall of the mold cavity 2120. The bottom wall is connected to the mold cavity 2120. The openings of the cavity 2120 are opposite; the first layer of active material 3100, the base material 211 and the second layer of active material 3200 are sequentially added into the mold cavity 2120, including:
S11:向模腔2120内依次加入第一层活性物料3100和基材211;S11: Add the first layer of active material 3100 and the base material 211 into the mold cavity 2120 in sequence;
S12:将覆盖件2200覆盖在基材211上;S12: Cover the cover 2200 on the base material 211;
S13:向覆盖件2200和/或模具2100施力,通过覆盖件2200和模具2100共同挤压第一层活性物料3100和基材211,以使凸出部2130贯穿基材211;S13: Apply force to the cover 2200 and/or the mold 2100, and co-extrude the first layer of active material 3100 and the base material 211 through the cover 2200 and the mold 2100, so that the protruding portion 2130 penetrates the base material 211;
S14:向模腔2120内加入第二层活性物料3200。S14: Add the second layer of active material 3200 into the mold cavity 2120.
其中,凸出部2130可以是圆柱体结构、也可以是椎体结构,当然也可以是其他常规的或异型的立体结构,凸出部2130可以设置一个,也可以设置多个,示例性的,凸出部2130设置多个,多个凸出部2130呈散点状间隔分布在模腔2120的底壁。进一步的,多个凸出部2130之间的距离可以相等,当然,多个凸出部2130之间的距离也可以不等。The protruding part 2130 may be a cylindrical structure, a vertebral structure, or other conventional or special-shaped three-dimensional structure. One protruding part 2130 may be provided, or multiple protruding parts 2130 may be provided. For example, A plurality of protruding parts 2130 are provided, and the plurality of protruding parts 2130 are distributed at scattered points on the bottom wall of the mold cavity 2120. Furthermore, the distances between the plurality of protruding parts 2130 may be equal. Of course, the distances between the plurality of protruding parts 2130 may also be unequal.
凸出部2130凸出于底壁的高度可以小于模腔2120的深度(底壁和开口之间的距离),也可以等于模腔2120的深度(即凸出部2130的端面与模腔2120的开口面平齐),当然,凸出部2130凸出于底壁的高度也可以大于模腔2120的深度(即凸出部2130的端面伸出模腔2120的开口面)。示例性的,凸出部2130的端面与模腔2120的开口面平齐。The height of the protruding portion 2130 protruding from the bottom wall can be less than the depth of the mold cavity 2120 (the distance between the bottom wall and the opening), or can be equal to the depth of the mold cavity 2120 (that is, the distance between the end surface of the protruding portion 2130 and the distance between the mold cavity 2120 The opening surface is flush). Of course, the height of the protruding portion 2130 protruding from the bottom wall can also be greater than the depth of the mold cavity 2120 (that is, the end surface of the protruding portion 2130 protrudes from the opening surface of the mold cavity 2120). For example, the end surface of the protruding portion 2130 is flush with the opening surface of the mold cavity 2120 .
可以理解的是,覆盖件2200上可以设置避让凸出部2130的避让孔2210,以避免凸出 部2130干涉模具2100和覆盖件2200的挤压。It can be understood that the cover 2200 can be provided with an escape hole 2210 to avoid the protruding portion 2130 to prevent the protruding portion 2130 from interfering with the extrusion of the mold 2100 and the cover 2200.
因模腔2120内设置有凸出部2130,将基材211加入模腔2120后,凸出部2130的端部抵顶在基材211上,而将覆盖件2200覆盖在基材211上并向覆盖件2200和/或模具2100施力,可使凸出部2130向基材211施力并贯穿基材211,贯穿基材211的凸出部2130进入第二层活性物料3200的填料空间。Since the protruding portion 2130 is provided in the mold cavity 2120, after the base material 211 is added to the mold cavity 2120, the end of the protruding portion 2130 presses against the base material 211, and the cover 2200 covers the base material 211 and moves toward the base material 211. The cover 2200 and/or the mold 2100 exert force to cause the protruding portion 2130 to exert force on the base material 211 and penetrate the base material 211 . The protruding portion 2130 penetrating the base material 211 enters the filling space of the second layer of active material 3200 .
其中,可向模具2100施力以使凸出部2130直接向基材211施力,也可向覆盖件2200施力,使得凸出部2130向基材211施加反向作用力,当然,也可向模具2100和基材211均施力,使凸出部2130向基材211同时施加作用力和反向作用力。Among them, the mold 2100 can be exerted to make the protruding portion 2130 directly exert force on the base material 211, or the cover 2200 can be exerted to make the protruding portion 2130 exert a reverse force on the base material 211. Of course, it can also be Force is applied to both the mold 2100 and the base material 211, so that the protruding portion 2130 applies an acting force and a reverse force to the base material 211 at the same time.
凸出部2130贯穿基材211后,再向模腔2120内加入第二层活性物料3200。After the protruding portion 2130 penetrates the base material 211, the second layer of active material 3200 is added into the mold cavity 2120.
模具包括设置在模腔2120底壁的凸出部2130,通过覆盖件2200和模具2100共同挤压活性物料3000和基材211时,凸出部2130可以在活性物料3000上形成用于容纳电解液的容置腔,以促进电解液在极片21内部的存储和浸润,改善极片21离子阻抗大的问题,增加电池100循环寿命;当极片21为双面涂覆式极片21时,凸出部2130可以贯穿基材211,以确保凸出部2130能够在基材211的两侧的活性物料3000上均形成容置腔。在向模腔2120内依次加入第一层活性物料3100、基材211和第二层活性物料3200时,先向模腔2120内依次加入第一层活性物料3100和基材211,通过覆盖件2200和模具2100共同挤压基材211和第一层活性物料3100,从而使得基材211穿设于凸出部2130并向第一层活性物料3100靠拢,为第二层活性物料3200腾出填入空间。将第二层活性物料3200加入模具2100后,再次将覆盖件2200覆盖在第二层活性物料3200上并与模具2100共同挤压,以使第一层活性物料3100、基材211和第二层活性物料3200复合成型为一体,同时,凸出部2130在第一层活性物料3100内和第二层活性物料3200内均形成容置腔。The mold includes a protrusion 2130 disposed on the bottom wall of the mold cavity 2120. When the active material 3000 and the base material 211 are co-extruded through the cover 2200 and the mold 2100, the protrusion 2130 can be formed on the active material 3000 to accommodate the electrolyte. accommodating cavity to promote the storage and infiltration of electrolyte inside the pole piece 21, improve the problem of large ionic resistance of the pole piece 21, and increase the 100 cycle life of the battery; when the pole piece 21 is a double-sided coated pole piece 21, The protruding portion 2130 can penetrate the base material 211 to ensure that the protruding portion 2130 can form accommodating cavities on the active materials 3000 on both sides of the base material 211 . When the first layer of active material 3100, the base material 211 and the second layer of active material 3200 are sequentially added to the mold cavity 2120, first the first layer of active material 3100 and the base material 211 are sequentially added to the mold cavity 2120, through the cover 2200 The base material 211 and the first layer of active material 3100 are extruded together with the mold 2100, so that the base material 211 penetrates the protruding portion 2130 and moves closer to the first layer of active material 3100, freeing up space for the second layer of active material 3200 to be filled. space. After the second layer of active material 3200 is added to the mold 2100, the cover 2200 is again covered on the second layer of active material 3200 and extruded together with the mold 2100, so that the first layer of active material 3100, the base material 211 and the second layer The active material 3200 is compositely molded into one body. At the same time, the protruding portion 2130 forms accommodating cavities in both the first layer of active material 3100 and the second layer of active material 3200 .
请参照图6,图6为本申请一些实施例提供的极片制备装置的结构示意图,本申请提供了一种极片制备装置2000,极片制备装置2000包括:模具2100和覆盖件2200,模具2100设有模腔2120,模腔2120用于容置活性物料3000和基材211。覆盖件2200被配置为经模腔2120的开口至少部分伸入模腔2120,以与模具2100共同挤压活性物料3000和基材211,使活性物料3000与基材211复合形成极片21。Please refer to Figure 6. Figure 6 is a schematic structural diagram of a pole piece preparation device provided by some embodiments of the present application. The present application provides a pole piece preparation device 2000. The pole piece preparation device 2000 includes: a mold 2100 and a cover 2200. The mold 2100 is provided with a mold cavity 2120, which is used to accommodate the active material 3000 and the base material 211. The cover 2200 is configured to at least partially extend into the mold cavity 2120 through the opening of the mold cavity 2120, so as to co-extrude the active material 3000 and the base material 211 with the mold 2100, so that the active material 3000 and the base material 211 are composited to form the pole piece 21.
模具2100(用于成型物品的模子和工具)的模腔2120用于容置活性物料3000和基材211,以对活性物料3000和基材211期待限位和边界限制作用,可以理解的是,模腔2120的横截面形状可以根据极片21的形状对应,比如,模腔2120的横截面形状可以为圆形,以挤压成型出圆形的极片21,模腔2120的横截面形状可以为矩形,以挤压成型出矩形的极片21。当然,模腔2120的横截面形状也可以为其他常规的形状,以制备不同形状的极片21。模具2100的整体外形可以与模腔2120的形状对应,也可以不对应。The mold cavity 2120 of the mold 2100 (a mold and tool used for molding articles) is used to accommodate the active material 3000 and the base material 211, so as to have a limiting and boundary limiting effect on the active material 3000 and the base material 211. It can be understood that, The cross-sectional shape of the mold cavity 2120 can correspond to the shape of the pole piece 21. For example, the cross-sectional shape of the mold cavity 2120 can be circular to extrudate the circular pole piece 21. The cross-sectional shape of the mold cavity 2120 can be It is rectangular, and the rectangular pole piece 21 is extruded. Of course, the cross-sectional shape of the mold cavity 2120 can also be other conventional shapes to prepare pole pieces 21 of different shapes. The overall shape of the mold 2100 may or may not correspond to the shape of the mold cavity 2120 .
覆盖件2200的至少伸入模腔2120的部分可以与模腔2120匹配,或者覆盖件2200的外周尺寸略小于模腔2120的开口尺寸,示例性的,模腔2120的横截面为矩形,覆盖件2200的横截面亦为矩形,覆盖件2200与模腔2120适配。At least the part of the cover 2200 that extends into the mold cavity 2120 can match the mold cavity 2120, or the outer circumferential size of the cover 2200 is slightly smaller than the opening size of the mold cavity 2120. For example, the cross section of the mold cavity 2120 is rectangular, and the cover 2200 has a rectangular cross-section. The cross-section of 2200 is also rectangular, and the cover 2200 is adapted to the mold cavity 2120.
其中,覆盖件2200可以为板状结构,也可以为块状结构。The cover 2200 may be a plate-like structure or a block-like structure.
在又一些实施例中,请参照图7,图7为本申请又一些实施例提供的极片制备装置的结构示意图,覆盖件2200的一侧边缘可以设置延伸部2220,模具2100的侧壁设置有供该延伸部2220插入的避让槽2140,延伸部2220和避让槽2140的设计对模具2100和覆盖件2200的挤压起到导向作用。In some embodiments, please refer to FIG. 7 , which is a schematic structural diagram of a pole piece preparation device provided in some embodiments of the present application. An extension 2220 may be provided on one edge of the cover 2200 , and an extension 2220 may be provided on the side wall of the mold 2100 . There is an escape groove 2140 for the extension part 2220 to be inserted. The design of the extension part 2220 and the escape groove 2140 guides the extrusion of the mold 2100 and the cover 2200.
另外,基材211一侧的边缘可以设置能够伸出模腔2120的留白区,该留白区可以最终成为极片21的极耳,在将基材211放入模腔2120时,可将该留白区插入避让槽2140内,模具2100和覆盖件2200相向挤压后,基材211的边缘延伸出的留白区夹持在延伸部2220和避让槽2140的槽底壁之间,以有效避免该留白区发生折叠、褶皱的问题。In addition, the edge on one side of the base material 211 can be provided with a blank area that can extend out of the mold cavity 2120. This blank area can eventually become the tab of the pole piece 21. When the base material 211 is placed into the mold cavity 2120, it can be The blank area is inserted into the escape groove 2140. After the mold 2100 and the cover 2200 are pressed toward each other, the blank area extending from the edge of the base material 211 is clamped between the extension part 2220 and the bottom wall of the escape groove 2140, so as to Effectively avoid folding and wrinkles in the blank area.
极片21制备装置包括模具2100和覆盖件2200,模具2100设有用于容置活性物料3000和基材211的模腔2120,使用时,将活性物料3000和基材211加入模腔2120,并将覆盖件2200覆盖在模腔2120内的活性物料3000或基材211上,向模具2100和/或覆盖件2200施力,以使覆盖件2200的至少部分伸入模腔2120,覆盖件2200和模具2100共同挤压活性物料3000和基材211,以使活性物料3000和基材211复合形成极片21。一方面,模具2100和覆盖件2200共同 挤压的结构可有效提高活性物料3000在基材211上的压实性和致密性,能够有效提高极片21能量密度,另一方面,模具2100和覆盖件2200共同挤压的结构便于增厚活性物料层厚度,从而能够稳定制备出厚度需求较高的极片21,以满足厚极片21制备需求,且便于通过增加极片21的厚度有效提高活性物质客容量,从而有效提高其能量密度。再者,通过控制模具2100模腔2120的形状、尺寸,即可直接制备得到目标形状和尺寸的极片21,有利于提高极片21生产效率。The pole piece 21 preparation device includes a mold 2100 and a cover 2200. The mold 2100 is provided with a mold cavity 2120 for accommodating the active material 3000 and the base material 211. During use, the active material 3000 and the base material 211 are added to the mold cavity 2120, and the The cover 2200 covers the active material 3000 or the substrate 211 in the mold cavity 2120, and exerts force on the mold 2100 and/or the cover 2200, so that at least part of the cover 2200 extends into the mold cavity 2120, and the cover 2200 and the mold 2100 co-extrudes the active material 3000 and the base material 211, so that the active material 3000 and the base material 211 are composited to form the pole piece 21. On the one hand, the co-extruded structure of the mold 2100 and the cover 2200 can effectively improve the compaction and density of the active material 3000 on the base material 211, and can effectively increase the energy density of the pole piece 21. On the other hand, the mold 2100 and the cover The co-extruded structure of the parts 2200 is convenient for thickening the thickness of the active material layer, so that the pole piece 21 with a higher thickness requirement can be stably prepared to meet the preparation requirements of the thick pole piece 21, and it is easy to effectively increase the activity by increasing the thickness of the pole piece 21 material passenger capacity, thereby effectively increasing its energy density. Furthermore, by controlling the shape and size of the cavity 2120 of the mold 2100, the pole piece 21 of the target shape and size can be directly prepared, which is beneficial to improving the production efficiency of the pole piece 21.
根据本申请的一些实施例,请继续参照图6和图7,模具2100包括本体2110和凸出部2130,本体2110具有模腔2120,凸出部2130凸出于模腔2120的底壁,底壁与模腔2120的开口相对,凸出部2130用于在活性物料3000上形成容纳电解液的容置腔。According to some embodiments of the present application, please continue to refer to Figures 6 and 7. The mold 2100 includes a body 2110 and a protruding portion 2130. The body 2110 has a mold cavity 2120. The protruding portion 2130 protrudes from the bottom wall of the mold cavity 2120. The wall is opposite to the opening of the mold cavity 2120, and the protruding portion 2130 is used to form a receiving cavity on the active material 3000 to accommodate the electrolyte.
如前所述,凸出部2130可以是圆柱体结构、也可以是椎体结构,当然也可以是其他常规的或异型的立体结构,凸出部2130可以设置一个,也可以设置多个,示例性的,凸出部2130设置多个,多个凸出部2130间隔分布在模腔2120的底壁。多个凸出部2130之间的距离可以相等也可以不等。As mentioned above, the protruding portion 2130 can be a cylindrical structure, a vertebral structure, or other conventional or special-shaped three-dimensional structures. One or more protruding portions 2130 can be provided. Examples Optionally, multiple protrusions 2130 are provided, and the plurality of protrusions 2130 are spacedly distributed on the bottom wall of the mold cavity 2120. The distance between the plurality of protrusions 2130 may be equal or unequal.
凸出部2130凸出于底壁的高度可以小于、大于或等于模腔2120的深度(底壁和开口之间的距离),示例性的,凸出部2130的端面与模腔2120的开口面平齐。The height of the protruding portion 2130 protruding from the bottom wall may be less than, greater than, or equal to the depth of the mold cavity 2120 (the distance between the bottom wall and the opening). For example, the end surface of the protruding portion 2130 and the opening surface of the mold cavity 2120 Flush.
模具2100包括设置在模腔2120底壁上的凸出部2130,通过模具2100和覆盖件2200共同挤压活性物料3000和基材211以复合形成极片21时,凸出部2130能够在活性物料3000被压实过程中在活性物料3000上预留出一定空间,该空间形成用于容纳电解液的容置腔,极片21厚度越厚,液相离子的扩散路径越长,电解液的扩散阻抗越大,会影响电池100的倍率性。而通过物理成孔的方式在极片21的活性物料3000层设置用于容纳电解液的容置腔,可在增大极片21的活性物料3000层厚度和压密性的同时,促进电解液在极片21内部的存储和浸润,改善极片21离子阻抗大的问题,有效增加电池100的循环寿命,从而有利于在保证电池100能量密度的同时有效保证电池100的充放电倍率。The mold 2100 includes a protruding portion 2130 disposed on the bottom wall of the mold cavity 2120. When the active material 3000 and the base material 211 are co-extruded by the mold 2100 and the cover 2200 to compositely form the pole piece 21, the protruding portion 2130 can move the active material When 3000 is compacted, a certain space is reserved on the active material 3000. This space forms a receiving cavity for accommodating the electrolyte. The thicker the electrode piece 21 is, the longer the diffusion path of liquid phase ions is, and the diffusion of the electrolyte is The greater the impedance, the higher the rate capability of the battery 100 will be affected. By physically forming a hole in the active material layer 3000 of the pole piece 21, a receiving cavity for containing the electrolyte can be provided, which can increase the thickness and compactness of the active material layer 3000 of the pole piece 21 and at the same time promote the electrolyte. The storage and infiltration inside the pole piece 21 improves the problem of large ionic resistance of the pole piece 21 and effectively increases the cycle life of the battery 100, thereby ensuring the energy density of the battery 100 while effectively ensuring the charge and discharge rate of the battery 100.
根据本申请的一些实施例,凸出部2130设有多个,多个凸出部2130间隔设置。According to some embodiments of the present application, multiple protrusions 2130 are provided, and the plurality of protrusions 2130 are spaced apart.
如图6和图7所示,多个凸出部2130可以呈散点式分布于模腔2120的底壁,多个凸出部2130之间的距离可以相等也可以不等,示例性的,多个凸出部2130之间的距离相等。As shown in Figures 6 and 7, the plurality of protrusions 2130 can be distributed on the bottom wall of the mold cavity 2120 in a scattered point manner, and the distance between the plurality of protrusions 2130 can be equal or unequal. For example, The distances between the plurality of protrusions 2130 are equal.
模腔2120内设置多个间隔分布的凸出部2130,以便于在极片21上形成多个间隔分布的用于容纳电解液的容置腔,从而进一步提高电解液在极片21上的存储、浸润量,且有效提高电解液分布、渗透的均匀性。A plurality of spaced-apart protrusions 2130 are provided in the mold cavity 2120 to form a plurality of spaced-apart accommodation cavities for accommodating electrolyte on the pole piece 21 , thereby further improving the storage of electrolyte on the pole piece 21 , infiltration amount, and effectively improve the uniformity of electrolyte distribution and penetration.
根据本申请的一些实施例,覆盖件2200设有供凸出部2130穿过的避让孔2210。According to some embodiments of the present application, the cover 2200 is provided with an escape hole 2210 for the protrusion 2130 to pass through.
可以理解的是,如图6和图7所示,当凸出部2130设有多个时,覆盖件2200可以设置多个避让孔2210,多个避让孔2210与多个凸出部2130一一对应。It can be understood that, as shown in FIGS. 6 and 7 , when multiple protrusions 2130 are provided, the cover 2200 can be provided with multiple escape holes 2210 , and the multiple escape holes 2210 are connected to the multiple protrusions 2130 one by one. correspond.
覆盖件2200设有供凸出部2130穿过的避让孔2210,一方面,避让孔2210的设置可为凸出部2130提供更多延伸空间,从而保证容置腔沿极片21的厚度方向的深度,有效增大容置腔的容积,并且,能够使得凸出部2130沿极片21的厚度方向贯穿极片21,在一些实施例中,基材211的厚度方向的两侧可均设置活性物料3000,凸出部2130沿极片21的厚度方向贯穿极片21有利于在基材211两侧的活性物料3000上均形成容置腔;另一方面,避让孔2210的设置可有效避免覆盖件2200与凸出部2130发生位置干涉而影响模具2100和覆盖件2200的挤压强度的问题,从而有效保证极片21的挤压成型的致密性,在保证极片21能量密度的同时保证极片21的结构稳定性。The cover 2200 is provided with an escape hole 2210 for the protruding portion 2130 to pass through. On the one hand, the arrangement of the escape hole 2210 can provide more extension space for the protruding portion 2130, thereby ensuring that the accommodation cavity is arranged along the thickness direction of the pole piece 21. depth, effectively increasing the volume of the accommodation cavity, and enabling the protruding portion 2130 to penetrate the pole piece 21 along the thickness direction of the pole piece 21. In some embodiments, active elements can be provided on both sides of the substrate 211 in the thickness direction. material 3000, the protruding portion 2130 penetrates the pole piece 21 along the thickness direction of the pole piece 21, which is beneficial to forming accommodation cavities for the active material 3000 on both sides of the base material 211; on the other hand, the setting of the avoidance hole 2210 can effectively avoid covering The problem of positional interference between the member 2200 and the protruding portion 2130 affects the extrusion strength of the mold 2100 and the covering member 2200, thereby effectively ensuring the compactness of the extrusion molding of the pole piece 21, and ensuring the energy density of the pole piece 21 while ensuring the pole piece 21. Structural stability of sheet 21.
根据本申请的一些实施例,极片制备装置2000还包括烘干机构,烘干机构用于对极片21进行烘干。According to some embodiments of the present application, the pole piece preparation device 2000 also includes a drying mechanism, which is used to dry the pole piece 21 .
烘干机构的实施形式有多种,示例性的,烘干机构可以采用工业生产使用的烘干设备(比如烤炉、烤箱等),可以将挤压成型后的极片21从模具2100中取出后送入烘干设备,也可以直接将承载有极片21的模具2100送入烘干设备,使得极片21进行烘干。There are many implementation forms of the drying mechanism. As an example, the drying mechanism can use drying equipment used in industrial production (such as ovens, ovens, etc.), and can take out the extruded pole piece 21 from the mold 2100 Then it is sent to the drying equipment, or the mold 2100 carrying the pole piece 21 can be directly sent to the drying equipment, so that the pole piece 21 is dried.
极片制备装置设置烘干机构,以对挤压成型的极片21进行烘干定型。The pole piece preparation device is provided with a drying mechanism to dry and shape the extruded pole piece 21 .
根据本申请的一些实施例,烘干机构包括供电机构,模具2100为金属件,供电机构用于向模具2100通电,使模具2100升温以烘干极片21;和/或,覆盖件2200为金属件,供电机构用于向覆盖件2200通电,使覆盖件2200升温以烘干极片21。According to some embodiments of the present application, the drying mechanism includes a power supply mechanism. The mold 2100 is a metal part. The power supply mechanism is used to energize the mold 2100 to heat the mold 2100 to dry the pole piece 21; and/or the cover 2200 is metal. The power supply mechanism is used to energize the cover 2200 to heat the cover 2200 to dry the pole piece 21 .
供电机构泛指能够向模具2100和/或覆盖件2200通电的机构,即可采用常规的市电供电结构,也可以采用常规的电池供电结构,只要能够向金属通电使其发热即可。The power supply mechanism generally refers to a mechanism that can energize the mold 2100 and/or the cover 2200. It can use a conventional mains power supply structure or a conventional battery power supply structure, as long as it can energize the metal to make it heat.
供电机构可以向模具2100通电使模具2100产生电热(电流通过导体时,导体会发热,这种由电流产生的热叫做电热),以对模腔2120内的极片21进行加热烘干。The power supply mechanism can energize the mold 2100 to generate electric heat (when current passes through a conductor, the conductor will generate heat, and this heat generated by the current is called electric heat) to heat and dry the pole piece 21 in the mold cavity 2120.
当然,供电机构也可以单独向覆盖件2200通电,或者同时向模具2100和覆盖件2200通电,以对模腔2120内的极片21进行加热烘干。Of course, the power supply mechanism can also energize the cover 2200 alone, or energize the mold 2100 and the cover 2200 at the same time to heat and dry the pole piece 21 in the mold cavity 2120.
可以理解的是,模腔2120的内壁可以设置导热性能好的绝缘层,可有效防止模具2100通电对活性物料3000和基材211造成影响。当然,当覆盖件2200通电时,覆盖件2200的至少与模具2100和极片21接触的表面也可以设置导热性能好的绝缘层,有效防止覆盖件2200通电对活性物料3000和基材211造成影响。It can be understood that the inner wall of the mold cavity 2120 can be provided with an insulating layer with good thermal conductivity, which can effectively prevent the impact of electricity on the mold 2100 on the active material 3000 and the base material 211. Of course, when the cover 2200 is powered on, at least the surface of the cover 2200 that is in contact with the mold 2100 and the pole piece 21 can also be provided with an insulating layer with good thermal conductivity to effectively prevent the impact of the cover 2200 on the active material 3000 and the base material 211 .
采用供电机构向模具2100和/或覆盖件2200供电,模具2100和/或覆盖件2200产生电热,其升温速度快且升温均衡性强,有利于进一步提高极片21烘干效率和极片21烘干质量,且有利于进一步降低极片21生产成本;同时,极片21在模具2100和覆盖件2200之间受热烘干,模具2100和覆盖件2200对极片21起到夹持定位作用,有效降低极片21烘干变形的风险,从而保证极片21烘干质量。A power supply mechanism is used to supply power to the mold 2100 and/or the cover 2200. The mold 2100 and/or the cover 2200 generate electric heat, which has a fast heating speed and strong temperature rise balance, which is conducive to further improving the drying efficiency of the pole piece 21 and the drying efficiency of the pole piece 21. dry quality, and is conducive to further reducing the production cost of the pole piece 21; at the same time, the pole piece 21 is heated and dried between the mold 2100 and the cover 2200, and the mold 2100 and the cover 2200 play a clamping and positioning role for the pole piece 21, effectively The risk of drying deformation of the pole piece 21 is reduced, thereby ensuring the drying quality of the pole piece 21.
根据本申请的一些实施例,极片制备装置2000还包括加压机构,加压机构连接于覆盖件2200,加压机构用于向覆盖件2200施加压力,以使覆盖件2200和模具2100共同挤压模腔2120内的活性物料3000和基材211。According to some embodiments of the present application, the pole piece preparation device 2000 further includes a pressurizing mechanism connected to the cover 2200. The pressurizing mechanism is used to apply pressure to the cover 2200 so that the cover 2200 and the mold 2100 are co-extruded. The active material 3000 and the substrate 211 in the mold cavity 2120 are pressed.
加压机构是指可以为覆盖件2200提供压力驱动的结构,加压机构的实施形式有多种,比如,加压机构可以为液压机,液压机驱动覆盖件2200移动。当然,加压机构也可以为气动压力机、伺服电缸等压力提供机构。The pressurizing mechanism refers to a structure that can provide pressure drive for the cover 2200. There are many implementation forms of the pressurizing mechanism. For example, the pressurizing mechanism can be a hydraulic press, and the hydraulic press drives the cover 2200 to move. Of course, the pressurizing mechanism can also be a pressure providing mechanism such as a pneumatic press or a servo electric cylinder.
使用时,固定模具2100的位置,覆盖件2200安装在加压机构的输出端,加压机构可以驱动覆盖件2200朝向模具2100移动,以使覆盖件2200和模具2100共同挤压模腔2120内的基材211和活性物料3000,加压机构也可以驱动覆盖件2200背离模具2100移动,以使覆盖件2200与模具2100分离。During use, the position of the mold 2100 is fixed, and the cover 2200 is installed at the output end of the pressurizing mechanism. The pressurizing mechanism can drive the cover 2200 to move toward the mold 2100, so that the cover 2200 and the mold 2100 jointly squeeze the material in the mold cavity 2120. The base material 211 and the active material 3000, and the pressing mechanism can also drive the cover 2200 to move away from the mold 2100, so that the cover 2200 is separated from the mold 2100.
设置加压机构向覆盖件2200施加压力,使得覆盖件2200能够和模具2100共同挤压模腔2120内的活性物料3000和基材211,以便于活性物料3000和基材211复合成型为极片21。A pressurizing mechanism is provided to apply pressure to the cover 2200, so that the cover 2200 and the mold 2100 can jointly squeeze the active material 3000 and the base material 211 in the mold cavity 2120, so that the active material 3000 and the base material 211 can be compositely formed into the pole piece 21 .
本申请一些实施例提供一种使用电池作为电源的用电装置,用电装置可以为但不限于手机、平板、笔记本电脑、电动玩具、电动工具、电瓶车、电动汽车、轮船、航天器等等。其中,电动玩具可以包括固定式或移动式的电动玩具,例如,游戏机、电动汽车玩具、电动轮船玩具和电动飞机玩具等等,航天器可以包括飞机、火箭、航天飞机和宇宙飞船等等。Some embodiments of the present application provide an electrical device that uses a battery as a power source. The electrical device can be, but is not limited to, a mobile phone, a tablet, a laptop, an electric toy, an electric tool, a battery car, an electric vehicle, a ship, a spacecraft, etc. Among them, electric toys can include fixed or mobile electric toys, such as game consoles, electric car toys, electric ship toys, electric airplane toys, etc., and spacecraft can include airplanes, rockets, space shuttles, spaceships, etc.
本申请的实施例描述的电池不仅仅局限适用于上述所描述的用电装置,还可以适用于所有使用电池电池的用电装置,但为描述简洁,以下实施例以本申请一实施例的一种用电装置为车辆为例进行说明。The battery described in the embodiments of the present application is not limited to the above-described electrical devices, but can also be applied to all electrical devices using batteries. However, for the sake of simplicity of description, the following embodiment uses an example of an embodiment of the present application. An electrical device is a vehicle as an example for illustration.
请参照图8,图8为本申请一些实施例提供的车辆1000的结构示意图。车辆1000可以为燃油汽车、燃气汽车或新能源汽车,新能源汽车可以是纯电动汽车、混合动力汽车或增程式汽车等。车辆1000的内部设置有电池100,电池100可以设置在车辆1000的底部或头部或尾部。电池100可以用于车辆1000的供电,例如,电池100可以作为车辆1000的操作电源。车辆1000还可以包括控制器200和马达300,控制器200用来控制电池100为马达300供电,例如,用于车辆1000的启动、导航和行驶时的工作用电需求。Please refer to FIG. 8 , which is a schematic structural diagram of a vehicle 1000 provided by some embodiments of the present application. The vehicle 1000 may be a fuel vehicle, a gas vehicle or a new energy vehicle, and the new energy vehicle may be a pure electric vehicle, a hybrid vehicle or an extended-range vehicle, etc. The battery 100 is disposed inside the vehicle 1000 , and the battery 100 may be disposed at the bottom, head, or tail of the vehicle 1000 . The battery 100 may be used to power the vehicle 1000 , for example, the battery 100 may serve as an operating power source for the vehicle 1000 . The vehicle 1000 may also include a controller 200 and a motor 300 . The controller 200 is used to control the battery 100 to provide power to the motor 300 , for example, for starting, navigating and driving the vehicle 1000 .
在其他一些实施例中,电池100不仅可以作为车辆1000的操作电源,还可以作为车辆1000的驱动电源,代替或部分地代替燃油或天然气为车辆1000提供驱动动力。In some other embodiments, the battery 100 can not only be used as an operating power source for the vehicle 1000 , but also can be used as a driving power source for the vehicle 1000 , replacing or partially replacing fuel or natural gas to provide driving power for the vehicle 1000 .
请参照图9,图9为本申请一些实施例提供的电池100的爆炸图,电池100可以包括箱体20和电池单体10,电池单体10容纳于箱体20内。其中,箱体20用于为电池单体10提供容纳空间,箱体20可以采用多种结构。在一些实施例中,箱体20可以包括第一部分201和第二部分202,第一部分201与第二部分202相互盖合,第一部分201和第二部分202共同限定出用于容纳电池单体10的容纳空间。第二部分202可以为一端开口的空心结构,第一部分201可以为板状结构,第一部分201盖合于第二部分202的开口侧,以使第一部分201与第二部分202共同限定出容 纳空间;第一部分201和第二部分202也可以是均为一侧开口的空心结构,第一部分201的开口侧盖合于第二部分202的开口侧。当然,第一部分201和第二部分202形成的箱体20可以是多种形状,比如,长方体、正方体等。Please refer to FIG. 9 , which is an exploded view of the battery 100 provided by some embodiments of the present application. The battery 100 may include a box 20 and a battery cell 10 , and the battery cell 10 is accommodated in the box 20 . The box 20 is used to provide an accommodation space for the battery cells 10 , and the box 20 can adopt a variety of structures. In some embodiments, the box 20 may include a first part 201 and a second part 202 , the first part 201 and the second part 202 cover each other, and the first part 201 and the second part 202 jointly define a space for accommodating the battery cell 10 of accommodation space. The second part 202 may be a hollow structure with one end open, and the first part 201 may be a plate-like structure. The first part 201 covers the open side of the second part 202 so that the first part 201 and the second part 202 jointly define a receiving space. ; The first part 201 and the second part 202 may also be hollow structures with one side open, and the open side of the first part 201 is covered with the open side of the second part 202. Of course, the box 20 formed by the first part 201 and the second part 202 can be in various shapes, such as rectangular parallelepiped, cube, etc.
在电池100中,电池单体10可以是多个,多个电池单体10之间可串联或并联或混联,混联是指多个电池单体10中既有串联又有并联。多个电池单体10之间可直接串联或并联或混联在一起。In the battery 100 , there may be a plurality of battery cells 10 , and the plurality of battery cells 10 may be connected in series, in parallel, or in mixed connection. Mixed connection means that the plurality of battery cells 10 are connected in series and in parallel. Multiple battery cells 10 can be directly connected in series or in parallel or mixed together.
请参照图10,图10为本申请一些实施例提供的电池单体10的爆炸图,本申请一些实施例提供的电池单体10可以包括外壳1、电极组件2和电解液,外壳1是用于容纳电极组件2和电解液以及其他构件的部件。外壳1可以是多种形状,例如长方体。在又一些实施例中,请参照图11,图11为本申请又一些实施例提供的电池单体10的爆炸图,外壳1呈圆柱体。当然,外壳的形状不限于上述的长方体和圆柱体,还可以是其他形状。Please refer to Figure 10. Figure 10 is an exploded view of a battery cell 10 provided in some embodiments of the present application. The battery cell 10 provided in some embodiments of the present application may include a casing 1, an electrode assembly 2 and an electrolyte. The casing 1 is made of Parts used to accommodate the electrode assembly 2, electrolyte and other components. The housing 1 can be in various shapes, such as rectangular parallelepiped. In some embodiments, please refer to FIG. 11 . FIG. 11 is an exploded view of the battery cell 10 provided in some embodiments of the present application. The casing 1 is in the form of a cylinder. Of course, the shape of the shell is not limited to the above-mentioned rectangular parallelepiped and cylinder, and can also be other shapes.
外壳1可以包括壳体11和盖体12,盖体12盖合于壳体11的开口,盖体12与壳体11共同限定出用于容纳电极组件2、电解液以及其他部件的密封空间。The housing 1 may include a housing 11 and a cover 12. The cover 12 covers the opening of the housing 11. The cover 12 and the housing 11 jointly define a sealed space for accommodating the electrode assembly 2, electrolyte and other components.
电极组件2是电池单体10中发生电化学反应的部件。电极组件2可以包括正极极片21a、负极极片21b和隔离膜22。电极组件2可以是由正极极片21a、隔离膜22和负极极片21b通过卷绕形成的卷绕式结构,也可以是叠片结构。示例性的,电极组件2为叠片结构。The electrode assembly 2 is a component in the battery cell 10 where electrochemical reactions occur. The electrode assembly 2 may include a positive electrode piece 21a, a negative electrode piece 21b, and a separation film 22. The electrode assembly 2 may be a rolled structure formed by winding the positive electrode piece 21a, the isolation film 22 and the negative electrode piece 21b, or may be a laminate structure. Exemplarily, the electrode assembly 2 is a laminate structure.
请参照图12,图12为本申请一些实施例提供的极片的轴测图。本申请一些实施例还提供了一种极片21,该极片21包括基材211和第一活性物料层212,第一活性物料层212设置于基材211的厚度方向的一侧,第一活性物料层212包括背离基材211的第一表面2121;其中,第一表面2121设有用于容纳电解液的第一容置腔2122。Please refer to Figure 12, which is an isometric view of a pole piece provided by some embodiments of the present application. Some embodiments of the present application also provide a pole piece 21. The pole piece 21 includes a base material 211 and a first active material layer 212. The first active material layer 212 is disposed on one side of the base material 211 in the thickness direction. The active material layer 212 includes a first surface 2121 facing away from the substrate 211; wherein the first surface 2121 is provided with a first accommodation cavity 2122 for accommodating electrolyte.
该极片21可以采用前述的极片制备方法和极片制备装置制成,基材211可以是正极基材也可以是负极基材,第一活性物料层212可以由活性物料3000挤压复合在基材211上形成。当然,在其他一些实施例中,第一活性物料层212也可以通过喷涂、辊压等方式与基材211复合。The pole piece 21 can be made by using the aforementioned pole piece preparation method and pole piece preparation device. The base material 211 can be a positive electrode base material or a negative electrode base material. The first active material layer 212 can be extruded and compounded by the active material 3000. formed on the base material 211. Of course, in other embodiments, the first active material layer 212 can also be compounded with the base material 211 by spraying, rolling, or other methods.
第一表面2121背离基材211,第一容置腔2122可以沿极片21的厚度方向贯穿第一活性物料层212,也可以不贯穿第一活性物料层212。第一容置腔2122可以设置一个,也可以间隔设置多个,示例性的,第一容置腔2122间隔设置多个。The first surface 2121 faces away from the base material 211 , and the first accommodation cavity 2122 may penetrate the first active material layer 212 along the thickness direction of the pole piece 21 , or may not penetrate the first active material layer 212 . One first accommodating cavity 2122 may be provided, or multiple first accommodating cavities 2122 may be provided at intervals. For example, a plurality of first accommodating cavities 2122 may be provided at intervals.
第一容置腔2122可以在极片21挤压成型时通过模具2100内的凸出部2130直接成型,即模具2100包括本体2110和凸出部2130,本体2110具有模腔2120,凸出部2130凸出于模腔2120的底壁,模具2100与覆盖件2200共同挤压活性物料3000和基材211,凸出部2130在活性物料3000上成型第一容置腔2122。当然,在其他一些实施例中,第一容置腔2122也可以在成品极片21上加工而成。The first receiving cavity 2122 can be directly formed through the protruding portion 2130 in the mold 2100 when the pole piece 21 is extruded. That is, the mold 2100 includes a body 2110 and a protruding portion 2130. The body 2110 has a mold cavity 2120 and a protruding portion 2130. Protruding from the bottom wall of the mold cavity 2120 , the mold 2100 and the cover 2200 jointly squeeze the active material 3000 and the base material 211 , and the protruding portion 2130 forms a first accommodation cavity 2122 on the active material 3000 . Of course, in some other embodiments, the first accommodating cavity 2122 can also be processed on the finished pole piece 21 .
另外,基材211一侧的边缘可以设置能够伸出模腔2120的留白区,该留白区最终成为极片21的极耳区2112。In addition, a blank area that can protrude out of the mold cavity 2120 may be provided on the edge of one side of the base material 211 , and this blank area eventually becomes the tab area 2112 of the pole piece 21 .
极片21包括基材211和第一活性物料层212,第一活性物料层212设置有第一容置腔2122,第一容置腔2122用于容纳电解液。极片21厚度越厚,液相离子的扩散路径越长,电解液的扩散阻抗越大,将该极片21应用至电池单体10后,第一容置腔2122的设计可在增大极片21的活性物料3000层厚度和压密性的同时,促进电解液在极片21内部的存储和浸润,改善极片21离子阻抗大的问题,有效增加电池100的循环寿命。同时,第一容置腔2122的设置可协助电解液向第一活性物料层212的内部渗透,有效提高电解液渗透厚度,从而保证极片21的充分利用性,降低因极片21厚度较厚而反应不充分的风险,因此,本申请技术方案的极片21可在有效保证电池100能量密度的同时有效保证电池100的使用性能。The pole piece 21 includes a base material 211 and a first active material layer 212. The first active material layer 212 is provided with a first accommodation cavity 2122, and the first accommodation cavity 2122 is used to accommodate electrolyte. The thicker the electrode piece 21 is, the longer the diffusion path of liquid phase ions is, and the greater the diffusion resistance of the electrolyte is. After applying the electrode piece 21 to the battery cell 10, the design of the first accommodation cavity 2122 can increase the electrode size. The thickness and tightness of the active material layer 3000 of the sheet 21 simultaneously promotes the storage and infiltration of the electrolyte inside the pole piece 21, improves the problem of large ionic impedance of the pole piece 21, and effectively increases the cycle life of the battery 100. At the same time, the setting of the first accommodation cavity 2122 can assist the electrolyte to penetrate into the interior of the first active material layer 212, effectively increasing the penetration thickness of the electrolyte, thereby ensuring the full utilization of the pole piece 21 and reducing the risk of the thick pole piece 21. There is a risk of insufficient reaction. Therefore, the pole piece 21 of the technical solution of the present application can effectively ensure the energy density of the battery 100 and the performance of the battery 100 at the same time.
根据本申请的又一些实施例,请参照图13和图14,图13为本申请又一些实施例提供的极片的轴测图,图14为本申请又一些实施例提供的极片的侧视剖面图。极片21还包括第二活性物料层213,第二活性物料层213设置于基材211的厚度方向的另一侧,第二活性物料层213包括背离基材211的第二表面2131,第二表面2131设有用于容纳电解液的第二容置腔2132。According to some further embodiments of the present application, please refer to Figures 13 and 14. Figure 13 is an isometric view of a pole piece provided in some further embodiments of the present application, and Figure 14 is a side view of a pole piece provided in some further embodiments of the present application. View section view. The pole piece 21 also includes a second active material layer 213. The second active material layer 213 is disposed on the other side in the thickness direction of the base material 211. The second active material layer 213 includes a second surface 2131 facing away from the base material 211. The surface 2131 is provided with a second containing cavity 2132 for containing electrolyte.
可以理解的是,第二活性物料层213和第一活性物料层212的材质相同,同样的,第二活性物料层213可以由活性物料3000挤压复合在基材211上形成。当然,在其他一些实施例中,第二活性物料层213也可以通过喷涂、辊压等方式与基材211复合。It can be understood that the second active material layer 213 and the first active material layer 212 are made of the same material. Similarly, the second active material layer 213 can be formed by extrusion compounding of the active material 3000 on the base material 211 . Of course, in other embodiments, the second active material layer 213 can also be compounded with the base material 211 by spraying, rolling, or other methods.
第二表面2131背离基材211,第二容置腔2132可以沿极片21的厚度方向贯穿第二活性物料层213,也可以不贯穿第二活性物料层213。第二容置腔2132可以设置一个,也可以间隔设置多个,示例性的,第二容置腔2132间隔设置多个。The second surface 2131 faces away from the base material 211 , and the second accommodation cavity 2132 may penetrate the second active material layer 213 along the thickness direction of the pole piece 21 , or may not penetrate the second active material layer 213 . One second accommodating cavity 2132 may be provided, or multiple second accommodating cavities 2132 may be provided at intervals. For example, a plurality of second accommodating cavities 2132 may be provided at intervals.
第二容置腔2132可以在极片21挤压成型时通过模具2100内的凸出部2130直接成型,当然,在其他一些实施例中,第二容置腔2132也可以在成品极片21上加工而成。The second accommodating cavity 2132 can be directly formed through the protruding portion 2130 in the mold 2100 when the pole piece 21 is extruded. Of course, in some other embodiments, the second accommodating cavity 2132 can also be formed on the finished pole piece 21 Processed.
极片21包括基材211和涂覆在基材211厚度方向两侧的第一活性物料层212和第二活性物料层213,有效提高极片21的活性物质客容量,从而提高能量密度;第一活性物料层212和第二活性物料层213均设置容置腔,有利于进一步提高电解液的存储量和浸润效率,且有效提高电解液在极片21上分布、渗透的均匀性,保证双面涂覆式极片21的充分利用性。The pole piece 21 includes a base material 211 and a first active material layer 212 and a second active material layer 213 coated on both sides of the thickness direction of the base material 211, which effectively increases the active material capacity of the pole piece 21, thereby increasing the energy density; Both the first active material layer 212 and the second active material layer 213 are provided with accommodating cavities, which is conducive to further improving the storage capacity and infiltration efficiency of the electrolyte, and effectively improves the uniformity of the distribution and penetration of the electrolyte on the pole piece 21 to ensure both sides. Full utilization of the surface-coated pole piece 21.
根据本申请的一些实施例,请继续参照图14,基材211设有通孔2111,第一容置腔2122和第二容置腔2132通过通孔2111相互连通。According to some embodiments of the present application, please continue to refer to FIG. 14 , the base material 211 is provided with a through hole 2111 , and the first accommodating cavity 2122 and the second accommodating cavity 2132 are connected to each other through the through hole 2111 .
可以理解的是,基于“模具2100包括本体2110和凸出部2130”的实施形式,通孔2111可以在极片21挤压成型时通过模具2100内的凸出部2130贯穿基材211而直接成型,当然,在其他一些实施例中,基材211可以在极片21成型前提前设置通孔2111,通孔2111可供凸出部2130穿过。It can be understood that, based on the implementation form of "the mold 2100 includes a body 2110 and a protruding portion 2130", the through hole 2111 can be directly formed by penetrating the base material 211 through the protruding portion 2130 in the mold 2100 when the pole piece 21 is extruded. , of course, in some other embodiments, the base material 211 can be provided with through holes 2111 in advance before the pole piece 21 is formed, and the through holes 2111 can allow the protruding portion 2130 to pass through.
其中,通孔2111的数量可以和第一容置腔2122以及第二容置腔2132一一对应。The number of through holes 2111 may correspond to the first accommodating cavity 2122 and the second accommodating cavity 2132.
第一容置腔2122和第二容置腔2132通过基材211上的通孔2111连通,可有效提高电解液在极片21内的流通性,增加了电解液的浸润路径,进一步提高电解液的浸润效率和渗透充分性。The first accommodating cavity 2122 and the second accommodating cavity 2132 are connected through the through hole 2111 on the base material 211, which can effectively improve the circulation of the electrolyte in the pole piece 21, increase the infiltration path of the electrolyte, and further improve the efficiency of the electrolyte. Wetting efficiency and penetration adequacy.
根据本申请的一些实施例,请继续参照图14,第二活性物料层213的厚度为H1,满足H1≤1500μm,优选地,70μm≤H1≤1500μm。According to some embodiments of the present application, please continue to refer to Figure 14. The thickness of the second active material layer 213 is H1, satisfying H1≤1500 μm, preferably, 70 μm≤H1≤1500 μm.
第二活性物料层213的厚度H1可以是大于0且小于等于1500μm的任意数值,比如H1可以为10μm,50μm,100μm,300μm,1000μm,1500μm等。The thickness H1 of the second active material layer 213 can be any value greater than 0 and less than or equal to 1500 μm. For example, H1 can be 10 μm, 50 μm, 100 μm, 300 μm, 1000 μm, 1500 μm, etc.
优选地,H1可以是大于等于70μm且小于等于1500μm的任意数值,比如H1可以为70μm,80μm,200μm,1200μm等。示例性的,H1为1500μm。Preferably, H1 can be any value greater than or equal to 70 μm and less than or equal to 1500 μm. For example, H1 can be 70 μm, 80 μm, 200 μm, 1200 μm, etc. For example, H1 is 1500 μm.
极片21厚度过大易存在反应充分性低、倍率性差的问题,而本申请的设置有容置腔的极片21的活性物料层的厚度可以达到70μm至1500μm,在有效增加极片21厚度的同时能够保证极片21的反应充分性、倍率性,从而有效保证应用该极片21的电池的能量密度和充放电倍率。If the thickness of the pole piece 21 is too large, problems such as low reaction adequacy and poor rate capability may occur. However, the thickness of the active material layer of the pole piece 21 provided with the accommodation cavity of the present application can reach 70 μm to 1500 μm, which effectively increases the thickness of the pole piece 21. At the same time, the reaction adequacy and rate capability of the pole piece 21 can be ensured, thereby effectively ensuring the energy density and charge and discharge rate of the battery using the pole piece 21.
根据本申请的一些实施例,请继续参照图14,第一活性物料层212的厚度为H2,满足H2≤1500μm,优选地,70μm≤H2≤1500μm。According to some embodiments of the present application, please continue to refer to Figure 14. The thickness of the first active material layer 212 is H2, satisfying H2≤1500 μm, preferably, 70 μm≤H2≤1500 μm.
第一活性物料层212的厚度H2可以是大于0且小于等于1500μm的任意数值,比如H2可以为70μm,80μm,200μm,1200μm等。The thickness H2 of the first active material layer 212 can be any value greater than 0 and less than or equal to 1500 μm. For example, H2 can be 70 μm, 80 μm, 200 μm, 1200 μm, etc.
优选地,H2可以是大于等于70μm且小于等于1500μm的任意数值,比如H2可以为70μm,80μm,200μm,1200μm等。示例性的,H2为1500μm。Preferably, H2 can be any value greater than or equal to 70 μm and less than or equal to 1500 μm. For example, H2 can be 70 μm, 80 μm, 200 μm, 1200 μm, etc. For example, H2 is 1500 μm.
其中,H1和H2可以相同也可以不同,示例性的,H1和H2相同。Among them, H1 and H2 may be the same or different. As an example, H1 and H2 are the same.
第一活性物料层212和第二活性物料层213均设置有容纳电解液的容置腔,第一活性物料层212的厚度可以达到70μm至1500μm,能够在有效增加极片21厚度的同时保证极片21的反应充分性、倍率性,进一步在保证应用该极片21的电池的能量密度的同时保证其使用性能。Both the first active material layer 212 and the second active material layer 213 are provided with accommodating cavities for accommodating the electrolyte. The thickness of the first active material layer 212 can reach 70 μm to 1500 μm, which can effectively increase the thickness of the pole piece 21 while ensuring the electrolyte. The reaction adequacy and rate capability of the pole piece 21 further ensure the energy density of the battery using the pole piece 21 while ensuring its performance.
根据本申请的再一些实施例中,请参照图15,图15为本申请再一些实施例提供的极片的轴测图,第一活性物料层212设有沿第一方向X贯穿第一活性物料层212的安装孔2123,第一方向X与基材211所在平面相交,极片21还包括电能引出部214,电能引出部214穿设于安装孔2123,电能引出部214的一端与基材211焊接,另一端伸出极片21的轮廓。According to some further embodiments of the present application, please refer to FIG. 15 , which is an isometric view of a pole piece provided in some further embodiments of the present application. The first active material layer 212 is provided with a first active material layer penetrating through the first active material layer 212 along the first direction X. In the mounting hole 2123 of the material layer 212, the first direction 211 welding, the other end extends out of the outline of pole piece 21.
电能引出部起到过流作用,用于将极片21的电能引出,电能引出部214可以作为极片21的极耳。The electric energy extraction part plays an overcurrent role and is used to extract the electric energy from the pole piece 21 . The electric energy extraction part 214 can serve as the pole tab of the pole piece 21 .
第一方向X与基材211所在平面相交,是指第一方向X与基材211所在平面之间的角度不为零,第一方向X可以垂直于基材211所在平面,也可以不垂直于基材211所在平面,示例性的,第一方向X垂直于基材211所在平面。The intersection of the first direction X and the plane of the base material 211 means that the angle between the first direction X and the plane of the base material 211 is not zero. The first direction The plane where the base material 211 is located, for example, the first direction X is perpendicular to the plane where the base material 211 is located.
将该极片21应用至电池单体10时,电能引出部214伸出极片21的轮廓的一端可以通过转接件等过流部件连接至设置在电池单体10的外壳1上的电极端子(用于将电池单体10内的电能引出电池单体10),当然,电能引出部214伸出极片21的轮廓的一端也可以直接伸出电池单体10的外壳1。When the pole piece 21 is applied to the battery cell 10, one end of the electric energy extraction part 214 extending out of the outline of the pole piece 21 can be connected to the electrode terminal provided on the casing 1 of the battery cell 10 through an adapter or other current-carrying component. (It is used to draw the electric energy in the battery cell 10 out of the battery cell 10 ). Of course, one end of the electric energy extraction part 214 extending out of the outline of the pole piece 21 can also directly extend out of the casing 1 of the battery cell 10 .
电能引出部214可以预先焊接在基材211上,然后将活性物料和带有该电能引出部214的基材211加入模腔2120,通过覆盖件2200和模具2100挤压成型极片21。The electric energy extraction part 214 can be welded on the base material 211 in advance, and then the active material and the base material 211 with the electric energy extraction part 214 are added to the mold cavity 2120, and the pole piece 21 is extruded through the cover 2200 and the mold 2100.
当然,也可以在极片21成型后,在第一活性物料层212加工出安装孔2123,再将电能引出部214焊接于基材211。Of course, after the pole piece 21 is formed, the mounting hole 2123 can be processed in the first active material layer 212, and then the electric energy extraction part 214 can be welded to the base material 211.
相较于基材211的侧边预留留白区形成极片21的极耳的结构,极片21设置电能引出部214,且电能引出部214沿与基材211所在表面相交的第一方向X引出,更方便基材211和活性物料在模具2100内挤压成型,有效降低电能引出部214在极片21挤压成型中发生弯折、变形甚至断裂的风险。Compared with the structure of leaving a blank area on the side of the base material 211 to form the tabs of the pole piece 21, the pole piece 21 is provided with an electric energy extraction part 214, and the electric energy extraction part 214 is along the first direction that intersects with the surface of the base material 211. X extraction makes it easier for the base material 211 and the active material to be extruded in the mold 2100, effectively reducing the risk of the electrical energy extraction part 214 being bent, deformed or even broken during the extrusion molding of the pole piece 21.
请再次参照图11,本申请还提供了一种电极组件2,包括正极极片21a、负极极片21b和隔离膜22,正极极片21a、负极极片21b和隔离膜22层叠形成电极组件2,隔离膜22设置于正极极片21a和负极极片21b之间;其中,正极极片21a和负极极片21b中的至少一者为上述任一项所述的极片21。Please refer to Figure 11 again. This application also provides an electrode assembly 2, including a positive electrode piece 21a, a negative electrode piece 21b and an isolation film 22. The positive electrode piece 21a, the negative electrode piece 21b and the isolation film 22 are stacked to form the electrode assembly 2 , the isolation film 22 is disposed between the positive electrode piece 21a and the negative electrode piece 21b; wherein at least one of the positive electrode piece 21a and the negative electrode piece 21b is the pole piece 21 described in any one of the above.
也就是说,正极极片21a和负极极片21b可以两个都是上述方案所述的极片21,也可以只有其中一个是上述方案所述的极片21。示例性的,正极极片21a和负极极片21b均为上述方案所述的极片21。That is to say, both the positive electrode piece 21a and the negative electrode piece 21b can be the pole piece 21 described in the above solution, or only one of them can be the pole piece 21 described in the above solution. For example, both the positive electrode piece 21a and the negative electrode piece 21b are the electrode pieces 21 described in the above solution.
其中,正极极片21a可以包括正极电能引出部214a,负极极片21b可以包括负极电能引出部214b,正极电能引出部214a和负极电能引出部214b可以分布于正极极片21a和负极极片21b的层叠方向的两侧。Among them, the positive electrode piece 21a can include a positive electric energy extraction part 214a, and the negative electrode piece 21b can include a negative electrode electric energy extraction part 214b. The positive electrode electric energy extraction part 214a and the negative electrode electric energy extraction part 214b can be distributed between the positive electrode piece 21a and the negative electrode piece 21b. Both sides of the stacking direction.
该电极组件2有利于在保证电池100的能量密度的同时保证电池100的使用性能。The electrode assembly 2 is beneficial to ensure the energy density of the battery 100 while ensuring the performance of the battery 100 .
本申请还提供了一种电池单体10,包括壳体11和上述方案所述的电极组件2,所述电极组件2容置于所述壳体11内。This application also provides a battery cell 10, which includes a case 11 and the electrode assembly 2 described in the above solution. The electrode assembly 2 is accommodated in the case 11.
可以理解的是,外壳1可以为前述的任意结构的外壳,外壳1内可以包括一个前述的电极组件2,也可以包括多个前述的电极组件2,当外壳1内容置多个电极组件2时,多个电极组件2可以沿极片21的层叠方向堆叠,也可以沿垂直于极片21层叠方向的方向排列,本实施例并不对此做唯一性限定。It can be understood that the housing 1 can be a housing of any structure mentioned above, and the housing 1 can include one aforementioned electrode assembly 2 or multiple aforementioned electrode assemblies 2. When the housing 1 houses multiple electrode assemblies 2 , multiple electrode assemblies 2 may be stacked along the stacking direction of the pole pieces 21 , or may be arranged in a direction perpendicular to the stacking direction of the pole pieces 21 , which is not uniquely limited in this embodiment.
示例性的,如图11所示,外壳1为圆柱体结构,极片21亦为圆形结构,外壳1内包括一个电极组件2,电极组件2的极片21的层叠方向沿壳体11的轴向延伸。For example, as shown in Figure 11, the housing 1 has a cylindrical structure, and the pole pieces 21 are also circular structures. The housing 1 includes an electrode assembly 2, and the stacking direction of the pole pieces 21 of the electrode assembly 2 is along the direction of the housing 11. Axial extension.
电极组件2的正极极片21a和负极极片21b均包括基材211、第一活性物料层212和第二活性物料层213,第一活性物料层212设有多个第一容置腔2122,第二活性物料层213设有多个第二容置腔2132,基材211设有多个通孔2111,第一容置腔2122通过通孔2111与第二容置腔2132一一对应连通。The positive electrode piece 21a and the negative electrode piece 21b of the electrode assembly 2 each include a base material 211, a first active material layer 212 and a second active material layer 213. The first active material layer 212 is provided with a plurality of first accommodation cavities 2122. The second active material layer 213 is provided with a plurality of second accommodating cavities 2132. The base material 211 is provided with a plurality of through holes 2111. The first accommodating cavities 2122 are connected to the second accommodating cavities 2132 through the through holes 2111 in a one-to-one correspondence.
正极极片21a和负极极片21b的第一活性物料层212分布于极片21层叠方向的两侧,正极极片21a包括正极电能引出部214a,正极电能引出部214a的一端与正极极片21a的基材211焊接,另一端沿壳体11的轴向伸出正极极片21a的第一活性物料层212,负极极片21b包括负极电能引出部214b,负极电能引出部214b的一端与负极极片21b的基材211焊接,另一端沿壳体11的轴向伸出负极极片21b的第一活性物料层212。The first active material layer 212 of the positive electrode piece 21a and the negative electrode piece 21b is distributed on both sides of the stacking direction of the electrode piece 21. The positive electrode piece 21a includes a positive electric energy extraction part 214a. One end of the positive electric energy extraction part 214a is connected to the positive electrode piece 21a. The base material 211 is welded, and the other end extends out of the first active material layer 212 of the positive electrode piece 21a along the axial direction of the housing 11. The negative electrode piece 21b includes a negative electrode electric energy extraction part 214b. One end of the negative electrode electric energy extraction part 214b is connected to the negative electrode. The base material 211 of the piece 21b is welded, and the other end extends out of the first active material layer 212 of the negative electrode piece 21b along the axial direction of the housing 11.
本申请一些实施例提供了一种电池100,包括箱体20和上述方案所述的电池单体10,所述电池单体10容置于所述箱体20内。Some embodiments of the present application provide a battery 100, including a box 20 and the battery cell 10 described in the above solution, and the battery cell 10 is accommodated in the box 20.
本申请一些实施例提供了一种用电装置,包括上述方案所述的电池单体10,所述电池单体10用于提供电能,所述用电装置可以是前述任意一种用电装置。Some embodiments of the present application provide an electrical device, including the battery cell 10 described in the above solution. The battery cell 10 is used to provide electrical energy. The electrical device can be any of the aforementioned electrical devices.
请参照图5至图7,本申请一些实施例提供了一种极片制备装置2000,极片制备装置2000包括:模具2100、覆盖件2200、供电机构和加压机构,模具2100包括本体2110和多个凸出部2130,本体2110具有模腔2120,多个凸出部2130凸出于模腔2120的底壁且相互间隔设置,底 壁与模腔2120的开口相对,模腔2120用于容置活性物料3000和基材211。覆盖件2200设有供凸出部2130穿过的避让孔2210,加压机构的输出端连接于覆盖件2200,加压机构用于向覆盖件2200施加压力,以使覆盖件2200经模腔2120的开口至少部分伸入模腔2120,与模具2100共同挤压活性物料3000和基材211,使活性物料3000与基材211复合形成极片21,多个凸出部2130用于在极片21的活性物料3000上形成多个容纳电解液的容置腔。Please refer to Figures 5 to 7. Some embodiments of the present application provide a pole piece preparation device 2000. The pole piece preparation device 2000 includes: a mold 2100, a cover 2200, a power supply mechanism and a pressurizing mechanism. The mold 2100 includes a body 2110 and a The body 2110 has a plurality of protrusions 2130. The body 2110 has a mold cavity 2120. The plurality of protrusions 2130 protrude from the bottom wall of the mold cavity 2120 and are spaced apart from each other. The bottom wall is opposite to the opening of the mold cavity 2120. The mold cavity 2120 is used to accommodate The active material 3000 and the substrate 211 are placed. The cover 2200 is provided with an escape hole 2210 for the protruding portion 2130 to pass through. The output end of the pressurizing mechanism is connected to the cover 2200. The pressurizing mechanism is used to apply pressure to the cover 2200 so that the cover 2200 passes through the mold cavity 2120. The opening at least partially extends into the mold cavity 2120, and the active material 3000 and the base material 211 are extruded together with the mold 2100, so that the active material 3000 and the base material 211 are combined to form the pole piece 21, and the plurality of protrusions 2130 are used to form the pole piece 21 A plurality of accommodation chambers for accommodating electrolyte are formed on the active material 3000.
其中,模具2100为金属件,供电机构用于向模具2100通电,使模具2100升温以烘干极片21。The mold 2100 is a metal piece, and the power supply mechanism is used to energize the mold 2100 to heat the mold 2100 to dry the pole piece 21 .
请参照图14和图15,本申请一些实施例提供了一种极片21,该极片21包括基材211、第一活性物料层212、第二活性物料层213和电能引出部214,第一活性物料层212设置于基材211的厚度方向的一侧,第二活性物料层213设置于基材211的厚度方向的另一侧,第一活性物料层212包括背离基材211的第一表面2121,第二活性物料层213包括背离基材211的第二表面2131,其中,第一表面2121设有用于容纳电解液的第一容置腔2122,第二表面2131设有用于容纳电解液的第二容置腔2132。基材211设置有通孔2111,第一容置腔2122和第二容置腔2132通过通孔2111相互连通。Please refer to Figures 14 and 15. Some embodiments of the present application provide a pole piece 21. The pole piece 21 includes a base material 211, a first active material layer 212, a second active material layer 213 and an electric energy extraction part 214. An active material layer 212 is provided on one side of the substrate 211 in the thickness direction, and a second active material layer 213 is provided on the other side of the substrate 211 in the thickness direction. The first active material layer 212 includes a first layer facing away from the substrate 211 . Surface 2121, the second active material layer 213 includes a second surface 2131 facing away from the substrate 211, wherein the first surface 2121 is provided with a first accommodation cavity 2122 for accommodating the electrolyte, and the second surface 2131 is provided with a first accommodation cavity 2122 for accommodating the electrolyte. The second accommodation cavity 2132. The base material 211 is provided with a through hole 2111, and the first accommodating cavity 2122 and the second accommodating cavity 2132 are connected to each other through the through hole 2111.
第一活性物料层212设有沿第一方向X贯穿第一活性物料层212的安装孔2123,第一方向X与基材211所在平面相交,电能引出部214穿设于安装孔2123,电能引出部214的一端与基材211焊接,另一端伸出极片21的轮廓。The first active material layer 212 is provided with a mounting hole 2123 that penetrates the first active material layer 212 along the first direction X. The first direction One end of the portion 214 is welded to the base material 211, and the other end extends out of the outline of the pole piece 21.
需要说明的是,在不冲突的情况下,本申请中的实施例中的特征可以相互结合。It should be noted that, as long as there is no conflict, the features in the embodiments of this application can be combined with each other.
虽然已经参考优选实施例对本申请进行了描述,但在不脱离本申请的范围的情况下,可以对其进行各种改进并且可以用等效物替换其中的部件。尤其是,只要不存在结构冲突,各个实施例中所提到的各项技术特征均可以任意方式组合起来。本申请并不局限于文中公开的特定实施例,而是包括落入权利要求的范围内的所有技术方案。While the present application has been described with reference to preferred embodiments, various modifications may be made and equivalents may be substituted for components thereof without departing from the scope of the application. In particular, as long as there is no structural conflict, the technical features mentioned in the various embodiments can be combined in any way. The application is not limited to the specific embodiments disclosed herein, but includes all technical solutions falling within the scope of the claims.

Claims (24)

  1. 一种极片制备方法,包括:A method for preparing pole pieces, including:
    将活性物料和基材加入到模具的模腔中;Add active materials and base materials into the cavity of the mold;
    将覆盖件覆盖在所述活性物料和所述基材上;Cover the active material and the base material with a covering member;
    向所述覆盖件和/或所述模具施力,通过所述覆盖件和所述模具共同挤压所述活性物料和所述基材,以使所述活性物料与所述基材复合形成极片。Applying force to the cover and/or the mold, the active material and the base material are co-extruded through the cover and the mold, so that the active material and the base material are composited to form a pole. piece.
  2. 根据权利要求1所述的极片制备方法,其中,还包括:The pole piece preparation method according to claim 1, further comprising:
    对位于所述模腔内的所述极片进行干燥;Drying the pole piece located in the mold cavity;
    将干燥后的所述极片从所述模具中取出。The dried pole piece is taken out from the mold.
  3. 根据权利要求2所述的极片制备方法,其中,所述对位于所述模腔内的所述极片进行干燥,包括:The pole piece preparation method according to claim 2, wherein drying the pole piece located in the mold cavity includes:
    提高所述模具和/或所述覆盖件的温度,以对所述极片进行烘干。The temperature of the mold and/or the cover is increased to dry the pole piece.
  4. 根据权利要求3所述的极片制备方法,其中,所述模具为金属件,所述提高所述模具和/或所述覆盖件的温度,包括:The pole piece preparation method according to claim 3, wherein the mold is a metal piece, and increasing the temperature of the mold and/or the cover includes:
    对所述模具通电,以提高所述模具的温度。The mold is energized to increase the temperature of the mold.
  5. 根据权利要求1-4中任一项所述的极片制备方法,其中,所述将活性物料和基材加入到模具的模腔中,包括:The pole piece preparation method according to any one of claims 1-4, wherein adding the active material and the base material into the mold cavity of the mold includes:
    向所述模腔内依次加入所述活性物料和所述基材;Add the active material and the base material sequentially into the mold cavity;
    所述将覆盖件覆盖在所述活性物料和所述基材上,包括:The covering member on the active material and the base material includes:
    将所述覆盖件覆盖在所述基材上。The cover is placed on the substrate.
  6. 根据权利要求1-4中任一项所述的极片制备方法,其中,所述将活性物料和基材加入到模具的模腔中,包括:The pole piece preparation method according to any one of claims 1-4, wherein adding the active material and the base material into the mold cavity of the mold includes:
    向所述模腔内依次加入第一层所述活性物料、所述基材和第二层所述活性物料;Add the first layer of the active material, the base material and the second layer of the active material into the mold cavity in sequence;
    所述将覆盖件覆盖在所述活性物料和所述基材上,包括:The covering member on the active material and the base material includes:
    将所述覆盖件覆盖在第二层所述活性物料上。Cover the second layer of active material with the covering member.
  7. 根据权利要求6所述的极片制备方法,其中,所述模具包括本体和凸出部,所述本体具有所述模腔,所述凸出部凸出于所述模腔的底壁,所述底壁与所述模腔的开口相对;The pole piece preparation method according to claim 6, wherein the mold includes a body and a protruding portion, the body has the mold cavity, and the protruding portion protrudes from the bottom wall of the mold cavity, so The bottom wall is opposite to the opening of the mold cavity;
    所述向所述模腔内依次加入第一层所述活性物料、所述基材和第二层所述活性物料,包括:The step of sequentially adding the first layer of the active material, the base material and the second layer of the active material into the mold cavity includes:
    向所述模腔内依次加入第一层所述活性物料和所述基材;Sequentially adding the first layer of the active material and the base material into the mold cavity;
    将所述覆盖件覆盖在所述基材上;Cover the covering member on the base material;
    向所述覆盖件和/或所述模具施力,通过所述覆盖件和所述模具共同挤压第一层所述活性物料和基材,以使所述凸出部贯穿所述基材;Applying force to the cover and/or the mold, the first layer of the active material and the base material are co-extruded through the cover and the mold, so that the protrusion penetrates the base material;
    向所述模腔内加入第二层所述活性物料。Add a second layer of the active material into the mold cavity.
  8. 一种极片制备装置,包括:A pole piece preparation device, including:
    模具,所述模具设有模腔,所述模腔用于容置活性物料和基材;Mold, the mold is provided with a mold cavity, and the mold cavity is used to accommodate active materials and base materials;
    覆盖件,所述覆盖件被配置为经所述模腔的开口至少部分伸入所述模腔,以与所述模具共同挤压所述活性物料和基材,使所述活性物料与所述基材复合形成极片。Cover, the cover is configured to at least partially extend into the mold cavity through the opening of the mold cavity to co-extrude the active material and the base material with the mold, so that the active material and the The base materials are combined to form pole pieces.
  9. 根据权利要求8所述的极片制备装置,其中,所述模具包括本体和凸出部,所述本体具有所述模腔,所述凸出部凸出于所述模腔的底壁,所述底壁与所述模腔的开口相对,所述凸出部用于在所述活性物料上形成容纳电解液的容置腔。The pole piece preparation device according to claim 8, wherein the mold includes a body and a protruding portion, the body has the mold cavity, and the protruding portion protrudes from the bottom wall of the mold cavity, so The bottom wall is opposite to the opening of the mold cavity, and the protruding portion is used to form a receiving cavity for accommodating electrolyte on the active material.
  10. 根据权利要求9所述的极片制备装置,其中,所述凸出部设有多个,多个所述凸出部间隔设置。The pole piece preparation device according to claim 9, wherein there are a plurality of protruding parts, and the plurality of protruding parts are arranged at intervals.
  11. 根据权利要求9或10所述的极片制备装置,其中,所述覆盖件设有供所述凸出部穿过的避让孔。The pole piece preparation device according to claim 9 or 10, wherein the cover is provided with an escape hole for the protruding portion to pass through.
  12. 根据权利要求8-11中任一项所述的极片制备装置,其中,所述极片制备装置还包括:The pole piece preparation device according to any one of claims 8-11, wherein the pole piece preparation device further includes:
    烘干机构,用于对所述极片进行烘干。A drying mechanism is used to dry the pole piece.
  13. 根据权利要求12所述的极片制备装置,其中,所述烘干机构包括供电机构,所述模具为金属件,所述供电机构用于向所述模具通电,使所述模具升温以烘干所述极片;和/或The pole piece preparation device according to claim 12, wherein the drying mechanism includes a power supply mechanism, the mold is a metal piece, and the power supply mechanism is used to energize the mold to heat the mold for drying. The pole piece; and/or
    所述覆盖件为金属件,所述供电机构用于向所述覆盖件通电,使所述覆盖件升温以烘干所述极片。The cover is a metal piece, and the power supply mechanism is used to energize the cover to heat the cover to dry the pole piece.
  14. 根据权利要求8-13中任一项所述的极片制备装置,其中,所述极片制备装置还包括:The pole piece preparation device according to any one of claims 8-13, wherein the pole piece preparation device further includes:
    加压机构,连接于所述覆盖件,所述加压机构用于向所述覆盖件施加压力,以使所述覆盖件和所述模具共同挤压所述模腔内的所述活性物料和基材。A pressurizing mechanism, connected to the cover, is used to apply pressure to the cover so that the cover and the mold jointly squeeze the active material and the active material in the mold cavity. base material.
  15. 一种极片,包括:A pole piece including:
    基材;base material;
    第一活性物料层,设置于所述基材的厚度方向的一侧,所述第一活性物料层包括背离所述基材的第一表面;A first active material layer is disposed on one side of the substrate in the thickness direction, and the first active material layer includes a first surface facing away from the substrate;
    其中,所述第一表面设有用于容纳电解液的第一容置腔。Wherein, the first surface is provided with a first accommodation cavity for accommodating electrolyte.
  16. 根据权利要求15所述的极片,其中,所述极片还包括:The pole piece according to claim 15, wherein the pole piece further includes:
    第二活性物料层,设置于所述基材的厚度方向的另一侧,所述第二活性物料层包括背离所述基材的第二表面,所述第二表面设有用于容纳电解液的第二容置腔。A second active material layer is disposed on the other side in the thickness direction of the base material. The second active material layer includes a second surface facing away from the base material. The second surface is provided with a hole for accommodating electrolyte. The second accommodation cavity.
  17. 根据权利要求16所述的极片,其中,所述基材设有通孔,所述第一容置腔和所述第二容置腔通过所述通孔相互连通。The pole piece according to claim 16, wherein the base material is provided with a through hole, and the first accommodating cavity and the second accommodating cavity are connected to each other through the through hole.
  18. 根据权利要求16或17所述的极片,其中,所述第二活性物料层的厚度为H1,满足H1≤1500μm,优选地,70μm≤H1≤1500μm。The pole piece according to claim 16 or 17, wherein the thickness of the second active material layer is H1, satisfying H1≤1500 μm, preferably, 70 μm≤H1≤1500 μm.
  19. 根据权利要求16-18中任一项所述的极片,其中,所述第一活性物料层的厚度为H2,满足H2≤1500μm,优选地,70μm≤H2≤1500μm。The pole piece according to any one of claims 16 to 18, wherein the thickness of the first active material layer is H2, satisfying H2≤1500 μm, preferably, 70 μm≤H2≤1500 μm.
  20. 根据权利要求15-19中任一项所述的极片,其中,所述第一活性物料层设有沿第一方向贯穿所述第一活性物料层的安装孔,所述第一方向与所述基材所在平面相交,所述极片还包括:The pole piece according to any one of claims 15 to 19, wherein the first active material layer is provided with a mounting hole penetrating the first active material layer in a first direction, and the first direction is consistent with the first active material layer. The planes where the base materials are located intersect, and the pole pieces also include:
    电能引出部,穿设于所述安装孔,所述电能引出部的一端与所述基材焊接,另一端伸出所述极片的轮廓。An electric energy extraction part is inserted through the mounting hole. One end of the electric energy extraction part is welded to the base material, and the other end extends out of the outline of the pole piece.
  21. 一种电极组件,包括正极极片、负极极片和隔离膜,所述正极极片、所述负极极片和所述隔离膜层叠形成所述电极组件,所述隔离膜设置于所述正极极片和所述负极极片之间;An electrode assembly, including a positive electrode piece, a negative electrode piece and an isolation film. The positive electrode piece, the negative electrode piece and the isolation film are stacked to form the electrode assembly. The isolation film is disposed on the positive electrode. between the plate and the negative electrode plate;
    其中,所述正极极片和所述负极极片中的至少一者为权利要求15-20中任一项所述的极片。Wherein, at least one of the positive electrode piece and the negative electrode piece is the electrode piece according to any one of claims 15-20.
  22. 一种电池单体,包括壳体和权利要求21所述的电极组件,所述电极组件容置于所述壳体内。A battery cell includes a case and an electrode assembly according to claim 21, and the electrode assembly is accommodated in the case.
  23. 一种电池,包括箱体和权利要求22所述的电池单体,所述电池单体容置于所述箱体内。A battery includes a box and the battery cell according to claim 22, and the battery cell is accommodated in the box.
  24. 一种用电装置,包括权利要求22所述的电池单体,所述电池单体用于提供电能。An electrical device, comprising the battery cell according to claim 22, wherein the battery cell is used to provide electrical energy.
PCT/CN2022/109153 2022-07-29 2022-07-29 Plate preparation method, plate preparation device, plate, electrode assembly, battery cell, battery and electric device WO2024021084A1 (en)

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2015195144A (en) * 2014-03-31 2015-11-05 積水化学工業株式会社 Manufacturing method of electrode, manufacturing method of lithium ion secondary battery, and lithium ion secondary battery
CN208706458U (en) * 2018-08-01 2019-04-05 Bgt材料有限公司 The electrode structure of electrochemical energy storage device
CN113394366A (en) * 2021-06-11 2021-09-14 四川无量智慧道桥科技有限公司 Production process and system of high-precision lithium battery pole piece
CN214956959U (en) * 2021-07-12 2021-11-30 四川无量智慧道桥科技有限公司 Lithium battery pole piece die forming and die casting device and die casting system

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2015195144A (en) * 2014-03-31 2015-11-05 積水化学工業株式会社 Manufacturing method of electrode, manufacturing method of lithium ion secondary battery, and lithium ion secondary battery
CN208706458U (en) * 2018-08-01 2019-04-05 Bgt材料有限公司 The electrode structure of electrochemical energy storage device
CN113394366A (en) * 2021-06-11 2021-09-14 四川无量智慧道桥科技有限公司 Production process and system of high-precision lithium battery pole piece
CN214956959U (en) * 2021-07-12 2021-11-30 四川无量智慧道桥科技有限公司 Lithium battery pole piece die forming and die casting device and die casting system

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