WO2024016452A1 - Separator, battery cell, hot-pressing mold, battery, and electric device - Google Patents

Separator, battery cell, hot-pressing mold, battery, and electric device Download PDF

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Publication number
WO2024016452A1
WO2024016452A1 PCT/CN2022/118487 CN2022118487W WO2024016452A1 WO 2024016452 A1 WO2024016452 A1 WO 2024016452A1 CN 2022118487 W CN2022118487 W CN 2022118487W WO 2024016452 A1 WO2024016452 A1 WO 2024016452A1
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WO
WIPO (PCT)
Prior art keywords
adhesive layer
battery
separator
present application
adhesive
Prior art date
Application number
PCT/CN2022/118487
Other languages
French (fr)
Chinese (zh)
Inventor
刘桓基
Original Assignee
宁德时代新能源科技股份有限公司
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Publication of WO2024016452A1 publication Critical patent/WO2024016452A1/en

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C65/00Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor
    • B29C65/48Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor using adhesives, i.e. using supplementary joining material; solvent bonding
    • B29C65/50Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor using adhesives, i.e. using supplementary joining material; solvent bonding using adhesive tape, e.g. thermoplastic tape; using threads or the like
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00Adhesives in the form of films or foils
    • C09J7/20Adhesives in the form of films or foils characterised by their carriers
    • C09J7/29Laminated material
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/05Accumulators with non-aqueous electrolyte
    • H01M10/052Li-accumulators
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/05Accumulators with non-aqueous electrolyte
    • H01M10/054Accumulators with insertion or intercalation of metals other than lithium, e.g. with magnesium or aluminium
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/40Separators; Membranes; Diaphragms; Spacing elements inside cells
    • H01M50/409Separators, membranes or diaphragms characterised by the material
    • H01M50/449Separators, membranes or diaphragms characterised by the material having a layered structure
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

Definitions

  • This application relates to the field of battery technology, and in particular to a separator, a battery cell, a hot pressing mold, a battery and an electrical device.
  • batteries are widely used in electronic equipment, such as mobile phones, laptops, battery cars, electric cars, electric airplanes, electric ships, electric toy cars, electric toy ships, electric toy airplanes, electric tools, etc. .
  • the battery cell includes an anode plate, a separator and a cathode plate.
  • the separator is located between the anode plate and the cathode plate. The separator separates the anode and cathode plates to prevent direct contact between the anode and cathode to cause a short circuit in the battery.
  • the battery will emit heat during use, and the separator will shrink when heated, which can easily cause the positive and negative poles of the battery to come into direct contact and cause a short circuit in the battery.
  • one object of the present application is to provide a separator, a battery cell, a hot-pressing mold, a battery, and an electrical device to solve the problem of a short circuit in the battery caused by thermal shrinkage of the separator.
  • An embodiment of the first aspect of the present application provides a separator.
  • the separator includes: a base material having two first areas and a second area. The second area is located between the two first areas in the width direction of the base material. ;
  • the second adhesive layer is disposed on the two opposite surfaces of each of the two first areas of the base material along the thickness direction. The adhesive force of the second adhesive layer is greater than or equal to 1N/m and less than or equal to 1N/m. Equal to 40N/m.
  • the second adhesive layer on the separator Arrange the second adhesive layer on the separator. After the pole pieces are made, stack or curl the pole pieces.
  • the second adhesive layer on the separator will be laminated. Both surfaces of the base material have the second adhesive layer. This stacking
  • the separators that are together can be bonded together through their own second adhesive layer to fix the separators and avoid battery short circuit due to shrinkage of the separators.
  • the adhesive force of the second adhesive layer is greater than or equal to 1N/m and less than or equal to 40N/m, which ensures the adhesive force of the second adhesive layer and prevents the separator from coming off.
  • the adhesive force of the second adhesive layer is greater than or equal to 5 N/m and less than or equal to 40 N/m.
  • the adhesive force of the second adhesive layer is further limited to ensure the adhesion between the separators and achieve effective fixation of the separators.
  • the width of the second adhesive layer is less than or equal to 20 mm in the width direction of the substrate. Ensure that there is a second adhesive layer on the base material that can be used to fix the diaphragm, and at the same time, avoid the width of the second adhesive layer being too wide, which will affect the size of the diaphragm.
  • the width of the second adhesive layer is greater than or equal to 7 mm and less than or equal to 11 mm in the width direction of the substrate. Further limiting the width of the second adhesive layer not only ensures the fixing effect on the diaphragm, but also avoids affecting the size of the diaphragm.
  • the separator further includes: a first insulating layer disposed on two opposite surfaces of the second region of the substrate along the thickness direction, and the first insulating layer includes adhesive glue and ceramic slurry.
  • the first insulating layer is used to ensure the insulation of the separator and prevent the cathode and anode plates from being in direct contact and causing a battery short circuit.
  • Ceramic slurry is a commonly used insulating material with good insulation properties. The adhesive glue and ceramic slurry are mixed to ensure that the ceramic slurry can be bonded to the base material.
  • the separator further includes: a second insulating layer, which is disposed on two opposite surfaces of the base material in the thickness direction and completely covers both surfaces of the base material. In the thickness direction of the base material, the second insulating layer is located Between the second adhesive layer and the base material, the second insulating layer includes adhesive glue and ceramic slurry.
  • the second insulating layer is used to ensure the insulation of the separator and prevent the cathode and anode plates from being in direct contact and causing a battery short circuit.
  • Ceramic slurry is a commonly used insulating material with good insulation properties. The adhesive glue and ceramic slurry are mixed to ensure that the ceramic slurry can be bonded to the base material.
  • the second embodiment of the present application provides a battery cell.
  • the battery cell includes a pole piece and the separator in the above embodiment.
  • the second adhesive layers of the two separators located on both sides of the same pole piece are fixed together.
  • the separators stacked together can be bonded together through a second adhesive layer to fix the separators.
  • the separator in the battery cell can be effectively fixed.
  • the separator will not shrink, so that the separator can separate the cathode and anode tabs and avoid direct contact between the cathode and anode tabs to cause a battery short circuit.
  • the second adhesive layer fixed together is located on both sides of the active material layer of the pole piece in the width direction of the separator substrate. This prevents the second adhesive layer from affecting the active material layer and thus affecting the performance of the battery.
  • a third embodiment of the present application provides a hot-pressing mold.
  • the hot-pressing mold is used to produce the battery cell in the above embodiment.
  • the hot-pressing mold includes: a first splint; at least two first bumps; at least two first bumps;
  • the first protrusions are all located on the same first surface of the first plywood, and in the width direction of the first plywood, some of the at least two first protrusions are disposed close to a certain side of the first surface, and the other part is disposed close to The other side of the first surface is provided, wherein one side and the other side are opposite sides of the first surface, so that when making the battery cell, the positions of at least two first bumps are in line with the second The position of the adhesive layer corresponds.
  • pressure can be applied to the diaphragm and the pole piece through the first bump on the first plywood.
  • the second adhesive layer on the diaphragm is thermally compounded and bonded together to prevent The diaphragm shrinks at high temperatures.
  • the hot pressing mold further includes: a second plywood, opposite to the first plywood; at least two second protrusions, the at least two second protrusions are located on the same second surface of the second plywood, and the One surface is opposite to the second surface, and the positions of at least two second bumps correspond to the positions of at least two first bumps.
  • the first bump and the second bump on the hot pressing mold simultaneously apply pressure to the diaphragm and the pole piece. Under the action of heat, the second adhesive layer on the diaphragm is thermally compounded and bonded together to prevent the diaphragm from shrinking at high temperatures. .
  • An embodiment of the fourth aspect of the present application provides a battery.
  • the battery includes at least two battery cells in the above embodiment.
  • An embodiment of the fifth aspect of the present application provides an electric device.
  • the electric device includes the battery in the above embodiment, and the battery is used to provide electric energy.
  • Figure 1 is a schematic structural diagram of a vehicle according to some embodiments of the present application.
  • Figure 2 is a schematic diagram of the exploded structure of a battery according to some embodiments of the present application.
  • Figure 3 is a schematic diagram of the exploded structure of a battery cell according to some embodiments of the present application.
  • Figure 4 is a top view of a current collector provided by some embodiments of the present application.
  • Figure 5 is a schematic cross-sectional view of a current collector provided by some embodiments of the present application.
  • Figure 6 is a schematic cross-sectional view of a current collector provided by some embodiments of the present application.
  • Figure 7 is a schematic cross-sectional view of a current collector provided by some embodiments of the present application.
  • Figure 8 is a top view of the pole piece provided by some embodiments of the present application.
  • Figure 9 is a schematic cross-sectional view of a pole piece provided by some embodiments of the present application.
  • Figure 10 is a schematic diagram of the pole piece manufacturing process provided by some embodiments of the present application.
  • Figure 11 is a top view of a separator provided by some embodiments of the present application.
  • Figure 12 is a cross-sectional view of a separator provided by some embodiments of the present application.
  • Figure 13 is a cross-sectional view of a separator provided by some embodiments of the present application.
  • Figure 14 is a cross-sectional view of a pole piece provided by some embodiments of the present application.
  • Figure 15 is a cross-sectional view of a pole piece provided by some embodiments of the present application.
  • Figure 16 is a cross-sectional view of the cooperation between the pole piece and the diaphragm provided by some embodiments of the present application;
  • Figure 17 is a structural diagram of a hot pressing mold provided by some embodiments of the present application.
  • Figure 18 is a structural diagram of the hot pressing mold provided by some embodiments of the present application from another perspective;
  • Figure 19 is a front view of a hot pressing mold provided by some embodiments of the present application.
  • FIG. 20 is a cross-sectional view along the C-C plane in FIG. 19 .
  • an embodiment means that a particular feature, structure or characteristic described in connection with the embodiment can be included in at least one embodiment of the present application.
  • the appearances of this phrase in various places in the specification are not necessarily all referring to the same embodiment, nor are separate or alternative embodiments mutually exclusive of other embodiments. Those skilled in the art understand, both explicitly and implicitly, that the embodiments described herein may be combined with other embodiments.
  • multiple refers to more than two (including two).
  • multiple groups refers to two or more groups (including two groups), and “multiple pieces” refers to It is more than two pieces (including two pieces).
  • Power batteries are not only used in energy storage power systems such as hydropower, thermal power, wind power and solar power stations, but are also widely used in electric vehicles such as electric bicycles, electric motorcycles and electric cars, as well as in many fields such as military equipment and aerospace. . As the application fields of power batteries continue to expand, their market demand is also constantly expanding.
  • the temperature of the battery will increase during use. As the temperature of the battery increases, the battery may short-circuit.
  • a separator is arranged between the anode and cathode tabs in the battery cell. The separator separates the anode and cathode tabs.
  • the temperature of the battery will inevitably increase, and the separator will heat up after being heated. It will shrink. After the separator shrinks, it cannot effectively separate the cathode and anode plates, causing direct contact between the anode and cathode plates, causing the battery to short-circuit.
  • the pole piece includes a current collector and an active material arranged on the current collector.
  • the applicant designed a current collector and a separator after in-depth research, and arranged them on both The first adhesive layer and the second adhesive layer fix the separator through the first adhesive layer or the second adhesive layer. Even if the battery temperature rises, the separator cannot move after being heated, which can effectively separate the cathode plates. and anode plates to avoid battery short circuit due to separator shrinkage.
  • the battery cells disclosed in the embodiments of the present application can be used in, but are not limited to, electrical devices such as vehicles, ships, or aircrafts.
  • the power supply system of the electrical device composed of the battery cells and batteries disclosed in this application can be used to improve the stability of battery performance and battery life.
  • Embodiments of the present application provide an electrical device that uses a battery as a power source.
  • the electrical device may be, but is not limited to, a mobile phone, a tablet, a laptop, an electric toy, an electric tool, a battery car, an electric vehicle, a ship, a spacecraft, etc.
  • electric toys can include fixed or mobile electric toys, such as game consoles, electric car toys, electric ship toys, electric airplane toys, etc.
  • spacecraft can include airplanes, rockets, space shuttles, spaceships, etc.
  • an electric device 1000 according to an embodiment of the present application is used as an example.
  • FIG. 1 is a schematic structural diagram of a vehicle 1000 provided by some embodiments of the present application.
  • the vehicle 1000 may be a fuel vehicle, a gas vehicle or a new energy vehicle, and the new energy vehicle may be a pure electric vehicle, a hybrid vehicle or an extended-range vehicle, etc.
  • the battery 100 is disposed inside the vehicle 1000 , and the battery 100 may be disposed at the bottom, head, or tail of the vehicle 1000 .
  • the battery 100 may be used to power the vehicle 1000 , for example, the battery 100 may serve as an operating power source for the vehicle 1000 .
  • the vehicle 1000 may also include a controller 200 and a motor 300 .
  • the controller 200 is used to control the battery 100 to provide power to the motor 300 , for example, for starting, navigating and driving the vehicle 1000 .
  • the battery 100 can not only be used as an operating power source for the vehicle 1000 , but also can be used as a driving power source for the vehicle 1000 , replacing or partially replacing fuel or natural gas to provide driving power for the vehicle 1000 .
  • FIG. 2 is an exploded view of the battery 100 provided by some embodiments of the present application.
  • the battery 100 includes a case 10 and battery cells 20 , and the battery cells 20 are accommodated in the case 10 .
  • the box 10 is used to provide an accommodation space for the battery cells 20, and the box 10 can adopt a variety of structures.
  • the box 10 may include a first part 101 and a second part 102 , the first part 101 and the second part 102 cover each other, and the first part 101 and the second part 102 jointly define a space for accommodating the battery cells 20 of accommodation space.
  • the second part 102 may be a hollow structure with one end open, and the first part 101 may be a plate-like structure.
  • the first part 101 covers the open side of the second part 102 so that the first part 101 and the second part 102 jointly define a receiving space.
  • the first part 101 and the second part 102 may also be hollow structures with one side open, and the open side of the first part 101 is covered with the open side of the second part 102.
  • the box 10 formed by the first part 101 and the second part 102 can be in various shapes, such as a cylinder, a cuboid, etc.
  • the battery 100 there may be a plurality of battery cells 20, and the plurality of battery cells 20 may be connected in series, in parallel, or in mixed connection.
  • Mixed connection means that the plurality of battery cells 20 are connected in series and in parallel.
  • the plurality of battery cells 20 can be directly connected in series or in parallel or mixed together, and then the whole composed of the plurality of battery cells 20 can be accommodated in the box 10 ; of course, the battery 100 can also be a plurality of battery cells 20 First, the battery modules are connected in series, parallel, or mixed to form a battery module, and then multiple battery modules are connected in series, parallel, or mixed to form a whole, and are accommodated in the box 10 .
  • the battery 100 may also include other structures.
  • the battery 100 may further include a bus component for realizing electrical connections between multiple battery cells 20 .
  • Each battery cell 20 may be a secondary battery or a primary battery; it may also be a lithium-sulfur battery, a sodium-ion battery or a magnesium-ion battery, but is not limited thereto.
  • the battery cell 20 may be in the shape of a cylinder, a flat body, a rectangular parallelepiped or other shapes.
  • FIG. 3 is an exploded structural diagram of a battery cell 20 provided in some embodiments of the present application.
  • the battery cell 20 refers to the smallest unit that constitutes the battery.
  • the battery cell 20 includes an end cover 201 , a housing 202 , a battery cell assembly 203 and other functional components.
  • the end cap 201 refers to a component that covers the opening of the case 202 to isolate the internal environment of the battery cell 20 from the external environment.
  • the shape of the end cap 201 can be adapted to the shape of the housing 202 to fit the housing 202 .
  • the end cap 201 can be made of a material with a certain hardness and strength (such as aluminum alloy). In this way, the end cap 201 is less likely to deform when subjected to extrusion and collision, so that the battery cell 20 can have better performance. With high structural strength, safety performance can also be improved.
  • Functional components such as electrode terminals 2011 may be provided on the end cap 201 .
  • the electrode terminal 2011 may be used to electrically connect with the battery cell assembly 203 for outputting or inputting electrical energy of the battery cell 20 .
  • the end cap 201 may also be provided with a pressure relief mechanism for releasing the internal pressure when the internal pressure or temperature of the battery cell 20 reaches a threshold.
  • the end cap 201 can also be made of various materials, such as copper, iron, aluminum, stainless steel, aluminum alloy, plastic, etc., which are not particularly limited in the embodiment of the present application.
  • an insulating member may also be provided inside the end cover 201, and the insulating member may be used to isolate the electrical connection components in the housing 202 from the end cover 201 to reduce the risk of short circuit.
  • the insulating member may be plastic, rubber, etc.
  • the housing 202 is a component used to cooperate with the end cover 201 to form an internal environment of the battery cell 20 , wherein the formed internal environment can be used to accommodate the battery cell assembly 203 , electrolyte, and other components.
  • the housing 202 and the end cover 201 may be independent components, and an opening may be provided on the housing 202.
  • the end cover 201 covers the opening at the opening to form the internal environment of the battery cell 20.
  • the end cap 201 and the shell 202 can also be integrated. Specifically, the end cap 201 and the shell 202 can form a common connection surface before other components are put into the shell. When it is necessary to encapsulate the inside of the shell 202 When the end cap 201 is closed, the housing 202 is closed.
  • the housing 202 can be of various shapes and sizes, such as rectangular parallelepiped, cylinder, hexagonal prism, etc. Specifically, the shape of the housing 202 can be determined according to the specific shape and size of the battery cell assembly 203 .
  • the housing 202 can be made of a variety of materials, such as copper, iron, aluminum, stainless steel, aluminum alloy, plastic, etc., which are not particularly limited in the embodiment of the present application.
  • the battery cell assembly 203 is a component in the battery cell 20 where electrochemical reactions occur.
  • One or more battery cell assemblies 203 may be contained within the housing 202 .
  • the battery cell assembly 203 is mainly formed by winding or stacking an anode electrode sheet and a cathode electrode sheet, and a separator is usually provided between the anode electrode sheet and the cathode electrode sheet.
  • the portions of the anode and cathode plates that contain active material constitute the main body of the battery cell assembly, and the portions of the anode and cathode plates that do not contain active material each constitute the battery tab 2031 .
  • the anode tab and the cathode tab can be located together at one end of the main body or respectively at both ends of the main body.
  • the anode active material and the cathode active material react with the electrolyte, and the battery tabs 2031 are connected to the electrode terminals to form a current loop.
  • FIG. 4 is a top view of a current collector provided by some embodiments of the present application
  • FIG. 5 is a schematic cross-sectional view of a current collector provided by some embodiments of the present application.
  • the embodiment of the present application provides a current collector 11 including a current collector body 111 and a first adhesive layer 112 .
  • the current collector body 111 has an active material area 1111, a tab area 1112 and a glue coating area 1113.
  • the tab area 1112 is located on one side of the active material area 1111, and the glue coating area 1113 is located between the active material area 1111 and the tab area 1112.
  • the first adhesive layer 112 is disposed in the glue coating area 1113.
  • the adhesive force of the first adhesive layer 112 is greater than or equal to 1 Newton per meter (N/m) and less than or equal to 40 N/m.
  • the first adhesive layer 112 is For bonding to the separator of the battery cell.
  • the current collector 11 refers to a structure or part that collects current.
  • the main function of the current collector 11 is to connect the powdery active materials through coating. , the current generated by the active material is collected and output, and the electrode current is input to the active material.
  • the current collector body 111 is the carrier of the current collector 11, which mainly refers to a metal foil in a lithium-ion battery.
  • the current collector body 111 of the anode plate is usually made of aluminum foil.
  • Aluminum foil has serious corrosion problems at low potentials and is mainly used for anode plates.
  • the current collector body 111 of the cathode plate is usually made of copper foil. Since copper foil is easily oxidized at a higher potential, it is mainly used for cathode plates with lower potential.
  • the active material area 1111 is used for arranging the active material layer 12
  • the glue coating area 1113 is used for arranging the first adhesive layer 112
  • the tab area 1112 is used for arranging the tabs 13 .
  • the active material area 1111 is quadrilateral, and the glue-coating areas 1113 are located on opposite sides of the active material area 1111. That is, the current collector body 111 has two glue-coating areas 1113, one of which is located on the active material area 1113. Between material area 1111 and tab area 1112.
  • the first adhesive layer 112 is located in the glue coating area 1113, that is, the first adhesive layer 112 is located on opposite sides of the active material area 1111.
  • the adhesive force of the first adhesive layer 112 is greater than or equal to 1 N/m and less than or equal to 40N/m, ensuring the adhesive force of the first adhesive layer 112.
  • the adhesive force can be measured by a tensile tester.
  • the first adhesive layer 112 is arranged on the current collector 11, and the current collector 11 is applied to the pole piece 1.
  • the first adhesive layer 112 can be used to The pole piece 1 and the diaphragm 2 are bonded to fix the diaphragm 2. In this way, even if the temperature of the battery rises, when the separator 2 is heated, both sides of the separator 2 are fixed, and the separator 2 will not shrink, so that the separator 2 can separate the cathode pole piece and the anode pole piece, and avoid the cathode pole piece and the anode pole piece. Direct contact causes the battery to short circuit.
  • the adhesive force of the first adhesive layer 112 is greater than or equal to 1 N/m and less than or equal to 40 N/m, ensuring the adhesive force of the first adhesive layer 112 , that is, ensuring that the first adhesive layer 112 and the separator 2 to prevent the first adhesive layer 112 from shrinking too much when heated, causing the diaphragm 2 to detach from the first adhesive layer 112 and failing to fix the diaphragm 2 .
  • the adhesive force of the first adhesive layer 112 is greater than or equal to 5 N/m and less than or equal to 40 N/m.
  • the adhesive force of the first adhesive layer 112 is 5 N/m, or the adhesive force of the first adhesive layer 112 is 10 N/m, or the adhesive force of the first adhesive layer 112 is 20 N/m. , or the adhesive force of the first adhesive layer 112 is 30 N/m, or the adhesive force of the first adhesive layer 112 is 40 N/m.
  • the adhesive force of the first adhesive layer 112 can be other values, which is not limited by this application.
  • the adhesive force of the first adhesive layer 112 is further limited to ensure the adhesion between the first adhesive layer 112 and the separator 2 and achieve effective fixation of the separator 2 .
  • the width L1 (L2) of the first adhesive layer 112 is less than or equal to 20 millimeters (mm).
  • the arrangement direction A of the glue coating area 1113 and the active material area 1111 is also the extending direction of one side of the current collector body 111 .
  • the arrangement direction A of the glue coating area 1113 and the active material area 1111 is the width direction of the current collector body 111.
  • the glue coating area 1113 and the active material area 1111 The arrangement direction A may be the length direction of the current collector body 111 .
  • the width of the first adhesive layer 112 on the side of the current collector 11 where the tab area 1112 is located is L1
  • the width of the first adhesive layer 112 on the side opposite to the tab area 1112 of the current collector 11 is L1.
  • the width is L2. L1 and L2 may or may not be equal.
  • L1 is 8mm and L2 is 10mm; or both L1 and L2 are 12mm.
  • Limiting the width L1 (L2) of the first adhesive layer 112 to less than or equal to 20 mm not only ensures that the first adhesive layer 112 on the current collector 11 can be used to fix the separator 2, but also prevents the width of the first adhesive layer 112 from being too wide. , causing the width of the glue coating area 1113 to be too wide, causing the width of the active material area 1111 to be too narrow, thus affecting the capacitance of the battery cell.
  • the width L1 (L2) of the first adhesive layer 112 is greater than or equal to 7 mm and less than or equal to 11 mm.
  • the width L1 (L2) of the first adhesive layer 112 is 7 mm, or the width L1 (L2) of the first adhesive layer 112 is 8 mm, or the width L1 (L2) of the first adhesive layer 112 is 9 mm. , or the width L1 (L2) of the first adhesive layer 112 is 10 mm, or the width L1 (L2) of the first adhesive layer 112 is 11 mm.
  • the width L1 (L2) of the first adhesive layer 112 can be other values, which is not limited by this application.
  • the width L1 (L2) of the first adhesive layer 112 is further limited to be greater than or equal to 7 mm and less than or equal to 11 mm, which not only ensures the fixation effect of the current collector 11 on the separator 2, but also avoids affecting the capacitance of the battery cells.
  • the material for preparing the first adhesive layer 112 includes adhesive glue, and the ratio of the mass of the adhesive glue to the total mass of the first adhesive layer 112 is greater than or equal to 10% and less than or equal to 50%. .
  • the adhesive glue ensures the adhesive force of the first adhesive layer 112 .
  • the mass of the adhesive glue accounts for 10% of the total mass of the first adhesive layer 112; the mass of the adhesive glue accounts for 20% of the total mass of the first adhesive layer 112; the mass of the adhesive glue accounts for 10% of the total mass of the first adhesive layer 112; The mass of the adhesive layer 112 accounts for 30% of the total mass of the first adhesive layer 112 ; the mass of the adhesive glue accounts for 40% of the total mass of the first adhesive layer 112 ; and the mass of the adhesive glue accounts for 50% of the total mass of the first adhesive layer 112 .
  • the mass proportion of the adhesive glue in the first adhesive layer 112 is increased to ensure the adhesion of the current collector 11 to the separator 2 so that the current collector 11 can effectively fix the separator 2 .
  • Figure 6 is a schematic cross-sectional view of a current collector provided by some embodiments of the present application.
  • the first adhesive layer 112 includes ceramic slurry and adhesive glue; or, Figure 7 is a schematic diagram of the present application. Some embodiments provide a schematic cross-sectional view of a current collector. Refer to FIG. 7 .
  • the first adhesive layer 112 includes a stacked ceramic slurry layer 1121 and an adhesive layer 1122 .
  • the ceramic slurry layer 1121 is located between the current collector body 111 and the adhesive layer 1122 . between the glue layers 1122.
  • the battery capacity loss caused by internal spontaneous reactions is the battery's self-discharge.
  • the battery's self-discharge will cause the battery capacity loss.
  • a layer of ceramic slurry can be applied to the edge of the current collector 11 to reduce battery self-discharge.
  • the ceramic slurry and the adhesive glue are first mixed and then applied on the glue coating area 1113 of the current collector body 111 .
  • the first adhesive layer 112 includes a stacked ceramic slurry layer 1121 and an adhesive glue layer 1122, a layer of ceramic slurry layer 1121 can be first applied to the glue coating area 1113 of the current collector body 111, and then An adhesive layer 1122 is coated on the ceramic slurry layer 1121 .
  • the adhesive glue is evenly distributed in the first adhesive layer 112 to ensure that the first adhesive layer 112 is in contact with the diaphragm 2
  • the adhesion enables the pole piece 1 to effectively fix the diaphragm 2.
  • the first adhesive layer 112 includes a stacked ceramic slurry layer 1121 and an adhesive glue layer 1122, the effect of bonding the separator 2 can be achieved without changing the original formula of the ceramic slurry layer 1121.
  • the adhesive glue includes polyvinylidene fluoride, polyvinylidene fluoride-hexafluoropropylene mixture, polyvinylidene fluoride-chlorotrifluoroethylene mixture, polytetrafluoroethylene, polymethylmethacrylate , at least one of polyacrylonitrile and polyethylene oxide.
  • the adhesive may include one, two, three or even more of the above materials, which is not limited in this application.
  • the adhesive glue includes polyvinylidene fluoride, or the adhesive glue includes polyvinylidene fluoride and a polyvinylidene fluoride-hexafluoropropylene mixture, or the adhesive glue includes polyvinylidene fluoride, polytetrafluoroethylene, polymethylmethacrylate Methyl acrylate, polyacrylonitrile and polyethylene oxide.
  • the adhesive material is made of high-adhesion glue, which reduces the production cost and ensures the adhesion of the first adhesive layer 112 .
  • the present application provides a pole piece 1 .
  • Figure 8 is a top view of a pole piece provided by some embodiments of the present application.
  • Figure 9 is a schematic cross-sectional view of a pole piece provided by some embodiments of the present application.
  • the pole piece 1 includes a current collector 11 and an active material layer 12 and the tab 13, and the current collector 11 is any current collector 11 in the above embodiments.
  • the first adhesive layer 112 of the current collector 11 is located between the active material layer 12 and the tab 13 , and between the active material layer 12 and the tab area 1112 .
  • the active material layer 12 is arranged in the active material area 1111 of the current collector 11; and the tab 13 is arranged in the tab area of the current collector 11.
  • the active material layer 12 is located in the active material area 1111.
  • the active material is a part of the battery constituting materials and directly affects the performance of the battery.
  • the active material layer 12 of the anode plate is composed of adhesive, conductive agent, anode material, etc.; the active material layer 12 of the cathode plate is composed of adhesive, graphite carbon powder, etc.
  • the liquid active material is coated on the current collector 11 , and after drying and solidifying, the active material becomes a solid active material, thereby bonding to the current collector 11 to form the active material layer 12 .
  • the tab 13 is a metal conductor that leads out the cathode and anode from the battery cell.
  • the anode of the battery is made of aluminum material
  • the cathode is made of nickel material
  • the cathode is also made of copper-nickel-plated material. They are made of film and The metal strip is composed of two parts.
  • FIG. 10 is a schematic diagram of the pole piece manufacturing process provided by some embodiments of the present application. As shown in FIG. 4 and FIG. 10 , when making the pole piece 1 , both sides of the current collector 11 have tab areas 1112 . After the active material layer 12 and the first adhesive layer 112 are formed on the current collector body 111 , It will be cut to form pole pieces.
  • cutting is performed along the cutting line B in FIG. 10 , thus forming a pole piece, so as to obtain multiple continuous pole pieces of a battery cell. Since both opposite ends of the pole piece have the first adhesive layer 112, and the first adhesive layer 112 is cut during cutting, it will not affect the active material layer 12 and reduce the occurrence of burrs or burrs on the pole piece 1. bump phenomenon and improve production yield. At the same time, the adhesive glue in the first adhesive layer 112 can ensure that the pole piece 1 can be effectively bonded to the diaphragm 2 .
  • the pole piece 1 provided by the embodiment of the present application can effectively fix the separator 2, avoid battery short circuit caused by the shrinkage of the separator 2, reduce the occurrence of burrs or bumps on the pole piece 1, and improve the production yield.
  • FIG. 11 is a top view of a separator provided by some embodiments of the present application
  • Figure 12 is a cross-sectional view of a separator provided by some embodiments of the present application.
  • the separator 2 includes a base material 21 and a second adhesive layer 22 .
  • the base material 21 has two first regions 211 and one second region 212. In the width direction C of the base material 21, the second region 212 is located between the two first regions 211; the second adhesive layer 22 is provided on The adhesive force of the second adhesive layer 22 on the two first areas 211 of the base material 21 on two opposite surfaces along the thickness direction of each first area 211 is greater than or equal to 1 N/m and less than or equal to 40 N/m.
  • the separator 2 refers to a layer of isolation material between the anode plate and the cathode plate. It is a very critical part of the battery and has a direct impact on the safety and cost of the battery. Its main function is to isolate the anode and cathode and make the electrons in the battery It cannot pass freely, allowing ions in the electrolyte to pass freely between the cathode and anode.
  • the base material 21 is used to support the second adhesive layer 22.
  • the base material 21 can be a single-layer polyethylene, a single-layer polypropylene, a double-layer polyethylene, a double-layer polypropylene, or a multi-layer polyethylene. Multiple layers of polypropylene or laminates of polyethylene and polypropylene.
  • the base material 21 can be made of other materials, which is not limited by this application.
  • the second adhesive layer 22 includes adhesive glue, thereby ensuring the adhesive force of the second adhesive layer 22 .
  • the adhesive glue includes polyvinylidene fluoride, polyvinylidene fluoride-hexafluoropropylene mixture, polyvinylidene fluoride-chlorotrifluoroethylene mixture, polytetrafluoroethylene, polymethylmethacrylate , at least one of polyacrylonitrile and polyethylene oxide.
  • the adhesive may include one, two, three or even more of the above materials, which is not limited in this application.
  • the pole piece 1 is laminated or curled.
  • the second adhesive layer 22 on the diaphragm 2 will be laminated, and both surfaces of the base material 21 have the second adhesive layer.
  • the separators 2 stacked together can be bonded together through their own second adhesive layer 22, thereby fixing the separator 2 and preventing the battery from short-circuiting due to shrinkage of the separator 2.
  • the adhesive force of the second adhesive layer 22 is greater than or equal to 1 N/m and less than or equal to 40 N/m, which ensures the adhesive force of the second adhesive layer 22 and prevents the separator 2 from coming off.
  • the adhesive force of the second adhesive layer 22 is greater than or equal to 5 N/m and less than or equal to 40 N/m.
  • the adhesive force of the second adhesive layer 22 is 5 N/m, or the adhesive force of the second adhesive layer 22 is 10 N/m, or the adhesive force of the second adhesive layer 22 is 20 N/m. , or the adhesive force of the second adhesive layer 22 is 30N/m, or the adhesive force of the second adhesive layer 22 is 40N/m.
  • the adhesive force of the second adhesive layer 22 can be other values, which is not limited by this application.
  • the adhesive force of the second adhesive layer 22 is further limited to ensure the adhesion between the second adhesive layers 22 and achieve effective fixation of the separator 2 .
  • the width L3 (L4) of the second adhesive layer 22 is less than or equal to 20 mm.
  • Limiting the width L3 (L4) of the second adhesive layer 22 to less than or equal to 20 mm not only ensures that the second adhesive layer 22 on the base material 21 can be used to fix the diaphragm 2, but also prevents the width of the second adhesive layer 22 from being too wide. , affecting the size of diaphragm 2.
  • the widths of the second adhesive layer 22 on both sides of the base material 21 are L3 and L4 respectively.
  • L3 and L4 may or may not be equal.
  • L3 is 5mm and L4 is 8mm; or both L3 and L4 are 9mm.
  • the width L3 (L4) of the second adhesive layer 22 is greater than or equal to 7 mm and less than or equal to 11 mm.
  • the width L3 (L4) of the second adhesive layer 22 is 7 mm, or the width L3 (L4) of the second adhesive layer 22 is 8 mm, or the width L3 (L4) of the second adhesive layer 22 is 9 mm. , or the width L3 (L4) of the second adhesive layer 22 is 10 mm, or the width L3 (L4) of the second adhesive layer 22 is 11 mm.
  • the width L3 (L4) of the second adhesive layer 22 can be other values, which is not limited by this application.
  • the width L3 (L4) of the second adhesive layer 22 is further limited to be greater than or equal to 7 mm and less than or equal to 11 mm, which not only ensures the fixing effect on the diaphragm 2, but also prevents the second adhesive layer 22 from being too wide, making the diaphragm 2 occupy less space.
  • the ratio is too large, thus affecting the energy density of the battery.
  • the separator 2 further includes a first insulating layer 23.
  • the first insulating layer 23 is disposed on two opposite surfaces of the second region 212 of the base material 21 along the thickness direction.
  • the first insulating layer 23 23 including adhesive glue and ceramic slurry.
  • the first insulating layer 23 is used to ensure the insulation of the separator 2 and prevent the cathode plate and the anode plate from being in direct contact and causing a short circuit in the battery.
  • Ceramic slurry is a commonly used insulating material with good insulation properties. The adhesive glue and ceramic slurry are mixed to ensure that the ceramic slurry can be bonded to the base material 21 .
  • the second adhesive layer 22 and the first insulating layer 23 are formed in the same layer.
  • the second adhesive layer 22 and the first insulating layer 23 are both made on the base material 21 through a microgravure roller.
  • the area corresponding to the rolling surface of the microgravure roller has the slurry to be coated.
  • the microgravure roller is on the base material. 21. Apply the slurry to the corresponding area after rolling.
  • adhesive glue can be placed in the area corresponding to the first area 211 on the rolling surface of the microgravure roller, and adhesive glue and The mixture of ceramic slurry is then rolled on the substrate 21 by a microgravure roller to form the second adhesive layer 22 and the first insulating layer 23 respectively.
  • the second adhesive layer 22 and the first insulating layer 23 are made in the same layer, which can reduce the number of manufacturing steps and improve work efficiency.
  • FIG. 13 is a cross-sectional view of a separator provided by some embodiments of the present application.
  • the separator 2 further includes a second insulating layer 24 , and the second insulating layer 24 is disposed on the base material 21 along the thickness. The two opposite surfaces in the direction completely cover the two surfaces of the base material 21. In the thickness direction of the base material 21, the second insulating layer 24 is located between the second adhesive layer 22 and the base material 21.
  • the second insulating layer 24 Includes adhesives and ceramic slurries.
  • the second adhesive layer 22 and the second insulating layer 24 can be made in layers. For example, a layer of the second insulating layer 24 is first made on the base material 21 , and then a layer of the second insulating layer 24 is made on the first area 211 of the base material 21 . Two adhesive layers 22.
  • the second insulating layer 24 is used to ensure the insulation of the separator 2 and prevent the cathode plate and the anode plate from being in direct contact and causing a short circuit in the battery.
  • Ceramic slurry is a commonly used insulating material with good insulation properties. The adhesive glue and ceramic slurry are mixed to ensure that the ceramic slurry can be bonded to the base material 21 .
  • the embodiment of the present application provides a battery cell, which includes the pole piece in the above embodiment and/or the separator in the above embodiment.
  • one of the cathode electrode piece and the anode electrode piece of the battery cell adopts the electrode piece in the above embodiment.
  • both the cathode pole piece and the anode pole piece of the battery cell can adopt the pole pieces in the above embodiments.
  • the separator 2 can be effectively fixed. After the separator 2 is heated, the separator 2 will not shrink, so that the separator 2 can separate the cathode pole piece and the anode pole piece, avoiding the cathode pole piece and the anode. Direct contact between the pole pieces causes a short circuit in the battery.
  • Figure 14 is a cross-sectional view of a pole piece provided by some embodiments of the present application. Referring to Figure 14, when the battery cell includes the above-mentioned pole piece 1, the first adhesive layer of the pole piece 1 112 is fixed with diaphragm 2.
  • the pole piece 1 and the separator 2 can be bonded through the first adhesive layer 112 to fix them together to fix the separator 2 .
  • the separator 2 will not shrink, so that the separator 2 can separate the cathode pole piece and the anode pole piece, and avoid the cathode pole piece and the anode pole piece. Direct contact causes the battery to short circuit.
  • Figure 15 is a cross-sectional view of a pole piece provided by some embodiments of the present application.
  • the cathode pole piece 14 and the anode pole piece 15 of the battery cell both adopt the pole pieces in the above embodiments.
  • the separator 2 is located between the cathode pole piece 14 and the anode pole piece 15, and the first adhesive layer 112 of the cathode pole piece 14 and the first adhesive layer 112 of the anode pole piece 15 are both fixed to the separator 2.
  • the first adhesive layer 112 of the cathode plate 14 and the first adhesive layer 112 of the anode plate 15 are both bonded to the separator 2 to increase the fixing effect on the separator 2 .
  • Figure 16 is a cross-sectional view of the cooperation between the pole piece and the separator provided in some embodiments of the present application.
  • the battery cell includes the separator 2 in the above embodiment, it is located on the same pole piece 1
  • the second adhesive layers 22 of the two diaphragms 2 on both sides are fixed together.
  • the second adhesive layer 22 on the separator 2 will be stacked, so that the stacked separators 2 can be bonded together through the second adhesive layer 22 to fix the separator 2. Avoid battery short circuit due to shrinkage of separator 2.
  • the second adhesive layer 22 fixed together is located on both sides of the active material layer 12 of the pole piece 1 in the width direction of the current collector 11 .
  • the second adhesive layer 22 is located on both sides of the active material layer 12 of the pole piece 1 to prevent the second adhesive layer 22 from affecting the active material layer 12 and thereby affecting the performance of the battery.
  • the embodiments of the present application provide a hot-pressing mold 3 for producing battery cells.
  • Figure 17 is a structural diagram of the hot-pressing mold provided by some embodiments of the present application.
  • Figure 18 is a hot-pressing mold provided by some embodiments of the present application.
  • Structural diagram from another perspective Figure 19 is a front view of the hot pressing mold provided by some embodiments of the present application, and
  • Figure 20 is a cross-sectional view of the C-C plane in Figure 19.
  • the hot pressing mold 3 includes a first clamping plate 31 and at least two first bumps 32 .
  • the at least two first bumps 32 are located on the same first surface of the first clamping plate 31 , and in the width direction of the first clamping plate 31 , a part of the at least two first bumps 32 is close to a certain part of the first surface. One side is provided, and the other part is provided close to the other side of the first surface, where one side and the other side are opposite sides of the first surface, so that at least two first protrusions are formed when making the battery cell.
  • the position of the block 32 corresponds to the position of the first adhesive layer 112 .
  • the first clamping plate 31 and the first bump 32 may be integrally formed, or the first bump 32 may be bonded to the first surface of the first clamping plate 31 .
  • the hot-pressing mold 3 includes two first bumps 32 , and the two first bumps 32 are located on opposite sides of the first surface, so that the structure of the hot-pressing mold 3 is simpler.
  • the hot pressing mold 3 may include a plurality of first bumps 32 , and the first bumps 32 located on the same side of the first surface are arranged along the length direction of the first clamping plate 31 .
  • the positions of at least two first bumps 32 correspond to the positions of the first adhesive layer 112 , and the at least two first bumps 32 are To bond the first adhesive layer 112 and the diaphragm 2 together.
  • Pressure can be applied to the diaphragm 2 and the pole piece 1 through the first bump 32 on the first clamping plate 31.
  • the first adhesive layer 112 and the second adhesive layer 22 on the diaphragm 2 are thermally combined and bonded. together to prevent diaphragm 2 from shrinking at high temperatures.
  • the hot pressing mold 3 also includes a second clamping plate 33 and at least two second protrusions 34.
  • the second clamping plate 33 is opposite to the first clamping plate 31; the at least two second protrusions 34 are located on the second plying plate 33.
  • the same second surface of the clamping plate 33 has a one-to-one correspondence with the positions of the at least two second bumps 34 and the positions of the at least two first bumps 32 .
  • the second clamping plate 33 and the second protrusion 34 can be integrally formed, or the second protrusion 34 can be bonded to the second surface of the second plying plate 33 .
  • the hot-pressing mold 3 includes two second bumps 34 , and the two second bumps 34 are located on opposite sides of the second surface, so that the structure of the hot-pressing mold 3 is simpler.
  • the hot pressing mold 3 may include a plurality of second bumps 34 , and the second bumps 34 located on the same side of the second surface are arranged along the length direction of the second clamping plate 33 .
  • the first bump 32 and the second bump 34 on the hot pressing mold 3 simultaneously exert pressure on the separator 2 and the pole piece 1. Under the action of heat, the first adhesive layer 112 and the second adhesive layer 22 on the diaphragm 2 are thermally combined and bonded together to prevent the diaphragm 2 from shrinking at high temperatures.
  • the positions of at least two first bumps 32 correspond to the positions of the second adhesive layer 22 , and the at least two first bumps 32 are The second adhesive layer 22 of the diaphragm 2 is bonded together to prevent the diaphragm 2 from shrinking at high temperature.
  • Embodiments of the present application provide a battery, including at least two battery cells in any embodiment.
  • Batteries can be used in, but are not limited to, mobile phones, tablets, laptops, electric toys, power tools, battery cars, electric vehicles, ships, spacecraft, etc.
  • electric toys can include fixed or mobile electric toys, such as game consoles, electric car toys, electric ship toys, electric airplane toys, etc.
  • spacecraft can include airplanes, rockets, space shuttles, spaceships, etc.
  • the battery cells By using the battery cells in the embodiments of the present disclosure, it can be ensured that the battery 100 is not prone to short circuit and has high safety.
  • Embodiments of the present application provide an electrical device.
  • the electrical device includes a battery in any embodiment, and the battery is used to provide electrical energy.
  • Electric devices can be, but are not limited to, mobile phones, tablets, laptops, electric toys, power tools, battery cars, electric vehicles, ships, spacecraft, etc.
  • electric toys can include fixed or mobile electric toys, such as game consoles, electric car toys, electric ship toys, electric airplane toys, etc.
  • spacecraft can include airplanes, rockets, space shuttles, spaceships, etc.
  • the present application provides a pole piece 1.
  • the pole piece 1 includes a current collector 11, a first adhesive layer 112, an active material layer 12 and a pole tab 13.
  • the current collector 11 includes a current collector body 111.
  • the current collector body 111 has an active material area 1111, a tab area 1112 and a glue coating area 1113.
  • the tab area 1112 is located on one side of the active material area 1111, and the glue application area 1113 is located in the active material area.
  • the first adhesive layer 112 is provided in the glue coating area 1113, and the adhesive force of the first adhesive layer 112 is greater than or Equal to 5N/m and less than or equal to 40N/m.
  • the width of the first adhesive layer 112 is greater than or equal to 7 mm and less than or equal to 11 mm.
  • the first adhesive layer 112 includes adhesive glue, and the ratio of the mass of the adhesive glue to the total mass of the first adhesive layer 112 is greater than or equal to 10% and less than or equal to 50%.
  • the first adhesive layer 112 includes a stacked ceramic slurry layer 1121 and an adhesive layer 1122 .
  • the ceramic slurry layer 1121 is located between the current collector body 111 and the adhesive layer 1122 .
  • the active material layer 12 is disposed in the active material region 1111 of the current collector.
  • the tab 13 is disposed in the tab area 1112 of the current collector. The first adhesive layer 112 of the pole piece 1 and the diaphragm 2 are fixed together.

Abstract

Provided in the present application are a separator, a battery cell, a hot-pressing mold, a battery, and an electric device. The present application belongs to the technical field of batteries. The separator comprises a substrate and second bonding layers. The substrate has two first regions and a second region, wherein in the width direction of the substrate, the second region is located between the two first regions; the second bonding layers are arranged on two opposite surfaces, in a thickness direction, of either of the two first regions of the substrate; and the bonding force of the second bonding layers is greater than or equal to 1 N/m and less than or equal to 40 N/m. The second bonding layers are arranged on the separator; after electrode plates are completely manufactured, the electrode plates are stacked or curled, and thus the second bonding layers on the separator are stacked; and the two surfaces of the substrate are provided with the second bonding layers, so that separators stacked together can be bonded together by means of their own second bonding layers, so as to fix the separators, thus avoiding a battery short circuit caused by shrinkage of the separators.

Description

隔膜、电池单体、热压模具、电池和用电装置Separators, battery cells, hot pressing molds, batteries and electrical devices
交叉引用cross reference
本申请引用于2022年7月19日递交的名称为“隔膜、电池单体、热压模具、电池和用电装置”的第202221853206.5号中国专利申请,其通过引用被全部并入本申请。This application cites Chinese patent application No. 202221853206.5 titled "Separator, Battery Cell, Hot Pressing Mold, Battery and Electrical Device" submitted on July 19, 2022, which is fully incorporated into this application by reference.
技术领域Technical field
本申请涉及电池技术领域,尤其涉及一种隔膜、电池单体、热压模具、电池和用电装置。This application relates to the field of battery technology, and in particular to a separator, a battery cell, a hot pressing mold, a battery and an electrical device.
背景技术Background technique
随着新能源技术的快速发展,电池广泛应用于电子设备,例如手机、笔记本电脑、电瓶车、电动汽车、电动飞机、电动轮船、电动玩具汽车、电动玩具轮船、电动玩具飞机和电动工具等等领域。With the rapid development of new energy technology, batteries are widely used in electronic equipment, such as mobile phones, laptops, battery cars, electric cars, electric airplanes, electric ships, electric toy cars, electric toy ships, electric toy airplanes, electric tools, etc. .
电池的电池单体包括阳极极片、隔膜和阴极极片,隔膜位于阳极极片和阴极极片之间,隔膜将阳极极片和阴极极片隔开,防止阴阳两极直接接触造成电池短路。The battery cell includes an anode plate, a separator and a cathode plate. The separator is located between the anode plate and the cathode plate. The separator separates the anode and cathode plates to prevent direct contact between the anode and cathode to cause a short circuit in the battery.
电池在使用的过程种会散发热量,隔膜受热后会收缩,容易使得电池的阴阳两极直接接触造成电池短路。The battery will emit heat during use, and the separator will shrink when heated, which can easily cause the positive and negative poles of the battery to come into direct contact and cause a short circuit in the battery.
发明内容Contents of the invention
本申请旨在至少解决背景技术中存在的技术问题之一。为此,本申请的一个目的在于提供一种隔膜、电池单体、热压模具、电池和用电装置,以解决隔膜受热收缩而造成电池短路的问题。This application aims to solve at least one of the technical problems existing in the background art. To this end, one object of the present application is to provide a separator, a battery cell, a hot-pressing mold, a battery, and an electrical device to solve the problem of a short circuit in the battery caused by thermal shrinkage of the separator.
本申请第一方面的实施例提供一种隔膜,隔膜包括:基材,具有两个第一区域和一个第二区域,在基材的宽度方向上,第二区域位于两个第一区域之间;第二粘接层,设置于基材的两个第一区域中每一个第一区域沿厚度方向上相对的两表面,第二粘接层的粘接力大于或等于1N/m且小于或等于40N/m。An embodiment of the first aspect of the present application provides a separator. The separator includes: a base material having two first areas and a second area. The second area is located between the two first areas in the width direction of the base material. ; The second adhesive layer is disposed on the two opposite surfaces of each of the two first areas of the base material along the thickness direction. The adhesive force of the second adhesive layer is greater than or equal to 1N/m and less than or equal to 1N/m. Equal to 40N/m.
在隔膜上布置第二粘接层,极片制作完成后,对极片进行层叠或者卷曲,隔膜上的第二粘接层会层叠,基材的两表面均具有第二粘接层,这样堆叠在一起的隔膜可以通过自身的第二粘接层粘接在一起,从而对隔膜进行固定,避免由于隔膜收缩造成电池短路。 第二粘接层的粘接力大于或等于1N/m且小于或等于40N/m,保证了第二粘接层的粘接力,避免隔膜脱开。Arrange the second adhesive layer on the separator. After the pole pieces are made, stack or curl the pole pieces. The second adhesive layer on the separator will be laminated. Both surfaces of the base material have the second adhesive layer. This stacking The separators that are together can be bonded together through their own second adhesive layer to fix the separators and avoid battery short circuit due to shrinkage of the separators. The adhesive force of the second adhesive layer is greater than or equal to 1N/m and less than or equal to 40N/m, which ensures the adhesive force of the second adhesive layer and prevents the separator from coming off.
在一些实施例中,第二粘接层的粘接力大于或等于5N/m且小于或等于40N/m。进一步限定第二粘接层的粘接力,保证了隔膜之间的粘附性,实现对隔膜的有效固定。In some embodiments, the adhesive force of the second adhesive layer is greater than or equal to 5 N/m and less than or equal to 40 N/m. The adhesive force of the second adhesive layer is further limited to ensure the adhesion between the separators and achieve effective fixation of the separators.
在一些实施例中,在基材的宽度方向上,第二粘接层的宽度小于或等于20mm。保证基材上有第二粘接层能够用来固定隔膜,同时避免第二粘接层的宽度太宽,影响隔膜的大小。In some embodiments, the width of the second adhesive layer is less than or equal to 20 mm in the width direction of the substrate. Ensure that there is a second adhesive layer on the base material that can be used to fix the diaphragm, and at the same time, avoid the width of the second adhesive layer being too wide, which will affect the size of the diaphragm.
在一些实施例中,在基材的宽度方向上,第二粘接层的宽度大于或等于7mm且小于或等于11mm。进一步限定第二粘接层的宽度,既保证对隔膜的固定效果,同时避免影响隔膜的大小。In some embodiments, the width of the second adhesive layer is greater than or equal to 7 mm and less than or equal to 11 mm in the width direction of the substrate. Further limiting the width of the second adhesive layer not only ensures the fixing effect on the diaphragm, but also avoids affecting the size of the diaphragm.
在一些实施例中,隔膜还包括:第一绝缘层,设置于基材的第二区域沿厚度方向上相对的两表面,第一绝缘层包括粘接胶和陶瓷浆料。第一绝缘层用于保证隔膜的绝缘性,避免阴极极片和阳极极片直接接触造成电池短路。陶瓷浆料是常用的绝缘材料具有很好的绝缘性,粘接胶和陶瓷浆料混合,保证陶瓷浆料能够粘接在基材上。In some embodiments, the separator further includes: a first insulating layer disposed on two opposite surfaces of the second region of the substrate along the thickness direction, and the first insulating layer includes adhesive glue and ceramic slurry. The first insulating layer is used to ensure the insulation of the separator and prevent the cathode and anode plates from being in direct contact and causing a battery short circuit. Ceramic slurry is a commonly used insulating material with good insulation properties. The adhesive glue and ceramic slurry are mixed to ensure that the ceramic slurry can be bonded to the base material.
在一些实施例中,隔膜还包括:第二绝缘层,设置于基材沿厚度方向上相对的两表面并且全部覆盖基材的两个表面,在基材的厚度方向上,第二绝缘层位于第二粘接层和基材之间,第二绝缘层包括粘接胶和陶瓷浆料。第二绝缘层用于保证隔膜的绝缘性,避免阴极极片和阳极极片直接接触造成电池短路。陶瓷浆料是常用的绝缘材料具有很好的绝缘性,粘接胶和陶瓷浆料混合,保证陶瓷浆料能够粘接在基材上。In some embodiments, the separator further includes: a second insulating layer, which is disposed on two opposite surfaces of the base material in the thickness direction and completely covers both surfaces of the base material. In the thickness direction of the base material, the second insulating layer is located Between the second adhesive layer and the base material, the second insulating layer includes adhesive glue and ceramic slurry. The second insulating layer is used to ensure the insulation of the separator and prevent the cathode and anode plates from being in direct contact and causing a battery short circuit. Ceramic slurry is a commonly used insulating material with good insulation properties. The adhesive glue and ceramic slurry are mixed to ensure that the ceramic slurry can be bonded to the base material.
本申请第二方面的实施例提供一种电池单体,电池单体包括极片和上述实施例中的隔膜,位于同一极片两侧的两个隔膜的第二粘接层固定在一起。The second embodiment of the present application provides a battery cell. The battery cell includes a pole piece and the separator in the above embodiment. The second adhesive layers of the two separators located on both sides of the same pole piece are fixed together.
本申请实施例的技术方案中,堆叠在一起的隔膜可以通过第二粘接层粘接在一起,从而对隔膜进行固定。由此,电池单体中隔膜可以被有效固定,隔膜受热后,隔膜不会收缩,使得隔膜能够将阴极极片和阳极极片隔开,避免阴极极片和阳极极片直接接触造成电池短路。In the technical solution of the embodiment of the present application, the separators stacked together can be bonded together through a second adhesive layer to fix the separators. As a result, the separator in the battery cell can be effectively fixed. When the separator is heated, the separator will not shrink, so that the separator can separate the cathode and anode tabs and avoid direct contact between the cathode and anode tabs to cause a battery short circuit.
在一些实施例中,在隔膜基材的宽度方向上,固定在一起的第二粘接层位于极片的活性物质层的两侧。避免第二粘接层对活性物质层产生影响从而影响电池的性能。In some embodiments, the second adhesive layer fixed together is located on both sides of the active material layer of the pole piece in the width direction of the separator substrate. This prevents the second adhesive layer from affecting the active material layer and thus affecting the performance of the battery.
本申请第三方面的实施例提供一种热压模具,热压模具用于制作上述实施例中的电池单体,热压模具包括:第一夹板;至少两个第一凸块,至少两个第一凸块均位于第一夹板的同一第一表面,并且在第一夹板的宽度方向上,至少两个第一凸块中的其中一部 分靠近第一表面的某一侧边设置,另一部分靠近第一表面的另一侧边设置,其中某一侧边与另一侧边为第一表面的相对两侧边,以使得在制作电池单体时至少两个第一凸块的位置与第二粘接层的位置相对应。A third embodiment of the present application provides a hot-pressing mold. The hot-pressing mold is used to produce the battery cell in the above embodiment. The hot-pressing mold includes: a first splint; at least two first bumps; at least two first bumps; The first protrusions are all located on the same first surface of the first plywood, and in the width direction of the first plywood, some of the at least two first protrusions are disposed close to a certain side of the first surface, and the other part is disposed close to The other side of the first surface is provided, wherein one side and the other side are opposite sides of the first surface, so that when making the battery cell, the positions of at least two first bumps are in line with the second The position of the adhesive layer corresponds.
本申请实施例的技术方案中,可以通过第一夹板上的第一凸块对隔膜与极片施加压力,在热作用下,隔膜上的第二粘接层热复合,粘接在一起,防止隔膜在高温下收缩。In the technical solution of the embodiment of the present application, pressure can be applied to the diaphragm and the pole piece through the first bump on the first plywood. Under the action of heat, the second adhesive layer on the diaphragm is thermally compounded and bonded together to prevent The diaphragm shrinks at high temperatures.
在一些实施例中,热压模具还包括:第二夹板,与第一夹板相对;至少两个第二凸块,至少两个第二凸块均位于第二夹板的同一第二表面,且第一表面和第二表面相对,至少两个第二凸块的位置与至少两个第一凸块的位置一一对应。热压模具上的第一凸块和第二凸块同时对隔膜与极片施加压力,在热作用下,隔膜上的第二粘接层热复合,粘接在一起,防止隔膜在高温下收缩。In some embodiments, the hot pressing mold further includes: a second plywood, opposite to the first plywood; at least two second protrusions, the at least two second protrusions are located on the same second surface of the second plywood, and the One surface is opposite to the second surface, and the positions of at least two second bumps correspond to the positions of at least two first bumps. The first bump and the second bump on the hot pressing mold simultaneously apply pressure to the diaphragm and the pole piece. Under the action of heat, the second adhesive layer on the diaphragm is thermally compounded and bonded together to prevent the diaphragm from shrinking at high temperatures. .
本申请第四方面的实施例提供一种电池,电池包括至少两个上述实施例中的电池单体。An embodiment of the fourth aspect of the present application provides a battery. The battery includes at least two battery cells in the above embodiment.
本申请第五方面的实施例提供一种用电装置,用电装置包括上述实施例中的电池,电池用于提供电能。An embodiment of the fifth aspect of the present application provides an electric device. The electric device includes the battery in the above embodiment, and the battery is used to provide electric energy.
上述说明仅是本申请技术方案的概述,为了能够更清楚了解本申请的技术手段,而可依照说明书的内容予以实施,并且为了让本申请的上述和其它目的、特征和优点能够更明显易懂,以下特举本申请的具体实施方式。The above description is only an overview of the technical solutions of the present application. In order to have a clearer understanding of the technical means of the present application, they can be implemented according to the content of the description, and in order to make the above and other purposes, features and advantages of the present application more obvious and understandable. , the specific implementation methods of the present application are specifically listed below.
附图说明Description of drawings
在附图中,除非另外规定,否则贯穿多个附图相同的附图标记表示相同或相似的部件或元素。这些附图不一定是按照比例绘制的。应该理解,这些附图仅描绘了根据本申请公开的一些实施方式,而不应将其视为是对本申请范围的限制。In the drawings, unless otherwise specified, the same reference numbers refer to the same or similar parts or elements throughout the several figures. The drawings are not necessarily to scale. It should be understood that these drawings depict only some embodiments disclosed in accordance with the present application and should not be considered as limiting the scope of the present application.
为了更清楚地说明本申请实施例的技术方案,下面将对本申请实施例中所需要使用的附图作简单地介绍,显而易见地,下面所描述的附图仅仅是本申请的一些实施例,对于本领域普通技术人员来讲,在不付出创造性劳动的前提下,还可以根据附图获得其他的附图。In order to explain the technical solutions of the embodiments of the present application more clearly, the drawings required to be used in the embodiments of the present application will be briefly introduced below. Obviously, the drawings described below are only some embodiments of the present application. Those of ordinary skill in the art can also obtain other drawings based on the drawings without exerting creative efforts.
图1为本申请一些实施例的车辆的结构示意图;Figure 1 is a schematic structural diagram of a vehicle according to some embodiments of the present application;
图2为本申请一些实施例的电池的分解结构示意图;Figure 2 is a schematic diagram of the exploded structure of a battery according to some embodiments of the present application;
图3为本申请一些实施例的电池单体的分解结构示意图;Figure 3 is a schematic diagram of the exploded structure of a battery cell according to some embodiments of the present application;
图4为本申请一些实施例提供的集流体的俯视图;Figure 4 is a top view of a current collector provided by some embodiments of the present application;
图5为本申请一些实施例提供的集流体的截面示意图;Figure 5 is a schematic cross-sectional view of a current collector provided by some embodiments of the present application;
图6为本申请一些实施例提供的集流体的截面示意图;Figure 6 is a schematic cross-sectional view of a current collector provided by some embodiments of the present application;
图7为本申请一些实施例提供的集流体的截面示意图;Figure 7 is a schematic cross-sectional view of a current collector provided by some embodiments of the present application;
图8为本申请一些实施例提供的极片的俯视图;Figure 8 is a top view of the pole piece provided by some embodiments of the present application;
图9为本申请一些实施例提供的极片的截面示意图;Figure 9 is a schematic cross-sectional view of a pole piece provided by some embodiments of the present application;
图10为本申请一些实施例提供的极片制作过程中示意图;Figure 10 is a schematic diagram of the pole piece manufacturing process provided by some embodiments of the present application;
图11为本申请一些实施例提供的隔膜的俯视图;Figure 11 is a top view of a separator provided by some embodiments of the present application;
图12为本申请一些实施例提供的隔膜的截面图;Figure 12 is a cross-sectional view of a separator provided by some embodiments of the present application;
图13为本申请一些实施例提供的隔膜的截面图;Figure 13 is a cross-sectional view of a separator provided by some embodiments of the present application;
图14为本申请一些实施例提供的极片的截面图;Figure 14 is a cross-sectional view of a pole piece provided by some embodiments of the present application;
图15为本申请一些实施例提供的极片的截面图;Figure 15 is a cross-sectional view of a pole piece provided by some embodiments of the present application;
图16为本申请一些实施例提供的极片与隔膜配合的截面图;Figure 16 is a cross-sectional view of the cooperation between the pole piece and the diaphragm provided by some embodiments of the present application;
图17为本申请一些实施例提供的热压模具的结构图;Figure 17 is a structural diagram of a hot pressing mold provided by some embodiments of the present application;
图18为本申请一些实施例提供的热压模具在另一视角下的结构图;Figure 18 is a structural diagram of the hot pressing mold provided by some embodiments of the present application from another perspective;
图19为本申请一些实施例提供的热压模具的主视图;Figure 19 is a front view of a hot pressing mold provided by some embodiments of the present application;
图20为图19中C-C面的截面图。FIG. 20 is a cross-sectional view along the C-C plane in FIG. 19 .
具体实施方式Detailed ways
下面将结合附图对本申请技术方案的实施例进行详细的描述。以下实施例仅用于更加清楚地说明本申请的技术方案,因此只作为示例,而不能以此来限制本申请的保护范围。The embodiments of the technical solution of the present application will be described in detail below with reference to the accompanying drawings. The following examples are only used to illustrate the technical solution of the present application more clearly, and are therefore only used as examples and cannot be used to limit the protection scope of the present application.
除非另有定义,本文所使用的所有的技术和科学术语与属于本申请的技术领域的技术人员通常理解的含义相同;本文中所使用的术语只是为了描述具体的实施例的目的,不是旨在于限制本申请;本申请的说明书和权利要求书及上述附图说明中的术语“包括”和“具有”以及它们的任何变形,意图在于覆盖不排他的包含。Unless otherwise defined, all technical and scientific terms used herein have the same meanings as commonly understood by those skilled in the technical field belonging to this application; the terms used herein are for the purpose of describing specific embodiments only and are not intended to be used in Limitation of this application; the terms "including" and "having" and any variations thereof in the description and claims of this application and the above description of the drawings are intended to cover non-exclusive inclusion.
在本申请实施例的描述中,技术术语“第一”“第二”等仅用于区别不同对象,而不能理解为指示或暗示相对重要性或者隐含指明所指示的技术特征的数量、特定顺序或主次关系。在本申请实施例的描述中,“多个”的含义是两个以上,除非另有明确具体的限定。In the description of the embodiments of this application, the technical terms "first", "second", etc. are only used to distinguish different objects, and cannot be understood as indicating or implying the relative importance or implicitly indicating the quantity or specificity of the indicated technical features. Sequence or priority relationship. In the description of the embodiments of this application, "plurality" means two or more, unless otherwise explicitly and specifically limited.
在本文中提及“实施例”意味着,结合实施例描述的特定特征、结构或特性可以包含在本申请的至少一个实施例中。在说明书中的各个位置出现该短语并不一定均是指相同 的实施例,也不是与其它实施例互斥的独立的或备选的实施例。本领域技术人员显式地和隐式地理解的是,本文所描述的实施例可以与其它实施例相结合。Reference herein to "an embodiment" means that a particular feature, structure or characteristic described in connection with the embodiment can be included in at least one embodiment of the present application. The appearances of this phrase in various places in the specification are not necessarily all referring to the same embodiment, nor are separate or alternative embodiments mutually exclusive of other embodiments. Those skilled in the art understand, both explicitly and implicitly, that the embodiments described herein may be combined with other embodiments.
在本申请实施例的描述中,术语“和/或”仅仅是一种描述关联对象的关联关系,表示可以存在三种关系,例如A和/或B,可以表示:单独存在A,同时存在A和B,单独存在B这三种情况。另外,本文中字符“/”,一般表示前后关联对象是一种“或”的关系。In the description of the embodiments of this application, the term "and/or" is only an association relationship describing associated objects, indicating that there can be three relationships, such as A and/or B, which can mean: A exists alone, and A exists simultaneously and B, there are three cases of B alone. In addition, the character "/" in this article generally indicates that the related objects are an "or" relationship.
在本申请实施例的描述中,术语“多个”指的是两个以上(包括两个),同理,“多组”指的是两组以上(包括两组),“多片”指的是两片以上(包括两片)。In the description of the embodiments of this application, the term "multiple" refers to more than two (including two). Similarly, "multiple groups" refers to two or more groups (including two groups), and "multiple pieces" refers to It is more than two pieces (including two pieces).
在本申请实施例的描述中,技术术语“中心”、“纵向”、“横向”、“长度”、“宽度”、“厚度”、“上”、“下”、“前”、“后”、“左”、“右”、“竖直”、“水平”、“顶”、“底”、“内”、“外”、“顺时针”、“逆时针”、“轴向”、“径向”、“周向”等指示的方位或位置关系为基于附图所示的方位或位置关系,仅是为了便于描述本申请实施例和简化描述,而不是指示或暗示所指的装置或元件必须具有特定的方位、以特定的方位构造和操作,因此不能理解为对本申请实施例的限制。In the description of the embodiments of this application, the technical terms "center", "longitudinal", "transverse", "length", "width", "thickness", "upper", "lower", "front", "back" , "Left", "Right", "Vertical", "Horizontal", "Top", "Bottom", "Inside", "Outside", "Clockwise", "Counterclockwise", "Axis", " The orientations or positional relationships indicated by "radial", "circumferential", etc. are based on the orientations or positional relationships shown in the drawings. They are only for the convenience of describing the embodiments of the present application and simplifying the description, and are not intended to indicate or imply the devices or devices referred to. Elements must have a specific orientation, be constructed and operate in a specific orientation, and therefore are not to be construed as limitations on the embodiments of the present application.
在本申请实施例的描述中,除非另有明确的规定和限定,技术术语“安装”、“相连”“连接”、“固定”等术语应做广义理解,例如,可以是固定连接,也可以是可拆卸连接,或成一体;也可以是机械连接,也可以是电连接;可以是直接相连,也可以通过中间媒介间接相连,可以是两个元件内部的连通或两个元件的相互作用关系。对于本领域的普通技术人员而言,可以根据具体情况理解上述术语在本申请实施例中的具体含义。In the description of the embodiments of this application, unless otherwise explicitly stated and limited, technical terms such as "installation", "connection", "connection", and "fixing" should be understood in a broad sense. For example, it can be a fixed connection or a fixed connection. It can be detachably connected or integrated; it can also be mechanically connected or electrically connected; it can be directly connected or indirectly connected through an intermediate medium; it can be the internal connection of two elements or the interaction between two elements. . For those of ordinary skill in the art, the specific meanings of the above terms in the embodiments of this application can be understood according to specific circumstances.
目前,从市场形势的发展来看,动力电池的应用越加广泛。动力电池不仅被应用于水力、火力、风力和太阳能电站等储能电源系统,而且还被广泛应用于电动自行车、电动摩托车、电动汽车等电动交通工具,以及军事装备和航空航天等多个领域。随着动力电池应用领域的不断扩大,其市场的需求量也在不断地扩增。At present, judging from the development of the market situation, the application of power batteries is becoming more and more extensive. Power batteries are not only used in energy storage power systems such as hydropower, thermal power, wind power and solar power stations, but are also widely used in electric vehicles such as electric bicycles, electric motorcycles and electric cars, as well as in many fields such as military equipment and aerospace. . As the application fields of power batteries continue to expand, their market demand is also constantly expanding.
本申请人注意到,电池在使用的过程中电池的温度会升高,随着电池温度的升高,电池可能会短路。申请人经过研究发现,在高温状态下,大多数电池的短路是由于电池中的阴极极片和阳极极片直接接触造成的。电池单体中的阳极极片和阴极极片之间布置有隔膜,隔膜将阳极极片和阴极极片隔开,但是随着电池的使用,电池的温度难免会升高,而隔膜在受热后会收缩,隔膜收缩后不能有效地隔开阴极极片和阳极极片,造成阳极极片和阴极极片直接接触,使得电池短路。The applicant noticed that the temperature of the battery will increase during use. As the temperature of the battery increases, the battery may short-circuit. The applicant found through research that at high temperatures, short circuits in most batteries are caused by direct contact between the cathode and anode plates in the battery. A separator is arranged between the anode and cathode tabs in the battery cell. The separator separates the anode and cathode tabs. However, as the battery is used, the temperature of the battery will inevitably increase, and the separator will heat up after being heated. It will shrink. After the separator shrinks, it cannot effectively separate the cathode and anode plates, causing direct contact between the anode and cathode plates, causing the battery to short-circuit.
同时当其中一个电池单体短路后,会造成该短路的电池单体的温度升高,从而影响相邻的电池单体,可能也会造成相邻的电池单体短路,这种现象被成为热扩散。At the same time, when one of the battery cells is short-circuited, the temperature of the short-circuited battery cell will increase, which will affect the adjacent battery cells and may also cause the adjacent battery cells to short-circuit. This phenomenon is called thermal diffusion.
极片包括集流体和设置在集流体上的活性物质,为了缓解电池在高温状态下的短路问题,申请人经过深入研究,设计了一种集流体和一种隔膜,在其二者上分别布置第一粘接层和第二粘接层,通过第一粘接层或者第二粘接层对隔膜进行固定,即使电池温度升高,隔膜受热后也不能移动,可以有效地隔开阴极极片和阳极极片,避免由于隔膜收缩造成的电池短路。The pole piece includes a current collector and an active material arranged on the current collector. In order to alleviate the short circuit problem of the battery at high temperature, the applicant designed a current collector and a separator after in-depth research, and arranged them on both The first adhesive layer and the second adhesive layer fix the separator through the first adhesive layer or the second adhesive layer. Even if the battery temperature rises, the separator cannot move after being heated, which can effectively separate the cathode plates. and anode plates to avoid battery short circuit due to separator shrinkage.
本申请实施例公开的电池单体可以但不限用于车辆、船舶或飞行器等用电装置中。可以使用具备本申请公开的电池单体、电池等组成该用电装置的电源系统,提升电池性能的稳定性和电池寿命。The battery cells disclosed in the embodiments of the present application can be used in, but are not limited to, electrical devices such as vehicles, ships, or aircrafts. The power supply system of the electrical device composed of the battery cells and batteries disclosed in this application can be used to improve the stability of battery performance and battery life.
本申请实施例提供一种使用电池作为电源的用电装置,用电装置可以为但不限于手机、平板、笔记本电脑、电动玩具、电动工具、电瓶车、电动汽车、轮船、航天器等等。其中,电动玩具可以包括固定式或移动式的电动玩具,例如,游戏机、电动汽车玩具、电动轮船玩具和电动飞机玩具等等,航天器可以包括飞机、火箭、航天飞机和宇宙飞船等等。Embodiments of the present application provide an electrical device that uses a battery as a power source. The electrical device may be, but is not limited to, a mobile phone, a tablet, a laptop, an electric toy, an electric tool, a battery car, an electric vehicle, a ship, a spacecraft, etc. Among them, electric toys can include fixed or mobile electric toys, such as game consoles, electric car toys, electric ship toys, electric airplane toys, etc., and spacecraft can include airplanes, rockets, space shuttles, spaceships, etc.
以下实施例为了方便说明,以本申请一实施例的一种用电装置为车辆1000为例进行说明。For the convenience of explanation in the following embodiments, an electric device 1000 according to an embodiment of the present application is used as an example.
请参照图1,图1为本申请一些实施例提供的车辆1000的结构示意图。车辆1000可以为燃油汽车、燃气汽车或新能源汽车,新能源汽车可以是纯电动汽车、混合动力汽车或增程式汽车等。车辆1000的内部设置有电池100,电池100可以设置在车辆1000的底部或头部或尾部。电池100可以用于车辆1000的供电,例如,电池100可以作为车辆1000的操作电源。车辆1000还可以包括控制器200和马达300,控制器200用来控制电池100为马达300供电,例如,用于车辆1000的启动、导航和行驶时的工作用电需求。Please refer to FIG. 1 , which is a schematic structural diagram of a vehicle 1000 provided by some embodiments of the present application. The vehicle 1000 may be a fuel vehicle, a gas vehicle or a new energy vehicle, and the new energy vehicle may be a pure electric vehicle, a hybrid vehicle or an extended-range vehicle, etc. The battery 100 is disposed inside the vehicle 1000 , and the battery 100 may be disposed at the bottom, head, or tail of the vehicle 1000 . The battery 100 may be used to power the vehicle 1000 , for example, the battery 100 may serve as an operating power source for the vehicle 1000 . The vehicle 1000 may also include a controller 200 and a motor 300 . The controller 200 is used to control the battery 100 to provide power to the motor 300 , for example, for starting, navigating and driving the vehicle 1000 .
在本申请一些实施例中,电池100不仅可以作为车辆1000的操作电源,还可以作为车辆1000的驱动电源,代替或部分地代替燃油或天然气为车辆1000提供驱动动力。In some embodiments of the present application, the battery 100 can not only be used as an operating power source for the vehicle 1000 , but also can be used as a driving power source for the vehicle 1000 , replacing or partially replacing fuel or natural gas to provide driving power for the vehicle 1000 .
请参照图2,图2为本申请一些实施例提供的电池100的爆炸图。电池100包括箱体10和电池单体20,电池单体20容纳于箱体10内。其中,箱体10用于为电池单体20提供容纳空间,箱体10可以采用多种结构。在一些实施例中,箱体10可以包括第一部分101和第二部分102,第一部分101与第二部分102相互盖合,第一部分101和第二部分102共同限定出用于容纳电池单体20的容纳空间。第二部分102可以为一端开口的空心结构,第一部分101可以为板状结构,第一部分101盖合于第二部分102的开口侧,以使第一部分101与第二部分102共同限定出容纳空间;第一部分101和第二部分102 也可以是均为一侧开口的空心结构,第一部分101的开口侧盖合于第二部分102的开口侧。当然,第一部分101和第二部分102形成的箱体10可以是多种形状,比如,圆柱体、长方体等。Please refer to FIG. 2 , which is an exploded view of the battery 100 provided by some embodiments of the present application. The battery 100 includes a case 10 and battery cells 20 , and the battery cells 20 are accommodated in the case 10 . Among them, the box 10 is used to provide an accommodation space for the battery cells 20, and the box 10 can adopt a variety of structures. In some embodiments, the box 10 may include a first part 101 and a second part 102 , the first part 101 and the second part 102 cover each other, and the first part 101 and the second part 102 jointly define a space for accommodating the battery cells 20 of accommodation space. The second part 102 may be a hollow structure with one end open, and the first part 101 may be a plate-like structure. The first part 101 covers the open side of the second part 102 so that the first part 101 and the second part 102 jointly define a receiving space. ; The first part 101 and the second part 102 may also be hollow structures with one side open, and the open side of the first part 101 is covered with the open side of the second part 102. Of course, the box 10 formed by the first part 101 and the second part 102 can be in various shapes, such as a cylinder, a cuboid, etc.
在电池100中,电池单体20可以是多个,多个电池单体20之间可串联或并联或混联,混联是指多个电池单体20中既有串联又有并联。多个电池单体20之间可直接串联或并联或混联在一起,再将多个电池单体20构成的整体容纳于箱体10内;当然,电池100也可以是多个电池单体20先串联或并联或混联组成电池模块形式,多个电池模块再串联或并联或混联形成一个整体,并容纳于箱体10内。电池100还可以包括其他结构,例如,该电池100还可以包括汇流部件,用于实现多个电池单体20之间的电连接。In the battery 100, there may be a plurality of battery cells 20, and the plurality of battery cells 20 may be connected in series, in parallel, or in mixed connection. Mixed connection means that the plurality of battery cells 20 are connected in series and in parallel. The plurality of battery cells 20 can be directly connected in series or in parallel or mixed together, and then the whole composed of the plurality of battery cells 20 can be accommodated in the box 10 ; of course, the battery 100 can also be a plurality of battery cells 20 First, the battery modules are connected in series, parallel, or mixed to form a battery module, and then multiple battery modules are connected in series, parallel, or mixed to form a whole, and are accommodated in the box 10 . The battery 100 may also include other structures. For example, the battery 100 may further include a bus component for realizing electrical connections between multiple battery cells 20 .
其中,每个电池单体20可以为二次电池或一次电池;还可以是锂硫电池、钠离子电池或镁离子电池,但不局限于此。电池单体20可呈圆柱体、扁平体、长方体或其它形状等。Each battery cell 20 may be a secondary battery or a primary battery; it may also be a lithium-sulfur battery, a sodium-ion battery or a magnesium-ion battery, but is not limited thereto. The battery cell 20 may be in the shape of a cylinder, a flat body, a rectangular parallelepiped or other shapes.
请参照图3,图3为本申请一些实施例提供的电池单体20的分解结构示意图。电池单体20是指组成电池的最小单元。如图3,电池单体20包括有端盖201、壳体202、电池单体组件203以及其他的功能性部件。Please refer to FIG. 3 , which is an exploded structural diagram of a battery cell 20 provided in some embodiments of the present application. The battery cell 20 refers to the smallest unit that constitutes the battery. As shown in FIG. 3 , the battery cell 20 includes an end cover 201 , a housing 202 , a battery cell assembly 203 and other functional components.
端盖201是指盖合于壳体202的开口处以将电池单体20的内部环境隔绝于外部环境的部件。不限地,端盖201的形状可以与壳体202的形状相适应以配合壳体202。在一些实施例中,端盖201可以由具有一定硬度和强度的材质(如铝合金)制成,这样,端盖201在受挤压碰撞时就不易发生形变,使电池单体20能够具备更高的结构强度,安全性能也可以有所提高。端盖201上可以设置有如电极端子2011等的功能性部件。电极端子2011可以用于与电池单体组件203电连接,以用于输出或输入电池单体20的电能。在一些实施例中,端盖201上还可以设置有用于在电池单体20的内部压力或温度达到阈值时泄放内部压力的泄压机构。端盖201的材质也可以是多种的,比如,铜、铁、铝、不锈钢、铝合金、塑胶等,本申请实施例对此不作特殊限制。在一些实施例中,在端盖201的内侧还可以设置有绝缘件,绝缘件可以用于隔离壳体202内的电连接部件与端盖201,以降低短路的风险。示例性的,绝缘件可以是塑料、橡胶等。The end cap 201 refers to a component that covers the opening of the case 202 to isolate the internal environment of the battery cell 20 from the external environment. Without limitation, the shape of the end cap 201 can be adapted to the shape of the housing 202 to fit the housing 202 . In some embodiments, the end cap 201 can be made of a material with a certain hardness and strength (such as aluminum alloy). In this way, the end cap 201 is less likely to deform when subjected to extrusion and collision, so that the battery cell 20 can have better performance. With high structural strength, safety performance can also be improved. Functional components such as electrode terminals 2011 may be provided on the end cap 201 . The electrode terminal 2011 may be used to electrically connect with the battery cell assembly 203 for outputting or inputting electrical energy of the battery cell 20 . In some embodiments, the end cap 201 may also be provided with a pressure relief mechanism for releasing the internal pressure when the internal pressure or temperature of the battery cell 20 reaches a threshold. The end cap 201 can also be made of various materials, such as copper, iron, aluminum, stainless steel, aluminum alloy, plastic, etc., which are not particularly limited in the embodiment of the present application. In some embodiments, an insulating member may also be provided inside the end cover 201, and the insulating member may be used to isolate the electrical connection components in the housing 202 from the end cover 201 to reduce the risk of short circuit. For example, the insulating member may be plastic, rubber, etc.
壳体202是用于配合端盖201以形成电池单体20的内部环境的组件,其中,形成的内部环境可以用于容纳电池单体组件203、电解液以及其他部件。壳体202和端盖201可以是独立的部件,可以于壳体202上设置开口,通过在开口处使端盖201盖合开口以形成电池单体20的内部环境。不限地,也可以使端盖201和壳体202一体化,具体地, 端盖201和壳体202可以在其他部件入壳前先形成一个共同的连接面,当需要封装壳体202的内部时,再使端盖201盖合壳体202。壳体202可以是多种形状和多种尺寸的,例如长方体形、圆柱体形、六棱柱形等。具体地,壳体202的形状可以根据电池单体组件203的具体形状和尺寸大小来确定。壳体202的材质可以是多种,比如,铜、铁、铝、不锈钢、铝合金、塑胶等,本申请实施例对此不作特殊限制。The housing 202 is a component used to cooperate with the end cover 201 to form an internal environment of the battery cell 20 , wherein the formed internal environment can be used to accommodate the battery cell assembly 203 , electrolyte, and other components. The housing 202 and the end cover 201 may be independent components, and an opening may be provided on the housing 202. The end cover 201 covers the opening at the opening to form the internal environment of the battery cell 20. Without limitation, the end cap 201 and the shell 202 can also be integrated. Specifically, the end cap 201 and the shell 202 can form a common connection surface before other components are put into the shell. When it is necessary to encapsulate the inside of the shell 202 When the end cap 201 is closed, the housing 202 is closed. The housing 202 can be of various shapes and sizes, such as rectangular parallelepiped, cylinder, hexagonal prism, etc. Specifically, the shape of the housing 202 can be determined according to the specific shape and size of the battery cell assembly 203 . The housing 202 can be made of a variety of materials, such as copper, iron, aluminum, stainless steel, aluminum alloy, plastic, etc., which are not particularly limited in the embodiment of the present application.
电池单体组件203是电池单体20中发生电化学反应的部件。壳体202内可以包含一个或更多个电池单体组件203。电池单体组件203主要由阳极极片和阴极极片卷绕或层叠放置形成,并且通常在阳极极片与阴极极片之间设有隔膜。阳极极片和阴极极片具有活性物质的部分构成电池单体组件的主体部,阳极极片和阴极极片不具有活性物质的部分各自构成电池极耳2031。阳极极耳和阴极极耳可以共同位于主体部的一端或是分别位于主体部的两端。在电池的充放电过程中,阳极活性物质和阴极活性物质与电解液发生反应,电池极耳2031连接电极端子以形成电流回路。The battery cell assembly 203 is a component in the battery cell 20 where electrochemical reactions occur. One or more battery cell assemblies 203 may be contained within the housing 202 . The battery cell assembly 203 is mainly formed by winding or stacking an anode electrode sheet and a cathode electrode sheet, and a separator is usually provided between the anode electrode sheet and the cathode electrode sheet. The portions of the anode and cathode plates that contain active material constitute the main body of the battery cell assembly, and the portions of the anode and cathode plates that do not contain active material each constitute the battery tab 2031 . The anode tab and the cathode tab can be located together at one end of the main body or respectively at both ends of the main body. During the charging and discharging process of the battery, the anode active material and the cathode active material react with the electrolyte, and the battery tabs 2031 are connected to the electrode terminals to form a current loop.
根据本申请的一些实施例,请参照图4和图5,图4为本申请一些实施例提供的集流体的俯视图,图5为本申请一些实施例提供的集流体的截面示意图。本申请的实施例提供了一种集流体11,包括集流体本体111和第一粘接层112。其中,集流体本体111具有活性物质区1111、极耳区1112和涂胶区1113,极耳区1112位于活性物质区1111的一侧,涂胶区1113位于活性物质区1111和极耳区1112之间以及活性物质区1111的与极耳区1112相对的另一侧。第一粘接层112设置于涂胶区1113,第一粘接层112的粘接力大于或等于1牛每米(N/m)且小于或等于40N/m,第一粘接层112用于与电池单体的隔膜粘接。According to some embodiments of the present application, please refer to FIGS. 4 and 5 . FIG. 4 is a top view of a current collector provided by some embodiments of the present application, and FIG. 5 is a schematic cross-sectional view of a current collector provided by some embodiments of the present application. The embodiment of the present application provides a current collector 11 including a current collector body 111 and a first adhesive layer 112 . Among them, the current collector body 111 has an active material area 1111, a tab area 1112 and a glue coating area 1113. The tab area 1112 is located on one side of the active material area 1111, and the glue coating area 1113 is located between the active material area 1111 and the tab area 1112. and the other side of the active material region 1111 opposite to the tab region 1112 . The first adhesive layer 112 is disposed in the glue coating area 1113. The adhesive force of the first adhesive layer 112 is greater than or equal to 1 Newton per meter (N/m) and less than or equal to 40 N/m. The first adhesive layer 112 is For bonding to the separator of the battery cell.
在本申请的实施例中,集流体11指汇集电流的结构或零件,将集流体11应用于电池的极片1时,集流体11的作用主要是通过涂覆将粉状的活性物质连接起来,将活性物质产生的电流汇集输出、将电极电流输入给活性物质。In the embodiment of this application, the current collector 11 refers to a structure or part that collects current. When the current collector 11 is applied to the pole piece 1 of the battery, the main function of the current collector 11 is to connect the powdery active materials through coating. , the current generated by the active material is collected and output, and the electrode current is input to the active material.
集流体本体111为集流体11的载体,在锂离子电池上主要指的是金属箔。对于锂电池,阳极极片的集流体本体111通常采用铝箔,铝箔在低电位时腐蚀问题较为严重,主要用于阳极极片。阴极极片的集流体本体111通常采用铜箔,由于铜箔在较高电位时易被氧化,主要用于电位较低的阴极极片。The current collector body 111 is the carrier of the current collector 11, which mainly refers to a metal foil in a lithium-ion battery. For lithium batteries, the current collector body 111 of the anode plate is usually made of aluminum foil. Aluminum foil has serious corrosion problems at low potentials and is mainly used for anode plates. The current collector body 111 of the cathode plate is usually made of copper foil. Since copper foil is easily oxidized at a higher potential, it is mainly used for cathode plates with lower potential.
活性物质区1111用于布置活性物质层12,涂胶区1113用于布置第一粘接层112,极耳区1112用于设置极耳13。在本申请实施例中,活性物质区1111为四边形,涂胶区 1113位于活性物质区1111的相对两侧,也即集流体本体111具有两个涂胶区1113,其中一个涂胶区1113位于活性物质区1111和极耳区1112之间。The active material area 1111 is used for arranging the active material layer 12 , the glue coating area 1113 is used for arranging the first adhesive layer 112 , and the tab area 1112 is used for arranging the tabs 13 . In the embodiment of the present application, the active material area 1111 is quadrilateral, and the glue-coating areas 1113 are located on opposite sides of the active material area 1111. That is, the current collector body 111 has two glue-coating areas 1113, one of which is located on the active material area 1113. Between material area 1111 and tab area 1112.
第一粘接层112位于涂胶区1113,也即第一粘接层112位于活性物质区1111的相对两侧,第一粘接层112的粘接力大于或等于1N/m且小于或等于40N/m,保证了第一粘接层112的粘接力。The first adhesive layer 112 is located in the glue coating area 1113, that is, the first adhesive layer 112 is located on opposite sides of the active material area 1111. The adhesive force of the first adhesive layer 112 is greater than or equal to 1 N/m and less than or equal to 40N/m, ensuring the adhesive force of the first adhesive layer 112.
在本申请实施例中,粘接力可以通过拉力测试仪测量得到。In the embodiment of the present application, the adhesive force can be measured by a tensile tester.
在本申请实施例中,在集流体11上布置第一粘接层112,将该集流体11应用于极片1,在组装极片1和隔膜2时,可以通过第一粘接层112将极片1与隔膜2粘接起来,对隔膜2进行固定。这样即使电池的温度升高,隔膜2受热时,隔膜2的两侧被固定,隔膜2不会收缩,使得隔膜2能够将阴极极片和阳极极片隔开,避免阴极极片和阳极极片直接接触造成电池短路。同时第一粘接层112的粘接力大于或等于1N/m且小于或等于40N/m,保证了第一粘接层112的粘接力,也即保证了第一粘接层112与隔膜2之间的粘附性,避免第一粘接层112受热时的收缩力过大,使得隔膜2与第一粘接层112脱开,无法达到对隔膜2的固定作用。In the embodiment of the present application, the first adhesive layer 112 is arranged on the current collector 11, and the current collector 11 is applied to the pole piece 1. When assembling the pole piece 1 and the separator 2, the first adhesive layer 112 can be used to The pole piece 1 and the diaphragm 2 are bonded to fix the diaphragm 2. In this way, even if the temperature of the battery rises, when the separator 2 is heated, both sides of the separator 2 are fixed, and the separator 2 will not shrink, so that the separator 2 can separate the cathode pole piece and the anode pole piece, and avoid the cathode pole piece and the anode pole piece. Direct contact causes the battery to short circuit. At the same time, the adhesive force of the first adhesive layer 112 is greater than or equal to 1 N/m and less than or equal to 40 N/m, ensuring the adhesive force of the first adhesive layer 112 , that is, ensuring that the first adhesive layer 112 and the separator 2 to prevent the first adhesive layer 112 from shrinking too much when heated, causing the diaphragm 2 to detach from the first adhesive layer 112 and failing to fix the diaphragm 2 .
根据本申请的一些实施例,第一粘接层112的粘接力大于或等于5N/m且小于或等于40N/m。According to some embodiments of the present application, the adhesive force of the first adhesive layer 112 is greater than or equal to 5 N/m and less than or equal to 40 N/m.
示例性地,第一粘接层112的粘接力为5N/m,或者第一粘接层112的粘接力为10N/m,或者第一粘接层112的粘接力为20N/m,或者第一粘接层112的粘接力为30N/m,或者第一粘接层112的粘接力为40N/m。For example, the adhesive force of the first adhesive layer 112 is 5 N/m, or the adhesive force of the first adhesive layer 112 is 10 N/m, or the adhesive force of the first adhesive layer 112 is 20 N/m. , or the adhesive force of the first adhesive layer 112 is 30 N/m, or the adhesive force of the first adhesive layer 112 is 40 N/m.
在其他实现方式中,第一粘接层112的粘接力可以为其他值,本申请对此不作限制。In other implementations, the adhesive force of the first adhesive layer 112 can be other values, which is not limited by this application.
进一步限定第一粘接层112的粘接力,保证了第一粘接层112与隔膜2之间的粘附性,实现对隔膜2的有效固定。The adhesive force of the first adhesive layer 112 is further limited to ensure the adhesion between the first adhesive layer 112 and the separator 2 and achieve effective fixation of the separator 2 .
根据本申请的一些实施例,在涂胶区1113和活性物质区1111的排布方向A上,第一粘接层112的宽度L1(L2)小于或等于20毫米(mm)。According to some embodiments of the present application, in the arrangement direction A of the glue coating area 1113 and the active material area 1111, the width L1 (L2) of the first adhesive layer 112 is less than or equal to 20 millimeters (mm).
涂胶区1113和活性物质区1111的排布方向A也为集流体本体111其中一条侧边的延伸方向。在本申请实施例的一种实现方式中,涂胶区1113和活性物质区1111的排布方向A为集流体本体111的宽度方向,在其他实现方式中,涂胶区1113和活性物质区1111的排布方向A可以为集流体本体111的长度方向。The arrangement direction A of the glue coating area 1113 and the active material area 1111 is also the extending direction of one side of the current collector body 111 . In one implementation of the embodiment of the present application, the arrangement direction A of the glue coating area 1113 and the active material area 1111 is the width direction of the current collector body 111. In other implementations, the glue coating area 1113 and the active material area 1111 The arrangement direction A may be the length direction of the current collector body 111 .
在本申请实施例中,在集流体11的极耳区1112所在的一侧的第一粘接层112的宽度为L1,在集流体11的极耳区1112相对侧的第一粘接层112的宽度为L2。L1和L2可以相等也可以不相等。In the embodiment of the present application, the width of the first adhesive layer 112 on the side of the current collector 11 where the tab area 1112 is located is L1, and the width of the first adhesive layer 112 on the side opposite to the tab area 1112 of the current collector 11 is L1. The width is L2. L1 and L2 may or may not be equal.
示例性地,L1为8mm,L2为10mm;或者L1和L2均为12mm。For example, L1 is 8mm and L2 is 10mm; or both L1 and L2 are 12mm.
限定第一粘接层112的宽度L1(L2)小于或等于20mm,既保证集流体11上有第一粘接层112能够用来固定隔膜2,同时避免第一粘接层112的宽度太宽,使得涂胶区1113的宽度太宽,造成活性物质区1111的宽度太窄,从而影响电池单体的电容量。Limiting the width L1 (L2) of the first adhesive layer 112 to less than or equal to 20 mm not only ensures that the first adhesive layer 112 on the current collector 11 can be used to fix the separator 2, but also prevents the width of the first adhesive layer 112 from being too wide. , causing the width of the glue coating area 1113 to be too wide, causing the width of the active material area 1111 to be too narrow, thus affecting the capacitance of the battery cell.
根据本申请的一些实施例,在涂胶区1113和活性物质区1111的排布方向A上,第一粘接层112的宽度L1(L2)大于或等于7mm且小于或等于11mm。According to some embodiments of the present application, in the arrangement direction A of the glue coating area 1113 and the active material area 1111, the width L1 (L2) of the first adhesive layer 112 is greater than or equal to 7 mm and less than or equal to 11 mm.
示例性地,第一粘接层112的宽度L1(L2)为7mm,或者第一粘接层112的宽度L1(L2)为8mm,或者第一粘接层112的宽度L1(L2)为9mm,或者第一粘接层112的宽度L1(L2)为10mm,或者第一粘接层112的宽度L1(L2)为11mm。For example, the width L1 (L2) of the first adhesive layer 112 is 7 mm, or the width L1 (L2) of the first adhesive layer 112 is 8 mm, or the width L1 (L2) of the first adhesive layer 112 is 9 mm. , or the width L1 (L2) of the first adhesive layer 112 is 10 mm, or the width L1 (L2) of the first adhesive layer 112 is 11 mm.
在其他实现方式中,第一粘接层112的宽度L1(L2)可以为其他数值,本申请对此不作限制。In other implementations, the width L1 (L2) of the first adhesive layer 112 can be other values, which is not limited by this application.
进一步限定第一粘接层112的宽度L1(L2)大于或等于7mm且小于或等于11mm,既保证集流体11对隔膜2的固定效果,同时避免影响电池单体的电容量。The width L1 (L2) of the first adhesive layer 112 is further limited to be greater than or equal to 7 mm and less than or equal to 11 mm, which not only ensures the fixation effect of the current collector 11 on the separator 2, but also avoids affecting the capacitance of the battery cells.
根据本申请的一些实施例,制备第一粘接层112的材料包括粘接胶,粘接胶的质量与第一粘接层112的总质量的比值大于或等于10%且小于或等于50%。According to some embodiments of the present application, the material for preparing the first adhesive layer 112 includes adhesive glue, and the ratio of the mass of the adhesive glue to the total mass of the first adhesive layer 112 is greater than or equal to 10% and less than or equal to 50%. .
粘接胶保证了第一粘接层112的粘接力。The adhesive glue ensures the adhesive force of the first adhesive layer 112 .
示例性地,粘接胶的质量占第一粘接层112的总质量的10%;粘接胶的质量占第一粘接层112的总质量的20%;粘接胶的质量占第一粘接层112的总质量的30%;粘接胶的质量占第一粘接层112的总质量的40%;粘接胶的质量占第一粘接层112的总质量的50%。For example, the mass of the adhesive glue accounts for 10% of the total mass of the first adhesive layer 112; the mass of the adhesive glue accounts for 20% of the total mass of the first adhesive layer 112; the mass of the adhesive glue accounts for 10% of the total mass of the first adhesive layer 112; The mass of the adhesive layer 112 accounts for 30% of the total mass of the first adhesive layer 112 ; the mass of the adhesive glue accounts for 40% of the total mass of the first adhesive layer 112 ; and the mass of the adhesive glue accounts for 50% of the total mass of the first adhesive layer 112 .
在本申请的实施例中,提高第一粘接层112中粘接胶的质量占比,保证集流体11对隔膜2的粘附性,使得集流体11能够对隔膜2进行有效固定。In the embodiment of the present application, the mass proportion of the adhesive glue in the first adhesive layer 112 is increased to ensure the adhesion of the current collector 11 to the separator 2 so that the current collector 11 can effectively fix the separator 2 .
根据本申请的一些实施例,图6为本申请一些实施例提供的集流体的截面示意图,参见图6,第一粘接层112包括陶瓷浆料和粘接胶;或者,图7为本申请一些实施例提供的集流体的截面示意图,参见图7,第一粘接层112包括层叠设置的陶瓷浆料层1121和粘接胶层1122,陶瓷浆料层1121位于集流体本体111和粘接胶层1122之间。According to some embodiments of the present application, Figure 6 is a schematic cross-sectional view of a current collector provided by some embodiments of the present application. Referring to Figure 6 , the first adhesive layer 112 includes ceramic slurry and adhesive glue; or, Figure 7 is a schematic diagram of the present application. Some embodiments provide a schematic cross-sectional view of a current collector. Refer to FIG. 7 . The first adhesive layer 112 includes a stacked ceramic slurry layer 1121 and an adhesive layer 1122 . The ceramic slurry layer 1121 is located between the current collector body 111 and the adhesive layer 1122 . between the glue layers 1122.
电池在不与外电路连接时,由内部自发反应引起的电池容量损失为电池的自放电,电池的自放电会造成了电池容量损失。在生产极片1的过程中,可以在集流体11的边缘涂一层陶瓷浆料,可以减小电池自放电现象。When the battery is not connected to an external circuit, the battery capacity loss caused by internal spontaneous reactions is the battery's self-discharge. The battery's self-discharge will cause the battery capacity loss. During the production of the pole piece 1, a layer of ceramic slurry can be applied to the edge of the current collector 11 to reduce battery self-discharge.
当第一粘接层112包括陶瓷浆料和粘接胶时,陶瓷浆料和粘接胶先混合,然后再涂敷在集流体本体111的涂胶区1113上。当第一粘接层112包括层叠设置的陶瓷浆料层1121和粘接胶层1122时,可以先在在集流体本体111的涂胶区1113上涂敷一层陶瓷浆料层1121,然后在陶瓷浆料层1121上涂敷一层粘接胶层1122。When the first adhesive layer 112 includes ceramic slurry and adhesive glue, the ceramic slurry and the adhesive glue are first mixed and then applied on the glue coating area 1113 of the current collector body 111 . When the first adhesive layer 112 includes a stacked ceramic slurry layer 1121 and an adhesive glue layer 1122, a layer of ceramic slurry layer 1121 can be first applied to the glue coating area 1113 of the current collector body 111, and then An adhesive layer 1122 is coated on the ceramic slurry layer 1121 .
在本申请的实施例中,当第一粘接层112包括陶瓷浆料和粘接胶时,使得第一粘接层112中均匀分布有粘接胶,保证第一粘接层112对隔膜2的粘附性,使得极片1能够对隔膜2进行有效固定。当第一粘接层112包括层叠设置的陶瓷浆料层1121和粘接胶层1122时,既不会改变原有的陶瓷浆料层1121的配方也能达到粘接隔膜2的效果。In the embodiment of the present application, when the first adhesive layer 112 includes ceramic slurry and adhesive glue, the adhesive glue is evenly distributed in the first adhesive layer 112 to ensure that the first adhesive layer 112 is in contact with the diaphragm 2 The adhesion enables the pole piece 1 to effectively fix the diaphragm 2. When the first adhesive layer 112 includes a stacked ceramic slurry layer 1121 and an adhesive glue layer 1122, the effect of bonding the separator 2 can be achieved without changing the original formula of the ceramic slurry layer 1121.
根据本申请的一些实施例,粘接胶包括聚偏氟乙烯、聚偏氟乙烯-六氟丙烯混合物、聚偏氟乙烯-氯代三氟乙烯混合物、聚四氟乙烯、聚甲基丙烯酸甲酯、聚丙烯腈和聚氧化乙烯中的至少一种。According to some embodiments of the present application, the adhesive glue includes polyvinylidene fluoride, polyvinylidene fluoride-hexafluoropropylene mixture, polyvinylidene fluoride-chlorotrifluoroethylene mixture, polytetrafluoroethylene, polymethylmethacrylate , at least one of polyacrylonitrile and polyethylene oxide.
粘接胶可以包括以上材料中的一种、两种、三种甚至更多,本申请对此不做限制。The adhesive may include one, two, three or even more of the above materials, which is not limited in this application.
示例性地,粘接胶包括聚偏氟乙烯,或者粘接胶包括聚偏氟乙烯和聚偏氟乙烯-六氟丙烯混合物,或者粘接胶包括聚偏氟乙烯、聚四氟乙烯、聚甲基丙烯酸甲酯、聚丙烯腈和聚氧化乙烯。Exemplarily, the adhesive glue includes polyvinylidene fluoride, or the adhesive glue includes polyvinylidene fluoride and a polyvinylidene fluoride-hexafluoropropylene mixture, or the adhesive glue includes polyvinylidene fluoride, polytetrafluoroethylene, polymethylmethacrylate Methyl acrylate, polyacrylonitrile and polyethylene oxide.
聚偏氟乙烯、聚偏氟乙烯-六氟丙烯混合物、聚偏氟乙烯-氯代三氟乙烯混合物、聚四氟乙烯、聚甲基丙烯酸甲酯、聚丙烯腈和聚氧化乙烯都是容易获得的粘接胶材质,且粘附性较高,降低制作成本,且保证第一粘接层112的粘附性。Polyvinylidene fluoride, polyvinylidene fluoride-hexafluoropropylene mixtures, polyvinylidene fluoride-chlorotrifluoroethylene mixtures, polytetrafluoroethylene, polymethyl methacrylate, polyacrylonitrile and polyethylene oxide are all readily available The adhesive material is made of high-adhesion glue, which reduces the production cost and ensures the adhesion of the first adhesive layer 112 .
根据本申请的一些实施例,本申请提供了一种极片1。图8为本申请一些实施例提供的极片的俯视图,图9为本申请一些实施例提供的极片的截面示意图,参照图8和图9,极片1包括集流体11、活性物质层12和极耳13,集流体11为上述实施例中任意一个集流体11。在活性物质区1111、涂胶区1113和极耳区1112的排布方向上,集流体11的第一粘接层112位于活性物质层12和极耳13之间,以及活性物质层12的与极耳13相对的一侧;活性物质层12设置于集流体11的活性物质区1111;极耳13设置于集流体11的极耳区。According to some embodiments of the present application, the present application provides a pole piece 1 . Figure 8 is a top view of a pole piece provided by some embodiments of the present application. Figure 9 is a schematic cross-sectional view of a pole piece provided by some embodiments of the present application. Referring to Figures 8 and 9 , the pole piece 1 includes a current collector 11 and an active material layer 12 and the tab 13, and the current collector 11 is any current collector 11 in the above embodiments. In the arrangement direction of the active material area 1111 , the glue coating area 1113 and the tab area 1112 , the first adhesive layer 112 of the current collector 11 is located between the active material layer 12 and the tab 13 , and between the active material layer 12 and the tab area 1112 . On the opposite side of the tab 13; the active material layer 12 is arranged in the active material area 1111 of the current collector 11; and the tab 13 is arranged in the tab area of the current collector 11.
活性物质层12位于活性物质区1111,活性物质是电池构成材料的一部分,直接影响着电池的性能。阳极极片的活性物质层12由粘合剂、导电剂、阳极材料等组成;阴极 极片的活性物质层12则由粘合剂、石墨碳粉等组成。液体的活性物质涂敷在集流体11上,待活性物质干燥固化后变成固体的活性物质,从而粘接在集流体11上形成活性物质层12。The active material layer 12 is located in the active material area 1111. The active material is a part of the battery constituting materials and directly affects the performance of the battery. The active material layer 12 of the anode plate is composed of adhesive, conductive agent, anode material, etc.; the active material layer 12 of the cathode plate is composed of adhesive, graphite carbon powder, etc. The liquid active material is coated on the current collector 11 , and after drying and solidifying, the active material becomes a solid active material, thereby bonding to the current collector 11 to form the active material layer 12 .
极耳13是从电池单体中将阴阳极引出来的金属导电体,在一些实施例中,电池的阳极使用铝材料,阴极使用镍材料,阴极也有铜镀镍材料,它们都是由胶片和金属带两部分复合而成。The tab 13 is a metal conductor that leads out the cathode and anode from the battery cell. In some embodiments, the anode of the battery is made of aluminum material, the cathode is made of nickel material, and the cathode is also made of copper-nickel-plated material. They are made of film and The metal strip is composed of two parts.
图10为本申请一些实施例提供的极片制作过程中示意图。结合图4和图10所示,在制作极片1时,集流体11的两侧均具有极耳区1112,在集流体本体111上制作完活性物质层12和第一粘接层112后,会对其进行切割,形成极片。Figure 10 is a schematic diagram of the pole piece manufacturing process provided by some embodiments of the present application. As shown in FIG. 4 and FIG. 10 , when making the pole piece 1 , both sides of the current collector 11 have tab areas 1112 . After the active material layer 12 and the first adhesive layer 112 are formed on the current collector body 111 , It will be cut to form pole pieces.
在本申请的实施例中,沿着图10中的切割线B进行切割,这样就会形成一个极片,以分割得到一个电池单体的多个连续极片。由于极片的相对两端均具有第一粘接层112,且在切割时是对第一粘接层112进行切割的,不会对活性物质层12造成影响,减少极片1上出现毛刺或者凸点的现象,提高生产良率。同时第一粘接层112中的粘接胶可以保证极片1能够与隔膜2进行有效的粘接。In the embodiment of the present application, cutting is performed along the cutting line B in FIG. 10 , thus forming a pole piece, so as to obtain multiple continuous pole pieces of a battery cell. Since both opposite ends of the pole piece have the first adhesive layer 112, and the first adhesive layer 112 is cut during cutting, it will not affect the active material layer 12 and reduce the occurrence of burrs or burrs on the pole piece 1. bump phenomenon and improve production yield. At the same time, the adhesive glue in the first adhesive layer 112 can ensure that the pole piece 1 can be effectively bonded to the diaphragm 2 .
本申请实施例提供的极片1能够对隔膜2进行有效固定,避免隔膜2收缩造成的电池短路,同时减少极片1上出现毛刺或者凸点的现象,提高生产良率。The pole piece 1 provided by the embodiment of the present application can effectively fix the separator 2, avoid battery short circuit caused by the shrinkage of the separator 2, reduce the occurrence of burrs or bumps on the pole piece 1, and improve the production yield.
参照图11和图12,图11为本申请一些实施例提供的隔膜的俯视图,图12为本申请一些实施例提供的隔膜的截面图。隔膜2包括基材21和第二粘接层22。基材21,具有两个第一区域211和一个第二区域212,在基材21的宽度方向C上,第二区域212位于两个第一区域211之间;第二粘接层22设置于基材21的两个第一区域211中每一个第一区域211沿厚度方向上相对的两表面,第二粘接层22的粘接力大于或等于1N/m且小于或等于40N/m。Referring to Figures 11 and 12, Figure 11 is a top view of a separator provided by some embodiments of the present application, and Figure 12 is a cross-sectional view of a separator provided by some embodiments of the present application. The separator 2 includes a base material 21 and a second adhesive layer 22 . The base material 21 has two first regions 211 and one second region 212. In the width direction C of the base material 21, the second region 212 is located between the two first regions 211; the second adhesive layer 22 is provided on The adhesive force of the second adhesive layer 22 on the two first areas 211 of the base material 21 on two opposite surfaces along the thickness direction of each first area 211 is greater than or equal to 1 N/m and less than or equal to 40 N/m.
隔膜2是指在阳极极片和阴极极片之间一层隔离材料,是电池中非常关键的部分,对电池安全性和成本有直接影响,其主要作用是隔离阳极阴极并使电池内的电子不能自由穿过,让电解液中的离子在阴极和阳极之间自由通过。The separator 2 refers to a layer of isolation material between the anode plate and the cathode plate. It is a very critical part of the battery and has a direct impact on the safety and cost of the battery. Its main function is to isolate the anode and cathode and make the electrons in the battery It cannot pass freely, allowing ions in the electrolyte to pass freely between the cathode and anode.
基材21用于支撑第二粘接层22,在本申请实施例中,基材21可以为单层聚乙烯、单层聚丙烯、双层聚乙烯、双层聚丙烯、多层聚乙烯、多层聚丙烯或者聚乙烯和聚丙烯叠层。The base material 21 is used to support the second adhesive layer 22. In the embodiment of the present application, the base material 21 can be a single-layer polyethylene, a single-layer polypropylene, a double-layer polyethylene, a double-layer polypropylene, or a multi-layer polyethylene. Multiple layers of polypropylene or laminates of polyethylene and polypropylene.
在其他实现方式中,基材21可以为其他材质,本申请对此不作限制。In other implementations, the base material 21 can be made of other materials, which is not limited by this application.
在本申请实施例中,第二粘接层22中包括粘接胶,从而保证第二粘接层22的粘接力。In the embodiment of the present application, the second adhesive layer 22 includes adhesive glue, thereby ensuring the adhesive force of the second adhesive layer 22 .
根据本申请的一些实施例,粘接胶包括聚偏氟乙烯、聚偏氟乙烯-六氟丙烯混合物、聚偏氟乙烯-氯代三氟乙烯混合物、聚四氟乙烯、聚甲基丙烯酸甲酯、聚丙烯腈和聚氧化乙烯中的至少一种。According to some embodiments of the present application, the adhesive glue includes polyvinylidene fluoride, polyvinylidene fluoride-hexafluoropropylene mixture, polyvinylidene fluoride-chlorotrifluoroethylene mixture, polytetrafluoroethylene, polymethylmethacrylate , at least one of polyacrylonitrile and polyethylene oxide.
粘接胶可以包括以上材料中的一种、两种、三种甚至更多,本申请对此不做限制。The adhesive may include one, two, three or even more of the above materials, which is not limited in this application.
在隔膜2上布置粘接胶,极片1制作完成后,对极片1进行层叠或者卷曲,隔膜2上的第二粘接层22会层叠,基材21的两表面均具有第二粘接层22,这样堆叠在一起的隔膜2可以通过自身的第二粘接层22粘接在一起,从而对隔膜2进行固定,避免由于隔膜2收缩造成电池短路。第二粘接层22的粘接力大于或等于1N/m且小于或等于40N/m,保证了第二粘接层22的粘接力,避免隔膜2脱开。Arrange adhesive glue on the diaphragm 2. After the pole piece 1 is produced, the pole piece 1 is laminated or curled. The second adhesive layer 22 on the diaphragm 2 will be laminated, and both surfaces of the base material 21 have the second adhesive layer. layer 22, the separators 2 stacked together can be bonded together through their own second adhesive layer 22, thereby fixing the separator 2 and preventing the battery from short-circuiting due to shrinkage of the separator 2. The adhesive force of the second adhesive layer 22 is greater than or equal to 1 N/m and less than or equal to 40 N/m, which ensures the adhesive force of the second adhesive layer 22 and prevents the separator 2 from coming off.
根据本申请的一些实施例,第二粘接层22的粘接力大于或等于5N/m且小于或等于40N/m。According to some embodiments of the present application, the adhesive force of the second adhesive layer 22 is greater than or equal to 5 N/m and less than or equal to 40 N/m.
示例性地,第二粘接层22的粘接力为5N/m,或者第二粘接层22的粘接力为10N/m,或者第二粘接层22的粘接力为20N/m,或者第二粘接层22的粘接力为30N/m,或者第二粘接层22的粘接力为40N/m。For example, the adhesive force of the second adhesive layer 22 is 5 N/m, or the adhesive force of the second adhesive layer 22 is 10 N/m, or the adhesive force of the second adhesive layer 22 is 20 N/m. , or the adhesive force of the second adhesive layer 22 is 30N/m, or the adhesive force of the second adhesive layer 22 is 40N/m.
在其他实现方式中,第二粘接层22的粘接力可以为其他值,本申请对此不作限制。In other implementations, the adhesive force of the second adhesive layer 22 can be other values, which is not limited by this application.
进一步限定第二粘接层22的粘接力,保证了第二粘接层22之间的粘附性,实现对隔膜2的有效固定。The adhesive force of the second adhesive layer 22 is further limited to ensure the adhesion between the second adhesive layers 22 and achieve effective fixation of the separator 2 .
根据本申请的一些实施例,在基材21的宽度方向C上,第二粘接层22的宽度L3(L4)小于或等于20mm。According to some embodiments of the present application, in the width direction C of the base material 21, the width L3 (L4) of the second adhesive layer 22 is less than or equal to 20 mm.
限定第二粘接层22的宽度L3(L4)小于或等于20mm,既保证基材21上有第二粘接层22能够用来固定隔膜2,同时避免第二粘接层22的宽度太宽,影响隔膜2的大小。Limiting the width L3 (L4) of the second adhesive layer 22 to less than or equal to 20 mm not only ensures that the second adhesive layer 22 on the base material 21 can be used to fix the diaphragm 2, but also prevents the width of the second adhesive layer 22 from being too wide. , affecting the size of diaphragm 2.
在本申请实施例中,基材21两侧的第二粘接层22的宽度分别为L3和L4。L3和L4可以相等也可以不相等。In the embodiment of the present application, the widths of the second adhesive layer 22 on both sides of the base material 21 are L3 and L4 respectively. L3 and L4 may or may not be equal.
示例性地,L3为5mm,L4为8mm;或者L3和L4均为9mm。For example, L3 is 5mm and L4 is 8mm; or both L3 and L4 are 9mm.
根据本申请的一些实施例,在基材21的宽度方向C上,第二粘接层22的宽度L3(L4)大于或等于7mm且小于或等于11mm。According to some embodiments of the present application, in the width direction C of the base material 21, the width L3 (L4) of the second adhesive layer 22 is greater than or equal to 7 mm and less than or equal to 11 mm.
示例性地,第二粘接层22的宽度L3(L4)为7mm,或者第二粘接层22的宽度L3(L4)为8mm,或者第二粘接层22的宽度L3(L4)为9mm,或者第二粘接层22的宽度L3(L4)为10mm,或者第二粘接层22的宽度L3(L4)为11mm。For example, the width L3 (L4) of the second adhesive layer 22 is 7 mm, or the width L3 (L4) of the second adhesive layer 22 is 8 mm, or the width L3 (L4) of the second adhesive layer 22 is 9 mm. , or the width L3 (L4) of the second adhesive layer 22 is 10 mm, or the width L3 (L4) of the second adhesive layer 22 is 11 mm.
在其他实现方式中,第二粘接层22的宽度L3(L4)可以为其他数值,本申请对此不作限制。In other implementations, the width L3 (L4) of the second adhesive layer 22 can be other values, which is not limited by this application.
进一步限定第二粘接层22的宽度L3(L4)大于或等于7mm且小于或等于11mm,既保证对隔膜2的固定效果,同时避免第二粘接层22的太宽,使得隔膜2的占比太大,从而影响电池的能量密度。The width L3 (L4) of the second adhesive layer 22 is further limited to be greater than or equal to 7 mm and less than or equal to 11 mm, which not only ensures the fixing effect on the diaphragm 2, but also prevents the second adhesive layer 22 from being too wide, making the diaphragm 2 occupy less space. The ratio is too large, thus affecting the energy density of the battery.
根据本申请的一些实施例,参见图12,隔膜2还包括第一绝缘层23,第一绝缘层23设置于基材21的第二区域212沿厚度方向上相对的两表面,第一绝缘层23包括粘接胶和陶瓷浆料。According to some embodiments of the present application, referring to Figure 12, the separator 2 further includes a first insulating layer 23. The first insulating layer 23 is disposed on two opposite surfaces of the second region 212 of the base material 21 along the thickness direction. The first insulating layer 23 23Including adhesive glue and ceramic slurry.
第一绝缘层23用于保证隔膜2的绝缘性,避免阴极极片和阳极极片直接接触造成电池短路。陶瓷浆料是常用的绝缘材料具有很好的绝缘性,粘接胶和陶瓷浆料混合,保证陶瓷浆料能够粘接在基材21上。The first insulating layer 23 is used to ensure the insulation of the separator 2 and prevent the cathode plate and the anode plate from being in direct contact and causing a short circuit in the battery. Ceramic slurry is a commonly used insulating material with good insulation properties. The adhesive glue and ceramic slurry are mixed to ensure that the ceramic slurry can be bonded to the base material 21 .
根据本申请的一些实施例,第二粘接层22和第一绝缘层23同层制作形成。According to some embodiments of the present application, the second adhesive layer 22 and the first insulating layer 23 are formed in the same layer.
第二粘接层22和第一绝缘层23都是通过微凹版辊制作在基材21上的,微凹版辊的辊压面对应的区域有待涂敷的浆料,微凹版辊在基材21上辊压后将浆料涂敷在对应的区域。在本申请实施例中,可以在微凹版辊的辊压面对应第一区域211的区域放置粘接胶,在微凹版辊的辊压面对应第二区域212的区域放置粘接胶和陶瓷浆料的混合物,然后微凹版辊在基材21上辊压分别形成第二粘接层22和第一绝缘层23。The second adhesive layer 22 and the first insulating layer 23 are both made on the base material 21 through a microgravure roller. The area corresponding to the rolling surface of the microgravure roller has the slurry to be coated. The microgravure roller is on the base material. 21. Apply the slurry to the corresponding area after rolling. In the embodiment of the present application, adhesive glue can be placed in the area corresponding to the first area 211 on the rolling surface of the microgravure roller, and adhesive glue and The mixture of ceramic slurry is then rolled on the substrate 21 by a microgravure roller to form the second adhesive layer 22 and the first insulating layer 23 respectively.
第二粘接层22和第一绝缘层23同层制作可以减少制作步骤,提高工作效率。The second adhesive layer 22 and the first insulating layer 23 are made in the same layer, which can reduce the number of manufacturing steps and improve work efficiency.
根据本申请的另一些实施例,图13为本申请一些实施例提供的隔膜的截面图,参见图13,隔膜2还包括第二绝缘层24,第二绝缘层24设置于基材21沿厚度方向上相对的两表面并且全部覆盖基材21的两个表面,在基材21的厚度方向上,第二绝缘层24位于第二粘接层22和基材21之间,第二绝缘层24包括粘接胶和陶瓷浆料。According to other embodiments of the present application, FIG. 13 is a cross-sectional view of a separator provided by some embodiments of the present application. Referring to FIG. 13 , the separator 2 further includes a second insulating layer 24 , and the second insulating layer 24 is disposed on the base material 21 along the thickness. The two opposite surfaces in the direction completely cover the two surfaces of the base material 21. In the thickness direction of the base material 21, the second insulating layer 24 is located between the second adhesive layer 22 and the base material 21. The second insulating layer 24 Includes adhesives and ceramic slurries.
第二粘接层22和第二绝缘层24可以分层制作,示例性地,先在基材21上做一层第二绝缘层24,然后在基材21的第一区域211做一层第二粘接层22。The second adhesive layer 22 and the second insulating layer 24 can be made in layers. For example, a layer of the second insulating layer 24 is first made on the base material 21 , and then a layer of the second insulating layer 24 is made on the first area 211 of the base material 21 . Two adhesive layers 22.
第二绝缘层24用于保证隔膜2的绝缘性,避免阴极极片和阳极极片直接接触造成电池短路。陶瓷浆料是常用的绝缘材料具有很好的绝缘性,粘接胶和陶瓷浆料混合,保证陶瓷浆料能够粘接在基材21上。The second insulating layer 24 is used to ensure the insulation of the separator 2 and prevent the cathode plate and the anode plate from being in direct contact and causing a short circuit in the battery. Ceramic slurry is a commonly used insulating material with good insulation properties. The adhesive glue and ceramic slurry are mixed to ensure that the ceramic slurry can be bonded to the base material 21 .
本申请的实施例提供了一种电池单体,该电池单体包括上述实施例中的极片,和/或上述实施例中的隔膜。The embodiment of the present application provides a battery cell, which includes the pole piece in the above embodiment and/or the separator in the above embodiment.
在一些实施例,电池单体的阴极极片和阳极极片中的一种极片采用上述实施例中的极片。在另一些实施例中,电池单体的阴极极片和阳极极片两者均可以采用上述实施例中的极片。In some embodiments, one of the cathode electrode piece and the anode electrode piece of the battery cell adopts the electrode piece in the above embodiment. In other embodiments, both the cathode pole piece and the anode pole piece of the battery cell can adopt the pole pieces in the above embodiments.
在本申请实施例提供的极片1中隔膜2可以被有效固定,隔膜2受热后,隔膜2不会收缩,使得隔膜2能够将阴极极片和阳极极片隔开,避免阴极极片和阳极极片直接接触造成电池短路。In the pole piece 1 provided by the embodiment of the present application, the separator 2 can be effectively fixed. After the separator 2 is heated, the separator 2 will not shrink, so that the separator 2 can separate the cathode pole piece and the anode pole piece, avoiding the cathode pole piece and the anode. Direct contact between the pole pieces causes a short circuit in the battery.
根据本申请的一些实施例,图14为本申请一些实施例提供的极片的截面图,参见图14,当电池单体包括上述中的极片1时,极片1的第一粘接层112与隔膜2固定在一起。According to some embodiments of the present application, Figure 14 is a cross-sectional view of a pole piece provided by some embodiments of the present application. Referring to Figure 14, when the battery cell includes the above-mentioned pole piece 1, the first adhesive layer of the pole piece 1 112 is fixed with diaphragm 2.
在电池单体中,可以通过第一粘接层112将极片1与隔膜2粘接起来,从而固定在一起,以对隔膜2进行固定。这样即使电池的温度升高,隔膜2受热时,隔膜2的两侧被固定,隔膜2不会收缩,使得隔膜2能够将阴极极片和阳极极片隔开,避免阴极极片和阳极极片直接接触造成电池短路。In the battery cell, the pole piece 1 and the separator 2 can be bonded through the first adhesive layer 112 to fix them together to fix the separator 2 . In this way, even if the temperature of the battery rises, when the separator 2 is heated, both sides of the separator 2 are fixed, and the separator 2 will not shrink, so that the separator 2 can separate the cathode pole piece and the anode pole piece, and avoid the cathode pole piece and the anode pole piece. Direct contact causes the battery to short circuit.
根据本申请的一些实施例,图15为本申请一些实施例提供的极片的截面图,参见图15,电池单体的阴极极片14和阳极极片15均采用上述实施例中的极片,隔膜2位于阴极极片14和阳极极片15之间,阴极极片14的第一粘接层112和阳极极片15的第一粘接层112均与隔膜2固定在一起。According to some embodiments of the present application, Figure 15 is a cross-sectional view of a pole piece provided by some embodiments of the present application. Referring to Figure 15, the cathode pole piece 14 and the anode pole piece 15 of the battery cell both adopt the pole pieces in the above embodiments. , the separator 2 is located between the cathode pole piece 14 and the anode pole piece 15, and the first adhesive layer 112 of the cathode pole piece 14 and the first adhesive layer 112 of the anode pole piece 15 are both fixed to the separator 2.
阴极极片14的第一粘接层112和阳极极片15的第一粘接层112均与隔膜2粘接,增加对隔膜2的固定效果。The first adhesive layer 112 of the cathode plate 14 and the first adhesive layer 112 of the anode plate 15 are both bonded to the separator 2 to increase the fixing effect on the separator 2 .
根据本申请的一些实施例,参见图16,图16为本申请一些实施例提供的极片与隔膜配合的截面图,当电池单体包括上述实施例中的隔膜2时,位于同一极片1两侧的两个隔膜2的第二粘接层22固定在一起。According to some embodiments of the present application, see Figure 16. Figure 16 is a cross-sectional view of the cooperation between the pole piece and the separator provided in some embodiments of the present application. When the battery cell includes the separator 2 in the above embodiment, it is located on the same pole piece 1 The second adhesive layers 22 of the two diaphragms 2 on both sides are fixed together.
对极片1进行层叠或者卷曲时,隔膜2上的第二粘接层22会层叠,这样堆叠在一起的隔膜2可以通过第二粘接层22粘接在一起,从而对隔膜2进行固定,避免由于隔膜2收缩造成电池短路。When the pole pieces 1 are stacked or rolled, the second adhesive layer 22 on the separator 2 will be stacked, so that the stacked separators 2 can be bonded together through the second adhesive layer 22 to fix the separator 2. Avoid battery short circuit due to shrinkage of separator 2.
根据本申请的一些实施例,在集流体11的宽度方向上,固定在一起的第二粘接层22位于极片1的活性物质层12的两侧。According to some embodiments of the present application, the second adhesive layer 22 fixed together is located on both sides of the active material layer 12 of the pole piece 1 in the width direction of the current collector 11 .
第二粘接层22位于极片1的活性物质层12的两侧,避免第二粘接层22对活性物质层12产生影响从而影响电池的性能。The second adhesive layer 22 is located on both sides of the active material layer 12 of the pole piece 1 to prevent the second adhesive layer 22 from affecting the active material layer 12 and thereby affecting the performance of the battery.
本申请实施例提供了一种用于制作电池单体的热压模具3,图17为本申请一些实施例提供的热压模具的结构图,图18为本申请一些实施例提供的热压模具在另一视角下的结构图,图19为本申请一些实施例提供的热压模具的主视图,图20为图19中C-C面的截面图。结合图17至图20,热压模具3包括第一夹板31和至少两个第一凸块32。至少两个第一凸块32均位于第一夹板31的同一第一表面,并且在第一夹板31的宽度方向上,至少两个第一凸块32中的其中一部分靠近第一表面的某一侧边设置,另一部分靠近第一表面的另一侧边设置,其中某一侧边与另一侧边为第一表面的相对两侧,以使得在制作电池单体时至少两个第一凸块32的位置与第一粘接层112的位置相对应。The embodiments of the present application provide a hot-pressing mold 3 for producing battery cells. Figure 17 is a structural diagram of the hot-pressing mold provided by some embodiments of the present application. Figure 18 is a hot-pressing mold provided by some embodiments of the present application. Structural diagram from another perspective, Figure 19 is a front view of the hot pressing mold provided by some embodiments of the present application, and Figure 20 is a cross-sectional view of the C-C plane in Figure 19. 17 to 20 , the hot pressing mold 3 includes a first clamping plate 31 and at least two first bumps 32 . The at least two first bumps 32 are located on the same first surface of the first clamping plate 31 , and in the width direction of the first clamping plate 31 , a part of the at least two first bumps 32 is close to a certain part of the first surface. One side is provided, and the other part is provided close to the other side of the first surface, where one side and the other side are opposite sides of the first surface, so that at least two first protrusions are formed when making the battery cell. The position of the block 32 corresponds to the position of the first adhesive layer 112 .
第一夹板31和第一凸块32可以是一体成型,也可以将第一凸块32粘接在第一夹板31的第一表面。在本申请的实施例中热压模具3包括两个第一凸块32,两个第一凸块32位于第一表面的相对两侧,这样热压模具3的结构更加简单。在其他实现方式中,热压模具3可以包括多个第一凸块32,位于第一表面同一侧的第一凸块32沿第一夹板31的长度方向排布。The first clamping plate 31 and the first bump 32 may be integrally formed, or the first bump 32 may be bonded to the first surface of the first clamping plate 31 . In the embodiment of the present application, the hot-pressing mold 3 includes two first bumps 32 , and the two first bumps 32 are located on opposite sides of the first surface, so that the structure of the hot-pressing mold 3 is simpler. In other implementations, the hot pressing mold 3 may include a plurality of first bumps 32 , and the first bumps 32 located on the same side of the first surface are arranged along the length direction of the first clamping plate 31 .
在本申请实施例的一种实现方式中,在制作电池单体时,至少两个第一凸块32的位置与第一粘接层112的位置相对应,至少两个第一凸块32用于将第一粘接层112与隔膜2粘接在一起。可以通过第一夹板31上的第一凸块32对隔膜2与极片1施加压力,在热作用下,第一粘接层112与隔膜2上的第二粘接层22热复合,粘接在一起,防止隔膜2在高温下收缩。In an implementation manner of the embodiment of the present application, when manufacturing a battery cell, the positions of at least two first bumps 32 correspond to the positions of the first adhesive layer 112 , and the at least two first bumps 32 are To bond the first adhesive layer 112 and the diaphragm 2 together. Pressure can be applied to the diaphragm 2 and the pole piece 1 through the first bump 32 on the first clamping plate 31. Under the action of heat, the first adhesive layer 112 and the second adhesive layer 22 on the diaphragm 2 are thermally combined and bonded. together to prevent diaphragm 2 from shrinking at high temperatures.
结合图17至图20,热压模具3还包括第二夹板33和至少两个第二凸块34,第二夹板33与第一夹板31相对;至少两个第二凸块34均位于第二夹板33的同一第二表面,且至少两个第二凸块34的位置与至少两个第一凸块32的位置一一对应。With reference to Figures 17 to 20, the hot pressing mold 3 also includes a second clamping plate 33 and at least two second protrusions 34. The second clamping plate 33 is opposite to the first clamping plate 31; the at least two second protrusions 34 are located on the second plying plate 33. The same second surface of the clamping plate 33 has a one-to-one correspondence with the positions of the at least two second bumps 34 and the positions of the at least two first bumps 32 .
第二夹板33和第二凸块34可以是一体成型,也可以将第二凸块34粘接在第二夹板33的第二表面。在本申请的实施例中热压模具3包括两个第二凸块34,两个第二凸块34位于第二表面的相对两侧,这样热压模具3的结构更加简单。在其他实现方式中,热压模具3可以包括多个第二凸块34,位于第二表面同一侧的第二凸块34沿第二夹板33的长度方向排布。The second clamping plate 33 and the second protrusion 34 can be integrally formed, or the second protrusion 34 can be bonded to the second surface of the second plying plate 33 . In the embodiment of the present application, the hot-pressing mold 3 includes two second bumps 34 , and the two second bumps 34 are located on opposite sides of the second surface, so that the structure of the hot-pressing mold 3 is simpler. In other implementations, the hot pressing mold 3 may include a plurality of second bumps 34 , and the second bumps 34 located on the same side of the second surface are arranged along the length direction of the second clamping plate 33 .
在本申请实施例的一种实现方式中,在制作电池单体时,热压模具3上的第一凸块32和第二凸块34同时对隔膜2与极片1施加压力,在热作用下,第一粘接层112与隔膜2上的第二粘接层22热复合,粘接在一起,防止隔膜2在高温下收缩。In one implementation of the embodiment of the present application, when manufacturing a battery cell, the first bump 32 and the second bump 34 on the hot pressing mold 3 simultaneously exert pressure on the separator 2 and the pole piece 1. Under the action of heat, The first adhesive layer 112 and the second adhesive layer 22 on the diaphragm 2 are thermally combined and bonded together to prevent the diaphragm 2 from shrinking at high temperatures.
在本申请实施例的一种实现方式中,在制作电池单体时,至少两个第一凸块32的位置与第二粘接层22的位置相对应,至少两个第一凸块32用于将隔膜2的第二粘接层22粘接在一起,防止隔膜2在高温下收缩。In an implementation manner of the embodiment of the present application, when making a battery cell, the positions of at least two first bumps 32 correspond to the positions of the second adhesive layer 22 , and the at least two first bumps 32 are The second adhesive layer 22 of the diaphragm 2 is bonded together to prevent the diaphragm 2 from shrinking at high temperature.
本申请实施例提供了一种电池,包括至少两个任意实施方式中的电池单体。Embodiments of the present application provide a battery, including at least two battery cells in any embodiment.
电池可以应用于但不限于手机、平板、笔记本电脑、电动玩具、电动工具、电瓶车、电动汽车、轮船、航天器等等。其中,电动玩具可以包括固定式或移动式的电动玩具,例如,游戏机、电动汽车玩具、电动轮船玩具和电动飞机玩具等等,航天器可以包括飞机、火箭、航天飞机和宇宙飞船等等。Batteries can be used in, but are not limited to, mobile phones, tablets, laptops, electric toys, power tools, battery cars, electric vehicles, ships, spacecraft, etc. Among them, electric toys can include fixed or mobile electric toys, such as game consoles, electric car toys, electric ship toys, electric airplane toys, etc., and spacecraft can include airplanes, rockets, space shuttles, spaceships, etc.
通过采用本公开实施例中的电池单体,能够保证电池100不易短路,安全性高。By using the battery cells in the embodiments of the present disclosure, it can be ensured that the battery 100 is not prone to short circuit and has high safety.
本申请的实施例提供了一种用电装置,用电装置包括任意实施方式中的电池,电池用于提供电能。Embodiments of the present application provide an electrical device. The electrical device includes a battery in any embodiment, and the battery is used to provide electrical energy.
用电装置可以为但不限于手机、平板、笔记本电脑、电动玩具、电动工具、电瓶车、电动汽车、轮船、航天器等等。其中,电动玩具可以包括固定式或移动式的电动玩具,例如,游戏机、电动汽车玩具、电动轮船玩具和电动飞机玩具等等,航天器可以包括飞机、火箭、航天飞机和宇宙飞船等等。Electric devices can be, but are not limited to, mobile phones, tablets, laptops, electric toys, power tools, battery cars, electric vehicles, ships, spacecraft, etc. Among them, electric toys can include fixed or mobile electric toys, such as game consoles, electric car toys, electric ship toys, electric airplane toys, etc., and spacecraft can include airplanes, rockets, space shuttles, spaceships, etc.
通过采用本公开实施例中的电池,能够保证电池不易短路,从而使得该用电装置的安全性高。By using the battery in the embodiment of the present disclosure, it can be ensured that the battery is not easily short-circuited, thereby making the safety of the electrical device high.
根据本申请的一些实施例,本申请提供了一种极片1,极片1包括集流体11、第一粘接层112、活性物质层12和极耳13。集流体11包括集流体本体111,集流体本体111具有活性物质区1111、极耳区1112和涂胶区1113,极耳区1112位于活性物质区1111的一侧,涂胶区1113位于活性物质区1111和极耳区1112之间以及活性物质区1111的与极耳区1112相对的另一侧;第一粘接层112设置于涂胶区1113,第一粘接层112的粘接力大于或等于5N/m且小于或等于40N/m。在涂胶区1113和活性物质区1111的排布方向上,第一粘接层112的宽度大于或等于7mm且小于或等于11mm。第一粘接层112包括粘接胶,粘接胶的质量与第一粘接层112的总质量的比值大于或等于10%且小于或等于50%。第一粘接层112包括层叠设置的陶瓷浆料层1121和粘接胶层1122,陶瓷浆料层1121位于集流体本体111和粘接胶层1122之间。活性物质层12设置于集流体的活 性物质区1111。极耳13设置于集流体的极耳区1112。极片1的第一粘接层112与隔膜2固定在一起。According to some embodiments of the present application, the present application provides a pole piece 1. The pole piece 1 includes a current collector 11, a first adhesive layer 112, an active material layer 12 and a pole tab 13. The current collector 11 includes a current collector body 111. The current collector body 111 has an active material area 1111, a tab area 1112 and a glue coating area 1113. The tab area 1112 is located on one side of the active material area 1111, and the glue application area 1113 is located in the active material area. 1111 and the tab area 1112 and the other side of the active material area 1111 opposite to the tab area 1112; the first adhesive layer 112 is provided in the glue coating area 1113, and the adhesive force of the first adhesive layer 112 is greater than or Equal to 5N/m and less than or equal to 40N/m. In the arrangement direction of the glue coating area 1113 and the active material area 1111, the width of the first adhesive layer 112 is greater than or equal to 7 mm and less than or equal to 11 mm. The first adhesive layer 112 includes adhesive glue, and the ratio of the mass of the adhesive glue to the total mass of the first adhesive layer 112 is greater than or equal to 10% and less than or equal to 50%. The first adhesive layer 112 includes a stacked ceramic slurry layer 1121 and an adhesive layer 1122 . The ceramic slurry layer 1121 is located between the current collector body 111 and the adhesive layer 1122 . The active material layer 12 is disposed in the active material region 1111 of the current collector. The tab 13 is disposed in the tab area 1112 of the current collector. The first adhesive layer 112 of the pole piece 1 and the diaphragm 2 are fixed together.
最后应说明的是:以上各实施例仅用以说明本申请的技术方案,而非对其限制;尽管参照前述各实施例对本申请进行了详细的说明,本领域的普通技术人员应当理解:其依然可以对前述各实施例所记载的技术方案进行修改,或者对其中部分或者全部技术特征进行等同替换;而这些修改或者替换,并不使相应技术方案的本质脱离本申请各实施例技术方案的范围,其均应涵盖在本申请的权利要求和说明书的范围当中。尤其是,只要不存在结构冲突,各个实施例中所提到的各项技术特征均可以任意方式组合起来。本申请并不局限于文中公开的特定实施例,而是包括落入权利要求的范围内的所有技术方案。Finally, it should be noted that the above embodiments are only used to illustrate the technical solution of the present application, but not to limit it; although the present application has been described in detail with reference to the foregoing embodiments, those of ordinary skill in the art should understand that: The technical solutions described in the foregoing embodiments can still be modified, or some or all of the technical features can be equivalently replaced; and these modifications or substitutions do not deviate from the essence of the corresponding technical solutions from the technical solutions of the embodiments of the present application. The scope shall be covered by the claims and description of this application. In particular, as long as there is no structural conflict, the technical features mentioned in the various embodiments can be combined in any way. The application is not limited to the specific embodiments disclosed herein, but includes all technical solutions falling within the scope of the claims.

Claims (12)

  1. 一种隔膜,所述隔膜(2)包括:A diaphragm, the diaphragm (2) includes:
    基材(21),具有两个第一区域(211)和一个第二区域(212),在所述基材(21)的宽度方向上,所述第二区域(212)位于所述两个第一区域(211)之间;The base material (21) has two first areas (211) and one second area (212). In the width direction of the base material (21), the second area (212) is located between the two first areas (211) and a second area (212). between the first area (211);
    第二粘接层(22),设置于所述基材(21)的所述两个第一区域(211)中每一个所述第一区域(211)沿厚度方向上相对的两表面,所述第二粘接层(22)的粘接力大于或等于1N/m且小于或等于40N/m。The second adhesive layer (22) is disposed on two surfaces of each of the two first regions (211) of the base material (21) opposite in the thickness direction, so The adhesive force of the second adhesive layer (22) is greater than or equal to 1N/m and less than or equal to 40N/m.
  2. 根据权利要求1所述的隔膜,其中,所述第二粘接层(22)的粘接力大于或等于5N/m且小于或等于40N/m。The separator according to claim 1, wherein the adhesive force of the second adhesive layer (22) is greater than or equal to 5 N/m and less than or equal to 40 N/m.
  3. 根据权利要求1或2所述的隔膜,其中,在所述基材(21)的宽度方向上,所述第二粘接层(22)的宽度小于或等于20mm。The separator according to claim 1 or 2, wherein the width of the second adhesive layer (22) in the width direction of the base material (21) is less than or equal to 20 mm.
  4. 根据权利要求1至3中任一项所述的隔膜,其中,在所述基材(21)的宽度方向上,所述第二粘接层(22)的宽度大于或等于7mm且小于或等于11mm。The separator according to any one of claims 1 to 3, wherein the width of the second adhesive layer (22) in the width direction of the base material (21) is greater than or equal to 7 mm and less than or equal to 11mm.
  5. 根据权利要求1至4中任一项所述的隔膜,其中,所述隔膜(2)还包括:The membrane according to any one of claims 1 to 4, wherein the membrane (2) further comprises:
    第一绝缘层(23),设置于所述基材(21)的所述第二区域(212)沿厚度方向上相对的两表面,所述第一绝缘层(23)包括粘接胶和陶瓷浆料。A first insulating layer (23) is provided on two opposite surfaces of the second region (212) of the base material (21) in the thickness direction. The first insulating layer (23) includes adhesive and ceramics. slurry.
  6. 根据权利要求1至5中任一项所述的隔膜,其中,所述隔膜(2)还包括:The membrane according to any one of claims 1 to 5, wherein the membrane (2) further comprises:
    第二绝缘层(24),设置于所述基材(21)沿厚度方向上相对的两表面并且全部覆盖所述基材(21)的两个所述表面,在所述基材(21)的厚度方向上,所述第二绝缘层(24)位于所述第二粘接层(22)和所述基材(21)之间,所述第二绝缘层(24)包括粘接胶和陶瓷浆料。The second insulating layer (24) is disposed on two opposite surfaces of the base material (21) in the thickness direction and completely covers the two surfaces of the base material (21). In the thickness direction, the second insulation layer (24) is located between the second adhesive layer (22) and the base material (21). The second insulation layer (24) includes adhesive glue and Ceramic slurry.
  7. 一种电池单体,所述电池单体包括极片(1)和如权利要求1至6中任一项所述的隔膜(2),位于同一极片(1)两侧的两个所述隔膜(2)的第二粘接层(22)固定在一起。A battery cell, the battery cell includes a pole piece (1) and a separator (2) as claimed in any one of claims 1 to 6, two of which are located on both sides of the same pole piece (1). The second adhesive layer (22) of the membrane (2) is held together.
  8. 根据权利要求7所述的电池单体,其中,在所述隔膜(2)的基材(21)的宽度方向上,固定在一起的所述第二粘接层(22)位于所述极片(1)的活性物质层的两侧。The battery cell according to claim 7, wherein the second adhesive layer (22) fixed together is located on the pole piece in the width direction of the base material (21) of the separator (2). (1) Both sides of the active material layer.
  9. 一种热压模具,所述热压模具(3)用于制作如权利要求7或8所述的电池单体,所述热压模具(3)包括:A hot-pressing mold, the hot-pressing mold (3) is used to produce the battery cell as claimed in claim 7 or 8, and the hot-pressing mold (3) includes:
    第一夹板(31);The first splint (31);
    至少两个第一凸块(32),所述至少两个第一凸块(32)均位于所述第一夹板(31)的同一第一表面,并且在所述第一夹板(31)的宽度方向上,所述至少两个第一凸块(32)中的其中一部分靠近所述第一表面的某一侧边设置,另一部分靠近所述第一表面的另一侧边设置,其中所述某一侧边与所述另一侧边为所述第一表面的相对两侧边,以使得在制作所述电池单体时所述至少两个第一凸块(32)的位置与所述第二粘接层(22)的位置相对应。At least two first bumps (32), the at least two first bumps (32) are located on the same first surface of the first plywood (31), and on the first plywood (31) In the width direction, a part of the at least two first bumps (32) is disposed close to a certain side of the first surface, and the other part is disposed close to the other side of the first surface, wherein the The certain side and the other side are opposite sides of the first surface, so that the positions of the at least two first bumps (32) are consistent with the position of the first surface when making the battery cell. The position of the second adhesive layer (22) corresponds to that of the second adhesive layer (22).
  10. 根据权利要求9所述的热压模具,其中,所述热压模具(3)还包括:The hot pressing mold according to claim 9, wherein the hot pressing mold (3) further includes:
    第二夹板(33),与所述第一夹板(31)相对;The second plywood (33) is opposite to the first plywood (31);
    至少两个第二凸块(34),所述至少两个第二凸块(34)均位于所述第二夹板(33)的同一第二表面,且所述第一表面和所述第二表面相对,所述至少两个第二凸块(34)的位置与所述至少两个第一凸块(32)的位置一一对应。At least two second bumps (34), the at least two second bumps (34) are located on the same second surface of the second clamping plate (33), and the first surface and the second The surfaces are opposite, and the positions of the at least two second bumps (34) correspond to the positions of the at least two first bumps (32).
  11. 一种电池,所述电池包括至少两个如权利要求7或8所述的电池单体。A battery comprising at least two battery cells according to claim 7 or 8.
  12. 一种用电装置,所述用电装置包括如权利要求11所述的电池,所述电池用于提供电能。An electrical device, the electrical device comprising the battery as claimed in claim 11, the battery being used to provide electrical energy.
PCT/CN2022/118487 2022-07-19 2022-09-13 Separator, battery cell, hot-pressing mold, battery, and electric device WO2024016452A1 (en)

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CN202221853206.5U CN217589312U (en) 2022-07-19 2022-07-19 Diaphragm, battery monomer, hot pressing die, battery and power consumption device
CN202221853206.5 2022-07-19

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CN108232092A (en) * 2017-12-26 2018-06-29 惠州Tcl金能电池有限公司 Diaphragm, lithium ion battery and its manufacturing method
CN111162323A (en) * 2019-12-30 2020-05-15 东莞维科电池有限公司 Winding type lithium ion battery cell and preparation method thereof
CN111564593A (en) * 2020-06-04 2020-08-21 江苏星源新材料科技有限公司 Diaphragm, diaphragm roll, battery core and power lithium battery
CN211404608U (en) * 2019-11-29 2020-09-01 无锡恩捷新材料科技有限公司 Heat-resistant adhesive low-cost coating film
CN114597590A (en) * 2022-03-14 2022-06-07 华鼎国联四川动力电池有限公司 Special edge-coated diaphragm and application thereof
CN114725623A (en) * 2020-12-22 2022-07-08 华为技术有限公司 Battery, electronic device, and mobile device

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108232092A (en) * 2017-12-26 2018-06-29 惠州Tcl金能电池有限公司 Diaphragm, lithium ion battery and its manufacturing method
CN211404608U (en) * 2019-11-29 2020-09-01 无锡恩捷新材料科技有限公司 Heat-resistant adhesive low-cost coating film
CN111162323A (en) * 2019-12-30 2020-05-15 东莞维科电池有限公司 Winding type lithium ion battery cell and preparation method thereof
CN111564593A (en) * 2020-06-04 2020-08-21 江苏星源新材料科技有限公司 Diaphragm, diaphragm roll, battery core and power lithium battery
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CN114597590A (en) * 2022-03-14 2022-06-07 华鼎国联四川动力电池有限公司 Special edge-coated diaphragm and application thereof

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