WO2024003162A1 - Filament of recycled polypropylene for pile yarn - Google Patents
Filament of recycled polypropylene for pile yarn Download PDFInfo
- Publication number
- WO2024003162A1 WO2024003162A1 PCT/EP2023/067693 EP2023067693W WO2024003162A1 WO 2024003162 A1 WO2024003162 A1 WO 2024003162A1 EP 2023067693 W EP2023067693 W EP 2023067693W WO 2024003162 A1 WO2024003162 A1 WO 2024003162A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- sheath
- filament
- core
- polymer
- additive
- Prior art date
Links
- 239000004743 Polypropylene Substances 0.000 title claims abstract description 93
- 229920001155 polypropylene Polymers 0.000 title claims abstract description 93
- -1 polypropylene Polymers 0.000 title claims abstract description 88
- 239000000654 additive Substances 0.000 claims abstract description 89
- 230000000996 additive effect Effects 0.000 claims abstract description 78
- 229920000642 polymer Polymers 0.000 claims description 96
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 46
- 239000000049 pigment Substances 0.000 claims description 41
- 229920000728 polyester Polymers 0.000 claims description 31
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 20
- 239000000835 fiber Substances 0.000 claims description 20
- 239000004408 titanium dioxide Substances 0.000 claims description 19
- 239000004953 Aliphatic polyamide Substances 0.000 claims description 16
- 229920003231 aliphatic polyamide Polymers 0.000 claims description 16
- 229920000098 polyolefin Polymers 0.000 claims description 12
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 10
- 238000000034 method Methods 0.000 claims description 6
- 239000006229 carbon black Substances 0.000 claims description 4
- 238000005520 cutting process Methods 0.000 claims description 2
- 229920003232 aliphatic polyester Polymers 0.000 claims 2
- 229920000139 polyethylene terephthalate Polymers 0.000 description 21
- 239000005020 polyethylene terephthalate Substances 0.000 description 21
- 235000004879 dioscorea Nutrition 0.000 description 14
- 229920002292 Nylon 6 Polymers 0.000 description 11
- 229920002302 Nylon 6,6 Polymers 0.000 description 10
- 239000000463 material Substances 0.000 description 9
- 239000003086 colorant Substances 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- 239000000203 mixture Substances 0.000 description 5
- 238000004040 coloring Methods 0.000 description 4
- 230000000873 masking effect Effects 0.000 description 4
- 239000004753 textile Substances 0.000 description 3
- 240000005319 Sedum acre Species 0.000 description 2
- 239000011324 bead Substances 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000004064 recycling Methods 0.000 description 2
- 238000009987 spinning Methods 0.000 description 2
- 239000002216 antistatic agent Substances 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 238000002845 discoloration Methods 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000010687 lubricating oil Substances 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 239000004626 polylactic acid Substances 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000001054 red pigment Substances 0.000 description 1
- 230000002441 reversible effect Effects 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- 238000009732 tufting Methods 0.000 description 1
- 239000012463 white pigment Substances 0.000 description 1
- 239000001052 yellow pigment Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/02—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D01F6/04—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds from polyolefins
- D01F6/06—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds from polyolefins from polypropylene
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
- D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
- D01F8/06—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyolefin as constituent
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2201/00—Chemical constitution of the fibres, threads or yarns
- D06N2201/02—Synthetic macromolecular fibres
- D06N2201/0254—Polyolefin fibres
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2201/00—Chemical constitution of the fibres, threads or yarns
- D06N2201/10—Conjugate fibres, e.g. core-sheath, side-by-side
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N7/00—Flexible sheet materials not otherwise provided for, e.g. textile threads, filaments, yarns or tow, glued on macromolecular material
- D06N7/0063—Floor covering on textile basis comprising a fibrous top layer being coated at the back with at least one polymer layer, e.g. carpets, rugs, synthetic turf
- D06N7/0065—Floor covering on textile basis comprising a fibrous top layer being coated at the back with at least one polymer layer, e.g. carpets, rugs, synthetic turf characterised by the pile
Definitions
- the present invention relates to a filament of a recycled polymer like polypropylene.
- Such filaments may be used in yarns for carpets, e.g. carpets comprising a backing and pile comprising tufts of pile yarn extending from the backing.
- carpets and rugs have been used as textile floor coverings to provide comfort, durability, safety, and decoration.
- carpets and rugs are used interchangeably in the art. They may be used to cover the entire floor in a room and fastened thereto. Sometimes, the term carpet is used to denote such a floor covering. The term carpet may however also be used to denote a textile floor covering not fastened and typically not covering the entire floor, in the same manner as the term rug is used.
- Synthetic fibers used in yarns for carpets and mgs include inter alia polyethyleneterephthalate (PET) fibers and polypropylene (PP) fibers.
- PET polyethyleneterephthalate
- PP polypropylene
- Re-cycled PET e.g. from PET -bottles
- recycling of PP has turned more challenging.
- Re-cycled polyethyleneterephthalate is typically transparent and not strongly discolored and may thus be colored in principle as desired by adding pigment.
- PET is a more expensive material than PP.
- PVA polylactic acid
- the lower density of PP compared to PET implies that more PET is needed to get the same yarn specification as with for PP.
- One of the most commonly used material in carpets is thus PP.
- Use of re-cycled PP would thus be highly desirable in order to provide more sustainable yams at a low cost.
- re-cycled PP is typically very dark, nearly black. Though there are qualities of re-cycled PP available not being that dark, these are typically more expensive making them less attractive from an economical perspective. Further, processes for purifying (i.e. discoloring) re-cycled PP are known in the art. As purification will add costs, it is less attractive from an economical perspective.
- the dark color of re-cycled PP hampers its use in providing yarns for textile applications, such as carpets and mgs. By adding pigments to re-cycled PP, the color may be slightly affected. However, the initial dark color still significantly limits the available colors. Especially, lighter colors may in principle not be obtained. It would this be of interest to provide for replacing virgin PP with re-cycled PP in further applications.
- DE202008016836U1 discloses non-woven carpet backing comprising bicomponent binder fibers with a core/sheath structure.
- the core polymer is PET, whereas the sheath polymer is polyamide 6.
- the use of core polymers is no longer limited to raw materials with a constant coloration. Contrary to re-cycled PET, a dark constant color is however already at hand for re-cycled PP. Further, in carpet backing a dark material is typically acceptable.
- a filament for a pile yam is a multi-component filament comprising a core and at least a first sheath.
- the first sheath at least partly encloses the core.
- the core comprises recycled polypropylene and the first sheath comprises polypropylene.
- the first sheath comprises a particulate, opaque additive.
- the particulate, opaque additive is added to mask the color of the underlying core. It is thus preferred if the particulate additive is opaque. Further, the particulate, opaque additive is preferable white, or at least bright, to provide for flexibility in terms of color of the filament.
- the particulate, opaque additive may be an inorganic additive, such as titanium dioxide or calcium carbonate. According to an embodiment, the particulate, opaque additive is titanium dioxide.
- the content of the particulate, opaque additive may vary. On the one hand, a high content may improve the masking effect and provide a brighter filament, on the other, a too high content may negatively affect the mechanical properties of the filament, as well as the bonding between the filament and the core.
- the first sheath As the first sheath is to mask the core, it may constitute 5 to 30 wt.% of the filament. According to some embodiments, it constitutes 10 to 25 wt.% of the filament. The more it constitutes, the better masking effect. However, as one objective is to provide for use of recycled polypropylene, it is preferred if the first sheath is a minor component, i.e. constitutes less than 50 wt.% of the filament. Further, the thickness of the first sheath may vary over its circumference; especially if the cross-section of filament is multi-lobal. In order to mask the core, the first sheath may be at least 0.2 pm thick, such as at least 1.0 pm thick. According to an embodiment, the first sheath is 1.0 to 10.0 pm thick, such as 1.0 to 4.0 pm thick.
- the first sheath encloses the core entirely. However, in some embodiments it may be of interest to cover the circumference of the core only partly, thereby providing a filament with a melange effect (also referred to as heathered effect in the art).
- the first sheath may thus enclose at least 80%, such as at least 90% or 95%, of the circumference of the core. Further, the first sheath may enclose 80 to 99%, such as 90% or 97%, of the circumference of the core.
- the core may comprises an inorganic particulate, opaque additive, such as titanium dioxide or calcium carbonate.
- the core may comprise up to 5 wt.% of the inorganic particulate, opaque additive.
- a too high content of an inorganic particulate, opaque additive may, as already described, affect the mechanical properties of the filament negatively.
- the core may comprise a dark pigment, such as carbon black.
- the first sheath comprises polypropylene. This polypropylene may be virgin polypropylene. Virgin polypropylene does not suffer from being discolored. Further, the polypropylene in the first sheath may be recycled polypropylene.
- recycled polypropylene in the first sheath it is preferred if the recycled polypropylene in the first sheath is lighter in its color than the recycled polypropylene in the core. At least for some applications, e.g. in dark filaments, recycled polypropylene could be used in the first sheath.
- the discoloration of recycled polypropylene varies and lighter qualities are available, tough being a bit more expensive.
- Use of recycled polypropylene in filaments for carpets may thus be provided for either by using a first sheath comprising virgin polypropylene, or by using a first sheath comprising recycled polypropylene being lighter in its color than the recycled polypropylene in the core.
- the present multi-component filament allows for use of darkly colored, recycled polypropylene. It is desired to use as much recycled material as possible in the filament.
- the core may constitutes at least 40 wt.% of the filament. According to an embodiment, the core constitutes 50 to 85 wt.% of the filament.
- the multi-component filament further comprises a second sheath at least partly enclosing the first sheath.
- the second sheath comprises a polymer.
- the color of the filament may be varied and adjusted.
- the apparent color of the filament may not be the same if both pigments are present in the same sheath. Further, the color may be different depending on which pigment is present in the outer sheath.
- the second sheath comprises a polyester, such as a semiaromatic polyester (e.g. polyethylene terephthalate) and/or an aliphatic polyamide (e.g. polyamide 6 or polyamide 66).
- a polyester such as a semiaromatic polyester (e.g. polyethylene terephthalate) and/or an aliphatic polyamide (e.g. polyamide 6 or polyamide 66).
- the second sheath comprises a pigment.
- the pigment is typically not white, unless a whitish fiber is desired.
- the second sheath may comprises 1 to 20 wt.% of the pigment.
- the second sheath may optionally, or alternatively, comprise a particulate, opaque additive.
- the particulate, opaque additive typically is white and may thus serve as white pigment as well.
- the second sheath comprises a particulate, opaque additive, such as titanium dioxide, and a pigment in addition to the particulate, opaque additive.
- the particulate, opaque additive may be an inorganic particulate, opaque additive, such as titanium dioxide or calcium carbonate.
- the particulate, opaque additive is titanium dioxide.
- the second sheath may comprise 5 to 40 wt.%, such as such as 5 to 30 wt.% or 10 to 20 wt.%, of the particulate, opaque additive. According to some embodiments, wherein a lighter color is desired, the second sheath may comprise at least 10 wt.% of the particulate, opaque additive.
- the second sheath As the second sheath is to color the filament, it may constitute 5 to 30 wt.% of the filament. According to some embodiments, it constitutes 10 to 25 wt.% of the filament. The more it constitutes, the stronger coloring effect. However, as one objective is to provide for use of recycled polypropylene, it is preferred if the second sheath is a minor component, i.e. constitutes less than 50 wt.% of the filament. Further, the thickness of the second sheath may vary over its circumference; especially if the cross-section of filament is multilobal. In order to color the filament, the second sheath may be at least 0.2 pm thick, such as at least 1.0 pm thick. According to an embodiment, the second sheath is 1.0 to 10.0 pm thick, such as 1.0 to 4.0 pm thick.
- both the first and the second sheath affects the color of the resulting filament.
- the first sheath constitutes larger proportion of the filament than the second sheath.
- the first sheath may constitute 10 to 30 wt.% of the filament, whereas the second sheath may constitute 5 to 20 wt.% of the filament.
- the second sheath may be somewhat thinner, still providing the desired color.
- the second sheath encloses the first sheath entirely. However, in some embodiments it may be of interest to cover the circumference of the first sheath only partly, thereby providing a filament with a melange effect .
- the second sheath may thus enclose at least 80%, such as at least 90% or 95%, of the circumference of the first sheath. Further, the second sheath may enclose 80 to 99%, such as 90% or 97%, of the circumference of the first sheath.
- the polymer in the core typically is recycled polypropylene
- the concept of using a first and a second sheath may be applied also in providing filaments of various colors, wherein the core comprise other types of recycled polymers than polypropylene, like a polyester, such as a semi-aromatic polyester (e.g. polyethylene terephthalate) or an aliphatic polyamide (e.g. polyamide 6 or polyamide 66).
- a multi-component filament for a pile yarn comprises a core, at a first sheath, at least partly enclosing the core, and a second sheath, at least partly enclosing the first sheath.
- the core comprises a polymer, typically a recycled polymer.
- This polymer may be a polyolefin (e.g. polypropylene), a polyester, such as a semi-aromatic polyester (e.g. polyethylene terephthalate), or an aliphatic polyamide (e.g. polyamide 6 or polyamide 66).
- the first sheath comprise a polymer.
- the first sheath may thus comprise a polyolefin (e.g. polypropylene), an aliphatic polyamide (e.g. polyamide 6 or polyamide 66), or a polyester, such as semi-aromatic polyester (e.g. polyethylene terephthalate).
- the polymer used in the first sheath is typically a virgin polymer. It may however also be a recycled polymer. If to use a recycled polymer in the first sheath, it is preferred if such recycled polymer is lighter in its color than the recycled polymer in the core.
- the second sheath comprises a polymer.
- the second sheath may thus comprise a polyolefin (e.g. polypropylene), an aliphatic polyamide (e.g. polyamide 6 or polyamide 66), or a polyester, such as semi-aromatic polyester (e.g. polyethylene terephthalate).
- the polymer used in the second sheath is typically a virgin polymer.
- the first sheath comprises a first particulate, opaque additive.
- the first particulate, opaque additive may be an inorganic additive, such as titanium dioxide or calcium carbonate.
- the first particulate, opaque additive is titanium dioxide.
- the second sheath does optionally comprise a pigment and/or a second particulate, opaque additive.
- the second particulate, opaque additive if present, may be an inorganic additive, such as titanium dioxide or calcium carbonate.
- the second particulate, opaque additive is titanium dioxide.
- the color of the filament may even further be varied and adjusted.
- the use of first sheath, masking the color of the core, and a second sheath, coloring the filaments facilitates the provision of filaments with lighter colors.
- concentrating pigments to an outermost layer implies the less pigment is required to provide the same color.
- the first sheath comprises a first pigment and the second sheath comprises a second pigment, distinct from the first pigment.
- the color of the filament may be varied and adjusted.
- the apparent color of the filament may not be the same if both pigments are comprised in the same sheath. Further, the color may be different, depending on which pigment is present in the outer sheath.
- the first sheath may comprises 5 to 40 wt.%, such as 5 to 30 wt.% or 10 to 20 wt.%, of the particulate, opaque additive.
- the second sheath may comprise 1 to 20 wt.% of the pigment and/or 5 to 30 wt.%, such as 5 to 30 wt.% or 10 to 20 wt.%, of the particulate, opaque additive.
- the core may constitutes at least 40 wt.%, such as 50 to 85 wt.%, of the filament.
- the first sheath may constitute 5 to 30 wt.%, such as 10 to 25 wt.%, of the filament.
- the second sheath may constitute 5 to 30 wt.%, such as 10 to 25 wt.%, of the filament.
- the thickness of the first sheath may in embodiments of according to the second aspect, vary over its circumference; especially if the cross-section of filament is multilobal.
- the first sheath may be at least 0.2 pm thick, such as at least 1.0 pm thick.
- the first sheath is 1.0 to 10.0 pm thick, such as 1.0 to 4.0 pm thick.
- the first sheath typically encloses the core entirely. However, in some embodiments it may be of interest to cover the circumference of the core only partly, thereby providing a filament with a melange effect.
- the first sheath may thus enclose at least 80%, such as at least 90% or 95%, of the circumference of the core. Further, the first sheath may enclose 80 to 99%, such as 90% or 97%, of the circumference of the core.
- the second sheath may be at least 0.2 pm thick, such as at least 1.0 pm thick. According to an embodiment, the second sheath is 1.0 to 10.0 gm thick, such as 1.0 to 4.0 pm thick.
- the second sheath typically encloses the first sheath entirely. However, in some embodiments it may be of interest to cover only the circumference of the first sheath partly, thereby providing a filament with a melange effect.
- the second sheath may thus enclose at least 80%, such as at least 90% or 95%, of the circumference of the first sheath. Further, the second sheath may enclose 80 to 99%, such as 90% or 97%, of the circumference of the first sheath.
- the cross-section of the multicomponent filament may have at least two lobes.
- the cross-section of the multicomponent filament may thus be bi-lobal, tri-lobal, or quad-lobal.
- the cross-section of the filament does not only directly affect mechanical properties. Especially when used in carpets, also other properties like the hand-feel and touch are affected and typically improved, as described in WO 2022/005383.
- For a filament with a bi-lobal crosssection it is preferred if the waist is concave.
- the sides are concave.
- the present is not limited to a given size or diameter.
- the liner mass density of the filament may be in the range 1 dtex to 20 dtex.
- additional additives may be present in the first sheath and/or the second sheath.
- a reflective additive such as glass beads, glitter, or crystal
- the reflective additive may be a retro-reflective additive, such as glass beads.
- additives making the filament, or a pile yarn comprising the filament, changing color with different light sources may be added.
- the additive is a photochromic material. Photochromic materials change color when exposed to e.g. UV light. The photochromic material used is typically reversible. Some common examples of photochromic materials include silver halides, spirooxazines and naphthopyrans.
- a reflective additive or a photochromic material is used instead of a pigment in the second sheath.
- a multi-component filament for a pile yarn comprises a core, at a first sheath, at least partly enclosing the core, and a second sheath, at least partly enclosing the first sheath.
- the core comprises a polymer, typically a recycled polymer.
- This polymer may be a polyolefin (e.g. polypropylene), polyester, such as a semi-aromatic polyester (e.g. polyethylene terephthalate), or an aliphatic polyamide (e.g. polyamide 6 or polyamide 66).
- the first sheath comprise a polymer.
- the first sheath may thus comprise a polyolefin (e.g. polypropylene), an aliphatic polyamide (e.g. polyamide 6 or polyamide 66), or a polyester, such as a semi-aromatic polyester (e.g. polyethylene terephthalate).
- a polyolefin e.g. polypropylene
- an aliphatic polyamide e.g. polyamide 6 or polyamide 66
- a polyester such as a semi-aromatic polyester (e.g. polyethylene terephthalate).
- the polymer used in the first sheath is typically a virgin polymer. It may however also be a recycled polymer. If to use a recycled polymer in the first sheath, it is preferred if such recycled polymer is lighter in its color than the polymer in the core.
- the second sheath comprises a polymer.
- the second sheath may thus comprise a polyolefin (e.g.
- the polymer used in the second sheath is typically a virgin polymer. It may however also be a recycled polymer. If to use a recycled polymer in the second sheath, it is preferred if such recycled polymer is lighter in its color than the polymer in the core.
- the first sheath optionally comprises a first additive.
- the second sheath comprises a second additive. The second additive is distinct from the first additive if present. By having distinct additives in separate sheaths, the properties of the filament may be improved and tuned. Further, the presence of the first sheath will separate the additive in the second sheath from the core. It will be appreciated that each sheath may comprise several additives, and it is sufficient if one of these additives is distinct between the first and second sheaths.
- the core of the filament may constitute at least 40 wt.%, such as 50 to 85 wt.%, of the filament.
- the first sheath may constitute 5 to 30 wt.%, such as 10 to 25 wt.%, of the filament.
- the second sheath may constitute 5 to 30 wt.%, such as 10 to 25 wt.%, of the filament.
- the first sheath may be at least 0.2 pm thick, such as at least 1.0 pm thick.
- the first sheath may enclose at least 80%, such as at least 90% or 95%, of the circumference of the core. According to an embodiment, the first sheath encloses the core entirely.
- the second sheath may be at least 0.2 pm thick, such as at least 1.0 pm thick.
- the second sheath may enclose at least 80%, such as at least 90% or 95%, of the circumference of the first sheath. According to an embodiment, the second sheath encloses the first sheath entirely.
- polymers may as already outlined, be used in the filament. Further, various combinations of polymers be used. According to an embodiment, the polymer in the first sheath is distinct from the polymer in the second sheath. According to another embodiment, the polymer in the first sheath is the same type of polymer as the polymer in the second sheath. Further, the polymer in the core may according to an embodiment be distinct from the polymer in the first sheath. Alternatively, the polymer in the core may be the same type of polymer as the polymer in the first sheath.
- the cross-section of the multi-component filament has at least two lobes. According to an embodiment, its cross-section is bi-lobal, tri-lobal or quad-1 obal. According to an embodiment, the waist of a bi-lobal cross-section is concave and the sides of a tri-lobal and/or a quad-lobal cross-section is concave.
- the liner mass density of the filament may be 1 dtex to 20 dtex.
- a yarn such as a pile yam.
- the yam comprises at least two filaments, but typically further filaments are present, of the type described herein above.
- the yarn may be drawn and texturized to form a bulked continuous fiber (BCF) yam.
- BCF bulked continuous fiber
- the yarn may be bulked continuous fiber (BCF) yarn.
- a staple fiber is provided.
- the staple fiber is obtainable by cutting the filament of the type described herein above into staple fibers.
- the staple fibers may be 20 to 100 mm long, such as 30 to 70 mm long.
- a carpet or a mg comprises the yam described herein above, or the staple fibers described herein above.
- a method of producing a filament according to the first, or the second, aspect of the invention as disclosed herein above comprises the steps of
- a first melt comprising a recycled polymer such as polypropylene, to form a core
- a second melt comprising a polymer, such as polypropylene, and a particulate, opaque additive to form a sheath at least partly enclosing the core
- a third melt comprising a polymer, preferably polypropylene, to form a second sheath at least partly enclosing the first sheath
- Fig. la shows a cross-section of filaments with a first sheath according to an embodiment
- Fig. lb shows a cross-section of filaments with a first sheath and a second sheath according to an embodiment
- Fig. la a number of cross-section of filaments according to an embodiment is shown.
- the filament is a bi-component filament with a first sheath 20 enclosing a core 10.
- the filament’s cross-section is tri-lobal. As can be seen, the thickness if the first sheath 20 varies slightly over the circumference of the filament.
- Fig. lb a number of cross-section of filaments according to an embodiment is shown.
- the filament is a tri-component filament with a first sheath 20, enclosing a core 10, and a second sheath 30, enclosing the first sheath 20.
- the filament’s crosssection is tri-lobal. As can be seen, the thickness of the first sheath 20 and the second sheath 30, respectively, varies slightly over the circumference of the filament.
- the present sheath-core fibers may be spun using conventional fiber-forming equipment.
- separate melt flows of the virgin sheath polypropylene and re-cycled core polypropylene may be fed to a conventional sheath-core spinneret pack (examples are given inter alia in US 5,162,074, US 5,125,818, US 5,344,297 and 5,445,884) where the melt flows are combined to form extruded multi-lobal (e.g., tri-, tetra-, penta- or hexalobal) filaments having sheath and core structures.
- an additional melt flow is fed to the spinneret pack.
- the extruded filaments are quenched, for example with air, in order to solidify the filaments.
- the filaments may then be treated with a finish comprising a lubricating oil or mixture of oils and antistatic agents.
- the thus formed filaments are then combined to form a yam bundle.
- the yam may be drawn and texturized to form a bulked continuous fiber (BCF) yam suitable for e.g. tufting into carpets. Further, the spinning and the drawing may be combined in a single process.
- a one-step method of making BCF is generally known in the art as spin-draw-texturing (SDT).
- a first flat yam (cf. Fig la) of core sheath-core filaments with recycled polypropylene in the core 10 were provided with the following specification:
- Weight ratio core/sheath 60/40
- Polymer in the core 10 recycled polypropylene from A.D. Compound S.p.a. (MFI at 230°C/2.16 kg according to ISO 1133: 26.4 g/10 min; density at 23°C 0.964 g/cm 3 )
- Additives in the core 10 TiO2 (5 wt.%) and carbon black (3 wt.%)
- Polymer in the sheath 20 virgin polypropylene (Metocene MF650Y) from LyondellBasell (MFI at 230°C/2.16 kg according to ISO 1133: 18 g/10 min)
- Additives in the sheath 20 TiO2 (35 wt.%) and red pigment (2 wt.%)
- Linear density filament 12 denier per filament (dpf)
- the yarn was reddish brown had a tenacity of 2.16 and an elongation of 106%
- a second flat yarn (cf. Fig lb) of sheath-sheath-core filaments with recycled polypropylene in the core 10 were provided with the following specification:
- Weight ratio core/sheath/sheath 60/30/10
- Polymer in the core 10 recycled polypropylene MFI at 230°C/2.16 kg according to ISO 1133: 26.4 g/10 min; density at 23°C 0.964 g/cm 3 )
- Polymer in the first sheath 20 virgin polypropylene (Metocene MF650Y) from LyondellBasell (MFI at 230°C/2.16 kg according to ISO 1133: 18 g/10 min)
- Polymer in the second sheath 30 virgin polypropylene (Metocene MF650Y) from LyondellBasell (MFI at 230°C/2.16 kg according to ISO 1133: 18 g/10 min)
- Additives in the second sheath 30 TiO2 (10 wt. %) and yellow pigment (2 wt.%)
- Linear density filament 12 denier per filament (dpf)
- the yarn was greenish and had a tenacity of 2.08 and an elongation of 98%
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Abstract
A filament for a pile yarn. The filament is a multi-component filament, comprising a core (10), at least a first sheath (20) at least partly enclosing the core (10) and optionally a second sheath (30) at least partly enclosing the first sheath (20). The core (10) comprises recycled polypropylene, and the first sheath (20) comprises polypropylene and a particulate, opaque additive.
Description
FILAMENT OF RECYCLED POLYPROPYLENE FOR PILE YARN
Technical field
The present invention relates to a filament of a recycled polymer like polypropylene. Such filaments may be used in yarns for carpets, e.g. carpets comprising a backing and pile comprising tufts of pile yarn extending from the backing.
Background
For long, carpets and rugs have been used as textile floor coverings to provide comfort, durability, safety, and decoration. The terms carpets and rugs are used interchangeably in the art. They may be used to cover the entire floor in a room and fastened thereto. Sometimes, the term carpet is used to denote such a floor covering. The term carpet may however also be used to denote a textile floor covering not fastened and typically not covering the entire floor, in the same manner as the term rug is used.
Various yams are used in producing carpets and mgs. Synthetic as well as natural fibers are used in such yarns. Synthetic fibers used in yarns for carpets and mgs include inter alia polyethyleneterephthalate (PET) fibers and polypropylene (PP) fibers.
Whereas use of re-cycled PET, e.g. from PET -bottles, has become common, recycling of PP has turned more challenging. Re-cycled polyethyleneterephthalate is typically transparent and not strongly discolored and may thus be colored in principle as desired by adding pigment. However, from a cost perspective PET is a more expensive material than PP. This also applies for other polyesters like polylactic acid (PLA). Further, the lower density of PP compared to PET, implies that more PET is needed to get the same yarn specification as with for PP. One of the most commonly used material in carpets is thus PP. Use of re-cycled PP would thus be highly desirable in order to provide more sustainable yams at a low cost.
However, standard re-cycled PP is typically very dark, nearly black. Though there are qualities of re-cycled PP available not being that dark, these are typically more expensive making them less attractive from an economical perspective. Further, processes for purifying (i.e. discoloring) re-cycled PP are known in the art. As purification will add costs, it is less attractive from an economical perspective. The dark color of re-cycled PP hampers its use in providing yarns for textile applications, such as carpets and mgs. By adding pigments to re-cycled PP, the color may be slightly affected. However, the initial dark color still significantly limits the available colors.
Especially, lighter colors may in principle not be obtained. It would this be of interest to provide for replacing virgin PP with re-cycled PP in further applications.
DE202008016836U1 discloses non-woven carpet backing comprising bicomponent binder fibers with a core/sheath structure. The core polymer is PET, whereas the sheath polymer is polyamide 6. By coloring the PET core polymer, the use of core polymers is no longer limited to raw materials with a constant coloration. Contrary to re-cycled PET, a dark constant color is however already at hand for re-cycled PP. Further, in carpet backing a dark material is typically acceptable.
In order to facilitate recycling of PP in filaments for yams for e.g. carpets, it would be desired to provide for use of dark, recycled PP in filaments of various colored, such that flexibility is provided.
Summary
Accordingly, there is according to a first aspect provided a filament for a pile yam. The filament is a multi-component filament comprising a core and at least a first sheath. The first sheath at least partly encloses the core. The core comprises recycled polypropylene and the first sheath comprises polypropylene. Further, the first sheath comprises a particulate, opaque additive. By coating the core of recycled polypropylene being dark (the dark color further varying between different batches) with a sheath comprising a particulate, opaque additive, the color of the core may be masked. Further, the at least a first sheath may, apart from the particulate, opaque additive, comprise a pigment to provide a colored filament. Thus, there is provided for use of dark, recycled polypropylene in filaments of various color.
The particulate, opaque additive is added to mask the color of the underlying core. It is thus preferred if the particulate additive is opaque. Further, the particulate, opaque additive is preferable white, or at least bright, to provide for flexibility in terms of color of the filament. The particulate, opaque additive may be an inorganic additive, such as titanium dioxide or calcium carbonate. According to an embodiment, the particulate, opaque additive is titanium dioxide. The content of the particulate, opaque additive may vary. On the one hand, a high content may improve the masking effect and provide a brighter filament, on the other, a too high content may negatively affect the mechanical properties of the filament, as well as the bonding between the filament and the core. The first sheath may typically comprise 5 to 40 wt.% of the particulate, opaque additive. Thus, it may comprise 5 to 30 wt.% or 10 to 20 wt.% of the particulate, opaque
additive. According to some embodiments, e.g. wherein a lighter color is desired, the first sheath may comprise at least 10 wt.% of the particulate, opaque additive.
As the first sheath is to mask the core, it may constitute 5 to 30 wt.% of the filament. According to some embodiments, it constitutes 10 to 25 wt.% of the filament. The more it constitutes, the better masking effect. However, as one objective is to provide for use of recycled polypropylene, it is preferred if the first sheath is a minor component, i.e. constitutes less than 50 wt.% of the filament. Further, the thickness of the first sheath may vary over its circumference; especially if the cross-section of filament is multi-lobal. In order to mask the core, the first sheath may be at least 0.2 pm thick, such as at least 1.0 pm thick. According to an embodiment, the first sheath is 1.0 to 10.0 pm thick, such as 1.0 to 4.0 pm thick.
Typically, the first sheath encloses the core entirely. However, in some embodiments it may be of interest to cover the circumference of the core only partly, thereby providing a filament with a melange effect (also referred to as heathered effect in the art). The first sheath may thus enclose at least 80%, such as at least 90% or 95%, of the circumference of the core. Further, the first sheath may enclose 80 to 99%, such as 90% or 97%, of the circumference of the core.
In addition to the particulate, opaque additive (e.g. titanium dioxide), the first sheath may comprises a pigment, apart from the particulate, opaque additive. This pigment is typically not white. By adding a pigment, filaments of different colors may be provided. The particulate, opaque additive is typically white. By applying a first sheath to the core, whereby providing a multi-component filament, the particulate, opaque additive and the optional pigment may be localized to the surface of the filament. This implies that less additive has to be used in order to affect the color of the filament. Actually, a corresponding color as for the present multi-component filament is difficult to provide in recycled polypropylene mono-component filament, as a too high amount of the additives may affect the mechanical properties negatively.
However, according to some embodiments, the core may comprises an inorganic particulate, opaque additive, such as titanium dioxide or calcium carbonate. The core may comprise up to 5 wt.% of the inorganic particulate, opaque additive. A too high content of an inorganic particulate, opaque additive may, as already described, affect the mechanical properties of the filament negatively. Further, in order to compensate for a slight color variation between different batches and to provide a uniformly colored core, the core may comprise a dark pigment, such as carbon black.
The first sheath comprises polypropylene. This polypropylene may be virgin polypropylene. Virgin polypropylene does not suffer from being discolored. Further, the polypropylene in the first sheath may be recycled polypropylene. If to use recycled polypropylene in the first sheath, it is preferred if the recycled polypropylene in the first sheath is lighter in its color than the recycled polypropylene in the core. At least for some applications, e.g. in dark filaments, recycled polypropylene could be used in the first sheath. The discoloration of recycled polypropylene varies and lighter qualities are available, tough being a bit more expensive. Use of recycled polypropylene in filaments for carpets may thus be provided for either by using a first sheath comprising virgin polypropylene, or by using a first sheath comprising recycled polypropylene being lighter in its color than the recycled polypropylene in the core.
The present multi-component filament allows for use of darkly colored, recycled polypropylene. It is desired to use as much recycled material as possible in the filament. The core may constitutes at least 40 wt.% of the filament. According to an embodiment, the core constitutes 50 to 85 wt.% of the filament.
According to an embodiment, the multi-component filament further comprises a second sheath at least partly enclosing the first sheath. The second sheath comprises a polymer. By means of multi-component filament with a first and a second sheath, the color of the filament may even further be varied and adjusted. Further, the use of first sheath, masking the color of the core, and a second sheath, coloring the filaments, facilitates the provision of filaments with lighter colors. Further, concentrating pigments to an outermost layer implies the less pigment is required to provide the same color. According to an embodiment, the first sheath comprises a first pigment and the second sheath comprises a second pigment, distinct from the first pigment. By having a first pigment in the first sheath and a second pigment, distinct from the first pigment, in the second sheath, the color of the filament may be varied and adjusted. The apparent color of the filament may not be the same if both pigments are present in the same sheath. Further, the color may be different depending on which pigment is present in the outer sheath.
The polymer in the second sheath may be polypropylene. The polypropylene in the second sheath is typically virgin polypropylene. However, in some alternative embodiments, the polypropylene in the second sheath the second sheath may be, or at least comprise, recycled polypropylene. Similar to the first sheath, it is preferred if recycled polypropylene to be used in the second sheath is lighter in its color than the recycled polypropylene in the core.
According to an embodiment, the second sheath comprises polypropylene. However, while the polymer in the second sheath typically is polypropylene, it may also be another type of polymer, like polyester, such as semi-aromatic polyester (e.g. polyethylene terephthalate) or aliphatic polyamide (e.g. polyamide 6 or polyamide 66). According to an embodiment, the second sheath comprises a polyester, such as a semiaromatic polyester (e.g. polyethylene terephthalate) and/or an aliphatic polyamide (e.g. polyamide 6 or polyamide 66). An outer sheath comprising a polyester, such as a semiaromatic polyester (e.g. polyethylene terephthalate), and/or an aliphatic polyamide (e.g. polyamide 6 or polyamide 66) may provide the multi-component filament with improved moisture management.
Typically, the second sheath comprises a pigment. The pigment is typically not white, unless a whitish fiber is desired. The second sheath may comprises 1 to 20 wt.% of the pigment. Further, the second sheath may optionally, or alternatively, comprise a particulate, opaque additive. The particulate, opaque additive typically is white and may thus serve as white pigment as well. According to an embodiment, the second sheath comprises a particulate, opaque additive, such as titanium dioxide, and a pigment in addition to the particulate, opaque additive. The particulate, opaque additive may be an inorganic particulate, opaque additive, such as titanium dioxide or calcium carbonate. According to an embodiment, the particulate, opaque additive is titanium dioxide. The second sheath may comprise 5 to 40 wt.%, such as such as 5 to 30 wt.% or 10 to 20 wt.%, of the particulate, opaque additive. According to some embodiments, wherein a lighter color is desired, the second sheath may comprise at least 10 wt.% of the particulate, opaque additive.
As the second sheath is to color the filament, it may constitute 5 to 30 wt.% of the filament. According to some embodiments, it constitutes 10 to 25 wt.% of the filament. The more it constitutes, the stronger coloring effect. However, as one objective is to provide for use of recycled polypropylene, it is preferred if the second sheath is a minor component, i.e. constitutes less than 50 wt.% of the filament. Further, the thickness of the second sheath may vary over its circumference; especially if the cross-section of filament is multilobal. In order to color the filament, the second sheath may be at least 0.2 pm thick, such as at least 1.0 pm thick. According to an embodiment, the second sheath is 1.0 to 10.0 pm thick, such as 1.0 to 4.0 pm thick.
Furthermore, both the first and the second sheath affects the color of the resulting filament. In some embodiments, the first sheath constitutes larger proportion of the filament than the second sheath. According to such an embodiment, the first
sheath may constitute 10 to 30 wt.% of the filament, whereas the second sheath may constitute 5 to 20 wt.% of the filament. Provided that the first sheath sufficiently masks the core, the second sheath may be somewhat thinner, still providing the desired color.
Typically, the second sheath encloses the first sheath entirely. However, in some embodiments it may be of interest to cover the circumference of the first sheath only partly, thereby providing a filament with a melange effect . The second sheath may thus enclose at least 80%, such as at least 90% or 95%, of the circumference of the first sheath. Further, the second sheath may enclose 80 to 99%, such as 90% or 97%, of the circumference of the first sheath.
Further, though the polymer in the core typically is recycled polypropylene, the concept of using a first and a second sheath may be applied also in providing filaments of various colors, wherein the core comprise other types of recycled polymers than polypropylene, like a polyester, such as a semi-aromatic polyester (e.g. polyethylene terephthalate) or an aliphatic polyamide (e.g. polyamide 6 or polyamide 66). According to a second aspect, there is thus provided a multi-component filament for a pile yarn. The multi-component filament comprises a core, at a first sheath, at least partly enclosing the core, and a second sheath, at least partly enclosing the first sheath. The core comprises a polymer, typically a recycled polymer. This polymer may be a polyolefin (e.g. polypropylene), a polyester, such as a semi-aromatic polyester (e.g. polyethylene terephthalate), or an aliphatic polyamide (e.g. polyamide 6 or polyamide 66). Similarly, the first sheath comprise a polymer. The first sheath may thus comprise a polyolefin (e.g. polypropylene), an aliphatic polyamide (e.g. polyamide 6 or polyamide 66), or a polyester, such as semi-aromatic polyester (e.g. polyethylene terephthalate). As already outlined herein above, the polymer used in the first sheath is typically a virgin polymer. It may however also be a recycled polymer. If to use a recycled polymer in the first sheath, it is preferred if such recycled polymer is lighter in its color than the recycled polymer in the core. Further, also the second sheath comprises a polymer. The second sheath may thus comprise a polyolefin (e.g. polypropylene), an aliphatic polyamide (e.g. polyamide 6 or polyamide 66), or a polyester, such as semi-aromatic polyester (e.g. polyethylene terephthalate). As already outlined herein above, the polymer used in the second sheath is typically a virgin polymer. It may however also be a recycled polymer. If to use a recycled polymer in the second sheath, it is preferred if such recycled polymer is lighter in its color than the recycled polymer in the core. Furthermore, similar to what already have been described, the first sheath comprises a first particulate, opaque additive. The first particulate, opaque additive may be an
inorganic additive, such as titanium dioxide or calcium carbonate. Preferably, the first particulate, opaque additive is titanium dioxide. In a corresponding manner, the second sheath does optionally comprise a pigment and/or a second particulate, opaque additive. The second particulate, opaque additive, if present, may be an inorganic additive, such as titanium dioxide or calcium carbonate. Preferably, the second particulate, opaque additive is titanium dioxide.
By means of multi-component filament with a first and a second sheath, the color of the filament may even further be varied and adjusted. Further, the use of first sheath, masking the color of the core, and a second sheath, coloring the filaments, facilitates the provision of filaments with lighter colors. Further, concentrating pigments to an outermost layer implies the less pigment is required to provide the same color. According to an embodiment, the first sheath comprises a first pigment and the second sheath comprises a second pigment, distinct from the first pigment. By having a first pigment in the first sheath and a second pigment, distinct from the first pigment, in the second sheath, the color of the filament may be varied and adjusted. The apparent color of the filament may not be the same if both pigments are comprised in the same sheath. Further, the color may be different, depending on which pigment is present in the outer sheath.
Preferred embodiments of the first and second aspect of the invention are closely related to each other. Thus, the first sheath may comprises 5 to 40 wt.%, such as 5 to 30 wt.% or 10 to 20 wt.%, of the particulate, opaque additive. Further, the second sheath may comprise 1 to 20 wt.% of the pigment and/or 5 to 30 wt.%, such as 5 to 30 wt.% or 10 to 20 wt.%, of the particulate, opaque additive. Furthermore, the core may constitutes at least 40 wt.%, such as 50 to 85 wt.%, of the filament. The first sheath may constitute 5 to 30 wt.%, such as 10 to 25 wt.%, of the filament. The second sheath may constitute 5 to 30 wt.%, such as 10 to 25 wt.%, of the filament.
In a corresponding manner as described for the first aspect, the thickness of the first sheath may in embodiments of according to the second aspect, vary over its circumference; especially if the cross-section of filament is multilobal. In order to mask the core, the first sheath may be at least 0.2 pm thick, such as at least 1.0 pm thick. According to an embodiment, the first sheath is 1.0 to 10.0 pm thick, such as 1.0 to 4.0 pm thick. Further, the first sheath typically encloses the core entirely. However, in some embodiments it may be of interest to cover the circumference of the core only partly, thereby providing a filament with a melange effect. The first sheath may thus enclose at least 80%, such as at least 90% or 95%, of the circumference of the core. Further, the
first sheath may enclose 80 to 99%, such as 90% or 97%, of the circumference of the core. Similarly, the second sheath may be at least 0.2 pm thick, such as at least 1.0 pm thick. According to an embodiment, the second sheath is 1.0 to 10.0 gm thick, such as 1.0 to 4.0 pm thick. Furthermore, the second sheath typically encloses the first sheath entirely. However, in some embodiments it may be of interest to cover only the circumference of the first sheath partly, thereby providing a filament with a melange effect. The second sheath may thus enclose at least 80%, such as at least 90% or 95%, of the circumference of the first sheath. Further, the second sheath may enclose 80 to 99%, such as 90% or 97%, of the circumference of the first sheath.
Turning to preferred features equally applicable to both aspects of the invention as outlined herein above, it is to be noted that the cross-section of the multicomponent filament may have at least two lobes. The cross-section of the multicomponent filament may thus be bi-lobal, tri-lobal, or quad-lobal. The cross-section of the filament does not only directly affect mechanical properties. Especially when used in carpets, also other properties like the hand-feel and touch are affected and typically improved, as described in WO 2022/005383. For a filament with a bi-lobal crosssection, it is preferred if the waist is concave. For a filament with tri-lobal or the quad- lobal cross-section, it is preferred if the sides are concave. The present is not limited to a given size or diameter. The liner mass density of the filament may be in the range 1 dtex to 20 dtex.
Further, additional additives may be present in the first sheath and/or the second sheath. According to one embodiment, a reflective additive, such as glass beads, glitter, or crystal, is present in the first sheath and/or the second sheath. The reflective additive may be a retro-reflective additive, such as glass beads. Further, additives making the filament, or a pile yarn comprising the filament, changing color with different light sources may be added. According to an embodiment, the additive is a photochromic material. Photochromic materials change color when exposed to e.g. UV light. The photochromic material used is typically reversible. Some common examples of photochromic materials include silver halides, spirooxazines and naphthopyrans. In some embodiments, a reflective additive or a photochromic material is used instead of a pigment in the second sheath.
According to a third aspect, there is provided a multi-component filament for a pile yarn. The multi-component filament comprises a core, at a first sheath, at least partly enclosing the core, and a second sheath, at least partly enclosing the first sheath. The core comprises a polymer, typically a recycled polymer. This polymer may be a
polyolefin (e.g. polypropylene), polyester, such as a semi-aromatic polyester (e.g. polyethylene terephthalate), or an aliphatic polyamide (e.g. polyamide 6 or polyamide 66). Similarly, the first sheath comprise a polymer. The first sheath may thus comprise a polyolefin (e.g. polypropylene), an aliphatic polyamide (e.g. polyamide 6 or polyamide 66), or a polyester, such as a semi-aromatic polyester (e.g. polyethylene terephthalate). As already outlined herein above, the polymer used in the first sheath is typically a virgin polymer. It may however also be a recycled polymer. If to use a recycled polymer in the first sheath, it is preferred if such recycled polymer is lighter in its color than the polymer in the core. Further, also the second sheath comprises a polymer. The second sheath may thus comprise a polyolefin (e.g. polypropylene), an aliphatic polyamide (e.g. polyamide 6 or polyamide 66), or a polyester, such as a semi-aromatic polyester (e.g. polyethylene terephthalate). As already outlined herein above, the polymer used in the second sheath is typically a virgin polymer. It may however also be a recycled polymer. If to use a recycled polymer in the second sheath, it is preferred if such recycled polymer is lighter in its color than the polymer in the core. Further, the first sheath optionally comprises a first additive. The second sheath comprises a second additive. The second additive is distinct from the first additive if present. By having distinct additives in separate sheaths, the properties of the filament may be improved and tuned. Further, the presence of the first sheath will separate the additive in the second sheath from the core. It will be appreciated that each sheath may comprise several additives, and it is sufficient if one of these additives is distinct between the first and second sheaths.
Preferred embodiments of the second and third aspect of the invention are closely related to each other. Thus, the core of the filament may constitute at least 40 wt.%, such as 50 to 85 wt.%, of the filament. Further, the first sheath may constitute 5 to 30 wt.%, such as 10 to 25 wt.%, of the filament. Furthermore, the second sheath may constitute 5 to 30 wt.%, such as 10 to 25 wt.%, of the filament. The first sheath may be at least 0.2 pm thick, such as at least 1.0 pm thick. The first sheath may enclose at least 80%, such as at least 90% or 95%, of the circumference of the core. According to an embodiment, the first sheath encloses the core entirely. The second sheath may be at least 0.2 pm thick, such as at least 1.0 pm thick. The second sheath may enclose at least 80%, such as at least 90% or 95%, of the circumference of the first sheath. According to an embodiment, the second sheath encloses the first sheath entirely.
Various polymers may as already outlined, be used in the filament. Further, various combinations of polymers be used. According to an embodiment, the polymer
in the first sheath is distinct from the polymer in the second sheath. According to another embodiment, the polymer in the first sheath is the same type of polymer as the polymer in the second sheath. Further, the polymer in the core may according to an embodiment be distinct from the polymer in the first sheath. Alternatively, the polymer in the core may be the same type of polymer as the polymer in the first sheath.
The cross-section of the multi-component filament has at least two lobes. According to an embodiment, its cross-section is bi-lobal, tri-lobal or quad-1 obal. According to an embodiment, the waist of a bi-lobal cross-section is concave and the sides of a tri-lobal and/or a quad-lobal cross-section is concave.
The liner mass density of the filament may be 1 dtex to 20 dtex.
According to a fourth aspect, there is provided a yarn, such as a pile yam. The yam comprises at least two filaments, but typically further filaments are present, of the type described herein above. Further, the yarn may be drawn and texturized to form a bulked continuous fiber (BCF) yam. Thus, the yarn may be bulked continuous fiber (BCF) yarn. Manufacture of bi-component continuous filaments having a sheath-core arrangement for use in e.g. bulk continuous filament (BCF) fibers and floor coverings, such as mats, mgs, and carpets is known in the art (see for example US2018282908A1).
According to a fifth aspect, there is provided a staple fiber. The staple fiber is obtainable by cutting the filament of the type described herein above into staple fibers. The staple fibers may be 20 to 100 mm long, such as 30 to 70 mm long.
According to a sixth aspect, there is provided a carpet or a mg. The carpet or the mg comprises the yam described herein above, or the staple fibers described herein above.
According to a seventh aspect, there is provided a method of producing a filament according to the first, or the second, aspect of the invention as disclosed herein above. The method comprises the steps of
- extmding a first melt comprising a recycled polymer such as polypropylene, to form a core, a second melt comprising a polymer, such as polypropylene, and a particulate, opaque additive to form a sheath at least partly enclosing the core, and optionally a third melt comprising a polymer, preferably polypropylene, to form a second sheath at least partly enclosing the first sheath;
- drawing and solidifying the filament; and
- optionally texturing and/or stretching the filaments.
Further aspects of such an embodiment is disclosed inter alia in WO 2022/005383.
Although the present invention has been described above with reference to specific embodiments, it is not intended to be limited to the specific form set forth herein. Rather, the invention is limited only by the accompanying claims and other embodiments than the specific embodiments described above are equally possible within the scope of these appended claims.
In the claims, the term "comprises/comprising" does not exclude the presence of other elements or steps. Additionally, although individual features may be included in different claims, these may possibly advantageously be combined, and the inclusion in different claims does not imply that a combination of features is not feasible and/or advantageous.
In addition, singular references do not exclude a plurality. The terms "a", "an", “first”, “second” etc. do not preclude a plurality.
Brief description of the drawings
These and other aspects, features and advantages of which the invention is capable of will be apparent and elucidated from the following description of embodiments of the present invention, reference being made to the accompanying drawings, in which:
Fig. la shows a cross-section of filaments with a first sheath according to an embodiment;
Fig. lb shows a cross-section of filaments with a first sheath and a second sheath according to an embodiment;
Detailed description
In Fig. la, a number of cross-section of filaments according to an embodiment is shown. The filament is a bi-component filament with a first sheath 20 enclosing a core 10. The filament’s cross-section is tri-lobal. As can be seen, the thickness if the first sheath 20 varies slightly over the circumference of the filament.
In Fig. lb, a number of cross-section of filaments according to an embodiment is shown. The filament is a tri-component filament with a first sheath 20, enclosing a core 10, and a second sheath 30, enclosing the first sheath 20. The filament’s crosssection is tri-lobal. As can be seen, the thickness of the first sheath 20 and the second sheath 30, respectively, varies slightly over the circumference of the filament.
Experimental
Filament spinning and yarn drawing
The present sheath-core fibers may be spun using conventional fiber-forming equipment. Thus, for example, separate melt flows of the virgin sheath polypropylene and re-cycled core polypropylene may be fed to a conventional sheath-core spinneret pack (examples are given inter alia in US 5,162,074, US 5,125,818, US 5,344,297 and 5,445,884) where the melt flows are combined to form extruded multi-lobal (e.g., tri-, tetra-, penta- or hexalobal) filaments having sheath and core structures. In embodiments including two sheaths, an additional melt flow is fed to the spinneret pack.
After the extrusion, the extruded filaments are quenched, for example with air, in order to solidify the filaments. The filaments may then be treated with a finish comprising a lubricating oil or mixture of oils and antistatic agents. The thus formed filaments are then combined to form a yam bundle.
In a subsequent step, the yam may be drawn and texturized to form a bulked continuous fiber (BCF) yam suitable for e.g. tufting into carpets. Further, the spinning and the drawing may be combined in a single process. A one-step method of making BCF is generally known in the art as spin-draw-texturing (SDT).
Example 1
A first flat yam (cf. Fig la) of core sheath-core filaments with recycled polypropylene in the core 10 were provided with the following specification:
Weight ratio core/sheath: 60/40
Polymer in the core 10: recycled polypropylene from A.D. Compound S.p.a. (MFI at 230°C/2.16 kg according to ISO 1133: 26.4 g/10 min; density at 23°C 0.964 g/cm3)
Additives in the core 10: TiO2 (5 wt.%) and carbon black (3 wt.%)
Polymer in the sheath 20: virgin polypropylene (Metocene MF650Y) from LyondellBasell (MFI at 230°C/2.16 kg according to ISO 1133: 18 g/10 min)
Additives in the sheath 20: TiO2 (35 wt.%) and red pigment (2 wt.%)
Linear density filament: 12 denier per filament (dpf)
Linear density yam: 1700 dtex
The yarn was reddish brown had a tenacity of 2.16 and an elongation of 106%
Example 2
A second flat yarn (cf. Fig lb) of sheath-sheath-core filaments with recycled polypropylene in the core 10 were provided with the following specification:
Weight ratio core/sheath/sheath: 60/30/10
Polymer in the core 10: recycled polypropylene MFI at 230°C/2.16 kg according to ISO 1133: 26.4 g/10 min; density at 23°C 0.964 g/cm3)
Additives in the core 10: carbon black (3 wt.%)
Polymer in the first sheath 20: virgin polypropylene (Metocene MF650Y) from LyondellBasell (MFI at 230°C/2.16 kg according to ISO 1133: 18 g/10 min)
Additives in the first sheath 20: TiO2 (15 wt.%)
Polymer in the second sheath 30: virgin polypropylene (Metocene MF650Y) from LyondellBasell (MFI at 230°C/2.16 kg according to ISO 1133: 18 g/10 min)
Additives in the second sheath 30: TiO2 (10 wt. %) and yellow pigment (2 wt.%)
Linear density filament: 12 denier per filament (dpf)
Linear density yam: 1800 dtex
The yarn was greenish and had a tenacity of 2.08 and an elongation of 98%
Claims
1. A filament for a pile yam, wherein the filament is a multi-component filament comprising a core (10) and at least a first sheath (20) at least partly enclosing the core (10), said core (10) comprising recycled polypropylene, wherein said first sheath (20) comprises polypropylene and a particulate, opaque additive.
2. The filament according to claim 1, wherein the particulate, opaque additive is an inorganic additive, such as titanium dioxide or calcium carbonate; preferably the particulate, opaque additive being titanium dioxide.
3. The filament according to claim 1 or 2, wherein the first sheath (20) comprises 5 to 40 wt.%, such as 5 to 30 wt.% or 10 to 20 wt.%, of the particulate, opaque additive.
4. The filament according to any one of claims 1 to 3, wherein the first sheath (20), in addition to the particulate, opaque additive, further comprises a pigment; and/or the core (10) comprises up to 5 wt.% of a particulate, opaque additive, preferably an inorganic particulate, opaque additive, such as titanium dioxide or calcium carbonate, and/or the core (10) comprises a pigment, such as carbon black.
5. The filament according to any one of claims 1 to 4, wherein the core (10) constitutes at least 40 wt.%, such as 50 to 85 wt.%, of the filament.
6. The filament according to any one of claims 1 to 5, wherein the multicomponent filament further comprises a second sheath (30) at least partly enclosing the first sheath (20), said second sheath (30) comprising a polymer, preferably said polymer being polypropylene.
7. The filament according to claim 6, wherein the second sheath (30) comprises a pigment and/or a particulate, opaque additive, preferably an inorganic particulate, opaque additive, such as titanium dioxide or calcium carbonate.
8. The filament according to claim 7, wherein the second sheath (30) comprises 1 to 20 wt.% of the pigment and/or 5 to 40 wt.%, such as such as 5 to 30 wt.% or 10 to 20 wt.%, of the particulate, opaque additive.
9. The filament according to any one of claims 1 to 8, wherein:
- the first sheath (20) constitutes 5 to 30 wt.%, such as 10 to 25 wt.%, of the filament; and/or
- the first sheath (20) is at least 0.2 pm thick, such as at least 1.0 pm thick; and/or
- the first sheath (20) encloses at least 80%, such as at least 90% or 95%, of the circumference of the core (10); preferably the first sheath (20) encloses the core (10) entirely; and/or
- the second sheath (30), if present, constitutes 5 to 30 wt.%, such as 10 to 25 wt.%, of the filament; and/or
- the second sheath (30), if present, is at least 0.2 pm thick, such as at least 1.0 pm thick; and/or
- the second sheath (30), if present, encloses at least 80%, such as at least 90% or 95%, of the circumference of the first sheath (20); preferably the second sheath (30) encloses the first sheath (20) entirely.
10. The filament according to any one of claims 1 to 9, wherein the first sheath (20) comprises virgin polypropylene, or wherein the first sheath (20) comprises recycled polypropylene; preferably the recycled polypropylene in the first sheath (20) being lighter in its color than the recycled polypropylene in the core (10); and/or wherein the second sheath (30), if present, comprises virgin polypropylene, or wherein the second sheath (30) comprises recycled polypropylene; preferably the recycled polypropylene in the second sheath (30) being lighter in its color than the recycled polypropylene in the core (10).
11. A filament for a pile yarn, wherein the filament is a multi-component filament, comprising a core (10), comprising a polymer, at least a first sheath (20) at least partly enclosing the core (10), and a second sheath (30) at least partly enclosing the first sheath (20), wherein said first sheath (20) comprises a polymer and a first particulate, opaque additive, and wherein said second sheath (30) optionally comprises a polymer, a pigment, and/or a second particulate, opaque additive.
12. The filament according to claim 11, wherein the first particulate, opaque additive is an inorganic additive, such as titanium dioxide or calcium carbonate; preferably the additive being titanium dioxide; and wherein the second particulate, opaque additive, if present, is an inorganic additive, such as titanium dioxide or calcium carbonate; preferably the additive being titanium dioxide.
13. The filament according to claim 11 or 12, wherein:
- the first sheath (20) comprises 5 to 40 wt.%, such as 5 to 30 wt.% or 10 to 20 wt.%, of the particulate, opaque additive; and/or
- the second sheath (30) comprises 1 to 20 wt.% of the pigment, and/or 5 to 30 wt.%, such as 5 to 30 wt.% or 10 to 20 wt.%, of the particulate, opaque additive.
14. The filament according to any one of claims 11 to 13, wherein:
- the core (10) constitutes at least 40 wt.%, such as 50 to 85 wt.%, of the filament; and/or
- the first sheath (20) constitutes 5 to 30 wt.%, such as 10 to 25 wt.%, of the filament; and/or
- the second sheath (30) constitutes 5 to 30 wt.%, such as 10 to 25 wt.%, of the filament.
15. The filament according to any one of claims 11 to 14, wherein:
- the first sheath (20) is at least 0.2 pm thick, such as at least 1.0 pm thick; and/or
- the first sheath (20) encloses at least 80%, such as at least 90% or 95%, of the circumference of the core (10); preferably the first sheath (20) encloses the core (10) entirely; and/or
- the second sheath (30) is at least 0.2 pm thick, such as at least 1.0 pm thick; and/or
- the second sheath (30) encloses at least 80%, such as at least 90% or 95%, of the circumference of the first sheath (20); preferably the second sheath (30) encloses the first sheath (20) entirely.
16. The filament according to any one of claims 11 to 15, wherein:
- the polymer in the core (10) is recycled polyolefin, recycled aliphatic polyamide, or recycled polyester, such as recycled semi-aromatic polyester; preferably the polymer in the core (10) being recycled polypropylene; and/or
- the polymer in the first sheath (20) is polyolefin, aliphatic polyamide, or polyester, such as semi-aromatic polyester; preferably the polymer in the first sheath (20) being polypropylene; and/or
- the polymer in the second sheath (30) is polyolefin, aliphatic polyamide, or polyester, such as semi-aromatic polyester; preferably the polymer in the second sheath (30) being polypropylene.
17. The filament according to any one of claims 1 to 16, wherein the crosssection of the multi-component filament has at least two lobes, preferably the crosssection being bi-lobal, tri-lobal or quad-lobal; more preferably the waist of the bi-lobal cross-section being concave and the sides of the tri-lobal and/or the quad-lobal crosssection being concave.
18. The filament to any one of claims 1 to 16, wherein the liner mass density of the filament is 1 dtex to 20 dtex.
19. A filament for a pile yarn, wherein the filament is a multi-component filament, comprising a core (10), the core (10) comprising a polymer, at least a first sheath (20) at least partly enclosing the core (10), and a second sheath (30) at least partly enclosing the first sheath (20), wherein said first sheath (20) comprises a polymer and optionally a first additive, and wherein said second sheath (30) comprises a polymer and a second additive, said second additive being distinct from the first additive.
20. The filament according to claim 19, wherein the polymer in the core (10) is a recycled polymer.
21. The filament according to any one of claims 19 to 20, wherein:
- the core (10) constitutes at least 40 wt.%, such as 50 to 85 wt.%, of the filament; and/or
- the first sheath (20) constitutes 5 to 30 wt.%, such as 10 to 25 wt.%, of the filament; and/or
- the second sheath (30) constitutes 5 to 30 wt.%, such as 10 to 25 wt.%, of the filament.
22. The filament according to any one of claims 19 to 21, wherein:
- the first sheath (20) is at least 0.2 gm thick, such as at least 1.0 gm thick; and/or
- the first sheath (20) encloses at least 80%, such as at least 90% or 95%, of the circumference of the core (10); preferably the first sheath (20) encloses the core (10) entirely; and/or
- the second sheath (30) is at least 0.2 pm thick, such as at least 1.0 pm thick; and/or
- the second sheath (30) encloses at least 80%, such as at least 90% or 95%, of the circumference of the first sheath (20); preferably the second sheath (30) encloses the first sheath (20) entirely.
23. The filament according to any one of claims 19 to 22, wherein:
- the polymer in the core (10) is recycled polyolefin, recycled aliphatic polyamide, or recycled polyester, such as a semi-aromatic polyester; preferably the polymer in the core (10) being recycled polypropylene; and/or
- the polymer in the first sheath (20) is polyolefin, aliphatic polyamide, or a polyester, such as a semi-aromatic polyester; and/or
- the polymer in the second sheath (30) is polyolefin, aliphatic polyamide, or a polyester, such as a semi-aromatic polyester.
24. The filament according to any one of claims 19 to 23, wherein the polymer in the first sheath (20) is distinct from the polymer in the second sheath (30).
25. The filament according to any one of claims 19 to 23, wherein the polymer in the first sheath (20) is the same type of polymer as the polymer in the second sheath (30).
26. The filament according to any one of claims 19 to 25, wherein the polymer in the core (10) is distinct from the polymer in the first sheath (20).
27. The filament according to any one of claims 19 to 25, wherein the polymer in the core (10) is the same type of polymer as the polymer in the first sheath (20).
28. The filament according to any one of claims 19 to 27, wherein the crosssection of the multi-component filament has at least two lobes, preferably the crosssection being bi-lobal, tri-lobal or quad-lobal; more preferably the waist of the bi-lobal cross-section being concave and the sides of the tri-lobal and/or the quad-lobal crosssection being concave.
29. The filament to any one of claims 19 to 28, wherein the liner mass density of the filament is 1 dtex to 20 dtex.
30. A yam comprising at least two filaments according to any one of claims 1 to 29.
31. A staple fiber, wherein the staple fiber is obtainable by cutting the filament according to any one of claims 1 to 29 into staple fibers; preferably the staple fibers being 20 to 100 mm long, such as 30 to 70 mm long.
32. A carpet or a rug comprising the yarn according claim 30, or the staple fibers according to claim 31.
33. A method of producing a filament according to any one of claims 1 to 29, wherein the method comprises the steps of
- extruding a first melt comprising recycled polypropylene to form a core (10), a second melt comprising polypropylene and optionally a particulate, opaque additive to form a sheath (20) at least partly enclosing the core (10), and optionally a third melt comprising a polymer, preferably polypropylene, to form a second sheath (30) at least partly enclosing the first sheath (20);
- drawing and solidifying the filament; and
- optionally texturing and/or stretching the filaments.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
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SE2250796 | 2022-06-28 | ||
SE2250796-6 | 2022-06-28 |
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WO2024003162A1 true WO2024003162A1 (en) | 2024-01-04 |
Family
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Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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PCT/EP2023/067693 WO2024003162A1 (en) | 2022-06-28 | 2023-06-28 | Filament of recycled polypropylene for pile yarn |
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WO (1) | WO2024003162A1 (en) |
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US5162074A (en) | 1987-10-02 | 1992-11-10 | Basf Corporation | Method of making plural component fibers |
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JP2003129329A (en) * | 2001-10-19 | 2003-05-08 | Mitsubishi Rayon Co Ltd | Recycled polypropylene fiber and method of producing the same |
DE202008016836U1 (en) | 2008-12-22 | 2009-02-26 | Colbond B.V. | Fleece backing |
US20170002116A1 (en) * | 2015-06-30 | 2017-01-05 | The Procter & Gamble Company | Articles of Reclaimed Polypropylene Compositions |
US20180282908A1 (en) | 2017-03-29 | 2018-10-04 | Welspun Flooring Limited | Manufacture of bi-component continuous filaments and articles made therefrom |
WO2022005383A1 (en) | 2020-07-02 | 2022-01-06 | Ikea Supply Ag | A carpet, a carpet pile yarn, and a method for producing the same |
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2023
- 2023-06-28 WO PCT/EP2023/067693 patent/WO2024003162A1/en unknown
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US5162074A (en) | 1987-10-02 | 1992-11-10 | Basf Corporation | Method of making plural component fibers |
US5344297A (en) | 1987-10-02 | 1994-09-06 | Basf Corporation | Apparatus for making profiled multi-component yarns |
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US5445884A (en) | 1992-06-18 | 1995-08-29 | Basf Corporation | Multi-lobal composite filaments with reduced stainability |
JP2003129329A (en) * | 2001-10-19 | 2003-05-08 | Mitsubishi Rayon Co Ltd | Recycled polypropylene fiber and method of producing the same |
DE202008016836U1 (en) | 2008-12-22 | 2009-02-26 | Colbond B.V. | Fleece backing |
US20170002116A1 (en) * | 2015-06-30 | 2017-01-05 | The Procter & Gamble Company | Articles of Reclaimed Polypropylene Compositions |
US20180282908A1 (en) | 2017-03-29 | 2018-10-04 | Welspun Flooring Limited | Manufacture of bi-component continuous filaments and articles made therefrom |
WO2022005383A1 (en) | 2020-07-02 | 2022-01-06 | Ikea Supply Ag | A carpet, a carpet pile yarn, and a method for producing the same |
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