WO2023288162A1 - Procédés de fonctionnement de systèmes d'élimination d'hydrocarbures dans des courants de gaz naturel - Google Patents

Procédés de fonctionnement de systèmes d'élimination d'hydrocarbures dans des courants de gaz naturel Download PDF

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Publication number
WO2023288162A1
WO2023288162A1 PCT/US2022/072897 US2022072897W WO2023288162A1 WO 2023288162 A1 WO2023288162 A1 WO 2023288162A1 US 2022072897 W US2022072897 W US 2022072897W WO 2023288162 A1 WO2023288162 A1 WO 2023288162A1
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Prior art keywords
stream
column
natural gas
methane
produce
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PCT/US2022/072897
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English (en)
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Yijun Liu
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Exxonmobil Upstream Research Company
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Publication of WO2023288162A1 publication Critical patent/WO2023288162A1/fr

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    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
    • F25J1/0002—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the fluid to be liquefied
    • F25J1/0022—Hydrocarbons, e.g. natural gas
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
    • F25J1/003—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production
    • F25J1/0032—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using the feed stream itself or separated fractions from it, i.e. "internal refrigeration"
    • F25J1/0042—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using the feed stream itself or separated fractions from it, i.e. "internal refrigeration" by liquid expansion with extraction of work
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    • F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
    • F25J1/003—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production
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    • F25J1/0214—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process using a multi-component refrigerant [MCR] fluid in a closed vapor compression cycle as a dual level refrigeration cascade with at least one MCR cycle
    • F25J1/0215—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process using a multi-component refrigerant [MCR] fluid in a closed vapor compression cycle as a dual level refrigeration cascade with at least one MCR cycle with one SCR cycle
    • F25J1/0216—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process using a multi-component refrigerant [MCR] fluid in a closed vapor compression cycle as a dual level refrigeration cascade with at least one MCR cycle with one SCR cycle using a C3 pre-cooling cycle
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    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2280/00—Control of the process or apparatus
    • F25J2280/02—Control in general, load changes, different modes ("runs"), measurements

Definitions

  • the invention relates to methods for increasing ethane and non-freezing heavier hydrocarbons recovery in natural gas streams for the liquefaction of natural gas to form liquefied natural gas (LNG), and in particular, utilizing scrub columns to treat the natural gas feedstreams.
  • LNG liquefied natural gas
  • Natural gas can contain a wide range of compositions of undesirable species which are capable of forming solids during the cryogenic process of liquefying natural gas. Such species are referred to as “freezable species” and the solids formed of the freezable species are referred to as “freezable solids”.
  • Freezable species and other contaminants which are not removed prior to entering the cryogenic LNG cooling vessel precipitate and accumulate on the cold surfaces of the heat exchangers and other equipment, eventually rendering these items inoperable.
  • the cooling vessel When fouling has reached a sufficient level, the cooling vessel must be taken off-line for the fouling to be removed. In the process, the cooling vessel, baffles or pipework can be damaged which only encourages further fouling in the next production cycle.
  • solids condensing on metal surfaces form an insulating film reducing thermal efficiency of the heat exchanger.
  • a pre-treatment of the natural gas is required to remove the freezable species and other contaminants prior to the natural gas feed stream being directed to the cooling stages to cause liquefaction.
  • the CO2 composition can range between 0.5% to 30% and can be as high as 70%.
  • the level of CO2 present in the natural gas is typically reduced down to the level of 50 to 125 ppm prior to the natural gas feed stream being directed to liquefaction.
  • Another of the freezable species namely hydrogen sulphide (H2S)
  • H2S hydrogen sulphide
  • One of the methods typically used to remove the freezable species and other contaminants from the natural gas feed stream is a chemical reaction using reversible absorption processes such as absorption with an amine solvent.
  • feed gas is required to be conditioned to remove heavy hydrocarbons which would freeze under cryogenic condition such as aromatics and long chain alkanes.
  • Heavy hydrocarbons typically C5+
  • a cryogenic distillation column is required, with cooling provided from the main refrigerant cycle. This can be an expensive and a complex process, especially if the removed components are required for refrigerant make-up in a Mixed Refrigerant (MR) cycle.
  • MR Mixed Refrigerant
  • the gas conditioning can involve deep Natural Gas Liquid (NGL) recovery which not only removes freezing heavies but also extracts C2 and Liquefied Petroleum Gas (LPG) to generate MR makeups via the downstream deethanizer, depropanizer and debutanizer.
  • NNL Natural Gas Liquid
  • LPG Liquefied Petroleum Gas
  • MR components can be made up from other resources such as existing C2/C3/C4 streams in “brownfield” expansion projects (i.e., existing plants) or external importing where logistics are convenient or it is critical to simplify downstream processing, it is desired to minimize non-freezing C2 + slip to the scrub column bottom but ideally only targeting to remove freezing heavies.
  • feed gas composition changes e.g., from rich to lean and/or higher benzene to lower benzene
  • the required condenser temperature will require a change accordingly to generate sufficient reflux to meet the heavy (freezing) component specifications in the scrub column overhead stream.
  • a typical scrub system is composed of three levels of C3 refrigerant to pre cool feed to -34°C, and then use MR cooling to generate reflux for the scrub column.
  • Methane is the main component of natural gas, usually accounting for 70%-90% of the total volume produced.
  • lean gas refers to Natural Gas that contains a few or no liquefiable liquid hydrocarbons, wherein gas typically composes of 90% or higher methane. Reboiler is used at the bottom to generate stripping gas.
  • a lean feed gas stream 3 is pre-cooled in three heat exchangers (5, 7 and 9) in series and then feeds a fractionation column 11.
  • the pre-cooled and partially condensed gas is then fractionated to a heavier bottom stream 13 and a lighter overhead stream 19.
  • the heavier bottom stream 13 is heated in a reboiler 15, generating a stripping gas 17 returning back to the column 11 and a liquid stream 14.
  • Stream 19 is then routed to a main cryogenic heat exchanger (MCHX) 29 where it is further cooled and partially condensed to a two phase stream 23.
  • MCHX main cryogenic heat exchanger
  • the stream 23 then separates in a reflux drum 21 to a reflux liquid stream 25 and a vapor overhead stream 27.
  • the stream 25 returns to column 11 to absorb a heavy freezing component and wash down these components to the bottom.
  • the column operates in such a way that the stream 27 is essentially free of freezing heavy hydrocarbons and it will be routed to MCHX 29 to produce an LNG stream 31.
  • the bottom stream 33 in FIG. IB (also 14 in FIG. 1A) from the reboiler 15 contains heavy hydrocarbons is then routed to a stabilization column 35, where it separates into a heavier bottom stream 59 at the bottom of the column 35 and an overhead stream 37 at the overhead.
  • the heavier bottom stream 59 is heated in a reboiler 61, generating a stripping gas 63 returning back to the column 35 and a stabilized liquid stream 57.
  • Stream 37 is then cooled in a heat exchanger 39 to partially condense to stream 41 and then separate in vessel 43 to vapor stream 45 and reflux stream 55.
  • Stream 45 is further cooled against refrigerant in heat exchanger 47 and partially condensed to stream 49.
  • Stream 49 is then separated inside vessel 51 to vapor stream 53 and liquid stream 67. Depending on the flow rates of vapor stream 53 and liquid stream 67, they are either routed for LNG production or used as fuel.
  • a typical scrub system is composed of two levels of C3 refrigerant. It uses LLP (Low Pressure) C3 for reflux generation and reboiler is used to generate stripping gas.
  • “rich gas” refers to a gas containing heavier hydrocarbons than a lean gas, where the gas is typically composed of lower than 90% methane.
  • a rich gas configuration 200 is provided.
  • a rich feed gas stream 201 is pre- cooled in two heat exchangers 203 and 205 in series to produce a pre-cooled stream 207 and then feeds into a fractionation column 209 to produce a pre-cooled and partially condensed gas.
  • the pre-cooled and partially condensed gas is then fractionated to a heavier bottom stream 225 and a lighter overhead stream 211.
  • the heavier bottom stream 225 is heated in a reboiler 227, generating a stripping gas 229 returning back to the column 209 and a liquid stream 228.
  • the lighter overhead stream 211 is then routed to an overhead condenser 213 where it is further cooled and partially condensed to a two phase stream which then separates in a reflux drum 215 to a reflux liquid stream 217 and a vapor overhead stream 219.
  • the reflux liquid stream 217 returns to column 209 to absorb heavy freezing components and wash down these components to the bottom of the column 209.
  • the column 209 operates in such a way that the stream 219 is essentially free of freezing heavy hydrocarbons and it will be routed to MCHX 221 to produce an LNG stream 223.
  • the bottom stream 228 in FIG. 2 from the reboiler 227 contains heavy hydrocarbons is routed to a stabilization system as shown in FIG. IB.
  • the invention provides for a method for operating a hydrocarbon removal system, the method comprising the steps of: (a) separating at least a portion of a natural gas stream to produce a split stream and a separated natural gas stream; (b) cooling at least a portion of the separated natural gas feed stream in one or more heat exchangers to form a pre-cooled feed stream; (c) feeding the pre-cooled feed stream into a column, the column comprising an upper section, a mid-section, and a lower section; (d) separating a methane-rich overhead stream and a bottom stream from a C5 + hydrocarbon-rich mixture in the upper section of the column; (e) cooling the methane-rich overhead stream in a first heat exchanger to produce a first cooled methane-rich stream; (f) subsequently, (i) feeding the first cooled methane-rich stream to a reflux drum to produce a reflux stream; and/or (ii) feeding the first cooled methane-rich
  • the invention provides for a method for operating a hydrocarbon removal system, the method comprising the steps of: (a) separating at least a portion of a natural gas stream to produce a split stream and a separated natural gas stream; (b) cooling at least a portion of the separated natural gas feed stream in a single heat exchanger to form a pre cooled feed stream; (c) feeding the pre-cooled feed stream into a column, the column comprising an upper section, a mid-section, and a lower section; (d) separating a methane-rich overhead stream and a bottom stream from a C5 + hydrocarbon-rich mixture in the upper section of the column; (e) cooling the methane-rich overhead stream in the single heat exchanger to produce a two-phase stream; (f) feeding the two-phase stream into a reflux drum to produce a second overhead stream and a reflux stream; and (g) feeding the second overhead stream into a Main Cryogenic Heat Exchanger (MCHX) of a liquef
  • MCHX Main Cryogenic Heat
  • FIG. l is a schematic representation for a system including a scrub column configured for lean feed gas in accordance with the prior art.
  • FIG. 2 is a schematic representation for a system including a scrub column configured for rich feed gas in accordance with the prior art.
  • FIG. 3 is a schematic representation for a system including a scrub column configured in accordance with one class of embodiments of invention.
  • FIG. 4 is a schematic representation for a system including a scrub column configured in accordance with another class of embodiments of invention.
  • cooling broadly refers to lowering and/or dropping a temperature and/or internal energy of a substance by any suitable, desired, or required amount. Cooling may include a temperature drop of at least about 1°C, at least about 5°C, at least about 10°C, at least about 15°C, at least about 25°C, at least about 35°C, or least about 50°C, or at least about 75°C, or at least about 85°C, or at least about 95°C, or at least about 100°C.
  • the cooling may use any suitable heat sink, such as steam generation, hot water heating, cooling water, air, refrigerant, other process streams (integration), and combinations thereof.
  • One or more sources of cooling may be combined and/or cascaded to reach a desired outlet temperature.
  • the cooling step may use a cooling unit with any suitable device and/or equipment.
  • cooling may include indirect heat exchange, such as with one or more heat exchangers.
  • the cooling may use evaporative (heat of vaporization) cooling and/or direct heat exchange, such as a liquid sprayed directly into a process stream.
  • the term “environment” refers to ambient local conditions, e.g., temperatures and pressures, in the vicinity of a process, for example, in the range between 60 and 75°F or 15 and 25°C.
  • the term “essentially free” refers to a heavy hydrocarbon concentration that is sufficiently low in a stream that does not freeze under cryogenic conditions.
  • external refrigerant refers to a liquid, mixture, or other substances capable of cooling a material located exterior to streams that are processed to generate products. External refrigerants typically form closed loop cooling streams, rejecting heat to environment.
  • expanded external refrigerant refers to an external refrigerant that has increased in volume due to a rise in pressure.
  • heat exchanger broadly means any device capable of transferring heat energy or cold energy from one medium to another medium, such as between at least two distinct fluids. Heat exchangers include “direct heat exchangers” and “indirect heat exchangers.” Thus, a heat exchanger may be of any suitable design, such as a co-current or counter-current heat exchanger, an indirect heat exchanger (e.g.
  • Heat exchanger may also refer to any column, tower, unit or other arrangement adapted to allow the passage of one or more streams there through, and to affect direct or indirect heat exchange between one or more lines of refrigerant, and one or more feed streams.
  • the term “heavy hydrocarbons” refers to hydrocarbons having more than four carbon atoms. Principal examples include pentane, hexane and heptane. Other examples include benzene, aromatics, etc.
  • natural gas refers to a multi-component gas obtained from a crude oil well (associated gas) or from a subterranean gas-bearing formation (non-associated gas).
  • the composition and pressure of natural gas can vary significantly.
  • a typical natural gas stream contains methane (Ci) as a significant component.
  • the natural gas stream may also contain ethane (C2), higher molecular weight hydrocarbons, and one or more acid gases.
  • the natural gas may also contain minor amounts of contaminants such as water, nitrogen, iron sulfide, wax, and crude oil.
  • the term “separation device” or “separator” refers to any vessel configured to receive a fluid having at least two constituent elements and configured to produce a gaseous stream out of a top portion and a liquid (or bottoms) stream out of the bottom of the vessel.
  • the separation device/separator may include internal contact-enhancing structures (e.g. packing elements, strippers, weir plates, chimneys, etc.), may include one, two, or more sections (e.g. a stripping section and a reboiler section), and/or may include additional inlets and outlets.
  • Exemplary separation devices/separators include bulk fractionators, stripping columns, phase separators, scrub columns, and others.
  • the term “scrub column” or “column” refers to a separation device used for the removal of heavy hydrocarbons from a natural gas stream.
  • a natural gas scrub column designed to separate freezable C5 + components from natural gas, typically reduces the burden to provide refrigeration and reboiler as well as greatly enhances C5 + separation efficiency when operated substantially as an absorber.
  • a cryogenic gas processing facility such as a liquefied natural gas (LNG) plant
  • LNG liquefied natural gas
  • the gas treatment section of the plant plays a critical role in treating the gas to meet its final specifications for the natural gas liquefaction unit.
  • the specifications to be met are FLS removal to under 4 ppmv, CO2 to 50 ppmv, total sulfur under 30 ppmv as S, water to 0.1 ppmv, and mercury (Hg) to levels of 0.01 pg/Nm 3 .
  • the raw gas from the well typically is first processed in a slug catcher.
  • a slug catcher collects the largest liquid slugs expected from the upstream operation and then allows them to slowly drain to the downstream processing equipment.
  • the feed gas will then be processed in an acid gas removal unit.
  • the acid gas removal unit primarily removes the acidic components such as hydrogen sulfide and carbon dioxide from the feed gas stream.
  • the next step in the process is a molecular sieve unit which removes water (gas dehydration) and mercaptans, typically, followed by mercury removal.
  • the feed gas from this pre-treatment processing is introduced to a scrub column.
  • the cryogenic distillation tower known as the scrub column or column is a crucial operation within an LNG processing train.
  • the column’s functions are to control the concentration of heavier hydrocarbons (C3+) in the vapor overheads product and maximize the recovery of hydrocarbon liquids in the bottoms product.
  • the feed point to the scrub column is selected in conjunction with temperature and composition similarity of the feed gas and a given location in the column.
  • the feed gas may be fed through a line under pressure to the column preferably as a vapor or at a high mass ratio of vapor to liquid C2 - C4 components, e.g., more than 90 to 10.
  • the feed gas is preferably at a relatively low feed point with respect to the column, i.e., there are more stages in the enriching section above the feed point than in the lower stripping section below the feed point, to effect removal of freezable C5 + components.
  • the temperature of the feed gas line may be ambient temperature, for example, about 17°C.
  • the pressure in the feed gas line generally ranges between about 3.5 MPa (500 psia) to about 14 MPa (2000 psia), and more preferably between about 3.5 MPa to about 7 MPa (1000 psia). It is known that the operating pressure in the column must be lower than the critical pressure of the gas mixture (the critical pressure of methane is 4.64 MPa (673 psia)) to enable phase separation based on boiling point differences of gas components to take place.
  • the column is substantially operated in an absorption region, i.e., more C2 - C4 components are obtained in the vapor product than in the bottoms line, and substantially all of the C5 + components are discharged to the bottoms line.
  • the overhead vapor stream comprising primarily methane and C2 - C4 components is taken from the column through a line in the overhead section.
  • a portion of the overhead vapor is condensed by refrigeration cooler or partial condenser and collected in a separator.
  • the condensed overhead stream is returned to the column to provide a reflux.
  • the reflux liquid is thus essentially free of C5 + and absorbs C5 + components from the vapor stream rising in the column.
  • one or more intercondensers can be operated, typically up to three intercondensers spaced between the feed point and the reflux line.
  • the overhead partial condenser preferably operates at a temperature less than ambient to about -40°C.
  • Suitable refrigerants include, for example, propane and FreonTM refrigerant.
  • An overhead vapor product comprising less than about 1 ppm C 6+ components is removed for subsequent liquefaction in an LNG plant.
  • a bottoms liquid rich in C5 + components with a minor amount of C2 - C4 components is removed at the bottom section of the column. A portion of the liquid is vaporized by the reboiler and returned to the column. A bottoms stream comprising a natural gas liquids (NGL) product is withdrawn for distribution.
  • NNL natural gas liquids
  • the third feed/C 3 chiller is located at the column overhead.
  • the bypass line is used to fully bypass MCHX (Main Cryogenic Heat Exchanger) for richer gas operation and partially used for Condenser Temperature adjustment for leaner gas operation, so that the same configuration can process both lean and rich gas without over-chill feed stream, driving excess C2 + to the bottom of the column.
  • Reboiler of the column can be replaced with stripping gas from part of warm feed as shown.
  • the downstream fractionation column can either use the same base configuration but with a reduced size or greatly simplified design depending on project considerations, plant fuel balance, etc.
  • Table 1 the advantages in energy and cost saving brought by this class of embodiments is discussed in more detail in Table 1 below.
  • a feed gas stream 301 is split into a slip stream 303 which is depressurized to lower pressure via a pressure reducing device such as Joule-Thomson (JT) valve 305 and then fed to the bottom of the column 307 as stripping gas to regulate light hydrocarbon (such as Ci) slippage to the bottom of the column 307.
  • a pressure reducing device such as Joule-Thomson (JT) valve 305
  • JT Joule-Thomson
  • a reboiler (not shown) can be used to generate stripping gas for the same purpose.
  • the remaining portion of the stream 301 is then chilled in one or more pre-chillers 311, 313, exchanging heat with an external refrigerant such as propane.
  • the pre-chilled stream 314 is then routed to the column 307 wherein it separates into a bottom stream 309 that will be further fractionated in downstream fractionation column(s) as shown in FIG. IB, and an overhead stream 315.
  • Overhead stream 315 is then further partially condensed in a chiller 317, transferring heat to an external refrigerant such as propane.
  • an external refrigerant such as propane.
  • sufficient condensation may be achieved by 317.
  • the stream exiting chiller 317 will bypass MCHX 321 entirely and directly feed the reflux drum 327.
  • the chilled stream separates into stream 329 that meets the requirements for further liquefaction under cryogenic conditions occurring in MCHX 321, and a reflux stream 328 that will be returned column 307 via a reflux pump 308.
  • a reflux pump 308 For the case wherein sufficient condensation is not able to be achieved by using the chiller 317, part or all the stream leaving 317 will be routed to MCHX 321 via stream 319 to achieve deeper cooling insuring sufficient condensation to generate stream 325.
  • Stream 325 is then routed to the reflux drum 327 to generate sufficient reflux and stream 329 that is essentially free of freezing hydrocarbons and is then routed to the MCHX 321 to be liquefied under cryogenic conditions to generate a liquefied stream 323 exiting the MCHX 321.
  • the concept may be applied to other MR based technology such as EMR (Enhanced Mixed Refrigerant) or other type of DMR (Dual Mixed Refrigerant) processes.
  • EMR Enhanced Mixed Refrigerant
  • DMR Double Mixed Refrigerant
  • the feed pre-cooling and reflux generation by a slip stream of WMR is integrated in one HX (Heat Exchanger) such as plate-fine type exchange unit.
  • HX Heat Exchanger
  • part of WMR is used to exchange heat with overhead stream from column to generate reflux.
  • the reflux can be used alone or proportionally supplemented with condensate present in the feed gas.
  • the exact proportion of reflux to condensate in the column feed is determined by several considerations including composition of the feed gas, LNG specification, desired LPG and/or C5+ recovery, energy costs, type of refrigeration system used in the LNG plant, and the like.
  • the pre-chilling of a feed stream 301 via pre-chillers 311 and 313 and the partial condensation of an overhead stream 315 via chiller 317 in FIG. 3, can be combined into a single heat exchanger.
  • part of a feed stream 401 is pre-cooled via heat exchanger 409 where it is cooled against a refrigerant stream 421 after depressurization via a pressure reducing element such as JT valve 419.
  • the feed gas stream 401 is then separated into a bottom stream 405 and an overhead stream 407 in column 403. Similar to FIG.
  • part of the feed stream 401 can be split into a slip stream prior to being cooled by heat exchanger 409, feeding to the bottom of column 403 to serve as stripping gas (not shown).
  • a reboiler can be used to achieve a similar stripping effect that regulates the amount of lighter hydrocarbons slip to column bottoms 405.
  • the overhead stream 407 is then routed to heat exchanger 409 to be partially condensed into a two-phase stream 411, which then separates in reflux drum 413 into a reflux stream 415 and an overhead stream 423 that meets the requirement for further liquefaction under cryogenic conditions occurring in the MCHX 425 of a liquefaction system (denoted by a broken-line box in FIG. 4) to produce LNG.
  • the dual mixed refrigerant or MR system 400 for producing LNG includes a gas turbine 471 to power the compressor(s) 431 tasked with compressing the warm mixed refrigerant.
  • System 400 also includes a gas turbine 505 tasked with compressing the cold MR.
  • stream 423 may be directed to the liquefaction system (denoted by a broken-line box in FIG. 4) which liquefies a natural gas feed stream to produce LNG using two refrigeration cycles in the MCHX 425: a warm mixed refrigerant (warm MR) cycle and a cold mixed refrigerant (cold MR) cycle.
  • the feed gas 423 is chilled using a warm MR to about -100°F, with the actual temperature being a process variable.
  • the gas is then further cooled to the final cryogenic temperatures by a cold MR.
  • the resulting cryogenic fluid 516 is then reduced in pressure, preferably by an LNG turbine 514, generating an LNG rundown stream 518. 518 is then routed to a storage area (not shown) and to further reduce pressure across valve 520, generating stream 521.
  • the warm MR is primarily composed of ethane with lesser amounts of propane and iso-butane.
  • the warm MR enters the MCHX 425 at 455 and then splits into multiple portions. Each portion provides cooling to the chilled pretreated gas stream, exits the MCHX 425, is reduced in pressure by valves 457, 466, 473, re-enters the MCHX 425 to provide further cooling to the chilled pretreated gas stream, and exits the heat exchanger to be directed to knock-out vessels 441, 463, 469, respectively.
  • the output of knock-out vessels 469 and 463 are directed to the first two stages of a first compressor 431 to a pressure that is equal to or slightly higher than the operating pressure of knock-out vessel 441.
  • the combined output of the first two stages of the first compressor is cooled in an ambient cooler 435 and directed to the knockout vessel 441.
  • the output of the knock-out vessel 441 is directed to a third stage 445 of the first compressor, which is depicted schematically as being separate from compressor 431 and connected by a common shaft thereto.
  • the output of the third stage 445 is cooled in an ambient cooler 449 and sent to a surge drum 453 that feeds the MCHX 425 with stream 455 and heat exchanger 409, thereby completing the Warm Mixed Refrigerant (WMR) cycle.
  • WMR Warm Mixed Refrigerant
  • the composition of the cold MR is primarily methane with lesser amounts of ethane, nitrogen, and propane.
  • the function of the cold MR which enters the MCHX 425 at 495 and is evaporated at a single pressure level and is used to cool the pretreated gas stream 423 to cryogenic temperatures as well as to subcool itself.
  • Cold MR exiting the MCHX 425 is collected in a knock out drum 509 and expanded in a cryogenic expander 513, after which it re-enters the MCHX 425.
  • the cold MR exiting the MCHX 425 the second time enters a knock-out vessel 479 and is then compressed in two stages in a second compressor 483 to a pressure sufficient to completely condense it against the WMR in the heat exchanger.
  • the cold mixed refrigerant from the second compressor is cooled in ambient coolers 487, 493 before being directed to the inlet 495 of the MCHX 425, thereby completing the cold mixed refrigerant cycle.
  • the focus of pretreatment can shift from supplying ethane, propane and butane makeup gas to conventional LNG refrigeration systems to the removal of freezable C5 + components.
  • Embodiments of the present invention has several advantages over conventional treatment schemes.
  • the chilled feed produces liquids which are stripped to remove light components from the bottoms product and heavy components are absorbed near the top of the column by the reflux.
  • the feed temperature is optimally controlled and cooled in the column where the cooling is preferably provided by the overhead condenser.
  • Table 1 compares the refrigerant compressor power required to produce a nominal
  • Table 2 demonstrates the impact of employing a heavy hydrocarbon removal scheme as illustrated in FIG. 3 on the stabilizer section. As shown, for both rich feed and lean feed, the stabilizer section would be more cost effective in installation, material and total cost when compared to the prior art as illustrated in FIG. 1 (for lean feed) and FIG. 2 (for rich feed).

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Abstract

L'invention concerne des procédés pour augmenter la récupération d'éthane et d'hydrocarbures plus lourds sans congélation dans des courants de gaz naturel pour la liquéfaction de gaz naturel afin de former du gaz naturel liquéfié (GNL), et en particulier, l'utilisation de colonnes de lavage pour traiter les courants d'alimentation de gaz naturel. D'autres variantes indépendantes des procédés sont décrites dans la description.
PCT/US2022/072897 2021-07-16 2022-06-13 Procédés de fonctionnement de systèmes d'élimination d'hydrocarbures dans des courants de gaz naturel WO2023288162A1 (fr)

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Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4445916A (en) 1982-08-30 1984-05-01 Newton Charles L Process for liquefying methane
US5325673A (en) 1993-02-23 1994-07-05 The M. W. Kellogg Company Natural gas liquefaction pretreatment process
US6401486B1 (en) 2000-05-18 2002-06-11 Rong-Jwyn Lee Enhanced NGL recovery utilizing refrigeration and reflux from LNG plants
US20050072186A1 (en) 2002-01-18 2005-04-07 Curtin University Of Technology Process and device for production of lng by removal of freezable solids
WO2006123240A1 (fr) 2005-05-19 2006-11-23 Air Products And Chemicals, Inc. Recuperation de lgn et production de gaz naturel liquefie integrees
US20120060552A1 (en) 2009-05-18 2012-03-15 Carolus Antonius Cornelis Van De Lisdonk Method and apparatus for cooling a gaseous hydrocarbon stream
WO2014022510A2 (fr) 2012-08-03 2014-02-06 Air Products And Chemicals, Inc. Élimination d'hydrocarbures lourds à partir d'un courant de gaz naturel
CN103409188B (zh) * 2013-08-05 2014-07-09 中国石油集团工程设计有限责任公司 一种天然气液化过程中脱除重烃的工艺装置及方法
US20170051970A1 (en) * 2010-12-23 2017-02-23 Fluor Technologies Corporation Ethane recovery and ethane rejection methods and configurations
US20190376740A1 (en) 2018-06-07 2019-12-12 Yijun Liu Pretreatment and Pre-Cooling of Natural Gas by High Pressure Compression and Expansion

Patent Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4445916A (en) 1982-08-30 1984-05-01 Newton Charles L Process for liquefying methane
US5325673A (en) 1993-02-23 1994-07-05 The M. W. Kellogg Company Natural gas liquefaction pretreatment process
US6401486B1 (en) 2000-05-18 2002-06-11 Rong-Jwyn Lee Enhanced NGL recovery utilizing refrigeration and reflux from LNG plants
US20050072186A1 (en) 2002-01-18 2005-04-07 Curtin University Of Technology Process and device for production of lng by removal of freezable solids
WO2006123240A1 (fr) 2005-05-19 2006-11-23 Air Products And Chemicals, Inc. Recuperation de lgn et production de gaz naturel liquefie integrees
US20120060552A1 (en) 2009-05-18 2012-03-15 Carolus Antonius Cornelis Van De Lisdonk Method and apparatus for cooling a gaseous hydrocarbon stream
US20170051970A1 (en) * 2010-12-23 2017-02-23 Fluor Technologies Corporation Ethane recovery and ethane rejection methods and configurations
WO2014022510A2 (fr) 2012-08-03 2014-02-06 Air Products And Chemicals, Inc. Élimination d'hydrocarbures lourds à partir d'un courant de gaz naturel
CN103409188B (zh) * 2013-08-05 2014-07-09 中国石油集团工程设计有限责任公司 一种天然气液化过程中脱除重烃的工艺装置及方法
US20190376740A1 (en) 2018-06-07 2019-12-12 Yijun Liu Pretreatment and Pre-Cooling of Natural Gas by High Pressure Compression and Expansion

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