WO2023207328A1 - Semiconductor structure and preparation method therefor, and electronic device - Google Patents

Semiconductor structure and preparation method therefor, and electronic device Download PDF

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Publication number
WO2023207328A1
WO2023207328A1 PCT/CN2023/079419 CN2023079419W WO2023207328A1 WO 2023207328 A1 WO2023207328 A1 WO 2023207328A1 CN 2023079419 W CN2023079419 W CN 2023079419W WO 2023207328 A1 WO2023207328 A1 WO 2023207328A1
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shallow trench
sub
substrate
preparation
transistor
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PCT/CN2023/079419
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French (fr)
Chinese (zh)
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杨荣华
刘少鹏
张敏
张恒
赵杰
宋俊存
余剑
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华为技术有限公司
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/70Manufacture or treatment of devices consisting of a plurality of solid state components formed in or on a common substrate or of parts thereof; Manufacture of integrated circuit devices or of parts thereof
    • H01L21/71Manufacture of specific parts of devices defined in group H01L21/70
    • H01L21/76Making of isolation regions between components
    • H01L21/762Dielectric regions, e.g. EPIC dielectric isolation, LOCOS; Trench refilling techniques, SOI technology, use of channel stoppers
    • H01L21/76224Dielectric regions, e.g. EPIC dielectric isolation, LOCOS; Trench refilling techniques, SOI technology, use of channel stoppers using trench refilling with dielectric materials
    • H01L21/76237Dielectric regions, e.g. EPIC dielectric isolation, LOCOS; Trench refilling techniques, SOI technology, use of channel stoppers using trench refilling with dielectric materials introducing impurities in trench side or bottom walls, e.g. for forming channel stoppers or alter isolation behavior
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/70Manufacture or treatment of devices consisting of a plurality of solid state components formed in or on a common substrate or of parts thereof; Manufacture of integrated circuit devices or of parts thereof
    • H01L21/71Manufacture of specific parts of devices defined in group H01L21/70
    • H01L21/76Making of isolation regions between components
    • H01L21/762Dielectric regions, e.g. EPIC dielectric isolation, LOCOS; Trench refilling techniques, SOI technology, use of channel stoppers
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/70Manufacture or treatment of devices consisting of a plurality of solid state components formed in or on a common substrate or of parts thereof; Manufacture of integrated circuit devices or of parts thereof
    • H01L21/77Manufacture or treatment of devices consisting of a plurality of solid state components or integrated circuits formed in, or on, a common substrate
    • H01L21/78Manufacture or treatment of devices consisting of a plurality of solid state components or integrated circuits formed in, or on, a common substrate with subsequent division of the substrate into plural individual devices
    • H01L21/82Manufacture or treatment of devices consisting of a plurality of solid state components or integrated circuits formed in, or on, a common substrate with subsequent division of the substrate into plural individual devices to produce devices, e.g. integrated circuits, each consisting of a plurality of components
    • H01L21/822Manufacture or treatment of devices consisting of a plurality of solid state components or integrated circuits formed in, or on, a common substrate with subsequent division of the substrate into plural individual devices to produce devices, e.g. integrated circuits, each consisting of a plurality of components the substrate being a semiconductor, using silicon technology
    • H01L21/8232Field-effect technology
    • H01L21/8234MIS technology, i.e. integration processes of field effect transistors of the conductor-insulator-semiconductor type
    • H01L21/8238Complementary field-effect transistors, e.g. CMOS
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/70Manufacture or treatment of devices consisting of a plurality of solid state components formed in or on a common substrate or of parts thereof; Manufacture of integrated circuit devices or of parts thereof
    • H01L21/77Manufacture or treatment of devices consisting of a plurality of solid state components or integrated circuits formed in, or on, a common substrate
    • H01L21/78Manufacture or treatment of devices consisting of a plurality of solid state components or integrated circuits formed in, or on, a common substrate with subsequent division of the substrate into plural individual devices
    • H01L21/82Manufacture or treatment of devices consisting of a plurality of solid state components or integrated circuits formed in, or on, a common substrate with subsequent division of the substrate into plural individual devices to produce devices, e.g. integrated circuits, each consisting of a plurality of components
    • H01L21/822Manufacture or treatment of devices consisting of a plurality of solid state components or integrated circuits formed in, or on, a common substrate with subsequent division of the substrate into plural individual devices to produce devices, e.g. integrated circuits, each consisting of a plurality of components the substrate being a semiconductor, using silicon technology
    • H01L21/8232Field-effect technology
    • H01L21/8234MIS technology, i.e. integration processes of field effect transistors of the conductor-insulator-semiconductor type
    • H01L21/8238Complementary field-effect transistors, e.g. CMOS
    • H01L21/823878Complementary field-effect transistors, e.g. CMOS isolation region manufacturing related aspects, e.g. to avoid interaction of isolation region with adjacent structure
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L27/00Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate
    • H01L27/02Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components specially adapted for rectifying, oscillating, amplifying or switching and having potential barriers; including integrated passive circuit elements having potential barriers
    • H01L27/04Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components specially adapted for rectifying, oscillating, amplifying or switching and having potential barriers; including integrated passive circuit elements having potential barriers the substrate being a semiconductor body
    • H01L27/08Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components specially adapted for rectifying, oscillating, amplifying or switching and having potential barriers; including integrated passive circuit elements having potential barriers the substrate being a semiconductor body including only semiconductor components of a single kind
    • H01L27/085Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components specially adapted for rectifying, oscillating, amplifying or switching and having potential barriers; including integrated passive circuit elements having potential barriers the substrate being a semiconductor body including only semiconductor components of a single kind including field-effect components only
    • H01L27/088Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components specially adapted for rectifying, oscillating, amplifying or switching and having potential barriers; including integrated passive circuit elements having potential barriers the substrate being a semiconductor body including only semiconductor components of a single kind including field-effect components only the components being field-effect transistors with insulated gate
    • H01L27/092Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components specially adapted for rectifying, oscillating, amplifying or switching and having potential barriers; including integrated passive circuit elements having potential barriers the substrate being a semiconductor body including only semiconductor components of a single kind including field-effect components only the components being field-effect transistors with insulated gate complementary MIS field-effect transistors
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10BELECTRONIC MEMORY DEVICES
    • H10B53/00Ferroelectric RAM [FeRAM] devices comprising ferroelectric memory capacitors
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10BELECTRONIC MEMORY DEVICES
    • H10B61/00Magnetic memory devices, e.g. magnetoresistive RAM [MRAM] devices
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10BELECTRONIC MEMORY DEVICES
    • H10B63/00Resistance change memory devices, e.g. resistive RAM [ReRAM] devices
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10NELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10N59/00Integrated devices, or assemblies of multiple devices, comprising at least one galvanomagnetic or Hall-effect element covered by groups H10N50/00 - H10N52/00
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10NELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10N79/00Integrated devices, or assemblies of multiple devices, comprising at least one solid-state element covered by group H10N70/00

Definitions

  • the present application relates to the field of semiconductor technology, and in particular, to a semiconductor structure and its preparation method, and electronic equipment.
  • ferroelectric memory is more and more widely used than traditional dynamic random access memory (DRAM) because it has the advantages of non-volatility, high speed, and low power consumption. .
  • DRAM dynamic random access memory
  • the bit cell of ferroelectric memory is generally composed of a gate tube and a ferroelectric capacitor.
  • ferroelectric memory uses input and output devices (IO devices) as strobes.
  • IO devices input and output devices
  • the size of the input and output devices is usually relatively large. Therefore, the area of the bit cell of the ferroelectric memory using the input and output devices is also relatively large, which is not conducive to high-density and high-performance applications.
  • transistors with a complementary metal oxide semiconductor (CMOS) structure (the transistors can be referred to as CMOS transistors for short) are usually used to replace the above input and output devices as gate transistors to achieve high-density and high-performance applications.
  • CMOS complementary metal oxide semiconductor
  • CMOS transistors As the semiconductor manufacturing process enters the deep sub-micron stage, in order to achieve higher density and higher performance applications, the size of CMOS transistors needs to be greatly reduced. Therefore, the isolation process between CMOS transistors becomes more and more important.
  • the current semiconductor manufacturing process uses shallow trench isolation (STI) technology to isolate different CMOS transistors.
  • STI shallow trench isolation
  • NWE narrow width effect
  • Embodiments of the present application provide a semiconductor structure, a preparation method thereof, and electronic equipment, which are used to improve the narrow channel effect and reduce the area of bit cells to achieve higher density and higher performance applications.
  • a method for preparing a semiconductor structure includes: providing a substrate with a preset shallow trench area; etching a portion of the substrate located in the preset shallow trench area to form a third A sub-shallow trench; ion implantation is performed on the sidewall of the first sub-shallow trench to form a doped region in the substrate; the bottom wall of the first sub-shallow trench is etched, and the bottom wall of the first sub-shallow trench is etched.
  • a second sub-shallow trench is formed below to obtain a shallow trench including a first sub-shallow trench and a second sub-shallow trench; a filling portion is formed in the shallow trench.
  • the above-mentioned shallow trench, the filling portion located in the shallow trench, and the doped region located in the substrate can be called a shallow trench isolation structure, for example.
  • this application can utilize the doping region in the shallow trench isolation structure to adjust the transistor to be formed.
  • the threshold voltage reduces the leakage current of the transistor to be formed and improves the performance of the transistor to be formed, thereby improving the narrow channel effect. This is conducive to compressing the channel size of the transistor to be formed, which in turn is conducive to reducing the area of the bit cell to be formed, and achieving higher density and higher performance applications.
  • this application decomposes the formation process of shallow trenches, using two etching processes to form the first sub-shallow trench and the second sub-shallow trench respectively, and before etching to form the second sub-shallow trench, Then, ions are implanted into the exposed sidewalls of the first sub-shallow trench ST1, and after etching to form the second sub-shallow trench, a filling portion that at least fills the shallow trench is formed at once. In this way, on the one hand, it is possible to avoid etching back the filling part, avoid the filling part being bombarded by plasma, and ensure the insulation performance and reliability of the filling part.
  • etching the portion of the substrate located in the preset shallow trench area includes: sequentially forming a liner layer, a hard mask layer and a photoresist layer on the substrate; etching Etch the portion of the photoresist layer located in the preset shallow trench area, and form a first opening in the photoresist layer; through the first opening, etch the hard mask layer, liner layer and substrate located in the preset shallow trench area.
  • a second opening is formed in the hard mask layer and the liner layer, and a first sub-shallow trench is formed in the substrate.
  • this application after forming the first sub-shallow trench, ions can be implanted into the sidewalls of the first sub-shallow trench, and then the bottom wall of the first sub-shallow trench can be etched to form the second sub-shallow trench. . That is to say, this application mainly uses the hard mask layer to define the first sub-shallow trench, and then defines the shallow trench.
  • the method of defining shallow trenches is relatively simple and does not require additional processes. It can not only reduce process costs, but also avoid modifying the photolithography dimensions of the active area in advance, reducing process risks.
  • performing ion implantation on the sidewall of the first sub-shallow trench includes: removing the photoresist layer; using the hard mask layer and the liner layer as masks, through the second opening, Ion implantation is performed on the sidewall of the first sub-shallow trench; there is an angle between the direction of the ion implantation and the direction perpendicular to the substrate.
  • the hard mask layer and the liner layer can be used as masks to block and shield the first surface of the substrate, ensuring that ions can be injected into the sidewalls of the first shallow trench and preventing ions from being injected into the substrate. first surface to avoid affecting the performance of the transistor to be formed.
  • the angle between the direction of ion implantation and the direction perpendicular to the substrate ranges from 5° to 45°. This can ensure that most of the ions can be injected into the sidewalls of the first sub-shallow trench, and reduce the amount of ions injected into the bottom wall of the first sub-shallow trench, so as to facilitate the adjustment of the threshold voltage of the transistor to be formed. , while improving the narrow channel effect, reducing the usage (or waste) of ions and reducing process costs.
  • forming the filling part in the shallow trench includes: forming a filling film on the hard mask layer, with a part of the filling film located in the shallow trench; and removing the part of the filling film covering the hard mask layer. and a hard mask layer, retaining the portion of the filling film located in the shallow trench to form a filling portion.
  • This can not only avoid the formation of defects in the filling part, avoid the filling part from being affected by additional ion implantation, and ensure the insulation performance and reliability of the filling part. It can also simplify the preparation process of the filling part and reduce the process cost.
  • the preparation method further includes: annealing the doped region. This can repair the lattice damage of the material caused by ion implantation and activate the implanted ions.
  • the preparation method further includes: annealing the filling film; wherein, during the annealing treatment of the filling film, the doping region is also annealed.
  • this application can integrate the annealing process of the doped region into the existing annealing process in the preparation method of the semiconductor structure, and simultaneously perform the annealing process on the filling film and the doped region in one annealing process. , which can avoid the introduction of additional annealing processes, simplify the preparation process of semiconductor structures, and reduce process costs.
  • the preparation method further includes: performing ion implantation on a portion of the substrate surrounded by the shallow trench to form an active region; forming a gate dielectric layer and a gate electrode on the active region; The portion of the source region that is not covered by the gate dielectric layer and the gate electrode is ion implanted to form the source and drain electrodes of the transistor.
  • a transistor can be prepared.
  • the channel of the transistor will still be in contact with the doped region, so additional channel implantation will be formed in the area where the two are in contact.
  • This additional channel injection will have an impact on the channel of the transistor, which can adjust and stabilize the threshold voltage of the transistor, reduce the leakage of the transistor, improve and suppress the narrow channel effect, and improve the performance of the transistor. This will help reduce the channel width of the transistor, reduce the area of the transistor, and facilitate the formation of more transistors in the substrate.
  • ion implantation is performed on the portion of the substrate surrounded by the shallow trench, including: removing the photoresist layer and the hard mask layer; using the liner layer as a protective layer, through the liner The layer implants ions into the portion of the substrate surrounded by the shallow trenches.
  • the liner layer can protect the surface of the substrate and prevent the surface of the substrate from being damaged.
  • the preparation method before sequentially forming the gate dielectric layer and the gate electrode on the active area, the preparation method further includes: removing the liner layer. This can avoid affecting the formation of the gate dielectric layer and gate electrode.
  • the transistor is an N-type transistor, and the ions injected into the sidewall of the first sub-shallow trench are P-type ions.
  • the transistor is a P-type transistor, and the ions injected into the sidewall of the first sub-shallow trench are N-type ions. That is to say, the type of transistor is opposite to the type of ions injected into the sidewall of the first sub-shallow trench. This can form an inversion layer, thereby adjusting the threshold voltage of the transistor, reducing the leakage of the transistor, and improving and suppressing the leakage of the transistor. Narrow channel effect improves transistor performance.
  • the transistor is an N-type transistor
  • the ions injected into the sidewall of the first sub-shallow trench are boron ions.
  • the preparation method further includes: forming a storage structure on the first electrode, the storage structure being electrically connected to the first electrode; and the first electrode being the source electrode or the drain electrode.
  • Transistors and the memory structures electrically connected to them can constitute bit cells, and bit cell arrays can constitute memories.
  • the depth range of the first sub-shallow trench is By limiting the depth of the first shallow trench, the amount of ions injected into the sidewalls of the first sub-shallow trench can be ensured, the threshold voltage of the transistor to be formed can be effectively adjusted, and the narrow channel effect can be effectively improved.
  • a semiconductor structure in a second aspect, includes: a substrate and a filling part.
  • the substrate has a doped region, and a shallow trench is opened on the first surface of the substrate.
  • the filling part is located in the shallow groove and has an integrated structure.
  • the shallow trench includes a first sub-shallow trench close to the first surface of the substrate, and a second sub-shallow trench located below the first sub-shallow trench, and the doped region is located on the sidewall of the first sub-shallow trench; Compared with the second sub-shallow trench, the first sub-shallow trench and the doped region are formed first.
  • the semiconductor structure provided by this application can, on the one hand, use the doping region to adjust the threshold voltage of the transistor, reduce the leakage current of the transistor, and improve the performance of the transistor, thereby improving the narrow channel effect, so as to compress the channel size of the transistor and reduce the
  • the area of the bit cell can achieve higher density and higher performance applications. On the other hand, it can avoid damaging the filling part and avoid doping ions in the filling part, which will affect the insulation performance and reliability of the filling part.
  • the semiconductor structure further includes: an active region, a source electrode, a drain electrode, a gate dielectric layer and a gate electrode.
  • the active area extends from the first surface of the substrate to the interior of the substrate, and the active area is surrounded by shallow trenches.
  • the source and drain are located in the active area.
  • the gate dielectric layer is located on the first surface of the substrate and between the source electrode and the drain electrode.
  • the gate electrode is located on the gate dielectric layer.
  • the active area, source, drain, gate dielectric layer and gate can constitute a transistor.
  • the above-mentioned doped area can adjust and stabilize the threshold voltage of the transistor, reduce the leakage of the transistor, improve and suppress the narrow channel effect, and improve Transistor performance.
  • the semiconductor structure further includes: a storage structure.
  • the storage structure is located on the first pole and is electrically connected to the first pole.
  • the first pole is the source or drain.
  • the memory structure 10 allows the semiconductor structure to constitute a memory. Since this application can improve and suppress the narrow channel effect, reduce the channel width of the transistor, and reduce the area of the transistor, it can further reduce the area of the bit unit, and can provide more transistors and more bit units to achieve Higher density, higher performance applications.
  • a third aspect provides an electronic device, which includes the semiconductor structure according to any one of the above second aspects.
  • Figure 1 is a structural diagram of a ferroelectric random access memory provided by an embodiment of the present application.
  • FIG. 2 is a circuit diagram of a ferroelectric random access memory provided by an embodiment of the present application.
  • Figures 3a to 3g are structural diagrams corresponding to each step of a method for preparing a semiconductor structure provided in an implementation manner
  • Figures 4a to 4i are structural diagrams corresponding to each step of a method for preparing a semiconductor structure provided in another implementation mode
  • Figure 5 is a flow chart of a method for preparing a semiconductor structure provided by an embodiment of the present application.
  • Figure 6 is a structural diagram corresponding to a step of a method for preparing a semiconductor structure provided by an embodiment of the present application
  • FIG. 7a to 7b are structural diagrams corresponding to another step of a method for preparing a semiconductor structure provided by an embodiment of the present application.
  • FIGS. 8a to 8b are structural diagrams corresponding to another step of a method for preparing a semiconductor structure provided by an embodiment of the present application.
  • FIGS. 9a to 9c are structural diagrams corresponding to another step of a method for preparing a semiconductor structure provided by an embodiment of the present application.
  • Figures 10a to 10b are structural diagrams corresponding to another step of a method for preparing a semiconductor structure provided by an embodiment of the present application;
  • Figures 11a to 11b are structural diagrams corresponding to another step of a method for preparing a semiconductor structure provided by an embodiment of the present application;
  • Figures 12a to 12b are structural diagrams corresponding to another step of a method for preparing a semiconductor structure provided by an embodiment of the present application;
  • Figures 13a to 13d are structural diagrams corresponding to another step of a method for preparing a semiconductor structure provided by an embodiment of the present application;
  • Figures 14a to 14b are structural diagrams corresponding to another step of a method for preparing a semiconductor structure provided by an embodiment of the present application;
  • Figures 15a to 15b are structural diagrams corresponding to another step of a method for preparing a semiconductor structure provided by an embodiment of the present application;
  • Figures 16a to 16b are structural diagrams corresponding to another step of a method for preparing a semiconductor structure provided by an embodiment of the present application;
  • Figure 17 is a structural diagram corresponding to another step of a method for preparing a semiconductor structure provided by an embodiment of the present application.
  • Figure 18 is a structural diagram of a semiconductor structure provided by an embodiment of the present application.
  • Figure 19 is a structural diagram of another semiconductor structure provided by an embodiment of the present application.
  • Figure 20 is a structural diagram of another semiconductor structure provided by an embodiment of the present application.
  • Figure 21 is a structural diagram of an electronic device provided by an embodiment of the present application.
  • “plurality” means two or more than two. “At least one item (item)” or similar expressions thereof refers to any combination of these items, including any combination of single item (items) or plural items (items). For example, at least one of a, b, or c can mean: a, b, c, a-b, a-c, b-c, or a-b-c, where a, b, c can be single or multiple .
  • words such as “first” and “second” are used to distinguish identical or similar items with basically the same functions and effects. Those skilled in the art can understand that words such as “first” and “second” do not limit the number and execution order, and words such as “first” and “second” do not limit the number and execution order.
  • words such as “exemplary” or “for example” are used to represent examples, illustrations or explanations. Any embodiment or design described as “exemplary” or “such as” in the embodiments of the present application is not to be construed as preferred or advantageous over other embodiments or designs. Rather, the use of words such as “exemplary” or “such as” is intended to present related concepts in a concrete manner that is easier to understand.
  • Example embodiments are described herein with reference to cross-sectional illustrations and/or plan illustrations that are idealized illustrations.
  • the thickness of layers and regions are exaggerated for clarity. Accordingly, variations from the shapes in the drawings due, for example, to manufacturing techniques and/or tolerances are contemplated. Therefore, example embodiments should not be construed as limited to the shapes of regions illustrated herein but are to include deviations in shapes that result from, for example, manufacturing. For example, an etched area shown as a rectangle will typically have curved features. Accordingly, the regions shown in the figures are schematic in nature and their shapes are not intended to illustrate the actual shapes of regions of the device and are not intended to limit the scope of the exemplary embodiments.
  • ferroelectric memory mainly includes ferroelectric random access memory (ferroelectric random access memory, FeRAM) and ferroelectric field effect transistor (ferroelectric field-effect-transistor, FeFET) memory.
  • FeRAM ferroelectric random access memory
  • FeFET ferroelectric field effect transistor
  • Each bit cell (or memory cell) of a ferroelectric memory includes a CMOS transistor and at least one ferroelectric capacitor electrically connected to the CMOS transistor.
  • the ferroelectric memory may be a 3D memory.
  • the difference between FeRAM and FeFET lies in the location of the ferroelectric capacitor.
  • FIG. 1 is a structural diagram of FeRAM
  • Figure 1 is a circuit diagram of FeRAM.
  • forty bit cells BC in FeRAM are exemplified respectively.
  • Each bit cell BC includes a CMOS transistor Tr and a ferroelectric capacitor C.
  • the gate of the CMOS transistor Tr is electrically connected to the word line WL
  • the second electrode of the CMOS transistor Tr is electrically connected to the bit line BL
  • the first electrode of the CMOS transistor Tr is electrically connected to the first terminal of the ferroelectric capacitor C.
  • connection, the second end of the ferroelectric capacitor C is electrically connected to the plate line PL.
  • the above-mentioned COMS transistor Tr may be a transistor with an N-channel metal oxide semiconductor (N-channel metal oxide semiconductor, NMOS) structure (the transistor may be referred to as an NMOS transistor for short), or may be a P-type metal oxide semiconductor ( P-channel metal oxide semiconductor, PMOS) structure transistor (this transistor can be referred to as PMOS transistor for short).
  • N-channel metal oxide semiconductor, NMOS N-channel metal oxide semiconductor
  • PMOS P-type metal oxide semiconductor
  • One of the drain or the source of the CMOS transistor Tr is the first electrode, and the other is the second electrode.
  • the ferroelectric capacitor C includes a ferroelectric material between a first end and a second end thereof.
  • FeRAM can store data by taking advantage of the fact that ferroelectric materials can undergo spontaneous polarization and the polarization state can be reoriented with the action of an external electric field.
  • ferroelectric domains form polarization charges (also called flip charges) under the action of an electric field.
  • the flipping charge formed by the flipping of ferroelectric domains under the action of electric field is high, and the flipping charge formed by ferroelectric domains not flipping under the action of electric field is low.
  • This binary stable state of ferroelectric materials allows ferroelectric materials to be used as The memory uses the difference in the direction of the residual polarization intensity and applies an electric field in the same direction to generate different flip charges, which can be used to store data "0" and "1".
  • each ferroelectric capacitor C can be used to store 1 bit of data.
  • the number of bit cells that can be set for storing data becomes larger, and accordingly, higher density and higher performance applications can be achieved.
  • the reduction in the area of the bit cell will inevitably compress the size of the CMOS transistor in the bit cell. After the size of a CMOS transistor is compressed and reduced to a certain extent, a narrow channel effect will occur, causing the threshold voltage of the CMOS transistor to become lower and the leakage current to increase, resulting in serious degradation of the performance of the CMOS transistor. At the same time, after the narrow channel effect occurs, it is difficult to further compress and reduce the size of the CMOS transistor, and it is difficult to further reduce the area of the bit cell.
  • a method for preparing a semiconductor structure for improving the narrow channel effect so as to further compress and reduce the size of the CMOS transistor and reduce the area of the bit cell.
  • the flow chart of this preparation method is shown in Figures 3a to 3g.
  • the preparation method of the above-mentioned semiconductor structure includes: S10a to S60a.
  • a liner layer 2 and a hard mask layer 3 are sequentially formed on the substrate 1, and then the hard mask layer 3 is patterned to form an opening in the hard mask layer 3. Corresponds to the location of the shallow trench to be formed.
  • the liner layer 2 and the substrate 1 are then sequentially patterned through the opening to form a shallow trench ST in the substrate 1 .
  • the shallow trench ST is filled with oxide, and the oxide at least fills the shallow trench ST. Then, the oxide is etched back to remove part of the oxide, thereby obtaining the first filled portion 41 .
  • the thickness of the first filling portion 41 is smaller than the depth of the shallow trench ST so as to expose the top of the sidewall of the shallow trench ST.
  • S30a perform ion implantation on the top of the sidewall of the shallow trench ST through the opening in the hard mask layer 3, corresponding to the top of the sidewall of the shallow trench ST in the substrate 1.
  • a doped region DR is formed at the position.
  • the implanted ions may be fluorine ions.
  • the first filling portion 41 is filled with oxide again through the opening in the hard mask layer 3.
  • the oxide not only fills the shallow trench ST and the opening in the hard mask layer 3, will also be located on hard mask layer 3.
  • the oxide located on the hard mask layer 3 is then polished until the surface of the hard mask layer 3 is exposed, and a portion of the oxide located in the shallow trench ST and the opening in the hard mask layer 3 is retained.
  • the second filling part 42 including the first filling part 41 is obtained.
  • wet etching is used to sequentially remove the hard mask layer 3 and the liner layer 2, and simultaneously remove a part of the second filling portion 42 to obtain the final filling portion 4.
  • a recess is formed at the interface between the top of the filling part 4 and the substrate 1, and this recess exposes a part of the doped region DR.
  • CMOS transistors such as PMOS transistors and NMOS transistors
  • CMOS transistors can be formed in the area surrounded by the shallow trench ST.
  • the thickness of the partial gate dielectric layer 6 grown in the recess is greater than the thickness of the partial gate dielectric layer 6 grown in other locations. That is to say, by forming the doped region DR, the growth rate of the gate dielectric layer 6 at different positions can be affected. By forming the gate dielectric layer 6 with different thicknesses, the formation of parasitic transistors at the position of the shallow trench ST can be avoided, and thus It can effectively improve the narrow channel effect. This is beneficial to reducing the size of the subsequently formed CMOS transistor, which in turn is beneficial to reducing the area of the bit cell.
  • the preparation method of the semiconductor structure provided by the above-mentioned implementation requires an additional etching-back process, which will increase the complexity of the process flow of the above-mentioned preparation method and increase the process cost.
  • a method for preparing a semiconductor structure is provided to improve the narrow channel effect so as to further compress and reduce the size of the CMOS transistor and reduce the area of the bit cell.
  • the flow chart of this preparation method is shown in Figures 4a to 4i.
  • the preparation method of the above-mentioned semiconductor structure includes: S10b to S60b.
  • a liner layer 2 and a hard mask layer 3 are sequentially formed on the substrate 1, and then the liner layer 2 and the hard mask layer 3 are patterned.
  • An opening K is formed in the mask layer 3 , the opening K corresponds to the position of the shallow trench to be formed, and includes a portion of the surface of the substrate 1 .
  • ions are implanted into the exposed part of the surface of the substrate 1 through the above-mentioned opening K, and then the substrate 1 is annealed to form a doped region DR in the substrate 1.
  • the implanted ions may be boron ions.
  • an insulating film 7a is formed on the hard mask layer 3, and the insulating film 7a also covers the sidewall of the opening K. Then, the insulating film 7a is patterned, and the portion of the insulating film 7a covering the sidewalls of the opening K is retained to form the sidewalls 7.
  • the substrate 1 is patterned to form a shallow trench ST in the substrate 1 . Then, the spacers 7 are removed, leaving the doped region DR in the substrate 1 .
  • the doped region DR is located on the top of the sidewall of the shallow trench ST.
  • S50b fill the shallow trench ST with oxide through the above-mentioned opening K to form a filling film 4a.
  • the filling film 4a not only fills the shallow trench ST and the above-mentioned opening K, but also is located in the shallow trench ST. on hard mask layer 3. Then, the portion of the filling film 4a located on the hard mask layer 3 is removed, and the hard mask layer 3 is removed, leaving the portion of the filling film 4a located in the shallow trench ST to obtain the filling portion 4.
  • CMOS transistor can be formed in the area surrounded by the shallow trench ST.
  • the doping region DR formed by ion implantation can be used to adjust the threshold voltage of the subsequently formed CMOS transistor and improve the narrow channel effect. This is beneficial to reducing the size of the subsequently formed CMOS transistor, which in turn is beneficial to reducing the area of the bit cell.
  • the above-mentioned another implementation method uses the sidewall 7 as a mask to define the shallow trench ST, which requires additional formation processes and etching processes of the insulating film 7a, which will increase the process flow of the above-mentioned preparation method.
  • the complexity increases the process cost.
  • the width of the shallow trench ST is generally fixed, and the sidewalls 7 have a certain width. This will cause the size of the active area 5 to be affected by the sidewalls 7, and further requires photolithography of the active area 5 in advance.
  • the dimensions are corrected to make up for the width of the side wall 7 in advance and increase the width of the opening K, which increases the process risk of the above preparation method.
  • Some embodiments of the present application provide a method of manufacturing a semiconductor structure. As shown in Figure 5, the preparation method The method includes S100 ⁇ S500.
  • a substrate 1 is provided.
  • the substrate 1 has a preset shallow trench area A.
  • the above-mentioned substrate 1 is a wafer substrate, which can provide support for subsequent semiconductor manufacturing process steps.
  • the material of the substrate 1 can be single crystal silicon, polycrystalline silicon, single crystal germanium, silicon germanium or silicon carbide; it can also be silicon on insulator or germanium on insulator; it can also be other materials, such as gallium arsenide. etc. III-V compounds.
  • the shape of the above-mentioned preset shallow trench region A can be set according to the position of the transistor to be formed (eg, CMOS transistor), which is not limited in this application.
  • the spacing between the transistors to be formed is relatively large.
  • the preset shallow trench areas A may be in an annular shape and surround different transistors to be formed.
  • the spacing between the transistors to be formed is small.
  • the preset shallow trench area A can be in a grid shape (as shown in Figure 1) to separate the transistors to be formed.
  • this application can use a dry etching process or a wet etching process to etch the substrate 1 to remove a part of the substrate 1 located in the preset shallow trench area A.
  • the substrate 1 has a first surface 1a and a second surface 1b arranged opposite each other.
  • the first surface 1a of the substrate 1 can be etched to form a first sub-shallow trench ST1.
  • the depth of the first sub-shallow trench ST1 is less than the thickness of the substrate 1 . That is to say, as shown in FIG. 9c, during the process of forming the first sub-shallow trench ST1, the bottom wall W1 of the first sub-shallow trench ST1 is located inside the substrate 1, and the first sub-shallow trench ST1 does not penetrate the substrate. Bottom 1.
  • the shape of the orthographic projection (or plan view shape) of the first sub-shallow trench ST1 on the plane of the substrate 1 is the same as the shape of the preset shallow trench area A.
  • the cross-sectional shape of the first sub-shallow trench ST1 is, for example, rectangular (as shown in FIG. 9c) or an inverted trapezoid.
  • S300 as shown in FIG. 10a and FIG. 10b, perform ion implantation on the sidewall of the first sub-shallow trench ST1 to form a doped region DR in the substrate 1.
  • this application may use an ion implantation process to implant ions into the sidewalls of the first sub-shallow trench ST1.
  • the implanted ions can enter the interior of the substrate 1 , so that a doped region DR can be formed in the substrate 1 .
  • the doped region DR may surround the sidewall of the first sub-shallow trench ST1.
  • ion implantation may be performed only at the top position of the sidewall; for example, ion implantation may be performed at the entire sidewall position.
  • the depth of implantation of ions into the interior of the substrate 1 can be selected and set as needed, and is not limited in this application.
  • the first sub-shallow trench ST1 has two sidewalls W2 and W3.
  • the two sidewalls W2 and W3 are respectively located on both sides of the bottom wall W1 and are respectively connected with the to-be-formed corresponding to the transistor.
  • the two sidewalls W2 and W3 of the first sub-shallow trench ST1 may be ion-implanted at the same time; for another example, the ion implantation may be performed first into the sidewalls W2 and W3 of the first sub-shallow trench ST1.
  • One of the two side walls W2 and W3 of the first sub-shallow trench ST1 is ion implanted, and then the other of the two side walls W2 and W3 of the first sub-shallow trench ST1 is ion implanted.
  • the above doped region DR can be used to adjust the threshold voltage of the transistor to be formed, for example, can be used to increase the threshold voltage of the transistor to be formed.
  • this application can use a dry etching process or a wet etching process to etch the bottom wall W1 of the first sub-shallow trench ST1, and further remove the substrate 1 located in the preset shallow trench area A. part to form a second sub-shallow trench ST2 below the first sub-shallow trench ST1.
  • the first sub-shallow trench ST1 and the second sub-shallow trench ST2 are connected.
  • the sum of the depths of the first sub-shallow trench ST1 and the second sub-shallow trench ST2 is less than the thickness of the substrate 1 . That is to say, as shown in FIG. 11b , after the second sub-shallow trench ST2 is formed, the bottom wall of the second sub-shallow trench ST2 is located inside the substrate 1 , and the second sub-shallow trench ST2 does not penetrate the substrate 1 . Since the shallow trench ST includes the first sub-shallow trench ST1 and the second sub-shallow trench ST2, the sum of the depths of the first sub-shallow trench ST1 and the depth of the second sub-shallow trench ST2 is shallow trench ST.
  • the depth of the second sub-shallow trench ST2 is the bottom wall of the shallow trench ST. That is to say, the shallow trench ST does not penetrate the substrate 1 , and there is a certain distance between the bottom wall of the shallow trench ST and the second surface 1 b of the substrate 1 . This is beneficial to ensuring the structural stability of the substrate 1 .
  • the depth of the shallow trench ST ranges from
  • the depth of shallow trench ST is or wait.
  • the shape of the orthographic projection (or plan view shape) of the second sub-shallow trench ST2 on the plane of the substrate 1 is the same as the shape of the preset shallow trench area A.
  • the cross-sectional shape of the second sub-shallow trench ST2 is, for example, rectangular or inverted trapezoid (as shown in Figure 11b).
  • the filling portion 4 is formed in the shallow trench ST.
  • the material of the filling portion 4 is an insulating material, and the insulating material includes, for example, insulating oxide.
  • the material of the filling portion 4 includes silicon dioxide.
  • the filling portion 4 fills at least the shallow trench ST.
  • the above-mentioned shallow trench ST, the filling portion 4 located in the shallow trench ST, and the doped region DR located in the substrate 1 can be called a shallow trench isolation structure, for example.
  • this application can use the shallow trench ST in the shallow trench isolation structure to isolate the transistors to be formed.
  • the application can use the filling portion 4 in the shallow trench isolation structure to improve the structural stability of the substrate 1.
  • isolate the transistor to be formed to improve the performance of the transistor to be formed.
  • the doping region DR with injected ions can also be used to adjust the threshold voltage of the transistor to be formed, reduce the leakage current of the transistor to be formed, and improve the performance of the transistor to be formed.
  • the performance of the transistor is improved thereby improving the narrow channel effect. This is conducive to compressing the channel size of the transistor to be formed, which in turn is conducive to reducing the area of the bit cell to be formed, and achieving higher density and higher performance applications.
  • this application decomposes the formation process of the shallow trench ST, using two etching processes to form the first sub-shallow trench ST1 and the second sub-shallow trench ST2 respectively, and then etching to form the second sub-shallow trench ST1.
  • Sub-shallow trench ST2 Before that, ion implantation is performed on the exposed sidewalls of the first sub-shallow trench ST1.
  • the filling portion 4 that at least fills the shallow trench ST is formed in one go.
  • this application forms the shallow trench ST and then forms the filling portion 4 in the shallow trench ST that at least fills the shallow trench ST, on the one hand, it can avoid filling
  • the filling part 4 is etched back to prevent the filling part 4 from being bombarded by plasma, ensuring the insulation performance and reliability of the filling part 4.
  • it can avoid increasing the engraving process and reduce process costs.
  • this application since this application first performs ion implantation on the exposed sidewalls of the first sub-shallow trench ST1 and then forms the filling part 4, this can avoid implanting ions into the filling part 4, so that the filling part 4 can be without additional The influence of ion implantation can further ensure the insulation performance and reliability of the filling part 4 .
  • the portion of the substrate 1 located in the preset shallow trench area A is etched, including: S210 to S230.
  • a liner layer 2 As shown in FIG. 7a and FIG. 7b, a liner layer 2, a hard mask layer 3 and a photoresist layer 8 are sequentially formed on the substrate 1.
  • this application may use chemical vapor deposition (CVD), physical vapor deposition (PVD), atomic layer deposition (ALD) or any combination of thin film deposition processes.
  • CVD chemical vapor deposition
  • PVD physical vapor deposition
  • ALD atomic layer deposition
  • a liner layer 2 is formed on the first surface 1a of the substrate 1, and then a thin film deposition process such as CVD, PVD, ALD or any combination thereof can be used to form a hard mask layer 3 on the liner layer 2, and then a coating process is used (For example, spin coating or dot coating, etc.)
  • a photoresist layer 8 is formed on the hard mask layer 3 .
  • the material of the liner layer 2 includes silicon dioxide
  • the material of the hard mask layer 3 includes silicon nitride
  • the material of the photoresist layer 8 includes negative photoresist.
  • the liner layer 2 By disposing the liner layer 2 between the substrate 1 and the hard mask layer 3, the liner layer 2 can be used as a transition to relieve the stress between the substrate 1 and the hard mask layer 3.
  • this application may use a photolithography process to etch the portion of the photoresist layer 8 located in the preset shallow trench area A.
  • this application can set a mask on the photoresist layer 8, which blocks the portion of the photoresist layer 8 located in the preset shallow trench area A, and exposes the portion of the photoresist layer 8 located in the preset shallow trench area A.
  • the portion outside the preset shallow trench area A is exposed to the photoresist layer 8 through a mask, so that the portion of the photoresist layer 8 outside the preset shallow trench area A is cured, and then the photoresist layer 8 is exposed.
  • the layer 8 is developed, retaining the portion of the photoresist layer 8 located outside the preset shallow trench area A, and removing the portion of the photoresist layer 8 located in the preset shallow trench area A, so that in the photoresist layer 8 A first opening K1 is formed.
  • the photoresist layer 8 can protect the parts of the hard mask layer 3, the liner layer 2 and the substrate 1 that are blocked and shielded by the photoresist layer 8.
  • this application can use a dry etching process or a wet etching process to etch the hard mask layer 3, the liner layer 2 and the portion of the substrate 1 located in the preset shallow trench area A.
  • This application can complete the etching of the hard mask layer 3, the liner layer 2 and the portion of the substrate 1 located in the preset shallow trench area A in one etching process, or this application can use multiple etching processes.
  • An etching process is performed to complete the etching of the hard mask layer 3, the liner layer 2 and the portion of the substrate 1 located in the preset shallow trench area A.
  • the etching process includes, for example, but is not limited to : As shown in Figure 9b, the hard mask layer 3 and the liner layer 2 are etched through the first opening K1 in the photoresist layer 8, and a second opening K1 is formed in the hard mask layer 3 and the liner layer 2. Opening K2; as shown in Figure 9c, through the above-mentioned first opening K1 and the second opening K2, the portion of the substrate 1 located in the preset shallow trench area A is etched, and a first sub-shallow trench is formed in the substrate 1. Trench ST1.
  • the hard mask layer 3 has a high etching selectivity ratio. Therefore, the sidewall morphology and bottom wall morphology of the first sub-shallow trench ST1 are relatively regular, and the morphology of the first sub-shallow trench ST1 is relatively regular.
  • the width is relatively uniform, and the width of the first sub-shallow trench ST1 is basically the same as the width of the second opening K2.
  • this application after forming the first sub-shallow trench ST1, ion implantation can be performed on the sidewalls of the first sub-shallow trench ST1, and then the bottom wall of the first sub-shallow trench ST1 can be etched. , forming the second sub-shallow trench ST2, and obtaining the shallow trench ST. That is to say, this application mainly uses the hard mask layer 3 to define the first sub-shallow trench ST1 and then define the shallow trench ST.
  • the method of forming the shallow trench ST1 in this application is simpler. On the one hand, it can reduce the process of forming the insulating film 7a and etching the insulating film 7a to form the sidewalls 7 process to reduce process costs. On the other hand, the width of the second opening K1 and the width of the second opening K2 can be made consistent with the width of the shallow trench ST, thereby avoiding the need to pre-set the active area 5 due to the provision of sidewalls 7 The photolithography dimensions are modified to reduce the process risk of the preparation method provided by this application.
  • the depth range of the above-mentioned first sub-shallow trench ST1 is (angstrom)
  • the depth of the first shallow trench ST1 may be or wait.
  • the depth of the first shallow trench ST1 By limiting the depth of the first shallow trench ST1, the amount of ions injected into the sidewalls of the first sub-shallow trench ST1 can be ensured, the threshold voltage of the transistor to be formed can be effectively adjusted, and the narrow trench can be effectively improved. Tao effect. This can avoid the situation that it is difficult to adjust the threshold voltage of the transistor to be formed and improve the narrow channel effect due to the small amount of ion implantation due to the small depth of the first sub-shallow trench ST1. Alternatively, it can avoid the situation that the first sub-shallow trench ST1 has a small depth. The depth of the sub-shallow trench ST1 is relatively large, resulting in a large amount of ion implantation, thereby reducing the adjustment effect of the threshold voltage of the transistor to be formed and the improvement effect of the narrow channel effect.
  • ion implantation is performed on the sidewall of the first sub-shallow trench ST1, including: S310 ⁇ S320.
  • this application can use a plasma font etching process, a wet etching process or any other etching process to remove the photoresist layer 8 and expose the hard mask layer 3 .
  • the hard mask layer 3 and the liner layer 2 can be used as masks to shield the first surface of the substrate 1. Shielding ensures ion energy It can be implanted into the sidewall of the first shallow trench ST1 to prevent ions from being implanted into the first surface of the substrate 1 and thus avoid affecting the performance of the transistor to be formed.
  • angle ⁇ between the direction of ion implantation and the direction perpendicular to the substrate 1, which means that the direction of ion implantation is not parallel to the direction perpendicular to the substrate 1, and the direction of ion implantation is not parallel to the direction where the substrate 1 is located.
  • the angle between the directions of the planes is less than 90°.
  • the angle ⁇ between the direction of the ion implantation and the direction perpendicular to the substrate 1 ranges from 5° to 45°.
  • the above-mentioned included angle ⁇ may be 5°, 10°, 15°, 20°, 25°, 29°, 33°, or 45°, etc.
  • the filling portion 4 is formed in the shallow trench ST, including: S510 to S520.
  • a filling film 4a is formed on the hard mask layer 3, and a part of the filling film 4a is located in the shallow trench ST.
  • this application can use a film deposition process such as CVD, PVD, ALD or any combination thereof to form the filling film 4a.
  • a part of the filling film 4a is located in the shallow trench ST and fills the shallow trench ST; the other part of the filling film 4a is located on the hard mask layer 3 and covers the hard mask layer 3.
  • this application can use a chemical mechanical polish (CMP) process to polish the filling film 4a to planarize it, and expose the hard mask layer 3, and then use a wet etching process to polish the hard mask layer. 3 is etched to remove the hard mask layer 3 and expose the liner layer 2.
  • CMP chemical mechanical polish
  • the side surface of the filling portion 4 away from the substrate 1 may be higher than the side surface of the liner layer 2 away from the substrate 1 .
  • the filling film 4a and the hard mask layer 3 have different polishing rates. In this way, during the process of grinding and removing the filling film 4a, part of the hard mask layer 3 may be removed.
  • the filling part 4 in this application has an integrated structure and is formed at one time through a semiconductor process (that is, a CMP process). This not only avoids the formation of defects in the filling part 4, prevents the filling part 4 from being affected by additional ion implantation, ensures the insulation performance and reliability of the filling part 4, but also simplifies the preparation process of the filling part 4 and reduces the process cost.
  • a semiconductor process that is, a CMP process
  • the preparation method provided by this application also includes: annealing the filling film 4a formed in the above S510.
  • this application may use an annealing process such as a thermal annealing process or a laser annealing process to anneal the filling film 4a.
  • an annealing process such as a thermal annealing process or a laser annealing process to anneal the filling film 4a.
  • the preparation method provided by this application further includes: annealing the doped region DR.
  • this application may use an annealing process such as a thermal annealing process or a laser annealing process to anneal the doped region DR.
  • an annealing process such as a thermal annealing process or a laser annealing process to anneal the doped region DR.
  • the doping region DR can also be annealed.
  • this application can integrate the annealing process of the doped region DR into the existing annealing process in the preparation method of the semiconductor structure, and simultaneously perform the annealing process on the filling film 4a and the doped region DR in one annealing process.
  • the annealing process can avoid the introduction of additional annealing processes, simplify the preparation process of semiconductor structures, and reduce process costs.
  • the preparation method provided by this application also includes: S600 to S800.
  • ion implantation is performed on the portion of the substrate 1 surrounded by the shallow trench ST to form the active region 5.
  • this application may use multiple ion implantation processes to form the active region 5 .
  • this application can use three ion implantation processes to form the active region 5 .
  • ions can be implanted into the interior of the substrate 1 to form the well region 51 in the substrate 1; wherein, the depth of the first ion implantation is greater than the first sub-shallow trench.
  • the depth of trench ST1 is smaller than the depth of shallow trench ST.
  • the formed well region 51 may be a P well (P well) or an N well (N well).
  • ions can be implanted into the well region 51 and deep into the interior of the substrate 1 to form an anti-penetration layer in the substrate 1; wherein, the depth of the second ion implantation is smaller than the depth of the second ion implantation process. The depth of one ion implantation.
  • ions may be implanted into the well region 51 and substantially close to or located at the first surface 1 a of the substrate 1 to form a trench substantially close to or located at the first surface 1 a of the substrate 1 Road District 52.
  • ion implantation is performed on the portion of the substrate 1 surrounded by the shallow trench ST, including: S610 ⁇ S620.
  • the liner layer 2 can protect the surface of the substrate 1 (that is, the first surface 1a) to prevent the liner from forming.
  • the surface of bottom 1 is damaged.
  • the gate dielectric layer 6 and the gate electrode 9 are formed on the active area 5.
  • the preparation method provided by this application further includes: removing the liner layer 2. This can avoid affecting the formation of the gate dielectric layer 6 and the gate electrode 9 .
  • this application may use a wet etching process or a dry etching process to remove the liner layer 2 .
  • this application uses a thermal oxidation process to A gate dielectric film 6 a is formed on the source region 5 , and the gate dielectric film 6 a is located on the first surface 1 a of the substrate 1 . Then, a deposition process or a sputtering process is used to form a gate conductive film on the gate dielectric film 6a, and then a photolithography process or the like can be used to etch the gate dielectric film 6a and the gate conductive film to form the gate dielectric layer 6 and the gate electrode 9.
  • the gate dielectric layer 6 and the gate electrode 9 are strip-shaped, covering a part of the active area 5 and dividing the uncovered part of the active area 5 into two parts.
  • the material of the gate dielectric layer 6 includes an oxide material, and the oxide material includes, for example, silicon oxide.
  • Using a thermal oxidation process to form the gate dielectric film 6a is beneficial to improving the quality of the subsequently formed gate dielectric layer 6.
  • ion implantation is performed in the portion of the active region 5 that is not covered by the gate dielectric layer 6 and the gate electrode 9 to form the source S and drain D of the transistor T.
  • the portion of the active region 5 covered by the gate dielectric layer 6 and the gate electrode 9 is blocked, and ions are basically not implanted into this portion, but are injected into the portion that is not covered by the gate dielectric layer 6 and the gate electrode 9 .
  • the portion covered by the gate electrode 9 that is, the gate dielectric layer 6 and both sides of the gate electrode 9 .
  • the portion of the active region 5 that is not covered by the gate dielectric layer 6 and the gate electrode 9 will form two conductors located on both sides of the gate dielectric layer 6 and the gate electrode 9 respectively.
  • the two conductors form the source S and drain D of the transistor T respectively.
  • the part of the channel region 52 located between the source electrode S and the drain electrode D and covered by the gate dielectric layer 6 and the gate electrode 9 constitutes a channel that only provides T.
  • the transistor T can be prepared and formed.
  • the transistor T can be a PMOS transistor or an NMOS transistor.
  • a semiconductor structure in which a plurality of transistors T is formed in the substrate 1 may constitute, for example, an integrated circuit or a control circuit.
  • the channel region 52 in the active region 5 and the doping region DR (for example, called a local channel) are in contact.
  • the channel of the transistor T will still be in contact with the doped region DR. Therefore, additional channel implantation will be formed in the contact area between the two. This additional channel injection will have an impact on the channel of the transistor T, which can adjust and stabilize the threshold voltage of the transistor T, reduce the leakage of the transistor T, improve and suppress the narrow channel effect, and improve the performance of the transistor T. This is beneficial to reducing the channel width of the transistor T, reducing the area of the transistor T, and facilitating the formation of more transistors T in the substrate 1 .
  • the channel width of the transistor T formed using the preparation method provided by this application can reach the minimum design value required by the design rule manual, or even be smaller than the minimum design value required by the design rule manual. That is to say, using the preparation method provided by this application can greatly increase the number of transistors T formed in the substrate 1, increase the density of the transistors T, and achieve high-performance and high-density applications.
  • the type of the above-mentioned transistor T is related to the type of ions implanted into the sidewall of the first sub-shallow trench ST1.
  • the transistor T is an N-type transistor (that is, an NMOS transistor), and the ions injected into the sidewall of the first sub-shallow trench ST1 are P-type ions.
  • the transistor is a P-type transistor (that is, a PMOS transistor), and the ions injected into the sidewall of the first sub-shallow trench ST1 are N-type ions.
  • the type of transistor T and the type of ions injected into the sidewall of the first sub-shallow trench ST1 are opposite. Since the doping region DR is located at the position of the channel region 52 in the active region 5, this can make The channel region 52 is in contact with the doped region DR to form an inversion layer. The doped region DR can then be used to adjust the threshold voltage of the transistor T, reduce the leakage of the transistor T, improve and suppress the narrow channel effect, and improve the performance of the transistor T. .
  • the number of transistors T formed is multiple.
  • the plurality of transistors T can be of the same type, for example, they are all N-type transistors (that is, NMOS transistors) or all are P-type transistors (that is, PMOS transistors); or the types of the plurality of transistors T can also be different, for example, At least one transistor T is an N-type transistor (that is, an NMOS transistor), and at least one transistor T is a P-type transistor (that is, a PMOS transistor).
  • the formed well regions 51 are all P-wells, and accordingly, the formed transistors are all N-type transistors (that is, NMOS transistors).
  • the ions injected into the sidewall of the first sub-shallow trench ST1 are all boron ions.
  • the implantation energy range of boron ions includes but is not limited to 1Kev ⁇ 100KeV, and the dose range includes but is not limited to 1e 11 /cm 2 to 1e 14 /cm 2 .
  • the implantation energy of boron ions is 1Kev, 15Kev, 30Kev, 35Kev, 70Kev or 100KeV, etc.
  • the dosage is 1e 11 /cm 2 , 2e 11 /cm 2 , 1e 12 /cm 2 , 5e 12 /cm 2 or 1e 14 /cm 2 etc.
  • the dose of boron ions can be determined according to the amount of ion implantation in the channel.
  • the two cooperate with each other to effectively adjust the threshold voltage of the transistor T, reduce the leakage of the transistor T, and improve and suppress the narrow channel effect. Improve the performance of transistor T.
  • the preparation method provided by this application further includes: S900.
  • the memory structure 10 is formed on the first pole of the transistor T.
  • the memory structure 10 is electrically connected to the first pole.
  • the first electrode is source S or drain D.
  • the present application can also form a first interconnection line between the first pole of the transistor T and the memory structure 10 , and one end of the first interconnection line is electrically connected to the first pole of the transistor T. , the other end is electrically connected to the storage structure 10 .
  • the present application can also form a second interconnection line on the storage structure 10 , one end of the second interconnection line is electrically connected to the storage structure 10 , and the other end is connected to other signal lines (such as board lines). ) electrical connection.
  • the above-mentioned memory structure 10 includes but is not limited to a first electrode layer 101 , a memory function layer 102 and a second electrode layer 103 .
  • the storage function layer 102 is used to store data.
  • the transistor T and the memory structure 10 electrically connected thereto can constitute a bit cell, and the bit cell array can constitute a memory.
  • this application can effectively use the doped region DR to adjust the threshold voltage of the transistor T, reduce the leakage of the transistor T, and improve and suppress the narrow channel effect. So that the width of the channel 52 of the transistor T can be reduced, the area of the transistor T can be reduced, the spacing between different active areas 5 can be reduced, and the area of the bit cell can be reduced, so that more transistors T can be provided and more transistors T can be provided. More bit cells enable higher-density, higher-performance applications.
  • the above-mentioned storage functional layer 102 includes but is not limited to a ferroelectric layer, a resistive layer, a phase change layer, or a magnetic tunnel junction (MTJ).
  • a ferroelectric layer a resistive layer
  • a phase change layer a phase change layer
  • MTJ magnetic tunnel junction
  • the type of memory may be a random access memory (FeRAM).
  • the type of memory may be resistive random access memory (RRAM).
  • the type of memory may be a phase change memory (PCM).
  • PCM phase change memory
  • MRAM magnetoresistive random access memory
  • some embodiments of the present application provide a semiconductor structure 100.
  • the semiconductor structure 100 can be prepared and formed, for example, using the preparation methods provided in some of the above embodiments.
  • semiconductor structure 100 includes substrate 1 and fill 4 .
  • a shallow trench ST is formed on the first surface 1 a of the substrate 1 .
  • the shallow trench ST includes a first sub-shallow trench ST1 close to the first surface 1a of the substrate 1, and a second sub-shallow trench ST2 located below the first sub-shallow trench ST1.
  • the second sub-shallow trench ST2 is deeper into the interior of the substrate 1 than the first sub-shallow trench ST1.
  • the sidewalls of the first sub-shallow trench ST1 are, for example, perpendicular to the plane where the substrate 1 is located, and the sidewalls of the second sub-shallow trench ST2 are, for example, arranged at an obtuse angle to the plane where the substrate 1 is located, so that the first sub-shallow trench ST1
  • the side wall of the second sub-shallow trench ST2 may be arranged at an obtuse angle.
  • the substrate 1 has a doping region DR, and ions are doped in the doping region DR.
  • the doping region DR is located on the sidewall of the first sub-shallow trench ST1 and surrounds the sidewall of the first sub-shallow trench ST1.
  • the filling portion 4 is located in the shallow trench ST.
  • the filling portion 4 fills at least the shallow trench ST, for example.
  • the above-mentioned filling part 4 has an integrated structure, that is, the structure of the filling part 4 is continuous and not divided. In the process of preparing the filling part 4, the filling part 4 is formed at once.
  • the first sub-shallow trench ST1 and the doping region DR are formed earlier.
  • the above-mentioned shallow trench ST is formed in two times, one time to form the first sub-shallow trench ST1, and the other time to form the second sub-shallow trench ST2. Moreover, before forming the second sub-shallow trench ST2, ion implantation is performed on the sidewall of the first sub-shallow trench ST1 to form a doped region DR. After the second sub-shallow trench ST2 is formed, the filling portion 4 that at least fills the shallow trench ST is formed at once.
  • the semiconductor structure 100 provided by this application can, on the one hand, use the doping region DR to adjust the threshold voltage of the transistor, reduce the leakage current of the transistor, and improve the performance of the transistor, thereby improving the narrow channel effect and compressing the channel size of the transistor. Reduce the area of the bit cell to achieve higher density and higher performance applications. On the other hand, it can avoid damaging the filling part 4 and avoid doping ions in the filling part 4, which will affect the insulation performance and reliability of the filling part 4.
  • the above-mentioned semiconductor structure 100 further includes a transistor T.
  • the transistor T includes an active region 5 , a source S, a drain D, a gate dielectric layer 6 and a gate 9 .
  • the active region 5 extends from the first surface 1 a of the substrate 1 to the interior of the substrate 1 .
  • the active region 5 also includes a channel region 52 (or channel) located close to the first surface 1 a of the substrate 1 .
  • the gate dielectric layer 6 is located on the first surface 1 a of the substrate 1 and covers the channel region 52 .
  • the gate electrode 9 is located on the gate dielectric layer 6 .
  • the source electrode S and the drain electrode D are located in the active region 5 , wherein the channel region 52 , the gate dielectric layer 6 and the gate electrode 9 are all located between the source electrode S and the drain electrode D.
  • the active area 5 is surrounded by shallow trenches ST.
  • the doped region DR surrounds the sidewall of the first sub-shallow trench ST1 in the shallow trench ST, the doped region DR also surrounds the active region 5 and is in contact with the channel region 52 in the active region 5 .
  • the area where the doped region DR and the channel region 52 are in contact will form an additional channel injection.
  • This additional channel injection will have an impact on the channel of the transistor T, and can adjust and stabilize the threshold voltage of the transistor T, and reduce the threshold voltage of the transistor T. leakage, improve and suppress the narrow channel effect, Improve the performance of transistor T. This is beneficial to reducing the channel width of the transistor T, reducing the area of the transistor T, and facilitating the formation of more transistors T in the substrate 1 .
  • the above-mentioned semiconductor structure 100 further includes: a memory structure 10 .
  • the memory structure 10 is located on the first pole and is electrically connected to the first pole.
  • the first pole is the source S or the drain D of the transistor T.
  • the storage structure 10 is used to store data, and the storage structure 10 and the transistor T electrically connected thereto may be called a bit cell.
  • the semiconductor structure 100 can constitute a memory.
  • the storage structure 10 By electrically connecting the storage structure 10 to the transistor T, the storage structure 10 can be controlled, thereby enabling data storage or reading.
  • the present application can improve and suppress the narrow channel effect, reduce the channel width of the transistor T, and reduce the area of the transistor T, it can further reduce the area of the bit cell and enable more transistors T to be provided. Configure more bit cells to enable higher density, higher performance applications.
  • the above-mentioned storage functional layer 102 includes but is not limited to a ferroelectric layer, a resistive layer, a phase change layer, or a magnetic tunnel junction (MTJ).
  • a ferroelectric layer a resistive layer
  • a phase change layer a phase change layer
  • MTJ magnetic tunnel junction
  • the type of memory may be a random access memory (FeRAM).
  • the type of memory may be resistive random access memory (RRAM).
  • the type of memory may be a phase change memory (PCM).
  • the type of memory may be magnetoresistive random access memory (MRAM).
  • the electronic device can be a mobile phone (mobile phone), tablet computer (pad), television, desktop computer, laptop computer, handheld computer, notebook computer, ultra-mobile personal computer (UMPC), netbook, As well as cellular phones, personal digital assistants (PDAs), augmented reality (AR) devices, virtual reality (VR) devices, artificial intelligence (AI) devices, smart wearable devices (such as , smart watches, smart bracelets), vehicle-mounted equipment, smart home equipment and/or smart city equipment.
  • PDAs personal digital assistants
  • AR augmented reality
  • VR virtual reality
  • AI artificial intelligence
  • smart wearable devices such as , smart watches, smart bracelets
  • vehicle-mounted equipment smart home equipment and/or smart city equipment.
  • FIG. 21 is an architectural schematic diagram of an electronic device provided by an exemplary embodiment of the present application.
  • the electronic device 1000 includes: a memory 100, a processor 200, an input device 300, an output device 400 and other components.
  • the structure of the electronic device shown in Figure 21 does not constitute a limitation on the electronic device 100, and the electronic device 100 may include more or less components than those shown in Figure 21.
  • some of the components shown in FIG. 1 may be combined, or may be arranged differently than those shown in FIG. 21 .
  • the memory 100 is used to store software programs and modules.
  • the memory 100 mainly includes a storage program area and a storage data area, wherein the storage program area can store the operating system, at least one application program required for a function (such as a sound playback function, an image playback function, etc.), etc.; the storage data area can store an electronic program according to the electronic program. Data created by the use of the device (such as audio data, image data, phone book, etc.), etc.
  • the memory 100 includes an external memory 110 and an internal memory 120 . Data stored in the external memory 110 and the internal memory 120 can be transferred to each other.
  • the external memory 110 includes, for example, a hard disk, a USB disk, a floppy disk, etc.
  • the internal memory 120 includes, for example, static random access memory (static random access memory). random access memory (SRAM), dynamic random access memory (dynamic random access memory (DRAM)), read-only memory, etc.
  • the processor 200 is the control center of the above-mentioned electronic device 1000. It uses various interfaces and lines to connect various parts of the entire electronic device 1000, by running or executing software programs and/or modules stored in the memory 100, and by calling the software programs and/or modules stored in the memory 100.
  • the electronic device 1000 performs various functions and processes data based on the data in the electronic device 1000, thereby overall monitoring the electronic device 1000.
  • the processor 200 may include one or more processing units.
  • the processor 200 may include a central processing unit (CPU), an artificial intelligence (artificial intelligence, AI) processor, a digital signal processor (DSP), a neural network processor, or other processors. Application specific integrated circuit (ASIC), etc.
  • the processor 200 is a CPU as an example.
  • the CPU may include a calculator 210 and a controller 220 .
  • the arithmetic unit 210 obtains the data stored in the internal memory 120 and processes the data stored in the internal memory 120. The processed result is usually sent back to the internal memory 120.
  • the controller 220 can control the arithmetic unit 210 to process data, and the controller 220 can also control the external memory 110 and the internal memory 120 to store data or read data.
  • the input device 300 is used to receive input numeric or character information and generate key signal input related to user settings and function control of the electronic device 1000 .
  • the input device 300 may include a touch screen and other input devices.
  • the touch screen also known as the touch panel, can collect the user's touch operations on or near the touch screen (such as the user's operations on or near the touch screen using fingers, stylus, or any suitable objects or accessories), and perform operations based on preset settings.
  • the program drives the corresponding connection device.
  • the touch screen may include two parts: a touch detection device and a touch controller.
  • the touch detection device detects the user's touch orientation, detects the signal brought by the touch operation, and transmits the signal to the touch controller; the touch controller receives the touch information from the touch detection device, converts it into contact point coordinates, and then sends it to the touch controller. to the processor 200, and can receive commands sent by the processor 200 and execute them.
  • touch screens can be implemented in various types such as resistive, capacitive, infrared, and surface acoustic wave.
  • Other input devices may include, but are not limited to, one or more of physical keyboards, function keys (such as volume control keys, power switch keys, etc.), trackballs, mice, joysticks, etc.
  • the controller 220 in the above-mentioned processor 200 can also control the input device 300 to receive the input signal or not to receive the input signal.
  • the input numeric or character information received by the input device 300 and the key signal input generated related to user settings and function control of the electronic device may be stored in the internal memory 120 .
  • the output device 400 is used to output signals corresponding to data input by the input device 300 and stored in the internal memory 120 .
  • the output device 400 outputs a sound signal or a video signal.
  • the controller 220 in the above-mentioned processor 200 can also control the output device 400 to output a signal or not to output a signal.
  • the thick arrows in Figure 21 are used to indicate data transmission, and the direction of the thick arrow indicates the direction of data transmission.
  • a one-way arrow between the input device 300 and the internal memory 120 indicates that data received by the input device 300 is transmitted to the internal memory 120 .
  • the bidirectional arrow between the operator 210 and the internal memory 120 indicates that the data stored in the internal memory 120 can be transferred to the operator 210 , and the data processed by the operator 210 can be transferred to the internal memory 120 .
  • the thin arrows in Figure 21 indicate components that controller 220 can control.
  • the controller 220 can control the external memory 110, the internal memory 120, the operator 210, the input device 300, the output device 400, etc.
  • the electronic device 1000 shown in FIG. 21 may also include various sensors.
  • gyroscope sensor gyroscope sensor, hygrometer sensor, infrared sensor, magnetometer sensor, etc.
  • the power The sub-device 1000 may also include a wireless fidelity (WiFi) module, a Bluetooth module, etc., which will not be described again here.
  • WiFi wireless fidelity
  • the semiconductor structure provided by the embodiment of the present application can be used as the memory 100 in the above-mentioned electronic device 1000.
  • the semiconductor structure provided by the embodiment of the present application can be used as the external memory 110 in the above-mentioned memory 100, or can be used as the internal memory 120 in the above-mentioned memory 100.
  • the semiconductor structure provided by this application can be used in independent memory chip particles.

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Abstract

The embodiments of the present application relate to the technical field of semiconductors. Disclosed are a semiconductor structure and a preparation method therefor, and an electronic device, which are used for alleviating the narrow width effect and reducing the area of a bit cell, thereby achieving higher-density and higher-performance applications. The preparation method for a semiconductor structure comprises: providing a substrate, which has a preset shallow trench region; etching the part of the substrate that is located in the preset shallow trench region, so as to form a first sub-shallow trench; performing ion implantation on a side wall of the first sub-shallow trench, so as to form a doped region in the substrate; etching a bottom wall of the first sub-shallow trench, and forming a second sub-shallow trench below the first sub-shallow trench, so as to obtain a shallow trench comprising the first sub-shallow trench and the second sub-shallow trench; and forming a filling portion in the shallow trench.

Description

半导体结构及其制备方法、电子设备Semiconductor structure and preparation method thereof, electronic equipment
本申请要求于2022年04月28日提交国家知识产权局、申请号为202210471432.5、申请名称为“半导体结构及其制备方法、电子设备”的中国专利申请的优先权,其全部内容通过引用结合在本申请中。This application claims priority to the Chinese patent application submitted to the State Intellectual Property Office on April 28, 2022, with application number 202210471432.5 and the application name "Semiconductor Structure and Preparation Methods and Electronic Equipment", the entire content of which is incorporated by reference. in this application.
技术领域Technical field
本申请涉及半导体技术领域,尤其涉及一种半导体结构及其制备方法、电子设备。The present application relates to the field of semiconductor technology, and in particular, to a semiconductor structure and its preparation method, and electronic equipment.
背景技术Background technique
铁电存储器作为一种新型存储器,较传统的动态随机存取存储器(dynamic random access memory,DRAM),因同时具有非易失性、高速率,低功耗等优势,越来越广泛的被利用。As a new type of memory, ferroelectric memory is more and more widely used than traditional dynamic random access memory (DRAM) because it has the advantages of non-volatility, high speed, and low power consumption. .
铁电存储器的位单元(bit cell)一般由选通管和铁电电容组成。在先进工艺节点,铁电存储器采用输入输出器件(IO device)作为选通管。但是输入输出器件的尺寸通常比较大,因此,采用输入输出器件的铁电存储器的位单元的面积也比较大,这样不利于高密度、高性能的应用。目前,通常采用互补金属氧化物半导体(complementary metal oxide semiconductor,CMOS)结构的晶体管(该晶体管可以简称为CMOS晶体管),代替上述输入输出器件作为选通管,以实现高密度、高性能的应用。The bit cell of ferroelectric memory is generally composed of a gate tube and a ferroelectric capacitor. At advanced process nodes, ferroelectric memory uses input and output devices (IO devices) as strobes. However, the size of the input and output devices is usually relatively large. Therefore, the area of the bit cell of the ferroelectric memory using the input and output devices is also relatively large, which is not conducive to high-density and high-performance applications. At present, transistors with a complementary metal oxide semiconductor (CMOS) structure (the transistors can be referred to as CMOS transistors for short) are usually used to replace the above input and output devices as gate transistors to achieve high-density and high-performance applications.
随着半导体制造工艺进入深亚微米阶段后,为实现更高密度、更高性能的应用,CMOS晶体管的尺寸需要大大减小,因此,CMOS晶体管之间的隔离工艺变得越来越重要。当前的半导体制造工艺采用浅沟槽隔离(shallow trench isolation,STI)技术对不同的CMOS晶体管进行隔离,但是,随着CMOS晶体管的尺寸的减小,CMOS晶体管的沟道宽度会逐渐缩小,这样会出现窄沟道效应(narrow width effect,NWE),导致CMOS晶体管的阈值电压变低、漏电流增加,进而导致CMOS晶体管的性能严重退化。另外,由于窄沟道效应的制约,这就使得CMOS晶体管的沟道宽度难以进一步缩小,进而导致采用CMOS晶体管的铁电存储器的位单元的面积难以减小,难以实现更高密度、更高性能的应用。As the semiconductor manufacturing process enters the deep sub-micron stage, in order to achieve higher density and higher performance applications, the size of CMOS transistors needs to be greatly reduced. Therefore, the isolation process between CMOS transistors becomes more and more important. The current semiconductor manufacturing process uses shallow trench isolation (STI) technology to isolate different CMOS transistors. However, as the size of CMOS transistors decreases, the channel width of the CMOS transistors will gradually shrink, which will The narrow width effect (NWE) occurs, causing the threshold voltage of the CMOS transistor to become lower and the leakage current to increase, which in turn causes the performance of the CMOS transistor to seriously degrade. In addition, due to the restriction of the narrow channel effect, it is difficult to further reduce the channel width of CMOS transistors, which in turn makes it difficult to reduce the area of the bit cells of ferroelectric memories using CMOS transistors, making it difficult to achieve higher density and higher performance. Applications.
发明内容Contents of the invention
本申请实施例提供一种半导体结构及其制备方法、电子设备,用于改善窄沟道效应,并减小位单元的面积,实现更高密度、更高性能的应用。Embodiments of the present application provide a semiconductor structure, a preparation method thereof, and electronic equipment, which are used to improve the narrow channel effect and reduce the area of bit cells to achieve higher density and higher performance applications.
为达到上述目的,本申请的实施例采用如下技术方案:In order to achieve the above objectives, the embodiments of the present application adopt the following technical solutions:
第一方面,提供了一种半导体结构的制备方法,该制备方法包括:提供衬底,衬底具有预设浅沟槽区;刻蚀衬底中位于预设浅沟槽区的部分,形成第一子浅沟槽;对第一子浅沟槽的侧壁进行离子注入,以在衬底中形成掺杂区;刻蚀第一子浅沟槽的底壁,在第一子浅沟槽的下方形成第二子浅沟槽,得到包括第一子浅沟槽和第二子浅沟槽的浅沟槽;在浅沟槽内形成填充部。In a first aspect, a method for preparing a semiconductor structure is provided. The preparation method includes: providing a substrate with a preset shallow trench area; etching a portion of the substrate located in the preset shallow trench area to form a third A sub-shallow trench; ion implantation is performed on the sidewall of the first sub-shallow trench to form a doped region in the substrate; the bottom wall of the first sub-shallow trench is etched, and the bottom wall of the first sub-shallow trench is etched. A second sub-shallow trench is formed below to obtain a shallow trench including a first sub-shallow trench and a second sub-shallow trench; a filling portion is formed in the shallow trench.
上述浅沟槽、位于浅沟槽内的填充部及位于衬底中的掺杂区,例如可以称为浅沟槽隔离结构。本申请一方面可以利用浅沟槽隔离结构中的掺杂区,调节待形成晶体管 的阈值电压,降低待形成晶体管的漏电流,提高待形成晶体管的性能,从而改善窄沟道效应。这样有利于压缩待形成晶体管的沟道尺寸,进而有利于减小待形成的位单元的面积,实现更高密度、更高性能的应用。The above-mentioned shallow trench, the filling portion located in the shallow trench, and the doped region located in the substrate can be called a shallow trench isolation structure, for example. On the one hand, this application can utilize the doping region in the shallow trench isolation structure to adjust the transistor to be formed. The threshold voltage reduces the leakage current of the transistor to be formed and improves the performance of the transistor to be formed, thereby improving the narrow channel effect. This is conducive to compressing the channel size of the transistor to be formed, which in turn is conducive to reducing the area of the bit cell to be formed, and achieving higher density and higher performance applications.
而且,本申请对浅沟槽的形成过程进行了分解,采用两次刻蚀工艺分别形成第一子浅沟槽和第二子浅沟槽,并在刻蚀形成第二子浅沟槽之前,便对第一子浅沟槽ST1暴露的侧壁进行离子注入,在刻蚀形成第二子浅沟槽之后,一次性形成至少填满浅沟槽的填充部。这样,一方面可以避免对填充部进行回刻,避免填充部受到等离子体的轰击,确保填充部的绝缘性能和可靠性,另一方面,可以避免在形成填充部的过程中破真空,进而避免填充部接触空气而形成缺陷,又一方面,可以避免增加回刻的工序,降低工艺成本。另外,由于本申请是先对第一子浅沟槽暴露的侧壁进行离子注入、后形成填充部的,这样可以避免将离子注入至填充部中,使得填充部可以没有额外的离子注入的影响,从而可以进一步确保填充部的绝缘性能和可靠性。Moreover, this application decomposes the formation process of shallow trenches, using two etching processes to form the first sub-shallow trench and the second sub-shallow trench respectively, and before etching to form the second sub-shallow trench, Then, ions are implanted into the exposed sidewalls of the first sub-shallow trench ST1, and after etching to form the second sub-shallow trench, a filling portion that at least fills the shallow trench is formed at once. In this way, on the one hand, it is possible to avoid etching back the filling part, avoid the filling part being bombarded by plasma, and ensure the insulation performance and reliability of the filling part. On the other hand, it is possible to avoid breaking the vacuum during the formation of the filling part, thereby preventing The filling part contacts the air and forms defects. On the other hand, it can avoid increasing the process of engraving back and reduce the process cost. In addition, since this application first performs ion implantation on the exposed sidewalls of the first sub-shallow trench and then forms the filling part, this can avoid implanting ions into the filling part, so that the filling part can be free from the influence of additional ion implantation. , which can further ensure the insulation performance and reliability of the filling part.
在第一方面可能的实现方式中,刻蚀衬底中位于预设浅沟槽区的部分,包括:在所述衬底上依次形成衬垫层、硬掩模层和光刻胶层;刻蚀光刻胶层中位于预设浅沟槽区的部分,在光刻胶层中形成第一开口;通过第一开口,刻蚀硬掩模层、衬垫层和衬底中位于预设浅沟槽区的部分,在硬掩模层和衬垫层中形成第二开口,并在衬底中形成第一子浅沟槽。In a possible implementation of the first aspect, etching the portion of the substrate located in the preset shallow trench area includes: sequentially forming a liner layer, a hard mask layer and a photoresist layer on the substrate; etching Etch the portion of the photoresist layer located in the preset shallow trench area, and form a first opening in the photoresist layer; through the first opening, etch the hard mask layer, liner layer and substrate located in the preset shallow trench area. In the portion of the trench area, a second opening is formed in the hard mask layer and the liner layer, and a first sub-shallow trench is formed in the substrate.
本申请在形成第一子浅沟槽之后,便可以对第一子浅沟槽的侧壁进行离子注入,然后对第一子浅沟槽的底壁进行刻蚀,形成第二子浅沟槽。也就是说,本申请主要利用硬掩膜层来定义第一子浅沟槽,进而定义浅沟槽。定义浅沟槽的方法较为简单,无需增加额外的工序,不仅可以降低工艺成本,还可以避免预先对有源区的光刻尺寸进行修改的情况,降低工艺风险。In this application, after forming the first sub-shallow trench, ions can be implanted into the sidewalls of the first sub-shallow trench, and then the bottom wall of the first sub-shallow trench can be etched to form the second sub-shallow trench. . That is to say, this application mainly uses the hard mask layer to define the first sub-shallow trench, and then defines the shallow trench. The method of defining shallow trenches is relatively simple and does not require additional processes. It can not only reduce process costs, but also avoid modifying the photolithography dimensions of the active area in advance, reducing process risks.
在第一方面可能的实现方式中,对第一子浅沟槽的侧壁进行离子注入,包括:去除光刻胶层;以硬掩模层和衬垫层为掩模,通过第二开口,对第一子浅沟槽的侧壁进行离子注入;离子注入的方向与垂直于衬底的方向之间具有夹角。本申请可以将硬掩模层和衬垫层可以作为掩模,对衬底的第一表面进行遮挡、屏蔽,可以确保离子能够注入至第一浅沟槽的侧壁,避免离子注入至衬底的第一表面,进而避免影响待形成的晶体管的性能。另外,通过使得离子注入的方向与垂直于衬底的方向之间具有夹角,可以确保离子能够注入至第一子浅沟槽的侧壁,进而能够对待形成的晶体管的阈值电压进行调整,改善窄沟道效应。In a possible implementation of the first aspect, performing ion implantation on the sidewall of the first sub-shallow trench includes: removing the photoresist layer; using the hard mask layer and the liner layer as masks, through the second opening, Ion implantation is performed on the sidewall of the first sub-shallow trench; there is an angle between the direction of the ion implantation and the direction perpendicular to the substrate. In this application, the hard mask layer and the liner layer can be used as masks to block and shield the first surface of the substrate, ensuring that ions can be injected into the sidewalls of the first shallow trench and preventing ions from being injected into the substrate. first surface to avoid affecting the performance of the transistor to be formed. In addition, by making an angle between the direction of ion implantation and the direction perpendicular to the substrate, it can be ensured that ions can be implanted into the sidewalls of the first sub-shallow trench, and thus the threshold voltage of the transistor to be formed can be adjusted and improved. Narrow channel effect.
在第一方面可能的实现方式中,离子注入的方向与垂直于衬底的方向之间的夹角的范围为5°~45°。这样可以确保大部分的离子能够注入至第一子浅沟槽的侧壁,减少注入至第一子浅沟槽的底壁的离子的量,以便于在实现对待形成的晶体管的阈值电压的调节、对窄沟道效应的改善的同时,减少离子的使用量(或浪费量),降低工艺成本。In a possible implementation manner of the first aspect, the angle between the direction of ion implantation and the direction perpendicular to the substrate ranges from 5° to 45°. This can ensure that most of the ions can be injected into the sidewalls of the first sub-shallow trench, and reduce the amount of ions injected into the bottom wall of the first sub-shallow trench, so as to facilitate the adjustment of the threshold voltage of the transistor to be formed. , while improving the narrow channel effect, reducing the usage (or waste) of ions and reducing process costs.
在第一方面可能的实现方式中,在浅沟槽内形成填充部,包括:在硬掩模层上形成填充薄膜,填充薄膜的一部分位于浅沟槽;去除填充薄膜覆盖硬掩模层的部分及硬掩模层,保留填充薄膜的位于浅沟槽的部分,形成填充部。这样不仅可以避免在填充部中形成缺陷,避免填充部受到额外的离子注入的影响,确保填充部的绝缘性能和可 靠性,还可以简化填充部的制备工艺,降低工艺成本。In a possible implementation of the first aspect, forming the filling part in the shallow trench includes: forming a filling film on the hard mask layer, with a part of the filling film located in the shallow trench; and removing the part of the filling film covering the hard mask layer. and a hard mask layer, retaining the portion of the filling film located in the shallow trench to form a filling portion. This can not only avoid the formation of defects in the filling part, avoid the filling part from being affected by additional ion implantation, and ensure the insulation performance and reliability of the filling part. It can also simplify the preparation process of the filling part and reduce the process cost.
在第一方面可能的实现方式中,制备方法还包括:对掺杂区进行退火处理。这样可以修复经离子注入后造成的材料的晶格损伤及激活注入的离子。In a possible implementation manner of the first aspect, the preparation method further includes: annealing the doped region. This can repair the lattice damage of the material caused by ion implantation and activate the implanted ions.
在第一方面可能的实现方式中,制备方法还包括:对填充薄膜进行退火处理;其中,在对填充薄膜进行退火处理的过程中,还对掺杂区进行退火处理。也就是说,本申请可以将掺杂区的退火处理工序集成到半导体结构的制备方法中已有的退火处理工序内,在一次退过工艺中,同时对填充薄膜和掺杂区进行退过处理,这样可以避免引入额外的退火处理工序,简化半导体结构的制备工艺,降低工艺成本。In a possible implementation manner of the first aspect, the preparation method further includes: annealing the filling film; wherein, during the annealing treatment of the filling film, the doping region is also annealed. In other words, this application can integrate the annealing process of the doped region into the existing annealing process in the preparation method of the semiconductor structure, and simultaneously perform the annealing process on the filling film and the doped region in one annealing process. , which can avoid the introduction of additional annealing processes, simplify the preparation process of semiconductor structures, and reduce process costs.
在第一方面可能的实现方式中,制备方法还包括:对衬底的被浅沟槽围绕的部分进行离子注入,形成有源区;在有源区上形成栅介质层和栅极;在有源区中未被栅介质层和栅极覆盖的部分进行离子注入,形成晶体管的源极和漏极。采用该制备方法,可以制备形成晶体管。另外,由于制备形成晶体管之后,晶体管的沟道仍然会和掺杂区相接触,因此,两者接触的区域会形成额外的沟道注入。该额外的沟道注入会对晶体管的沟道产生影响,能够调整、稳定晶体管的阈值电压,降低晶体管的漏电,改善、抑制窄沟道效应,提高晶体管的性能。这样有利于减小晶体管的沟道宽度,减小晶体管的面积,便于在衬底中形成更多的晶体管。In a possible implementation of the first aspect, the preparation method further includes: performing ion implantation on a portion of the substrate surrounded by the shallow trench to form an active region; forming a gate dielectric layer and a gate electrode on the active region; The portion of the source region that is not covered by the gate dielectric layer and the gate electrode is ion implanted to form the source and drain electrodes of the transistor. Using this preparation method, a transistor can be prepared. In addition, after the transistor is prepared and formed, the channel of the transistor will still be in contact with the doped region, so additional channel implantation will be formed in the area where the two are in contact. This additional channel injection will have an impact on the channel of the transistor, which can adjust and stabilize the threshold voltage of the transistor, reduce the leakage of the transistor, improve and suppress the narrow channel effect, and improve the performance of the transistor. This will help reduce the channel width of the transistor, reduce the area of the transistor, and facilitate the formation of more transistors in the substrate.
在第一方面可能的实现方式中,对衬底的被浅沟槽围绕的部分进行离子注入,包括:去除光刻胶层和硬掩模层;以衬垫层为保护层,透过衬垫层对衬底的被浅沟槽围绕的部分进行离子注入。这样衬垫层可以对衬底的表面形成保护,避免衬底的表面受到损伤。In a possible implementation of the first aspect, ion implantation is performed on the portion of the substrate surrounded by the shallow trench, including: removing the photoresist layer and the hard mask layer; using the liner layer as a protective layer, through the liner The layer implants ions into the portion of the substrate surrounded by the shallow trenches. In this way, the liner layer can protect the surface of the substrate and prevent the surface of the substrate from being damaged.
在第一方面可能的实现方式中,在有源区上依次形成栅介质层和栅极之前,制备方法还包括:去除衬垫层。这样可以避免影响栅介质层和栅极的形成。In a possible implementation of the first aspect, before sequentially forming the gate dielectric layer and the gate electrode on the active area, the preparation method further includes: removing the liner layer. This can avoid affecting the formation of the gate dielectric layer and gate electrode.
在第一方面可能的实现方式中,晶体管为N型晶体管,注入至第一子浅沟槽的侧壁的离子为P型离子。或者,晶体管为P型晶体管,注入至第一子浅沟槽的侧壁的离子为N型离子。也就是说,晶体管的类型和注入至第一子浅沟槽的侧壁的离子的类型是相反的,这样可以形成反型层,进而可以调整晶体管的阈值电压,降低晶体管的漏电,改善、抑制窄沟道效应,提高晶体管的性能。In a possible implementation of the first aspect, the transistor is an N-type transistor, and the ions injected into the sidewall of the first sub-shallow trench are P-type ions. Alternatively, the transistor is a P-type transistor, and the ions injected into the sidewall of the first sub-shallow trench are N-type ions. That is to say, the type of transistor is opposite to the type of ions injected into the sidewall of the first sub-shallow trench. This can form an inversion layer, thereby adjusting the threshold voltage of the transistor, reducing the leakage of the transistor, and improving and suppressing the leakage of the transistor. Narrow channel effect improves transistor performance.
在第一方面可能的实现方式中,晶体管为N型晶体管,注入至第一子浅沟槽的侧壁的离子为硼离子。In a possible implementation manner of the first aspect, the transistor is an N-type transistor, and the ions injected into the sidewall of the first sub-shallow trench are boron ions.
在第一方面可能的实现方式中,制备方法还包括:在第一极上形成存储结构,存储结构与第一极电连接;第一极为所述源极或所述漏极。晶体管及与其电连接的存储结构,可以构成位单元,位单元阵列可以构成存储器。本申请通过改善、抑制窄沟道效应,便于减小晶体管的沟道宽度,减小晶体管的面积,减小位单元的面积,进而能够设置更多的晶体管T,设置更多的位单元,实现更高密度、更高性能的应用。In a possible implementation of the first aspect, the preparation method further includes: forming a storage structure on the first electrode, the storage structure being electrically connected to the first electrode; and the first electrode being the source electrode or the drain electrode. Transistors and the memory structures electrically connected to them can constitute bit cells, and bit cell arrays can constitute memories. By improving and suppressing the narrow channel effect, this application can easily reduce the channel width of the transistor, reduce the area of the transistor, and reduce the area of the bit unit, thereby enabling more transistors T and more bit units to be set up to achieve Higher density, higher performance applications.
在第一方面可能的实现方式中,第一子浅沟槽的深度范围为通过对第一浅沟槽的深度进行限制,可以确保注入至第一子浅沟槽的侧壁的离子的量,能够对待形成的晶体管的阈值电压进行有效地调整,有效地改善窄沟道效应。In a possible implementation of the first aspect, the depth range of the first sub-shallow trench is By limiting the depth of the first shallow trench, the amount of ions injected into the sidewalls of the first sub-shallow trench can be ensured, the threshold voltage of the transistor to be formed can be effectively adjusted, and the narrow channel effect can be effectively improved. .
第二方面,提供一种半导体结构。该半导体结构包括:衬底和填充部。衬底具有掺杂区,衬底的第一表面开设有浅沟槽。填充部位于浅沟槽内,且呈一体结构。其中, 浅沟槽包括靠近衬底的第一表面的第一子浅沟槽,及位于第一子浅沟槽下方的第二子浅沟槽,掺杂区位于第一子浅沟槽的侧壁;相比于第二子浅沟槽,第一子浅沟槽和掺杂区在先形成。In a second aspect, a semiconductor structure is provided. The semiconductor structure includes: a substrate and a filling part. The substrate has a doped region, and a shallow trench is opened on the first surface of the substrate. The filling part is located in the shallow groove and has an integrated structure. in, The shallow trench includes a first sub-shallow trench close to the first surface of the substrate, and a second sub-shallow trench located below the first sub-shallow trench, and the doped region is located on the sidewall of the first sub-shallow trench; Compared with the second sub-shallow trench, the first sub-shallow trench and the doped region are formed first.
本申请提供的半导体结构,一方面可以利用掺杂区,调节晶体管的阈值电压,降低晶体管的漏电流,提高晶体管的性能,从而改善窄沟道效应,以便于压缩晶体管的沟道尺寸,减小位单元的面积,实现更高密度、更高性能的应用,另一方面,可以避免破坏填充部,避免在填充部中掺杂离子,影响填充部的绝缘性能和可靠性。The semiconductor structure provided by this application can, on the one hand, use the doping region to adjust the threshold voltage of the transistor, reduce the leakage current of the transistor, and improve the performance of the transistor, thereby improving the narrow channel effect, so as to compress the channel size of the transistor and reduce the The area of the bit cell can achieve higher density and higher performance applications. On the other hand, it can avoid damaging the filling part and avoid doping ions in the filling part, which will affect the insulation performance and reliability of the filling part.
在第二方面可能的实现方式中,半导体结构还包括:有源区、源极、漏极、栅介质层和栅极。有源区从衬底的第一表面延伸至衬底内部,有源区被浅沟槽围绕。源极和漏极位于有源区内。栅介质层位于衬底的第一表面上,且位于源极和漏极之间。栅极位于栅介质层上。此处,有源区、源极、漏极、栅介质层和栅极可以构成晶体管,上述掺杂区能够调整、稳定晶体管的阈值电压,降低晶体管的漏电,改善、抑制窄沟道效应,提高晶体管的性能。In a possible implementation of the second aspect, the semiconductor structure further includes: an active region, a source electrode, a drain electrode, a gate dielectric layer and a gate electrode. The active area extends from the first surface of the substrate to the interior of the substrate, and the active area is surrounded by shallow trenches. The source and drain are located in the active area. The gate dielectric layer is located on the first surface of the substrate and between the source electrode and the drain electrode. The gate electrode is located on the gate dielectric layer. Here, the active area, source, drain, gate dielectric layer and gate can constitute a transistor. The above-mentioned doped area can adjust and stabilize the threshold voltage of the transistor, reduce the leakage of the transistor, improve and suppress the narrow channel effect, and improve Transistor performance.
在第二方面可能的实现方式中,半导体结构还包括:存储结构。存储结构位于第一极上,且与第一极电连接。第一极为源极或漏极。通过存储结构10,可以使得半导体结构构成存储器。由于本申请能够改善、抑制窄沟道效应,减小晶体管的沟道宽度,减小晶体管的面积,进而可以减小位单元的面积,能够设置更多的晶体管,设置更多的位单元,实现更高密度、更高性能的应用。In a possible implementation manner of the second aspect, the semiconductor structure further includes: a storage structure. The storage structure is located on the first pole and is electrically connected to the first pole. The first pole is the source or drain. The memory structure 10 allows the semiconductor structure to constitute a memory. Since this application can improve and suppress the narrow channel effect, reduce the channel width of the transistor, and reduce the area of the transistor, it can further reduce the area of the bit unit, and can provide more transistors and more bit units to achieve Higher density, higher performance applications.
第三方面,提供了一种电子设备,该电子设备包括如上述第二方面中中任一项所述的半导体结构。A third aspect provides an electronic device, which includes the semiconductor structure according to any one of the above second aspects.
其中,第二方面中的设计方式所带来的技术效果可参见第一方面和第二方面中不同设计方式所带来的技术效果,此处不再赘述。Among them, the technical effects brought by the design method in the second aspect can be found in the technical effects brought by the different design methods in the first aspect and the second aspect, and will not be described again here.
附图说明Description of drawings
图1为本申请实施例提供的一种铁电随机存取存储器的结构图;Figure 1 is a structural diagram of a ferroelectric random access memory provided by an embodiment of the present application;
图2为本申请实施例提供的一种铁电随机存取存储器的电路图;Figure 2 is a circuit diagram of a ferroelectric random access memory provided by an embodiment of the present application;
图3a~图3g为一种实现方式提供的一种半导体结构的制备方法的各步骤对应的结构图;Figures 3a to 3g are structural diagrams corresponding to each step of a method for preparing a semiconductor structure provided in an implementation manner;
图4a~图4i为另一种实现方式提供的一种半导体结构的制备方法的各步骤对应的结构图;Figures 4a to 4i are structural diagrams corresponding to each step of a method for preparing a semiconductor structure provided in another implementation mode;
图5为本申请实施例提供的一种半导体结构的制备方法的流程图;Figure 5 is a flow chart of a method for preparing a semiconductor structure provided by an embodiment of the present application;
图6为本申请实施例提供的一种半导体结构的制备方法的一种步骤对应的结构图;Figure 6 is a structural diagram corresponding to a step of a method for preparing a semiconductor structure provided by an embodiment of the present application;
图7a~图7b为本申请实施例提供的一种半导体结构的制备方法的另一种步骤对应的结构图;7a to 7b are structural diagrams corresponding to another step of a method for preparing a semiconductor structure provided by an embodiment of the present application;
图8a~图8b为本申请实施例提供的一种半导体结构的制备方法的又一种步骤对应的结构图;8a to 8b are structural diagrams corresponding to another step of a method for preparing a semiconductor structure provided by an embodiment of the present application;
图9a~图9c为本申请实施例提供的一种半导体结构的制备方法的又一种步骤对应的结构图;9a to 9c are structural diagrams corresponding to another step of a method for preparing a semiconductor structure provided by an embodiment of the present application;
图10a~图10b为本申请实施例提供的一种半导体结构的制备方法的又一种步骤对应的结构图; Figures 10a to 10b are structural diagrams corresponding to another step of a method for preparing a semiconductor structure provided by an embodiment of the present application;
图11a~图11b为本申请实施例提供的一种半导体结构的制备方法的又一种步骤对应的结构图;Figures 11a to 11b are structural diagrams corresponding to another step of a method for preparing a semiconductor structure provided by an embodiment of the present application;
图12a~图12b为本申请实施例提供的一种半导体结构的制备方法的又一种步骤对应的结构图;Figures 12a to 12b are structural diagrams corresponding to another step of a method for preparing a semiconductor structure provided by an embodiment of the present application;
图13a~图13d为本申请实施例提供的一种半导体结构的制备方法的又一种步骤对应的结构图;Figures 13a to 13d are structural diagrams corresponding to another step of a method for preparing a semiconductor structure provided by an embodiment of the present application;
图14a~图14b为本申请实施例提供的一种半导体结构的制备方法的又一种步骤对应的结构图;Figures 14a to 14b are structural diagrams corresponding to another step of a method for preparing a semiconductor structure provided by an embodiment of the present application;
图15a~图15b为本申请实施例提供的一种半导体结构的制备方法的又一种步骤对应的结构图;Figures 15a to 15b are structural diagrams corresponding to another step of a method for preparing a semiconductor structure provided by an embodiment of the present application;
图16a~图16b为本申请实施例提供的一种半导体结构的制备方法的又一种步骤对应的结构图;Figures 16a to 16b are structural diagrams corresponding to another step of a method for preparing a semiconductor structure provided by an embodiment of the present application;
图17为本申请实施例提供的一种半导体结构的制备方法的又一种步骤对应的结构图;Figure 17 is a structural diagram corresponding to another step of a method for preparing a semiconductor structure provided by an embodiment of the present application;
图18为本申请实施例提供的一种半导体结构的结构图;Figure 18 is a structural diagram of a semiconductor structure provided by an embodiment of the present application;
图19为本申请实施例提供的另一种半导体结构的结构图;Figure 19 is a structural diagram of another semiconductor structure provided by an embodiment of the present application;
图20为本申请实施例提供的又一种半导体结构的结构图;Figure 20 is a structural diagram of another semiconductor structure provided by an embodiment of the present application;
图21为本申请实施例提供的一种电子设备的结构图。Figure 21 is a structural diagram of an electronic device provided by an embodiment of the present application.
具体实施方式Detailed ways
下面将结合本申请实施例中的附图,对本申请实施例中的技术方案进行描述,显然,所描述的实施例仅仅是本申请一部分实施例,而不是全部的实施例。The technical solutions in the embodiments of the present application will be described below with reference to the accompanying drawings in the embodiments of the present application. Obviously, the described embodiments are only some of the embodiments of the present application, rather than all of the embodiments.
其中,在本申请的描述中,除非另有说明,“多个”是指两个或多于两个。“至少一项(个)”或其类似表达,是指的这些项中的任意组合,包括单项(个)或复数项(个)的任意组合。例如,a,b,或c中的至少一项(个),可以表示:a,b,c,a-b,a-c,b-c,或a-b-c,其中a,b,c可以是单个,也可以是多个。Among them, in the description of this application, unless otherwise stated, "plurality" means two or more than two. “At least one item (item)” or similar expressions thereof refers to any combination of these items, including any combination of single item (items) or plural items (items). For example, at least one of a, b, or c can mean: a, b, c, a-b, a-c, b-c, or a-b-c, where a, b, c can be single or multiple .
另外,为了便于清楚描述本申请实施例的技术方案,在本申请的实施例中,采用了“第一”、“第二”等字样对功能和作用基本相同的相同项或相似项进行区分。本领域技术人员可以理解“第一”、“第二”等字样并不对数量和执行次序进行限定,并且“第一”、“第二”等字样也并不限定一定不同。同时,在本申请实施例中,“示例性的”或者“例如”等词用于表示作例子、例证或说明。本申请实施例中被描述为“示例性的”或者“例如”的任何实施例或设计方案不应被解释为比其它实施例或设计方案更优选或更具优势。确切而言,使用“示例性的”或者“例如”等词旨在以具体方式呈现相关概念,便于理解。In addition, in order to facilitate a clear description of the technical solutions of the embodiments of the present application, in the embodiments of the present application, words such as “first” and “second” are used to distinguish identical or similar items with basically the same functions and effects. Those skilled in the art can understand that words such as "first" and "second" do not limit the number and execution order, and words such as "first" and "second" do not limit the number and execution order. At the same time, in the embodiments of this application, words such as "exemplary" or "for example" are used to represent examples, illustrations or explanations. Any embodiment or design described as "exemplary" or "such as" in the embodiments of the present application is not to be construed as preferred or advantageous over other embodiments or designs. Rather, the use of words such as "exemplary" or "such as" is intended to present related concepts in a concrete manner that is easier to understand.
本申请实施例中,“上”、“下”、“左”以及“右”不限于相对附图中的部件示意置放的方位来定义的,应当理解到,这些方向性术语可以是相对的概念,它们用于相对于的描述和澄清,其可以根据附图中部件附图所放置的方位的变化而相应地发生变化。在附图中,为了清楚起见,夸大了层和区域的厚度,图示中的各部分之间的尺寸比例关系并不反映实际的尺寸比例关系。In the embodiments of the present application, "upper", "lower", "left" and "right" are not limited to being defined relative to the schematically placed directions of the components in the drawings. It should be understood that these directional terms may be relative. Concepts, which are used for relative description and clarification, may change accordingly depending on the orientation in which components are placed in the drawings. In the drawings, the thickness of layers and regions are exaggerated for clarity, and the dimensional proportions between the various parts in the illustrations do not reflect actual dimensional proportions.
本申请参照作为理想化示例性附图的剖视图和/或平面图描述了示例性实施方式。 在附图中,为了清楚,放大了层和区域的厚度。因此,可设想到由于例如制造技术和/或公差引起的相对于附图的形状的变动。因此,示例性实施方式不应解释为局限于本申请示出的区域的形状,而是包括因例如制造而引起的形状偏差。例如,示为矩形的蚀刻区域通常将具有弯曲的特征。因此,附图中所示的区域本质上是示意性的,且它们的形状并非旨在示出设备的区域的实际形状,并且并非旨在限制示例性实施方式的范围。Example embodiments are described herein with reference to cross-sectional illustrations and/or plan illustrations that are idealized illustrations. In the drawings, the thickness of layers and regions are exaggerated for clarity. Accordingly, variations from the shapes in the drawings due, for example, to manufacturing techniques and/or tolerances are contemplated. Therefore, example embodiments should not be construed as limited to the shapes of regions illustrated herein but are to include deviations in shapes that result from, for example, manufacturing. For example, an etched area shown as a rectangle will typically have curved features. Accordingly, the regions shown in the figures are schematic in nature and their shapes are not intended to illustrate the actual shapes of regions of the device and are not intended to limit the scope of the exemplary embodiments.
此外,本申请实施例描述的架构以及场景是为了更加清楚的说明本申请实施例的技术方案,并不构成对于本申请实施例提供的技术方案的限定,本领域普通技术人员可知,随着架构的演变和新场景的出现,本申请实施例提供的技术方案对于类似的技术问题,同样适用。In addition, the architecture and scenarios described in the embodiments of the present application are for the purpose of explaining the technical solutions of the embodiments of the present application more clearly, and do not constitute a limitation on the technical solutions provided by the embodiments of the present application. Those of ordinary skill in the art will know that as the architecture With the evolution of technology and the emergence of new scenarios, the technical solutions provided by the embodiments of this application are also applicable to similar technical problems.
需要说明的是,铁电存储器主要包括铁电随机存取存储器(ferroelectric random access memory,FeRAM)和铁电场效应晶体管(ferroelectric filed-effect-transistor,FeFET)存储器。每种铁电存储器的位单元(或称为存储单元),均包括CMOS晶体管及与该CMOS晶体管电连接的至少一个铁电电容。在位单元包括多个铁电电容的情况下,铁电存储器可以为3D存储器。其中,FeRAM和FeFET的区别在于铁电电容的设置位置不同。It should be noted that ferroelectric memory mainly includes ferroelectric random access memory (ferroelectric random access memory, FeRAM) and ferroelectric field effect transistor (ferroelectric field-effect-transistor, FeFET) memory. Each bit cell (or memory cell) of a ferroelectric memory includes a CMOS transistor and at least one ferroelectric capacitor electrically connected to the CMOS transistor. Where the bit cell includes multiple ferroelectric capacitors, the ferroelectric memory may be a 3D memory. Among them, the difference between FeRAM and FeFET lies in the location of the ferroelectric capacitor.
本申请以FeRAM为例。图1为一种FeRAM的结构图,图1为一种FeRAM的电路图。图1和图2中,分别示例性地给出了FeRAM中的四十个位单元BC,每个位单元BC包括一个CMOS晶体管Tr和一个铁电电容C。每个位单元BC中,CMOS晶体管Tr的栅极与字线WL电连接,CMOS晶体管Tr的第二极与位线BL电连接,CMOS晶体管Tr第一极与铁电电容C的第一端电连接,铁电电容C的第二端与板线PL电连接。This application takes FeRAM as an example. Figure 1 is a structural diagram of FeRAM, and Figure 1 is a circuit diagram of FeRAM. In Figures 1 and 2, forty bit cells BC in FeRAM are exemplified respectively. Each bit cell BC includes a CMOS transistor Tr and a ferroelectric capacitor C. In each bit cell BC, the gate of the CMOS transistor Tr is electrically connected to the word line WL, the second electrode of the CMOS transistor Tr is electrically connected to the bit line BL, and the first electrode of the CMOS transistor Tr is electrically connected to the first terminal of the ferroelectric capacitor C. connection, the second end of the ferroelectric capacitor C is electrically connected to the plate line PL.
在本申请中,上述COMS晶体管Tr可以为N型金属氧化物半导体(N-channel metal oxide semiconductor,NMOS)结构的晶体管(该晶体管可以简称为NMOS晶体管),或者可以为P型金属氧化物半导体(P-channel metal oxide semiconductor,PMOS)结构的晶体管(该晶体管可以简称为PMOS晶体管)。CMOS晶体管Tr的漏极(drain)或源极(source)中的一极为第一极,另一极为第二极。In this application, the above-mentioned COMS transistor Tr may be a transistor with an N-channel metal oxide semiconductor (N-channel metal oxide semiconductor, NMOS) structure (the transistor may be referred to as an NMOS transistor for short), or may be a P-type metal oxide semiconductor ( P-channel metal oxide semiconductor, PMOS) structure transistor (this transistor can be referred to as PMOS transistor for short). One of the drain or the source of the CMOS transistor Tr is the first electrode, and the other is the second electrode.
示例性的,铁电电容C包括位于其第一端和第二端之间的铁电材料。FeRAM利用铁电材料可以发生自发极化、且极化状态能够随外电场作用而重新取向的特点,可以对数据进行存储。Illustratively, the ferroelectric capacitor C includes a ferroelectric material between a first end and a second end thereof. FeRAM can store data by taking advantage of the fact that ferroelectric materials can undergo spontaneous polarization and the polarization state can be reoriented with the action of an external electric field.
具体地,当一个电场被施加到铁电材料时,其中心原子顺着电场停留在一个低能量状态位置,反之,当电场翻转被施加到同一铁电材料时,其中心原子顺着电场的方向在晶体里移动并停留在另一低能量状态位置。大量中心原子在晶体单胞中移动耦合形成铁电畴(ferroelectric domains),铁电畴在电场作用下形成极化电荷(也称为翻转电荷)。铁电畴在电场作用下翻转所形成的翻转电荷较高,铁电畴在电场作用下无翻转所形成的翻转电荷较低,这种铁电材料的二元稳定状态使得铁电材料可以用作为存储器,利用剩余极化强度方向的不同,施加相同方向的电场,产生的翻转电荷不同,可以用于存储数据“0”和“1”。Specifically, when an electric field is applied to a ferroelectric material, its central atom stays in a low-energy state along the electric field. Conversely, when an electric field flip is applied to the same ferroelectric material, its central atom follows the direction of the electric field. Move within the crystal and stay in another lower energy state. A large number of central atoms move and couple in the crystal unit cell to form ferroelectric domains. The ferroelectric domains form polarization charges (also called flip charges) under the action of an electric field. The flipping charge formed by the flipping of ferroelectric domains under the action of electric field is high, and the flipping charge formed by ferroelectric domains not flipping under the action of electric field is low. This binary stable state of ferroelectric materials allows ferroelectric materials to be used as The memory uses the difference in the direction of the residual polarization intensity and applies an electric field in the same direction to generate different flip charges, which can be used to store data "0" and "1".
示例性的,每个铁电电容C可以用于存储1bit的数据。 For example, each ferroelectric capacitor C can be used to store 1 bit of data.
可以理解的是,随着铁电存储器中位单元的面积的减小,可设置的、用于存储数据的位单元的数量则越多,相应的,可实现更高密度、更高性能的应用。但是,位单元的面积的减小,势必会压缩位单元中CMOS晶体管的尺寸。在将CMOS晶体管的尺寸压缩减小至一定程度后,便会出现窄沟道效应,导致CMOS晶体管的阈值电压变低、漏电流增加,进而导致CMOS晶体管的性能严重退化。同时,在出现窄沟道效应后,便难以进一步压缩减小CMOS晶体管的尺寸,难以进一步减小位单元的面积。It can be understood that as the area of the bit cells in the ferroelectric memory decreases, the number of bit cells that can be set for storing data becomes larger, and accordingly, higher density and higher performance applications can be achieved. . However, the reduction in the area of the bit cell will inevitably compress the size of the CMOS transistor in the bit cell. After the size of a CMOS transistor is compressed and reduced to a certain extent, a narrow channel effect will occur, causing the threshold voltage of the CMOS transistor to become lower and the leakage current to increase, resulting in serious degradation of the performance of the CMOS transistor. At the same time, after the narrow channel effect occurs, it is difficult to further compress and reduce the size of the CMOS transistor, and it is difficult to further reduce the area of the bit cell.
在一种实现方式中,提供了一种半导体结构的制备方法,用于改善窄沟道效应,以便能够进一步压缩减小CMOS晶体管的尺寸,减小位单元的面积。该制备方法的流程如图3a~图3g所示。In one implementation, a method for preparing a semiconductor structure is provided for improving the narrow channel effect so as to further compress and reduce the size of the CMOS transistor and reduce the area of the bit cell. The flow chart of this preparation method is shown in Figures 3a to 3g.
在一些示例中,上述半导体结构的制备方法包括:S10a~S60a。In some examples, the preparation method of the above-mentioned semiconductor structure includes: S10a to S60a.
S10a,如图3a所示,在衬底1上依次形成衬垫层2和硬掩模层3,然后对硬掩模层3进行图案化处理,在硬掩模层3中形成开口,该开口与待形成的浅沟槽的位置相对应。之后通过该开口依次对衬垫层2和衬底1进行图案化处理,以在衬底1中形成浅沟槽ST。S10a, as shown in Figure 3a, a liner layer 2 and a hard mask layer 3 are sequentially formed on the substrate 1, and then the hard mask layer 3 is patterned to form an opening in the hard mask layer 3. Corresponds to the location of the shallow trench to be formed. The liner layer 2 and the substrate 1 are then sequentially patterned through the opening to form a shallow trench ST in the substrate 1 .
S20a,如图3b和图3c所示,在浅沟槽ST内填充氧化物,该氧化物至少填满浅沟槽ST。然后对该氧化物进行回刻,去除该氧化物的一部分,得到第一填充部41。其中,第一填充部41的厚度小于浅沟槽ST的深度,以便暴露浅沟槽ST的侧壁的顶部。S20a, as shown in FIG. 3b and FIG. 3c, the shallow trench ST is filled with oxide, and the oxide at least fills the shallow trench ST. Then, the oxide is etched back to remove part of the oxide, thereby obtaining the first filled portion 41 . The thickness of the first filling portion 41 is smaller than the depth of the shallow trench ST so as to expose the top of the sidewall of the shallow trench ST.
S30a,如图3d所示,通过硬掩模层3中的开口,对浅沟槽ST的侧壁的顶部进行离子注入,在衬底1中的与浅沟槽ST的侧壁的顶部相对应的位置处形成掺杂区DR。其中,注入的离子可以为氟离子。S30a, as shown in FIG. 3d, perform ion implantation on the top of the sidewall of the shallow trench ST through the opening in the hard mask layer 3, corresponding to the top of the sidewall of the shallow trench ST in the substrate 1. A doped region DR is formed at the position. The implanted ions may be fluorine ions.
S40a,如图3e所示,通过硬掩模层3中的开口,在第一填充部41上再次填充氧化物,该氧化物不仅填满浅沟槽ST和硬掩模层3中的开口,还会位于硬掩模层3上。然后对位于硬掩模层3上的氧化物进行研磨,直至暴露硬掩模层3的表面,并保留位于浅沟槽ST和硬掩模层3中的开口的部分氧化物。此时,得到包括第一填充部41的第二填充部42。S40a, as shown in FIG. 3e, the first filling portion 41 is filled with oxide again through the opening in the hard mask layer 3. The oxide not only fills the shallow trench ST and the opening in the hard mask layer 3, will also be located on hard mask layer 3. The oxide located on the hard mask layer 3 is then polished until the surface of the hard mask layer 3 is exposed, and a portion of the oxide located in the shallow trench ST and the opening in the hard mask layer 3 is retained. At this time, the second filling part 42 including the first filling part 41 is obtained.
S50a,如图3f所示,采用湿法刻蚀依次去除硬掩模层3和衬垫层2,同时去除第二填充部42的一部分,得到最终的填充部4。其中,填充部4的顶端与衬底1的交接面处形成凹陷,该凹陷暴露掺杂区DR的一部分。S50a, as shown in FIG. 3f, wet etching is used to sequentially remove the hard mask layer 3 and the liner layer 2, and simultaneously remove a part of the second filling portion 42 to obtain the final filling portion 4. Wherein, a recess is formed at the interface between the top of the filling part 4 and the substrate 1, and this recess exposes a part of the doped region DR.
S60a,如图3g所示,对衬底1进行离子注入形成N型和P型掺杂的有源区5,并在衬底1中与有源区5对应的部分的表面上生长形成栅介质层6。之后便可以在浅沟槽ST围成的区域内形成CMOS晶体管(例如PMOS晶体管和NMOS晶体管)。S60a, as shown in Figure 3g, ion implantation is performed on the substrate 1 to form N-type and P-type doped active regions 5, and a gate dielectric is grown on the surface of the portion of the substrate 1 corresponding to the active region 5. Layer 6. Then, CMOS transistors (such as PMOS transistors and NMOS transistors) can be formed in the area surrounded by the shallow trench ST.
其中,受凹陷处的掺杂区DR的影响,在凹陷处生长的部分栅介质层6的厚度,要大于其他位置处生成的部分栅介质层6的厚度。也就是说,通过形成掺杂区DR,可以影响栅介质层6在不同位置的生长速率,通过形成具有不同厚度的栅介质层6,可以避免在浅沟槽ST的位置处形成寄生晶体管,进而可以有效改善窄沟道效应。这样有利于减小后续形成的CMOS晶体管的尺寸,进而有利于减小位单元的面积。Among them, due to the influence of the doped region DR in the recess, the thickness of the partial gate dielectric layer 6 grown in the recess is greater than the thickness of the partial gate dielectric layer 6 grown in other locations. That is to say, by forming the doped region DR, the growth rate of the gate dielectric layer 6 at different positions can be affected. By forming the gate dielectric layer 6 with different thicknesses, the formation of parasitic transistors at the position of the shallow trench ST can be avoided, and thus It can effectively improve the narrow channel effect. This is beneficial to reducing the size of the subsequently formed CMOS transistor, which in turn is beneficial to reducing the area of the bit cell.
需要说明的是,在上述S20a中,由于需要对填充至浅沟槽ST内的氧化物进行回刻,这样会导致回刻后形成的第一填充部41收到等离子体的轰击,降低第一填充部41的绝缘性能,降低第一填充部41的可靠性。而且,在对填充至浅沟槽ST内的氧化 物进行回刻后,需要确认回刻的尺寸是否符合预期,这样会使得第一填充部41会暴露在空气中,导致第一填充部41的表面接触空气而形成缺陷。It should be noted that in the above-mentioned S20a, since the oxide filled into the shallow trench ST needs to be etched back, this will cause the first filling portion 41 formed after the etching back to be bombarded by plasma, reducing the first The insulation performance of the filling part 41 reduces the reliability of the first filling part 41 . Moreover, in filling the oxide into the shallow trench ST After the object is re-engraved, it is necessary to confirm whether the size of the re-engraving is as expected. This will expose the first filling part 41 to the air, causing the surface of the first filling part 41 to contact the air and form defects.
在上述S30a中,在对浅沟槽ST的侧壁的顶部进行离子注入的过程中,氟离子会注入到第一填充部41中,这样会改变第一填充部41的掺杂浓度,进一步降低第一填充部41的绝缘性能,进一步降低第一填充部41的可靠性。In the above S30a, during the process of ion implantation into the top of the sidewall of the shallow trench ST, fluorine ions will be implanted into the first filling portion 41, which will change the doping concentration of the first filling portion 41 and further reduce the doping concentration of the first filling portion 41. The insulation performance of the first filling part 41 further reduces the reliability of the first filling part 41 .
另外,上述一种实现方式提供的半导体结构的制备方法,需要增加回刻的工序,这样会增大上述制备方法的工艺流程的复杂度,增加工艺成本。In addition, the preparation method of the semiconductor structure provided by the above-mentioned implementation requires an additional etching-back process, which will increase the complexity of the process flow of the above-mentioned preparation method and increase the process cost.
在另一种实现方式中,又提供了一种半导体结构的制备方法,用于改善窄沟道效应,以便能够进一步压缩减小CMOS晶体管的尺寸,减小位单元的面积。该制备方法的流程如图4a~图4i所示。In another implementation, a method for preparing a semiconductor structure is provided to improve the narrow channel effect so as to further compress and reduce the size of the CMOS transistor and reduce the area of the bit cell. The flow chart of this preparation method is shown in Figures 4a to 4i.
在一些示例中,上述半导体结构的制备方法包括:S10b~S60b。In some examples, the preparation method of the above-mentioned semiconductor structure includes: S10b to S60b.
S10b,如图4a所示,在衬底1上依次形成衬垫层2和硬掩模层3,然后对衬垫层2和硬掩模层3进行图案化处理,在衬垫层2和硬掩模层3中形成开口K,该开口K与待形成的浅沟槽的位置相对应,并包括衬底1的部分表面。S10b, as shown in Figure 4a, a liner layer 2 and a hard mask layer 3 are sequentially formed on the substrate 1, and then the liner layer 2 and the hard mask layer 3 are patterned. An opening K is formed in the mask layer 3 , the opening K corresponds to the position of the shallow trench to be formed, and includes a portion of the surface of the substrate 1 .
S20b,如图4b所示,通过上述开口K,对衬底1暴露的部分表面进行离子注入,然后对衬底1进行退火处理,在衬底1中形成掺杂区DR。其中,注入的离子可以为硼离子。S20b, as shown in FIG. 4b, ions are implanted into the exposed part of the surface of the substrate 1 through the above-mentioned opening K, and then the substrate 1 is annealed to form a doped region DR in the substrate 1. The implanted ions may be boron ions.
S30b,如图4c和图4d所示,在硬掩模层3上形成一绝缘薄膜7a,该绝缘薄膜7a还覆盖上述开口K的侧壁。然后对绝缘薄膜7a进行图案化处理,保留绝缘薄膜7a覆盖上述开口K的侧壁的部分,形成侧墙7。S30b, as shown in FIG. 4c and FIG. 4d, an insulating film 7a is formed on the hard mask layer 3, and the insulating film 7a also covers the sidewall of the opening K. Then, the insulating film 7a is patterned, and the portion of the insulating film 7a covering the sidewalls of the opening K is retained to form the sidewalls 7.
S40b,如图4e和图4f所示,以侧墙7作为掩膜,对衬底1进行图案化处理,以在衬底1中形成浅沟槽ST。然后去除侧墙7,在衬底1中保留掺杂区DR。该掺杂区DR位于浅沟槽ST的侧壁的顶部。S40b, as shown in FIG. 4e and FIG. 4f , using the sidewall 7 as a mask, the substrate 1 is patterned to form a shallow trench ST in the substrate 1 . Then, the spacers 7 are removed, leaving the doped region DR in the substrate 1 . The doped region DR is located on the top of the sidewall of the shallow trench ST.
S50b,如图4g和图4h所示,通过上述开口K,在浅沟槽ST内填充氧化物,形成一填充薄膜4a,该填充薄膜4a不仅填满浅沟槽ST和上述开口K,还位于硬掩模层3上。然后去除填充薄膜4a位于硬掩模层3上的部分,并去除硬掩膜层3,保留填充薄膜4a位于浅沟槽ST内的部分,得到填充部4。S50b, as shown in FIG. 4g and FIG. 4h, fill the shallow trench ST with oxide through the above-mentioned opening K to form a filling film 4a. The filling film 4a not only fills the shallow trench ST and the above-mentioned opening K, but also is located in the shallow trench ST. on hard mask layer 3. Then, the portion of the filling film 4a located on the hard mask layer 3 is removed, and the hard mask layer 3 is removed, leaving the portion of the filling film 4a located in the shallow trench ST to obtain the filling portion 4.
S60b,如图4i所示,去除衬垫层2,并对衬底1进行离子注入形成有源区5。之后便可以在浅沟槽ST围成的区域内形成CMOS晶体管。S60b, as shown in FIG. 4i, remove the liner layer 2, and perform ion implantation on the substrate 1 to form the active region 5. After that, a CMOS transistor can be formed in the area surrounded by the shallow trench ST.
通过侧墙7作为掩膜来定义浅沟槽ST,可以利用离子注入的方式形成的掺杂区DR,调节后续形成的CMOS晶体管的阈值电压,改善窄沟道效应。这样有利于减小后续形成的CMOS晶体管的尺寸,进而有利于减小位单元的面积。By using the sidewall 7 as a mask to define the shallow trench ST, the doping region DR formed by ion implantation can be used to adjust the threshold voltage of the subsequently formed CMOS transistor and improve the narrow channel effect. This is beneficial to reducing the size of the subsequently formed CMOS transistor, which in turn is beneficial to reducing the area of the bit cell.
需要说明的是,上述另一种实现方式通过侧墙7作为掩膜来定义浅沟槽ST,便需要额外增加绝缘薄膜7a的形成工序及刻蚀工序,这样会增大上述制备方法的工艺流程的复杂度,增加工艺成本。而且,浅沟槽ST的宽度一般是固定的,且侧墙7具有一定的宽度,这样会使得有源区5的尺寸受到侧墙7的影响,进而便需要预先对有源区5的光刻尺寸进行修正,提前弥补侧墙7的宽度,将上述开口K的宽度增大,这样增加了上述制备方法的工艺风险。It should be noted that the above-mentioned another implementation method uses the sidewall 7 as a mask to define the shallow trench ST, which requires additional formation processes and etching processes of the insulating film 7a, which will increase the process flow of the above-mentioned preparation method. The complexity increases the process cost. Moreover, the width of the shallow trench ST is generally fixed, and the sidewalls 7 have a certain width. This will cause the size of the active area 5 to be affected by the sidewalls 7, and further requires photolithography of the active area 5 in advance. The dimensions are corrected to make up for the width of the side wall 7 in advance and increase the width of the opening K, which increases the process risk of the above preparation method.
本申请的一些实施例提供了一种半导体结构的制备方法。如图5所示,该制备方 法包括S100~S500。Some embodiments of the present application provide a method of manufacturing a semiconductor structure. As shown in Figure 5, the preparation method The method includes S100~S500.
S100,如图6所示,提供衬底1。该衬底1具有预设浅沟槽区A。S100, as shown in Figure 6, a substrate 1 is provided. The substrate 1 has a preset shallow trench area A.
示例性的,上述衬底1为晶圆衬底,其可以为后续的半导体制备工艺步骤提供支撑作用。例如,上述衬底1的材料可以为单晶硅、多晶硅、单晶锗、硅锗或碳化硅等;也可以为绝缘体上硅或绝缘体上锗等;还可以为其它的材料,例如砷化镓等Ⅲ-Ⅴ族化合物。For example, the above-mentioned substrate 1 is a wafer substrate, which can provide support for subsequent semiconductor manufacturing process steps. For example, the material of the substrate 1 can be single crystal silicon, polycrystalline silicon, single crystal germanium, silicon germanium or silicon carbide; it can also be silicon on insulator or germanium on insulator; it can also be other materials, such as gallium arsenide. etc. III-V compounds.
上述预设浅沟槽区A的形状可以根据待形成的晶体管(例如CMOS晶体管)的位置设置,本申请对此不作限定。The shape of the above-mentioned preset shallow trench region A can be set according to the position of the transistor to be formed (eg, CMOS transistor), which is not limited in this application.
例如,各待形成的晶体管之间的间距较大。预设浅沟槽区A可以呈环形,分别围绕不同的待形成的晶体管。For example, the spacing between the transistors to be formed is relatively large. The preset shallow trench areas A may be in an annular shape and surround different transistors to be formed.
又如,各待形成的晶体管之间的间距较小。预设浅沟槽区A可以呈网格状(如图1所示),将各待形成的晶体管隔开。For another example, the spacing between the transistors to be formed is small. The preset shallow trench area A can be in a grid shape (as shown in Figure 1) to separate the transistors to be formed.
S200,如图9a~图9c所示,刻蚀上述衬底1中位于预设浅沟槽区A的部分,形成第一子浅沟槽ST1。S200, as shown in FIGS. 9a to 9c, the portion of the substrate 1 located in the preset shallow trench area A is etched to form a first sub-shallow trench ST1.
示例性的,本申请可以采用干法刻蚀工艺或湿法刻蚀工艺对衬底1进行刻蚀,去除衬底1中位于预设浅沟槽区A的一部分。衬底1例如具有相对设置的第一表面1a和第二表面1b,本申请可以对衬底1的第一表面1a进行刻蚀,形成第一子浅沟槽ST1。For example, this application can use a dry etching process or a wet etching process to etch the substrate 1 to remove a part of the substrate 1 located in the preset shallow trench area A. For example, the substrate 1 has a first surface 1a and a second surface 1b arranged opposite each other. In this application, the first surface 1a of the substrate 1 can be etched to form a first sub-shallow trench ST1.
第一子浅沟槽ST1的深度小于衬底1的厚度。也就是说,如图9c所示,形成第一子浅沟槽ST1的过程中,第一子浅沟槽ST1的底壁W1位于衬底1的内部,第一子浅沟槽ST1未贯穿衬底1。The depth of the first sub-shallow trench ST1 is less than the thickness of the substrate 1 . That is to say, as shown in FIG. 9c, during the process of forming the first sub-shallow trench ST1, the bottom wall W1 of the first sub-shallow trench ST1 is located inside the substrate 1, and the first sub-shallow trench ST1 does not penetrate the substrate. Bottom 1.
第一子浅沟槽ST1在衬底1所在平面上的正投影的形状(或者俯视形状),与预设浅沟槽区A的形状相同。第一子浅沟槽ST1的剖视形状,例如呈矩形(如图9c所示)或倒梯形。The shape of the orthographic projection (or plan view shape) of the first sub-shallow trench ST1 on the plane of the substrate 1 is the same as the shape of the preset shallow trench area A. The cross-sectional shape of the first sub-shallow trench ST1 is, for example, rectangular (as shown in FIG. 9c) or an inverted trapezoid.
S300,如图10a和图10b所示,对第一子浅沟槽ST1的侧壁进行离子注入,以在衬底1中形成掺杂区DR。S300, as shown in FIG. 10a and FIG. 10b, perform ion implantation on the sidewall of the first sub-shallow trench ST1 to form a doped region DR in the substrate 1.
示例性的,本申请可以采用离子注入工艺,对第一子浅沟槽ST1的侧壁进行离子注入。注入的离子可以进入衬底1的内部,从而可以在衬底1中形成掺杂区DR。该掺杂区DR可以围绕第一子浅沟槽ST1的侧壁。For example, this application may use an ion implantation process to implant ions into the sidewalls of the first sub-shallow trench ST1. The implanted ions can enter the interior of the substrate 1 , so that a doped region DR can be formed in the substrate 1 . The doped region DR may surround the sidewall of the first sub-shallow trench ST1.
在对第一子浅沟槽ST1的侧壁进行离子注入的过程中,例如,可以仅对侧壁的顶部位置处进行离子注入;又如,可以对侧壁整体的位置处进行离子注入。In the process of ion implantation into the sidewall of the first sub-shallow trench ST1, for example, ion implantation may be performed only at the top position of the sidewall; for example, ion implantation may be performed at the entire sidewall position.
此处,离子注入至衬底1的内部的注入深度,可以根据需要选择设置,本申请对此不作限定。Here, the depth of implantation of ions into the interior of the substrate 1 can be selected and set as needed, and is not limited in this application.
示例性的,在图10b所示的剖视图中,第一子浅沟槽ST1具有两个侧壁W2、W3,两个侧壁W2、W3分别位于底壁W1的两侧,且分别与待形成的晶体管相对应。For example, in the cross-sectional view shown in FIG. 10b, the first sub-shallow trench ST1 has two sidewalls W2 and W3. The two sidewalls W2 and W3 are respectively located on both sides of the bottom wall W1 and are respectively connected with the to-be-formed corresponding to the transistor.
在对第一子浅沟槽ST1的侧壁进行离子注入的过程中,例如,可以同时对第一子浅沟槽ST1的两个侧壁W2、W3进行离子注入;又如,可以先对第一子浅沟槽ST1的两个侧壁W2、W3中的一者进行离子注入,然后对第一子浅沟槽ST1的两个侧壁W2、W3中的另一者进行离子注入。During the process of ion implantation into the sidewalls of the first sub-shallow trench ST1, for example, the two sidewalls W2 and W3 of the first sub-shallow trench ST1 may be ion-implanted at the same time; for another example, the ion implantation may be performed first into the sidewalls W2 and W3 of the first sub-shallow trench ST1. One of the two side walls W2 and W3 of the first sub-shallow trench ST1 is ion implanted, and then the other of the two side walls W2 and W3 of the first sub-shallow trench ST1 is ion implanted.
可以理解的是,如图10b所示,在对第一子浅沟槽ST1的侧壁进行离子注入的过 程中,离子可能也会注入至第一子浅沟槽ST1的底壁W1,从而使得掺杂区DR可以呈网格状,并围绕第一子浅沟槽ST1的底壁W1。It can be understood that, as shown in Figure 10b, during the ion implantation into the sidewall of the first sub-shallow trench ST1 During the process, ions may also be implanted into the bottom wall W1 of the first sub-shallow trench ST1, so that the doping region DR may be in a grid shape and surround the bottom wall W1 of the first sub-shallow trench ST1.
需要说明的是,上述掺杂区DR,可以用于调节待形成的晶体管的阈值电压,例如可以用于调高待形成的晶体管的阈值电压。It should be noted that the above doped region DR can be used to adjust the threshold voltage of the transistor to be formed, for example, can be used to increase the threshold voltage of the transistor to be formed.
S400,如图11a和图11b所示,刻蚀第一子浅沟槽ST1的底壁W1,在第一子浅沟槽ST1的下方形成第二子浅沟槽ST2,得到包括第一子浅沟槽ST1和第二子浅沟槽ST2的浅沟槽ST。S400, as shown in Figures 11a and 11b, etch the bottom wall W1 of the first sub-shallow trench ST1, and form a second sub-shallow trench ST2 below the first sub-shallow trench ST1, to obtain a structure including the first sub-shallow trench ST1. The trench ST1 and the shallow trench ST of the second sub-shallow trench ST2.
示例性的,本申请可以采用干法刻蚀工艺或湿法刻蚀工艺对第一子浅沟槽ST1的底壁W1进行刻蚀,进一步去除衬底1中位于预设浅沟槽区A的一部分,以在第一子浅沟槽ST1的下方形成第二子浅沟槽ST2。第一子浅沟槽ST1和第二子浅沟槽ST2相连通。For example, this application can use a dry etching process or a wet etching process to etch the bottom wall W1 of the first sub-shallow trench ST1, and further remove the substrate 1 located in the preset shallow trench area A. part to form a second sub-shallow trench ST2 below the first sub-shallow trench ST1. The first sub-shallow trench ST1 and the second sub-shallow trench ST2 are connected.
如图11a所示,形成第二子浅沟槽ST2之后,仅保留围绕第一子浅沟槽ST1的侧壁的部分掺杂区DR。As shown in FIG. 11a , after the second sub-shallow trench ST2 is formed, only a portion of the doped region DR surrounding the sidewall of the first sub-shallow trench ST1 remains.
第一子浅沟槽ST1的深度及第二子浅沟槽ST2的深度之和,小于衬底1的厚度。也就是说,如图11b所示,在形成第二子浅沟槽ST2后,第二子浅沟槽ST2的底壁位于衬底1的内部,第二子浅沟槽ST2未贯穿衬底1。由于浅沟槽ST包括第一子浅沟槽ST1和第二子浅沟槽ST2的,第一子浅沟槽ST1的深度及第二子浅沟槽ST2的深度之和则为浅沟槽ST的深度,第二子浅沟槽ST2的底壁则为浅沟槽ST的底壁。也就是说,浅沟槽ST未贯穿衬底1,浅沟槽ST的底壁和衬底1的第二表面1b之间具有一定的间距。这样有利于确保衬底1的结构稳定性。The sum of the depths of the first sub-shallow trench ST1 and the second sub-shallow trench ST2 is less than the thickness of the substrate 1 . That is to say, as shown in FIG. 11b , after the second sub-shallow trench ST2 is formed, the bottom wall of the second sub-shallow trench ST2 is located inside the substrate 1 , and the second sub-shallow trench ST2 does not penetrate the substrate 1 . Since the shallow trench ST includes the first sub-shallow trench ST1 and the second sub-shallow trench ST2, the sum of the depths of the first sub-shallow trench ST1 and the depth of the second sub-shallow trench ST2 is shallow trench ST. The depth of the second sub-shallow trench ST2 is the bottom wall of the shallow trench ST. That is to say, the shallow trench ST does not penetrate the substrate 1 , and there is a certain distance between the bottom wall of the shallow trench ST and the second surface 1 b of the substrate 1 . This is beneficial to ensuring the structural stability of the substrate 1 .
示例性的,浅沟槽ST的深度的范围为 Exemplarily, the depth of the shallow trench ST ranges from
例如,浅沟槽ST的深度为等。For example, the depth of shallow trench ST is or wait.
第二子浅沟槽ST2在衬底1所在平面上的正投影的形状(或者俯视形状),与预设浅沟槽区A的形状相同。第二子浅沟槽ST2的剖视形状,例如呈矩形或倒梯形(如图11b所示)。The shape of the orthographic projection (or plan view shape) of the second sub-shallow trench ST2 on the plane of the substrate 1 is the same as the shape of the preset shallow trench area A. The cross-sectional shape of the second sub-shallow trench ST2 is, for example, rectangular or inverted trapezoid (as shown in Figure 11b).
S500,如图13a~图13d所示,在上述浅沟槽ST内形成填充部4。S500, as shown in FIGS. 13a to 13d , the filling portion 4 is formed in the shallow trench ST.
示例性的,填充部4的材料为绝缘材料,该绝缘材料例如包括绝缘氧化物。例如,填充部4的材料包括二氧化硅。填充部4至少填满浅沟槽ST。For example, the material of the filling portion 4 is an insulating material, and the insulating material includes, for example, insulating oxide. For example, the material of the filling portion 4 includes silicon dioxide. The filling portion 4 fills at least the shallow trench ST.
上述浅沟槽ST、位于浅沟槽ST内的填充部4及位于衬底1中的掺杂区DR,例如可以称为浅沟槽隔离结构。本申请一方面可以利用浅沟槽隔离结构中的浅沟槽ST将待形成的晶体管隔开,另一方面,可以利用浅沟槽隔离结构中的填充部4提高衬底1的结构稳定性,并对待形成的晶体管进行隔离,提高待形成的晶体管的性能,再一方面,还可以利用具有注入离子的掺杂区DR,调节待形成晶体管的阈值电压,降低待形成晶体管的漏电流,提高待形成晶体管的性能,从而改善窄沟道效应。这样有利于压缩待形成晶体管的沟道尺寸,进而有利于减小待形成的位单元的面积,实现更高密度、更高性能的应用。The above-mentioned shallow trench ST, the filling portion 4 located in the shallow trench ST, and the doped region DR located in the substrate 1 can be called a shallow trench isolation structure, for example. On the one hand, this application can use the shallow trench ST in the shallow trench isolation structure to isolate the transistors to be formed. On the other hand, the application can use the filling portion 4 in the shallow trench isolation structure to improve the structural stability of the substrate 1. And isolate the transistor to be formed to improve the performance of the transistor to be formed. On the other hand, the doping region DR with injected ions can also be used to adjust the threshold voltage of the transistor to be formed, reduce the leakage current of the transistor to be formed, and improve the performance of the transistor to be formed. The performance of the transistor is improved thereby improving the narrow channel effect. This is conducive to compressing the channel size of the transistor to be formed, which in turn is conducive to reducing the area of the bit cell to be formed, and achieving higher density and higher performance applications.
需要说明的是,本申请对浅沟槽ST的形成过程进行了分解,采用两次刻蚀工艺分别形成第一子浅沟槽ST1和第二子浅沟槽ST2,并在刻蚀形成第二子浅沟槽ST2之 前,便对第一子浅沟槽ST1暴露的侧壁进行离子注入,在刻蚀形成第二子浅沟槽ST2之后,一次性形成至少填满浅沟槽ST的填充部4。It should be noted that this application decomposes the formation process of the shallow trench ST, using two etching processes to form the first sub-shallow trench ST1 and the second sub-shallow trench ST2 respectively, and then etching to form the second sub-shallow trench ST1. Sub-shallow trench ST2 Before that, ion implantation is performed on the exposed sidewalls of the first sub-shallow trench ST1. After the second sub-shallow trench ST2 is formed by etching, the filling portion 4 that at least fills the shallow trench ST is formed in one go.
相比于上述一种实现方式提供的制备方法,由于本申请是形成浅沟槽ST之后,再在浅沟槽ST内形成至少填满浅沟槽ST的填充部4,一方面可以避免对填充部4进行回刻,避免填充部4受到等离子体的轰击,确保填充部4的绝缘性能和可靠性,另一方面,可以避免在形成填充部4的过程中破真空,进而避免填充部4接触空气而形成缺陷,又一方面,可以避免增加回刻的工序,降低工艺成本。另外,由于本申请是先对第一子浅沟槽ST1暴露的侧壁进行离子注入、后形成填充部4的,这样可以避免将离子注入至填充部4中,使得填充部4可以没有额外的离子注入的影响,从而可以进一步确保填充部4的绝缘性能和可靠性。Compared with the preparation method provided by one of the above implementations, since this application forms the shallow trench ST and then forms the filling portion 4 in the shallow trench ST that at least fills the shallow trench ST, on the one hand, it can avoid filling The filling part 4 is etched back to prevent the filling part 4 from being bombarded by plasma, ensuring the insulation performance and reliability of the filling part 4. On the other hand, it is possible to avoid breaking the vacuum during the formation of the filling part 4, thereby preventing the filling part 4 from contacting Defects are formed due to air. On the other hand, it can avoid increasing the engraving process and reduce process costs. In addition, since this application first performs ion implantation on the exposed sidewalls of the first sub-shallow trench ST1 and then forms the filling part 4, this can avoid implanting ions into the filling part 4, so that the filling part 4 can be without additional The influence of ion implantation can further ensure the insulation performance and reliability of the filling part 4 .
在一些示例中,在上述S200中,刻蚀衬底1中位于预设浅沟槽区A的部分,包括:S210~S230。In some examples, in the above S200, the portion of the substrate 1 located in the preset shallow trench area A is etched, including: S210 to S230.
S210,如图7a和图7b所示,在衬底1上依次形成衬垫层2、硬掩模层3和光刻胶层8。S210, as shown in FIG. 7a and FIG. 7b, a liner layer 2, a hard mask layer 3 and a photoresist layer 8 are sequentially formed on the substrate 1.
示例性的,本申请可以采用化学气相沉积(chemical vapor deposition,CVD)、物理气相沉积(physical vapor deposition,PVD)、原子层沉积(atomic layer deposition,ALD)或其任何组合的薄膜沉积工艺,在衬底1的第一表面1a上形成衬垫层2,然后可以采用CVD、PVD、ALD或其任何组合的薄膜沉积工艺,在衬垫层2上形成硬掩模层3,然后采用涂覆工艺(例如旋涂或点涂等)在硬掩模层3上形成光刻胶层8。For example, this application may use chemical vapor deposition (CVD), physical vapor deposition (PVD), atomic layer deposition (ALD) or any combination of thin film deposition processes. A liner layer 2 is formed on the first surface 1a of the substrate 1, and then a thin film deposition process such as CVD, PVD, ALD or any combination thereof can be used to form a hard mask layer 3 on the liner layer 2, and then a coating process is used (For example, spin coating or dot coating, etc.) A photoresist layer 8 is formed on the hard mask layer 3 .
示例性的,衬垫层2的材料包括二氧化硅,硬掩模层3的材料包括氮化硅,光刻胶层8的材料包括负性光刻胶。For example, the material of the liner layer 2 includes silicon dioxide, the material of the hard mask layer 3 includes silicon nitride, and the material of the photoresist layer 8 includes negative photoresist.
通过在衬底1和硬掩模层3之间设置衬垫层2,可以利用衬垫层2作为过渡,缓解衬底1和硬掩模层3之间的应力。By disposing the liner layer 2 between the substrate 1 and the hard mask layer 3, the liner layer 2 can be used as a transition to relieve the stress between the substrate 1 and the hard mask layer 3.
S220,如图8a~图8b所示,刻蚀光刻胶层8中位于预设浅沟槽区A的部分,在光刻胶层8中形成第一开口K1。S220, as shown in FIGS. 8a to 8b, the portion of the photoresist layer 8 located in the preset shallow trench area A is etched, and a first opening K1 is formed in the photoresist layer 8.
示例性的,本申请可以采用光刻工艺对光刻胶层8中位于预设浅沟槽区A的部分进行刻蚀。可选地,本申请可以在光刻胶层8上设置掩膜板,该掩膜板遮挡光刻胶层8中位于预设浅沟槽区A的部分,并暴露光刻胶层8中位于预设浅沟槽区A以外的部分,通过掩膜板对光刻胶层8进行曝光,使得光刻胶层8中位于预设浅沟槽区A以外的部分进行固化,然后对光刻胶层8进行显影,保留光刻胶层8中位于预设浅沟槽区A以外的部分,去除光刻胶层8中位于预设浅沟槽区A的部分,从而在光刻胶层8中形成第一开口K1。For example, this application may use a photolithography process to etch the portion of the photoresist layer 8 located in the preset shallow trench area A. Optionally, this application can set a mask on the photoresist layer 8, which blocks the portion of the photoresist layer 8 located in the preset shallow trench area A, and exposes the portion of the photoresist layer 8 located in the preset shallow trench area A. The portion outside the preset shallow trench area A is exposed to the photoresist layer 8 through a mask, so that the portion of the photoresist layer 8 outside the preset shallow trench area A is cured, and then the photoresist layer 8 is exposed. The layer 8 is developed, retaining the portion of the photoresist layer 8 located outside the preset shallow trench area A, and removing the portion of the photoresist layer 8 located in the preset shallow trench area A, so that in the photoresist layer 8 A first opening K1 is formed.
其中,光刻胶层8可以对硬掩模层3、衬垫层2和衬底1中被其所遮挡、屏蔽的部分进行保护。Among them, the photoresist layer 8 can protect the parts of the hard mask layer 3, the liner layer 2 and the substrate 1 that are blocked and shielded by the photoresist layer 8.
S230,如图9a~图9c所示,通过上述第一开口K1,刻蚀硬掩模层3、衬垫层2和衬底1中位于预设浅沟槽区A的部分,在硬掩模层3和衬垫层2中形成第二开口K2,并在衬底1中形成第一子浅沟槽ST1。S230, as shown in Figures 9a to 9c, etch the hard mask layer 3, the liner layer 2 and the portion of the substrate 1 located in the preset shallow trench area A through the first opening K1. A second opening K2 is formed in layer 3 and liner layer 2 , and a first sub-shallow trench ST1 is formed in substrate 1 .
示例性的,本申请可以采用干法刻蚀工艺或湿法刻蚀工艺对硬掩模层3、衬垫层2和衬底1中位于预设浅沟槽区A的部分进行刻蚀。 For example, this application can use a dry etching process or a wet etching process to etch the hard mask layer 3, the liner layer 2 and the portion of the substrate 1 located in the preset shallow trench area A.
本申请可以在一次刻蚀工艺中,完成对硬掩模层3、衬垫层2和衬底1中位于预设浅沟槽区A的部分的刻蚀,或者,本申请可以采用多次刻蚀工艺,完成对硬掩模层3、衬垫层2和衬底1中位于预设浅沟槽区A的部分的刻蚀。This application can complete the etching of the hard mask layer 3, the liner layer 2 and the portion of the substrate 1 located in the preset shallow trench area A in one etching process, or this application can use multiple etching processes. An etching process is performed to complete the etching of the hard mask layer 3, the liner layer 2 and the portion of the substrate 1 located in the preset shallow trench area A.
在采用多次刻蚀工艺,完成对硬掩模层3、衬垫层2和衬底1中位于预设浅沟槽区A的部分的刻蚀的情况下,刻蚀过程例如包括但不限于:如图9b所示,通过光刻胶层8中的第一开口K1,对硬掩模层3和衬垫层2进行刻蚀,在硬掩模层3和衬垫层2中形成第二开口K2;如图9c所示,通过上述第一开口K1和第二开口K2,对衬底1中位于预设浅沟槽区A的部分进行刻蚀,在衬底1中形成第一子浅沟槽ST1。In the case where multiple etching processes are used to complete the etching of the hard mask layer 3 , the liner layer 2 and the portion of the substrate 1 located in the preset shallow trench area A, the etching process includes, for example, but is not limited to : As shown in Figure 9b, the hard mask layer 3 and the liner layer 2 are etched through the first opening K1 in the photoresist layer 8, and a second opening K1 is formed in the hard mask layer 3 and the liner layer 2. Opening K2; as shown in Figure 9c, through the above-mentioned first opening K1 and the second opening K2, the portion of the substrate 1 located in the preset shallow trench area A is etched, and a first sub-shallow trench is formed in the substrate 1. Trench ST1.
可以理解的是,硬掩模层3具有较高的刻蚀选择比,因此,第一子浅沟槽ST1的侧壁形貌、底壁形貌均较为规则,第一子浅沟槽ST1的宽度较为均一,且第一子浅沟槽ST1的宽度与第二开口K2的宽度基本一致。It can be understood that the hard mask layer 3 has a high etching selectivity ratio. Therefore, the sidewall morphology and bottom wall morphology of the first sub-shallow trench ST1 are relatively regular, and the morphology of the first sub-shallow trench ST1 is relatively regular. The width is relatively uniform, and the width of the first sub-shallow trench ST1 is basically the same as the width of the second opening K2.
需要说明的是,本申请在形成第一子浅沟槽ST1之后,便可以对第一子浅沟槽ST1的侧壁进行离子注入,然后对第一子浅沟槽ST1的底壁进行刻蚀,形成第二子浅沟槽ST2,得到浅沟槽ST。也就是说,本申请主要利用硬掩模层3来定义第一子浅沟槽ST1,进而定义浅沟槽ST。It should be noted that in this application, after forming the first sub-shallow trench ST1, ion implantation can be performed on the sidewalls of the first sub-shallow trench ST1, and then the bottom wall of the first sub-shallow trench ST1 can be etched. , forming the second sub-shallow trench ST2, and obtaining the shallow trench ST. That is to say, this application mainly uses the hard mask layer 3 to define the first sub-shallow trench ST1 and then define the shallow trench ST.
相比于上述另一种实现方式提供的制备方法,本申请形成浅沟槽ST1的方法更为简单,一方面可以减少形成绝缘薄膜7a的工序及对绝缘薄膜7a进行刻蚀以形成侧墙7的工序,降低工艺成本,另一方面可以使得第二开口K1的宽度、第二开口K2的宽度,与浅沟槽ST的宽度一致,避免出现因设置侧墙7而需预先对有源区5的光刻尺寸进行修改的情况,降低本申请提供的制备方法的工艺风险。Compared with the preparation method provided by the other implementation method mentioned above, the method of forming the shallow trench ST1 in this application is simpler. On the one hand, it can reduce the process of forming the insulating film 7a and etching the insulating film 7a to form the sidewalls 7 process to reduce process costs. On the other hand, the width of the second opening K1 and the width of the second opening K2 can be made consistent with the width of the shallow trench ST, thereby avoiding the need to pre-set the active area 5 due to the provision of sidewalls 7 The photolithography dimensions are modified to reduce the process risk of the preparation method provided by this application.
在一些示例中,上述第一子浅沟槽ST1的深度范围为(埃) In some examples, the depth range of the above-mentioned first sub-shallow trench ST1 is (angstrom)
示例性的,第一浅沟槽ST1的深度可以为 等。For example, the depth of the first shallow trench ST1 may be or wait.
通过对第一浅沟槽ST1的深度进行限制,可以确保注入至第一子浅沟槽ST1的侧壁的离子的量,能够对待形成的晶体管的阈值电压进行有效地调整,有效地改善窄沟道效应。这样可以避免出现因第一子浅沟槽ST1的深度较小,导致离子注入量较少而难以调整待形成的晶体管的阈值电压、难以改善窄沟道效应的情况,或者,可以避免出现因第一子浅沟槽ST1的深度较大,导致离子注入量较大而降低对待形成的晶体管的阈值电压的调整效果、降低窄沟道效应的改善效果。By limiting the depth of the first shallow trench ST1, the amount of ions injected into the sidewalls of the first sub-shallow trench ST1 can be ensured, the threshold voltage of the transistor to be formed can be effectively adjusted, and the narrow trench can be effectively improved. Tao effect. This can avoid the situation that it is difficult to adjust the threshold voltage of the transistor to be formed and improve the narrow channel effect due to the small amount of ion implantation due to the small depth of the first sub-shallow trench ST1. Alternatively, it can avoid the situation that the first sub-shallow trench ST1 has a small depth. The depth of the sub-shallow trench ST1 is relatively large, resulting in a large amount of ion implantation, thereby reducing the adjustment effect of the threshold voltage of the transistor to be formed and the improvement effect of the narrow channel effect.
在一些示例中,在上述S300中,对第一子浅沟槽ST1的侧壁进行离子注入,包括:S310~S320。In some examples, in the above-mentioned S300, ion implantation is performed on the sidewall of the first sub-shallow trench ST1, including: S310˜S320.
S310,如图10a和图10b所示,去除上述光刻胶层8。S310, as shown in Figure 10a and Figure 10b, remove the above photoresist layer 8.
示例性的,本申请可以采用等离子字体刻蚀工艺、湿法刻蚀工艺或其他任何刻蚀工艺,去除光刻胶层8,并暴露硬掩模层3。For example, this application can use a plasma font etching process, a wet etching process or any other etching process to remove the photoresist layer 8 and expose the hard mask layer 3 .
S320,如图10a和图10b所示,以硬掩模层3和衬垫层2为掩模,通过第二开口K2,对第一子浅沟槽ST1的侧壁进行离子注入。离子注入的方向与垂直于衬底1的方向之间具有夹角,该夹角例如为α。S320, as shown in FIG. 10a and FIG. 10b, using the hard mask layer 3 and the liner layer 2 as masks, ion implantation is performed into the sidewall of the first sub-shallow trench ST1 through the second opening K2. There is an included angle between the direction of ion implantation and the direction perpendicular to the substrate 1, and the included angle is, for example, α.
可以理解的是,在对第一子浅沟槽ST1的侧壁进行离子注入的过程中,硬掩模层3和衬垫层2可以作为掩模,对衬底1的第一表面进行遮挡、屏蔽,可以确保离子能 够注入至第一浅沟槽ST1的侧壁,避免离子注入至衬底1的第一表面,进而避免影响待形成的晶体管的性能。It can be understood that during the process of ion implantation into the sidewall of the first sub-shallow trench ST1, the hard mask layer 3 and the liner layer 2 can be used as masks to shield the first surface of the substrate 1. Shielding ensures ion energy It can be implanted into the sidewall of the first shallow trench ST1 to prevent ions from being implanted into the first surface of the substrate 1 and thus avoid affecting the performance of the transistor to be formed.
示例性的,离子注入的方向与垂直于衬底1的方向之间具有夹角α,指的是离子注入的方向与垂直于衬底1的方向不平行,离子注入的方向与衬底1所在平面的方向之间的夹角小于90°。For example, there is an angle α between the direction of ion implantation and the direction perpendicular to the substrate 1, which means that the direction of ion implantation is not parallel to the direction perpendicular to the substrate 1, and the direction of ion implantation is not parallel to the direction where the substrate 1 is located. The angle between the directions of the planes is less than 90°.
这样可以确保离子能够注入至第一子浅沟槽ST1的侧壁,进而能够对待形成的晶体管的阈值电压进行调整,改善窄沟道效应。This ensures that ions can be implanted into the sidewall of the first sub-shallow trench ST1, thereby adjusting the threshold voltage of the transistor to be formed and improving the narrow channel effect.
在一些示例中,上述离子注入的方向与垂直于衬底1的方向之间的夹角α的范围为5°~45°。In some examples, the angle α between the direction of the ion implantation and the direction perpendicular to the substrate 1 ranges from 5° to 45°.
示例性的,上述夹角α可以为5°、10°、15°、20°、25°、29°、33°、或45°等。For example, the above-mentioned included angle α may be 5°, 10°, 15°, 20°, 25°, 29°, 33°, or 45°, etc.
这样可以确保大部分的离子能够注入至第一子浅沟槽ST1的侧壁,减少注入至第一子浅沟槽ST1的底壁的离子的量,以便于在实现对待形成的晶体管的阈值电压的调节、对窄沟道效应的改善的同时,减少离子的使用量(或浪费量),降低工艺成本。This can ensure that most of the ions can be injected into the sidewalls of the first sub-shallow trench ST1 and reduce the amount of ions injected into the bottom wall of the first sub-shallow trench ST1, so as to achieve the threshold voltage of the transistor to be formed. While adjusting and improving the narrow channel effect, it also reduces the usage (or waste) of ions and reduces process costs.
可以理解的是,如图11a和图11b所示,在对第一子浅沟槽ST1的侧壁进行离子注入之后,本申请仍然可以硬掩模层3和衬垫层2为掩模,通过第二开口K2,对第一子浅沟槽ST1的底壁进行刻蚀,形成第二子浅沟槽ST2,以便于确保第二子浅沟槽ST2的均一性。It can be understood that, as shown in Figure 11a and Figure 11b, after ion implantation is performed on the sidewall of the first sub-shallow trench ST1, the present application can still use the hard mask layer 3 and the liner layer 2 as masks, through The second opening K2 is used to etch the bottom wall of the first sub-shallow trench ST1 to form the second sub-shallow trench ST2, so as to ensure the uniformity of the second sub-shallow trench ST2.
在一些示例中,在上述S500中,在浅沟槽ST内形成填充部4,包括:S510~S520。In some examples, in the above S500, the filling portion 4 is formed in the shallow trench ST, including: S510 to S520.
S510,如图12a和图12b所示,在硬掩模层3上形成填充薄膜4a,该填充薄膜4a的一部分位于浅沟槽ST。S510, as shown in FIG. 12a and FIG. 12b, a filling film 4a is formed on the hard mask layer 3, and a part of the filling film 4a is located in the shallow trench ST.
示例性的,本申请可以采用CVD、PVD、ALD或其任何组合的薄膜沉积工艺,形成填充薄膜4a。其中,填充薄膜4a的一部分位于浅沟槽ST内,填满浅沟槽ST;填充薄膜4a的另一部分位于硬掩模层3上,并覆盖硬掩模层3。For example, this application can use a film deposition process such as CVD, PVD, ALD or any combination thereof to form the filling film 4a. Among them, a part of the filling film 4a is located in the shallow trench ST and fills the shallow trench ST; the other part of the filling film 4a is located on the hard mask layer 3 and covers the hard mask layer 3.
S520,如图13a和图13b所示,去除填充薄膜4a覆盖硬掩模层3的部分及硬掩模层3,保留填充薄膜4a的位于浅沟槽ST的部分,形成填充部4。S520, as shown in FIGS. 13a and 13b, remove the portion of the filling film 4a covering the hard mask layer 3 and the hard mask layer 3, leaving the portion of the filling film 4a located in the shallow trench ST to form the filling portion 4.
示例性的,本申请可以采用化学机械研磨(chemical mechanical polish,CMP)工艺对填充薄膜4a进行研磨以平坦化,并暴露硬掩模层3,然后可以采用湿法刻蚀工艺对硬掩模层3进行刻蚀,去除硬掩模层3,并暴露衬垫层2。其中,填充部4远离衬底1的一侧表面,可以高于衬垫层2远离衬底1的一侧表面。For example, this application can use a chemical mechanical polish (CMP) process to polish the filling film 4a to planarize it, and expose the hard mask layer 3, and then use a wet etching process to polish the hard mask layer. 3 is etched to remove the hard mask layer 3 and expose the liner layer 2. The side surface of the filling portion 4 away from the substrate 1 may be higher than the side surface of the liner layer 2 away from the substrate 1 .
可以理解的是,填充薄膜4a和硬掩模层3的研磨速率不同。这样在研磨去除填充薄膜4a的过程中,可能会去除部分硬掩模层3。It can be understood that the filling film 4a and the hard mask layer 3 have different polishing rates. In this way, during the process of grinding and removing the filling film 4a, part of the hard mask layer 3 may be removed.
由上可知,本申请中的填充部4呈一体结构,是通过一次半导体工艺(也即CMP工艺)一次性形成的。这样不仅可以避免在填充部4中形成缺陷,避免填充部4受到额外的离子注入的影响,确保填充部4的绝缘性能和可靠性,还可以简化填充部4的制备工艺,降低工艺成本。It can be seen from the above that the filling part 4 in this application has an integrated structure and is formed at one time through a semiconductor process (that is, a CMP process). This not only avoids the formation of defects in the filling part 4, prevents the filling part 4 from being affected by additional ion implantation, ensures the insulation performance and reliability of the filling part 4, but also simplifies the preparation process of the filling part 4 and reduces the process cost.
在一些示例中,本申请提供的制备方法还包括:对上述S510中形成的填充薄膜4a进行退火处理。In some examples, the preparation method provided by this application also includes: annealing the filling film 4a formed in the above S510.
示例性的,本申请可以采用热退火工艺或激光退火工艺等退火工艺,对填充薄膜4a进行退火处理。 For example, this application may use an annealing process such as a thermal annealing process or a laser annealing process to anneal the filling film 4a.
在一些示例中,本申请提供的制备方法还包括:对掺杂区DR进行退火处理。In some examples, the preparation method provided by this application further includes: annealing the doped region DR.
示例性的,本申请可以采用热退火工艺或激光退火工艺等退火工艺,对掺杂区DR进行退火处理。For example, this application may use an annealing process such as a thermal annealing process or a laser annealing process to anneal the doped region DR.
这样可以修复经离子注入后造成的材料的晶格损伤及激活注入的离子。This can repair the lattice damage of the material caused by ion implantation and activate the implanted ions.
示例性的,本申请可以在对上述填充薄膜4a进行退火处理的过程中,还对掺杂区DR进行退火处理。For example, in this application, during the annealing process of the above-mentioned filling film 4a, the doping region DR can also be annealed.
也就是说,本申请可以将掺杂区DR的退火处理工序集成到半导体结构的制备方法中已有的退火处理工序内,在一次退过工艺中,同时对填充薄膜4a和掺杂区DR进行退过处理,这样可以避免引入额外的退火处理工序,简化半导体结构的制备工艺,降低工艺成本。In other words, this application can integrate the annealing process of the doped region DR into the existing annealing process in the preparation method of the semiconductor structure, and simultaneously perform the annealing process on the filling film 4a and the doped region DR in one annealing process. The annealing process can avoid the introduction of additional annealing processes, simplify the preparation process of semiconductor structures, and reduce process costs.
在一些实施例中,本申请提供的制备方法还包括:S600~S800。In some embodiments, the preparation method provided by this application also includes: S600 to S800.
S600,如图13c所示,对衬底1的被浅沟槽ST围绕的部分进行离子注入,形成有源区5。S600, as shown in FIG. 13c, ion implantation is performed on the portion of the substrate 1 surrounded by the shallow trench ST to form the active region 5.
示例性的,本申请可以采用多次离子注入工艺形成有源区5。For example, this application may use multiple ion implantation processes to form the active region 5 .
例如,本申请可以采用三次离子注入工艺形成有源区5。For example, this application can use three ion implantation processes to form the active region 5 .
可选地,在第一次离子注入工艺中,可以将离子注入至衬底1的内部,以在衬底1中形成阱区51;其中,第一次离子注入的深度大于第一子浅沟槽ST1的深度,小于浅沟槽ST的深度。根据注入离子的类型,所形成的阱区51可以为P阱(P well)或N阱(N well)。Optionally, in the first ion implantation process, ions can be implanted into the interior of the substrate 1 to form the well region 51 in the substrate 1; wherein, the depth of the first ion implantation is greater than the first sub-shallow trench. The depth of trench ST1 is smaller than the depth of shallow trench ST. Depending on the type of implanted ions, the formed well region 51 may be a P well (P well) or an N well (N well).
在第二次离子注入工艺中,可以将离子注入至阱区51内,且深入衬底1的内部,以在衬底1中形成防穿通层;其中,第二次离子注入的深度,小于第一次离子注入的深度。In the second ion implantation process, ions can be implanted into the well region 51 and deep into the interior of the substrate 1 to form an anti-penetration layer in the substrate 1; wherein, the depth of the second ion implantation is smaller than the depth of the second ion implantation process. The depth of one ion implantation.
在第三次离子注入工艺中,可以将离子注入至阱区51内,且基本靠近或位于衬底1的第一表面1a,以在基本靠近或位于衬底1的第一表面1a处形成沟道区52。In the third ion implantation process, ions may be implanted into the well region 51 and substantially close to or located at the first surface 1 a of the substrate 1 to form a trench substantially close to or located at the first surface 1 a of the substrate 1 Road District 52.
在一些示例中,在上述S600中,对衬底1的被浅沟槽ST围绕的部分进行离子注入,包括:S610~S620。In some examples, in the above-mentioned S600, ion implantation is performed on the portion of the substrate 1 surrounded by the shallow trench ST, including: S610˜S620.
S610,去除光刻胶层8和硬掩模层3。S610, remove the photoresist layer 8 and the hard mask layer 3.
此处,去除光刻胶层8和硬掩模层3的过程,可以参照上述S310和S320中的说明,此处不再赘述。Here, for the process of removing the photoresist layer 8 and the hard mask layer 3, reference can be made to the descriptions in S310 and S320 above, which will not be described again here.
S620,如图13c所示,以衬垫层2为保护层,透过衬垫层2对衬底1的被浅沟槽ST围绕的部分进行离子注入。S620, as shown in FIG. 13c, using the liner layer 2 as a protective layer, ions are implanted through the liner layer 2 into the portion of the substrate 1 surrounded by the shallow trench ST.
可以理解的是,在对衬底1的被浅沟槽ST围绕的部分进行离子注入的过程中,衬垫层2可以对衬底1的表面(也即第一表面1a)形成保护,避免衬底1的表面受到损伤。It can be understood that during the ion implantation process into the portion of the substrate 1 surrounded by the shallow trench ST, the liner layer 2 can protect the surface of the substrate 1 (that is, the first surface 1a) to prevent the liner from forming. The surface of bottom 1 is damaged.
S700,如图14a~图15b所示,在有源区5上形成栅介质层6和栅极9。S700, as shown in FIGS. 14a to 15b, the gate dielectric layer 6 and the gate electrode 9 are formed on the active area 5.
在一些示例中,如图13d所示,在上述S700之前,本申请提供的制备方法还包括:去除衬垫层2。这样可以避免影响栅介质层6和栅极9的形成。In some examples, as shown in Figure 13d, before the above-mentioned S700, the preparation method provided by this application further includes: removing the liner layer 2. This can avoid affecting the formation of the gate dielectric layer 6 and the gate electrode 9 .
示例性的,本申请可以采用湿法刻蚀工艺或干法刻蚀工艺等去除衬垫层2。For example, this application may use a wet etching process or a dry etching process to remove the liner layer 2 .
在去除衬垫层2之后,如图14a和图14b所示,本申请例如采用热氧化工艺在有 源区5上形成栅介质薄膜6a,栅介质薄膜6a位于衬底1的第一表面1a上。然后采用沉积工艺或溅射工艺等在栅介质薄膜6a上形成栅导电薄膜,之后可以采用光刻工艺等对栅介质薄膜6a和栅导电薄膜进行刻蚀,形成栅介质层6和栅极9。其中,栅介质层6和栅极9呈条状,覆盖有源区5的一部分,并将有源区5未被覆盖的部分划分为了两部分。After removing the liner layer 2, as shown in Figure 14a and Figure 14b, this application uses a thermal oxidation process to A gate dielectric film 6 a is formed on the source region 5 , and the gate dielectric film 6 a is located on the first surface 1 a of the substrate 1 . Then, a deposition process or a sputtering process is used to form a gate conductive film on the gate dielectric film 6a, and then a photolithography process or the like can be used to etch the gate dielectric film 6a and the gate conductive film to form the gate dielectric layer 6 and the gate electrode 9. Among them, the gate dielectric layer 6 and the gate electrode 9 are strip-shaped, covering a part of the active area 5 and dividing the uncovered part of the active area 5 into two parts.
示例性的,栅介质层6的材料包括氧化物材料,该氧化物材料例如包括氧化硅等。For example, the material of the gate dielectric layer 6 includes an oxide material, and the oxide material includes, for example, silicon oxide.
采用热氧化工艺形成栅介质薄膜6a,有利于提高后续形成的栅介质层6的质量。Using a thermal oxidation process to form the gate dielectric film 6a is beneficial to improving the quality of the subsequently formed gate dielectric layer 6.
S800,如图16a和图16b所示,在有源区5中未被栅介质层6和栅极9覆盖的部分进行离子注入,形成晶体管T的源极S和漏极D。S800, as shown in FIG. 16a and FIG. 16b, ion implantation is performed in the portion of the active region 5 that is not covered by the gate dielectric layer 6 and the gate electrode 9 to form the source S and drain D of the transistor T.
示例性的,在进行离子注入的过程中,有源区5中被栅介质层6和栅极9覆盖的部分被遮挡,离子基本没有注入该部分,而是注入至未被栅介质层6和栅极9覆盖的部分,也即,栅介质层6和栅极9的两侧。For example, during the ion implantation process, the portion of the active region 5 covered by the gate dielectric layer 6 and the gate electrode 9 is blocked, and ions are basically not implanted into this portion, but are injected into the portion that is not covered by the gate dielectric layer 6 and the gate electrode 9 . The portion covered by the gate electrode 9 , that is, the gate dielectric layer 6 and both sides of the gate electrode 9 .
可以理解的是,有源区5中未被栅介质层6和栅极9覆盖的部分在进行离子注入之后,会形成分别位于栅介质层6和栅极9两侧的两个导体,该两个导体分别构成晶体管T的源极S和漏极D。位于源极S和漏极D之间、且被栅介质层6和栅极9覆盖的部分沟道区52构成仅提供T的沟道。It can be understood that, after ion implantation, the portion of the active region 5 that is not covered by the gate dielectric layer 6 and the gate electrode 9 will form two conductors located on both sides of the gate dielectric layer 6 and the gate electrode 9 respectively. The two conductors form the source S and drain D of the transistor T respectively. The part of the channel region 52 located between the source electrode S and the drain electrode D and covered by the gate dielectric layer 6 and the gate electrode 9 constitutes a channel that only provides T.
采用上述制备方法,便可以制备形成晶体管T,该晶体管T可以为PMOS晶体管,也可以为NMOS晶体管。在衬底1中形成多个晶体管T的半导体结构,例如可以构成集成电路或控制电路等结构。Using the above preparation method, the transistor T can be prepared and formed. The transistor T can be a PMOS transistor or an NMOS transistor. A semiconductor structure in which a plurality of transistors T is formed in the substrate 1 may constitute, for example, an integrated circuit or a control circuit.
可以理解的是,形成有源区5后,有源区5中的沟道区52和掺杂区DR(例如称为局部沟道)相接触。由于制备形成晶体管T之后,晶体管T的沟道仍然会和掺杂区DR相接触,因此,两者接触的区域会形成额外的沟道注入。该额外的沟道注入会对晶体管T的沟道产生影响,能够调整、稳定晶体管T的阈值电压,降低晶体管T的漏电,改善、抑制窄沟道效应,提高晶体管T的性能。这样有利于减小晶体管T的沟道宽度,减小晶体管T的面积,便于在衬底1中形成更多的晶体管T。It can be understood that after the active region 5 is formed, the channel region 52 in the active region 5 and the doping region DR (for example, called a local channel) are in contact. After the transistor T is fabricated and formed, the channel of the transistor T will still be in contact with the doped region DR. Therefore, additional channel implantation will be formed in the contact area between the two. This additional channel injection will have an impact on the channel of the transistor T, which can adjust and stabilize the threshold voltage of the transistor T, reduce the leakage of the transistor T, improve and suppress the narrow channel effect, and improve the performance of the transistor T. This is beneficial to reducing the channel width of the transistor T, reducing the area of the transistor T, and facilitating the formation of more transistors T in the substrate 1 .
值得一提的是,采用本申请提供的制备方法所形成的晶体管T的沟道宽度,可以达到设计规则手册要求的最小设计值,甚至小于设计规则手册要求的最小设计值。也就是说,采用本申请提供的制备方法,有利于大大增加衬底1中所形成的晶体管T的数量,提高晶体管T的密度,实现高性能、高密度的应用。It is worth mentioning that the channel width of the transistor T formed using the preparation method provided by this application can reach the minimum design value required by the design rule manual, or even be smaller than the minimum design value required by the design rule manual. That is to say, using the preparation method provided by this application can greatly increase the number of transistors T formed in the substrate 1, increase the density of the transistors T, and achieve high-performance and high-density applications.
在一些示例中,上述晶体管T的类型和注入至第一子浅沟槽ST1的侧壁的离子类型相关。In some examples, the type of the above-mentioned transistor T is related to the type of ions implanted into the sidewall of the first sub-shallow trench ST1.
示例性的,晶体管T为N型晶体管(也即NMOS晶体管),注入至第一子浅沟槽ST1的侧壁的离子为P型离子。For example, the transistor T is an N-type transistor (that is, an NMOS transistor), and the ions injected into the sidewall of the first sub-shallow trench ST1 are P-type ions.
示例性的,晶体管为P型晶体管(也即PMOS晶体管),注入至第一子浅沟槽ST1的侧壁的离子为N型离子。For example, the transistor is a P-type transistor (that is, a PMOS transistor), and the ions injected into the sidewall of the first sub-shallow trench ST1 are N-type ions.
也就是说,晶体管T的类型和注入至第一子浅沟槽ST1的侧壁的离子的类型是相反的,由于掺杂区DR处于有源区5中沟道区52的位置,这样可以使得沟道区52和掺杂区DR相接触而形成反型层,进而可以利用掺杂区DR调整晶体管T的阈值电压,降低晶体管T的漏电,改善、抑制窄沟道效应,提高晶体管T的性能。 That is to say, the type of transistor T and the type of ions injected into the sidewall of the first sub-shallow trench ST1 are opposite. Since the doping region DR is located at the position of the channel region 52 in the active region 5, this can make The channel region 52 is in contact with the doped region DR to form an inversion layer. The doped region DR can then be used to adjust the threshold voltage of the transistor T, reduce the leakage of the transistor T, improve and suppress the narrow channel effect, and improve the performance of the transistor T. .
可以理解的是,在上述S800中,所形成的晶体管T的数量为多个。该多个晶体管T的类型可以相同,例如均为N型晶体管(也即NMOS晶体管)或均为P型晶体管(也即PMOS晶体管);或者,该多个晶体管T的类型也可以不同,例如,至少一个晶体管T为N型晶体管(也即NMOS晶体管),至少一个晶体管T为P型晶体管(也即PMOS晶体管)。It can be understood that in the above S800, the number of transistors T formed is multiple. The plurality of transistors T can be of the same type, for example, they are all N-type transistors (that is, NMOS transistors) or all are P-type transistors (that is, PMOS transistors); or the types of the plurality of transistors T can also be different, for example, At least one transistor T is an N-type transistor (that is, an NMOS transistor), and at least one transistor T is a P-type transistor (that is, a PMOS transistor).
在相邻两个晶体管T的类型不同的情况下,位于该相邻两个晶体管T之间的第一子浅沟槽ST1的两个侧壁中,所注入的离子类型则不同。When two adjacent transistors T are of different types, the types of ions implanted in the two sidewalls of the first sub-shallow trench ST1 between the two adjacent transistors T are different.
可选地,在上述S600中,所形成的阱区51均为P阱,相应的,所形成的晶体管均为N型晶体管(也即NMOS晶体管)。此时,注入至第一子浅沟槽ST1的侧壁的离子均为硼离子。Optionally, in the above S600, the formed well regions 51 are all P-wells, and accordingly, the formed transistors are all N-type transistors (that is, NMOS transistors). At this time, the ions injected into the sidewall of the first sub-shallow trench ST1 are all boron ions.
示例性的,硼离子的注入能量范围包括但不局限于1Kev~100KeV,剂量范围包括但不局限于1e11/cm2~1e14/cm2For example, the implantation energy range of boron ions includes but is not limited to 1Kev~100KeV, and the dose range includes but is not limited to 1e 11 /cm 2 to 1e 14 /cm 2 .
例如,硼离子的注入能量为1Kev、15Kev、30Kev、35Kev、70Kev或100KeV等。剂量为1e11/cm2、2e11/cm2、1e12/cm2、5e12/cm2或1e14/cm2等。For example, the implantation energy of boron ions is 1Kev, 15Kev, 30Kev, 35Kev, 70Kev or 100KeV, etc. The dosage is 1e 11 /cm 2 , 2e 11 /cm 2 , 1e 12 /cm 2 , 5e 12 /cm 2 or 1e 14 /cm 2 etc.
需要说明的是,硼离子的剂量可以根据沟道的离子注入量而定,两者相互配合,以便于能够有效调整晶体管T的阈值电压,降低晶体管T的漏电,改善、抑制窄沟道效应,提高晶体管T的性能。It should be noted that the dose of boron ions can be determined according to the amount of ion implantation in the channel. The two cooperate with each other to effectively adjust the threshold voltage of the transistor T, reduce the leakage of the transistor T, and improve and suppress the narrow channel effect. Improve the performance of transistor T.
在一些实施例中,本申请提供的制备方法还包括:S900。In some embodiments, the preparation method provided by this application further includes: S900.
S900,如图17所示,在晶体管T的第一极上形成存储结构10。该存储结构10与第一极电连接。该第一极为源极S或漏极D。S900, as shown in FIG. 17, the memory structure 10 is formed on the first pole of the transistor T. The memory structure 10 is electrically connected to the first pole. The first electrode is source S or drain D.
在一些示例中,如图17所示,本申请还可以在晶体管T的第一极和存储结构10之间形成第一互联线,该第一互联线的一端与晶体管T的第一极电连接,另一端与存储结构10电连接。In some examples, as shown in FIG. 17 , the present application can also form a first interconnection line between the first pole of the transistor T and the memory structure 10 , and one end of the first interconnection line is electrically connected to the first pole of the transistor T. , the other end is electrically connected to the storage structure 10 .
在一些示例中,如图17所示,本申请还可以在存储结构10上形成第二互联线,该第二互联线的一端与存储结构10电连接,另一端与其他信号线(例如板线)电连接。In some examples, as shown in FIG. 17 , the present application can also form a second interconnection line on the storage structure 10 , one end of the second interconnection line is electrically connected to the storage structure 10 , and the other end is connected to other signal lines (such as board lines). ) electrical connection.
示例性的,如图17所示,上述存储结构10包括但不局限于第一电极层101、存储功能层102和第二电极层103。其中,存储功能层102用于存储数据。For example, as shown in FIG. 17 , the above-mentioned memory structure 10 includes but is not limited to a first electrode layer 101 , a memory function layer 102 and a second electrode layer 103 . Among them, the storage function layer 102 is used to store data.
可以理解的是,晶体管T及与其电连接的存储结构10,可以构成位单元,位单元阵列可以构成存储器。本申请通过改进形成浅沟槽ST、掺杂区DR和填充部4的方法,可以有效地利用掺杂区DR调整晶体管T的阈值电压,降低晶体管T的漏电,改善、抑制窄沟道效应,以便于可以减小晶体管T的沟道52宽度,减小晶体管T的面积,减小不同有源区5之间的间距,减小位单元的面积,进而能够设置更多的晶体管T,设置更多的位单元,实现更高密度、更高性能的应用。It can be understood that the transistor T and the memory structure 10 electrically connected thereto can constitute a bit cell, and the bit cell array can constitute a memory. By improving the method of forming the shallow trench ST, the doped region DR and the filling portion 4, this application can effectively use the doped region DR to adjust the threshold voltage of the transistor T, reduce the leakage of the transistor T, and improve and suppress the narrow channel effect. So that the width of the channel 52 of the transistor T can be reduced, the area of the transistor T can be reduced, the spacing between different active areas 5 can be reduced, and the area of the bit cell can be reduced, so that more transistors T can be provided and more transistors T can be provided. More bit cells enable higher-density, higher-performance applications.
上述存储功能层102的类型包括多种,可以根据实际需要选择设置。There are many types of the above-mentioned storage function layer 102, which can be selected and set according to actual needs.
示例性的,上述存储功能层102包括但不局限于铁电层、阻变层、相变层或磁性隧道结(MTJ)等。For example, the above-mentioned storage functional layer 102 includes but is not limited to a ferroelectric layer, a resistive layer, a phase change layer, or a magnetic tunnel junction (MTJ).
此处,在存储功能层102包括铁电层的情况下,上述存储器的类型可以为随机存取存储器(FeRAM)。在存储功能层102包括阻变层的情况下,上述存储器的类型可以为电阻式随机存取存储器(resistive random access memory,RRAM)。在存储功能 层102包括相变层的情况下,上述存储器的类型可以为相变存储器(phase change memory,PCM)。在存储功能层102包括磁性隧道结的情况下,上述存储器的类型可以为磁阻式随机存取存储器(magnetoresistive random access memory,MRAM)。Here, in the case where the storage function layer 102 includes a ferroelectric layer, the type of memory may be a random access memory (FeRAM). In the case where the storage function layer 102 includes a resistive switching layer, the type of memory may be resistive random access memory (RRAM). in storage function When the layer 102 includes a phase change layer, the type of memory may be a phase change memory (PCM). In the case where the storage function layer 102 includes a magnetic tunnel junction, the type of memory may be magnetoresistive random access memory (MRAM).
如图18~图20所示,本申请的一些实施例提供了一种半导体结构100。该半导体结构100例如可以采用上述一些实施例中提供的制备方法制备形成。As shown in Figures 18 to 20, some embodiments of the present application provide a semiconductor structure 100. The semiconductor structure 100 can be prepared and formed, for example, using the preparation methods provided in some of the above embodiments.
在一些示例中,如图18所示,半导体结构100包括衬底1和填充部4。In some examples, as shown in FIG. 18 , semiconductor structure 100 includes substrate 1 and fill 4 .
示例性的,如图18所示,衬底1的第一表面1a开设有浅沟槽ST。浅沟槽ST包括靠近衬底1的第一表面1a的第一子浅沟槽ST1,及位于第一子浅沟槽ST1下方的第二子浅沟槽ST2。第二子浅沟槽ST2相比第一子浅沟槽ST1更深入衬底1的内部。第一子浅沟槽ST1的侧壁例如垂直于衬底1所在平面,第二子浅沟槽ST2的侧壁例如与衬底1所在平面之间呈钝角设置,这样第一子浅沟槽ST1的侧壁和第二子浅沟槽ST2的侧壁之间可以呈钝角设置。For example, as shown in FIG. 18 , a shallow trench ST is formed on the first surface 1 a of the substrate 1 . The shallow trench ST includes a first sub-shallow trench ST1 close to the first surface 1a of the substrate 1, and a second sub-shallow trench ST2 located below the first sub-shallow trench ST1. The second sub-shallow trench ST2 is deeper into the interior of the substrate 1 than the first sub-shallow trench ST1. The sidewalls of the first sub-shallow trench ST1 are, for example, perpendicular to the plane where the substrate 1 is located, and the sidewalls of the second sub-shallow trench ST2 are, for example, arranged at an obtuse angle to the plane where the substrate 1 is located, so that the first sub-shallow trench ST1 The side wall of the second sub-shallow trench ST2 may be arranged at an obtuse angle.
衬底1具有掺杂区DR,该掺杂区DR中掺杂有离子。掺杂区DR位于第一子浅沟槽ST1的侧壁,并围绕第一子浅沟槽ST1的侧壁。The substrate 1 has a doping region DR, and ions are doped in the doping region DR. The doping region DR is located on the sidewall of the first sub-shallow trench ST1 and surrounds the sidewall of the first sub-shallow trench ST1.
上述填充部4位于该浅沟槽ST内。填充部4例如至少填满浅沟槽ST。The filling portion 4 is located in the shallow trench ST. The filling portion 4 fills at least the shallow trench ST, for example.
示例性的,上述填充部4呈一体结构,也即,填充部4的结构是连续的、未分隔的。在制备填充部4的过程中,填充部4是一次性形成的。For example, the above-mentioned filling part 4 has an integrated structure, that is, the structure of the filling part 4 is continuous and not divided. In the process of preparing the filling part 4, the filling part 4 is formed at once.
示例性的,相比于第二子浅沟槽ST2,第一子浅沟槽ST1和掺杂区DR在先形成。For example, compared with the second sub-shallow trench ST2, the first sub-shallow trench ST1 and the doping region DR are formed earlier.
也就是说,上述浅沟槽ST分两次形成的,一次形成第一子浅沟槽ST1,另一次形成第二子浅沟槽ST2。而且,在形成第二子浅沟槽ST2之前,先对第一子浅沟槽ST1的侧壁进行离子注入,形成掺杂区DR。在形成第二子浅沟槽ST2之后,一次性形成至少填满浅沟槽ST的填充部4。That is to say, the above-mentioned shallow trench ST is formed in two times, one time to form the first sub-shallow trench ST1, and the other time to form the second sub-shallow trench ST2. Moreover, before forming the second sub-shallow trench ST2, ion implantation is performed on the sidewall of the first sub-shallow trench ST1 to form a doped region DR. After the second sub-shallow trench ST2 is formed, the filling portion 4 that at least fills the shallow trench ST is formed at once.
本申请提供的半导体结构100,一方面可以利用掺杂区DR,调节晶体管的阈值电压,降低晶体管的漏电流,提高晶体管的性能,从而改善窄沟道效应,以便于压缩晶体管的沟道尺寸,减小位单元的面积,实现更高密度、更高性能的应用,另一方面,可以避免破坏填充部4,避免在填充部4中掺杂离子,影响填充部4的绝缘性能和可靠性。The semiconductor structure 100 provided by this application can, on the one hand, use the doping region DR to adjust the threshold voltage of the transistor, reduce the leakage current of the transistor, and improve the performance of the transistor, thereby improving the narrow channel effect and compressing the channel size of the transistor. Reduce the area of the bit cell to achieve higher density and higher performance applications. On the other hand, it can avoid damaging the filling part 4 and avoid doping ions in the filling part 4, which will affect the insulation performance and reliability of the filling part 4.
在一些实施例中,如图19所示,上述半导体结构100还包括晶体管T。该晶体管T包括有源区5、源极S、漏极D、栅介质层6和栅极9。In some embodiments, as shown in FIG. 19 , the above-mentioned semiconductor structure 100 further includes a transistor T. The transistor T includes an active region 5 , a source S, a drain D, a gate dielectric layer 6 and a gate 9 .
在一些示例中,如图19所示,有源区5从衬底1的第一表面1a延伸至衬底1的内部。有源区5还包括位于靠近衬底1的第一表面1a的沟道区52(或称沟道)。栅介质层6位于衬底1的第一表面1a上,并覆盖沟道区52。栅极9位于栅介质层6上。源极S和漏极D位于有源区5内,其中,沟道区52、栅介质层6和栅极9均位于源极S和漏极D之间。In some examples, as shown in FIG. 19 , the active region 5 extends from the first surface 1 a of the substrate 1 to the interior of the substrate 1 . The active region 5 also includes a channel region 52 (or channel) located close to the first surface 1 a of the substrate 1 . The gate dielectric layer 6 is located on the first surface 1 a of the substrate 1 and covers the channel region 52 . The gate electrode 9 is located on the gate dielectric layer 6 . The source electrode S and the drain electrode D are located in the active region 5 , wherein the channel region 52 , the gate dielectric layer 6 and the gate electrode 9 are all located between the source electrode S and the drain electrode D.
示例性的,有源区5被浅沟槽ST围绕。Exemplarily, the active area 5 is surrounded by shallow trenches ST.
由于掺杂区DR围绕浅沟槽ST中第一子浅沟槽ST1的侧壁,因此,掺杂区DR也会围绕有源区5,并与有源区5中的沟道区52相接触。掺杂区DR和沟道区52相接触的区域会形成额外的沟道注入,该额外的沟道注入会对晶体管T的沟道产生影响,能够调整、稳定晶体管T的阈值电压,降低晶体管T的漏电,改善、抑制窄沟道效应, 提高晶体管T的性能。这样有利于减小晶体管T的沟道宽度,减小晶体管T的面积,便于在衬底1中形成更多的晶体管T。Since the doped region DR surrounds the sidewall of the first sub-shallow trench ST1 in the shallow trench ST, the doped region DR also surrounds the active region 5 and is in contact with the channel region 52 in the active region 5 . The area where the doped region DR and the channel region 52 are in contact will form an additional channel injection. This additional channel injection will have an impact on the channel of the transistor T, and can adjust and stabilize the threshold voltage of the transistor T, and reduce the threshold voltage of the transistor T. leakage, improve and suppress the narrow channel effect, Improve the performance of transistor T. This is beneficial to reducing the channel width of the transistor T, reducing the area of the transistor T, and facilitating the formation of more transistors T in the substrate 1 .
在一些实施例中,如图20所示,上述半导体结构100还包括:存储结构10。该存储结构10位于第一极上,且与第一极电连接。其中,该第一极为晶体管T的源极S或漏极D。存储结构10用于存储数据,存储结构10及与其电连接的晶体管T可以称为位单元。In some embodiments, as shown in FIG. 20 , the above-mentioned semiconductor structure 100 further includes: a memory structure 10 . The memory structure 10 is located on the first pole and is electrically connected to the first pole. The first pole is the source S or the drain D of the transistor T. The storage structure 10 is used to store data, and the storage structure 10 and the transistor T electrically connected thereto may be called a bit cell.
通过在上述半导体结构100中设置存储结构10,可以使得半导体结构100构成存储器。通过将存储结构10与晶体管T电连接,可以实现对存储结构10的控制,进而实现数据的存储或读取。By arranging the memory structure 10 in the above-mentioned semiconductor structure 100, the semiconductor structure 100 can constitute a memory. By electrically connecting the storage structure 10 to the transistor T, the storage structure 10 can be controlled, thereby enabling data storage or reading.
可以理解的是,由于本申请能够改善、抑制窄沟道效应,减小晶体管T的沟道宽度,减小晶体管T的面积,进而可以减小位单元的面积,能够设置更多的晶体管T,设置更多的位单元,实现更高密度、更高性能的应用。It can be understood that since the present application can improve and suppress the narrow channel effect, reduce the channel width of the transistor T, and reduce the area of the transistor T, it can further reduce the area of the bit cell and enable more transistors T to be provided. Configure more bit cells to enable higher density, higher performance applications.
上述存储功能层102的类型包括多种,可以根据实际需要选择设置。There are many types of the above-mentioned storage function layer 102, which can be selected and set according to actual needs.
示例性的,上述存储功能层102包括但不局限于铁电层、阻变层、相变层或磁性隧道结(MTJ)等。For example, the above-mentioned storage functional layer 102 includes but is not limited to a ferroelectric layer, a resistive layer, a phase change layer, or a magnetic tunnel junction (MTJ).
此处,在存储功能层102包括铁电层的情况下,上述存储器的类型可以为随机存取存储器(FeRAM)。在存储功能层102包括阻变层的情况下,上述存储器的类型可以为电阻式随机存取存储器(resistive random access memory,RRAM)。在存储功能层102包括相变层的情况下,上述存储器的类型可以为相变存储器(phase change memory,PCM)。在存储功能层102包括磁性隧道结的情况下,上述存储器的类型可以为磁阻式随机存取存储器(magnetoresistive random access memory,MRAM)。Here, in the case where the storage function layer 102 includes a ferroelectric layer, the type of memory may be a random access memory (FeRAM). In the case where the storage function layer 102 includes a resistive switching layer, the type of memory may be resistive random access memory (RRAM). In the case where the storage function layer 102 includes a phase change layer, the type of memory may be a phase change memory (PCM). In the case where the storage function layer 102 includes a magnetic tunnel junction, the type of memory may be magnetoresistive random access memory (MRAM).
本申请的一些实施例提供了一种电子设备。该电子设备可以是手机(mobile phone)、平板电脑(pad)、电视、桌面型计算机、膝上型计算机、手持计算机、笔记本电脑、超级移动个人计算机(ultra-mobile personal computer,UMPC)、上网本,以及蜂窝电话、个人数字助理(personal digital assistant,PDA)、增强现实(augmented reality,AR)设备、虚拟现实(virtual reality,VR)设备、人工智能(artificial intelligence,AI)设备、智能穿戴设备(例如,智能手表、智能手环)、车载设备、智能家居设备和/或智慧城市设备,本申请实施例对该电子设备的具体类型不作特殊限制。Some embodiments of the present application provide an electronic device. The electronic device can be a mobile phone (mobile phone), tablet computer (pad), television, desktop computer, laptop computer, handheld computer, notebook computer, ultra-mobile personal computer (UMPC), netbook, As well as cellular phones, personal digital assistants (PDAs), augmented reality (AR) devices, virtual reality (VR) devices, artificial intelligence (AI) devices, smart wearable devices (such as , smart watches, smart bracelets), vehicle-mounted equipment, smart home equipment and/or smart city equipment. The embodiments of this application do not place special restrictions on the specific types of electronic equipment.
图21为本申请实施例示例性的提供的一种电子设备的架构示意图。如图21所示,该电子设备1000包括:存储器100、处理器200、输入设备300、输出设备400等部件。本领域技术人员可以理解到,图21中示出的电子设备的结构并不构成对该电子设备100的限定,该电子设备100可以包括比如图21所示的部件更多或更少的部件,或者可以组合如图1所示的部件中的某些部件,或者可以与如图21所示的部件布置不同。FIG. 21 is an architectural schematic diagram of an electronic device provided by an exemplary embodiment of the present application. As shown in Figure 21, the electronic device 1000 includes: a memory 100, a processor 200, an input device 300, an output device 400 and other components. Those skilled in the art can understand that the structure of the electronic device shown in Figure 21 does not constitute a limitation on the electronic device 100, and the electronic device 100 may include more or less components than those shown in Figure 21. Alternatively, some of the components shown in FIG. 1 may be combined, or may be arranged differently than those shown in FIG. 21 .
存储器100用于存储软件程序以及模块。存储器100主要包括存储程序区和存储数据区,其中,存储程序区可存储操作系统、至少一个功能所需的应用程序(比如声音播放功能、图像播放功能等)等;存储数据区可存储根据电子设备的使用所创建的数据(比如音频数据、图像数据、电话本等)等。此外,存储器100包括外存储器110和内存储器120。外存储器110和内存储器120存储的数据可以相互传输。外存储器110例如包括硬盘、U盘、软盘等。内存储器120例如包括静态随机存取存储器(static  random access memory,SRAM)、动态随机存取存储器(dynamic random access memory,DRAM)、只读存储器等。The memory 100 is used to store software programs and modules. The memory 100 mainly includes a storage program area and a storage data area, wherein the storage program area can store the operating system, at least one application program required for a function (such as a sound playback function, an image playback function, etc.), etc.; the storage data area can store an electronic program according to the electronic program. Data created by the use of the device (such as audio data, image data, phone book, etc.), etc. In addition, the memory 100 includes an external memory 110 and an internal memory 120 . Data stored in the external memory 110 and the internal memory 120 can be transferred to each other. The external memory 110 includes, for example, a hard disk, a USB disk, a floppy disk, etc. The internal memory 120 includes, for example, static random access memory (static random access memory). random access memory (SRAM), dynamic random access memory (dynamic random access memory (DRAM)), read-only memory, etc.
处理器200是上述电子设备1000的控制中心,利用各种接口和线路连接整个电子设备1000的各个部分,通过运行或执行存储在存储器100内的软件程序和/或模块,以及调用存储在存储器100内的数据,执行电子设备1000的各种功能和处理数据,从而对电子设备1000进行整体监控。可选的,处理器200可以包括一个或多个处理单元。例如,处理器200可以包括中央处理器(central processing unit,CPU)、人工智能(artificial intelligence,AI)处理器、数字信号处理器(digital signal processor,DSP)和神经网络处理器,还可以是其他特定集成电路(application specific integrated circuit,ASIC)等。图21中以处理器200为CPU为例,CPU可以包括运算器210和控制器220。运算器210获取内存储器120存储的数据,并对内存储器120存储的数据进行处理,处理后的结果通常送回内存储器120。控制器220可以控制运算器210对数据进行处理,控制器220还可以控制外存储器110和内存储器120存储数据或读取数据。The processor 200 is the control center of the above-mentioned electronic device 1000. It uses various interfaces and lines to connect various parts of the entire electronic device 1000, by running or executing software programs and/or modules stored in the memory 100, and by calling the software programs and/or modules stored in the memory 100. The electronic device 1000 performs various functions and processes data based on the data in the electronic device 1000, thereby overall monitoring the electronic device 1000. Optionally, the processor 200 may include one or more processing units. For example, the processor 200 may include a central processing unit (CPU), an artificial intelligence (artificial intelligence, AI) processor, a digital signal processor (DSP), a neural network processor, or other processors. Application specific integrated circuit (ASIC), etc. In FIG. 21 , the processor 200 is a CPU as an example. The CPU may include a calculator 210 and a controller 220 . The arithmetic unit 210 obtains the data stored in the internal memory 120 and processes the data stored in the internal memory 120. The processed result is usually sent back to the internal memory 120. The controller 220 can control the arithmetic unit 210 to process data, and the controller 220 can also control the external memory 110 and the internal memory 120 to store data or read data.
输入设备300用于接收输入的数字或字符信息,以及产生与电子设备1000的用户设置以及功能控制有关的键信号输入。示例的,输入设备300可以包括触摸屏以及其他输入设备。触摸屏,也称为触摸面板,可收集用户在触摸屏上或附近的触摸操作(比如用户使用手指、触笔等任何适合的物体或附件在触摸屏上或在触摸屏附近的操作),并根据预先设定的程式驱动相应的连接装置。可选的,触摸屏可包括触摸检测装置和触摸控制器两个部分。其中,触摸检测装置检测用户的触摸方位,并检测触摸操作带来的信号,将信号传送给触摸控制器;触摸控制器从触摸检测装置上接收触摸信息,并将它转换成触点坐标,再送给处理器200,并能接收处理器200发来的命令并加以执行。此外,可以采用电阻式、电容式、红外线以及表面声波等多种类型实现触摸屏。其他输入设备可以包括但不限于物理键盘、功能键(比如音量控制按键、电源开关按键等)、轨迹球、鼠标、操作杆等中的一种或多种。上述处理器200中的控制器220还可以控制输入设备300接收输入的信号或不接收输入的信号。此外,输入设备300接收到的输入的数字或字符信息,以及产生与电子设备的用户设置以及功能控制有关的键信号输入可以存储在内存储器120中。The input device 300 is used to receive input numeric or character information and generate key signal input related to user settings and function control of the electronic device 1000 . By way of example, the input device 300 may include a touch screen and other input devices. The touch screen, also known as the touch panel, can collect the user's touch operations on or near the touch screen (such as the user's operations on or near the touch screen using fingers, stylus, or any suitable objects or accessories), and perform operations based on preset settings. The program drives the corresponding connection device. Optionally, the touch screen may include two parts: a touch detection device and a touch controller. Among them, the touch detection device detects the user's touch orientation, detects the signal brought by the touch operation, and transmits the signal to the touch controller; the touch controller receives the touch information from the touch detection device, converts it into contact point coordinates, and then sends it to the touch controller. to the processor 200, and can receive commands sent by the processor 200 and execute them. In addition, touch screens can be implemented in various types such as resistive, capacitive, infrared, and surface acoustic wave. Other input devices may include, but are not limited to, one or more of physical keyboards, function keys (such as volume control keys, power switch keys, etc.), trackballs, mice, joysticks, etc. The controller 220 in the above-mentioned processor 200 can also control the input device 300 to receive the input signal or not to receive the input signal. In addition, the input numeric or character information received by the input device 300 and the key signal input generated related to user settings and function control of the electronic device may be stored in the internal memory 120 .
输出设备400用于输出输入设备300输入,并存储在内存储器120中的数据对应的信号。例如,输出设备400输出声音信号或视频信号。上述处理器200中的控制器220还可以控制输出设备400输出信号或不输出信号。The output device 400 is used to output signals corresponding to data input by the input device 300 and stored in the internal memory 120 . For example, the output device 400 outputs a sound signal or a video signal. The controller 220 in the above-mentioned processor 200 can also control the output device 400 to output a signal or not to output a signal.
需要说明的是,图21中的粗箭头用于表示数据的传输,粗箭头的方向表示数据传输的方向。例如,输入设备300和内存储器120之间的单向箭头表示输入设备300接收到的数据向内存储器120传输。又例如,运算器210和内存储器120之间的双向箭头表示内存储器120存储的数据可以向运算器210传输,且运算器210处理后的数据可以向内存储器120传输。图21中的细箭头表示控制器220可以控制的部件。示例的,控制器220可以对外存储器110、内存储器120、运算器210、输入设备300和输出设备400等进行控制。It should be noted that the thick arrows in Figure 21 are used to indicate data transmission, and the direction of the thick arrow indicates the direction of data transmission. For example, a one-way arrow between the input device 300 and the internal memory 120 indicates that data received by the input device 300 is transmitted to the internal memory 120 . For another example, the bidirectional arrow between the operator 210 and the internal memory 120 indicates that the data stored in the internal memory 120 can be transferred to the operator 210 , and the data processed by the operator 210 can be transferred to the internal memory 120 . The thin arrows in Figure 21 indicate components that controller 220 can control. For example, the controller 220 can control the external memory 110, the internal memory 120, the operator 210, the input device 300, the output device 400, etc.
可选的,如图21所示的电子设备1000还可以包括各种传感器。例如陀螺仪传感器、湿度计传感器、红外线传感器、磁力计传感器等,在此不再赘述。可选的,该电 子设备1000还可以包括无线保真(wireless fidelity,WiFi)模块、蓝牙模块等,在此不再赘述。Optionally, the electronic device 1000 shown in FIG. 21 may also include various sensors. For example, gyroscope sensor, hygrometer sensor, infrared sensor, magnetometer sensor, etc., which will not be described in detail here. Optionally, the power The sub-device 1000 may also include a wireless fidelity (WiFi) module, a Bluetooth module, etc., which will not be described again here.
可以理解的是,本申请实施例提供的半导体结构可以作为上述电子设备1000中的存储器100。例如,本申请实施例提供的半导体结构可以作为上述存储器100中的外存储器110,也可以作为上述存储器100中的内存储器120。另外,本申请提供的半导体结构可以用于独立存储芯片颗粒中。It can be understood that the semiconductor structure provided by the embodiment of the present application can be used as the memory 100 in the above-mentioned electronic device 1000. For example, the semiconductor structure provided by the embodiment of the present application can be used as the external memory 110 in the above-mentioned memory 100, or can be used as the internal memory 120 in the above-mentioned memory 100. In addition, the semiconductor structure provided by this application can be used in independent memory chip particles.
以上所述,仅为本申请的具体实施方式,但本申请的保护范围并不局限于此,任何熟悉本技术领域的技术人员在本公开揭露的技术范围内,想到变化或替换,都应涵盖在本申请的保护范围之内。因此,本申请的保护范围应以所述权利要求的保护范围为准。 The above are only specific embodiments of the present application, but the protection scope of the present application is not limited thereto. Any changes or substitutions that come to mind within the technical scope disclosed by the present disclosure by any person familiar with the technical field should be covered. within the protection scope of this application. Therefore, the protection scope of this application should be subject to the protection scope of the claims.

Claims (18)

  1. 一种半导体结构的制备方法,其特征在于,所述制备方法包括:A method for preparing a semiconductor structure, characterized in that the preparation method includes:
    提供衬底,所述衬底具有预设浅沟槽区;providing a substrate having a preset shallow trench area;
    刻蚀所述衬底中位于所述预设浅沟槽区的部分,形成第一子浅沟槽;Etching the portion of the substrate located in the preset shallow trench area to form a first sub-shallow trench;
    对所述第一子浅沟槽的侧壁进行离子注入,以在所述衬底中形成掺杂区;Perform ion implantation on the sidewall of the first sub-shallow trench to form a doped region in the substrate;
    刻蚀所述第一子浅沟槽的底壁,在所述第一子浅沟槽的下方形成第二子浅沟槽,得到包括所述第一子浅沟槽和所述第二子浅沟槽的浅沟槽;Etch the bottom wall of the first sub-shallow trench and form a second sub-shallow trench below the first sub-shallow trench to obtain the first sub-shallow trench and the second sub-shallow trench. Shallow trenches of trenches;
    在所述浅沟槽内形成填充部。A filling portion is formed in the shallow trench.
  2. 根据权利要求1所述的制备方法,其特征在于,所述刻蚀所述衬底中位于所述预设浅沟槽区的部分,包括:The preparation method according to claim 1, wherein etching the portion of the substrate located in the preset shallow trench region includes:
    在所述衬底上依次形成衬垫层、硬掩模层和光刻胶层;sequentially forming a liner layer, a hard mask layer and a photoresist layer on the substrate;
    刻蚀所述光刻胶层中位于所述预设浅沟槽区的部分,在所述光刻胶层中形成第一开口;Etching the portion of the photoresist layer located in the preset shallow trench area to form a first opening in the photoresist layer;
    通过所述第一开口,刻蚀所述硬掩模层、所述衬垫层和所述衬底中位于所述预设浅沟槽区的部分,在所述硬掩模层和所述衬垫层中形成第二开口,并在所述衬底中形成所述第一子浅沟槽。Through the first opening, the hard mask layer, the liner layer and the portion of the substrate located in the preset shallow trench area are etched. A second opening is formed in the pad layer, and the first sub-shallow trench is formed in the substrate.
  3. 根据权利要求2所述的制备方法,其特征在于,所述对所述第一子浅沟槽的侧壁进行离子注入,包括:The preparation method according to claim 2, wherein the ion implantation into the sidewall of the first sub-shallow trench includes:
    去除所述光刻胶层;Remove the photoresist layer;
    以所述硬掩模层和所述衬垫层为掩模,通过所述第二开口,对所述第一子浅沟槽的侧壁进行离子注入;所述离子注入的方向与垂直于所述衬底的方向之间具有夹角。Using the hard mask layer and the liner layer as masks, ion implantation is performed on the sidewall of the first sub-shallow trench through the second opening; the direction of the ion implantation is perpendicular to the There is an angle between the directions of the substrates.
  4. 根据权利要求3所述的制备方法,其特征在于,所述离子注入的方向与垂直于所述衬底的方向之间的夹角的范围为5°~45°。The preparation method according to claim 3, characterized in that the angle between the direction of the ion implantation and the direction perpendicular to the substrate ranges from 5° to 45°.
  5. 根据权利要求2所述的制备方法,其特征在于,所述在所述浅沟槽内形成填充部,包括:The preparation method according to claim 2, wherein forming a filling portion in the shallow trench includes:
    在所述硬掩模层上形成填充薄膜,所述填充薄膜的一部分位于所述浅沟槽;forming a filling film on the hard mask layer, with a portion of the filling film located in the shallow trench;
    去除所述填充薄膜覆盖所述硬掩模层的部分及所述硬掩模层,保留填充薄膜的位于所述浅沟槽的部分,形成所述填充部。The part of the filling film covering the hard mask layer and the hard mask layer is removed, and the part of the filling film located in the shallow trench is retained to form the filling part.
  6. 根据权利要求5所述的制备方法,其特征在于,所述制备方法还包括:The preparation method according to claim 5, characterized in that the preparation method further includes:
    对所述掺杂区进行退火处理。The doped region is annealed.
  7. 根据权利要求6所述的制备方法,其特征在于,所述制备方法还包括:The preparation method according to claim 6, characterized in that the preparation method further includes:
    对所述填充薄膜进行退火处理;annealing the filled film;
    其中,在对所述填充薄膜进行退火处理的过程中,还对所述掺杂区进行退火处理。In the process of annealing the filling film, the doped region is also annealed.
  8. 根据权利要求2所述的制备方法,其特征在于,所述制备方法还包括:The preparation method according to claim 2, characterized in that the preparation method further includes:
    对所述衬底的被所述浅沟槽围绕的部分进行离子注入,形成有源区;Perform ion implantation on the portion of the substrate surrounded by the shallow trench to form an active region;
    在所述有源区上形成栅介质层和栅极;forming a gate dielectric layer and a gate electrode on the active area;
    在所述有源区中未被所述栅介质层和栅极覆盖的部分进行离子注入,形成晶体管的源极和漏极。Ions are implanted into the portion of the active area that is not covered by the gate dielectric layer and the gate electrode to form the source and drain of the transistor.
  9. 根据权利要求8所述的制备方法,其特征在于,所述对所述衬底的被所述浅沟 槽围绕的部分进行离子注入,包括:The preparation method according to claim 8, characterized in that the pair of substrates is covered by the shallow trench. The part surrounding the groove is ion implanted, including:
    去除所述光刻胶层和所述硬掩模层;Remove the photoresist layer and the hard mask layer;
    以所述衬垫层为保护层,透过所述衬垫层对所述衬底的被所述浅沟槽围绕的部分进行离子注入。Using the liner layer as a protective layer, ions are implanted through the liner layer into the portion of the substrate surrounded by the shallow trench.
  10. 根据权利要求9所述的制备方法,其特征在于,所述在所述有源区上依次形成栅介质层和栅极之前,所述制备方法还包括:The preparation method according to claim 9, characterized in that, before sequentially forming a gate dielectric layer and a gate electrode on the active region, the preparation method further includes:
    去除所述衬垫层。Remove the backing layer.
  11. 根据权利要求8所述的制备方法,其特征在于,所述晶体管为N型晶体管,注入至所述第一子浅沟槽的侧壁的离子为P型离子;或者,The preparation method according to claim 8, wherein the transistor is an N-type transistor, and the ions injected into the sidewall of the first sub-shallow trench are P-type ions; or,
    所述晶体管为P型晶体管,注入至所述第一子浅沟槽的侧壁的离子为N型离子。The transistor is a P-type transistor, and the ions injected into the sidewall of the first sub-shallow trench are N-type ions.
  12. 根据权利要求11所述的制备方法,其特征在于,所述晶体管为N型晶体管,注入至所述第一子浅沟槽的侧壁的离子为硼离子。The preparation method according to claim 11, wherein the transistor is an N-type transistor, and the ions injected into the sidewall of the first sub-shallow trench are boron ions.
  13. 根据权利要求8所述的制备方法,其特征在于,所述制备方法还包括:The preparation method according to claim 8, characterized in that the preparation method further includes:
    在第一极上形成存储结构,所述存储结构与所述第一极电连接;所述第一极为所述源极或所述漏极。A storage structure is formed on the first electrode, and the storage structure is electrically connected to the first electrode; the first electrode is the source electrode or the drain electrode.
  14. 根据权利要求1~13中任一项所述的制备方法,其特征在于,所述第一子浅沟槽的深度范围为 The preparation method according to any one of claims 1 to 13, characterized in that the depth range of the first sub-shallow trench is
  15. 一种半导体结构,其特征在于,所述半导体结构包括:A semiconductor structure, characterized in that the semiconductor structure includes:
    衬底,具有掺杂区;所述衬底的第一表面开设有浅沟槽;A substrate has a doped region; a shallow trench is provided on the first surface of the substrate;
    填充部,位于所述浅沟槽内,且呈一体结构;The filling part is located in the shallow groove and has an integrated structure;
    其中,所述浅沟槽包括靠近所述衬底的第一表面的第一子浅沟槽,及位于所述第一子浅沟槽下方的第二子浅沟槽,所述掺杂区位于所述第一子浅沟槽的侧壁;相比于所述第二子浅沟槽,所述第一子浅沟槽和所述掺杂区在先形成。Wherein, the shallow trench includes a first sub-shallow trench close to the first surface of the substrate, and a second sub-shallow trench located below the first sub-shallow trench, and the doped region is located at The sidewalls of the first sub-shallow trench; compared to the second sub-shallow trench, the first sub-shallow trench and the doped region are formed earlier.
  16. 根据权利要求15所述的半导体结构,其特征在于,所述半导体结构还包括:The semiconductor structure according to claim 15, characterized in that the semiconductor structure further includes:
    有源区,从所述衬底的第一表面延伸至所述衬底内部;所述有源区被所述浅沟槽围绕;An active area extends from the first surface of the substrate to the interior of the substrate; the active area is surrounded by the shallow trench;
    源极和漏极,位于所述有源区内;Source and drain electrodes located in the active area;
    栅介质层,位于所述衬底的第一表面上,且位于所述源极和所述漏极之间;A gate dielectric layer located on the first surface of the substrate and between the source electrode and the drain electrode;
    栅极,位于所述栅介质层上。A gate electrode is located on the gate dielectric layer.
  17. 根据权利要求16所述的半导体结构,其特征在于,所述半导体结构还包括:存储结构;The semiconductor structure according to claim 16, wherein the semiconductor structure further comprises: a memory structure;
    所述存储结构位于第一极上,且与所述第一极电连接;所述第一极为所述源极或所述漏极。The memory structure is located on the first pole and is electrically connected to the first pole; the first pole is the source electrode or the drain electrode.
  18. 一种电子设备,其特征在于,所述电子设备包括如权利要求15~17中任一项所述的半导体结构。 An electronic device, characterized in that the electronic device includes the semiconductor structure according to any one of claims 15 to 17.
PCT/CN2023/079419 2022-04-28 2023-03-02 Semiconductor structure and preparation method therefor, and electronic device WO2023207328A1 (en)

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CN104576501A (en) * 2013-10-16 2015-04-29 中芯国际集成电路制造(上海)有限公司 Semiconductor device and manufacturing method thereof
CN106298630A (en) * 2015-06-01 2017-01-04 中芯国际集成电路制造(上海)有限公司 Fleet plough groove isolation structure and forming method thereof

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Publication number Priority date Publication date Assignee Title
CN101295663A (en) * 2007-04-28 2008-10-29 中芯国际集成电路制造(上海)有限公司 Shallow trench isolation production method for small size device
CN103456673A (en) * 2012-05-29 2013-12-18 中芯国际集成电路制造(上海)有限公司 STI (shallow trench isolation) preparation method and CMOS (complementary metal oxide semiconductor) manufacturing method
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