WO2023182364A1 - Methods for cooling down and warming up liquefied gas storage tank - Google Patents
Methods for cooling down and warming up liquefied gas storage tank Download PDFInfo
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- WO2023182364A1 WO2023182364A1 PCT/JP2023/011260 JP2023011260W WO2023182364A1 WO 2023182364 A1 WO2023182364 A1 WO 2023182364A1 JP 2023011260 W JP2023011260 W JP 2023011260W WO 2023182364 A1 WO2023182364 A1 WO 2023182364A1
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- Prior art keywords
- tank
- temperature
- inner tank
- space
- gas
- Prior art date
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- 238000000034 method Methods 0.000 title claims abstract description 58
- 238000001816 cooling Methods 0.000 title claims abstract description 52
- 238000003860 storage Methods 0.000 title claims description 55
- 238000010792 warming Methods 0.000 title description 7
- 239000007789 gas Substances 0.000 claims description 84
- 238000010438 heat treatment Methods 0.000 claims description 25
- 239000000112 cooling gas Substances 0.000 claims description 12
- 238000007599 discharging Methods 0.000 claims description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 57
- 239000001257 hydrogen Substances 0.000 description 31
- 229910052739 hydrogen Inorganic materials 0.000 description 31
- 238000004891 communication Methods 0.000 description 19
- 238000001514 detection method Methods 0.000 description 7
- 239000000470 constituent Substances 0.000 description 6
- 230000008602 contraction Effects 0.000 description 6
- 238000010586 diagram Methods 0.000 description 6
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 238000009529 body temperature measurement Methods 0.000 description 4
- 238000009413 insulation Methods 0.000 description 4
- 238000012545 processing Methods 0.000 description 4
- 238000005507 spraying Methods 0.000 description 4
- 238000010276 construction Methods 0.000 description 3
- 230000007423 decrease Effects 0.000 description 3
- 238000012423 maintenance Methods 0.000 description 3
- 238000009826 distribution Methods 0.000 description 2
- 239000003949 liquefied natural gas Substances 0.000 description 2
- 239000003915 liquefied petroleum gas Substances 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 238000007792 addition Methods 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
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- 230000037430 deletion Effects 0.000 description 1
- 238000006073 displacement reaction Methods 0.000 description 1
- 238000007710 freezing Methods 0.000 description 1
- 230000008014 freezing Effects 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 230000006870 function Effects 0.000 description 1
- 239000001307 helium Substances 0.000 description 1
- 229910052734 helium Inorganic materials 0.000 description 1
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
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- 238000002360 preparation method Methods 0.000 description 1
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- 230000032258 transport Effects 0.000 description 1
- 239000006200 vaporizer Substances 0.000 description 1
Images
Classifications
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C3/00—Vessels not under pressure
- F17C3/02—Vessels not under pressure with provision for thermal insulation
- F17C3/10—Vessels not under pressure with provision for thermal insulation by liquid-circulating or vapour-circulating jackets
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C13/00—Details of vessels or of the filling or discharging of vessels
- F17C13/001—Thermal insulation specially adapted for cryogenic vessels
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C13/00—Details of vessels or of the filling or discharging of vessels
- F17C13/02—Special adaptations of indicating, measuring, or monitoring equipment
- F17C13/026—Special adaptations of indicating, measuring, or monitoring equipment having the temperature as the parameter
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C3/00—Vessels not under pressure
- F17C3/02—Vessels not under pressure with provision for thermal insulation
- F17C3/022—Land-based bulk storage containers
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C3/00—Vessels not under pressure
- F17C3/02—Vessels not under pressure with provision for thermal insulation
- F17C3/025—Bulk storage in barges or on ships
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C5/00—Methods or apparatus for filling containers with liquefied, solidified, or compressed gases under pressures
- F17C5/02—Methods or apparatus for filling containers with liquefied, solidified, or compressed gases under pressures for filling with liquefied gases
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C6/00—Methods and apparatus for filling vessels not under pressure with liquefied or solidified gases
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2201/00—Vessel construction, in particular geometry, arrangement or size
- F17C2201/05—Size
- F17C2201/052—Size large (>1000 m3)
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2203/00—Vessel construction, in particular walls or details thereof
- F17C2203/03—Thermal insulations
- F17C2203/0362—Thermal insulations by liquid means
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2203/00—Vessel construction, in particular walls or details thereof
- F17C2203/06—Materials for walls or layers thereof; Properties or structures of walls or their materials
- F17C2203/0602—Wall structures; Special features thereof
- F17C2203/0612—Wall structures
- F17C2203/0626—Multiple walls
- F17C2203/0629—Two walls
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2205/00—Vessel construction, in particular mounting arrangements, attachments or identifications means
- F17C2205/03—Fluid connections, filters, valves, closure means or other attachments
- F17C2205/0302—Fittings, valves, filters, or components in connection with the gas storage device
- F17C2205/0323—Valves
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2250/00—Accessories; Control means; Indicating, measuring or monitoring of parameters
- F17C2250/03—Control means
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2250/00—Accessories; Control means; Indicating, measuring or monitoring of parameters
- F17C2250/04—Indicating or measuring of parameters as input values
- F17C2250/0486—Indicating or measuring characterised by the location
- F17C2250/0491—Parameters measured at or inside the vessel
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2270/00—Applications
- F17C2270/01—Applications for fluid transport or storage
- F17C2270/0102—Applications for fluid transport or storage on or in the water
- F17C2270/0105—Ships
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2270/00—Applications
- F17C2270/01—Applications for fluid transport or storage
- F17C2270/0134—Applications for fluid transport or storage placed above the ground
Definitions
- the present disclosure relates to a method for cooling down and warming up a liquefied gas storage tank.
- the tank when storing low-temperature liquefied gas in a tank, in order to avoid rapid cooling of the tank by filling a room-temperature tank with a large amount of liquefied gas to be stored at once, the tank is cooled at a relatively low speed (hereinafter referred to as “cool down”). Furthermore, when it is necessary to empty the tank for maintenance or the like, the tank is heated (hereinafter referred to as "warm-up") after the liquefied gas to be stored is discharged.
- an object of the present disclosure is to shorten the time and reduce costs while suppressing the generation of stress during cool-down and warm-up of a multi-layered heat-insulated structure tank for storing liquefied gas. .
- a method for cooling down a liquefied gas storage tank includes: A method for cooling a tank including an inner tank and an outer tank for storing liquefied gas before filling it with the liquefied gas to be stored, the method comprising: Introducing a cooling liquefied gas into the inner tank space; Measuring the temperature of the inner tank and the temperature of the outer tank, respectively; Based on the temperature difference between the temperature of the inner tank and the temperature of the outer tank, the temperature difference is maintained at a predetermined value or less by adjusting at least one of the temperature change rate of the inner tank and the temperature change rate of the outer tank. to do and including.
- a method for warming up a liquefied gas storage tank includes: A method for heating a tank for storing liquefied gas, including an inner tank and an outer tank, after discharging the liquefied gas to be stored, the method comprising: Introducing a first heating gas into the inner tank space; Forcibly supplying a second heating gas to the space between the inner and outer tanks; Measuring the temperature of the inner tank and the temperature of the outer tank, respectively; Based on the temperature difference between the temperature of the inner tank and the temperature of the outer tank, the temperature difference is maintained at a predetermined value or less by adjusting at least one of the temperature change rate of the inner tank and the temperature change rate of the outer tank. to do and including.
- the time and cost can be reduced while suppressing the generation of stress during the cool-down and warm-up of a multi-layered heat-insulated structure tank for storing liquefied gas. Can be suppressed.
- FIG. 1 is a cross-sectional view showing a schematic configuration of a liquefied gas storage tank to which a cool-down method according to an embodiment of the present disclosure is applied.
- FIG. 2 is a schematic diagram showing an initial state before the start of a cool-down method according to an embodiment of the present disclosure.
- FIG. 3 is a schematic diagram showing a state during cooling of the inner tank in a cool-down method according to an embodiment of the present disclosure.
- FIG. 2 is a schematic diagram showing a state in which temperature difference adjustment is performed in a cool-down method according to an embodiment of the present disclosure.
- FIG. 2 is a schematic diagram showing a state in which a cool-down method according to an embodiment of the present disclosure has been completed.
- FIG. 2 is a schematic diagram showing a state at the start of a warm-up method according to an embodiment of the present disclosure.
- FIG. 3 is a schematic diagram showing a state in which temperature difference adjustment is performed in a warm-up method according to an embodiment of the present disclosure.
- FIG. 1 shows a liquefied gas storage tank (hereinafter simply referred to as “storage tank”) 1 to which a cool-down method and a warm-up method according to an embodiment of the present disclosure are applied.
- This storage tank 1 is a tank for storing liquefied gas, and is configured as a double shell tank including an inner tank 3 and an outer tank 5.
- cool down means cooling the storage tank 1 before filling the storage tank 1 with the liquefied gas to be stored.
- warming up means heating the low-temperature storage tank 1 in preparation for subsequent maintenance and the like after the liquefied gas to be stored is discharged.
- liquefied hydrogen at an extremely low temperature (approximately -250° C.) will be explained as an example of the liquefied gas to be stored.
- liquefied gas can also include other types of gas, such as liquefied petroleum gas (LPG, approximately -45°C), liquefied ethylene gas (LEG, approximately -100°C), liquefied natural gas (LNG, approximately -160°C), It may be helium (LHe, about ⁇ 270° C.) or the like.
- the storage tank 1 is installed, for example, on a ship such as a liquefied hydrogen carrier.
- the liquefied hydrogen storage facility in which the storage tank 1 is installed is not limited to this example as long as it has a structure and function capable of storing liquefied hydrogen.
- the liquefied hydrogen storage facility in which the storage tank 1 is installed may be, for example, a ship that uses liquefied hydrogen as a propulsion fuel, a land-based liquefied hydrogen storage facility other than a ship, or a plant that uses liquefied hydrogen. It's fine.
- the storage tank 1 is configured as a double shell tank having an inner tank 3 and an outer tank 5.
- the inner tank 3 has an inner tank shell that forms a storage space (hereinafter referred to as "inner tank interior space 7") for liquefied hydrogen to be stored, and an outer circumferential surface of the inner tank shell. It has an inner tank heat insulation layer that covers the inner tank.
- the outer tank 5 has an outer tank shell that forms an inter-inner/outer tank space 9 that is a heat insulating layer between it and the inner tank 3, and an outer tank heat insulating layer that covers the outer peripheral surface of the outer tank shell. Note that the locations where the heat insulating layers of the inner tank 3 and the outer tank 5 are installed are not limited to this example, but are arbitrary.
- the heat insulating layers may be installed so as to cover the inner circumferential surface of the outer tank shell.
- one or both of the heat-insulating layers of the inner tank 3 and the outer tank 5 may be omitted.
- This storage tank 1 is normally operated with low-temperature hydrogen gas sealed in the space 9 between the inner and outer tanks, which is a heat insulating layer.
- a communication passage 11 is provided that communicates the inner tank interior space 7 and the outer and outer tank space 9.
- the communication path 11 is configured to be openable and closable.
- a vaporized gas discharge passage 13 that discharges vaporized gas of liquefied hydrogen (hereinafter simply referred to as “vaporized gas”) G1 generated in the inner tank space 7 to the outside of the storage tank 1 and a hydrogen gas introduction passage 15 that introduces hydrogen gas (hereinafter referred to as "external hydrogen gas”) G2 from a hydrogen gas source (not shown) provided outside the storage tank 1 into the space 9 between the inner and outer tanks.
- a connecting passage 17 connecting the vaporized gas discharge passage 13 and the hydrogen gas introduction passage 15 is provided outside the storage tank 1.
- a communication passage 11 is formed by the vaporized gas discharge passage 13, the connection passage 17, and the hydrogen gas introduction passage 15. Further, an on-off valve 19 is provided in the communication passage 11, and the communication passage 11 is configured to be openable and closable by this on-off valve 19.
- the on-off valve 19 is provided in a portion of the hydrogen gas introduction passage 15 downstream of the connection point with the connection passage 17, but the position and number of the on-off valves 19 are not limited to this example.
- the on-off valve 19 may be a valve that can be opened and closed manually, or may be a valve that is automatically opened and closed according to a set differential pressure.
- the specific configuration of the communication path 11 between the inner tank interior space 7 and the outer and outer tank space 9 and the specific configuration that allows the communication path 11 to be opened and closed are not limited to this example.
- the above-mentioned "hydrogen gas source” may have any configuration as long as it can serve as a supply source of hydrogen gas, and is typically a tank that stores hydrogen gas, but for example, it may be a tank that stores liquefied hydrogen. It may also be a combination of a tank and a vaporizer.
- a device that forcibly feeds cooling gas, which will be described later, to the space 9 between the inner and outer tanks is provided in the communication path 11, such as a compressor or a blower.
- the gas supply device 31 is a device that moves gas by applying pressure to the gas, such as a turbo or positive displacement compressor, blower, or fan.
- a gas supply device 31 is provided in the connection passage 17 .
- a cooling device 33 is provided on the communication path 11, for example, on the hydrogen gas introduction path 15.
- the cooling device 33 includes, for example, a temperature sensor that detects gas temperature, a cooling source such as a compression refrigerator or an absorption refrigerator, a control circuit that controls these, and the like.
- the cooling device 35 may be a device having a configuration other than the above, for example, a heat exchanger.
- the gas supply device 31 and the cooling device 33 that are necessary may be provided depending on the embodiment of the cool-down method and warm-up method described later.
- an inner tank temperature detection device 21 that detects the temperature of the inner tank 3
- an inner tank space pressure detection device 23 that monitors the pressure of the inner tank space 7
- a temperature detection device 23 that detects the temperature of the space 9 between the inner and outer tanks.
- the inner and outer tank space temperature detection device 25 detects the pressure in the inner and outer tank space 9
- the inner and outer tank space pressure sensor 27 detects the pressure in the inner and outer tank space 9.
- the device is equipped with a memory for storing the data, a power source circuit such as a power supply element such as a battery or a power supply circuit for receiving power supply from the outside, a transmission circuit for transmitting the output signal to the outside by wire or wirelessly, and the like.
- a temperature sensing device and a pressure sensing device a device that measures parts other than those described above, such as an inner tank temperature sensing device or an outer tank temperature sensing device, may be provided.
- only the necessary temperature sensing devices and pressure sensing devices may be provided depending on the embodiment of the cool-down method and warm-up method described later.
- hydrogen gas exists at room temperature and atmospheric pressure (0 kPaG), for example.
- the temperature and pressure of the hydrogen gas in the initial state are not limited to room temperature and atmospheric pressure.
- hydrogen for cooling liquefied hydrogen for cooling
- FIG. 2B cooling hydrogen CH is sprayed into the inner tank space 7 using the sprayer 29 .
- the temperature of the inner tank 3 is reduced.
- the temperature of the space 9 between the inner and outer tanks also decreases.
- vaporized gas G1 in which the cooling hydrogen CH is vaporized is generated, and the pressure increases, while in the inner tank space 9, the pressure decreases due to the temperature drop. Since the communication passage 11 is opened as described above, the vaporized gas G1 generated in the inner tank inner space 7 flows into the inner and outer tank space 9 via the communication passage 11 due to the pressure difference between both spaces 7 and 9. do.
- a pressure difference adjustment device is used to adjust the pressure difference between the two spaces. may be adjusted so that it falls within a predetermined range. For example, if the pressure in the space 9 between the inner and outer tanks is excessively low, the hydrogen gas supply device 31 may be used to supply the vaporized gas G1 in the inner tank space 7 to the space 9 between the inner and outer tanks. In place of or in addition to the forced supply of the vaporized gas G1, external hydrogen gas G2 may be supplied from the hydrogen gas introduction passage 15 to the space 9 between the inner and outer tanks. In the following description, the gas that is forcibly supplied to cool the space 9 between the inner and outer tanks in this manner will be collectively referred to as "cooling gas CG.”
- a discharge passage (not shown) is provided to discharge the cooling gas CG from the space 9 between the inner and outer tanks. It may also be possible to prevent the pressure in the space 9 from increasing excessively.
- the communication passage 11 is opened from the start of cool-down, that is, from the start of spraying of the cooling hydrogen CH, but the timing of opening the communication passage 11 is not limited to this. That is, spraying of the cooling hydrogen CH is started with the communication passage 11 closed, and if necessary, such as when the pressure in the space 9 between the inner and outer tanks falls below a predetermined value, the communication passage 11 is opened to spray the vaporized gas G1. may be supplied.
- the temperature difference between the inner tank 3 and the outer tank 5 becomes too large, and the difference in the amount of thermal contraction of the constituent members becomes too large, which may generate large stress.
- the temperature of the inner tank 3 and the temperature of the outer tank 5 are measured respectively, and the temperature difference between the temperature of the inner tank 3 and the temperature of the outer tank 5 (hereinafter simply referred to as "temperature The temperature difference is maintained at a predetermined value or less by adjusting at least one of the temperature change rate of the inner tank 3 and the outer tank 5 based on the temperature change rate of the inner tank 3 and the outer tank 5.
- temperature of inner tank 3 and “temperature of outer tank 5" refer to the temperature of the inner space in contact with each tank, that is, the temperature of inner tank inner space 7 for inner tank 3, and the temperature of inner tank inner space 7 for outer tank 5. includes the temperature of the space 9 between the inner and outer tanks.
- the "predetermined value" of the temperature difference here is set, for example, based on the temperature difference at the start of normal operation of the storage tank 1, and is, for example, a value larger than the temperature difference at the start of normal operation, for example, about 150K. It is. However, the "predetermined value” is not limited to this value.
- the rate of introduction of cooling hydrogen CH into the inner tank 3 is adjusted. Specifically, the cooling rate of the inner tank 3 is reduced by reducing the introduction speed of cooling hydrogen CH into the inner tank 3. Note that "reducing the introduction speed” herein includes stopping the introduction.
- the supply rate of the cooling gas CG to the space 9 between the inner and outer tanks is adjusted. Specifically, the temperature of the vaporized gas G1 and/or the external hydrogen gas G2 to the space 9 between the inner and outer tanks is lowered by the cooling device 33, and the supply rate of the cooling gas CG is increased by using the gas feeding device 31.
- FIG. 2C shows a state in which spraying of the cooling hydrogen CH to the inner tank 3 is stopped and the supply rate of the cooling gas CG to the space 9 between the inner and outer tanks is increased.
- the adjustment of the introduction speed of the cooling hydrogen CH into the inner tank 3 is not limited to the above example, and includes, for example, increasing the introduction speed when the inner tank 3 is insufficiently cooled.
- the adjustment of the supply rate of the cooling gas CG to the space 9 between the inner and outer tanks is not limited to the above example, and includes, for example, reducing the supply rate when the outer tank 5 is cooled too much.
- the method of adjusting at least one of the temperature change rate of the inner tank 3 and the temperature change rate of the outer tank 5 is not limited to the example described above. For example, hydrogen gas having a higher temperature than the inner tank temperature may be supplied to the inner tank space 7.
- the respective temperatures are measured at, for example, a predetermined location where the representative temperature of the inner tank 3 can be detected, and the outer tank 5. Select a predetermined location where the representative temperature can be detected.
- the term "representative temperature” as used herein means a temperature that is considered to most appropriately represent the temperature of each of the inner tank 3 and outer tank 5 in view of the overall temperature distribution of each of the inner tank 3 and outer tank 5.
- An example of the "representative temperature” is the average value of the overall temperature distribution of each of the inner tank 3 and the outer tank 5.
- connection points with other members that perform temperature measurement include connection points with the skirt, which is a cylindrical support member that supports the storage tank 1 relative to the hull, and the center of the storage tank 1.
- connection point with a pipe-shaped tower that protrudes vertically from the top By measuring the temperature of the connection points with other members and adjusting the temperature difference, the state of connection between the inner tank 3, outer tank 5 and other members can be effectively maintained.
- An example is the space 9 between the inner and outer tanks. According to this configuration, the temperature measurement location used for steady operation of the storage tank 1 can be used, so there is no need to add a measurement device or the like.
- the combination of locations at which temperatures are measured in the inner tank 3 and outer tank 5 is not limited to the example described above. That is, for example, for the inner tank 3, the temperature may be measured at a connection point with other members, and for the outer tank 5, the temperature of the space 9 between the inner and outer tanks may be measured.
- the device used for these temperature measurements may be, for example, a temperature detection device as described above, or a differential thermometer that outputs the difference in temperature detected by individual temperature detection elements.
- cool down is performed using liquefied hydrogen for cooling, but cool down may be performed using liquefied gas other than liquefied hydrogen.
- the cooldown may be performed in stages, such as introducing liquefied nitrogen from a state in which air is present in the inner tank 3, and then replacing the nitrogen with hydrogen.
- the cool down according to the present embodiment is typically performed, for example, after construction of the storage tank 1, after construction of liquefied gas storage equipment such as a ship in which the storage tank 1 is installed, or after the construction of the equipment or the storage tank 1. Maintenance is carried out after warming up the storage tank 1 and before loading it again.
- the cool-down method according to the present embodiment is also applied when carrying out an empty voyage (ballast voyage) after unloading the liquefied gas in the storage tank 1 when the storage tank 1 is installed on a ship. be able to. That is, during a ballast voyage, the temperature of the inner tank 3 may gradually rise, and in that case, the above-mentioned cool-down method can be applied.
- the liquefied gas left in the inner tank 3 for cooling down without unloading is used to cool down the pumps etc. installed in the inner tank 3.
- a feeding device transports the liquefied gas to the top of the tank for cooling down.
- liquefied gas or vaporized gas for cooling down may be supplied from other storage tanks 1.
- liquefied hydrogen is discharged from the storage tank 1, and the on-off valve 19 of the communication passage 11 is in a closed state in the storage tank 1 in an initial state at the time of starting the warm-up shown in FIG. 3A.
- hydrogen gas exists in the inner tank space 7 at a pressure slightly higher than atmospheric pressure, for example, at a temperature of about 20 K, which is the freezing point, under 5 kPaG.
- hydrogen gas exists at a temperature of about 110 K under a steady operating state, for example, at a pressure of -10 kPaG, which is slightly lower than atmospheric pressure.
- the temperature and pressure values of the hydrogen gas in the initial state are not limited to the above example.
- heating hydrogen gas (hereinafter referred to as "first heating gas") HG1 is supplied to the inner tank space 7 using the sprayer 29.
- the first heating gas may be supplied using another line connected to the inner tank 3, for example, a line provided for supplying liquefied gas to the storage tank 1.
- the temperature difference between the inner tank 3 and the outer tank 5 may become too large, and the difference in the amount of thermal contraction of the constituent members may become excessive.
- the temperature of the inner tank 3 and the temperature of the outer tank 5 are measured respectively, and the temperature difference between the temperature of the inner tank 3 and the temperature of the outer tank 5 (hereinafter simply referred to as "temperature The temperature difference is maintained at a predetermined value or less by adjusting at least one of the temperature change rate of the inner tank 3 and the outer tank 5 based on the temperature change rate of the inner tank 3 and the outer tank 5.
- the "predetermined value" of the temperature difference here is set, for example, based on the temperature difference at the end of normal operation of the storage tank 1, and is, for example, a value larger than the temperature difference at the start of normal operation, for example, about 150K. .
- the "predetermined value” is not limited to this value.
- heating gas hereinafter referred to as "second heating gas" HG2 is also supplied to the space 9 between the inner and outer tanks. By doing so, the temperature increase rate of the outer tank 5 is increased.
- the second heating gas HG2 is supplied to the space 9 between the inner and outer tanks, for example, via a dedicated heating gas supply path 41.
- the second heating gas HG2 may be supplied to the space 9 between the inner and outer tanks, for example, via the hydrogen gas introduction passage 15, bypassing the cooling device 33.
- at least one of the supply speed of the first heating gas to the inner tank inner space 7 and the supply speed of the second heating gas HG2 to the inner and outer tank space 9 is adjusted. do.
- the locations at which the temperatures of each of the inner tank 3 and outer tank 5 are measured during warm-up are the same as in the case of cool-down described above. That is, for example, a predetermined location where the representative temperature of each tank 3, 5 can be detected, a connection location of each tank 3, 5 with other members, and an inner tank space that is an inner space in contact with each tank 3, 5. 7. The temperature of the space 9 between the inner and outer tanks can be measured.
- the second heating gas HG2 is preferably supplied to the space 9 between the inner and outer tanks after the temperature of the inner tank 3 rises to a predetermined value or higher.
- the "predetermined value" of the temperature of the inner tank 3 here means a temperature at which there is no possibility of hydrogen gas condensing in the space 9 between the inner and outer tanks.
- the temperature of the space 9 between the inner and outer tanks and the outer tank 5 can also be increased. Therefore, compared to the case where only the inner tank 3 is heated, the time required to warm up the entire storage tank 1 can be shortened and costs can be suppressed. Furthermore, by maintaining the temperature difference between the inner tank 3 and the outer tank 5 below a predetermined value, it is possible to suppress the difference in the amount of thermal contraction of the constituent members.
- FIG. 1 shows an independent double-shell tank formed independently of the ship's hull as an example of the storage tank 1
- the cool-down method and warm-up method according to this embodiment are based on this example. It is not limited to, but can be applied to any type of storage tank.
- the cool-down method and warm-up method according to this embodiment can also be applied to a type of storage tank that is formed integrally with the hull.
- the multiple structure of the storage tank may be a triple structure or more, and the cool-down method and warm-up method according to the present embodiment may be applied to the internal tank space and any other inter-tank space of such a multiple structure. Can be applied.
- cooling gas CG is supplied to the space 9 between the inner and outer tanks.
- the rate of temperature change in the inner tank 3 may be adjusted by reducing the rate of introduction of cooling liquefied hydrogen CH into the inner tank 3. Further, the temperature change rate of the outer tank 5 may be adjusted by increasing the cooling gas supply rate to the space 9 between the inner and outer tanks. According to this configuration, the temperature difference can be adjusted with a simple structure.
- the temperature of the inner tank 3 and the temperature of the outer tank 5 are measured by measuring the temperature at a predetermined location where each representative temperature of the inner tank 3 and the outer tank 5 can be detected. You may go. According to this configuration, the temperature difference can be adjusted with high precision.
- the temperature of the inner tank 3 and the temperature of the outer tank 5 are measured by measuring the temperature of each connection point with other members in the inner tank 3 and the outer tank 5. Good too. According to this configuration, the state of connection between the inner tank 3, outer tank 5, and other members can be effectively maintained by adjusting the temperature difference.
- the temperature of the inner tank 3 and the temperature of the outer tank 5 may be measured by measuring the temperature of the inner tank space 7 and the space 9 between the inner and outer tanks. According to this configuration, the temperature measurement location used for steady operation of the storage tank 1 can be used, so there is no need to add a measurement device or the like.
- the inner tank 3 and the outer tank are heated by supplying the second heating gas HG2 to the space 9 between the inner and outer tanks while heating the inner tank 3 with the first heating gas HG1.
- the temperature difference in the tank 5 below a predetermined value, it is possible to suppress the difference in the amount of thermal contraction of the constituent members, shorten the time required for warm-up, and suppress costs.
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Abstract
This method for cooling down a tank, which is for storing liquefied gas and is equipped with an inner tank (3) and an outer tank (5), before filling the same with the liquefied gas to be stored therein comprises: introducing a cooling liquefied gas (CH) into an interior space (7) of the inner tank; measuring the respective temperatures of the inner tank (3) and the outer tank (5); and maintaining the difference in temperature between the inner tank (3) and the outer tank (5) at a prescribed value or lower by adjusting the temperature variation speed of the inner tank (3) and/or the temperature variation speed of the outer tank (5) on the basis of the difference in temperature.
Description
この出願は、2022年3月23日出願の特願2022-046799の優先権を主張するものであり、その全体を参照により本願の一部をなすものとして引用する。
This application claims priority to Japanese Patent Application No. 2022-046799 filed on March 23, 2022, and is hereby incorporated by reference in its entirety.
本開示は、液化ガス貯蔵タンクのクールダウン方法およびウォームアップ方法に関する。
The present disclosure relates to a method for cooling down and warming up a liquefied gas storage tank.
従来、液化ガス、例えば極低温の液化水素を貯蔵するタンクとして、内槽および外槽を備える二重殻タンクを用いることが提案されている(例えば、特許文献1参照)。
Conventionally, it has been proposed to use a double-shell tank including an inner tank and an outer tank as a tank for storing liquefied gas, such as cryogenic liquefied hydrogen (see, for example, Patent Document 1).
一般的に、低温の液化ガスをタンクに貯蔵する場合、常温のタンクに一度に多量の貯蔵対象の液化ガスを充填することによってタンクを急激に冷却することを回避するため、貯蔵対象の液化ガスを充填する前に、予めタンクを比較的低速で冷却すること(以下、「クールダウン」という。)が行われている。また、メンテナンス等のためタンクを空にする必要がある場合には、貯蔵対象の液化ガスを排出した後タンクを加熱すること(以下、「ウォームアップ」という。)が行われている。
Generally, when storing low-temperature liquefied gas in a tank, in order to avoid rapid cooling of the tank by filling a room-temperature tank with a large amount of liquefied gas to be stored at once, Before filling the tank, the tank is cooled at a relatively low speed (hereinafter referred to as "cool down"). Furthermore, when it is necessary to empty the tank for maintenance or the like, the tank is heated (hereinafter referred to as "warm-up") after the liquefied gas to be stored is discharged.
しかし、液化ガス用二重殻タンクのような多重防熱構造のタンクの場合、高い断熱性を有することから、上述したように比較的低速でタンクを冷却した場合でも、タンクの場所によって大きな温度差が生じ、その結果大きな応力が生じる可能性がある。これを回避するため、従来の二重殻タンクのクールダウンにおいては、さらに低速に冷却するなどの対応が必要となり、タンク全体の冷却に長時間を要し、かつ多量の冷却用の液化ガスを要することになる。したがって、クールダウンに要するコストが増大する。多重防熱構造タンクのウォームアップについても、同様の課題が存在する。
However, in the case of tanks with multiple heat insulation structures such as double-shell tanks for liquefied gas, they have high insulation properties, so even when the tank is cooled at a relatively slow rate as described above, there are large temperature differences depending on the location of the tank. can occur, resulting in large stresses. To avoid this, conventional double-shell tank cool-down requires measures such as cooling at an even slower rate, which requires a long time to cool the entire tank and requires a large amount of liquefied gas for cooling. It will take a while. Therefore, the cost required for cooldown increases. A similar problem exists with regard to warming up tanks with multiple thermal insulation structures.
本開示の目的は、上記の課題を解決するために、液化ガス貯蔵用の多重防熱構造タンクのクールダウンおよびウォームアップにおいて応力の発生を抑制しながら時間を短縮し、コストを抑制することにある。
In order to solve the above-mentioned problems, an object of the present disclosure is to shorten the time and reduce costs while suppressing the generation of stress during cool-down and warm-up of a multi-layered heat-insulated structure tank for storing liquefied gas. .
上記目的を達成するために、本開示に係る液化ガス貯蔵タンクのクールダウン方法は、
液化ガスを貯蔵するための、内槽および外槽を備えるタンクを、貯蔵対象である前記液化ガスを充填する前に冷却する方法であって、
内槽内空間に、冷却用液化ガスを導入することと、
前記内槽の温度と、前記外槽の温度とをそれぞれ測定することと、
前記内槽の温度と前記外槽の温度との温度差に基づいて、前記内槽の温度変化速度および前記外槽の温度変化速度の少なくとも一方を調整することにより温度差を所定値以下に維持することと、
を含む。 In order to achieve the above object, a method for cooling down a liquefied gas storage tank according to the present disclosure includes:
A method for cooling a tank including an inner tank and an outer tank for storing liquefied gas before filling it with the liquefied gas to be stored, the method comprising:
Introducing a cooling liquefied gas into the inner tank space;
Measuring the temperature of the inner tank and the temperature of the outer tank, respectively;
Based on the temperature difference between the temperature of the inner tank and the temperature of the outer tank, the temperature difference is maintained at a predetermined value or less by adjusting at least one of the temperature change rate of the inner tank and the temperature change rate of the outer tank. to do and
including.
液化ガスを貯蔵するための、内槽および外槽を備えるタンクを、貯蔵対象である前記液化ガスを充填する前に冷却する方法であって、
内槽内空間に、冷却用液化ガスを導入することと、
前記内槽の温度と、前記外槽の温度とをそれぞれ測定することと、
前記内槽の温度と前記外槽の温度との温度差に基づいて、前記内槽の温度変化速度および前記外槽の温度変化速度の少なくとも一方を調整することにより温度差を所定値以下に維持することと、
を含む。 In order to achieve the above object, a method for cooling down a liquefied gas storage tank according to the present disclosure includes:
A method for cooling a tank including an inner tank and an outer tank for storing liquefied gas before filling it with the liquefied gas to be stored, the method comprising:
Introducing a cooling liquefied gas into the inner tank space;
Measuring the temperature of the inner tank and the temperature of the outer tank, respectively;
Based on the temperature difference between the temperature of the inner tank and the temperature of the outer tank, the temperature difference is maintained at a predetermined value or less by adjusting at least one of the temperature change rate of the inner tank and the temperature change rate of the outer tank. to do and
including.
本開示に係る液化ガス貯蔵タンクのウォームアップ方法は、
液化ガスを貯蔵するための、内槽および外槽を備えるタンクを、貯蔵対象である前記液化ガスを排出した後に加熱する方法であって、
内槽内空間に、第1加熱用ガスを導入することと、
内外槽間空間へ第2加熱用ガスを強制的に供給すること
前記内槽の温度と、前記外槽の温度とをそれぞれ測定することと、
前記内槽の温度と前記外槽の温度との温度差に基づいて、前記内槽の温度変化速度および前記外槽の温度変化速度の少なくとも一方を調整することにより温度差を所定値以下に維持することと、
を含む。 A method for warming up a liquefied gas storage tank according to the present disclosure includes:
A method for heating a tank for storing liquefied gas, including an inner tank and an outer tank, after discharging the liquefied gas to be stored, the method comprising:
Introducing a first heating gas into the inner tank space;
Forcibly supplying a second heating gas to the space between the inner and outer tanks; Measuring the temperature of the inner tank and the temperature of the outer tank, respectively;
Based on the temperature difference between the temperature of the inner tank and the temperature of the outer tank, the temperature difference is maintained at a predetermined value or less by adjusting at least one of the temperature change rate of the inner tank and the temperature change rate of the outer tank. to do and
including.
液化ガスを貯蔵するための、内槽および外槽を備えるタンクを、貯蔵対象である前記液化ガスを排出した後に加熱する方法であって、
内槽内空間に、第1加熱用ガスを導入することと、
内外槽間空間へ第2加熱用ガスを強制的に供給すること
前記内槽の温度と、前記外槽の温度とをそれぞれ測定することと、
前記内槽の温度と前記外槽の温度との温度差に基づいて、前記内槽の温度変化速度および前記外槽の温度変化速度の少なくとも一方を調整することにより温度差を所定値以下に維持することと、
を含む。 A method for warming up a liquefied gas storage tank according to the present disclosure includes:
A method for heating a tank for storing liquefied gas, including an inner tank and an outer tank, after discharging the liquefied gas to be stored, the method comprising:
Introducing a first heating gas into the inner tank space;
Forcibly supplying a second heating gas to the space between the inner and outer tanks; Measuring the temperature of the inner tank and the temperature of the outer tank, respectively;
Based on the temperature difference between the temperature of the inner tank and the temperature of the outer tank, the temperature difference is maintained at a predetermined value or less by adjusting at least one of the temperature change rate of the inner tank and the temperature change rate of the outer tank. to do and
including.
本開示に係る液化ガス貯蔵タンクのクールダウン方法およびウォームアップ方法によれば、液化ガス貯蔵用の多重防熱構造タンクのクールダウンおよびウォームアップにおいて応力の発生を抑制しながら時間を短縮し、コストを抑制することができる。
According to the cool-down method and warm-up method for a liquefied gas storage tank according to the present disclosure, the time and cost can be reduced while suppressing the generation of stress during the cool-down and warm-up of a multi-layered heat-insulated structure tank for storing liquefied gas. Can be suppressed.
請求の範囲および/または明細書および/または図面に開示された少なくとも2つの構成のどのような組合せも、本発明に含まれる。特に、請求の範囲の各請求項の2つ以上のどのような組合せも、本発明に含まれる。
Any combination of at least two configurations disclosed in the claims and/or the specification and/or the drawings is included in the present invention. In particular, any combination of two or more of each of the claims is included in the invention.
本発明は、添付の図面を参考にした以下の好適な実施形態の説明からより明瞭に理解されるであろう。しかしながら、実施形態および図面は単なる図示および説明のためのものであり、本発明の範囲を定めるために利用されるべきものではない。本発明の範囲は添付の請求の範囲によって定まる。添付図面において、複数の図面における同一の部品番号は、同一または相当部分を示す。
本開示の一実施形態に係るクールダウン方法が適用される液化ガス貯蔵タンクの概略構成を示す断面図である。
本開示の一実施形態に係るクールダウン方法の開始前の初期状態を示す模式図である。
本開示の一実施形態に係るクールダウン方法における内槽冷却中の状態を示す模式図である。
本開示の一実施形態に係るクールダウン方法における温度差調整を行っている状態を示す模式図である。
本開示の一実施形態に係るクールダウン方法の終了した状態を示す模式図である。
本開示の一実施形態に係るウォームアップ方法の開始時の状態を示す模式図である。
本開示の一実施形態に係るウォームアップ方法における温度差調整を行っている状態を示す模式図である。
The invention will be more clearly understood from the following description of preferred embodiments with reference to the accompanying drawings. However, the embodiments and drawings are merely for illustration and explanation, and should not be used to define the scope of the present invention. The scope of the invention is defined by the appended claims. In the accompanying drawings, the same part numbers in multiple drawings indicate the same or corresponding parts.
1 is a cross-sectional view showing a schematic configuration of a liquefied gas storage tank to which a cool-down method according to an embodiment of the present disclosure is applied. FIG. 2 is a schematic diagram showing an initial state before the start of a cool-down method according to an embodiment of the present disclosure. FIG. 3 is a schematic diagram showing a state during cooling of the inner tank in a cool-down method according to an embodiment of the present disclosure. FIG. 2 is a schematic diagram showing a state in which temperature difference adjustment is performed in a cool-down method according to an embodiment of the present disclosure. FIG. 2 is a schematic diagram showing a state in which a cool-down method according to an embodiment of the present disclosure has been completed. FIG. 2 is a schematic diagram showing a state at the start of a warm-up method according to an embodiment of the present disclosure. FIG. 3 is a schematic diagram showing a state in which temperature difference adjustment is performed in a warm-up method according to an embodiment of the present disclosure.
以下、本開示の好ましい実施形態について図面を参照しながら説明する。図1に本開示の一実施形態に係るクールダウン方法およびウォームアップ方法が適用される液化ガス貯蔵タンク(以下、単に「貯蔵タンク」という。)1を示す。この貯蔵タンク1は、液化ガスを貯蔵するためのタンクであり、内槽3および外槽5を備える二重殻タンクとして構成されている。なお、本明細書において、「クールダウン」とは、貯蔵対象である液化ガスを貯蔵タンク1に充填する前に、貯蔵タンク1を冷却することを意味する。また、本明細書において、「ウォームアップ」とは、貯蔵対象である前記液化ガスを排出した後に、その後のメンテナンス等に備えて、低温の貯蔵タンク1を加熱することを意味する。
Hereinafter, preferred embodiments of the present disclosure will be described with reference to the drawings. FIG. 1 shows a liquefied gas storage tank (hereinafter simply referred to as "storage tank") 1 to which a cool-down method and a warm-up method according to an embodiment of the present disclosure are applied. This storage tank 1 is a tank for storing liquefied gas, and is configured as a double shell tank including an inner tank 3 and an outer tank 5. Note that in this specification, "cool down" means cooling the storage tank 1 before filling the storage tank 1 with the liquefied gas to be stored. Furthermore, in this specification, "warming up" means heating the low-temperature storage tank 1 in preparation for subsequent maintenance and the like after the liquefied gas to be stored is discharged.
以下に説明する本実施形態においては、貯蔵対象である液化ガスとして極低温(約-250℃)の液化水素を例として説明する。もっとも、液化ガスは他の種類のガス、例えば、液化石油ガス(LPG、約-45℃)、液化エチレンガス(LEG、約-100℃)、液化天然ガス(LNG、約-160℃)、液化ヘリウム(LHe、約-270℃)などであってよい。
In the present embodiment described below, liquefied hydrogen at an extremely low temperature (approximately -250° C.) will be explained as an example of the liquefied gas to be stored. However, liquefied gas can also include other types of gas, such as liquefied petroleum gas (LPG, approximately -45°C), liquefied ethylene gas (LEG, approximately -100°C), liquefied natural gas (LNG, approximately -160°C), It may be helium (LHe, about −270° C.) or the like.
貯蔵タンク1は、例えば液化水素運搬船のような船舶に設置される。もっとも、貯蔵タンク1が設置される液化水素貯蔵設備は、液化水素を貯蔵することが可能な構造、機能を有する設備であればこの例に限定されない。貯蔵タンク1が設置される液化水素貯蔵設備は、例えば、液化水素を推進用燃料として使用する船舶であってもよく、船舶以外の地上の液化水素貯蔵設備や、液化水素を利用するプラントであってよい。
The storage tank 1 is installed, for example, on a ship such as a liquefied hydrogen carrier. However, the liquefied hydrogen storage facility in which the storage tank 1 is installed is not limited to this example as long as it has a structure and function capable of storing liquefied hydrogen. The liquefied hydrogen storage facility in which the storage tank 1 is installed may be, for example, a ship that uses liquefied hydrogen as a propulsion fuel, a land-based liquefied hydrogen storage facility other than a ship, or a plant that uses liquefied hydrogen. It's fine.
貯蔵タンク1は、内槽3および外槽5を有する二重殻タンクとして構成されている。具体的には、内槽3は、その内側に貯蔵対象である液化水素の貯蔵空間(以下、「内槽内空間7」と呼ぶ。)を形成する内槽殻と、内槽殻の外周面を覆う内槽防熱層とを有する。外槽5は、内槽3との間に断熱層である内外槽間空間9を形成する外槽殻と、外槽殻の外周面を覆う外槽防熱層とを有する。なお、内槽3および外槽5の防熱層を設置する箇所はこの例に限定されず任意であり、例えば防熱層を外槽殻の内周面を覆うように設置してもよい。また、内槽3および外槽5の防熱層の一方または両方を省略してもよい。この貯蔵タンク1は、断熱層である内外槽間空間9に低温の水素ガスを封入した状態で定常運用される。
The storage tank 1 is configured as a double shell tank having an inner tank 3 and an outer tank 5. Specifically, the inner tank 3 has an inner tank shell that forms a storage space (hereinafter referred to as "inner tank interior space 7") for liquefied hydrogen to be stored, and an outer circumferential surface of the inner tank shell. It has an inner tank heat insulation layer that covers the inner tank. The outer tank 5 has an outer tank shell that forms an inter-inner/outer tank space 9 that is a heat insulating layer between it and the inner tank 3, and an outer tank heat insulating layer that covers the outer peripheral surface of the outer tank shell. Note that the locations where the heat insulating layers of the inner tank 3 and the outer tank 5 are installed are not limited to this example, but are arbitrary. For example, the heat insulating layers may be installed so as to cover the inner circumferential surface of the outer tank shell. Moreover, one or both of the heat-insulating layers of the inner tank 3 and the outer tank 5 may be omitted. This storage tank 1 is normally operated with low-temperature hydrogen gas sealed in the space 9 between the inner and outer tanks, which is a heat insulating layer.
本実施形態では、内槽内空間7と内外槽間空間9とを連通させる連通路11が設けられている。連通路11は開閉可能に構成されている。図示の例では、具体的には、内槽内空間7で生じた液化水素の気化ガス(以下、単に「気化ガス」と呼ぶ。)G1を貯蔵タンク1の外部へ排出する気化ガス排出通路13と、貯蔵タンク1の外部に設けられた水素ガス源(図示せず)からの水素ガス(以下、「外部水素ガス」と呼ぶ。)G2を内外槽間空間9に導入する水素ガス導入通路15と、貯蔵タンク1の外部において気化ガス排出通路13と水素ガス導入通路15とを接続する接続通路17とが設けられている。これら気化ガス排出通路13、接続通路17および水素ガス導入通路15によって連通路11が形成されている。また、連通路11に開閉弁19が設けられており、この開閉弁19によって連通路11が開閉可能に構成されている。この例では、水素ガス導入通路15における接続通路17との接続点の下流側の部分に開閉弁19が設けられているが、開閉弁19の位置および個数はこの例に限定されない。また、開閉弁19は、手動で開閉可能な弁のほか、設定された差圧に応じて自動的に開閉する弁であってもよい。
In this embodiment, a communication passage 11 is provided that communicates the inner tank interior space 7 and the outer and outer tank space 9. The communication path 11 is configured to be openable and closable. In the illustrated example, specifically, a vaporized gas discharge passage 13 that discharges vaporized gas of liquefied hydrogen (hereinafter simply referred to as “vaporized gas”) G1 generated in the inner tank space 7 to the outside of the storage tank 1 and a hydrogen gas introduction passage 15 that introduces hydrogen gas (hereinafter referred to as "external hydrogen gas") G2 from a hydrogen gas source (not shown) provided outside the storage tank 1 into the space 9 between the inner and outer tanks. A connecting passage 17 connecting the vaporized gas discharge passage 13 and the hydrogen gas introduction passage 15 is provided outside the storage tank 1. A communication passage 11 is formed by the vaporized gas discharge passage 13, the connection passage 17, and the hydrogen gas introduction passage 15. Further, an on-off valve 19 is provided in the communication passage 11, and the communication passage 11 is configured to be openable and closable by this on-off valve 19. In this example, the on-off valve 19 is provided in a portion of the hydrogen gas introduction passage 15 downstream of the connection point with the connection passage 17, but the position and number of the on-off valves 19 are not limited to this example. Further, the on-off valve 19 may be a valve that can be opened and closed manually, or may be a valve that is automatically opened and closed according to a set differential pressure.
なお、内槽内空間7と内外槽間空間9との間の連通路11の具体的な構成、および連通路11を開閉可能とする具体的な構成は、この例に限定されない。また、上記「水素ガス源」は、水素ガスの供給源となり得るものであればどのような構成であってもよく、典型的には水素ガスを貯蔵したタンクであるが、例えば液化水素を貯蔵したタンクと気化器を組み合わせたものであってもよい。
Note that the specific configuration of the communication path 11 between the inner tank interior space 7 and the outer and outer tank space 9 and the specific configuration that allows the communication path 11 to be opened and closed are not limited to this example. Further, the above-mentioned "hydrogen gas source" may have any configuration as long as it can serve as a supply source of hydrogen gas, and is typically a tank that stores hydrogen gas, but for example, it may be a tank that stores liquefied hydrogen. It may also be a combination of a tank and a vaporizer.
さらに、本実施形態では、連通路11に、圧縮機や送風機といった、後述する冷却用ガスを強制的に内外槽間空間9に送給する装置(以下、単に「ガス送給装置」と呼ぶ。)31が設けられている。ガス送給装置31は、例えばターボ式または容積式の圧縮機、ブロワ、ファンといったガスに圧力をかけることによりガスを移動させる装置である。図示の例では接続通路17にガス送給装置31が設けられている。また、連通路11上、例えば水素ガス導入通路15上に冷却装置33が設けられている。冷却装置33は、例えば、ガス温度を検知する温度センサ、圧縮式冷凍機や吸収式冷凍機といった冷却源、これらを制御する制御回路等を備える。もっとも、冷却装置35は、上記以外の構成の装置、例えば熱交換器であってもよい。また、ガス送給装置31,冷却装置33は、後述するクールダウン方法およびウォームアップ方法の実施の態様に応じて必要なもののみが設けられていてよい。
Furthermore, in the present embodiment, a device (hereinafter simply referred to as a "gas feeding device") that forcibly feeds cooling gas, which will be described later, to the space 9 between the inner and outer tanks is provided in the communication path 11, such as a compressor or a blower. ) 31 are provided. The gas supply device 31 is a device that moves gas by applying pressure to the gas, such as a turbo or positive displacement compressor, blower, or fan. In the illustrated example, a gas supply device 31 is provided in the connection passage 17 . Further, a cooling device 33 is provided on the communication path 11, for example, on the hydrogen gas introduction path 15. The cooling device 33 includes, for example, a temperature sensor that detects gas temperature, a cooling source such as a compression refrigerator or an absorption refrigerator, a control circuit that controls these, and the like. However, the cooling device 35 may be a device having a configuration other than the above, for example, a heat exchanger. Furthermore, only the gas supply device 31 and the cooling device 33 that are necessary may be provided depending on the embodiment of the cool-down method and warm-up method described later.
また、本実施形態では、内槽3の温度を検知する内槽温度検知装置21、内槽内空間7の圧力を監視する内槽内空間圧力検知装置23、内外槽間空間9の温度を検知する内外槽間空間温度検知装置25、および内外槽間空間9の圧力を検知する内外槽間空間圧力検知装置27を備えている。これらの検知装置は、検知対象の物理量(温度、圧力)を検知するセンサ素子、取得した検出量に対して信号変換処理、演算処理等必要な処理を行う各種回路、これらの処理に必要な情報を格納するためのメモリ、電池等の電源素子または外部から電源供給を受けるための電源回路、出力信号を有線または無線で外部へ送信するための送信回路等を備えている。なお、このような温度検知装置,圧力検知装置として、上記以外の部分を計測する装置、例えば内槽温度検知装置や外槽温度検知装置が設けられていてもよい。また、これらの温度検知装置,圧力検知装置は、後述するクールダウン方法およびウォームアップ方法の実施の態様に応じて必要なもののみが設けられていてよい。
Further, in this embodiment, an inner tank temperature detection device 21 that detects the temperature of the inner tank 3, an inner tank space pressure detection device 23 that monitors the pressure of the inner tank space 7, and a temperature detection device 23 that detects the temperature of the space 9 between the inner and outer tanks. The inner and outer tank space temperature detection device 25 detects the pressure in the inner and outer tank space 9, and the inner and outer tank space pressure sensor 27 detects the pressure in the inner and outer tank space 9. These detection devices consist of a sensor element that detects the physical quantity to be detected (temperature, pressure), various circuits that perform necessary processing such as signal conversion processing and arithmetic processing on the obtained detected quantity, and information necessary for these processing. The device is equipped with a memory for storing the data, a power source circuit such as a power supply element such as a battery or a power supply circuit for receiving power supply from the outside, a transmission circuit for transmitting the output signal to the outside by wire or wirelessly, and the like. Note that as such a temperature sensing device and a pressure sensing device, a device that measures parts other than those described above, such as an inner tank temperature sensing device or an outer tank temperature sensing device, may be provided. Furthermore, only the necessary temperature sensing devices and pressure sensing devices may be provided depending on the embodiment of the cool-down method and warm-up method described later.
このように構成された貯蔵タンク1のクールダウン方法について、以下に詳細に説明する。
A method for cooling down the storage tank 1 configured in this way will be described in detail below.
本実施形態では、図2Aに示すクールダウンを開始する時点での初期状態の貯蔵タンク1において、連通路11の開閉弁19を開いた状態とされており、内槽内空間7および内外槽間空間9には、いずれも、例えば常温,大気圧(0kPaG)の水素ガスが存在している。もっとも、初期状態の水素ガスの温度,圧力は常温,大気圧に限定されない。この状態から、図2Bに示すように、内槽内空間7に冷却用の液化水素(以下、単に「冷却用水素」と呼ぶ。)CHを導入する。この例では、噴霧器29を用いて、内槽内空間7に、冷却用水素CHを噴霧する。
In this embodiment, in the storage tank 1 in the initial state at the time of starting the cool-down shown in FIG. In each of the spaces 9, hydrogen gas exists at room temperature and atmospheric pressure (0 kPaG), for example. However, the temperature and pressure of the hydrogen gas in the initial state are not limited to room temperature and atmospheric pressure. From this state, as shown in FIG. 2B, liquefied hydrogen for cooling (hereinafter simply referred to as "hydrogen for cooling") CH is introduced into the inner tank space 7. In this example, cooling hydrogen CH is sprayed into the inner tank space 7 using the sprayer 29 .
この状態で冷却用水素CHの噴霧を続けることにより、内槽3の温度が低下する。内槽3の温度が低下することにより、内外槽間空間9の温度も低下する。また、内槽内空間7においては、冷却用水素CHが気化した気化ガスG1が発生して圧力が上昇する一方、内外槽間空間9においては温度低下によって圧力が低下する。上記のように連通路11が開かれているので、内槽内空間7で発生した気化ガスG1は、両空間7,9の圧力差によって、連通路11を介して内外槽間空間9に流入する。
By continuing to spray the cooling hydrogen CH in this state, the temperature of the inner tank 3 is reduced. As the temperature of the inner tank 3 decreases, the temperature of the space 9 between the inner and outer tanks also decreases. Further, in the inner tank space 7, vaporized gas G1 in which the cooling hydrogen CH is vaporized is generated, and the pressure increases, while in the inner tank space 9, the pressure decreases due to the temperature drop. Since the communication passage 11 is opened as described above, the vaporized gas G1 generated in the inner tank inner space 7 flows into the inner and outer tank space 9 via the communication passage 11 due to the pressure difference between both spaces 7 and 9. do.
なお、連通路11を開状態としながら内槽3を冷却している間、両空間の圧力差が所定の範囲を超えた場合には、圧力差を調整する装置を用いて両空間の圧力差が所定の範囲内に収まるように調整してもよい。例えば、内外槽間空間9の圧力が過度に低い場合には、水素ガス送給装置31を用いて内槽内空間7の気化ガスG1を内外槽間空間9に供給してもよい。気化ガスG1の強制的な供給に代えて、または追加して、水素ガス導入通路15から外部水素ガスG2を内外槽間空間9に供給してもよい。以下の説明では、このように内外槽間空間9を冷却するために強制的に供給されるガスを総称して「冷却ガスCG」と呼ぶ。
If the pressure difference between the two spaces exceeds a predetermined range while cooling the inner tank 3 with the communication passage 11 open, a pressure difference adjustment device is used to adjust the pressure difference between the two spaces. may be adjusted so that it falls within a predetermined range. For example, if the pressure in the space 9 between the inner and outer tanks is excessively low, the hydrogen gas supply device 31 may be used to supply the vaporized gas G1 in the inner tank space 7 to the space 9 between the inner and outer tanks. In place of or in addition to the forced supply of the vaporized gas G1, external hydrogen gas G2 may be supplied from the hydrogen gas introduction passage 15 to the space 9 between the inner and outer tanks. In the following description, the gas that is forcibly supplied to cool the space 9 between the inner and outer tanks in this manner will be collectively referred to as "cooling gas CG."
なお、上述のように内外槽間空間9に冷却ガスCGを強制的に供給する場合は、内外槽間空間9から冷却ガスCGを排出する排出通路(図示せず)を設けて、内外槽間空間9の圧力が過度に上昇することを防止してもよい。
In addition, when the cooling gas CG is forcibly supplied to the space 9 between the inner and outer tanks as described above, a discharge passage (not shown) is provided to discharge the cooling gas CG from the space 9 between the inner and outer tanks. It may also be possible to prevent the pressure in the space 9 from increasing excessively.
また、本実施形態では、クールダウンの開始時、つまり冷却用水素CHの噴霧の開始時から連通路11を開状態にする例について説明したが、連通路11を開くタイミングはこれに限定されない。すなわち、連通路11を閉じた状態で冷却用水素CHの噴霧を開始し、内外槽間空間9の圧力が所定値以下となった場合など、必要に応じて連通路11を開いて気化ガスG1を供給してもよい。
Furthermore, in this embodiment, an example has been described in which the communication passage 11 is opened from the start of cool-down, that is, from the start of spraying of the cooling hydrogen CH, but the timing of opening the communication passage 11 is not limited to this. That is, spraying of the cooling hydrogen CH is started with the communication passage 11 closed, and if necessary, such as when the pressure in the space 9 between the inner and outer tanks falls below a predetermined value, the communication passage 11 is opened to spray the vaporized gas G1. may be supplied.
このようにして行われるクールダウンの過程で、内槽3と外槽5の温度差が大きくなりすぎ、構成部材の熱収縮量の差が過大になり大きな応力が発生する場合がある。これを回避するため、本実施形態では、内槽3の温度と、外槽5の温度とをそれぞれ測定し、内槽3の温度と外槽5の温度との温度差(以下、単に「温度差」という。)に基づいて、内槽3の温度変化速度および外槽5の温度変化速度の少なくとも一方を調整することにより温度差を所定値以下に維持する。ここでの、「内槽3の温度」,「外槽5の温度」には、各槽に接する内方空間の温度、すなわち内槽3については内槽内空間7の温度、外槽5については内外槽間空間9の温度を含む。また、ここでの、温度差の「所定値」は、例えば、貯蔵タンク1の通常運用開始時の温度差を基準として設定され、例えば通常運用開始時の温度差よりも大きい値、例えば150K程度である。もっとも、当該「所定値」はこの値に限定されない。
During the cool-down process performed in this manner, the temperature difference between the inner tank 3 and the outer tank 5 becomes too large, and the difference in the amount of thermal contraction of the constituent members becomes too large, which may generate large stress. In order to avoid this, in this embodiment, the temperature of the inner tank 3 and the temperature of the outer tank 5 are measured respectively, and the temperature difference between the temperature of the inner tank 3 and the temperature of the outer tank 5 (hereinafter simply referred to as "temperature The temperature difference is maintained at a predetermined value or less by adjusting at least one of the temperature change rate of the inner tank 3 and the outer tank 5 based on the temperature change rate of the inner tank 3 and the outer tank 5. Here, "temperature of inner tank 3" and "temperature of outer tank 5" refer to the temperature of the inner space in contact with each tank, that is, the temperature of inner tank inner space 7 for inner tank 3, and the temperature of inner tank inner space 7 for outer tank 5. includes the temperature of the space 9 between the inner and outer tanks. Further, the "predetermined value" of the temperature difference here is set, for example, based on the temperature difference at the start of normal operation of the storage tank 1, and is, for example, a value larger than the temperature difference at the start of normal operation, for example, about 150K. It is. However, the "predetermined value" is not limited to this value.
内槽3の温度変化速度を調整する方法として、本実施形態では、内槽3への冷却用水素CHの導入速度を調整する。具体的には、内槽3への冷却用水素CHの導入速度を低下させることにより内槽3の冷却速度を低下させる。なお、ここでの、「導入速度を低下させる」には、導入を停止することを含む。また、外槽5の温度変化速度を調整する方法として、本実施形態では、内外槽間空間9への冷却ガスCGの供給速度を調整する。具体的には、内外槽間空間9への気化ガスG1および/または外部水素ガスG2の温度を冷却装置33によって低下させ、かつガス送給装置31を用いて冷却ガスCGの供給速度を上昇させることにより、外槽5の冷却速度を上昇させる。内槽3の冷却速度の低下と外槽5の冷却速度の上昇は、いずれか一方のみを実施してもよく、両方を組み合わせて実施してもよい。一例として、図2Cに、内槽3への冷却用水素CHの噴霧を停止し、かつ内外槽間空間9への冷却ガスCGの供給速度を上昇させた状態を示す。
In this embodiment, as a method for adjusting the rate of temperature change in the inner tank 3, the rate of introduction of cooling hydrogen CH into the inner tank 3 is adjusted. Specifically, the cooling rate of the inner tank 3 is reduced by reducing the introduction speed of cooling hydrogen CH into the inner tank 3. Note that "reducing the introduction speed" herein includes stopping the introduction. Moreover, as a method of adjusting the temperature change rate of the outer tank 5, in this embodiment, the supply rate of the cooling gas CG to the space 9 between the inner and outer tanks is adjusted. Specifically, the temperature of the vaporized gas G1 and/or the external hydrogen gas G2 to the space 9 between the inner and outer tanks is lowered by the cooling device 33, and the supply rate of the cooling gas CG is increased by using the gas feeding device 31. This increases the cooling rate of the outer tank 5. Either one of reducing the cooling rate of the inner tank 3 and increasing the cooling rate of the outer tank 5 may be implemented, or both may be implemented in combination. As an example, FIG. 2C shows a state in which spraying of the cooling hydrogen CH to the inner tank 3 is stopped and the supply rate of the cooling gas CG to the space 9 between the inner and outer tanks is increased.
なお、内槽3への冷却用水素CHの導入速度の調整は、上記の例に限定されず、例えば内槽3の冷却が不十分な場合に導入速度を上昇させることも含む。同様に、内外槽間空間9への冷却ガスCGの供給速度の調整は、上記の例に限定されず、例えば外槽5を冷却しすぎた場合に供給速度を低下させることも含む。内槽3の温度変化速度および外槽5の温度変化速度の少なくとも一方を調整する方法は、上述した例に限定されない。例えば、内槽内空間7に内槽温度よりも高温の水素ガスを供給してもよい。
Note that the adjustment of the introduction speed of the cooling hydrogen CH into the inner tank 3 is not limited to the above example, and includes, for example, increasing the introduction speed when the inner tank 3 is insufficiently cooled. Similarly, the adjustment of the supply rate of the cooling gas CG to the space 9 between the inner and outer tanks is not limited to the above example, and includes, for example, reducing the supply rate when the outer tank 5 is cooled too much. The method of adjusting at least one of the temperature change rate of the inner tank 3 and the temperature change rate of the outer tank 5 is not limited to the example described above. For example, hydrogen gas having a higher temperature than the inner tank temperature may be supplied to the inner tank space 7.
また、温度差制御を高精度に行うため、内槽3および外槽5において、各々の温度を測定する箇所として、例えば、内槽3の代表温度を検知可能な所定の箇所、および外槽5の代表温度を検知可能な所定の箇所を選択する。ここでの「代表温度」とは、内槽3および外槽5の各々の全体の温度分布からみて内槽3,外槽5各々の温度を最も適切に代表すると考えられる温度を意味する。「代表温度」の例として、内槽3および外槽5の各々の全体の温度分布の平均値が挙げられる。
In addition, in order to perform temperature difference control with high precision, in the inner tank 3 and the outer tank 5, the respective temperatures are measured at, for example, a predetermined location where the representative temperature of the inner tank 3 can be detected, and the outer tank 5. Select a predetermined location where the representative temperature can be detected. The term "representative temperature" as used herein means a temperature that is considered to most appropriately represent the temperature of each of the inner tank 3 and outer tank 5 in view of the overall temperature distribution of each of the inner tank 3 and outer tank 5. An example of the "representative temperature" is the average value of the overall temperature distribution of each of the inner tank 3 and the outer tank 5.
内槽3および外槽5において各々の温度を測定する箇所の他の例として、内槽3における他の部材との接続箇所および外槽5における他の部材との接続箇所が挙げられる。具体的には、温度測定を行う他の部材との接続箇所の例として、貯蔵タンク1を船体に対して支持する筒状の支持部材であるスカートとの接続箇所や、貯蔵タンク1内の中央部に上下方向に突設されるパイプ状のタワーとの接続箇所が挙げられる。他の部材との接続箇所の温度を測定し、温度差を調整することによって、内槽3,外槽5と他の部材との接続状態を効果的に維持することができる。
Other examples of locations where the temperatures of each of the inner tank 3 and the outer tank 5 are measured include locations where the inner tank 3 is connected to other members and locations where the outer tank 5 is connected to other members. Specifically, examples of connection points with other members that perform temperature measurement include connection points with the skirt, which is a cylindrical support member that supports the storage tank 1 relative to the hull, and the center of the storage tank 1. An example of this is the connection point with a pipe-shaped tower that protrudes vertically from the top. By measuring the temperature of the connection points with other members and adjusting the temperature difference, the state of connection between the inner tank 3, outer tank 5 and other members can be effectively maintained.
内槽3および外槽5において各々の温度を測定する箇所のさらなる他の例として、各槽3,5に接する内方空間、すなわち内槽3についての内槽内空間7、外槽5についての内外槽間空間9が挙げられる。この構成によれば、貯蔵タンク1の定常運転に使用される温度測定箇所を利用できるので、測定装置等の追加が不要となる。
As still another example of the locations where the temperature of each of the inner tank 3 and the outer tank 5 is measured, the inner space in contact with each tank 3, 5, that is, the inner tank inner space 7 for the inner tank 3, and the inner tank space 7 for the outer tank 5. An example is the space 9 between the inner and outer tanks. According to this configuration, the temperature measurement location used for steady operation of the storage tank 1 can be used, so there is no need to add a measurement device or the like.
なお、内槽3および外槽5において各々の温度を測定する箇所の組合せは、上記で説明した例に限定されない。すなわち、例えば、内槽3については他の部材との接続箇所の温度を測定し、外槽5については内外槽間空間9の温度を測定してもよい。
Note that the combination of locations at which temperatures are measured in the inner tank 3 and outer tank 5 is not limited to the example described above. That is, for example, for the inner tank 3, the temperature may be measured at a connection point with other members, and for the outer tank 5, the temperature of the space 9 between the inner and outer tanks may be measured.
また、これらの温度測定に用いる装置は、例えば、上述したような温度検知装置であってもよく、個別の温度検知素子で検知した温度の差を出力する差温計であってもよい。
Further, the device used for these temperature measurements may be, for example, a temperature detection device as described above, or a differential thermometer that outputs the difference in temperature detected by individual temperature detection elements.
このように、内槽3を冷却用水素CHで冷却しながら、必要に応じて水素ガスを内外槽間空間9に供給することにより、内外槽間空間9および外槽5の冷却が促進されるので、単に内槽3のみを冷却する場合に比べて貯蔵タンク1全体のクールダウンに要する時間を短縮し、コストを抑制することができる。さらに、内槽3と外槽5の温度差を所定値以下に維持することにより、構成部材の熱収縮量差を抑制することができる。
In this way, by supplying hydrogen gas to the space 9 between the inner and outer tanks as needed while cooling the inner tank 3 with the cooling hydrogen CH, cooling of the space 9 between the inner and outer tanks and the outer tank 5 is promoted. Therefore, compared to the case where only the inner tank 3 is cooled, the time required to cool down the entire storage tank 1 can be shortened and costs can be suppressed. Furthermore, by maintaining the temperature difference between the inner tank 3 and the outer tank 5 below a predetermined value, it is possible to suppress the difference in the amount of thermal contraction of the constituent members.
その後、図2Dに示すように、内槽3の温度および内外槽間空間9の温度がそれぞれ目標温度まで低下した時点で、連通路11が開状態であればこれを閉状態にするとともに、冷却用水素CHの噴霧を停止してクールダウンを終了する。
Thereafter, as shown in FIG. 2D, when the temperature of the inner tank 3 and the temperature of the space 9 between the inner and outer tanks have respectively decreased to the target temperatures, if the communication passage 11 is open, it is closed, and the cooling The spraying of hydrogen CH is stopped to complete the cool-down.
本実施形態では、クールダウンを冷却用の液化水素を用いて行う例について説明したが、クールダウンは液化水素以外の液化ガスを用いて行ってもよい。例えば、内槽3内に空気が存在する状態から、液化窒素を導入した後、さらに窒素を水素で置換するというように、段階的にクールダウンを進めてもよい。
In this embodiment, an example has been described in which cool down is performed using liquefied hydrogen for cooling, but cool down may be performed using liquefied gas other than liquefied hydrogen. For example, the cooldown may be performed in stages, such as introducing liquefied nitrogen from a state in which air is present in the inner tank 3, and then replacing the nitrogen with hydrogen.
本実施形態に係るクールダウンは、典型的には、例えば、貯蔵タンク1の建造後、貯蔵タンク1が設置される船舶のような液化ガス貯蔵設備の建造後、または、当該設備や貯蔵タンク1のメンテナンスのために貯蔵タンク1をウォームアップした後に再度積荷を実施する前に行われる。もっとも、本実施形態に係るクールダウン方法は、貯蔵タンク1が船舶に設置される場合において、貯蔵タンク1内の液化ガスを揚荷した後の空荷航海(バラスト航海)する際にも適用することができる。すなわち、バラスト航海においては内槽3の温度が徐々に上昇する場合があり、その場合に上記クールダウン方法を適用することができる。なお、バラスト航海中の貯蔵タンク1のクールダウンにおいては、例えば、揚荷せずにクールダウン用として内槽3内に残した液化ガスを用いて、内槽3内に設置されたポンプ等の送給装置によって液化ガスをタンク上部まで移送してクールダウンを行う。貯蔵タンク1が複数設置される場合には、他の貯蔵タンク1からクールダウン用の液化ガスや気化ガスの供給を受けてもよい。
The cool down according to the present embodiment is typically performed, for example, after construction of the storage tank 1, after construction of liquefied gas storage equipment such as a ship in which the storage tank 1 is installed, or after the construction of the equipment or the storage tank 1. Maintenance is carried out after warming up the storage tank 1 and before loading it again. However, the cool-down method according to the present embodiment is also applied when carrying out an empty voyage (ballast voyage) after unloading the liquefied gas in the storage tank 1 when the storage tank 1 is installed on a ship. be able to. That is, during a ballast voyage, the temperature of the inner tank 3 may gradually rise, and in that case, the above-mentioned cool-down method can be applied. In addition, when cooling down the storage tank 1 during a ballast voyage, for example, the liquefied gas left in the inner tank 3 for cooling down without unloading is used to cool down the pumps etc. installed in the inner tank 3. A feeding device transports the liquefied gas to the top of the tank for cooling down. When a plurality of storage tanks 1 are installed, liquefied gas or vaporized gas for cooling down may be supplied from other storage tanks 1.
次に、本実施形態に係る、貯蔵タンク1のウォームアップ方法について、以下に詳細に説明する。
Next, a method for warming up the storage tank 1 according to the present embodiment will be described in detail below.
本実施形態では、貯蔵タンク1から液化水素が排出され、図3Aに示すウォームアップを開始する時点での初期状態の貯蔵タンク1において、連通路11の開閉弁19を閉じた状態とされている。内槽内空間7には、例えば、大気圧よりも若干高圧、例えば5kPaG下で凝固点である20K程度の温度の水素ガスが存在している。内外槽間空間9には、定常運用状態である、例えば、大気圧よりも若干低圧である-10kPaG下で110K程度の温度の水素ガスが存在している。もっとも、初期状態の水素ガスの温度および圧力の値は上記の例に限定されない。この状態から、同図に示すように、噴霧器29を用いて、内槽内空間7に、加熱用の水素ガス(以下、「第1加熱用ガス」と呼ぶ。)HG1を供給する。噴霧器29ではなく、内槽3に接続される他のライン、例えば、液化ガスを貯蔵タンク1に供給するために設けられているラインを用いて第1加熱用ガスを供給してもよい。
In this embodiment, liquefied hydrogen is discharged from the storage tank 1, and the on-off valve 19 of the communication passage 11 is in a closed state in the storage tank 1 in an initial state at the time of starting the warm-up shown in FIG. 3A. . For example, hydrogen gas exists in the inner tank space 7 at a pressure slightly higher than atmospheric pressure, for example, at a temperature of about 20 K, which is the freezing point, under 5 kPaG. In the space 9 between the inner and outer tanks, hydrogen gas exists at a temperature of about 110 K under a steady operating state, for example, at a pressure of -10 kPaG, which is slightly lower than atmospheric pressure. However, the temperature and pressure values of the hydrogen gas in the initial state are not limited to the above example. From this state, as shown in the figure, heating hydrogen gas (hereinafter referred to as "first heating gas") HG1 is supplied to the inner tank space 7 using the sprayer 29. Instead of the atomizer 29, the first heating gas may be supplied using another line connected to the inner tank 3, for example, a line provided for supplying liquefied gas to the storage tank 1.
このようにして行われるウォームアップの過程で、内槽3と外槽5の温度差が大きくなりすぎ、構成部材の熱収縮量の差が過大になる場合がある。本実施形態では、これを回避するため、内槽3の温度と、外槽5の温度とをそれぞれ測定し、内槽3の温度と外槽5の温度との温度差(以下、単に「温度差」という。)に基づいて、内槽3の温度変化速度および外槽5の温度変化速度の少なくとも一方を調整することにより温度差を所定値以下に維持する。ここでの、温度差の「所定値」は、例えば、貯蔵タンク1の通常運用終了時の温度差を基準として設定され、例えば通常運用開始時の温度差よりも大きい値、例えば150K程度である。もっとも、当該「所定値」はこの値に限定されない。
During the warm-up process performed in this manner, the temperature difference between the inner tank 3 and the outer tank 5 may become too large, and the difference in the amount of thermal contraction of the constituent members may become excessive. In this embodiment, in order to avoid this, the temperature of the inner tank 3 and the temperature of the outer tank 5 are measured respectively, and the temperature difference between the temperature of the inner tank 3 and the temperature of the outer tank 5 (hereinafter simply referred to as "temperature The temperature difference is maintained at a predetermined value or less by adjusting at least one of the temperature change rate of the inner tank 3 and the outer tank 5 based on the temperature change rate of the inner tank 3 and the outer tank 5. The "predetermined value" of the temperature difference here is set, for example, based on the temperature difference at the end of normal operation of the storage tank 1, and is, for example, a value larger than the temperature difference at the start of normal operation, for example, about 150K. . However, the "predetermined value" is not limited to this value.
温度差を所定値以下に維持する方法として、本実施形態では、図3Bに示すように、内外槽間空間9にも加熱用ガス(以下、「第2加熱用ガス」という。)HG2を供給することにより、外槽5の昇温速度を上昇させる。内外槽間空間9への第2加熱用ガスHG2の供給は、例えば、専用の加熱用ガス供給路41を介して行われる。もっとも、内外槽間空間9への第2加熱用ガスHG2の供給は、例えば水素ガス導入通路15を介して、冷却装置33をバイパスして、行ってもよい。温度差を所定値以下に維持するため、内槽内空間7への第1加熱用ガスの供給速度および内外槽間空間9への第2加熱用ガスHG2の供給速度の少なくともいずれか一方を調整する。
As a method for maintaining the temperature difference below a predetermined value, in this embodiment, as shown in FIG. 3B, heating gas (hereinafter referred to as "second heating gas") HG2 is also supplied to the space 9 between the inner and outer tanks. By doing so, the temperature increase rate of the outer tank 5 is increased. The second heating gas HG2 is supplied to the space 9 between the inner and outer tanks, for example, via a dedicated heating gas supply path 41. However, the second heating gas HG2 may be supplied to the space 9 between the inner and outer tanks, for example, via the hydrogen gas introduction passage 15, bypassing the cooling device 33. In order to maintain the temperature difference below a predetermined value, at least one of the supply speed of the first heating gas to the inner tank inner space 7 and the supply speed of the second heating gas HG2 to the inner and outer tank space 9 is adjusted. do.
ウォームアップにおいて内槽3および外槽5の各々の温度を測定する箇所は、上述したクールダウンの場合と同様である。すなわち、例えば、各槽3,5の代表温度を検知可能な所定の箇所、各槽3,5の他の部材との接続箇所、各槽3,5に接する内方空間である内槽内空間7,内外槽間空間9の温度を測定することができる。
The locations at which the temperatures of each of the inner tank 3 and outer tank 5 are measured during warm-up are the same as in the case of cool-down described above. That is, for example, a predetermined location where the representative temperature of each tank 3, 5 can be detected, a connection location of each tank 3, 5 with other members, and an inner tank space that is an inner space in contact with each tank 3, 5. 7. The temperature of the space 9 between the inner and outer tanks can be measured.
なお、内外槽間空間9への第2加熱用ガスHG2の供給は、内槽3の温度が所定値以上まで上昇した後に行うことが好ましい。ここでの内槽3温度の「所定値」は、内外槽間空間9において水素ガス凝縮の可能性がない温度を意味する。
Note that the second heating gas HG2 is preferably supplied to the space 9 between the inner and outer tanks after the temperature of the inner tank 3 rises to a predetermined value or higher. The "predetermined value" of the temperature of the inner tank 3 here means a temperature at which there is no possibility of hydrogen gas condensing in the space 9 between the inner and outer tanks.
このように、内槽3を第1加熱用ガスHG1で加熱しながら、第2加熱用ガスHG2を内外槽間空間9に供給することにより、内外槽間空間9および外槽5の温度上昇も促進されるので、単に内槽3のみを加熱する場合に比べて貯蔵タンク1全体のウォームアップに要する時間を短縮し、コストを抑制することができる。さらに、内槽3と外槽5の温度差を所定値以下に維持することにより、構成部材の熱収縮量差を抑制することができる。
In this way, by supplying the second heating gas HG2 to the space 9 between the inner and outer tanks while heating the inner tank 3 with the first heating gas HG1, the temperature of the space 9 between the inner and outer tanks and the outer tank 5 can also be increased. Therefore, compared to the case where only the inner tank 3 is heated, the time required to warm up the entire storage tank 1 can be shortened and costs can be suppressed. Furthermore, by maintaining the temperature difference between the inner tank 3 and the outer tank 5 below a predetermined value, it is possible to suppress the difference in the amount of thermal contraction of the constituent members.
なお、図1には、貯蔵タンク1の一例として、船体とは独立に形成される独立型の二重殻タンクを示したが、本実施形態に係るクールダウン方法およびウォームアップ方法は、この例に限定されず、いかなるタイプの貯蔵タンクにも適用することができる。例えば、本実施形態に係るクールダウン方法およびウォームアップ方法は、船体と一体に形成されるタイプの貯蔵タンクにも適用することができる。また、貯蔵タンクの多重構造は、三重構造以上であってよく、そのような多重構造の内槽内空間と他の任意の槽間空間とに本実施形態に係るクールダウン方法およびウォームアップ方法を適用することができる。
Note that although FIG. 1 shows an independent double-shell tank formed independently of the ship's hull as an example of the storage tank 1, the cool-down method and warm-up method according to this embodiment are based on this example. It is not limited to, but can be applied to any type of storage tank. For example, the cool-down method and warm-up method according to this embodiment can also be applied to a type of storage tank that is formed integrally with the hull. Moreover, the multiple structure of the storage tank may be a triple structure or more, and the cool-down method and warm-up method according to the present embodiment may be applied to the internal tank space and any other inter-tank space of such a multiple structure. Can be applied.
以上説明した本実施形態に係るクールダウン方法によれば、図2Bに示すように、内槽3を冷却用水素CHで冷却しながら、冷却ガスCGを内外槽間空間9に供給することなどによって内槽3と外槽5の温度差を所定値以下に維持することにより、構成部材間で生じる熱収縮量差に起因する応力の発生を抑制するとともに、クールダウンに要する時間を短縮し、コストを抑制することができる。
According to the cool-down method according to the present embodiment described above, as shown in FIG. 2B, while cooling the inner tank 3 with cooling hydrogen CH, cooling gas CG is supplied to the space 9 between the inner and outer tanks. By maintaining the temperature difference between the inner tank 3 and the outer tank 5 below a predetermined value, it is possible to suppress the generation of stress caused by the difference in the amount of thermal contraction that occurs between the constituent members, reduce the time required for cool-down, and reduce costs. can be suppressed.
本実施形態に係るクールダウン方法において、内槽3の温度変化速度の調整を、内槽3への冷却用液化水素CHの導入速度を低下させることにより行ってもよい。また、外槽5の温度変化速度の調整を、内外槽間空間9への冷却ガス供給速度を上昇させることにより行ってもよい。この構成によれば、簡易な構造で温度差の調整を行うことができる。
In the cool-down method according to the present embodiment, the rate of temperature change in the inner tank 3 may be adjusted by reducing the rate of introduction of cooling liquefied hydrogen CH into the inner tank 3. Further, the temperature change rate of the outer tank 5 may be adjusted by increasing the cooling gas supply rate to the space 9 between the inner and outer tanks. According to this configuration, the temperature difference can be adjusted with a simple structure.
本実施形態に係るクールダウン方法において、内槽3の温度および外槽5の温度の測定は、内槽3および外槽5の各代表温度を検知可能な所定の箇所の温度を測定することにより行ってもよい。この構成によれば、高精度に温度差の調整を行うことができる。
In the cool-down method according to the present embodiment, the temperature of the inner tank 3 and the temperature of the outer tank 5 are measured by measuring the temperature at a predetermined location where each representative temperature of the inner tank 3 and the outer tank 5 can be detected. You may go. According to this configuration, the temperature difference can be adjusted with high precision.
本実施形態に係るクールダウン方法において、内槽3の温度および外槽5の温度の測定は、内槽3および外槽5における他の部材との各接続箇所の温度を測定することによって行ってもよい。この構成によれば、温度差の調整によって、内槽3,外槽5と他の部材との接続状態を効果的に維持することができる。
In the cool-down method according to the present embodiment, the temperature of the inner tank 3 and the temperature of the outer tank 5 are measured by measuring the temperature of each connection point with other members in the inner tank 3 and the outer tank 5. Good too. According to this configuration, the state of connection between the inner tank 3, outer tank 5, and other members can be effectively maintained by adjusting the temperature difference.
本実施形態に係るクールダウン方法において、内槽3の温度および外槽5の温度の測定は、内槽内空間7および内外槽間空間9の温度を測定することによって行ってもよい。この構成によれば、貯蔵タンク1の定常運転に使用される温度測定箇所を利用できるので、測定装置等の追加が不要となる。
In the cool-down method according to the present embodiment, the temperature of the inner tank 3 and the temperature of the outer tank 5 may be measured by measuring the temperature of the inner tank space 7 and the space 9 between the inner and outer tanks. According to this configuration, the temperature measurement location used for steady operation of the storage tank 1 can be used, so there is no need to add a measurement device or the like.
本実施形態に係るウォームアップ方法によれば、内槽3を第1加熱用ガスHG1で加熱しながら、第2加熱用ガスHG2を内外槽間空間9に供給することなどによって内槽3と外槽5の温度差を所定値以下に維持することにより、構成部材の熱収縮量差を抑制するとともに、ウォームアップに要する時間を短縮し、コストを抑制することができる。
According to the warm-up method according to the present embodiment, the inner tank 3 and the outer tank are heated by supplying the second heating gas HG2 to the space 9 between the inner and outer tanks while heating the inner tank 3 with the first heating gas HG1. By maintaining the temperature difference in the tank 5 below a predetermined value, it is possible to suppress the difference in the amount of thermal contraction of the constituent members, shorten the time required for warm-up, and suppress costs.
以上のとおり、図面を参照しながら本開示の好適な実施形態を説明したが、本開示の趣旨を逸脱しない範囲内で、種々の追加、変更または削除が可能である。したがって、そのようなものも本開示の範囲内に含まれる。
As described above, the preferred embodiments of the present disclosure have been described with reference to the drawings, but various additions, changes, or deletions can be made without departing from the spirit of the present disclosure. Accordingly, such are also included within the scope of this disclosure.
1 液化ガス貯蔵タンク
3 内槽
5 外槽
7 内槽内空間
9 内外槽間空間
11 連通路
29 噴霧器
33 冷却装置
CG 冷却ガス
CH 冷却用液化ガス
G1 気化ガス
G2 外部水素ガス
HG1 第1加熱用ガス
HG2 第2加熱用ガス 1 Liquefiedgas storage tank 3 Inner tank 5 Outer tank 7 Inner tank space 9 Space between the inner and outer tanks 11 Communication path 29 Sprayer 33 Cooling device CG Cooling gas CH Cooling liquefied gas G1 Vaporized gas G2 External hydrogen gas HG1 First heating gas HG2 Second heating gas
3 内槽
5 外槽
7 内槽内空間
9 内外槽間空間
11 連通路
29 噴霧器
33 冷却装置
CG 冷却ガス
CH 冷却用液化ガス
G1 気化ガス
G2 外部水素ガス
HG1 第1加熱用ガス
HG2 第2加熱用ガス 1 Liquefied
Claims (7)
- 液化ガスを貯蔵するための、内槽および外槽を備えるタンクを、貯蔵対象である前記液化ガスを充填する前に冷却する方法であって、
内槽内空間に、冷却用液化ガスを導入することと、
前記内槽の温度と、前記外槽の温度とをそれぞれ測定することと、
前記内槽の温度と前記外槽の温度との温度差に基づいて、前記内槽の温度変化速度および前記外槽の温度変化速度の少なくとも一方を調整することにより温度差を所定値以下に維持することと、
を含む、
液化ガス貯蔵タンクのクールダウン方法。 A method for cooling a tank including an inner tank and an outer tank for storing liquefied gas before filling it with the liquefied gas to be stored, the method comprising:
Introducing a cooling liquefied gas into the inner tank space;
Measuring the temperature of the inner tank and the temperature of the outer tank, respectively;
Based on the temperature difference between the temperature of the inner tank and the temperature of the outer tank, the temperature difference is maintained at a predetermined value or less by adjusting at least one of the temperature change rate of the inner tank and the temperature change rate of the outer tank. to do and
including,
How to cool down a liquefied gas storage tank. - 請求項1に記載のクールダウン方法において、
前記内槽の温度変化速度および前記外槽の温度変化速度の少なくとも一方を調整することが、
前記内槽内空間への前記冷却用液化ガスの導入速度を調整することを含む
クールダウン方法。 The cool-down method according to claim 1,
Adjusting at least one of the temperature change rate of the inner tank and the temperature change rate of the outer tank,
A cool-down method comprising adjusting the introduction speed of the cooling liquefied gas into the inner tank space. - 請求項1または2に記載のクールダウン方法において、
前記内槽の温度変化速度および前記外槽の温度変化速度の少なくとも一方を調整することが、
内外槽間空間への冷却ガス供給速度を調整することを含む、
クールダウン方法。 The cool-down method according to claim 1 or 2,
Adjusting at least one of the temperature change rate of the inner tank and the temperature change rate of the outer tank,
including adjusting the cooling gas supply rate to the space between the inner and outer tanks;
How to cool down. - 請求項1から3のいずれか一項に記載のクールダウン方法において、
前記内槽の温度と前記外槽の温度とをそれぞれ測定することが、
前記内槽の代表温度を検知可能な所定の箇所の温度を測定すること
前記外槽の代表温度を検知可能な所定の箇所の温度を測定すること
を含む、
クールダウン方法。 The cool-down method according to any one of claims 1 to 3,
Measuring the temperature of the inner tank and the temperature of the outer tank,
Measuring the temperature at a predetermined location where the representative temperature of the inner tank can be detected; Measuring the temperature at a predetermined location where the representative temperature of the outer tank can be detected;
How to cool down. - 請求項1から4のいずれか一項に記載のクールダウン方法において、
前記内槽の温度と前記外槽の温度とをそれぞれ測定することが、
前記内槽における他の部材との接続箇所の温度を測定することと、
前記外槽における他の部材との接続箇所の温度を測定することと、
を含む
クールダウン方法。 The cool-down method according to any one of claims 1 to 4,
Measuring the temperature of the inner tank and the temperature of the outer tank,
Measuring the temperature of a connection point with other members in the inner tank;
Measuring the temperature of a connection point with other members in the outer tank;
Cool down methods including. - 請求項1から5のいずれか一項に記載のクールダウン方法において、
前記内槽の温度と前記外槽の温度とをそれぞれ測定することが、
前記内槽内空間の温度を測定することと、
内外槽間空間の温度を測定することと、
を含む
クールダウン方法。 The cool-down method according to any one of claims 1 to 5,
Measuring the temperature of the inner tank and the temperature of the outer tank,
Measuring the temperature of the inner tank space;
Measuring the temperature of the space between the inner and outer tanks;
Cool down methods including. - 液化ガスを貯蔵するための、内槽および外槽を備えるタンクを、貯蔵対象である前記液化ガスを排出した後に加熱する方法であって、
内槽内空間に、第1加熱用ガスを導入することと、
前記内槽の温度と、前記外槽の温度とをそれぞれ測定することと、
前記内槽の温度と前記外槽の温度との温度差に基づいて、前記内槽の温度変化速度および前記外槽の温度変化速度の少なくとも一方を調整することにより温度差を所定値以下に維持することと、
を含む、
液化ガス貯蔵タンクのウォームアップ方法。 A method for heating a tank for storing liquefied gas, including an inner tank and an outer tank, after discharging the liquefied gas to be stored, the method comprising:
Introducing a first heating gas into the inner tank space;
Measuring the temperature of the inner tank and the temperature of the outer tank, respectively;
Based on the temperature difference between the temperature of the inner tank and the temperature of the outer tank, the temperature difference is maintained at a predetermined value or less by adjusting at least one of the temperature change rate of the inner tank and the temperature change rate of the outer tank. to do and
including,
How to warm up a liquefied gas storage tank.
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