WO2023145306A1 - Hair and/or skin composition, method for treating hair and/or skin, and device for hair and/or skin - Google Patents

Hair and/or skin composition, method for treating hair and/or skin, and device for hair and/or skin Download PDF

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Publication number
WO2023145306A1
WO2023145306A1 PCT/JP2022/046820 JP2022046820W WO2023145306A1 WO 2023145306 A1 WO2023145306 A1 WO 2023145306A1 JP 2022046820 W JP2022046820 W JP 2022046820W WO 2023145306 A1 WO2023145306 A1 WO 2023145306A1
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Prior art keywords
composition
hair
skin
mass
mist
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PCT/JP2022/046820
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French (fr)
Japanese (ja)
Inventor
亮 井口
雄介 瀧野
寛歳 追風
Original Assignee
株式会社ミルボン
パナソニックホールディングス株式会社
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Priority claimed from JP2022159767A external-priority patent/JP2023111819A/en
Application filed by 株式会社ミルボン, パナソニックホールディングス株式会社 filed Critical 株式会社ミルボン
Publication of WO2023145306A1 publication Critical patent/WO2023145306A1/en

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    • AHUMAN NECESSITIES
    • A45HAND OR TRAVELLING ARTICLES
    • A45DHAIRDRESSING OR SHAVING EQUIPMENT; EQUIPMENT FOR COSMETICS OR COSMETIC TREATMENTS, e.g. FOR MANICURING OR PEDICURING
    • A45D20/00Hair drying devices; Accessories therefor
    • A45D20/04Hot-air producers
    • A45D20/08Hot-air producers heated electrically
    • A45D20/10Hand-held drying devices, e.g. air douches
    • A45D20/12Details thereof or accessories therefor, e.g. nozzles, stands
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/02Cosmetics or similar toiletry preparations characterised by special physical form
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/02Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/04Dispersions; Emulsions
    • A61K8/06Emulsions
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/31Hydrocarbons
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/34Alcohols
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/37Esters of carboxylic acids
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89Polysiloxanes
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/92Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00Preparations for care of the skin
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00Preparations for care of the hair

Definitions

  • the present invention provides a composition for hair and/or skin containing an oily component and the like, which is used by applying it to the surface of hair and/or skin in the form of a mist, a method for treating hair and/or skin, and a composition for hair and/or skin. and/or skin devices.
  • a non-aqueous composition for skin or hair containing an ultraviolet absorber and a liquid hydrocarbon has a quaternary ammonium group-containing group.
  • a containerized liquid cosmetic for spraying containing hyaluronic acid and/or a salt thereof having a degree of cationization of 0.15 to 0.6 see Patent Document 2.
  • Patent Document 3 discloses a method of using a hair care device having a mist generating portion as a different coating method from Patent Documents 1 and 2 (see paragraph 0023, etc.).
  • the uniform application of the composition to the hair and skin is a factor in improving the uniformity of the expected action and effect of the composition.
  • the application tends to be localized with an awareness of the application site.
  • the action and effect of the composition are generally more likely to be exhibited by components that do not evaporate. is easy to manifest.
  • the present invention provides a composition for hair and/or skin that can realize highly uniform application even if the blending amount of components that generally exert their actions and effects is increased. and a hair and/or skin device comprising the same composition.
  • the present invention is as follows [1] to [9].
  • composition A composition for hair and/or skin that has an evaporation residue of 1.0% by mass or more after being left at 50° C. for 24 hours, and is discharged from a device having a blowing unit that generates an air flow.
  • hair and/or skin composition may be simply referred to as “composition”
  • the airflow has the effect of detangling the hair.
  • the composition in the form of mist can be easily applied not only to the surface of the hair that can be observed from the outside in a stationary state, but also to the other surfaces of the hair.
  • composition according to [1] or [2] above which has a viscosity of 200 mPa ⁇ s or less.
  • the discharged composition according to [3] can be atomized efficiently and easily.
  • the viscosity refers to a value obtained by measuring the liquid composition, not the mist composition (hereinafter the same).
  • composition according to any one of [1] to [3], containing a nonionic surfactant. Addition of a nonionic surfactant to the composition is suitable for improving the smooth feel of the hair.
  • the composition can be easily discharged in the form of a mist.
  • the blending amount refers to the blending amount of the composition in a liquid form, not in a mist form (the same shall apply hereinafter).
  • composition for hair and/or skin contains a nonionic surfactant.
  • the hair and/or skin composition contains a liquid oily component as an evaporation residue, and the amount of the liquid oily component is 1.0% by mass or more.
  • the device according to any one of [10] to [14].
  • composition for hair and/or skin contains one or more selected from among hydrocarbons, waxes, ester oils, fats and oils, higher alcohols, and silicones, as the component to be the evaporation residue.
  • the above hair and/or skin composition is an oil-in-water emulsion composition, a water-in-oil emulsion composition, or a non-aqueous composition containing two or more oily components.
  • the device according to any one of [10] to [16].
  • [18] A method for treating hair and/or skin using the device according to any one of [10] to [17].
  • the composition for hair and/or skin according to the present invention is discharged in the form of a mist and is dispersed by an air flow, so that highly uniform application is possible and the evaporation residue is 1.0. Since it is mass % or more, the action and effect of the component are enhanced.
  • the mist composition is discharged together with the air flow sent out from the air blowing section, so that the composition is more diffused and uniform in the air flow.
  • the evaporation residue of the composition is 1.0% by mass or more, the actions and effects of the components are enhanced.
  • the misty composition discharged from the mist generating part is diffused by the airflow sent out from the air blowing part, so that the composition can be applied with high uniformity. Moreover, since the evaporation residue of the composition is 1.0% by mass or more, the actions and effects of the components are enhanced.
  • the mist composition since the mist composition is discharged together with the airflow sent out from the air blower, the composition can be more easily absorbed in the airflow. Since the composition can be diffused and applied with high uniformity, and the evaporation residue of the composition is 1.0% by mass or more, the actions and effects of the components are enhanced.
  • FIG. 1 is a side view of an example of a device according to the invention
  • FIG. 2 is a cross-sectional view of the device of FIG. 1
  • FIG. FIG. 2 is a block diagram showing the electrical connections of the device of FIG. 1
  • Schematic diagram for explaining the diffusion of the mist composition Images for explaining the state of application to the water sensitivity test paper of Example 3 and Comparative Example 3.
  • FIG. Images for explaining the coating uniformity of Reference Examples 1 and 2.
  • the present invention will be described below based on the embodiments of the present invention.
  • the composition of the present embodiment has a predetermined amount or more of evaporation residue and is discharged in the form of a mist from a specific device.
  • the evaporation residue in the composition of the present embodiment is preferably 1.0% by mass or more and 90% by mass or less, preferably 2.0% by mass or more and 50% by mass or less, and more preferably 3.0% by mass or more and 40% by mass or less. It is preferably 4.0% by mass or more and 35% by mass or less, and even more preferably 5.0% by mass or more and 30% by mass or less.
  • the action and effect of the component such as imparting a feeling to the touch, are easily exerted, and when it is 90% by mass or less, it is suitable for suppressing excessive action and effect by the same component. is.
  • the above-mentioned “evaporation residue” is the remaining amount after the composition is left in a constant temperature bath set at 50 ° C. for 24 hours, (mass of the composition after standing in the constant temperature bath) / (constant temperature It is a value calculated by multiplying the mass of the composition before being left in the bath) ⁇ 100.
  • the composition of the present embodiment contains an oily component that becomes an evaporation residue, an oily component that does not remain after evaporation, or an oily component that becomes an evaporation residue and an evaporation It is good if it contains an oily component that does not leave a residue behind.
  • the oily component is one or more selected from hydrocarbons, waxes, ester oils, fats and oils, higher alcohols, and silicones.
  • hydrocarbon one or more selected from known hydrocarbons can be blended. Also, hydrocarbons that are liquid at 25°C and/or hydrocarbons that are solid at 25°C can be blended.
  • hydrocarbons include hydrogenated polyisobutene, isododecane, (C13-15) alkane, liquid paraffin, squalane, pristane, ozokerite, paraffin, ceresin, petrolatum, and microcrystalline wax.
  • the above waxes are classified as esters derived from natural products, and generally correspond to esters of fatty acids and water-insoluble higher monohydric alcohols or dihydric alcohols.
  • wax When wax is blended, one or more selected from known waxes can be blended.
  • the wax include beeswax, Japanese wax, jojoba oil, candelilla wax, rice bran wax, carnauba wax, and sunflower seed wax.
  • the above ester oil is classified as an ester obtained by synthesis.
  • an ester oil one or more selected from known ester oils can be blended.
  • an ester oil that is liquid at 25°C and/or an ester oil that is solid at 25°C can be blended.
  • ester oils include ethyl oleate, oleyl oleate, isopropyl myristate, isopropyl palmitate, butyl stearate, cetyl palmitate, myristyl myristate, octyldodecyl myristate, isopropyl isostearate, ethyl isostearate, 2-ethyl Cetyl hexanoate, hexyl isostearate, ethylene glycol di-2-ethylhexanoate, ethylene glycol dioleate, propylene glycol di(capryl-caprate), propylene glycol dioleate, trimethylolpropane triisostearate, tetra-2-ethylhexanoic acid pentaerythritol, isocetyl isostearate, 2-octyldodecyl dimethyloctanoate, myristyl lactate,
  • Fats and oils are mainly composed of triesters of fatty acids and glycerin.
  • fats and oils When blending fats and oils, one or more selected from known fats and oils can be blended.
  • fats and oils that are liquid at 25°C and/or fats and oils that are solid at 25°C can be blended.
  • the oils include almond oil, avocado oil, apricot kernel oil, olive oil, rice bran oil, shea butter, shea butter oil, evening primrose oil, passionflower seed oil, camellia oil, babassu oil, peanut oil, sunflower seed oil, rose hip oil.
  • a higher alcohol is a monohydric alcohol with 12 or more carbon atoms.
  • a higher alcohol one or more selected from known higher alcohols can be blended.
  • a higher alcohol that is liquid at 25°C and/or a higher alcohol that is solid at 25°C can be blended.
  • higher alcohols include lauryl alcohol, myristyl alcohol, cetyl alcohol, stearyl alcohol, behenyl alcohol, octyldodecanol, isostearyl alcohol, and oleyl alcohol.
  • silicone When blending silicone, one or more selected from known silicones can be blended.
  • the silicone include dimethyl silicone (methylpolysiloxane, highly polymerized methylpolysiloxane, etc.), methylphenyl silicone, cyclic silicone (octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, etc.), amino-modified silicone (aminoethylamino propylsiloxane/dimethylsiloxane copolymer, aminoethylaminopropylmethylsiloxane/dimethylsiloxane copolymer, etc.), long-chain alkyl-modified silicones, and dimethiconol.
  • dimethyl silicone methylpolysiloxane, highly polymerized methylpolysiloxane, etc.
  • methylphenyl silicone methylphenyl silicone
  • cyclic silicone octamethylcyclotetrasiloxane, de
  • an oily component that becomes an evaporation residue in the composition of the present embodiment one or more selected from hydrocarbons, waxes, ester oils, fats, higher alcohols, and silicones that correspond to the evaporation residue. to be blended.
  • the amount of the oily component that becomes the evaporation residue in the composition of the present embodiment is preferably 1.0% by mass or more and 50% by mass or less, preferably 2.0% by mass or more and 40% by mass or less, and 3.0% by mass. 30 mass % or less is more preferable, 4.0 mass % or more and 15 mass % or less is still more preferable, and 5.0 mass % or more and 10 mass % or less is still more preferable.
  • the amount is 1.0% by mass or more, the action and effect of the component, such as imparting a feeling to the touch, are easily exerted, and when the amount is 50% by mass or less, it is suitable for suppressing the excessive action and effect of the same component. is.
  • blending a liquid oily component as an evaporation residue component in the composition of the present embodiment is suitable for improving the smoothness of the hair and skin surface.
  • the amount of the liquid oil component in the composition of the present embodiment is preferably 1.0% by mass or more and 50% by mass or less, preferably 2.0% by mass or more and 40% by mass or less, and 3.0% by mass or more and 30% by mass. The following is more preferable, 4.0 to 15 mass % is still more preferable, and 5.0 to 10 mass % is even more preferable.
  • the blending amount is 1.0% by mass or more, the action and effect of the component, such as imparting a feeling to the touch, are easily exerted. be.
  • the composition of the present embodiment may be appropriately blended with a known surfactant.
  • a known surfactant polyhydric alcohols, saccharides, polymer compounds, amino acids, animal and plant extracts, inorganic compounds, fragrances, preservatives, sequestering agents, ultraviolet absorbers, thickeners, and the like, known hair compositions and known skin You may mix
  • the composition of the present embodiment preferably does not contain solid particles in order to make the hair and skin feel smooth.
  • Nonionic surfactant is suitable for improving the smooth feel of hair.
  • This nonionic surfactant is preferably one or more selected from known nonionic surfactants blended in hair and/or skin compositions.
  • Nonionic surfactants include, for example, polyoxyethylene alkyl ethers, polyoxyethylene polyoxypropylene alkyl ethers, polyoxyethylene fatty acid esters, polyoxyethylene sorbitan fatty acid esters, polyoxyethylene curing castor oil, polyoxyethylene sorbitol tetra-fatty acid ester, glycerin fatty acid ester, alkyl glucoside, sorbitan fatty acid ester, polyglycerin fatty acid ester, polyoxyethylene glycerin fatty acid ester, sucrose fatty acid ester, and alkylalkanolamide.
  • the amount of the nonionic surfactant in the composition of the present embodiment is preferably 0.1% by mass or more and 15% by mass or less, preferably 0.5% by mass or more and 10% by mass or less, and 1% by mass or more and 8% by mass or less. is more preferable, and 2% by mass or more and 6% by mass or less is even more preferable.
  • a blending amount of 0.1% by mass or more is suitable for improving the smooth feeling of the hair, and a blending amount of 10% by mass or less is suitable when setting the viscosity of the composition to be low.
  • the dosage form of the composition of the present embodiment is a liquid that facilitates ejection of the composition in the form of a mist.
  • the viscosity of the liquid composition of the present embodiment is, for example, 200 mPa s or less, preferably 100 mPa s or less, preferably 70 mPa s or less, more preferably 50 mPa s or less, and further preferably 30 mPa s or less. It is preferably 10 mPa ⁇ s or less, and more preferably 10 mPa ⁇ s or less (in order to reduce the viscosity, for example, the amount of solid components or relatively highly viscous components blended in the composition of the present embodiment may be reduced).
  • the composition of the present embodiment can be easily and efficiently finely divided into a mist, and is also suitable for imparting a smooth feel to hair and skin surfaces.
  • the viscosity was measured using a rheometer "Thermo Scientific HAAKE MARS 40" manufactured by Thermo Fisher Scientific Co., Ltd. in steady flow curve mode, shear rate (d ⁇ /dt) 50 s -1 , cone plate sensor (diameter 35 mm, The value of ⁇ (mPa ⁇ s) was adopted under the conditions of an inclination angle of 2°) and a temperature of 25°C.
  • the composition of the present embodiment includes, for example, an oil-in-water emulsion composition in which an oily component is dispersed with a surfactant, a water-in-oil emulsion composition in which an aqueous component is dispersed with a surfactant, two or more kinds of oily Examples include non-aqueous compositions in which ingredients are blended.
  • the amount of water to be blended is preferably 50% by mass or more, preferably 60% by mass or more, when the viscosity of the composition is to be kept low. 70% by mass or more is more preferable, and 75% by mass or more is even more preferable.
  • the non-aqueous composition refers to a composition that does not correspond to a water-in-oil emulsion composition and contains less than 0.5% by mass of water or does not contain water.
  • FIGS. 1 to 3 show an apparatus according to the present embodiment for ejecting the composition in the form of a mist when using the composition according to the present embodiment, which is an example of the apparatus according to the present invention.
  • FIG. 1 is a side view of the device of this embodiment.
  • the device 10 can continuously generate an air flow and can continuously spray the composition of the present embodiment in the form of a mist. mentioned.).
  • the term “continuously” for spraying in the form of a mist means 1 second or more, 5 seconds or more, 10 seconds or more, 30 seconds or more, 1 minute or more, 3 minutes or more, 5 minutes or more, or 10 minutes or more. It is meant to last for hours, unlike spraying from a pump-type container where the dispensing ends instantly.
  • the device 10 comprises a housing 11 that constitutes the appearance of the device 10 and accommodates a plurality of elements, a grip portion 12 that has an operation portion 40 and is gripped by a user, and a power line 61 for supplying power.
  • the housing 11 and the grip portion 12 are preferably connected so that the position of the housing 11 with respect to the grip portion 12 can be changed.
  • the housing 11 has an inlet 11A for inflow of external air and an outlet 11B for discharging the composition of the present embodiment or airflow to the outside.
  • the shape of the intake port 11A and the discharge port 11B is, for example, elliptical.
  • FIG. 2 is a cross-sectional view of the device 10 shown in FIG.
  • the housing 11 has a channel 13 in which a fluid flow is formed.
  • the flow path 13 has an appropriate hollow structure so that the air from the suction port 11A shown in FIG. 1 can be delivered to the discharge port 11B.
  • the flow path 13 includes a first flow path 13A through which air mainly passes, and a second flow path 13B through which the misty composition of the present embodiment mainly passes.
  • FIG. 3 is a block diagram showing electrical connections of the device 10 shown in FIG.
  • the device 10 has a control section 20 connected to a power line 61 for supplying power shown in FIG.
  • a mist generator 90 is further provided. These parts are preferably held inside the housing 11 as shown in FIG. 2, for example.
  • the control unit 20 is composed of an arithmetic processing unit that executes a control program.
  • the control unit 20 is configured to communicate with the operating unit 40, the air blowing unit 70, the heating unit 80, and the mist generating unit 90 wirelessly or by wire.
  • the control unit 20 starts control when an operation signal is input from the operation unit 40 .
  • the operation unit 40 outputs an operation signal to the control unit 20, for example, according to an operation by the user.
  • the operation signal includes a signal for switching ON and OFF of the control unit 20 or a signal for changing the output of at least one of the air blowing unit 70 , the heating unit 80 , and the mist generating unit 90 by the control unit 20 .
  • a part of the operation part 40 is configured to protrude outward from the housing 11 so that the user can easily operate it.
  • the operation unit 40 is composed of buttons, switches, and dials, for example.
  • blower section 70 includes motor 71 and fan 72 .
  • motor 71 By driving the motor 71 , the fan 72 rotates to generate an air flow in the flow path 13 .
  • the motor 71 is controlled by the controller 20 .
  • the device 10 of this embodiment generates a continuous airflow by maintaining the rotating state of the fan 72 .
  • Air blower 70 exists upstream of first flow path 13A and second flow path 13B in flow path 13, and supplies airflow to both first flow path 13A and second flow path 13B.
  • the heating unit 80 heats the air flow inside the housing 11 to create warm air.
  • the warm air is, for example, air within the range of 100-120°C.
  • Heating unit 80 includes a heater 81 .
  • An example of the heater 81 is a PTC (Positive Temperature Coefficient) heater and an infrared heater.
  • the heating unit 80 is provided, for example, in the first flow path 13A.
  • the controller 20 controls the output of the heater 81 .
  • the mist generator 90 mists the composition of the present embodiment and ejects it.
  • Mist generator 90 includes pump 91, tank 92, and nozzle 93 shown in FIG.
  • Pump 91 is a liquid pump that supplies the composition of the present embodiment stored in tank 92 to nozzle 93 by driving a motor (not shown) (an example of the liquid pump is a gear pump).
  • Tank 92 stores the compositions of the present embodiments within device 10 .
  • Tank 92 is constructed of known materials suitable for holding liquid compositions such as polypropylene.
  • Nozzle 93 atomizes the composition of this embodiment. In order to realize this atomization, for example, the air and the composition of the present embodiment are mixed inside the nozzle 93, and atomization is possible by shearing force during this mixing.
  • pump 91 further includes a gas pump such as a diaphragm pump.
  • the control unit 20 controls the flow rate of the composition of the present embodiment that is discharged in the form of a mist from the mist generating unit 90, and the composition of the present embodiment that is discharged in the form of a mist from the mist generating unit 90.
  • the amount of composition is controllable.
  • the amount of the composition of the present embodiment that is discharged in the form of a mist per second is preferably 0.1 mg/s or more and 100 mg/s or less, preferably 0.3 mg/s or more and 50 mg/s or less, and 0.5 mg/s.
  • the discharge amount is 100 mg/s or less, it is suitable for improving uniformity of coating, and when it is 0.1 mg/s or more, it is suitable for shortening the coating process.
  • Power is supplied to the control unit 20 by operating the operation unit 40, and power is further supplied to the pump 91, the motor 71, or the heater 81 as necessary.
  • the composition of the present embodiment is discharged from the nozzle 93 in the form of a mist, and the composition is led to the outside of the device 10 through the second flow path 13B.
  • the fan 72 operates and the airflow sent out by the fan 72 is blown out of the apparatus 10 through the first flow path 13A.
  • the particle size of the composition discharged in the form of a mist may be, for example, 20 ⁇ m or more and 200 ⁇ m or less.
  • the particle size refers to a volume average particle size measured by a laser diffraction scattering method.
  • FIG. 4 is a schematic diagram for explaining the diffusion of the composition of the present embodiment (fog composition M) in the form of a mist (the mist composition in FIG. 4 is shown in a circular shape).
  • the misty composition M discharged from the second flow path 13B is attracted to the air flow A sent out from the first flow path 13A and spreads.
  • the air flow A sent out from the first flow path 13A is suppressed, and highly uniform application becomes possible.
  • the air is heated by the heater 81 of FIG. 2, it is possible to apply the composition of the present embodiment and dry the same composition at the same time.
  • the composition of the present embodiment can be obtained in the form of a mist.
  • a highly uniform application treatment can be achieved by applying the composition of (1) to hair, skin, or hair and skin.
  • Examples 1 and 2 Comparative Examples 1 and 2>> The hair compositions of Examples 1 and 2 and Comparative Examples 1 and 2 were produced, and after the hair was treated with these compositions, the feel and luster of the hair were evaluated. Details are as follows.
  • composition for hair Squalane, which is a non-volatile hydrocarbon, and isododecane, which is a volatile hydrocarbon, were mixed to produce non-aqueous liquid hair compositions of Comparative Examples 1 and 2 and Examples 1 and 2 having a viscosity of 100 mPa ⁇ s or less. .
  • the blending amounts during production were as shown in Table 1 below.
  • the evaporation residue was calculated based on the mass before and after leaving 10 g of the hair composition in a constant temperature bath at a set temperature of 50° C. for 24 hours.
  • Table 1 shows the components blended in the compositions of Comparative Examples 1 and 2 and Examples 1 and 2, their blending amounts, the evaluation of the feel of the hair, and the evaluation of the luster of the hair (in addition, in the two evaluations, , two evaluators gave the same evaluation).
  • Example 3 Comparative Example 3>> A panel of 152 mm x 208 mm was prepared by arranging a plurality of water sensitivity test papers (manufactured by Spraying Systems, size 52 mm x 76 mm). The panel was sprayed with the hair composition shown in Table 2 below. This coating method was as follows in Example 3 and Comparative Example 3.
  • Example 3 Warm air (temperature of about 80° C., wind speed of 20 m/s) was blown onto the panel from an apparatus having a blowing unit and a mist generating unit, and 200 mg of the misted hair composition was applied over 3 minutes. .
  • Comparative Example 3 A metered discharge mist pump manufactured by Yoshino Kogyo Co., Ltd., which discharges about 200 mg at one time, was used for application.
  • FIG. 5 is an image for explaining the state of application to the water sensitivity test paper of Example 3 and Comparative Example 3, and Table 3 below summarizes the application of Example 3 and Comparative Example 3.
  • Comparative Example 3 the coating amount in the central portion of the water sensitivity test paper panel was large.
  • Example 3 it can be confirmed that there is no bias in the amount of application to the central portion as in Comparative Example 3, and the application is highly uniform.
  • Examples 4 to 7 The hair compositions of Examples 4 to 7 shown in Table 4 below were applied in the form of a mist to bundles of hair (about 30 cm in length, 10 g in weight) that had been washed with water and towel-dried.
  • warm air temperature of about 80°C, wind speed of 20 m/s
  • 200 mg of the misted hair composition is applied. It was applied for 3 minutes.
  • particle size of the mist composition discharged from the apparatus was measured using a particle size distribution meter "AEROTRAC II" manufactured by Microtrack Bell. In this measurement, the lens used is "f100 lens", the exposure time is “10 seconds”, and the distance from the lens to the mist composition is "50 mm”. The particle size of the composition”.
  • Table 4 shows the results of evaluating the surface smoothness of the hair tresses to which the hair compositions of Examples 4 to 7 were applied.
  • Reference example 1 A device having an air blower and a mist generator blows hot air (temperature about 80°C, wind speed 20 m/s) as an air flow while combing, and applies the liquid hair composition in the form of a mist. bottom.
  • FIG. 6 is an image for explaining the coating uniformity of Reference Examples 1 and 2.
  • the extracted image of Reference Example 1 has clearly less color unevenness than the extracted image of Reference Example 2, and the coating uniformity is good. It can be confirmed that it was

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Abstract

Provided are a hair and/or skin composition, a hair and/or skin treatment method, and a device for the hair and/or skin, that can achieve a highly uniform application even when the amount of incorporation of components that commonly exert actions and effects is increased. The hair and/or skin composition has an evaporation residue of at least 1.0 mass% and is discharged in mist form from a device that has an air blowing element that produces an air current. The hair and/or skin treatment method uses a composition that has an evaporation residue of at least 1.0 mass% and that is discharged in mist form from a device that has an air blowing element that produces an air current. The device for the hair and/or skin comprises a tank that stores a composition that has a evaporation residue of at least 1.0 mass%, and a mist-generating element that discharges the composition in the tank in mist form.

Description

毛髪用及び/又は皮膚用組成物、毛髪及び/又は皮膚の処理方法、並びに、毛髪用及び/又は皮膚用装置Hair and/or skin composition, hair and/or skin treatment method and hair and/or skin device
 本発明は、毛髪及び/又は皮膚の表面に霧状にして塗布して使用される油性成分などを含む毛髪用及び/又は皮膚用組成物、毛髪及び/又は皮膚の処理方法、並びに、毛髪用及び/又は皮膚用装置に関するものである。 The present invention provides a composition for hair and/or skin containing an oily component and the like, which is used by applying it to the surface of hair and/or skin in the form of a mist, a method for treating hair and/or skin, and a composition for hair and/or skin. and/or skin devices.
 毛髪や皮膚に塗布する組成物として、例えば、紫外線吸収剤および液状炭化水素が配合された皮膚用又は毛髪用の非水系組成物(特許文献1参照)、第四級アンモニウム基含有基を有し、カチオン化度が0.15~0.6であるヒアルロン酸及び/又はその塩が配合された噴霧用容器詰め液状化粧料(特許文献2参照)が開示されている。これら開示された組成物を使用する際には、その組成物を手で直接塗布する方法、ポンプ式容器からの噴霧で塗布する方法などがとられる。また、特許文献3には、特許文献1、2とは異なる塗布方法として、ミスト発生部を有するヘアケア装置を使用する方法が開示されている(段落0023等参照)。 As a composition to be applied to hair or skin, for example, a non-aqueous composition for skin or hair containing an ultraviolet absorber and a liquid hydrocarbon (see Patent Document 1) has a quaternary ammonium group-containing group. , a containerized liquid cosmetic for spraying containing hyaluronic acid and/or a salt thereof having a degree of cationization of 0.15 to 0.6 (see Patent Document 2). These disclosed compositions can be used by directly applying the composition by hand, by spraying from a pump-type container, and the like. Further, Patent Document 3 discloses a method of using a hair care device having a mist generating portion as a different coating method from Patent Documents 1 and 2 (see paragraph 0023, etc.).
特開2021-075498号公報JP 2021-075498 A 特開2010-24207号公報JP 2010-24207 A 特開2021-132688号公報Japanese Patent Application Laid-Open No. 2021-132688
 ところで、毛髪や皮膚への均一な組成物の塗布は、期待する組成物の作用、効果の均一性向上の要素となる。しかし、手による直接塗布やポンプ式容器からの噴霧塗布を行う場合、塗布箇所を意識した局所的な塗布となり易い。また、組成物による作用、効果は一般的に蒸発しない成分が発揮し易いが、その成分の配合量を高めた場合、塗布が不均一となった場合の組成物による作用、効果の不均一性は顕在化し易い。 By the way, the uniform application of the composition to the hair and skin is a factor in improving the uniformity of the expected action and effect of the composition. However, when direct application by hand or spray application from a pump-type container is performed, the application tends to be localized with an awareness of the application site. In addition, the action and effect of the composition are generally more likely to be exhibited by components that do not evaporate. is easy to manifest.
 本発明は、上記事情に鑑み、作用、効果を発揮させるのが一般的な成分の配合量を高めても、均一性の高い塗布を実現できる毛髪用及び/又は皮膚用組成物、この組成物を使用する毛髪及び/又は皮膚の処理方法、並びに、同組成物を備えた毛髪用及び/又は皮膚用装置の提供を目的とする。 In view of the above circumstances, the present invention provides a composition for hair and/or skin that can realize highly uniform application even if the blending amount of components that generally exert their actions and effects is increased. and a hair and/or skin device comprising the same composition.
 本発明者等が鋭意検討を行った結果、所定条件における蒸発残分が1.0質量%以上、かつ、空気流を発生させる送風部を有する装置から霧状に吐出される毛髪用及び/又は皮膚用組成物であれば、その蒸発残分であっても、均一性の高い塗布を実現できる知見を得、本発明を完成するに至った。
 すなわち、本発明は、以下の[1]~[9]の通りである。
As a result of intensive studies by the present inventors, it has been found that the evaporation residue under predetermined conditions is 1.0% by mass or more, and for hair that is discharged in the form of a mist from a device having an air blower that generates an air flow and / or As long as it is a composition for skin, even if it is an evaporation residue, it is possible to realize highly uniform application, which led to the completion of the present invention.
That is, the present invention is as follows [1] to [9].
 [1]50℃で24時間放置した後の蒸発残分が1.0質量%以上であり、空気流を発生させる送風部を有する装置から吐出させた霧状の毛髪用及び/又は皮膚用組成物(以下、「毛髪用及び/又は皮膚用組成物」を単に「組成物」と称することがある。)。[1]に係る組成物を毛髪用に使用すれば、空気流が毛髪を解きほぐす作用を有する。その結果、静止状態で外部観察可能な毛髪表面だけではなく、他の毛髪表面にまで霧状の組成物が行き届き易くなるから、毛髪全体に対して均一性の高い塗布が可能となる。 [1] A composition for hair and/or skin that has an evaporation residue of 1.0% by mass or more after being left at 50° C. for 24 hours, and is discharged from a device having a blowing unit that generates an air flow. (hereinafter, "hair and/or skin composition" may be simply referred to as "composition"). When the composition according to [1] is used for hair, the airflow has the effect of detangling the hair. As a result, the composition in the form of mist can be easily applied not only to the surface of the hair that can be observed from the outside in a stationary state, but also to the other surfaces of the hair.
 [2]前記吐出における吐出量が100mg/s以下である前記[1]に記載の毛髪用及び/又は皮膚用組成物。[2]に係る組成物であれば、より均一性の高い塗布を実現できる。 [2] The composition for hair and/or skin according to [1], wherein the ejection amount in the ejection is 100 mg/s or less. With the composition according to [2], more uniform application can be achieved.
 [3]粘度が200mPa・s以下である前記[1]又は[2]に記載の組成物。当該組成物が200mPa・s以下の粘度であると、吐出される[3]に係る組成物を効率的かつ簡易に霧状にできる。
 なお、粘度は、前記組成物について、霧状ではなく液状のものを測定して得られる値をいう(以下、同様)。
[3] The composition according to [1] or [2] above, which has a viscosity of 200 mPa·s or less. When the composition has a viscosity of 200 mPa·s or less, the discharged composition according to [3] can be atomized efficiently and easily.
The viscosity refers to a value obtained by measuring the liquid composition, not the mist composition (hereinafter the same).
 [4]ノニオン界面活性剤が配合されている前記[1]から[3]のいずれかに記載の組成物。当該組成物へのノニオン界面活性剤の配合は、毛髪の滑らかな感触の向上に好適である。 [4] The composition according to any one of [1] to [3], containing a nonionic surfactant. Addition of a nonionic surfactant to the composition is suitable for improving the smooth feel of the hair.
 [5]前記ノニオン界面活性剤の配合量が15質量%以下である前記[4]に記載の組成物。当該組成物であれば、霧状に吐出させることが容易となる。
 なお、配合量は、前記組成物について、霧状ではなく液状のものにおける配合量をいう(以下、同様)。
[5] The composition according to [4], wherein the amount of the nonionic surfactant is 15% by mass or less. The composition can be easily discharged in the form of a mist.
The blending amount refers to the blending amount of the composition in a liquid form, not in a mist form (the same shall apply hereinafter).
 [6]前記蒸発残分となる成分として液状の油性成分が配合されており、前記液状の油性成分の配合量が1.0質量%以上である前記[1]から[5]のいずれかに記載の組成物。当該組成物における油性成分は、毛髪や皮膚の滑らかな感触付与に好適で、1.0質量%以上の配合により、その滑らかさがより向上する。 [6] Any one of the above [1] to [5], wherein a liquid oily component is blended as the component that becomes the evaporation residue, and the blending amount of the liquid oily component is 1.0% by mass or more. The described composition. The oily component in the composition is suitable for imparting a smooth feel to hair and skin, and the addition of 1.0% by mass or more further improves the smoothness.
 [7]前記蒸発残分となる成分として、炭化水素、ロウ、エステル油、油脂、高級アルコール、及びシリコーンから選ばれる1種又は2種以上の油性成分が配合された前記[1]から[6]のいずれかに記載の組成物。この油性成分の配合により、毛髪や皮膚の滑らかさが良好となる。 [7] The above [1] to [6] in which one or more oily components selected from hydrocarbons, waxes, ester oils, oils and fats, higher alcohols, and silicones are blended as the components that form the evaporation residue. ] The composition according to any one of the above. The blending of this oily component improves the smoothness of hair and skin.
 [8]水中油型乳化組成物、油中水型乳化組成物、又は二種以上の油性成分が配合された非水系組成物である前記[1]から[7]のいずれかに記載の組成物。 [8] The composition according to any one of [1] to [7], which is an oil-in-water emulsion composition, a water-in-oil emulsion composition, or a non-aqueous composition containing two or more oily components. thing.
 [9]前記[1]から[8]のいずれかに記載の組成物を使用する毛髪及び/又は皮膚の処理方法。 [9] A method for treating hair and/or skin using the composition according to any one of [1] to [8] above.
 [10]50℃で24時間放置した後の蒸発残分が1.0質量%以上の毛髪用及び/又は皮膚用組成物を貯蔵するタンクと、空気流を発生させる送風部と、前記組成物を霧状に吐出するミスト発生部と、を備える装置。 [10] A tank for storing a composition for hair and/or skin that has an evaporation residue of 1.0% by mass or more after being left at 50°C for 24 hours, an air blower for generating an air flow, and the composition. and a mist generator for ejecting in the form of a mist.
 [11]前記ミスト発生部からの霧状吐出における吐出量が100mg/s以下である前記[10]に記載の装置。 [11] The device according to the above [10], wherein the ejection amount in mist ejection from the mist generating section is 100 mg/s or less.
 [12]前記毛髪用及び/又は皮膚用組成物の粘度が200mPa・s以下である前記[10]又は[11]に記載の装置。 [12] The device according to [10] or [11], wherein the viscosity of the composition for hair and/or skin is 200 mPa·s or less.
 [13]前記毛髪用及び/又は皮膚用組成物において、ノニオン界面活性剤が配合されている前記[10]から[12]のいずれかに記載の装置。 [13] The device according to any one of [10] to [12], wherein the composition for hair and/or skin contains a nonionic surfactant.
 [14]前記ノニオン界面活性剤の配合量が15質量%以下である前記[13]に記載の装置。 [14] The device according to [13], wherein the amount of the nonionic surfactant is 15% by mass or less.
 [15]前記毛髪用及び/又は皮膚用組成物には、蒸発残分となる成分として液状の油性成分が配合されており、前記液状の油性成分の配合量が1.0質量%以上である前記[10]から[14]のいずれかに記載の装置。 [15] The hair and/or skin composition contains a liquid oily component as an evaporation residue, and the amount of the liquid oily component is 1.0% by mass or more. The device according to any one of [10] to [14].
 [16]前記毛髪用及び/又は皮膚用組成物には、前記蒸発残分となる成分として、炭化水素、ロウ、エステル油、油脂、高級アルコール、及びシリコーンから選ばれる1種又は2種以上の油性成分が配合されている前記[10]から[15]のいずれかに記載の装置。 [16] The composition for hair and/or skin contains one or more selected from among hydrocarbons, waxes, ester oils, fats and oils, higher alcohols, and silicones, as the component to be the evaporation residue. The device according to any one of [10] to [15] above, which contains an oily component.
 [17]前前記毛髪用及び/又は皮膚用組成物が、水中油型乳化組成物、油中水型乳化組成物、又は二種以上の油性成分が配合されている非水系組成物である前記[10]から[16]のいずれかに記載の装置。 [17] The above hair and/or skin composition is an oil-in-water emulsion composition, a water-in-oil emulsion composition, or a non-aqueous composition containing two or more oily components. The device according to any one of [10] to [16].
 [18]前記[10]から[17]のいずれかに記載の装置を使用する毛髪及び/又は皮膚の処理方法。 [18] A method for treating hair and/or skin using the device according to any one of [10] to [17].
 本発明に係る毛髪用及び/又は皮膚用組成物によれば、霧状に吐出されると共に空気流により拡散するから、均一性の高い塗布が可能となる上に、蒸発残分が1.0質量%以上であるから、その成分による作用、効果が高くなる。 According to the composition for hair and/or skin according to the present invention, the composition for hair and/or skin according to the present invention is discharged in the form of a mist and is dispersed by an air flow, so that highly uniform application is possible and the evaporation residue is 1.0. Since it is mass % or more, the action and effect of the component are enhanced.
 また、本発明に係る毛髪及び/又は皮膚の処理方法によれば、送風部から送り出される空気流と共に霧状組成物が吐出されるから、その組成物が空気流の中でより拡散して均一性の高い塗布が可能となる上に、組成物の蒸発残分が1.0質量%以上であるから、その成分による作用、効果が高くなる。 In addition, according to the method for treating hair and/or skin according to the present invention, the mist composition is discharged together with the air flow sent out from the air blowing section, so that the composition is more diffused and uniform in the air flow. In addition, since the evaporation residue of the composition is 1.0% by mass or more, the actions and effects of the components are enhanced.
 また、本発明に係る装置によれば、ミスト発生部から吐出される霧状組成物が、送風部から送り出される空気流により拡散するから、その組成物の均一性の高い塗布が可能となる上に、組成物の蒸発残分が1.0質量%以上であるから、その成分による作用、効果が高くなる。 In addition, according to the apparatus of the present invention, the misty composition discharged from the mist generating part is diffused by the airflow sent out from the air blowing part, so that the composition can be applied with high uniformity. Moreover, since the evaporation residue of the composition is 1.0% by mass or more, the actions and effects of the components are enhanced.
 また、本発明に係る装置を使用する毛髪及び/又は皮膚の処理方法によれば、送風部から送り出される空気流と共に霧状組成物が吐出されるから、その組成物が空気流の中でより拡散して均一性の高い塗布が可能となる上に、組成物の蒸発残分が1.0質量%以上であるから、その成分による作用、効果が高くなる。 In addition, according to the hair and/or skin treatment method using the device according to the present invention, since the mist composition is discharged together with the airflow sent out from the air blower, the composition can be more easily absorbed in the airflow. Since the composition can be diffused and applied with high uniformity, and the evaporation residue of the composition is 1.0% by mass or more, the actions and effects of the components are enhanced.
本発明に係る装置の一例の側面図。1 is a side view of an example of a device according to the invention; FIG. 図1の装置の断面図。2 is a cross-sectional view of the device of FIG. 1; FIG. 図1の装置の電気的な接続を示すブロック図。FIG. 2 is a block diagram showing the electrical connections of the device of FIG. 1; 霧状組成物の拡散を説明するための模式図。Schematic diagram for explaining the diffusion of the mist composition. 実施例3、比較例3の感水試験紙への塗布状態を説明するための画像。Images for explaining the state of application to the water sensitivity test paper of Example 3 and Comparative Example 3. FIG. 参考例1~2の塗布均一性を説明するための画像。Images for explaining the coating uniformity of Reference Examples 1 and 2.
 本発明の実施形態に基づき、本発明を以下に説明する。
 本実施形態の組成物は、蒸発残分が所定量以上のものであって、特定の装置から霧状に吐出されるものである。
The present invention will be described below based on the embodiments of the present invention.
The composition of the present embodiment has a predetermined amount or more of evaporation residue and is discharged in the form of a mist from a specific device.
 本実施形態の組成物における蒸発残分は、1.0質量%以上90質量%以下が良く、2.0質量%以上50質量%以下が好ましく、3.0質量%以上40質量%以下がより好ましく、4.0質量%以上35質量%以下が更に好ましく、5.0質量%以上30質量%以下がより更に好ましい。蒸発残分が1.0質量%以上であると、その成分による感触付与などの作用、効果を発揮させやすくなり、90質量%以下であると、同成分による過剰な作用、効果の抑制に好適である。 The evaporation residue in the composition of the present embodiment is preferably 1.0% by mass or more and 90% by mass or less, preferably 2.0% by mass or more and 50% by mass or less, and more preferably 3.0% by mass or more and 40% by mass or less. It is preferably 4.0% by mass or more and 35% by mass or less, and even more preferably 5.0% by mass or more and 30% by mass or less. When the evaporation residue is 1.0% by mass or more, the action and effect of the component, such as imparting a feeling to the touch, are easily exerted, and when it is 90% by mass or less, it is suitable for suppressing excessive action and effect by the same component. is.
 ここで、上記「蒸発残分」は、組成物を50℃に設定した恒温槽内に24時間放置した後の残量あり、(恒温槽内に放置した後の組成物の質量)/(恒温槽内に放置する前の組成物の質量)×100にて算出される値である。 Here, the above-mentioned "evaporation residue" is the remaining amount after the composition is left in a constant temperature bath set at 50 ° C. for 24 hours, (mass of the composition after standing in the constant temperature bath) / (constant temperature It is a value calculated by multiplying the mass of the composition before being left in the bath)×100.
 本実施形態の組成物には、毛髪又は皮膚表面の感触を滑らかにするなどの目的で、蒸発残分となる油性成分、蒸発後に残らない油性成分、又は、蒸発残分となる油性成分および蒸発後に残らない油性成分が配合されていると良い。当該油性成分は、炭化水素、ロウ、エステル油、油脂、高級アルコール、及びシリコーンから選ばれた一種又は二種以上である。 For the purpose of smoothing the feel of the hair or skin surface, the composition of the present embodiment contains an oily component that becomes an evaporation residue, an oily component that does not remain after evaporation, or an oily component that becomes an evaporation residue and an evaporation It is good if it contains an oily component that does not leave a residue behind. The oily component is one or more selected from hydrocarbons, waxes, ester oils, fats and oils, higher alcohols, and silicones.
 上記炭化水素として、公知の炭化水素から選ばれた一種又は二種以上を配合できる。また、25℃で液状の炭化水素及び/又は25℃で固体の炭化水素を配合できる。この炭化水素としては、例えば、水添ポリイソブテン、イソドデカン、(C13-15)アルカン、流動パラフィン、スクワラン、プリスタン、オゾケライト、パラフィン、セレシン、ワセリン、マイクロクリスタリンワックスが挙げられる。 As the hydrocarbon, one or more selected from known hydrocarbons can be blended. Also, hydrocarbons that are liquid at 25°C and/or hydrocarbons that are solid at 25°C can be blended. Examples of the hydrocarbon include hydrogenated polyisobutene, isododecane, (C13-15) alkane, liquid paraffin, squalane, pristane, ozokerite, paraffin, ceresin, petrolatum, and microcrystalline wax.
 上記ロウは、天然物を起源とするエステルとして分類され、一般的には、脂肪酸と水に不溶性の高級一価アルコール又は二価アルコールとのエステルが該当する。また、ロウを配合する場合、公知のロウから選ばれた一種又は二種以上を配合できる。このロウとしては、例えば、ミツロウ、モクロウ、ホホバ油、キャンデリラロウ、コメヌカロウ、カルナウバロウ、ヒマワリ種子ロウが挙げられる。 The above waxes are classified as esters derived from natural products, and generally correspond to esters of fatty acids and water-insoluble higher monohydric alcohols or dihydric alcohols. When wax is blended, one or more selected from known waxes can be blended. Examples of the wax include beeswax, Japanese wax, jojoba oil, candelilla wax, rice bran wax, carnauba wax, and sunflower seed wax.
 上記エステル油は、合成により得られたエステルとして分類されるものである。エステル油を配合する場合、公知のエステル油から選ばれた一種又は二種以上を配合できる。また、25℃で液状のエステル油及び/又は25℃で固体のエステル油を配合できる。このエステル油としては、オレイン酸エチル、オレイン酸オレイル、ミリスチン酸イソプロピル、パルミチン酸イソプロピル、ステアリン酸ブチル、パルミチン酸セチル、ミリスチン酸ミリスチル、ミリスチン酸オクチルドデシル、イソステアリン酸イソプロピル、イソステアリン酸エチル、2-エチルヘキサン酸セチル、イソステアリン酸ヘキシル、ジ2-エチルヘキサン酸エチレングリコール、ジオレイン酸エチレングリコール、ジ(カプリル・カプリン酸)プロピレングリコール、ジオレイン酸プロピレングリコール、トリイソステアリン酸トリメチロールプロパン、テトラ2-エチルヘキサン酸ペンタエリスリトール、イソステアリン酸イソセチル、ジメチルオクタン酸2-オクチルドデシル、乳酸ミリスチル、クエン酸トリオクチルドデシル、リンゴ酸ジイソステアリル、コハク酸ジ2-エチルヘキシル、アジピン酸ジイソブチル、ステアリン酸コレステリル、イソステアリン酸イソステアリル、イソノナン酸イソトリデシル、(カプリル/カプリン酸)ヤシアルキルが挙げられる。 The above ester oil is classified as an ester obtained by synthesis. When blending an ester oil, one or more selected from known ester oils can be blended. Also, an ester oil that is liquid at 25°C and/or an ester oil that is solid at 25°C can be blended. The ester oils include ethyl oleate, oleyl oleate, isopropyl myristate, isopropyl palmitate, butyl stearate, cetyl palmitate, myristyl myristate, octyldodecyl myristate, isopropyl isostearate, ethyl isostearate, 2-ethyl Cetyl hexanoate, hexyl isostearate, ethylene glycol di-2-ethylhexanoate, ethylene glycol dioleate, propylene glycol di(capryl-caprate), propylene glycol dioleate, trimethylolpropane triisostearate, tetra-2-ethylhexanoic acid pentaerythritol, isocetyl isostearate, 2-octyldodecyl dimethyloctanoate, myristyl lactate, trioctyldodecyl citrate, diisostearyl malate, di-2-ethylhexyl succinate, diisobutyl adipate, cholesteryl stearate, isostearyl isostearate, isotridecyl isononanoate, (caprylic/capric)cocoalkyl.
 油脂は、脂肪酸とグリセリンとのトリエステルを主成分とするものである。油脂を配合する場合、公知の油脂から選ばれた一種又は二種以上を配合できる。また、25℃で液状の油脂及び/又は25℃で固体の油脂を配合できる。この油脂としては、例えば、アーモンド油、アボガド油、アンズ核油、オリーブ油、コメヌカ油、シア脂、シア脂油、月見草油、チャボトケイソウ種子油、ツバキ油、ババス油、ピーナッツ油、ヒマワリ種子油、ローズヒップ油が挙げられる。 Fats and oils are mainly composed of triesters of fatty acids and glycerin. When blending fats and oils, one or more selected from known fats and oils can be blended. In addition, fats and oils that are liquid at 25°C and/or fats and oils that are solid at 25°C can be blended. Examples of the oils include almond oil, avocado oil, apricot kernel oil, olive oil, rice bran oil, shea butter, shea butter oil, evening primrose oil, passionflower seed oil, camellia oil, babassu oil, peanut oil, sunflower seed oil, rose hip oil.
 高級アルコールは、炭素数12以上の一価アルコールである。高級アルコールを配合する場合、公知の高級アルコールから選ばれた一種又は二種以上を配合できる。また、25℃で液状の高級アルコール及び/又は25℃で固体の高級アルコールを配合できる。この高級アルコールとしては、例えば、ラウリルアルコール、ミリスチルアルコール、セチルアルコール、ステアリルアルコール、ベヘニルアルコール、オクチルドデカノール、イソステアリルアルコール、オレイルアルコールが挙げられる。 A higher alcohol is a monohydric alcohol with 12 or more carbon atoms. When blending a higher alcohol, one or more selected from known higher alcohols can be blended. Further, a higher alcohol that is liquid at 25°C and/or a higher alcohol that is solid at 25°C can be blended. Examples of higher alcohols include lauryl alcohol, myristyl alcohol, cetyl alcohol, stearyl alcohol, behenyl alcohol, octyldodecanol, isostearyl alcohol, and oleyl alcohol.
 シリコーンを配合する場合、公知のシリコーンから選ばれた一種又は二種以上を配合できる。このシリコーンとしては、例えば、ジメチルシリコーン(メチルポリシロキサン、高重合メチルポリシロキサンなど)、メチルフェニルシリコーン、環状シリコーン(オクタメチルシクロテトラシロキサン、デカメチルシクロペンタシロキサンなど)、アミノ変性シリコーン(アミノエチルアミノプロピルシロキサン・ジメチルシロキサン共重合体、アミノエチルアミノプロピルメチルシロキサン・ジメチルシロキサン共重合体など)長鎖アルキル変性シリコーン、ジメチコノールが挙げられる。 When blending silicone, one or more selected from known silicones can be blended. Examples of the silicone include dimethyl silicone (methylpolysiloxane, highly polymerized methylpolysiloxane, etc.), methylphenyl silicone, cyclic silicone (octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, etc.), amino-modified silicone (aminoethylamino propylsiloxane/dimethylsiloxane copolymer, aminoethylaminopropylmethylsiloxane/dimethylsiloxane copolymer, etc.), long-chain alkyl-modified silicones, and dimethiconol.
 本実施形態の組成物に蒸発残分となる油性成分を配合する場合、当該蒸発残分に該当する炭化水素、ロウ、エステル油、油脂、高級アルコール、及びシリコーンから選ばれる1種又は2種以上を配合する。本実施形態の組成物における蒸発残分となる油性成分の配合量は、1.0質量%以上50質量%以下が良く、2.0質量%以上40質量%以下が好ましく、3.0質量%以上30質量%以下がより好ましく、4.0質量%以上15質量%以下が更に好ましく、5.0質量%以上10質量%以下がより更に好ましい。その1.0質量%以上の配合量であると、その成分による感触付与などの作用、効果を発揮させやすくなり、50質量%以下であると、同成分による過剰な作用、効果の抑制に好適である。 When blending an oily component that becomes an evaporation residue in the composition of the present embodiment, one or more selected from hydrocarbons, waxes, ester oils, fats, higher alcohols, and silicones that correspond to the evaporation residue. to be blended. The amount of the oily component that becomes the evaporation residue in the composition of the present embodiment is preferably 1.0% by mass or more and 50% by mass or less, preferably 2.0% by mass or more and 40% by mass or less, and 3.0% by mass. 30 mass % or less is more preferable, 4.0 mass % or more and 15 mass % or less is still more preferable, and 5.0 mass % or more and 10 mass % or less is still more preferable. When the amount is 1.0% by mass or more, the action and effect of the component, such as imparting a feeling to the touch, are easily exerted, and when the amount is 50% by mass or less, it is suitable for suppressing the excessive action and effect of the same component. is.
 また、本実施形態の組成物に蒸発残分となる成分として液状油性成分を配合すると、毛髪や皮膚表面の滑らかさの向上に好適である。本実施形態の組成物における液状油性成分の配合量は、1.0質量%以上50質量%以下が良く、2.0質量%以上40質量%以下が好ましく、3.0質量%以上30質量%以下がより好ましく、4.0質量%以上15質量%以下が更に好ましく、5.0質量%以上10質量%以下がより更に好ましい。1.0質量%以上の配合量であると、その成分による感触付与などの作用、効果を発揮させやすくなり、50質量%以下であると、同成分による過剰な作用、効果の抑制に好適である。 In addition, blending a liquid oily component as an evaporation residue component in the composition of the present embodiment is suitable for improving the smoothness of the hair and skin surface. The amount of the liquid oil component in the composition of the present embodiment is preferably 1.0% by mass or more and 50% by mass or less, preferably 2.0% by mass or more and 40% by mass or less, and 3.0% by mass or more and 30% by mass. The following is more preferable, 4.0 to 15 mass % is still more preferable, and 5.0 to 10 mass % is even more preferable. When the blending amount is 1.0% by mass or more, the action and effect of the component, such as imparting a feeling to the touch, are easily exerted. be.
 本実施形態の組成物には、油性成分の乳化分散性、可溶化などの目的で公知の界面活性剤を適宜配合すると良い。また、多価アルコール、糖類、高分子化合物、アミノ酸、動植物抽出物、無機化合物、香料、防腐剤、金属イオン封鎖剤、紫外線吸収剤、増粘剤など、公知の毛髪用組成物や公知の皮膚用組成物に配合されている成分を配合しても良い。なお、本実施形態の組成物は、毛髪や皮膚表面の感触を滑らかにするため、固形粒子を配合しないことが最適である。 For the purpose of emulsifying and dispersing and solubilizing the oily component, the composition of the present embodiment may be appropriately blended with a known surfactant. In addition, polyhydric alcohols, saccharides, polymer compounds, amino acids, animal and plant extracts, inorganic compounds, fragrances, preservatives, sequestering agents, ultraviolet absorbers, thickeners, and the like, known hair compositions and known skin You may mix|blend the component mix|blended with the composition for. In addition, the composition of the present embodiment preferably does not contain solid particles in order to make the hair and skin feel smooth.
 本実施形態の組成物へのノニオン界面活性剤の配合は、毛髪の滑らかな感触の向上に好適である。このノニオン界面活性剤は、毛髪用及び/又は皮膚用組成物に配合される公知のノニオン界面活性剤から選ばれた一種又は二種以上であると良い。ノニオン界面活性剤としては、例えば、ノニオン界面活性剤としては、例えば、ポリオキシエチレンアルキルエーテル、ポリオキシエチレンポリオキシプロピレンアルキルエーテル、ポリオキシエチレン脂肪酸エステル、ポリオキシエチレンソルビタン脂肪酸エステル、ポリオキシエチレン硬化ヒマシ油、ポリオキシエチレンソルビトールテトラ脂肪酸エステル、グリセリン脂肪酸エステル、アルキルグルコシド、ソルビタン脂肪酸エステル、ポリグリセリン脂肪酸エステル、ポリオキシエチレングリセリン脂肪酸エステル、ショ糖脂肪酸エステル、アルキルアルカノールアミドが挙げられる。 The addition of a nonionic surfactant to the composition of this embodiment is suitable for improving the smooth feel of hair. This nonionic surfactant is preferably one or more selected from known nonionic surfactants blended in hair and/or skin compositions. Nonionic surfactants include, for example, polyoxyethylene alkyl ethers, polyoxyethylene polyoxypropylene alkyl ethers, polyoxyethylene fatty acid esters, polyoxyethylene sorbitan fatty acid esters, polyoxyethylene curing castor oil, polyoxyethylene sorbitol tetra-fatty acid ester, glycerin fatty acid ester, alkyl glucoside, sorbitan fatty acid ester, polyglycerin fatty acid ester, polyoxyethylene glycerin fatty acid ester, sucrose fatty acid ester, and alkylalkanolamide.
 本実施形態の組成物におけるノニオン界面活性剤の配合量は、0.1質量%以上15質量%以下が良く、0.5質量%以上10質量%以下が好ましく、1質量%以上8質量%以下がより好ましく、2質量%以上6質量%以下が更に好ましい。0.1質量%以上の配合量であると、毛髪の滑らかな感触の向上に好適であり、10質量%以下の配合量であると、組成物の粘度を低く設定する場合に好適である。 The amount of the nonionic surfactant in the composition of the present embodiment is preferably 0.1% by mass or more and 15% by mass or less, preferably 0.5% by mass or more and 10% by mass or less, and 1% by mass or more and 8% by mass or less. is more preferable, and 2% by mass or more and 6% by mass or less is even more preferable. A blending amount of 0.1% by mass or more is suitable for improving the smooth feeling of the hair, and a blending amount of 10% by mass or less is suitable when setting the viscosity of the composition to be low.
 本実施形態の組成物の剤型は、当該組成物を霧状に吐出させることが容易な液状である。この液状である本実施形態の組成物の粘度は、例えば200mPa・s以下であり、100mPa・s以下が良く、70mPa・s以下が好ましく、50mPa・s以下がより好ましく、30mPa・s以下が更に好ましく、10mPa・s以下がより更に好ましい(なお、粘度を低下させるには、例えば、本実施形態の組成物に配合する固形成分又は相対的に粘性の高い成分を減量すると良い。)。200mPa・s以下の粘度であると、本実施形態の組成物を微細化して霧状にすることが容易かつ効率的となる上に、毛髪や皮膚表面の滑らかな感触付与にも好適である。ここで粘度は、サーモフィッシャーサイエンティフィック社製レオメーター「Thermo Scientific HAAKE MARS 40」を用いて、定常フローカーブモードにて、せん断速度(dγ/dt)50s-1、コーンプレートセンサー(直径35mm、傾斜角2°)、温度25℃の条件で、η(mPa・s)の値を採用したものである。 The dosage form of the composition of the present embodiment is a liquid that facilitates ejection of the composition in the form of a mist. The viscosity of the liquid composition of the present embodiment is, for example, 200 mPa s or less, preferably 100 mPa s or less, preferably 70 mPa s or less, more preferably 50 mPa s or less, and further preferably 30 mPa s or less. It is preferably 10 mPa·s or less, and more preferably 10 mPa·s or less (in order to reduce the viscosity, for example, the amount of solid components or relatively highly viscous components blended in the composition of the present embodiment may be reduced). When the viscosity is 200 mPa·s or less, the composition of the present embodiment can be easily and efficiently finely divided into a mist, and is also suitable for imparting a smooth feel to hair and skin surfaces. Here, the viscosity was measured using a rheometer "Thermo Scientific HAAKE MARS 40" manufactured by Thermo Fisher Scientific Co., Ltd. in steady flow curve mode, shear rate (dγ/dt) 50 s -1 , cone plate sensor (diameter 35 mm, The value of η (mPa·s) was adopted under the conditions of an inclination angle of 2°) and a temperature of 25°C.
 本実施形態の組成物は、例えば、界面活性剤で油性成分を分散させた水中油型乳化組成物、界面活性剤で水性成分を分散させた油中水型乳化組成物、二種以上の油性成分が配合された非水系組成物が挙げられる。本実施形態の組成物が水中油型乳化組成物である場合の水の配合量は、当該組成物の粘度を低く抑えたい場合には、50質量%以上が良く、60質量%以上が好ましく、70質量%以上がより好ましく、75質量%以上が更に好ましい。また、非水系組成物とは、油中水型乳化組成物に該当しないものであって、水の配合量が0.5質量%未満、又は、水が無配合の組成物をいう。 The composition of the present embodiment includes, for example, an oil-in-water emulsion composition in which an oily component is dispersed with a surfactant, a water-in-oil emulsion composition in which an aqueous component is dispersed with a surfactant, two or more kinds of oily Examples include non-aqueous compositions in which ingredients are blended. When the composition of the present embodiment is an oil-in-water emulsion composition, the amount of water to be blended is preferably 50% by mass or more, preferably 60% by mass or more, when the viscosity of the composition is to be kept low. 70% by mass or more is more preferable, and 75% by mass or more is even more preferable. In addition, the non-aqueous composition refers to a composition that does not correspond to a water-in-oil emulsion composition and contains less than 0.5% by mass of water or does not contain water.
 図1~3は、本実施形態の組成物を使用する際に、当該組成物を霧状に吐出する本実施形態の装置であって、本発明に係る装置の一例を表すものである。 FIGS. 1 to 3 show an apparatus according to the present embodiment for ejecting the composition in the form of a mist when using the composition according to the present embodiment, which is an example of the apparatus according to the present invention.
 図1は、本実施形態の装置の側面図である。装置10は、連続的に空気流を発生可能、かつ、本実施形態の組成物の霧状吐出が連続的に可能なものである(装置10の使用例として、毛髪に向けて送風するドライヤーが挙げられる。)。ここで、霧状吐出の「連続的」とは、1秒以上、5秒以上、10秒以上、30秒以上、1分以上、3分以上、5分以上、又は10分以上などの適宜な時間続くことを意味し、吐出が瞬時に終了するポンプ式容器からの噴霧吐出とは異なる。 FIG. 1 is a side view of the device of this embodiment. The device 10 can continuously generate an air flow and can continuously spray the composition of the present embodiment in the form of a mist. mentioned.). Here, the term “continuously” for spraying in the form of a mist means 1 second or more, 5 seconds or more, 10 seconds or more, 30 seconds or more, 1 minute or more, 3 minutes or more, 5 minutes or more, or 10 minutes or more. It is meant to last for hours, unlike spraying from a pump-type container where the dispensing ends instantly.
 装置10は、装置10の外観を構成し、複数の要素を収容するハウジング11と、操作部40を有し、使用者に握られる把持部12と、電力を供給するための電力線61と、を備える。ハウジング11と把持部12とは、把持部12に対してハウジング11の位置を変更できるように連結されていると良い。ハウジング11は、外部の空気を流入させる吸入口11Aと、外部に本実施形態の組成物または空気流を放出する放出口11Bと、を備える。吸入口11Aおよび放出口11Bの形状は、例えば楕円形状である。 The device 10 comprises a housing 11 that constitutes the appearance of the device 10 and accommodates a plurality of elements, a grip portion 12 that has an operation portion 40 and is gripped by a user, and a power line 61 for supplying power. Prepare. The housing 11 and the grip portion 12 are preferably connected so that the position of the housing 11 with respect to the grip portion 12 can be changed. The housing 11 has an inlet 11A for inflow of external air and an outlet 11B for discharging the composition of the present embodiment or airflow to the outside. The shape of the intake port 11A and the discharge port 11B is, for example, elliptical.
 図2は、図1で示した装置10の断面図である。ハウジング11は、内部に流体の流れが形成される流路13を備える。流路13は、図1で示した吸入口11Aからの空気を放出口11Bに送出可能なように適宜な中空構造を採る。そして、流路13は、主に空気が通過する第1流路13Aと、主に霧状の本実施形態の組成物が通過する第2流路13Bと、を含む。 FIG. 2 is a cross-sectional view of the device 10 shown in FIG. The housing 11 has a channel 13 in which a fluid flow is formed. The flow path 13 has an appropriate hollow structure so that the air from the suction port 11A shown in FIG. 1 can be delivered to the discharge port 11B. The flow path 13 includes a first flow path 13A through which air mainly passes, and a second flow path 13B through which the misty composition of the present embodiment mainly passes.
 図3は、図1で示した装置10の電気的な接続を示すブロック図である。装置10は、図2に示す電力を供給するための電力線61に接続された制御部20、操作部40、モータ71を有する送風部70、ヒータ81を有する加熱部80、および、ポンプ91を有するミスト発生部90をさらに備える。これら各部は、例えば、図2に示すようにハウジング11の内部などに保持されていると良い。 FIG. 3 is a block diagram showing electrical connections of the device 10 shown in FIG. The device 10 has a control section 20 connected to a power line 61 for supplying power shown in FIG. A mist generator 90 is further provided. These parts are preferably held inside the housing 11 as shown in FIG. 2, for example.
 制御部20は、制御プログラムを実行する演算処理装置により構成される。制御部20は、操作部40、送風部70、加熱部80、および、ミスト発生部90と、無線または有線で通信できるように構成される。制御部20は、操作部40からの操作信号が入力されることで制御を開始する。 The control unit 20 is composed of an arithmetic processing unit that executes a control program. The control unit 20 is configured to communicate with the operating unit 40, the air blowing unit 70, the heating unit 80, and the mist generating unit 90 wirelessly or by wire. The control unit 20 starts control when an operation signal is input from the operation unit 40 .
 操作部40は、例えばユーザからの操作による操作信号を制御部20に対して出力する。操作信号は、制御部20のオンおよびオフを切り替える信号、または、制御部20による送風部70、加熱部80、および、ミスト発生部90の少なくとも1つの出力変化を実行する信号を含む。操作部40の一部は、ユーザが操作しやすいようにハウジング11の外側に向けて突出するように構成される。操作部40は、例えばボタン、スイッチ、および、ダイヤルにより構成される。 The operation unit 40 outputs an operation signal to the control unit 20, for example, according to an operation by the user. The operation signal includes a signal for switching ON and OFF of the control unit 20 or a signal for changing the output of at least one of the air blowing unit 70 , the heating unit 80 , and the mist generating unit 90 by the control unit 20 . A part of the operation part 40 is configured to protrude outward from the housing 11 so that the user can easily operate it. The operation unit 40 is composed of buttons, switches, and dials, for example.
 送風部70は、図1に示す吸入口11Aから空気を吸入し、放出口11Bから送り出される空気流を形成する。図2に示す通り、送風部70は、モータ71およびファン72を含む。モータ71の駆動により、ファン72が回転することで、流路13において空気流が生じる。モータ71は、制御部20により制御される。本実施形態の装置10は、このファン72の回転状態が維持されることにより、連続的な空気流を発生させる。送風部70は、流路13において、第1流路13Aおよび第2流路13Bの上流に存在し、第1流路13Aおよび第2流路13Bの両方に空気流を供給する。 The air blower 70 sucks air from the intake port 11A shown in FIG. 1 and forms an air flow that is sent out from the discharge port 11B. As shown in FIG. 2 , blower section 70 includes motor 71 and fan 72 . By driving the motor 71 , the fan 72 rotates to generate an air flow in the flow path 13 . The motor 71 is controlled by the controller 20 . The device 10 of this embodiment generates a continuous airflow by maintaining the rotating state of the fan 72 . Air blower 70 exists upstream of first flow path 13A and second flow path 13B in flow path 13, and supplies airflow to both first flow path 13A and second flow path 13B.
 加熱部80は、ハウジング11内の空気流を加熱し、温風を作成する。温風は、例えば100~120℃の範囲内の空気である。加熱部80は、ヒータ81を含む。ヒータ81の一例は、PTC(Positive Temperature Coefficient)ヒータおよび赤外線ヒータである。加熱部80は、例えば第1流路13Aに設けられる。制御部20は、ヒータ81の出力を制御する。装置10から送り出される空気流の温度を高めて温風とすることにより、組成物の蒸発残分以外の成分の蒸発を促進させることが可能となる。 The heating unit 80 heats the air flow inside the housing 11 to create warm air. The warm air is, for example, air within the range of 100-120°C. Heating unit 80 includes a heater 81 . An example of the heater 81 is a PTC (Positive Temperature Coefficient) heater and an infrared heater. The heating unit 80 is provided, for example, in the first flow path 13A. The controller 20 controls the output of the heater 81 . By increasing the temperature of the air flow sent out from the device 10 to make it warm air, it is possible to accelerate the evaporation of components other than the evaporation residue of the composition.
 ミスト発生部90は、本実施形態の組成物を霧状にして吐出させる。ミスト発生部90は、図2に示すポンプ91、タンク92、および、ノズル93を含む。ポンプ91は、図示しないモータを駆動することで、タンク92に貯蔵される本実施形態の組成物をノズル93に供給する液体ポンプである(当該液体ポンプの例として、ギアポンプが挙げられる)。タンク92は、装置10内部において本実施形態の組成物を貯蔵する。タンク92は、ポリプロピレンなどの液状組成物の保持に適した公知の材料で構成される。ノズル93は、本実施形態の組成物を霧状にする。この霧状を実現するには、例えば、ノズル93の内部で空気と本実施形態の組成物とを混合し、この混合時のせん断力による霧状化が可能である。この場合、ポンプ91は、ダイヤフラムポンプなどの気体ポンプをさらに含む。ミスト発生部90おいては、制御部20により、ミスト発生部90から霧状に吐出される本実施形態の組成物の流速、及び、ミスト発生部90から霧状に吐出される本実施形態の組成物の量を、制御可能となっている。本実施形態の組成物が1秒間に霧状に吐出される量は、0.1mg/s以上100mg/s以下が良く、0.3mg/s以上50mg/s以下が好ましく、0.5mg/s以上10mg/s以下がより好ましく、0.5mg/s以上5mg/s以下が更に好ましく、0.5mg/s以上3mg/s以下がより更に好ましい。その吐出量が100mg/s以下であると、塗布の均一性向上に好適であり、0.1mg/s以上であると、塗布処理の短時間化に好適である。 The mist generator 90 mists the composition of the present embodiment and ejects it. Mist generator 90 includes pump 91, tank 92, and nozzle 93 shown in FIG. Pump 91 is a liquid pump that supplies the composition of the present embodiment stored in tank 92 to nozzle 93 by driving a motor (not shown) (an example of the liquid pump is a gear pump). Tank 92 stores the compositions of the present embodiments within device 10 . Tank 92 is constructed of known materials suitable for holding liquid compositions such as polypropylene. Nozzle 93 atomizes the composition of this embodiment. In order to realize this atomization, for example, the air and the composition of the present embodiment are mixed inside the nozzle 93, and atomization is possible by shearing force during this mixing. In this case, pump 91 further includes a gas pump such as a diaphragm pump. In the mist generating unit 90, the control unit 20 controls the flow rate of the composition of the present embodiment that is discharged in the form of a mist from the mist generating unit 90, and the composition of the present embodiment that is discharged in the form of a mist from the mist generating unit 90. The amount of composition is controllable. The amount of the composition of the present embodiment that is discharged in the form of a mist per second is preferably 0.1 mg/s or more and 100 mg/s or less, preferably 0.3 mg/s or more and 50 mg/s or less, and 0.5 mg/s. It is more preferably 0.5 mg/s or more and 5 mg/s or less, and even more preferably 0.5 mg/s or more and 3 mg/s or less. When the discharge amount is 100 mg/s or less, it is suitable for improving uniformity of coating, and when it is 0.1 mg/s or more, it is suitable for shortening the coating process.
 操作部40の操作により、制御部20に電力が供給され、必要に応じて、ポンプ91、モータ71、又はヒータ81に電力がさらに供給される。ポンプ91に電力が供給されると、ノズル93から本実施形態の組成物が霧状に吐出され、当該組成物は第2流路13Bを通過して装置10の外部に導かれる。モータ71に電力が供給されると、ファン72が作動してファン72によって送り出された空気流が第1流路13Aを通って装置10の外部に吹き出される。
 霧状に吐出された組成物の粒子径は、例えば、20μm以上200μm以下であってよい。ここで、粒子径は、レーザー回折散乱法によって測定される体積平均粒子径をいう。
Power is supplied to the control unit 20 by operating the operation unit 40, and power is further supplied to the pump 91, the motor 71, or the heater 81 as necessary. When power is supplied to the pump 91, the composition of the present embodiment is discharged from the nozzle 93 in the form of a mist, and the composition is led to the outside of the device 10 through the second flow path 13B. When electric power is supplied to the motor 71, the fan 72 operates and the airflow sent out by the fan 72 is blown out of the apparatus 10 through the first flow path 13A.
The particle size of the composition discharged in the form of a mist may be, for example, 20 μm or more and 200 μm or less. Here, the particle size refers to a volume average particle size measured by a laser diffraction scattering method.
 図4は、霧状となった本実施形態の組成物(霧状組成物M)の拡散を説明するための模式図である(図4における霧状組成物は、円形状で図示。)。第2流路13Bから吐出後の霧状組成物Mは、第1流路13Aから送り出される空気流Aに引き付けられて拡散する。その結果、本実施形態の組成物による毛髪や皮膚への局所的な塗布が抑えられ、均一性の高い塗布が可能となる。また、図2のヒータ81による空気の加熱がある場合には、本実施形態の組成物の塗布と、同組成物の乾燥を同時に行うことが可能となる。 FIG. 4 is a schematic diagram for explaining the diffusion of the composition of the present embodiment (fog composition M) in the form of a mist (the mist composition in FIG. 4 is shown in a circular shape). The misty composition M discharged from the second flow path 13B is attracted to the air flow A sent out from the first flow path 13A and spreads. As a result, local application of the composition of the present embodiment to the hair or skin is suppressed, and highly uniform application becomes possible. Moreover, when the air is heated by the heater 81 of FIG. 2, it is possible to apply the composition of the present embodiment and dry the same composition at the same time.
 本実施形態の組成物を貯蔵するタンクと、空気流を発生させる送風部と、その組成物を霧状に吐出するミスト発生部と、を備える装置を使用することにより、霧状の本実施形態の組成物を毛髪、皮膚、又は、毛髪及び皮膚に塗布すれば、均一性の高い塗布処理が可能となる。 By using an apparatus comprising a tank for storing the composition of the present embodiment, an air blowing section for generating an air flow, and a mist generating section for discharging the composition in the form of a mist, the composition of the present embodiment can be obtained in the form of a mist. A highly uniform application treatment can be achieved by applying the composition of (1) to hair, skin, or hair and skin.
 以下、実施例に基づき本発明を詳述するが、この実施例の記載に基づいて本発明が限定的に解釈されるものではない。 The present invention will be described in detail below based on examples, but the present invention should not be construed in a limited manner based on the description of these examples.
<<実施例1~2、比較例1~2>>
 実施例1~2及び比較例1~2の毛髪用組成物を製造し、これら組成物による毛髪処理を行った後に、毛髪の感触、艶の評価を行った。詳細は、次の通りである。
<<Examples 1 and 2, Comparative Examples 1 and 2>>
The hair compositions of Examples 1 and 2 and Comparative Examples 1 and 2 were produced, and after the hair was treated with these compositions, the feel and luster of the hair were evaluated. Details are as follows.
(毛髪用組成物)
 不揮発性炭化水素であるスクワラン、揮発性炭化水素であるイソドデカンを混合し、粘度が100mPa・s以下、非水系である比較例1~2、実施例1~2の液状毛髪用組成物を製造した。製造する際の配合量は、下記表1の通りとした。また、蒸発残分を、毛髪用組成物10gを設定温度50℃の恒温槽内に24時間放置し、その前後の質量に基づいて算出した。
(Composition for hair)
Squalane, which is a non-volatile hydrocarbon, and isododecane, which is a volatile hydrocarbon, were mixed to produce non-aqueous liquid hair compositions of Comparative Examples 1 and 2 and Examples 1 and 2 having a viscosity of 100 mPa·s or less. . The blending amounts during production were as shown in Table 1 below. In addition, the evaporation residue was calculated based on the mass before and after leaving 10 g of the hair composition in a constant temperature bath at a set temperature of 50° C. for 24 hours.
(毛髪処理)
 洗浄後、タオルで水分を拭き取った毛束(長さ30cm程度、12gの毛束)に対して、送風部とミスト発生部を有する装置から、1分間、手櫛による櫛通しを行いつつ空気流れとしての温風を吹き付けると共に、霧状にした比較例及び実施例の組成物のいずれかを塗布した(なお、当該組成物の塗布量は40mg)。
(hair treatment)
After washing, a bundle of hair (approximately 30 cm long and weighing 12 g) that has been wiped dry with a towel is combed with a hand comb for 1 minute from a device having an air blowing unit and a mist generating unit. At the same time, one of the atomized compositions of Comparative Examples and Examples was applied (the amount of the composition applied was 40 mg).
(評価:毛髪の感触)
 毛髪処理直後と毛髪処理から24時間後の毛髪の感触について、評価者2名により評価した。
(Evaluation: hair feel)
Two evaluators evaluated the feel of the hair immediately after the hair treatment and 24 hours after the hair treatment.
(評価:毛髪の艶)
 毛髪処理直後と毛髪処理から24時間後の毛髪の艶について、評価者2名の目視により評価した。
(Evaluation: Hair luster)
The luster of the hair immediately after the hair treatment and 24 hours after the hair treatment was visually evaluated by two evaluators.
 下記表1に、比較例1~2及び実施例1~2の組成物に配合した成分、その配合量と共に、毛髪の感触の評価、毛髪の艶の評価を示す(なお、その2つの評価においては、評価者2名共に同じ評価を行っていた。)。 Table 1 below shows the components blended in the compositions of Comparative Examples 1 and 2 and Examples 1 and 2, their blending amounts, the evaluation of the feel of the hair, and the evaluation of the luster of the hair (in addition, in the two evaluations, , two evaluators gave the same evaluation).
Figure JPOXMLDOC01-appb-T000001
Figure JPOXMLDOC01-appb-T000001
 表1に示す通り、蒸発残分が増えるにつれて、当該成分による感触がより発揮されていたことを確認できる。その効果は、霧状の実施例1~2の組成物が空気流で拡散されつつ毛髪に塗布されるから、均一性が高い。 As shown in Table 1, it can be confirmed that as the amount of the evaporation residue increased, the feel of the component was exhibited more. The effect is highly uniform because the mist compositions of Examples 1 and 2 are applied to the hair while being diffused by the air flow.
<<実施例3、比較例3>>
 複数の感水試験紙(スプレーイングシステムス社製、52mm×76mmサイズ)を並べて152mm×208mmのパネルを作成した。このパネルに、下記表2に記載の毛髪用組成物を霧状にして塗布した。この塗布方法は、実施例3及び比較例3で次の通りとした。
実施例3:
 送風部とミスト発生部を有する装置から、空気流れとしての温風(温度80℃程度、風速20m/s)をパネルに吹き付けると共に、霧状にした毛髪用組成物200mgを3分間かけて塗布した。
比較例3:
 一回の吐出量が約200mgである株式会社吉野工業所製の定量吐出ミストポンプを使用し、塗布した。
<<Example 3, Comparative Example 3>>
A panel of 152 mm x 208 mm was prepared by arranging a plurality of water sensitivity test papers (manufactured by Spraying Systems, size 52 mm x 76 mm). The panel was sprayed with the hair composition shown in Table 2 below. This coating method was as follows in Example 3 and Comparative Example 3.
Example 3:
Warm air (temperature of about 80° C., wind speed of 20 m/s) was blown onto the panel from an apparatus having a blowing unit and a mist generating unit, and 200 mg of the misted hair composition was applied over 3 minutes. .
Comparative Example 3:
A metered discharge mist pump manufactured by Yoshino Kogyo Co., Ltd., which discharges about 200 mg at one time, was used for application.
Figure JPOXMLDOC01-appb-T000002
Figure JPOXMLDOC01-appb-T000002
 図5は、実施例3、比較例3の感水試験紙への塗布状態を説明するための画像であり、下記表3は、実施例3及び比較例3の塗布を纏めたものである。図5に示す通り、比較例3では、感水試験紙パネルの中央部の塗布量が多くなっていた。一方、実施例3では、比較例3のような中央部への塗布量の偏りがなく、均一性の高い塗布となったことを確認できる。 FIG. 5 is an image for explaining the state of application to the water sensitivity test paper of Example 3 and Comparative Example 3, and Table 3 below summarizes the application of Example 3 and Comparative Example 3. As shown in FIG. 5, in Comparative Example 3, the coating amount in the central portion of the water sensitivity test paper panel was large. On the other hand, in Example 3, it can be confirmed that there is no bias in the amount of application to the central portion as in Comparative Example 3, and the application is highly uniform.
Figure JPOXMLDOC01-appb-T000003
Figure JPOXMLDOC01-appb-T000003
<<実施例4~7>>
 下記表4に記載の実施例4~7の毛髪用組成物を、水洗後にタオルドライした毛束(長さ30cm程度、質量10g)に霧状にして塗布した。この塗布方法は、送風部とミスト発生部を有する装置から、空気流れとしての温風(温度80℃程度、風速20m/s)を毛束に吹き付けると共に、霧状にした毛髪用組成物200mgを3分間かけて塗布した。また、装置から吐出する霧状組成物の粒子径を、マイクロトラック・ベル社製粒度分布計「AEROTRAC II」を使用し、測定した。この測定では、使用レンズ「f100レンズ」、露光時間「10秒」、レンズから霧状組成物の距離「50mm」の条件で測定し、20回測定した体積平均粒子径の平均値を「霧状組成物の粒子径」とした。
<<Examples 4 to 7>>
The hair compositions of Examples 4 to 7 shown in Table 4 below were applied in the form of a mist to bundles of hair (about 30 cm in length, 10 g in weight) that had been washed with water and towel-dried. In this application method, warm air (temperature of about 80°C, wind speed of 20 m/s) as an air flow is blown onto the hair bundle from an apparatus having an air blowing part and a mist generating part, and 200 mg of the misted hair composition is applied. It was applied for 3 minutes. In addition, the particle size of the mist composition discharged from the apparatus was measured using a particle size distribution meter "AEROTRAC II" manufactured by Microtrack Bell. In this measurement, the lens used is "f100 lens", the exposure time is "10 seconds", and the distance from the lens to the mist composition is "50 mm". The particle size of the composition”.
 下記表4において、実施例4~7の毛髪用組成物を塗布した後の毛束について、表面の滑らかさの評価を行った結果を示す。ノニオン界面活性剤を配合した実施例5~7は、実施例4よりも滑らかさに優れる結果であった。
Figure JPOXMLDOC01-appb-T000004
Table 4 below shows the results of evaluating the surface smoothness of the hair tresses to which the hair compositions of Examples 4 to 7 were applied. Examples 5 to 7, in which a nonionic surfactant was blended, were more excellent in smoothness than Example 4.
Figure JPOXMLDOC01-appb-T000004
<<参考例1~2>>
 人頭マネキンに装着されている毛髪を洗浄し、タオルで水分を拭き取った後に、赤色色素を追加配合した市販の液状毛髪用組成物(ミルボン社製「プラーミア デイエッセンス」)0.3gを、人頭マネキンの片側側面の毛髪に塗布した。この塗布は、下記の参考例1~2の処理により行った。
参考例1:
 送風部とミスト発生部を有する装置から、櫛通しをしつつ、空気流れとしての温風(温度80℃程度、風速20m/s)を吹き付けると共に、霧状にした上記液状毛髪用組成物を塗布した。
参考例2:
 手の平に伸ばした上記液状毛髪用組成物を塗布した。
<<Reference Examples 1 to 2>>
After washing the hair attached to the human head mannequin and wiping off moisture with a towel, 0.3 g of a commercially available liquid hair composition (“Plumia Day Essence” manufactured by Milbon Co., Ltd.) additionally containing a red pigment was applied to the human head. It was applied to the hair on one side of the head mannequin. This coating was carried out by the treatment of Reference Examples 1 and 2 below.
Reference example 1:
A device having an air blower and a mist generator blows hot air (temperature about 80°C, wind speed 20 m/s) as an air flow while combing, and applies the liquid hair composition in the form of a mist. bottom.
Reference example 2:
The liquid composition for hair was applied to the palm of the hand.
 参考例1~2の処理により塗布した毛髪を撮影したカラー画像から、画像処理により赤の色相を抽出し、その抽出画像により塗布の均一性を確認した。図6は、参考例1~2の塗布均一性を説明するための画像であり、参考例1の抽出画像は、参考例2の抽出画像よりも色むらが明らかに少なく、塗布均一性が良好であったことを確認できる。 From the color image of the hair applied by the treatment of Reference Examples 1 and 2, the red hue was extracted by image processing, and the uniformity of the application was confirmed from the extracted image. FIG. 6 is an image for explaining the coating uniformity of Reference Examples 1 and 2. The extracted image of Reference Example 1 has clearly less color unevenness than the extracted image of Reference Example 2, and the coating uniformity is good. It can be confirmed that it was
10 装置
20 制御部
70 送風部
71 モータ
72 ファン
90 ミスト発生部
91 ポンプ
92 タンク
M 霧状組成物
A 空気流
10 Device 20 Control Unit 70 Blower Unit 71 Motor 72 Fan 90 Mist Generation Unit 91 Pump 92 Tank M Atomized Composition A Air Flow

Claims (18)

  1.  50℃で24時間放置した後の蒸発残分が1.0質量%以上であり、
     空気流を発生させる送風部を有する装置から吐出させた霧状の毛髪用及び/又は皮膚用組成物。
    The evaporation residue after standing at 50 ° C. for 24 hours is 1.0% by mass or more,
    A mist composition for hair and/or skin discharged from a device having an air blower for generating an air flow.
  2.  前記吐出における吐出量が100mg/s以下である請求項1に記載の毛髪用及び/又は皮膚用組成物。 The composition for hair and/or skin according to claim 1, wherein the ejection amount in the ejection is 100 mg/s or less.
  3.  粘度が200mPa・s以下である請求項1又は2に記載の毛髪用及び/又は皮膚用組成物。 The composition for hair and/or skin according to claim 1 or 2, which has a viscosity of 200 mPa·s or less.
  4.  ノニオン界面活性剤が配合されている請求項1~3のいずれかに記載の毛髪用及び/又は皮膚用組成物。 The composition for hair and/or skin according to any one of claims 1 to 3, which contains a nonionic surfactant.
  5.  前記ノニオン界面活性剤の配合量が15質量%以下である請求項4に記載の毛髪用及び/又は皮膚用組成物。 The composition for hair and/or skin according to claim 4, wherein the content of the nonionic surfactant is 15% by mass or less.
  6.  前記蒸発残分となる成分として液状の油性成分が配合されており、前記液状の油性成分の配合量が1.0質量%以上である請求項1~5のいずれかに記載の毛髪用及び/又は皮膚用組成物。 6. The and/or for hair according to any one of claims 1 to 5, wherein a liquid oily component is blended as the component that becomes the evaporation residue, and the blending amount of the liquid oily component is 1.0% by mass or more. Or a composition for skin.
  7.  前記蒸発残分となる成分として、炭化水素、ロウ、エステル油、油脂、高級アルコール、及びシリコーンから選ばれる1種又は2種以上の油性成分が配合されている請求項1~6のいずれかに記載の毛髪用及び/又は皮膚用組成物。 7. Any one of Claims 1 to 6, wherein one or more oily components selected from hydrocarbons, waxes, ester oils, fats and oils, higher alcohols, and silicones are blended as the components that form the evaporation residue. A hair and/or skin composition as described.
  8.  水中油型乳化組成物、油中水型乳化組成物、又は二種以上の油性成分が配合された非水系組成物である請求項1~7のいずれかに記載の毛髪用及び/又は皮膚用組成物。 The composition for hair and/or skin according to any one of claims 1 to 7, which is an oil-in-water emulsion composition, a water-in-oil emulsion composition, or a non-aqueous composition containing two or more oily components. Composition.
  9.  請求項1~8のいずれか1項に記載の毛髪用及び/又は皮膚用組成物を使用する毛髪及び/又は皮膚の処理方法。 A method for treating hair and/or skin using the composition for hair and/or skin according to any one of claims 1 to 8.
  10.  50℃で24時間放置した後の蒸発残分が1.0質量%以上の毛髪用及び/又は皮膚用組成物を貯蔵するタンクと、
     空気流を発生させる送風部と、
     前記毛髪用及び/又は皮膚用組成物を霧状に吐出するミスト発生部と、
    を備える装置。
    A tank for storing a hair and/or skin composition having an evaporation residue of 1.0% by mass or more after being left at 50° C. for 24 hours;
    a blower for generating an airflow;
    a mist generator for ejecting the composition for hair and/or skin in the form of a mist;
    A device comprising
  11.  前記ミスト発生部からの霧状吐出における吐出量が100mg/s以下である請求項10に記載の装置。 11. The device according to claim 10, wherein the amount of mist ejected from the mist generator is 100 mg/s or less.
  12.  前記毛髪用及び/又は皮膚用組成物の粘度が200mPa・s以下である請求項10又は11に記載の装置。 The device according to claim 10 or 11, wherein the composition for hair and/or skin has a viscosity of 200 mPa·s or less.
  13.  前記毛髪用及び/又は皮膚用組成物において、ノニオン界面活性剤が配合されている請求項10~12のいずれかに記載の装置。 The device according to any one of claims 10 to 12, wherein the composition for hair and/or skin contains a nonionic surfactant.
  14.  前記ノニオン界面活性剤の配合量が15質量%以下である請求項13に記載の装置。 The device according to claim 13, wherein the amount of the nonionic surfactant is 15% by mass or less.
  15.  前記毛髪用及び/又は皮膚用組成物には、蒸発残分となる成分として液状の油性成分が配合されており、前記液状の油性成分の配合量が1.0質量%以上である請求項10~14のいずれかに記載の装置。 10. The composition for hair and/or skin contains a liquid oily component as an evaporation residue, and the content of the liquid oily component is 1.0% by mass or more. 15. The device according to any one of 14.
  16.  前記毛髪用及び/又は皮膚用組成物には、前記蒸発残分となる成分として、炭化水素、ロウ、エステル油、油脂、高級アルコール、及びシリコーンから選ばれる1種又は2種以上の油性成分が配合されている請求項10~15のいずれかに記載の装置。 The composition for hair and/or skin contains one or two or more oily components selected from hydrocarbons, waxes, ester oils, fats and oils, higher alcohols, and silicones, as components that form the evaporation residue. A device according to any one of claims 10 to 15 which is compounded.
  17.  前記毛髪用及び/又は皮膚用組成物が、水中油型乳化組成物、油中水型乳化組成物、又は二種以上の油性成分が配合されている非水系組成物である請求項10~16のいずれかに記載の装置。 The hair and/or skin composition is an oil-in-water emulsion composition, a water-in-oil emulsion composition, or a non-aqueous composition containing two or more oily components. A device according to any of the preceding claims.
  18.  請求項10~17のいずれかに記載の装置を使用する毛髪及び/又は皮膚の処理方法。
     
     
     
    A method for treating hair and/or skin using a device according to any one of claims 10-17.


PCT/JP2022/046820 2022-01-31 2022-12-20 Hair and/or skin composition, method for treating hair and/or skin, and device for hair and/or skin WO2023145306A1 (en)

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4523080A (en) * 1983-03-14 1985-06-11 Bolton John D Apparatus for treatment of hair and scalp
US4605019A (en) * 1984-09-05 1986-08-12 Sorenco, Inc. Sprayer attachment for a hair dryer
JPH05309013A (en) * 1991-05-23 1993-11-22 Matsushita Electric Works Ltd Mist hair drier
US20080235980A1 (en) * 2007-03-30 2008-10-02 Rovcal, Inc. Centrifugal sprayer and hair dryer having the same for application of a hair treatment liquid
US20190350335A1 (en) * 2018-05-16 2019-11-21 James G. Montagnino Ultrasonic mist conditioning hair styling apparatus

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4523080A (en) * 1983-03-14 1985-06-11 Bolton John D Apparatus for treatment of hair and scalp
US4605019A (en) * 1984-09-05 1986-08-12 Sorenco, Inc. Sprayer attachment for a hair dryer
JPH05309013A (en) * 1991-05-23 1993-11-22 Matsushita Electric Works Ltd Mist hair drier
US20080235980A1 (en) * 2007-03-30 2008-10-02 Rovcal, Inc. Centrifugal sprayer and hair dryer having the same for application of a hair treatment liquid
US20190350335A1 (en) * 2018-05-16 2019-11-21 James G. Montagnino Ultrasonic mist conditioning hair styling apparatus

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