WO2023138310A1 - Wet spinning apparatus and preparation process for sea-island fibers - Google Patents

Wet spinning apparatus and preparation process for sea-island fibers Download PDF

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Publication number
WO2023138310A1
WO2023138310A1 PCT/CN2022/141916 CN2022141916W WO2023138310A1 WO 2023138310 A1 WO2023138310 A1 WO 2023138310A1 CN 2022141916 W CN2022141916 W CN 2022141916W WO 2023138310 A1 WO2023138310 A1 WO 2023138310A1
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Prior art keywords
cavity
sea
needle
island
spinning solution
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PCT/CN2022/141916
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French (fr)
Chinese (zh)
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刘福娟
诸葛依娜
徐岚
王萍
张岩
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苏州大学
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Publication of WO2023138310A1 publication Critical patent/WO2023138310A1/en

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    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01DMECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D5/00Formation of filaments, threads, or the like
    • D01D5/06Wet spinning methods
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01DMECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D5/00Formation of filaments, threads, or the like
    • D01D5/28Formation of filaments, threads, or the like while mixing different spinning solutions or melts during the spinning operation; Spinnerette packs therefor
    • D01D5/30Conjugate filaments; Spinnerette packs therefor
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50Manufacturing or production processes characterised by the final manufactured product
    • Y02P70/62Manufacturing or production processes characterised by the final manufactured product related technologies for production or treatment of textile or flexible materials or products thereof, including footwear

Definitions

  • the invention belongs to the technical field of sea-island fiber preparation, and in particular relates to a wet spinning equipment for sea-island fiber, and meanwhile, the invention also relates to a preparation process for sea-island fiber.
  • Sea-island fiber refers to the high polymer of two or more components, which is distributed in the form of sea-islands on the cross-section of the fiber after composite spinning.
  • the “island” component can emerge from the wrapped “sea” component to obtain a bundled fiber; on the contrary, when the "island” component is dissolved, the remaining “sea” component can form a porous hollow fiber.
  • Sea-island fibers have excellent properties that other ordinary fibers cannot achieve, such as soft fibers, good hygroscopicity, waterproof and breathable, and heat insulation and warmth.
  • sea-island fibers are mostly prepared by melt spinning, but melt spinning requires high operating temperature and high voltage, the spinning process is cumbersome and complicated, and the preparation cost is high. At the same time, this preparation method requires high standardization of manual operations, and slight negligence can easily cause safety accidents. Therefore, it is necessary to propose a spinning equipment and preparation process that is safe and simple to prepare sea-island fibers.
  • the technical problem to be solved by the present invention is to overcome the deficiencies of the prior art and provide an improved wet spinning equipment for sea-island fibers.
  • the invention also provides a preparation process for sea-island fibers.
  • a kind of wet spinning equipment for sea-island fiber it comprises:
  • Injection unit comprising syringe, needle assembly
  • a coagulation unit comprising a coagulation bath coupled to the end of the needle assembly
  • a collecting unit comprising collecting rollers for collecting the coagulated sea-island fibers
  • the syringe includes a first cavity and a second cavity filled with the marine spinning solution and the island spinning solution respectively.
  • the first cavity and the second cavity are not connected to each other.
  • the needle assembly is inserted into the coagulation bath from the outlet end and includes a first needle and a second needle.
  • the first needle forms a marine spinning solution channel connected to the first cavity.
  • the connected island phase spinning solution channel, the marine phase spinning solution extruded synchronously from the first needle and the second needle wraps the multiple island phase spinning solution and injects into the coagulation bath.
  • the liquid inlet ends of the first needle and the second needle are located outside the coagulation bath to form an exposed section; the liquid outlet ends of the first needle and the second needle are located in the coagulation bath to form an inner section, wherein the length of the exposed section is shorter than the length of the inner section.
  • the marine-phase spinning solution can be wrapped around the outer periphery of the second needle in the exposed section, and the wrapping state is maintained after entering the coagulation bath until the island-phase spinning solution is covered by the marine-phase spinning solution from the liquid outlet end to form sea-island fibers.
  • the liquid inlet ends of the first needle and the second needle are arranged flush; the liquid outlet ends of the first needle and the second needle are arranged flush. That is to say, the wrapping is carried out under the premise that the lengths of the two remain equal.
  • one of the plurality of second needles is located at the center of the first needle, and the remaining second needles are distributed around the central second needle in order from inside to outside in an annular array. Such a distribution can achieve the best coating effect.
  • the number of the second needles distributed in a circular array sequentially from the inside to the outside increases in an arithmetic sequence.
  • the state of the distribution at this time is the optimal state.
  • the second cavity is located inside the first cavity, and the outlets of the first cavity and the second cavity are flush with each other. That is to say, the marine-phase spinning solution and the island-phase spinning solution are kept wrapped before they enter the needle assembly.
  • both the first cavity and the second cavity are cylindrical, and the first cavity is sleeved outside the second cavity.
  • Such arrangement facilitates the synchronous extrusion of the marine-phase spinning solution and the island-phase spinning solution into the first needle and the second needle.
  • the first cavity includes a front external cavity and a rear external cavity extending along its own length direction, wherein the inner diameter of the front external cavity is smaller than the inner diameter of the rear external cavity;
  • the second cavity includes a front inner cavity and a rear inner cavity extending along its own length direction, wherein the inner diameter of the front inner cavity is smaller than the inner diameter of the rear inner cavity, and the centerlines of the front inner cavity and the front outer cavity are coincidently arranged. Only such a layout can obtain the required injection thrust, and at the same time, the structure is simple, which is convenient for installation and implementation.
  • the rear end of the anterior inner cavity is located in the anterior external cavity.
  • the syringe further includes a piston movably arranged along the length direction of the cylinder, wherein the piston has a first pushing end matching the first cavity and a second pushing end matching the second cavity, and the first pushing end and the second pushing end can move synchronously to form an injection thrust.
  • a piston movably arranged along the length direction of the cylinder, wherein the piston has a first pushing end matching the first cavity and a second pushing end matching the second cavity, and the first pushing end and the second pushing end can move synchronously to form an injection thrust.
  • the syringe further includes a syringe pump connected to the piston, and the self-propelling part of the syringe pump is respectively docked with the first pushing end and the second pushing end. In this way, the injection is performed with the same force.
  • the first pushing end is ring-shaped
  • the second pushing end is disc-shaped
  • the first pushing end and the second pushing end are aligned. Keeping in sync facilitates injection implementation.
  • the first needles extend horizontally outward from the outlet of the first cavity, and the plurality of second needles extend horizontally outward from the outlet of the second cavity.
  • the injection thrust direction is consistent with the spinning dope injection direction, which is conducive to stable injection.
  • the liquid inlet ends of the plurality of second needles are sealed and connected to each other from the side walls, and the liquid outlet ends of the plurality of second needles are spaced apart, and the marine spinning solution enters the first cavity and wraps around the periphery of each second needle.
  • This arrangement ensures that the island-phase spinning solution enters each second needle to facilitate the formation of sea-island fibers; at the same time, it can effectively prevent the sea-phase spinning solution from flowing back into the second cavity.
  • the coagulation unit further includes a plurality of tension rollers arranged in the coagulation bath, wherein the plurality of tension rollers are arranged staggered up and down in the height direction of the coagulation bath.
  • Such setting can effectively increase the tension of the sea-island fibers and facilitate collection.
  • the collecting unit further includes an air-drying component, wherein the air-drying component is arranged close to the collecting roller and blows airflow toward the collecting roller.
  • the air-drying component is arranged close to the collecting roller and blows airflow toward the collecting roller.
  • the present invention has the following advantages compared with the prior art:
  • the present invention adopts wet spinning to prepare sea-island fibers, and the equipment structure is simple, reliable, and easy to operate. In this way, the preparation process has high safety and low cost; at the same time, it can stably control the coagulation process of the spinning solution in the coagulation bath to ensure that the generated sea-island fibers meet the preparation requirements.
  • Fig. 1 is the structural representation of the wet spinning equipment that the present invention is used for sea-island fiber
  • Figure 2 is an enlarged schematic view of the needle assembly in Figure 1;
  • Fig. 3 is the right view diagram of Fig. 2;
  • injection unit 10. syringe; 101. first cavity; 102. second cavity; 103. piston; a1. first pushing end; a2. second pushing end; 104. injection pump; 11. needle assembly; 111. first needle;
  • Coagulation unit 20. Coagulation bath; 21. Tension roller;
  • orientations or positional relationships indicated by the terms “center”, “longitudinal”, “transverse”, “length”, “width”, “thickness”, “upper”, “lower”, “front”, “rear”, “left”, “right”, “vertical”, “horizontal”, “top”, “bottom”, “inner”, “outer”, “clockwise”, “counterclockwise”, “axial”, “radial”, “circumferential” are based on the drawings.
  • the orientation or positional relationship is only for the convenience of describing the present application and simplifying the description, but does not indicate or imply that the referred device or element must have a specific orientation, be constructed and operated in a specific orientation, and therefore cannot be construed as a limitation of the present application.
  • first and second are used for descriptive purposes only, and cannot be interpreted as indicating or implying relative importance or implicitly specifying the quantity of indicated technical features.
  • the features defined as “first” and “second” may explicitly or implicitly include at least one of these features.
  • “plurality” means at least two, such as two, three, etc., unless otherwise specifically defined.
  • connection In this application, unless otherwise clearly specified and limited, the terms “installation”, “connection”, “connection”, “fixation” and other terms should be understood in a broad sense, for example, it may be a fixed connection, a detachable connection, or an integral body; it may be a mechanical connection or an electrical connection; it may be a direct connection or an indirect connection through an intermediate medium, and it may be the internal communication of two components or the interaction relationship between two components, unless otherwise clearly defined. Those of ordinary skill in the art can understand the specific meanings of the above terms in this application according to specific situations.
  • a first feature being "on” or “under” a second feature may mean that the first and second features are in direct contact, or the first and second features are in indirect contact through an intermediary.
  • “above”, “above” and “above” the first feature on the second feature may mean that the first feature is directly above or obliquely above the second feature, or simply means that the first feature is horizontally higher than the second feature.
  • “Below”, “beneath” and “beneath” the first feature may mean that the first feature is directly below or obliquely below the second feature, or simply means that the first feature is less horizontally than the second feature.
  • the wet spinning equipment for sea-island fibers in this embodiment includes an injection unit 1 , a coagulation unit 2 , and a collection unit 3 .
  • the injection unit 1 includes a syringe 10 and a needle assembly 11 communicating with the syringe 10 .
  • the syringe 10 includes a first cavity 101 , a second cavity 102 , a piston 103 , and a syringe pump 104 .
  • Such arrangement has a simple structure and is convenient for installation and implementation.
  • the second cavity 102 is located inside the first cavity 101 , and the outlets of the first cavity 101 and the second cavity 102 are flush with each other. That is to say, the marine-phase spinning solution and the island-phase spinning solution are kept wrapped before they enter the needle assembly.
  • Both the first cavity 101 and the second cavity 102 are cylindrical, and the first cavity 101 is sleeved outside the second cavity 102, and the first cavity 101 and the second cavity 102 are not connected to each other, wherein the marine phase spinning liquid and the island phase spinning liquid are respectively filled in the first cavity 101 and the second cavity 102.
  • Such arrangement facilitates the synchronous extrusion of the marine-phase spinning solution and the island-phase spinning solution into the first needle and the second needle.
  • the first cavity 101 includes an anterior external cavity and a rear external cavity extending along its length direction, wherein the inner diameter of the anterior external cavity is smaller than the internal diameter of the rear external cavity.
  • the second cavity 102 includes a front inner cavity and a rear inner cavity extending along its length direction, wherein the inner diameter of the front inner cavity is smaller than the inner diameter of the rear inner cavity, and the centerlines of the front inner cavity and the front outer cavity are coincidently arranged. Only such a layout can obtain the required injection thrust, and at the same time, the structure is simple, which is convenient for installation and implementation.
  • the rear end of the anterior lumen is located in the anterior exocrine.
  • the piston 103 is movable along the spinning liquid injection direction, and has a first pushing end a1 attached between the inner wall of the first cavity 101 and the outer wall of the second cavity 102, and a second pushing end a2 attached to the inner wall of the second cavity 102.
  • the syringe pump 104 is connected to the outer end of the piston 103 and pushes the piston 103 to move along the horizontal direction, wherein the advancing speed of the syringe pump 104 is set at 0-15 mL/h.
  • Such setting can realize the stable injection of the sea-phase spinning solution and the island-phase spinning solution, which is convenient for controlling the forming of the sea-island fibers and improving the forming quality.
  • the needle assembly 11 includes a first needle 111 connected to the first cavity 101 and a second needle 112 connected to the second cavity 102 , wherein there are multiple second needles 112 distributed at intervals inside the first needle 111 , and the marine phase spinning solution extruded synchronously from the first needle 111 and the second needle 112 wraps the multi-strand island phase spinning solution and injects it into the coagulation unit 2 .
  • the first needle 111 extends horizontally outward from the outlet of the first cavity 101
  • a plurality of second needles 112 extends horizontally outward from the outlet of the second cavity 102
  • the liquid inlet ends of the plurality of second needles 112 are sealed and connected to each other from the side wall, and the liquid outlet ends of the plurality of second needles 112 are spaced apart
  • the marine spinning solution enters the first cavity 101 and is wrapped around the periphery of each second needle 112.
  • each second needle 112 is aligned with the liquid outlet end of the first needle 111 and inserted into the coagulation unit 2, wherein the diameter of the first needle 111 is d1, where 1mm ⁇ d1 ⁇ 5mm; the diameter of the second needle 112 is d2, where 0.2mm ⁇ d2 ⁇ 1mm.
  • the liquid inlet ends of the first needle 111 and the second needle 112 are arranged flush; the liquid outlet ends of the first needle 111 and the second needle 112 are arranged flush. That is to say, the wrapping is carried out under the premise that the lengths of the two remain equal.
  • a plurality of second needles 112 are located in the center of the first needle 111 , and the remaining second needles 112 are distributed around the central second needle 112 in order from inside to outside in an annular array. Such a distribution can achieve the best coating effect.
  • the number of the second needles 112 distributed in a circular array sequentially from the inside to the outside increases in an arithmetic sequence.
  • the state of the distribution at this time is the optimal state.
  • the first annular array formed from the inside to the outside has 6 second needles 112
  • the second annular array has 9 second needles 112
  • the second annular array has 12 second needles 112 that is to say, the number of the second needles 112 of the three annular arrays from the inside to the outside increases by 3 every time one annular array goes outward, therefore, it increases in an arithmetic sequence.
  • the coagulation unit 2 includes a coagulation bath 20 connected to the injection unit 1, and four tension rollers 21 distributed inside and above the coagulation bath 20, wherein the first needle 111 and the second needle 112 are respectively inserted into the coagulation bath 20 from the liquid outlet.
  • the liquid inlet ends of the first needle head 111 and the second needle head 112 are located outside the coagulation bath 20 to form an exposed section; the liquid outlet ends of the first needle head 111 and the second needle head 112 are located in the coagulation bath 20 to form an inner section, wherein the length of the exposed section is less than the length of the inner section.
  • the marine-phase spinning solution can be wrapped around the outer periphery of the second needle in the exposed section, and after entering the coagulation bath, the wrapping state is maintained until the island-phase spinning solution is covered by the marine-phase spinning solution from the liquid outlet end to form sea-island fibers.
  • two adjacent tension rollers 21 are staggered up and down. Such setting can effectively increase the tension of the sea-island fibers and facilitate collection.
  • the collection unit 3 includes a collection roller 30 for collecting sea-island fibers and an air-drying unit 31 .
  • the collecting roller 30 is arranged on the upper right of the coagulation bath 20, and the collecting roller 30 can move left and right. This arrangement facilitates the collection of fibers.
  • the formed sea-island fibers pass through four tension rollers 21 in turn and are drawn to the collection roller 30 for winding, and while the collection roller 30 is being wound, air-drying components 31 are used to blow dry air to the sea-island fibers from above and one side of the collection roller 30 respectively.
  • the liquid inlet ends of multiple second needles are sealed and connected to ensure that the island-phase spinning solution enters each second needle to facilitate the formation of sea-island fibers; at the same time, it can effectively prevent the sea-phase spinning solution from flowing back into the second cavity;
  • the fibers can be pre-dried to prevent the collection of fibers from sticking together, and the sea-island fibers can be prepared by continuous wet method.

Abstract

A wet spinning apparatus for sea-island fibers. The wet spinning apparatus for sea-island fibers comprises: an injection unit (1), comprising a syringe (10) and a needle assembly (11) in communication with the syringe (10); a coagulation unit (2), comprising a coagulation bath (20) connected to the injection unit (1), wherein the coagulation bath (20) is used for the coagulation of a spinning solution; and a collecting unit (3) connected to the coagulation bath (20) and comprising a collecting roller (30) for collecting the sea-island fibers. The syringe (10) comprises a first cavity (101) and a second cavity (102) which are not in communication with each other, a sea-phase spinning solution and an island-phase spinning solution are respectively filled into the first cavity (101) and the second cavity (102), and the needle assembly (11) comprises a first needle (111) in communication with the first cavity (101) and second needles (112) in communication with the second cavity (102), wherein the plurality of second needles (112) are distributed in the first needle (111) at intervals; and the sea-phase spinning solution simultaneously extruded from the first needle (111) and the second needles (112) is wrapped around the plurality of streams of the island-phase spinning solution and is injected into the coagulation bath (20). The sea-island fibers are prepared through a wet spinning method, and the apparatus is simple and reliable in structure and convenient to operate, such that a preparation process is highly safe and is low cost; moreover, a coagulation process of the spinning solutions in the coagulation bath can be stably controlled, and the generated sea-island fibers can be guaranteed to satisfy preparation requirements.

Description

用于海岛纤维的湿法纺丝设备及制备工艺Wet spinning equipment and preparation process for sea-island fibers 技术领域technical field
本发明属于海岛纤维制备技术领域,具体涉及一种用于海岛纤维的湿法纺丝设备,同时本发明还涉及一种用于海岛纤维的制备工艺。The invention belongs to the technical field of sea-island fiber preparation, and in particular relates to a wet spinning equipment for sea-island fiber, and meanwhile, the invention also relates to a preparation process for sea-island fiber.
背景技术Background technique
海岛纤维是指两种或两种以上组分的高聚物进行复合纺丝后,在纤维截面上以海岛的形式分布,其中,当将″海″的组分溶解后,“岛″组分就可从被包裹的″海″组分中显现出来,得到集束状的纤维;相反地,当溶解掉″岛″组分后,剩下的″海″组分则可形成多孔中空纤维。海岛纤维有其他普通纤维所达不到的优异性能,如纤维柔软、吸湿性好、防水透气性好、及隔热保暖等。Sea-island fiber refers to the high polymer of two or more components, which is distributed in the form of sea-islands on the cross-section of the fiber after composite spinning. When the "sea" component is dissolved, the "island" component can emerge from the wrapped "sea" component to obtain a bundled fiber; on the contrary, when the "island" component is dissolved, the remaining "sea" component can form a porous hollow fiber. Sea-island fibers have excellent properties that other ordinary fibers cannot achieve, such as soft fibers, good hygroscopicity, waterproof and breathable, and heat insulation and warmth.
目前,海岛纤维的制备多采用熔融纺丝,但是熔融纺丝所需要的操作温度高,所需电压较高,纺丝过程繁琐复杂,且制备成本高;同时,该制备方式对人工操作规范性要求高,稍有疏忽,很容易造成安全事故,因此,有必要提出一种安全简单制备海岛纤维的纺丝设备和制备工艺。At present, sea-island fibers are mostly prepared by melt spinning, but melt spinning requires high operating temperature and high voltage, the spinning process is cumbersome and complicated, and the preparation cost is high. At the same time, this preparation method requires high standardization of manual operations, and slight negligence can easily cause safety accidents. Therefore, it is necessary to propose a spinning equipment and preparation process that is safe and simple to prepare sea-island fibers.
发明内容Contents of the invention
本发明所要解决的技术问题是克服现有技术的不足,提供一种改进的用于海岛纤维的湿法纺丝设备。The technical problem to be solved by the present invention is to overcome the deficiencies of the prior art and provide an improved wet spinning equipment for sea-island fibers.
同时,本发明还提供一种用于海岛纤维的制备工艺。At the same time, the invention also provides a preparation process for sea-island fibers.
为解决上述技术问题,本发明采取的技术方案如下:In order to solve the problems of the technologies described above, the technical scheme that the present invention takes is as follows:
一种用于海岛纤维的湿法纺丝设备,其包括:A kind of wet spinning equipment for sea-island fiber, it comprises:
注射单元,其包括注射器、针头组件;Injection unit comprising syringe, needle assembly;
凝固单元,其包括与针头组件端部相相衔接的凝固浴;a coagulation unit comprising a coagulation bath coupled to the end of the needle assembly;
收集单元,其包括用于收集凝固后海岛纤维的收集辊,a collecting unit comprising collecting rollers for collecting the coagulated sea-island fibers,
特别是,in particular,
注射器包括具有分别填充海相纺丝液和岛相纺丝液的第一腔体和第二腔体,所述第一腔体和所述第二腔体互不连通,所述针头组件自出液端部插入所述凝固浴内,且包括第一针头和第二针头,其中所述第一针头内部形成与所述第一腔体连通的海相纺丝液通道,所述第二针头有多个并间隔分布在所述第一针头的海相纺丝液通道内部,各所述第二针头内部形成与所述第二腔体连通的岛相纺丝液通道,自所述第一针头和所述第二针头同步挤出的海相纺丝液将多 股岛相纺丝液包裹并注入所述凝固浴。The syringe includes a first cavity and a second cavity filled with the marine spinning solution and the island spinning solution respectively. The first cavity and the second cavity are not connected to each other. The needle assembly is inserted into the coagulation bath from the outlet end and includes a first needle and a second needle. The first needle forms a marine spinning solution channel connected to the first cavity. There are multiple second needles distributed in the marine spinning solution channel of the first needle. The connected island phase spinning solution channel, the marine phase spinning solution extruded synchronously from the first needle and the second needle wraps the multiple island phase spinning solution and injects into the coagulation bath.
优选地,第一针头和第二针头的进液端部位于凝固浴外形成外露段;第一针头和第二针头的出液端部位于凝固浴内形成内插段,其中所述外露段的长度小于内插段的长度。这样一来,在外露段海相纺丝液就能够包裹在第二针头外周,且进入凝固浴后保持着包裹状态直至自出液端部后海相纺丝液将岛相纺丝液包覆形成海岛纤维。Preferably, the liquid inlet ends of the first needle and the second needle are located outside the coagulation bath to form an exposed section; the liquid outlet ends of the first needle and the second needle are located in the coagulation bath to form an inner section, wherein the length of the exposed section is shorter than the length of the inner section. In this way, the marine-phase spinning solution can be wrapped around the outer periphery of the second needle in the exposed section, and the wrapping state is maintained after entering the coagulation bath until the island-phase spinning solution is covered by the marine-phase spinning solution from the liquid outlet end to form sea-island fibers.
优选地,第一针头和第二针头的进液端部齐平设置;第一针头和第二针头的出液端部的齐平设置。也就是说,两者的长度保持相等的前提下实施包裹。Preferably, the liquid inlet ends of the first needle and the second needle are arranged flush; the liquid outlet ends of the first needle and the second needle are arranged flush. That is to say, the wrapping is carried out under the premise that the lengths of the two remain equal.
根据本发明的一个具体实施和优选方面,多个第二针头以一个位于所述第一针头的中心、剩余的第二针头绕着中心第二针头由内向外依次呈环形阵列分布。这样的分布才能起到最佳的包覆效果。According to a specific implementation and a preferred aspect of the present invention, one of the plurality of second needles is located at the center of the first needle, and the remaining second needles are distributed around the central second needle in order from inside to outside in an annular array. Such a distribution can achieve the best coating effect.
优选地,自内向外依次呈环形阵列分布的各第二针头数量呈等差数列递增。此时分布的状态是最佳状态。Preferably, the number of the second needles distributed in a circular array sequentially from the inside to the outside increases in an arithmetic sequence. The state of the distribution at this time is the optimal state.
根据本发明的又一个具体实施和优选方面,第二腔体位于第一腔体的内部,且第一腔体和第二腔体的出口齐平设置。也就是说,在海相纺丝液和岛相纺丝液进入针头组件之前就保持着包裹状态。According to yet another specific implementation and preferred aspect of the present invention, the second cavity is located inside the first cavity, and the outlets of the first cavity and the second cavity are flush with each other. That is to say, the marine-phase spinning solution and the island-phase spinning solution are kept wrapped before they enter the needle assembly.
优选地,第一腔体和第二腔体均呈圆筒状,且第一腔体套设在第二腔体外。这样设置,便于实现海相纺丝液和岛相纺丝液同步挤入第一针头和第二针头。Preferably, both the first cavity and the second cavity are cylindrical, and the first cavity is sleeved outside the second cavity. Such arrangement facilitates the synchronous extrusion of the marine-phase spinning solution and the island-phase spinning solution into the first needle and the second needle.
进一步的,第一腔体包括沿着自身长度方向延伸的前外腔和后外腔,其中前外腔的内径小于后外腔的内径;第二腔体包括沿着自身长度方向延伸的前内腔和后内腔,其中前内腔的内径小于后内腔的内径,前内腔和前外腔的中心线重合设置。这样的布局,才能得到需要注射推力,同时,结构简单,便于安装和实施。Further, the first cavity includes a front external cavity and a rear external cavity extending along its own length direction, wherein the inner diameter of the front external cavity is smaller than the inner diameter of the rear external cavity; the second cavity includes a front inner cavity and a rear inner cavity extending along its own length direction, wherein the inner diameter of the front inner cavity is smaller than the inner diameter of the rear inner cavity, and the centerlines of the front inner cavity and the front outer cavity are coincidently arranged. Only such a layout can obtain the required injection thrust, and at the same time, the structure is simple, which is convenient for installation and implementation.
优选地,前内腔的后端位于前外腔内。Preferably, the rear end of the anterior inner cavity is located in the anterior external cavity.
根据本发明的又一个具体实施和优选方面,注射器还包括沿着圆筒长度方向活动设置的活塞,其中活塞具有与所述第一腔体相匹配的第一顶推端部、及与所述第二腔体相匹配的第二顶推端部,且所述第一顶推端部和所述第二顶推端部能够同步运动以形成注射推力。这样设置,能够实现海相纺丝液和岛相纺丝液的稳定注射,便于控制海岛纤维的成型,提高成型质量。According to yet another specific implementation and preferred aspect of the present invention, the syringe further includes a piston movably arranged along the length direction of the cylinder, wherein the piston has a first pushing end matching the first cavity and a second pushing end matching the second cavity, and the first pushing end and the second pushing end can move synchronously to form an injection thrust. Such setting can realize the stable injection of the sea-phase spinning solution and the island-phase spinning solution, which is convenient for controlling the forming of the sea-island fibers and improving the forming quality.
优选地,注射器还包括与所述活塞相连接的注射泵,注射泵自顶推部件分别与第一顶推端部和所述第二顶推端部对接。这样在同样的力度下实施注射。Preferably, the syringe further includes a syringe pump connected to the piston, and the self-propelling part of the syringe pump is respectively docked with the first pushing end and the second pushing end. In this way, the injection is performed with the same force.
优选地,第一顶推端部呈环状,第二顶推端部呈圆盘状,且第一顶推端部和第二顶推端部对齐设置。保持同步,有利于注射实施。Preferably, the first pushing end is ring-shaped, the second pushing end is disc-shaped, and the first pushing end and the second pushing end are aligned. Keeping in sync facilitates injection implementation.
根据本发明的又一个具体实施和优选方面,第一针头自第一腔体的出口水平向外延伸,多个第二针头自第二腔体的出口水平向外延伸。这样一来,注射推力方向和纺丝液射出方向保持一致,有利于稳定地注射。According to yet another specific implementation and preferred aspect of the present invention, the first needles extend horizontally outward from the outlet of the first cavity, and the plurality of second needles extend horizontally outward from the outlet of the second cavity. In this way, the injection thrust direction is consistent with the spinning dope injection direction, which is conducive to stable injection.
优选地,多个所述第二针头的进液端部之间自侧壁相互密封联结设置,且多个所述第二针头的出液端部之间隔开设置,所述海相纺丝液进入所述第一腔体并包裹在每个所述第二针头的外周。这样设置,保证岛相纺丝液进入每个第二针头,以便于海岛纤维的形成;同时,能够有效防止海相纺丝液回流至第二腔体。Preferably, the liquid inlet ends of the plurality of second needles are sealed and connected to each other from the side walls, and the liquid outlet ends of the plurality of second needles are spaced apart, and the marine spinning solution enters the first cavity and wraps around the periphery of each second needle. This arrangement ensures that the island-phase spinning solution enters each second needle to facilitate the formation of sea-island fibers; at the same time, it can effectively prevent the sea-phase spinning solution from flowing back into the second cavity.
根据本发明的又一个具体实施和优选方面,凝固单元还包括设置在所述凝固浴中的多个张力辊,其中多个所述张力辊在所述凝固浴的高度方向上下错开设置。这样设置,有效增加海岛纤维的张力,便于收集。According to yet another specific implementation and preferred aspect of the present invention, the coagulation unit further includes a plurality of tension rollers arranged in the coagulation bath, wherein the plurality of tension rollers are arranged staggered up and down in the height direction of the coagulation bath. Such setting can effectively increase the tension of the sea-island fibers and facilitate collection.
此外,收集单元还包括风干部件,其中所述风干部件靠近所述收集辊设置并向所述收集辊方向吹送气流。这样设置,使纤维进行初干燥,防止收集纤维粘连,可实现连续湿法制备海岛纤维。In addition, the collecting unit further includes an air-drying component, wherein the air-drying component is arranged close to the collecting roller and blows airflow toward the collecting roller. Such arrangement enables the fibers to be initially dried, prevents the fibers from being collected from sticking together, and can realize continuous wet preparation of sea-island fibers.
本发明的另一技术方案:一种用于海岛纤维的制备工艺,其采用了上述的湿法纺丝设备,且包括如下步骤:Another technical solution of the present invention: a preparation process for sea-island fibers, which uses the above-mentioned wet spinning equipment, and includes the following steps:
S1、将海相纺丝液和岛相纺丝液对应导入第一腔体和第二腔体内;S1, introducing the marine phase spinning solution and the island phase spinning solution into the first cavity and the second cavity correspondingly;
S2、将海相纺丝液和岛相纺丝液分别自第一针头和第二针头同步挤入凝固浴,使得海相纺丝液包裹在岛相纺丝液的外周并在凝固浴中凝固形成海岛纤维;S2. Squeeze the marine-phase spinning solution and the island-phase spinning solution into the coagulation bath synchronously from the first needle and the second needle, so that the marine-phase spinning solution is wrapped around the periphery of the island-phase spinning solution and coagulated in the coagulation bath to form sea-island fibers;
S3、将形成的海岛纤维牵引至收集辊并进行卷收。S3. Pulling the formed sea-island fibers to the collection roller and winding them up.
由于以上技术方案的实施,本发明与现有技术相比具有如下优点:Due to the implementation of the above technical solutions, the present invention has the following advantages compared with the prior art:
本发明采用湿法纺丝制备海岛纤维,设备结构简单、可靠,操作方便,这样一来,制备过程安全性高,成本低;同时,能够稳定把控纺丝液在凝固浴中的凝固过程,保证生成的海岛纤维满足制备要求。The present invention adopts wet spinning to prepare sea-island fibers, and the equipment structure is simple, reliable, and easy to operate. In this way, the preparation process has high safety and low cost; at the same time, it can stably control the coagulation process of the spinning solution in the coagulation bath to ensure that the generated sea-island fibers meet the preparation requirements.
附图说明Description of drawings
图1为本发明用于海岛纤维的湿法纺丝设备的结构示意图;Fig. 1 is the structural representation of the wet spinning equipment that the present invention is used for sea-island fiber;
图2为图1中针头组件的放大示意图;Figure 2 is an enlarged schematic view of the needle assembly in Figure 1;
图3为图2的右视示意图;Fig. 3 is the right view diagram of Fig. 2;
其中:1、注射单元;10、注射器;101、第一腔体;102、第二腔体;103、 活塞;a1、第一顶推端部;a2、第二顶推端部;104、注射泵;11、针头组件;111、第一针头;112、第二针头;Among them: 1. injection unit; 10. syringe; 101. first cavity; 102. second cavity; 103. piston; a1. first pushing end; a2. second pushing end; 104. injection pump; 11. needle assembly; 111. first needle;
2、凝固单元;20、凝固浴;21、张力辊;2. Coagulation unit; 20. Coagulation bath; 21. Tension roller;
3、收集单元;30、收集辊;31、风干部件。3. Collecting unit; 30. Collecting roller; 31. Air-dried parts.
具体实施方式Detailed ways
为使本申请的上述目的、特征和优点能够更加明显易懂,下面结合附图对本申请的具体实施方式做详细的说明。在下面的描述中阐述了很多具体细节以便于充分理解本申请。但是本申请能够以很多不同于在此描述的其它方式来实施,本领域技术人员可以在不违背本申请内涵的情况下做类似改进,因此本申请不受下面公开的具体实施例的限制。In order to make the above-mentioned purpose, features and advantages of the present application more obvious and understandable, the specific implementation manners of the present application will be described in detail below in conjunction with the accompanying drawings. In the following description, numerous specific details are set forth in order to provide a thorough understanding of the application. However, the present application can be implemented in many other ways different from those described here, and those skilled in the art can make similar improvements without departing from the connotation of the present application, so the present application is not limited by the specific embodiments disclosed below.
在本申请的描述中,需要理解的是,术语“中心”、“纵向”、“横向”、“长度”、“宽度”、“厚度”、“上”、“下”、“前”、“后”、“左”、“右”、“竖直”、“水平”、“顶”、“底”、“内”、“外”、“顺时针”、“逆时针”、“轴向”、“径向”、“周向”等指示的方位或位置关系为基于附图所示的方位或位置关系,仅是为了便于描述本申请和简化描述,而不是指示或暗示所指的装置或元件必须具有特定的方位、以特定的方位构造和操作,因此不能理解为对本申请的限制。In the description of the present application, it should be understood that the orientations or positional relationships indicated by the terms "center", "longitudinal", "transverse", "length", "width", "thickness", "upper", "lower", "front", "rear", "left", "right", "vertical", "horizontal", "top", "bottom", "inner", "outer", "clockwise", "counterclockwise", "axial", "radial", "circumferential" are based on the drawings. The orientation or positional relationship is only for the convenience of describing the present application and simplifying the description, but does not indicate or imply that the referred device or element must have a specific orientation, be constructed and operated in a specific orientation, and therefore cannot be construed as a limitation of the present application.
此外,术语“第一”、“第二”仅用于描述目的,而不能理解为指示或暗示相对重要性或者隐含指明所指示的技术特征的数量。由此,限定有“第一”、“第二”的特征可以明示或者隐含地包括至少一个该特征。在本申请的描述中,“多个”的含义是至少两个,例如两个,三个等,除非另有明确具体的限定。In addition, the terms "first" and "second" are used for descriptive purposes only, and cannot be interpreted as indicating or implying relative importance or implicitly specifying the quantity of indicated technical features. Thus, the features defined as "first" and "second" may explicitly or implicitly include at least one of these features. In the description of the present application, "plurality" means at least two, such as two, three, etc., unless otherwise specifically defined.
在本申请中,除非另有明确的规定和限定,术语“安装”、“相连”、“连接”、“固定”等术语应做广义理解,例如,可以是固定连接,也可以是可拆卸连接,或成一体;可以是机械连接,也可以是电连接;可以是直接相连,也可以通过中间媒介间接相连,可以是两个元件内部的连通或两个元件的相互作用关系,除非另有明确的限定。对于本领域的普通技术人员而言,可以根据具体情况理解上述术语在本申请中的具体含义。In this application, unless otherwise clearly specified and limited, the terms "installation", "connection", "connection", "fixation" and other terms should be understood in a broad sense, for example, it may be a fixed connection, a detachable connection, or an integral body; it may be a mechanical connection or an electrical connection; it may be a direct connection or an indirect connection through an intermediate medium, and it may be the internal communication of two components or the interaction relationship between two components, unless otherwise clearly defined. Those of ordinary skill in the art can understand the specific meanings of the above terms in this application according to specific situations.
在本申请中,除非另有明确的规定和限定,第一特征在第二特征“上”或“下”可以是第一和第二特征直接接触,或第一和第二特征通过中间媒介间接接触。而且,第一特征在第二特征“之上”、“上方”和“上面”可是第一特 征在第二特征正上方或斜上方,或仅仅表示第一特征水平高度高于第二特征。第一特征在第二特征“之下”、“下方”和“下面”可以是第一特征在第二特征正下方或斜下方,或仅仅表示第一特征水平高度小于第二特征。In the present application, unless otherwise specified and limited, a first feature being "on" or "under" a second feature may mean that the first and second features are in direct contact, or the first and second features are in indirect contact through an intermediary. Moreover, "above", "above" and "above" the first feature on the second feature may mean that the first feature is directly above or obliquely above the second feature, or simply means that the first feature is horizontally higher than the second feature. "Below", "beneath" and "beneath" the first feature may mean that the first feature is directly below or obliquely below the second feature, or simply means that the first feature is less horizontally than the second feature.
需要说明的是,当元件被称为“固定于”或“设置于”另一个元件,它可以直接在另一个元件上或者也可以存在居中的元件。当一个元件被认为是“连接”另一个元件,它可以是直接连接到另一个元件或者可能同时存在居中元件。本文所使用的术语“垂直的”、“水平的”、“上”、“下”、“左”、“右”以及类似的表述只是为了说明的目的,并不表示是唯一的实施方式。It should be noted that when an element is referred to as being “fixed on” or “disposed on” another element, it may be directly on the other element or there may be an intervening element. When an element is referred to as being "connected to" another element, it can be directly connected to the other element or intervening elements may also be present. As used herein, the terms "vertical", "horizontal", "upper", "lower", "left", "right" and similar expressions are for the purpose of illustration only and are not intended to represent the only embodiments.
如图1所示,本实施例的用于海岛纤维的湿法纺丝设备,其包括注射单元1、凝固单元2、及收集单元3。As shown in FIG. 1 , the wet spinning equipment for sea-island fibers in this embodiment includes an injection unit 1 , a coagulation unit 2 , and a collection unit 3 .
具体的,注射单元1包括注射器10、及与注射器10相连通的针头组件11。Specifically, the injection unit 1 includes a syringe 10 and a needle assembly 11 communicating with the syringe 10 .
注射器10包括第一腔体101、第二腔体102、活塞103、及注射泵104。The syringe 10 includes a first cavity 101 , a second cavity 102 , a piston 103 , and a syringe pump 104 .
这样设置,结构简单,便于安装和实施。Such arrangement has a simple structure and is convenient for installation and implementation.
第二腔体102位于第一腔体101的内部,且第一腔体101和第二腔体102的出口齐平设置。也就是说,在海相纺丝液和岛相纺丝液进入针头组件之前就保持着包裹状态。The second cavity 102 is located inside the first cavity 101 , and the outlets of the first cavity 101 and the second cavity 102 are flush with each other. That is to say, the marine-phase spinning solution and the island-phase spinning solution are kept wrapped before they enter the needle assembly.
第一腔体101和第二腔体102均呈圆筒状,且第一腔体101套设在第二腔体102外,并且第一腔体101和第二腔体102互不连通设置,其中海相纺丝液和岛相纺丝液分别填充在第一腔体101和第二腔体102内。这样设置,便于实现海相纺丝液和岛相纺丝液同步挤入第一针头和第二针头。Both the first cavity 101 and the second cavity 102 are cylindrical, and the first cavity 101 is sleeved outside the second cavity 102, and the first cavity 101 and the second cavity 102 are not connected to each other, wherein the marine phase spinning liquid and the island phase spinning liquid are respectively filled in the first cavity 101 and the second cavity 102. Such arrangement facilitates the synchronous extrusion of the marine-phase spinning solution and the island-phase spinning solution into the first needle and the second needle.
第一腔体101包括沿着自身长度方向延伸的前外腔和后外腔,其中前外腔的内径小于后外腔的内径。The first cavity 101 includes an anterior external cavity and a rear external cavity extending along its length direction, wherein the inner diameter of the anterior external cavity is smaller than the internal diameter of the rear external cavity.
第二腔体102包括沿着自身长度方向延伸的前内腔和后内腔,其中前内腔的内径小于后内腔的内径,前内腔和前外腔的中心线重合设置。这样的布局,才能得到需要注射推力,同时,结构简单,便于安装和实施。The second cavity 102 includes a front inner cavity and a rear inner cavity extending along its length direction, wherein the inner diameter of the front inner cavity is smaller than the inner diameter of the rear inner cavity, and the centerlines of the front inner cavity and the front outer cavity are coincidently arranged. Only such a layout can obtain the required injection thrust, and at the same time, the structure is simple, which is convenient for installation and implementation.
前内腔的后端位于前外腔内。具体的,活塞103沿着纺丝液喷射方向活动设置,且具有贴合在第一腔体101内壁与第二腔体102外壁之间的第一顶推端部a1、及贴合在第二腔体102内壁的第二顶推端部a2。The rear end of the anterior lumen is located in the anterior exocrine. Specifically, the piston 103 is movable along the spinning liquid injection direction, and has a first pushing end a1 attached between the inner wall of the first cavity 101 and the outer wall of the second cavity 102, and a second pushing end a2 attached to the inner wall of the second cavity 102.
注射泵104连接在活塞103的外端部,并推动活塞103沿着水平方向运动,其中注射泵104的推进速度设置为0~15mL/h。这样设置,能够实现海相纺丝液和岛相纺丝液的稳定注射,便于控制海岛纤维的成型,提高成型质量。The syringe pump 104 is connected to the outer end of the piston 103 and pushes the piston 103 to move along the horizontal direction, wherein the advancing speed of the syringe pump 104 is set at 0-15 mL/h. Such setting can realize the stable injection of the sea-phase spinning solution and the island-phase spinning solution, which is convenient for controlling the forming of the sea-island fibers and improving the forming quality.
结合图2和图3所示,针头组件11包括连通第一腔体101的第一针头111、及连通第二腔体102的第二针头112,其中第二针头112有多个并间隔分布在第一针头111的内部,自第一针头111和第二针头112同步挤出的海相纺丝液将多股岛相纺丝液包裹并注入凝固单元2。As shown in FIG. 2 and FIG. 3 , the needle assembly 11 includes a first needle 111 connected to the first cavity 101 and a second needle 112 connected to the second cavity 102 , wherein there are multiple second needles 112 distributed at intervals inside the first needle 111 , and the marine phase spinning solution extruded synchronously from the first needle 111 and the second needle 112 wraps the multi-strand island phase spinning solution and injects it into the coagulation unit 2 .
具体的,第一针头111自自第一腔体101的出口水平向外延伸,多个第二针头112自第二腔体102的出口水平向外延伸,其中多个第二针头112的进液端部之间自侧壁相互密封联结设置,且多个第二针头112的出液端部之间隔开设置,海相纺丝液进入第一腔体101并包裹在每个第二针头112的外周。这样设置,保证岛相纺丝液进入每个第二针头,以便于海岛纤维的形成;同时,能够有效防止海相纺丝液回流至第二腔体。Specifically, the first needle 111 extends horizontally outward from the outlet of the first cavity 101, and a plurality of second needles 112 extends horizontally outward from the outlet of the second cavity 102, wherein the liquid inlet ends of the plurality of second needles 112 are sealed and connected to each other from the side wall, and the liquid outlet ends of the plurality of second needles 112 are spaced apart, and the marine spinning solution enters the first cavity 101 and is wrapped around the periphery of each second needle 112. This arrangement ensures that the island-phase spinning solution enters each second needle to facilitate the formation of sea-island fibers; at the same time, it can effectively prevent the sea-phase spinning solution from flowing back into the second cavity.
同时,每个第二针头112的出液端部与第一针头111的出液端部对齐且插入凝固单元2中,其中,第一针头111的直径为d1,其中1mm≤d1≤5mm;第二针头112的直径为d2,其中0.2mm≤d2≤1mm。At the same time, the liquid outlet end of each second needle 112 is aligned with the liquid outlet end of the first needle 111 and inserted into the coagulation unit 2, wherein the diameter of the first needle 111 is d1, where 1mm≤d1≤5mm; the diameter of the second needle 112 is d2, where 0.2mm≤d2≤1mm.
第一针头111和第二针头112的进液端部齐平设置;第一针头111和第二针头112的出液端部的齐平设置。也就是说,两者的长度保持相等的前提下实施包裹。The liquid inlet ends of the first needle 111 and the second needle 112 are arranged flush; the liquid outlet ends of the first needle 111 and the second needle 112 are arranged flush. That is to say, the wrapping is carried out under the premise that the lengths of the two remain equal.
多个第二针头112以一个位于第一针头111的中心、剩余的第二针头112绕着中心第二针头112由内向外依次呈环形阵列分布。这样的分布才能起到最佳的包覆效果。A plurality of second needles 112 are located in the center of the first needle 111 , and the remaining second needles 112 are distributed around the central second needle 112 in order from inside to outside in an annular array. Such a distribution can achieve the best coating effect.
自内向外依次呈环形阵列分布的各第二针头112数量呈等差数列递增。此时分布的状态是最佳状态。The number of the second needles 112 distributed in a circular array sequentially from the inside to the outside increases in an arithmetic sequence. The state of the distribution at this time is the optimal state.
本例中,环形阵列有三个,由内向外形成的第一个环形阵列有6个第二针头112,第二个环形阵列有9个第二针头112,第二个环形阵列有12个第二针头112,也就是说,由内向外的三个环形阵列的第二针头112的数量每向外一个环形阵列就增加3个,因此,呈等差数列递增。In this example, there are three annular arrays, the first annular array formed from the inside to the outside has 6 second needles 112, the second annular array has 9 second needles 112, and the second annular array has 12 second needles 112, that is to say, the number of the second needles 112 of the three annular arrays from the inside to the outside increases by 3 every time one annular array goes outward, therefore, it increases in an arithmetic sequence.
本例中,凝固单元2包括与注射单元1相衔接的凝固浴20、及分布在凝固浴20内部和上方的四个张力辊21,其中第一针头111和第二针头112分别自出液端部插入凝固浴20中。In this example, the coagulation unit 2 includes a coagulation bath 20 connected to the injection unit 1, and four tension rollers 21 distributed inside and above the coagulation bath 20, wherein the first needle 111 and the second needle 112 are respectively inserted into the coagulation bath 20 from the liquid outlet.
具体的,第一针头111和第二针头112的进液端部位于凝固浴20外形成外露段;第一针头111和第二针头112的出液端部位于凝固浴20内形成内插段,其中外露段的长度小于内插段的长度。这样一来,在外露段海相纺丝液就 能够包裹在第二针头外周,且进入凝固浴后保持着包裹状态直至自出液端部后海相纺丝液将岛相纺丝液包覆形成海岛纤维。Specifically, the liquid inlet ends of the first needle head 111 and the second needle head 112 are located outside the coagulation bath 20 to form an exposed section; the liquid outlet ends of the first needle head 111 and the second needle head 112 are located in the coagulation bath 20 to form an inner section, wherein the length of the exposed section is less than the length of the inner section. In this way, the marine-phase spinning solution can be wrapped around the outer periphery of the second needle in the exposed section, and after entering the coagulation bath, the wrapping state is maintained until the island-phase spinning solution is covered by the marine-phase spinning solution from the liquid outlet end to form sea-island fibers.
同时,四个张力辊21中,相邻两个张力辊21上下错开设置。这样设置,有效增加海岛纤维的张力,便于收集。At the same time, among the four tension rollers 21, two adjacent tension rollers 21 are staggered up and down. Such setting can effectively increase the tension of the sea-island fibers and facilitate collection.
同时,四个张力辊21自左向右速度依次递增设置。Simultaneously, the speed of four tension rollers 21 increases successively from left to right.
本例中,收集单元3包括用于收集海岛纤维的收集辊30、及风干部件31。In this example, the collection unit 3 includes a collection roller 30 for collecting sea-island fibers and an air-drying unit 31 .
具体的,收集辊30设置在凝固浴20的右上方,且收集辊30能够左右移动。这样设置,便于收集纤维。Specifically, the collecting roller 30 is arranged on the upper right of the coagulation bath 20, and the collecting roller 30 can move left and right. This arrangement facilitates the collection of fibers.
具体的,风干部件31有两个,且分别沿着竖直方向和水平方向向缠绕在收集辊30上的海岛纤维吹送气流。这样设置,使纤维进行初干燥,防止收集纤维粘连,可实现连续湿法制备海岛纤维。Specifically, there are two air-drying components 31 , and airflows are respectively blown to the sea-island fibers wound on the collecting roller 30 along the vertical direction and the horizontal direction. Such arrangement enables the fibers to be initially dried, prevents the fibers from being collected from sticking together, and can realize continuous wet preparation of sea-island fibers.
综上,本实施例的实施过程如下:In summary, the implementation process of this embodiment is as follows:
S1、将海相纺丝液和岛相纺丝液对应导入第一腔体101和第二腔体102内;S1, introducing the marine phase spinning solution and the island phase spinning solution into the first cavity 101 and the second cavity 102 correspondingly;
S2、开启注射泵104,在注射泵104的驱动下,活塞103将海相纺丝液和岛相纺丝液分别自第一针头111和第二针头112同步挤入凝固浴20,使得海相纺丝液包裹在岛相纺丝液的外周并在凝固浴20中凝固形成海岛纤维;S2. Turn on the syringe pump 104. Driven by the syringe pump 104, the piston 103 squeezes the marine-phase spinning solution and the island-phase spinning solution from the first needle 111 and the second needle 112 into the coagulation bath 20 synchronously, so that the marine-phase spinning solution is wrapped around the periphery of the island-phase spinning solution and coagulated in the coagulation bath 20 to form sea-island fibers;
S3、将形成的海岛纤维依次经过四个张力辊21后牵引至收集辊30处进行卷收,并在收集辊30卷收的同时,采用风干部件31分别自收集辊30的上方和一侧向海岛纤维吹送干燥气流。S3. The formed sea-island fibers pass through four tension rollers 21 in turn and are drawn to the collection roller 30 for winding, and while the collection roller 30 is being wound, air-drying components 31 are used to blow dry air to the sea-island fibers from above and one side of the collection roller 30 respectively.
综上,本实施具有以下优势:In summary, this implementation has the following advantages:
1、采用湿法纺丝制备海岛纤维,设备结构简单、可靠,操作方便,这样一来,制备过程安全性高,成本低;1. Wet spinning is used to prepare sea-island fibers. The equipment structure is simple, reliable, and easy to operate. In this way, the preparation process has high safety and low cost;
2、能够稳定把控纺丝液在凝固浴中的凝固过程,保证生成的海岛纤维满足制备要求;2. It can stably control the coagulation process of the spinning solution in the coagulation bath to ensure that the generated sea-island fibers meet the preparation requirements;
3、多个第二针头的进液端部之间密封联结,能够保证岛相纺丝液进入每个第二针头,以便于海岛纤维的形成;同时,能够有效防止海相纺丝液回流至第二腔体;3. The liquid inlet ends of multiple second needles are sealed and connected to ensure that the island-phase spinning solution enters each second needle to facilitate the formation of sea-island fibers; at the same time, it can effectively prevent the sea-phase spinning solution from flowing back into the second cavity;
4、通过风干部件,能够使纤维进行初干燥,防止收集纤维粘连,可实现连续湿法制备海岛纤维。4. By air-drying the parts, the fibers can be pre-dried to prevent the collection of fibers from sticking together, and the sea-island fibers can be prepared by continuous wet method.
以上对本发明做了详尽的描述,其目的在于让熟悉此领域技术的人士能够 了解本发明的内容并加以实施,并不能以此限制本发明的保护范围,凡根据本发明的精神实质所作的等效变化或修饰,都应涵盖在本发明的保护范围内。The present invention has been described in detail above, and its purpose is to allow those skilled in the art to understand the content of the present invention and implement it, and can not limit the protection scope of the present invention with this, and all equivalent changes or modifications made according to the spirit of the present invention should be included in the protection scope of the present invention.

Claims (17)

  1. 一种用于海岛纤维的湿法纺丝设备,其包括:A kind of wet spinning equipment for sea-island fiber, it comprises:
    注射单元,其包括注射器、及与所述注射器相连通的针头组件;an injection unit, which includes a syringe, and a needle assembly communicating with the syringe;
    凝固单元,其包括与所述注射单元相衔接的凝固浴,其中所述凝固浴用于纺丝液的凝固;A coagulation unit comprising a coagulation bath connected to the injection unit, wherein the coagulation bath is used for coagulation of the spinning solution;
    收集单元,其与所述凝固浴相衔接设置,并包括用于收集海岛纤维的收集辊,a collection unit, which is connected to the coagulation bath and includes a collection roller for collecting sea-island fibers,
    其特征在于:It is characterized by:
    所述注射器包括互不连通的第一腔体和第二腔体,所述第二腔体位于所述第一腔体的内部,且所述第一腔体和所述第二腔体的出口齐平设置,所述第一腔体和所述第二腔体均呈圆筒状,且所述第一腔体的中心线与所述第二腔体的中心线重合设置;The syringe includes a first cavity and a second cavity that are not connected to each other, the second cavity is located inside the first cavity, and the outlets of the first cavity and the second cavity are arranged flush, the first cavity and the second cavity are both cylindrical, and the centerline of the first cavity is arranged to coincide with the centerline of the second cavity;
    所述注射器还包括沿着纺丝液喷射方向活动设置的活塞与所述活塞相连接的注射泵,其中所述活塞具有与所述第一腔体相匹配的第一顶推端部、及与所述第二腔体相匹配的第二顶推端部,所述注射泵推动所述活塞沿着纺丝液喷射方向运动;The injector also includes a piston movably arranged along the spinning solution injection direction and an injection pump connected to the piston, wherein the piston has a first pushing end matching the first cavity and a second pushing end matching the second cavity, and the injection pump pushes the piston to move along the spinning solution injection direction;
    海相纺丝液和岛相纺丝液分别填充在所述第一腔体和第二腔体内,所述针头组件包括连通所述第一腔体的第一针头、及连通所述第二腔体的第二针头,其中所述第一针头自所述第一腔体的出口水平向外延伸,所述第二针头有多个,多个所述第二针头自所述第二腔体的出口水平向外延伸,且多个所述第二针头并间隔分布在所述第一针头的内部,其中每个所述第二针头的出液端部与所述第一针头的出液端部对齐且插入所述凝固浴中,多个所述第二针头的进液端部之间自侧壁相互密封联结设置,且多个所述第二针头的出液端部之间隔开设置,所述海相纺丝液进入所述第一腔体并包裹在每个所述第二针头的外周,自所述第一针头和所述第二针头同步挤出的所述海相纺丝液将多股所述岛相纺丝液包裹并注入所述凝固浴;The marine-phase spinning solution and the island-phase spinning solution are respectively filled in the first cavity and the second cavity. The needle assembly includes a first needle connected to the first cavity and a second needle connected to the second cavity, wherein the first needle extends horizontally from the outlet of the first cavity, and there are multiple second needles. The liquid outlet ends of the needles are aligned and inserted into the coagulation bath, the liquid inlet ends of the plurality of second needles are sealed and connected to each other from the side wall, and the liquid outlet ends of the plurality of second needles are spaced apart, the marine phase spinning solution enters the first cavity and wraps around the periphery of each second needle, and the marine phase spinning solution extruded synchronously from the first needles and the second needles wraps multiple strands of the island phase spinning solution and injects them into the coagulation bath;
    所述凝固单元还包括设置在所述凝固浴中的多个张力辊,其中相邻两个所述张力辊上下错开设置;所述收集单元还包括风干部件,其中所述风干部件靠近所述收集辊设置并向所述收集辊方向吹送气流。The coagulation unit also includes a plurality of tension rollers arranged in the coagulation bath, wherein two adjacent tension rollers are staggered up and down; the collection unit also includes air-drying components, wherein the air-drying components are arranged close to the collection rollers and blow airflow toward the collection rollers.
  2. 一种用于海岛纤维的湿法纺丝设备,其包括:A kind of wet spinning equipment for sea-island fiber, it comprises:
    注射单元,其包括注射器、针头组件;Injection unit comprising syringe, needle assembly;
    凝固单元,其包括与针头组件端部相相衔接的凝固浴;a coagulation unit comprising a coagulation bath coupled to the end of the needle assembly;
    收集单元,其包括用于收集凝固后海岛纤维的收集辊,a collecting unit comprising collecting rollers for collecting the coagulated sea-island fibers,
    其特征在于:It is characterized by:
    所述注射器包括具有分别填充海相纺丝液和岛相纺丝液的第一腔体和第二腔体,所述第一腔体和所述第二腔体互不连通,所述针头组件自出液端部插入所述凝固浴内,且包括第一针头和第二针头,其中所述第一针头内部形成与所述第一腔体连通的海相纺丝液通道,所述第二针头有多个并间隔分布在所述第一针头的海相纺丝液通道内部,各所述第二针头内部形成与所述第二腔体连通的岛相纺丝液通道,自所述第一针头和所述第二针头同步挤出的海相纺丝液将多股岛相纺丝液包裹并注入所述凝固浴。The syringe includes a first cavity and a second cavity respectively filled with the marine spinning solution and the island spinning solution, the first cavity and the second cavity are not connected to each other, the needle assembly is inserted into the coagulation bath from the liquid outlet end, and includes a first needle and a second needle, wherein a marine spinning solution channel communicating with the first cavity is formed inside the first needle, and there are multiple second needles distributed in the marine spinning solution channel of the first needle. The island-phase spinning solution channels communicated with each other, and the marine-phase spinning solution extruded synchronously from the first needle and the second needle wraps multiple island-phase spinning solutions and injects them into the coagulation bath.
  3. 根据权利要求2所述的用于海岛纤维的湿法纺丝设备,其特征在于:所述第一针头和所述第二针头的进液端部位于所述凝固浴外形成外露段;所述第一针头和所述第二针头的出液端部位于所述凝固浴内形成内插段,其中所述外露段的长度小于内插段的长度。The wet spinning equipment for sea-island fibers according to claim 2, characterized in that: the liquid inlet ends of the first needle and the second needle are located outside the coagulation bath to form an exposed section; the liquid outlet ends of the first needle and the second needle are located in the coagulation bath to form an inner section, wherein the length of the exposed section is shorter than the length of the inner insertion section.
  4. 根据权利要求3所述的用于海岛纤维的湿法纺丝设备,其特征在于:所述第一针头和所述第二针头的进液端部齐平设置;所述第一针头和所述第二针头的出液端部的齐平设置。The wet spinning equipment for sea-island fibers according to claim 3, characterized in that: the liquid inlet ends of the first needle and the second needle are arranged flush; the liquid outlet ends of the first needle and the second needle are arranged flush.
  5. 根据权利要求3所述的用于海岛纤维的湿法纺丝设备,其特征在于:多个所述第二针头以一个位于所述第一针头的中心、剩余的所述第二针头绕着中心所述第二针头由内向外依次呈环形阵列分布。The wet spinning equipment for sea-island fibers according to claim 3, characterized in that one of the plurality of second needles is located at the center of the first needle, and the remaining second needles are distributed in a circular array around the center from inside to outside.
  6. 根据权利要求5所述的用于海岛纤维的湿法纺丝设备,其特征在于:自内向外依次呈环形阵列分布的各所述第二针头数量呈等差数列递增。The wet spinning equipment for sea-island fibers according to claim 5, characterized in that: the number of the second needles distributed in a circular array sequentially from the inside to the outside increases in an arithmetic sequence.
  7. 根据权利要求2所述的用于海岛纤维的湿法纺丝设备,其特征在于:所述第二腔体位于所述第一腔体的内部,且所述第一腔体和所述第二腔体的出口齐平设置。The wet spinning equipment for sea-island fibers according to claim 2, characterized in that: the second cavity is located inside the first cavity, and outlets of the first cavity and the second cavity are flush with each other.
  8. 根据权利要求7所述的用于海岛纤维的湿法纺丝设备,其特征在于:所述第一腔体和所述第二腔体均呈圆筒状,且所述第一腔体套设在所述第二腔体外。The wet spinning equipment for sea-island fibers according to claim 7, characterized in that: the first cavity and the second cavity are both cylindrical, and the first cavity is sleeved outside the second cavity.
  9. 根据权利要求8所述的用于海岛纤维的湿法纺丝设备,其特征在于:所述的第一腔体包括沿着自身长度方向延伸的前外腔和后外腔,其中所述前外 腔的内径小于后外腔的内径;所述第二腔体包括沿着自身长度方向延伸的前内腔和后内腔,其中所述前内腔的内径小于后内腔的内径,所述前内腔和所述前外腔的中心线重合设置。The wet spinning equipment for sea-island fibers according to claim 8, characterized in that: the first cavity includes a front outer cavity and a rear outer cavity extending along its own length direction, wherein the inner diameter of the front outer cavity is smaller than the inner diameter of the rear outer cavity; the second cavity includes a front inner cavity and a rear inner cavity extending along the length direction of itself, wherein the inner diameter of the front inner cavity is smaller than the inner diameter of the rear inner cavity, and the centerlines of the front inner cavity and the front outer cavity are coincident.
  10. 根据权利要求9所述的用于海岛纤维的湿法纺丝设备,其特征在于:所述前内腔的后端位于所述前外腔内。The wet spinning equipment for sea-island fibers according to claim 9, characterized in that: the rear end of the front inner cavity is located in the front outer cavity.
  11. 根据权利要求8所述的用于海岛纤维的湿法纺丝设备,其特征在于:所述注射器还包括沿着圆筒长度方向活动设置的活塞,其中所述活塞具有与所述第一腔体相匹配的第一顶推端部、及与所述第二腔体相匹配的第二顶推端部,且所述第一顶推端部和所述第二顶推端部能够同步运动以形成注射推力。The wet spinning equipment for sea-island fibers according to claim 8, wherein the injector further comprises a piston movably arranged along the length direction of the cylinder, wherein the piston has a first pushing end matching the first cavity and a second pushing end matching the second cavity, and the first pushing end and the second pushing end can move synchronously to form an injection thrust.
  12. 根据权利要求11所述的用于海岛纤维的湿法纺丝设备,其特征在于:所述注射器还包括与所述活塞相连接的注射泵,所述注射泵自顶推部件分别与所述第一顶推端部和所述第二顶推端部对接。The wet spinning equipment for sea-island fibers according to claim 11, characterized in that: the syringe further comprises a syringe pump connected to the piston, and the syringe pump is respectively docked with the first pushing end and the second pushing end from a pushing part.
  13. 根据权利要求11所述的用于海岛纤维的湿法纺丝设备,其特征在于:所述第一顶推端部呈环状,所述第二顶推端部呈圆盘状,且第一顶推端部和第二顶推端部对齐设置。The wet spinning equipment for sea-island fibers according to claim 11, wherein the first pushing end is ring-shaped, the second pushing end is disc-shaped, and the first pushing end and the second pushing end are aligned.
  14. 根据权利要求2所述的用于海岛纤维的湿法纺丝设备,其特征在于:所述第一针头自所述第一腔体的出口水平向外延伸,多个所述第二针头自所述第二腔体的出口水平向外延伸。15.根据权利要求14所述的用于海岛纤维的湿法纺丝设备,其特征在于:多个所述第二针头的进液端部之间自侧壁相互密封联结设置,且多个所述第二针头的出液端部之间隔开设置,所述海相纺丝液进入所述第一腔体并包裹在每个所述第二针头的外周。The wet spinning equipment for sea-island fibers according to claim 2, wherein the first needles extend horizontally outward from the outlet of the first cavity, and the plurality of second needles extend horizontally outward from the outlet of the second cavity. 15. The wet spinning equipment for sea-island fibers according to claim 14, characterized in that: the liquid inlet ends of the plurality of second needles are sealed and connected to each other from the side wall, and the liquid outlet ends of the plurality of second needles are spaced apart, and the marine phase spinning solution enters the first cavity and is wrapped around the periphery of each of the second needles.
  15. 根据权利要求2所述的用于海岛纤维的湿法纺丝设备,其特征在于:所述凝固单元还包括设置在所述凝固浴中的多个张力辊,其中多个所述张力辊在所述凝固浴的高度方向上下错开设置。The wet spinning equipment for sea-island fibers according to claim 2, wherein the coagulation unit further comprises a plurality of tension rollers arranged in the coagulation bath, wherein the plurality of tension rollers are arranged staggered up and down in the height direction of the coagulation bath.
  16. 根据权利要求2所述的用于海岛纤维的湿法纺丝设备,其特征在于:所述收集单元还包括风干部件,其中所述风干部件靠近所述收集辊设置并向所述收集辊方向吹送气流。The wet spinning equipment for sea-island fibers according to claim 2, wherein the collection unit further includes an air drying unit, wherein the air drying unit is arranged close to the collection roller and blows air toward the collection roller.
  17. 一种用于海岛纤维的制备工艺,其特征在于:其采用权利要求1至17中任一项所述的用于海岛纤维的湿法纺丝设备,且包括如下步骤:A preparation process for sea-island fibers, characterized in that it adopts the wet spinning equipment for sea-island fibers according to any one of claims 1 to 17, and comprises the following steps:
    S1、将海相纺丝液和岛相纺丝液对应导入第一腔体和第二腔体内;S1, introducing the marine phase spinning solution and the island phase spinning solution into the first cavity and the second cavity correspondingly;
    S2、将海相纺丝液和岛相纺丝液分别自第一针头和第二针头同步挤入凝固浴,使得海相纺丝液包裹在岛相纺丝液的外周并在凝固浴中凝固形成海岛纤维;S2. Squeeze the marine-phase spinning solution and the island-phase spinning solution into the coagulation bath synchronously from the first needle and the second needle, so that the marine-phase spinning solution is wrapped around the periphery of the island-phase spinning solution and coagulated in the coagulation bath to form sea-island fibers;
    S3、将形成的海岛纤维牵引至收集辊并进行卷收。S3. Pulling the formed sea-island fibers to the collection roller and winding them up.
PCT/CN2022/141916 2022-01-20 2022-12-26 Wet spinning apparatus and preparation process for sea-island fibers WO2023138310A1 (en)

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Families Citing this family (1)

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Publication number Priority date Publication date Assignee Title
CN114293270B (en) * 2022-01-20 2023-04-11 苏州大学 Wet spinning equipment for sea-island fibers and preparation process

Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2001192924A (en) * 2000-01-07 2001-07-17 Teijin Ltd Spinneret for sea-island type conjugate fiber and method for spinning with the same
CN2685358Y (en) * 2004-03-05 2005-03-16 苏州大学 Regenerated halabe silke micro-spinning machine
CN1795932A (en) * 2004-12-29 2006-07-05 东华大学 Composite collagen nerve ductus for promoting neural regeneration, and method for forming filature from hollow wet process
US20080296808A1 (en) * 2004-06-29 2008-12-04 Yong Lak Joo Apparatus and Method for Producing Electrospun Fibers
US20120082744A1 (en) * 2009-06-12 2012-04-05 Amogreentech., Ltd. Injection Nozzle for Electrospinning and Electrospinning Device Using the Same
CN203683744U (en) * 2013-12-19 2014-07-02 东华大学 Mini type wet method spinning device
CN110541209A (en) * 2019-09-19 2019-12-06 东华大学 Continuous preparation method of hydrogel optical fiber based on reactive spinning
CN111690993A (en) * 2020-06-24 2020-09-22 湖南工程学院 Coaxial injection needle tube for electrostatic spinning
CN113136628A (en) * 2021-05-25 2021-07-20 清华大学 Biological fiber, preparation method thereof and wet spinning device
CN215050876U (en) * 2021-04-08 2021-12-07 内蒙古工业大学 Miniature solution wet spinning machine
CN114293270A (en) * 2022-01-20 2022-04-08 苏州大学 Wet spinning equipment for sea-island fibers and preparation process

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6052202B2 (en) * 1982-09-20 1985-11-18 東レ株式会社 Spinning equipment for multicomponent fibers
CN102713034B (en) * 2010-01-29 2016-07-06 东丽株式会社 Island-in-sea type composite fiber, superfine fibre and composite spinning jete
CN105648576B (en) * 2016-04-06 2018-05-25 龙岩紫荆创新研究院 A kind of PTFE/PVA sea-island fibres and preparation method thereof
CN205616998U (en) * 2016-05-20 2016-10-05 郑州大学 Wet process spinning is simply installed
CN106192034A (en) * 2016-09-20 2016-12-07 哈尔滨工业大学 A kind of island spinning spinning pack and utilize its preparation method preparing ultrafine carbon fiber
CN110656387B (en) * 2019-10-15 2021-04-27 中国科学院长春应用化学研究所 Microfluidic biological spinning technology suitable for chemical crosslinking forming
CN212077208U (en) * 2020-01-08 2020-12-04 苏州大学 Wet spinning device for preparing triangular hollow porous fibers
CN111101214A (en) * 2020-01-09 2020-05-05 苏州大学 Coaxial skin-core layer structure color fiber and microfluidic preparation method thereof
CN211814735U (en) * 2020-02-25 2020-10-30 苏州大学 Simple and easy spinning equipment of aquogel fibre

Patent Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2001192924A (en) * 2000-01-07 2001-07-17 Teijin Ltd Spinneret for sea-island type conjugate fiber and method for spinning with the same
CN2685358Y (en) * 2004-03-05 2005-03-16 苏州大学 Regenerated halabe silke micro-spinning machine
US20080296808A1 (en) * 2004-06-29 2008-12-04 Yong Lak Joo Apparatus and Method for Producing Electrospun Fibers
CN1795932A (en) * 2004-12-29 2006-07-05 东华大学 Composite collagen nerve ductus for promoting neural regeneration, and method for forming filature from hollow wet process
US20120082744A1 (en) * 2009-06-12 2012-04-05 Amogreentech., Ltd. Injection Nozzle for Electrospinning and Electrospinning Device Using the Same
CN203683744U (en) * 2013-12-19 2014-07-02 东华大学 Mini type wet method spinning device
CN110541209A (en) * 2019-09-19 2019-12-06 东华大学 Continuous preparation method of hydrogel optical fiber based on reactive spinning
CN111690993A (en) * 2020-06-24 2020-09-22 湖南工程学院 Coaxial injection needle tube for electrostatic spinning
CN215050876U (en) * 2021-04-08 2021-12-07 内蒙古工业大学 Miniature solution wet spinning machine
CN113136628A (en) * 2021-05-25 2021-07-20 清华大学 Biological fiber, preparation method thereof and wet spinning device
CN114293270A (en) * 2022-01-20 2022-04-08 苏州大学 Wet spinning equipment for sea-island fibers and preparation process

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