WO2023119046A1

WO2023119046A1 - Fluff pulp

Info

Publication number: WO2023119046A1
Application number: PCT/IB2022/061988
Authority: WO
Inventors: Helena Tufvesson; Ulla Jansson
Original assignee: Stora Enso Oyj
Priority date: 2021-12-22
Filing date: 2022-12-09
Publication date: 2023-06-29
Also published as: SE2151591A1; SE545418C2

Abstract

The present invention is directed to a fluff pulp having improved compressibility and improved liquid spreading. The invention is also directed to a process for producing such fluff pulp and to the use thereof.

Description

FLUFF PULP

Field of the invention

Background

Fluff pulp is commonly made from softwood pulp from sulphate pulping. Depending on the pulping method, the properties of fluff pulp differs. Raw materials for softwood pulp may be various softwood species, such as Scots pine, Norway spruce, Southern pine, Loblolly pine, Slash pine, Radiata pine, Douglas fir, Hemlock Cedar, White spruce, Lodgepole pine, Alpine fir or mixtures thereof.

Fluff pulp is used for example for producing absorption cores for hygiene products and in airlaid-nonwoven for various applications such as pre-formed absorbent cores, wipes, tabletop, food pads etc.

Today there is a clear trend towards thinner hygiene products. Thinner products will save packaging materials and transportation space, and this will contribute to a reduction in carbon footprint and logistics costs. Another advantage is more under-wear like products for the end-users for discretion, fit and comfort. Thus, it would be desirable to achieve a more compressible fluff pulp, easier to densify. A more compressible fluff pulp will also improve the liquid spreading properties and have an advantage for air laid nonwoven enabling more distinct embossing pattern which will improve wicking properties. Summary of the invention

The present inventors have surprisingly found that by using a specific fraction of a fiber population, it is possible to obtain a fluff pulp that is easier to densify compared to commonly used fluff pulp made from the whole fiber population. A more densified structure with smaller pores also increases the wicking/spreading length and liquid spreading capacity of products comprising the fluff pulp according to the present invention.

According to the present invention, a standard fluff pulp is fractionated, so that the average fibre length in one of the fractions decreases from about 2 mm to about 1.4 mm, and the coarseness decreases from about 178 to about 159 pg/m. It was found that this fraction has increased compressibility.

The present invention is thus directed to fluff pulp having length weighted average fiber length in the range of from 1 .3 to 1 .5 mm and coarseness in the range of from 152 to 166 pg/m and having absorption time, in the dry defibrated state, in the range of from 2 to 4 seconds according to the standard SCAN-C 33:80 and having compressibility, measured at 70 kPa, in the range of from 0.065 to 0.080 g/cm³.

The present invention is also directed to a method to produce said fluff pulp.

The present invention is also directed to the use of said fluff pulp. The fluff pulp is produced and delivered to customers in the form of rolls. The fluff pulp is first defibrated. The defibrated pulp is then used in the manufacture of for example absorption cores for hygiene products and in airlaid-nonwoven for various applications such as pre-formed absorbent cores, wipes, tabletop, food pads etc. Description of the figures

Fig 1 : Fiber length distribution of reference pulp and fractionated pulp.

Detailed description

As used herein, the term, "fluff” means defibrated, i.e. fiberized or shredded “fluff pulp”.

As used herein, the term “absorption time” refers to the absorption properties of fluff pulp according to the standard SCAN-C 33:80, which involves the determination of the time consumed to completely saturate a standardized test specimen with absorbed liquid. A 3g fluff sample, 50 mm in diameter, is formed in a forming unit. The sample is placed in a sample holder and a load of 2.8 kPa is applied. Tap water (23°C) is applied underneath and the time required for the water to reach the top of the sample is recorded (average of 5 replicates).

As used herein, the term “compressibility” refers to the density of a defibrated fluff pulp sample, wherein the sample has been prepared at a specified pressure measured after different pressures (70 kPa or 1380 kPa). This is done as follows: 3g fluff sample, 50 mm in diameter, is formed in a forming unit and compressed in a tube with a cross sectional area of 19.625 cm² in an Instron with a speed of 600 mm/min. The density of the compressed sample is calculated after measuring the thickness after 2 minutes waiting time and determining the weight of the compressed sample. The compressibility, measured at 70 kPa is in the range of from 0.065 to 0.080 g/cm³, preferably in the range of from 0.067 to 0.074 g/cm³. Preferably, the compressibility, measured at 1380 kPa is in the range of from 0.250 to 0.300 g/cm³, preferably in the range of from 0.260 to 0.290 g/cm³.

The fluff pulp according to the present invention can be produced by the steps of a) preparing sulphate pulp; b) subjecting the pulp to fractionation; c) retaining a pulp fraction having length weighted average fiber length in the range of from 1.3 to 1.5 mm; d) drying the pulp to obtain fluff pulp, having a moisture content of less than 10 weight-%, in the form of a roll.

Fluff pulp fibers may be prepared by one or more known or suitable digestion, refining, and/or bleaching operations such as, for example, known mechanical, thermomechanical, chemical and/or semichemical pulping and/or other well-known pulping processes. The pulp is preferably sulphate pulp (Kraft pulp). The cellulosic fibers of the fluff pulp according to the present invention preferably originate from softwood such as spruce and/or pine. Preferably, the sulphate pulp originates to at least 90% from softwood, less than 10% hardwood has been used in the preparation of the sulphate pulp. Thus, the sulphate pulp mainly originates from softwood but may contain traces of hardwood. Preferably, from 65 wt-% to 90 wt-% of the fibers are fibers from Scots pine and from 10 wt-% to 35 wt-% of the fibers are fibers from Norway spruce.

The pulp used according to the present invention is fractionated. Preferably, the fractionation is carried out on wet pulp in a pressure screen. Preferably, the pressure screen has a hole diameter in the range of from 1.0 mm to 1.4 mm, preferably in the range of from 1.1 mm to 1.3 mm, such as 1.2 mm. Preferably, the fractionation is carried out on wet pulp in one step. The inject pulp is pumped through the screen and split into one finer fraction and one coarser fraction. The flow rate is typically about 1000 l/min. A pulp consistency of 10 g/l thus gives a mass flow of 10 kg/min. The mass reject ratio in the screen is selected to give the desired fiber length in the finer fraction (the accept fraction).

The pulp may be diluted to a desired consistency, such as between 3 and 15 g/l, such as between 3 and 6 g/l, before fractionation. The pulp is washed, either before or after fractionation. The washing is typically carried out using water and may be carried out in one or more steps and may involve filtration. As part of the washing or immediately after the washing step, the pH may be adjusted. Preferably, the pH of the washed pulp should in the range of from 5 to 8, such as from 5 to 7. The washed pulp preferably contains less than 0.5 weight-% (based on the solids) extractives, more preferably less than 0.2 weight-% extractives, even more preferably less than 0.1 weight-% extractives and most preferably less than 0.05 weight-% extractives. In this context, extractives are for examples resins and fatty acids.

The washed pulp is dried on a drying machine using methods known in the art. The dry pulp is formed into rolls after drying. The dried material has a moisture content of less than 10 weight-% (ISO 287), preferably less than 9%, such as in the range of from 6 to 9 weight-%.

In fiber defibration, the fluff pulp or dried web may be fed into one or more mill, such as hammermills, saw mills, knife mills, and/or pin mills, or any combination thereof. They may have a series of saws, knives, or pins, or small hammers, for example, that rotate at high speed separating the pulp into individual loose fibers.

The fluff (i.e. the defibrated form of the fluff pulp) according to the present invention can be used in articles and products wherein fluff is typically used. Thus, the fluff can be used in absorption cores in baby diapers, incontinence products and feminine hygiene products. The fluff is also the main component in airlaid nonwoven.

One embodiment of the present invention relates to a core, comprising the fluff and one or more superabsorbent polymer (SAP). In the course of making the core, the fluff may be combined with one or more superabsorbent polymers (SAP). SAPs are known in the absorbent product art. Nonlimiting examples of SAPs include starch-acrylonitrile copolymer, hydrolyzed starchacrylonitrile copolymer, acrylic acid (co)polymer, acrylamide (co)polymer, polyvinyl alcohol, polyacrylate/polyacrylamide copolymers, polyacrylic acid (co)polymers, sodium polyacrylate, ethylene maleic anhydride copolymer, cross-linked carboxymethylcellulose, polyvinyl alcohol copolymer, polyethylene oxide, cross-linked polyethylene oxide, and starch grafted copolymer of polyacrylonitrile, salts thereof, and combinations thereof.

The amount of SAP in the core may suitably range from 1 to 95% by weight of the core. Thus, the fluff pulp according to the present invention can, following defibration, for example be used in absorption cores and in airlaid nonwovens. It can be used as or in a liquid absorption material such as in absorbents in diapers, such as baby diapers as well as incontinence products. It can also be used for example in napkins and tissues. Such products can be produced using methods known in the art. The products typically comprise one or more further components, such as superabsorbents, polymers, wetting agents, viscose/rayon/lyocell fibers, bicomponent fibre, cotton fiber, other fibers, standard latex binder, specialty latex binder etc.

Examples

Example 1

A standard fluff pulp of Scots pine and Norway spruce in the proportion 80/20 was fractionated in a pressure screen with hole of diameter 1 .2 mm.

The average fibre length in one of the fractions decreased from 2.03 to 1 .42 mm, and the coarseness decreased from 178 to 159 pg/m. The fibre length distribution curves are seen in Fig 1 . The average fiber width decreased from 27.4 to 25.1 pm.

The improved properties compared with the standard material are found in the table below.

Table 1. Properties of reference and fractionated pulp

Table 2. Methods used for the analysis

In view of the above detailed description of the present invention, other modifications and variations will become apparent to those skilled in the art. However, it should be apparent that such other modifications and variations may be affected without departing from the spirit and scope of the invention.

Claims

1. Fluff pulp having length weighted average fiber length in the range of from 1.3 to 1.5 mm and coarseness in the range of from 152 to 166 pg/m and having absorption time, in the dry defibrated state, in the range of from 2 to 4 seconds according to the standard SCAN-C 33:80 and having compressibility, measured at 70 kPa, in the range of from 0.065 to 0.080 g/cm³.

2. Fluff pulp according to claim 1 having coarseness in the range of from 155 to 163 pg/m.

3. Fluff pulp according to claim 1 or 2 having compressibility, measured at 1380 kPa, in the range of from 0.250 to 0.300 g/cm³.

4. Fluff pulp according to any one of claims 1-3 wherein the sulphate pulp is prepared from at least 90% softwood.

5. Fluff pulp according to claim 4, wherein from 65 wt-% to 90 wt-% of the fibers are fibers from Scots pine and wherein from 10 wt-% to 35 wt-% of the fibers are fibers from Norway spruce.

6. Fluff pulp according to any one of claims 1-5, in the form of a roll.

7. A process for preparing fluff pulp comprising the steps of a) preparing sulphate pulp; b) subjecting the pulp to fractionation; c) retaining a pulp fraction having length weighted average fiber length in the range of from 1.3 to 1.5 mm; d) drying the pulp to obtain fluff pulp, having a moisture content of less than 10 weight-%, in the form of a roll.

8. A process according to claim 7 wherein the sulphate pulp is prepared from at least 90% softwood.

9. Fluff pulp obtainable according to the process of claim 7 or 8.

10. A product comprising or prepared from defibrated fluff pulp, wherein said fluff pulp is, prior to defibration, a fluff pulp according to any one of claims 1-6 or claim 9.

11. Airlaid nonwoven comprising or prepared from defibrated fluff wherein said fluff pulp is, prior to defibration, a fluff pulp according to any one of claims 1-6 or claim 9.

12. Absorption core comprising or prepared from defibrated fluff pulp, wherein said fluff pulp is, prior to defibration, a fluff pulp according to any one of claims 1-6 or claim 9.

13. Hygien product comprising absorption core according to claim 12.

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