WO2023066802A1 - Verfahren zur herstellung einer holzwerkstoffplatte und holzwerkstoffplatten-herstellvorrichtung - Google Patents
Verfahren zur herstellung einer holzwerkstoffplatte und holzwerkstoffplatten-herstellvorrichtung Download PDFInfo
- Publication number
- WO2023066802A1 WO2023066802A1 PCT/EP2022/078655 EP2022078655W WO2023066802A1 WO 2023066802 A1 WO2023066802 A1 WO 2023066802A1 EP 2022078655 W EP2022078655 W EP 2022078655W WO 2023066802 A1 WO2023066802 A1 WO 2023066802A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- wood
- liquid
- flame retardant
- based panel
- raw wood
- Prior art date
Links
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 44
- 239000002131 composite material Substances 0.000 title abstract 7
- 239000003063 flame retardant Substances 0.000 claims abstract description 160
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims abstract description 140
- 239000007788 liquid Substances 0.000 claims abstract description 138
- 239000002023 wood Substances 0.000 claims description 230
- 239000000463 material Substances 0.000 claims description 72
- 238000000034 method Methods 0.000 claims description 37
- 238000003825 pressing Methods 0.000 claims description 17
- 238000012360 testing method Methods 0.000 claims description 10
- 238000003780 insertion Methods 0.000 claims description 7
- 230000037431 insertion Effects 0.000 claims description 7
- 239000007864 aqueous solution Substances 0.000 claims description 2
- 230000003247 decreasing effect Effects 0.000 claims description 2
- 239000000725 suspension Substances 0.000 claims description 2
- 239000010410 layer Substances 0.000 description 69
- 239000000047 product Substances 0.000 description 25
- 230000002349 favourable effect Effects 0.000 description 18
- 239000011093 chipboard Substances 0.000 description 15
- 239000000243 solution Substances 0.000 description 13
- 229920002522 Wood fibre Polymers 0.000 description 11
- 239000002025 wood fiber Substances 0.000 description 11
- 239000011230 binding agent Substances 0.000 description 8
- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 description 5
- 238000003892 spreading Methods 0.000 description 5
- 239000012530 fluid Substances 0.000 description 4
- 238000005470 impregnation Methods 0.000 description 4
- 238000005507 spraying Methods 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 229920000538 Poly[(phenyl isocyanate)-co-formaldehyde] Polymers 0.000 description 3
- 239000002585 base Substances 0.000 description 3
- 239000000975 dye Substances 0.000 description 3
- 239000003292 glue Substances 0.000 description 3
- 238000009413 insulation Methods 0.000 description 3
- 229910052796 boron Inorganic materials 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 239000000109 continuous material Substances 0.000 description 2
- 238000001704 evaporation Methods 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 230000035515 penetration Effects 0.000 description 2
- 230000002093 peripheral effect Effects 0.000 description 2
- 239000011120 plywood Substances 0.000 description 2
- 239000002244 precipitate Substances 0.000 description 2
- 239000002344 surface layer Substances 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- 229920000877 Melamine resin Polymers 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 229920000388 Polyphosphate Polymers 0.000 description 1
- 229920001807 Urea-formaldehyde Polymers 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 1
- 239000007900 aqueous suspension Substances 0.000 description 1
- 238000000889 atomisation Methods 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- 238000005253 cladding Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 230000005284 excitation Effects 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000011094 fiberboard Substances 0.000 description 1
- 239000007850 fluorescent dye Substances 0.000 description 1
- 150000002357 guanidines Chemical class 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 230000001678 irradiating effect Effects 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 1
- 150000007974 melamines Chemical class 0.000 description 1
- 239000003595 mist Substances 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- UEZVMMHDMIWARA-UHFFFAOYSA-M phosphonate Chemical compound [O-]P(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-M 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 150000003018 phosphorus compounds Chemical class 0.000 description 1
- ODGAOXROABLFNM-UHFFFAOYSA-N polynoxylin Chemical compound O=C.NC(N)=O ODGAOXROABLFNM-UHFFFAOYSA-N 0.000 description 1
- 239000001205 polyphosphate Substances 0.000 description 1
- 235000011176 polyphosphates Nutrition 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000003908 quality control method Methods 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000004230 steam cracking Methods 0.000 description 1
- 238000005728 strengthening Methods 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27N—MANUFACTURE BY DRY PROCESSES OF ARTICLES, WITH OR WITHOUT ORGANIC BINDING AGENTS, MADE FROM PARTICLES OR FIBRES CONSISTING OF WOOD OR OTHER LIGNOCELLULOSIC OR LIKE ORGANIC MATERIAL
- B27N3/00—Manufacture of substantially flat articles, e.g. boards, from particles or fibres
- B27N3/08—Moulding or pressing
- B27N3/18—Auxiliary operations, e.g. preheating, humidifying, cutting-off
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K3/00—Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
- B27K3/02—Processes; Apparatus
- B27K3/0278—Processes; Apparatus involving an additional treatment during or after impregnation
- B27K3/0285—Processes; Apparatus involving an additional treatment during or after impregnation for improving the penetration of the impregnating fluid
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K3/00—Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
- B27K3/02—Processes; Apparatus
- B27K3/08—Impregnating by pressure, e.g. vacuum impregnation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K3/00—Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
- B27K3/16—Inorganic impregnating agents
- B27K3/166—Compounds of phosphorus
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K5/00—Treating of wood not provided for in groups B27K1/00, B27K3/00
- B27K5/02—Staining or dyeing wood; Bleaching wood
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27N—MANUFACTURE BY DRY PROCESSES OF ARTICLES, WITH OR WITHOUT ORGANIC BINDING AGENTS, MADE FROM PARTICLES OR FIBRES CONSISTING OF WOOD OR OTHER LIGNOCELLULOSIC OR LIKE ORGANIC MATERIAL
- B27N3/00—Manufacture of substantially flat articles, e.g. boards, from particles or fibres
- B27N3/02—Manufacture of substantially flat articles, e.g. boards, from particles or fibres from particles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27N—MANUFACTURE BY DRY PROCESSES OF ARTICLES, WITH OR WITHOUT ORGANIC BINDING AGENTS, MADE FROM PARTICLES OR FIBRES CONSISTING OF WOOD OR OTHER LIGNOCELLULOSIC OR LIKE ORGANIC MATERIAL
- B27N3/00—Manufacture of substantially flat articles, e.g. boards, from particles or fibres
- B27N3/04—Manufacture of substantially flat articles, e.g. boards, from particles or fibres from fibres
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27N—MANUFACTURE BY DRY PROCESSES OF ARTICLES, WITH OR WITHOUT ORGANIC BINDING AGENTS, MADE FROM PARTICLES OR FIBRES CONSISTING OF WOOD OR OTHER LIGNOCELLULOSIC OR LIKE ORGANIC MATERIAL
- B27N7/00—After-treatment, e.g. reducing swelling or shrinkage, surfacing; Protecting the edges of boards against access of humidity
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27N—MANUFACTURE BY DRY PROCESSES OF ARTICLES, WITH OR WITHOUT ORGANIC BINDING AGENTS, MADE FROM PARTICLES OR FIBRES CONSISTING OF WOOD OR OTHER LIGNOCELLULOSIC OR LIKE ORGANIC MATERIAL
- B27N9/00—Arrangements for fireproofing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B30—PRESSES
- B30B—PRESSES IN GENERAL
- B30B5/00—Presses characterised by the use of pressing means other than those mentioned in the preceding groups
- B30B5/04—Presses characterised by the use of pressing means other than those mentioned in the preceding groups wherein the pressing means is in the form of an endless band
- B30B5/06—Presses characterised by the use of pressing means other than those mentioned in the preceding groups wherein the pressing means is in the form of an endless band co-operating with another endless band
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K2240/00—Purpose of the treatment
- B27K2240/30—Fireproofing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27N—MANUFACTURE BY DRY PROCESSES OF ARTICLES, WITH OR WITHOUT ORGANIC BINDING AGENTS, MADE FROM PARTICLES OR FIBRES CONSISTING OF WOOD OR OTHER LIGNOCELLULOSIC OR LIKE ORGANIC MATERIAL
- B27N3/00—Manufacture of substantially flat articles, e.g. boards, from particles or fibres
- B27N3/08—Moulding or pressing
- B27N3/24—Moulding or pressing characterised by using continuously acting presses having endless belts or chains moved within the compression zone
Definitions
- the invention relates to a method for producing a wood-based panel.
- the invention relates to a wood-based material board manufacturing device with (a) a press, in particular a belt press, for pressing at least one pre-product layer to form a raw wood-based material board, (b) a liquid application device for applying a liquid the raw wood material panel and (c) a suction device which is designed to apply a negative pressure to a side surface of the raw wood material panel.
- Such methods and wood-based panel manufacturing devices are known and are used to manufacture wood-based panels.
- renewable raw materials such as wood as building materials, it is often required that they are flame-retardant.
- the production of flame-retardant wood-based panels has been known for several decades.
- the preliminary products for example wood chips, wood fibers or coarse chips, are treated with a liquid containing a flame retardant before the preliminary product layer is produced from the preliminary products. This is done by spraying the preliminary products in mixers, glue drums (coils) or blow lines. After that, the preliminary products are scattered onto a belt, so that at least one layer of preliminary products is created. Then the pre-product layer is pressed into a wood-based panel.
- EP 3 388 213 A2 describes a method for producing a hard-to-ignite and/or reinforced wood fiber board. First, a cut-to-size wood fiber board is arranged on a processing device. Flame retardant and/or strengthening agent is then applied to an upper side of the wood fiber board. The applied agent is sucked or pressed into the wood fiber board by applying a vacuum to the underside and/or by applying an overpressure to the top.
- EP 3 127 670 A2 discloses a method for impregnating wood fiber boards in which material boards lie on a transport device as an endless strand.
- the strand is continuously guided through an impregnation station for introducing an impregnation medium into the wood fiber board from above.
- the impregnation medium is applied in a time-controlled manner during the continued transport of the individual material panels of the line or of the continuous material panel line by means of a large number of application devices, which are arranged at least in one row over the full width of the individual material panel or the continuous material panel line and can be controlled individually.
- the impregnated material panels only show the impregnation at the points where it is necessary to obtain the desired performance properties.
- EP 2168 738 A1 describes a method for producing a wood fiber board, with the steps: pressing a fiber fleece to form a raw wood fiber board, applying an aqueous liquid at least to parts of an upper side of the raw wood fiber board and applying a negative pressure at least to parts of the underside by means of a Suction table, so that the aqueous liquid is sucked into and / or through the raw wood fiber board.
- the object of the invention is to improve the production of flame-retardant wood-based material panels.
- the invention solves the problem by a method for producing a wood-based material board with the steps (a) producing, in particular by pressing wood-containing precursors, a raw wood-based material board which has a first side surface and a second side surface which runs parallel to the first side surface, (b) applying a liquid containing a flame retardant to at least the first Side surface and (c) applying a negative pressure to the second side surface, so that the flame retardant-containing liquid is sucked into the raw wood-based panel, in particular in its edge zone, and / or applying an overpressure to the first side surface, so that the flame retardant-containing liquid in a Edge zone of the raw wood-based panel is pressed, so that the wood-based panel is formed.
- the invention also solves the problem with a generic wood-based panel manufacturing device in which the liquid contains a flame retardant and in which the suction device is designed to automatically apply the vacuum for such a suction time that the liquid containing the flame retardant gets into an edge zone of the raw wood-based panel is sucked, but not sucked through the raw wood-based material board and/or which has a pressure application device for applying an overpressure to the first side surface, so that the liquid containing the flame retardant is pressed into an edge zone of the raw wood-based material board.
- the invention solves the problem with a wood-based panel that has an in particular continuous concentration gradient of flame retardant, the flame retardant concentration decreasing with increasing distance from a surface to a center of the wood-based panel. It is favorable if the wood-based panel is flame-retardant according to the requirement standard DIN EN 13501-1:2010 and test standard DIN EN 13823:2015.
- the wood-based panel is a wood-based panel of class B, in particular B -s1 or B -s1 dO, or C, in particular C-s1, C-s1 dO, or Bn, in particular Bn -s1 or Bn -s1 dO, or Cfi, in particular Cn-s1, Cn-s1 D0, or in class B1, B2 or B3.
- the content of flame retardant in the wood-based panel can often be adjusted with a high level of process reliability. This reduces scrap compared to prior art methods.
- Another advantage of the invention is that the consumption of flame retardants can generally be reduced.
- the pre-products are sprayed as well as the subsequent transport of the sprayed preliminary products to the loss of flame retardants. There are often losses of more than 20% of flame retardant.
- the introduction of the flame retardant generally does not lead to an increase in the moisture content of the comminuted primary products.
- a high moisture content can lead to so-called steam cracking in the press, which is undesirable.
- a steam splitter is an area where the engineered wood board has cracked due to evaporating water.
- Increasing the proportion of binder i.e. the proportion of binder and/or glue in the pre-product layer, can generally also be dispensed with if flame retardants are introduced.
- Many binders such as polymeric diphenylmethane diisocyanate, react with some flame retardants. In the case of processes according to the prior art, therefore, more binder must also be added if flame retardants are used than if a wood-based panel is produced without flame retardants. This disadvantage generally does not apply to the production according to the invention.
- a press speed generally does not have to be reduced. Since, in the prior art, the flame retardant is introduced in a liquid before pressing, the moisture content of the pre-product layer often increases. In order to prevent steam splitting, the press speed and/or the press temperature usually has to be reduced. This can be omitted in a method according to the invention.
- the method according to the invention can also be carried out, at least in principle, independently of the time and place of production of the raw wood-based material board. It is thus possible to subsequently make non-flame-resistant raw wood-based panels that have already been produced flame-retardant. In particular, the flame retardant is applied to the raw wood-based panel that has already been pressed.
- the raw wood-based material board is stored and/or moved after pressing for a longer period of time, in particular at least one minute, in particular at least 10 minutes, before the liquid containing the flame retardant is applied.
- the raw wood-based panels are stored in a star cooler. This allows flexible production of flame-retardant wood-based panels, especially in small quantities.
- the liquid application device it is also possible and covered by the invention for the liquid application device to be arranged in the vicinity of the press. A distance between the liquid application device and the press is preferably at most 100 m, or at most 50 m, in particular at most 30 m.
- a raw wood-based material board is understood to mean, in particular, a board made of a wood-based material that can be processed into a wood-based material board by introducing the flame retardant.
- the application of the liquid is understood in particular to mean that the liquid is brought into contact with the first side surface.
- a liquid film preferably forms on the side surface.
- the edge zone is understood as meaning a region of the raw wood-based panel that is delimited on the one hand by a side surface and on the other hand does not extend to the center of the wood-based panel.
- the feature that the liquid is sucked into the edge zone means in particular that it is possible, but not necessary, for the liquid to be sucked exclusively into the edge zone.
- the application of the liquid to the raw wood-based material board is understood in particular to mean that the liquid is brought into contact with a surface of the raw wood-based material board.
- the liquid can be brought into contact with the raw wood-based panel from above or from below.
- the liquid application device is designed and/or arranged for applying the liquid from below onto the raw wood material panel.
- the suction device for automatically applying the negative pressure is arranged from above.
- the raw wood-based panel is, for example, a medium-density fibreboard (MDF board), a high-density fibreboard (HDF board), a oriented strand board (OSB board), a chipboard, a plywood board, a soft fibreboard, a hard fibreboard, flexible plywood board, a multiplex board, blockboard, laminboard, laminated wood board, low-density fiberboard (LDF board) or an insulating board.
- MDF board medium-density fibreboard
- HDF board high-density fibreboard
- OSB board oriented strand board
- chipboard a plywood board, a soft fibreboard, a hard fibreboard, flexible plywood board, a multiplex board, blockboard, laminboard, laminated wood board, low-density fiberboard (LDF board) or an insulating board.
- a thickness of the wooden board is preferably at least 6 mm, in particular at least 10 mm, particularly preferably at least 15 mm, particularly preferably at least 20 mm.
- the thickness of the wood-based material board is preferably at most 50 mm, in particular at most 30 mm, in particular at most 28 mm, preferably at most 25 mm.
- the flame retardant containing liquid contains a flame retardant.
- the liquid is an aqueous liquid. It is favorable if the flame retardant contains phosphorus.
- the flame retardant can contain organic and/or inorganic phosphorus compounds, for example phosphate, polyphosphate, phosphonate and/or a guanidine salt. It is possible that the flame retardant is based on melamine or melamine derivatives, aluminum hydroxide or alkali sulfates. However, it is preferred that the boron content of the flame retardant is at most one percent by weight.
- the flame retardant preferably contains ammonium.
- the wood-based panel produced is preferably flame-retardant in accordance with DIN EN 13501-1:2010.
- the wood-based panel produced has the properties of a wood-based panel according to the invention. It is favorable if the bulk density of the raw wood-based panel and/or the wood-based panel is at least 550 kg/cubic meter, in particular at least 600 kg/cubic meter. Preferably, the bulk density of the raw wood-based panel and/or the wood-based panel is at most 1000 kg/cubic meter, in particular at most 800 kg/cubic meter. However, it can also be favorable if the bulk density of the raw wood-based material panels is below 350 kg/cubic meter, for example below 300 kg/cubic meter. This is particularly the case when the raw wood-based panel is an insulating panel.
- the application of the liquid containing the flame retardant and/or the application of the negative pressure can take place both when the raw wood-based panel is in motion and when it is stationary.
- the overpressure is preferably applied locally and the liquid containing the flame retardant is introduced in the area of the overpressure.
- Local application of the overpressure means that the overpressure is not applied to the entire surface of the wood-based panel.
- the area to which the overpressure is applied is less than half the total area of the wood-based panel.
- An applicator is preferably pressed against the raw wood-based material board, so that an introduction space is formed between the applicator and the raw wood-based material board, which space is sealed by a seal of the applicator. In this way, a leakage flow of pressurized fluid, by means of which a pressure is built up in the introduction space, is reduced.
- the applicator is preferably part of the liquid applicator.
- the applicator is pressed against the raw wood-based panel. This is preferably done from below. Alternatively, the applicator is pressed against the raw wood-based panel from above.
- the liquid containing the flame retardant is preferably pressed or introduced into the introduction space. It is favorable if the liquid containing the flame retardant is at least half, preferably at least 75%, of the fills the volume of the insertion space. In this way, the volume of gas in the introduction space is kept small and the introduction pressure in the introduction space for injection can be built up and reduced quickly. After the liquid containing the flame retardant has been pressed into the introduction space and thus into the raw wood-based material board, the introduction pressure is reduced, in particular to ambient pressure.
- the applicator is preferably moved relative to the raw wood-based material board after the introduction pressure has been reduced.
- the applicator is then pressed against the raw wood-based panel again and more liquid containing flame retardants is pressed into the application area. Thereafter, the insertion pressure is reduced and the steps are repeated until the raw wood-based panel is provided with flame retardant on all specified surfaces.
- a negative pressure is applied to the raw wood-based material board, preferably from above, alternatively from below. This preferably takes place in the area in which an overpressure is applied from the other side of the raw wood-based panel. In other words, a negative pressure is applied to a side surface that corresponds to a pressure surface on which the flame retardant-containing liquid is pressed.
- the vacuum is applied by means of the suction device.
- the applicator it is possible, but not necessary, for the applicator to be moved relative to the raw wood-based panel when the liquid containing the flame retardant is pressed in. It is also possible for the raw wood material board and the applicator to be moved in the same way, so that the applicator is at rest relative to the raw wood material board but is moved in space.
- the suction device has a suction cup that can be positioned automatically at a predetermined location.
- the suction device is preferably designed to always arrange the suction cup opposite the applicator.
- a drive of the suction bell which can also be referred to as a positioning drive, is controlled by a control unit of the wood-based panel manufacturing device.
- a suction cup is understood to be a component which, when it is in contact with the raw wood-based panel, forms a sealed cavity to which the vacuum can be applied. It is possible, but not necessary, for the walls of the suction cup to be elastic, in particular entropy-elastic, but they can also be rigid.
- the suction cup preferably has a seal with which it rests against the wood-based panel.
- the vacuum is preferably applied in such a way that an internal concentration of flame retardant in an internal thickness quintile of a thickness extension from the first side surface to the second side surface of the wood-based panel is at most 0.8 times an external concentration in a first outermost thickness quintile, which extends to the first side surface is. It is favorable if the internal concentration is at most 0.7 times, in particular 0.6 times, preferably 0.5 times, particularly preferably 0.4 times, in particular 0.3 times, particularly preferably 0.2 times, for example at most 0.1 times, the external concentration.
- a cuboid with a base measuring 5 cm by 5 cm is first cut out of the wood-based panel.
- the base runs parallel to the first side surface.
- slices are cut off on both sides parallel to the side surface, the thickness of which is 0.2 times the thickness of the wood-based panel.
- the mass of flame retardant is determined on the sample obtained in this way and divided by the total mass of the sample. This gives the inside concentration.
- the outside concentration results from analysis of the material of a disk with a thickness of 0.2 times the thickness of the wood-based panel, with one side of the disk being the first side face.
- the concentration of flame retardants in at least one top layer is at least 65% higher, preferably at least 50% higher, in particular at least 100% higher than the concentration of flame retardants in a middle layer.
- the middle layer is arranged between the two top layers.
- the top layer consists of a Layer of pre-products spread separately from another layer from which the middle layer is formed when pressed.
- the liquid is applied in such a way that the edge zone of at least 80%, in particular at least 90%, of a side surface area of the wood-based panel contains flame retardants. In other words, this means that at most 10% of the wood-based panel does not contain any flame retardant in its edge zone. This reduces the amount of material board that has to be discarded because it does not contain sufficient flame retardant.
- the flame retardant is also introduced outside the edge area of the wood-based panel.
- the edge area includes all points of the wood-based panel whose distance to the edge of the wood-based panel is no more than 10 cm.
- the liquid can be applied by spraying, rinsing, spreading, rolling, pouring or other application.
- the spraying can take place, for example, by means of excess pressure, with the liquid being pressed through a nozzle.
- spraying can be done by atomization.
- the liquid can be applied to a moving body, in particular a rotating or vibrating body, so that droplets form.
- a concentration of flame retardant in the liquid corresponds to at least half, in particular at least 65%, of the solubility of the flame retardant.
- the flame retardant has a solubility that can be measured, for example, in grams per liter. This solubility is the maximum mass of flame retardant that can be in solution per unit volume of liquid.
- the concentration of the flame retardant in the liquid is at least half of this solubility. This means that only a small amount of liquid has to be applied to the raw wood-based panel.
- the quotient of the actual concentration according to DIN 1310 of the flame retardant and the solubility is at least 0.5, in particular at least 0.65, preferably at least 0.75.
- a concentration of flame retardant in the liquid is preferably at least 30 percent by weight, in particular at least 40 percent by weight, preferably at least 50 percent by weight.
- the liquid is preferably a solution, in particular an aqueous solution, or a suspension, in particular an aqueous suspension.
- the liquid preferably contains at least one dye.
- the dye is preferably selected in such a way that a flame retardant content, in particular spatially resolved, can be determined from the color of a cross section of the wood-based panel.
- the dye is a fluorescent dye, so that the content of flame retardants can be deduced from the flame retardant content by irradiating the cross section of the wood-based panel with excitation light and by spatially resolved measurement of an intensity of the resulting fluorescent radiation. This allows a particularly simple quality control.
- the liquid temperature of the liquid when applied to the side surface is preferably at least 40°C, in particular at least 50°C, particularly preferably at least 60°C.
- the solubility of flame retardants generally increases at high temperatures. A higher temperature therefore means that less liquid is required to apply a given amount of flame retardant. It is favorable if the temperature is less than 100°C, in particular less than 90°C.
- a surface temperature of the first side surface when the liquid is applied is at least 30°C, in particular at least 40°C.
- the surface temperature is preferably at most 65°C, in particular at most 50°C. It is favorable if the surface temperature is at most 20° C., in particular 10° C., lower than the liquid temperature.
- the surface temperature is at least as great as the liquid temperature. In this case, the flame retardant does not precipitate out of the liquid and the flame retardant can be sucked into the edge zone.
- the surface temperature of the first side surface at the location where the liquid containing the flame retardant is applied is preferably lower than the liquid temperature.
- a difference between the surface temperature and the liquid temperature is preferably at least 5 Kelvin, in particular at least 10 Kelvin.
- Flame retardant solution generally mixes poorly in solvents, especially water. However, the solubility increases with temperature.
- the temperature of the liquid containing the flame retardant is selected to be higher than the surface temperature.
- the introduction of the flame retardant into the raw wood-based material panel is particularly effective if the concentration of flame retardant in the liquid at the surface temperature of the first side surface at the location at which the liquid containing the flame retardant is applied is above a saturation concentration of the flame retardant in the liquid lies.
- flame retardant precipitates out of the solution shortly after the flame retardant-containing liquid comes into contact with the raw wood-based panel, which causes a particularly high concentration of flame retardant in the outer areas of the raw wood-based panel.
- a surface-specific application quantity of liquid is preferably at least 0.3 kg/square meter and/or at most 5 kg/square meter.
- the surface-specific application quantity of liquid which is measured, for example, in liters per square meter, is chosen such that the moisture content of a surface layer of a surface layer of the wood-based panel deviates by no more than 30% from the core moisture content after the liquid has been sucked into the edge zone.
- the raw wood-based panel loses water in the edge zone through evaporation. This results in a moisture gradient in the raw wood-based panel, which is undesirable.
- the liquid containing the flame retardant the loss of moisture in the edge zone can be at least partially compensated for again.
- the negative pressure is preferably at least 100 hPa, in particular at least 150 hPa, preferably at least 200 hPa, particularly preferably at least 300 hPa. This means that the pressure deviates by at least 300 hPa from the ambient pressure. It is favorable if the negative pressure is at least 400 hPa. For example, the pressure is at least 50 hPa and/or at most 700 hPa.
- the method comprises the steps: (a) after the liquid has been sucked into the edge zone of the first side surface, rotating the raw wood-based material board, (b) applying the liquid to the second side surface and (c) applying a vacuum to the first Side surface, so that the liquid is sucked into the edge zone of the second side surface of the raw wood-based panel, so that the wood-based panel is formed.
- the treatment with the solution containing the flame retardant is carried out on both sides.
- the method includes the steps (a) scattering of a first cover layer of chipboard, (b) scattering of at least one middle layer of chipboard arranged thereon, (c) scattering of a second cover layer of chipboard arranged on the middle chipboard layer, and (d ) Pressing the layers to form the raw wood-based material panel, which has a first cover layer, which has arisen from the first cover chipboard layer, a middle layer, which has arisen from the middle chipboard layer, and a second cover layer, which has arisen from the second cover chipboard layer , having.
- the method preferably comprises step (d1) applying the liquid containing the flame retardant with an area-specific application amount of liquid which corresponds to at least 10 percent by weight of an area-specific mass of the first cover layer.
- the method preferably comprises step (d2) applying the flame retardant-containing liquid with an area-specific application amount of flame retardant that corresponds to at least 10 percent by weight of the area-specific mass of the top layer. It has been found that a flame-retardant wood-based material panel can generally be obtained in this way. It is favorable if the first cover chip layer and/or the second cover chip layer consists of coarse chips. As an alternative or in addition, at least one top chip layer can consist of fine chips.
- the middle chip layer consists of coarse chips.
- the first cover chip layer and/or the second cover chip layer do not have to consist of coarse chips, they can also consist of other wood-containing primary products. The same applies to the middle chip layer.
- the coarse chips do not contain flame retardants or contain flame retardants in a concentration that is so small that the proportion of the flame retardant that is introduced into the wood-based panel via the coarse chips is at most 50 percent by weight, in particular at most 30 percent by weight, preferably at most 10 percent by weight, of the total corresponds to the flame retardant contained in the wood-based panel.
- a wood-based panel production device preferably has a pressure application device for applying the excess pressure to a pressure surface.
- the pressure surface is that surface which can be subjected to an overpressure by means of the pressure application device.
- the pressure area is preferably, but not necessarily, at most 50% of an area of the wood-based panel.
- the wood-based panel production device preferably has a control unit that is designed to control components of the wood-based panel production device, so that a generic method is automatically carried out.
- the wood-based panel production device preferably has an applicator which has a seal.
- the applicator is designed to press against the raw wood material panel, so that an introduction space is formed between the applicator and the raw wood material panel, which space is sealed off by the seal.
- the applicator preferably has an actuator, for example a hydraulic cylinder, a pneumatic cylinder or an electric drive, for pressing against the raw wood material board.
- the wood-based panel manufacturing device can have a positioning device, for example a robot, for positioning the applicator.
- an internal concentration of flame retardant in an internal thickness quintile of a thickness extension from the first side surface to the second side surface is at most 0.8 times, in particular at most 0.6 times, particularly preferably at most half, in particular at most 0.4 times, preferably at most 0.3 times and more preferably at most 0.1 times an outside concentration in a first outermost thickness quintile extending to the first side surface.
- the internal concentration of flame retardant is significantly lower than the concentration of flame retardant in the edge zone that is adjacent to the side surface. It has been found that the flame retardant is particularly effective at this point.
- a second decile concentration of flame retardant in the second thickness decile of the thickness extension is at least 0.1 times a first decile concentration in the first outermost thickness decile.
- flame retardants are not only found in the outermost deciles, but flame retardants are also introduced further into the interior of the raw wood-based panel.
- the wooden board according to the invention is a coarse chipboard, it is preferably a fire-protected building board. In particular, this chipboard is designed to be installed in buildings. If the wood-based panel according to the invention is an HDF panel, it can be used, for example, as floor, wall or ceiling cladding.
- a wood-based panel according to the invention in the form of an MDF panel is suitable, for example, as a door leaf or as a furniture front.
- an insulating element for example a facade insulating element, which has at least one layer of a wood-based panel according to the invention.
- FIG. 1 shows a schematic view of a wood-based panel production device according to the invention for carrying out a method according to the invention for producing a wood-based panel according to the invention
- FIG. 2 shows a schematic cross-sectional view of a suction device of the wood-based material board production device according to FIG.
- FIG. 3 in the sub-figures 3a, 3b and 3c each schematic cross-section through a wood-based material panel according to the invention, which was produced according to the invention
- FIG. 4 shows a section of a wood-based panel production device according to the invention according to a second embodiment
- FIG. 5 shows a schematic representation of two applicator rounds of the wood-based material board production device according to FIG. 4 and
- FIG. 6 shows in partial figures 6a and 6b two views of part of a wood-based panel manufacturing device according to the invention according to a third embodiment and in partial figure 6c a cross-sectional view of part of a wood-based panel manufacturing device according to a third embodiment.
- FIG 1 shows schematically a wood-based panel manufacturing device 10, the one
- Press 12 in the form of a continuous belt press for pressing at least one pre-product layer 14, in the present case three pre-product layers 14.i a raw wood material board 16 has.
- the at least one layer of preliminary product 14 is produced by a scattering device 18 .
- the spreading device 18 comprises a first spreader 20.1 for spreading a first layer of pre-product 14.1 in the form of a first layer of chipboard, a second spreader 20.2 for spreading a second layer of pre-product 14.2 in the form of a middle layer of chipboard, and a third spreader 20.3 for spreading a third Pre-product layer 14.3 in the form of a second covering chip layer.
- the resulting raw wood-based panel 16 After pressing using the press 12, the resulting raw wood-based panel 16 has a first cover layer 22.1, a middle layer 22.2 and a second cover layer 22.3.
- the press 12 is heated, for example, by means of a thermal fluid 24 that flows in the heating tubes 26.1, 26.2, .
- the heat of the thermal fluid 24 is transferred to a revolving press belt 28, which is pressed onto the pre-product layers 14.i by means of pressure rollers 30.1, 30.2, .
- a liquid application device 32 is arranged downstream of the press 12 in a material flow direction M, by means of which a liquid 34 containing a flame retardant can be applied to a first side surface S1 of the raw wood-based panel 16 .
- a suction device 36 is arranged behind the press 12 in the direction of material flow M, by means of which the liquid 34 that was applied to the first side surface S1 is sucked into the raw wood-based material board 16 .
- the liquid application device 32 comprises a liquid reservoir 38 and a pump 40, by means of which the liquid 34 is conveyed to at least one nozzle 41 under a liquid pressure p34.
- the nozzle 41 generates a spray mist 42 which settles on the first side surface S1.
- the nozzle 41 can be part of a nozzle bar 43 that has three or more nozzles.
- the liquid application device 32 can have a temperature control device 43, which keeps the liquid 34 at a predetermined temperature T34.
- FIG. 2 shows an enlarged view of the suction device 36, which has a vacuum table 37 which has a circumferential seal 44, by means of which the second side surface S2 is sealed off from a suction chamber 46.
- the suction chamber 46 is connected to a vacuum pump 52 by means of a vacuum line 49 .
- the liquid 34 is drawn into a first edge zone 50.1 of the raw wood-based panel.
- the suction chamber is aerated, the raw wood-based panel 16 is turned over, the pressure p46 is again applied to the suction chamber and liquid 34 is applied to the second side surface.
- the suction chamber is ventilated again.
- the liquid application device 32 can have, for example, an application roller 53 or another device for applying the liquid 34 to the first side surface S1.
- FIG. 3a schematically shows a cross section through a wood-based material board 54 according to the invention, which has a first edge surface K1 and a second edge surface K2.
- FIG. 3b shows the progression of the concentration CF,54 of flame retardant in the wood-based panel 54 as a function of the distance z from the respective nearest side surface. It can be seen that the concentration is greatest at the surface. As the distance z from the first side surface S1 of the wood-based panel 54 increases, the concentration decreases up to the middle of the wood-based panel 54 .
- the wood-based panel 54 has an inner concentration CF.QS of flame retardant.
- CF.QS an inner concentration of flame retardant.
- the wood-based panel 54 has a first external concentration CF.QI of flame retardant.
- FIG. 3c shows a division into deciles. It can be seen that a second decile concentration CF,D2 of flame retardant in the second thickness decile of the thickness extension, which lies in the direction of a middle of the thickness extension next to the first, outermost thickness decile, is at least 0.1 times a first decile -Concentration CF,DI in the first outermost decile of thickness.
- FIG. 4 shows a liquid application device 32 of a wood-based panel manufacturing device 10 according to the invention, which has a pressure application device 56 which, by means of the pump 40, introduces liquid 34 containing flame retardants from the liquid reservoir 38 into an introduction space 58 under an introduction pressure p e .
- the introduction space 58 is delimited by a seal 60 of the pressure application device.
- the pressure application device 56 can be designed to apply the liquid 34 containing the flame retardant from below or from above.
- a negative pressure can be applied to the raw wood-based panel 16 via the vacuum line 49 .
- FIG. 5 shows schematically that the suction device 36 can be designed to apply a local negative pressure.
- a suction surface Fs is smaller than the surface of the raw wood-based panel 16.
- the suction surface Fs is smaller than a tenth of the surface of the raw wood-based panel 16.
- the wood-based panel manufacturing device can also have a second suction device 36', which is preferably identical in construction to the first suction device 36.
- a pressure surface FD on which the pressure application device 56 applies the application pressure pe essentially corresponds, for example with a deviation of at most a factor of 2, in particular a maximum of a factor of 1.1, in particular a maximum of a factor of 1.25, to the suction surface Fs.
- Figure 6a shows a positioning device 62, for example a robot, for positioning an applicator 64 and for pressing the applicator 64 against the raw wood-based panel 16.
- the positioning device 62 has, for example, an arm 66.
- the arm 66 can have 2 or more partial arms 68.1 , 68.2, which can be connected to one another in an articulated manner.
- the applicator 64 can be positioned automatically in a predeterminable position relative to the raw wood material panel 16.
- the applicator 64 is supplied with pressurized liquid 34, which is sprayed onto the raw wood-based panel 16 and/or pressed into the raw wood-based panel 16 under pressure.
- the wood-based panel production device 10 can have a suction device 36 which has a suction bell 74 that can be positioned at a predetermined location.
- the suction device 36 is designed in such a way that the suction cup 74 is always arranged opposite the applicator 64 .
- the drive 70 is controlled by a control unit 76 of the wood-based panel manufacturing device 10 .
- the suction bell 74 is connected to the vacuum pump 52 by means of a flexible vacuum line.
- FIG. 6c shows a further embodiment of a pressure application device 56, in which the liquid 34 containing the flame retardant is introduced into the introduction space 58 by means of a nozzle 78.
- the introduction pressure p e can be adjusted by means of a pressure source 80 which is connected to the introduction chamber 58 via a pressure line 82 .
- PMDI polymeric diphenylmethane diisocyanate
- raw wood material panel 16 was rotated and the process repeated. Thereafter, raw wood-based panel 16 (base area: DIN A4, sample 1) was made from the panel and this was tested with a conventionally produced flame-retardant OSB panel.
- the conventionally produced flame-retardant OSB board had a comparable amount of the flame retardant mentioned above in the top layer and had been air-conditioned before the test (humidity: approx. 9%).
- the samples were flamed for different lengths of time using a gas burner positioned at a defined distance from the surface. After the flaming time had elapsed, it was noted whether burning/continued burning could be observed and the duration of the continued burning was determined.
- the liquid used corresponds to an amount of 15% by weight based on the top layer strands (thickness of the top layer approx. 3 mm per side).
- the conventionally produced OSB board had a comparable amount of the flame retardant mentioned above in the top layer and had been air-conditioned before the test (humidity: approx. 9%).
- the wood-based panels produced using the process according to the invention behave just as well as the reference panel. Even after 15 minutes of flaming, none of the samples continued to burn after the burner was switched off. Subsequent investigation showed that the wood-based material panels produced according to the invention still had a significantly higher strength after the test. In the case of the reference board, individual charred strands could easily be detached mechanically from the structure, which was only possible with greater expenditure of force in the case of the two wood-based material boards produced according to the invention.
- the binder content was also increased in this panel (2% more than in the standard).
- the wood-based panel produced conventionally had a comparable amount of the flame retardant mentioned above in the panel and had been air-conditioned before the test (humidity: approx. 9%).
- the samples When tested for flammability, the samples were tested just like a conventionally manufactured MDF board.
- the MDF board produced according to the invention has met or exceeded the results in terms of flammability and strength compared to the conventionally produced MDF board.
- the insulation board produced according to the invention has met or exceeded the results in terms of flammability and strength compared to the conventionally produced insulation board.
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- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Forests & Forestry (AREA)
- Manufacturing & Machinery (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Mechanical Engineering (AREA)
- Chemical And Physical Treatments For Wood And The Like (AREA)
Abstract
Description
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CN202280077701.8A CN118284500A (zh) | 2021-10-18 | 2022-10-14 | 木质复合板生产方法和木质复合板生产装置 |
EP22802954.2A EP4419304A1 (de) | 2021-10-18 | 2022-10-14 | Verfahren zur herstellung einer holzwerkstoffplatte und holzwerkstoffplatten-herstellvorrichtung |
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EP21203262.7A EP4166294A1 (de) | 2021-10-18 | 2021-10-18 | Verfahren zum herstellen einer holzwerkstoffplatte und holzwerkstoffplatten-herstellvorrichtung |
EP21203262.7 | 2021-10-18 |
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Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP2168738A1 (de) | 2008-09-26 | 2010-03-31 | Flooring Technologies Ltd. | Verfahren zum Herstellen einer Holzfaserplatte und Holzfaserplattenherstellvorrichtung |
EP3127670A2 (de) | 2012-01-31 | 2017-02-08 | Flooring Technologies Ltd. | Verfahren zum imprägnieren von werkstoffplatten |
EP3388213A2 (de) | 2017-02-24 | 2018-10-17 | Cefla Deutschland GmbH | Verfahren zur herstellung einer schwer entzündbaren und/oder verfestigten holzfaserplatte |
CN112440347A (zh) * | 2020-11-25 | 2021-03-05 | 山东宜居新材料科技有限公司 | 一种纳镁板加工工艺及阻燃浸渍装置 |
US20210189245A1 (en) * | 2018-05-11 | 2021-06-24 | Burnblock Holding Aps | Flame-retardant and latent hardener composition, a method for making flame-retarded wood and cellulose-fiber based composites and boards and flame-retarded wood and cellulose-fiber based boards |
-
2021
- 2021-10-18 EP EP21203262.7A patent/EP4166294A1/de active Pending
-
2022
- 2022-10-14 CN CN202280077701.8A patent/CN118284500A/zh active Pending
- 2022-10-14 WO PCT/EP2022/078655 patent/WO2023066802A1/de active Application Filing
- 2022-10-14 EP EP22802954.2A patent/EP4419304A1/de active Pending
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP2168738A1 (de) | 2008-09-26 | 2010-03-31 | Flooring Technologies Ltd. | Verfahren zum Herstellen einer Holzfaserplatte und Holzfaserplattenherstellvorrichtung |
EP3127670A2 (de) | 2012-01-31 | 2017-02-08 | Flooring Technologies Ltd. | Verfahren zum imprägnieren von werkstoffplatten |
EP3388213A2 (de) | 2017-02-24 | 2018-10-17 | Cefla Deutschland GmbH | Verfahren zur herstellung einer schwer entzündbaren und/oder verfestigten holzfaserplatte |
US20210189245A1 (en) * | 2018-05-11 | 2021-06-24 | Burnblock Holding Aps | Flame-retardant and latent hardener composition, a method for making flame-retarded wood and cellulose-fiber based composites and boards and flame-retarded wood and cellulose-fiber based boards |
CN112440347A (zh) * | 2020-11-25 | 2021-03-05 | 山东宜居新材料科技有限公司 | 一种纳镁板加工工艺及阻燃浸渍装置 |
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EP4419304A1 (de) | 2024-08-28 |
EP4166294A1 (de) | 2023-04-19 |
CN118284500A (zh) | 2024-07-02 |
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