WO2023047406A1 - Novel mixtures for crop protection - Google Patents
Novel mixtures for crop protection Download PDFInfo
- Publication number
- WO2023047406A1 WO2023047406A1 PCT/IL2022/051023 IL2022051023W WO2023047406A1 WO 2023047406 A1 WO2023047406 A1 WO 2023047406A1 IL 2022051023 W IL2022051023 W IL 2022051023W WO 2023047406 A1 WO2023047406 A1 WO 2023047406A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- fluvalinate
- tau
- insect
- weight ratio
- controlling
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title claims description 541
- INISTDXBRIBGOC-XMMISQBUSA-N tau-fluvalinate Chemical compound N([C@H](C(C)C)C(=O)OC(C#N)C=1C=C(OC=2C=CC=CC=2)C=CC=1)C1=CC=C(C(F)(F)F)C=C1Cl INISTDXBRIBGOC-XMMISQBUSA-N 0.000 claims abstract description 804
- 239000005936 tau-Fluvalinate Substances 0.000 claims abstract description 803
- 238000000034 method Methods 0.000 claims abstract description 123
- 150000001875 compounds Chemical class 0.000 claims abstract description 87
- 241000238631 Hexapoda Species 0.000 claims description 397
- 230000001276 controlling effect Effects 0.000 claims description 202
- 241000196324 Embryophyta Species 0.000 claims description 139
- 238000009395 breeding Methods 0.000 claims description 98
- 230000001488 breeding effect Effects 0.000 claims description 98
- 235000013305 food Nutrition 0.000 claims description 95
- 230000000694 effects Effects 0.000 claims description 69
- 239000002689 soil Substances 0.000 claims description 62
- 239000003112 inhibitor Substances 0.000 claims description 48
- 239000002917 insecticide Substances 0.000 claims description 32
- 241000825556 Halyomorpha halys Species 0.000 claims description 31
- 108050006807 Nicotinic acetylcholine receptors Proteins 0.000 claims description 31
- 102000019315 Nicotinic acetylcholine receptors Human genes 0.000 claims description 28
- 241001600408 Aphis gossypii Species 0.000 claims description 27
- WCXDHFDTOYPNIE-RIYZIHGNSA-N (E)-acetamiprid Chemical compound N#C/N=C(\C)N(C)CC1=CC=C(Cl)N=C1 WCXDHFDTOYPNIE-RIYZIHGNSA-N 0.000 claims description 24
- 239000005875 Acetamiprid Substances 0.000 claims description 24
- WPALTCMYPARVNV-UHFFFAOYSA-N tolfenpyrad Chemical compound CCC1=NN(C)C(C(=O)NCC=2C=CC(OC=3C=CC(C)=CC=3)=CC=2)=C1Cl WPALTCMYPARVNV-UHFFFAOYSA-N 0.000 claims description 24
- RAMUASXTSSXCMB-UHFFFAOYSA-N 3-bromo-N-{2-bromo-4-chloro-6-[(1-cyclopropylethyl)carbamoyl]phenyl}-1-(3-chloropyridin-2-yl)-1H-pyrazole-5-carboxamide Chemical compound C1CC1C(C)NC(=O)C1=CC(Cl)=CC(Br)=C1NC(=O)C1=CC(Br)=NN1C1=NC=CC=C1Cl RAMUASXTSSXCMB-UHFFFAOYSA-N 0.000 claims description 23
- NJPPVKZQTLUDBO-UHFFFAOYSA-N novaluron Chemical compound C1=C(Cl)C(OC(F)(F)C(OC(F)(F)F)F)=CC=C1NC(=O)NC(=O)C1=C(F)C=CC=C1F NJPPVKZQTLUDBO-UHFFFAOYSA-N 0.000 claims description 23
- ZXQYGBMAQZUVMI-RDDWSQKMSA-N (1S)-cis-(alphaR)-cyhalothrin Chemical compound CC1(C)[C@H](\C=C(/Cl)C(F)(F)F)[C@@H]1C(=O)O[C@@H](C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 ZXQYGBMAQZUVMI-RDDWSQKMSA-N 0.000 claims description 22
- XGWIJUOSCAQSSV-XHDPSFHLSA-N (S,S)-hexythiazox Chemical compound S([C@H]([C@@H]1C)C=2C=CC(Cl)=CC=2)C(=O)N1C(=O)NC1CCCCC1 XGWIJUOSCAQSSV-XHDPSFHLSA-N 0.000 claims description 22
- SWBHWUYHHJCADA-UHFFFAOYSA-N 3-(2-chlorophenyl)-6-(2,6-difluorophenyl)-1,2,4,5-tetrazine Chemical compound FC1=CC=CC(F)=C1C1=NN=C(C=2C(=CC=CC=2)Cl)N=N1 SWBHWUYHHJCADA-UHFFFAOYSA-N 0.000 claims description 22
- 239000005653 Bifenazate Substances 0.000 claims description 22
- JFLRKDZMHNBDQS-UCQUSYKYSA-N CC[C@H]1CCC[C@@H]([C@H](C(=O)C2=C[C@H]3[C@@H]4C[C@@H](C[C@H]4C(=C[C@H]3[C@@H]2CC(=O)O1)C)O[C@H]5[C@@H]([C@@H]([C@H]([C@@H](O5)C)OC)OC)OC)C)O[C@H]6CC[C@@H]([C@H](O6)C)N(C)C.CC[C@H]1CCC[C@@H]([C@H](C(=O)C2=C[C@H]3[C@@H]4C[C@@H](C[C@H]4C=C[C@H]3C2CC(=O)O1)O[C@H]5[C@@H]([C@@H]([C@H]([C@@H](O5)C)OC)OC)OC)C)O[C@H]6CC[C@@H]([C@H](O6)C)N(C)C Chemical compound CC[C@H]1CCC[C@@H]([C@H](C(=O)C2=C[C@H]3[C@@H]4C[C@@H](C[C@H]4C(=C[C@H]3[C@@H]2CC(=O)O1)C)O[C@H]5[C@@H]([C@@H]([C@H]([C@@H](O5)C)OC)OC)OC)C)O[C@H]6CC[C@@H]([C@H](O6)C)N(C)C.CC[C@H]1CCC[C@@H]([C@H](C(=O)C2=C[C@H]3[C@@H]4C[C@@H](C[C@H]4C=C[C@H]3C2CC(=O)O1)O[C@H]5[C@@H]([C@@H]([C@H]([C@@H](O5)C)OC)OC)OC)C)O[C@H]6CC[C@@H]([C@H](O6)C)N(C)C JFLRKDZMHNBDQS-UCQUSYKYSA-N 0.000 claims description 22
- 239000005654 Clofentezine Substances 0.000 claims description 22
- 239000005897 Etoxazole Substances 0.000 claims description 22
- 239000005657 Fenpyroximate Substances 0.000 claims description 22
- 239000005661 Hexythiazox Substances 0.000 claims description 22
- 101001018064 Homo sapiens Lysosomal-trafficking regulator Proteins 0.000 claims description 22
- 101000667110 Homo sapiens Vacuolar protein sorting-associated protein 13B Proteins 0.000 claims description 22
- 102100033472 Lysosomal-trafficking regulator Human genes 0.000 claims description 22
- 239000005929 Spinetoram Substances 0.000 claims description 22
- GOENIMGKWNZVDA-OAMCMWGQSA-N Spinetoram Chemical compound CO[C@@H]1[C@H](OCC)[C@@H](OC)[C@H](C)O[C@H]1OC1C[C@H]2[C@@H]3C=C4C(=O)[C@H](C)[C@@H](O[C@@H]5O[C@H](C)[C@H](CC5)N(C)C)CCC[C@H](CC)OC(=O)CC4[C@@H]3CC[C@@H]2C1 GOENIMGKWNZVDA-OAMCMWGQSA-N 0.000 claims description 22
- 239000005930 Spinosad Substances 0.000 claims description 22
- LRZWFURXIMFONG-HRSIRGMGSA-N afidopyropen Chemical compound C([C@@]1(C)[C@H]2[C@]([C@H]3[C@@H](O)C=4C(=O)OC(=CC=4O[C@]3(C)[C@@H](O)C2)C=2C=NC=CC=2)(C)CC[C@@H]1OC(=O)C1CC1)OC(=O)C1CC1 LRZWFURXIMFONG-HRSIRGMGSA-N 0.000 claims description 22
- VHLKTXFWDRXILV-UHFFFAOYSA-N bifenazate Chemical compound C1=C(NNC(=O)OC(C)C)C(OC)=CC=C1C1=CC=CC=C1 VHLKTXFWDRXILV-UHFFFAOYSA-N 0.000 claims description 22
- UXADOQPNKNTIHB-UHFFFAOYSA-N clofentezine Chemical compound ClC1=CC=CC=C1C1=NN=C(C=2C(=CC=CC=2)Cl)N=N1 UXADOQPNKNTIHB-UHFFFAOYSA-N 0.000 claims description 22
- IXSZQYVWNJNRAL-UHFFFAOYSA-N etoxazole Chemical compound CCOC1=CC(C(C)(C)C)=CC=C1C1N=C(C=2C(=CC=CC=2F)F)OC1 IXSZQYVWNJNRAL-UHFFFAOYSA-N 0.000 claims description 22
- YYJNOYZRYGDPNH-MFKUBSTISA-N fenpyroximate Chemical compound C=1C=C(C(=O)OC(C)(C)C)C=CC=1CO/N=C/C=1C(C)=NN(C)C=1OC1=CC=CC=C1 YYJNOYZRYGDPNH-MFKUBSTISA-N 0.000 claims description 22
- 239000005910 lambda-Cyhalothrin Substances 0.000 claims description 22
- 229940014213 spinosad Drugs 0.000 claims description 22
- LHZOTJOOBRODLL-UHFFFAOYSA-N 4-oxo-1-(pyrimidin-5-ylmethyl)-3-[3-(trifluoromethyl)phenyl]pyrido[1,2-a]pyrimidin-5-ium-2-olate Chemical compound O=C1[N+]2=CC=CC=C2N(CC=2C=NC=NC=2)C([O-])=C1C1=CC=CC(C(F)(F)F)=C1 LHZOTJOOBRODLL-UHFFFAOYSA-N 0.000 claims description 21
- 241000193388 Bacillus thuringiensis Species 0.000 claims description 21
- 239000005926 Pyridalyl Substances 0.000 claims description 21
- 241001454293 Tetranychus urticae Species 0.000 claims description 21
- 229940097012 bacillus thuringiensis Drugs 0.000 claims description 21
- WOWBFOBYOAGEEA-UHFFFAOYSA-N diafenthiuron Chemical compound CC(C)C1=C(NC(=S)NC(C)(C)C)C(C(C)C)=CC(OC=2C=CC=CC=2)=C1 WOWBFOBYOAGEEA-UHFFFAOYSA-N 0.000 claims description 21
- AEHJMNVBLRLZKK-UHFFFAOYSA-N pyridalyl Chemical group N1=CC(C(F)(F)F)=CC=C1OCCCOC1=C(Cl)C=C(OCC=C(Cl)Cl)C=C1Cl AEHJMNVBLRLZKK-UHFFFAOYSA-N 0.000 claims description 21
- 239000003053 toxin Substances 0.000 claims description 21
- 231100000765 toxin Toxicity 0.000 claims description 21
- 239000000463 material Substances 0.000 claims description 20
- -1 tetranortriterpenoid limonoid Chemical class 0.000 claims description 20
- PXMNMQRDXWABCY-UHFFFAOYSA-N 1-(4-chlorophenyl)-4,4-dimethyl-3-(1H-1,2,4-triazol-1-ylmethyl)pentan-3-ol Chemical compound C1=NC=NN1CC(O)(C(C)(C)C)CCC1=CC=C(Cl)C=C1 PXMNMQRDXWABCY-UHFFFAOYSA-N 0.000 claims description 19
- 239000005886 Chlorantraniliprole Substances 0.000 claims description 19
- 239000005889 Cyantraniliprole Substances 0.000 claims description 19
- 239000005760 Difenoconazole Substances 0.000 claims description 19
- 239000005901 Flubendiamide Substances 0.000 claims description 19
- 239000005925 Pymetrozine Substances 0.000 claims description 19
- 239000005934 Sulfoxaflor Substances 0.000 claims description 19
- 239000005839 Tebuconazole Substances 0.000 claims description 19
- ZVQOOHYFBIDMTQ-UHFFFAOYSA-N [methyl(oxido){1-[6-(trifluoromethyl)pyridin-3-yl]ethyl}-lambda(6)-sulfanylidene]cyanamide Chemical compound N#CN=S(C)(=O)C(C)C1=CC=C(C(F)(F)F)N=C1 ZVQOOHYFBIDMTQ-UHFFFAOYSA-N 0.000 claims description 19
- 230000015572 biosynthetic process Effects 0.000 claims description 19
- PSOVNZZNOMJUBI-UHFFFAOYSA-N chlorantraniliprole Chemical compound CNC(=O)C1=CC(Cl)=CC(C)=C1NC(=O)C1=CC(Br)=NN1C1=NC=CC=C1Cl PSOVNZZNOMJUBI-UHFFFAOYSA-N 0.000 claims description 19
- DVBUIBGJRQBEDP-UHFFFAOYSA-N cyantraniliprole Chemical compound CNC(=O)C1=CC(C#N)=CC(C)=C1NC(=O)C1=CC(Br)=NN1C1=NC=CC=C1Cl DVBUIBGJRQBEDP-UHFFFAOYSA-N 0.000 claims description 19
- BQYJATMQXGBDHF-UHFFFAOYSA-N difenoconazole Chemical compound O1C(C)COC1(C=1C(=CC(OC=2C=CC(Cl)=CC=2)=CC=1)Cl)CN1N=CN=C1 BQYJATMQXGBDHF-UHFFFAOYSA-N 0.000 claims description 19
- ZGNITFSDLCMLGI-UHFFFAOYSA-N flubendiamide Chemical compound CC1=CC(C(F)(C(F)(F)F)C(F)(F)F)=CC=C1NC(=O)C1=CC=CC(I)=C1C(=O)NC(C)(C)CS(C)(=O)=O ZGNITFSDLCMLGI-UHFFFAOYSA-N 0.000 claims description 19
- QHMTXANCGGJZRX-WUXMJOGZSA-N pymetrozine Chemical compound C1C(C)=NNC(=O)N1\N=C\C1=CC=CN=C1 QHMTXANCGGJZRX-WUXMJOGZSA-N 0.000 claims description 19
- 239000002728 pyrethroid Substances 0.000 claims description 19
- MIOBBYRMXGNORL-UHFFFAOYSA-N pyrifluquinazon Chemical compound C1C2=CC(C(F)(C(F)(F)F)C(F)(F)F)=CC=C2N(C(=O)C)C(=O)N1NCC1=CC=CN=C1 MIOBBYRMXGNORL-UHFFFAOYSA-N 0.000 claims description 19
- DGOAXBPOVUPPEB-UHFFFAOYSA-N 3-(difluoromethyl)-N-methoxy-1-methyl-N-[1-(2,4,6-trichlorophenyl)propan-2-yl]pyrazole-4-carboxamide Chemical compound C=1N(C)N=C(C(F)F)C=1C(=O)N(OC)C(C)CC1=C(Cl)C=C(Cl)C=C1Cl DGOAXBPOVUPPEB-UHFFFAOYSA-N 0.000 claims description 18
- 239000005730 Azoxystrobin Substances 0.000 claims description 18
- 229920002101 Chitin Polymers 0.000 claims description 18
- 239000005891 Cyromazine Substances 0.000 claims description 18
- 239000005894 Emamectin Substances 0.000 claims description 18
- 239000005900 Flonicamid Substances 0.000 claims description 18
- 239000005781 Fludioxonil Substances 0.000 claims description 18
- 239000005907 Indoxacarb Substances 0.000 claims description 18
- 239000005802 Mancozeb Substances 0.000 claims description 18
- 239000005927 Pyriproxyfen Substances 0.000 claims description 18
- 239000005931 Spirotetramat Substances 0.000 claims description 18
- ONHBDDJJTDTLIR-UHFFFAOYSA-N azocyclotin Chemical compound C1CCCCC1[Sn](N1N=CN=C1)(C1CCCCC1)C1CCCCC1 ONHBDDJJTDTLIR-UHFFFAOYSA-N 0.000 claims description 18
- WFDXOXNFNRHQEC-GHRIWEEISA-N azoxystrobin Chemical compound CO\C=C(\C(=O)OC)C1=CC=CC=C1OC1=CC(OC=2C(=CC=CC=2)C#N)=NC=N1 WFDXOXNFNRHQEC-GHRIWEEISA-N 0.000 claims description 18
- LVQDKIWDGQRHTE-UHFFFAOYSA-N cyromazine Chemical compound NC1=NC(N)=NC(NC2CC2)=N1 LVQDKIWDGQRHTE-UHFFFAOYSA-N 0.000 claims description 18
- 229950000775 cyromazine Drugs 0.000 claims description 18
- RLQJEEJISHYWON-UHFFFAOYSA-N flonicamid Chemical compound FC(F)(F)C1=CC=NC=C1C(=O)NCC#N RLQJEEJISHYWON-UHFFFAOYSA-N 0.000 claims description 18
- MUJOIMFVNIBMKC-UHFFFAOYSA-N fludioxonil Chemical compound C=12OC(F)(F)OC2=CC=CC=1C1=CNC=C1C#N MUJOIMFVNIBMKC-UHFFFAOYSA-N 0.000 claims description 18
- VBCVPMMZEGZULK-NRFANRHFSA-N indoxacarb Chemical compound C([C@@]1(OC2)C(=O)OC)C3=CC(Cl)=CC=C3C1=NN2C(=O)N(C(=O)OC)C1=CC=C(OC(F)(F)F)C=C1 VBCVPMMZEGZULK-NRFANRHFSA-N 0.000 claims description 18
- NHDHVHZZCFYRSB-UHFFFAOYSA-N pyriproxyfen Chemical compound C=1C=CC=NC=1OC(C)COC(C=C1)=CC=C1OC1=CC=CC=C1 NHDHVHZZCFYRSB-UHFFFAOYSA-N 0.000 claims description 18
- WOPFPAIGRGHWAQ-UHFFFAOYSA-N spiropidion Chemical compound CCOC(=O)OC1=C(C=2C(=CC(Cl)=CC=2C)C)C(=O)N(C)C11CCN(OC)CC1 WOPFPAIGRGHWAQ-UHFFFAOYSA-N 0.000 claims description 18
- CLSVJBIHYWPGQY-GGYDESQDSA-N spirotetramat Chemical compound CCOC(=O)OC1=C(C=2C(=CC=C(C)C=2)C)C(=O)N[C@@]11CC[C@H](OC)CC1 CLSVJBIHYWPGQY-GGYDESQDSA-N 0.000 claims description 18
- MLGCXEBRWGEOQX-UHFFFAOYSA-N tetradifon Chemical compound C1=CC(Cl)=CC=C1S(=O)(=O)C1=CC(Cl)=C(Cl)C=C1Cl MLGCXEBRWGEOQX-UHFFFAOYSA-N 0.000 claims description 18
- PTQBEFQWTBZMED-UHFFFAOYSA-N 2-(3-ethylsulfonylpyridin-2-yl)-5-(trifluoromethylsulfonyl)-1,3-benzoxazole Chemical group CCS(=O)(=O)C1=CC=CN=C1C1=NC2=CC(S(=O)(=O)C(F)(F)F)=CC=C2O1 PTQBEFQWTBZMED-UHFFFAOYSA-N 0.000 claims description 17
- BOTNFCTYKJBUMU-UHFFFAOYSA-N 2-[4-(2-methylpropyl)piperazin-4-ium-1-yl]-2-oxoacetate Chemical compound CC(C)C[NH+]1CCN(C(=O)C([O-])=O)CC1 BOTNFCTYKJBUMU-UHFFFAOYSA-N 0.000 claims description 17
- 239000005878 Azadirachtin Substances 0.000 claims description 17
- 239000005788 Fluxapyroxad Substances 0.000 claims description 17
- VEHPJKVTJQSSKL-UHFFFAOYSA-N azadirachtin Natural products O1C2(C)C(C3(C=COC3O3)O)CC3C21C1(C)C(O)C(OCC2(OC(C)=O)C(CC3OC(=O)C(C)=CC)OC(C)=O)C2C32COC(C(=O)OC)(O)C12 VEHPJKVTJQSSKL-UHFFFAOYSA-N 0.000 claims description 17
- FTNJWQUOZFUQQJ-NDAWSKJSSA-N azadirachtin A Chemical compound C([C@@H]([C@]1(C=CO[C@H]1O1)O)[C@]2(C)O3)[C@H]1[C@]23[C@]1(C)[C@H](O)[C@H](OC[C@@]2([C@@H](C[C@@H]3OC(=O)C(\C)=C\C)OC(C)=O)C(=O)OC)[C@@H]2[C@]32CO[C@@](C(=O)OC)(O)[C@@H]12 FTNJWQUOZFUQQJ-NDAWSKJSSA-N 0.000 claims description 17
- FTNJWQUOZFUQQJ-IRYYUVNJSA-N azadirachtin A Natural products C([C@@H]([C@]1(C=CO[C@H]1O1)O)[C@]2(C)O3)[C@H]1[C@]23[C@]1(C)[C@H](O)[C@H](OC[C@@]2([C@@H](C[C@@H]3OC(=O)C(\C)=C/C)OC(C)=O)C(=O)OC)[C@@H]2[C@]32CO[C@@](C(=O)OC)(O)[C@@H]12 FTNJWQUOZFUQQJ-IRYYUVNJSA-N 0.000 claims description 17
- ZYXYTGQFPZEUFX-UHFFFAOYSA-N benzpyrimoxan Chemical compound O1C(OCCC1)C=1C(=NC=NC=1)OCC1=CC=C(C=C1)C(F)(F)F ZYXYTGQFPZEUFX-UHFFFAOYSA-N 0.000 claims description 17
- QSLZKWPYTWEWHC-UHFFFAOYSA-N broflanilide Chemical compound C=1C=CC(C(=O)NC=2C(=CC(=CC=2Br)C(F)(C(F)(F)F)C(F)(F)F)C(F)(F)F)=C(F)C=1N(C)C(=O)C1=CC=CC=C1 QSLZKWPYTWEWHC-UHFFFAOYSA-N 0.000 claims description 17
- SXSGXWCSHSVPGB-UHFFFAOYSA-N fluxapyroxad Chemical compound FC(F)C1=NN(C)C=C1C(=O)NC1=CC=CC=C1C1=CC(F)=C(F)C(F)=C1 SXSGXWCSHSVPGB-UHFFFAOYSA-N 0.000 claims description 17
- DHQKLWKZSFCKTA-UHFFFAOYSA-N n-[1-[(6-chloropyridin-3-yl)methyl]pyridin-2-ylidene]-2,2,2-trifluoroacetamide Chemical compound FC(F)(F)C(=O)N=C1C=CC=CN1CC1=CC=C(Cl)N=C1 DHQKLWKZSFCKTA-UHFFFAOYSA-N 0.000 claims description 17
- 244000103451 Scirpus litoralis Species 0.000 claims description 16
- 239000003630 growth substance Substances 0.000 claims description 16
- 230000002438 mitochondrial effect Effects 0.000 claims description 16
- 210000000056 organ Anatomy 0.000 claims description 16
- DNVLJEWNNDHELH-UHFFFAOYSA-N thiocyclam Chemical compound CN(C)C1CSSSC1 DNVLJEWNNDHELH-UHFFFAOYSA-N 0.000 claims description 16
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 16
- 230000002860 competitive effect Effects 0.000 claims description 14
- 230000002708 enhancing effect Effects 0.000 claims description 14
- 230000002195 synergetic effect Effects 0.000 claims description 14
- 239000012528 membrane Substances 0.000 claims description 13
- 230000000813 microbial effect Effects 0.000 claims description 13
- 108091006146 Channels Proteins 0.000 claims description 12
- 206010061217 Infestation Diseases 0.000 claims description 12
- 102000013379 Mitochondrial Proton-Translocating ATPases Human genes 0.000 claims description 12
- 108010026155 Mitochondrial Proton-Translocating ATPases Proteins 0.000 claims description 12
- 102000003563 TRPV Human genes 0.000 claims description 12
- 108060008564 TRPV Proteins 0.000 claims description 12
- 239000003966 growth inhibitor Substances 0.000 claims description 12
- 239000003992 organochlorine insecticide Substances 0.000 claims description 12
- 229940075993 receptor modulator Drugs 0.000 claims description 12
- 102000042094 ryanodine receptor (TC 1.A.3.1) family Human genes 0.000 claims description 12
- 108091052345 ryanodine receptor (TC 1.A.3.1) family Proteins 0.000 claims description 12
- 238000003197 gene knockdown Methods 0.000 claims description 11
- 230000000361 pesticidal effect Effects 0.000 claims description 10
- 239000004094 surface-active agent Substances 0.000 claims description 10
- 230000002035 prolonged effect Effects 0.000 claims description 9
- 238000001228 spectrum Methods 0.000 claims description 9
- 241000256250 Spodoptera littoralis Species 0.000 claims description 8
- 230000008635 plant growth Effects 0.000 claims description 8
- 239000000417 fungicide Substances 0.000 claims description 7
- 108050006905 Glutamate-Gated Chloride Channel Proteins 0.000 claims description 6
- 241000256248 Spodoptera Species 0.000 claims description 6
- 239000003085 diluting agent Substances 0.000 claims description 6
- NYPJDWWKZLNGGM-UHFFFAOYSA-N fenvalerate Chemical compound C=1C=C(Cl)C=CC=1C(C(C)C)C(=O)OC(C#N)C(C=1)=CC=CC=1OC1=CC=CC=C1 NYPJDWWKZLNGGM-UHFFFAOYSA-N 0.000 claims description 6
- 230000008121 plant development Effects 0.000 claims description 6
- 241000254127 Bemisia tabaci Species 0.000 claims description 5
- 230000001105 regulatory effect Effects 0.000 claims description 5
- 239000007787 solid Substances 0.000 claims description 5
- 241001600407 Aphis <genus> Species 0.000 claims description 4
- 241000255581 Drosophila <fruit fly, genus> Species 0.000 claims description 4
- 241000255990 Helicoverpa Species 0.000 claims description 4
- 241001414826 Lygus Species 0.000 claims description 4
- 241001389006 Tuta absoluta Species 0.000 claims description 4
- 230000000855 fungicidal effect Effects 0.000 claims description 4
- 239000007788 liquid Substances 0.000 claims description 4
- JYEUMXHLPRZUAT-UHFFFAOYSA-N 1,2,3-triazine Chemical compound C1=CN=NN=C1 JYEUMXHLPRZUAT-UHFFFAOYSA-N 0.000 claims description 3
- 102000000452 Acetyl-CoA carboxylase Human genes 0.000 claims description 3
- 108010016219 Acetyl-CoA carboxylase Proteins 0.000 claims description 3
- 240000005343 Azadirachta indica Species 0.000 claims description 3
- 239000005874 Bifenthrin Substances 0.000 claims description 3
- 108010018763 Biotin carboxylase Proteins 0.000 claims description 3
- 239000005946 Cypermethrin Substances 0.000 claims description 3
- 239000005892 Deltamethrin Substances 0.000 claims description 3
- 241000189565 Frankliniella Species 0.000 claims description 3
- 235000013500 Melia azadirachta Nutrition 0.000 claims description 3
- 241000721623 Myzus Species 0.000 claims description 3
- 241001454295 Tetranychidae Species 0.000 claims description 3
- 229940125516 allosteric modulator Drugs 0.000 claims description 3
- OMFRMAHOUUJSGP-IRHGGOMRSA-N bifenthrin Chemical compound C1=CC=C(C=2C=CC=CC=2)C(C)=C1COC(=O)[C@@H]1[C@H](\C=C(/Cl)C(F)(F)F)C1(C)C OMFRMAHOUUJSGP-IRHGGOMRSA-N 0.000 claims description 3
- 229960005424 cypermethrin Drugs 0.000 claims description 3
- KAATUXNTWXVJKI-UHFFFAOYSA-N cypermethrin Chemical compound CC1(C)C(C=C(Cl)Cl)C1C(=O)OC(C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 KAATUXNTWXVJKI-UHFFFAOYSA-N 0.000 claims description 3
- 229960002483 decamethrin Drugs 0.000 claims description 3
- OWZREIFADZCYQD-NSHGMRRFSA-N deltamethrin Chemical compound CC1(C)[C@@H](C=C(Br)Br)[C@H]1C(=O)O[C@H](C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 OWZREIFADZCYQD-NSHGMRRFSA-N 0.000 claims description 3
- 230000001419 dependent effect Effects 0.000 claims description 3
- 229960000490 permethrin Drugs 0.000 claims description 3
- RLLPVAHGXHCWKJ-UHFFFAOYSA-N permethrin Chemical compound CC1(C)C(C=C(Cl)Cl)C1C(=O)OCC1=CC=CC(OC=2C=CC=CC=2)=C1 RLLPVAHGXHCWKJ-UHFFFAOYSA-N 0.000 claims description 3
- 150000003230 pyrimidines Chemical class 0.000 claims description 3
- 229940125794 sodium channel blocker Drugs 0.000 claims description 3
- 239000003195 sodium channel blocking agent Substances 0.000 claims description 3
- 240000003949 Sporobolus virginicus Species 0.000 claims 4
- CXEGAUYXQAKHKJ-NSBHKLITSA-N emamectin B1a Chemical compound C1=C[C@H](C)[C@@H]([C@@H](C)CC)O[C@]11O[C@H](C\C=C(C)\[C@@H](O[C@@H]2O[C@@H](C)[C@H](O[C@@H]3O[C@@H](C)[C@H](NC)[C@@H](OC)C3)[C@@H](OC)C2)[C@@H](C)\C=C\C=C/2[C@]3([C@H](C(=O)O4)C=C(C)[C@@H](O)[C@H]3OC\2)O)C[C@H]4C1 CXEGAUYXQAKHKJ-NSBHKLITSA-N 0.000 claims 1
- 241000607479 Yersinia pestis Species 0.000 abstract description 52
- 238000009472 formulation Methods 0.000 description 212
- 239000000126 substance Substances 0.000 description 84
- HTSGKJQDMSTCGS-UHFFFAOYSA-N 1,4-bis(4-chlorophenyl)-2-(4-methylphenyl)sulfonylbutane-1,4-dione Chemical compound C1=CC(C)=CC=C1S(=O)(=O)C(C(=O)C=1C=CC(Cl)=CC=1)CC(=O)C1=CC=C(Cl)C=C1 HTSGKJQDMSTCGS-UHFFFAOYSA-N 0.000 description 65
- 208000015181 infectious disease Diseases 0.000 description 48
- 239000004480 active ingredient Substances 0.000 description 29
- GCKZANITAMOIAR-XWVCPFKXSA-N dsstox_cid_14566 Chemical compound [O-]C(=O)C1=CC=CC=C1.C1=C[C@H](C)[C@@H]([C@@H](C)CC)O[C@]11O[C@H](C\C=C(C)\[C@@H](O[C@@H]2O[C@@H](C)[C@H](O[C@@H]3O[C@@H](C)[C@H]([NH2+]C)[C@@H](OC)C3)[C@@H](OC)C2)[C@@H](C)\C=C\C=C/2[C@]3([C@H](C(=O)O4)C=C(C)[C@@H](O)[C@H]3OC\2)O)C[C@H]4C1 GCKZANITAMOIAR-XWVCPFKXSA-N 0.000 description 17
- 241000254171 Curculionidae Species 0.000 description 15
- 230000009471 action Effects 0.000 description 10
- 230000001965 increasing effect Effects 0.000 description 10
- 239000003921 oil Substances 0.000 description 8
- 241000254173 Coleoptera Species 0.000 description 7
- 241000258937 Hemiptera Species 0.000 description 7
- 241000256259 Noctuidae Species 0.000 description 7
- 238000011161 development Methods 0.000 description 7
- 230000018109 developmental process Effects 0.000 description 7
- 239000000839 emulsion Substances 0.000 description 7
- 235000019198 oils Nutrition 0.000 description 7
- 230000002829 reductive effect Effects 0.000 description 7
- 241001124076 Aphididae Species 0.000 description 6
- 101150026868 CHS1 gene Proteins 0.000 description 6
- 230000006378 damage Effects 0.000 description 6
- 239000008187 granular material Substances 0.000 description 6
- 239000002904 solvent Substances 0.000 description 6
- 241000255925 Diptera Species 0.000 description 5
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 5
- 241000255967 Helicoverpa zea Species 0.000 description 5
- 241001414989 Thysanoptera Species 0.000 description 5
- 239000000654 additive Substances 0.000 description 5
- 239000000969 carrier Substances 0.000 description 5
- 235000013399 edible fruits Nutrition 0.000 description 5
- 230000000749 insecticidal effect Effects 0.000 description 5
- 150000003014 phosphoric acid esters Chemical class 0.000 description 5
- 239000007921 spray Substances 0.000 description 5
- 241000353522 Earias insulana Species 0.000 description 4
- 241001441330 Grapholita molesta Species 0.000 description 4
- 241001261104 Lobesia botrana Species 0.000 description 4
- 241001477931 Mythimna unipuncta Species 0.000 description 4
- 241000255588 Tephritidae Species 0.000 description 4
- 230000000996 additive effect Effects 0.000 description 4
- 239000002671 adjuvant Substances 0.000 description 4
- 239000012141 concentrate Substances 0.000 description 4
- 244000038559 crop plants Species 0.000 description 4
- 230000012010 growth Effects 0.000 description 4
- 235000012054 meals Nutrition 0.000 description 4
- 238000012986 modification Methods 0.000 description 4
- 230000004048 modification Effects 0.000 description 4
- 239000000575 pesticide Substances 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- 235000000346 sugar Nutrition 0.000 description 4
- 241001166626 Aulacorthum solani Species 0.000 description 3
- 241001414720 Cicadellidae Species 0.000 description 3
- 241000592377 Cryptolestes ferrugineus Species 0.000 description 3
- 241000122098 Ephestia kuehniella Species 0.000 description 3
- 241000233866 Fungi Species 0.000 description 3
- 241001147381 Helicoverpa armigera Species 0.000 description 3
- 241001665120 Metisa plana Species 0.000 description 3
- 241001414825 Miridae Species 0.000 description 3
- 241000257159 Musca domestica Species 0.000 description 3
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
- 241001630088 Parlatoria ziziphi Species 0.000 description 3
- 241000676810 Phytocoris Species 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- 241000180219 Sitobion avenae Species 0.000 description 3
- 241001168723 Sitona lineatus Species 0.000 description 3
- 235000013339 cereals Nutrition 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 239000002270 dispersing agent Substances 0.000 description 3
- 239000006185 dispersion Substances 0.000 description 3
- 230000007613 environmental effect Effects 0.000 description 3
- 238000002474 experimental method Methods 0.000 description 3
- 239000003337 fertilizer Substances 0.000 description 3
- 239000004009 herbicide Substances 0.000 description 3
- 230000002452 interceptive effect Effects 0.000 description 3
- 239000002949 juvenile hormone Substances 0.000 description 3
- 230000000670 limiting effect Effects 0.000 description 3
- 108090000623 proteins and genes Proteins 0.000 description 3
- 230000002786 root growth Effects 0.000 description 3
- 239000000725 suspension Substances 0.000 description 3
- 239000004546 suspension concentrate Substances 0.000 description 3
- 239000002562 thickening agent Substances 0.000 description 3
- 235000013311 vegetables Nutrition 0.000 description 3
- 230000000007 visual effect Effects 0.000 description 3
- 239000004562 water dispersible granule Substances 0.000 description 3
- 239000000080 wetting agent Substances 0.000 description 3
- 239000002023 wood Substances 0.000 description 3
- 241001143309 Acanthoscelides obtectus Species 0.000 description 2
- 241001014341 Acrosternum hilare Species 0.000 description 2
- 241000275062 Agrilus planipennis Species 0.000 description 2
- 241001136249 Agriotes lineatus Species 0.000 description 2
- 241001003964 Agromyza frontella Species 0.000 description 2
- 241000590412 Agromyzidae Species 0.000 description 2
- 241000566547 Agrotis ipsilon Species 0.000 description 2
- 241000307865 Aleurothrixus floccosus Species 0.000 description 2
- 241001302676 Anabrus simplex Species 0.000 description 2
- 241001198505 Anarsia lineatella Species 0.000 description 2
- 241001136527 Anastrepha suspensa Species 0.000 description 2
- 241001609695 Anoplophora glabripennis Species 0.000 description 2
- 241000254175 Anthonomus grandis Species 0.000 description 2
- 241000625764 Anticarsia gemmatalis Species 0.000 description 2
- 241001414828 Aonidiella aurantii Species 0.000 description 2
- 244000105624 Arachis hypogaea Species 0.000 description 2
- 241001002470 Archips argyrospila Species 0.000 description 2
- 241000384125 Argyrotaenia citrana Species 0.000 description 2
- 241001174347 Atomaria Species 0.000 description 2
- 241001124181 Bactrocera dorsalis Species 0.000 description 2
- 241001629132 Blissus leucopterus Species 0.000 description 2
- 240000002791 Brassica napus Species 0.000 description 2
- 240000007124 Brassica oleracea Species 0.000 description 2
- 235000003899 Brassica oleracea var acephala Nutrition 0.000 description 2
- 235000011299 Brassica oleracea var botrytis Nutrition 0.000 description 2
- 235000011301 Brassica oleracea var capitata Nutrition 0.000 description 2
- 235000001169 Brassica oleracea var oleracea Nutrition 0.000 description 2
- 240000003259 Brassica oleracea var. botrytis Species 0.000 description 2
- 241001444260 Brassicogethes aeneus Species 0.000 description 2
- 241000982105 Brevicoryne brassicae Species 0.000 description 2
- 241000726760 Cadra cautella Species 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- 241000907862 Callosobruchus maculatus Species 0.000 description 2
- 241001350371 Capua Species 0.000 description 2
- 241001347511 Carposina sasakii Species 0.000 description 2
- 241001465828 Cecidomyiidae Species 0.000 description 2
- 241001450756 Ceroplastes rubens Species 0.000 description 2
- 241001124201 Cerotoma trifurcata Species 0.000 description 2
- 241000604356 Chamaepsila rosae Species 0.000 description 2
- 241001488956 Chlumetia transversa Species 0.000 description 2
- 241001124562 Choristoneura rosaceana Species 0.000 description 2
- 241001367803 Chrysodeixis includens Species 0.000 description 2
- 241001635683 Cimex hemipterus Species 0.000 description 2
- 241001327638 Cimex lectularius Species 0.000 description 2
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 2
- 241000098289 Cnaphalocrocis medinalis Species 0.000 description 2
- 241001465977 Coccoidea Species 0.000 description 2
- 241001529599 Colaspis brunnea Species 0.000 description 2
- 241000683561 Conoderus Species 0.000 description 2
- 241000532642 Conotrachelus nenuphar Species 0.000 description 2
- 229920000742 Cotton Polymers 0.000 description 2
- 241000902369 Crioceris asparagi Species 0.000 description 2
- 241000456564 Cryptolestes turcicus Species 0.000 description 2
- 241001635274 Cydia pomonella Species 0.000 description 2
- 241000969022 Dasineura Species 0.000 description 2
- 241001609607 Delia platura Species 0.000 description 2
- 241001564528 Deporaus marginatus Species 0.000 description 2
- 241001641896 Dermestes lardarius Species 0.000 description 2
- 241001513837 Dermestes maculatus Species 0.000 description 2
- 241000122105 Diatraea Species 0.000 description 2
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 2
- 241001279823 Diuraphis noxia Species 0.000 description 2
- 241001517923 Douglasiidae Species 0.000 description 2
- 241001581006 Dysaphis plantaginea Species 0.000 description 2
- 241001035625 Dysdercus suturellus Species 0.000 description 2
- 241001533565 Dysmicoccus brevipes Species 0.000 description 2
- 241000241133 Earias Species 0.000 description 2
- 241000400698 Elasmopalpus lignosellus Species 0.000 description 2
- 241000462639 Epilachna varivestis Species 0.000 description 2
- 241000917107 Eriosoma lanigerum Species 0.000 description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 2
- 239000005977 Ethylene Substances 0.000 description 2
- 241001181621 Eurygaster maura Species 0.000 description 2
- 241001619920 Euschistus servus Species 0.000 description 2
- 241001605556 Euxoa auxiliaris Species 0.000 description 2
- 241000958182 Fannia scalaris Species 0.000 description 2
- 241000654868 Frankliniella fusca Species 0.000 description 2
- 241000927584 Frankliniella occidentalis Species 0.000 description 2
- 241001660201 Gasterophilus intestinalis Species 0.000 description 2
- 244000068988 Glycine max Species 0.000 description 2
- 241000923682 Grapholita funebrana Species 0.000 description 2
- 241001243087 Gryllotalpidae Species 0.000 description 2
- 241000257232 Haematobia irritans Species 0.000 description 2
- 244000020551 Helianthus annuus Species 0.000 description 2
- 235000003222 Helianthus annuus Nutrition 0.000 description 2
- 241001581044 Hellula undalis Species 0.000 description 2
- 241001508566 Hypera postica Species 0.000 description 2
- 241000257174 Hypoderma lineatum Species 0.000 description 2
- 241001058150 Icerya purchasi Species 0.000 description 2
- 241000595926 Idioscopus nitidulus Species 0.000 description 2
- 241000400431 Keiferia lycopersicella Species 0.000 description 2
- 241001470017 Laodelphax striatella Species 0.000 description 2
- 241000258916 Leptinotarsa decemlineata Species 0.000 description 2
- 241000086074 Leucinodes orbonalis Species 0.000 description 2
- 241000540210 Leucoptera coffeella Species 0.000 description 2
- 229920001732 Lignosulfonate Polymers 0.000 description 2
- 241000403259 Liogenys Species 0.000 description 2
- 241000966204 Lissorhoptrus oryzophilus Species 0.000 description 2
- 241000721703 Lymantria dispar Species 0.000 description 2
- 241000721715 Macrosiphum Species 0.000 description 2
- 241000180172 Macrosiphum rosae Species 0.000 description 2
- 241001414662 Macrosteles fascifrons Species 0.000 description 2
- 241001598997 Maecolaspis Species 0.000 description 2
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 2
- 241000555303 Mamestra brassicae Species 0.000 description 2
- 241001232130 Maruca testulalis Species 0.000 description 2
- 241000771994 Melophagus ovinus Species 0.000 description 2
- 241000168713 Metopolophium dirhodum Species 0.000 description 2
- 241000238745 Musca autumnalis Species 0.000 description 2
- 241001477928 Mythimna Species 0.000 description 2
- 241000721621 Myzus persicae Species 0.000 description 2
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 2
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 2
- 241000400685 Neoleucinodes elegantalis Species 0.000 description 2
- 241000359016 Nephotettix Species 0.000 description 2
- 241001671709 Nezara viridula Species 0.000 description 2
- 241001556089 Nilaparvata lugens Species 0.000 description 2
- 241000543819 Oestrus ovis Species 0.000 description 2
- 240000007817 Olea europaea Species 0.000 description 2
- 241001012098 Omiodes indicata Species 0.000 description 2
- 241001250072 Oryctes rhinoceros Species 0.000 description 2
- 241001275917 Oryzaephilus mercator Species 0.000 description 2
- 241000131101 Oryzaephilus surinamensis Species 0.000 description 2
- 241001147398 Ostrinia nubilalis Species 0.000 description 2
- 241001160353 Oulema melanopus Species 0.000 description 2
- 241000940835 Pales Species 0.000 description 2
- 206010033546 Pallor Diseases 0.000 description 2
- 241001204114 Pandemis cerasana Species 0.000 description 2
- 241000373498 Parapoynx stagnalis Species 0.000 description 2
- 241000669431 Parlatoria pergandii Species 0.000 description 2
- 241000721451 Pectinophora gossypiella Species 0.000 description 2
- 241001013804 Peridroma saucia Species 0.000 description 2
- 241001439019 Phthorimaea operculella Species 0.000 description 2
- 241001640279 Phyllophaga Species 0.000 description 2
- 241000907661 Pieris rapae Species 0.000 description 2
- 241000595629 Plodia interpunctella Species 0.000 description 2
- 241000500437 Plutella xylostella Species 0.000 description 2
- 241001662912 Poecilocapsus lineatus Species 0.000 description 2
- 241000254101 Popillia japonica Species 0.000 description 2
- 241000806442 Prays oleae Species 0.000 description 2
- 241000157279 Rhagoletis cerasi Species 0.000 description 2
- 241001136903 Rhagoletis pomonella Species 0.000 description 2
- 241000318997 Rhyzopertha dominica Species 0.000 description 2
- 241000722027 Schizaphis graminum Species 0.000 description 2
- 241000343234 Scirtothrips citri Species 0.000 description 2
- 241000365764 Scirtothrips dorsalis Species 0.000 description 2
- 241001244091 Scudderia furcata Species 0.000 description 2
- 241000563489 Sesamia inferens Species 0.000 description 2
- 241000068648 Sitodiplosis mosellana Species 0.000 description 2
- 241000254181 Sitophilus Species 0.000 description 2
- 241000254179 Sitophilus granarius Species 0.000 description 2
- 241000254152 Sitophilus oryzae Species 0.000 description 2
- 241000753145 Sitotroga cerealella Species 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 2
- 241000176086 Sogatella furcifera Species 0.000 description 2
- 235000002595 Solanum tuberosum Nutrition 0.000 description 2
- 244000061456 Solanum tuberosum Species 0.000 description 2
- 241000256247 Spodoptera exigua Species 0.000 description 2
- 229920002472 Starch Polymers 0.000 description 2
- 241001177161 Stegobium paniceum Species 0.000 description 2
- 241001494115 Stomoxys calcitrans Species 0.000 description 2
- 241000255628 Tabanidae Species 0.000 description 2
- 240000006909 Tilia x europaea Species 0.000 description 2
- 235000011941 Tilia x europaea Nutrition 0.000 description 2
- 241000333690 Tineola bisselliella Species 0.000 description 2
- 241000018135 Trialeurodes Species 0.000 description 2
- 241000018137 Trialeurodes vaporariorum Species 0.000 description 2
- 241000254113 Tribolium castaneum Species 0.000 description 2
- 241000254112 Tribolium confusum Species 0.000 description 2
- 241000255993 Trichoplusia ni Species 0.000 description 2
- 241000778089 Trogoderma variabile Species 0.000 description 2
- 241001630065 Unaspis yanonensis Species 0.000 description 2
- 240000008042 Zea mays Species 0.000 description 2
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 2
- 241001136529 Zeugodacus cucurbitae Species 0.000 description 2
- 241000213698 Zeuzera coffeae Species 0.000 description 2
- 241001198528 Zeuzera pyrina Species 0.000 description 2
- 239000000642 acaricide Substances 0.000 description 2
- 239000000956 alloy Substances 0.000 description 2
- 229910045601 alloy Inorganic materials 0.000 description 2
- 125000000129 anionic group Chemical group 0.000 description 2
- 230000003042 antagnostic effect Effects 0.000 description 2
- 239000003963 antioxidant agent Substances 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 2
- 125000002091 cationic group Chemical group 0.000 description 2
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 2
- MWKFXSUHUHTGQN-UHFFFAOYSA-N decan-1-ol Chemical compound CCCCCCCCCCO MWKFXSUHUHTGQN-UHFFFAOYSA-N 0.000 description 2
- SWXVUIWOUIDPGS-UHFFFAOYSA-N diacetone alcohol Chemical compound CC(=O)CC(C)(C)O SWXVUIWOUIDPGS-UHFFFAOYSA-N 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- 238000010790 dilution Methods 0.000 description 2
- 239000012895 dilution Substances 0.000 description 2
- 201000010099 disease Diseases 0.000 description 2
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 2
- 235000013601 eggs Nutrition 0.000 description 2
- 239000003995 emulsifying agent Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 230000035784 germination Effects 0.000 description 2
- CATSNJVOTSVZJV-UHFFFAOYSA-N heptan-2-one Chemical compound CCCCCC(C)=O CATSNJVOTSVZJV-UHFFFAOYSA-N 0.000 description 2
- 230000002363 herbicidal effect Effects 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 230000002401 inhibitory effect Effects 0.000 description 2
- 230000005764 inhibitory process Effects 0.000 description 2
- HJOVHMDZYOCNQW-UHFFFAOYSA-N isophorone Chemical compound CC1=CC(=O)CC(C)(C)C1 HJOVHMDZYOCNQW-UHFFFAOYSA-N 0.000 description 2
- 239000004571 lime Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 150000002790 naphthalenes Chemical class 0.000 description 2
- 235000021231 nutrient uptake Nutrition 0.000 description 2
- 239000006072 paste Substances 0.000 description 2
- 102000004169 proteins and genes Human genes 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 238000003892 spreading Methods 0.000 description 2
- 230000007480 spreading Effects 0.000 description 2
- 239000003381 stabilizer Substances 0.000 description 2
- 235000019698 starch Nutrition 0.000 description 2
- 239000008107 starch Substances 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 239000004548 suspo-emulsion Substances 0.000 description 2
- 239000011885 synergistic combination Substances 0.000 description 2
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 1
- LDMOEFOXLIZJOW-UHFFFAOYSA-N 1-dodecanesulfonic acid Chemical compound CCCCCCCCCCCCS(O)(=O)=O LDMOEFOXLIZJOW-UHFFFAOYSA-N 0.000 description 1
- TVFWYUWNQVRQRG-UHFFFAOYSA-N 2,3,4-tris(2-phenylethenyl)phenol Chemical compound C=1C=CC=CC=1C=CC1=C(C=CC=2C=CC=CC=2)C(O)=CC=C1C=CC1=CC=CC=C1 TVFWYUWNQVRQRG-UHFFFAOYSA-N 0.000 description 1
- PAWQVTBBRAZDMG-UHFFFAOYSA-N 2-(3-bromo-2-fluorophenyl)acetic acid Chemical compound OC(=O)CC1=CC=CC(Br)=C1F PAWQVTBBRAZDMG-UHFFFAOYSA-N 0.000 description 1
- HTXMJCHSFOPGME-UHFFFAOYSA-N 4,7-dimethoxy-1,3-benzodioxole Chemical compound COC1=CC=C(OC)C2=C1OCO2 HTXMJCHSFOPGME-UHFFFAOYSA-N 0.000 description 1
- 241001143308 Acanthoscelides Species 0.000 description 1
- 241000254032 Acrididae Species 0.000 description 1
- 235000009434 Actinidia chinensis Nutrition 0.000 description 1
- 244000298697 Actinidia deliciosa Species 0.000 description 1
- 235000009436 Actinidia deliciosa Nutrition 0.000 description 1
- 241000253994 Acyrthosiphon pisum Species 0.000 description 1
- 241001516607 Adelges Species 0.000 description 1
- 241001672675 Adoxophyes Species 0.000 description 1
- 241000256111 Aedes <genus> Species 0.000 description 1
- 241001136265 Agriotes Species 0.000 description 1
- 241000993143 Agromyza Species 0.000 description 1
- 241000218473 Agrotis Species 0.000 description 1
- 241000449794 Alabama argillacea Species 0.000 description 1
- 241001414848 Aleurodicus Species 0.000 description 1
- 241000107983 Aleyrodes proletella Species 0.000 description 1
- 244000291564 Allium cepa Species 0.000 description 1
- 235000002732 Allium cepa var. cepa Nutrition 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- 239000004254 Ammonium phosphate Substances 0.000 description 1
- 241001420348 Amorbia cuneana Species 0.000 description 1
- 241000839189 Amrasca Species 0.000 description 1
- 241001259789 Amyelois transitella Species 0.000 description 1
- 244000144725 Amygdalus communis Species 0.000 description 1
- 235000007119 Ananas comosus Nutrition 0.000 description 1
- 244000099147 Ananas comosus Species 0.000 description 1
- 241001136523 Anastrepha Species 0.000 description 1
- 241001465588 Anomis sabulifera Species 0.000 description 1
- 241000256186 Anopheles <genus> Species 0.000 description 1
- 241000254177 Anthonomus Species 0.000 description 1
- 241001523597 Aphidius Species 0.000 description 1
- 241001095118 Aphis pomi Species 0.000 description 1
- 241000273311 Aphis spiraecola Species 0.000 description 1
- 241001164244 Aphrophora Species 0.000 description 1
- 241001507652 Aphrophoridae Species 0.000 description 1
- 241000533363 Apion Species 0.000 description 1
- 241000256844 Apis mellifera Species 0.000 description 1
- 241001227591 Apogonia Species 0.000 description 1
- 241001423665 Archips fuscocupreana Species 0.000 description 1
- 241001423656 Archips rosana Species 0.000 description 1
- 241000384127 Argyrotaenia Species 0.000 description 1
- 244000003416 Asparagus officinalis Species 0.000 description 1
- 235000005340 Asparagus officinalis Nutrition 0.000 description 1
- 206010003497 Asphyxia Diseases 0.000 description 1
- 241001227614 Ataenius Species 0.000 description 1
- 241001227734 Ataenius strigatus Species 0.000 description 1
- 241001367053 Autographa gamma Species 0.000 description 1
- 241001109971 Bactericera cockerelli Species 0.000 description 1
- 235000021537 Beetroot Nutrition 0.000 description 1
- 241000254123 Bemisia Species 0.000 description 1
- 241001302798 Bemisia argentifolii Species 0.000 description 1
- 241001350395 Bonagota Species 0.000 description 1
- 241001622619 Borbo cinnara Species 0.000 description 1
- 241000318995 Bostrichidae Species 0.000 description 1
- 241000260909 Bothynoderes Species 0.000 description 1
- 241001093996 Brachycorynella asparagi Species 0.000 description 1
- 235000011331 Brassica Nutrition 0.000 description 1
- 241000219198 Brassica Species 0.000 description 1
- 235000006008 Brassica napus var napus Nutrition 0.000 description 1
- 235000017647 Brassica oleracea var italica Nutrition 0.000 description 1
- 241001325378 Bruchus Species 0.000 description 1
- 241001414201 Bruchus pisorum Species 0.000 description 1
- 241001517925 Bucculatrix Species 0.000 description 1
- 241000906761 Calocoris Species 0.000 description 1
- 241001525574 Caloptilia Species 0.000 description 1
- 235000002566 Capsicum Nutrition 0.000 description 1
- 235000002568 Capsicum frutescens Nutrition 0.000 description 1
- 241000290397 Carpophilus Species 0.000 description 1
- 241001183369 Carpophilus hemipterus Species 0.000 description 1
- 241000411507 Cassida vittata Species 0.000 description 1
- 241000255580 Ceratitis <genus> Species 0.000 description 1
- 241000255579 Ceratitis capitata Species 0.000 description 1
- 241001450758 Ceroplastes Species 0.000 description 1
- 241001124145 Cerotoma Species 0.000 description 1
- 241001156313 Ceutorhynchus Species 0.000 description 1
- 241001180296 Ceutorhynchus assimilis Species 0.000 description 1
- 241000259804 Ceutorhynchus inaffectatus Species 0.000 description 1
- 241001399348 Ceutorhynchus napi Species 0.000 description 1
- 241000902406 Chaetocnema Species 0.000 description 1
- 241000426499 Chilo Species 0.000 description 1
- 241000426497 Chilo suppressalis Species 0.000 description 1
- 241000668556 Chionaspis Species 0.000 description 1
- 241001364932 Chrysodeixis Species 0.000 description 1
- 241000668561 Chrysomphalus Species 0.000 description 1
- 241001124179 Chrysops Species 0.000 description 1
- 241000034870 Chrysoteuchia culmella Species 0.000 description 1
- 244000241235 Citrullus lanatus Species 0.000 description 1
- 235000012828 Citrullus lanatus var citroides Nutrition 0.000 description 1
- 235000005979 Citrus limon Nutrition 0.000 description 1
- 244000131522 Citrus pyriformis Species 0.000 description 1
- 240000000560 Citrus x paradisi Species 0.000 description 1
- 241000098277 Cnaphalocrocis Species 0.000 description 1
- 241001478240 Coccus Species 0.000 description 1
- 241000202814 Cochliomyia hominivorax Species 0.000 description 1
- 240000007154 Coffea arabica Species 0.000 description 1
- 241000143940 Colias Species 0.000 description 1
- 241001663470 Contarinia <gall midge> Species 0.000 description 1
- 241000084473 Contarinia nasturtii Species 0.000 description 1
- 240000000491 Corchorus aestuans Species 0.000 description 1
- 235000011777 Corchorus aestuans Nutrition 0.000 description 1
- 235000010862 Corchorus capsularis Nutrition 0.000 description 1
- 241001579853 Cossus Species 0.000 description 1
- 241001579839 Cossus cossus Species 0.000 description 1
- 241000867174 Cotinis nitida Species 0.000 description 1
- 241000065610 Cotinus Species 0.000 description 1
- 241001340508 Crambus Species 0.000 description 1
- 241000456565 Cryptolestes pusillus Species 0.000 description 1
- 241000242268 Ctenicera Species 0.000 description 1
- 241000219112 Cucumis Species 0.000 description 1
- 235000015510 Cucumis melo subsp melo Nutrition 0.000 description 1
- 235000009849 Cucumis sativus Nutrition 0.000 description 1
- 240000008067 Cucumis sativus Species 0.000 description 1
- 241000256054 Culex <genus> Species 0.000 description 1
- 241000721021 Curculio Species 0.000 description 1
- 241001156075 Cyclocephala Species 0.000 description 1
- 241001634817 Cydia Species 0.000 description 1
- 241001580979 Cydia nigricana Species 0.000 description 1
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical class OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 1
- 241000592374 Daktulosphaira vitifoliae Species 0.000 description 1
- 241001406277 Darna Species 0.000 description 1
- 235000002767 Daucus carota Nutrition 0.000 description 1
- 244000000626 Daucus carota Species 0.000 description 1
- 241001414890 Delia Species 0.000 description 1
- 241000489975 Diabrotica Species 0.000 description 1
- 241000832201 Diaphania Species 0.000 description 1
- 241000586568 Diaspidiotus perniciosus Species 0.000 description 1
- 241000122106 Diatraea saccharalis Species 0.000 description 1
- 241000497893 Dichagyris Species 0.000 description 1
- 241001549096 Dichelops furcatus Species 0.000 description 1
- 241000255582 Drosophilidae Species 0.000 description 1
- 241001572697 Earias vittella Species 0.000 description 1
- UPEZCKBFRMILAV-JNEQICEOSA-N Ecdysone Natural products O=C1[C@H]2[C@@](C)([C@@H]3C([C@@]4(O)[C@@](C)([C@H]([C@H]([C@@H](O)CCC(O)(C)C)C)CC4)CC3)=C1)C[C@H](O)[C@H](O)C2 UPEZCKBFRMILAV-JNEQICEOSA-N 0.000 description 1
- 241000051720 Edessa meditabunda Species 0.000 description 1
- 235000001950 Elaeis guineensis Nutrition 0.000 description 1
- 244000127993 Elaeis melanococca Species 0.000 description 1
- 241000995023 Empoasca Species 0.000 description 1
- 241000086608 Empoasca vitis Species 0.000 description 1
- 241000630736 Ephestia Species 0.000 description 1
- 241001555556 Ephestia elutella Species 0.000 description 1
- 241000098279 Epinotia aporema Species 0.000 description 1
- 241000918644 Epiphyas postvittana Species 0.000 description 1
- 241001251922 Erionota thrax Species 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- 241000060469 Eupoecilia ambiguella Species 0.000 description 1
- 241000098295 Euschistus heros Species 0.000 description 1
- 239000001653 FEMA 3120 Substances 0.000 description 1
- 241000371383 Fannia Species 0.000 description 1
- 241000953886 Fannia canicularis Species 0.000 description 1
- 241000233488 Feltia Species 0.000 description 1
- 241001284615 Frangula californica Species 0.000 description 1
- 241000654849 Frankliniella schultzei Species 0.000 description 1
- 241000508745 Frankliniella williamsi Species 0.000 description 1
- 235000010469 Glycine max Nutrition 0.000 description 1
- 241000486458 Gortyna Species 0.000 description 1
- 241000219146 Gossypium Species 0.000 description 1
- 241000578422 Graphosoma lineatum Species 0.000 description 1
- 241000256257 Heliothis Species 0.000 description 1
- 241000256244 Heliothis virescens Species 0.000 description 1
- 241000339323 Heliothrips Species 0.000 description 1
- 241000345510 Helopeltis antonii Species 0.000 description 1
- 241000877151 Helopeltis theivora Species 0.000 description 1
- 240000005979 Hordeum vulgare Species 0.000 description 1
- 235000007340 Hordeum vulgare Nutrition 0.000 description 1
- 241001153229 Hylobius Species 0.000 description 1
- 241000370523 Hypena scabra Species 0.000 description 1
- 241001508558 Hypera Species 0.000 description 1
- 241000577496 Hypothenemus hampei Species 0.000 description 1
- 241001580023 Indarbela Species 0.000 description 1
- 235000010702 Insulata Nutrition 0.000 description 1
- 244000165077 Insulata Species 0.000 description 1
- 241001201644 Iridopsis Species 0.000 description 1
- 241000758791 Juglandaceae Species 0.000 description 1
- 239000005909 Kieselgur Substances 0.000 description 1
- 235000003228 Lactuca sativa Nutrition 0.000 description 1
- 240000008415 Lactuca sativa Species 0.000 description 1
- 241000255679 Lasiocampidae Species 0.000 description 1
- 241001177160 Lasioderma Species 0.000 description 1
- 241001177117 Lasioderma serricorne Species 0.000 description 1
- 241000255777 Lepidoptera Species 0.000 description 1
- 241000669027 Lepidosaphes Species 0.000 description 1
- 241000661345 Leptocorisa Species 0.000 description 1
- 241000661348 Leptocorisa acuta Species 0.000 description 1
- 241001578972 Leucoptera malifoliella Species 0.000 description 1
- 239000004117 Lignosulphonate Substances 0.000 description 1
- 235000019738 Limestone Nutrition 0.000 description 1
- 235000004431 Linum usitatissimum Nutrition 0.000 description 1
- 240000006240 Linum usitatissimum Species 0.000 description 1
- 241000594036 Liriomyza Species 0.000 description 1
- 241000685571 Liriomyza brassicae Species 0.000 description 1
- 241000254022 Locusta migratoria Species 0.000 description 1
- 235000007688 Lycopersicon esculentum Nutrition 0.000 description 1
- 241001177134 Lyctus Species 0.000 description 1
- 241001414823 Lygus hesperus Species 0.000 description 1
- 241000501345 Lygus lineolaris Species 0.000 description 1
- 241001581015 Lyonetia clerkella Species 0.000 description 1
- 241000766395 Maconellicoccus hirsutus Species 0.000 description 1
- 241000721714 Macrosiphum euphorbiae Species 0.000 description 1
- 241001164204 Mahanarva Species 0.000 description 1
- 241000030790 Mahasena Species 0.000 description 1
- 241000255676 Malacosoma Species 0.000 description 1
- 241000220225 Malus Species 0.000 description 1
- 241001331901 Mediterranea Species 0.000 description 1
- 241000902265 Megascelis Species 0.000 description 1
- 241001415013 Melanoplus Species 0.000 description 1
- 241001394950 Melanotus communis (Gyllenhal, 1817) Species 0.000 description 1
- 241000766511 Meligethes Species 0.000 description 1
- 241000254071 Melolontha Species 0.000 description 1
- 241000254099 Melolontha melolontha Species 0.000 description 1
- 241000254043 Melolonthinae Species 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 241000406525 Microcentrum Species 0.000 description 1
- 241000406524 Microcentrum rhombifolium Species 0.000 description 1
- 241001219549 Mictis Species 0.000 description 1
- 241000257229 Musca <genus> Species 0.000 description 1
- 241000257226 Muscidae Species 0.000 description 1
- FXHOOIRPVKKKFG-UHFFFAOYSA-N N,N-Dimethylacetamide Chemical compound CN(C)C(C)=O FXHOOIRPVKKKFG-UHFFFAOYSA-N 0.000 description 1
- 241000244206 Nematoda Species 0.000 description 1
- 241001666408 Neurocolpus longirostris Species 0.000 description 1
- 235000002637 Nicotiana tabacum Nutrition 0.000 description 1
- 244000061176 Nicotiana tabacum Species 0.000 description 1
- 241001105104 Oberea Species 0.000 description 1
- 241001352334 Oberea linearis Species 0.000 description 1
- 241001491877 Operophtera brumata Species 0.000 description 1
- 241000238814 Orthoptera Species 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 241000975417 Oscinella frit Species 0.000 description 1
- 241001157807 Oscinella sp. HMR-1993 Species 0.000 description 1
- 241000346285 Ostrinia furnacalis Species 0.000 description 1
- 241000131737 Otiorhynchus Species 0.000 description 1
- 241001570894 Oulema oryzae Species 0.000 description 1
- 241001424098 Oxydia vesulia Species 0.000 description 1
- 241001441425 Pandemis heparana Species 0.000 description 1
- 241001204961 Pantomorus Species 0.000 description 1
- 241000050720 Papilio demodocus Species 0.000 description 1
- 241000497111 Paralobesia viteana Species 0.000 description 1
- 235000010678 Paulownia tomentosa Nutrition 0.000 description 1
- 240000002834 Paulownia tomentosa Species 0.000 description 1
- 235000019483 Peanut oil Nutrition 0.000 description 1
- 241000562493 Pegomya Species 0.000 description 1
- 241000408999 Pelopidas thrax Species 0.000 description 1
- 241000320508 Pentatomidae Species 0.000 description 1
- 241000256682 Peregrinus maidis Species 0.000 description 1
- 241001013845 Peridroma Species 0.000 description 1
- 235000010627 Phaseolus vulgaris Nutrition 0.000 description 1
- 244000046052 Phaseolus vulgaris Species 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 241001414822 Philaenus Species 0.000 description 1
- 241000720470 Phyllonorycter Species 0.000 description 1
- 241001525802 Phyllonorycter pomonella Species 0.000 description 1
- 241000275067 Phyllotreta Species 0.000 description 1
- 241000941941 Physokermes Species 0.000 description 1
- 241000316891 Physokermes jezoensis Species 0.000 description 1
- 241000940371 Piezodorus Species 0.000 description 1
- 241000758706 Piperaceae Species 0.000 description 1
- 241000219843 Pisum Species 0.000 description 1
- 235000010582 Pisum sativum Nutrition 0.000 description 1
- 240000004713 Pisum sativum Species 0.000 description 1
- 229920001213 Polysorbate 20 Polymers 0.000 description 1
- 241001201614 Prays Species 0.000 description 1
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 1
- 241001459657 Prostephanus Species 0.000 description 1
- 241001459653 Prostephanus truncatus Species 0.000 description 1
- 241001290151 Prunus avium subsp. avium Species 0.000 description 1
- 235000005805 Prunus cerasus Nutrition 0.000 description 1
- 240000005809 Prunus persica Species 0.000 description 1
- 235000006040 Prunus persica var persica Nutrition 0.000 description 1
- 241001274606 Pseudacysta perseae Species 0.000 description 1
- 241000722234 Pseudococcus Species 0.000 description 1
- 241001105508 Pterophylla Species 0.000 description 1
- 241000421343 Pygovepres vaccinicola Species 0.000 description 1
- 241000220324 Pyrus Species 0.000 description 1
- 241001456339 Rachiplusia nu Species 0.000 description 1
- 235000019484 Rapeseed oil Nutrition 0.000 description 1
- 108020004511 Recombinant DNA Proteins 0.000 description 1
- 241000125167 Rhopalosiphum padi Species 0.000 description 1
- 241000344244 Rhynchophorus Species 0.000 description 1
- 235000004443 Ricinus communis Nutrition 0.000 description 1
- 241000220317 Rosa Species 0.000 description 1
- 241000109329 Rosa xanthina Species 0.000 description 1
- 235000004789 Rosa xanthina Nutrition 0.000 description 1
- 240000000111 Saccharum officinarum Species 0.000 description 1
- 235000007201 Saccharum officinarum Nutrition 0.000 description 1
- 241001450655 Saissetia Species 0.000 description 1
- 241000316887 Saissetia oleae Species 0.000 description 1
- 241000726725 Scaptocoris castanea Species 0.000 description 1
- 241001249129 Scirpophaga incertulas Species 0.000 description 1
- 241000098281 Scirpophaga innotata Species 0.000 description 1
- 241000365762 Scirtothrips Species 0.000 description 1
- 241000055238 Scolytus Species 0.000 description 1
- 241000931987 Sesamia Species 0.000 description 1
- 241000661452 Sesamia nonagrioides Species 0.000 description 1
- 235000003434 Sesamum indicum Nutrition 0.000 description 1
- 244000040738 Sesamum orientale Species 0.000 description 1
- 235000004433 Simmondsia californica Nutrition 0.000 description 1
- UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 description 1
- 240000003768 Solanum lycopersicum Species 0.000 description 1
- 240000003829 Sorghum propinquum Species 0.000 description 1
- 235000011684 Sorghum saccharatum Nutrition 0.000 description 1
- 241000277984 Sparganothis pilleriana Species 0.000 description 1
- 235000009337 Spinacia oleracea Nutrition 0.000 description 1
- 244000300264 Spinacia oleracea Species 0.000 description 1
- 241001521235 Spodoptera eridania Species 0.000 description 1
- 241000256251 Spodoptera frugiperda Species 0.000 description 1
- 241000098292 Striacosta albicosta Species 0.000 description 1
- 241001470116 Strymon megarus Species 0.000 description 1
- 241001528589 Synanthedon Species 0.000 description 1
- 241000255626 Tabanus <genus> Species 0.000 description 1
- 241000189578 Taeniothrips Species 0.000 description 1
- 244000269722 Thea sinensis Species 0.000 description 1
- 241000530360 Therioaphis Species 0.000 description 1
- 241000131345 Tipula <genus> Species 0.000 description 1
- 241000131339 Tipulidae Species 0.000 description 1
- 241000255901 Tortricidae Species 0.000 description 1
- 241001651212 Toumeyella Species 0.000 description 1
- 241000271862 Toxoptera Species 0.000 description 1
- 241001414833 Triatoma Species 0.000 description 1
- 241001249488 Triatoma sanguisuga Species 0.000 description 1
- 241001210412 Triatominae Species 0.000 description 1
- 241000254086 Tribolium <beetle> Species 0.000 description 1
- 241000219793 Trifolium Species 0.000 description 1
- 235000021307 Triticum Nutrition 0.000 description 1
- 244000098338 Triticum aestivum Species 0.000 description 1
- 241000669245 Unaspis Species 0.000 description 1
- 241000447718 Valanga Species 0.000 description 1
- 241000895647 Varroa Species 0.000 description 1
- 241001274788 Viteus vitifoliae Species 0.000 description 1
- 235000014787 Vitis vinifera Nutrition 0.000 description 1
- 240000006365 Vitis vinifera Species 0.000 description 1
- 241001466337 Yponomeuta Species 0.000 description 1
- 235000004552 Yucca aloifolia Nutrition 0.000 description 1
- 235000012044 Yucca brevifolia Nutrition 0.000 description 1
- 235000017049 Yucca glauca Nutrition 0.000 description 1
- 240000005780 Yucca gloriosa Species 0.000 description 1
- 241001035865 Zabrus Species 0.000 description 1
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 1
- 235000016383 Zea mays subsp huehuetenangensis Nutrition 0.000 description 1
- 229910021536 Zeolite Inorganic materials 0.000 description 1
- 241001164238 Zulia Species 0.000 description 1
- FJJCIZWZNKZHII-UHFFFAOYSA-N [4,6-bis(cyanoamino)-1,3,5-triazin-2-yl]cyanamide Chemical compound N#CNC1=NC(NC#N)=NC(NC#N)=N1 FJJCIZWZNKZHII-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000000895 acaricidal effect Effects 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 239000000556 agonist Substances 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 150000004996 alkyl benzenes Chemical class 0.000 description 1
- 235000020224 almond Nutrition 0.000 description 1
- UPEZCKBFRMILAV-UHFFFAOYSA-N alpha-Ecdysone Natural products C1C(O)C(O)CC2(C)C(CCC3(C(C(C(O)CCC(C)(C)O)C)CCC33O)C)C3=CC(=O)C21 UPEZCKBFRMILAV-UHFFFAOYSA-N 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 229910000148 ammonium phosphate Inorganic materials 0.000 description 1
- 235000019289 ammonium phosphates Nutrition 0.000 description 1
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 1
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 1
- 235000011130 ammonium sulphate Nutrition 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 230000003254 anti-foaming effect Effects 0.000 description 1
- 230000000433 anti-nutritional effect Effects 0.000 description 1
- 239000002518 antifoaming agent Substances 0.000 description 1
- 239000007798 antifreeze agent Substances 0.000 description 1
- 235000021016 apples Nutrition 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 239000000440 bentonite Substances 0.000 description 1
- 229910000278 bentonite Inorganic materials 0.000 description 1
- 235000012216 bentonite Nutrition 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- 235000021028 berry Nutrition 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 239000003139 biocide Substances 0.000 description 1
- 230000004071 biological effect Effects 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- 229920001400 block copolymer Polymers 0.000 description 1
- 239000000872 buffer Substances 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 235000010216 calcium carbonate Nutrition 0.000 description 1
- 235000011132 calcium sulphate Nutrition 0.000 description 1
- 239000002775 capsule Substances 0.000 description 1
- 235000013877 carbamide Nutrition 0.000 description 1
- 235000014633 carbohydrates Nutrition 0.000 description 1
- 150000001720 carbohydrates Chemical class 0.000 description 1
- 239000004359 castor oil Substances 0.000 description 1
- 235000019438 castor oil Nutrition 0.000 description 1
- 239000003093 cationic surfactant Substances 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 235000019693 cherries Nutrition 0.000 description 1
- 235000020971 citrus fruits Nutrition 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 229910052570 clay Inorganic materials 0.000 description 1
- 239000007931 coated granule Substances 0.000 description 1
- 235000019864 coconut oil Nutrition 0.000 description 1
- 239000003240 coconut oil Substances 0.000 description 1
- 235000016213 coffee Nutrition 0.000 description 1
- 235000013353 coffee beverage Nutrition 0.000 description 1
- 230000005757 colony formation Effects 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 235000005822 corn Nutrition 0.000 description 1
- 235000012343 cottonseed oil Nutrition 0.000 description 1
- 238000012272 crop production Methods 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- HPXRVTGHNJAIIH-UHFFFAOYSA-N cyclohexanol Chemical compound OC1CCCCC1 HPXRVTGHNJAIIH-UHFFFAOYSA-N 0.000 description 1
- 230000000593 degrading effect Effects 0.000 description 1
- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 description 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- 239000010459 dolomite Substances 0.000 description 1
- 229910000514 dolomite Inorganic materials 0.000 description 1
- UPEZCKBFRMILAV-JMZLNJERSA-N ecdysone Chemical compound C1[C@@H](O)[C@@H](O)C[C@]2(C)[C@@H](CC[C@@]3([C@@H]([C@@H]([C@H](O)CCC(C)(C)O)C)CC[C@]33O)C)C3=CC(=O)[C@@H]21 UPEZCKBFRMILAV-JMZLNJERSA-N 0.000 description 1
- 230000032669 eclosion Effects 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 150000002191 fatty alcohols Chemical class 0.000 description 1
- 230000003031 feeding effect Effects 0.000 description 1
- 235000004426 flaxseed Nutrition 0.000 description 1
- 235000013312 flour Nutrition 0.000 description 1
- 239000000499 gel Substances 0.000 description 1
- 238000010353 genetic engineering Methods 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- 229920000578 graft copolymer Polymers 0.000 description 1
- 208000037824 growth disorder Diseases 0.000 description 1
- 230000010243 gut motility Effects 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 230000007407 health benefit Effects 0.000 description 1
- RNQBLUNNAYFBIW-NPULLEENSA-M hexadecyl(trimethyl)azanium (2S)-2-(6-methoxynaphthalen-2-yl)propanoate Chemical compound COc1ccc2cc(ccc2c1)[C@H](C)C([O-])=O.CCCCCCCCCCCCCCCC[N+](C)(C)C RNQBLUNNAYFBIW-NPULLEENSA-M 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000005414 inactive ingredient Substances 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 239000002563 ionic surfactant Substances 0.000 description 1
- 229930014550 juvenile hormone Natural products 0.000 description 1
- 150000003633 juvenile hormone derivatives Chemical class 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 230000002147 killing effect Effects 0.000 description 1
- 235000019357 lignosulphonate Nutrition 0.000 description 1
- 239000006028 limestone Substances 0.000 description 1
- 244000144972 livestock Species 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- 235000012245 magnesium oxide Nutrition 0.000 description 1
- 229910052943 magnesium sulfate Inorganic materials 0.000 description 1
- 235000019341 magnesium sulphate Nutrition 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- 235000009973 maize Nutrition 0.000 description 1
- 230000013011 mating Effects 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
- 239000004530 micro-emulsion Substances 0.000 description 1
- 239000003094 microcapsule Substances 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- 239000010446 mirabilite Substances 0.000 description 1
- 238000002703 mutagenesis Methods 0.000 description 1
- 231100000350 mutagenesis Toxicity 0.000 description 1
- PSZYNBSKGUBXEH-UHFFFAOYSA-N naphthalene-1-sulfonic acid Chemical compound C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 PSZYNBSKGUBXEH-UHFFFAOYSA-N 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 235000016709 nutrition Nutrition 0.000 description 1
- 235000014571 nuts Nutrition 0.000 description 1
- 235000020232 peanut Nutrition 0.000 description 1
- 235000021017 pears Nutrition 0.000 description 1
- 230000000243 photosynthetic effect Effects 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 235000021018 plums Nutrition 0.000 description 1
- 229920001515 polyalkylene glycol Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000000256 polyoxyethylene sorbitan monolaurate Substances 0.000 description 1
- 235000010486 polyoxyethylene sorbitan monolaurate Nutrition 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 229920000136 polysorbate Polymers 0.000 description 1
- 229950008882 polysorbate Drugs 0.000 description 1
- 235000012015 potatoes Nutrition 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 230000035755 proliferation Effects 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 230000001568 sexual effect Effects 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 235000017550 sodium carbonate Nutrition 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 239000004550 soluble concentrate Substances 0.000 description 1
- 238000009331 sowing Methods 0.000 description 1
- 235000012424 soybean oil Nutrition 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 230000005082 stem growth Effects 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 150000008163 sugars Chemical class 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 235000013616 tea Nutrition 0.000 description 1
- 230000002110 toxicologic effect Effects 0.000 description 1
- 231100000027 toxicology Toxicity 0.000 description 1
- 150000003672 ureas Chemical class 0.000 description 1
- 230000017260 vegetative to reproductive phase transition of meristem Effects 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 239000011782 vitamin Substances 0.000 description 1
- 235000013343 vitamin Nutrition 0.000 description 1
- 229940088594 vitamin Drugs 0.000 description 1
- 229930003231 vitamin Natural products 0.000 description 1
- 235000020234 walnut Nutrition 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/44—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a nitrogen atom attached to the same carbon skeleton by a single or double bond, this nitrogen atom not being a member of a derivative or of a thio analogue of a carboxylic group, e.g. amino-carboxylic acids
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/36—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids
- A01N37/38—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids having at least one oxygen or sulfur atom attached to an aromatic ring system
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N53/00—Biocides, pest repellants or attractants, or plant growth regulators containing cyclopropane carboxylic acids or derivatives thereof
Definitions
- the present invention relates to mixture combinations of active compounds comprising, Tau-fluvalinate and at least one further crop protection chemical, and to methods of controlling pests comprising applying said combinations.
- mixtures comprising Tau fluvalinate and at least one further crop protection chemical are synergistically effective, being applied simultaneously, that is jointly or separately, or in succession, allows better control of insect pests than is possible with the individual compounds alone, providing synergistic results and solving at least one of the challenges in the prior art by reducing the dosage rate or enhancing the spectrum of activity or combining knock-down activity with prolonged control or facilitating resistance management.
- the present invention relates to a mixture combination comprising, as active compounds: i) Tau-fluvaiinate; and ii) at least one crop protection chemical compound II selected from the groups (a) to (x):
- nAChR Nicotinic acetylcholine receptor
- a Nicotinic acetylcholine receptor channel blocker selected from a group comprising Thiocyclam
- a Chordotonal organ modulator with undefined target site selected from a group comprising Flonicamid
- an Inhibitor of mitochondrial ATP synthase selected from a group comprising Azocyclotin, Diafenthiuron, Fenbutatin oxide and Tetradifon
- a pyrimidine derivative selected from a group comprising Benzpyrimoxan
- a Mitochondrial complex electron transport inhibitor selected from a group comprising Bifenazate, Fenpyroximate, Tolfenpyrad and pyromite,
- a triazine insect growth regulator selected from a group comprising Cyromazine
- GluCl Glutamate-gated chloride channel
- the present invention further provides a mixture combination comprising a mixture of Tau- fluvalinate and one or more active compounds II, as mentioned above, comprising an agriculturally acceptable carrier, and further comprising at least one surfactant, solid diluent, liquid diluent, or a combination thereof.
- the present invention further provides a method for protecting plants from attack or infestation by insects comprising contacting the plant, or the soil or water in which the plant is growing, with an effective amount of the mixture of Tau-fluvalinate and one or more active compounds II, as mentioned above or the composition thereof, so as to thereby protect plants from attack or infestation by insects.
- pests is used to include animal pests, as well as harmful fungi.
- agriculturally acceptable carrier means carrier which is known and accepted in the art for the formation of compositions for agricultural or horticultural use.
- the term "agriculturally acceptable inert additives” is defined as any substance that itself is not an active ingredient but is added to the composition such as thickening agent, sticking agents, surfactants, anti-oxidation agent, anti-foaming agents and thickeners.
- the term “tank mix” means that two or more chemical pesticides or compositions are mixed in the spray tank at the time of spray application.
- mixture or “combination” refers, but is not limited to, a combination in any physical form, e.g., blend, solution, suspension, dispersion, emulsion, alloy, or the like.
- enhancing roots system means the roots system is improved qualitatively or quantitatively in a plant to which the mixture or composition described herein has been applied as compared to the roots systems in a control plant grown under the same conditions except to which the mixture or composition described herein has not been applied.
- Enhanced roots systems include but are not limited to improved visual appearance and composition of the roots system (i.e., improved color, density, and uniformity), increased root growth, a more developed root system, stronger and healthier roots, improved plant stand, and increased roots system weight.
- plant growth regulation or “regulating plant growth” includes restricting vertical stem growth, promoting root growth, stunting, increasing stem diameter and stem-wall thickness, and the like.
- surfactant means an agriculturally acceptable material which imparts emulsifiability, stability, spreading, wetting, dispersibility or other surface-modifying properties.
- suitable surfactants include non-ionic, anionic, cationic and ampholytic surfactants.
- the present invention relates to a mixture combination comprising, as active compounds: i) Tau-fluvalinate; and ii) at least one crop protection chemical, compound II selected from the groups (a) to (x):
- an Inhibitor of mitochondrial ATP synthase selected from a group comprising Azocyclotin, Diafenthiuron, Fenbutatin oxide and Tetradifon,
- a triazine insect growth regulator selected from a group comprising Cyromazine
- a broad- spectrum insect growth regulator selected from a group comprising Pyriproxyfen,
- GluCl Glutamate-gated chloride channel
- an Inhibitor of acetyl CoA carboxylase selected from a group comprising Spiropidion and Spirotetramat
- a Microbial disruptor of insect midgut membranes selected from a group comprising Bacillus thuringiensis toxin
- a fungicide selected from a group comprising Pydiflumetofen, Fluxapyroxad, Difenoconazole, Tebuconazole, Fludioxonil, Azoxystrobin and Mancozeb, and
- the crop protection chemical, compound II is at least one of Acetamiprid, Spinetoram, Spinosad and Sulfoxaflor.
- the crop protection chemical, compound II is Acetamiprid.
- the crop protection chemical, compound II is Spinetoram.
- the crop protection chemical, compound II is Spinosad.
- the crop protection chemical, compound II is Sulfoxaflor.
- the crop protection chemical, compound II is Thiocyclam.
- the crop protection chemical, compound II is at least one of Azocyclotin, Diafenthiuron, Fenbutatin oxide and Tetradifon.
- the crop protection chemical, compound II is Azocyclotin.
- the crop protection chemical, compound II is Diafenthiuron.
- the crop protection chemical, compound II is Fenbutatin oxide.
- the crop protection chemical, compound II is Tetradifon.
- the crop protection chemical, compound II is Benzpyrimoxan.
- the crop protection chemical, compound II is Broflanilide.
- the crop protection chemical, compound II is at least one of chlorantraniliprole, Cyclaniliprole, cyantraniliprole and Flubendiamide.
- the crop protection chemical, compound II is chlorantraniliprole.
- the crop protection chemical, compound II is Cyclaniliprole.
- the crop protection chemical, compound II is cyantraniliprole.
- the crop protection chemical, compound II is Flubendiamide.
- the crop protection chemical, compound II is Cyromazine.
- the crop protection chemical, compound II is Pyriproxyfen.
- the crop protection chemical, compound II is Emamectin.
- the crop protection chemical, compound II is Flupyrimin.
- the crop protection chemical, compound II is Novaluron.
- the crop protection chemical, compound II is Oxazosulfyl.
- the crop protection chemical, compound II is Pyridalyl.
- the crop protection chemical, compound II is Bacillus thuringiensis toxin.
- the crop protection chemical, compound II is Triflumezopyrim
- the weight ratio between Tau-fluvalinate and at least one crop protection chemical, compound II, as defined above, varies depending upon various conditions such as the type of the formulation, weather conditions, the type of crop and the type of pests.
- the weight ratio of Tau-fluvalinate to the crop protection chemical, compound II is from about 1:100 to 100:1. In another embodiment, the weight ratio of the Tau- fluvalinate to the crop protection chemical, compound II is from about 1:50 to 50:1. In another embodiment, the weight ratio of the Tau-fluvalinate to the crop protection chemical, compound II is from about 1 :25 to 25: 1. In yet another embodiment, the weight ratio of the of the Tau-fluvalinate to the crop protection chemical, compound II is from about 1:10 to 10:1. In a further embodiment, the weight ratio of the Tau-fluvalinate to the crop protection chemical, compound II is from about 1:5 to 5:1.
- the weight ratio of the Tau-fluvalinate to the crop protection chemical, compound II may be any in-between range selected from the above indicated ratios.
- the weight ratio of Tau-fluvalinate to lambda-cyhalothrin is from about 1:100 to 100:1. In another embodiment, the weight ratio of Tau-fluvalinate to lambda- cyhalothrin is from about 1 :50 to 50: 1. In another embodiment, the weight ratio of Tau-fluvalinate to lambda-cyhalothrin is from about 1:2 to 2:1.
- the weight ratio of Tau-fluvalinate to the Nicotinic acetylcholine receptor (nAChR) competitive modulator is from about 1:100 to 100:1. In another embodiment, the weight ratio of Tau-fluvalinate to the Nicotinic acetylcholine receptor (nAChR) competitive modulator is from about 1:50 to 50:1.
- the weight ratio of Tau-fluvalinate to Acetamiprid is from about 1 : 100 to 100: 1. In another embodiment, the weight ratio of Tau-fluvalinate to Acetamiprid is from about 1:50 to 50:1. In another embodiment, the weight ratio of Tau-fluvalinate to Acetamiprid is from about 1:1 to 1:2.
- the weight ratio of Tau-fluvalinate to Spinetoram is from about 1 : 100 to 100: 1. In another embodiment, the weight ratio of Tau-fluvalinate to Spinetoram is from about 1:50 to 50:1. In another embodiment, the weight ratio of Tau-fluvalinate to Spinetoram is 1:1.
- the weight ratio of Tau-fluvalinate to Spinosad is from about 1:100 to 100:1. In another embodiment, the weight ratio of Tau-fluvalinate to Spinosad is from about 1 :50 to 50: 1. In another embodiment, the weight ratio of Tau-fluvalinate to Spinosad is 1:1.
- the weight ratio of Tau-fluvalinate to Sulfoxaflor is from about 1:100 to 100:1. In another embodiment, the weight ratio of Tau-fluvalinate to Sulfoxaflor is from about 1:50 to 50:1. In another embodiment, the weight ratio of Tau-fluvalinate to Sulfoxaflor is from about 1:25 to 25:1. In yet another embodiment, the weight ratio of the Tau-fluvalinate to Sulfoxaflor is from about 1:10 to 10:1. In an embodiment, the weight ratio of the Tau-fluvalinate to Sulfoxaflor is from about 1:5 to 5:1. In a specific embodiment, the weight ratio of Tau- fluvalinate to Sulfoxaflor is about 1:1.
- the weight ratio of Tau- fluvalinate to Sulfoxaflor is about 2:1. In a specific embodiment, the weight ratio of Tau- fluvalinate to Sulfoxaflor is about 1:5. The weight ratio of Tau-fluvalinate to Sulfoxaflor may be any in-between range selected from the above indicated ratios.
- the weight ratio of Tau-fluvalinate to Thiocyclam is from about 1:100 to 100:1. In another embodiment, the weight ratio of Tau-fluvalinate to Thiocyclam is from about 1:50 to 50:1. In another embodiment, the weight ratio of Tau-fluvalinate to Thiocyclam is from about 1:25 to 25:1. In yet another embodiment, the weight ratio of the Tau-fluvalinate to Thiocyclam is from about 1:10 to 10:1. In an embodiment, the weight ratio of the Tau-fluvalinate to Thiocyclam is from about 1:5 to 5:1. In a specific embodiment, the weight ratio of Tau- fluvalinate to Thiocyclam is about 1:1. The weight ratio of Tau-fluvalinate to Thiocyclam may be any in-between range selected from the above indicated ratios.
- the weight ratio of Tau-fluvalinate to a Chordotonal organ TRPV channel modulator is from about 1:100 to 100:1. In another embodiment, the weight ratio of Tau- fluvalinate to a Chordotonal organ TRPV channel modulator is from about 1:50 to 50:1.
- the weight ratio of Tau-fluvalinate to Afidopyropen is from about 1 : 100 to 100: 1. In another embodiment, the weight ratio of Tau-fluvalinate to Afidopyropen is from about 1:50 to 50:1. In another embodiment, the weight ratio of Tau-fluvalinate to Afidopyropen is 20:1.
- the weight ratio of Tau-fluvalinate to Pymetrozine is from about 1 : 100 to 100: 1. In another embodiment, the weight ratio of Tau-fluvalinate to Pymetrozine is from about 1:50 to 50:1. In another embodiment, the weight ratio of Tau-fluvalinate to Pymetrozine is from about 1:25 to 25:1. In yet another embodiment, the weight ratio of the Tau-fluvalinate to Pymetrozine is from about 1:10 to 10:1. In an embodiment, the weight ratio of the Tau-fluvalinate to Pymetrozine is from about 1:5 to 5:1. In a specific embodiment, the weight ratio of Tau- fluvalinate to Pymetrozine is about 1:1. In a specific embodiment, the weight ratio of Tau- fluvalinate to Pymetrozine is about 1:2. In a specific embodiment, the weight ratio of Tau- fluvalinate to Pymetrozine is about 1:5. The weight ratio of Tau-fluvalinate to Pymetrozine may be any in-between range selected from the above indicated ratios.
- the weight ratio of Tau-fluvalinate to Pyrifluquinazon is from about 1:100 to 100:1. In another embodiment, the weight ratio of Tau-fluvalinate to Pyrifluquinazon is from about 1:50 to 50:1. In another embodiment, the weight ratio of Tau-fluvalinate to Pyrifluquinazon is from about 1:25 to 25:1. In yet another embodiment, the weight ratio of the Tau-fluvalinate to Pyrifluquinazon is from about 1:10 to 10:1. In an embodiment, the weight ratio of the Tau-fluvalinate to Pyrifluquinazon is from about 1:5 to 5:1. In a specific embodiment, the weight ratio of Tau-fluvalinate to Pyrifluquinazon is about 1:2.5.
- the weight ratio of Tau-fluvalinate to Azadirachtin is from about 1 : 100 to 100: 1. In another embodiment, the weight ratio of Tau-fluvalinate to Azadirachtin is from about 1:50 to 50:1. In another embodiment, the weight ratio of Tau-fluvalinate to Azadirachtin is from about 1:25 to 25:1. In yet another embodiment, the weight ratio of the Tau-fluvalinate to Azadirachtin is from about 1:10 to 10:1. In an embodiment, the weight ratio of the Tau-fluvalinate to Azadirachtin is from about 1:2 to 1:10. In a specific embodiment, the weight ratio of Tau- fluvalinate to Azadirachtin is about 1:1. In a specific embodiment, the weight ratio of Tau- fluvalinate to Azadirachtin is about 1:2.5. The weight ratio of Tau-fluvalinate to Azadirachtin may be any in-between range selected from the above indicated ratios.
- the weight ratio of Tau-fluvalinate to Azocyclotin is from about 1 : 100 to 100: 1. In another embodiment, the weight ratio of Tau-fluvalinate to Azocyclotin is from about 1:50 to 50:1. In another embodiment, the weight ratio of Tau-fluvalinate to Azocyclotin is from about 1:25 to 25:1. In yet another embodiment, the weight ratio of the Tau-fluvalinate to Azocyclotin is from about 1:10 to 10:1. In an embodiment, the weight ratio of the Tau-fluvalinate to Azocyclotin is from about 1:5 to 5:1. In a specific embodiment, the weight ratio of Tau- fluvalinate to Azocyclotin is about 1:10. In a specific embodiment, the weight ratio of Tau- fluvalinate to Azocyclotin is about 1:3. The weight ratio of Tau-fluvalinate to Azocyclotin may be any in-between range selected from the above indicated ratios.
- the weight ratio of Tau-fluvalinate to Diafenthiuron is from about 1 : 100 to 100: 1. In another embodiment, the weight ratio of Tau-fluvalinate to Diafenthiuron is from about 1:50 to 50:1. In another embodiment, the weight ratio of Tau-fluvalinate to Diafenthiuron is from 1: 1 to 5:1.
- the weight ratio of Tau-fluvalinate to Fenbutatin oxide is from about 1:100 to 100:1. In another embodiment, the weight ratio of Tau-fluvalinate to Fenbutatin oxide is from about 1 :50 to 50: 1. In another embodiment, the weight ratio of Tau-fluvalinate to Fenbutatin oxide is from about 1 :25 to 25 : 1. In yet another embodiment, the weight ratio of the T au-fluvalinate to Fenbutatin oxide is from about 1:10 to 10:1. In an embodiment, the weight ratio of the Tau- fluvalinate to Fenbutatin oxide is from about 1:5 to 5:1. In a specific embodiment, the weight ratio of Tau-fluvalinate to Fenbutatin oxide is about 1:1. The weight ratio of Tau-fluvalinate to Fenbutatin oxide may be any in-between range selected from the above indicated ratios.
- the weight ratio of Tau-fluvalinate to Tetradifon is from about 1:100 to 100:1. In another embodiment, the weight ratio of Tau-fluvalinate to Tetradifon is from about 1:50 to 50:1. In another embodiment, the weight ratio of Tau-fluvalinate to Tetradifon is from about 1 :25 to 25 : 1. In yet another embodiment, the weight ratio of the T au-fluvalinate to Tetradifon is from about 1 : 10 to 10: 1. In an embodiment, the weight ratio of the Tau-fluvalinate to Tetradifon is from about 1:5 to 5:1. In a specific embodiment, the weight ratio of Tau-fluvalinate to Tetradifon is about 1:1. In a specific embodiment, the weight ratio of Tau-fluvalinate to Tetradifon is about 1:2. The weight ratio of Tau-fluvalinate to Tetradifon may be any in-between range selected from the above indicated ratios.
- the weight ratio of Tau-fluvalinate to Benzpyrimoxan is from about 1:100 to 100:1. In another embodiment, the weight ratio of Tau-fluvalinate to Benzpyrimoxan is from about 1:50 to 50:1. In another embodiment, the weight ratio of Tau-fluvalinate to Benzpyrimoxan is from about 1:25 to 25:1. In yet another embodiment, the weight ratio of the Tau-fluvalinate to Benzpyrimoxan is from about 1:10 to 10:1. In an embodiment, the weight ratio of the Tau-fluvalinate to Benzpyrimoxan is from about 1:10 to 1:30. In a specific embodiment, the weight ratio of Tau-fluvalinate to Benzpyrimoxan is about 1:30. In a specific embodiment, the weight ratio of Tau-fluvalinate to Benzpyrimoxan is about 1:10. The weight ratio of Tau- fluvalinate to Benzpyrimoxan may be any in-between range selected from the above indicated ratios.
- the weight ratio of Tau-fluvalinate to Bifenazate is from about 1:100 to 100:1. In another embodiment, the weight ratio of Tau-fluvalinate to Bifenazate is from about 1:50 to 50:1. In another embodiment, the weight ratio of Tau-fluvalinate to Bifenazate is from 1:25 to 25:1. In a specific embodiment, the weight ratio of Tau-fluvalinate to Fenpyroximate is from about 1:100 to 100:1. In another embodiment, the weight ratio of Tau-fluvalinate to Fenpyroximate is from about 1:50 to 50:1. In another embodiment, the weight ratio of Tau-fluvalinate to Fenpyroximate is 25:1.
- the weight ratio of Tau-fluvalinate to Tolfenpyrad is from about 1:100 to 100:1. In another embodiment, the weight ratio of Tau-fluvalinate to Tolfenpyrad is from about 1:50 to 50:1. In another embodiment, the weight ratio of Tau-fluvalinate to Tolfenpyrad is from 1:20 to 20:1.
- the weight ratio of Tau-fluvalinate to pyromite is from about 1:100 to 100:1. In another embodiment, the weight ratio of Tau-fluvalinate to pyromite is from about 1:50 to 50: 1. In another embodiment, the weight ratio of Tau-fluvalinate to pyromite is from about 1 :25 to 25:1. In yet another embodiment, the weight ratio of the Tau-fluvalinate to pyromite is from about 1:10 to 10:1. In an embodiment, the weight ratio of the Tau-fluvalinate to pyromite is from about 1:5 to 5:1. In a specific embodiment, the weight ratio of Tau-fluvalinate to pyromite is about 1:2 to 2:1. In a specific embodiment, the weight ratio of Tau-fluvalinate to pyromite is about 1:1. The weight ratio of Tau-fluvalinate to pyromite may be any in-between range selected from the above indicated ratios.
- the weight ratio of Tau-fluvalinate to Broflanilide is from about 1:100 to 100: 1. In another embodiment, the weight ratio of Tau-fluvalinate to Broflanilide is from about 1:50 to 50:1. In another embodiment, the weight ratio of Tau-fluvalinate to Broflanilide is from about 1:25 to 25:1. In yet another embodiment, the weight ratio of the Tau-fluvalinate to Broflanilide is from about 1:10 to 10:1. In an embodiment, the weight ratio of the Tau-fluvalinate to Broflanilide is from about 1:5 to 5:1. In a specific embodiment, the weight ratio of Tau- fluvalinate to Broflanilide is about 1:2 to 2:1. In a specific embodiment, the weight ratio of Tau- fluvalinate to Broflanilide is about 1:1. The weight ratio of Tau-fluvalinate to Broflanilide may be any in-between range selected from the above indicated ratios.
- the weight ratio of Tau-fluvalinate to a Mite growth inhibitor affecting CHS 1 is from about 1 : 100 to 100: 1. In another embodiment, the weight ratio of Tau-fluvalinate to a Mite growth inhibitor affecting CHS1 is from about 1:50 to 50:1.
- the weight ratio of Tau-fluvalinate to Clofentezine is from about 1 : 100 to 100: 1. In another embodiment, the weight ratio of Tau-fluvalinate to Clofentezine is from about 1:50 to 50:1. In another embodiment, the weight ratio of Tau-fluvalinate to Clofentezine is from 1:25 to 25:1. In a specific embodiment, the weight ratio of Tau-fluvalinate to Diflovidazin is from about 1 : 100 to 100: 1. In another embodiment, the weight ratio of Tau-fluvalinate to Diflovidazin is from about 1:50 to 50:1. In another embodiment, the weight ratio of Tau-fluvalinate to Diflovidazin is from 1:1 to 25:1.
- the weight ratio of Tau-fluvalinate to chlorantraniliprole is from about 1:100 to 100:1. In another embodiment, the weight ratio of Tau-fluvalinate to chlorantraniliprole is from about 1:50 to 50:1. In another embodiment, the weight ratio of Tau-fluvalinate to chlorantraniliprole is from about 1:25 to 25:1. In yet another embodiment, the weight ratio of the Tau-fluvalinate to chlorantraniliprole is from about 1:10 to 10:1. In an embodiment, the weight ratio of the Tau-fluvalinate to chlorantraniliprole is from about 1:5 to 5:1. In a specific embodiment, the weight ratio of Tau-fluvalinate to chlorantraniliprole is about 1:2.5.
- the weight ratio of Tau-fluvalinate to chlorantraniliprole is about 1.5:1. In a specific embodiment, the weight ratio of Tau-fluvalinate to chlorantraniliprole is about 15:1.
- the weight ratio of Tau-fluvalinate to chlorantraniliprole may be any in-between range selected from the above indicated ratios.
- the weight ratio of Tau-fluvalinate to a Ryanodine receptor modulator is from about 1:100 to 100:1. In another embodiment, the weight ratio of Tau-fluvalinate to a Ryanodine receptor modulator is from about 1:50 to 50:1.
- the weight ratio of Tau-fluvalinate to cyantraniliprole is about 1.5:1. In a specific embodiment, the weight ratio of Tau-fluvalinate to cyantraniliprole is about 15:1.
- the weight ratio of Tau- fluvalinate to cyantraniliprole may be any in-between range selected from the above indicated ratios.
- the weight ratio of Tau-fluvalinate to Flubendiamide is about 1:1. In a specific embodiment, the weight ratio of Tau-fluvalinate to Flubendiamide is about 4: 1.
- the weight ratio of Tau-fluvalinate to Flubendiamide may be any in-between range selected from the above indicated ratios.
- the weight ratio of Tau-fluvalinate to a broad-spectrum insect growth regulator is from about 1 : 100 to 100: 1. In another embodiment, the weight ratio of Tau-fluvalinate to a broad-spectrum insect growth regulator is from about 1:50 to 50:1. In a specific embodiment, the weight ratio of Tau-fluvalinate to Pyriproxyfen is from about 1 : 100 to 100: 1. In another embodiment, the weight ratio of Tau-fluvalinate to Pyriproxyfen is from about 1:50 to 50:1.
- the weight ratio of Tau-fluvalinate to Indoxacarb is from about 1:100 to 100:1. In another embodiment, the weight ratio of Tau-fluvalinate to Indoxacarb is from about 1:50 to 50:1. In another embodiment, the weight ratio of Tau-fluvalinate to Indoxacarb is from about 1:25 to 25:1. In yet another embodiment, the weight ratio of the Tau-fluvalinate to Indoxacarb is from about 1:10 to 10:1. In an embodiment, the weight ratio of the Tau-fluvalinate to Indoxacarb is from about 1:5 to 5:1. In a specific embodiment, the weight ratio of Tau- fluvalinate to Indoxacarb is about 1:3.
- the weight ratio of Tau- fluvalinate to Indoxacarb is about 1:1. In a specific embodiment, the weight ratio of Tau- fluvalinate to Indoxacarb is about 12:1.
- the weight ratio of Tau-fluvalinate to Indoxacarb may be any in-between range selected from the above indicated ratios. In one embodiment, the weight ratio of Tau-fluvalinate to an Inhibitor of chitin biosynthesis affecting CHS1 is from about 1:100 to 100:1. In another embodiment, the weight ratio of Tau-fluvalinate to an Inhibitor of chitin biosynthesis affecting CHS1 is from about 1:50 to 50:1.
- the weight ratio of Tau-fluvalinate to Novaluron is from about 1:100 to 100:1. In another embodiment, the weight ratio of Tau-fluvalinate to Novaluron is from about 1:1 to 1:100.
- the weight ratio of Tau-fluvalinate to Spiropidion from about 1:100 to 100:1. In another embodiment, the weight ratio of Tau-fluvalinate to Spiropidion is from about 1:50 to 50:1. In another embodiment, the weight ratio of Tau-fluvalinate to Spiropidion is from about 1:25 to 25:1. In yet another embodiment, the weight ratio of the Tau-fluvalinate to Spiropidion is from about 1:10 to 10:1. In an embodiment, the weight ratio of the Tau-fluvalinate to Spiropidion is from about 1:5 to 5:1. In a specific embodiment, the weight ratio of Tau- fluvalinate to Spiropidion is about 1:2 to 2:1. In a specific embodiment, the weight ratio of Tau- fluvalinate to Spiropidion is about 1:1. The weight ratio of Tau-fluvalinate to Spiropidion may be any in-between range selected from the above indicated ratios.
- the weight ratio of Tau-fluvalinate to Spirotetramat from about 1:100 to 100:1. In another embodiment, the weight ratio of Tau-fluvalinate to Spirotetramat is from about 1:50 to 50:1. In another embodiment, the weight ratio of Tau-fluvalinate to Spirotetramat is from about 1:25 to 25:1. In yet another embodiment, the weight ratio of the Tau-fluvalinate to Spirotetramat is from about 1 : 10 to 10: 1. In an embodiment, the weight ratio of the Tau-fluvalinate to Spirotetramat is from about 1:5 to 5:1. In a specific embodiment, the weight ratio of Tau- fluvalinate to Spirotetramat is about 1:2 to 2:1. In a specific embodiment, the weight ratio of Tau- fluvalinate to Spirotetramat is about 1:1. The weight ratio of Tau-fluvalinate to Spirotetramat may be any in-between range selected from the above indicated ratios.
- the weight ratio of Tau-fluvalinate to a Microbial disruptor of insect midgut membranes is from about 1:100 to 100:1. In another embodiment, the weight ratio of Tau- fluvalinate to a Microbial disruptor of insect midgut membranes is from about 1:50 to 50:1.
- the weight ratio of Tau-fluvalinate to Bacillus thuringiensis toxin is from about 1:100 to 100:1. In another embodiment, the weight ratio of Tau-fluvalinate to Bacillus thuringiensis toxin is from about 1:50 to 50:1. In another embodiment, the weight ratio of Tau-fluvalinate to Bacillus thuringiensis toxin is from 1:1 to 1:5.
- the weight ratio of Tau-fluvalinate to Pydiflumetofen from about 1:100 to 100:1. In another embodiment, the weight ratio of Tau-fluvalinate to Pydiflumetofen is from about 1:50 to 50:1. In another embodiment, the weight ratio of Tau-fluvalinate to Pydiflumetofen is from about 1 :25 to 25: 1. In yet another embodiment, the weight ratio of the Tau- fluvalinate to Pydiflumetofen is from about 1:10 to 10:1. In an embodiment, the weight ratio of the Tau-fluvalinate to Pydiflumetofen is from about 1:5 to 5:1. In a specific embodiment, the weight ratio of Tau-fluvalinate to Pydiflumetofen is about 1:1. In a specific embodiment, the weight ratio of Tau-fluvalinate to Pydiflumetofen is about 3:1. The weight ratio of Tau-fluvalinate to Pydiflumetofen may be any in-between range selected from the above indicated ratios.
- the weight ratio of Tau-fluvalinate to Fluxapyroxad from about 1:100 to 100: 1. In another embodiment, the weight ratio of Tau-fluvalinate to Fluxapyroxad is from about 1:50 to 50:1. In another embodiment, the weight ratio of Tau-fluvalinate to Fluxapyroxad is from about 1:25 to 25:1. In yet another embodiment, the weight ratio of the Tau-fluvalinate to Fluxapyroxad is from about 1 : 10 to 10: 1. In an embodiment, the weight ratio of the Tau-fluvalinate to Fluxapyroxad is from about 1:5 to 5:1. In a specific embodiment, the weight ratio of Tau- fluvalinate to Fluxapyroxad is about 1:1. The weight ratio of Tau-fluvalinate to Fluxapyroxad may be any in-between range selected from the above indicated ratios.
- the weight ratio of Tau-fluvalinate to Difenoconazole from about 1:100 to 100:1. In another embodiment, the weight ratio of Tau-fluvalinate to Difenoconazole is from about 1:50 to 50:1. In another embodiment, the weight ratio of Tau-fluvalinate to Dif enoconazole is from about 1:25 to 25:1. In yet another embodiment, the weight ratio of the Tau-fluvalinate to Difenoconazole is from about 1:10 to 10:1. In an embodiment, the weight ratio of the Tau-fluvalinate to Difenoconazole is from about 1:5 to 5:1. In a specific embodiment, the weight ratio of Tau-fluvalinate to Difenoconazole is about 1:1.
- the weight ratio of Tau-fluvalinate to Difenoconazole is about 5:1. In a specific embodiment, the weight ratio of Tau-fluvalinate to Difenoconazole is about 1:3.
- the weight ratio of Tau-fluvalinate to Difenoconazole may be any in-between range selected from the above indicated ratios.
- the weight ratio of Tau- fluvalinate to Tebuconazole is about 2:1. In a specific embodiment, the weight ratio of Tau- fluvalinate to Tebuconazole is about 1:2. The weight ratio of Tau-fluvalinate to Tebuconazole may be any in-between range selected from the above indicated ratios.
- the weight ratio of Tau-fluvalinate to Azoxystrobin from about 1:100 to 100:1. In another embodiment, the weight ratio of Tau-fluvalinate to Azoxystrobin is from about 1:50 to 50:1. In another embodiment, the weight ratio of Tau-fluvalinate to Azoxystrobin is from about 1:25 to 25:1. In yet another embodiment, the weight ratio of the Tau-fluvalinate to Azoxystrobin is from about 1 : 10 to 10: 1. In an embodiment, the weight ratio of the Tau-fluvalinate to Azoxystrobin is from about 1:5 to 5:1. In a specific embodiment, the weight ratio of Tau- fluvalinate to Azoxy strobin is about 1:1. In a specific embodiment, the weight ratio of Tau- fluvalinate to Azoxystrobin is about 1:3. The weight ratio of Tau-fluvalinate to Azoxystrobin may be any in-between range selected from the above indicated ratios.
- the weight ratio of Tau-fluvalinate to Mancozeb from about 1:100 to 100: 1. In another embodiment, the weight ratio of Tau-fluvalinate to Mancozeb is from about 1 :50 to 50:1. In another embodiment, the weight ratio of Tau-fluvalinate to Mancozeb is from about 1:25 to 25:1. In yet another embodiment, the weight ratio of the Tau-fluvalinate to Mancozeb is from about 1:10 to 10:1. In an embodiment, the weight ratio of the Tau-fluvalinate to Mancozeb is from about 1:5 to 5:1. In a specific embodiment, the weight ratio of Tau-fluvalinate to Mancozeb is about 1:1. In a specific embodiment, the weight ratio of Tau-fluvalinate to Mancozeb is about 1:10. The weight ratio of Tau-fluvalinate to Mancozeb may be any in-between range selected from the above indicated ratios.
- the weight ratio of Tau-fluvalinate to a mesoionic insecticide is from about 1:100 to 100:1. In another embodiment, the weight ratio of Tau-fluvalinate to a mesoionic insecticide is from about 1:50 to 50:1.
- the weight ratio of Tau-fluvalinate to Triflumezopyrim is from about 1:100 to 100:1. In another embodiment, the weight ratio of Tau-fluvalinate to Triflumezopyrim is from about 1:50 to 50:1. In another embodiment, the weight ratio of Tau- fluvalinate to Triflumezopyrim is 2:1.
- the mixture combination of the present invention may be applied presowing or post-sowing, pre-emergence, or early-post-emergence of the crop.
- the mixture combination may be applied via in furrow spray, foliar application, broadcast, basal application, soil application, soil incorporation or soil injection.
- the mixture combination is applied in non-crop areas which include but are not limited to, commercial areas, residential areas, lawns, ornamental plants, shrubs, trees, parks, livestock areas, warehouses, food storage facilities, grain bins, turfgrass, pastures, grasslands, rangelands, fallow land, rights-of-way, golf courses, parks, along roadsides, power-lines, pipelines, railways, forests, well sites, and equipment yards.
- the plants include vegetables, such as tomatoes, peppers, cabbage, broccoli, lettuce, spinach, cauliflower, cucurbits, melon, watermelon, cucumbers, carrots, onions, potatoes, tobacco, pome and stone fruits, walnuts, kiwi, berries, olive, almonds, pineapples, apples, pears, plums, peaches, and cherries, table and wine grapes, citrus fruit, such as oranges, lemons, grapefruits and limes, cotton, soybean, oil seed rape, tree nuts, wheat, barley, maize, sorghum, sunflower, peanuts, rice, pasture, com, coffee, beans, peas, yucca, sugar cane, clover, chili and ornamentals such as roses.
- vegetables such as tomatoes, peppers, cabbage, broccoli, lettuce, spinach, cauliflower, cucurbits, melon, watermelon, cucumbers, carrots, onions, potatoes, tobacco, pome and stone fruits, walnuts, kiwi, berries, olive, almonds, pineapples, apples, pears
- the plants include cultivated plants which tolerate the action of herbicides, fungicides or insecticides as a result of breeding and/or genetically engineered methods.
- the insect pests are of the order Coleoptera, such as Acanthoscelides spp. (weevils), Acanthoscelides obtectus (common bean weevil), Agrilus planipennis (emerald ash borer), Agriotes spp. (wireworms), Anoplophora glabripennis (Asian longhorned beetle), Anthonomus spp. (weevils), Anthonomus grandis (boll weevil), Aphidius spp., Apion spp. (weevils), Apogonia spp.
- Acanthoscelides spp. (weevils)
- Acanthoscelides obtectus common bean weevil
- Agrilus planipennis emerald ash borer
- Agriotes spp. wireworms
- Anoplophora glabripennis Asian longhorned beetle
- the insect pests are of the order Diptera, such as Aedes spp. (mosquitoes), Agromyza frontella (alfalfa blotch leafminer), Agromyza spp. (leaf miner flies), Anastrepha spp. (fruit flies), Anastrepha suspensa (Caribbean fruit fly), Anopheles spp. (mosquitoes), Batrocera spp. (fruit flies), Bactrocera cucurbitae (melon fly), Bactrocera dorsalis (oriental fruit fly), Ceratitis spp.
- Aedes spp. mosquitoes
- Agromyza frontella alfalfa blotch leafminer
- Agromyza spp. leaf miner flies
- Anastrepha spp. fruit flies
- Anastrepha suspensa Caribbean fruit fly
- Anopheles spp. mosquit
- Muscid flies Musca autumnalis (face fly), Musca domestica (house fly), Oestrus ovis (sheep bot fly), Oscinella frit (grass fly), Pegomyia betae (beet leafminer), Phorbia spp., Psila rosae (carrot rust fly), Rhagoletis cerasi (cherry fruit fly), Rhagoletis pomonella (apple maggot), Sitodiplosis mosellana (orange wheat blossom midge), Stomoxys calcitrans (stable fly), Tabanus spp. (horse flies) and Tipula spp. (crane flies).
- the insect pests are of the order Hemiptera, such as Acrosternum hilare (green stink bug), Blissus leucopterus (chinch bug), Calocoris norvegicus (potato mirid), Cimex hemipterus (tropical bed bug), Cimex lectularius (bed bug), Dagbertus fasciatus, Dichelops furcatus, Dysdercus suturellus (cotton Stainer), Edessa meditabunda, Eurygaster maura (cereal bug), Euschistus heros, Euschistus servus (brown stink bug), Helopeltis antonii, Helopeltis theivora (tea blight plantbug), Lagynotomus spp.
- Hemiptera such as Acrosternum hilare (green stink bug), Blissus leucopterus (chinch bug), Calocoris norvegicus (potato mirid), Cim
- the insect pests are of the order Homoptera, such as Acrythosiphon pisum (pea aphid), Adelges spp. (adelgids), Aleurodes proletella (cabbage whitefly), Aleurodicus disperses, Aleurothrixus floccosus (woolly whitefly), Aluacaspis spp., Amrasca bigutella, Aphrophora spp. (leafhoppers), Aonidiella aurantii (California red scale), Aphis spp.
- Homoptera such as Acrythosiphon pisum (pea aphid), Adelges spp. (adelgids), Aleurodes proletella (cabbage whitefly), Aleurodicus disperses, Aleurothrixus floccosus (woolly whitefly), Aluacaspis spp., Amrasca bigutella, Aphrophora
- Aphids Aphis gossypii (cotton aphid), Aphis pomi (apple aphid), Aulacorthum solani (foxglove aphid), Bemisia spp. (whiteflies), Bemisia argentifolii, Bemisia tabaci (sweetpotato whitefly), Brachycolus noxius (Russian aphid), Brachycorynella asparagi (asparagus aphid), Brevennia rehi, Brevicoryne brassicae (cabbage aphid), Ceroplastes spp. (scales), Ceroplastes rubens (red wax scale), Chionaspis spp.
- Rhapalosiphum spp. aphids
- Rhapalosiphum maida com leaf aphid
- Rhapalosiphum padi oat bird-cherry aphid
- Saissetia spp. scales
- Saissetia oleae black scale
- Schizaphis graminum greenbug
- Sitobion avenae English grain aphid
- Sogatella furcifera white -backed planthopper
- the insect pests are of the order Lepidoptera, such as Achoea janata, Adoxophyes spp., Adoxophyes orana, Agrotis spp. (cutworms), Agrotis ipsilon (black cutworm), Alabama argillacea (cotton leafworm), Amorbia cuneana, Amyelosis transitella (navel orangeworm), Anacamptodes defectaria, Anarsia lineatella (peach twig borer), Anomis sabulifera (jute looper), Anticarsia gemmatalis (velvetbean caterpillar), Archips argyrospila (fruittree leafroller), Archips rosana (rose leaf roller), Argyrotaenia spp.
- Lepidoptera such as Achoea janata, Adoxophyes spp., Adoxophyes orana
- Agrotis spp. (cutworms), Agrotis ipsilon (black cutworm), Alabama
- Sod webworms Cydia funebrana (plum fruit moth), Cydia molesta (oriental fruit moth), Cydia nignicana (pea moth), Cydia pomonella (codling moth), Darna diducta, Diaphania spp. (stem borers), Diatraea spp. (stalk borers), Diatraea saccharalis (sugarcane borer), Diatraea graniosella (southwester corn borer), Earias spp.
- the insect pests are of the order Orthoptera, such as Anabrus simplex (Mormon cricket), Gryllotalpidae (mole crickets), Locusta migratoria, Melanoplus spp. (grasshoppers), Microcentrum retinerve (angularwinged katydid), Pterophylla spp. (kaydids), chistocerca gregaria, Scudderia furcata (forktailed bush katydid) and Valanga nigricorni.
- Orthoptera such as Anabrus simplex (Mormon cricket), Gryllotalpidae (mole crickets), Locusta migratoria, Melanoplus spp. (grasshoppers), Microcentrum retinerve (angularwinged katydid), Pterophylla spp. (kaydids), chistocerca gregaria, Scudderia furcata (forktailed bush katydid) and Valanga nigri
- each of Tau-fluvalinate, and the crop protection chemical compound II may be applied jointly or in succession.
- Tau-fluvalinate, and the crop protection chemical compound II are prepared separately, and the individual formulations are applied as is, or diluted to predetermined concentrations.
- Tau-fluvalinate, and the crop protection chemical compound II are prepared separately, and the formulations are mixed when diluted to a predetermined concentration.
- Tau-fluvalinate, and the crop protection chemical compound II are formulated together, and the formulation is applied as it is, or the formulation is diluted to a predetermined concentration.
- tau-fluvalinate, and lambda-cyhalothrin can be applied simultaneously, that is jointly or separately, or in succession, the sequence, in the case of separate application, generally not having any effect on the result of the control measures.
- tau-fluvalinate, and lambda-cyhalothrin are prepared separately, and the individual formulations are applied as is, or diluted to predetermined concentrations.
- tau-fluvalinate, and lambda- cyhalothrin are prepared separately, and the formulations are mixed when diluted to a predetermined concentration.
- tau-fluvalinate, and lambda-cyhalothrin are formulated together, and the formulation is applied as it is, or the formulation is diluted to a predetermined concentration.
- tau-fluvalinate, and Acetamiprid can be applied simultaneously, that is jointly or separately, or in succession, the sequence, in the case of separate application, generally not having any effect on the result of the control measures.
- tau-fluvalinate, and Acetamiprid are prepared separately, and the individual formulations are applied as is, or diluted to predetermined concentrations.
- tau-fluvalinate, and Acetamiprid are prepared separately, and the formulations are mixed when diluted to a predetermined concentration.
- tau-fluvalinate, and Acetamiprid are formulated together, and the formulation is applied as it is, or the formulation is diluted to a predetermined concentration.
- tau-fluvalinate, and Sulfoxaflor can be applied simultaneously, that is jointly or separately, or in succession, the sequence, in the case of separate application, generally not having any effect on the result of the control measures.
- tau-fluvalinate, and Sulfoxaflor are prepared separately, and the individual formulations are applied as is, or diluted to predetermined concentrations.
- tau-fluvalinate, and Sulfoxaflor are prepared separately, and the formulations are mixed when diluted to a predetermined concentration.
- tau-fluvalinate, and Sulfoxaflor are formulated together, and the formulation is applied as it is, or the formulation is diluted to a predetermined concentration.
- tau-fluvalinate, and Thiocyclam can be applied simultaneously, that is jointly or separately, or in succession, the sequence, in the case of separate application, generally not having any effect on the result of the control measures.
- tau-fluvalinate, and Thiocyclam are prepared separately, and the individual formulations are applied as is, or diluted to predetermined concentrations.
- tau-fluvalinate, and Thiocyclam are prepared separately, and the formulations are mixed when diluted to a predetermined concentration.
- tau-fluvalinate, and Thiocyclam are formulated together, and the formulation is applied as it is, or the formulation is diluted to a predetermined concentration.
- tau-fluvalinate, and Pymetrozine can be applied simultaneously, that is jointly or separately, or in succession, the sequence, in the case of separate application, generally not having any effect on the result of the control measures.
- tau-fluvalinate, and Pymetrozine are prepared separately, and the individual formulations are applied as is, or diluted to predetermined concentrations.
- tau-fluvalinate, and Pymetrozine are prepared separately, and the formulations are mixed when diluted to a predetermined concentration.
- tau-fluvalinate, and Pymetrozine are formulated together, and the formulation is applied as it is, or the formulation is diluted to a predetermined concentration.
- tau-fluvalinate, and Pyrifluquinazon can be applied simultaneously, that is jointly or separately, or in succession, the sequence, in the case of separate application, generally not having any effect on the result of the control measures.
- tau-fluvalinate, and Pyrifluquinazon are prepared separately, and the individual formulations are applied as is, or diluted to predetermined concentrations.
- tau-fluvalinate, and Pyrifluquinazon are prepared separately, and the formulations are mixed when diluted to a predetermined concentration.
- tau-fluvalinate, and Pyrifluquinazon are formulated together, and the formulation is applied as it is, or the formulation is diluted to a predetermined concentration.
- tau-fluvalinate, and Flonicamid can be applied simultaneously, that is jointly or separately, or in succession, the sequence, in the case of separate application, generally not having any effect on the result of the control measures.
- tau-fluvalinate, and Flonicamid are prepared separately, and the individual formulations are applied as is, or diluted to predetermined concentrations.
- tau-fluvalinate, and Flonicamid are prepared separately, and the formulations are mixed when diluted to a predetermined concentration.
- tau-fluvalinate, and Flonicamid are formulated together, and the formulation is applied as it is, or the formulation is diluted to a predetermined concentration.
- tau-fluvalinate, and Azadirachtin can be applied simultaneously, that is jointly or separately, or in succession, the sequence, in the case of separate application, generally not having any effect on the result of the control measures.
- tau-fluvalinate, and Azadirachtin are prepared separately, and the individual formulations are applied as is, or diluted to predetermined concentrations.
- tau-fluvalinate, and Azadirachtin are prepared separately, and the formulations are mixed when diluted to a predetermined concentration.
- tau-fluvalinate, and Azadirachtin are formulated together, and the formulation is applied as it is, or the formulation is diluted to a predetermined concentration.
- tau-fluvalinate, and Azocyclotin can be applied simultaneously, that is jointly or separately, or in succession, the sequence, in the case of separate application, generally not having any effect on the result of the control measures.
- tau-fluvalinate, and Azocyclotin are prepared separately, and the individual formulations are applied as is, or diluted to predetermined concentrations.
- tau-fluvalinate, and Azocyclotin are prepared separately, and the formulations are mixed when diluted to a predetermined concentration.
- tau-fluvalinate, and Azocyclotin are formulated together, and the formulation is applied as it is, or the formulation is diluted to a predetermined concentration.
- tau-fluvalinate, and Diafenthiuron can be applied simultaneously, that is jointly or separately, or in succession, the sequence, in the case of separate application, generally not having any effect on the result of the control measures.
- tau-fluvalinate, and Diafenthiuron are prepared separately, and the individual formulations are applied as is, or diluted to predetermined concentrations.
- tau-fluvalinate, and Diafenthiuron are prepared separately, and the formulations are mixed when diluted to a predetermined concentration.
- tau-fluvalinate, and Diafenthiuron are formulated together, and the formulation is applied as it is, or the formulation is diluted to a predetermined concentration.
- tau-fluvalinate, and Fenbutatin oxide can be applied simultaneously, that is jointly or separately, or in succession, the sequence, in the case of separate application, generally not having any effect on the result of the control measures.
- tau-fluvalinate, and Fenbutatin oxide are prepared separately, and the individual formulations are applied as is, or diluted to predetermined concentrations.
- tau-fluvalinate, and Fenbutatin oxide are prepared separately, and the formulations are mixed when diluted to a predetermined concentration.
- tau-fluvalinate, and Fenbutatin oxide are formulated together, and the formulation is applied as it is, or the formulation is diluted to a predetermined concentration.
- tau-fluvalinate, and Tetradifon can be applied simultaneously, that is jointly or separately, or in succession, the sequence, in the case of separate application, generally not having any effect on the result of the control measures.
- tau-fluvalinate, and Tetradifon are prepared separately, and the individual formulations are applied as is, or diluted to predetermined concentrations.
- tau-fluvalinate, and Tetradifon are prepared separately, and the formulations are mixed when diluted to a predetermined concentration.
- tau-fluvalinate, and Tetradifon are formulated together, and the formulation is applied as it is, or the formulation is diluted to a predetermined concentration.
- tau-fluvalinate, and Benzpyrimoxan can be applied simultaneously, that is jointly or separately, or in succession, the sequence, in the case of separate application, generally not having any effect on the result of the control measures.
- tau-fluvalinate, and Benzpyrimoxan are prepared separately, and the individual formulations are applied as is, or diluted to predetermined concentrations.
- tau-fluvalinate, and Benzpyrimoxan are prepared separately, and the formulations are mixed when diluted to a predetermined concentration.
- tau-fluvalinate, and Benzpyrimoxan are formulated together, and the formulation is applied as it is, or the formulation is diluted to a predetermined concentration.
- tau-fluvalinate, and Fenpyroximate can be applied simultaneously, that is jointly or separately, or in succession, the sequence, in the case of separate application, generally not having any effect on the result of the control measures.
- tau-fluvalinate, and Fenpyroximate are prepared separately, and the individual formulations are applied as is, or diluted to predetermined concentrations.
- tau-fluvalinate, and Fenpyroximate are prepared separately, and the formulations are mixed when diluted to a predetermined concentration.
- tau-fluvalinate, and Fenpyroximate are formulated together, and the formulation is applied as it is, or the formulation is diluted to a predetermined concentration.
- tau-fluvalinate, and Tolfenpyrad can be applied simultaneously, that is jointly or separately, or in succession, the sequence, in the case of separate application, generally not having any effect on the result of the control measures.
- tau-fluvalinate, and Tolfenpyrad are prepared separately, and the individual formulations are applied as is, or diluted to predetermined concentrations.
- tau-fluvalinate, and Tolfenpyrad are prepared separately, and the formulations are mixed when diluted to a predetermined concentration.
- tau-fluvalinate, and Tolfenpyrad are formulated together, and the formulation is applied as it is, or the formulation is diluted to a predetermined concentration.
- tau-fluvalinate, and pyromite can be applied simultaneously, that is jointly or separately, or in succession, the sequence, in the case of separate application, generally not having any effect on the result of the control measures.
- tau-fluvalinate, and pyromite are prepared separately, and the individual formulations are applied as is, or diluted to predetermined concentrations.
- tau-fluvalinate, and pyromite are prepared separately, and the formulations are mixed when diluted to a predetermined concentration.
- tau-fluvalinate, and pyromite are formulated together, and the formulation is applied as it is, or the formulation is diluted to a predetermined concentration.
- tau-fluvalinate, and Broflanilide can be applied simultaneously, that is jointly or separately, or in succession, the sequence, in the case of separate application, generally not having any effect on the result of the control measures.
- tau-fluvalinate, and Broflanilide are prepared separately, and the individual formulations are applied as is, or diluted to predetermined concentrations.
- tau-fluvalinate, and Broflanilide are prepared separately, and the formulations are mixed when diluted to a predetermined concentration.
- tau-fluvalinate, and Broflanilide are formulated together, and the formulation is applied as it is, or the formulation is diluted to a predetermined concentration.
- tau-fluvalinate, and Clofentezine can be applied simultaneously, that is jointly or separately, or in succession, the sequence, in the case of separate application, generally not having any effect on the result of the control measures.
- tau-fluvalinate, and Clofentezine are prepared separately, and the individual formulations are applied as is, or diluted to predetermined concentrations.
- tau-fluvalinate, and Clofentezine are prepared separately, and the formulations are mixed when diluted to a predetermined concentration.
- tau-fluvalinate, and Clofentezine are formulated together, and the formulation is applied as it is, or the formulation is diluted to a predetermined concentration.
- tau-fluvalinate, and Diflovidazin can be applied simultaneously, that is jointly or separately, or in succession, the sequence, in the case of separate application, generally not having any effect on the result of the control measures.
- tau-fluvalinate, and Diflovidazin are prepared separately, and the individual formulations are applied as is, or diluted to predetermined concentrations.
- tau-fluvalinate, and Diflovidazin are prepared separately, and the formulations are mixed when diluted to a predetermined concentration.
- tau-fluvalinate, and Diflovidazin are formulated together, and the formulation is applied as it is, or the formulation is diluted to a predetermined concentration.
- tau-fluvalinate, and Etoxazole can be applied simultaneously, that is jointly or separately, or in succession, the sequence, in the case of separate application, generally not having any effect on the result of the control measures.
- tau-fluvalinate, and Etoxazole are prepared separately, and the individual formulations are applied as is, or diluted to predetermined concentrations.
- tau-fluvalinate, and Etoxazole are prepared separately, and the formulations are mixed when diluted to a predetermined concentration.
- tau-fluvalinate, and Etoxazole are formulated together, and the formulation is applied as it is, or the formulation is diluted to a predetermined concentration.
- tau-fluvalinate, and Hexythiazox can be applied simultaneously, that is jointly or separately, or in succession, the sequence, in the case of separate application, generally not having any effect on the result of the control measures.
- tau-fluvalinate, and Hexythiazox are prepared separately, and the individual formulations are applied as is, or diluted to predetermined concentrations.
- tau-fluvalinate, and Hexythiazox are prepared separately, and the formulations are mixed when diluted to a predetermined concentration.
- tau-fluvalinate, and Hexythiazox are formulated together, and the formulation is applied as it is, or the formulation is diluted to a predetermined concentration.
- tau-fluvalinate, and chlorantraniliprole can be applied simultaneously, that is jointly or separately, or in succession, the sequence, in the case of separate application, generally not having any effect on the result of the control measures.
- tau-fluvalinate, and chlorantraniliprole are prepared separately, and the individual formulations are applied as is, or diluted to predetermined concentrations.
- tau-fluvalinate, and chlorantraniliprole are prepared separately, and the formulations are mixed when diluted to a predetermined concentration.
- tau-fluvalinate, and chlorantraniliprole are formulated together, and the formulation is applied as it is, or the formulation is diluted to a predetermined concentration.
- tau-fluvalinate, and Cyclaniliprole can be applied simultaneously, that is jointly or separately, or in succession, the sequence, in the case of separate application, generally not having any effect on the result of the control measures.
- tau-fluvalinate, and Cyclaniliprole are prepared separately, and the individual formulations are applied as is, or diluted to predetermined concentrations.
- tau-fluvalinate, and Cyclaniliprole are prepared separately, and the formulations are mixed when diluted to a predetermined concentration.
- tau-fluvalinate, and Cyclaniliprole are formulated together, and the formulation is applied as it is, or the formulation is diluted to a predetermined concentration.
- tau-fluvalinate, and cyantraniliprole can be applied simultaneously, that is jointly or separately, or in succession, the sequence, in the case of separate application, generally not having any effect on the result of the control measures.
- tau-fluvalinate, and cyantraniliprole are prepared separately, and the individual formulations are applied as is, or diluted to predetermined concentrations.
- tau-fluvalinate, and cyantraniliprole are prepared separately, and the formulations are mixed when diluted to a predetermined concentration.
- tau-fluvalinate, and cyantraniliprole are formulated together, and the formulation is applied as it is, or the formulation is diluted to a predetermined concentration.
- tau-fluvalinate, and Cyromazine can be applied simultaneously, that is jointly or separately, or in succession, the sequence, in the case of separate application, generally not having any effect on the result of the control measures.
- tau-fluvalinate, and Cyromazine are prepared separately, and the individual formulations are applied as is, or diluted to predetermined concentrations.
- tau-fluvalinate, and Cyromazine are prepared separately, and the formulations are mixed when diluted to a predetermined concentration.
- tau-fluvalinate, and Cyromazine are formulated together, and the formulation is applied as it is, or the formulation is diluted to a predetermined concentration.
- tau-fluvalinate, and Pyriproxyfen can be applied simultaneously, that is jointly or separately, or in succession, the sequence, in the case of separate application, generally not having any effect on the result of the control measures.
- tau-fluvalinate, and Pyriproxyfen are prepared separately, and the individual formulations are applied as is, or diluted to predetermined concentrations.
- tau-fluvalinate, and Pyriproxyfen are prepared separately, and the formulations are mixed when diluted to a predetermined concentration.
- tau-fluvalinate, and Pyriproxyfen are formulated together, and the formulation is applied as it is, or the formulation is diluted to a predetermined concentration.
- tau-fluvalinate, and Flupyrimin can be applied simultaneously, that is jointly or separately, or in succession, the sequence, in the case of separate application, generally not having any effect on the result of the control measures.
- tau-fluvalinate, and Flupyrimin are prepared separately, and the individual formulations are applied as is, or diluted to predetermined concentrations.
- tau-fluvalinate, and Flupyrimin are prepared separately, and the formulations are mixed when diluted to a predetermined concentration.
- tau-fluvalinate, and Flupyrimin are formulated together, and the formulation is applied as it is, or the formulation is diluted to a predetermined concentration.
- tau-fluvalinate, and Indoxacarb can be applied simultaneously, that is jointly or separately, or in succession, the sequence, in the case of separate application, generally not having any effect on the result of the control measures.
- tau-fluvalinate, and Indoxacarb are prepared separately, and the individual formulations are applied as is, or diluted to predetermined concentrations.
- tau-fluvalinate, and Indoxacarb are prepared separately, and the formulations are mixed when diluted to a predetermined concentration.
- tau-fluvalinate, and Indoxacarb are formulated together, and the formulation is applied as it is, or the formulation is diluted to a predetermined concentration.
- tau-fluvalinate, and Novaluron can be applied simultaneously, that is jointly or separately, or in succession, the sequence, in the case of separate application, generally not having any effect on the result of the control measures.
- tau-fluvalinate, and Novaluron are prepared separately, and the individual formulations are applied as is, or diluted to predetermined concentrations.
- tau-fluvalinate, and Novaluron are prepared separately, and the formulations are mixed when diluted to a predetermined concentration.
- tau-fluvalinate, and Novaluron are formulated together, and the formulation is applied as it is, or the formulation is diluted to a predetermined concentration.
- tau-fluvalinate, and Oxazosulfyl can be applied simultaneously, that is jointly or separately, or in succession, the sequence, in the case of separate application, generally not having any effect on the result of the control measures.
- tau-fluvalinate, and Oxazosulfyl are prepared separately, and the individual formulations are applied as is, or diluted to predetermined concentrations.
- tau-fluvalinate, and Oxazosulfyl are prepared separately, and the formulations are mixed when diluted to a predetermined concentration.
- tau-fluvalinate, and Oxazosulfyl are formulated together, and the formulation is applied as it is, or the formulation is diluted to a predetermined concentration.
- tau-fluvalinate, and Pyridalyl can be applied simultaneously, that is jointly or separately, or in succession, the sequence, in the case of separate application, generally not having any effect on the result of the control measures.
- tau-fluvalinate, and Pyridalyl are prepared separately, and the individual formulations are applied as is, or diluted to predetermined concentrations.
- tau-fluvalinate, and Pyridalyl are prepared separately, and the formulations are mixed when diluted to a predetermined concentration.
- tau-fluvalinate, and Pyridalyl are formulated together, and the formulation is applied as it is, or the formulation is diluted to a predetermined concentration.
- tau-fluvalinate, and Spiropidion can be applied simultaneously, that is jointly or separately, or in succession, the sequence, in the case of separate application, generally not having any effect on the result of the control measures.
- tau-fluvalinate, and Spiropidion are prepared separately, and the individual formulations are applied as is, or diluted to predetermined concentrations.
- tau-fluvalinate, and Spiropidion are prepared separately, and the formulations are mixed when diluted to a predetermined concentration.
- tau-fluvalinate, and Spiropidion are formulated together, and the formulation is applied as it is, or the formulation is diluted to a predetermined concentration.
- tau-fluvalinate, and Bacillus thuringiensis toxin can be applied simultaneously, that is jointly or separately, or in succession, the sequence, in the case of separate application, generally not having any effect on the result of the control measures.
- tau-fluvalinate, and Bacillus thuringiensis toxin are prepared separately, and the individual formulations are applied as is, or diluted to predetermined concentrations.
- tau-fluvalinate, and Bacillus thuringiensis toxin are prepared separately, and the formulations are mixed when diluted to a predetermined concentration.
- tau-fluvalinate, and Bacillus thuringiensis toxin are formulated together, and the formulation is applied as it is, or the formulation is diluted to a predetermined concentration.
- tau-fluvalinate, and Pydiflumetofen can be applied simultaneously, that is jointly or separately, or in succession, the sequence, in the case of separate application, generally not having any effect on the result of the control measures.
- tau-fluvalinate, and Pydiflumetofen are prepared separately, and the individual formulations are applied as is, or diluted to predetermined concentrations.
- tau-fluvalinate, and Pydiflumetofen are prepared separately, and the formulations are mixed when diluted to a predetermined concentration.
- tau-fluvalinate, and Pydiflumetofen are formulated together, and the formulation is applied as it is, or the formulation is diluted to a predetermined concentration.
- tau-fluvalinate, and Fluxapyroxad can be applied simultaneously, that is jointly or separately, or in succession, the sequence, in the case of separate application, generally not having any effect on the result of the control measures.
- tau-fluvalinate, and Fluxapyroxad are prepared separately, and the individual formulations are applied as is, or diluted to predetermined concentrations.
- tau-fluvalinate, and Fluxapyroxad are prepared separately, and the formulations are mixed when diluted to a predetermined concentration.
- tau-fluvalinate, and Fluxapyroxad are formulated together, and the formulation is applied as it is, or the formulation is diluted to a predetermined concentration.
- tau-fluvalinate, and Difenoconazole can be applied simultaneously, that is jointly or separately, or in succession, the sequence, in the case of separate application, generally not having any effect on the result of the control measures.
- tau-fluvalinate, and Difenoconazole are prepared separately, and the individual formulations are applied as is, or diluted to predetermined concentrations.
- tau-fluvalinate, and Difenoconazole are prepared separately, and the formulations are mixed when diluted to a predetermined concentration.
- tau-fluvalinate, and Difenoconazole are formulated together, and the formulation is applied as it is, or the formulation is diluted to a predetermined concentration.
- tau-fluvalinate, and Tebuconazole can be applied simultaneously, that is jointly or separately, or in succession, the sequence, in the case of separate application, generally not having any effect on the result of the control measures.
- tau-fluvalinate, and Tebuconazole are prepared separately, and the individual formulations are applied as is, or diluted to predetermined concentrations.
- tau-fluvalinate, and Tebuconazole are prepared separately, and the formulations are mixed when diluted to a predetermined concentration.
- tau-fluvalinate, and Tebuconazole are formulated together, and the formulation is applied as it is, or the formulation is diluted to a predetermined concentration.
- tau-fluvalinate, and Azoxystrobin can be applied simultaneously, that is jointly or separately, or in succession, the sequence, in the case of separate application, generally not having any effect on the result of the control measures.
- tau-fluvalinate, and Azoxystrobin are prepared separately, and the individual formulations are applied as is, or diluted to predetermined concentrations.
- tau-fluvalinate, and Azoxystrobin are prepared separately, and the formulations are mixed when diluted to a predetermined concentration.
- tau-fluvalinate, and Azoxystrobin are formulated together, and the formulation is applied as it is, or the formulation is diluted to a predetermined concentration.
- tau-fluvalinate, and Mancozeb can be applied simultaneously, that is jointly or separately, or in succession, the sequence, in the case of separate application, generally not having any effect on the result of the control measures.
- tau-fluvalinate, and Mancozeb are prepared separately, and the individual formulations are applied as is, or diluted to predetermined concentrations.
- tau-fluvalinate, and Mancozeb are prepared separately, and the formulations are mixed when diluted to a predetermined concentration.
- tau-fluvalinate, and Mancozeb are formulated together, and the formulation is applied as it is, or the formulation is diluted to a predetermined concentration.
- tau-fluvalinate, and Triflumezopyrim can be applied simultaneously, that is jointly or separately, or in succession, the sequence, in the case of separate application, generally not having any effect on the result of the control measures.
- tau-fluvalinate, and Triflumezopyrim are prepared separately, and the individual formulations are applied as is, or diluted to predetermined concentrations.
- tau-fluvalinate, and Triflumezopyrim are prepared separately, and the formulations are mixed when diluted to a predetermined concentration.
- tau-fluvalinate and Triflumezopyrim are formulated together, and the formulation is applied as it is, or the formulation is diluted to a predetermined concentration.
- an amount of tau-fluvalinate and an amount of a synthetic pyrethroid if applied together are more effective than when tau-fluvalinate, at the same amount, and the synthetic pyrethroid at the same amount, is applied alone.
- the amount of tau-fluvalinate and (ii) an amount of a synthetic pyrethroid in a ratio from 1:100 to 100:1, if applied together are more effective in treating a plant or soil against insect infection than if (i) at the same amount, and (ii) at the same amount, is applied alone.
- the amount of tau-fluvalinate and (ii) an amount of lambda- cyhalothrin in a ratio from 1:2 to 2:1, if applied together are more effective in treating a plant or soil against insect infection than if (i) at the same amount, and (ii) at the same amount, is applied alone.
- nAChR Nicotinic acetylcholine receptor
- the amount of tau-fluvalinate and (ii) an amount of Acetamiprid in a ratio from 1:100 to 100:1, if applied together are more effective in treating a plant or soil against insect infection than if (i) at the same amount, and (ii) at the same amount, is applied alone.
- the amount of tau-fluvalinate and (ii) an amount of Spinetoram in a ratio from 1:100 to 100:1, if applied together are more effective in treating a plant or soil against insect infection than if (i) at the same amount, and (ii) at the same amount, is applied alone.
- the amount of tau-fluvalinate and (ii) an amount of Spinetoram in a ratio of 1:1, if applied together are more effective in treating a plant or soil against insect infection than if (i) at the same amount, and (ii) at the same amount, is applied alone.
- the amount of tau-fluvalinate and (ii) an amount of Spinosad in a ratio from 1 : 100 to 100: 1 , if applied together are more effective in treating a plant or soil against insect infection than if (i) at the same amount, and (ii) at the same amount, is applied alone.
- the amount of tau-fluvalinate and (ii) an amount of Spinosad in a ratio of 1 : 1 are more effective in treating a plant or soil against insect infection than if (i) at the same amount, and (ii) at the same amount, is applied alone.
- an amount of tau-fluvalinate and an amount of a Chordotonal organ TRPV channel modulator if applied together are more effective than when tau-fluvalinate, at the same amount, and the Chordotonal organ TRPV channel modulator at the same amount, is applied alone.
- the amount of tau-fluvalinate and (ii) an amount of an Inhibitor of mitochondrial ATP synthase in a ratio from 1 : 100 to 100: 1 , if applied together are more effective in treating a plant or soil against insect infection than if (i) at the same amount, and (ii) at the same amount, is applied alone.
- the amount of tau-fluvalinate and (ii) an amount of Diafenthiuron in a ratio from 1:1 to 5:1, if applied together are more effective in treating a plant or soil against insect infection than if (i) at the same amount, and (ii) at the same amount, is applied alone.
- an amount of tau-fluvalinate and an amount of a Mitochondrial complex electron transport inhibitor (METI) if applied together are more effective than when tau- fluvalinate, at the same amount, and a Mitochondrial complex electron transport inhibitor (METI) at the same amount, is applied alone.
- the amount of tau-fluvalinate and (ii) an amount of Bifenazate in a ratio from 1:100 to 100:1, if applied together are more effective in treating a plant or soil against insect infection than if (i) at the same amount, and (ii) at the same amount, is applied alone.
- the amount of tau-fluvalinate and (ii) an amount of Bifenazate in a ratio from 1:25 to 25:1, if applied together are more effective in treating a plant or soil against insect infection than if (i) at the same amount, and (ii) at the same amount, is applied alone.
- an amount of tau-fluvalinate and an amount of a Mite growth inhibitor affecting CHS 1 if applied together are more effective than when tau-fluvalinate, at the same amount, and a Mite growth inhibitor affecting CHS 1 at the same amount, is applied alone.
- the amount of tau-fluvalinate and (ii) an amount of Clofentezine in a ratio from 1:25 to 25:1, if applied together are more effective in treating a plant or soil against insect infection than if (i) at the same amount, and (ii) at the same amount, is applied alone.
- the amount of tau-fluvalinate and (ii) an amount of Diflovidazin in a ratio from 1:100 to 100:1, if applied together are more effective in treating a plant or soil against insect infection than if (i) at the same amount, and (ii) at the same amount, is applied alone.
- the amount of tau-fluvalinate and (ii) an amount of Diflovidazin in a ratio from 1:1 to 25:1, if applied together are more effective in treating a plant or soil against insect infection than if (i) at the same amount, and (ii) at the same amount, is applied alone.
- the amount of tau-fluvalinate and (ii) an amount of Hexythiazox in a ratio from 1:100 to 100:1, if applied together are more effective in treating a plant or soil against insect infection than if (i) at the same amount, and (ii) at the same amount, is applied alone.
- the amount of tau-fluvalinate and (ii) an amount of Hexythiazox in a ratio from 1:25 to 25:1, if applied together are more effective in treating a plant or soil against insect infection than if (i) at the same amount, and (ii) at the same amount, is applied alone.
- an amount of tau-fluvalinate and an amount of a Ryanodine receptor modulator if applied together are more effective than when tau-fluvalinate, at the same amount, and a Ryanodine receptor modulator at the same amount, is applied alone.
- the amount of tau-fluvalinate and (ii) an amount of a Ryanodine receptor modulator in a ratio from 1 : 100 to 100: 1 are more effective in treating a plant or soil against insect infection than if (i) at the same amount, and (ii) at the same amount, is applied alone.
- the amount of tau-fluvalinate and (ii) an amount of Cyclaniliprole in a ratio from 1:100 to 100:1, if applied together are more effective in treating a plant or soil against insect infection than if (i) at the same amount, and (ii) at the same amount, is applied alone.
- the amount of tau-fluvalinate and (ii) an amount of Cyclaniliprole in a ratio from 1:1 to 10:1, if applied together are more effective in treating a plant or soil against insect infection than if (i) at the same amount, and (ii) at the same amount, is applied alone.
- an amount of tau-fluvalinate and an amount of a broad-spectrum insect growth regulator if applied together are more effective than when tau-fluvalinate, at the same amount, and a broad- spectrum insect growth regulator at the same amount, is applied alone.
- an amount of tau-fluvalinate and an amount of an Inhibitor of chitin biosynthesis affecting CHS 1 if applied together are more effective than when tau-fluvalinate, at the same amount, and an Inhibitor of chitin biosynthesis affecting CHS 1 at the same amount, is applied alone.
- the amount of tau-fluvalinate and (ii) an amount of novaluron in a ratio from 1 : 100 to 100: 1 , if applied together are more effective in treating a plant or soil against insect infection than if (i) at the same amount, and (ii) at the same amount, is applied alone.
- the amount of tau-fluvalinate and (ii) an amount of novaluron in a ratio from 1:1 to 1:100, if applied together are more effective in treating a plant or soil against insect infection than if (i) at the same amount, and (ii) at the same amount, is applied alone.
- an amount of tau-fluvalinate and an amount of an organochlorine insecticide if applied together are more effective than when tau-fluvalinate, at the same amount, and an organochlorine insecticide at the same amount, is applied alone.
- the amount of tau-fluvalinate and (ii) an amount of an organochlorine insecticide in a ratio from 1:100 to 100:1, if applied together are more effective in treating a plant or soil against insect infection than if (i) at the same amount, and (ii) at the same amount, is applied alone.
- the amount of tau-fluvalinate and (ii) an amount of Pyridalyl in a ratio from 1 : 100 to 100: 1 are more effective in treating a plant or soil against insect infection than if (i) at the same amount, and (ii) at the same amount, is applied alone.
- an amount of tau-fluvalinate and an amount of a Microbial disruptor of insect midgut membranes if applied together are more effective than when tau-fluvalinate, at the same amount, and a Microbial disruptor of insect midgut membranes at the same amount, is applied alone.
- an amount of tau-fluvalinate and an amount of a mesoionic insecticide if applied together are more effective than when tau-fluvalinate, at the same amount, and a mesoionic insecticide at the same amount, is applied alone.
- the amount of tau-fluvalinate and (ii) an amount of Triflumezopyrim in a ratio from 1:100 to 100:1, if applied together are more effective in treating a plant or soil against insect infection than if (i) at the same amount, and (ii) at the same amount, is applied alone.
- the amount of tau-fluvalinate and (ii) an amount of Triflumezopyrim in a ratio of 2:1, if applied together are more effective in treating a plant or soil against insect infection than if (i) at the same amount, and (ii) at the same amount, is applied alone.
- the mixture combination of active compounds of the invention comprising: (i) tau-fluvalinate; and (ii) at least one crop protection chemical compound II as defined above, is synergistically effective for controlling pests compared to when compound (i) at the same amount, and compound (ii) at the same amount, is applied alone, after several hours to several days of applications.
- the mixture combination of active compounds of the invention comprising: (i) tau-fluvalinate; and (ii) at least one crop protection chemical compound II as defined above, is synergistically effective for controlling pests compared to when compound (i) at the same amount, and compound (ii) at the same amount, is applied alone, after 48 hours of applications.
- the mixture combination of active compounds of the invention comprising: (i) tau-fluvalinate; and (ii) at least one crop protection chemical compound II as defined above, is synergistically effective for controlling pests compared to when compound (i) at the same amount, and compound (ii) at the same amount, is applied alone, after 72 hours of applications.
- the mixture combination of active compounds of the invention comprising: (i) tau-fluvalinate; and (ii) at least one crop protection chemical compound II as defined above, is synergistically effective for controlling pests compared to when compound (i) at the same amount, and compound (ii) at the same amount, is applied alone, after 1 day of applications.
- the mixture combination of active compounds of the invention comprising: (i) tau-fluvalinate; and (ii) at least one crop protection chemical compound II as defined above, is synergistically effective for controlling pests compared to when compound (i) at the same amount, and compound (ii) at the same amount, is applied alone, after 2 days of applications.
- the mixture combination of active compounds of the invention comprising: (i) tau-fluvalinate; and (ii) at least one crop protection chemical compound II as defined above, is synergistically effective for controlling pests compared to when compound (i) at the same amount, and compound (ii) at the same amount, is applied alone, after 4 days of applications.
- the mixture combination of active compounds of the invention comprising: (i) tau-fluvalinate; and (ii) at least one crop protection chemical compound II as defined above, is synergistically effective for controlling pests compared to when compound (i) at the same amount, and compound (ii) at the same amount, is applied alone, after 7 days of applications.
- the synergistic composition may be applied in various mixtures or combinations of Tau-fluvalinate, and a crop protection chemical compound II, as defined above, for example in a single “ready-for-use” form, or in a combined spray mixture composed from separate formulations of the single active ingredients, such as a “tank-mix” form.
- the composition is applied in the form of a ready-for-use formulation comprising Tau-fluvalinate, and a crop protection chemical compound.
- This formulation can be obtained by combining the active ingredients in an effective amount with an agriculturally acceptable carrier, a surfactant or other application-promoting adjuvant customarily employed in formulation technology.
- the composition comprises at least one additional component selected from the group of surfactants, solid diluents and liquid diluents.
- additional component selected from the group of surfactants, solid diluents and liquid diluents.
- Such compositions can be formulated using agriculturally acceptable carriers, surfactants or other application-promoting adjuvants customarily employed in formulation technology and formulation techniques that are known in the art.
- liquid carriers potentially useful in the present compositions include but are not limited to water; aromatic hydrocarbons such as alkylbenzenes and alkylnaphthalenes; alcohols such as cyclohexanol, and decanol; ethylene glycol; polypropylene glycol; dipropropylene glycol; N,N-dimethylformamide; dimethylsulfoxide; dimethylacetamide; N- alkylpyrrolidones such as N-methyl-2-pyrrolidone; paraffins; various oils such as olive, castor, linseed, tung, sesame, com, peanut, cotton-seed, soybean, rape-seed, or coconut oil; fatty acid esters; ketones such as cyclohexanone, 2-heptanone, isophorone, and 4-hydroxy-4-methyl-2- pentanone; and the like.
- aromatic hydrocarbons such as alkylbenzenes and alkylnaphthalenes
- alcohols such as
- the present composition may be employed or prepared in any conventional form, for example, as wettable powders (WP), emulsion concentrates (EC), microemulsion concentrates (MEC), water-soluble powders (SP), water-soluble concentrates (SL), suspoemulsion (SE), oil dispersions (OD), concentrated emulsions (BW) such as oil-in-water and water-in-oil emulsions, sprayable solutions or emulsions, capsule suspensions (CS), suspension concentrates (SC), suspension concentrates, dusts (DP), oil-miscible solutions (OL), seed-dressing products, granules (GR) in the form of microgranules, spray granules, coated granules and absorption granules, granules for soil application or broadcasting, water-soluble granules (SG), water-dispersible granules (WDG), ULV formulations, microcapsules or waxes. These individual formulation types are known in the art.
- phosphate esters such as phosphate esters of alcohol alkoxylates, phosphate esters of alkylphenol alkoxylates and phosphate esters of styrylphenol ethoxylates, condensates of sulfonated naphthalene and naphthalene derivatives with formaldehyde, condensates of naphthalene or of naphthalenesulfonic acid with phenol and formaldehyde, alkylarylsulfonates, ethoxylated alkylphenols and aryl phenols, polyalkylene glycols, sorbitol esters, alkali metal, sodium salts of lignosulphonates, tristyrylphenol ethoxylate phosphate esters, aliphatic alcohol ethoxylates, alkylphenol ethoxylates, ethylene oxide/propylene oxide block copolymers, graft copolymers and
- Aqueous use forms can be prepared from emulsion concentrates, suspensions, pastes, wettable powders or water-dispersible granules by adding water.
- emulsions, pastes or oil dispersions the components of the compositions either as such or dissolved in an oil or solvent, can be homogenized in water by means of a wetting agent, tackifier, dispersant or emulsifier.
- concentrates comprising active ingredient, wetting agent, tackifier, dispersant or emulsifier and, if desired, a solvent or oil, which are suitable for dilution with water.
- the amount of the mixture of active ingredients in the composition is about 0.1-99 wt.
- the amount of the mixture of active ingredients in the composition is about 1-70 wt. %, based on the total weight of the composition. In yet another embodiment, the amount of the mixture of active ingredients in the composition is about 1-50 wt. %, based on the total weight of the composition. In yet another embodiment, the amount of the mixture of active ingredients in the composition is about 1-40 wt. %, based on the total weight of the composition. In yet another embodiment, the amount of the mixture of active ingredients in the composition is about 1-30 wt. %, based on the total weight of the composition.
- the amount of the mixture of active ingredients in the composition is about 1-20 wt. %, based on the total weight of the composition. In yet another embodiment, the amount of the mixture of active ingredients in the composition is about 1-10 wt. %, based on the total weight of the composition.
- the remaining components in the formulation are for example the carrier and additives.
- kits comprising a synergistic pesticidal composition as described herein, or components thereof.
- kits may comprise, in addition to the aforementioned active components, one or more additional active and/or inactive ingredients, either within the provided pesticidal composition or separately.
- compositions, kits and methods described herein exhibit a synergistic effect.
- a synergistic effect exists wherever the action of a combination of active components is greater than the sum of the action of each of the components alone. Therefore, a synergistically effective amount (or an effective amount of a synergistic composition or combination) is an amount that exhibits greater pesticidal activity than the sum of the activities of the individual components.
- the present invention provides a method for enhancing root system comprising applying an effective amount of the any one of the mixtures or the compositions disclosed herein to one or more plants, the locus thereof or propagation material thereof so as to thereby enhance the root system.
- the present invention provides a method for improving plant potential yield comprising applying an effective amount of the any one of the mixtures or the compositions disclosed herein to one or more plants, the locus thereof or propagation material thereof so as to thereby improve plant potential yield.
- the present invention provides a method for regulating plant growth comprising applying an effective amount of the any one of the mixtures or the compositions disclosed herein to one or more plants, the locus thereof or propagation material thereof so as to thereby regulate plant growth.
- the present invention provides a method for control of insects by contacting the insect or their food supply, habitat, breeding grounds or their locus with an effective amount of the any one of the mixtures or the compositions disclosed herein so as to thereby control insects.
- the present invention provides a method of protecting plants from attack or infestation by insects comprising contacting the plant, or the soil or water in which the plant is growing, with an effective amount of the any one of the mixtures or the compositions disclosed herein so as to thereby protecting plants from attack or infestation by insects.
- This present invention also provides a method for enhancing knock-down activity and/or prolonged control comprising contacting the plant, or the soil or water in which the plant is growing, with an effective amount of the mixture of Tau-fluvalinate and one or more active compounds II, as mentioned above or the composition thereof, so as to thereby enhance knockdown activity and/or prolonged control.
- this invention provides a method for controlling the insect comprising contacting the insect or their food supply, habitat, breeding grounds or their locus with an effective amount of the mixture combination of Tau-fluvalinate and one or more active compounds II, as mentioned above or the composition thereof, thereby controlling the said insect.
- this invention provides a method for controlling the insect comprising contacting the insect or their food supply, habitat, breeding grounds or their locus with an effective amount of the mixture combination of Tau-fluvalinate and one or more active compounds II, as mentioned above or the composition thereof, wherein the insect is selected from a group comprising Spidermites, Tetranychus urticae, Spodoptera littoralis, Spodoptera spp, Helicoverpa spp., Aphis spp., Myzus spp., Bemisia tabaci, Trialurodes vaporariorum, Tuta absoluta, Halyomorpha halys, Drosophila spp., Frankliniella spp., Aphis gossypii, Tetranichus spp. and Lygus spp.
- Spidermites Tetranychus urticae
- Spodoptera littoralis Spodoptera spp
- Helicoverpa spp. Aphis spp.
- this invention provides a method for controlling the insect, H. halys by contacting the insect or their food supply, habitat, breeding grounds or their locus with an effective amount of the mixture combination of Tau-fluvalinate and one or more active compounds II, as mentioned above or the composition thereof, in a weight ratio from 1 : 100 to 100: 1 , so as to thereby controlling the said insect.
- this invention provides a method for controlling the insect, H. halys by contacting the insect or their food supply, habitat, breeding grounds or their locus with an effective amount of mixture of Tau fluvalinate and lambda-cyhalothrin in a weight ratio from 1:100 to 100:1, so as to thereby controlling the said insect.
- this invention provides a method for controlling the insect, H. halys by contacting the insect or their food supply, habitat, breeding grounds or their locus with an effective amount of mixture of Tau fluvalinate and lambda-cyhalothrin in a weight ratio from 1:100 to 100:1, so as to thereby controlling the said insect.
- this invention provides a method for controlling the insect, H. halys by contacting the insect or their food supply, habitat, breeding grounds or their locus with an effective amount of mixture of Tau fluvalinate and an Inhibitor of mitochondrial ATP synthase in a weight ratio from 1:100 to 100:1, so as to thereby controlling the said insect.
- this invention provides a method for controlling the insect, H. halys by contacting the insect or their food supply, habitat, breeding grounds or their locus with an effective amount of mixture of Tau fluvalinate and Diafenthiuron in a weight ratio from 1:100 to 100:1, so as to thereby controlling the said insect.
- this invention provides a method for controlling the insect, H. halys by contacting the insect or their food supply, habitat, breeding grounds or their locus with an effective amount of mixture of Tau fluvalinate and Tolfenpyrad in a weight ratio from 1:100 to 100:1, so as to thereby controlling the said insect.
- this invention provides a method for controlling the insect, H. halys by contacting the insect or their food supply, habitat, breeding grounds or their locus with an effective amount of mixture of Tau fluvalinate and a Ryanodine receptor modulator in a weight ratio from 1:100 to 100:1, so as to thereby controlling the said insect.
- this invention provides a method for controlling the insect, H. halys by contacting the insect or their food supply, habitat, breeding grounds or their locus with an effective amount of mixture of Tau fluvalinate and Cyclaniliprole in a weight ratio from 1:100 to 100:1, so as to thereby controlling the said insect.
- this invention provides a method for controlling the insect, H. halys by contacting the insect or their food supply, habitat, breeding grounds or their locus with an effective amount of mixture of Tau fluvalinate and Novaluron in a weight ratio from 1:100 to 100:1, so as to thereby controlling the said insect.
- this invention provides a method for controlling the insect, S. littoralis by contacting the insect or their food supply, habitat, breeding grounds or their locus with an effective amount of the mixture combination of Tau-fluvalinate and one or more active compounds II, as mentioned above or the composition thereof, in a weight ratio from 1:100 to 100:1, so as to thereby controlling the said insect.
- this invention provides a method for controlling the insect, S. litoralis by contacting the insect or their food supply, habitat, breeding grounds or their locus with an effective amount of mixture of Tau fluvalinate and a Nicotinic acetylcholine receptor (nAChR) competitive modulator in a weight ratio from 1:100 to 100:1, so as to thereby controlling the said insect.
- nAChR Nicotinic acetylcholine receptor
- this invention provides a method for controlling the insect, S. litoralis by contacting the insect or their food supply, habitat, breeding grounds or their locus with an effective amount of mixture of Tau fluvalinate and Spinetoram in a weight ratio from 1:100 to 100:1, so as to thereby controlling the said insect.
- this invention provides a method for controlling the insect, S. litoralis by contacting the insect or their food supply, habitat, breeding grounds or their locus with an effective amount of mixture of Tau fluvalinate and an Inhibitor of chitin biosynthesis affecting CHS1 in a weight ratio from 1:100 to 100:1, so as to thereby controlling the said insect.
- this invention provides a method for controlling the insect, S. litoralis by contacting the insect or their food supply, habitat, breeding grounds or their locus with an effective amount of mixture of Tau fluvalinate and Novaluron in a weight ratio from 1:100 to 100:1, so as to thereby controlling the said insect.
- this invention provides a method for controlling the insect, S. littoralis by contacting the insect or their food supply, habitat, breeding grounds or their locus with an effective amount of mixture of Tau fluvalinate and an organochlorine insecticide in a weight ratio from 1:100 to 100:1, so as to thereby controlling the said insect.
- this invention provides a method for controlling the insect, S. litoralis by contacting the insect or their food supply, habitat, breeding grounds or their locus with an effective amount of mixture of Tau fluvalinate and Pyridalyl in a weight ratio from 1:100 to 100:1, so as to thereby controlling the said insect.
- this invention provides a method for controlling the insect, S. litoralis by contacting the insect or their food supply, habitat, breeding grounds or their locus with an effective amount of mixture of Tau fluvalinate and a Microbial disruptor of insect midgut membranes in a weight ratio from 1:100 to 100:1, so as to thereby controlling the said insect.
- this invention provides a method for controlling the insect, S. litoralis by contacting the insect or their food supply, habitat, breeding grounds or their locus with an effective amount of mixture of Tau fluvalinate and Bacillus thuringiensis toxin in a weight ratio from 1:100 to 100:1, so as to thereby controlling the said insect.
- this invention provides a method for controlling the insect, A. gossypii by contacting the insect or their food supply, habitat, breeding grounds or their locus with an effective amount of the mixture combination of Tau-fluvalinate and one or more active compounds II, as mentioned above or the composition thereof, in a weight ratio from 1:100 to 100:1, so as to thereby controlling the said insect.
- this invention provides a method for controlling the insect, A. gossypii by contacting the insect or their food supply, habitat, breeding grounds or their locus with an effective amount of mixture of Tau fluvalinate and a Chordotonal organ TRPV channel modulator in a weight ratio from 1: 100 to 100:1, so as to thereby controlling the said insect.
- this invention provides a method for controlling the insect, A. gossypii by contacting the insect or their food supply, habitat, breeding grounds or their locus with an effective amount of mixture of Tau fluvalinate and Afidopyropen in a weight ratio from 1:100 to 100:1, so as to thereby controlling the said insect.
- this invention provides a method for controlling the insect, A. gossypii by contacting the insect or their food supply, habitat, breeding grounds or their locus with an effective amount of mixture of Tau fluvalinate and a Mitochondrial complex electron transport inhibitor (METI) in a weight ratio from 1:100 to 100:1, so as to thereby controlling the said insect.
- this invention provides a method for controlling the insect, A. gossypii by contacting the insect or their food supply, habitat, breeding grounds or their locus with an effective amount of mixture of Tau fluvalinate and Tolfenpyrad in a weight ratio from 1:100 to 100:1, so as to thereby controlling the said insect.
- METI Mitochondrial complex electron transport inhibitor
- this invention provides a method for controlling the insect, A. gossypii by contacting the insect or their food supply, habitat, breeding grounds or their locus with an effective amount of mixture of Tau fluvalinate and a broad-spectrum insect growth regulator in a weight ratio from 1:100 to 100:1, so as to thereby controlling the said insect.
- this invention provides a method for controlling the insect, A. gossypii by contacting the insect or their food supply, habitat, breeding grounds or their locus with an effective amount of mixture of Tau fluvalinate and Pyriproxyfen in a weight ratio from 1:100 to 100:1, so as to thereby controlling the said insect.
- this invention provides a method for controlling the insect, A. gossypii by contacting the insect or their food supply, habitat, breeding grounds or their locus with an effective amount of mixture of Tau fluvalinate and an Inhibitor of chitin biosynthesis affecting CHS1 in a weight ratio from 1:100 to 100:1, so as to thereby controlling the said insect.
- this invention provides a method for controlling the insect, A. gossypii by contacting the insect or their food supply, habitat, breeding grounds or their locus with an effective amount of mixture of Tau fluvalinate and Novaluron in a weight ratio from 1:100 to 100:1, so as to thereby controlling the said insect.
- this invention provides a method for controlling the insect, A. gossypii by contacting the insect or their food supply, habitat, breeding grounds or their locus with an effective amount of mixture of Tau fluvalinate and a mesoionic insecticide in a weight ratio from 1:100 to 100:1, so as to thereby controlling the said insect.
- this invention provides a method for controlling the insect, A. gossypii by contacting the insect or their food supply, habitat, breeding grounds or their locus with an effective amount of mixture of Tau fluvalinate and Triflumezopyrim in a weight ratio from 1:100 to 100:1, so as to thereby controlling the said insect.
- this invention provides a method for controlling the insect, T.urticae by contacting the insect or their food supply, habitat, breeding grounds or their locus with an effective amount of the mixture combination of Tau-fluvalinate and one or more active compounds II, as mentioned above or the composition thereof, in a weight ratio from 1 : 100 to 100: 1 , so as to thereby controlling the said insect.
- this invention provides a method for controlling the insect, T.urticae by contacting the insect or their food supply, habitat, breeding grounds or their locus with an effective amount of mixture of Tau fluvalinate and a Mitochondrial complex electron transport inhibitor (METI) in a weight ratio from 1:100 to 100:1, so as to thereby controlling the said insect.
- METI Mitochondrial complex electron transport inhibitor
- this invention provides a method for controlling the insect, T.urticae by contacting the insect or their food supply, habitat, breeding grounds or their locus with an effective amount of mixture of Tau fluvalinate and Fenpyroximate in a weight ratio from 1:100 to 100:1, so as to thereby controlling the said insect.
- this invention provides a method for controlling the insect, T.urticae by contacting the insect or their food supply, habitat, breeding grounds or their locus with an effective amount of mixture of Tau fluvalinate and a Mite growth inhibitor affecting CHS 1 in a weight ratio from 1:100 to 100:1, so as to thereby controlling the said insect.
- this invention provides a method for controlling the insect, T.urticae by contacting the insect or their food supply, habitat, breeding grounds or their locus with an effective amount of mixture of Tau fluvalinate and Clofentezine in a weight ratio from 1:100 to 100:1, so as to thereby controlling the said insect.
- this invention provides a method for controlling the insect, T.urticae by contacting the insect or their food supply, habitat, breeding grounds or their locus with an effective amount of mixture of Tau fluvalinate and Diflovidazin in a weight ratio from 1:100 to 100:1, so as to thereby controlling the said insect.
- this invention provides a method for controlling the insect, T.urticae by contacting the insect or their food supply, habitat, breeding grounds or their locus with an effective amount of mixture of Tau fluvalinate and Hexythiazox in a weight ratio from 1:100 to 100:1, so as to thereby controlling the said insect.
- a mixture combination may be prepared by thoroughly mixing Tau-fluvalinate (weight %) with a crop protection chemical compound such as lambda-cyhalothrin, Acetamiprid, Spinetoram, Spinosad, Afidopyropen, Diafenthiuron, Bifenazate, Fenpyroximate, Tolfenpyrad, Clofentezine, Diflovidazin, Etoxazole, Hexythiazox, Cyclaniliprole, Pyriproxyfen, Novaluron, Pyridalyl, Bacillus thuringiensis toxin and Triflumezopyrim (weight %).
- a crop protection chemical compound such as lambda-cyhalothrin, Acetamiprid, Spinetoram, Spinosad, Afidopyropen, Diafenthiuron, Bifenazate, Fenpyroximate, Tolfenpyrad, Clofentezine, Diflovi
- synergistic effect exists whenever the action of a combination of active ingredients is greater than the sum of the action of each of the ingredients alone. Therefore, a synergistic combination is a combination of active ingredients having an action that is greater than the sum of the action of each active ingredient alone, and a synergistically effective amount is an effective amount of a synergistic combination.
- Colby s method is used to determine if synergy exists for a combination of active ingredients. According to Colby, the expected action (E) of active ingredients A+B is:
- the insecticidal compounds A Tau fluvalinate
- B mixture partner
- Efficacy of the insecticidal compositions is evaluated with reference to a scale of 0% to 100% in comparison with untreated control plots. 0 means no damage and 100 means complete destruction of the harmful pests.
- the experiments were conducted by applying commercially available formulations of Tau fluvalinate and other mixture partners, alone or with their tank-mixed compositions with the same weight ratio.
- the compositions were diluted with water or some other suitable solvents to the stated concentration of the active compounds.
- the active ingredients used in the experiments are having following formulation types and the concentrations:
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Dentistry (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Agronomy & Crop Science (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Description
Claims
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP22787013.6A EP4404749A1 (en) | 2021-09-25 | 2022-09-25 | Novel mixtures for crop protection |
MX2024003649A MX2024003649A (en) | 2021-09-25 | 2022-09-25 | Novel mixtures for crop protection. |
PE2024000537A PE20241402A1 (en) | 2021-09-25 | 2022-09-25 | NOVEL MIXTURES FOR CROP PROTECTION |
CA3232990A CA3232990A1 (en) | 2021-09-25 | 2022-09-25 | Novel mixtures for crop protection |
AU2022353246A AU2022353246A1 (en) | 2021-09-25 | 2022-09-25 | Novel mixtures for crop protection |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
IN202111043563 | 2021-09-25 | ||
IN202111043563 | 2021-09-25 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2023047406A1 true WO2023047406A1 (en) | 2023-03-30 |
Family
ID=83689981
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/IL2022/051023 WO2023047406A1 (en) | 2021-09-25 | 2022-09-25 | Novel mixtures for crop protection |
Country Status (8)
Country | Link |
---|---|
EP (1) | EP4404749A1 (en) |
AR (1) | AR127133A1 (en) |
AU (1) | AU2022353246A1 (en) |
CA (1) | CA3232990A1 (en) |
MX (1) | MX2024003649A (en) |
PE (1) | PE20241402A1 (en) |
TW (1) | TW202312872A (en) |
WO (1) | WO2023047406A1 (en) |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2015021991A1 (en) * | 2013-08-16 | 2015-02-19 | Cheminova A/S | Combination of 2-methylbiphenyl-3-ylmethyl (z)-(1r)-cis-3-(2-chloro-3,3,3-trifluoroprop-1-enyl)-2,2-dimethylcyclopropanecarboxylate with at least one insecticide, acaricide, nematicide and/or fungicide. |
WO2017176836A1 (en) * | 2016-04-06 | 2017-10-12 | Fmc Corporation | Compositions and methods for controlling fecundity of arachnida species |
-
2022
- 2022-09-23 AR ARP220102565A patent/AR127133A1/en unknown
- 2022-09-25 WO PCT/IL2022/051023 patent/WO2023047406A1/en active Application Filing
- 2022-09-25 EP EP22787013.6A patent/EP4404749A1/en active Pending
- 2022-09-25 MX MX2024003649A patent/MX2024003649A/en unknown
- 2022-09-25 PE PE2024000537A patent/PE20241402A1/en unknown
- 2022-09-25 AU AU2022353246A patent/AU2022353246A1/en active Pending
- 2022-09-25 CA CA3232990A patent/CA3232990A1/en active Pending
- 2022-09-26 TW TW111136379A patent/TW202312872A/en unknown
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2015021991A1 (en) * | 2013-08-16 | 2015-02-19 | Cheminova A/S | Combination of 2-methylbiphenyl-3-ylmethyl (z)-(1r)-cis-3-(2-chloro-3,3,3-trifluoroprop-1-enyl)-2,2-dimethylcyclopropanecarboxylate with at least one insecticide, acaricide, nematicide and/or fungicide. |
WO2017176836A1 (en) * | 2016-04-06 | 2017-10-12 | Fmc Corporation | Compositions and methods for controlling fecundity of arachnida species |
Non-Patent Citations (4)
Title |
---|
"The E-Pesticide Manual", 2010 |
BRANDES MEIKE ET AL: "Effects of thiacloprid, tau-fluvalinate and lambda-cyhalothrin on overwintered pollen beetles (Brassicogethes aeneus(Fabricius)) and their offspring in oilseed rape", ARTHROPOD-PLANT INTERACTIONS, SPRINGER NETHERLANDS, DORDRECHT, vol. 12, no. 6, 2 July 2018 (2018-07-02), pages 823 - 833, XP036637098, ISSN: 1872-8855, [retrieved on 20180702], DOI: 10.1007/S11829-018-9621-1 * |
COLBY, S. R.: "Calculating synergistic and antagonistic responses of herbicide combination", WEEDS, vol. 15, 1967, pages 20 - 22, XP001112961 |
LIMPEL ET AL., PROC. NEWCC, vol. 16, 1962, pages 48 - 53 |
Also Published As
Publication number | Publication date |
---|---|
TW202312872A (en) | 2023-04-01 |
AR127133A1 (en) | 2023-12-20 |
PE20241402A1 (en) | 2024-07-11 |
CA3232990A1 (en) | 2023-03-30 |
MX2024003649A (en) | 2024-04-15 |
EP4404749A1 (en) | 2024-07-31 |
AU2022353246A1 (en) | 2024-04-11 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
KR101846595B1 (en) | Synergistic insecticidal mixtures containing a pyrethroid, a neonicotinoid and a benzoylphenylurez insecticide | |
AU2022247410A1 (en) | Pesticidal mixtures | |
WO2024069632A2 (en) | Novaluron mixtures for efficient insecticidal controls | |
US20230053477A1 (en) | Insecticidal Mixtures | |
WO2020075167A1 (en) | Ternary insecticidal mixture | |
US9872497B2 (en) | Pest control mixture | |
WO2023281511A1 (en) | Insecticidal mixtures | |
AU2012232689B2 (en) | Synergistic agricultural pest control | |
US10687534B2 (en) | Method to control adult insect population | |
WO2023047406A1 (en) | Novel mixtures for crop protection | |
WO2024157264A1 (en) | Plant health / plant vigor improving mixture of insecticides | |
WO2024032778A1 (en) | Liquid pesticidal composition | |
WO2023205870A1 (en) | Insecticide composition and method for insect control | |
WO2022106838A1 (en) | Insecticide composition and method for insect control |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
121 | Ep: the epo has been informed by wipo that ep was designated in this application |
Ref document number: 22787013 Country of ref document: EP Kind code of ref document: A1 |
|
WWE | Wipo information: entry into national phase |
Ref document number: 2022353246 Country of ref document: AU Ref document number: 809403 Country of ref document: NZ Ref document number: AU2022353246 Country of ref document: AU |
|
WWE | Wipo information: entry into national phase |
Ref document number: 3232990 Country of ref document: CA |
|
REG | Reference to national code |
Ref country code: BR Ref legal event code: B01A Ref document number: 112024005880 Country of ref document: BR |
|
ENP | Entry into the national phase |
Ref document number: 2022353246 Country of ref document: AU Date of ref document: 20220925 Kind code of ref document: A |
|
WWE | Wipo information: entry into national phase |
Ref document number: 202490820 Country of ref document: EA |
|
WWE | Wipo information: entry into national phase |
Ref document number: 2022787013 Country of ref document: EP |
|
NENP | Non-entry into the national phase |
Ref country code: DE |
|
ENP | Entry into the national phase |
Ref document number: 2022787013 Country of ref document: EP Effective date: 20240425 |
|
REG | Reference to national code |
Ref country code: BR Ref legal event code: B01E Ref document number: 112024005880 Country of ref document: BR Free format text: APRESENTE DOCUMENTO DE CESSAO ESPECIFICO PARA A PRIORIDADE IN 202111043563 DE 25.09.2021 UMA VEZ QUE O DOCUMENTO ENVIADO NA PETICAO NO 870240044234 DE 24/05/2024 NAO POSSUI A ASSINATURA DO TITULAR ADAMA AGAN LTD.. A CESSAO DEVE CONTER A ASSINATURA DE TODOS OS TITULARES, CONFORME DISPOSTO NO ART. 19 3O DA PORTARIA/INPI/NO 39/2021. A EXIGENCIA DEVE SER RESPONDIDA EM ATE 60 (SESSENTA) DIAS DE SUA PUBLICACAO E DEVE SER REALIZADA POR MEIO DA PETICAO GRU CODIGO DE SERVICO 207. |