WO2023024869A1 - Semiconductor surface planarization method, manufactured semiconductor and use - Google Patents

Semiconductor surface planarization method, manufactured semiconductor and use Download PDF

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Publication number
WO2023024869A1
WO2023024869A1 PCT/CN2022/110438 CN2022110438W WO2023024869A1 WO 2023024869 A1 WO2023024869 A1 WO 2023024869A1 CN 2022110438 W CN2022110438 W CN 2022110438W WO 2023024869 A1 WO2023024869 A1 WO 2023024869A1
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dielectric layer
thickness
semiconductor
nth
stage
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PCT/CN2022/110438
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French (fr)
Chinese (zh)
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黄清波
周雪梅
翁杰
潘代强
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上海芯物科技有限公司
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/70Manufacture or treatment of devices consisting of a plurality of solid state components formed in or on a common substrate or of parts thereof; Manufacture of integrated circuit devices or of parts thereof
    • H01L21/71Manufacture of specific parts of devices defined in group H01L21/70
    • H01L21/768Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics
    • H01L21/76801Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics characterised by the formation and the after-treatment of the dielectrics, e.g. smoothing
    • H01L21/76819Smoothing of the dielectric
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/04Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
    • H01L21/18Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
    • H01L21/30Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26
    • H01L21/31Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26 to form insulating layers thereon, e.g. for masking or by using photolithographic techniques; After treatment of these layers; Selection of materials for these layers
    • H01L21/3105After-treatment
    • H01L21/31051Planarisation of the insulating layers
    • H01L21/31053Planarisation of the insulating layers involving a dielectric removal step
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L23/00Details of semiconductor or other solid state devices
    • H01L23/52Arrangements for conducting electric current within the device in operation from one component to another, i.e. interconnections, e.g. wires, lead frames
    • H01L23/522Arrangements for conducting electric current within the device in operation from one component to another, i.e. interconnections, e.g. wires, lead frames including external interconnections consisting of a multilayer structure of conductive and insulating layers inseparably formed on the semiconductor body

Definitions

  • the embodiments of the present application relate to the technical field of semiconductor manufacturing, for example, a method for flattening the surface of a semiconductor, and the manufactured semiconductor and its application.
  • the chemical mechanical polishing of Cu is mainly used for the planarization of the copper surface of Damascus metal in the back section.
  • Metal copper chemical mechanical polishing is mainly carried out through three grinding discs.
  • the first grinding disc removes copper under high pressure and removes most of the copper above the groove; the second grinding disc removes the remaining metal copper above the groove with relatively small pressure ;
  • the third grinding disc thins the groove and the oxide layer beside it to the thickness required by the process.
  • the existing technology usually continues grinding when the second grinding disc detects the grinding end point to ensure that the remaining metallic copper above the groove is completely removed. After the grinding end point is detected, there is generally a period of over-polishing process to ensure that the metallic copper above the groove is removed. clean. In the process of over-throwing, a butterfly structure with copper depressions will be formed, and the longer the over-throwing time, the greater the depth of the butterfly.
  • the uneven surface of the silicon wafer with severe dishing will cause a series of problems, the most serious of which is the inability to perform patterning on the surface of the silicon wafer, which will lead to the stability of the subsequent process Reduced, affecting the process window for chemical mechanical polishing of copper metal in multilayer interconnect structures.
  • the dishing produced by excessive grinding during chemical mechanical polishing of copper can also lead to excessive resistance of copper interconnection lines, resulting in slower processing of semiconductor devices, and even the loss of copper due to excessive heat generation.
  • the interconnection line is blown, whereby the disconnection of the semiconductor device occurs.
  • CN108682650A discloses a surface planarization method and a semiconductor multilayer interconnection structure.
  • the method includes: a first chemical mechanical polishing process, which is to chemically mechanically polish the metal deposited in the deep hole in the semiconductor multilayer interconnection structure; the second medium A layer forming process, forming a second dielectric layer on the surface of the barrier layer in the semiconductor multilayer interconnection structure; and a second chemical mechanical polishing process, performing chemical mechanical polishing on the second dielectric layer and the barrier layer.
  • this method adds a second dielectric layer forming process and a chemical mechanical polishing process, and the cost is high.
  • the methods such as CN1855417A and CN1855420A also have the problems of high cost and complicated process.
  • the embodiment of the present application provides a method for planarizing the surface of a semiconductor and the semiconductor and its use.
  • the method only adds a planarization process without changing the original deposition process.
  • the process solves the superposition problem of the butterfly-shaped depressions in the multilayer interconnection structure, and improves the performance of the semiconductor with the multilayer interconnection structure.
  • an embodiment of the present application provides a method for planarizing a semiconductor surface, the method comprising:
  • the nth section of the initial dielectric layer is first planarized in the thickness direction to obtain the nth section of the dielectric layer, Then proceed to the follow-up process;
  • the thickness of the nth section of the initial dielectric layer is greater than the thickness of the nth section of the dielectric layer, n ⁇ 2.
  • the method described in this application makes the thickness of the nth initial dielectric layer thicker than that of the prior art when covering the nth initial dielectric layer, and then adds a planarization treatment step to make the processed nth initial dielectric layer
  • the initial dielectric layer no longer has butterfly-shaped depressions, but is a flat surface, thereby solving the superposition problem of butterfly-shaped depressions on the semiconductor surface in the multilayer interconnection structure.
  • n mentioned in this application is a natural number ⁇ 2, for example, it can be 2, 3, 4, 5 or 6, etc., and can be adjusted according to the actual process, as long as it is a manufacturing process superimposed on the basis of the first stage of manufacturing process That's it.
  • the planarization method includes a chemical mechanical polishing method.
  • the thickness of the n-th initial dielectric layer is greater than the thickness of the first-stage dielectric layer in the first-stage manufacturing process. Due to the planarization treatment step, one layer thickness is removed in the thickness direction, and at the same time, the portion with the recess in the nth segment of the initial dielectric layer is removed to obtain a flat surface of the nth segment of the dielectric layer.
  • the thickness of the nth dielectric layer is equal to the thickness of the first dielectric layer in the first manufacturing process.
  • the dielectric layers of each layer of the semiconductor of the multilayer interconnection structure are set to be the same, so the thickness of the nth dielectric layer is preferred to be the same as that of the first dielectric layer in this application, but each segment can also be set according to the actual situation.
  • the thickness of the dielectric layer as long as the thickness of the final nth dielectric layer is combined with the expected design thickness.
  • the surface of the nth initial dielectric layer contains butterfly-shaped depressions. Since the surface topography of the dielectric layer in the first stage or the dielectric layer in the previous stage has a butterfly-shaped depression, this butterfly-shaped depression is due to the grinding of the metal in the first-stage manufacturing process or the first-stage manufacturing process, in order to ensure complete removal
  • the remaining metal above the groove generally requires over-throwing to ensure that the metal above the groove is removed, and the metal inside the groove will be removed during the over-throwing process, resulting in the formation of butterfly-shaped depressions.
  • the surface of the nth initial dielectric layer contains a butterfly-shaped depression.
  • the thickness of the n-th initial dielectric layer is greater than the thickness of the n-th dielectric layer by a value greater than the depth of the butterfly-shaped depression.
  • the application preferably has the thickness of the nth segment of the initial dielectric layer greater than the thickness of the nth segment of the dielectric layer. The value is greater than the depth value of the butterfly-shaped depression, so as to reserve sufficient operating thickness for planarization.
  • the thickness of the nth initial dielectric layer is 2000-3000A thicker than that of the nth dielectric layer, such as 2000A, 2100A, 2200A, 2300A, 2400A, 2500A, 2600A, 2800A or 3000A.
  • the present application can also adjust appropriately the difference between the thickness of the nth section of the initial dielectric layer and the thickness of the nth section of dielectric layer according to the actual process design; The thickness is generally considered to be around 2000A.
  • the present application generally does not make special restrictions on the subsequent process, and the subsequent manufacturing process well-known to those skilled in the art can be used, and can also be adjusted according to the actual process situation, but further preferably, in the n-th stage of manufacturing process, the Subsequent processes sequentially include capping the etch barrier layer, photolithography, etching, capping the barrier layer, capping the metal layer, and polishing.
  • said polishing comprises chemical mechanical polishing.
  • the covering metal layer includes photolithography, etching and deposition performed in sequence.
  • the manufacturing process includes a damascene manufacturing process.
  • the present application has no special restrictions on other process parameters in the Damascus manufacturing process, and any process parameters known to those skilled in the art that can be used in the Damascus manufacturing process can be used, and can also be adjusted according to the actual process.
  • the metal layer comprises a copper layer.
  • the present application has no special restrictions on the material and thickness of the dielectric layer, and any material and thickness known to those skilled in the art that can be used in semiconductor dielectric layers can be used, for example, oxides and/or nitrides can be included, for example, it can be Silicon nitride or silicon oxide, etc., may have a thickness of 2500 ⁇ , for example.
  • the present application has no special restrictions on the material and thickness of the barrier layer, and any material and thickness known to those skilled in the art that can be used for barrier layers in semiconductors can be used, for example, it can include oxide and/or nitride, for example, it can be positive Silicon oxide prepared from tetraethyl silicate (TEOS), etc., may have a thickness of 400 ⁇ , for example.
  • TEOS tetraethyl silicate
  • the method includes the following steps:
  • the nth section of the initial dielectric layer is first planarized in the thickness direction to obtain the nth section of the dielectric layer ;
  • the thickness of the nth segment of the initial dielectric layer is greater than the thickness of the nth segment of the dielectric layer, n ⁇ 2;
  • an embodiment of the present application provides a semiconductor, which is manufactured according to the method for flattening a semiconductor surface described in the first aspect.
  • the semiconductor described in the present application has small bow-shaped depressions and low resistance of metal interconnection lines, the processing speed of the finally formed semiconductor device is fast, and the disconnection phenomenon of the semiconductor device can be reduced.
  • the semiconductor has at least two layers of interconnection structures.
  • the at least two-layer interconnection structure in this application refers to at least two repeated vertically stacked semiconductor structural units.
  • the semiconductor structure of the first stage from bottom to top in the semiconductor includes a dielectric layer, the surface of the dielectric layer is provided with a first barrier layer, and the dielectric layer and the first barrier layer are provided with grooves at corresponding positions, so The groove of the first barrier layer penetrates from the surface of the first barrier layer into the dielectric layer, the dielectric layer and the first barrier layer correspond to metal deposited in the groove, and the surface of the metal in the groove contains butterfly-shaped depressions.
  • the semiconductor structure of the other stage is preferably the same as the semiconductor structure of the first stage.
  • the semiconductor is a wafer.
  • the degree of butterfly dishing of the wafer is significantly reduced.
  • the embodiment of the present application provides an application of the semiconductor described in the first aspect in an integrated circuit.
  • the semiconductor described in the present application has excellent processing speed and low resistance due to the small butterfly depression, and can be used in integrated circuits to greatly increase the operating efficiency of integrated circuits.
  • the semiconductor surface planarization method provided by the embodiment of the present application overcomes the influence of the butterfly-shaped depressions produced by the front-end manufacturing process in the at least two-layer interconnection structure, which is superimposed on the back-end process, and only needs to increase the thickness of the dielectric layer in the original step
  • the thinning step can effectively control the size of the butterfly, and the difference between the depth of the butterfly depression of the nth semiconductor structure and the depth of the butterfly depression of the first semiconductor structure is ⁇ 70A, and under optimal conditions ⁇ 20A, It can even reach ⁇ 2A or the depth of the butterfly-shaped recess of the n-th semiconductor structure is smaller than that of the first-stage semiconductor structure, and the preparation process is simple and the cost is low;
  • the semiconductor provided by the embodiment of the present application has a small butterfly-shaped depression and low resistance of the metal interconnection line, so the processing speed of the final semiconductor device is fast, and the disconnection phenomenon of the semiconductor device can be reduced, so it can be better applied to integrated circuits. in the circuit.
  • FIG. 1 is a schematic flowchart of a method for planarizing a semiconductor surface provided by the present application.
  • FIG. 2 is a schematic flowchart of a method for preparing a semiconductor provided in Comparative Example 1.
  • a method for planarizing the surface of a semiconductor is provided. Taking the two-stage Damascene process as an example, as shown in Figure 1, the method includes the following steps:
  • the first section of semiconductor structure 1 includes a dielectric layer, the surface of the dielectric layer is provided with a first barrier layer, the dielectric layer and the first section of semiconductor structure 1
  • a barrier layer is provided with a groove at a corresponding position, and the groove of the first barrier layer penetrates from the surface of the first barrier layer into the dielectric layer, and metal copper is deposited in the dielectric layer, and the metal copper in the groove is The surface contains butterfly-shaped depressions;
  • step (2) After the surface of the first stage semiconductor structure 1 described in step (1) is covered with the second initial dielectric layer 21, a semiconductor structure covered with the second initial dielectric layer 21 is obtained, as shown in a in FIG. 1, at this time The butterfly-shaped depression 22 on the surface of the second initial dielectric layer can be seen;
  • the second initial dielectric layer 21 is first planarized in the thickness direction to obtain a second dielectric layer 23, as shown in b in Figure 1; the thickness of the second initial dielectric layer 21 is greater than that of the second dielectric layer 23 thickness;
  • the butterfly-shaped depression of the semiconductor structure 1 in the first stage has not been transferred to the second stage , to obtain the second section of semiconductor structure;
  • the second section of semiconductor structure after molding includes a second dielectric layer 23, the surface of the dielectric layer 23 is provided with grooves, and metal copper is deposited in the corresponding grooves of the dielectric layer 23 25.
  • the surface of the metal copper 25 in the groove contains a butterfly-shaped depression 26 on the surface of the metal copper to obtain a designed double-layer Damascus metal copper wafer.
  • the depth of the groove is not particularly limited, and can be adjusted according to the actual process, for example, it can be 200A.
  • the thicknesses of the dielectric layer, the etch barrier layer, the first barrier layer, and the second barrier layer are not particularly limited, and can be adjusted according to the actual process.
  • the thickness of the dielectric layer can be 2500 ⁇ , etc.
  • the first barrier layer and the second barrier layer The thickness of the layer may be 400A and so on.
  • This embodiment provides a method for flattening a semiconductor surface, the method comprising the following steps:
  • the first paragraph of damascene manufacturing process specifically includes: performing chemical vapor deposition of 400A of etching barrier layer (silicon oxide) on the surface of dielectric layer (silicon oxide), and then performing photolithography in sequence , etching and copper deposition (electroplating, the process parameter is 7000A), and then perform three chemical mechanical polishing, the first chemical mechanical polishing is ground with high pressure ⁇ 2psi to remove most of the copper above the trench; the second chemical mechanical polishing is used Relatively small pressure ⁇ 1.2psi removes the remaining metal copper above the trench; the third chemical mechanical polishing thins the trench and the silicon oxide next to it to a thickness of ⁇ 1000A required by the process, and deposits the first barrier layer.
  • the first barrier layer is a silicon carbide layer used to prevent metal from diffusing into the dielectric layer, with a thickness of 200 ⁇ , to obtain the first-stage semiconductor structure 1; a first barrier layer is provided on the surface of the dielectric layer, and the dielectric layer and the first The barrier layer is provided with grooves at corresponding positions, and the groove of the first barrier layer penetrates from the surface of the first barrier layer into the dielectric layer, and metal copper is deposited in the dielectric layer, and the surface of the metal copper in the groove is Contains butterfly-shaped depressions;
  • the second initial dielectric layer 21 is covered on the surface of the second semiconductor structure in step (1), the second initial dielectric layer 21 is first subjected to a planarization process in the thickness direction, and the planarization process is chemical mechanical polishing treatment, the pressure is ⁇ 2.0psi, and the time is ⁇ 30s to obtain the second dielectric layer 23; the thickness of the second initial dielectric layer 21 is 2500A thicker than the thickness of the second dielectric layer 23;
  • etching barrier layer 24 (silicon oxide, 400A) on the surface of the second dielectric layer 23, through photolithography, etching, depositing the second barrier layer and covering metal copper 25 and chemical mechanical polishing three times, wherein the The second barrier layer is a tantalum nitride layer used to prevent the metal from diffusing into the dielectric layer, with a thickness of 100 ⁇ .
  • the three chemical mechanical polishing and deposition steps are carried out with reference to step (1) to obtain the second segment of the semiconductor structure, and the designed double layer damascus metal copper wafer.
  • This embodiment provides a method for flattening a semiconductor surface, the method comprising the following steps:
  • the first chemical mechanical polishing is performed under high pressure ⁇ 2.5psi grinding to remove most of the copper above the trench; the second The first chemical mechanical polishing uses a relatively small pressure ⁇ 1.4psi to remove the remaining metal copper above the trench; the third chemical mechanical polishing thins the trench and the oxide layer next to it to the thickness required by the process ⁇ 1600A, and deposits the first
  • the barrier layer that is, silicon carbide, has a thickness of 150 ⁇ , and the first semiconductor structure 1 is obtained;
  • the first semiconductor structure 1 includes a dielectric layer, and a first barrier layer is provided on the surface of the dielectric layer, and the dielectric layer and the first semiconductor structure
  • a barrier layer is provided with a groove at a corresponding position, and the groove of the first barrier layer penetrates from the surface of the first barrier layer into the dielectric layer, and metal copper is deposited in the dielectric layer, and the metal copper in the groove is
  • the surface contains butterfly-shaped depressions;
  • the second initial dielectric layer 21 is covered on the surface of the second semiconductor structure in step (1), the second initial dielectric layer 21 is first subjected to a planarization process in the thickness direction, and the planarization process is chemical mechanical polishing treatment, the pressure is ⁇ 2.5psi, the time is ⁇ 30s, to obtain the second dielectric layer 23; the thickness of the second initial dielectric layer 21 is 2000A thicker than the thickness of the second dielectric layer 23;
  • etching barrier layer 24 (500A) on the surface of the second dielectric layer 23, and sequentially undergo photolithography, etching, depositing the second barrier layer and covering the metal copper layer and chemical mechanical polishing three times, wherein the first
  • the second barrier layer is a tantalum nitride layer used to prevent the metal from diffusing into the dielectric layer, with a thickness of 120A.
  • the three chemical mechanical polishing and deposition steps are carried out with reference to step (1) to obtain the second semiconductor structure and the designed double layer Damascus metal copper wafer.
  • This embodiment provides a method for flattening a semiconductor surface, the method comprising the following steps:
  • Carry out the first paragraph of damascene manufacturing process and the first paragraph of damascene manufacturing process specifically includes: depositing (chemical vapor deposition, process parameter is 600A) etching barrier layer (silicon oxide) on the surface of dielectric layer (silicon oxide) and Etch the deep hole, then perform photolithography, etching and copper deposition (electroplating, process parameter is 8000A) in sequence, and then perform three chemical mechanical polishing.
  • the first chemical mechanical polishing is performed under high pressure ⁇ 1.8psi grinding to remove most of the top of the groove Copper; the second chemical mechanical polishing uses a relatively small pressure ⁇ 1.5psi to remove the remaining metallic copper above the trench; the third chemical mechanical polishing thins the trench and the oxide layer next to it to the thickness required by the process ⁇ 1200A , to obtain the first semiconductor structure 1;
  • the first semiconductor structure 1 includes a dielectric layer, the surface of the dielectric layer is provided with a first barrier layer, and the dielectric layer and the first barrier layer are provided with grooves at corresponding positions , the groove of the first barrier layer penetrates from the surface of the first barrier layer into the dielectric layer, metal copper is deposited in the dielectric layer, and the surface of the metal copper in the groove contains butterfly-shaped depressions;
  • the second initial dielectric layer 21 is covered on the surface of the second semiconductor structure in step (1), the second initial dielectric layer 21 is first subjected to a planarization process in the thickness direction, and the planarization process is Chemical mechanical polishing treatment, the pressure is ⁇ 2.1psi, the time is ⁇ 35s, to obtain the second dielectric layer 23; the thickness of the second initial dielectric layer 21 is 3000A thicker than the thickness of the second dielectric layer 23;
  • Steps (2) to (3) are repeated to construct the third semiconductor structure on the second semiconductor structure to obtain a designed three-layer damascene copper wafer.
  • This embodiment provides a method for flattening the surface of a semiconductor.
  • the method is the same as that of Embodiment 1 except that the thickness of the second initial dielectric layer 21 is 6000 ⁇ thicker than that of the second dielectric layer 23 .
  • the cost of the present embodiment is increased due to the thicker thickness of the initially deposited dielectric layer.
  • This embodiment provides a method for flattening the surface of a semiconductor.
  • the method is the same as that of Embodiment 1 except that the thickness of the second initial dielectric layer 21 is 200 ⁇ thicker than that of the second dielectric layer 23 .
  • the surface of the second dielectric layer 23 still has a small butterfly-shaped depression after the planarization treatment.
  • This comparative example provides a method for semiconductor preparation, as shown in Figure 2, except that the thickness of the second initial dielectric layer 21 covered in step (2) is directly the same as the thickness of the second dielectric layer 23 in Example 1 , the preparation process parameter in step (1) ⁇ (3) is all identical with embodiment 1, specifically comprises the following steps:
  • the first paragraph of damascene manufacturing process specifically includes: performing chemical vapor deposition of 400A of etching barrier layer (silicon oxide) on the surface of dielectric layer (silicon oxide), and then performing photolithography in sequence , etching and copper deposition (electroplating, the process parameter is 7000A), and then perform three chemical mechanical polishing, the first chemical mechanical polishing is ground with high pressure ⁇ 2psi to remove most of the copper above the trench; the second chemical mechanical polishing is used Relatively small pressure ⁇ 1.2psi removes the remaining metal copper above the trench; the third chemical mechanical polishing thins the trench and the silicon oxide next to it to a thickness of ⁇ 1000A required by the process, and deposits the first barrier layer.
  • the first barrier layer is a silicon carbide layer used to prevent metal from diffusing into the dielectric layer, with a thickness of 200 ⁇ , to obtain the first-stage semiconductor structure 1; a first barrier layer is provided on the surface of the dielectric layer, and the dielectric layer and the first The barrier layer is provided with grooves at corresponding positions, and the groove of the first barrier layer penetrates from the surface of the first barrier layer into the dielectric layer, and metal copper is deposited in the dielectric layer, and the surface of the metal copper in the groove is Contains butterfly-shaped depressions;
  • the etching barrier layer 24 (silicon oxide, 400A) on the surface of the second dielectric layer 23 in sequence, and sequentially undergoing photolithography, etching, depositing the second barrier layer, covering metal copper 25 and chemical mechanical polishing three times,
  • the second barrier layer is a tantalum nitride layer used to prevent the metal from diffusing to the dielectric layer, with a thickness of 100 ⁇ .
  • the butterfly-shaped depression of the first segment of the semiconductor structure 1 continues to be transmitted to the second segment to obtain the second segment of the semiconductor structure;
  • the second segment of the semiconductor structure after molding includes The second dielectric layer 23, the dielectric layer 23 is provided with a groove, the groove deposited on the dielectric layer 23 has metal copper 25, and the surface of the metal copper 25 in the groove contains a butterfly-shaped depression 26 on the surface of the metal copper , the designed double-layer damascene metal copper wafer is obtained, but the butterfly-shaped depression of the second-stage semiconductor structure in the wafer is significantly increased compared with the butterfly-shaped depression of the first-stage semiconductor structure 1.
  • the method described in the present application is also applicable to the semiconductor manufacturing of other multi-segment semiconductor structures, and will not be repeated here for the sake of space.
  • Test method AFM (atomic force microscope) was used to measure the depth of the butterfly-shaped depressions in the wafers prepared in the above examples and comparative examples, and the results are shown in Table 1.
  • the method for flattening the semiconductor surface provided by the present application can effectively organize the depth value of the butterfly-shaped depression in the semiconductor structure of the first stage in the semiconductor structure manufacturing process of at least two stages.
  • the second-stage semiconductor structure or the third-stage semiconductor structure transformation that is, the difference between the butterfly-shaped depression depth of the semiconductor structure larger than the first stage and the butterfly-shaped depression depth of the first-stage semiconductor structure is ⁇ 20A;
  • Example 2 the thickness of the second initial dielectric layer in Example 1 is 2500 ⁇ thicker than that of the second dielectric layer, compared with Example 4 and Example 5
  • the butterfly-shaped depression of the second stage semiconductor structure in Example 1 is only 220A, which is 15A larger than that of the first stage , while in Example 4, although it is only increased by 2A compared with the first section, the thickness of the dielectric layer is increased too much, and the cost increases significantly.
  • the second section is increased by 70A compared with the first section, and the butterfly-shaped depression has a certain degree of transmission. This shows that the present application can reduce the transfer of butterfly-shaped depressions while controlling the cost by controlling the thickness of the nth initial dielectric layer to be thicker than that of the nth dielectric layer within a specific range;
  • Example 1 Combining Example 1 and Comparative Example 1, it can be seen that in Comparative Example 1, only the thickness of the final second dielectric layer is deposited directly during deposition, and the butterfly-shaped depression of the final second section of the semiconductor structure is as high as 295 ⁇ , which is higher than that of the first section.
  • the butterfly-shaped depression of the semiconductor structure is 100A high, which is much higher than 15A in Example 1. This shows that the present application significantly reduces the butterfly-shaped depression by increasing the thickness of the dielectric layer during initial deposition and adding a step of chemical mechanical polishing. Transfer between several segments of semiconductor structures.
  • the semiconductor surface planarization method provided by this application overcomes the influence of superposition of butterfly-shaped depressions produced by the front-end manufacturing process in the back-end process in at least two-layer interconnection structures, so that the size of the butterfly is effectively controlled and the cost is reduced. Low, suitable for industrial promotion.

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Abstract

Disclosed is a semiconductor surface planarization method, the method comprising: in the nth stage manufacturing process of a semiconductor structure having at least two interconnected layers, laying down an initial nth-stage dielectric layer, the nth-stage initial dielectric layer first undergoing planarization in a thickness direction, and obtaining an nth-stage dielectric layer, and then performing a subsequent process; the thickness of the nth-stage initial dielectric layer is greater than the thickness of the nth-stage dielectric layer, and n ≥ 2. In a semiconductor structure having at least two interconnected layers, the method overcomes the impact on additional later-stage processes of a butterfly recess generated in an early-stage manufacturing process, allowing for effectively controlling the size of the butterfly shape.

Description

一种半导体表面平坦化的方法及制得的半导体和用途A method for flattening the surface of a semiconductor, the prepared semiconductor and its use 技术领域technical field
本申请实施例涉及半导体制造技术领域,例如一种半导体表面平坦化的方法及制得的半导体和用途。The embodiments of the present application relate to the technical field of semiconductor manufacturing, for example, a method for flattening the surface of a semiconductor, and the manufactured semiconductor and its application.
背景技术Background technique
在半导体制造工艺中,Cu的化学机械抛光主要是用于后段大马士革金属铜表面的平坦化。In the semiconductor manufacturing process, the chemical mechanical polishing of Cu is mainly used for the planarization of the copper surface of Damascus metal in the back section.
金属铜化学机械研磨主要通过三个研磨盘进行,第一研磨盘进行大压力铜的去除,去除沟槽上方大部分的铜;第二研磨盘用相对小的压力去除沟槽上方剩余的金属铜;第三研磨盘对沟槽和旁边的氧化层进行减薄到工艺需求的厚度。Metal copper chemical mechanical polishing is mainly carried out through three grinding discs. The first grinding disc removes copper under high pressure and removes most of the copper above the groove; the second grinding disc removes the remaining metal copper above the groove with relatively small pressure ; The third grinding disc thins the groove and the oxide layer beside it to the thickness required by the process.
现有技术通常在第二研磨盘探测到研磨终点时仍然继续研磨,以确保完全去除沟槽上方剩余的金属铜,探测到研磨终点后一般会有一段过抛过程来确保沟槽上方金属铜去除干净。而在过抛过程中会形成具有铜凹陷的蝶形结构,而过抛时间越长蝶形深度越大。The existing technology usually continues grinding when the second grinding disc detects the grinding end point to ensure that the remaining metallic copper above the groove is completely removed. After the grinding end point is detected, there is generally a period of over-polishing process to ensure that the metallic copper above the groove is removed. clean. In the process of over-throwing, a butterfly structure with copper depressions will be formed, and the longer the over-throwing time, the greater the depth of the butterfly.
在半导体多层互连结构中,具有严重的碟形凹陷的不平坦的硅片表面将会产生一系列问题,其中最为严重的就是无法在硅片表面进行图形制作,从而导致后续制程的稳定性降低,影响多层互连结构中金属铜化学机械抛光的工艺窗口。In the semiconductor multilayer interconnection structure, the uneven surface of the silicon wafer with severe dishing will cause a series of problems, the most serious of which is the inability to perform patterning on the surface of the silicon wafer, which will lead to the stability of the subsequent process Reduced, affecting the process window for chemical mechanical polishing of copper metal in multilayer interconnect structures.
另一方面,对铜进行化学机械抛光时进行的过度研磨所产生的碟形凹陷还会导致铜互连线的电阻过大,造成半导体器件的处理速度变慢,甚至由于发热过大而将铜互连线熔断,从而发生半导体器件的断路。On the other hand, the dishing produced by excessive grinding during chemical mechanical polishing of copper can also lead to excessive resistance of copper interconnection lines, resulting in slower processing of semiconductor devices, and even the loss of copper due to excessive heat generation. The interconnection line is blown, whereby the disconnection of the semiconductor device occurs.
CN108682650A公开了一种表面平坦化方法及半导体多层互连结构,该方法包括:第一化学机械抛光工序,对半导体多层互连结构中沉积于深孔的金属进行化学机械抛光;第二介质层形成工序,在半导体多层互连结构中阻挡层的表面形成第二介质层;以及第二化学机械抛光工序,对第二介质层及阻挡层进行化学机械抛光。但该方法新增第二介质层的形成工序和化学机械抛光程序,成本高。诸如CN1855417A和CN1855420A的方法同样存在成本较高,工艺较为复杂的问题。CN108682650A discloses a surface planarization method and a semiconductor multilayer interconnection structure. The method includes: a first chemical mechanical polishing process, which is to chemically mechanically polish the metal deposited in the deep hole in the semiconductor multilayer interconnection structure; the second medium A layer forming process, forming a second dielectric layer on the surface of the barrier layer in the semiconductor multilayer interconnection structure; and a second chemical mechanical polishing process, performing chemical mechanical polishing on the second dielectric layer and the barrier layer. However, this method adds a second dielectric layer forming process and a chemical mechanical polishing process, and the cost is high. The methods such as CN1855417A and CN1855420A also have the problems of high cost and complicated process.
因此,需要成本较低的、能够控制蝶形凹陷的大小的半导体表面平坦化工艺。Therefore, a low-cost semiconductor surface planarization process capable of controlling the size of the butterfly recess is needed.
发明内容Contents of the invention
以下是对本文详细描述的主题的概述。本概述并非是为了限制权利要求的保护范围。The following is an overview of the topics described in detail in this article. This summary is not intended to limit the scope of the claims.
鉴于相关技术中存在的问题,本申请实施例提供一种半导体表面平坦化的方法及制得的半导体和用途,所述方法在不改变原有沉积工艺的基础上,仅通过增加一道平坦化处理工序,就解决了多层互连结构中蝶形凹陷的叠加问题,提高了多层互连结构半导体的性能。In view of the problems existing in the related technology, the embodiment of the present application provides a method for planarizing the surface of a semiconductor and the semiconductor and its use. The method only adds a planarization process without changing the original deposition process. The process solves the superposition problem of the butterfly-shaped depressions in the multilayer interconnection structure, and improves the performance of the semiconductor with the multilayer interconnection structure.
第一方面,本申请实施例提供一种半导体表面平坦化的方法,所述方法包括:In a first aspect, an embodiment of the present application provides a method for planarizing a semiconductor surface, the method comprising:
在半导体至少两层互连结构的第n段制造工艺中,覆盖第n段初始介质层后,所述第n段初始介质层先经厚度方向上的平坦化处理,得到第n段介质层,再进行后续工序;In the manufacturing process of the nth section of the at least two-layer semiconductor interconnection structure, after the nth section of the initial dielectric layer is covered, the nth section of the initial dielectric layer is first planarized in the thickness direction to obtain the nth section of the dielectric layer, Then proceed to the follow-up process;
所述第n段初始介质层的厚度大于第n段介质层的厚度,n≥2。The thickness of the nth section of the initial dielectric layer is greater than the thickness of the nth section of the dielectric layer, n≥2.
本申请所述方法通过在覆盖第n段初始介质层时,使第n段初始介质层的厚度比现有技术的介质层厚度厚,再通过增设平坦化处理步骤,使处理后的第n段初始介质层不再具有蝶形凹陷,为平坦表面,从而解决了多层互连结构中半导体表面蝶形凹陷的叠加问题。The method described in this application makes the thickness of the nth initial dielectric layer thicker than that of the prior art when covering the nth initial dielectric layer, and then adds a planarization treatment step to make the processed nth initial dielectric layer The initial dielectric layer no longer has butterfly-shaped depressions, but is a flat surface, thereby solving the superposition problem of butterfly-shaped depressions on the semiconductor surface in the multilayer interconnection structure.
本申请所述n的取值范围为≥2的自然数,例如可以是2、3、4、5或6等,可根据实际工艺进行调整,只要是在第1段制造工艺基础上叠加的制造工艺即可。The value range of n mentioned in this application is a natural number ≥ 2, for example, it can be 2, 3, 4, 5 or 6, etc., and can be adjusted according to the actual process, as long as it is a manufacturing process superimposed on the basis of the first stage of manufacturing process That's it.
优选地,所述平坦化处理的方法包括化学机械抛光方法。Preferably, the planarization method includes a chemical mechanical polishing method.
优选地,所述第n段初始介质层的厚度大于第1段制造工艺中第1段介质层的厚度。由于具有平坦化处理步骤,将其在厚度方向上去除一层厚度,同时去除具有第n段初始介质层中具有凹陷的部分,得到第n段介质层的平坦表面。Preferably, the thickness of the n-th initial dielectric layer is greater than the thickness of the first-stage dielectric layer in the first-stage manufacturing process. Due to the planarization treatment step, one layer thickness is removed in the thickness direction, and at the same time, the portion with the recess in the nth segment of the initial dielectric layer is removed to obtain a flat surface of the nth segment of the dielectric layer.
优选地,所述第n段介质层的厚度等于第1段制造工艺中第1段介质层的厚度。Preferably, the thickness of the nth dielectric layer is equal to the thickness of the first dielectric layer in the first manufacturing process.
一般情况下,多层互连结构的半导体每一层的介质层设置相同,因此本申 请优选第n段介质层的厚度与第1段介质层的厚度相同,但也可根据实际情况设置每一段的介质层厚度,只要满足最终第n段介质层的厚度复合预期设计厚度即可。In general, the dielectric layers of each layer of the semiconductor of the multilayer interconnection structure are set to be the same, so the thickness of the nth dielectric layer is preferred to be the same as that of the first dielectric layer in this application, but each segment can also be set according to the actual situation. The thickness of the dielectric layer, as long as the thickness of the final nth dielectric layer is combined with the expected design thickness.
优选地,所述第n段初始介质层的表面含有蝶形凹陷。由于第1段介质层或者前面段介质层的表面形貌是具有蝶形凹陷的,这一蝶形凹陷是由于第1段制造工艺或前1段制造工艺对金属进行研磨时,为了确保完全去除沟槽上方剩余的金属,因此一般需要过抛来保障沟槽上方金属去除干净,而在过抛过程中就会导致对沟槽内部金属的去除,从而造成蝶形凹陷的形成。在上述工艺的基础上,继续在其表面覆盖介质层,上一蝶形凹陷将继续保留,因此第n段初始介质层的表面含有蝶形凹陷。Preferably, the surface of the nth initial dielectric layer contains butterfly-shaped depressions. Since the surface topography of the dielectric layer in the first stage or the dielectric layer in the previous stage has a butterfly-shaped depression, this butterfly-shaped depression is due to the grinding of the metal in the first-stage manufacturing process or the first-stage manufacturing process, in order to ensure complete removal The remaining metal above the groove generally requires over-throwing to ensure that the metal above the groove is removed, and the metal inside the groove will be removed during the over-throwing process, resulting in the formation of butterfly-shaped depressions. On the basis of the above process, continue to cover the surface with a dielectric layer, and the previous butterfly-shaped depression will continue to remain, so the surface of the nth initial dielectric layer contains a butterfly-shaped depression.
优选地,所述第n段初始介质层的厚度比第n段介质层的厚度多出的厚度值大于所述蝶形凹陷的深度值。为了确保经平坦化处理后的介质层表面既没有蝶形凹陷,其厚度值又能符合标准,本申请优选所述第n段初始介质层的厚度比第n段介质层的厚度多出的厚度值大于所述蝶形凹陷的深度值,从而能够为平坦化处理预留足够的操作厚度。Preferably, the thickness of the n-th initial dielectric layer is greater than the thickness of the n-th dielectric layer by a value greater than the depth of the butterfly-shaped depression. In order to ensure that the surface of the dielectric layer after planarization has no butterfly-shaped depressions, and its thickness value can meet the standard, the application preferably has the thickness of the nth segment of the initial dielectric layer greater than the thickness of the nth segment of the dielectric layer. The value is greater than the depth value of the butterfly-shaped depression, so as to reserve sufficient operating thickness for planarization.
优选地,所述第n段初始介质层的厚度比第n段介质层的厚度多2000~3000A,例如可以是2000A、2100A、2200A、2300A、2400A、2500A、2600A、2800A或3000A等。虽然本申请也可根据实际工艺设计情况,对所述第n段初始介质层的厚度比第n段介质层的厚度之间的差值进行适当调整;但出于现有单段蝶形凹陷的厚度一般在2000A左右考虑,本申请中优选限定第n段初始介质层的厚度比第n段介质层的厚度多2000~3000A,能够更好地符合半导体的结构设计。Preferably, the thickness of the nth initial dielectric layer is 2000-3000A thicker than that of the nth dielectric layer, such as 2000A, 2100A, 2200A, 2300A, 2400A, 2500A, 2600A, 2800A or 3000A. Although the present application can also adjust appropriately the difference between the thickness of the nth section of the initial dielectric layer and the thickness of the nth section of dielectric layer according to the actual process design; The thickness is generally considered to be around 2000A. In this application, it is preferable to limit the thickness of the nth initial dielectric layer to be 2000-3000A thicker than the thickness of the nth dielectric layer, which can better meet the structural design of the semiconductor.
本申请一般对所述后续工序不做特殊限定,采用本领域技术人员熟知的后续制造工艺即可,也可根据实际工艺情况进行调整,但进一步优选地,在第n段制造工艺中,所述后续工序依次包括覆盖蚀刻阻挡层、光刻、蚀刻、覆盖阻挡层、覆盖金属层和抛光。The present application generally does not make special restrictions on the subsequent process, and the subsequent manufacturing process well-known to those skilled in the art can be used, and can also be adjusted according to the actual process situation, but further preferably, in the n-th stage of manufacturing process, the Subsequent processes sequentially include capping the etch barrier layer, photolithography, etching, capping the barrier layer, capping the metal layer, and polishing.
优选地,所述抛光包括化学机械抛光。Preferably, said polishing comprises chemical mechanical polishing.
优选地,所述覆盖金属层包括依次进行的光刻、蚀刻和沉积。Preferably, the covering metal layer includes photolithography, etching and deposition performed in sequence.
优选地,所述制造工艺包括大马士革制造工艺。Preferably, the manufacturing process includes a damascene manufacturing process.
本申请对所述大马士革制造工艺中的其他工艺参数没有特殊限制,可采用本领域技术人员熟知的任何可用于大马士革制造工艺的工艺参数进行,也可根 据实际工艺进行调整。The present application has no special restrictions on other process parameters in the Damascus manufacturing process, and any process parameters known to those skilled in the art that can be used in the Damascus manufacturing process can be used, and can also be adjusted according to the actual process.
优选地,所述金属层包括铜层。Preferably, the metal layer comprises a copper layer.
本申请对所述介质层的材质和厚度没有特殊限制,采用本领域技术人员熟知的任何可用于半导体中介质层的材质和厚度即可,例如可以包括氧化物和/或氮化物,例如可以是氮化硅或氧化硅等,厚度例如可以是2500A等。The present application has no special restrictions on the material and thickness of the dielectric layer, and any material and thickness known to those skilled in the art that can be used in semiconductor dielectric layers can be used, for example, oxides and/or nitrides can be included, for example, it can be Silicon nitride or silicon oxide, etc., may have a thickness of 2500 Å, for example.
本申请对所述阻挡层的材质和厚度没有特殊限制,采用本领域技术人员熟知的任何可用于半导体中阻挡层的材质和厚度即可,例如可以包括氧化物和/或氮化物,例如可以是正硅酸四乙酯(TEOS)制备的氧化硅等,厚度例如可以是400A等。The present application has no special restrictions on the material and thickness of the barrier layer, and any material and thickness known to those skilled in the art that can be used for barrier layers in semiconductors can be used, for example, it can include oxide and/or nitride, for example, it can be positive Silicon oxide prepared from tetraethyl silicate (TEOS), etc., may have a thickness of 400 Å, for example.
作为本申请优选地技术方案,所述方法包括如下步骤:As a preferred technical solution of the present application, the method includes the following steps:
(1)进行第一段大马士革制造工艺,得到第1段半导体结构;(1) Perform the first stage of Damascus manufacturing process to obtain the first stage of semiconductor structure;
(2)在步骤(1)所述第1段半导体结构的表面覆盖第n段初始介质层后,所述第n段初始介质层先经厚度方向上的平坦化处理,得到第n段介质层;所述第n段初始介质层的厚度大于第n段介质层的厚度,n≥2;(2) After the surface of the first section of the semiconductor structure in step (1) is covered with the nth section of the initial dielectric layer, the nth section of the initial dielectric layer is first planarized in the thickness direction to obtain the nth section of the dielectric layer ; The thickness of the nth segment of the initial dielectric layer is greater than the thickness of the nth segment of the dielectric layer, n≥2;
(3)在所述第n段介质层的表面覆盖蚀刻阻挡层、光刻、蚀刻、覆盖阻挡层、覆盖金属层和抛光,得到第n段半导体结构;(3) Covering the surface of the nth section dielectric layer with an etching barrier layer, photolithography, etching, covering the barrier layer, covering the metal layer and polishing to obtain the nth section semiconductor structure;
重复步骤(2)~(3)直至得到设计的半导体。Repeat steps (2)-(3) until the designed semiconductor is obtained.
第二方面,本申请实施例提供一种半导体,所述半导体根据第一方面所述的半导体表面平坦化的方法制得。In a second aspect, an embodiment of the present application provides a semiconductor, which is manufactured according to the method for flattening a semiconductor surface described in the first aspect.
本申请所述半导体由于蝶形凹陷小,金属互连线的电阻低,最终形成的半导体器件的处理速度快,而且能够减少半导体器件的断路现象。Because the semiconductor described in the present application has small bow-shaped depressions and low resistance of metal interconnection lines, the processing speed of the finally formed semiconductor device is fast, and the disconnection phenomenon of the semiconductor device can be reduced.
优选地,所述半导体具有至少两层互连结构。本申请所述至少两层互连结构是指具有至少两个重复的竖直叠加的半导体结构单元。Preferably, the semiconductor has at least two layers of interconnection structures. The at least two-layer interconnection structure in this application refers to at least two repeated vertically stacked semiconductor structural units.
本申请对每一段内半导体的结构单元没有特殊限制,可采用本领域技术人员熟知的任何半导体的单元结构,也可根据实际情况进行调整。In this application, there is no special limitation on the structural unit of the semiconductor in each segment, and any semiconductor unit structure known to those skilled in the art can be used, and can also be adjusted according to the actual situation.
优选地,所述半导体中自下向上第1段半导体结构包括介质层,所述介质层的表面设置有第一阻挡层,所述介质层和第一阻挡层在对应位置设置有凹槽,所述第一阻挡层的凹槽从第一阻挡层表面贯穿至介质层中,所述介质层和第一阻挡层对应凹槽内沉积有金属,所述凹槽内金属的表面含有蝶形凹陷。其他段半导体结构优选与第1段半导体结构相同。Preferably, the semiconductor structure of the first stage from bottom to top in the semiconductor includes a dielectric layer, the surface of the dielectric layer is provided with a first barrier layer, and the dielectric layer and the first barrier layer are provided with grooves at corresponding positions, so The groove of the first barrier layer penetrates from the surface of the first barrier layer into the dielectric layer, the dielectric layer and the first barrier layer correspond to metal deposited in the groove, and the surface of the metal in the groove contains butterfly-shaped depressions. The semiconductor structure of the other stage is preferably the same as the semiconductor structure of the first stage.
优选地,所述半导体为晶圆。通过进一步优选为晶圆,显著降低了晶圆的蝶形凹陷程度。Preferably, the semiconductor is a wafer. By further optimizing the wafer, the degree of butterfly dishing of the wafer is significantly reduced.
第三方面,本申请实施例提供一种第一方面所述的半导体在集成电路中的用途。In a third aspect, the embodiment of the present application provides an application of the semiconductor described in the first aspect in an integrated circuit.
本申请所述半导体由于蝶形凹陷小,因此具有优良的处理速度和低电阻,应用在集成电路中,能够大幅增加集成电路的运行效率。The semiconductor described in the present application has excellent processing speed and low resistance due to the small butterfly depression, and can be used in integrated circuits to greatly increase the operating efficiency of integrated circuits.
与相关技术相比,本申请实施例至少具有以下有益效果:Compared with related technologies, the embodiments of the present application have at least the following beneficial effects:
(1)本申请实施例提供的半导体表面平坦化的方法克服了至少两层互连结构中前段制造工艺产生的蝶形凹陷在后段工艺叠加的影响,仅需要在原始步骤中增加介质层厚度减薄步骤即可使蝶形大小得到了有效控制,第n段半导体结构的蝶形凹陷的深度与第1段半导体结构的蝶形凹陷的深度的差值≤70A,在优选条件下≤20A,甚至可达到≤2A或第n段半导体结构的蝶形凹陷的深度比第1段半导体结构的蝶形凹陷的深度小,而且制备工艺流程简单,成本低廉;(1) The semiconductor surface planarization method provided by the embodiment of the present application overcomes the influence of the butterfly-shaped depressions produced by the front-end manufacturing process in the at least two-layer interconnection structure, which is superimposed on the back-end process, and only needs to increase the thickness of the dielectric layer in the original step The thinning step can effectively control the size of the butterfly, and the difference between the depth of the butterfly depression of the nth semiconductor structure and the depth of the butterfly depression of the first semiconductor structure is ≤70A, and under optimal conditions ≤20A, It can even reach ≤2A or the depth of the butterfly-shaped recess of the n-th semiconductor structure is smaller than that of the first-stage semiconductor structure, and the preparation process is simple and the cost is low;
(2)本申请实施例提供的半导体由于蝶形凹陷小,金属互连线的电阻低,最终形成的半导体器件的处理速度快,而且能够减少半导体器件的断路现象,能够较好的应用在集成电路中。(2) The semiconductor provided by the embodiment of the present application has a small butterfly-shaped depression and low resistance of the metal interconnection line, so the processing speed of the final semiconductor device is fast, and the disconnection phenomenon of the semiconductor device can be reduced, so it can be better applied to integrated circuits. in the circuit.
在阅读并理解了附图和详细描述后,可以明白其他方面。Other aspects will be apparent to others upon reading and understanding the drawings and detailed description.
附图说明Description of drawings
附图用来提供对本文技术方案的进一步理解,并且构成说明书的一部分,与本申请的实施例一起用于解释本文的技术方案,并不构成对本文技术方案的限制。The accompanying drawings are used to provide a further understanding of the technical solutions herein, and constitute a part of the description, and are used together with the embodiments of the application to explain the technical solutions herein, and do not constitute limitations to the technical solutions herein.
图1是本申请提供的半导体表面平坦化的方法流程示意图。FIG. 1 is a schematic flowchart of a method for planarizing a semiconductor surface provided by the present application.
图2是对比例1提供的半导体的制备方法流程示意图。FIG. 2 is a schematic flowchart of a method for preparing a semiconductor provided in Comparative Example 1.
图中:1-第1段半导体结构;21-第2初始介质层;22-第2初始介质层表面的蝶形凹陷;23-第2介质层;24-蚀刻阻挡层;25-金属铜;26-金属铜表面的蝶形凹陷。In the figure: 1-the first semiconductor structure; 21-the second initial dielectric layer; 22-the butterfly-shaped depression on the surface of the second initial dielectric layer; 23-the second dielectric layer; 24-etching barrier layer; 25-metal copper; 26 - Butterfly-shaped depressions on metallic copper surfaces.
具体实施方式Detailed ways
下面结合附图并通过具体实施方式来进一步说明本申请的技术方案。The technical solution of the present application will be further described below in conjunction with the accompanying drawings and through specific implementation methods.
下面对本申请进一步详细说明。但下述的实例仅仅是本申请的简易例子, 并不代表或限制本申请的权利保护范围,本申请的保护范围以权利要求书为准。The application will be further described in detail below. However, the following examples are only simple examples of the present application, and do not represent or limit the protection scope of the present application, and the protection scope of the present application shall be determined by the claims.
需要理解的是,在本申请的描述中,术语“中心”、“纵向”、“横向”、“上”、“下”、“前”、“后”、“左”、“右”、“竖直”、“水平”、“顶”、“底”、“内”、“外”等指示的方位或位置关系为基于附图所示的方位或位置关系,仅是为了便于描述本申请和简化描述,而不是指示或暗示所指的装置或元件必须具有特定的方位、以特定的方位构造和操作,因此不能理解为对本申请的限制。此外,术语“第一”、“第二”等仅用于描述目的,而不能理解为指示或暗示相对重要性或者隐含指明所指示的技术特征的数量。由此,限定有“第一”、“第二”等的特征可以明示或者隐含地包括一个或者更多个该特征。在本申请的描述中,除非另有说明,“多个”的含义是两个或两个以上。It should be understood that in the description of the present application, the terms "center", "longitudinal", "transverse", "upper", "lower", "front", "rear", "left", "right", " The orientation or positional relationship indicated by "vertical", "horizontal", "top", "bottom", "inner", "outer", etc. is based on the orientation or positional relationship shown in the drawings, and is only for the convenience of describing the present application and The description is simplified, rather than indicating or implying that the device or element referred to must have a specific orientation, be constructed in a specific orientation, and operate, and thus should not be construed as limiting the application. In addition, the terms "first", "second", etc. are used for descriptive purposes only, and should not be understood as indicating or implying relative importance or implicitly specifying the quantity of the indicated technical features. Thus, a feature defined as "first", "second", etc. may expressly or implicitly include one or more of that feature. In the description of the present application, unless otherwise specified, "plurality" means two or more.
需要说明的是,在本申请的描述中,除非另有明确的规定和限定,术语“设置”、“相连”、“连接”应做广义理解,例如,可以是固定连接,也可以是可拆卸连接,或一体连接;可以是机械连接,也可以是电连接;可以是直接相连,也可以通过中间媒介间接相连,可以是两个元件内部的连通。对于本领域的普通技术人员而言,可以通过具体情况理解上述术语在本申请中的具体含义。It should be noted that, in the description of this application, unless otherwise clearly stipulated and limited, the terms "set", "connected" and "connected" should be understood in a broad sense, for example, it can be a fixed connection or a detachable connection. Connection, or integral connection; it can be mechanical connection or electrical connection; it can be direct connection or indirect connection through an intermediary, and it can be the internal communication of two components. Those of ordinary skill in the art can understand the specific meanings of the above terms in this application based on specific situations.
作为本申请的一个具体实施方式,提供一种半导体表面平坦化的方法,以两段大马士革工艺为例,如图1所示,所述方法包括如下步骤:As a specific embodiment of the present application, a method for planarizing the surface of a semiconductor is provided. Taking the two-stage Damascene process as an example, as shown in Figure 1, the method includes the following steps:
(1)进行第一段大马士革制造工艺,得到第1段半导体结构1,所述第1段半导体结构1包括介质层,所述介质层的表面设置有第一阻挡层,所述介质层和第一阻挡层在对应位置设置有凹槽,所述第一阻挡层的凹槽从第一阻挡层表面贯穿至介质层中,所述介质层内沉积有金属铜,所述凹槽内金属铜的表面含有蝶形凹陷;(1) Carry out the first section of damascene manufacturing process to obtain the first section of semiconductor structure 1, the first section of semiconductor structure 1 includes a dielectric layer, the surface of the dielectric layer is provided with a first barrier layer, the dielectric layer and the first section of semiconductor structure 1 A barrier layer is provided with a groove at a corresponding position, and the groove of the first barrier layer penetrates from the surface of the first barrier layer into the dielectric layer, and metal copper is deposited in the dielectric layer, and the metal copper in the groove is The surface contains butterfly-shaped depressions;
(2)在步骤(1)所述第1段半导体结构1的表面覆盖第2初始介质层21后,得到覆盖有第2初始介质层21的半导体结构,如图1中a所示,此时可以看到第2初始介质层表面的蝶形凹陷22;(2) After the surface of the first stage semiconductor structure 1 described in step (1) is covered with the second initial dielectric layer 21, a semiconductor structure covered with the second initial dielectric layer 21 is obtained, as shown in a in FIG. 1, at this time The butterfly-shaped depression 22 on the surface of the second initial dielectric layer can be seen;
所述第2初始介质层21先经厚度方向上的平坦化处理,得到第2介质层23,如图1中b所示;所述第2初始介质层21的厚度大于第2介质层23的厚度;The second initial dielectric layer 21 is first planarized in the thickness direction to obtain a second dielectric layer 23, as shown in b in Figure 1; the thickness of the second initial dielectric layer 21 is greater than that of the second dielectric layer 23 thickness;
(3)依次在所述第2介质层23的表面覆盖蚀刻阻挡层24、光刻、蚀刻、覆盖第二阻挡层(未示出)、覆盖金属铜25和抛光,覆盖蚀刻阻挡层24后如图 1中c所示、覆盖金属铜25后如图1中d所示、抛光后如图1中e所示,可以看出第1段半导体结构1的蝶形凹陷并未传递至第2段,得到第2段半导体结构;成型后的所述第2段半导体结构包括第2介质层23,所述介质层23的表面设置有凹槽,所述介质层23对应凹槽内沉积有金属铜25,所述凹槽内金属铜25的表面含有金属铜表面的蝶形凹陷26,得到设计的双层大马士革金属铜晶圆。(3) covering the etching barrier layer 24, photolithography, etching, covering the second barrier layer (not shown), covering metal copper 25 and polishing successively on the surface of the second dielectric layer 23, after covering the etching barrier layer 24, as As shown in c in Fig. 1, covered with metal copper 25, as shown in d in Fig. 1, and after polishing, as shown in e in Fig. 1, it can be seen that the butterfly-shaped depression of the semiconductor structure 1 in the first stage has not been transferred to the second stage , to obtain the second section of semiconductor structure; the second section of semiconductor structure after molding includes a second dielectric layer 23, the surface of the dielectric layer 23 is provided with grooves, and metal copper is deposited in the corresponding grooves of the dielectric layer 23 25. The surface of the metal copper 25 in the groove contains a butterfly-shaped depression 26 on the surface of the metal copper to obtain a designed double-layer Damascus metal copper wafer.
上述具体实施方式中,凹槽的深度不做特殊限定,可根据实际工艺进行调整,例如可以是200A等。同样对介质层、蚀刻阻挡层、第一阻挡层和第二阻挡层的厚度不做特殊限定,可根据实际工艺进行调整,例如介质层的厚度可以是2500A等,第一阻挡层和第二阻挡层的厚度可以是400A等。In the above specific implementation manner, the depth of the groove is not particularly limited, and can be adjusted according to the actual process, for example, it can be 200A. Likewise, the thicknesses of the dielectric layer, the etch barrier layer, the first barrier layer, and the second barrier layer are not particularly limited, and can be adjusted according to the actual process. For example, the thickness of the dielectric layer can be 2500 Å, etc., and the first barrier layer and the second barrier layer The thickness of the layer may be 400A and so on.
实施例1Example 1
本实施例提供一种半导体表面平坦化的方法,所述方法包括如下步骤:This embodiment provides a method for flattening a semiconductor surface, the method comprising the following steps:
(1)进行第1段大马士革制造工艺,所述第1段大马士革制造工艺具体包括:在介质层(氧化硅)的表面进行化学气相沉积400A的蚀刻阻挡层(氧化硅),然后依次进行光刻、蚀刻和铜沉积(电镀,工艺参数为7000A),再进行三次化学机械抛光,第一次化学机械抛光进行大压力~2psi研磨,去除沟槽上方大部分的铜;第二次化学机械抛光用相对小的压力~1.2psi去除沟槽上方剩余的金属铜;第三次化学机械抛光对沟槽和旁边的氧化硅进行减薄到工艺需求的厚度~1000A,并沉积第一阻挡层,所述第一阻挡层为用于阻止金属向介质层扩散的碳化硅层,厚度为200A,得到第1段半导体结构1;所述介质层的表面设置有第一阻挡层,所述介质层和第一阻挡层在对应位置设置有凹槽,所述第一阻挡层的凹槽从第一阻挡层表面贯穿至介质层中,所述介质层内沉积有金属铜,所述凹槽内金属铜的表面含有蝶形凹陷;(1) Carry out the first paragraph of damascene manufacturing process. The first paragraph of damascene manufacturing process specifically includes: performing chemical vapor deposition of 400A of etching barrier layer (silicon oxide) on the surface of dielectric layer (silicon oxide), and then performing photolithography in sequence , etching and copper deposition (electroplating, the process parameter is 7000A), and then perform three chemical mechanical polishing, the first chemical mechanical polishing is ground with high pressure ~ 2psi to remove most of the copper above the trench; the second chemical mechanical polishing is used Relatively small pressure ~1.2psi removes the remaining metal copper above the trench; the third chemical mechanical polishing thins the trench and the silicon oxide next to it to a thickness of ~1000A required by the process, and deposits the first barrier layer. The first barrier layer is a silicon carbide layer used to prevent metal from diffusing into the dielectric layer, with a thickness of 200 Å, to obtain the first-stage semiconductor structure 1; a first barrier layer is provided on the surface of the dielectric layer, and the dielectric layer and the first The barrier layer is provided with grooves at corresponding positions, and the groove of the first barrier layer penetrates from the surface of the first barrier layer into the dielectric layer, and metal copper is deposited in the dielectric layer, and the surface of the metal copper in the groove is Contains butterfly-shaped depressions;
(2)在步骤(1)所述第2段半导体结构的表面覆盖第2初始介质层21后,所述第2初始介质层21先经厚度方向上的平坦化处理,所述平坦化处理为化学机械抛光处理,压力为~2.0psi,时间为~30s得到第2介质层23;所述第2初始介质层21的厚度比第2介质层23的厚度厚2500A;(2) After the second initial dielectric layer 21 is covered on the surface of the second semiconductor structure in step (1), the second initial dielectric layer 21 is first subjected to a planarization process in the thickness direction, and the planarization process is chemical mechanical polishing treatment, the pressure is ~2.0psi, and the time is ~30s to obtain the second dielectric layer 23; the thickness of the second initial dielectric layer 21 is 2500A thicker than the thickness of the second dielectric layer 23;
(3)在所述第2介质层23的表面覆盖蚀刻阻挡层24(氧化硅、400A)、经光刻、蚀刻、沉积第二阻挡层以及覆盖金属铜25和三次化学机械抛光,其中所述第二阻挡层为用于阻止金属向介质层扩散的氮化钽层,厚度为100A,该三次化学机械抛光和沉积等步骤参照步骤(1)进行,得到第2段半导体结构,得 到设计的双层大马士革金属铜晶圆。(3) Cover the etching barrier layer 24 (silicon oxide, 400A) on the surface of the second dielectric layer 23, through photolithography, etching, depositing the second barrier layer and covering metal copper 25 and chemical mechanical polishing three times, wherein the The second barrier layer is a tantalum nitride layer used to prevent the metal from diffusing into the dielectric layer, with a thickness of 100 Å. The three chemical mechanical polishing and deposition steps are carried out with reference to step (1) to obtain the second segment of the semiconductor structure, and the designed double layer damascus metal copper wafer.
实施例2Example 2
本实施例提供一种半导体表面平坦化的方法,所述方法包括如下步骤:This embodiment provides a method for flattening a semiconductor surface, the method comprising the following steps:
(1)进行第1段大马士革制造工艺,所述第1段大马士革制造工艺具体包括:在介质层(氧化硅)的表面沉积(化学气相沉积,工艺参数为300A)蚀刻阻挡层(氧化硅)并依次进行光刻、蚀刻和铜沉积(电镀,工艺参数为7500A),再进行三次化学机械抛光,第一次化学机械抛光进行大压力~2.5psi研磨,去除沟槽上方大部分的铜;第二次化学机械抛光用相对小的压力~1.4psi去除沟槽上方剩余的金属铜;第三次化学机械抛光对沟槽和旁边的氧化层进行减薄到工艺需求的厚度~1600A,并沉积第一阻挡层,即碳化硅,厚度为150A,得到第1段半导体结构1;所述第1段半导体结构1包括介质层,所述介质层的表面设置有第一阻挡层,所述介质层和第一阻挡层在对应位置设置有凹槽,所述第一阻挡层的凹槽从第一阻挡层表面贯穿至介质层中,所述介质层内沉积有金属铜,所述凹槽内金属铜的表面含有蝶形凹陷;(1) Carry out the first paragraph of damascene manufacturing process, and the first paragraph of damascene manufacturing process specifically includes: depositing (chemical vapor deposition, process parameter is 300A) etching barrier layer (silicon oxide) on the surface of dielectric layer (silicon oxide) and Perform photolithography, etching and copper deposition (electroplating, process parameters: 7500A) in sequence, and then perform chemical mechanical polishing three times. The first chemical mechanical polishing is performed under high pressure ~ 2.5psi grinding to remove most of the copper above the trench; the second The first chemical mechanical polishing uses a relatively small pressure ~ 1.4psi to remove the remaining metal copper above the trench; the third chemical mechanical polishing thins the trench and the oxide layer next to it to the thickness required by the process ~ 1600A, and deposits the first The barrier layer, that is, silicon carbide, has a thickness of 150 Å, and the first semiconductor structure 1 is obtained; the first semiconductor structure 1 includes a dielectric layer, and a first barrier layer is provided on the surface of the dielectric layer, and the dielectric layer and the first semiconductor structure A barrier layer is provided with a groove at a corresponding position, and the groove of the first barrier layer penetrates from the surface of the first barrier layer into the dielectric layer, and metal copper is deposited in the dielectric layer, and the metal copper in the groove is The surface contains butterfly-shaped depressions;
(2)在步骤(1)所述第2段半导体结构的表面覆盖第2初始介质层21后,所述第2初始介质层21先经厚度方向上的平坦化处理,所述平坦化处理为化学机械抛光处理,压力为~2.5psi,时间为~30s,得到第2介质层23;所述第2初始介质层21的厚度比第2介质层23的厚度厚2000A;(2) After the second initial dielectric layer 21 is covered on the surface of the second semiconductor structure in step (1), the second initial dielectric layer 21 is first subjected to a planarization process in the thickness direction, and the planarization process is chemical mechanical polishing treatment, the pressure is ~2.5psi, the time is ~30s, to obtain the second dielectric layer 23; the thickness of the second initial dielectric layer 21 is 2000A thicker than the thickness of the second dielectric layer 23;
(3)在所述第2介质层23的表面覆盖蚀刻阻挡层24(500A)、并依次经光刻、蚀刻、沉积第二阻挡层和覆盖金属铜层和三次化学机械抛光,其中所述第二阻挡层为用于阻止金属向介质层扩散的氮化钽层,厚度为120A,该三次化学机械抛光和沉积等步骤参照步骤(1)进行,得到第2段半导体结构,得到设计的双层大马士革金属铜晶圆。(3) Cover the etching barrier layer 24 (500A) on the surface of the second dielectric layer 23, and sequentially undergo photolithography, etching, depositing the second barrier layer and covering the metal copper layer and chemical mechanical polishing three times, wherein the first The second barrier layer is a tantalum nitride layer used to prevent the metal from diffusing into the dielectric layer, with a thickness of 120A. The three chemical mechanical polishing and deposition steps are carried out with reference to step (1) to obtain the second semiconductor structure and the designed double layer Damascus metal copper wafer.
实施例3Example 3
本实施例提供一种半导体表面平坦化的方法,所述方法包括如下步骤:This embodiment provides a method for flattening a semiconductor surface, the method comprising the following steps:
(1)进行第1段大马士革制造工艺,所述第1段大马士革制造工艺具体包括:在介质层(氧化硅)的表面沉积(化学气相沉积,工艺参数为600A)蚀刻阻挡层(氧化硅)并蚀刻深孔,然后依次进行光刻、蚀刻和铜沉积(电镀,工艺参数为8000A),再进行三次化学机械抛光,第一次化学机械抛光进行大压力~1.8psi研磨,去除沟槽上方大部分的铜;第二次化学机械抛光用相对小的压力 ~1.5psi去除沟槽上方剩余的金属铜;第三次化学机械抛光对沟槽和旁边的氧化层进行减薄到工艺需求的厚度~1200A,得到第1段半导体结构1;所述第1段半导体结构1包括介质层,所述介质层的表面设置有第一阻挡层,所述介质层和第一阻挡层在对应位置设置有凹槽,所述第一阻挡层的凹槽从第一阻挡层表面贯穿至介质层中,所述介质层内沉积有金属铜,所述凹槽内金属铜的表面含有蝶形凹陷;(1) Carry out the first paragraph of damascene manufacturing process, and the first paragraph of damascene manufacturing process specifically includes: depositing (chemical vapor deposition, process parameter is 600A) etching barrier layer (silicon oxide) on the surface of dielectric layer (silicon oxide) and Etch the deep hole, then perform photolithography, etching and copper deposition (electroplating, process parameter is 8000A) in sequence, and then perform three chemical mechanical polishing. The first chemical mechanical polishing is performed under high pressure ~ 1.8psi grinding to remove most of the top of the groove Copper; the second chemical mechanical polishing uses a relatively small pressure ~ 1.5psi to remove the remaining metallic copper above the trench; the third chemical mechanical polishing thins the trench and the oxide layer next to it to the thickness required by the process ~ 1200A , to obtain the first semiconductor structure 1; the first semiconductor structure 1 includes a dielectric layer, the surface of the dielectric layer is provided with a first barrier layer, and the dielectric layer and the first barrier layer are provided with grooves at corresponding positions , the groove of the first barrier layer penetrates from the surface of the first barrier layer into the dielectric layer, metal copper is deposited in the dielectric layer, and the surface of the metal copper in the groove contains butterfly-shaped depressions;
(2)在步骤(1)所述第2段半导体结构的表面覆盖第2初始介质层21后,所述第2初始介质层21先经厚度方向上的平坦化处理,所述平坦化处理为化学机械抛光处理,压力为~2.1psi,时间为~35s,得到第2介质层23;所述第2初始介质层21的厚度比第2介质层23的厚度厚3000A;(2) After the second initial dielectric layer 21 is covered on the surface of the second semiconductor structure in step (1), the second initial dielectric layer 21 is first subjected to a planarization process in the thickness direction, and the planarization process is Chemical mechanical polishing treatment, the pressure is ~2.1psi, the time is ~35s, to obtain the second dielectric layer 23; the thickness of the second initial dielectric layer 21 is 3000A thicker than the thickness of the second dielectric layer 23;
(3)在所述第2介质层23的表面覆盖蚀刻阻挡层24(400A)并依次经光刻、蚀刻、沉积第二阻挡层、覆盖金属铜25和三次化学机械抛光,其中所述第二阻挡层为用于阻止金属向介质层扩散的氮化钽层,厚度为110A,该三次化学机械抛光和沉积等步骤参照步骤(1)进行,得到第2段半导体结构;(3) Cover the etching stopper layer 24 (400A) on the surface of the second dielectric layer 23 and sequentially undergo photolithography, etching, depositing a second stopper layer, covering metal copper 25 and chemical mechanical polishing three times, wherein the second The barrier layer is a tantalum nitride layer used to prevent the metal from diffusing into the dielectric layer, with a thickness of 110 Å. The three steps of chemical mechanical polishing and deposition are carried out with reference to step (1) to obtain the second semiconductor structure;
重复步骤(2)~(3)在所述第2段半导体结构上构造第3段半导体结构,得到设计的三层大马士革金属铜晶圆。Steps (2) to (3) are repeated to construct the third semiconductor structure on the second semiconductor structure to obtain a designed three-layer damascene copper wafer.
实施例4Example 4
本实施例提供一种半导体表面平坦化的方法,所述方法除所述第2初始介质层21的厚度比第2介质层23的厚度厚6000A外,其余均与实施例1相同。本实施例与实施例1相比,由于初始沉积介质层的厚度较厚,成本增加较多。This embodiment provides a method for flattening the surface of a semiconductor. The method is the same as that of Embodiment 1 except that the thickness of the second initial dielectric layer 21 is 6000 Å thicker than that of the second dielectric layer 23 . Compared with the first embodiment, the cost of the present embodiment is increased due to the thicker thickness of the initially deposited dielectric layer.
实施例5Example 5
本实施例提供一种半导体表面平坦化的方法,所述方法除所述第2初始介质层21的厚度比第2介质层23的厚度厚200A外,其余均与实施例1相同。本实施例由于初始沉积的介质层厚度不够填补由于第1段工艺累积的蝶形凹陷的深度,平坦化处理后第2介质层23的表面仍然具有小幅的蝶形凹陷。This embodiment provides a method for flattening the surface of a semiconductor. The method is the same as that of Embodiment 1 except that the thickness of the second initial dielectric layer 21 is 200 Å thicker than that of the second dielectric layer 23 . In this embodiment, since the thickness of the initially deposited dielectric layer is not enough to fill the depth of the butterfly-shaped depression accumulated in the first stage of the process, the surface of the second dielectric layer 23 still has a small butterfly-shaped depression after the planarization treatment.
对比例1Comparative example 1
本对比例提供一种半导体制备的方法,如图2所示,所述方法除步骤(2)中覆盖第2初始介质层21的厚度直接与实施例1中第2介质层23的厚度相同外,步骤(1)~(3)中的制备工艺参数均与实施例1相同,具体包括如下步骤:This comparative example provides a method for semiconductor preparation, as shown in Figure 2, except that the thickness of the second initial dielectric layer 21 covered in step (2) is directly the same as the thickness of the second dielectric layer 23 in Example 1 , the preparation process parameter in step (1)~(3) is all identical with embodiment 1, specifically comprises the following steps:
(1)进行第1段大马士革制造工艺,所述第1段大马士革制造工艺具体包 括:在介质层(氧化硅)的表面进行化学气相沉积400A的蚀刻阻挡层(氧化硅),然后依次进行光刻、蚀刻和铜沉积(电镀,工艺参数为7000A),再进行三次化学机械抛光,第一次化学机械抛光进行大压力~2psi研磨,去除沟槽上方大部分的铜;第二次化学机械抛光用相对小的压力~1.2psi去除沟槽上方剩余的金属铜;第三次化学机械抛光对沟槽和旁边的氧化硅进行减薄到工艺需求的厚度~1000A,并沉积第一阻挡层,所述第一阻挡层为用于阻止金属向介质层扩散的碳化硅层,厚度为200A,得到第1段半导体结构1;所述介质层的表面设置有第一阻挡层,所述介质层和第一阻挡层在对应位置设置有凹槽,所述第一阻挡层的凹槽从第一阻挡层表面贯穿至介质层中,所述介质层内沉积有金属铜,所述凹槽内金属铜的表面含有蝶形凹陷;(1) Carry out the first paragraph of damascene manufacturing process. The first paragraph of damascene manufacturing process specifically includes: performing chemical vapor deposition of 400A of etching barrier layer (silicon oxide) on the surface of dielectric layer (silicon oxide), and then performing photolithography in sequence , etching and copper deposition (electroplating, the process parameter is 7000A), and then perform three chemical mechanical polishing, the first chemical mechanical polishing is ground with high pressure ~ 2psi to remove most of the copper above the trench; the second chemical mechanical polishing is used Relatively small pressure ~1.2psi removes the remaining metal copper above the trench; the third chemical mechanical polishing thins the trench and the silicon oxide next to it to a thickness of ~1000A required by the process, and deposits the first barrier layer. The first barrier layer is a silicon carbide layer used to prevent metal from diffusing into the dielectric layer, with a thickness of 200 Å, to obtain the first-stage semiconductor structure 1; a first barrier layer is provided on the surface of the dielectric layer, and the dielectric layer and the first The barrier layer is provided with grooves at corresponding positions, and the groove of the first barrier layer penetrates from the surface of the first barrier layer into the dielectric layer, and metal copper is deposited in the dielectric layer, and the surface of the metal copper in the groove is Contains butterfly-shaped depressions;
(2)在步骤(1)所述第2段半导体结构的表面覆盖第2介质层23;(2) Covering the second dielectric layer 23 on the surface of the second semiconductor structure described in step (1);
(3)依次在所述第2介质层23的表面覆盖蚀刻阻挡层24(氧化硅、400A)、并依次经光刻、蚀刻、沉积第二阻挡层以及覆盖金属铜25和三次化学机械抛光,其中所述第二阻挡层为用于阻止金属向介质层扩散的氮化钽层,厚度为100A,蚀刻阻挡层24后如图2中c所示、覆盖金属铜25后如图2中d所述、抛光后如图2中e所示,可以看出第1段半导体结构1的蝶形凹陷继续传递至第2段,得到第2段半导体结构;成型后的所述第2段半导体结构包括第2介质层23,所述介质层23设置有凹槽,所述介质层23沉积的凹槽内有金属铜25,所述凹槽内金属铜25的表面含有金属铜表面的蝶形凹陷26,得到设计的双层大马士革金属铜晶圆,但所述晶圆中第2段半导体结构的蝶形凹陷较第1段半导体结构1的蝶形凹陷显著增加。(3) covering the etching barrier layer 24 (silicon oxide, 400A) on the surface of the second dielectric layer 23 in sequence, and sequentially undergoing photolithography, etching, depositing the second barrier layer, covering metal copper 25 and chemical mechanical polishing three times, Wherein the second barrier layer is a tantalum nitride layer used to prevent the metal from diffusing to the dielectric layer, with a thickness of 100 Å. After the barrier layer 24 is etched, it is shown in c in FIG. 2 , and after covering the metal copper 25, it is shown in d in FIG. 2 As shown in e in Figure 2 after polishing, it can be seen that the butterfly-shaped depression of the first segment of the semiconductor structure 1 continues to be transmitted to the second segment to obtain the second segment of the semiconductor structure; the second segment of the semiconductor structure after molding includes The second dielectric layer 23, the dielectric layer 23 is provided with a groove, the groove deposited on the dielectric layer 23 has metal copper 25, and the surface of the metal copper 25 in the groove contains a butterfly-shaped depression 26 on the surface of the metal copper , the designed double-layer damascene metal copper wafer is obtained, but the butterfly-shaped depression of the second-stage semiconductor structure in the wafer is significantly increased compared with the butterfly-shaped depression of the first-stage semiconductor structure 1.
本申请所述方法还可适用于其他多段半导体结构的半导体制造,出于篇幅的考虑,在此不再赘述。The method described in the present application is also applicable to the semiconductor manufacturing of other multi-segment semiconductor structures, and will not be repeated here for the sake of space.
测试方法:采用AFM(原子力显微镜)方法测量上述实施例和对比例制得的晶圆中的蝶形凹陷的深度,结果如表1所示。Test method: AFM (atomic force microscope) was used to measure the depth of the butterfly-shaped depressions in the wafers prepared in the above examples and comparative examples, and the results are shown in Table 1.
表1Table 1
Figure PCTCN2022110438-appb-000001
Figure PCTCN2022110438-appb-000001
Figure PCTCN2022110438-appb-000002
Figure PCTCN2022110438-appb-000002
从表1可以看出以下几点:The following points can be seen from Table 1:
(1)综合实施例1~3可以看出,本申请提供的半导体表面平坦化的方法在至少两段的半导体结构制造过程中,能够有效组织第1段半导体结构中蝶形凹陷的深度值向第2段半导体结构或第3段半导体结构转化,即大于1段的半导体结构的蝶形凹陷的深度与第1段半导体结构的蝶形凹陷深度的差值≤20A;(1) It can be seen from comprehensive embodiments 1 to 3 that the method for flattening the semiconductor surface provided by the present application can effectively organize the depth value of the butterfly-shaped depression in the semiconductor structure of the first stage in the semiconductor structure manufacturing process of at least two stages. The second-stage semiconductor structure or the third-stage semiconductor structure transformation, that is, the difference between the butterfly-shaped depression depth of the semiconductor structure larger than the first stage and the butterfly-shaped depression depth of the first-stage semiconductor structure is ≤ 20A;
(2)综合实施例1和实施例4~5可以看出,实施例1中所述第2初始介质层的厚度比第2介质层的厚度厚2500A,相较于实施例4和实施例5中所述第2初始介质层的厚度比第2介质层的厚度分别厚6000A和200A而言,实施例1中第2段半导体结构的蝶形凹陷仅为220A,相较于第1段增加15A,而实施例4中虽然仅比第1段增加2A,但介质层增加的厚度过多,成本增加显著,实施例5中第2段比第段增加70A,蝶形凹陷有一定程度的传递,由此表明,本申请通过将第n初始介质层的厚度比第n介质层的厚度加厚的值控制在特定范围内,能够减少蝶形凹陷传递的同时控制成本;(2) Combining Example 1 and Examples 4 to 5, it can be seen that the thickness of the second initial dielectric layer in Example 1 is 2500 Å thicker than that of the second dielectric layer, compared with Example 4 and Example 5 In terms of the thickness of the second initial dielectric layer being 6000A and 200A thicker than the thickness of the second dielectric layer, the butterfly-shaped depression of the second stage semiconductor structure in Example 1 is only 220A, which is 15A larger than that of the first stage , while in Example 4, although it is only increased by 2A compared with the first section, the thickness of the dielectric layer is increased too much, and the cost increases significantly. In Example 5, the second section is increased by 70A compared with the first section, and the butterfly-shaped depression has a certain degree of transmission. This shows that the present application can reduce the transfer of butterfly-shaped depressions while controlling the cost by controlling the thickness of the nth initial dielectric layer to be thicker than that of the nth dielectric layer within a specific range;
(3)综合实施例1和对比例1可以看出,对比例1中直接在沉积时仅沉积最终第2介质层的厚度,最终第2段半导体结构的蝶形凹陷高达295A,比第1段半导体结构的蝶形凹陷高100A,远高于实施例1中的15A,由此表明,本申请通过增加初始沉积时介质层的厚度,并增加一步化学机械抛光步骤,显著减少了蝶形凹陷在几段半导体结构之间的传递。(3) Combining Example 1 and Comparative Example 1, it can be seen that in Comparative Example 1, only the thickness of the final second dielectric layer is deposited directly during deposition, and the butterfly-shaped depression of the final second section of the semiconductor structure is as high as 295 Å, which is higher than that of the first section. The butterfly-shaped depression of the semiconductor structure is 100A high, which is much higher than 15A in Example 1. This shows that the present application significantly reduces the butterfly-shaped depression by increasing the thickness of the dielectric layer during initial deposition and adding a step of chemical mechanical polishing. Transfer between several segments of semiconductor structures.
综上所述,本申请提供的半导体表面平坦化的方法克服了至少两层互连结构中前段制造工艺产生的蝶形凹陷在后段工艺叠加的影响,使蝶形大小得到了 有效控制,成本低,适合工业化推广。To sum up, the semiconductor surface planarization method provided by this application overcomes the influence of superposition of butterfly-shaped depressions produced by the front-end manufacturing process in the back-end process in at least two-layer interconnection structures, so that the size of the butterfly is effectively controlled and the cost is reduced. Low, suitable for industrial promotion.
申请人声明,本申请通过上述实施例来说明本申请的详细结构特征,但本申请并不局限于上述详细结构特征,即不意味着本申请必须依赖上述详细结构特征才能实施。所属技术领域的技术人员应该明了,对本申请的任何改进,对本申请所选用部件的等效替换以及辅助部件的增加、具体方式的选择等,均落在本申请的保护范围和公开范围之内。The applicant declares that the present application illustrates the detailed structural features of the present application through the above embodiments, but the present application is not limited to the above detailed structural features, that is, it does not mean that the application must rely on the above detailed structural features to be implemented. Those skilled in the art should understand that any improvement to the application, equivalent replacement of the components selected in the application, addition of auxiliary components, selection of specific methods, etc., all fall within the scope of protection and disclosure of the application.

Claims (12)

  1. 一种半导体表面平坦化的方法,其包括:A method for flattening a semiconductor surface, comprising:
    在半导体至少两层互连结构的第n段制造工艺中,覆盖第n段初始介质层后,所述第n段初始介质层先经厚度方向上的平坦化处理,得到第n段介质层,再进行后续工序;In the manufacturing process of the nth section of the at least two-layer semiconductor interconnection structure, after the nth section of the initial dielectric layer is covered, the nth section of the initial dielectric layer is first planarized in the thickness direction to obtain the nth section of the dielectric layer, Then proceed to the follow-up process;
    所述第n段初始介质层的厚度大于第n段介质层的厚度,n≥2。The thickness of the nth section of the initial dielectric layer is greater than the thickness of the nth section of the dielectric layer, n≥2.
  2. 根据权利要求1所述的方法,其中,所述第n段初始介质层的厚度大于第1段制造工艺中第1段介质层的厚度。The method according to claim 1, wherein the thickness of the n-th initial dielectric layer is greater than the thickness of the first-stage dielectric layer in the first-stage manufacturing process.
  3. 根据权利要求1或2所述的方法,其中,所述第n段介质层的厚度等于第1段制造工艺中第1段介质层的厚度。The method according to claim 1 or 2, wherein the thickness of the nth dielectric layer is equal to the thickness of the first dielectric layer in the first manufacturing process.
  4. 根据权利要求1~3任一项所述的方法,其中,所述第n段初始介质层的表面含有蝶形凹陷。The method according to any one of claims 1-3, wherein the surface of the nth stage of initial dielectric layer contains butterfly-shaped depressions.
  5. 根据权利要求4所述的方法,其中,所述第n段初始介质层的厚度比第n段介质层的厚度多出的厚度值大于所述蝶形凹陷的深度值。The method according to claim 4, wherein the thickness of the nth initial dielectric layer is greater than the thickness of the nth dielectric layer by a value greater than the depth of the butterfly-shaped depression.
  6. 根据权利要求1~5任一项所述的方法,其中,所述第n段初始介质层的厚度比第n段介质层的厚度多2000~3000A。The method according to any one of claims 1 to 5, wherein the thickness of the nth stage of initial dielectric layer is 2000˜3000 Å greater than the thickness of the nth stage of dielectric layer.
  7. 根据权利要求1~6任一项所述的方法,其中,在第n段制造工艺中,所述后续工序依次包括覆盖蚀刻阻挡层、光刻、蚀刻、覆盖阻挡层、覆盖金属层和抛光。The method according to any one of claims 1 to 6, wherein, in the n-th manufacturing process, the subsequent steps sequentially include covering the etching barrier layer, photolithography, etching, covering the barrier layer, covering the metal layer and polishing.
  8. 根据权利要求7所述的方法,其中,所述抛光包括化学机械抛光。The method of claim 7, wherein the polishing comprises chemical mechanical polishing.
  9. 根据权利要求1~8任一项所述的方法,其中,所述制造工艺包括大马士革制造工艺。The method according to any one of claims 1-8, wherein the manufacturing process comprises a damascene manufacturing process.
  10. 一种半导体,其特征在于,所述半导体根据权利要求1~9任一项所述的半导体表面平坦化的方法制得。A semiconductor, characterized in that the semiconductor is produced according to the method for planarizing the surface of a semiconductor according to any one of claims 1-9.
  11. 根据权利要求10所述的半导体,其中,所述半导体为晶圆。The semiconductor according to claim 10, wherein said semiconductor is a wafer.
  12. 一种根据权利要求11所述的半导体在集成电路中的用途。Use of a semiconductor according to claim 11 in an integrated circuit.
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