WO2023011932A3 - Small-scale clean fuel gas production system using flexible fuel gasification - Google Patents

Small-scale clean fuel gas production system using flexible fuel gasification Download PDF

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Publication number
WO2023011932A3
WO2023011932A3 PCT/EP2022/070472 EP2022070472W WO2023011932A3 WO 2023011932 A3 WO2023011932 A3 WO 2023011932A3 EP 2022070472 W EP2022070472 W EP 2022070472W WO 2023011932 A3 WO2023011932 A3 WO 2023011932A3
Authority
WO
WIPO (PCT)
Prior art keywords
fuel gas
filters
small
ash
production system
Prior art date
Application number
PCT/EP2022/070472
Other languages
French (fr)
Other versions
WO2023011932A2 (en
Inventor
Dimitrios MERTZIS
Stefanos TSIAKMAKIS
Zisis Samaras
Original Assignee
Technologies Vio-Energeias Idiotiki Kefalaiouchiki Etaireia (Βιο2Chp I.K.E.)
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Technologies Vio-Energeias Idiotiki Kefalaiouchiki Etaireia (Βιο2Chp I.K.E.) filed Critical Technologies Vio-Energeias Idiotiki Kefalaiouchiki Etaireia (Βιο2Chp I.K.E.)
Priority to CA3228189A priority Critical patent/CA3228189A1/en
Priority to EP22757221.1A priority patent/EP4380713A2/en
Publication of WO2023011932A2 publication Critical patent/WO2023011932A2/en
Publication of WO2023011932A3 publication Critical patent/WO2023011932A3/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/46—Gasification of granular or pulverulent flues in suspension
    • C10J3/48—Apparatus; Plants
    • C10J3/482—Gasifiers with stationary fluidised bed
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B09—DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
    • B09B—DISPOSAL OF SOLID WASTE NOT OTHERWISE PROVIDED FOR
    • B09B3/00—Destroying solid waste or transforming solid waste into something useful or harmless
    • B09B3/40—Destroying solid waste or transforming solid waste into something useful or harmless involving thermal treatment, e.g. evaporation
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B49/00—Destructive distillation of solid carbonaceous materials by direct heating with heat-carrying agents including the partial combustion of the solid material to be treated
    • C10B49/02—Destructive distillation of solid carbonaceous materials by direct heating with heat-carrying agents including the partial combustion of the solid material to be treated with hot gases or vapours, e.g. hot gases obtained by partial combustion of the charge
    • C10B49/04—Destructive distillation of solid carbonaceous materials by direct heating with heat-carrying agents including the partial combustion of the solid material to be treated with hot gases or vapours, e.g. hot gases obtained by partial combustion of the charge while moving the solid material to be treated
    • C10B49/08—Destructive distillation of solid carbonaceous materials by direct heating with heat-carrying agents including the partial combustion of the solid material to be treated with hot gases or vapours, e.g. hot gases obtained by partial combustion of the charge while moving the solid material to be treated in dispersed form
    • C10B49/10—Destructive distillation of solid carbonaceous materials by direct heating with heat-carrying agents including the partial combustion of the solid material to be treated with hot gases or vapours, e.g. hot gases obtained by partial combustion of the charge while moving the solid material to be treated in dispersed form according to the "fluidised bed" technique
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B53/00—Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form
    • C10B53/02—Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form of cellulose-containing material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/72—Other features
    • C10J3/723—Controlling or regulating the gasification process
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K1/00—Purifying combustible gases containing carbon monoxide
    • C10K1/02—Dust removal
    • C10K1/024—Dust removal by filtration
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K1/00—Purifying combustible gases containing carbon monoxide
    • C10K1/02—Dust removal
    • C10K1/026—Dust removal by centrifugal forces
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K1/00—Purifying combustible gases containing carbon monoxide
    • C10K1/04—Purifying combustible gases containing carbon monoxide by cooling to condense non-gaseous materials
    • C10K1/046—Reducing the tar content
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K3/00—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide
    • C10K3/02—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide by catalytic treatment
    • C10K3/023—Reducing the tar content
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23C—METHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN  A CARRIER GAS OR AIR 
    • F23C10/00—Fluidised bed combustion apparatus
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G5/00—Incineration of waste; Incinerator constructions; Details, accessories or control therefor
    • F23G5/02—Incineration of waste; Incinerator constructions; Details, accessories or control therefor with pretreatment
    • F23G5/027—Incineration of waste; Incinerator constructions; Details, accessories or control therefor with pretreatment pyrolising or gasifying stage
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0903—Feed preparation
    • C10J2300/0906—Physical processes, e.g. shredding, comminuting, chopping, sorting
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0913—Carbonaceous raw material
    • C10J2300/0916—Biomass

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • General Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Materials Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Dispersion Chemistry (AREA)
  • Industrial Gases (AREA)
  • Processing Of Solid Wastes (AREA)
  • Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)

Abstract

The present disclosure includes a system for the production and refining of fuel gas produced from solid fuels of low energy quality and high ash content, such as solid agricultural residues. The system comprises, among others, a fluidized bed gasifier, which is adjusted for the production of fuel gas at a lower temperature than the melting temperature of ash, a plurality of monolithic ceramic or metallic honeycomb filters with plugged alternate channels, which are configured to and operate under conditions which avoid ash and other gasified compound deposition on the filters, so as to facilitate filter cleaning without interrupting the system's operation, and at the same time to avoid thermally and mechanically induced stress, which could damage the filters.
PCT/EP2022/070472 2021-08-02 2022-07-21 Small-scale clean fuel gas production system using flexible fuel gasification WO2023011932A2 (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
CA3228189A CA3228189A1 (en) 2021-08-02 2022-07-21 Small-scale clean fuel gas production system using flexible fuel gasification
EP22757221.1A EP4380713A2 (en) 2021-08-02 2022-07-21 Small-scale clean fuel gas production system using flexible fuel gasification

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GR20210100526 2021-08-02
GR20210100526A GR1010414B (en) 2021-08-02 2021-08-02 Small-scale clean fuel production system using flexible fuel gasification

Publications (2)

Publication Number Publication Date
WO2023011932A2 WO2023011932A2 (en) 2023-02-09
WO2023011932A3 true WO2023011932A3 (en) 2023-03-16

Family

ID=82943347

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2022/070472 WO2023011932A2 (en) 2021-08-02 2022-07-21 Small-scale clean fuel gas production system using flexible fuel gasification

Country Status (4)

Country Link
EP (1) EP4380713A2 (en)
CA (1) CA3228189A1 (en)
GR (1) GR1010414B (en)
WO (1) WO2023011932A2 (en)

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5531798A (en) * 1994-05-26 1996-07-02 Foster Wheeler Energia Oy Eliminating ash bridging in ceramic filters
US6077490A (en) * 1999-03-18 2000-06-20 Mcdermott Technology, Inc. Method and apparatus for filtering hot syngas
CN104073297B (en) * 2014-06-19 2016-04-20 广东正鹏生物质能源科技有限公司 The integrated system of a kind of biomass gas purifying and combustion tail gas residual heat recovery

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB0423037D0 (en) * 2004-10-18 2004-11-17 Accentus Plc Process and plant for treating biomass
FI124014B (en) 2012-01-13 2014-01-31 Carbona Oy Fluidized bed gasifier grate
CA2937445C (en) 2016-07-28 2022-07-12 Glock Gaston Wood gasification
WO2018037152A1 (en) 2016-08-25 2018-03-01 Volter Oy A combined heat and power plant and a method for treating raw synthesis gas produced by a gasifier in a combined heat and power plant
CN106336905A (en) 2016-08-25 2017-01-18 武汉高斯生态能源技术有限公司 Fluidized-bed gasification furnace for treating biomass
NL2021739B1 (en) 2018-10-01 2020-05-07 Milena Olga Joint Innovation Assets B V Reactor for producing a synthesis gas from a fuel

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5531798A (en) * 1994-05-26 1996-07-02 Foster Wheeler Energia Oy Eliminating ash bridging in ceramic filters
US6077490A (en) * 1999-03-18 2000-06-20 Mcdermott Technology, Inc. Method and apparatus for filtering hot syngas
CN104073297B (en) * 2014-06-19 2016-04-20 广东正鹏生物质能源科技有限公司 The integrated system of a kind of biomass gas purifying and combustion tail gas residual heat recovery

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
KURKELA ESA ET AL: "Pressurised fluidised-bed gasification experiments with wood, peat and coal at VTT in 1991-1994: Part 2. Experiences from peat and coal gasification and hot gas filtration", 31 December 1995 (1995-12-31), XP055982368, ISBN: 978-951-38-4787-6, Retrieved from the Internet <URL:https://www.researchgate.net/profile/Esa-Kurkela/publication/298663544_Pressurised_fluidised-bed_gasification_experiments_with_wood_peat_and_coal_at_VTT_in_1991-1994_Part_2_Experiences_from_peat_and_coal_gasification_and_hot_gas_filtration/links/57edfb9c08ae2df36403404d/Pressurised-fluidised-bed-gas> [retrieved on 20221116] *
SIMELL PEKKA ET AL: "Clean syngas from biomass-process development and concept assessment", BIOMASS CONVERSION AND BIOREFINERY, 1 December 2014 (2014-12-01), Berlin/Heidelberg, pages 357 - 370, XP055982370, ISSN: 2190-6815, Retrieved from the Internet <URL:https://link.springer.com/content/pdf/10.1007/s13399-014-0121-y.pdf> [retrieved on 20221115], DOI: 10.1007/s13399-014-0121-y *

Also Published As

Publication number Publication date
EP4380713A2 (en) 2024-06-12
CA3228189A1 (en) 2023-02-09
GR1010414B (en) 2023-02-24
WO2023011932A2 (en) 2023-02-09

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