WO2022269554A1 - Cogeneration process and related apparatus - Google Patents

Cogeneration process and related apparatus Download PDF

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Publication number
WO2022269554A1
WO2022269554A1 PCT/IB2022/055875 IB2022055875W WO2022269554A1 WO 2022269554 A1 WO2022269554 A1 WO 2022269554A1 IB 2022055875 W IB2022055875 W IB 2022055875W WO 2022269554 A1 WO2022269554 A1 WO 2022269554A1
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WIPO (PCT)
Prior art keywords
syngas
burner
threshold value
combustion
phase
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PCT/IB2022/055875
Other languages
French (fr)
Inventor
Fabio Pellegrini
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Kira Technology S.R.L.
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Application filed by Kira Technology S.R.L. filed Critical Kira Technology S.R.L.
Priority to EP22741848.0A priority Critical patent/EP4359653A1/en
Publication of WO2022269554A1 publication Critical patent/WO2022269554A1/en

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Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N5/00Exhaust or silencing apparatus combined or associated with devices profiting from exhaust energy
    • F01N5/02Exhaust or silencing apparatus combined or associated with devices profiting from exhaust energy the devices using heat
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23BMETHODS OR APPARATUS FOR COMBUSTION USING ONLY SOLID FUEL
    • F23B50/00Combustion apparatus in which the fuel is fed into or through the combustion zone by gravity, e.g. from a fuel storage situated above the combustion zone
    • F23B50/02Combustion apparatus in which the fuel is fed into or through the combustion zone by gravity, e.g. from a fuel storage situated above the combustion zone the fuel forming a column, stack or thick layer with the combustion zone at its bottom
    • F23B50/06Combustion apparatus in which the fuel is fed into or through the combustion zone by gravity, e.g. from a fuel storage situated above the combustion zone the fuel forming a column, stack or thick layer with the combustion zone at its bottom the flue gases being removed downwards through one or more openings in the fuel-supporting surface
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23BMETHODS OR APPARATUS FOR COMBUSTION USING ONLY SOLID FUEL
    • F23B90/00Combustion methods not related to a particular type of apparatus
    • F23B90/04Combustion methods not related to a particular type of apparatus including secondary combustion
    • F23B90/06Combustion methods not related to a particular type of apparatus including secondary combustion the primary combustion being a gasification or pyrolysis in a reductive atmosphere
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G5/00Incineration of waste; Incinerator constructions; Details, accessories or control therefor
    • F23G5/02Incineration of waste; Incinerator constructions; Details, accessories or control therefor with pretreatment
    • F23G5/027Incineration of waste; Incinerator constructions; Details, accessories or control therefor with pretreatment pyrolising or gasifying stage
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G5/00Incineration of waste; Incinerator constructions; Details, accessories or control therefor
    • F23G5/44Details; Accessories
    • F23G5/46Recuperation of heat
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G7/00Incinerators or other apparatus for consuming industrial waste, e.g. chemicals
    • F23G7/10Incinerators or other apparatus for consuming industrial waste, e.g. chemicals of field or garden waste or biomasses
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02GHOT GAS OR COMBUSTION-PRODUCT POSITIVE-DISPLACEMENT ENGINE PLANTS; USE OF WASTE HEAT OF COMBUSTION ENGINES; NOT OTHERWISE PROVIDED FOR
    • F02G2243/00Stirling type engines having closed regenerative thermodynamic cycles with flow controlled by volume changes
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G2206/00Waste heat recuperation
    • F23G2206/20Waste heat recuperation using the heat in association with another installation
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G2900/00Special features of, or arrangements for incinerators
    • F23G2900/50204Waste pre-treatment by pyrolysis, gasification or cracking
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23NREGULATING OR CONTROLLING COMBUSTION
    • F23N2223/00Signal processing; Details thereof
    • F23N2223/12Integration
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23NREGULATING OR CONTROLLING COMBUSTION
    • F23N2227/00Ignition or checking
    • F23N2227/02Starting or ignition cycles

Definitions

  • the present invention relates to a process of cogeneration of electrical energy and heat and the related apparatus.
  • the present invention relates to a process of cogeneration of electrical energy and heat and the related apparatus for household or small consumer use, starting from a renewable and sustainable energy source, e.g., woody biomass.
  • Biomass-fueled cogeneration systems consisting of three basic parts, i.e. a pyrolytic gasifier, a burner, and a Stirling engine, are well known.
  • the fuel syngas is produced starting from the biomass in the pyrolytic gasifier; the syngas produced is burned with a controlled supply of air in the burner; the Stirling engine, by virtue of the heat generated by the combustion of the syngas, sets the electric generator in oscillation, thus producing electrical energy.
  • Pyrolytic gasification is a thermal-chemical process by virtue of which a combustible gas (syngas), comprising a mixture of hydrogen, carbon monoxide, methane and, to a lesser extent, other compounds, can be extracted from organic material, such as biomass. Pyrolytic gasification occurs by maintaining the biomass at a particularly high temperature in a low-oxygen environment.
  • the by-product of pyrolytic gasification is a solid residue, named char, which contains almost exclusively carbon.
  • pyrolytic gasification compared with direct combustion of the biomass, reduces carbon emissions into the atmosphere because, once the fuel syngas is extracted, only the char remains which contains the portion of carbon that will not be emitted into the atmosphere in the form of CO2, but is evacuated in solid form and collected. Furthermore, the use of pyrolytic gasification provides a fuel gas which is much more effective in the combustion in terms of maximum achievable temperature, emissions of particulate matter and heating of the heat exchangers. Examples of cogenerators based on the application of the pyrolytic gasification and the Stirling engine are described in US 2009/0078176 and US 2006/0089516.
  • the problem underlying the present invention is to make available a cogeneration process for domestic use and related apparatus capable of high- performance characteristics under all circumstances and of meeting all the requirements explained above.
  • a first object of the invention is a process of cogeneration of electrical energy and heat starting from a renewable and sustainable energy source, preferably woody biomass, in a micro-cogenerator comprising a pyrolytic gasifier, a burner, and a Stirling engine, said process comprising the following steps: i) feeding said energy source to the pyrolytic gasifier which comprises a reaction chamber inside which said energy source reacts thus generating syngas and biochar; ii) feeding the syngas generated during step i) to said burner which comprises a combustion chamber inside which the syngas is burned in the presence of combustion air thus generating hot combustion gases; iii) subjecting said hot combustion gases to heat exchange in a heat exchanger (the so-called "hot exchanger") of the Stirling engine adapted to generate electrical energy, obtaining exhaust fumes deriving from said heat exchange, during said step ii), the ratio of combustion air to syngas being adjusted based on a signal provided by a lambda probe crossed by a flow of said exhaust fumes said process compris
  • said step b) further comprises the generation of an ignition spark; more in particular, said ignition spark is advantageously generated before the supply of said combustion air.
  • said ignition spark is generated at the beginning of the start-up phase.
  • Said ignition spark of the flame is generated by a high-voltage electronic transformer.
  • the onset (ignition) of the combustion inside the burner is performed by means of an electric arc generated by a high-voltage electronic transformer and related electrodes appropriately positioned, such as to be lapped by the gas flow.
  • first threshold value means the preset threshold value of the integral over time of the temperature of the reaction chamber of the pyrolytic gasifier.
  • second threshold value means the preset threshold value of the integral over time of the value read by the lambda probe.
  • the process according to the present invention allows detecting the time when the pyrolytic gasifier begins to produce fuel syngas and, consequently, the time when the latter is available for combustion in the burner. Detecting the presence of fuel syngas in the burner is critical to identify the exact moment in which the burner can be ignited, the latter being a crucial stage for the following reasons.
  • said start-up phase further comprises a step c) of detecting the presence of the flame in the combustion chamber of the burner.
  • step c) the derivative of the temperature, i.e., the temperature gradient, of the combustion chamber with respect to time is compared with a preset threshold value of said derivative; the exceeding of said threshold value is an indication of the presence of the flame.
  • two thermocouples are placed in the hot exchanger of the Stirling engine and, during the aforesaid step c), the value of the gradient of the average temperature of the two thermocouples is compared with said threshold value.
  • the lambda probe provides an electrical signal (in mV) through which it is possible to have a measurement of the "lambda value (l) " properly so called, i.e., the ratio between the actual AFR (air-fuel-ratio) and the stoichiometric AFR (air-fuel-ratio); in other words, the "lambda value (X) " properly so called is to be understood as the ratio of air to fuel relative to the stoichiometric ratio of the fuel used.
  • the electrical signal provided by the lambda probe is an indirect measurement of said lambda value (X); the higher the value of the electrical signal, the lower the lambda value (X).
  • the "value read by the lambda probe” means the electrical signal provided by the lambda probe, while the “lambda value (X) " means the theoretical value properly so called as defined above.
  • a lambda value (X) equal to 0 indicates the presence of syngas only and the absence of air
  • a lambda value (X) of 1 indicates the presence of air in stoichiometric amount
  • a lambda value (X) greater than 1 indicates the presence of air in excess of the amount strictly necessary for syngas combustion.
  • the lambda value (X) is 0 or close to 0, e.g., it is comprised between 0 and 0.2.
  • the lambda value (l) is higher, preferably it is about 1, e.g., it is comprised between
  • the value read by the lambda probe is lower than during the start-up phase, hence the lambda value (l) is higher; preferably the lambda value (l) is higher than 1, e.g., is comprised between 1.1 and 1.5.
  • the mV values of the electrical signal provided by the lambda probe were detected experimentally with the lambda probe NGK - OZA685-WW1.
  • said step c) further comprises a control of the value read by the lambda probe.
  • a value comprised between 0 and 1000 mV, e.g., comprised between 5 and 960 mV, or between
  • threshold value means a calibratable threshold value, i.e., subject to calibration by means of experimental tests.
  • the threshold value of the integral over time of the temperature of the reaction chamber of the gasifier (first threshold value) is preferably comprised between 5000 and 25000 °C-s, more preferably between 10000 and 20000 °C-s even more preferably between 13000 and 18000 °C-s, e.g., it is 15000 °C-s.
  • the threshold value of the integral over time of the value read by the lambda probe is preferably comprised between 500 and 5000 mV-s, more preferably between 800 and 3000 mV-s, even more preferably between 1000 and 2000 mV-s, e.g, it is 2000 mV-s.
  • the aforesaid integral over time of the temperature of the reaction chamber of the gasifier is calculated, then compared with the corresponding threshold value (first threshold value), for temperatures of the reaction chamber of the gasifier of at least 300°C, preferably of at least 400°C, or at least 500°C, or at least 600°C, or at least 700°C, or at least 800°C.
  • the aforesaid integral over time of the value read by the lambda probe is calculated, then compared with the corresponding threshold value (second threshold value), for values read by the lambda probe of at least 400 mV, preferably of at least 500 mV, or at least 600 mV, or at least 700 mV, or at least 800, or at least 900, or at least 1000 mV.
  • the integral over time of the value read by the lambda probe is calculated, then compared with the corresponding threshold value, for values read by the lambda probe of at least 850 mV.
  • the threshold value of the derivative of the temperature of the combustion chamber with respect to time is preferably comprised between 0.1 and 5.0 °C/s, more preferably between 0.3 and 2.0 °C/s, even more preferably between 0.5 and 1.0 °C/s, e.g., it is 0.5°C/s.
  • the regime phase is started at the end of the start-up phase and is characterized by a lower value read by the lambda probe, i.e., a higher combustion air-syngas ratio, than the start-up phase. More advantageously, the regime phase is started at the end of said step c).
  • the combustion air- syngas ratio is regulated by a lambda probe crossed by a flow of said exhaust fumes, meaning that said combustion air-syngas ratio is adjusted based on the signal provided by said lambda probe.
  • the combustion air inflow is advantageously adjusted by means of an electronically- driven motorized valve.
  • a valve is driven based on a signal provided by the lambda probe, i.e., based on the information provided by the lambda probe about the amount of air present in the exhaust fumes.
  • the excess air is comprised between 1 and 15%, or between 3 and 10%.
  • the need to carefully control the amount of air is related to the fact that performance (in terms of burner power) and emissions (CO, NO x ) are strongly affected by the fuel/combustion air ratio.
  • An optimal ratio of combustion air to syngas can be maintained by virtue of the signal provided by the lambda probe. Said ratio of combustion air to syngas is kept substantially constant during the regime phase.
  • the optimal value read by the lambda probe is identified as compromise between performance and emissions, which is used as an input to a PID controller.
  • the optimal lambda value (l) during the regime phase is greater than 1.
  • the position of the valve which regulates the combustion air supply is calculated by a PID (Proportional Integrative Derivative) control, which takes as input the value read by the lambda probe and outputs the position of the air adjustment valve.
  • the position of the valve which adjusts the supply of combustion air is calculated by a PID control.
  • step ii) the syngas exiting the pyrolytic gasifier is sucked into the combustion chamber of the burner by virtue of the presence of a vacuum generated by an appropriate extraction fan of said exhaust fumes.
  • said extraction fan is active with a speed proportional to the temperature of the reaction chamber of the pyrolytic gasifier during the start-up phase.
  • the extraction fan is driven by taking into account a power error (or delta) or by taking into account a temperature error (or delta).
  • the electrical power of the micro- cogenerator is compared with a target electrical power thus obtaining a power delta, and the speed of the extraction fan is adjusted, i.e., increased or decreased as needed, as a function of the power delta thus obtained.
  • the speed of the extraction fan is increased until the temperature of the burner exceeds a predetermined limit value.
  • the temperature of the burner is compared with a target temperature thus obtaining a temperature delta and the speed of the extraction fan is adjusted i.e., increased or decreased as needed, as a function of the temperature delta.
  • biomass should by no means be understood as limiting.
  • the biomass is fed to the pyrolytic gasifier through an appropriate loading auger.
  • the latter is advantageously started whenever the filling level of a connecting element (so-called “buffer") between the loading auger and the inlet of the reaction chamber of the pyrolytic gasifier is below a predetermined threshold value.
  • the filling level of said connecting element is advantageously detected by a suitable sensor, preferably based on ultrasound technology.
  • the reaction chamber of the pyrolytic gasifier is maintained at a suitable gasification temperature at which the biomass reacts generating syngas and biochar.
  • Said gasification temperature is preferably comprised between 1000°C and 1200°C to maximize syngas production.
  • the reaction front of the biomass inside the gasifier is comprised between an upper limit and a lower limit, and the biomass under reaction is supported by the biochar accumulated in the gasifier as long as the integral over time of the temperature of the upper limit of the reaction front does not exceed a preset threshold value of said integral; when said threshold value is exceeded, the biochar is at least partially discharged through an unloading auger causing the reaction front to lower so that it is maintained between said upper limit and said lower limit.
  • threshold value means a calibratable threshold value, i.e., subject to calibration by means of experimental tests.
  • the aforesaid threshold value of the integral over time of the temperature of the upper limit of the biomass reaction front inside the gasifier is preferably comprised between 10000 and 90000 °C-s, more preferably between 15000 and 80000 °C-s, even more preferably between 20000 and
  • 70000 °C-s e.g., is 50000 °C-s.
  • the aforesaid integral over time of the temperature of the upper limit of the biomass reaction front inside the gasifier is calculated, then compared with the corresponding threshold value, for temperatures of said upper limit of at least 300°C, preferably of at least 400°C, or at least 500°C, or at least 600°C, or at least 700°C, or at least 800°C.
  • said lower limit is defined by an electric heater placed inside the reaction chamber by virtue of which the gasification reaction of the biomass is initiated, while said upper limit is defined by a thermocouple designed to monitor the temperature in the upper part of the reaction chamber. This means that the reaction front of the biomass is comprised between said electric heater and said thermocouple.
  • the aforesaid heater integrates a special sensor inside it, e.g., a thermocouple.
  • temperature of the reaction chamber of the gasifier means the temperature of the electric heater when the process according to the present invention is in its start-up phase, and it means the temperature measured by the thermocouple when the process according to the present invention is in its regime phase.
  • a further object of the present invention is a micro cogenerator comprising: a pyrolytic gasifier adapted to produce syngas and biochar starting from a renewable and sustainable energy source, preferably woody biomass, a burner adapted to receive the syngas produced by said pyrolytic gasifier and to generate hot combustion gases a Stirling engine comprising a heat exchanger (the so-called "hot exchanger") fed with said hot combustion gases, said Stirling engine being adapted to generate electrical energy, wherein said burner comprises: a combustion chamber inside which the syngas is burned in the presence of combustion air, pre-mixing flanges for the syngas and the combustion air upstream of the combustion chamber, a means downstream of said pre-mixing flanges adapted to convey the syngas and the air into the combustion chamber, said micro-cogenerator being characterized in that said combustion chamber comprises: a bell open at the bottom inside which the hot exchanger of the Stirling engine is housed, said bell being adapted to convey the hot combustion gases into said hot exchanger and comprising steel surfaces internally
  • said means adapted to convey syngas and air into the combustion chamber consists of a nozzle or a duct; preferably, said nozzle or duct is made of ceramic material.
  • said means is a hole made in the insulating material that internally lines the bell.
  • said insulating material has a hole at the outlet of the pre-mixing flanges.
  • the aforesaid bell In addition to constraining the hot combustion gases to flow through the entire hot exchanger of the Stirling engine, the aforesaid bell also has the advantage of optimizing heat exchange by radiation.
  • porous ceramic means the element made of porous ceramic material will be also referred to as a "porous ceramic means".
  • the porous ceramic means is thermally insulated from the bell by virtue of the presence of the refractory insulating material covering it.
  • said porous ceramic means allows to stabilize the combustion, optimize the distribution thereof, and extend the flammability limit to higher air-fuel ratios, thus allowing to reduce polluting emissions at the exhaust.
  • said combustion chamber comprises an additional element made of refractory insulating material interposed between said porous ceramic means and said hot exchanger of the Stirling engine.
  • Said additional element has the advantage of preventing the unwanted entrance of heat into a part of the Stirling engine where it would reduce the thermodynamic efficiency of the engine itself.
  • said refractory insulating material is a polycrystalline alumina fiber- based material, which ensures high reflection of radiations and reduced heat accumulation.
  • said material comprises at least 70% by weight of polycrystalline alumina, preferably at least 75% by weight, more preferably at least 80% by weight, for example about 90% by weight.
  • said material further comprises at least 5% by weight of silica, preferably between 10% and 30% by weight of silica, more preferably between 10% and 25% by weight of silica, even more preferably between 10% and 20% by weight of silica.
  • said polycrystalline alumina fiber-based material is produced by the company Schupp under the trade name ITM-Fibermax®, preferably Blanket 1600-130.
  • said porous ceramic material comprises silicon carbide, alumina and silica.
  • said porous ceramic material is produced by the company Lanik under the trade name Vukopor® S.
  • said porous ceramic material comprises alumina, silica, zirconia and magnesium oxide.
  • said porous ceramic material is produced by the company Lanik under the trade name Vukopor® HT.
  • the micro generator comprises a cooling ring downstream of the hot exchanger of the Stirling engine inside which a cooling fluid flows.
  • Said cooling ring is such to prevent heat transfer downstream of said hot exchanger, preventing the entry of unwanted heat into the part of the Stirling engine below the hot exchanger, which comprises, for example, a regenerator, a low-temperature heat exchanger and an electric generator, safeguarding these components from an excessive heating.
  • the process and the micro-cogenerator according to the present invention advantageously allow to maximize the syngas combustion efficiency, minimize the production of polluting gases, maximize the heat exchange with the Stirling engine, minimize the entry of heat through unwanted points of the engine which would reduce the efficiency thereof, minimize the heat capacity of the elements close to the hot exchanger of the Stirling engine and reduce the thermal inertia in case of an emergency shutdown, make combustion safe under all circumstances, simplify construction and periodic maintenance. Further features and advantages of the invention will be apparent from the description of some embodiments, given here by way of a non-limiting example.
  • Figure 1 shows a section of the micro-cogenerator according to an embodiment of the present invention.
  • Figure 2 shows a section of the pyrolytic gasifier of the micro-cogenerator according to an embodiment of the present invention.
  • Figure 3 shows a section of the assembly comprising the reactor and the hopper of the pyrolytic gasifier according to an embodiment of the present invention.
  • Figure 4 shows a perspective view of a butterfly valve according to an embodiment of the present invention adapted to allow the inflow of the biomass into the reactor of the gasifier shown in Figure 3 or the evacuation of the biochar from said reactor, if necessary.
  • Figure 5 shows a detail of the butterfly valve of Figure 4 when said valve is in the fully open position.
  • Figure 6 shows a first view of the assembly consisting of the burner and the Stirling engine according to an embodiment of the present invention.
  • Figure 7 shows the section, along the axis A-A shown in Figure 6, of the assembly consisting of the burner and the Stirling engine according to an embodiment of the present invention.
  • Figure 8 shows a detail of the burner shown in Figure
  • Figure 9 shows a second view of the assembly consisting of the burner and the Stirling engine according to an embodiment of the present invention.
  • Figure 10 shows the section, along the axis C-C shown in Figure 9, of the assembly consisting of the burner and the Stirling engine according to an embodiment of the present invention.
  • Figure 11 shows a cross-section of the combustion chamber of the burner shown in Figures 6 and 9.
  • micro-cogenerator according to an embodiment of the present invention is globally indicated with reference numeral 1.
  • Said micro-cogenerator 1 comprises a pyrolytic gasifier 2, a burner 3, and a Stirling engine 4.
  • the pyrolytic gasifier 2 is shown in more detail in Figure 2, while the burner 3 and the Stirling engine 4 are more visible in Figures 6-10.
  • the gasifier 2 in Figure 2 comprises: a storage container 5 of the biomass 6; a reactor 7 inside which the biomass 6 is gasified generating combustible syngas 8 and biochar 9; a loading auger 10 of the biomass 6 which connects the container 5 to the inlet 11 of the reactor 7; an unloading auger 12 through which the biochar 9 is evacuated; an outlet duct 13 for the combustible syngas 8, through which the latter is fed to the burner 3; a hopper 14, which connects the outlet 15 of the reactor 7 to the unloading auger 12 of the biochar 9, and through which the combustible syngas 8 is sucked into the duct 13; a collection container 16 of the biochar 9 extracted from the reactor 7.
  • the reactor 7 defines a reaction chamber 17 and comprises an electric heater 18 and a thermocouple 19.
  • the electric heater 18 brings the biomass contained in the reaction chamber 17 to the gasification temperature of, e.g., 900°C, while the thermocouple 19 monitors the temperature in the upper part of the reaction chamber 17 during the gasification process.
  • the heater 18 and the thermocouple 19, respectively, represent the lower limit and the upper limit of the zone within which the biomass reaction front 6 must be maintained.
  • a connecting element 20, named “buffer”, is interposed between the loading auger 10 of the biomass 6 and the inlet 11 of the reactor 7.
  • a sensor 21 detects the filling level of the buffer 20, and the loading auger 10 of the biomass 6 is started whenever said sensor 21 detects that the filling level of the buffer 20 is below a predetermined threshold value.
  • the biomass 6 under reaction is supported by the biochar 9 generated during the pyrolytic gasification process seamlessly inside the reaction chamber 17.
  • the pyrolytic gasifier 2 according to the present invention has no support grid for the biomass under reaction which separates it from the spent biochar 9.
  • the unloading auger 12 and the hopper 14 are constantly kept full of biochar 9.
  • the reactor 7 of the pyrolytic gasifier 2 is shown in greater detail in Figure 3.
  • the reactor 7 comprises a reaction chamber 17 in which the biomass 6 is gasified in the presence of a given amount of air (sub-stoichiometric).
  • the reactor 7 further comprises an outer coating 71 with respect to said reaction chamber 17.
  • Said reaction chamber 17 has truncated-cone shape and is advantageously made of a polycrystalline alumina fiber-based material.
  • said material comprises at least 70% by weight of polycrystalline alumina, preferably at least 75% by weight, more preferably at least 80% by weight, for example about 90% by weight.
  • said material further comprises at least 5% by weight of silica, preferably between 10% and 30% by weight of silica, more preferably between 10% and 25% by weight of silica, even more preferably between 10% and 20% by weight of silica.
  • said material has a density comprised between 350 and 500 kg/m 3 .
  • said polycrystalline alumina fiber- based material is produced by the company Unifrax under the trade name High Temperature Saffil® RigiformTM.
  • said material is produced by the company
  • the reaction chamber 17 has an upper surface 72 and a lower surface 73, wherein the diameter of the upper surface 72 is slightly smaller than the diameter of the lower surface 73 in order to give an adequate draft angle, e.g., about 4°, to the inner surface of the reaction chamber 17.
  • the diameter of the upper surface 72 is comprised between 70 and 90 mm and the diameter of the lower surface 73 is comprised between 100 and 120 mm. Said geometry of the reaction chamber 17 facilitates the downward flow of the biomass 6.
  • Said outer coating 71 has an annular shape and is advantageously made of a microporous insulating material.
  • the latter preferably comprises silica, for example powder or reinforcing filaments of pyrogenic silica, to which opacifiers and/or inorganic oxides may be added.
  • said microporous insulating material is produced by the company Promat under the trade name Promalight®, or by the company Bifire under the trade name Microbifire®, or by the company Unifrax under the trade name Excelfrax®.
  • Said outer coating 71 consists of a plurality of overlapping rings 74 made of said microporous insulating material, which guarantee the thermal insulation of the reactor 7.
  • the reactor 7 further comprises a layer 75 of said polycrystalline alumina fiber based material having varying thickness interposed between the reaction chamber 17 and the outer coating 71.
  • the reaction chamber 17 and the layer 75 of the polycrystalline alumina fiber-based material form a monolithic structure.
  • said monolithic structure is sealed on top with the structure by means of a rubber gasket 76; on the bottom, instead, given the high working temperature, it is sealed by means of a polycrystalline alumina fiber-based gasket 77.
  • the hopper 14 shown in Figures 2 and 3 comprises an upper frame (or edge) 78 adapted to support the outer coating 71 through an appropriate support plate 79, preferably annular.
  • an insulating plate 80 which is also preferably annular, made, e.g., with biosoluble refractory fibers, is placed above said support plate 79; said plate 80 ensures the thermal break with the support plate 79 and thus with the hopper 14, as well as an airtight seal.
  • Both the hopper 14 and the support plate 79 are advantageously made of stainless steel.
  • Said hopper 14 further comprises a lip 81, which projects below said frame 78 and defines a support base for the reaction chamber 17 through which the hopper 14 itself receives the produced syngas 8.
  • Said geometry allows creating an annular volume in the upper part of the hopper
  • the syngas feeding duct 13 has a gasket at the interface with the support plate 79 consisting of polycrystalline alumina fiber-based rings 82.
  • the hopper 14 is advantageously insulated from the unloading auger 12 by means of an element 83 made of said microporous insulating material.
  • a first valve 22 separating the biomass 6 (shown in Figures 2 and 3) is placed at the inlet interface of the biomass 6 in the reactor 7, in particular above the buffer 20.
  • a second valve 23 separating the biochar 9 (shown in Figure 2) is positioned at the outlet interface of the biochar 9 from the unloading auger 12.
  • the separation valve 22 of the biomass 6 is opened at the process start-up and allows the inflow of biomass 6 and air into the reactor 7.
  • the air supply although limited, is necessary to support the gasification process by providing heat through the combustion of a small portion of the biomass 6 and the produced syngas 8.
  • the separation valve 23 of the biochar 9 is opened whenever it is necessary to expel the biochar 9, thus operating discontinuously.
  • Said separation valves 22, 23 are butterfly valves and are shown in more detail in Figures 4 and 5.
  • the valve 22, 23 shown in Figure 4 is in the fully closed position while the valve 22, 23 shown in Figure 5 is in the fully open position.
  • the valve 22, 23 according to the embodiment of Figure 4 comprises an actuator 24, a cylindrical valve body 25, a plate-like shutter 26 and an insert 27 shaped as an arc of circumference.
  • the plate-like shutter 26 assumes a position parallel to the longitudinal axis X-X of the cylindrical valve body 25 and the insert 27 adheres to a portion 28 of the edge of the shutter 26 which would otherwise come into contact with the biomass 6 or with the biochar 9.
  • the gap between the valve body 25 and the shutter 26 is filled along the longitudinal axis X-X of the valve body 25, preventing the biomass 6 and the biochar 9 from settling on the edge of the shutter 26, clogging the valve 22, 23 and preventing the proper closing of the valve itself. Therefore, the insert 27 fulfills the function of protecting the seal of the plate-like shutter 26 when the valve 22, 23 is in the fully open position.
  • the gasifier 2 is of the “downdraft” (i.e., the biomass 6 flows downward and the syngas 8 produced transits in the same direction) "open core” (i.e., with air supply from above along with the biomass) type.
  • Figures 6-10 illustrate the assembly consisting of the burner 3 and the Stirling engine 4.
  • the burner 3 comprises: a combustion chamber 30 in which the fuel syngas 8 coming from the gasifier 2 is burned in the presence of combustion air 31 generating hot combustion gases 32; an exhaust system 33, fixed on top of the combustion chamber 30, which receives the exhaust fumes 34 exiting the Stirling engine 4, as further described below; pre-mixing flanges 35 for the fuel syngas 8 and the combustion air 31; a nozzle or duct 36, preferably ceramic, downstream of the pre-mixing flanges 35, which conveys the fuel syngas 8 and the combustion air 31 into the combustion chamber 30.
  • the mixture of fuel syngas 8 and combustion air 31 exiting the nozzle 36 is indicated with the as reference numeral 37 in Figure 8.
  • pre-mixing flanges 35 allow partial cooling of the fuel syngas 8 by means of the combustion air 31.
  • the Stirling engine 4 comprises a high-temperature heat exchanger 38 (so-called “hot exchanger") shown in Figures 7, 8, 10, a low-temperature heat exchanger (so- called “cold exchanger”), a regenerator and an electric generator 39.
  • the cold exchanger and the regenerator are not visible in the figures.
  • the hot exchanger 38 of the Stirling engine is inserted inside the combustion chamber 30.
  • a tubular element 40 Downstream of the hot exchanger 38 of the Stirling engine, a tubular element 40 is placed, also indicated as a cooling ring, inside which a cooling fluid flows, so that heat transfer downstream of said hot exchanger 38 is prevented.
  • the cooling ring 40 performs the thermal break function between the burner 3 and the Stirling engine 4, preventing unwanted heat from entering the part of the Stirling engine 4 under the hot exchanger 38 and safeguarding the underlying components from excessive heating.
  • the combustion chamber 30 of the burner 3 consists of a cylinder which integrates connections for the feeding duct 13 of the fuel syngas 8 coming from the gasifier 2 and for the feeding duct 41 of the combustion air 31. Furthermore, the combustion chamber 30 integrates the attachment flange 42 to the Stirling engine 4 and the attachment flange 43 to the exhaust system 33. A bell 44 and a means 45 made of porous ceramic material (porous ceramic means 45) are placed inside the combustion chamber 30 of the burner 3.
  • Said bell 44 is open at the bottom and houses the hot exchanger 38 of the Stirling engine inside.
  • said hot exchanger 38 is inserted from the open bottom of the bell 44.
  • Said bell 44 is such to convey the hot combustion gases 32 into the hot exchanger 38, where they undergo heat exchange providing heat and generating exhaust fumes 34 (or combustion fumes 34).
  • said bell 44 constrains the hot combustion gases 32 to flow through the entire hot exchanger 38 with minimal heat dissipation to the outside, thus optimizing the heat exchange with the Stirling engine 4.
  • Said bell 44 comprises steel walls internally lined with a refractory insulating material, as further described below with reference to Figure 11.
  • the aforementioned nozzle or duct 36 may be replaced by a hole made in said refractory insulating material, such as to convey the fuel syngas 8 and the combustion air 31 inside the combustion chamber 30.
  • the porous ceramic means 45 is housed in the upper part of the bell 44 above the hot exchanger 38 and is supported at least partially by the refractory insulating material of the bell 44. Said porous ceramic means 45 is an optimized combustion volume in which the syngas 8 is combusted in the presence of combustion air 31 generating hot combustion gases 32 ( Figure 8). Furthermore, the porous means 45 allows a homogeneous temperature distribution, ensuring optimal heat exchange with the Stirling engine 4 and low polluting emissions.
  • the bell 44 is open at the bottom and the hot exchanger of the Stirling engine is inserted in its inside (not shown in Figure 11). Said bell 44 is delimited by an upper wall 47 and side walls 48. Said walls 47, 48 are made of steel and are internally lined with a refractory insulating material, e.g., based on polycrystalline alumina fiber. For example, said material is produced by the company Schupp under the trade name ITM-Fibermax®, preferably Blanket 1600-130.
  • the upper steel wall 47 is internally coated with a layer 49 of polycrystalline alumina fiber-based material.
  • said layer 49 is further coated, at its ends, with two layers 50 of polycrystalline alumina fiber-based material, which act as spacers defining a space 51 interposed therebetween for the passage of the mixture 37 of syngas and combustion air exiting the nozzle 36.
  • Said layers 50 can have variable thickness and size; consequently, the space 51 interposed therebetween has variable thickness and inner diameter as well.
  • the steel side walls 48 are internally coated with first layers 52 of polycrystalline alumina fiber having a given thickness and with second layers 53 of polycrystalline alumina fiber having a different thickness, in this case a greater thickness.
  • the porous ceramic means 45 is housed between said layers 52 of insulating material. Consequently, by means of said layers 52, the porous ceramic means 45 is thermally insulated from the bell 44.
  • the porous ceramic material from which the means 45 is made is produced by the company Lanik under the trade name Vukopor® S or Vukopor® HT.
  • the bell 44 comprises an additional element 54 made of refractory insulating material, e.g., based on polycrystalline alumina fiber, immediately below the porous ceramic means 45, such as to prevent unwanted entry of heat through the top of the Stirling engine below.
  • Said element 54 mimics the shape of the upper dome of the hot exchanger 38 of the Stirling engine, visible in Figures 7, 8, 10.
  • the exhaust system 33 mentioned above receives the combustion fumes 34 exiting the hot exchanger 38 of the Stirling engine 4, once the latter have traveled upward through the gap 46 present between the combustion chamber 30 and the bell 44.
  • Said exhaust system 33 comprises an exhaust 55 from which combustion fumes 34 escape, a heat exchanger 56 connected to said exhaust 55 for recovering heat from the exhaust fumes 34 (Figure 10), a lambda probe 57 which provides a signal based on which the air-syngas ratio at the inlet of burner 3 is adjusted ( Figures 6, 10), and a thermocouple 58 which measures the temperature of the combustion fumes 34 ( Figures 6, 10).
  • An extraction fan 59 (shown in Figures 6 and 10) of the combustion fumes 34 is connected to said heat exchanger
  • Said extraction fan 59 has variable speed.
  • the micro-cogenerator 1 can advantageously be coupled to electrical energy storage systems (batteries) and thermal energy accumulation systems (puffers). The remaining capacity is measured for both accumulations so that micro-cogenerator 1 will only turn on if a minimum operating time necessary for heat regulation of all syngas ducts is guaranteed.
  • a temperature probe is used for the puffer, and a voltage probe is used for the batteries.
  • SoC state of charge
  • the micro-generator 1 is equipped with an electronic control, which manages the operation of the machine through the installed sensors and actuators and is independently powered by on-board batteries so that it can be safely shut down even in case the external electrical connection is interrupted. To be able to start up, the micro-generator 1 checks for the presence of the external power grid (both
  • the pyrolytic gasification process is started by means of the electric heater 18, which brings the biomass 6 to the gasification temperature, e.g., about 900°C.
  • the separation valve 22 of the biomass 6 is opened.
  • the extraction fan 59 is activated with a speed proportional to the temperature of the electric heater 18.
  • the biomass 6 is fed into the reactor 7 of the pyrolytic gasifier 2, through the inlet 11, by means of the loading auger 10.
  • the biomass loading auger 10 When the filling level of the buffer 20 is under a given threshold, the biomass loading auger
  • reaction front advances from the bottom to the top where biomass 6 not yet gasified is located.
  • thermocouple 19 keeps the temperature of the upper part of the reaction chamber 17 monitored; when the integral over time of the temperature measured by thermocouple 19 exceeds a given threshold value of said integral, the separation valve 23 of the biochar 9 is opened, the unloading auger 12 is started and part of the biochar 9 is extracted. In this manner, the reacting biomass 6 is made to flow downward and along with it the reaction front as well, which remains confined to the reaction zone delimited between the thermocouple 19 and the electric heater 18.
  • the gasifier 2 once fully operational, works with a slow and intermittent flow of biomass 6 such as to maintain the reaction front within the aforementioned reaction zone.
  • the extraction fan 59 By operating the extraction fan 59, the system consisting of the gasifier 2 and the burner 3 is depressurized and the inflows of fuel syngas 8 from the gasifier 2 to the burner 3 and of air to both the gasifier 2 and the burner 3 are adjusted.
  • the extraction fan 59 By operating the extraction fan 59, the combustion fumes 34 are extracted which travel upward through the gap 46 between the combustion chamber 30 and the bell 44, creating a vacuum inside the burner 3. In turn, the fuel syngas 8 exiting the gasifier 2 and the combustion air 31 are sucked into the combustion chamber 30 of the burner, respectively, through the supply ducts 13 and 41. In turn, air is sucked into the gasifier 2.
  • the fuel syngas 8 and the combustion air 31 are sucked inside the combustion chamber 30 passing through the pre mixing flanges 35, then the nozzle 36, until they arrive inside the porous ceramic means 45, which defines the volume in which the combustion takes place with the generation of the hot combustion gases 32.
  • the hot combustion gases 32 are subjected to heat exchange within the hot exchanger 38 of the Stirling engine 4, from which heat is recovered that puts the electric generator 39 in oscillation, thus obtaining the aforementioned combustion fumes 34 resulting from said heat exchange.
  • the combustion fumes 34 are extracted through the extraction fan 59. Said combustion fumes 34 travel upward through the cavity 46 present between the combustion chamber 30 and the bell 44, pass through the exhaust 55 on which the lambda probe 57 and the thermocouple 58 are placed, then they are fed to the heat exchanger 56 for recovery of the heat contained therein.
  • the lambda probe 57 adjusts the air-syngas ratio accurately by virtue of the valve 60 located on the inlet duct 41 of the combustion air 31, adjusting the pressure drop and thus the inflow. More specifically, the lambda probe 57 provides a signal based on which the aforementioned air-syngas ratio is accurately adjusted.

Abstract

The present invention relates to a process of cogeneration of electrical energy and heat starting from biomass (6) in a micro-cogenerator (1), said process comprising: i) feeding the biomass (6) to a pyrolytic gasifier (2) where it reacts thus generating syngas (8); ii) feeding the syngas (8) to a burner (3) where it is burned thus generating combustion gases (32); iii) subjecting the combustion gases (32) to heat exchange in the hot exchanger of a Stirling engine (4), with exhaust fumes (34) being obtained, during said step ii) the air-syngas ratio is adjusted based on a signal provided by a lambda probe (57) crossed by a flow of said exhaust fumes (34), said process comprising a start-up phase the micro-cogenerator (1) which comprises, in turn, a step a) of detecting the presence of syngas (8) inside the burner (3) and a subsequent step b) of ignition of the burner (3), wherein: said first step a) comprises calculating the integral over time of the temperature of the reaction chamber (17) of the pyrolytic gasifier (2) and calculating the integral over time of the value read by said lambda probe (57), during said step a) the value of the integral over time of the temperature is compared with a preset threshold value of said integral and, when said threshold value is exceeded, the value of the integral over time of the value read by the lambda probe (57) is, in turn, compared with a corresponding threshold value until it is exceeded, said second step b) is started when the latter threshold value is exceeded.

Description

COGENERATION PROCESS AND RELATED APPARATUS
Description
Field of the invention
The present invention relates to a process of cogeneration of electrical energy and heat and the related apparatus. In particular, the present invention relates to a process of cogeneration of electrical energy and heat and the related apparatus for household or small consumer use, starting from a renewable and sustainable energy source, e.g., woody biomass.
Background art
The need to search for solutions suited to new values and lifestyles is increasingly felt at a point in history in which the transition from a linear economy logic (in which every process creates new waste) to a circular economy logic has become vitally important, and in which fossil fuels are becoming increasingly scarce and expensive. Self-generation is the most suitable answer in terms of sustainability, autonomy, and safety in electrical energy production.
Biomass-fueled cogeneration systems consisting of three basic parts, i.e. a pyrolytic gasifier, a burner, and a Stirling engine, are well known. The fuel syngas is produced starting from the biomass in the pyrolytic gasifier; the syngas produced is burned with a controlled supply of air in the burner; the Stirling engine, by virtue of the heat generated by the combustion of the syngas, sets the electric generator in oscillation, thus producing electrical energy. Pyrolytic gasification is a thermal-chemical process by virtue of which a combustible gas (syngas), comprising a mixture of hydrogen, carbon monoxide, methane and, to a lesser extent, other compounds, can be extracted from organic material, such as biomass. Pyrolytic gasification occurs by maintaining the biomass at a particularly high temperature in a low-oxygen environment. The by-product of pyrolytic gasification is a solid residue, named char, which contains almost exclusively carbon.
The use of pyrolytic gasification, compared with direct combustion of the biomass, reduces carbon emissions into the atmosphere because, once the fuel syngas is extracted, only the char remains which contains the portion of carbon that will not be emitted into the atmosphere in the form of CO2, but is evacuated in solid form and collected. Furthermore, the use of pyrolytic gasification provides a fuel gas which is much more effective in the combustion in terms of maximum achievable temperature, emissions of particulate matter and heating of the heat exchangers. Examples of cogenerators based on the application of the pyrolytic gasification and the Stirling engine are described in US 2009/0078176 and US 2006/0089516.
However, to date, the need is increasingly felt to maximize syngas combustion efficiency and heat exchange with the Stirling engine, and to minimize the production of pollutant gases, making combustion safe under all circumstances and simplifying construction and periodic maintenance. Other requirements that are currently very much in demand, especially in CHP systems for domestic use, concern the quietness of the system and the ability to start and stop the gasification process according to the energy demands of the consumer.
Until today, there is no cogeneration system for domestic, or small consumers, use that can meet all of the above benefits.
Therefore, the problem underlying the present invention is to make available a cogeneration process for domestic use and related apparatus capable of high- performance characteristics under all circumstances and of meeting all the requirements explained above.
Summary of the invention
The problem presented above is solved by a process of cogeneration of electrical energy and heat and the related apparatus as outlined in the accompanying claims, the definitions of which form an integral part of the present description.
A first object of the invention is a process of cogeneration of electrical energy and heat starting from a renewable and sustainable energy source, preferably woody biomass, in a micro-cogenerator comprising a pyrolytic gasifier, a burner, and a Stirling engine, said process comprising the following steps: i) feeding said energy source to the pyrolytic gasifier which comprises a reaction chamber inside which said energy source reacts thus generating syngas and biochar; ii) feeding the syngas generated during step i) to said burner which comprises a combustion chamber inside which the syngas is burned in the presence of combustion air thus generating hot combustion gases; iii) subjecting said hot combustion gases to heat exchange in a heat exchanger (the so-called "hot exchanger") of the Stirling engine adapted to generate electrical energy, obtaining exhaust fumes deriving from said heat exchange, during said step ii), the ratio of combustion air to syngas being adjusted based on a signal provided by a lambda probe crossed by a flow of said exhaust fumes said process comprising a start-up phase of the micro cogenerator and a full operation phase (regime phase) following said start-up phase, and being characterized in that said start-up phase comprises a first step a) of detecting the presence of syngas inside the burner and a subsequent step b) of ignition of the burner, wherein: said first step a) comprises calculating the integral over time of the temperature of the reaction chamber of the pyrolytic gasifier and calculating the integral over time of the value read by said lambda probe, during said step a) the calculated value of the integral over time of the temperature of the reaction chamber is compared with a preset threshold value of said integral (the so-called first threshold value) and, when said first threshold value is exceeded, the calculated value of the integral over time of the value read by the lambda probe is compared with a preset threshold value of said integral (so-called second threshold value) until it is exceeded, the exceeding of said second threshold value being an indication of the presence of syngas and of the substantial absence of air inside the burner, said second step b) is started when said second threshold value is exceeded and comprises an increasing supply of combustion air into the combustion chamber of said burner until the ignition of a flame. According to an embodiment, said step b) further comprises the generation of an ignition spark; more in particular, said ignition spark is advantageously generated before the supply of said combustion air. Alternatively, said ignition spark is generated at the beginning of the start-up phase. Said ignition spark of the flame is generated by a high-voltage electronic transformer. Advantageously, the onset (ignition) of the combustion inside the burner is performed by means of an electric arc generated by a high-voltage electronic transformer and related electrodes appropriately positioned, such as to be lapped by the gas flow.
The expression "first threshold value" means the preset threshold value of the integral over time of the temperature of the reaction chamber of the pyrolytic gasifier. The expression "second threshold value" means the preset threshold value of the integral over time of the value read by the lambda probe.
Advantageously, the process according to the present invention allows detecting the time when the pyrolytic gasifier begins to produce fuel syngas and, consequently, the time when the latter is available for combustion in the burner. Detecting the presence of fuel syngas in the burner is critical to identify the exact moment in which the burner can be ignited, the latter being a crucial stage for the following reasons.
An excessively long wait before ignition of the burner would result in the emission of unburned syngas, rich in pollutants such as carbon monoxide and methane, into the atmosphere .
Conversely, an excessively short wait before ignition of the burner could cause a burst inside the combustion chamber that could risk damaging some components of the micro-cogenerator. Furthermore, given the application in the domestic scope, it is desirable for the micro cogenerator to be silent; therefore, generating a burst whenever the burner is ignited is highly undesirable.
According to a preferred embodiment, said start-up phase further comprises a step c) of detecting the presence of the flame in the combustion chamber of the burner. During said step c), the derivative of the temperature, i.e., the temperature gradient, of the combustion chamber with respect to time is compared with a preset threshold value of said derivative; the exceeding of said threshold value is an indication of the presence of the flame. In a preferred embodiment of the invention, two thermocouples are placed in the hot exchanger of the Stirling engine and, during the aforesaid step c), the value of the gradient of the average temperature of the two thermocouples is compared with said threshold value.
The lambda probe provides an electrical signal (in mV) through which it is possible to have a measurement of the "lambda value (l) " properly so called, i.e., the ratio between the actual AFR (air-fuel-ratio) and the stoichiometric AFR (air-fuel-ratio); in other words, the "lambda value (X) " properly so called is to be understood as the ratio of air to fuel relative to the stoichiometric ratio of the fuel used. The electrical signal provided by the lambda probe is an indirect measurement of said lambda value (X); the higher the value of the electrical signal, the lower the lambda value (X).
In this description, the "value read by the lambda probe" means the electrical signal provided by the lambda probe, while the "lambda value (X) " means the theoretical value properly so called as defined above.
Generally, a lambda value (X) equal to 0 indicates the presence of syngas only and the absence of air, a lambda value (X) of 1 indicates the presence of air in stoichiometric amount, and a lambda value (X) greater than 1 indicates the presence of air in excess of the amount strictly necessary for syngas combustion. During the aforesaid step a), the lambda value (X) is 0 or close to 0, e.g., it is comprised between 0 and 0.2. During the aforesaid steps b) and c), the lambda value (l) is higher, preferably it is about 1, e.g., it is comprised between
0.9 and 1.1. During the regime phase, the value read by the lambda probe is lower than during the start-up phase, hence the lambda value (l) is higher; preferably the lambda value (l) is higher than 1, e.g., is comprised between 1.1 and 1.5.
The mV values of the electrical signal provided by the lambda probe, indicated in the present patent application, were detected experimentally with the lambda probe NGK - OZA685-WW1.
According to a preferred embodiment, said step c) further comprises a control of the value read by the lambda probe. Advantageously, a value comprised between 0 and 1000 mV, e.g., comprised between 5 and 960 mV, or between
10 and 900 mV, or between 50 and 800 mV, is an indication of the presence of the flame.
The expression "threshold value" means a calibratable threshold value, i.e., subject to calibration by means of experimental tests.
During the aforesaid step a) of the start-up phase, the threshold value of the integral over time of the temperature of the reaction chamber of the gasifier (first threshold value) is preferably comprised between 5000 and 25000 °C-s, more preferably between 10000 and 20000 °C-s even more preferably between 13000 and 18000 °C-s, e.g., it is 15000 °C-s.
During the aforesaid step a) of the start-up phase, the threshold value of the integral over time of the value read by the lambda probe (second threshold value) is preferably comprised between 500 and 5000 mV-s, more preferably between 800 and 3000 mV-s, even more preferably between 1000 and 2000 mV-s, e.g, it is 2000 mV-s.
Preferably, the aforesaid integral over time of the temperature of the reaction chamber of the gasifier is calculated, then compared with the corresponding threshold value (first threshold value), for temperatures of the reaction chamber of the gasifier of at least 300°C, preferably of at least 400°C, or at least 500°C, or at least 600°C, or at least 700°C, or at least 800°C.
Preferably, the aforesaid integral over time of the value read by the lambda probe is calculated, then compared with the corresponding threshold value (second threshold value), for values read by the lambda probe of at least 400 mV, preferably of at least 500 mV, or at least 600 mV, or at least 700 mV, or at least 800, or at least 900, or at least 1000 mV. For example, the integral over time of the value read by the lambda probe is calculated, then compared with the corresponding threshold value, for values read by the lambda probe of at least 850 mV. During the aforesaid step c) of the start-up phase the threshold value of the derivative of the temperature of the combustion chamber with respect to time is preferably comprised between 0.1 and 5.0 °C/s, more preferably between 0.3 and 2.0 °C/s, even more preferably between 0.5 and 1.0 °C/s, e.g., it is 0.5°C/s.
Advantageously, the regime phase is started at the end of the start-up phase and is characterized by a lower value read by the lambda probe, i.e., a higher combustion air-syngas ratio, than the start-up phase. More advantageously, the regime phase is started at the end of said step c).
During the aforesaid step ii), the combustion air- syngas ratio is regulated by a lambda probe crossed by a flow of said exhaust fumes, meaning that said combustion air-syngas ratio is adjusted based on the signal provided by said lambda probe.
During said step ii), the combustion air inflow is advantageously adjusted by means of an electronically- driven motorized valve. Advantageously, such a valve is driven based on a signal provided by the lambda probe, i.e., based on the information provided by the lambda probe about the amount of air present in the exhaust fumes. As already mentioned above, during the regime phase, air in excess of the amount strictly necessary for syngas combustion will be present in the exhaust fumes. For example, the excess air is comprised between 1 and 15%, or between 3 and 10%.
The need to carefully control the amount of air is related to the fact that performance (in terms of burner power) and emissions (CO, NOx) are strongly affected by the fuel/combustion air ratio. An optimal ratio of combustion air to syngas can be maintained by virtue of the signal provided by the lambda probe. Said ratio of combustion air to syngas is kept substantially constant during the regime phase.
Advantageously, through experimental tests, the optimal value read by the lambda probe is identified as compromise between performance and emissions, which is used as an input to a PID controller. As already mentioned above, the optimal lambda value (l) during the regime phase is greater than 1. More in particular, the position of the valve which regulates the combustion air supply is calculated by a PID (Proportional Integrative Derivative) control, which takes as input the value read by the lambda probe and outputs the position of the air adjustment valve. During the start-up phase as well, the position of the valve which adjusts the supply of combustion air is calculated by a PID control. According to a preferred embodiment, during step ii) the syngas exiting the pyrolytic gasifier is sucked into the combustion chamber of the burner by virtue of the presence of a vacuum generated by an appropriate extraction fan of said exhaust fumes. Preferably, said extraction fan is active with a speed proportional to the temperature of the reaction chamber of the pyrolytic gasifier during the start-up phase.
According to alternative embodiments of the present invention, during the regime phase the extraction fan is driven by taking into account a power error (or delta) or by taking into account a temperature error (or delta).
In other words, according to a first embodiment, during the regime phase the electrical power of the micro- cogenerator is compared with a target electrical power thus obtaining a power delta, and the speed of the extraction fan is adjusted, i.e., increased or decreased as needed, as a function of the power delta thus obtained. According to this embodiment, the speed of the extraction fan is increased until the temperature of the burner exceeds a predetermined limit value.
According to an alternative embodiment, during the regime phase the temperature of the burner is compared with a target temperature thus obtaining a temperature delta and the speed of the extraction fan is adjusted i.e., increased or decreased as needed, as a function of the temperature delta.
For ease of reference, the terms energy source and biomass will be used indiscriminately in the description below. Therefore, the term biomass should by no means be understood as limiting.
According to a preferred embodiment, during both the start-up phase and the regime phase, the biomass is fed to the pyrolytic gasifier through an appropriate loading auger. The latter is advantageously started whenever the filling level of a connecting element (so-called "buffer") between the loading auger and the inlet of the reaction chamber of the pyrolytic gasifier is below a predetermined threshold value. The filling level of said connecting element is advantageously detected by a suitable sensor, preferably based on ultrasound technology.
According to a preferred embodiment, the reaction chamber of the pyrolytic gasifier is maintained at a suitable gasification temperature at which the biomass reacts generating syngas and biochar. Said gasification temperature is preferably comprised between 1000°C and 1200°C to maximize syngas production.
Preferably, the reaction front of the biomass inside the gasifier is comprised between an upper limit and a lower limit, and the biomass under reaction is supported by the biochar accumulated in the gasifier as long as the integral over time of the temperature of the upper limit of the reaction front does not exceed a preset threshold value of said integral; when said threshold value is exceeded, the biochar is at least partially discharged through an unloading auger causing the reaction front to lower so that it is maintained between said upper limit and said lower limit.
The expression "threshold value" means a calibratable threshold value, i.e., subject to calibration by means of experimental tests.
The aforesaid threshold value of the integral over time of the temperature of the upper limit of the biomass reaction front inside the gasifier is preferably comprised between 10000 and 90000 °C-s, more preferably between 15000 and 80000 °C-s, even more preferably between 20000 and
70000 °C-s, e.g., is 50000 °C-s.
Preferably, the aforesaid integral over time of the temperature of the upper limit of the biomass reaction front inside the gasifier is calculated, then compared with the corresponding threshold value, for temperatures of said upper limit of at least 300°C, preferably of at least 400°C, or at least 500°C, or at least 600°C, or at least 700°C, or at least 800°C. According to a preferred embodiment, said lower limit is defined by an electric heater placed inside the reaction chamber by virtue of which the gasification reaction of the biomass is initiated, while said upper limit is defined by a thermocouple designed to monitor the temperature in the upper part of the reaction chamber. This means that the reaction front of the biomass is comprised between said electric heater and said thermocouple. The aforesaid heater integrates a special sensor inside it, e.g., a thermocouple.
The expression "temperature of the reaction chamber of the gasifier" means the temperature of the electric heater when the process according to the present invention is in its start-up phase, and it means the temperature measured by the thermocouple when the process according to the present invention is in its regime phase.
A further object of the present invention is a micro cogenerator comprising: a pyrolytic gasifier adapted to produce syngas and biochar starting from a renewable and sustainable energy source, preferably woody biomass, a burner adapted to receive the syngas produced by said pyrolytic gasifier and to generate hot combustion gases a Stirling engine comprising a heat exchanger (the so-called "hot exchanger") fed with said hot combustion gases, said Stirling engine being adapted to generate electrical energy, wherein said burner comprises: a combustion chamber inside which the syngas is burned in the presence of combustion air, pre-mixing flanges for the syngas and the combustion air upstream of the combustion chamber, a means downstream of said pre-mixing flanges adapted to convey the syngas and the air into the combustion chamber, said micro-cogenerator being characterized in that said combustion chamber comprises: a bell open at the bottom inside which the hot exchanger of the Stirling engine is housed, said bell being adapted to convey the hot combustion gases into said hot exchanger and comprising steel surfaces internally coated, at least partially, with a refractory insulating material having low thermal inertia and high thermal reflectivity, an element made of a porous ceramic material housed in the upper part of the bell above the heat exchanger of the Stirling engine, said element made of porous ceramic material being at least partially supported by the refractory insulating material and representing an optimized combustion volume inside which the syngas is burned in the presence of combustion air.
As will become apparent from the following description, the exhaust fumes resulting from the heat exchange of the hot combustion gases feeding said heat exchanger escape from the hot exchanger of the Stirling engine.
According to a first embodiment, said means adapted to convey syngas and air into the combustion chamber consists of a nozzle or a duct; preferably, said nozzle or duct is made of ceramic material.
According to a second embodiment, said means is a hole made in the insulating material that internally lines the bell. According to this embodiment, said insulating material has a hole at the outlet of the pre-mixing flanges.
In addition to constraining the hot combustion gases to flow through the entire hot exchanger of the Stirling engine, the aforesaid bell also has the advantage of optimizing heat exchange by radiation.
For the sake of brevity, in this description, the element made of porous ceramic material will be also referred to as a "porous ceramic means".
The porous ceramic means is thermally insulated from the bell by virtue of the presence of the refractory insulating material covering it. Advantageously, said porous ceramic means allows to stabilize the combustion, optimize the distribution thereof, and extend the flammability limit to higher air-fuel ratios, thus allowing to reduce polluting emissions at the exhaust.
According to a preferred embodiment, said combustion chamber comprises an additional element made of refractory insulating material interposed between said porous ceramic means and said hot exchanger of the Stirling engine. Said additional element has the advantage of preventing the unwanted entrance of heat into a part of the Stirling engine where it would reduce the thermodynamic efficiency of the engine itself.
According to a preferred embodiment, said refractory insulating material is a polycrystalline alumina fiber- based material, which ensures high reflection of radiations and reduced heat accumulation. Preferably, said material comprises at least 70% by weight of polycrystalline alumina, preferably at least 75% by weight, more preferably at least 80% by weight, for example about 90% by weight. Preferably, said material further comprises at least 5% by weight of silica, preferably between 10% and 30% by weight of silica, more preferably between 10% and 25% by weight of silica, even more preferably between 10% and 20% by weight of silica. For example, said polycrystalline alumina fiber-based material is produced by the company Schupp under the trade name ITM-Fibermax®, preferably Blanket 1600-130.
According to an embodiment, said porous ceramic material comprises silicon carbide, alumina and silica. Preferably, said porous ceramic material is produced by the company Lanik under the trade name Vukopor® S.
According to another embodiment, said porous ceramic material comprises alumina, silica, zirconia and magnesium oxide. Preferably, said porous ceramic material is produced by the company Lanik under the trade name Vukopor® HT.
According to a preferred embodiment, the micro generator comprises a cooling ring downstream of the hot exchanger of the Stirling engine inside which a cooling fluid flows. Said cooling ring is such to prevent heat transfer downstream of said hot exchanger, preventing the entry of unwanted heat into the part of the Stirling engine below the hot exchanger, which comprises, for example, a regenerator, a low-temperature heat exchanger and an electric generator, safeguarding these components from an excessive heating.
By virtue of the above-mentioned special features, the process and the micro-cogenerator according to the present invention advantageously allow to maximize the syngas combustion efficiency, minimize the production of polluting gases, maximize the heat exchange with the Stirling engine, minimize the entry of heat through unwanted points of the engine which would reduce the efficiency thereof, minimize the heat capacity of the elements close to the hot exchanger of the Stirling engine and reduce the thermal inertia in case of an emergency shutdown, make combustion safe under all circumstances, simplify construction and periodic maintenance. Further features and advantages of the invention will be apparent from the description of some embodiments, given here by way of a non-limiting example.
Brief description of the drawings
Figure 1 shows a section of the micro-cogenerator according to an embodiment of the present invention.
Figure 2 shows a section of the pyrolytic gasifier of the micro-cogenerator according to an embodiment of the present invention.
Figure 3 shows a section of the assembly comprising the reactor and the hopper of the pyrolytic gasifier according to an embodiment of the present invention.
Figure 4 shows a perspective view of a butterfly valve according to an embodiment of the present invention adapted to allow the inflow of the biomass into the reactor of the gasifier shown in Figure 3 or the evacuation of the biochar from said reactor, if necessary.
Figure 5 shows a detail of the butterfly valve of Figure 4 when said valve is in the fully open position. Figure 6 shows a first view of the assembly consisting of the burner and the Stirling engine according to an embodiment of the present invention.
Figure 7 shows the section, along the axis A-A shown in Figure 6, of the assembly consisting of the burner and the Stirling engine according to an embodiment of the present invention.
Figure 8 shows a detail of the burner shown in Figure
7.
Figure 9 shows a second view of the assembly consisting of the burner and the Stirling engine according to an embodiment of the present invention.
Figure 10 shows the section, along the axis C-C shown in Figure 9, of the assembly consisting of the burner and the Stirling engine according to an embodiment of the present invention.
Figure 11 shows a cross-section of the combustion chamber of the burner shown in Figures 6 and 9.
Detailed description of the figures With reference to Figure 1, a micro-cogenerator according to an embodiment of the present invention is globally indicated with reference numeral 1.
Said micro-cogenerator 1 comprises a pyrolytic gasifier 2, a burner 3, and a Stirling engine 4.
The pyrolytic gasifier 2 is shown in more detail in Figure 2, while the burner 3 and the Stirling engine 4 are more visible in Figures 6-10.
The gasifier 2 in Figure 2 comprises: a storage container 5 of the biomass 6; a reactor 7 inside which the biomass 6 is gasified generating combustible syngas 8 and biochar 9; a loading auger 10 of the biomass 6 which connects the container 5 to the inlet 11 of the reactor 7; an unloading auger 12 through which the biochar 9 is evacuated; an outlet duct 13 for the combustible syngas 8, through which the latter is fed to the burner 3; a hopper 14, which connects the outlet 15 of the reactor 7 to the unloading auger 12 of the biochar 9, and through which the combustible syngas 8 is sucked into the duct 13; a collection container 16 of the biochar 9 extracted from the reactor 7. The reactor 7 defines a reaction chamber 17 and comprises an electric heater 18 and a thermocouple 19. The electric heater 18 brings the biomass contained in the reaction chamber 17 to the gasification temperature of, e.g., 900°C, while the thermocouple 19 monitors the temperature in the upper part of the reaction chamber 17 during the gasification process. The heater 18 and the thermocouple 19, respectively, represent the lower limit and the upper limit of the zone within which the biomass reaction front 6 must be maintained.
A connecting element 20, named "buffer", is interposed between the loading auger 10 of the biomass 6 and the inlet 11 of the reactor 7. A sensor 21 detects the filling level of the buffer 20, and the loading auger 10 of the biomass 6 is started whenever said sensor 21 detects that the filling level of the buffer 20 is below a predetermined threshold value.
The biomass 6 under reaction is supported by the biochar 9 generated during the pyrolytic gasification process seamlessly inside the reaction chamber 17. Advantageously, the pyrolytic gasifier 2 according to the present invention has no support grid for the biomass under reaction which separates it from the spent biochar 9.
Preferably, the unloading auger 12 and the hopper 14 are constantly kept full of biochar 9. The reactor 7 of the pyrolytic gasifier 2 is shown in greater detail in Figure 3.
As mentioned above, the reactor 7 comprises a reaction chamber 17 in which the biomass 6 is gasified in the presence of a given amount of air (sub-stoichiometric). The reactor 7 further comprises an outer coating 71 with respect to said reaction chamber 17. Said reaction chamber 17 has truncated-cone shape and is advantageously made of a polycrystalline alumina fiber-based material. Preferably, said material comprises at least 70% by weight of polycrystalline alumina, preferably at least 75% by weight, more preferably at least 80% by weight, for example about 90% by weight. Preferably, said material further comprises at least 5% by weight of silica, preferably between 10% and 30% by weight of silica, more preferably between 10% and 25% by weight of silica, even more preferably between 10% and 20% by weight of silica. Preferably, said material has a density comprised between 350 and 500 kg/m3. For example, said polycrystalline alumina fiber- based material is produced by the company Unifrax under the trade name High Temperature Saffil® Rigiform™.
Preferably, said material is produced by the company
Unifrax under the trade name Saffil® 160 HD. The reaction chamber 17 has an upper surface 72 and a lower surface 73, wherein the diameter of the upper surface 72 is slightly smaller than the diameter of the lower surface 73 in order to give an adequate draft angle, e.g., about 4°, to the inner surface of the reaction chamber 17. For example, the diameter of the upper surface 72 is comprised between 70 and 90 mm and the diameter of the lower surface 73 is comprised between 100 and 120 mm. Said geometry of the reaction chamber 17 facilitates the downward flow of the biomass 6.
Said outer coating 71 has an annular shape and is advantageously made of a microporous insulating material. The latter preferably comprises silica, for example powder or reinforcing filaments of pyrogenic silica, to which opacifiers and/or inorganic oxides may be added. For example, said microporous insulating material is produced by the company Promat under the trade name Promalight®, or by the company Bifire under the trade name Microbifire®, or by the company Unifrax under the trade name Excelfrax®. Said outer coating 71 consists of a plurality of overlapping rings 74 made of said microporous insulating material, which guarantee the thermal insulation of the reactor 7.
In the example in Figure 3, the reactor 7 further comprises a layer 75 of said polycrystalline alumina fiber based material having varying thickness interposed between the reaction chamber 17 and the outer coating 71. Preferably, the reaction chamber 17 and the layer 75 of the polycrystalline alumina fiber-based material form a monolithic structure. According to a specific example, said monolithic structure is sealed on top with the structure by means of a rubber gasket 76; on the bottom, instead, given the high working temperature, it is sealed by means of a polycrystalline alumina fiber-based gasket 77.
The hopper 14 shown in Figures 2 and 3 comprises an upper frame (or edge) 78 adapted to support the outer coating 71 through an appropriate support plate 79, preferably annular. In the example of Figure 3, an insulating plate 80, which is also preferably annular, made, e.g., with biosoluble refractory fibers, is placed above said support plate 79; said plate 80 ensures the thermal break with the support plate 79 and thus with the hopper 14, as well as an airtight seal. Both the hopper 14 and the support plate 79 are advantageously made of stainless steel.
Said hopper 14 further comprises a lip 81, which projects below said frame 78 and defines a support base for the reaction chamber 17 through which the hopper 14 itself receives the produced syngas 8. Said geometry allows creating an annular volume in the upper part of the hopper
14 through which the syngas 8 is sucked into the duct 13.
The syngas feeding duct 13 has a gasket at the interface with the support plate 79 consisting of polycrystalline alumina fiber-based rings 82.
The hopper 14 is advantageously insulated from the unloading auger 12 by means of an element 83 made of said microporous insulating material.
A first valve 22 separating the biomass 6 (shown in Figures 2 and 3) is placed at the inlet interface of the biomass 6 in the reactor 7, in particular above the buffer 20. A second valve 23 separating the biochar 9 (shown in Figure 2) is positioned at the outlet interface of the biochar 9 from the unloading auger 12. The separation valve 22 of the biomass 6 is opened at the process start-up and allows the inflow of biomass 6 and air into the reactor 7. The air supply, although limited, is necessary to support the gasification process by providing heat through the combustion of a small portion of the biomass 6 and the produced syngas 8.
The separation valve 23 of the biochar 9 is opened whenever it is necessary to expel the biochar 9, thus operating discontinuously.
Said separation valves 22, 23 are butterfly valves and are shown in more detail in Figures 4 and 5. The valve 22, 23 shown in Figure 4 is in the fully closed position while the valve 22, 23 shown in Figure 5 is in the fully open position.
The valve 22, 23 according to the embodiment of Figure 4 comprises an actuator 24, a cylindrical valve body 25, a plate-like shutter 26 and an insert 27 shaped as an arc of circumference.
When said valve 22, 23 is in the fully open position (Figure 5), the plate-like shutter 26 assumes a position parallel to the longitudinal axis X-X of the cylindrical valve body 25 and the insert 27 adheres to a portion 28 of the edge of the shutter 26 which would otherwise come into contact with the biomass 6 or with the biochar 9. In this manner, the gap between the valve body 25 and the shutter 26 is filled along the longitudinal axis X-X of the valve body 25, preventing the biomass 6 and the biochar 9 from settling on the edge of the shutter 26, clogging the valve 22, 23 and preventing the proper closing of the valve itself. Therefore, the insert 27 fulfills the function of protecting the seal of the plate-like shutter 26 when the valve 22, 23 is in the fully open position.
In light of the aforesaid description, it is apparent that the gasifier 2 is of the "downdraft" (i.e., the biomass 6 flows downward and the syngas 8 produced transits in the same direction) "open core" (i.e., with air supply from above along with the biomass) type.
As mentioned above, Figures 6-10 illustrate the assembly consisting of the burner 3 and the Stirling engine 4.
The burner 3 comprises: a combustion chamber 30 in which the fuel syngas 8 coming from the gasifier 2 is burned in the presence of combustion air 31 generating hot combustion gases 32; an exhaust system 33, fixed on top of the combustion chamber 30, which receives the exhaust fumes 34 exiting the Stirling engine 4, as further described below; pre-mixing flanges 35 for the fuel syngas 8 and the combustion air 31; a nozzle or duct 36, preferably ceramic, downstream of the pre-mixing flanges 35, which conveys the fuel syngas 8 and the combustion air 31 into the combustion chamber 30. The mixture of fuel syngas 8 and combustion air 31 exiting the nozzle 36 is indicated with the as reference numeral 37 in Figure 8.
Furthermore, the pre-mixing flanges 35 allow partial cooling of the fuel syngas 8 by means of the combustion air 31.
The Stirling engine 4 comprises a high-temperature heat exchanger 38 (so-called "hot exchanger") shown in Figures 7, 8, 10, a low-temperature heat exchanger (so- called "cold exchanger"), a regenerator and an electric generator 39. The cold exchanger and the regenerator are not visible in the figures. The hot exchanger 38 of the Stirling engine is inserted inside the combustion chamber 30.
Downstream of the hot exchanger 38 of the Stirling engine, a tubular element 40 is placed, also indicated as a cooling ring, inside which a cooling fluid flows, so that heat transfer downstream of said hot exchanger 38 is prevented. In other words, the cooling ring 40 performs the thermal break function between the burner 3 and the Stirling engine 4, preventing unwanted heat from entering the part of the Stirling engine 4 under the hot exchanger 38 and safeguarding the underlying components from excessive heating.
The combustion chamber 30 of the burner 3 consists of a cylinder which integrates connections for the feeding duct 13 of the fuel syngas 8 coming from the gasifier 2 and for the feeding duct 41 of the combustion air 31. Furthermore, the combustion chamber 30 integrates the attachment flange 42 to the Stirling engine 4 and the attachment flange 43 to the exhaust system 33. A bell 44 and a means 45 made of porous ceramic material (porous ceramic means 45) are placed inside the combustion chamber 30 of the burner 3.
Said bell 44 is open at the bottom and houses the hot exchanger 38 of the Stirling engine inside. In particular, said hot exchanger 38 is inserted from the open bottom of the bell 44. Said bell 44 is such to convey the hot combustion gases 32 into the hot exchanger 38, where they undergo heat exchange providing heat and generating exhaust fumes 34 (or combustion fumes 34). In other words, said bell 44 constrains the hot combustion gases 32 to flow through the entire hot exchanger 38 with minimal heat dissipation to the outside, thus optimizing the heat exchange with the Stirling engine 4. Said bell 44 comprises steel walls internally lined with a refractory insulating material, as further described below with reference to Figure 11. The aforementioned nozzle or duct 36 may be replaced by a hole made in said refractory insulating material, such as to convey the fuel syngas 8 and the combustion air 31 inside the combustion chamber 30.
There is a gap 46 between said bell 44 and said combustion chamber 30 which is traveled upward by the exhaust fumes 34 exiting the hot exchanger 38, as evident from Figure 8. The porous ceramic means 45 is housed in the upper part of the bell 44 above the hot exchanger 38 and is supported at least partially by the refractory insulating material of the bell 44. Said porous ceramic means 45 is an optimized combustion volume in which the syngas 8 is combusted in the presence of combustion air 31 generating hot combustion gases 32 (Figure 8). Furthermore, the porous means 45 allows a homogeneous temperature distribution, ensuring optimal heat exchange with the Stirling engine 4 and low polluting emissions.
The bell 44 and the porous ceramic means 45 are most visible in Figure 11.
The bell 44 is open at the bottom and the hot exchanger of the Stirling engine is inserted in its inside (not shown in Figure 11). Said bell 44 is delimited by an upper wall 47 and side walls 48. Said walls 47, 48 are made of steel and are internally lined with a refractory insulating material, e.g., based on polycrystalline alumina fiber. For example, said material is produced by the company Schupp under the trade name ITM-Fibermax®, preferably Blanket 1600-130.
Referring to the example in Figure 11, the upper steel wall 47 is internally coated with a layer 49 of polycrystalline alumina fiber-based material. In the specific example of Figure 11, said layer 49 is further coated, at its ends, with two layers 50 of polycrystalline alumina fiber-based material, which act as spacers defining a space 51 interposed therebetween for the passage of the mixture 37 of syngas and combustion air exiting the nozzle 36. Said layers 50 can have variable thickness and size; consequently, the space 51 interposed therebetween has variable thickness and inner diameter as well.
Always referring to the example in Figure 11, the steel side walls 48 are internally coated with first layers 52 of polycrystalline alumina fiber having a given thickness and with second layers 53 of polycrystalline alumina fiber having a different thickness, in this case a greater thickness. The porous ceramic means 45 is housed between said layers 52 of insulating material. Consequently, by means of said layers 52, the porous ceramic means 45 is thermally insulated from the bell 44. For example, the porous ceramic material from which the means 45 is made is produced by the company Lanik under the trade name Vukopor® S or Vukopor® HT. The mixture 37 of fuel syngas 8 and combustion air
31, after crossing the space 51, enters the porous ceramic means 45 where it is combusted, generating hot combustion gases 32, which are then conveyed to the hot exchanger 38 of the Stirling engine (not shown in Figure 11). In the example in Figure 11, the bell 44 comprises an additional element 54 made of refractory insulating material, e.g., based on polycrystalline alumina fiber, immediately below the porous ceramic means 45, such as to prevent unwanted entry of heat through the top of the Stirling engine below. Said element 54 mimics the shape of the upper dome of the hot exchanger 38 of the Stirling engine, visible in Figures 7, 8, 10.
The exhaust system 33 mentioned above receives the combustion fumes 34 exiting the hot exchanger 38 of the Stirling engine 4, once the latter have traveled upward through the gap 46 present between the combustion chamber 30 and the bell 44.
Said exhaust system 33 comprises an exhaust 55 from which combustion fumes 34 escape, a heat exchanger 56 connected to said exhaust 55 for recovering heat from the exhaust fumes 34 (Figure 10), a lambda probe 57 which provides a signal based on which the air-syngas ratio at the inlet of burner 3 is adjusted (Figures 6, 10), and a thermocouple 58 which measures the temperature of the combustion fumes 34 (Figures 6, 10).
An extraction fan 59 (shown in Figures 6 and 10) of the combustion fumes 34 is connected to said heat exchanger
56, by virtue of which the combustible syngas 8 from the gasifier 2 and the combustion air 31 are sucked inside the combustion chamber 30. Said extraction fan 59 has variable speed.
To obviate the fact that the pyrolytic gasifier and the Stirling engine, by their nature, have rather slow start-up and control reaction times, the micro-cogenerator 1 can advantageously be coupled to electrical energy storage systems (batteries) and thermal energy accumulation systems (puffers). The remaining capacity is measured for both accumulations so that micro-cogenerator 1 will only turn on if a minimum operating time necessary for heat regulation of all syngas ducts is guaranteed. In particular, a temperature probe is used for the puffer, and a voltage probe is used for the batteries. For the batteries, there is the possibility of both voltage reading and SoC ("state of charge") reading from the Bus and input of a digital request signal.
The micro-generator 1 is equipped with an electronic control, which manages the operation of the machine through the installed sensors and actuators and is independently powered by on-board batteries so that it can be safely shut down even in case the external electrical connection is interrupted. To be able to start up, the micro-generator 1 checks for the presence of the external power grid (both
"on-grid" and "off-grid" via inverter). The process of cogeneration of electrical energy and heat within the micro-cogenerator 1 starting from the biomass 6 is described below with reference to the figures.
The pyrolytic gasification process is started by means of the electric heater 18, which brings the biomass 6 to the gasification temperature, e.g., about 900°C. During the start-up phase of the process, the separation valve 22 of the biomass 6 is opened. During the start-up phase of the process, the extraction fan 59 is activated with a speed proportional to the temperature of the electric heater 18.
The biomass 6 is fed into the reactor 7 of the pyrolytic gasifier 2, through the inlet 11, by means of the loading auger 10. When the filling level of the buffer 20 is under a given threshold, the biomass loading auger
10 is started; when the filling level of the buffer 20 is above said threshold, the biomass loading auger 10 is stopped and the feeding of the biomass 6 to the reactor is interrupted . Once the gasification has been started and the biochar
9 has accumulated in the reactor 7, the reaction front advances from the bottom to the top where biomass 6 not yet gasified is located.
The thermocouple 19 keeps the temperature of the upper part of the reaction chamber 17 monitored; when the integral over time of the temperature measured by thermocouple 19 exceeds a given threshold value of said integral, the separation valve 23 of the biochar 9 is opened, the unloading auger 12 is started and part of the biochar 9 is extracted. In this manner, the reacting biomass 6 is made to flow downward and along with it the reaction front as well, which remains confined to the reaction zone delimited between the thermocouple 19 and the electric heater 18. The gasifier 2, once fully operational, works with a slow and intermittent flow of biomass 6 such as to maintain the reaction front within the aforementioned reaction zone.
The produced fuel syngas 8, before flowing out of the gasifier 2 through the duct 13, crosses a layer of biochar 9, which is still warm and ensures a good abatement of dust and tar.
During the step of shutting down the process, a small amount of biochar 9 is extracted to ensure that the biomass 6 is in a sufficiently low and safe zone of the reaction chamber, and the biomass separation valve 22 is closed to prevent air from entering the reactor 7 and fumes from escaping.
By operating the extraction fan 59, the system consisting of the gasifier 2 and the burner 3 is depressurized and the inflows of fuel syngas 8 from the gasifier 2 to the burner 3 and of air to both the gasifier 2 and the burner 3 are adjusted.
By operating the extraction fan 59, the combustion fumes 34 are extracted which travel upward through the gap 46 between the combustion chamber 30 and the bell 44, creating a vacuum inside the burner 3. In turn, the fuel syngas 8 exiting the gasifier 2 and the combustion air 31 are sucked into the combustion chamber 30 of the burner, respectively, through the supply ducts 13 and 41. In turn, air is sucked into the gasifier 2.
Once the presence of fuel syngas 8 is detected inside the burner 3, the latter is ignited and an increasing amount of combustion air 31 is supplied by acting on the air valve 60 located on the duct 41.
The fuel syngas 8 and the combustion air 31 are sucked inside the combustion chamber 30 passing through the pre mixing flanges 35, then the nozzle 36, until they arrive inside the porous ceramic means 45, which defines the volume in which the combustion takes place with the generation of the hot combustion gases 32.
The hot combustion gases 32 are subjected to heat exchange within the hot exchanger 38 of the Stirling engine 4, from which heat is recovered that puts the electric generator 39 in oscillation, thus obtaining the aforementioned combustion fumes 34 resulting from said heat exchange.
The combustion fumes 34 are extracted through the extraction fan 59. Said combustion fumes 34 travel upward through the cavity 46 present between the combustion chamber 30 and the bell 44, pass through the exhaust 55 on which the lambda probe 57 and the thermocouple 58 are placed, then they are fed to the heat exchanger 56 for recovery of the heat contained therein. The lambda probe 57 adjusts the air-syngas ratio accurately by virtue of the valve 60 located on the inlet duct 41 of the combustion air 31, adjusting the pressure drop and thus the inflow. More specifically, the lambda probe 57 provides a signal based on which the aforementioned air-syngas ratio is accurately adjusted.
It is apparent that only one particular embodiment of the present invention was described. The person skilled in the art will be able to make all the modifications needed to adapt both the micro-cogenerator 1 and the process of cogeneration to particular conditions, without, however, departing from the scope of protection as defined in the appended claims.

Claims

1. A process of cogeneration of electrical energy and heat starting from a renewable and sustainable energy source (6), preferably woody biomass, in a micro- cogenerator (1) comprising a pyrolytic gasifier (2), a burner (3), and a Stirling engine (4), said process comprising the following steps: i) feeding said energy source (6) to the pyrolytic gasifier (2) which comprises a reaction chamber (17) inside which said energy source (6) reacts thus generating syngas (8) and biochar (9); ii) feeding the syngas (8) generated during step i) to said burner (3) which comprises a combustion chamber
(30) inside which the syngas (8) is burned in the presence of combustion air (31) thus generating hot combustion gases
(32); iii) subjecting said hot combustion gases (32) to heat exchange in a heat exchanger (38) (the so-called "hot exchanger") of the Stirling engine (4) adapted to generate electrical energy, obtaining exhaust fumes (34) deriving from said heat exchange, during said step ii), the ratio of combustion air
(31) to syngas (8) being adjusted based on a signal provided by a lambda probe (57) crossed by a flow of said exhaust fumes (34) said process comprising a start-up phase of the micro cogenerator (1) and a full operation phase (regime phase) following said start-up phase, and being characterized in that said start-up phase comprises a first step a) of detecting the presence of syngas (8) inside the burner (3) and a subsequent step b) of ignition of the burner (3), wherein: said first step a) comprises calculating the integral over time of the temperature of the reaction chamber (17) of the pyrolytic gasifier (2) and calculating the integral over time of the value read by said lambda probe (57), during said step a) the calculated value of the integral over time of the temperature of the reaction chamber (17) is compared with a preset threshold value of said integral (so-called first threshold value) and, when said first threshold value is exceeded, the calculated value of the integral over time of the value read by the lambda probe (57) is compared with a preset threshold value of said integral (so-called second threshold value) until it is exceeded, the exceeding of said second threshold value being an indication of the presence of syngas (8) and of the substantial absence of air (31) inside the burner (3), said second step b) is started when said second threshold value is exceeded and comprises an increasing supply of combustion air (31) into the combustion chamber
(30) of said burner (3) until the ignition of a flame.
2. A process according to claim 1, comprising the generation of an ignition spark of said flame in step b) or comprising the generation of an ignition spark of said flame at the beginning of the start-up phase.
3. A process according to claim 1 or 2, wherein said start-up phase comprises a step c) of detecting the presence of said flame in the combustion chamber (30) of said burner (3), in said step c) the derivative of the temperature of the combustion chamber (30) with respect to time is compared with a preset threshold value of said derivative, the exceeding of which being an indication of the presence of the flame.
4. A process according to any one of the preceding claims, said regime phase being characterized by a lower value read by the lambda probe, i.e., a higher ratio of combustion air (31) to syngas (8), than the start-up phase, and said regime phase being started at the end of said step c). 5. A process according to any one of the preceding claims, wherein during step ii) the syngas (8) leaving the pyrolytic gasifier (2) is sucked into the combustion chamber (30) of the burner (3) by virtue of the presence of a vacuum generated by an appropriate extraction fan (59) for extraction of said exhaust fumes (34), and wherein during the start-up phase said extraction fan (59) is active with a speed proportional to the temperature of the reaction chamber (17) of the pyrolytic gasifier (2).
6. A process according to claim 5, wherein: during the regime phase, the electric power of the micro-cogenerator (1) is compared with a target electric power thus obtaining a power delta, and wherein during the regime phase, the speed of the extraction fan (59) is increased or decreased as a function of the power delta obtained, or during the regime phase, the temperature of the burner is compared with a target temperature thus obtaining a temperature delta and the speed of the extraction fan is increased or decreased as a function of the temperature delta.
7. A process according to any one of the preceding claims, wherein during both the start-up phase and the regime phase, said energy source (6) is fed to the pyrolytic gasifier (2) through a loading auger (10), said loading auger (10) being started every time the fill level of a connecting element (20) between the loading auger (10) and the inlet (11) of the reaction chamber (17) of the pyrolytic gasifier (2) is below a preset threshold value, said fill level being detected by an appropriate sensor (21). 8. A process according to any one of the preceding claims, wherein the reaction chamber (17) of the pyrolytic gasifier (2) is brought to a gasification temperature, preferably between 1000°C and 1200°C, at which the energy source (6) reacts thus generating syngas (8) and biochar (9), the reaction front of said energy source (6) being comprised between an upper limit and a lower limit, said energy source (6) under reaction being supported by the biochar (9) which is accumulated inside the pyrolytic gasifier (2) as long as the integral over time of the temperature of the upper limit of the reaction front does not exceed a preset threshold value of said integral, and when said threshold value is exceeded, the biochar (9) is at least partially discharged through an unloading auger (12) causing the reaction front to lower so that it is comprised between said upper limit and said lower limit.
9. A micro-cogenerator (1) comprising: a pyrolytic gasifier (2) adapted to produce syngas
(8) and biochar (9) from a renewable and sustainable energy source (6), preferably woody biomass, a burner (3) adapted to receive the syngas (8) produced by said pyrolytic gasifier (2) and to generate hot combustion gases (32), a Stirling engine (4) comprising a heat exchanger (38) (the so-called "hot exchanger") fed with said hot combustion gases (32), said Stirling engine (4) being adapted to generate electrical energy, wherein said burner (3) comprises: a combustion chamber (30) inside which the syngas (8) is burned in the presence of combustion air (31), pre-mixing flanges (35) for the syngas (8) and the combustion air (31) upstream of the combustion chamber (30), a means downstream of said pre-mixing flanges (35) adapted to convey the syngas (8) and the air (31) into the combustion chamber (30), said means being preferably a nozzle or a duct (36) said micro-cogenerator (1) being characterized in that said combustion chamber (30) comprises: a bell (44) open at the bottom inside which the hot exchanger (38) of the Stirling engine (4) is housed, said bell (44) being adapted to convey the hot combustion gases (32) into said hot exchanger (38) and comprising steel surfaces (47, 48) internally coated, at least partially, with a refractory insulating material (49, 50, 52, 53), an element (45) made of a porous ceramic material housed in the upper part of the bell (44) above the hot exchanger (38) of the Stirling engine (4), said element (45) made of porous ceramic material being at least partially supported by the refractory insulating material (50, 52) and representing an optimized combustion volume inside which the syngas (8) is burned in the presence of combustion air (31).
10. A micro-cogenerator (1) according to claim 9, said bell (44) being formed by a cylinder open at the bottom comprising an upper surface and a lateral surface, or by a parallelepiped open at the bottom comprising an upper surface (47) and four lateral surfaces (48), said surfaces being made of steel and being internally coated, at least partially, with a refractory insulating material (49, 50, 52, 53). 11. A micro-cogenerator (1) according to claim 9 or
10, said combustion chamber (30) comprising a further element (54) made of refractory insulating material, said element (54) being interposed between said element (45) made of porous ceramic material and said hot exchanger (38) of the Stirling engine (4).
12. A micro-cogenerator (1) according to any one of claims from 9 to 11, said refractory insulating material being a polycrystalline alumina fiber-based material comprising at least 70% by weight of polycrystalline alumina and/or said porous material comprising silicon carbide, alumina and silica.
13. A micro-cogenerator (1) according to any one of claims from 9 to 12, comprising a cooling ring (40) downstream of the hot exchanger (38) of the Stirling engine (4) inside which a cooling fluid flows, said cooling ring (40) being adapted to prevent the thermal transfer downstream of said hot exchanger (38).
14. A micro-cogenerator (1) according to any one of claims from 9 to 13, comprising an exhaust system (33) adapted to receive exhaust fumes (34) leaving the hot exchanger (38) of the Stirling engine (4), preferably said exhaust fumes (34) being evacuated by traveling upwards in a gap (46) which is present between said bell (44) and said combustion chamber (30), wherein said exhaust system (33) comprises an exchanger (56) for the recovery of heat from said exhaust fumes (34), a lambda probe (57) which provides a signal based on which the ratio of air (31) to syngas (8) at the inlet of the burner (3) is adjusted, and a thermocouple (58) which measures the temperature of said exhaust fumes
(34).
15. A micro-cogenerator (1) according to claim 14, comprising an extraction fan (59) connected to said exchanger (56) for the recovery of heat from the exhaust fumes (34), said extraction fan (59) being such as to extract the exhaust fumes (34) thus creating a vacuum inside the burner (3) and, in turn, to adjust the inflow of the syngas (8) coming from the gasifier (2) and of the combustion air (31) into the burner (3) itself.
16. A micro-cogenerator (1) according to any one of claims 9 to 15, wherein said pyrolytic gasifier (2) comprises: a reactor (7) comprising a reaction chamber (17) inside which said energy source (6) is gasified in the presence of air thus generating syngas (8) and biochar
(9), an electric heater (18) adapted to heat the reaction chamber (17) to the gasification temperature, and a thermocouple (19) adapted to monitor the temperature in the upper part of the reaction chamber (17), the reaction front being comprised between said heater (18) and said thermocouple (19), a loading auger (10) for feeding said renewable source
(6) into the reactor (7), a connecting element (20) between the loading auger
(10) and the reactor (7) provided with a sensor (21) adapted to detect the level of the renewable source (6) present in its inside, an unloading auger (12) for the evacuation of the biochar (9), a hopper (14) connecting the reactor (7) and the unloading auger (12), said hopper (14) forming a collection volume of the syngas (8) produced in the reactor (7), a connection duct (13) between said hopper (14) and the burner (3), from which the syngas (8) is sucked and fed to said burner (3).
PCT/IB2022/055875 2021-06-25 2022-06-24 Cogeneration process and related apparatus WO2022269554A1 (en)

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IT102021000016703 2021-06-25
IT102021000016703A IT202100016703A1 (en) 2021-06-25 2021-06-25 COGENERATION PROCESS AND RELATED EQUIPMENT

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2005274123A (en) * 2004-02-27 2005-10-06 Ecomeet Solutions Co Ltd Power generation system and control method thereof
US20060089516A1 (en) * 2004-10-25 2006-04-27 Giercke Ronald K Biomass conversion by combustion
US20090078176A1 (en) * 2006-01-11 2009-03-26 Eckhart Weber Wood-Pellet Cogeneration Unit With Stirling Engine in Condensing Technology
EP2522708A2 (en) * 2011-05-11 2012-11-14 Anglia Ruskin University Gasifier

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2005274123A (en) * 2004-02-27 2005-10-06 Ecomeet Solutions Co Ltd Power generation system and control method thereof
US20060089516A1 (en) * 2004-10-25 2006-04-27 Giercke Ronald K Biomass conversion by combustion
US20090078176A1 (en) * 2006-01-11 2009-03-26 Eckhart Weber Wood-Pellet Cogeneration Unit With Stirling Engine in Condensing Technology
EP2522708A2 (en) * 2011-05-11 2012-11-14 Anglia Ruskin University Gasifier

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