WO2022257745A1 - Online measuring device for electrolyte density of automatic liquid suction type lead-acid storage battery - Google Patents

Online measuring device for electrolyte density of automatic liquid suction type lead-acid storage battery Download PDF

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Publication number
WO2022257745A1
WO2022257745A1 PCT/CN2022/094502 CN2022094502W WO2022257745A1 WO 2022257745 A1 WO2022257745 A1 WO 2022257745A1 CN 2022094502 W CN2022094502 W CN 2022094502W WO 2022257745 A1 WO2022257745 A1 WO 2022257745A1
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cavity
electrolyte
lead
measuring device
floating
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PCT/CN2022/094502
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French (fr)
Chinese (zh)
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陈明
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陈明
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/42Methods or arrangements for servicing or maintenance of secondary cells or secondary half-cells
    • H01M10/48Accumulators combined with arrangements for measuring, testing or indicating the condition of cells, e.g. the level or density of the electrolyte
    • H01M10/484Accumulators combined with arrangements for measuring, testing or indicating the condition of cells, e.g. the level or density of the electrolyte for measuring electrolyte level, electrolyte density or electrolyte conductivity
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/06Lead-acid accumulators
    • H01M10/12Construction or manufacture
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50Manufacturing or production processes characterised by the final manufactured product

Definitions

  • the application relates to the field of measuring the electrolyte density of lead-acid batteries, in particular to an on-line measuring device for the electrolyte density of an automatic liquid-absorbing lead-acid battery.
  • the density of the electrolyte is an important basis for analyzing the actual capacity of the battery.
  • the density of the electrolyte increases with the increase of the charge level of the battery and decreases with the increase of the discharge level. Because the battery is charged, the lead sulfate on the plate is decomposed, the content of sulfuric acid in the electrolyte increases, and the density increases. When the battery is discharged, lead sulfate is generated on the two pole plates, the content of sulfuric acid in the electrolyte decreases, and the density decreases. In addition, during the charging process of the battery, the gassing will also cause the battery to lack water (especially the open battery), which will affect the density of the battery electrolyte.
  • the Chinese invention patent authorization announcement number CN105958141B discloses a lead-acid battery intelligent detection device.
  • This intelligent detection device Equipped with a liquid level detection rod and a density sensor.
  • the liquid level detection rod of the lead-acid battery intelligent detection device is set in the acid battery to detect the liquid level
  • the density sensor is a floating density sensor floating in the electrolyte in the acid battery. Indicates the density of the electrolyte, the more the part that floats out of the water, the greater the density, and the less the part that floats out of the water, the lower the density of the electrolyte.
  • the structure of the floating liquid density sensor is relatively simple. It generally includes a sphere with a counterweight and a cylinder connected to the sphere. The diameter of the cylinder is smaller than that of the sphere.
  • the liquid sinks inwards, and part of the cylinder part will float on the liquid surface.
  • the cylinder part will be perpendicular to the horizontal plane.
  • the counterweight By adjusting the counterweight, the entire sphere can sink under the water during measurement, and the cylinder part will protrude. On the water surface, the specific gravity of the liquid can be measured by measuring the height of the cylinder part.
  • the density of the electrolyte can be determined by measuring the volume of the floating liquid surface in real time.
  • the height of the column part of the floating density sensor is generally used to correspond to the corresponding density.
  • the liquid level will also change continuously due to the constant temperature change. , resulting in the height of the column part of the floating density sensor will also change accordingly, resulting in errors in measurement.
  • This application aims at the shortcomings of the current floating density sensor when detecting the electrolyte density of lead-acid batteries, and provides an on-line measuring device for the electrolyte density of lead-acid batteries with automatic liquid absorption. In this device, a certain amount is automatically sampled when measurement is required. The electrolyte solution, the density detection of the sampled electrolyte solution is carried out.
  • an on-line measuring device for the electrolyte density of an automatic liquid-absorbing lead-acid battery including a floating density sensor and a cavity; the cavity is installed on the lead-acid battery to be tested ; The electrolyte of the lead-acid battery to be tested is pumped into the cavity or discharged from the cavity into the pump to be tested in the lead-acid battery; a collection floating density sensor is arranged on the top of the cavity to float in the cavity data acquisition device.
  • the cavity is a cylindrical cavity, and the bottom is provided with a plug partially immersed in the electrolyte in the lead-acid battery ;
  • the top of the cavity is provided with a piston and a motor that drives the piston to slide up and down in the cavity.
  • the cavity is a cylindrical cavity
  • the bottom is provided with a plug partially immersed in the electrolyte in the lead-acid battery
  • the pump is arranged on the upper side wall of the cylindrical cavity, including a cylinder communicated with the cylindrical cavity, a piston set in the cylinder, and a motor that drives the piston to reciprocate in the cylinder.
  • the cavity and the cylinder form a three-way structure.
  • the diameter of the spherical part of the floating density sensor is smaller than the diameter of the cylindrical cavity, and a positioning ring is also included.
  • the positioning ring is tightly fixed in the middle of the column part of the floating density sensor.
  • the above-mentioned on-line measuring device for the electrolyte density of the automatic liquid-absorbing lead-acid battery also includes a buoy floating on the surface of the electrolyte to indicate the liquid level of the electrolyte, and the buoy is arranged at a position The lower side of the ring is sleeved on the cylinder part of the floating density sensor.
  • the above-mentioned on-line measuring device for the electrolyte density of the automatic liquid-absorbing lead-acid battery also includes a plug arranged at the bottom of the cavity to prevent the floating density sensor from falling out of the cavity, and the plug has The tip inserted into the electrolyte also has a channel for the electrolyte to enter the cavity in the middle of the plug.
  • the data acquisition device is a capacitive data acquisition device, including a capacitor assembly tightly fixed on the top of the cavity and arranged on the The electrode on the top outside of the floating density sensor cylinder part;
  • the capacitor assembly includes a first semi-circular electrode and a second semi-circular electrode arranged oppositely, under the buoyancy of the electrolyte, the floating density sensor cylinder Part of the electrodes on the outside of the top extend into the middle of the first semi-circular electrode and the second semi-circular electrode, and a detection circuit for detecting the capacitance between the first semi-circular electrode and the second semi-circular electrode is also included.
  • the data acquisition device is a photoelectric data acquisition device, including a The shading plate and at least two groups of optoelectronic components composed of photoelectric transceivers arranged on both sides of the shading plate, the light shading plate has light-transmitting long holes of different heights, and each group of photoelectric components is opposite to a light-transmitting long hole.
  • the data acquisition device is a grating type data acquisition device, including a fixed grating fixed on the top of the cavity, oppositely arranged A pair of sending and receiving optoelectronic devices on both sides of the fixed grating, set on the movable grating on the top of the floating density sensor cylinder, the movable grating is parallel to the fixed grating, and the movable grating moves up and down relative to the fixed grating to generate Moiré fringes; a detection circuit for detecting the moiré fringes is also included.
  • the present application adopts the method of sampling the electrolyte to measure the density, so as to overcome the deficiency of the error caused by the change of the liquid level of the electrolyte in the storage battery due to the temperature change.
  • Accompanying drawing 1 is the structure diagram of the on-line measurement device of the electrolyte density of the self-absorbing type lead-acid storage battery of embodiment 1 of the present application.
  • Accompanying drawing 11 is the structure schematic diagram of the on-line measurement device of the electrolyte density of the self-absorbing type lead-acid storage battery of embodiment 4 of the present application.
  • Embodiment 1 is an online measuring device for the electrolyte density of an automatic liquid-absorbing lead-acid battery that detects the electrolyte density of a lead-acid battery in real time, and it is an automatic liquid-absorbing type lead-acid battery electrolyte density sensor. As shown in Figure 1, the density sensor is installed on the lead-acid battery and connected with the battery management system of the lead-acid battery.
  • the floating density sensor 6 is a conventional density sensor for measuring liquid density at present, as shown in Fig. 1 and Fig.
  • the floating density sensor 6 is mainly composed of two parts, a sphere part 6-1 with a counterweight and a cylinder part 6-2 connected with the sphere part 6-1. Since the sphere part 6-1 has a counterweight, Therefore, when it is suspended on the liquid surface, the spherical part 6-1 is down, and the column part 6-2 is up, and the weight of the discharged liquid is the total weight of the floating density sensor 6 itself.
  • the total weight is constant, therefore, the more the volume of the spherical part 6-1 combined with the cylindrical part 6-2 surfaced, the smaller the volume of the discharged liquid, and therefore, the denser the liquid, and vice versa . Therefore, in this embodiment, the measurement of the density of the electrolyte is attributed to the height of the top surface of the measurement column part 6-2, the higher the height, the greater the density of the electrolyte.
  • the density measurement is carried out after sampling the electrolyte in the lead-acid battery. Therefore, there is a chamber 1 for measuring the electrolyte as shown in Figure 1.
  • the chamber 1 is as shown in FIG.
  • the test tube body is general, and the floating density sensor 6 is arranged in the cavity 1.
  • the lower end of the cavity 1 is blocked by a plug 7 to prevent the floating density sensor 6 from falling from the lower end of the cavity 1.
  • the plunger pump is used to extract the air in the cavity to absorb the liquid.
  • the liquid suction device Including a cylinder 11 communicating with the cavity 1, a piston 10 is arranged in the cylinder 11, and a motor 12 (screw motor is used in this embodiment) is used to drive the piston 10 to reciprocate rapidly in the cylinder 11.
  • a one-way switch is arranged on the cylinder body 11, and the air in the chamber body 1 can be pumped out once every time it goes back and forth. After several times of pumping out, the electrolyte solution can be sucked into the chamber.
  • the plug 7 has a hole in the middle, which is the passage 7-1 through which the electrolyte enters the cavity 1, and can absorb the electrolyte in the lead-acid battery.
  • a positioning ring 3 is also provided in the cavity 1, and the positioning ring 3 is tightly fixed in the middle of the cavity 1 as shown in Figure 3, and its function It is to make the floating density sensor 6 move up and down along the axis without deviation, and there is a through hole 3-1 in the middle through which the cylindrical part 6-2 of the floating density sensor 6 passes.
  • the float 5 is a light material, and can also be an annular shape like a fixed ring, which has enough space with the cavity 1 and the floating density sensor 6, can float on the electrolyte surface, and is used for indication
  • Electrolyte liquid level height in the present embodiment, cavity body 1 is a section glass tube, can utilize position sensor 4 to judge the height of liquid level in cavity body 1 outside glass tube, like this, can control motor 12 by this position sensor 4 To work, it is enough to make the electrolyte pumped into the cavity 1 reach the measurement standard. In this way, the detection device arranged at the upper end of the cavity 1, that is, the data acquisition device 2, can be used for measurement preparation.
  • both the cavity 1 and the cylinder 11 can be made of glass or other transparent PVC materials.
  • the cavity 1 and the cylinder 11 form a three-way structure, as shown in FIG. 1 .
  • the data acquisition device 2 is a capacitive data acquisition device, as shown in Figure 4 and Figure 5, including a capacitor assembly tightly fixed on the top of the cavity 1 and arranged on the outside of the top of the floating density sensor 6 cylinder part 6-2
  • the electrode 2-3; the capacitor assembly includes the first semi-circular electrode 2-1 and the second semi-circular electrode 2-2 oppositely arranged, under the buoyancy of the electrolyte, the floating density sensor 6 cylinder part 6 -2
  • the electrode 2-3 on the outside of the top extends into the middle of the first semi-circular electrode 2-2 and the second semi-circular electrode 2-3, and the electrode 2- on the outside of the floating density sensor 6 cylinder part 6-2 top 3 Change the capacitance between the first semi-circular electrode 2-1 and the second semi-circular electrode 2-2 when moving up and down, and also include detecting the first semi-circular electrode 2-1 and the second semi-circular electrode The detection circuit of capacitance between 2-2.
  • the screw motor is controlled, and the electrolyte is sucked into the chamber 1 by the plug 7 channel 7-1 until the float 5 rises to the designated position (positioned by the position sensor 4, the purpose of this step is to make the electrolysis liquid height is a fixed value), measure the capacitance between the first semi-circular ring electrode 2-2 and the second semi-circular ring electrode 2-3, and convert the corresponding electrolyte specific gravity value.
  • the screw motor is controlled to discharge the electrolyte from the plug 7 channel 7-1 into the lead-acid battery.
  • Embodiment 2 as shown in Figures 6 and 7, the difference between this embodiment and Embodiment 1 is that the data acquisition device 2 used in this embodiment is a photoelectric data acquisition device, including 6 columns of floating density sensors
  • the shading plate 2-6 on the top of the part 6-2 and the four groups of photoelectric components 2-4 composed of photoelectric transceivers arranged on both sides of the shading plate 2-6, the shading plate 2-6 has light transmission lengths of different heights.
  • the hole 2-6-1 is shown in Figure 8, and each group of photoelectric components 2-4 is opposite to a long light-transmitting hole 2-6-1.
  • light-shielding plate 2-6 structure as shown in Figure 8 light-shielding plate 2-6 is pure black, has 4 slits of different lengths above (translucent long hole 2-6-1 ), when the transmitting tube in the photoelectric module 2-4 is in the slit position, the receiving device outputs a digital value of 1; otherwise, the receiving device outputs a digital value of 0.
  • the photoelectric components 2-4 can use a pair of infrared receiving diodes and infrared emitting diodes, the shortest slit corresponds to the photoelectric switch 1, the longest slit corresponds to the photoelectric switch 4, and so on.
  • Embodiment 3 The difference between embodiment 3 and the previous two embodiments is that the data acquisition device 2 is a raster type data acquisition device, as shown in FIG. 9 and FIG. 10 .
  • the grating type data acquisition device includes a fixed grating 2-8 fixed on the top of the cavity 1, a pair of sending and receiving optoelectronic devices 2-7 arranged on both sides of the fixed grating 2-8, and arranged on the floating density sensor 6 cylinder
  • the movable grating 2-9 on the top of the part 6-2 is parallel to the fixed grating 2-8, and the movable grating 2-9 moves up and down relative to the fixed grating 2-9 to generate moiré fringes; it also includes detection The moiré fringe detection circuit.
  • a movable grating 2-9 on the top of the column part 6-2 of the floating density sensor 6, and the movable grating 2-9 will be relatively fixed according to the depth of the floating density sensor 6 sinking into the electrolyte.
  • the grating 2-8 moves up and down to generate moiré fringes, and a pulse signal proportional to the relative displacement can be generated through the detection circuit.
  • the change of the measured pulse signal can calculate the change of the height of the hydrometer, and then calculate the change of the specific gravity of the electrolyte.
  • the screw motor is controlled, and the electrolyte is sucked into the chamber 1 from the plug 7 channel 7-1 until the float 5 rises to the designated position, until the float rises to the designated position (positioned by the position sensor, the purpose of this step
  • the height of the electrolyte is a fixed value)
  • the float 5 rises to the designated position
  • the change of the grating pulse signal is measured at the same time to calculate the height change of the hydrometer, and then calculate the change of the specific gravity of the electrolyte.
  • the screw motor is controlled to discharge the electrolyte out of the sensor cavity through the opening of the plug.
  • Embodiment 4 As shown in Figure 11, the main difference between this embodiment and previous embodiments 1, 2, 3, and 4 is that it is an online measuring device for the electrolyte density of the automatic liquid-absorbing lead-acid storage battery in embodiment 4 of the present application Among them, the structure of the plunger pump used is different.
  • the pump is installed on the top of the cylindrical cavity 1, including a piston 10 with the inner wall of the cylindrical cavity 1 as the cylinder body, and drives the piston 10 along the cylinder.
  • the motor 12 that slides up and down on the inner wall of the cylindrical cavity 1 is like a suction cylinder formed by the piston 10 and the cylindrical cavity 1.

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  • Manufacturing & Machinery (AREA)
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Abstract

An online measuring device for the electrolyte density of an automatic liquid suction type lead-acid storage battery, comprising: a floating type density sensor (6); a cavity (1), the cavity (1) being mounted on a lead-acid storage battery to be tested; and a pump, which pumps electrolyte of the lead-acid storage battery into the cavity (1) or discharges the electrolyte from the cavity (1) into the lead-acid storage battery. A data acquisition device (2) that acquires data of the floating type density sensor (6) floating in the cavity (1) is provided on the top of the cavity (1). Density measurement is carried out by employing an electrolyte sampling means, and the insufficiency of errors caused by liquid level height change of electrolyte in a storage battery due to temperature change is overcome.

Description

一种自动吸液式铅酸蓄电池电解液密度的在线测量装置An on-line measuring device for the electrolyte density of an automatic liquid-absorbing lead-acid battery
相关申请related application
本申请要求于2021年6月10日提交中国专利局、申请号为202110645401.2、申请名称为“一种自动吸液式铅酸蓄电池电解液密度的在线测量装置”的中国专利申请的优先权。This application claims the priority of the Chinese patent application submitted to the China Patent Office on June 10, 2021 with the application number 202110645401.2 and the application title "An on-line measuring device for the electrolyte density of an automatic liquid-absorbing lead-acid battery".
技术领域technical field
本申请涉及铅酸蓄电池电解液密度测量领域,特别是一种自动吸液式铅酸蓄电池电解液密度的在线测量装置。The application relates to the field of measuring the electrolyte density of lead-acid batteries, in particular to an on-line measuring device for the electrolyte density of an automatic liquid-absorbing lead-acid battery.
背景技术Background technique
在铅酸蓄电池(尤其是开口电池)使用过程中,电解液密度高低是作为分析电池实际容量的重要依据。电解液密度随蓄电池充电程度增加而上升,随放电程度增加而降低。因为蓄电池充电,极板上的硫酸铅分解,电解液中硫酸含量增加,密度升高。蓄电池放电,两极板生成硫酸铅,电解液中硫酸含量减少,密度降低。此外,蓄电池在充电过程中,也会由析气导致电池缺水(尤其是开口电池),影响蓄电池电解液的密度。During the use of lead-acid batteries (especially open batteries), the density of the electrolyte is an important basis for analyzing the actual capacity of the battery. The density of the electrolyte increases with the increase of the charge level of the battery and decreases with the increase of the discharge level. Because the battery is charged, the lead sulfate on the plate is decomposed, the content of sulfuric acid in the electrolyte increases, and the density increases. When the battery is discharged, lead sulfate is generated on the two pole plates, the content of sulfuric acid in the electrolyte decreases, and the density decreases. In addition, during the charging process of the battery, the gassing will also cause the battery to lack water (especially the open battery), which will affect the density of the battery electrolyte.
因此,在对铅酸蓄电池进行在线检测时,往往也需要检测铅酸蓄电池的电解液的密度,中国发明专利授权公告号CN105958141B就公开了一种铅酸蓄电池智能检测装置,该智能检测装置中,设置有液位检测棒、密度传感器。在该铅酸蓄电池智能检测装置的液位检测棒是设置在酸蓄电池内检测液位,而密度传感器漂浮于酸蓄电池内的电解液中的漂浮式密度传感器,通过漂浮在电解液面上的高度表示电解液的密度,浮出水面的部分越多则密度越大,浮出水面的部分越少则说明电解液的密度越小。Therefore, when the lead-acid battery is detected online, it is often necessary to detect the density of the electrolyte of the lead-acid battery. The Chinese invention patent authorization announcement number CN105958141B discloses a lead-acid battery intelligent detection device. In this intelligent detection device, Equipped with a liquid level detection rod and a density sensor. The liquid level detection rod of the lead-acid battery intelligent detection device is set in the acid battery to detect the liquid level, and the density sensor is a floating density sensor floating in the electrolyte in the acid battery. Indicates the density of the electrolyte, the more the part that floats out of the water, the greater the density, and the less the part that floats out of the water, the lower the density of the electrolyte.
漂浮式液体密度传感器的结构比较简单,一般包括具有配重的球体,与球体相连的柱体,柱体的直径较球体的直径小,测量时,由于球体内具有配重,因此,球体一端向液体内沉,而柱体部分将有部分浮于液面,一般情况是柱体部分将垂直于水平面,通过调节配重,在测量时均可以使整个球体沉于水下,柱体部分伸出水面,通过测量柱体部分的高度就可以测量出液体的比重。The structure of the floating liquid density sensor is relatively simple. It generally includes a sphere with a counterweight and a cylinder connected to the sphere. The diameter of the cylinder is smaller than that of the sphere. When measuring, because the sphere has a counterweight, one end of the sphere The liquid sinks inwards, and part of the cylinder part will float on the liquid surface. Generally, the cylinder part will be perpendicular to the horizontal plane. By adjusting the counterweight, the entire sphere can sink under the water during measurement, and the cylinder part will protrude. On the water surface, the specific gravity of the liquid can be measured by measuring the height of the cylinder part.
利用漂浮式密度传感器漂浮在铅酸蓄电池的液面上,可以通过实时测量其浮出液面的体积确定电解液的密度。目前,为了方便计量,一般采用测量漂浮式密度传感器的柱体部分的高度对应相应的密度,但是,在实时测量铅酸蓄电池的电解液时,由于温度不断变化,使液面高度也会不断变化,导致测量漂浮式密度传感器的柱体部分的高度也会随之而变化,在测量时产生误差。Using a floating density sensor to float on the liquid surface of the lead-acid battery, the density of the electrolyte can be determined by measuring the volume of the floating liquid surface in real time. At present, in order to facilitate the measurement, the height of the column part of the floating density sensor is generally used to correspond to the corresponding density. However, when measuring the electrolyte of the lead-acid battery in real time, the liquid level will also change continuously due to the constant temperature change. , resulting in the height of the column part of the floating density sensor will also change accordingly, resulting in errors in measurement.
以上内容仅用于辅助对本申请方案的理解,并不意味着承认上述内容是现有技术。The above content is only used to assist the understanding of the solution of the present application, and does not mean to admit that the above content is the prior art.
技术问题technical problem
本申请针对目前漂浮式密度传感器检测铅酸蓄电池电解液密度时所产生的不足,提供一种自动吸液式铅酸蓄电池电解液密度的在线测量装置,该装置中在需要测量时自动取样一定量的电解液,对取样的电解液进行密度检测。This application aims at the shortcomings of the current floating density sensor when detecting the electrolyte density of lead-acid batteries, and provides an on-line measuring device for the electrolyte density of lead-acid batteries with automatic liquid absorption. In this device, a certain amount is automatically sampled when measurement is required. The electrolyte solution, the density detection of the sampled electrolyte solution is carried out.
技术解决方案technical solution
本申请实现其技术目的技术方案是:一种自动吸液式铅酸蓄电池电解液密度的在线测量装置,包括漂浮式密度传感器和腔体;所述的腔体安装在待测的铅酸蓄电池上;将待测铅酸蓄电池的电解液抽入到腔体或者从腔体中排出到待测铅酸蓄电池内的泵;在所述的腔体顶上设置有采集漂浮式密度传感器漂浮在腔体内的数据采集装置。The technical solution of this application to achieve its technical purpose is: an on-line measuring device for the electrolyte density of an automatic liquid-absorbing lead-acid battery, including a floating density sensor and a cavity; the cavity is installed on the lead-acid battery to be tested ; The electrolyte of the lead-acid battery to be tested is pumped into the cavity or discharged from the cavity into the pump to be tested in the lead-acid battery; a collection floating density sensor is arranged on the top of the cavity to float in the cavity data acquisition device.
在一个实施例中,上述的自动吸液式铅酸蓄电池电解液密度的在线测量装置中:所述的腔体为圆柱形腔体,底部设置有部分浸入铅酸蓄电池内电解液中的堵头;在腔体的顶部设置有活塞和带动所述活塞在腔体内上下滑动的电机。In one embodiment, in the above-mentioned online measuring device for the electrolyte density of the automatic liquid-absorbing lead-acid battery: the cavity is a cylindrical cavity, and the bottom is provided with a plug partially immersed in the electrolyte in the lead-acid battery ; The top of the cavity is provided with a piston and a motor that drives the piston to slide up and down in the cavity.
在一个实施例中,上述的自动吸液式铅酸蓄电池电解液密度的在线测量装置中:所述的腔体为柱形腔体,底部设置有部分浸入铅酸蓄电池内电解液中的堵头;所述泵设置在柱形腔体的上部侧壁上,包括与柱形腔体内连通的缸体,设置在缸体内的活塞,带动活塞在缸体内来回往复运动的电机。In one embodiment, in the above-mentioned online measuring device for the electrolyte density of the automatic liquid-absorbing lead-acid battery: the cavity is a cylindrical cavity, and the bottom is provided with a plug partially immersed in the electrolyte in the lead-acid battery The pump is arranged on the upper side wall of the cylindrical cavity, including a cylinder communicated with the cylindrical cavity, a piston set in the cylinder, and a motor that drives the piston to reciprocate in the cylinder.
在一个实施例中,上述的自动吸液式铅酸蓄电池电解液密度的在线测量装置中:所述的腔体与缸体形成三通结构。In one embodiment, in the above-mentioned on-line measuring device for the electrolyte density of the automatic liquid-absorbing lead-acid battery: the cavity and the cylinder form a three-way structure.
在一个实施例中,上述的自动吸液式铅酸蓄电池电解液密度的在线测量装置中:所述的漂浮式密度传感器的球体部分的直径小于柱形腔体的直径,还包括定位环,所述的定位环紧密固定于所述的漂浮式密度传感器的柱体部分中部。In one embodiment, in the above-mentioned on-line measuring device for the electrolyte density of the automatic liquid-absorbing lead-acid battery: the diameter of the spherical part of the floating density sensor is smaller than the diameter of the cylindrical cavity, and a positioning ring is also included. The positioning ring is tightly fixed in the middle of the column part of the floating density sensor.
在一个实施例中,上述的自动吸液式铅酸蓄电池电解液密度的在线测量装置中:还包括漂浮于电解液面上用于指示电解液液面高度的浮漂,所述的浮漂设置在定位环下侧,套在所述的漂浮式密度传感器的柱体部分上。In one embodiment, the above-mentioned on-line measuring device for the electrolyte density of the automatic liquid-absorbing lead-acid battery: also includes a buoy floating on the surface of the electrolyte to indicate the liquid level of the electrolyte, and the buoy is arranged at a position The lower side of the ring is sleeved on the cylinder part of the floating density sensor.
在一个实施例中,上述的自动吸液式铅酸蓄电池电解液密度的在线测量装置中:还包括设置在腔体底部防止漂浮式密度传感器掉出腔体的堵头,所述的堵头具有介入到电解液中的尖部,在堵头中间还具有电解液进入到腔体内的通道。In one embodiment, the above-mentioned on-line measuring device for the electrolyte density of the automatic liquid-absorbing lead-acid battery: it also includes a plug arranged at the bottom of the cavity to prevent the floating density sensor from falling out of the cavity, and the plug has The tip inserted into the electrolyte also has a channel for the electrolyte to enter the cavity in the middle of the plug.
在一个实施例中,上述的自动吸液式铅酸蓄电池电解液密度的在线测量装置中:所述的数据采集装置为电容式数据采集器,包括紧密固定于腔体顶端的电容器组件和设置在漂浮式密度传感器柱体部分顶部外侧的电极;所述的电容器组件包括相对设置的第一半圆环形电极和第二半圆环电极,在电解液的浮力作用下,漂浮式密度传感器柱体部分顶部外侧的电极伸入第一半圆环形电极和第二半圆环电极中间,还包括检测第一半圆环形电极和第二半圆环电极之间电容量的检测电路。In one embodiment, in the above-mentioned online measuring device for the electrolyte density of the automatic liquid-absorbing lead-acid battery: the data acquisition device is a capacitive data acquisition device, including a capacitor assembly tightly fixed on the top of the cavity and arranged on the The electrode on the top outside of the floating density sensor cylinder part; the capacitor assembly includes a first semi-circular electrode and a second semi-circular electrode arranged oppositely, under the buoyancy of the electrolyte, the floating density sensor cylinder Part of the electrodes on the outside of the top extend into the middle of the first semi-circular electrode and the second semi-circular electrode, and a detection circuit for detecting the capacitance between the first semi-circular electrode and the second semi-circular electrode is also included.
在一个实施例中,上述的自动吸液式铅酸蓄电池电解液密度的在线测量装置中:所述的数据采集装置为光电式数据采集装置,包括设置在漂浮式密度传感器柱体部分顶上的遮光板和设置在遮光板两侧的至少两组由光电收发器组成的光电组件,所述的遮光板上具有不同高度的透光长孔,每组光电组件与一条透光长孔相对。In one embodiment, in the above-mentioned on-line measuring device for the electrolyte density of the automatic liquid-absorbing lead-acid battery: the data acquisition device is a photoelectric data acquisition device, including a The shading plate and at least two groups of optoelectronic components composed of photoelectric transceivers arranged on both sides of the shading plate, the light shading plate has light-transmitting long holes of different heights, and each group of photoelectric components is opposite to a light-transmitting long hole.
在一个实施例中,上述的自动吸液式铅酸蓄电池电解液密度的在线测量装置中:所述的数据采集装置为光栅式数据采集装置,包括固定在腔体顶上的固定光栅,相对设置在固定光栅两侧的一对发送接收光电器件,设置在在漂浮式密度传感器柱体部分顶上的活动光栅,所述的活动光栅与固定光栅平行,所述活动光栅相对固定光栅做上下移动产生摩尔条纹;还包括检测所述的摩尔条纹的检测电路。In one embodiment, in the above-mentioned on-line measuring device for the electrolyte density of the automatic liquid-absorbing lead-acid battery: the data acquisition device is a grating type data acquisition device, including a fixed grating fixed on the top of the cavity, oppositely arranged A pair of sending and receiving optoelectronic devices on both sides of the fixed grating, set on the movable grating on the top of the floating density sensor cylinder, the movable grating is parallel to the fixed grating, and the movable grating moves up and down relative to the fixed grating to generate Moiré fringes; a detection circuit for detecting the moiré fringes is also included.
有益效果Beneficial effect
本申请采用取样电解液的方式进行密度测量,克服由于温度变化导致蓄电池内电解液液面高度变化而产生的误差的不足。The present application adopts the method of sampling the electrolyte to measure the density, so as to overcome the deficiency of the error caused by the change of the liquid level of the electrolyte in the storage battery due to the temperature change.
以下将结合附图和实施例,对本申请进行较为详细的说明。The application will be described in more detail below with reference to the drawings and embodiments.
附图说明Description of drawings
附图1为本申请实施例1自动吸液式铅酸蓄电池电解液密度的在线测量装置的结构示意图。Accompanying drawing 1 is the structure diagram of the on-line measurement device of the electrolyte density of the self-absorbing type lead-acid storage battery of embodiment 1 of the present application.
附图2为本申请实施例1中使用的堵头的结构示意图。Accompanying drawing 2 is the structure diagram of the plug used in the embodiment 1 of the present application.
附图3为本申请实施例1中使用的定位环的结构示意图。Accompanying drawing 3 is the structure diagram of the positioning ring used in the embodiment 1 of the present application.
附图4为本申请实施例1中电容式数据采集器的结构示意图(一)。Accompanying drawing 4 is the structural diagram (1) of the capacitive data acquisition device in the embodiment 1 of the present application.
附图5为本申请实施例1中电容式数据采集器的结构示意图(二)。Accompanying drawing 5 is the structural diagram (2) of the capacitive data collector in the embodiment 1 of the present application.
附图6为本申请实施例2中光电式数据采集装置的结构示意图(一)。Accompanying drawing 6 is the structural diagram (1) of the photoelectric data acquisition device in the embodiment 2 of the present application.
附图7为本申请实施例2中光电式数据采集装置的结构示意图(二)。Accompanying drawing 7 is the structural schematic diagram (2) of the photoelectric data acquisition device in the embodiment 2 of the present application.
附图8为本申请实施例2中遮光板结构示意图。Accompanying drawing 8 is the structural diagram of the shading plate in the embodiment 2 of the present application.
附图9为本申请实施例3中光电式数据采集装置的结构示意图(一)。Accompanying drawing 9 is the structural diagram (1) of the photoelectric data acquisition device in the embodiment 3 of the present application.
附图10为本申请实施例3中光电式数据采集装置的结构示意图(二)。Accompanying drawing 10 is the structural schematic diagram (2) of the photoelectric data acquisition device in the embodiment 3 of the present application.
附图11为本申请实施例4自动吸液式铅酸蓄电池电解液密度的在线测量装置的结构示意图。Accompanying drawing 11 is the structure schematic diagram of the on-line measurement device of the electrolyte density of the self-absorbing type lead-acid storage battery of embodiment 4 of the present application.
本发明的实施方式Embodiments of the present invention
实施例1,本实施例是一种实时检测铅酸蓄电池电解液密度的自动吸液式铅酸蓄电池电解液密度的在线测量装置,它就是一种自动吸液式铅酸蓄电池电解液密度传感器,如图1所示,该密度传感器安装在铅酸蓄电池上,与铅酸蓄电池的电池管理系统相连。Embodiment 1, this embodiment is an online measuring device for the electrolyte density of an automatic liquid-absorbing lead-acid battery that detects the electrolyte density of a lead-acid battery in real time, and it is an automatic liquid-absorbing type lead-acid battery electrolyte density sensor. As shown in Figure 1, the density sensor is installed on the lead-acid battery and connected with the battery management system of the lead-acid battery.
本实施例中,在自动吸液式铅酸蓄电池电解液密度的在线测量装置中用于测量液体密度的是漂浮式密度传感器6;它是目前测量液体密度的常用密度传感器,如图1和图5所示,漂浮式密度传感器6主要由两部分组成,具有配重的球体部分6-1和与球体部分6-1相连的柱体部分6-2,由于球体部分6-1有配重,因此,将它悬浮在液面上时,球体部分6-1在下,柱体部分6-2在上,排出液体的重量就是漂浮式密度传感器6本身的总重量,由于漂浮式密度传感器6本身的总重量是不变的,因此,球体部分6-1与柱体部分6-2组合浮出液面的体积越多,则排出液体的体积越小,因此,液体的密度越大,反之亦然。因此,在本实施例中,测量电解液的密度归结于测量柱体部分6-2顶面的高度,高度越高,则电解液的密度越大。In the present embodiment, what is used to measure the liquid density in the on-line measuring device of the electrolyte density of the automatic liquid-absorbing type lead-acid battery is a floating density sensor 6; it is a conventional density sensor for measuring liquid density at present, as shown in Fig. 1 and Fig. As shown in 5, the floating density sensor 6 is mainly composed of two parts, a sphere part 6-1 with a counterweight and a cylinder part 6-2 connected with the sphere part 6-1. Since the sphere part 6-1 has a counterweight, Therefore, when it is suspended on the liquid surface, the spherical part 6-1 is down, and the column part 6-2 is up, and the weight of the discharged liquid is the total weight of the floating density sensor 6 itself. The total weight is constant, therefore, the more the volume of the spherical part 6-1 combined with the cylindrical part 6-2 surfaced, the smaller the volume of the discharged liquid, and therefore, the denser the liquid, and vice versa . Therefore, in this embodiment, the measurement of the density of the electrolyte is attributed to the height of the top surface of the measurement column part 6-2, the higher the height, the greater the density of the electrolyte.
本实施例中,是通过对铅酸蓄电池内的电解液取样后进行密度测量的,因此,具有一个用于测量电解液的腔体1如图1所示,本实施例中,腔体1如试管体一般,漂浮式密度传感器6就设置在腔体1内,本实施例中,在腔体1的下端采用堵头7堵住,防止漂浮式密度传感器6从腔体1下端掉落,当本实施例的自动吸液式铅酸蓄电池电解液密度的在线测量装置安装时,堵头7部分将会淹没在铅酸蓄电池的电解液中,如果腔体1上部也密封,则当采用泵抽出受体内部部分空气时,将吸取铅酸蓄电池内的电解液进入腔体1内,本实施例中采用柱塞泵的方式抽出腔体内的空气进行吸液,如图1所示,吸液装置包括与腔体1内连通的缸体11,在缸体11内设置活塞10,利用一台电机12(本实施例中使用的是螺杆电机)带动活塞10在缸体11内快速往复运动,在缸体11上设置一个单向开关,每次往返一次,可以将腔体1内的空气抽一些出去,多次抽出以后,可以将电解液吸进腔内。对于口吸液装置,还可以有很多形式,如一台抽气机,从腔体1上端抽走部分空气。堵头7如图2所示,它中间有一个孔,它就是电解液进入到腔体1内的通道7-1,可以吸取铅酸蓄电池内的电解液。In this embodiment, the density measurement is carried out after sampling the electrolyte in the lead-acid battery. Therefore, there is a chamber 1 for measuring the electrolyte as shown in Figure 1. In this embodiment, the chamber 1 is as shown in FIG. The test tube body is general, and the floating density sensor 6 is arranged in the cavity 1. In this embodiment, the lower end of the cavity 1 is blocked by a plug 7 to prevent the floating density sensor 6 from falling from the lower end of the cavity 1. When the on-line measuring device for the electrolyte density of the automatic liquid-absorbing lead-acid battery of this embodiment is installed, the plug 7 will be submerged in the electrolyte of the lead-acid battery. When there is some air in the receptor, the electrolyte in the lead-acid battery will be sucked into the cavity 1. In this embodiment, the plunger pump is used to extract the air in the cavity to absorb the liquid. As shown in Figure 1, the liquid suction device Including a cylinder 11 communicating with the cavity 1, a piston 10 is arranged in the cylinder 11, and a motor 12 (screw motor is used in this embodiment) is used to drive the piston 10 to reciprocate rapidly in the cylinder 11. A one-way switch is arranged on the cylinder body 11, and the air in the chamber body 1 can be pumped out once every time it goes back and forth. After several times of pumping out, the electrolyte solution can be sucked into the chamber. For the mouth suction device, there can also be many forms, such as an air extractor, which takes away part of the air from the cavity 1 upper end. As shown in Figure 2, the plug 7 has a hole in the middle, which is the passage 7-1 through which the electrolyte enters the cavity 1, and can absorb the electrolyte in the lead-acid battery.
如图1所示,本实施例中,为了防止漂浮式密度传感器6内倒伏,在腔体1内还设置定位环3,定位环3紧密固定于腔体1中部如图3所示,其作用是使漂浮式密度传感器6沿轴心上下运动不发生偏离,中间具有漂浮式密度传感器6柱形部分6-2穿过的通孔3-1。另外,还具有浮漂5,浮漂5为轻质材料,也可以如固定环一样为一环形,与腔体1及漂浮式密度传感器6有足够空隙,可漂浮于电解液面,采用上用于指示电解液液面高度,本实施例中,腔体1为一段玻璃管,可以在玻璃管外利用位置传感器4判断腔体1内液面的高度,这样,通过这个位置传感器4可以控制电机12的工作,使抽入到腔体1内的电解液达到测量标准即可,这样,可以利用在腔体1上端设置的检测装置也就是数据采集装置2测量准备。As shown in Figure 1, in this embodiment, in order to prevent lodging in the floating density sensor 6, a positioning ring 3 is also provided in the cavity 1, and the positioning ring 3 is tightly fixed in the middle of the cavity 1 as shown in Figure 3, and its function It is to make the floating density sensor 6 move up and down along the axis without deviation, and there is a through hole 3-1 in the middle through which the cylindrical part 6-2 of the floating density sensor 6 passes. In addition, there is also a float 5, the float 5 is a light material, and can also be an annular shape like a fixed ring, which has enough space with the cavity 1 and the floating density sensor 6, can float on the electrolyte surface, and is used for indication Electrolyte liquid level height, in the present embodiment, cavity body 1 is a section glass tube, can utilize position sensor 4 to judge the height of liquid level in cavity body 1 outside glass tube, like this, can control motor 12 by this position sensor 4 To work, it is enough to make the electrolyte pumped into the cavity 1 reach the measurement standard. In this way, the detection device arranged at the upper end of the cavity 1, that is, the data acquisition device 2, can be used for measurement preparation.
本实施例中,腔体1与缸体11本身都可以采用玻璃或者其它透明的PVC等材料,实践中,腔体1与缸体11形成三通结构,如图1所示。In this embodiment, both the cavity 1 and the cylinder 11 can be made of glass or other transparent PVC materials. In practice, the cavity 1 and the cylinder 11 form a three-way structure, as shown in FIG. 1 .
本实施例中数据采集装置2为电容式数据采集器如图4和图5所示,包括紧密固定于腔体1顶端的电容器组件和设置在漂浮式密度传感器6柱体部分6-2顶部外侧的电极2-3;电容器组件包括相对设置的第一半圆环形电极2-1和第二半圆环电极2-2,在电解液的浮力作用下,漂浮式密度传感器6柱体部分6-2顶部外侧的电极2-3伸入第一半圆环形电极2-2和第二半圆环电极2-3中间,漂浮式密度传感器6柱体部分6-2顶部外侧的电极2-3上下运动时改变第一半圆环形电极2-1和第二半圆环电极2-2之间电容量,还包括检测第一半圆环形电极2-1和第二半圆环电极2-2之间电容量的检测电路。In this embodiment, the data acquisition device 2 is a capacitive data acquisition device, as shown in Figure 4 and Figure 5, including a capacitor assembly tightly fixed on the top of the cavity 1 and arranged on the outside of the top of the floating density sensor 6 cylinder part 6-2 The electrode 2-3; the capacitor assembly includes the first semi-circular electrode 2-1 and the second semi-circular electrode 2-2 oppositely arranged, under the buoyancy of the electrolyte, the floating density sensor 6 cylinder part 6 -2 The electrode 2-3 on the outside of the top extends into the middle of the first semi-circular electrode 2-2 and the second semi-circular electrode 2-3, and the electrode 2- on the outside of the floating density sensor 6 cylinder part 6-2 top 3 Change the capacitance between the first semi-circular electrode 2-1 and the second semi-circular electrode 2-2 when moving up and down, and also include detecting the first semi-circular electrode 2-1 and the second semi-circular electrode The detection circuit of capacitance between 2-2.
利用本实施例测量时,控制螺杆电机,将电解液由堵头7通道7-1吸入腔体1,直至浮漂5升起到指定位置(由位置传感器4定位,这一步骤的目的是使电解液高度为一固定值),测量第一半圆环形电极2-2和第二半圆环电极2-3之间的电容,换算出与之对应的电解液比重值。测量结束,控制螺杆电机,将电解液由堵头7通道7-1排出腔体进入到铅酸蓄电池中。When using this embodiment to measure, the screw motor is controlled, and the electrolyte is sucked into the chamber 1 by the plug 7 channel 7-1 until the float 5 rises to the designated position (positioned by the position sensor 4, the purpose of this step is to make the electrolysis liquid height is a fixed value), measure the capacitance between the first semi-circular ring electrode 2-2 and the second semi-circular ring electrode 2-3, and convert the corresponding electrolyte specific gravity value. After the measurement is over, the screw motor is controlled to discharge the electrolyte from the plug 7 channel 7-1 into the lead-acid battery.
本实施例的自动吸液式铅酸蓄电池电解液密度的在线测量装置具有如下特点:The on-line measuring device for the electrolyte density of the automatic liquid-absorbing type lead-acid storage battery of the present embodiment has the following characteristics:
(1)可实现在线自动测量电解液比重。(1) On-line automatic measurement of electrolyte specific gravity can be realized.
(2)使得蓄电池组不断电自动化管理及控制成为可能。(2) Make it possible to automatically manage and control the uninterrupted power supply of the battery pack.
(3)减少人力成本。(3) Reduce labor costs.
(4)精确测量电池性能。(4) Accurately measure battery performance.
(5)使得铅酸蓄电池的大数据分析和管理成为可能。(5) Make big data analysis and management of lead-acid batteries possible.
(6)仅在测量时将电解液吸入传感器腔体,消除电解液液面变化对测量精度的影响。(6) The electrolyte is sucked into the sensor cavity only during the measurement, eliminating the influence of the change of the electrolyte level on the measurement accuracy.
实施例2,如图6和图7所示,本实施例中与实施例1的区别在于本实施例采用的数据采集装置2为光电式数据采集装置,包括设置在漂浮式密度传感器6柱体部分6-2顶上的遮光板2-6和设置在遮光板2-6两侧的四组由光电收发器组成的光电组件2-4,遮光板2-6上具有不同高度的透光长孔2-6-1如图8所示,每组光电组件2-4与一条透光长孔2-6-1相对。[0044]本实施例中,遮光板2-6结构如图8所示,遮光板2-6为纯黑色,上面开有4条长短不一的狭缝(透光长孔2-6-1),光电组件2-4中发射管处于狭缝位置时,接收器件输出数字量1;否则接收器件输出数字量0。本实施例中,光电组件2-4可以采用一对红外线接收二极管和红外线发射二极管,最短的狭缝对应光电开关1,最长的狭缝对应光电开关4,依次类推。当比重计从下(此时电解液比重最小)到上(此时电解液比重最大)移动时,相对地等于4组光电开关同时从上向下移动,通过不同的光电开关输出组合,即可获得电解液密度范围。[0045]测量时,控制螺杆电机,将电解液由堵头7通道7-1吸入腔体1,直至浮漂5升起到指定位置,此时,浮漂5升起到指定位置(由位置传感器4定位,这一步骤的目的是使电解液高度为一固定值),通过不同的光电组件2-4输出组合,获得电解液密度范围(见表一)。测量结束,控制螺杆电机,将电解液由堵头开孔排出传感器腔体。Embodiment 2, as shown in Figures 6 and 7, the difference between this embodiment and Embodiment 1 is that the data acquisition device 2 used in this embodiment is a photoelectric data acquisition device, including 6 columns of floating density sensors The shading plate 2-6 on the top of the part 6-2 and the four groups of photoelectric components 2-4 composed of photoelectric transceivers arranged on both sides of the shading plate 2-6, the shading plate 2-6 has light transmission lengths of different heights. The hole 2-6-1 is shown in Figure 8, and each group of photoelectric components 2-4 is opposite to a long light-transmitting hole 2-6-1. In the present embodiment, light-shielding plate 2-6 structure as shown in Figure 8, light-shielding plate 2-6 is pure black, has 4 slits of different lengths above (translucent long hole 2-6-1 ), when the transmitting tube in the photoelectric module 2-4 is in the slit position, the receiving device outputs a digital value of 1; otherwise, the receiving device outputs a digital value of 0. In this embodiment, the photoelectric components 2-4 can use a pair of infrared receiving diodes and infrared emitting diodes, the shortest slit corresponds to the photoelectric switch 1, the longest slit corresponds to the photoelectric switch 4, and so on. When the hydrometer moves from the bottom (at this time the specific gravity of the electrolyte is the smallest) to the top (at this time the specific gravity of the electrolyte is the largest), it is relatively equal to four groups of photoelectric switches moving from top to bottom at the same time, through different photoelectric switch output combinations, you can Get the electrolyte density range. During measurement, control screw motor, electrolytic solution is sucked cavity 1 by plug 7 passages 7-1, rises to designated position until float 5, and at this moment, float 5 rises to designated position (by position sensor 4 Positioning, the purpose of this step is to make the height of the electrolyte a fixed value), through different output combinations of photoelectric modules 2-4, the density range of the electrolyte is obtained (see Table 1). After the measurement is over, the screw motor is controlled to discharge the electrolyte out of the sensor cavity through the opening of the plug.
表一Table I
Figure dest_path_image001
Figure dest_path_image001
本实施例的自动吸液式铅酸蓄电池电解液密度的在线测量装置具有如下特点:The on-line measuring device for the electrolyte density of the automatic liquid-absorbing type lead-acid storage battery of the present embodiment has the following characteristics:
(1)可实现在线自动测量电解液比重。(1) On-line automatic measurement of electrolyte specific gravity can be realized.
(2)使得蓄电池组不断电自动化管理及控制成为可能。(2) Make it possible to automatically manage and control the uninterrupted power supply of the battery pack.
(3)减少人力成本。(3) Reduce labor costs.
(4)精确测量电池性能。(4) Accurately measure battery performance.
(5)使得铅酸蓄电池的大数据分析和管理成为可能。(5) Make big data analysis and management of lead-acid batteries possible.
(6)仅在测量时将电解液吸入传感器腔体,消除电解液液面变化对测量精度的影响。(6) The electrolyte is sucked into the sensor cavity only during the measurement, eliminating the influence of the change of the electrolyte level on the measurement accuracy.
实施例3,实施例3与前面两个实施例的区别在于数据采集装置2为光栅式数据采集装置如图9和图10。光栅式数据采集装置包括固定在腔体1顶上的固定光栅2-8,相对设置在固定光栅2-8两侧的一对发送接收光电器件2-7,设置在漂浮式密度传感器6柱体部分6-2顶上的活动光栅2-9,的活动光栅2-9与固定光栅2-8平行,所述活动光栅2-9相对固定光栅2-9做上下移动产生摩尔条纹;还包括检测所述的摩尔条纹的检测电路。Embodiment 3. The difference between embodiment 3 and the previous two embodiments is that the data acquisition device 2 is a raster type data acquisition device, as shown in FIG. 9 and FIG. 10 . The grating type data acquisition device includes a fixed grating 2-8 fixed on the top of the cavity 1, a pair of sending and receiving optoelectronic devices 2-7 arranged on both sides of the fixed grating 2-8, and arranged on the floating density sensor 6 cylinder The movable grating 2-9 on the top of the part 6-2 is parallel to the fixed grating 2-8, and the movable grating 2-9 moves up and down relative to the fixed grating 2-9 to generate moiré fringes; it also includes detection The moiré fringe detection circuit.
本实施例中,在漂浮式密度传感器6柱体部分6-2顶上高有活动光栅2-9,活动光栅2-9会随着漂浮式密度传感器6沉入电解液深度的不同,相对固定光栅2-8做上下移动并产生摩尔条纹,通过检测电路可产生与相对位移成正比的脉冲信号。测量脉冲信号的变化可计算出比重计高度变化,进而推算出电解液比重的变化。In this embodiment, there is a movable grating 2-9 on the top of the column part 6-2 of the floating density sensor 6, and the movable grating 2-9 will be relatively fixed according to the depth of the floating density sensor 6 sinking into the electrolyte. The grating 2-8 moves up and down to generate moiré fringes, and a pulse signal proportional to the relative displacement can be generated through the detection circuit. The change of the measured pulse signal can calculate the change of the height of the hydrometer, and then calculate the change of the specific gravity of the electrolyte.
测量时,控制螺杆电机,将电解液由堵头7通道7-1吸入腔体1,直至浮漂5升起到指定位置,直至浮漂升起到指定位置(由位置传感器定位,这一步骤的目的是使电解液高度为一固定值),此时,浮漂5升起到指定位置,同时测量光栅脉冲信号的变化可计算出比重计高度变化,进而推算出电解液比重的变化。测量结束,控制螺杆电机,将电解液由堵头开孔排出传感器腔体。During the measurement, the screw motor is controlled, and the electrolyte is sucked into the chamber 1 from the plug 7 channel 7-1 until the float 5 rises to the designated position, until the float rises to the designated position (positioned by the position sensor, the purpose of this step The height of the electrolyte is a fixed value), at this time, the float 5 rises to the designated position, and the change of the grating pulse signal is measured at the same time to calculate the height change of the hydrometer, and then calculate the change of the specific gravity of the electrolyte. After the measurement is over, the screw motor is controlled to discharge the electrolyte out of the sensor cavity through the opening of the plug.
本实施例的自动吸液式铅酸蓄电池电解液密度的在线测量装置具有如下特点:The on-line measuring device for the electrolyte density of the automatic liquid-absorbing type lead-acid storage battery of the present embodiment has the following characteristics:
(1)本申请的关键点是比重计+光栅式传感器的传感器组合结构。(1) The key point of this application is the sensor combination structure of hydrometer + grating sensor.
(2)比重计+光栅式组合传感器测量电解液比重的方法。(2) The method of measuring the specific gravity of the electrolyte with a hydrometer + a grating-type combined sensor.
(3)光栅组件结构。(3) Grating component structure.
(4)定位环结构及使用方法。(4) The structure and usage of the positioning ring.
(5)浮漂结构及使用方法。(5) Float structure and usage method.
(6)动光栅结构及使用方法。(6) Structure and usage of moving grating.
(7)螺杆电机+活塞的结构及使用方法。(7) The structure and usage of screw motor + piston.
实施例4如图11所示,本实施例与前面实施例1、2、3、4的主要区别在于:为本申请实施例4中的自动吸液式铅酸蓄电池电解液密度的在线测量装置中,采用的柱塞泵的结构不同,本实施例中,泵安装在圆柱形的腔体1的顶部,包括一个以圆柱形的腔体1内壁为缸体的活塞10,带动活塞10沿圆柱形的腔体1内壁上下滑动的电机12,就像活塞10与圆柱形的腔体1一起组成一个吸筒,当活塞10在电机12带动下向上滑动时,圆柱体形的腔体1内空气压强减小,则浸入到铅酸蓄电池的电解液内的堵头7中间的通道7-1中,电解液从通道7-1中进入到圆柱形的腔体1内,注意观察浮漂5的高度,当其达到设定的高度时,停止电机,进行电解液密度测试。Embodiment 4 As shown in Figure 11, the main difference between this embodiment and previous embodiments 1, 2, 3, and 4 is that it is an online measuring device for the electrolyte density of the automatic liquid-absorbing lead-acid storage battery in embodiment 4 of the present application Among them, the structure of the plunger pump used is different. In this embodiment, the pump is installed on the top of the cylindrical cavity 1, including a piston 10 with the inner wall of the cylindrical cavity 1 as the cylinder body, and drives the piston 10 along the cylinder. The motor 12 that slides up and down on the inner wall of the cylindrical cavity 1 is like a suction cylinder formed by the piston 10 and the cylindrical cavity 1. When the piston 10 slides upwards under the drive of the motor 12, the air pressure in the cylindrical cavity 1 decrease, then immerse in the channel 7-1 in the middle of the plug 7 in the electrolyte of the lead-acid battery, and the electrolyte enters the cylindrical cavity 1 from the channel 7-1, pay attention to observe the height of the float 5, When it reaches the set height, stop the motor and conduct electrolyte density test.

Claims (10)

  1. 一种自动吸液式铅酸蓄电池电解液密度的在线测量装置,包括:An on-line measuring device for electrolyte density of an automatic liquid-absorbing lead-acid battery, comprising:
    漂浮式密度传感器(6);Floating density sensor (6);
    腔体(1),所述的腔体(1)安装在待测的铅酸蓄电池上;A cavity (1), the cavity (1) is installed on the lead-acid battery to be tested;
    将待测铅酸蓄电池的电解液抽入到腔体(1)或者从腔体(1)中排出到待测铅酸蓄电池内的泵;A pump that pumps the electrolyte solution of the lead-acid battery to be tested into the cavity (1) or discharges it from the cavity (1) into the lead-acid battery to be tested;
    设置在所述的腔体(1)顶上并用于采集漂浮式密度传感器(6)漂浮在腔体(1)内的数据采集装置(2)。The data acquisition device (2) is arranged on the top of the cavity (1) and is used for collecting a floating density sensor (6) floating in the cavity (1).
  2. 根据权利要求1所述的在线测量装置,其中:所述的腔体(1)为圆柱形腔体,底部设置有部分浸入铅酸蓄电池内电解液中的堵头(7);在腔体(1)的顶部设置有活塞(10)和带动所述活塞(10)在腔体(1)内上下滑动的电机(12)。The on-line measuring device according to claim 1, wherein: the cavity (1) is a cylindrical cavity, and the bottom is provided with a plug (7) partially immersed in the electrolyte in the lead-acid battery; in the cavity ( 1) is provided with a piston (10) and a motor (12) that drives the piston (10) to slide up and down in the cavity (1).
  3. 根据权利要求1所述的在线测量装置,其中:所述的腔体(1)为圆柱形腔体,底部设置有部分浸入铅酸蓄电池内电解液中的堵头(7);所述泵设置在柱形腔体(1)的上部侧壁上,包括与柱形腔体(1)内连通的缸体(10),设置在缸体(10)内的活塞(11),带动活塞(11)在缸体(10)内来回往复运动的电机(12)。The on-line measurement device according to claim 1, wherein: the cavity (1) is a cylindrical cavity, and the bottom is provided with a plug (7) partially immersed in the electrolyte in the lead-acid battery; On the upper side wall of the cylindrical cavity (1), including the cylinder (10) communicated with the cylindrical cavity (1), the piston (11) arranged in the cylinder (10) drives the piston (11) ) a motor (12) that reciprocates back and forth in the cylinder body (10).
  4. 根据权利要求3所述的在线测量装置,其中:所述的腔体(1)与缸体(10)形成三通结构。The online measuring device according to claim 3, wherein: the cavity (1) and the cylinder (10) form a three-way structure.
  5. 根据权利要求3所述的在线测量装置,其中:所述的漂浮式密度传感器(6)的球体部分(6-1)的直径小于柱形腔体(1)的直径,所述在线测量装置还包括定位环(3),所述的定位环(3)紧密固定于所述腔体(1)的中部内壁,且与所述的漂浮式密度传感器(6)的柱体部分(6-2)之间存在间隙。The online measuring device according to claim 3, wherein: the diameter of the spherical part (6-1) of the floating density sensor (6) is smaller than the diameter of the cylindrical cavity (1), and the online measuring device also Including a positioning ring (3), the positioning ring (3) is tightly fixed on the inner wall of the middle part of the cavity (1), and is connected with the cylinder part (6-2) of the floating density sensor (6) There are gaps in between.
  6. 根据权利要求5所述的在线测量装置,其中:还包括漂浮于电解液面上用于指示电解液液面高度的浮漂(5),所述的浮漂(5)设置在定位环(3)下侧,套在所述的漂浮式密度传感器(6)的柱体部分(6-2)上。The online measuring device according to claim 5, wherein: it also includes a buoy (5) floating on the surface of the electrolyte for indicating the liquid level of the electrolyte, and the buoy (5) is arranged under the positioning ring (3) side, set on the column part (6-2) of the floating density sensor (6).
  7. 根据权利要求5所述的在线测量装置,其中:还包括设置在腔体(1)底部防止漂浮式密度传感器(6)掉出腔体(1)的堵头(7),所述的堵头(7)具有介入到电解液中的尖部,在堵头(7)中间还具有电解液进入到腔体(1)内的通道(7-1)。The online measuring device according to claim 5, wherein: it also includes a plug (7) arranged at the bottom of the cavity (1) to prevent the floating density sensor (6) from falling out of the cavity (1), said plug (7) has a tip that intervenes in the electrolyte, and also has a channel (7-1) for the electrolyte to enter the cavity (1) in the middle of the plug (7).
  8. 根据权利要求1至7中任一所述的在线测量装置,其中:The online measuring device according to any one of claims 1 to 7, wherein:
    所述的数据采集装置(2)为电容式数据采集器,包括紧密固定于腔体(1)顶端的电容器组件和设置在漂浮式密度传感器(6)柱体部分(6-2)顶部外侧的电极(2-3);所述的电容器组件包括相对设置的第一半圆环形电极(2-1)和第二半圆环电极(2-2),在电解液的浮力作用下,漂浮式密度传感器(6)柱体部分(6-2)顶部外侧的电极(2-3)伸入第一半圆环形电极(2-2)和第二半圆环电极(2-3)中间,还包括检测第一半圆环形电极(2-1)和第二半圆环电极(2-2)之间电容量的检测电路。The data acquisition device (2) is a capacitive data acquisition device, including a capacitor assembly tightly fixed on the top of the cavity (1) and a capacitor assembly arranged outside the top of the floating density sensor (6) cylinder part (6-2). Electrodes (2-3); the capacitor assembly includes a first semi-circular electrode (2-1) and a second semi-circular electrode (2-2) oppositely arranged, under the buoyancy of the electrolyte, the floating The electrode (2-3) outside the top of the cylinder part (6-2) of the type density sensor (6) stretches into the middle of the first semi-circular ring electrode (2-2) and the second semi-circular ring electrode (2-3) , also includes a detection circuit for detecting the capacitance between the first semi-circular electrode (2-1) and the second semi-circular electrode (2-2).
  9. 根据权利要求1至7中任一所述的在线测量装置,其中:The online measuring device according to any one of claims 1 to 7, wherein:
    所述的数据采集装置(2)为光电式数据采集装置,包括设置在漂浮式密度传感器(6)柱体部分(6-2)顶上的遮光板(2-6)和设置在遮光板(2-6)两侧的至少两组由光电收发器组成的光电组件(2-4),所述的遮光板(2-6)上具有不同高度的透光长孔(2-6-1),每组光电组件(2-4)与一条透光长孔(2-6-1)相对。Described data acquisition device (2) is the photoelectric data acquisition device, comprises the light shield (2-6) that is arranged on the top of the floating density sensor (6) cylinder part (6-2) and is arranged on the light shield ( 2-6) At least two groups of optoelectronic components (2-4) composed of optoelectronic transceivers on both sides, the light shielding plate (2-6) has light-transmitting long holes (2-6-1) of different heights , each group of photoelectric components (2-4) is opposite to a long light-transmitting hole (2-6-1).
  10. 根据权利要求1至7中任一所述的在线测量装置,其中:The online measuring device according to any one of claims 1 to 7, wherein:
    所述的数据采集装置(2)为光栅式数据采集装置,包括固定在腔体(1)顶上的固定光栅(2-8),相对设置在固定光栅(2-8)两侧的一对发送接收光电器件(2-7),设置在在漂浮式密度传感器(6)柱体部分(6-2)顶上的活动光栅(2-9),所述的活动光栅(2-9)与固定光栅(2-8)平行,所述活动光栅(2-9)相对固定光栅(2-9)做上下移动产生摩尔条纹;所述在线测量装置还包括检测所述的摩尔条纹的检测电路。The data acquisition device (2) is a grating type data acquisition device, comprising a fixed grating (2-8) fixed on the top of the cavity (1), and a pair of Transmitting and receiving optoelectronic devices (2-7), the movable grating (2-9) that is arranged on the top of the floating density sensor (6) cylinder part (6-2), the movable grating (2-9) and The fixed grating (2-8) is parallel, and the movable grating (2-9) moves up and down relative to the fixed grating (2-9) to generate moiré fringes; the on-line measurement device also includes a detection circuit for detecting the moiré fringes.
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CN113314774A (en) * 2021-06-10 2021-08-27 大城绿川(深圳)科技有限公司 Automatic liquid suction type lead-acid storage battery electrolyte density online measuring device

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