WO2022229297A3 - Methods of ligand exchange on surfaces comprising silicon and/or germanium - Google Patents
Methods of ligand exchange on surfaces comprising silicon and/or germanium Download PDFInfo
- Publication number
- WO2022229297A3 WO2022229297A3 PCT/EP2022/061283 EP2022061283W WO2022229297A3 WO 2022229297 A3 WO2022229297 A3 WO 2022229297A3 EP 2022061283 W EP2022061283 W EP 2022061283W WO 2022229297 A3 WO2022229297 A3 WO 2022229297A3
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- ligand
- silicon
- germanium
- methods
- ligand exchange
- Prior art date
Links
- 239000003446 ligand Substances 0.000 title abstract 10
- 229910052732 germanium Inorganic materials 0.000 title abstract 2
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 title abstract 2
- 229910052710 silicon Inorganic materials 0.000 title abstract 2
- 239000010703 silicon Substances 0.000 title abstract 2
- 239000003054 catalyst Substances 0.000 abstract 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 1
- 125000003342 alkenyl group Chemical group 0.000 abstract 1
- 125000000217 alkyl group Chemical group 0.000 abstract 1
- 150000001412 amines Chemical class 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 150000003573 thiols Chemical class 0.000 abstract 1
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
- B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
- B01J31/143—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of aluminium
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K11/00—Luminescent, e.g. electroluminescent, chemiluminescent materials
- C09K11/02—Use of particular materials as binders, particle coatings or suspension media therefor
- C09K11/025—Use of particular materials as binders, particle coatings or suspension media therefor non-luminescent particle coatings or suspension media
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K11/00—Luminescent, e.g. electroluminescent, chemiluminescent materials
- C09K11/08—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials
- C09K11/66—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials containing germanium, tin or lead
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y40/00—Manufacture or treatment of nanostructures
Abstract
A method for ligand exchange, the method comprising: providing a surface comprising a first ligand, wherein the surface comprises germanium, silicon, or a combination thereof; subjecting the surface comprising the first ligand to a catalyst in the presence of a second ligand that is different from the first ligand; and exchanging the first ligand for the second ligand. The catalyst is preferably EtAICI2. First ligands are preferably long-chain amines or hydrogen and second ligands are preferably long-chain thiols, alkyl or alkenyl groups.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US202163180697P | 2021-04-28 | 2021-04-28 | |
US63/180,697 | 2021-04-28 |
Publications (2)
Publication Number | Publication Date |
---|---|
WO2022229297A2 WO2022229297A2 (en) | 2022-11-03 |
WO2022229297A3 true WO2022229297A3 (en) | 2022-11-24 |
Family
ID=81850576
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/EP2022/061283 WO2022229297A2 (en) | 2021-04-28 | 2022-04-28 | Methods of ligand exchange on surfaces comprising silicon and/or germanium |
Country Status (1)
Country | Link |
---|---|
WO (1) | WO2022229297A2 (en) |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1999037409A1 (en) * | 1998-01-22 | 1999-07-29 | Purdue Research Foundation | Functionalized porous silicon surfaces |
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2022
- 2022-04-28 WO PCT/EP2022/061283 patent/WO2022229297A2/en active Application Filing
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1999037409A1 (en) * | 1998-01-22 | 1999-07-29 | Purdue Research Foundation | Functionalized porous silicon surfaces |
Non-Patent Citations (3)
Title |
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MA X ET AL: "Alkyl-terminated crystalline Ge nanoparticles prepared from NaGe: Synthesis, functionalization and optical properties", JOURNAL OF SOLID STATE CHEMISTRY, ORLANDO, FL, US, vol. 181, no. 7, 13 June 2008 (2008-06-13), pages 1628 - 1633, XP023520226, ISSN: 0022-4596, [retrieved on 20080613], DOI: 10.1016/J.JSSC.2008.06.018 * |
MUTHUSWAMY ELAYARAJA ET AL: "Thiol-Capped Germanium Nanocrystals: Preparation and Evidence for Quantum Size Effects", CHEMISTRY OF MATERIALS, vol. 26, no. 6, 26 February 2014 (2014-02-26), US, pages 2138 - 2146, XP055956759, ISSN: 0897-4756, DOI: 10.1021/cm4042154 * |
TANKE ROBIN S. ET AL: "Synthesis of Germanium Nanoclusters with Irreversibly Attached Functional Groups:? Acetals, Alcohols, Esters, and Polymers", CHEMISTRY OF MATERIALS, vol. 15, no. 8, 28 March 2003 (2003-03-28), US, pages 1682 - 1689, XP055956340, ISSN: 0897-4756, DOI: 10.1021/cm021778h * |
Also Published As
Publication number | Publication date |
---|---|
WO2022229297A2 (en) | 2022-11-03 |
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