WO2022227000A1 - Multi-refractive index light diffusion plate and synthesis method therefor - Google Patents

Multi-refractive index light diffusion plate and synthesis method therefor Download PDF

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Publication number
WO2022227000A1
WO2022227000A1 PCT/CN2021/091486 CN2021091486W WO2022227000A1 WO 2022227000 A1 WO2022227000 A1 WO 2022227000A1 CN 2021091486 W CN2021091486 W CN 2021091486W WO 2022227000 A1 WO2022227000 A1 WO 2022227000A1
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surface layer
layer
refractive index
particles
formaldehyde resin
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PCT/CN2021/091486
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French (fr)
Chinese (zh)
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张建林
张黎明
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苏州三鑫时代新材料股份有限公司
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    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B5/00Optical elements other than lenses
    • G02B5/02Diffusing elements; Afocal elements
    • G02B5/0205Diffusing elements; Afocal elements characterised by the diffusing properties
    • G02B5/021Diffusing elements; Afocal elements characterised by the diffusing properties the diffusion taking place at the element's surface, e.g. by means of surface roughening or microprismatic structures
    • G02B5/0226Diffusing elements; Afocal elements characterised by the diffusing properties the diffusion taking place at the element's surface, e.g. by means of surface roughening or microprismatic structures having particles on the surface
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B1/00Optical elements characterised by the material of which they are made; Optical coatings for optical elements
    • G02B1/10Optical coatings produced by application to, or surface treatment of, optical elements
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B1/00Optical elements characterised by the material of which they are made; Optical coatings for optical elements
    • G02B1/10Optical coatings produced by application to, or surface treatment of, optical elements
    • G02B1/16Optical coatings produced by application to, or surface treatment of, optical elements having an anti-static effect, e.g. electrically conducting coatings
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B5/00Optical elements other than lenses
    • G02B5/02Diffusing elements; Afocal elements
    • G02B5/0205Diffusing elements; Afocal elements characterised by the diffusing properties
    • G02B5/0236Diffusing elements; Afocal elements characterised by the diffusing properties the diffusion taking place within the volume of the element
    • G02B5/0242Diffusing elements; Afocal elements characterised by the diffusing properties the diffusion taking place within the volume of the element by means of dispersed particles

Definitions

  • the invention relates to the field of optoelectronic materials, and more particularly, to a multi-refractive index light diffusing plate and a synthesis method thereof.
  • Light diffusers have been widely used in liquid crystal display, LED lighting and imaging systems to fully diffuse the incident light and achieve a softer and more uniform illumination effect.
  • the light diffusing plate is formed by adding a light diffusing agent to the raw material when producing a solid plate.
  • the diffusing agent is evenly distributed in the plate, so that when the light passes through the plate, it will reflect, refract and scatter when it encounters the particles of the diffusing agent, so that the light can pass through the plate evenly without exposing the light source.
  • Variation of surface light sources It is suitable for direct-lit LED TV backlight modules and LED lighting, with high brightness and high diffusivity, which can improve the even diffusion effect of the luminous distribution of the backlight source.
  • the light diffuser is a diffuser layer that uses PMMA/PC/PE/PS as the plastic substrate. When it encounters diffusing particles with different refractive indices, it will refract, reflect and scatter in multiple directions and angles.
  • the refractive index of the existing optical grade polystyrene is 1.51-1.52; the refractive index of the silicone particles is 1.42-1.45, the refractive index of the PMMA particles is 1.45-1.49, and the refractive index of the titanium dioxide particles is 1.42-1.45, can you find an existing low-cost material with a different refractive index from the above-mentioned materials, so that the light passes through different materials, and the angle of refraction is different, thereby changing the direction of the light, so that the light source passes through the light diffuser plate
  • the large increase in light transmittance has become a problem that needs to be solved at present.
  • the present invention proposes a multi-refractive index light diffusing plate and a method for synthesizing the same, which mainly include three layers, namely a first outer surface layer 1, a second outer surface layer 3 and an intermediate layer 2, wherein the above
  • the base material of the three-layer diffuser plate is the same, and the functional particles in the first outer surface layer 1 and the second outer surface layer 3 are the same, which are used to enhance the special functions of the surface layer, such as anti-UV, anti-static, hair
  • the innovation of the present invention lies in that the first outer surface layer 1, the second outer surface layer 3 and the middle layer 2 are all added with 1%-2% by mass of melamine formaldehyde resin and silica composite microspheres 4.
  • the main components of melamine formaldehyde resin and silica composite microspheres 4 are melamine formaldehyde resin, melamine and formaldehyde raw materials are cheap and easy to obtain, and the reaction conditions of the two are mild and the reaction rate is relatively fast.
  • the refractive index of the silicon oxide composite microsphere 4 is 1.6-1.7.
  • a multi-refractive index light diffusing plate comprising: a first outer surface layer 1, an intermediate layer 2, a second outer surface layer 3, the first outer surface layer 1 is divided into an upper surface and a lower surface, the The intermediate layer 2 is divided into an upper surface and a lower surface, the second outer surface layer 3 is divided into an upper surface and a lower surface, the upper surface of the intermediate layer 2 is combined with the lower surface of the first outer surface layer 1, The lower surface of the intermediate layer 2 is combined with the upper surface of the second outer surface layer 3; the base materials of the first outer surface layer 1, the intermediate layer 2 and the second outer surface layer 3 are the same, and are characterized in that: The first outer surface layer 1, the middle layer 2 and the second outer surface layer 3 are all added with silicone particles, titanium dioxide particles, melamine formaldehyde resin and silica composite microspheres 4, the first outer surface layer 1 and the second outer surface layer 4.
  • One or more of anti-UV agents and antistatic agents are added to layer 3, and the main components of melamine formaldehyde resin and si
  • organosilicon particle, titanium dioxide particle, carbon dioxide particle and melamine formaldehyde resin and silica composite microsphere 4 in each layer of the first outer surface layer 1, intermediate layer 2 and second outer surface layer 3 are matched.
  • the ratios are the same, respectively: 90%-95% optical grade polystyrene or PMMA particles, 1%-2% silicone particles, 1%-2% titanium dioxide particles, 1%-2% carbon dioxide particles, 1%-2% Melamine formaldehyde resin and silica composite microspheres 4.
  • the refractive index of optical grade polystyrene is 1.51-1.52; the refractive index of silicone particles is 1.42-1.45, the refractive index of PMMA particles is 1.45-1.49, the refractive index of titanium dioxide particles is 1.42-1.45, and the refractive index of melamine formaldehyde resin is 1.42-1.45.
  • the refractive index of the silica composite microspheres 4 is 1.6-1.7.
  • the average particle size of the melamine formaldehyde resin and silica composite microspheres 4 is 1-20um, and the pore size should not be too large or too small.
  • the silicon composite microspheres 4 are in contact.
  • first outer surface layer 1 and the second outer surface layer 3 contain one or more functional materials such as anti-UV and anti-static.
  • adding an anti-UV agent to the substrate can make the light diffusing plate have anti-UV effect, which increases the anti-yellowing effect of the product; adding an antistatic agent to the substrate can make the light diffusing plate have anti-static properties
  • the function of making the product is not easy to be contaminated with dust.
  • first outer surface layer 1 and the second outer surface layer 3 contain an anti-UV agent
  • the anti-UV agent contains benzoic acids, benzophenones, benzotriazoles, or partially hindered amines At least one of the classes, and uniformly dispersed in the first outer surface layer 1 and the second outer surface layer 3, wherein the anti-UV agent accounts for 3% of the total mass of the first outer surface layer 1 and the second outer surface layer 3 ⁇ 5%.
  • first outer surface layer 1 and the second outer surface layer 3 contain antistatic agents, and the antistatic agents include sulfuric acid derivatives, phosphoric acid derivatives, amines, quaternary ammonium salts, imidazoles and epoxy resins. At least one of the ethane derivatives is uniformly dispersed in the first outer surface layer 1 and the second outer surface layer 3, wherein the antistatic agent accounts for the total mass of the first outer surface layer 1 and the second outer surface layer 3. 2% to 6%.
  • the invention also discloses a method for synthesizing the multi-refractive index light diffusing plate, comprising the following steps:
  • Step of preparing the base material select optical grade polystyrene particles or PMMA particles as the base material;
  • the synthesized silica microspheres were surface-treated with 1% KH-570;
  • Step of making optical masterbatch Select from the prepared base material: select two feeding bins, respectively the first feeding bin and the second feeding bin, and the mass percentage added in the first feeding bin is 95% optical grade polymer
  • the mixture of styrene, 1% silicone particles, 1% PMMA particles, 1% titanium dioxide particles, 1% carbon dioxide particles, 1% melamine formaldehyde resin and silica composite microspheres 4 and powder is uniformly stirred and mixed and then put into the first screw machine. In a pellet mill, melt it into a slurry;
  • the second feeding bin add mass percentage of 95% optical grade polystyrene, 1% silicone particles, 1% PMMA particles, 1% titanium dioxide particles, 1% carbon dioxide particles, 1% melamine formaldehyde resin and silica composite microparticles.
  • the mixture of ball 4 and powder is put into the second screw granulator after uniform stirring and mixing, and it is melted into slurry;
  • the powder includes one or more of a diffusing agent, an anti-UV agent, an oxidizing agent, a light stabilizer and a lubricating dispersing agent;
  • the slurry melt extruded from the head of the first screw granulator is sent to the first outer surface layer 1 and the second outer surface layer 3 of the three-layer superimposed die through the distributor, and the second screw is granulated.
  • the slurry-like melt extruded from the head of the machine is sent to the middle layer 2 of the three-layer superimposed die, and the extrusion rate of the first screw granulator and the second screw granulator and the distribution ratio of the distributor can be controlled at one time. Adjust the thickness of the first outer surface layer 1, the middle layer 2, the second outer surface layer 3 of the three-layer stacking die, and adjust the first outer surface layer 1 and the middle layer of the three-layer stacking die by adjusting the gap of the three-layer stacking die. 2.
  • the thickness of the second outer surface layer 3, the first outer surface layer of the three-layer superimposed die head 1 The spit of the die head forms the first outer surface layer 1 of the diffusion plate, and the spit of the middle layer 2 die head forms the spit of the diffusion plate.
  • the middle layer 2, the second outer surface layer 3 The spit from the die head forms the second outer surface of the diffuser plate, and the first outer surface, the middle layer 2 and the second outer surface of the diffuser plate are formed by three-roll rolling and cooling to form the diffuser plate finished product.
  • the diffuser plate is conveyed forward through the conveyor belt, and is naturally cooled during the conveying process or cooled to room temperature by the cooling liquid, and then cut to the appropriate finished product size.
  • the granulation temperature in the twin-screw granulator is between 160°C and 220°C, and the granulation pressure is between 4.5Mpa and 13.5Mpa.
  • the plate forming temperature in the extrusion forming machine is between 170°C and 230°C, and the plate forming pressure is between 4.5Mpa and 13.5Mpa.
  • the present invention proposes a multi-refractive index light diffusing plate and a method for synthesizing the same, which mainly comprises three layers, namely a first outer surface layer 1, a second outer surface layer 3 and an intermediate layer 2,
  • the base material of the above-mentioned three-layer diffusion plate is the same, and the functional particles in the first outer surface layer 1 and the second outer surface layer 3 are the same, which are used to improve the special functions of the surface layer, such as anti-UV, anti- Static electricity, foaming and other functions;
  • the innovation of the present invention is to add melamine formaldehyde resin and silicon dioxide with a mass percentage of 1%-2% in the first outer surface layer 1, the second outer surface layer 3 and the middle layer 2.
  • Composite microspheres 4 the main components of melamine formaldehyde resin and silica composite microspheres 4 are melamine formaldehyde resin, the raw materials of melamine and formaldehyde are cheap and easy to obtain, and the reaction conditions of the two are mild and the reaction rate is relatively fast.
  • the refractive index of resin and silica composite microspheres 4 is 1.6-1.7.
  • FIG. 1 is a schematic structural diagram of a multi-refractive index light diffusing plate according to a specific embodiment.
  • FIG. 1 it is a schematic structural diagram of a multi-refractive index light diffusing plate.
  • a multi-refractive index light diffusing plate comprising: a first outer surface layer 1, an intermediate layer 2, a second outer surface layer 3, the first outer surface layer 1 is divided into an upper surface and a lower surface, the The intermediate layer 2 is divided into an upper surface and a lower surface, the second outer surface layer 3 is divided into an upper surface and a lower surface, the upper surface of the intermediate layer 2 is combined with the lower surface of the first outer surface layer 1, The lower surface of the intermediate layer 2 is combined with the upper surface of the second outer surface layer 3; the base materials of the first outer surface layer 1, the intermediate layer 2 and the second outer surface layer 3 are the same, and are characterized in that: The first outer surface layer 1, the middle layer 2 and the second outer surface layer 3 are all added with silicone particles, titanium dioxide particles, melamine formaldehyde resin and silica composite microspheres 4, the first outer surface layer 1 and the second outer surface layer 4.
  • One or more of anti-UV agents and antistatic agents are added to layer 3, and the main components of melamine formaldehyde resin and si
  • the ratio of parts by weight of organosilicon particles, titanium dioxide particles, carbon dioxide particles and melamine formaldehyde resin and silica composite microspheres 4 in each layer of the first outer surface layer 1, the intermediate layer 2 and the second outer surface layer 3 The same, respectively: 90% ⁇ 95% optical grade polystyrene or PMMA particles, 1% ⁇ 2% silicone particles, 1% ⁇ 2% titanium dioxide particles, 1% ⁇ 2% carbon dioxide particles, 1% ⁇ 2% melamine Formaldehyde resin and silica composite microspheres 4.
  • the refractive index of the optical grade polystyrene is 1.51; the refractive index of the silicone particles is 1.42, the refractive index of the PMMA particles is 1.45, the refractive index of the titanium dioxide particles is 1.42, and the melamine formaldehyde resin and the silica composite microspheres 4
  • the refractive index is 1.6.
  • the average particle size of the melamine formaldehyde resin and silica composite microspheres 4 is 1-20um, and the pore size should not be too large or too small. By setting the pore size range, the light can be uniformly mixed with the melamine formaldehyde resin and silica.
  • the composite microspheres 4 are in contact.
  • the first outer surface layer 1 and the second outer surface layer 3 contain one or more functional materials such as anti-UV and anti-static. Under normal circumstances, adding an anti-UV agent to the substrate can make the light diffusing plate have anti-UV effect, which increases the anti-yellowing effect of the product; adding an antistatic agent to the substrate can make the light diffusing plate have anti-static properties The function of making the product is not easy to be contaminated with dust.
  • the first outer surface layer 1 and the second outer surface layer 3 contain an anti-UV agent, and the anti-UV agent contains benzoic acids, benzophenones, benzotriazoles, or partially hindered amines At least one of them is uniformly dispersed in the first outer surface layer 1 and the second outer surface layer 3, wherein the anti-UV agent accounts for 3% to 5% of the total mass of the first outer surface layer 1 and the second outer surface layer 3. %.
  • the first outer surface layer 1 and the second outer surface layer 3 contain antistatic agents, and the antistatic agents include sulfuric acid derivatives, phosphoric acid derivatives, amines, quaternary ammonium salts, imidazoles and ethylene oxide. At least one of the alkane derivatives, and uniformly dispersed in the first outer surface layer 1 and the second outer surface layer 3, wherein the antistatic agent accounts for 2 of the total mass of the first outer surface layer 1 and the second outer surface layer 3 % ⁇ 6%.
  • the invention also discloses a method for synthesizing the multi-refractive index light diffusing plate, comprising the following steps:
  • Step of preparing the base material select optical grade polystyrene particles or PMMA particles as the base material;
  • Step of preparing the base material select optical grade polystyrene particles or PMMA particles as the base material;
  • the synthesized silica microspheres were surface-treated with 1% KH-570;
  • Step of making optical masterbatch Select from the prepared base material: select two feeding bins, respectively the first feeding bin and the second feeding bin, and the mass percentage added in the first feeding bin is 95% optical grade polymer
  • the mixture of styrene, 1% silicone particles, 1% PMMA particles, 1% titanium dioxide particles, 1% carbon dioxide particles, 1% melamine formaldehyde resin and silica composite microspheres 4 and powder is uniformly stirred and mixed and then put into the first screw machine. In a pellet mill, melt it into a slurry;
  • the second feeding bin add mass percentage of 95% optical grade polystyrene, 1% silicone particles, 1% PMMA particles, 1% titanium dioxide particles, 1% carbon dioxide particles, 1% melamine formaldehyde resin and silica composite microparticles.
  • the mixture of ball 4 and powder is put into the second screw granulator after uniform stirring and mixing, and it is melted into slurry;
  • the powder includes one or more of a diffusing agent, an anti-UV agent, an oxidizing agent, a light stabilizer and a lubricating dispersing agent;
  • the slurry melt extruded from the head of the first screw granulator is sent to the first outer surface layer 1 and the second outer surface layer 3 of the three-layer superimposed die through the distributor, and the second screw is granulated.
  • the slurry-like melt extruded from the head of the machine is sent to the middle layer 2 of the three-layer superimposed die, and the extrusion rate of the first screw granulator and the second screw granulator and the distribution ratio of the distributor can be controlled at one time. Adjust the thickness of the first outer surface layer 1, the middle layer 2, the second outer surface layer 3 of the three-layer stacking die, and adjust the first outer surface layer 1 and the middle layer of the three-layer stacking die by adjusting the gap of the three-layer stacking die. 2.
  • the thickness of the second outer surface layer 3, the first outer surface layer of the three-layer superimposed die head 1 The spit of the die head forms the first outer surface layer 1 of the diffusion plate, and the spit of the middle layer 2 die head forms the spit of the diffusion plate.
  • the middle layer 2, the second outer surface layer 3 The spit from the die head forms the second outer surface of the diffuser plate, and the first outer surface, the middle layer 2 and the second outer surface of the diffuser plate are formed by three-roll rolling and cooling to form the diffuser plate finished product.
  • the diffuser plate is conveyed forward through the conveyor belt, and is naturally cooled during the conveying process or cooled to room temperature by the cooling liquid, and then cut to the appropriate finished product size.
  • the granulation temperature in the twin-screw granulator is between 160°C and 220°C, and the granulation pressure is between 4.5Mpa and 13.5Mpa.
  • the plate forming temperature in the extrusion forming machine is between 170°C and 230°C, and the plate forming pressure is between 4.5Mpa and 13.5Mpa.
  • a multi-refractive index light diffusing plate comprising: a first outer surface layer 1, an intermediate layer 2, a second outer surface layer 3, the first outer surface layer 1 is divided into an upper surface and a lower surface, the The intermediate layer 2 is divided into an upper surface and a lower surface, the second outer surface layer 3 is divided into an upper surface and a lower surface, the upper surface of the intermediate layer 2 is combined with the lower surface of the first outer surface layer 1, The lower surface of the intermediate layer 2 is combined with the upper surface of the second outer surface layer 3; the base materials of the first outer surface layer 1, the intermediate layer 2 and the second outer surface layer 3 are the same, and are characterized in that: The first outer surface layer 1, the middle layer 2 and the second outer surface layer 3 are all added with silicone particles, titanium dioxide particles, melamine formaldehyde resin and silica composite microspheres 4, the first outer surface layer 1 and the second outer surface layer 4.
  • One or more of anti-UV agents and antistatic agents are added to layer 3, and the main components of melamine formaldehyde resin and si
  • Optical grade polystyrene, organosilicon particles, PMMA particles, titanium dioxide particles, carbon dioxide particles and melamine formaldehyde resin and silicon dioxide composite in each layer of the first outer surface layer 1, the intermediate layer 2 and the second outer surface layer 3
  • the proportions by weight of the microspheres 4 are the same, respectively: 90% optical grade polystyrene, 2% silicone particles, 1% to 2% PMMA particles, 2% titanium dioxide particles, 2% carbon dioxide particles, 2% melamine formaldehyde Resin and silica composite microspheres 4.
  • the refractive index of optical grade polystyrene is 1.52; the refractive index of silicone particles is 1.45, the refractive index of PMMA particles is 1.49, the refractive index of titanium dioxide particles is 1.45, and the melamine formaldehyde resin and silica composite microspheres4 The index of refraction is 1.7.
  • the average particle size of the melamine formaldehyde resin and silica composite microspheres 4 is 1-20um, and the pore size should not be too large or too small. By setting the pore size range, the light can be uniformly mixed with the melamine formaldehyde resin and silica.
  • the composite microspheres 4 are in contact.
  • the first outer surface layer 1 and the second outer surface layer 3 contain one or more functional materials such as anti-UV and anti-static. Under normal circumstances, adding an anti-UV agent to the substrate can make the light diffusing plate have anti-UV effect, which increases the anti-yellowing effect of the product; adding an antistatic agent to the substrate can make the light diffusing plate have anti-static properties The function of making the product is not easy to be contaminated with dust.
  • the first outer surface layer 1 and the second outer surface layer 3 contain an anti-UV agent, and the anti-UV agent contains benzoic acids, benzophenones, benzotriazoles, or partially hindered amines At least one of them is uniformly dispersed in the first outer surface layer 1 and the second outer surface layer 3, wherein the anti-UV agent accounts for 3% to 5% of the total mass of the first outer surface layer 1 and the second outer surface layer 3. %.
  • the first outer surface layer 1 and the second outer surface layer 3 contain antistatic agents, and the antistatic agents include sulfuric acid derivatives, phosphoric acid derivatives, amines, quaternary ammonium salts, imidazoles and ethylene oxide. At least one of the alkane derivatives, and uniformly dispersed in the first outer surface layer 1 and the second outer surface layer 3, wherein the antistatic agent accounts for 2 of the total mass of the first outer surface layer 1 and the second outer surface layer 3 % ⁇ 6%.
  • the invention also discloses a method for synthesizing the multi-refractive index light diffusing plate, comprising the following steps:
  • Step of preparing the base material select optical grade polystyrene particles or PMMA particles as the base material;
  • Step of preparing the base material select optical grade polystyrene particles or PMMA particles as the base material;
  • the synthesized silica microspheres were surface-treated with 1% KH-570;
  • Step of making optical masterbatch Select from the prepared base material: select two feeding bins, respectively the first feeding bin and the second feeding bin, and the mass percentage added in the first feeding bin is 95% optical grade polymer
  • the mixture of styrene, 1% silicone particles, 1% PMMA particles, 1% titanium dioxide particles, 1% carbon dioxide particles, 1% melamine formaldehyde resin and silica composite microspheres 4 and powder is uniformly stirred and mixed and then put into the first screw machine. In a pellet mill, melt it into a slurry;
  • the second feeding bin add mass percentage of 95% optical grade polystyrene, 1% silicone particles, 1% PMMA particles, 1% titanium dioxide particles, 1% carbon dioxide particles, 1% melamine formaldehyde resin and silica composite microparticles.
  • the mixture of ball 4 and powder is put into the second screw granulator after uniform stirring and mixing, and it is melted into slurry;
  • the powder includes one or more of a diffusing agent, an anti-UV agent, an oxidizing agent, a light stabilizer and a lubricating dispersing agent;
  • the slurry melt extruded from the head of the first screw granulator is sent to the first outer surface layer 1 and the second outer surface layer 3 of the three-layer superimposed die through the distributor, and the second screw is granulated.
  • the slurry-like melt extruded from the head of the machine is sent to the middle layer 2 of the three-layer superimposed die, and the extrusion rate of the first screw granulator and the second screw granulator and the distribution ratio of the distributor can be controlled at one time. Adjust the thickness of the first outer surface layer 1, the middle layer 2, the second outer surface layer 3 of the three-layer stacking die, and adjust the first outer surface layer 1 and the middle layer of the three-layer stacking die by adjusting the gap of the three-layer stacking die. 2.
  • the thickness of the second outer surface layer 3, the first outer surface layer of the three-layer superimposed die head 1 The spit of the die head forms the first outer surface layer 1 of the diffusion plate, and the spit of the middle layer 2 die head forms the spit of the diffusion plate.
  • the middle layer 2, the second outer surface layer 3 The spit from the die head forms the second outer surface of the diffuser plate, and the first outer surface, the middle layer 2 and the second outer surface of the diffuser plate are formed by three-roll rolling and cooling to form the diffuser plate finished product.
  • the diffuser plate is conveyed forward through the conveyor belt, and is naturally cooled during the conveying process or cooled to room temperature by the cooling liquid, and then cut to the appropriate finished product size.
  • the granulation temperature in the twin-screw granulator is between 160°C and 220°C, and the granulation pressure is between 4.5Mpa and 13.5Mpa.
  • the plate forming temperature in the extrusion forming machine is between 170°C and 230°C, and the plate forming pressure is between 4.5Mpa and 13.5Mpa.
  • the high haze, high transmittance light diffusing plate of the present invention uses simple materials, which are relatively easy to obtain raw materials, and the amount used is relatively small, so the raw material cost is relatively low.
  • the refractive index of the silicone melamine formaldehyde resin and the silica composite microsphere 4 in the intermediate layer 2 in the present invention is 1.7
  • the refractive index of the optical grade polystyrene is 1.52
  • the refractive index of the optical grade polystyrene is 1.52.
  • the refractive index of silicone particles is 1.45
  • the refractive index of PMMA particles is 1.49
  • the refractive index of titanium dioxide particles is 1.45.
  • the refraction angle of light is enriched and the light passing through is increased.
  • the possibility of refraction angles of different materials, more changes in the direction of light, makes the light mixing effect better when the light source passes through the light diffuser, and the light transmittance is greatly increased, which can meet most market needs and conform to TFT-LCD products. needs and development.

Abstract

A multi-refractive index light diffusion plate and a synthesis method therefor. The multi-refractive index light diffusion plate mainly comprises three layers, namely a first outer surface layer, a second outer surface layer and an intermediate layer, wherein the three layers of the diffusion plate have the same base material, and functional particles in the first outer surface layer and the second outer surface layer are the same and are used for improving special functions of the surface layers. 1%-2% by weight of melamine formaldehyde resin and silicon dioxide composite microspheres are added into the first outer surface layer, the second outer surface layer and the intermediate layer, refraction angles of light are enriched by means of introducing a light diffusion agent with a high refractive index angle, the possibility of the refraction angles of the light passing through different materials is increased, and the direction of the light is changed more significantly, such that when light from a light source passes through the light diffusion plate, a better light mixing effect is provided, the light transmittance is greatly increased, most market requirements can be met, and requirements and development of TFT-LCD products are met.

Description

一种多折射率的光扩散板及其合成方法A kind of multi-refractive index light diffusing plate and its synthesis method 技术领域technical field
本发明涉及光电材料领域,较为具体的,涉及一种多折射率的光扩散板及其合成方法。The invention relates to the field of optoelectronic materials, and more particularly, to a multi-refractive index light diffusing plate and a synthesis method thereof.
背景技术Background technique
光扩散板目前已经广泛应用在液晶显示、LED照明以及成像等系统中,使入射光充分散射,实现更柔和、均匀的照射效果。光扩散板是在生产实心板的时候,在原料中添加光扩散剂而形成的。扩散剂通过均匀分布在板材内,使得光线经过板材时,碰到扩散剂颗粒发生反射、折射、散射的效果,从而是光线能够均匀得透过板材但又不会露出光源,达到从点光源到面光源的变化。适用于直下式LED电视机背光模组、LED照明,具有高辉度、高扩散性,提高背光源的发光分布均匀的扩散效果。Light diffusers have been widely used in liquid crystal display, LED lighting and imaging systems to fully diffuse the incident light and achieve a softer and more uniform illumination effect. The light diffusing plate is formed by adding a light diffusing agent to the raw material when producing a solid plate. The diffusing agent is evenly distributed in the plate, so that when the light passes through the plate, it will reflect, refract and scatter when it encounters the particles of the diffusing agent, so that the light can pass through the plate evenly without exposing the light source. Variation of surface light sources. It is suitable for direct-lit LED TV backlight modules and LED lighting, with high brightness and high diffusivity, which can improve the even diffusion effect of the luminous distribution of the backlight source.
光扩散板是光线通过以PMMA/PC/PE/PS等为塑料基材的扩散层,遇到与其折射率相异的扩散粒子时,会发生多方向、多角度的折射、反射以及散射现象,以此获得光学扩散效果,现有的光学级聚苯乙烯的折射率为1.51~1.52;有机硅粒子的折射率为1.42-1.45,PMMA粒子的折射率为1.45-1.49,二氧化钛粒子的折射率为1.42-1.45,能否找到一种现有的成本低的材料且与上述材料的折射率不同,从而使得光通过不同的材料,折射的角度不同,从而改变光的方向,使得光源通过光扩散板时透光率大大增加成了当下需要解决的问题。The light diffuser is a diffuser layer that uses PMMA/PC/PE/PS as the plastic substrate. When it encounters diffusing particles with different refractive indices, it will refract, reflect and scatter in multiple directions and angles. In order to obtain the optical diffusion effect, the refractive index of the existing optical grade polystyrene is 1.51-1.52; the refractive index of the silicone particles is 1.42-1.45, the refractive index of the PMMA particles is 1.45-1.49, and the refractive index of the titanium dioxide particles is 1.42-1.45, can you find an existing low-cost material with a different refractive index from the above-mentioned materials, so that the light passes through different materials, and the angle of refraction is different, thereby changing the direction of the light, so that the light source passes through the light diffuser plate The large increase in light transmittance has become a problem that needs to be solved at present.
发明内容SUMMARY OF THE INVENTION
有鉴于此,本发明提出一种多折射率的光扩散板及其合成方法,其主要包括三层,分别为第一外表面层1、第二外表面层3和中间层2,其中以上所述的三层扩散板的基材相同,而第一外表面层1和第二外表面层3中的功能型微粒相同,其用来提升表面层的特殊功能,例如抗UV、抗静电、发泡等功能;本发明的创新点在于在第一外表面层1、第二外表面层3和中间层2中 均加入质量百分比为1%-2%的三聚氰胺甲醛树脂和二氧化硅复合微球4,三聚氰胺甲醛树脂和二氧化硅复合微球4的主要成分为三聚氰胺甲醛树脂,三聚氰胺和甲醛原料均廉价易得,并且二者反应条件温和、反应速率较快,二氧化硅三聚氰胺甲醛树脂和二氧化硅复合微球4的折射率为1.6-1.7,通过引入高折射率角度的光扩散剂,丰富了光的折射角度,增加了光通过不同的材料的折射角度的可能性,更多的改变光的方向,使得光源通过光扩散板时混光效果更好,透光率大大增加,可以满足大部分的市场需求,符合TFT-LCD产品的需求和发展。In view of this, the present invention proposes a multi-refractive index light diffusing plate and a method for synthesizing the same, which mainly include three layers, namely a first outer surface layer 1, a second outer surface layer 3 and an intermediate layer 2, wherein the above The base material of the three-layer diffuser plate is the same, and the functional particles in the first outer surface layer 1 and the second outer surface layer 3 are the same, which are used to enhance the special functions of the surface layer, such as anti-UV, anti-static, hair The innovation of the present invention lies in that the first outer surface layer 1, the second outer surface layer 3 and the middle layer 2 are all added with 1%-2% by mass of melamine formaldehyde resin and silica composite microspheres 4. The main components of melamine formaldehyde resin and silica composite microspheres 4 are melamine formaldehyde resin, melamine and formaldehyde raw materials are cheap and easy to obtain, and the reaction conditions of the two are mild and the reaction rate is relatively fast. The refractive index of the silicon oxide composite microsphere 4 is 1.6-1.7. By introducing a light diffusing agent with a high refractive index angle, the refraction angle of the light is enriched, and the possibility of the refraction angle of the light passing through different materials is increased. More changes The direction of the light makes the light mixing effect better when the light source passes through the light diffusion plate, and the light transmittance is greatly increased, which can meet most market demands and meet the needs and development of TFT-LCD products.
一种多折射率的光扩散板,其包括:第一外表面层1、中间层2、第二外表面层3,所述的第一外表面层1分为上表面和下表面,所述的中间层2分为上表面和下表面,所述的第二外表面层3分为上表面和下表面,所述的中间层2的上表面与第一外表面层1的下表面结合,所述的中间层2的下表面与第二外表面层3的上表面结合;所述的第一外表面层1、中间层2和第二外表面层3的基材相同,其特征在于:第一外表面层1、中间层2和第二外表面层3均添加了有机硅粒子、二氧化钛粒子、三聚氰胺甲醛树脂和二氧化硅复合微球4,第一外表面层1和第二外表面层3中添加抗UV剂、抗静电剂中的一种或多种,三聚氰胺甲醛树脂和二氧化硅复合微球4的主要成分为三聚氰胺甲醛树脂。A multi-refractive index light diffusing plate, comprising: a first outer surface layer 1, an intermediate layer 2, a second outer surface layer 3, the first outer surface layer 1 is divided into an upper surface and a lower surface, the The intermediate layer 2 is divided into an upper surface and a lower surface, the second outer surface layer 3 is divided into an upper surface and a lower surface, the upper surface of the intermediate layer 2 is combined with the lower surface of the first outer surface layer 1, The lower surface of the intermediate layer 2 is combined with the upper surface of the second outer surface layer 3; the base materials of the first outer surface layer 1, the intermediate layer 2 and the second outer surface layer 3 are the same, and are characterized in that: The first outer surface layer 1, the middle layer 2 and the second outer surface layer 3 are all added with silicone particles, titanium dioxide particles, melamine formaldehyde resin and silica composite microspheres 4, the first outer surface layer 1 and the second outer surface layer 4. One or more of anti-UV agents and antistatic agents are added to layer 3, and the main components of melamine formaldehyde resin and silica composite microspheres 4 are melamine formaldehyde resin.
进一步的,第一外表面层1、中间层2和第二外表面层3每层中的有机硅粒子、二氧化钛粒子、二氧化碳粒子和三聚氰胺甲醛树脂和二氧化硅复合微球4的重量份数配比相同,分别为:90%~95%光学级聚苯乙烯或者PMMA粒子,1%~2%有机硅粒子,1%~2%二氧化钛粒子,1%~2%二氧化碳粒子,1%~2%三聚氰胺甲醛树脂和二氧化硅复合微球4。Further, the parts by weight of organosilicon particle, titanium dioxide particle, carbon dioxide particle and melamine formaldehyde resin and silica composite microsphere 4 in each layer of the first outer surface layer 1, intermediate layer 2 and second outer surface layer 3 are matched. The ratios are the same, respectively: 90%-95% optical grade polystyrene or PMMA particles, 1%-2% silicone particles, 1%-2% titanium dioxide particles, 1%-2% carbon dioxide particles, 1%-2% Melamine formaldehyde resin and silica composite microspheres 4.
进一步的,光学级聚苯乙烯的折射率为1.51~1.52;有机硅粒子的折射率为1.42-1.45,PMMA粒子的折射率为1.45-1.49,二氧化钛粒子的折射率为1.42-1.45,三聚氰胺甲醛树脂和二氧化硅复合微球4的折射率为1.6-1.7。Further, the refractive index of optical grade polystyrene is 1.51-1.52; the refractive index of silicone particles is 1.42-1.45, the refractive index of PMMA particles is 1.45-1.49, the refractive index of titanium dioxide particles is 1.42-1.45, and the refractive index of melamine formaldehyde resin is 1.42-1.45. The refractive index of the silica composite microspheres 4 is 1.6-1.7.
进一步的,三聚氰胺甲醛树脂和二氧化硅复合微球4的平均粒径为1~20um,孔径不宜过大也不宜过小,通过孔径范围的设置可以使得光可以均匀的与三聚氰胺甲醛树脂和二氧化硅复合微球4接触。Further, the average particle size of the melamine formaldehyde resin and silica composite microspheres 4 is 1-20um, and the pore size should not be too large or too small. The silicon composite microspheres 4 are in contact.
进一步的,第一外表面层1和第二外表面层3中包含具有抗UV、抗静电 等功能材料中的一种或多种。通常情况下,在基材中加入抗UV剂,可以使得光扩散板具有抗UV的效果,使得产品抗黄化的效果增加;在基材中加入抗静电剂,可以使得光扩散板具有抗静电的作用,使得产品上不易沾染灰尘。Further, the first outer surface layer 1 and the second outer surface layer 3 contain one or more functional materials such as anti-UV and anti-static. Under normal circumstances, adding an anti-UV agent to the substrate can make the light diffusing plate have anti-UV effect, which increases the anti-yellowing effect of the product; adding an antistatic agent to the substrate can make the light diffusing plate have anti-static properties The function of making the product is not easy to be contaminated with dust.
进一步的,第一外表面层1和第二外表面层3中含有抗UV剂,所述的抗UV剂为含苯甲酸类、二苯甲酮类、苯并三唑类、或部分受阻胺类中的至少一种,且均匀分散在第一外表面层1和第二外表面层3中,其中抗UV剂占第一外表面层1和第二外表面层3总质量的3%~5%。Further, the first outer surface layer 1 and the second outer surface layer 3 contain an anti-UV agent, and the anti-UV agent contains benzoic acids, benzophenones, benzotriazoles, or partially hindered amines At least one of the classes, and uniformly dispersed in the first outer surface layer 1 and the second outer surface layer 3, wherein the anti-UV agent accounts for 3% of the total mass of the first outer surface layer 1 and the second outer surface layer 3~ 5%.
进一步的,第一外表面层1和第二外表面层3中含有抗静电剂,所述的抗静电剂为包含硫酸衍生物、磷酸衍生物、胺类、季铵盐、咪唑类以及环氧乙烷衍生物中的至少一种,且均匀分散在第一外表面层1和第二外表面层3中,其中抗静电剂占第一外表面层1和第二外表面层3总质量的2%~6%。Further, the first outer surface layer 1 and the second outer surface layer 3 contain antistatic agents, and the antistatic agents include sulfuric acid derivatives, phosphoric acid derivatives, amines, quaternary ammonium salts, imidazoles and epoxy resins. At least one of the ethane derivatives is uniformly dispersed in the first outer surface layer 1 and the second outer surface layer 3, wherein the antistatic agent accounts for the total mass of the first outer surface layer 1 and the second outer surface layer 3. 2% to 6%.
本发明还公开了所述的多折射率的光扩散板的合成方法,包括如下步骤:The invention also discloses a method for synthesizing the multi-refractive index light diffusing plate, comprising the following steps:
(1)准备基材步骤:选用光学级聚苯乙烯颗粒或者PMMA粒子作为基材;(1) Step of preparing the base material: select optical grade polystyrene particles or PMMA particles as the base material;
(2)制作三聚氰胺甲醛树脂和二氧化硅复合微球4的步骤:首先,将三聚氰胺和质量百分浓度为37%-40%甲醛溶液按质量比1:(2.4-6)混合,调节pH为8-10,60℃-65℃的温度下搅拌反应,溶解于适量蒸馏水中,制备得到三聚氰胺-甲醛的可溶性预聚物溶液;(2) The steps of making melamine formaldehyde resin and silica composite microspheres 4: First, mix melamine and formaldehyde solution with a mass percentage concentration of 37%-40% in a mass ratio of 1:(2.4-6), and adjust the pH to be 8-10, stirring and reacting at a temperature of 60°C-65°C, and dissolving in an appropriate amount of distilled water to prepare a melamine-formaldehyde soluble prepolymer solution;
其次,用质量分数1%的KH-570对合成的二氧化硅微球进行表面处理;Secondly, the synthesized silica microspheres were surface-treated with 1% KH-570;
最后,在三聚氰胺-甲醛的可溶性预聚物溶液中加入用KH-570处理过的二氧化硅微球,用硫酸化合物调节溶液为酸性,离心干燥得到三聚氰胺甲醛树脂和二氧化硅复合微球4;Finally, adding silica microspheres treated with KH-570 to the soluble prepolymer solution of melamine-formaldehyde, adjusting the solution to be acidic with a sulfuric acid compound, and centrifuging to obtain melamine formaldehyde resin and silica composite microspheres 4;
(3)制作光学母粒步骤:从准备的基材中选取:选取两个加料仓,分别为第一加料仓和第二加料仓,在第一加料仓中添加质量百分比为95%光学级聚苯乙烯、1%有机硅粒子、1%PMMA粒子、1%二氧化钛粒子、1%二氧化碳粒子、1%三聚氰胺甲醛树脂和二氧化硅复合微球4和粉剂的混合物均匀搅拌混合后投入第一螺杆造粒机中,将其融化为浆状;(3) Step of making optical masterbatch: Select from the prepared base material: select two feeding bins, respectively the first feeding bin and the second feeding bin, and the mass percentage added in the first feeding bin is 95% optical grade polymer The mixture of styrene, 1% silicone particles, 1% PMMA particles, 1% titanium dioxide particles, 1% carbon dioxide particles, 1% melamine formaldehyde resin and silica composite microspheres 4 and powder is uniformly stirred and mixed and then put into the first screw machine. In a pellet mill, melt it into a slurry;
在第二加料仓中添加质量百分比为95%光学级聚苯乙烯、1%有机硅粒子、1%PMMA粒子、1%二氧化钛粒子、1%二氧化碳粒子、1%三聚氰胺甲醛树脂和二氧化硅复合微球4和粉剂的混合物均匀搅拌混合后投入第二螺杆造粒机中,将其融化为浆状;In the second feeding bin, add mass percentage of 95% optical grade polystyrene, 1% silicone particles, 1% PMMA particles, 1% titanium dioxide particles, 1% carbon dioxide particles, 1% melamine formaldehyde resin and silica composite microparticles. The mixture of ball 4 and powder is put into the second screw granulator after uniform stirring and mixing, and it is melted into slurry;
所述粉剂包括扩散剂、抗UV剂、氧化剂、光稳定剂和润滑分散剂中的一种或多种;The powder includes one or more of a diffusing agent, an anti-UV agent, an oxidizing agent, a light stabilizer and a lubricating dispersing agent;
(4)挤出成型步骤:(4) Extrusion molding steps:
将第一螺杆造粒机的机头挤出的浆状熔融物通过分配器后分别输送给三层叠加模头的第一外表面层1和第二外表面层3,将第二螺杆造粒机的机头挤出的浆状熔融物输送给三层叠加模头的中间层2,通过控制第一螺杆造粒机和第二螺杆造粒机的挤出速率和分配器的分配比例可以一次调节三层叠加模头第一外表面层1、中间层2、第二外表面层3厚度,通过调节三层叠加摸头的间隙可以二次调节三层叠加摸头第一外表面层1、中间层2、第二外表面层3厚度,三层叠加模头的第一外表面层1模头的吐出物形成扩散板的第一外表面层1,中间层2模头的吐出物形成扩散板的中间层2,第二外表面层3模头的吐出物形成扩散板的第二外表面,扩散板的第一外表面、中间层2和第二外表面通过三辊延压冷却成型形成扩散板成品。The slurry melt extruded from the head of the first screw granulator is sent to the first outer surface layer 1 and the second outer surface layer 3 of the three-layer superimposed die through the distributor, and the second screw is granulated. The slurry-like melt extruded from the head of the machine is sent to the middle layer 2 of the three-layer superimposed die, and the extrusion rate of the first screw granulator and the second screw granulator and the distribution ratio of the distributor can be controlled at one time. Adjust the thickness of the first outer surface layer 1, the middle layer 2, the second outer surface layer 3 of the three-layer stacking die, and adjust the first outer surface layer 1 and the middle layer of the three-layer stacking die by adjusting the gap of the three-layer stacking die. 2. The thickness of the second outer surface layer 3, the first outer surface layer of the three-layer superimposed die head 1 The spit of the die head forms the first outer surface layer 1 of the diffusion plate, and the spit of the middle layer 2 die head forms the spit of the diffusion plate. The middle layer 2, the second outer surface layer 3 The spit from the die head forms the second outer surface of the diffuser plate, and the first outer surface, the middle layer 2 and the second outer surface of the diffuser plate are formed by three-roll rolling and cooling to form the diffuser plate finished product.
(5)冷却裁切步骤:(5) Cooling and cutting steps:
经过三辊延压后的扩散板通过传送带向前输送,在输送过程中自然冷却或通过冷却液进行冷却至室温后,裁切至适当的成品尺寸。After the three-roller rolling, the diffuser plate is conveyed forward through the conveyor belt, and is naturally cooled during the conveying process or cooled to room temperature by the cooling liquid, and then cut to the appropriate finished product size.
进一步的,所述制作光学母粒步骤中,所述双螺杆造粒机中的造粒温度在160℃至220℃之间,造粒压力在4.5Mpa至13.5Mpa之间。Further, in the step of making the optical masterbatch, the granulation temperature in the twin-screw granulator is between 160°C and 220°C, and the granulation pressure is between 4.5Mpa and 13.5Mpa.
进一步的,挤出成型步骤中,所述挤出成型机中的板材成型温度在170℃至230℃之间,板材成型压力在4.5Mpa至13.5Mpa之间。Further, in the extrusion forming step, the plate forming temperature in the extrusion forming machine is between 170°C and 230°C, and the plate forming pressure is between 4.5Mpa and 13.5Mpa.
与现有技术相比,本发明提出一种多折射率的光扩散板及其合成方法,其主要包括三层,分别为第一外表面层1、第二外表面层3和中间层2,其中以上所述的三层扩散板的基材相同,而第一外表面层1和第二外表面层3中的功能型微粒相同,其用来提升表面层的特殊功能,例如抗UV、抗静电、发泡等功能;本发明的创新点在于在第一外表面层1、第二外表面层3和中间层2中均加入质量百分比为1%-2%的三聚氰胺甲醛树脂和二氧化硅复合微球4,三聚氰胺甲醛树脂和二氧化硅复合微球4的主要成分为三聚氰胺甲醛树脂,三聚氰胺和甲醛原料均廉价易得,并且二者反应条件温和、反应速率较快,二氧化硅三聚氰胺甲醛树脂和二氧化硅复合微球4的折射率为1.6-1.7,通过引入高折射率角度的光扩散剂,丰富了光的折射角度,增加了光通过不 同的材料的折射角度的可能性,更多的改变光的方向,使得光源通过光扩散板时混光效果更好,透光率大大增加,可以满足大部分的市场需求,符合TFT-LCD产品的需求和发展。Compared with the prior art, the present invention proposes a multi-refractive index light diffusing plate and a method for synthesizing the same, which mainly comprises three layers, namely a first outer surface layer 1, a second outer surface layer 3 and an intermediate layer 2, The base material of the above-mentioned three-layer diffusion plate is the same, and the functional particles in the first outer surface layer 1 and the second outer surface layer 3 are the same, which are used to improve the special functions of the surface layer, such as anti-UV, anti- Static electricity, foaming and other functions; the innovation of the present invention is to add melamine formaldehyde resin and silicon dioxide with a mass percentage of 1%-2% in the first outer surface layer 1, the second outer surface layer 3 and the middle layer 2. Composite microspheres 4, the main components of melamine formaldehyde resin and silica composite microspheres 4 are melamine formaldehyde resin, the raw materials of melamine and formaldehyde are cheap and easy to obtain, and the reaction conditions of the two are mild and the reaction rate is relatively fast. The refractive index of resin and silica composite microspheres 4 is 1.6-1.7. By introducing a light diffusing agent with a high refractive index angle, the refraction angle of light is enriched, and the possibility of light passing through different materials is increased. By changing the direction of the light more, the light mixing effect is better when the light source passes through the light diffusion plate, and the light transmittance is greatly increased, which can meet most of the market needs and meet the needs and development of TFT-LCD products.
附图说明Description of drawings
图1为具体实施方式的多折射率的光扩散板的结构示意图。FIG. 1 is a schematic structural diagram of a multi-refractive index light diffusing plate according to a specific embodiment.
主要元器件说明:Description of main components:
Figure PCTCN2021091486-appb-000001
Figure PCTCN2021091486-appb-000001
如下具体实施方式将结合上述附图进一步说明本发明。The following specific embodiments will further illustrate the present invention in conjunction with the above drawings.
具体实施方式Detailed ways
如图1所示,为多折射率的光扩散板的结构示意图。As shown in FIG. 1 , it is a schematic structural diagram of a multi-refractive index light diffusing plate.
具体实施例1Specific Example 1
一种多折射率的光扩散板,其包括:第一外表面层1、中间层2、第二外表面层3,所述的第一外表面层1分为上表面和下表面,所述的中间层2分为上表面和下表面,所述的第二外表面层3分为上表面和下表面,所述的中间层2的上表面与第一外表面层1的下表面结合,所述的中间层2的下表面与第二外表面层3的上表面结合;所述的第一外表面层1、中间层2和第二外表面层3的基材相同,其特征在于:第一外表面层1、中间层2和第二外表面层3均添加了有机硅粒子、二氧化钛粒子、三聚氰胺甲醛树脂和二氧化硅复合微球4,第一外表面层1和第二外表面层3中添加抗UV剂、抗静电剂中的一种或多种,三聚氰胺甲醛树脂和二氧化硅复合微球4的主要成分为有机硅。A multi-refractive index light diffusing plate, comprising: a first outer surface layer 1, an intermediate layer 2, a second outer surface layer 3, the first outer surface layer 1 is divided into an upper surface and a lower surface, the The intermediate layer 2 is divided into an upper surface and a lower surface, the second outer surface layer 3 is divided into an upper surface and a lower surface, the upper surface of the intermediate layer 2 is combined with the lower surface of the first outer surface layer 1, The lower surface of the intermediate layer 2 is combined with the upper surface of the second outer surface layer 3; the base materials of the first outer surface layer 1, the intermediate layer 2 and the second outer surface layer 3 are the same, and are characterized in that: The first outer surface layer 1, the middle layer 2 and the second outer surface layer 3 are all added with silicone particles, titanium dioxide particles, melamine formaldehyde resin and silica composite microspheres 4, the first outer surface layer 1 and the second outer surface layer 4. One or more of anti-UV agents and antistatic agents are added to layer 3, and the main components of melamine formaldehyde resin and silica composite microspheres 4 are organic silicon.
所述第一外表面层1、中间层2和第二外表面层3每层中的有机硅粒子、二氧化钛粒子、二氧化碳粒子和三聚氰胺甲醛树脂和二氧化硅复合微球4的重量份数配比相同,分别为:90%~95%光学级聚苯乙烯或者PMMA粒子,1%~2%有机硅粒子,1%~2%二氧化钛粒子,1%~2%二氧化碳粒子,1%~2%三聚氰胺甲醛树脂和二氧化硅复合微球4。The ratio of parts by weight of organosilicon particles, titanium dioxide particles, carbon dioxide particles and melamine formaldehyde resin and silica composite microspheres 4 in each layer of the first outer surface layer 1, the intermediate layer 2 and the second outer surface layer 3 The same, respectively: 90% ~ 95% optical grade polystyrene or PMMA particles, 1% ~ 2% silicone particles, 1% ~ 2% titanium dioxide particles, 1% ~ 2% carbon dioxide particles, 1% ~ 2% melamine Formaldehyde resin and silica composite microspheres 4.
所述光学级聚苯乙烯的折射率为1.51;有机硅粒子的折射率为1.42,PMMA粒子的折射率为1.45,二氧化钛粒子的折射率为1.42,三聚氰胺甲醛树脂和二氧化硅复合微球4的折射率为1.6。The refractive index of the optical grade polystyrene is 1.51; the refractive index of the silicone particles is 1.42, the refractive index of the PMMA particles is 1.45, the refractive index of the titanium dioxide particles is 1.42, and the melamine formaldehyde resin and the silica composite microspheres 4 The refractive index is 1.6.
所述三聚氰胺甲醛树脂和二氧化硅复合微球4的平均粒径为1~20um,孔径不宜过大也不宜过小,通过孔径范围的设置可以使得光可以均匀的与三聚氰胺甲醛树脂和二氧化硅复合微球4接触。The average particle size of the melamine formaldehyde resin and silica composite microspheres 4 is 1-20um, and the pore size should not be too large or too small. By setting the pore size range, the light can be uniformly mixed with the melamine formaldehyde resin and silica. The composite microspheres 4 are in contact.
所述第一外表面层1和第二外表面层3中包含具有抗UV、抗静电等功能材料中的一种或多种。通常情况下,在基材中加入抗UV剂,可以使得光扩散板具有抗UV的效果,使得产品抗黄化的效果增加;在基材中加入抗静电剂,可以使得光扩散板具有抗静电的作用,使得产品上不易沾染灰尘。The first outer surface layer 1 and the second outer surface layer 3 contain one or more functional materials such as anti-UV and anti-static. Under normal circumstances, adding an anti-UV agent to the substrate can make the light diffusing plate have anti-UV effect, which increases the anti-yellowing effect of the product; adding an antistatic agent to the substrate can make the light diffusing plate have anti-static properties The function of making the product is not easy to be contaminated with dust.
所述第一外表面层1和第二外表面层3中含有抗UV剂,所述的抗UV剂为含苯甲酸类、二苯甲酮类、苯并三唑类、或部分受阻胺类中的至少一种,且均匀分散在第一外表面层1和第二外表面层3中,其中抗UV剂占第一外表面层1和第二外表面层3总质量的3%~5%。The first outer surface layer 1 and the second outer surface layer 3 contain an anti-UV agent, and the anti-UV agent contains benzoic acids, benzophenones, benzotriazoles, or partially hindered amines At least one of them is uniformly dispersed in the first outer surface layer 1 and the second outer surface layer 3, wherein the anti-UV agent accounts for 3% to 5% of the total mass of the first outer surface layer 1 and the second outer surface layer 3. %.
所述第一外表面层1和第二外表面层3中含有抗静电剂,所述的抗静电剂为包含硫酸衍生物、磷酸衍生物、胺类、季铵盐、咪唑类以及环氧乙烷衍生物中的至少一种,且均匀分散在第一外表面层1和第二外表面层3中,其中抗静电剂占第一外表面层1和第二外表面层3总质量的2%~6%。The first outer surface layer 1 and the second outer surface layer 3 contain antistatic agents, and the antistatic agents include sulfuric acid derivatives, phosphoric acid derivatives, amines, quaternary ammonium salts, imidazoles and ethylene oxide. At least one of the alkane derivatives, and uniformly dispersed in the first outer surface layer 1 and the second outer surface layer 3, wherein the antistatic agent accounts for 2 of the total mass of the first outer surface layer 1 and the second outer surface layer 3 %~6%.
本发明还公开了所述的多折射率的光扩散板的合成方法,包括如下步骤:The invention also discloses a method for synthesizing the multi-refractive index light diffusing plate, comprising the following steps:
(1)准备基材步骤:选用光学级聚苯乙烯颗粒或者PMMA粒子作为基材;(1) Step of preparing the base material: select optical grade polystyrene particles or PMMA particles as the base material;
(1)准备基材步骤:选用光学级聚苯乙烯颗粒或者PMMA粒子作为基材;(1) Step of preparing the base material: select optical grade polystyrene particles or PMMA particles as the base material;
(2)制作三聚氰胺甲醛树脂和二氧化硅复合微球4的步骤:首先,将三聚氰胺和质量百分浓度为37%-40%甲醛溶液按质量比1:(2.4-6)混合,调节pH为8-10,60℃-65℃的温度下搅拌反应,溶解于适量蒸馏水中,制备得到三聚氰胺-甲醛的可溶性预聚物溶液;(2) The steps of making melamine formaldehyde resin and silica composite microspheres 4: First, mix melamine and formaldehyde solution with a mass percentage concentration of 37%-40% in a mass ratio of 1:(2.4-6), and adjust the pH to be 8-10, stirring and reacting at a temperature of 60°C-65°C, and dissolving in an appropriate amount of distilled water to prepare a melamine-formaldehyde soluble prepolymer solution;
其次,用质量分数1%的KH-570对合成的二氧化硅微球进行表面处理;Secondly, the synthesized silica microspheres were surface-treated with 1% KH-570;
最后,在三聚氰胺-甲醛的可溶性预聚物溶液中加入用KH-570处理过的二氧化硅微球,用硫酸化合物调节溶液为酸性,离心干燥得到三聚氰胺甲醛树脂和二氧化硅复合微球4;Finally, adding silica microspheres treated with KH-570 to the soluble prepolymer solution of melamine-formaldehyde, adjusting the solution to be acidic with a sulfuric acid compound, and centrifuging to obtain melamine formaldehyde resin and silica composite microspheres 4;
(3)制作光学母粒步骤:从准备的基材中选取:选取两个加料仓,分别 为第一加料仓和第二加料仓,在第一加料仓中添加质量百分比为95%光学级聚苯乙烯、1%有机硅粒子、1%PMMA粒子、1%二氧化钛粒子、1%二氧化碳粒子、1%三聚氰胺甲醛树脂和二氧化硅复合微球4和粉剂的混合物均匀搅拌混合后投入第一螺杆造粒机中,将其融化为浆状;(3) Step of making optical masterbatch: Select from the prepared base material: select two feeding bins, respectively the first feeding bin and the second feeding bin, and the mass percentage added in the first feeding bin is 95% optical grade polymer The mixture of styrene, 1% silicone particles, 1% PMMA particles, 1% titanium dioxide particles, 1% carbon dioxide particles, 1% melamine formaldehyde resin and silica composite microspheres 4 and powder is uniformly stirred and mixed and then put into the first screw machine. In a pellet mill, melt it into a slurry;
在第二加料仓中添加质量百分比为95%光学级聚苯乙烯、1%有机硅粒子、1%PMMA粒子、1%二氧化钛粒子、1%二氧化碳粒子、1%三聚氰胺甲醛树脂和二氧化硅复合微球4和粉剂的混合物均匀搅拌混合后投入第二螺杆造粒机中,将其融化为浆状;In the second feeding bin, add mass percentage of 95% optical grade polystyrene, 1% silicone particles, 1% PMMA particles, 1% titanium dioxide particles, 1% carbon dioxide particles, 1% melamine formaldehyde resin and silica composite microparticles. The mixture of ball 4 and powder is put into the second screw granulator after uniform stirring and mixing, and it is melted into slurry;
所述粉剂包括扩散剂、抗UV剂、氧化剂、光稳定剂和润滑分散剂中的一种或多种;The powder includes one or more of a diffusing agent, an anti-UV agent, an oxidizing agent, a light stabilizer and a lubricating dispersing agent;
(4)挤出成型步骤:(4) Extrusion molding steps:
将第一螺杆造粒机的机头挤出的浆状熔融物通过分配器后分别输送给三层叠加模头的第一外表面层1和第二外表面层3,将第二螺杆造粒机的机头挤出的浆状熔融物输送给三层叠加模头的中间层2,通过控制第一螺杆造粒机和第二螺杆造粒机的挤出速率和分配器的分配比例可以一次调节三层叠加模头第一外表面层1、中间层2、第二外表面层3厚度,通过调节三层叠加摸头的间隙可以二次调节三层叠加摸头第一外表面层1、中间层2、第二外表面层3厚度,三层叠加模头的第一外表面层1模头的吐出物形成扩散板的第一外表面层1,中间层2模头的吐出物形成扩散板的中间层2,第二外表面层3模头的吐出物形成扩散板的第二外表面,扩散板的第一外表面、中间层2和第二外表面通过三辊延压冷却成型形成扩散板成品。The slurry melt extruded from the head of the first screw granulator is sent to the first outer surface layer 1 and the second outer surface layer 3 of the three-layer superimposed die through the distributor, and the second screw is granulated. The slurry-like melt extruded from the head of the machine is sent to the middle layer 2 of the three-layer superimposed die, and the extrusion rate of the first screw granulator and the second screw granulator and the distribution ratio of the distributor can be controlled at one time. Adjust the thickness of the first outer surface layer 1, the middle layer 2, the second outer surface layer 3 of the three-layer stacking die, and adjust the first outer surface layer 1 and the middle layer of the three-layer stacking die by adjusting the gap of the three-layer stacking die. 2. The thickness of the second outer surface layer 3, the first outer surface layer of the three-layer superimposed die head 1 The spit of the die head forms the first outer surface layer 1 of the diffusion plate, and the spit of the middle layer 2 die head forms the spit of the diffusion plate. The middle layer 2, the second outer surface layer 3 The spit from the die head forms the second outer surface of the diffuser plate, and the first outer surface, the middle layer 2 and the second outer surface of the diffuser plate are formed by three-roll rolling and cooling to form the diffuser plate finished product.
(5)冷却裁切步骤:(5) Cooling and cutting steps:
经过三辊延压后的扩散板通过传送带向前输送,在输送过程中自然冷却或通过冷却液进行冷却至室温后,裁切至适当的成品尺寸。After the three-roller rolling, the diffuser plate is conveyed forward through the conveyor belt, and is naturally cooled during the conveying process or cooled to room temperature by the cooling liquid, and then cut to the appropriate finished product size.
所述制作光学母粒步骤中,所述双螺杆造粒机中的造粒温度在160℃至220℃之间,造粒压力在4.5Mpa至13.5Mpa之间。In the step of making the optical master batch, the granulation temperature in the twin-screw granulator is between 160°C and 220°C, and the granulation pressure is between 4.5Mpa and 13.5Mpa.
所述挤出成型步骤中,所述挤出成型机中的板材成型温度在170℃至230℃之间,板材成型压力在4.5Mpa至13.5Mpa之间。In the extrusion forming step, the plate forming temperature in the extrusion forming machine is between 170°C and 230°C, and the plate forming pressure is between 4.5Mpa and 13.5Mpa.
具体实施例2 Specific embodiment 2
一种多折射率的光扩散板,其包括:第一外表面层1、中间层2、第二外 表面层3,所述的第一外表面层1分为上表面和下表面,所述的中间层2分为上表面和下表面,所述的第二外表面层3分为上表面和下表面,所述的中间层2的上表面与第一外表面层1的下表面结合,所述的中间层2的下表面与第二外表面层3的上表面结合;所述的第一外表面层1、中间层2和第二外表面层3的基材相同,其特征在于:第一外表面层1、中间层2和第二外表面层3均添加了有机硅粒子、二氧化钛粒子、三聚氰胺甲醛树脂和二氧化硅复合微球4,第一外表面层1和第二外表面层3中添加抗UV剂、抗静电剂中的一种或多种,三聚氰胺甲醛树脂和二氧化硅复合微球4的主要成分为有机硅。A multi-refractive index light diffusing plate, comprising: a first outer surface layer 1, an intermediate layer 2, a second outer surface layer 3, the first outer surface layer 1 is divided into an upper surface and a lower surface, the The intermediate layer 2 is divided into an upper surface and a lower surface, the second outer surface layer 3 is divided into an upper surface and a lower surface, the upper surface of the intermediate layer 2 is combined with the lower surface of the first outer surface layer 1, The lower surface of the intermediate layer 2 is combined with the upper surface of the second outer surface layer 3; the base materials of the first outer surface layer 1, the intermediate layer 2 and the second outer surface layer 3 are the same, and are characterized in that: The first outer surface layer 1, the middle layer 2 and the second outer surface layer 3 are all added with silicone particles, titanium dioxide particles, melamine formaldehyde resin and silica composite microspheres 4, the first outer surface layer 1 and the second outer surface layer 4. One or more of anti-UV agents and antistatic agents are added to layer 3, and the main components of melamine formaldehyde resin and silica composite microspheres 4 are organic silicon.
所述第一外表面层1、中间层2和第二外表面层3每层中的光学级聚苯乙烯、有机硅粒子、PMMA粒子、二氧化钛粒子、二氧化碳粒子和三聚氰胺甲醛树脂和二氧化硅复合微球4的重量份数配比相同,分别为:90%光学级聚苯乙烯,2%有机硅粒子,1%~2%PMMA粒子,2%二氧化钛粒子,2%二氧化碳粒子,2%三聚氰胺甲醛树脂和二氧化硅复合微球4。Optical grade polystyrene, organosilicon particles, PMMA particles, titanium dioxide particles, carbon dioxide particles and melamine formaldehyde resin and silicon dioxide composite in each layer of the first outer surface layer 1, the intermediate layer 2 and the second outer surface layer 3 The proportions by weight of the microspheres 4 are the same, respectively: 90% optical grade polystyrene, 2% silicone particles, 1% to 2% PMMA particles, 2% titanium dioxide particles, 2% carbon dioxide particles, 2% melamine formaldehyde Resin and silica composite microspheres 4.
进一步的,光学级聚苯乙烯的折射率为1.52;有机硅粒子的折射率为1.45,PMMA粒子的折射率为1.49,二氧化钛粒子的折射率为1.45,三聚氰胺甲醛树脂和二氧化硅复合微球4的折射率为1.7。Further, the refractive index of optical grade polystyrene is 1.52; the refractive index of silicone particles is 1.45, the refractive index of PMMA particles is 1.49, the refractive index of titanium dioxide particles is 1.45, and the melamine formaldehyde resin and silica composite microspheres4 The index of refraction is 1.7.
所述三聚氰胺甲醛树脂和二氧化硅复合微球4的平均粒径为1~20um,孔径不宜过大也不宜过小,通过孔径范围的设置可以使得光可以均匀的与三聚氰胺甲醛树脂和二氧化硅复合微球4接触。The average particle size of the melamine formaldehyde resin and silica composite microspheres 4 is 1-20um, and the pore size should not be too large or too small. By setting the pore size range, the light can be uniformly mixed with the melamine formaldehyde resin and silica. The composite microspheres 4 are in contact.
所述第一外表面层1和第二外表面层3中包含具有抗UV、抗静电等功能材料中的一种或多种。通常情况下,在基材中加入抗UV剂,可以使得光扩散板具有抗UV的效果,使得产品抗黄化的效果增加;在基材中加入抗静电剂,可以使得光扩散板具有抗静电的作用,使得产品上不易沾染灰尘。The first outer surface layer 1 and the second outer surface layer 3 contain one or more functional materials such as anti-UV and anti-static. Under normal circumstances, adding an anti-UV agent to the substrate can make the light diffusing plate have anti-UV effect, which increases the anti-yellowing effect of the product; adding an antistatic agent to the substrate can make the light diffusing plate have anti-static properties The function of making the product is not easy to be contaminated with dust.
所述第一外表面层1和第二外表面层3中含有抗UV剂,所述的抗UV剂为含苯甲酸类、二苯甲酮类、苯并三唑类、或部分受阻胺类中的至少一种,且均匀分散在第一外表面层1和第二外表面层3中,其中抗UV剂占第一外表面层1和第二外表面层3总质量的3%~5%。The first outer surface layer 1 and the second outer surface layer 3 contain an anti-UV agent, and the anti-UV agent contains benzoic acids, benzophenones, benzotriazoles, or partially hindered amines At least one of them is uniformly dispersed in the first outer surface layer 1 and the second outer surface layer 3, wherein the anti-UV agent accounts for 3% to 5% of the total mass of the first outer surface layer 1 and the second outer surface layer 3. %.
所述第一外表面层1和第二外表面层3中含有抗静电剂,所述的抗静电剂为包含硫酸衍生物、磷酸衍生物、胺类、季铵盐、咪唑类以及环氧乙烷衍 生物中的至少一种,且均匀分散在第一外表面层1和第二外表面层3中,其中抗静电剂占第一外表面层1和第二外表面层3总质量的2%~6%。The first outer surface layer 1 and the second outer surface layer 3 contain antistatic agents, and the antistatic agents include sulfuric acid derivatives, phosphoric acid derivatives, amines, quaternary ammonium salts, imidazoles and ethylene oxide. At least one of the alkane derivatives, and uniformly dispersed in the first outer surface layer 1 and the second outer surface layer 3, wherein the antistatic agent accounts for 2 of the total mass of the first outer surface layer 1 and the second outer surface layer 3 %~6%.
本发明还公开了所述的多折射率的光扩散板的合成方法,包括如下步骤:The invention also discloses a method for synthesizing the multi-refractive index light diffusing plate, comprising the following steps:
(1)准备基材步骤:选用光学级聚苯乙烯颗粒或者PMMA粒子作为基材;(1) Step of preparing the base material: select optical grade polystyrene particles or PMMA particles as the base material;
(1)准备基材步骤:选用光学级聚苯乙烯颗粒或者PMMA粒子作为基材;(1) Step of preparing the base material: select optical grade polystyrene particles or PMMA particles as the base material;
(2)制作三聚氰胺甲醛树脂和二氧化硅复合微球4的步骤:首先,将三聚氰胺和质量百分浓度为37%-40%甲醛溶液按质量比1:(2.4-6)混合,调节pH为8-10,60℃-65℃的温度下搅拌反应,溶解于适量蒸馏水中,制备得到三聚氰胺-甲醛的可溶性预聚物溶液;(2) The steps of making melamine formaldehyde resin and silica composite microspheres 4: First, mix melamine and formaldehyde solution with a mass percentage concentration of 37%-40% in a mass ratio of 1:(2.4-6), and adjust the pH to be 8-10, stirring and reacting at a temperature of 60°C-65°C, and dissolving in an appropriate amount of distilled water to prepare a melamine-formaldehyde soluble prepolymer solution;
其次,用质量分数1%的KH-570对合成的二氧化硅微球进行表面处理;Secondly, the synthesized silica microspheres were surface-treated with 1% KH-570;
最后,在三聚氰胺-甲醛的可溶性预聚物溶液中加入用KH-570处理过的二氧化硅微球,用硫酸化合物调节溶液为酸性,离心干燥得到三聚氰胺甲醛树脂和二氧化硅复合微球4;Finally, adding silica microspheres treated with KH-570 to the soluble prepolymer solution of melamine-formaldehyde, adjusting the solution to be acidic with a sulfuric acid compound, and centrifuging to obtain melamine formaldehyde resin and silica composite microspheres 4;
(3)制作光学母粒步骤:从准备的基材中选取:选取两个加料仓,分别为第一加料仓和第二加料仓,在第一加料仓中添加质量百分比为95%光学级聚苯乙烯、1%有机硅粒子、1%PMMA粒子、1%二氧化钛粒子、1%二氧化碳粒子、1%三聚氰胺甲醛树脂和二氧化硅复合微球4和粉剂的混合物均匀搅拌混合后投入第一螺杆造粒机中,将其融化为浆状;(3) Step of making optical masterbatch: Select from the prepared base material: select two feeding bins, respectively the first feeding bin and the second feeding bin, and the mass percentage added in the first feeding bin is 95% optical grade polymer The mixture of styrene, 1% silicone particles, 1% PMMA particles, 1% titanium dioxide particles, 1% carbon dioxide particles, 1% melamine formaldehyde resin and silica composite microspheres 4 and powder is uniformly stirred and mixed and then put into the first screw machine. In a pellet mill, melt it into a slurry;
在第二加料仓中添加质量百分比为95%光学级聚苯乙烯、1%有机硅粒子、1%PMMA粒子、1%二氧化钛粒子、1%二氧化碳粒子、1%三聚氰胺甲醛树脂和二氧化硅复合微球4和粉剂的混合物均匀搅拌混合后投入第二螺杆造粒机中,将其融化为浆状;In the second feeding bin, add mass percentage of 95% optical grade polystyrene, 1% silicone particles, 1% PMMA particles, 1% titanium dioxide particles, 1% carbon dioxide particles, 1% melamine formaldehyde resin and silica composite microparticles. The mixture of ball 4 and powder is put into the second screw granulator after uniform stirring and mixing, and it is melted into slurry;
所述粉剂包括扩散剂、抗UV剂、氧化剂、光稳定剂和润滑分散剂中的一种或多种;The powder includes one or more of a diffusing agent, an anti-UV agent, an oxidizing agent, a light stabilizer and a lubricating dispersing agent;
(4)挤出成型步骤:(4) Extrusion molding steps:
将第一螺杆造粒机的机头挤出的浆状熔融物通过分配器后分别输送给三层叠加模头的第一外表面层1和第二外表面层3,将第二螺杆造粒机的机头挤出的浆状熔融物输送给三层叠加模头的中间层2,通过控制第一螺杆造粒机和第二螺杆造粒机的挤出速率和分配器的分配比例可以一次调节三层叠加模头第一外表面层1、中间层2、第二外表面层3厚度,通过调节三层叠加摸 头的间隙可以二次调节三层叠加摸头第一外表面层1、中间层2、第二外表面层3厚度,三层叠加模头的第一外表面层1模头的吐出物形成扩散板的第一外表面层1,中间层2模头的吐出物形成扩散板的中间层2,第二外表面层3模头的吐出物形成扩散板的第二外表面,扩散板的第一外表面、中间层2和第二外表面通过三辊延压冷却成型形成扩散板成品。The slurry melt extruded from the head of the first screw granulator is sent to the first outer surface layer 1 and the second outer surface layer 3 of the three-layer superimposed die through the distributor, and the second screw is granulated. The slurry-like melt extruded from the head of the machine is sent to the middle layer 2 of the three-layer superimposed die, and the extrusion rate of the first screw granulator and the second screw granulator and the distribution ratio of the distributor can be controlled at one time. Adjust the thickness of the first outer surface layer 1, the middle layer 2, the second outer surface layer 3 of the three-layer stacking die, and adjust the first outer surface layer 1 and the middle layer of the three-layer stacking die by adjusting the gap of the three-layer stacking die. 2. The thickness of the second outer surface layer 3, the first outer surface layer of the three-layer superimposed die head 1 The spit of the die head forms the first outer surface layer 1 of the diffusion plate, and the spit of the middle layer 2 die head forms the spit of the diffusion plate. The middle layer 2, the second outer surface layer 3 The spit from the die head forms the second outer surface of the diffuser plate, and the first outer surface, the middle layer 2 and the second outer surface of the diffuser plate are formed by three-roll rolling and cooling to form the diffuser plate finished product.
(5)冷却裁切步骤:(5) Cooling and cutting steps:
经过三辊延压后的扩散板通过传送带向前输送,在输送过程中自然冷却或通过冷却液进行冷却至室温后,裁切至适当的成品尺寸。After the three-roller rolling, the diffuser plate is conveyed forward through the conveyor belt, and is naturally cooled during the conveying process or cooled to room temperature by the cooling liquid, and then cut to the appropriate finished product size.
所述制作光学母粒步骤中,所述双螺杆造粒机中的造粒温度在160℃至220℃之间,造粒压力在4.5Mpa至13.5Mpa之间。In the step of making the optical master batch, the granulation temperature in the twin-screw granulator is between 160°C and 220°C, and the granulation pressure is between 4.5Mpa and 13.5Mpa.
所述挤出成型步骤中,所述挤出成型机中的板材成型温度在170℃至230℃之间,板材成型压力在4.5Mpa至13.5Mpa之间。In the extrusion forming step, the plate forming temperature in the extrusion forming machine is between 170°C and 230°C, and the plate forming pressure is between 4.5Mpa and 13.5Mpa.
与现有技术相比,本发明的高雾度、高透光率的光扩散板使用的材料简单,都是较为容易获得的原料,且用量相对较少,故原材料成本相对较低。另外,由于本发明中中间层2中有机硅的三聚氰胺甲醛树脂和二氧化硅复合微球4的折射率为1.7,光学级聚苯乙烯的的折射率为1.52,光学级聚苯乙烯的折射率为1.52;有机硅粒子的折射率为1.45,PMMA粒子的折射率为1.49,二氧化钛粒子的折射率为1.45,通过引入低折射率角度的光扩散剂,丰富了光的折射角度,增加了光通过不同的材料的折射角度的可能性,更多的改变光的方向,使得光源通过光扩散板时混光效果更好,透光率大大增加,可以满足大部分的市场需求,符合TFT-LCD产品的需求和发展。Compared with the prior art, the high haze, high transmittance light diffusing plate of the present invention uses simple materials, which are relatively easy to obtain raw materials, and the amount used is relatively small, so the raw material cost is relatively low. In addition, since the refractive index of the silicone melamine formaldehyde resin and the silica composite microsphere 4 in the intermediate layer 2 in the present invention is 1.7, the refractive index of the optical grade polystyrene is 1.52, and the refractive index of the optical grade polystyrene is 1.52. The refractive index of silicone particles is 1.45, the refractive index of PMMA particles is 1.49, and the refractive index of titanium dioxide particles is 1.45. By introducing a light diffusing agent with a low refractive index angle, the refraction angle of light is enriched and the light passing through is increased. The possibility of refraction angles of different materials, more changes in the direction of light, makes the light mixing effect better when the light source passes through the light diffuser, and the light transmittance is greatly increased, which can meet most market needs and conform to TFT-LCD products. needs and development.
以上所述实施例仅表达了本发明的几种实施方式,其描述较为具体和详细,但并不能因此而理解为对本发明专利范围的限制。应当指出的是,对于本领域的普通技术人员来说,在不脱离本发明构思的前提下,还可以做出若干变形和改进,这些都属于本发明的保护范围。因此,本发明专利的保护范围应以所附权利要求为准。The above-mentioned embodiments only represent several embodiments of the present invention, and the descriptions thereof are specific and detailed, but should not be construed as limiting the scope of the patent of the present invention. It should be pointed out that for those of ordinary skill in the art, without departing from the concept of the present invention, several modifications and improvements can also be made, which all belong to the protection scope of the present invention. Therefore, the protection scope of the patent of the present invention should be subject to the appended claims.

Claims (8)

  1. 一种多折射率的光扩散板,其包括:第一外表面层(1)、中间层(2)、第二外表面层(3),所述的第一外表面层(1)分为上表面和下表面,所述的中间层(2)分为上表面和下表面,所述的第二外表面层(3)分为上表面和下表面,所述的中间层(2)的上表面与第一外表面层(1)的下表面结合,所述的中间层(2)的下表面与第二外表面层(3)的上表面结合;所述的第一外表面层(1)、中间层(2)和第二外表面层(3)的基材相同,其特征在于:第一外表面层(1)、中间层(2)和第二外表面层(3)均添加了有机硅粒子、二氧化钛粒子、三聚氰胺甲醛树脂和二氧化硅复合微球(4),第一外表面层(1)和第二外表面层(3)中添加抗UV剂、抗静电剂中的一种或多种,三聚氰胺甲醛树脂和二氧化硅复合微球(4)的主要成分为三聚氰胺甲醛树脂。A multi-refractive index light diffusing plate, comprising: a first outer surface layer (1), an intermediate layer (2), and a second outer surface layer (3), wherein the first outer surface layer (1) is divided into Upper surface and lower surface, described intermediate layer (2) is divided into upper surface and lower surface, described second outer surface layer (3) is divided into upper surface and lower surface, described intermediate layer (2) The upper surface is combined with the lower surface of the first outer surface layer (1), the lower surface of the intermediate layer (2) is combined with the upper surface of the second outer surface layer (3); the first outer surface layer ( 1), the base material of the intermediate layer (2) and the second outer surface layer (3) is the same, and it is characterized in that: the first outer surface layer (1), the intermediate layer (2) and the second outer surface layer (3) are all Silicone particles, titanium dioxide particles, melamine formaldehyde resin and silica composite microspheres (4) are added, and anti-UV agents and antistatic agents are added to the first outer surface layer (1) and the second outer surface layer (3). One or more of the melamine formaldehyde resin and silica composite microspheres (4) are mainly composed of melamine formaldehyde resin.
  2. 如权利要求1所述的多折射率的光扩散板,其特征在于:第一外表面层(1)、中间层(2)和第二外表面层(3)每层中的有机硅粒子、二氧化钛粒子、二氧化碳粒子和三聚氰胺甲醛树脂和二氧化硅复合微球(4)的重量份数配比相同,分别为:90%~95%光学级聚苯乙烯或者PMMA粒子,1%~2%有机硅粒子,1%~2%二氧化钛粒子,1%~2%二氧化碳粒子,1%~2%三聚氰胺甲醛树脂和二氧化硅复合微球(4)。The multi-refractive index light diffusing plate according to claim 1, characterized in that: the organic silicon particles in each layer of the first outer surface layer (1), the intermediate layer (2) and the second outer surface layer (3), Titanium dioxide particles, carbon dioxide particles, melamine formaldehyde resin and silica composite microspheres (4) have the same proportions by weight, which are: 90% to 95% of optical grade polystyrene or PMMA particles, 1% to 2% of organic Silicon particles, 1% to 2% of titanium dioxide particles, 1% to 2% of carbon dioxide particles, 1% to 2% of melamine formaldehyde resin and silica composite microspheres (4).
  3. 如权利要求1所述的多折射率的光扩散板,其特征在于:光学级聚苯乙烯的折射率为1.51~1.52;有机硅粒子的折射率为1.42-1.45,PMMA粒子的折射率为1.45-1.49,二氧化钛粒子的折射率为1.42-1.45,三聚氰胺甲醛树脂和二氧化硅复合微球(4)的折射率为1.6-1.7。The multi-refractive index light diffusing plate according to claim 1, wherein the refractive index of optical grade polystyrene is 1.51-1.52; the refractive index of organic silicon particles is 1.42-1.45, and the refractive index of PMMA particles is 1.45 -1.49, the refractive index of the titanium dioxide particles is 1.42-1.45, and the refractive index of the melamine formaldehyde resin and silica composite microspheres (4) is 1.6-1.7.
  4. 如权利要求1所述的多折射率的光扩散板,其特征在于:三聚氰胺甲醛树脂和二氧化硅复合微球(4)的平均粒径为1~20um。The multi-refractive index light diffusing plate according to claim 1, wherein the average particle size of the melamine formaldehyde resin and silica composite microspheres (4) is 1-20um.
  5. 如权利要求1所述的多折射率的光扩散板,其特征在于:第一外表面层(1)和第二外表面层(3)中包含具有抗UV、抗静电等功能材料中的一种或多种。The multi-refractive index light diffusing plate according to claim 1, characterized in that: the first outer surface layer (1) and the second outer surface layer (3) contain one of the functional materials such as anti-UV and anti-static. one or more.
  6. 如权利要求1所述的多折射率的光扩散板,其特征在于:第一外表面层(1)和第二外表面层(3)中含有抗UV剂,所述的抗UV剂为含苯甲酸类、二苯甲酮类、苯并三唑类、或部分受阻胺类中的至少一种,且均匀 分散在第一外表面层(1)和第二外表面层(3)中,其中抗UV剂占第一外表面层(1)和第二外表面层(3)总质量的3%~5%。The multi-refractive index light diffusing plate according to claim 1, wherein the first outer surface layer (1) and the second outer surface layer (3) contain an anti-UV agent, and the anti-UV agent is a At least one of benzoic acids, benzophenones, benzotriazoles, or partially hindered amines, and uniformly dispersed in the first outer surface layer (1) and the second outer surface layer (3), The anti-UV agent accounts for 3% to 5% of the total mass of the first outer surface layer (1) and the second outer surface layer (3).
  7. 如权利要求1所述的多折射率的光扩散板,其特征在于:第一外表面层(1)和第二外表面层(3)中含有抗静电剂,所述的抗静电剂为包含硫酸衍生物、磷酸衍生物、胺类、季铵盐、咪唑类以及环氧乙烷衍生物中的至少一种,且均匀分散在第一外表面层(1)和第二外表面层(3)中,其中抗静电剂占第一外表面层(1)和第二外表面层(3)总质量的2%~6%。The multi-refractive index light diffusing plate according to claim 1, characterized in that: the first outer surface layer (1) and the second outer surface layer (3) contain an antistatic agent, and the antistatic agent is composed of At least one of sulfuric acid derivatives, phosphoric acid derivatives, amines, quaternary ammonium salts, imidazoles and ethylene oxide derivatives, and uniformly dispersed in the first outer surface layer (1) and the second outer surface layer (3 ), wherein the antistatic agent accounts for 2% to 6% of the total mass of the first outer surface layer (1) and the second outer surface layer (3).
  8. 如权利要求1所述的多折射率的光扩散板的合成方法,包括如下步骤:The method for synthesizing a multi-refractive index light diffusing plate as claimed in claim 1, comprising the steps of:
    (1)准备基材步骤:选用光学级聚苯乙烯颗粒或者PMMA粒子作为基材;(1) Step of preparing the base material: select optical grade polystyrene particles or PMMA particles as the base material;
    (2)制作三聚氰胺甲醛树脂和二氧化硅复合微球(4)的步骤:首先,将三聚氰胺和质量百分浓度为37%-40%甲醛溶液按质量比1:(2.4-6)混合,调节pH为8-10,60℃-65℃的温度下搅拌反应,溶解于适量蒸馏水中,制备得到三聚氰胺-甲醛的可溶性预聚物溶液;(2) The steps of making melamine formaldehyde resin and silica composite microspheres (4): First, mix melamine and formaldehyde solution with a mass percentage concentration of 37%-40% in a mass ratio of 1:(2.4-6), adjust The pH is 8-10, and the reaction is stirred at a temperature of 60°C-65°C, and dissolved in an appropriate amount of distilled water to prepare a melamine-formaldehyde soluble prepolymer solution;
    其次,用质量分数1%的KH-570对合成的二氧化硅微球进行表面处理;Secondly, the synthesized silica microspheres were surface-treated with 1% KH-570;
    最后,在三聚氰胺-甲醛的可溶性预聚物溶液中加入用KH-570处理过的二氧化硅微球,用硫酸化合物调节溶液为酸性,离心干燥得到三聚氰胺甲醛树脂和二氧化硅复合微球(4);Finally, add silica microspheres treated with KH-570 in the soluble prepolymer solution of melamine-formaldehyde, adjust the solution to be acidic with a sulfuric acid compound, and centrifugally dry to obtain melamine formaldehyde resin and silica composite microspheres (4 );
    (3)制作光学母粒步骤:从准备的基材中选取:选取两个加料仓,分别为第一加料仓和第二加料仓,在第一加料仓中添加质量百分比为95%光学级聚苯乙烯、1%有机硅粒子、1%PMMA粒子、1%二氧化钛粒子、1%二氧化碳粒子、1%三聚氰胺甲醛树脂和二氧化硅复合微球(4)和粉剂的混合物均匀搅拌混合后投入第一螺杆造粒机中,将其融化为浆状;(3) Step of making optical masterbatch: Select from the prepared base material: select two feeding bins, respectively the first feeding bin and the second feeding bin, and the mass percentage added in the first feeding bin is 95% optical grade polymer The mixture of styrene, 1% silicone particles, 1% PMMA particles, 1% titanium dioxide particles, 1% carbon dioxide particles, 1% melamine formaldehyde resin and silica composite microspheres (4) and powder is uniformly stirred and mixed and then put into the first In the screw granulator, melt it into a slurry;
    在第二加料仓中添加质量百分比为95%光学级聚苯乙烯、1%有机硅粒子、1%PMMA粒子、1%二氧化钛粒子、1%二氧化碳粒子、1%三聚氰胺甲醛树脂和二氧化硅复合微球(4)和粉剂的混合物均匀搅拌混合后投入第二螺杆造粒机中,将其融化为浆状;所述粉剂包括扩散剂、抗UV剂、氧化剂、光稳定剂和润滑分散剂中的一种或多种;In the second feeding bin, add mass percentage of 95% optical grade polystyrene, 1% silicone particles, 1% PMMA particles, 1% titanium dioxide particles, 1% carbon dioxide particles, 1% melamine formaldehyde resin and silica composite microparticles. The mixture of the ball (4) and the powder is uniformly stirred and mixed into the second screw granulator, and it is melted into a slurry; the powder includes a diffusing agent, an anti-UV agent, an oxidizing agent, a light stabilizer and a lubricating and dispersing agent. one or more;
    (4)挤出成型步骤:(4) Extrusion molding steps:
    将第一螺杆造粒机的机头挤出的浆状熔融物通过分配器后分别输送给三层叠加模头的第一外表面层(1)和第二外表面层(3),将第二螺杆造粒机的机头挤出的浆状熔融物输送给三层叠加模头的中间层(2),通过控制第一螺杆造粒机和第二螺杆造粒机的挤出速率和分配器的分配比例可以一次调节三层叠加模头第一外表面层(1)、中间层(2)、第二外表面层(3)厚度,通过调节三层叠加摸头的间隙可以二次调节三层叠加摸头第一外表面层(1)、中间层(2)、第二外表面层(3)厚度,三层叠加模头的第一外表面层(1)模头的吐出物形成扩散板的第一外表面层(1),中间层(2)模头的吐出物形成扩散板的中间层(2),第二外表面层(3)模头的吐出物形成扩散板的第二外表面,扩散板的第一外表面、中间层(2)和第二外表面通过三辊延压冷却成型形成扩散板成品。The slurry-like melt extruded from the head of the first screw granulator is conveyed to the first outer surface layer (1) and the second outer surface layer (3) of the three-layer superimposed die through the distributor, respectively. The slurry-like melt extruded from the head of the two-screw granulator is delivered to the middle layer (2) of the three-layer superimposed die, by controlling the extrusion rate and distribution of the first and second screw granulators. The distribution ratio of the three-layer superimposed die can be adjusted once to adjust the thickness of the first outer surface layer (1), the middle layer (2), and the second outer surface layer (3) of the three-layer superimposed die. The thickness of the first outer surface layer (1), the intermediate layer (2), and the second outer surface layer (3) of the superimposed die is layered, and the first outer surface layer (1) of the three-layer superimposed die is spit out of the die to form a diffuser plate The first outer surface layer (1) of the first outer surface layer (1), the middle layer (2) The spit of the die forms the middle layer (2) of the diffuser plate, and the second outer surface layer (3) The spit of the die head forms the second outer layer of the diffuser plate. Surface, the first outer surface, the intermediate layer (2) and the second outer surface of the diffuser plate are formed by three-roll rolling cooling to form a finished diffuser plate.
    (5)冷却裁切步骤:(5) Cooling and cutting steps:
    经过三辊延压后的扩散板通过传送带向前输送,在输送过程中自然冷却或通过冷却液进行冷却至室温后,裁切至适当的成品尺寸。After the three-roller rolling, the diffuser plate is conveyed forward through the conveyor belt, and is naturally cooled during the conveying process or cooled to room temperature by the cooling liquid, and then cut to the appropriate finished product size.
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