WO2022190112A1 - Manufacturing of nanoscale composite for plant nutrition - Google Patents
Manufacturing of nanoscale composite for plant nutrition Download PDFInfo
- Publication number
- WO2022190112A1 WO2022190112A1 PCT/IN2021/050480 IN2021050480W WO2022190112A1 WO 2022190112 A1 WO2022190112 A1 WO 2022190112A1 IN 2021050480 W IN2021050480 W IN 2021050480W WO 2022190112 A1 WO2022190112 A1 WO 2022190112A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- range
- nitrogen
- nanoscale
- composite
- phosphate
- Prior art date
Links
- 239000002131 composite material Substances 0.000 title claims description 17
- 238000004519 manufacturing process Methods 0.000 title description 2
- 230000001863 plant nutrition Effects 0.000 title 1
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims abstract description 40
- 229910052757 nitrogen Inorganic materials 0.000 claims abstract description 28
- 229910019142 PO4 Inorganic materials 0.000 claims abstract description 14
- 239000000203 mixture Substances 0.000 claims abstract description 14
- 239000010452 phosphate Substances 0.000 claims abstract description 13
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims abstract description 13
- 239000011785 micronutrient Substances 0.000 claims abstract description 10
- 235000013369 micronutrients Nutrition 0.000 claims abstract description 10
- 235000021073 macronutrients Nutrition 0.000 claims abstract description 9
- 239000004615 ingredient Substances 0.000 claims abstract description 8
- 235000015097 nutrients Nutrition 0.000 claims abstract description 8
- 229910052698 phosphorus Inorganic materials 0.000 claims description 13
- 239000002245 particle Substances 0.000 claims description 10
- 239000007787 solid Substances 0.000 claims description 10
- 238000009472 formulation Methods 0.000 claims description 7
- 239000008187 granular material Substances 0.000 claims description 7
- 239000008188 pellet Substances 0.000 claims description 7
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 6
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 5
- 239000011248 coating agent Substances 0.000 claims description 5
- 238000000576 coating method Methods 0.000 claims description 5
- 239000007788 liquid Substances 0.000 claims description 5
- 239000000463 material Substances 0.000 claims description 5
- 239000002114 nanocomposite Substances 0.000 claims description 5
- 239000011574 phosphorus Substances 0.000 claims description 5
- 239000003826 tablet Substances 0.000 claims description 5
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 4
- 239000011591 potassium Substances 0.000 claims description 4
- 229910052700 potassium Inorganic materials 0.000 claims description 4
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims description 3
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 3
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 3
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 3
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 3
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 3
- 229910052796 boron Inorganic materials 0.000 claims description 3
- 229910052791 calcium Inorganic materials 0.000 claims description 3
- 239000011575 calcium Substances 0.000 claims description 3
- 239000000460 chlorine Substances 0.000 claims description 3
- 229910052801 chlorine Inorganic materials 0.000 claims description 3
- 229910017052 cobalt Inorganic materials 0.000 claims description 3
- 239000010941 cobalt Substances 0.000 claims description 3
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 3
- 229910052802 copper Inorganic materials 0.000 claims description 3
- 239000010949 copper Substances 0.000 claims description 3
- 229910052742 iron Inorganic materials 0.000 claims description 3
- 239000011777 magnesium Substances 0.000 claims description 3
- 229910052749 magnesium Inorganic materials 0.000 claims description 3
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims description 3
- 229910052750 molybdenum Inorganic materials 0.000 claims description 3
- 239000011733 molybdenum Substances 0.000 claims description 3
- 229910052717 sulfur Inorganic materials 0.000 claims description 3
- 239000011593 sulfur Substances 0.000 claims description 3
- 239000011701 zinc Substances 0.000 claims description 3
- 229910052725 zinc Inorganic materials 0.000 claims description 3
- 239000003337 fertilizer Substances 0.000 claims description 2
- -1 comprising Chemical compound 0.000 claims 1
- 239000003516 soil conditioner Substances 0.000 claims 1
- 235000021317 phosphate Nutrition 0.000 description 11
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 8
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 8
- 238000002156 mixing Methods 0.000 description 8
- 239000010408 film Substances 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- 239000002002 slurry Substances 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- 238000000034 method Methods 0.000 description 3
- 239000002105 nanoparticle Substances 0.000 description 3
- 239000002689 soil Substances 0.000 description 3
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 2
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 2
- 229910021529 ammonia Inorganic materials 0.000 description 2
- 239000004202 carbamide Substances 0.000 description 2
- 238000005119 centrifugation Methods 0.000 description 2
- 235000019838 diammonium phosphate Nutrition 0.000 description 2
- 239000002270 dispersing agent Substances 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 239000012467 final product Substances 0.000 description 2
- 238000000227 grinding Methods 0.000 description 2
- 239000012669 liquid formulation Substances 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 235000016709 nutrition Nutrition 0.000 description 2
- 230000035764 nutrition Effects 0.000 description 2
- 239000002367 phosphate rock Substances 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 239000005696 Diammonium phosphate Substances 0.000 description 1
- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 description 1
- 229910000388 diammonium phosphate Inorganic materials 0.000 description 1
- 230000004720 fertilization Effects 0.000 description 1
- 239000013020 final formulation Substances 0.000 description 1
- 230000005714 functional activity Effects 0.000 description 1
- 238000002386 leaching Methods 0.000 description 1
- 239000000618 nitrogen fertilizer Substances 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 239000011435 rock Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05B—PHOSPHATIC FERTILISERS
- C05B7/00—Fertilisers based essentially on alkali or ammonium orthophosphates
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05B—PHOSPHATIC FERTILISERS
- C05B11/00—Fertilisers produced by wet-treating or leaching raw materials either with acids in such amounts and concentrations as to yield solutions followed by neutralisation, or with alkaline lyes
- C05B11/04—Fertilisers produced by wet-treating or leaching raw materials either with acids in such amounts and concentrations as to yield solutions followed by neutralisation, or with alkaline lyes using mineral acid
- C05B11/08—Fertilisers produced by wet-treating or leaching raw materials either with acids in such amounts and concentrations as to yield solutions followed by neutralisation, or with alkaline lyes using mineral acid using sulfuric acid
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05D—INORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C; FERTILISERS PRODUCING CARBON DIOXIDE
- C05D9/00—Other inorganic fertilisers
- C05D9/02—Other inorganic fertilisers containing trace elements
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G5/00—Fertilisers characterised by their form
- C05G5/10—Solid or semi-solid fertilisers, e.g. powders
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G5/00—Fertilisers characterised by their form
- C05G5/10—Solid or semi-solid fertilisers, e.g. powders
- C05G5/16—Films or sheets; Webs; Fibres
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Fertilizers (AREA)
Abstract
The present invention related to nutrient composition comprising an effective nitrogen and/ phosphate as principal ingredients in nanoscale dimension with or without other macro and micro nutrient required by plants for their growth and development.
Description
TITLE OF THE INVENTION: -
MANUFACTURING OF NANOSCALE COMPOSITE FOR PLANT
NUTRITION
Field of the invention
The present invention related to nutrient composition comprising an effective nitrogen and/ phosphate as principal ingredients in nanoscale dimension with or without other macro and micro nutrient required by plants for their growth and development.
Description of the related art
All the agricultural crops require balance nutrition consisted of elements such as nitrogen, phosphorus, potassium, calcium, magnesium, sulfur, iron, manganese, boron, molybdenum, copper, zinc, chlorine, cobalt, but not limited too. Among others, Nitrogen and Phosphorous are the major nutrient. Typically, a combination of two nutrients mainly nitrogen and phosphate as Diammonium phosphate (or DAP) or combination of three nutrients, nitrogen, phosphate and potassium (NPK) is applied to soil.
Currently used phosphorous and nitrogen fertilizer in combination or alone having low use efficiency thus leaching/releasing to the environment. So, they require to apply in very high dosages, can be extended to 50 Kg/Hectare. Further, the process of nutrients such as phosphate depends on the limited geological natural reserves of rock phosphates.
Therefore, it is essential to develop the method of effective composite of nitrogen and phosphate as principal ingredients, having high use efficiency and require substantially less than conventional counterpart. Nanotechnology offers opportunity where particles with nanoscale dimension (1-100 nm at least at one dimension) having high surface area to volume size ratio compare to their bulk counterpart. Nanoparticle composite of nitrogen and phosphate with or without other macro and micro nutrient required by plants for their growth and development address the concern of use efficiency and dosage per acre.
Summary of Invention
The present invention relates to novel nanoscale composition of at least two principal ingredients, nitrogen and phosphorus with or without other macro and micro nutrient required by plants for their growth and development address the concern of use efficiency and dosage per acre. According to an embodiment, the nitrogen is in the range of about 1% to about 47% (w/w or w/v or v/v), phosphate is in the range of about 5% to about 70% (w/w or w/v or v/v).
According to an embodiment, the composite nanoscale particles can be dispersed in water, in soil or other similar inorganic/organic media to develop liquid and/or solid formulation, pellet, powder, granule, film, and/or coating on seed surface with or without any dispersing agents.
According to an embodiment, the invention also relates to a method of treating the seed and the plants by applying the composite on seed surface as
coating, basal application for root exposure and foliar application for leaf exposure.
Detailed Description of the invention
The detailed embodiments of the present invention are disclosed herein, however, it is to be understood that the disclosed embodiments are merely exemplary of the invention, which can be embodied in various form. Therefore, specific structural and functional details disclosed herein are not to be interpreted as limiting, but merely as a basis for the claims and as a representative basis for teaching one skilled in art to variously employ the present invention in virtually any appropriately detailed structure. Further, the terms and phrases used herein are not intended to be limiting but rather to provide an understandable disclosure of the invention.
The present invention relates to novel nanoscale composition of at least two principal ingredients, nitrogen and phosphorus with or without other macro and micro nutrient required by plants for their growth and development address the concern of use efficiency and dosage per acre. According to an embodiment, the nitrogen is in the range of about 1% to about 47% (w/w or w/v or v/v), phosphate is in the range of about 5% to about 70% (w/w or w/v or v/v). According to an embodiment the total nitrogen and total phosphorous concentration will not exceed 47% and 70% (both w/w or w/v or v/v), respectively.
According to an embodiment, the final formulation composed of at least two principal ingredients, nitrogen and phosphorus with or without other macro
B
and micro nutrient required by plants for their growth and development. Further, the macro and micro nutrient can be potassium, calcium, magnesium, sulfur, iron, manganese, boron, molybdenum, copper, zinc, chlorine, cobalt, but not limited too. According to an embodiment the total concentration of one or all macro and micro nutrient will not exceed 20% (both w/w or w/v or v/v), respectively. However, those skilled in the art will appreciate that it is possible to utilize other elements and composition and sizes known in the art without departing from the scope of the claims of the present invention. Example 1
A slurry is obtained by mixing sulfuric acid and rock phosphate and/or phosphoric acid as phosphorous (P) source with ammonia and/or urea solution as nitrogen (N) source. The ratio was suitably adjusted for obtaining the nitrogen in the range of about 1% to about 47% (w/w or w/v or v/v), and phosphate is in the range of about 5% to about 70% (w/w or w/v or v/v). The mixing of two sources P and N were carried out at temperature ranging between 20 deg C to 150 deg C. The mixing of two sources P and N were carried out at solution RPM (rotation per minute) ranging between 15 rpm to 300 rpm. The mixing of two sources P and N were carried out in equal or sequential manner. After mixing the solution was allowed to stirrer continuously, wherein solution become semi-solid gel state. The semi-solid gel state slurry can be washed by filtration and/or by centrifugation with solvents such as water, ethanol, acetone etc, but not limited too. Further, the washed materials can be mixed in suitable solvents such as water, ethanol,
acetone etc, but not limited too, or the washed material can be dried in hot air at temperature from 30 deg C to 150 deg C to obtain the final product can be converted into liquid formulation and/or solid formulation, or pellet, film, tablet or granule. The final washed product (hereafter called composite or nano composite) consisted of at least two elements N and P, but not limited too. The final composite having particle size range of about 5 nanometers (nm) to 200 microns in its liquid and/or solid formulation atleast at one dimension. Further, the dried particles in form of pellet, tablet or granule are in the range of about 0.01 micron to 4 mm. Moreover, the dried particles in form of film on both the biological and/or non-biological surfaces, may having thickness which is in the range of about 5 nm to 5 microns.
Example 2
A slurry is obtained by mixing rock phosphate and/or phosphoric acid as phosphorous (P) source with ammonia and/or urea or composite powder/solid source of N and P. The ratio was suitably adjusted for obtaining the nitrogen in the range of about 1% to about 47% (w/w or w/v or v/v), and phosphate is in the range of about 5% to about 70% (w/w or w/v or v/v). The mixing of the P and N sources were carried out at temperature ranging between 20 deg C to 150 deg C. The mixing of the sources was carried out by wet or powder grinding in a suitable respective equipment. After grinding, the slurry can be washed by filtration and/or by centrifugation with solvents such as water, ethanol, acetone etc, but not limited too. Further, the washed materials can be mixed in suitable solvents such as water, ethanol, acetone etc, but not limited
too, or the washed material can be dried in hot air at temperature from 30 deg C to 150 deg C to obtain the final product can be converted into liquid formulation and/or solid formulation, or pellet, film, tablet or granule. The final washed product (hereafter called composite or nano composite) consisted of at least two elements N and P, but not limited too. The final composite having particle size range of about 5 nanometers (nm) to 200 microns in its liquid and/or solid formulation at least at one dimension. Further, the dried particles in form of pellet, tablet or granule are in the range of about 0.01 micron to 4 mm. Moreover, the dried particles in form of film on both the biological and/or non-biological surfaces, may having thickness which is in the range of about 5 nm to 5 microns.
The scope of the combination is not limited just by the above range, but also to other combinations, which can still maintain the same functional activity of the N and the P nutrient source as principal ingredient.
The obtained nanocomposite was used as a fertilizer on various crops, require N and P fertilization. The composite nanoscale particles can be dispersed in water, in soil or other similar inorganic/organic media to develop liquid and/or solid formulation, pellet, powder, granule, film, and/or coating on seed surface with or without any dispersing agents. Further, the nanocomposite can be applied on seed surface as coating, basal application for root exposure and foliar application for leaf exposure.
The specification, specific embodiments of the present invention have been described. Flowever, one of ordinary skill in the art appreciate that
various modification and changes can be made without departing from the scope of the present invention as set forth in the claims below. Accordingly, the specification and the examples are to be regarded in an illustrative rather than a restrictive sense, and all such modification are intended to be included within the scope of present invention.
Claims
1. The nanoscale composition of at least two principal ingredients, nitrogen and phosphorus with or without other macro and micro nutrient required by plants for better use efficiency and reducing dosage per acre for nitrogen and phosphate, comprising, nitrogen in the range of about 1% to 47% (w/w or w/v or v/v) and phosphate in the range of 5% to 70% (w/w or w/v or v/v).
2. The nanoscale composite as claimed in the claim 1 wherein the particle size range of 5 nanometers (nm) to 200 microns in its liquid and/or solid formulation at least at one dimension.
3. The nanoscale composite as claimed in the claim 1 and 2, the particles can be in the form of pellet, tablet or granule, and are in the range of 0.01 micron to 4 mm.
4. The nanoscale composite as claimed in the claim 1 and 2, the particles in form of film on both the biological and/or non-biological surfaces, having thickness which is in the range of 5 nm to 5 microns.
5. The nanoscale composite as claimed in the claim 1 , wherein the macro and micro nutrient can be potassium, calcium, magnesium, sulfur, iron, manganese, boron, molybdenum, copper, zinc, chlorine and cobalt, and all or none not exceed 20% (w/w or w/v or v/v).
6. The nanoscale composite as claimed in the claim 1 , wherein the nanocomposite can be used as a fertilizer, a nutrient composition, a soil conditioner and a seed coating material.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IN202121010603 | 2021-03-12 | ||
| IN202121010603 | 2021-03-12 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| WO2022190112A1 true WO2022190112A1 (en) | 2022-09-15 |
Family
ID=83226585
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/IN2021/050480 WO2022190112A1 (en) | 2021-03-12 | 2021-05-19 | Manufacturing of nanoscale composite for plant nutrition |
Country Status (1)
| Country | Link |
|---|---|
| WO (1) | WO2022190112A1 (en) |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20190202750A1 (en) * | 2016-07-01 | 2019-07-04 | Washington University | Synthesis of nanocomposites and their use in enhancing plant nutrition |
-
2021
- 2021-05-19 WO PCT/IN2021/050480 patent/WO2022190112A1/en active Application Filing
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20190202750A1 (en) * | 2016-07-01 | 2019-07-04 | Washington University | Synthesis of nanocomposites and their use in enhancing plant nutrition |
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