WO2022120408A1 - A gas separation apparatus - Google Patents
A gas separation apparatus Download PDFInfo
- Publication number
- WO2022120408A1 WO2022120408A1 PCT/AU2021/051267 AU2021051267W WO2022120408A1 WO 2022120408 A1 WO2022120408 A1 WO 2022120408A1 AU 2021051267 W AU2021051267 W AU 2021051267W WO 2022120408 A1 WO2022120408 A1 WO 2022120408A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- gas
- chambers
- separation apparatus
- gas separation
- gate
- Prior art date
Links
- 238000000926 separation method Methods 0.000 title claims abstract description 58
- 239000003463 adsorbent Substances 0.000 claims abstract description 24
- 230000000694 effects Effects 0.000 claims abstract description 5
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 82
- 229910002092 carbon dioxide Inorganic materials 0.000 claims description 41
- 239000001569 carbon dioxide Substances 0.000 claims description 41
- 238000007789 sealing Methods 0.000 claims description 36
- 238000003795 desorption Methods 0.000 claims description 26
- 238000010926 purge Methods 0.000 claims description 20
- 238000001179 sorption measurement Methods 0.000 claims description 16
- 238000000034 method Methods 0.000 claims description 15
- 230000001360 synchronised effect Effects 0.000 claims description 6
- 238000010438 heat treatment Methods 0.000 claims description 4
- 230000001737 promoting effect Effects 0.000 claims description 2
- 239000007789 gas Substances 0.000 description 80
- 206010037544 Purging Diseases 0.000 description 16
- 239000012621 metal-organic framework Substances 0.000 description 6
- 238000001816 cooling Methods 0.000 description 4
- 238000010276 construction Methods 0.000 description 3
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000005431 greenhouse gas Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 238000002336 sorption--desorption measurement Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
- B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
- B01D53/0407—Constructional details of adsorbing systems
- B01D53/0446—Means for feeding or distributing gases
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
- B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
- B01D53/0407—Constructional details of adsorbing systems
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
- B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
- B01D53/0454—Controlling adsorption
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J4/00—Feed or outlet devices; Feed or outlet control devices
- B01J4/008—Feed or outlet control devices
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
- B01J8/0207—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid flow within the bed being predominantly horizontal
- B01J8/0221—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid flow within the bed being predominantly horizontal in a cylindrical shaped bed
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
- B01D2253/20—Organic adsorbents
- B01D2253/204—Metal organic frameworks (MOF's)
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/50—Carbon oxides
- B01D2257/504—Carbon dioxide
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2258/00—Sources of waste gases
- B01D2258/06—Polluted air
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2259/00—Type of treatment
- B01D2259/40—Further details for adsorption processes and devices
- B01D2259/40003—Methods relating to valve switching
- B01D2259/40005—Methods relating to valve switching using rotary valves
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2259/00—Type of treatment
- B01D2259/40—Further details for adsorption processes and devices
- B01D2259/40083—Regeneration of adsorbents in processes other than pressure or temperature swing adsorption
- B01D2259/40088—Regeneration of adsorbents in processes other than pressure or temperature swing adsorption by heating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2259/00—Type of treatment
- B01D2259/40—Further details for adsorption processes and devices
- B01D2259/402—Further details for adsorption processes and devices using two beds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
- B01J20/223—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material containing metals, e.g. organo-metallic compounds, coordination complexes
- B01J20/226—Coordination polymers, e.g. metal-organic frameworks [MOF], zeolitic imidazolate frameworks [ZIF]
Definitions
- the present invention relates broadly to a gas separation apparatus such as that suitable for extracting carbon dioxide from atmosphere.
- the invention is also broadly related to a method of gas separation and more particularly is directed to a method of directly capturing carbon dioxide from air.
- a gas separation apparatus comprising: a plurality of gas chambers each containing an adsorbent structure adapted to directly adsorb carbon dioxide from gas exposed to the chamber; a gate assembly arranged to cooperate with the plurality of gas chambers, the gate assembly being movable from a first position to permit gas flow through at least one of the chambers for carbon dioxide adsorption whilst sealing closed the remaining of the chambers, to a second position to permit gas flow through at least said remaining of the chambers whilst sealing closed one of said at least one of the chambers; an actuator operatively coupled to the gate assembly to effect movement of the gate assembly from the first to the second positions.
- each of the gas chambers is defined by a tubular housing being open at each of its ends. More preferably the tubular housing is in the form of a canister arranged to cooperate with the gate assembly at each of said open ends of the tubular housing for opening and sealing closure of the respective gas chambers.
- the gate assembly includes a gate member dedicated to a common end of the canisters which are parallel and aligned with one another for simultaneously opening and sealing closure of select of the gas chambers in either the first or the second positions.
- the parallel canisters are equally spaced angularly relative to one another.
- the gate member includes a predetermined number of openings angularly separated to align with respective of said at least one of the chambers whilst the gate member blocks the remaining of the chambers in the first position.
- the gate member is arranged to rotate about the common end of the canisters for movement between the first and second positions, the canisters being angularly spaced relative to a rotational axis about which the gate member rotates wherein simultaneous opening and sealing closure of the select gas chambers is effected in either the first or the second positions.
- the gate assembly includes biasing means operatively coupled to the gate member to urge it into sealing contact with the open end of the canister of the remaining of the chambers to promote sealing closure of said canister in the first position. More preferably each of the canisters at its open end is associated with a seal arranged for sealing contact with the gate member under the biasing influence of the biasing means.
- the actuator includes a motor arranged to engage the gate member for rotation about its rotational axis between the first and second positions. More preferably the actuator also includes a clutch which on engagement deactivates the biasing means releasing it from the gate member releasing it from sealing contact with the canister of the select gas chamber whereupon rotation of the gate member is effected via the motor. Even more preferably the clutch is an electromagnetic clutch which on disengagement activates the biasing means urging it into contact with the gate member effecting its sealing contact with the canister of the select gas chamber.
- the gate member is one of a pair of gate members dedicated to respective of the pair of open ends of the tubular housings.
- the actuator includes a pair of motors dedicated to respective of the pair of gate members.
- the pair of gate members are configured and the motors synchronised for simultaneous opening or closure of the open ends of the same tubular housings.
- the actuator includes a shaft connected between the pair of gate members with a single motor coupled to the shaft for synchronised opening or closure of the tubular housings.
- the gas separation apparatus also comprises a fan operatively coupled to at least one of the gas chambers to promote the gas flow through said chambers for carbon dioxide adsorption. More preferably the fan is one of a plurality of fans dedicated to respective of the plurality of gas chambers.
- the gas separation apparatus further comprises a control device arranged to communicate with the actuator to control movement of the gate assembly from the first to the second positions after a predetermined period of time. More preferably the control device is arranged to communicate with the plurality of fans to deactivate the fan associated with the remaining of the chambers with the gate assembly in the first position.
- the gas separation apparatus additionally comprises a purging assembly associated with the gas chambers for purging of gas from the remaining of the chambers with the gate assembly in the first position.
- the purging assembly includes a vacuum pump arranged for evacuation of gas from said remaining chambers.
- the gas separation apparatus still further comprises a desorption assembly associated with the gas chambers for desorption of the carbon dioxide from the adsorbent structure to which it is directly adsorbed. More preferably the desorption assembly includes heating means operatively coupled to the gas chambers to elevate the temperature of the adsorbent structure for desorption of the carbon dioxide.
- a method of gas separation comprising the steps of: exposing gas to an adsorbent structure within a plurality of gas chambers for direct adsorption of carbon dioxide from the gas onto the adsorbent structure; moving a gate assembly arranged to cooperate with the plurality of gas chambers from i) a first position to permit gas flow through at least one of the chambers for carbon dioxide adsorption whilst sealing closed the remaining of the chambers, to ii) a second position to permit gas flow through at least said remaining of the chambers whilst sealing closed one of said at least one of the chambers.
- the step of exposing gas to an adsorbent structure involves promoting gas flow through a plurality of canisters each defining respective of the plurality of gas chambers.
- the step of moving the gate assembly from the first to the second positions involves rotating a gate member dedicated to a common end of the canisters, the gate member including a predetermined number of openings arranged in the first position to align with respective openings of said at least one of the chambers of the corresponding canisters.
- the gate assembly rotationally moves in substantially equal angular increments being equal to the angular offset of the canisters relative to one another. More preferably movement of the gate assembly is effected after substantially the same periods of time between the first and the second position, or consecutive positions, of the gate assembly. Still more preferably said periods of time are based on the time required for desorption of the carbon dioxide from the adsorbent structure onto which it is adsorbed.
- the plurality of gas chambers in number is determined based on i) the total time (T) required for a full cycle of gas separation for one of the gas chambers, and ii) the time (ts) required for the desorption stage of that cycle. More preferably the number of chambers is calculated according to the equation T/(fs + tp) where tp is the time required for purging of the gas chamber.
- Figure 1 is a perspective view of a gas separation apparatus according to a preferred embodiment of the invention.
- Figure 2 is an end elevational view of the gas separation apparatus of the embodiment of figure 1 ;
- Figure 3 is a perspective view shown exploded of the gas separation apparatus of the embodiment of figure 1 ;
- Figure 4 is a sectional view taken longitudinally of the gas separation apparatus of the embodiment of the preceding figures.
- gas separation apparatus 10 of a preferred embodiment of a first aspect of the invention.
- the gas separation apparatus is in the form of a direct air capture apparatus 10 generally comprising:
- a gate assembly 16 and 17 arranged to cooperate with each end of the plurality of air chambers 12a to 12f;
- an actuator 18 and 19 operatively coupled to the gate assembly 16 and 17 to effect its movement.
- the plurality of air chambers 12a to 12f are each defined by a tubular housing in the form of canisters 20a to 20f, respectively.
- the canisters such as 20a are open ended and arranged parallel to one another to cooperate with the gate assembly 16 and 17 for opening and sealing closure of the respective air chambers 12a to 12f.
- the gate assembly 16 and 17 includes a pair of gate members 22 and 24 each dedicated to a common end of the canisters 20a to 20f.
- the gate members 22 and 24 are together movable from:
- the canisters 20a to 20f are of substantially equal length and aligned with one another for simultaneous opening and sealing closure via the gate members 22 and 24 in either the first or the second positions.
- the parallel canisters 20a to 20f are as viewed from their common ends arranged in a circle and equally-spaced angularly relative to one another.
- the gate members such as 22 each include a predetermined number of openings, in this instance five openings 26a to 26e, angularly separated to align with respective of said at least one of the chambers 12a to 12e in the first position. The remaining of the chambers 12f is blocked or otherwise sealed by the gate members such as 22 and 24 in the first position.
- the gate members 22 and 24 of this embodiment are arranged to rotate about respective ends of the canisters 20a to 20f for movement between the first and consecutive angular positions.
- the gate members 22 and 24 rotate about a rotational axis 30 about which the canisters 20a to 20f are equally spaced both radially and angularly. This means simultaneous opening and sealing closure of the select air chambers such as 12a is effected by rotation of the gate members 22 and 24 into either of the first or the consecutive positions.
- the gate assembly 17 includes biasing means in the form of springs 32a to 32f operatively coupled to the gate member 24 to urge it into sealing contact with the canister 20f of the remaining of the chambers 12f in the first position.
- the springs 32a to 32f are mounted to an inside face of a housing plate 36 of the gate assembly 17.
- each of the canisters 20a to 20f is associated with a seal 38a to 38f arranged for sealing contact with the gate member 22 under the influence of the biasing means or springs such as 31 a.
- the canisters 20a to 20f are mounted to end plates 39 and 40 having apertures such as 42a to 42f for receipt of the corresponding canister 20a to 20f.
- Each of the apertures such as 42a is rebated on an outer face of the end plate 39 for seating of the corresponding seal 38a.
- the actuator such as 18 includes a motor 46 arranged to engage the gate member 22 for rotation about its rotational axis 30.
- the actuator 18 or 19 also includes a clutch arrangement in the form or an electromagnetic clutch (not designated) which on engagement deactivates the biasing means or springs such as 31 a or 32a from the gate member 22 or 24.
- the gate member 22 or 24 thus retracts from its sealing contact with the canisters 20a to 20f whereupon rotation of the gate member 22 and 24 is effected via the corresponding motor 46 and 47.
- the gate member such as 22 is rotated anticlockwise (when viewed from the left hand end) from the first into the second position where the electromagnetic clutch on disengagement activates the biasing means or springs such as 31 a which urge the gate member 22 into sealing contact with the canisters 20a to 20f.
- the canister 20a of the select air chamber 12a is sealed closed by the gate members 22 and 24 whereas the other canisters 20b to 20f are opened to atmosphere.
- the motor 46 is one of a pair of the motors dedicated to respective of the pair of gate members 22 and 24.
- the pair of gate members 22 and 24 are configured and the motors 46 and 47 synchronised for simultaneous opening or closure of the canisters such as 32a to 32f.
- the gas separation or direct air capture apparatus 10 also comprises a plurality of fans 52a to 52f dedicated to respective of the plurality of gas chambers 12a to 12f.
- the fans such as 52a are mounted to the housing plate 37 of the gate assembly 16and designed to promote gas flow through the corresponding chamber such as 12a for carbon dioxide adsorption.
- the gas separation or direct air capture apparatus 10 further comprises a control device (not shown) arranged to communicate with the actuator 18 and 19 or in this example the motors 46 and 47.
- the control device controls movement of the gate assembly 16 and 17 or more particularly the gate members 22 and 24 from the first to the second positions, or other consecutive positions, after a predetermined period of time.
- the control device is also arranged to communicate with the fans 50a to 50f to deactivate the fan such as 52f associated with the remaining or sealed closed of the chamber 12fwith the gate assembly 18 and 19 in the first position.
- the gas separation or direct air capture apparatus 10 additionally comprises a purging assembly (not shown) associated with each of the air chambers 12a to 12f for the purging of gas from the remaining or sealed closed of the chambers 12f with the gate assembly in the first position.
- the purging assembly includes a vacuum pump (not shown) arranged for evacuation of gas from the sealed closed chamber 12f.
- the gas separation or direct air capture apparatus 10 still further comprises a desorption assembly (not shown) associated with the air chambers 12a to 12f for desorption of the carbon dioxide from the adsorbent structure 14a to 14f onto which it is directly adsorbed.
- the desorption assembly includes heating means operatively coupled to the sealed closed air chamber such as 12f to elevate the temperature of the corresponding adsorbent structure 14f for desorption of the carbon dioxide.
- the adsorbent structure such as 14a is adapted to directly adsorb carbon dioxide from gas exposed to the chamber 12a.
- the adsorbent structure 14a includes a metal-organic framework (MOF) capable of directly adsorbing carbon dioxide from atmosphere.
- MOF metal-organic framework
- the gate assembly 16 and 17 is sequentially moved from a first position as depicted in the various illustrations of the apparatus 10 of the preferred embodiment to a second and consecutive positions (not illustrated) synchronous with the typical cycle for gas separation or direct air capture of carbon dioxide as outlined in the preceding paragraph.
- the total time for a full cycle of gas separation for each of the canisters such as 20a is 30 minutes.
- the gate assembly 16 and 17 of the preferred embodiment of the apparatus 10 rotates from its first to the second or consecutive positions every five minutes wherein each of the canisters 20a to 20f experiences the total cycle time of 30 minutes.
- the first position it will be understood that at the first position:
- canister 20a is open in the course of completing cooling at stage 4 and adsorption of carbon dioxide at stage 1 for a combined period of 25 minutes;
- canisters 20b to 20e are open in the course of stage 4 cooling and stage 1 adsorption for combined durations of 20, 15, 10, and 5 minutes, respectively;
- canister 20f is sealed closed in the course of completing its purging of residual air at stage 2 and desorption of the adsorbed carbon dioxide at stage 3 for a combined period of 5 minutes.
- the total cycle time for each of the canisters such as 20a is 30 minutes
- the canister 20a is sealed closed for stage 2 purging and stage 3 desorption;
- canisters 20b to 20f are open for stage 4 cooling and stage 1 adsorption of carbon dioxide.
- the apparatus 10 continues in this staged rotation of the gate assembly 16 and 17 whereby each of the canisters is sealed closed for purging and desorption for the requisite time.
- the total number of gas chambers (N) such as 12a or canisters 10a may be calculated based on the total time (T) required for a full cycle of gas separation or direct air capture according to the equation:
- N T/(fc/ + tp), where td is the time required for the desorption stage and tp is the time required for the purging stage.
- the required time for purging and desorption is 10 minutes and the total cycle time is 60 minutes then the number of gas chambers will be six (6).
- the time required for purging and desorption is a reciprocal fraction of the number of canisters of the apparatus. For example, if the apparatus consists of 10 canisters then one tenth of the time is dedicated to purging and desorption. If the total cycle time is 60 minutes this equates to 6 minutes for purging and desorption.
- the gate member 22 or 24 includes N-1 or in this case openings 26a to 26e, where N is the number of gas chambers or corresponding canisters.
- carbon dioxide obtained from the apparatus such as 10 according to this cycle not only directly removes this greenhouse gas from the atmosphere but also provides carbon dioxide as a potential feedstock.
- renewable methane may be synthesised by reacting carbon dioxide from the apparatus such as 10 with hydrogen from water hydrolysis powered by a renewable energy source.
- the applicant’s pending International patent publication No. W02020/000020 is directed to these technologies.
- the apparatus with a given footprint provides increased exposure of air or other gas to the adsorbent structure for increased direct carbon dioxide adsorption;
- the apparatus can be scaled up or down depending on the carbon dioxide requirement
- the apparatus can be reconfigured depending on the concentration of carbon dioxide in the air or other gas to which it is exposed where for example lower carbon dioxide concentrations require longer adsorption periods.
- the canisters of the preferred embodiment may be of a linear rather than circular arrangement with gate members moving in a shuttle action across the ends of the aligned canisters.
- the specific construction of the apparatus may vary where for example the clutch and biasing means is not required where vacuum pressure alone maintains sealing closure of the gas chambers in the course of desorption of the adsorbed carbon dioxide.
- the gate member of the preferred or alternative embodiments may have more than one of the openings vacant for blocking or sealing of the same number of gas chambers or corresponding canisters of the apparatus.
- the apparatus and method extend to other embodiments employing a combination of vacuum pressure swing and temperature swing driving the adsorption/desorption cycle which effects the required gas separation.
- the apparatus may be applied to gases other than air where carbon dioxide is adsorbed onto an adsorbent structure of the apparatus.
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Fluid Mechanics (AREA)
- Separation Of Gases By Adsorption (AREA)
Abstract
Description
Claims
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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AU2021395695A AU2021395695A1 (en) | 2020-12-11 | 2021-10-29 | A gas separation apparatus |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
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AU2020904622 | 2020-12-11 | ||
AU2020904622A AU2020904622A0 (en) | 2020-12-11 | A Gas Separation Apparatus |
Publications (1)
Publication Number | Publication Date |
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WO2022120408A1 true WO2022120408A1 (en) | 2022-06-16 |
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ID=81972746
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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PCT/AU2021/051267 WO2022120408A1 (en) | 2020-12-11 | 2021-10-29 | A gas separation apparatus |
Country Status (2)
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AU (1) | AU2021395695A1 (en) |
WO (1) | WO2022120408A1 (en) |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1589757A (en) * | 1977-04-04 | 1981-05-20 | Bendix Corp | Single bed adsorption separator apparatus |
GB2190014A (en) * | 1986-05-07 | 1987-11-11 | Boc Group Inc | Improved valving assembly for a pressure swing adsorption apparatus |
US5827358A (en) * | 1996-11-08 | 1998-10-27 | Impact Mst, Incorporation | Rapid cycle pressure swing adsorption oxygen concentration method and apparatus |
-
2021
- 2021-10-29 AU AU2021395695A patent/AU2021395695A1/en active Pending
- 2021-10-29 WO PCT/AU2021/051267 patent/WO2022120408A1/en active Application Filing
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1589757A (en) * | 1977-04-04 | 1981-05-20 | Bendix Corp | Single bed adsorption separator apparatus |
GB2190014A (en) * | 1986-05-07 | 1987-11-11 | Boc Group Inc | Improved valving assembly for a pressure swing adsorption apparatus |
US5827358A (en) * | 1996-11-08 | 1998-10-27 | Impact Mst, Incorporation | Rapid cycle pressure swing adsorption oxygen concentration method and apparatus |
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AU2021395695A1 (en) | 2023-07-06 |
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