WO2022110153A1 - Multi-color bathroom wall panel and preparation method therefor - Google Patents

Multi-color bathroom wall panel and preparation method therefor Download PDF

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Publication number
WO2022110153A1
WO2022110153A1 PCT/CN2020/132803 CN2020132803W WO2022110153A1 WO 2022110153 A1 WO2022110153 A1 WO 2022110153A1 CN 2020132803 W CN2020132803 W CN 2020132803W WO 2022110153 A1 WO2022110153 A1 WO 2022110153A1
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WO
WIPO (PCT)
Prior art keywords
powder coating
plate
wall panel
bathroom wall
spraying
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PCT/CN2020/132803
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French (fr)
Chinese (zh)
Inventor
胡福涛
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苏州科逸住宅设备股份有限公司
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Priority to PCT/CN2020/132803 priority Critical patent/WO2022110153A1/en
Publication of WO2022110153A1 publication Critical patent/WO2022110153A1/en

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C37/00Component parts, details, accessories or auxiliary operations, not covered by group B29C33/00 or B29C35/00
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C51/00Shaping by thermoforming, i.e. shaping sheets or sheet like preforms after heating, e.g. shaping sheets in matched moulds or by deep-drawing; Apparatus therefor
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C51/00Shaping by thermoforming, i.e. shaping sheets or sheet like preforms after heating, e.g. shaping sheets in matched moulds or by deep-drawing; Apparatus therefor
    • B29C51/26Component parts, details or accessories; Auxiliary operations
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C51/00Shaping by thermoforming, i.e. shaping sheets or sheet like preforms after heating, e.g. shaping sheets in matched moulds or by deep-drawing; Apparatus therefor
    • B29C51/26Component parts, details or accessories; Auxiliary operations
    • B29C51/42Heating or cooling
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C51/00Shaping by thermoforming, i.e. shaping sheets or sheet like preforms after heating, e.g. shaping sheets in matched moulds or by deep-drawing; Apparatus therefor
    • B29C51/26Component parts, details or accessories; Auxiliary operations
    • B29C51/46Measuring, controlling or regulating
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D167/00Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
    • C09D167/06Unsaturated polyesters having carbon-to-carbon unsaturation
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/03Powdery paints

Definitions

  • the invention relates to the technical field of home improvement building materials, in particular to a preparation method of a colored integral bathroom wall panel and a colored bathroom wall panel prepared by the preparation method.
  • the purpose of the present invention is to provide a preparation method of a colored bathroom wall panel, the molding material compression molding and the coating of the powder coating are completed at the same time, the preparation process is simple, and the preparation method
  • the prepared colored bathroom wall panel has high bonding strength between the colored coating on the surface and the base material.
  • the present invention adopts the following technical scheme:
  • a preparation method of a colored bathroom wall panel comprising the following steps:
  • a sheet-like molding compound is placed on the lower mold with a core, and the sheet-like molding compound is used to form the matrix, and the laying area of the sheet-like molding compound is 50% ⁇ 95%; during molding, the mold is closed for 1 to 6 minutes, and then the mold is opened to obtain a colored bathroom wall panel, which includes a substrate of sheet molding compound and a colored coating formed on the substrate;
  • the raw material components of the powder coating and the sheet molding compound both include unsaturated polyester resins, and the raw material components of the powder coating also include pigments; the softening point of the powder coating is lower than the heating temperature of the upper mold.
  • Unsaturated polyester resins have unsaturated bonds (carbon-carbon double bonds).
  • unsaturated bonds carbon-carbon double bonds.
  • the spraying is to uniformly spray the powder coating on the surface of the cavity in the form of electrostatic spraying, and the spraying is completed at one time.
  • the spray gun for electrostatic spraying should be cleaned. There should be no powder in the spray gun pipeline and powder supply channel, and the powder left in the spray gun is easy to absorb water and polymerize.
  • the upper mold has a top plate and a side plate, and the cavity is formed between the top plate and the side plate; when spraying, the powder coating is sprayed on the inner surface of the top plate .
  • the upper mold is pressed down, and the material between the upper mold and the lower mold is extruded into a predetermined shape through the cavity of the upper mold and the core of the lower mold.
  • the traditional upper mold and lower mold are being molded, there will be a certain distance between the side plate of the upper mold and the core of the lower mold, so that the gas in the cavity can be discharged during molding.
  • a protective cover when spraying, a protective cover is used to cover the side plate, so that the inner surface of the top plate is exposed, the protective cover has a bottom plate and a protective plate supported on the bottom plate, the protective cover The board is attached to the side board.
  • a protective cover is used to cover the side plate during spraying, to protect the side plate, and to expose the inner surface of the top plate. In this way, when spraying, the powder coating is mainly concentrated on the inner surface of the top plate to avoid molding. When the distance between the side plate and the core is reduced.
  • the distance between the end of the protective plate close to the top plate and the top plate is 0.5-1 cm, to prevent the distance between the protective plate and the top plate from being too close, and the spraying of the edge of the inner surface of the top plate will reduce to influence.
  • the mold temperature during the molding is 140-150° C., so that a chemical bond is formed between the powder coating and the sheet molding compound, and the unsaturated bonds on both sides are opened and connected, so that the coating The bonding of the layer to the substrate is stronger.
  • the moving speed of the upper mold during the molding is 0.1-3 mm/s, and the starting speed of the mold during molding is lower than that of the traditional molding, so that the gas in the mold is slowly and effectively discharged, and as far as possible Avoid up and down reciprocating exhaust to prevent air bubbles in the product caused by poor exhaust.
  • the moving speed of the upper mold is first slow and then fast, or blowing air into the cavity through the gap between the side plate of the upper mold and the core to release the mold
  • the stress between the mould and the colored bathroom wall panel prevents bad products.
  • the spraying thickness of the coating powder is 70-120um. In some embodiments of the present invention, it is preferable that the spray thickness of the coating powder is 80um.
  • the raw material of the powder coating includes the following components: unsaturated polyester resin, curing agent, leveling agent, titanium dioxide, pigment and auxiliary.
  • the raw material components and preparation steps of the powder coating are as follows:
  • step 2) The material obtained by pre-mixing in step 1) is extruded after being melted, and pulverized to obtain a powder with a predetermined particle size, which is the powder coating in this application.
  • the means such as mixing, melting, and pulverization are conventional technical means in the corresponding field, and are not the content to be protected by the present invention, and the detailed process will not be repeated here.
  • the density of the powder coating is 1.2-1.4 g/cm 3 .
  • the particle size of the powder coating is 38-45um.
  • the raw material components and preparation steps of the sheet molding compound are as follows:
  • the rolled sheet is transported to the thickening chamber for thickening, the temperature of the thickening chamber is set to 45°C, and the thickening time is 24 hours to obtain a sheet molding compound.
  • the curing agent in the above raw materials includes tert-butyl peroxybenzoate (TBPB) and/or benzoyl peroxide, specifically, the curing agent is tert-butyl peroxide (2-ethylhexanoate), One or more of methyl ethyl ketone, tert-butyl peroxybenzoate, dibenzoyl peroxide, di(4-tert-butyl) cyclohexyl peroxydicarbonate, dilauroyl peroxide or aliphatic polyamine, etc. combination;
  • TBPB tert-butyl peroxybenzoate
  • benzoyl peroxide specifically, the curing agent is tert-butyl peroxide (2-ethylhexanoate), One or more of methyl ethyl ketone, tert-butyl peroxybenzoate, dibenzoyl peroxide, di(4-tert-butyl) cycl
  • the coupling agent is a silane coupling agent and/or titanate; specifically, the silane coupling agent is ⁇ -(methacryloyloxypropyl)trimethoxysilane, ⁇ -(2,3 -Glycidoxy)propyltrimethoxysilane, N- ⁇ (aminoethyl)- ⁇ -aminopropylmethyldimethoxysilane, N-( ⁇ -aminoethyl)- ⁇ -aminopropyl Triethoxysilane, N- ⁇ (aminoethyl)- ⁇ -aminopropyltrimethoxysilane, anilinemethyltriethoxysilane, ⁇ -aminopropyltriethoxysilane, vinyltriethoxysilane One or more combinations of vinyltrimethoxysilane, vinyltrimethoxysilane, ⁇ -chloropropyltriethoxysilane, and the like.
  • the unsaturated polyester resins used are ortho-, meta-, or epoxy vinyl ester unsaturated resins.
  • the crosslinking agent is styrene; the filler is aluminum hydroxide micropowder with particle size less than or equal to 10um or calcium carbonate micropowder with particle size less than or equal to 10um or a mixture of the two; Molding agents, etc. can be selected according to the actual situation of conventional types.
  • the present invention also provides a colored bathroom wall panel prepared according to the above-mentioned preparation method, comprising a substrate of sheet molding compound and a colored coating formed on the surface of the substrate, the colored coating and the substrate There are chemical bonds between them.
  • the thickness of the color coating is 60-100um, and the thickness of the sheet molding compound base is 2-6mm.
  • the advantages of the present invention are: in the preparation method of the colored bathroom wall panel in the present invention, the main components of the powder coating and the substrate are similar, both contain unsaturated polyester resin, and the method of heating and softening is adopted.
  • the powder coating is softened before molding.
  • the powder coating and the sheet molding compound are cured together.
  • the molding material is pressed and the color coating is painted at the same time, which not only makes the preparation process easy to control, but also makes the molding process form
  • the combination between the color coating and the substrate is more firm and reliable, which solves the problems that the coating on the SMC product obtained by the traditional preparation method is easy to fall off and the adhesion is not strong.
  • FIG. 1 is a schematic structural diagram of an upper mold, a lower mold and a protective cover in a preferred embodiment of the present invention
  • upper mold-1 cavity-11, top plate-12, side plate-13, lower mold-2, core-21, protective cover-3, bottom plate-31, protective plate-32, support plate- 33, Snap-34.
  • the colored bathroom wall panel in this embodiment includes a sheet-mounted plastic film (SMC) substrate and a colored coating formed on the surface of the substrate.
  • the thickness of the color coating is 90um, the color coating is formed by powder coating, and the thickness of the sheet molding compound base is 3.5um.
  • the raw materials of the powder coating and the sheet-packed plastic film both contain unsaturated polyester resin
  • the double bond in the unsaturated polyester resin is opened and connected, and the color coating and the sheet-like molding compound matrix are passed through carbon
  • the chemical bonds of carbon bonds are connected to make the connection between the color coating and the substrate firm, and the color of the color coating can be changed by changing the pigment added in the powder coating, which makes the appearance of the bathroom wall panel more diverse.
  • Embodiment 2 The preparation method of colored bathroom wall panel
  • This embodiment provides a method for preparing the colored bathroom wall panel in Embodiment 1, which specifically includes the following steps:
  • step 1) The material obtained by premixing in step 1) is extruded after being melted, and pulverized to obtain a powder with a predetermined particle size, that is, the powder coating in this embodiment is obtained.
  • the powder coating obtained in this example is red, the density is 1.3g/cm 3 , the particle size is 40um, and the softening point temperature is 140°C.
  • the sheet molding compound specifically includes the following raw materials by weight, wherein E4 is the accelerator cobalt isooctanoate:
  • the rolled sheet is transported to a thickening chamber for thickening, the temperature of the thickening chamber is set to 45°C, and the thickening time is 24 hours to obtain a sheet molding compound.
  • the mold used in this embodiment includes an upper mold 1 and a lower mold 2 that cooperate with each other.
  • the upper mold 1 has a cavity 11, and the lower mold 2 has a core 21.
  • the upper mold 1 is pressed down, Through the cavity 11 of the upper die 1 and the core 21 of the lower die 2, the substance located between the upper die 1 and the lower die 2 is extruded into a predetermined shape to form a product.
  • the upper mold 1 has a top plate 12 and a side plate 13 , and a cavity 11 is formed between the top plate 12 and the side plate 13 ; when spraying, powder coating is sprayed on the inner surface of the top plate 12 .
  • the protective cover 3 is used to cover the side plate 13 during spraying, so that the inner surface of the top plate 12 is exposed, so that the powder coating is mainly concentrated on the inner surface of the top plate 12 during spraying.
  • the reduction of the distance between the side plate 13 and the core 21 is avoided.
  • the protective cover 3 in this embodiment has a bottom plate 31 and a protective plate 32 and a supporting plate 33 supported on the bottom plate 31.
  • the side plate 13 is located in the space formed between the supporting plate 33 and the protective plate 32.
  • the supporting plate 33 The distance from the protective plate 32 is the same as the thickness of the side plate 13 .
  • the protection plate 32 is attached to the inner surface of the side plate 13
  • the support plate 33 is attached to the outer surface of the side plate 13 .
  • the top of the support plate 33 is also designed with a buckle 34 to fix the protective cover 3 on the upper mold 1 .
  • the side plates 13 are distributed at the corners of the bottom plate 31 in the form of rods, and only need to play the role of fixed connection.
  • the spraying of the inner surface edge of the top plate 12 is affected, so the distance between the end of the protective plate 32 close to the top plate 12 and the top plate 12 is 0.5 cm , and the end is provided with an inclined surface, and the inclined surface faces the inside of the cavity 11 to avoid the influence on the spraying operation.
  • the end portion may also be arc-shaped.
  • the protective cover 3 to limit the spraying of the powder coating on the inner surface of the top plate 12 during spraying.
  • the upper mold 1 with the cavity 11 is heated to 150°C and kept warm, and the powder coating prepared in step 1) is sprayed on the surface of the cavity 11. After spraying, wait for 60 s to allow sufficient time for the powder coating to soften. Under the electrostatic adsorption and softening after heating, the concave-convex surface formed by the spherical shape of the powder coating becomes a flat surface.
  • the spraying is to uniformly spray the powder coating on the surface of the cavity 11 in the form of electrostatic spraying, and the spraying is completed at one time.
  • spraying it is necessary to design the spraying trajectory in advance, spray according to the spraying trajectory, and complete the spraying at one time; avoid repeated spraying on the already sprayed paint, the poor heat transfer of the paint leads to the low curing temperature of repeated spraying, and the bonding force of some coatings is poor .
  • the spray gun for electrostatic spraying should be cleaned. There should be no powder in the spray gun pipeline and powder supply channel. The powder left in the spray gun is easy to absorb water and cause polymerization.
  • the sheet molding compound prepared in step 2) is placed on the core 21 of the lower mold 2 at the same time.
  • the laying area of the sheet molding compound is 75% of the orthographic projection area of the final colored bathroom wall panel.
  • the moving speed of the upper mold 1 during molding is 0.3mm/s, and the starting speed of the mold during molding is lower than that of traditional molding, so that the gas in the mold can be discharged slowly and effectively, and the up and down reciprocating exhaust should be avoided as much as possible to prevent the cause of poor exhaust.
  • Product has air bubbles.
  • the moving speed of the upper mold 1 is slow first and then fast, or blow air into the cavity 11 through the gap between the side plate 13 of the upper mold 1 and the core 21 to release the mold and the colored bathroom wall panel. The stress between them prevents the product from being defective.
  • the steps are distinguished and numbered.
  • the above steps such as the preparation of powder coatings and the preparation of sheet molding compounds, can be carried out simultaneously or in random order.
  • Both the powder coating and the matrix include the raw material components of unsaturated polyester resin.
  • the main components of the powder coating and the matrix are the same, which not only makes the curing conditions the same, the preparation process is easy to control, but also the powder coating and the sheet molding compound are cross-linked during molding.
  • the reaction produces partial fusion to form an integrated product, and the color coating and the substrate are chemically bonded, so that the final product has high bonding strength and high peel strength between the substrate and the color coating.
  • Example 2 According to the method specified in GB/T13095-2008, the color bathroom wallboard products prepared in Example 2 were tested for peeling resistance, stain resistance, chemical corrosion resistance and other items.
  • the test results are as follows:
  • Table 1 shows that the wallboard product prepared by the method of Example 2 has excellent performance in items such as peel resistance, stain resistance, chemical corrosion resistance, etc., especially excellent adhesion performance, and the color of the coating can be changeable .
  • powder coating is combined with sheet molding compound, and SMC is pressed according to the normal molding process, and the coating film is formed and cured at the same time of molding, which reduces the production process, reduces the probability of quality problems in the process, and improves the product quality.
  • Pass rate improve production efficiency and reduce costs; reduce intermediate links, thus reducing the input of production sites and labor wages; for molded products with complex shapes, it is easier to carry out surface coating; as a primer, no sealing is required.
  • the hole is polished, and there is no peeling problem caused by poor adhesion between coatings.
  • the upper mold for making the SMC wallboard is sprayed first, so that a layer of powder coating is attached to the inner surface of the cavity, and then the SMC raw material is placed on the bottom.
  • the powder coating is bonded to the surface of the SMC product during molding to form a color-coated SMC wallboard product.

Abstract

A preparation method for a multi-color bathroom wall panel, comprising the following steps: heating an upper mold (1) having a mold cavity (11) to 130-155°C and maintaining the temperature, spraying a powder coating onto a surface of the mold cavity (11), and waiting for at least 40 seconds after the spraying is complete, wherein the powder coating is used to form a multi-color coating layer; laying, on a lower mold (2) having a mold core (21), a sheet molding compound used to form a substrate, wherein the area of the laid sheet molding compound accounts for 50-95% of the area of an orthographic projection of a resultant multi-color bathroom wall panel; and during molding, combining the two molds and maintaining the temperature for 1-6 minutes, and then opening the molds to obtain the multi-color bathroom wall panel, wherein the multi-color bathroom wall panel comprises the substrate composed of the sheet molding compound and the multi-color coating layer disposed on the substrate. The raw material composition of the powder coating and the raw material composition of the sheet molding compound both comprise an unsaturated polyester resin, and the raw material composition of the powder coating further comprises paints. The softening point of the powder coating is lower than the heating temperature of the upper mold (1).

Description

彩色浴室墙板及其制备方法Color bathroom wall panel and preparation method thereof 技术领域technical field
本发明涉及家装建材技术领域,具体涉及一种彩色整体浴室墙板的制备方法以及采用该制备方法制备得到的彩色浴室墙板。The invention relates to the technical field of home improvement building materials, in particular to a preparation method of a colored integral bathroom wall panel and a colored bathroom wall panel prepared by the preparation method.
背景技术Background technique
现有SMC彩色墙板主要通过饰面材料印刷、浸胶,与SMC一体模压来实现个性化颜色需求,或者如公布号CN107284107A的发明专利申请中所公开的采用喷砂,喷涂底漆后再木纹转印纸转印以达到无饰纸彩色模压墙板。以上两种工艺分别存在以下缺陷:1、饰纸材料模压彩色SMC墙板,由于使用过程中表层防护材料脱落后,会出现因为纸纤维外露于潮湿环境中出现下端发霉、发黄、变色等影响整体浴室的使用;2、CN107284107A专利申请中使用的工艺虽能解决饰纸材料的问题,但其工序复杂,先要模压单色墙板,再进行喷砂、喷漆、转印等工序,操作环境恶劣,耗时耗力。Existing SMC color wall panels are mainly used for printing, dipping of veneer materials, and integral molding with SMC to achieve personalized color requirements, or as disclosed in the patent application for invention publication number CN107284107A, sandblasting is used, and primer is sprayed before wood is used. Texture transfer paper transfer to achieve blank paper color moulded wallboard. The above two processes have the following defects: 1. Molded color SMC wallboard with decorative paper material. After the surface protective material falls off during use, there will be mildew, yellowing, and discoloration at the lower end because the paper fiber is exposed in a humid environment. The use of the whole bathroom; 2. Although the process used in the CN107284107A patent application can solve the problem of decorative paper materials, the process is complicated. First, the monochrome wallboard must be molded, and then sandblasting, painting, transfer printing and other processes. The operating environment Harsh, time-consuming and labor-intensive.
发明内容SUMMARY OF THE INVENTION
有鉴于此,为了克服现有技术的缺陷,本发明的目的是提供一种彩色浴室墙板的制备方法,模塑材料压制成型与粉末涂料的涂装同时完成,制备工序简单,通过该制备方法制备得到的彩色浴室墙板,表面的彩色涂层与基材结合强度高。In view of this, in order to overcome the defects of the prior art, the purpose of the present invention is to provide a preparation method of a colored bathroom wall panel, the molding material compression molding and the coating of the powder coating are completed at the same time, the preparation process is simple, and the preparation method The prepared colored bathroom wall panel has high bonding strength between the colored coating on the surface and the base material.
为了达到上述目的,本发明采用以下的技术方案:In order to achieve the above object, the present invention adopts the following technical scheme:
一种彩色浴室墙板的制备方法,包括以下步骤:A preparation method of a colored bathroom wall panel, comprising the following steps:
将具有型腔的上模加热至130~155℃并保温,在所述型腔的表面喷涂粉末涂料,喷涂结束后等待至少40s,所述粉末涂料用于形成彩色涂层;heating the upper mold with the cavity to 130-155 ℃ and keeping the temperature, spraying powder coating on the surface of the cavity, waiting for at least 40s after spraying, the powder coating is used to form a color coating;
在具有型芯的下模上放置片状模塑料,所述片状模塑料用于形成基体,所述片状模塑料的铺设面积为最终制得的彩色浴室墙板正投影面积的50%~95%;模压时合模保温1~6min,之后开模,得到彩色浴室墙板,所述彩色浴室墙板包括片状模塑料的基体以及形成在所述基体上的彩色涂层;A sheet-like molding compound is placed on the lower mold with a core, and the sheet-like molding compound is used to form the matrix, and the laying area of the sheet-like molding compound is 50%~ 95%; during molding, the mold is closed for 1 to 6 minutes, and then the mold is opened to obtain a colored bathroom wall panel, which includes a substrate of sheet molding compound and a colored coating formed on the substrate;
所述粉末涂料与所述片状模塑料的原料成分均包括不饱和聚酯树脂,所述粉末涂料的原料成分还包括颜料;所述粉末涂料的软化点低于所述上模的加热温度。The raw material components of the powder coating and the sheet molding compound both include unsaturated polyester resins, and the raw material components of the powder coating also include pigments; the softening point of the powder coating is lower than the heating temperature of the upper mold.
不饱和聚酯树脂具有不饱和键(碳碳双键),通过将粉末涂料和片状模塑料的原料组成均设置有不饱和聚酯树脂,在模压时,片状模塑料内的不饱和键、粉末涂料内的不饱和键打开,片状模塑料能够与粉末涂料发生交联反应,使得片状模塑料和粉末涂料之间形成化学键连接,产生融合,形成一体化制品,彩色涂层与基体的结合更加牢固。Unsaturated polyester resins have unsaturated bonds (carbon-carbon double bonds). By setting the raw material compositions of powder coatings and sheet molding compounds with unsaturated polyester resins, during molding, the unsaturated bonds in the sheet molding compound , The unsaturated bond in the powder coating is opened, and the sheet molding compound can undergo a cross-linking reaction with the powder coating, so that a chemical bond is formed between the sheet molding compound and the powder coating, resulting in fusion, forming an integrated product, the color coating and the substrate. combination is stronger.
根据本发明的一些优选实施方面,所述喷涂为采用静电喷涂的形式将粉末涂料均匀地喷涂至所述型腔的表面,且一次喷涂完毕。喷涂前需预先设计好喷涂轨迹,按照喷涂轨迹依次喷涂,一次喷涂完成;避免在已喷涂好的涂料上重复喷涂,涂料的传热差导致重复喷涂的固化温度低,最终使得部分涂层与基体的结合力差。且使用完毕后要将静电喷涂的喷枪吹洗干净,喷枪管道及供粉通道内不可以存有粉末,留存在喷枪中的粉末容易吸水发生聚合。According to some preferred implementation aspects of the present invention, the spraying is to uniformly spray the powder coating on the surface of the cavity in the form of electrostatic spraying, and the spraying is completed at one time. Before spraying, it is necessary to design the spraying trajectory in advance, spray according to the spraying trajectory, and complete the spraying in one time; avoid repeated spraying on the already sprayed coating, the poor heat transfer of the coating leads to the low curing temperature of repeated spraying, and finally makes some coatings and substrates poor bonding. And after use, the spray gun for electrostatic spraying should be cleaned. There should be no powder in the spray gun pipeline and powder supply channel, and the powder left in the spray gun is easy to absorb water and polymerize.
根据本发明的一些优选实施方面,所述上模具有顶板和侧板,所述顶板和侧板之间形成所述型腔;喷涂时,将所述粉末涂料喷涂至所述顶板的内表面上。模压时,上模下压,通过上模的型腔以及下模的型芯,将位于上模和下模之间的物质挤压呈预定的形状。传统的上模与下模在模压时,上模的侧板与下模的型芯会有一定的间距,以便在模压时,将型腔内的气体排出。在本申请中,由于需要在型腔内喷涂粉末涂料,会导致合模时上模的侧板与型芯之间的距离减少,模具剪切边的排气通道减少,导致最后的产品容易产生气泡,良品率下降。所以在喷涂粉末涂料的时候保证其主要位于所述顶板的内表面上,避免其附着在侧板上,防止侧板与型芯之间的距离减少。According to some preferred implementation aspects of the present invention, the upper mold has a top plate and a side plate, and the cavity is formed between the top plate and the side plate; when spraying, the powder coating is sprayed on the inner surface of the top plate . During molding, the upper mold is pressed down, and the material between the upper mold and the lower mold is extruded into a predetermined shape through the cavity of the upper mold and the core of the lower mold. When the traditional upper mold and lower mold are being molded, there will be a certain distance between the side plate of the upper mold and the core of the lower mold, so that the gas in the cavity can be discharged during molding. In this application, since powder coating needs to be sprayed in the cavity, the distance between the side plate of the upper mold and the core during mold closing will be reduced, and the exhaust passages of the cutting edge of the mold will be reduced, resulting in the easy production of the final product. Bubble, yield decreased. Therefore, when the powder coating is sprayed, it is ensured that it is mainly located on the inner surface of the top plate, so as to prevent it from adhering to the side plate and to prevent the distance between the side plate and the core from being reduced.
根据本发明的一些优选实施方面,喷涂时,采用保护罩罩住所述侧板,使所述顶板的内表面裸露,所述保护罩具有底板以及支撑在所述底板上的保护板,所述保护板与所述侧板贴合。为了解决上述问题,本申请中在喷涂时采用保护罩罩住所述侧板,保护侧板,使顶板的内表面裸露,这样在喷涂时,粉末涂料主要集中在顶板的内表面上,避免了模压时侧板与型芯之间的距离减少。According to some preferred implementation aspects of the present invention, when spraying, a protective cover is used to cover the side plate, so that the inner surface of the top plate is exposed, the protective cover has a bottom plate and a protective plate supported on the bottom plate, the protective cover The board is attached to the side board. In order to solve the above problem, in the present application, a protective cover is used to cover the side plate during spraying, to protect the side plate, and to expose the inner surface of the top plate. In this way, when spraying, the powder coating is mainly concentrated on the inner surface of the top plate to avoid molding. When the distance between the side plate and the core is reduced.
根据本发明的一些优选实施方面,所述保护板靠近所述顶板的一端与所述顶板之间的距离为0.5~1cm,防止保护板与顶板之间距离过近,顶板内表面边缘的喷涂收到影响。According to some preferred implementation aspects of the present invention, the distance between the end of the protective plate close to the top plate and the top plate is 0.5-1 cm, to prevent the distance between the protective plate and the top plate from being too close, and the spraying of the edge of the inner surface of the top plate will reduce to influence.
根据本发明的一些优选实施方面,所述模压时的模具温度为140~150℃,以使得所述粉末涂料与片状模塑料之间形成化学键连接,双方的不饱和键打开后相连,使得涂层与基体的结合更加牢固。According to some preferred implementation aspects of the present invention, the mold temperature during the molding is 140-150° C., so that a chemical bond is formed between the powder coating and the sheet molding compound, and the unsaturated bonds on both sides are opened and connected, so that the coating The bonding of the layer to the substrate is stronger.
根据本发明的一些优选实施方面,所述模压时上模的移动速度为0.1~3mm/s,模压时采用低于传统模压时模具的启动速度,使得模具内的气体缓慢、有效排出,且尽量避免上下往复排气,防止排气不良造成产品有气泡。According to some preferred implementation aspects of the present invention, the moving speed of the upper mold during the molding is 0.1-3 mm/s, and the starting speed of the mold during molding is lower than that of the traditional molding, so that the gas in the mold is slowly and effectively discharged, and as far as possible Avoid up and down reciprocating exhaust to prevent air bubbles in the product caused by poor exhaust.
根据本发明的一些优选实施方面,模压结束之后的开模时,上模的移动速度先慢后快,或通过上模侧板与型芯之间的间隙向所述型腔内吹气以解除模具与彩色浴室墙板之间的应力,防止产品不良。According to some preferred implementation aspects of the present invention, when the mold is opened after the molding is finished, the moving speed of the upper mold is first slow and then fast, or blowing air into the cavity through the gap between the side plate of the upper mold and the core to release the mold The stress between the mould and the colored bathroom wall panel prevents bad products.
根据本发明的一些优选实施方面,喷涂时,所述的涂料粉末的喷涂厚度为70~120um。在本发明的一些实施例中,优选涂料粉末的喷涂厚度为80um。According to some preferred implementation aspects of the present invention, when spraying, the spraying thickness of the coating powder is 70-120um. In some embodiments of the present invention, it is preferable that the spray thickness of the coating powder is 80um.
根据本发明的一些优选实施方面,所述粉末涂料的原料包括如下成分:不饱和聚酯树脂、固化剂、流平剂、钛白粉、颜料以及助剂。According to some preferred implementation aspects of the present invention, the raw material of the powder coating includes the following components: unsaturated polyester resin, curing agent, leveling agent, titanium dioxide, pigment and auxiliary.
根据本发明的一些优选方面,粉末涂料的原料成分以及制备步骤如下:According to some preferred aspects of the present invention, the raw material components and preparation steps of the powder coating are as follows:
1)先按照如下组分将不饱和聚酯树脂、固化剂、流平剂、钛白粉、颜料以及助剂等成分进行预混合;1) First, pre-mix the unsaturated polyester resin, curing agent, leveling agent, titanium dioxide, pigment and auxiliary according to the following components;
Figure PCTCN2020132803-appb-000001
Figure PCTCN2020132803-appb-000001
2)将步骤1)中预混合得到的物质进行熔融后挤出,并进行粉碎后得到预定粒径的粉末,即为本申请中的粉末涂料。2) The material obtained by pre-mixing in step 1) is extruded after being melted, and pulverized to obtain a powder with a predetermined particle size, which is the powder coating in this application.
关于混合、熔融以及粉碎等手段均为对应领域的常规技术手段,其也并不是本发明所要保护的内容,详细过程在此不再赘述。The means such as mixing, melting, and pulverization are conventional technical means in the corresponding field, and are not the content to be protected by the present invention, and the detailed process will not be repeated here.
根据本发明的一些优选实施方面,所述粉末涂料的密度为1.2~1.4g/cm 3According to some preferred implementation aspects of the present invention, the density of the powder coating is 1.2-1.4 g/cm 3 .
根据本发明的一些优选实施方面,所述粉末涂料的粒径为38-45um。According to some preferred implementation aspects of the present invention, the particle size of the powder coating is 38-45um.
根据本发明的一些优选方面,片状模塑料的原料成分以及制备步骤如下:According to some preferred aspects of the present invention, the raw material components and preparation steps of the sheet molding compound are as follows:
A.先按照如下组分将不饱和聚酯树脂、固化剂、偶联剂、填料、苯乙烯和助剂等混合制成树脂糊;A. First, mix unsaturated polyester resin, curing agent, coupling agent, filler, styrene and auxiliary agent according to the following components to make resin paste;
Figure PCTCN2020132803-appb-000002
Figure PCTCN2020132803-appb-000002
Figure PCTCN2020132803-appb-000003
Figure PCTCN2020132803-appb-000003
B.通过刮刀,将混合均匀的树脂糊均匀涂敷在PE膜上;再通过调节切割器,切割玻璃纤维,控制玻璃纤维的长度和含量;将PE膜相对粘贴,形成一种上、下均覆有PE膜的片材,再将片材通过压实机压挤,使玻璃纤维与树脂充分浸渍,成型为片材,然后进行收卷;B. Apply the evenly mixed resin paste on the PE film through the scraper; then adjust the cutter to cut the glass fiber to control the length and content of the glass fiber; paste the PE film relatively to form an upper and lower uniform Sheet covered with PE film, and then squeeze the sheet through a compactor to fully impregnate the glass fiber and resin, form into a sheet, and then roll it up;
C.将收卷的片材运到增稠室增稠,增稠室的温度设置为45℃,增稠时间为24h,得到片状模塑料。C. The rolled sheet is transported to the thickening chamber for thickening, the temperature of the thickening chamber is set to 45°C, and the thickening time is 24 hours to obtain a sheet molding compound.
以上原料中的固化剂包括过氧化苯甲酸叔丁酯(TBPB)和/或过氧化苯甲酰,具体的,所述固化剂为过氧化(2-乙基己酸)叔丁酯、过氧化甲乙酮、过氧化苯甲酸叔丁酯、过氧化二苯甲酰、过氧化二碳酸二(4-叔丁基)环己酯、过氧化二月桂酰或脂肪多元胺等中的一种或多种组合;The curing agent in the above raw materials includes tert-butyl peroxybenzoate (TBPB) and/or benzoyl peroxide, specifically, the curing agent is tert-butyl peroxide (2-ethylhexanoate), One or more of methyl ethyl ketone, tert-butyl peroxybenzoate, dibenzoyl peroxide, di(4-tert-butyl) cyclohexyl peroxydicarbonate, dilauroyl peroxide or aliphatic polyamine, etc. combination;
所述偶联剂为硅烷偶联剂和/或钛酸酯;具体的,所述硅烷偶联剂为γ-(甲基丙烯酰氧基丙基)三甲氧基硅烷、γ-(2,3-环氧丙氧)丙基三甲氧基硅烷、N-β(氨乙基)-γ-氨丙基甲基二甲氧基硅烷、N-(β-氨乙基)-γ-氨丙基三乙氧基硅烷、N-β(氨乙基)-γ-氨丙基三甲氧基硅烷、苯胺甲基三乙氧基硅烷、γ-氨丙基三乙氧基硅烷、乙烯基三乙氧基硅烷、乙烯基三甲氧基硅烷和γ-氯丙基三乙氧基硅烷等中的一种或多种组合。The coupling agent is a silane coupling agent and/or titanate; specifically, the silane coupling agent is γ-(methacryloyloxypropyl)trimethoxysilane, γ-(2,3 -Glycidoxy)propyltrimethoxysilane, N-β(aminoethyl)-γ-aminopropylmethyldimethoxysilane, N-(β-aminoethyl)-γ-aminopropyl Triethoxysilane, N-β(aminoethyl)-γ-aminopropyltrimethoxysilane, anilinemethyltriethoxysilane, γ-aminopropyltriethoxysilane, vinyltriethoxysilane One or more combinations of vinyltrimethoxysilane, vinyltrimethoxysilane, γ-chloropropyltriethoxysilane, and the like.
使用的不饱和聚酯树脂为邻苯、间苯、或环氧乙烯基酯不饱和树脂。所述交联剂为苯乙烯;所述填料为粒径小于或等于10um的氢氧化铝微粉或粒径小于或等于10um的碳酸钙微粉或者二者的混合物,所述助剂为抗氧化剂、脱模剂等可以根据实际情况进行选择的常规种类。The unsaturated polyester resins used are ortho-, meta-, or epoxy vinyl ester unsaturated resins. The crosslinking agent is styrene; the filler is aluminum hydroxide micropowder with particle size less than or equal to 10um or calcium carbonate micropowder with particle size less than or equal to 10um or a mixture of the two; Molding agents, etc. can be selected according to the actual situation of conventional types.
本发明还提供了一种根据如上所述的制备方法制备得到的彩色浴室墙板,包括片状模塑料的基体以及形成在所述基体表面的彩色涂层,所述彩色涂层与所述基体之间为化学键连接。彩色涂层的厚度为60~100um,片状模塑料基体的厚度为2~6mm。The present invention also provides a colored bathroom wall panel prepared according to the above-mentioned preparation method, comprising a substrate of sheet molding compound and a colored coating formed on the surface of the substrate, the colored coating and the substrate There are chemical bonds between them. The thickness of the color coating is 60-100um, and the thickness of the sheet molding compound base is 2-6mm.
相较于现有技术,本发明的有益之处在于:本发明中彩色浴室墙板的制备方法,粉末涂料与基体的主体成分类似,均包含了不饱和聚酯树脂,且采用加热软化的方式使得粉末涂料在模压之前软化,在模压时,粉末涂料和片状模塑 料一起固化成型,模塑材料压制成型与彩色涂层的涂装同时完成,不仅使得制备工艺易于控制,且使得模压后形成的彩色涂层与基体之间的结合更加牢固可靠,解决了传统制备方法得到的SMC制品上涂料容易脱落、附着力不强的问题。Compared with the prior art, the advantages of the present invention are: in the preparation method of the colored bathroom wall panel in the present invention, the main components of the powder coating and the substrate are similar, both contain unsaturated polyester resin, and the method of heating and softening is adopted. The powder coating is softened before molding. During molding, the powder coating and the sheet molding compound are cured together. The molding material is pressed and the color coating is painted at the same time, which not only makes the preparation process easy to control, but also makes the molding process form The combination between the color coating and the substrate is more firm and reliable, which solves the problems that the coating on the SMC product obtained by the traditional preparation method is easy to fall off and the adhesion is not strong.
附图说明Description of drawings
为了更清楚地说明本发明实施例中的技术方案,下面将对实施例描述中所需要使用的附图作简单地介绍,显而易见地,下面描述中的附图仅仅是本发明的一些实施例,对于本领域普通技术人员来讲,在不付出创造性劳动的前提下,还可以根据这些附图获得其他的附图。In order to illustrate the technical solutions in the embodiments of the present invention more clearly, the following briefly introduces the accompanying drawings used in the description of the embodiments. Obviously, the accompanying drawings in the following description are only some embodiments of the present invention. For those of ordinary skill in the art, other drawings can also be obtained from these drawings without creative effort.
图1为本发明优选实施例中上模、下模以及保护罩的结构示意图;1 is a schematic structural diagram of an upper mold, a lower mold and a protective cover in a preferred embodiment of the present invention;
附图中:上模-1,型腔-11,顶板-12,侧板-13,下模-2,型芯-21,保护罩-3,底板-31,保护板-32,支撑板-33,卡扣-34。In the drawings: upper mold-1, cavity-11, top plate-12, side plate-13, lower mold-2, core-21, protective cover-3, bottom plate-31, protective plate-32, support plate- 33, Snap-34.
具体实施方式Detailed ways
为了使本技术领域的人员更好地理解本发明的技术方案,下面将结合本发明实施例中的附图,对本发明实施例中的技术方案进行清楚、完整地描述,显然,所描述的实施例仅仅是本发明一部分的实施例,而不是全部的实施例。基于本发明中的实施例,本领域普通技术人员在没有做出创造性劳动前提下所获得的所有其他实施例,都应当属于本发明保护的范围。In order to make those skilled in the art better understand the technical solutions of the present invention, the technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the accompanying drawings in the embodiments of the present invention. Obviously, the described implementation Examples are only some of the embodiments of the present invention, but not all of the embodiments. Based on the embodiments of the present invention, all other embodiments obtained by persons of ordinary skill in the art without creative efforts shall fall within the protection scope of the present invention.
实施例1 彩色浴室墙板Example 1 Color bathroom wall panel
本实施例中的彩色浴室墙板,包括片装塑料膜(SMC)基体以及形成在基体表面的彩色涂层。彩色涂层的厚度为90um,彩色涂层由粉末涂料形成,片状模塑料基体的厚度为3.5um。The colored bathroom wall panel in this embodiment includes a sheet-mounted plastic film (SMC) substrate and a colored coating formed on the surface of the substrate. The thickness of the color coating is 90um, the color coating is formed by powder coating, and the thickness of the sheet molding compound base is 3.5um.
由于粉末涂料和片装塑料膜的原料均含有不饱和聚酯树脂,二者在热压时,不饱和聚酯树脂中的双键打开后连接,将彩色涂层和片状模塑料基体通过碳碳键的化学键连接起来,使得彩色涂层与基体之间的连接牢固,且可以通过改变粉末涂料中添加的颜料的不同改变彩色涂层的颜色,使得浴室墙板的外观更加多样化。Since the raw materials of the powder coating and the sheet-packed plastic film both contain unsaturated polyester resin, when the two are hot-pressed, the double bond in the unsaturated polyester resin is opened and connected, and the color coating and the sheet-like molding compound matrix are passed through carbon The chemical bonds of carbon bonds are connected to make the connection between the color coating and the substrate firm, and the color of the color coating can be changed by changing the pigment added in the powder coating, which makes the appearance of the bathroom wall panel more diverse.
实施例2 彩色浴室墙板的制备方法Embodiment 2 The preparation method of colored bathroom wall panel
本实施例提供了一种实施例1中彩色浴室墙板的制备方法,具体包括如下步骤:This embodiment provides a method for preparing the colored bathroom wall panel in Embodiment 1, which specifically includes the following steps:
1)粉末涂料的制备1) Preparation of powder coating
1.1)先按照如下组分将不饱和聚酯树脂、固化剂、流平剂、钛白粉、颜料 以及助剂等成分进行预混合。1.1) Pre-mix unsaturated polyester resin, curing agent, leveling agent, titanium dioxide, pigment and auxiliary according to the following components.
Figure PCTCN2020132803-appb-000004
Figure PCTCN2020132803-appb-000004
1.2)将步骤1)中预混合得到的物质进行熔融后挤出,并进行粉碎后得到预定粒径的粉末,即得到本实施例中的粉末涂料。1.2) The material obtained by premixing in step 1) is extruded after being melted, and pulverized to obtain a powder with a predetermined particle size, that is, the powder coating in this embodiment is obtained.
本实施例中得到的粉末涂料为红色,密度为1.3g/cm 3,粒径为40um,软化点温度为140℃。 The powder coating obtained in this example is red, the density is 1.3g/cm 3 , the particle size is 40um, and the softening point temperature is 140°C.
2)片状模塑料的制备:2) Preparation of sheet molding compound:
2.1)先按照如下组分将不饱和聚酯树脂、固化剂、偶联剂、填料、苯乙烯和助剂以及玻璃纤维等混合制成树脂糊。2.1) First, according to the following components, mix unsaturated polyester resin, curing agent, coupling agent, filler, styrene, auxiliary agent and glass fiber to make resin paste.
本实施例中,片状模塑料具体包括如下重量份的原料,其中E4为促进剂异辛酸钴:In this embodiment, the sheet molding compound specifically includes the following raw materials by weight, wherein E4 is the accelerator cobalt isooctanoate:
Figure PCTCN2020132803-appb-000005
Figure PCTCN2020132803-appb-000005
2.2)通过刮刀,将混合均匀的树脂糊均匀涂敷在PE膜上;再通过调节切割器,切割玻璃纤维,控制玻璃纤维的长度;将PE膜相对粘贴,形成一种上、下均覆有PE膜的片材,再将片材通过压实机压挤,使玻璃纤维与树脂充分浸渍,成型为片材,然后进行收卷。2.2) Apply the mixed resin paste evenly on the PE film by the scraper; then adjust the cutter to cut the glass fiber to control the length of the glass fiber; paste the PE film relatively to form a kind of upper and lower covered with The sheet of PE film is then squeezed by a compactor to fully impregnate the glass fiber with the resin, form a sheet, and then roll it up.
2.3)将收卷的片材运到增稠室增稠,增稠室的温度设置为45℃,增稠时间为24h,得到片状模塑料。2.3) The rolled sheet is transported to a thickening chamber for thickening, the temperature of the thickening chamber is set to 45°C, and the thickening time is 24 hours to obtain a sheet molding compound.
3)喷涂3) Spraying
如图1所示,本实施例中采用的模具包括相互配合的上模1和下模2,上模 1具有型腔11,下模2具有型芯21,模压时,上模1下压,通过上模1的型腔11以及下模2的型芯21,将位于上模1和下模2之间的物质挤压呈预定的形状,形成产品。上模1具有顶板12和侧板13,顶板12和侧板13之间形成型腔11;喷涂时,将粉末涂料喷涂至顶板12的内表面上。As shown in Figure 1, the mold used in this embodiment includes an upper mold 1 and a lower mold 2 that cooperate with each other. The upper mold 1 has a cavity 11, and the lower mold 2 has a core 21. During molding, the upper mold 1 is pressed down, Through the cavity 11 of the upper die 1 and the core 21 of the lower die 2, the substance located between the upper die 1 and the lower die 2 is extruded into a predetermined shape to form a product. The upper mold 1 has a top plate 12 and a side plate 13 , and a cavity 11 is formed between the top plate 12 and the side plate 13 ; when spraying, powder coating is sprayed on the inner surface of the top plate 12 .
现有的上模1与下模2在模压时,上模1的侧板13与下模2的型芯21会有一定的间距,以便在模压时,将型腔11内的气体排出。在本发明中,由于需要在型腔11内喷涂粉末涂料,会导致合模时上模1的侧板13与型芯21之间的距离减少,模具剪切边的排气通道减少,导致最后的产品容易产生气泡,良品率下降。所以在喷涂粉末涂料的时候保证其主要位于顶板12的内表面上,避免其附着在侧板13上,防止侧板13与型芯21之间的距离减少。When the existing upper mold 1 and lower mold 2 are being molded, there is a certain distance between the side plate 13 of the upper mold 1 and the core 21 of the lower mold 2, so as to discharge the gas in the cavity 11 during molding. In the present invention, since powder coating needs to be sprayed in the cavity 11, the distance between the side plate 13 of the upper mold 1 and the core 21 will be reduced when the mold is closed, and the exhaust passage of the cutting edge of the mold will be reduced, resulting in the final The products are prone to bubbles and the yield rate drops. Therefore, when spraying the powder coating, ensure that it is mainly located on the inner surface of the top plate 12 to prevent it from adhering to the side plate 13 and prevent the distance between the side plate 13 and the core 21 from being reduced.
如图1所示,为了解决上述问题,本申请中在喷涂时采用保护罩3罩住侧板13,使顶板12的内表面裸露,这样在喷涂时,粉末涂料主要集中在顶板12的内表面上,避免了侧板13与型芯21之间的距离减少。As shown in FIG. 1 , in order to solve the above problems, in the present application, the protective cover 3 is used to cover the side plate 13 during spraying, so that the inner surface of the top plate 12 is exposed, so that the powder coating is mainly concentrated on the inner surface of the top plate 12 during spraying. On the other hand, the reduction of the distance between the side plate 13 and the core 21 is avoided.
具体的,本实施例中的保护罩3具有底板31以及支撑在底板31上的保护板32和支撑板33,侧板13位于支撑板33和保护板32之间形成的空间内,支撑板33和保护板32之间的距离与侧板13的厚度相同。保护板32与侧板13的内表面贴合,支撑板33贴合在侧板13的外表面上。支撑板33的顶部还设计有卡扣34,从而将保护罩3固定在上模1上。侧板13采用杆件的形式分布在底板31的边角处,起到固定连接的作用即可。Specifically, the protective cover 3 in this embodiment has a bottom plate 31 and a protective plate 32 and a supporting plate 33 supported on the bottom plate 31. The side plate 13 is located in the space formed between the supporting plate 33 and the protective plate 32. The supporting plate 33 The distance from the protective plate 32 is the same as the thickness of the side plate 13 . The protection plate 32 is attached to the inner surface of the side plate 13 , and the support plate 33 is attached to the outer surface of the side plate 13 . The top of the support plate 33 is also designed with a buckle 34 to fix the protective cover 3 on the upper mold 1 . The side plates 13 are distributed at the corners of the bottom plate 31 in the form of rods, and only need to play the role of fixed connection.
本实施例中为了防止保护板32与顶板12之间的距离过近,顶板12内表面边缘的喷涂收到影响,所以设置保护板32靠近顶板12的一端与顶板12之间的距离为0.5cm,且该端部为斜面设置,倾斜面朝向型腔11的内部,避免对喷涂操作的影响。在其他的实施例中,该端部也可以为弧形设置。In this embodiment, in order to prevent the distance between the protective plate 32 and the top plate 12 from being too close, the spraying of the inner surface edge of the top plate 12 is affected, so the distance between the end of the protective plate 32 close to the top plate 12 and the top plate 12 is 0.5 cm , and the end is provided with an inclined surface, and the inclined surface faces the inside of the cavity 11 to avoid the influence on the spraying operation. In other embodiments, the end portion may also be arc-shaped.
以上为采用保护罩3的形式将喷涂时粉末涂料限制喷涂在顶板12的内表面上。在本发明的其他实施例中,也可以采用增大侧板13下端与型芯21边缘之间的间隙,即增大模具剪切边的间隙,如增大0.5cm,以使得喷涂粉末涂料之后,在模压时有足够的空隙排出气体。The above is the use of the protective cover 3 to limit the spraying of the powder coating on the inner surface of the top plate 12 during spraying. In other embodiments of the present invention, it is also possible to increase the gap between the lower end of the side plate 13 and the edge of the core 21, that is, to increase the gap between the cutting edges of the mold, for example, by 0.5 cm, so that after the powder coating is sprayed, the gap can be increased. , There is enough space to exhaust gas during molding.
将具有型腔11的上模1加热至150℃并保温,在型腔11的表面喷涂步骤1)中制备得到的粉末涂料,喷涂结束后等待60s,以使得粉末涂料有充分的时间软化。在静电的吸附作用以及加热后的软化下,粉末涂料由球型形成的凹凸面变成了一层平面。The upper mold 1 with the cavity 11 is heated to 150°C and kept warm, and the powder coating prepared in step 1) is sprayed on the surface of the cavity 11. After spraying, wait for 60 s to allow sufficient time for the powder coating to soften. Under the electrostatic adsorption and softening after heating, the concave-convex surface formed by the spherical shape of the powder coating becomes a flat surface.
喷涂完毕后将保护罩3取下来,准备模压。After spraying, remove the protective cover 3 and prepare for molding.
喷涂为采用静电喷涂的形式将粉末涂料均匀地喷涂至型腔11的表面,且一次喷涂完毕。喷涂前需预先设计好喷涂轨迹,按照喷涂轨迹依次喷涂,一次喷涂完成;避免在已喷涂好的涂料上重复喷涂,涂料的传热差导致重复喷涂的固化温度低,部分涂层的结合力差。且使用完毕要将静电喷涂的喷枪吹洗干净,喷枪管道及供粉通道内不可以存有粉末,留存在喷枪中的粉末容易吸水发生聚合。The spraying is to uniformly spray the powder coating on the surface of the cavity 11 in the form of electrostatic spraying, and the spraying is completed at one time. Before spraying, it is necessary to design the spraying trajectory in advance, spray according to the spraying trajectory, and complete the spraying at one time; avoid repeated spraying on the already sprayed paint, the poor heat transfer of the paint leads to the low curing temperature of repeated spraying, and the bonding force of some coatings is poor . And after use, the spray gun for electrostatic spraying should be cleaned. There should be no powder in the spray gun pipeline and powder supply channel. The powder left in the spray gun is easy to absorb water and cause polymerization.
在等待粉末涂料软化的过程中,同时将步骤2)中制备得到的片状模塑料放入下模2的型芯21上。片状模塑料的铺设面积为最终制得的彩色浴室墙板正投影面积的75%。While waiting for the powder coating to soften, the sheet molding compound prepared in step 2) is placed on the core 21 of the lower mold 2 at the same time. The laying area of the sheet molding compound is 75% of the orthographic projection area of the final colored bathroom wall panel.
模压,保持上模1温度为150℃,合模保温4min,之后开模,得到彩色浴室墙板,形成的彩色浴室墙板包括片状模塑料的基体以及形成在基体上的彩色涂层,如实施例1中所描述的。Molding, keeping the temperature of the upper mold 1 at 150°C, closing the mold for 4 minutes, and then opening the mold to obtain a colored bathroom wall panel. as described in Example 1.
模压时上模1的移动速度为0.3mm/s,模压时采用低于传统模压时模具的启动速度,使得模具内的气体缓慢、有效排出,且尽量避免上下往复排气,防止排气不良造成产品有气泡。模压结束之后的开模时,上模1的移动速度先慢后快,或通过上模1侧板13与型芯21之间的间隙向型腔11内吹气以解除模具与彩色浴室墙板之间的应力,防止产品不良。The moving speed of the upper mold 1 during molding is 0.3mm/s, and the starting speed of the mold during molding is lower than that of traditional molding, so that the gas in the mold can be discharged slowly and effectively, and the up and down reciprocating exhaust should be avoided as much as possible to prevent the cause of poor exhaust. Product has air bubbles. When the mold is opened after the molding is finished, the moving speed of the upper mold 1 is slow first and then fast, or blow air into the cavity 11 through the gap between the side plate 13 of the upper mold 1 and the core 21 to release the mold and the colored bathroom wall panel. The stress between them prevents the product from being defective.
以上为了便于叙述和方便理解,特将步骤进行了区分和编号,实际制备时,以上几个步骤如粉末涂料的制备以及片状模塑料的制备等可以同时进行或无先后顺序的进行。For the convenience of description and understanding, the steps are distinguished and numbered. In actual preparation, the above steps, such as the preparation of powder coatings and the preparation of sheet molding compounds, can be carried out simultaneously or in random order.
粉末涂料与基体均包括不饱和聚酯树脂的原料成分,粉末涂料与基体的主体成分相同,不仅使得固化条件相同、制备工艺易于控制,且在模压的时候粉末涂料与片状模塑料发生交联反应,产生部分融合,形成一体化制品,彩色涂层与基体之间化学键连接,使得最终产品的基体与彩色涂层的结合强度高,剥离强度高。Both the powder coating and the matrix include the raw material components of unsaturated polyester resin. The main components of the powder coating and the matrix are the same, which not only makes the curing conditions the same, the preparation process is easy to control, but also the powder coating and the sheet molding compound are cross-linked during molding. The reaction produces partial fusion to form an integrated product, and the color coating and the substrate are chemically bonded, so that the final product has high bonding strength and high peel strength between the substrate and the color coating.
实施例3 测试与分析Example 3 Testing and Analysis
按照GB/T13095-2008中规定的方法对实施例2制备得到的彩色浴室墙板产品进行耐剥离性、耐污、耐化学腐蚀等项目进行测试。测试结果如下:According to the method specified in GB/T13095-2008, the color bathroom wallboard products prepared in Example 2 were tested for peeling resistance, stain resistance, chemical corrosion resistance and other items. The test results are as follows:
表1 实验结果Table 1 Experimental results
Figure PCTCN2020132803-appb-000006
Figure PCTCN2020132803-appb-000006
表1表明,通过实施例2的方法制备得到的墙板产品,其在耐剥离性、耐污、耐化学腐蚀等项目上性能优异,尤其是附着力性能优异,且涂层的颜色可以多变。Table 1 shows that the wallboard product prepared by the method of Example 2 has excellent performance in items such as peel resistance, stain resistance, chemical corrosion resistance, etc., especially excellent adhesion performance, and the color of the coating can be changeable .
本申请将粉末涂料与片状模塑料结合,SMC按照正常的成形工艺压制,在模压的同时进行涂层成膜固化,减少了生产流程,降低了过程中的质量问题发生的概率,提高产品的合格率,提高生产效率,降低成本;中间环节的减少,由此生产场地、人工工资的投入均可下降;对于具有复杂形状的模压制品,更易进行表面涂装;作为底涂使用,不需要封孔打磨,不存在涂层间附着力不良引起的脱落问题。In this application, powder coating is combined with sheet molding compound, and SMC is pressed according to the normal molding process, and the coating film is formed and cured at the same time of molding, which reduces the production process, reduces the probability of quality problems in the process, and improves the product quality. Pass rate, improve production efficiency and reduce costs; reduce intermediate links, thus reducing the input of production sites and labor wages; for molded products with complex shapes, it is easier to carry out surface coating; as a primer, no sealing is required. The hole is polished, and there is no peeling problem caused by poor adhesion between coatings.
传统的液体涂料涂装,具有很多问题:步骤繁琐,工艺复杂,流程长;需要专门的喷涂车间及喷涂设备;需要污水处理装置;需要对模具表面进行处理;需要使用内脱模剂;生产的产品颜色深浅不均匀;产品容易产生气孔;涂层与基体之间的结合力差;产品耐候性能差;产品硬度较差,易刮花、耐污染性较差等。而粉末涂料与一般涂料不同,是不含溶剂的固体粉末状涂料,具有无溶剂、无污染、可回收、环保、节省能源和资源、减轻劳动强度,涂膜机械强度高等特点。采用涂料粉末与片状模塑料结合,具有工艺简单,流程短;不需要专门的喷涂车间;喷涂与产品成型同时完成;不需要污水处理;产品与涂料结合力强等诸多优点。Traditional liquid paint coating has many problems: cumbersome steps, complicated process and long process; special spraying workshop and spraying equipment are required; sewage treatment device is required; mold surface treatment is required; internal mold release agent is required; The color of the product is uneven; the product is prone to pores; the bonding force between the coating and the substrate is poor; the weather resistance of the product is poor; the product hardness is poor, it is easy to scratch, and the pollution resistance is poor. Different from general coatings, powder coatings are solvent-free solid powder coatings, which are solvent-free, pollution-free, recyclable, environmentally friendly, save energy and resources, reduce labor intensity, and have high mechanical strength of the coating film. The combination of coating powder and sheet molding compound has many advantages, such as simple process and short process; no special spraying workshop is required; spraying and product molding are completed at the same time; no sewage treatment is required;
本发明彩色整体浴室墙板的制备方法,在制作整体浴室SMC墙板时,先对制作SMC墙板的上模进行喷涂,使得型腔内表面上附着一层粉末涂料,然后将SMC原料放在下模的型芯中,进行模压,并在模压中让粉末涂料结合至SMC制品表面,形成一种彩色涂层的SMC墙板制品。使得SMC制品上色彩丰富艳丽,并且具有高耐酸碱、防腐蚀、抗老化、耐污染、易清洁等优点,一体化成型,通过模塑材料发生化学反应而结合在一起,使得制品涂料不容易脱落、附着力很强,性能得到明显的提升。In the preparation method of the colored integral bathroom wallboard of the present invention, when making the integral bathroom SMC wallboard, the upper mold for making the SMC wallboard is sprayed first, so that a layer of powder coating is attached to the inner surface of the cavity, and then the SMC raw material is placed on the bottom. In the core of the mold, molding is performed, and the powder coating is bonded to the surface of the SMC product during molding to form a color-coated SMC wallboard product. It makes SMC products rich and bright in color, and has the advantages of high acid and alkali resistance, anti-corrosion, anti-aging, anti-pollution, easy to clean, etc., integrated molding, combined by chemical reaction of molding materials, so that the product coating is not easy Falling off, strong adhesion, performance has been significantly improved.
上述实施例只为说明本发明的技术构思及特点,其目的在于让熟悉此项技术的人士能够了解本发明的内容并据以实施,并不能以此限制本发明的保护范围,凡根据本发明精神实质所作的等效变化或修饰,都应涵盖在本发明的保护范围之内。The above-mentioned embodiments are only for illustrating the technical concept and characteristics of the present invention, and their purpose is to enable those who are familiar with the technology to understand the content of the present invention and implement them accordingly, and cannot limit the scope of protection of the present invention with this. Equivalent changes or modifications made in the spirit and spirit should all be included within the protection scope of the present invention.

Claims (18)

  1. 一种彩色浴室墙板的制备方法,其特征在于,包括以下步骤:A preparation method of colored bathroom wall panel is characterized in that, comprises the following steps:
    将具有型腔的上模加热至130~155℃并保温,在所述型腔的表面喷涂粉末涂料,喷涂结束后等待至少40s,所述粉末涂料用于形成彩色涂层;heating the upper mold with the cavity to 130-155 ℃ and keeping the temperature, spraying powder coating on the surface of the cavity, waiting for at least 40s after spraying, the powder coating is used to form a color coating;
    在具有型芯的下模上放置片状模塑料,所述片状模塑料用于形成基体,所述片状模塑料的铺设面积为最终制得的彩色浴室墙板正投影面积的50%~95%;模压时合模保温1~6min,之后开模,得到彩色浴室墙板,所述彩色浴室墙板包括片状模塑料的基体以及形成在所述基体上的彩色涂层;A sheet-like molding compound is placed on the lower mold with a core, and the sheet-like molding compound is used to form the matrix, and the laying area of the sheet-like molding compound is 50%~ 95%; during molding, the mold is closed for 1 to 6 minutes, and then the mold is opened to obtain a colored bathroom wall panel, which includes a substrate of sheet molding compound and a colored coating formed on the substrate;
    所述粉末涂料与所述片状模塑料的原料成分均包括不饱和聚酯树脂,所述粉末涂料的原料成分还包括颜料;所述粉末涂料的软化点低于所述上模的加热温度;The raw material components of the powder coating and the sheet molding compound both include unsaturated polyester resins, and the raw material components of the powder coating also include pigments; the softening point of the powder coating is lower than the heating temperature of the upper mold;
    所述喷涂为采用静电喷涂的形式将粉末涂料均匀地喷涂至所述型腔的表面,且一次喷涂完毕;The spraying is to uniformly spray the powder coating on the surface of the cavity in the form of electrostatic spraying, and the spraying is completed once;
    所述上模具有顶板和侧板,所述顶板和侧板之间形成所述型腔;喷涂时,将所述粉末涂料喷涂至所述顶板的内表面上;The upper mold has a top plate and a side plate, and the cavity is formed between the top plate and the side plate; when spraying, the powder coating is sprayed on the inner surface of the top plate;
    喷涂时,采用保护罩罩住所述侧板,使所述顶板的内表面裸露,所述保护罩具有底板以及支撑在所述底板上的保护板,所述保护板与所述侧板的内表面贴合;When spraying, a protective cover is used to cover the side plate, so that the inner surface of the top plate is exposed, the protective cover has a bottom plate and a protective plate supported on the bottom plate, the protective plate and the inner surface of the side plate are fit;
    所述底板上还设置有支撑板,所述侧板位于所述支撑板和保护板之间形成的空间内,所述支撑板和保护板之间的距离与所述侧板的厚度相同;The bottom plate is also provided with a support plate, the side plate is located in the space formed between the support plate and the protection plate, and the distance between the support plate and the protection plate is the same as the thickness of the side plate;
    所述保护板与侧板的内表面贴合,所述支撑板贴合在侧板的外表面上;所述支撑板的顶部还设置有卡扣,所述卡扣用于将所述保护罩固定在所述上模上;The protection plate is attached to the inner surface of the side plate, and the support plate is attached to the outer surface of the side plate; the top of the support plate is also provided with a buckle, and the buckle is used to attach the protective cover fixed on the upper die;
    所述保护板靠近所述顶板的一端与所述顶板之间的距离为0.5~1cm;The distance between the end of the protection plate close to the top plate and the top plate is 0.5-1 cm;
    所述保护板靠近顶板的一端为斜面设置,倾斜面朝向所述型腔的内部;One end of the protection plate close to the top plate is provided with an inclined surface, and the inclined surface faces the interior of the cavity;
    所述模压时的模具温度为140~150℃,以使得所述粉末涂料与片状模塑料之间形成化学键连接;The mold temperature during the molding is 140-150° C., so as to form a chemical bond between the powder coating and the sheet molding compound;
    所述模压时上模的移动速度为0.1~3mm/s;The moving speed of the upper mold during the molding is 0.1-3 mm/s;
    所述开模时,上模的移动速度先慢后快;或,通过所述上模侧板与型芯之间的间隙向所述型腔内吹气用于解除模具与彩色浴室墙板之间的应力;When the mold is opened, the moving speed of the upper mold is first slow and then fast; or, blowing air into the cavity through the gap between the upper mold side plate and the core is used to release the mold and the colored bathroom wall panel. stress between
    所述粉末涂料的原料包括如下成分:不饱和聚酯树脂、固化剂、流平剂、钛白粉、颜料以及助剂;The raw material of the powder coating includes the following components: unsaturated polyester resin, curing agent, leveling agent, titanium dioxide, pigment and auxiliary;
    按重量份计,所述粉末涂料的原料包括如下成分:By weight, the raw materials of the powder coating include the following components:
    Figure PCTCN2020132803-appb-100001
    Figure PCTCN2020132803-appb-100001
    所述粉末涂料的制备方法包括如下步骤:将不饱和聚酯树脂、固化剂、流平剂、钛白粉、颜料以及助剂进行预混合;将预混合得到的物质进行熔融后挤出,并进行粉碎后得到预定粒径的粉末涂料;The preparation method of the powder coating comprises the following steps: premixing unsaturated polyester resin, curing agent, leveling agent, titanium dioxide, pigment and auxiliary; After pulverization, powder coating of predetermined particle size is obtained;
    所述粉末涂料的密度为1.2~1.4g/cm 3;所述粉末涂料的粒径为38-45um; The density of the powder coating is 1.2-1.4 g/cm 3 ; the particle size of the powder coating is 38-45um;
    喷涂时,所述的涂料粉末的喷涂厚度为70~120um。When spraying, the spraying thickness of the coating powder is 70-120um.
  2. 一种彩色浴室墙板的制备方法,其特征在于,包括以下步骤:A preparation method of colored bathroom wall panel is characterized in that, comprises the following steps:
    将具有型腔的上模加热至130~155℃并保温,在所述型腔的表面喷涂粉末涂料,喷涂结束后等待至少40s,所述粉末涂料用于形成彩色涂层;heating the upper mold with the cavity to 130-155 ℃ and keeping the temperature, spraying powder coating on the surface of the cavity, waiting for at least 40s after spraying, the powder coating is used to form a color coating;
    在具有型芯的下模上放置片状模塑料,所述片状模塑料用于形成基体,所述片状模塑料的铺设面积为最终制得的彩色浴室墙板正投影面积的50%~95%;模压时合模保温1~6min,之后开模,得到彩色浴室墙板,所述彩色浴室墙板包括片状模塑料的基体以及形成在所述基体上的彩色涂层;A sheet-like molding compound is placed on the lower mold with a core, and the sheet-like molding compound is used to form the matrix, and the laying area of the sheet-like molding compound is 50%~ 95%; during molding, the mold is closed for 1 to 6 minutes, and then the mold is opened to obtain a colored bathroom wall panel, which includes a substrate of sheet molding compound and a colored coating formed on the substrate;
    所述粉末涂料与所述片状模塑料的原料成分均包括不饱和聚酯树脂,所述粉末涂料的原料成分还包括颜料;所述粉末涂料的软化点低于所述上模的加热温度。The raw material components of the powder coating and the sheet molding compound both include unsaturated polyester resins, and the raw material components of the powder coating also include pigments; the softening point of the powder coating is lower than the heating temperature of the upper mold.
  3. 根据权利要求2所述的一种彩色浴室墙板的制备方法,其特征在于,所述喷涂为采用静电喷涂的形式将粉末涂料均匀地喷涂至所述型腔的表面,且一次喷涂完毕。The method for preparing a colored bathroom wall panel according to claim 2, wherein the spraying is to uniformly spray the powder coating on the surface of the cavity by electrostatic spraying, and the spraying is completed once.
  4. 根据权利要求2所述的一种彩色浴室墙板的制备方法,其特征在于,所述上模具有顶板和侧板,所述顶板和侧板之间形成所述型腔;喷涂时,将所述粉末涂料喷涂至所述顶板的内表面上。The method for preparing a colored bathroom wall panel according to claim 2, wherein the upper mold has a top plate and a side plate, and the cavity is formed between the top plate and the side plate; The powder coating is sprayed onto the inner surface of the top plate.
  5. 根据权利要求4所述的一种彩色浴室墙板的制备方法,其特征在于,喷涂时,采用保护罩罩住所述侧板,使所述顶板的内表面裸露,所述保护罩具有底板以及支撑在所述底板上的保护板,所述保护板与所述侧板的内表面贴合。The method for preparing a colored bathroom wall panel according to claim 4, characterized in that, when spraying, a protective cover is used to cover the side panel, so that the inner surface of the top panel is exposed, and the protective cover has a bottom plate and a support The protective plate on the bottom plate is attached to the inner surface of the side plate.
  6. 根据权利要求5所述的一种彩色浴室墙板的制备方法,其特征在于,所述 底板上还设置有支撑板,所述侧板位于所述支撑板和保护板之间形成的空间内,所述支撑板和保护板之间的距离与所述侧板的厚度相同。The method for preparing a colored bathroom wall panel according to claim 5, wherein a support plate is further provided on the bottom plate, and the side plate is located in the space formed between the support plate and the protection plate, The distance between the support plate and the protection plate is the same as the thickness of the side plate.
  7. 根据权利要求6所述的一种彩色浴室墙板的制备方法,其特征在于,所述保护板与侧板的内表面贴合,所述支撑板贴合在侧板的外表面上;所述支撑板的顶部还设置有卡扣,所述卡扣用于将所述保护罩固定在所述上模上。The method for preparing a colored bathroom wall panel according to claim 6, characterized in that, the protective plate is attached to the inner surface of the side panel, and the support plate is attached to the outer surface of the side panel; the The top of the support plate is also provided with a buckle, and the buckle is used to fix the protective cover on the upper mold.
  8. 根据权利要求5所述的一种彩色浴室墙板的制备方法,其特征在于,所述保护板靠近所述顶板的一端与所述顶板之间的距离为0.5~1cm。The method for preparing a colored bathroom wall panel according to claim 5, wherein the distance between the end of the protective plate close to the top panel and the top panel is 0.5-1 cm.
  9. 根据权利要求8所述的一种彩色浴室墙板的制备方法,其特征在于,所述保护板靠近顶板的一端为斜面设置,倾斜面朝向所述型腔的内部。The method for preparing a colored bathroom wall panel according to claim 8, wherein one end of the protective plate close to the top plate is provided with an inclined surface, and the inclined surface faces the interior of the cavity.
  10. 根据权利要求2所述的一种彩色浴室墙板的制备方法,其特征在于,所述模压时的模具温度为140~150℃,以使得所述粉末涂料与片状模塑料之间形成化学键连接。The method for preparing a colored bathroom wall panel according to claim 2, wherein the mold temperature during the molding is 140-150 °C, so that a chemical bond is formed between the powder coating and the sheet molding compound. .
  11. 根据权利要求2所述的一种彩色浴室墙板的制备方法,其特征在于,所述模压时上模的移动速度为0.1~3mm/s。The method for preparing a colored bathroom wall panel according to claim 2, wherein the moving speed of the upper mold during the molding is 0.1-3 mm/s.
  12. 根据权利要求11所述的一种彩色浴室墙板的制备方法,其特征在于,所述开模时,上模的移动速度先慢后快;或,通过所述上模侧板与型芯之间的间隙向所述型腔内吹气用于解除模具与彩色浴室墙板之间的应力。The method for preparing a colored bathroom wall panel according to claim 11, wherein when the mold is opened, the moving speed of the upper mold is first slow and then fast; Blowing air into the cavity is used to relieve the stress between the mold and the colored bathroom wall panel.
  13. 根据权利要求2所述的一种彩色浴室墙板的制备方法,其特征在于,所述粉末涂料的原料包括如下成分:不饱和聚酯树脂、固化剂、流平剂、钛白粉、颜料以及助剂。The method for preparing a colored bathroom wall panel according to claim 2, wherein the raw material of the powder coating comprises the following components: unsaturated polyester resin, curing agent, leveling agent, titanium dioxide, pigment and auxiliary agent.
  14. 根据权利要求13所述的一种彩色浴室墙板的制备方法,其特征在于,按重量份计,所述粉末涂料的原料包括如下成分:The method for preparing a colored bathroom wall panel according to claim 13, wherein, in parts by weight, the raw material of the powder coating comprises the following components:
    Figure PCTCN2020132803-appb-100002
    Figure PCTCN2020132803-appb-100002
  15. 根据权利要求13所述的一种彩色浴室墙板的制备方法,其特征在于,所述粉末涂料的制备方法包括如下步骤:将不饱和聚酯树脂、固化剂、流平剂、钛白粉、颜料以及助剂进行预混合;将预混合得到的物质进行熔融后挤出,并 进行粉碎后得到预定粒径的粉末涂料。The preparation method of a colored bathroom wall panel according to claim 13, wherein the preparation method of the powder coating comprises the following steps: mixing unsaturated polyester resin, curing agent, leveling agent, titanium dioxide, pigment and pre-mixing the auxiliary agent; the pre-mixed material is extruded after being melted, and pulverized to obtain a powder coating with a predetermined particle size.
  16. 根据权利要求2所述的一种彩色浴室墙板的制备方法,其特征在于,所述粉末涂料的密度为1.2~1.4g/cm 3;所述粉末涂料的粒径为38-45um。 The method for preparing a colored bathroom wall panel according to claim 2, wherein the density of the powder coating is 1.2-1.4 g/cm 3 ; the particle size of the powder coating is 38-45um.
  17. 根据权利要求2所述的一种彩色浴室墙板的制备方法,其特征在于:喷涂时,所述的涂料粉末的喷涂厚度为70~120um。The method for preparing a colored bathroom wall panel according to claim 2, wherein when spraying, the spraying thickness of the coating powder is 70-120um.
  18. 一种根据权利要求2-17任一项所述的制备方法制备得到的彩色浴室墙板,包括片状模塑料的基体以及形成在所述基体表面的彩色涂层,所述彩色涂层与所述基体之间为化学键连接。A colored bathroom wall panel prepared by the preparation method according to any one of claims 2-17, comprising a substrate of sheet molding compound and a colored coating formed on the surface of the substrate, the colored coating and the The substrates are connected by chemical bonds.
PCT/CN2020/132803 2020-11-30 2020-11-30 Multi-color bathroom wall panel and preparation method therefor WO2022110153A1 (en)

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DE3127557A1 (en) * 1981-07-11 1983-01-27 Messerschmitt-Bölkow-Blohm GmbH, 8000 München Process for the surface treatment of a heat-curable plastic moulded body
US4587160A (en) * 1983-06-13 1986-05-06 Ferro Corporation Electrostatically conductive premold coating
CN106189754A (en) * 2016-08-04 2016-12-07 龙马智能科技(常熟)有限公司 Powdery paints and there is the moulded products of described powdery paints
CN106280929A (en) * 2016-08-31 2017-01-04 苏州翰晨商贸有限公司 A kind of low-temperature setting extinction powder coating
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CN107461010A (en) * 2017-06-23 2017-12-12 苏州科逸住宅设备股份有限公司 Manufacture method for the colored decorating plate of integral bathroom
CN108395560A (en) * 2018-03-28 2018-08-14 株洲九方因赛德技术有限公司 A kind of method and its SMC products for improving SMC product surface performances

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3127557A1 (en) * 1981-07-11 1983-01-27 Messerschmitt-Bölkow-Blohm GmbH, 8000 München Process for the surface treatment of a heat-curable plastic moulded body
US4587160A (en) * 1983-06-13 1986-05-06 Ferro Corporation Electrostatically conductive premold coating
CN106189754A (en) * 2016-08-04 2016-12-07 龙马智能科技(常熟)有限公司 Powdery paints and there is the moulded products of described powdery paints
CN106366867A (en) * 2016-08-29 2017-02-01 江南载福粉末涂料(张家港)有限公司 PIMC (Powder in Mould Coating) coating for BMC (Bulk Molding Compounds)/SMC (Sheet Molding Compounds) with effect of brilliant silver metal
CN106280929A (en) * 2016-08-31 2017-01-04 苏州翰晨商贸有限公司 A kind of low-temperature setting extinction powder coating
CN107461010A (en) * 2017-06-23 2017-12-12 苏州科逸住宅设备股份有限公司 Manufacture method for the colored decorating plate of integral bathroom
CN108395560A (en) * 2018-03-28 2018-08-14 株洲九方因赛德技术有限公司 A kind of method and its SMC products for improving SMC product surface performances

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